	A	B	C	D	E	F	G	H	I	J	K
1								In title		In abstract
2	DOI	Link	Article Title	Abstract	Journal ISO Abbreviation	Cited Reference Count	Authors	Photo	Elec	Photo	Elec

3	10.1021/cr000013v	doi.org/10.1021/cr000013v	Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices		Chem. Rev.	2643	Grimsdale, AC	FALSE	TRUE	FALSE	FALSE
4	10.1016/0022-328X(92)83346-J	doi.org/10.1016/0022-328X(92)83346-J	NICKEL, PALLADIUM AND PLATINUM, SURVEY COVERING THE YEARS 1984 AND 1985		J. Organomet. Chem.	2346	CHALONER, PA	FALSE	FALSE	FALSE	FALSE
5	10.1021/acs.chemrev.8b00507	doi.org/10.1021/acs.chemrev.8b00507	3d Transition Metals for C-H Activation		Chem. Rev.	2011	Ackermann, L	FALSE	FALSE	FALSE	FALSE
6	10.1016/S0010-8545(02)00122-4	doi.org/10.1016/S0010-8545(02)00122-4	Transition metals in organic synthesis: highlights for the year 2000		Coord. Chem. Rev.	1786	Soderberg, BCG	FALSE	FALSE	FALSE	FALSE
7	10.1021/cr3002966	doi.org/10.1021/cr3002966	Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs		Chem. Rev.	1705	Mongin, F	FALSE	FALSE	FALSE	FALSE
8	10.1021/cr500425u	doi.org/10.1021/cr500425u	Iron Catalysis in Organic Synthesis		Chem. Rev.	1650	Knolker, HJ	FALSE	FALSE	FALSE	FALSE
9	10.1016/j.ccr.2004.05.002	doi.org/10.1016/j.ccr.2004.05.002	Transition metals in organic synthesis: highlights for the year 2002		Coord. Chem. Rev.	1606	Soderberg, BCG	FALSE	FALSE	FALSE	FALSE
10	10.1016/S0010-8545(01)00401-5	doi.org/10.1016/S0010-8545(01)00401-5	Transition metals in organic synthesis: highlights for the year 1999		Coord. Chem. Rev.	1575	Soderberg, BCG	FALSE	FALSE	FALSE	FALSE
11	10.1016/j.ccr.2007.03.011	doi.org/10.1016/j.ccr.2007.03.011	Transition metals in organic synthesis: Highlights for the year 2005		Coord. Chem. Rev.	1532	Soderberg, BCG	FALSE	FALSE	FALSE	FALSE
12	10.1039/d0cs00688b	doi.org/10.1039/d0cs00688b	Organic synthesis with the most abundant transition metal-iron: from rust to multitasking catalysts	C-Glycosides in which the interglycosidic oxygen atom have been replaced by carbon atom are widely found in natural products and drug molecules. They have better enzymatic and hydrolytic stablility compared to their corresponding O-glycosides and N-glycosides. The syntheses of them have received considerable attention because of their unique chemical structure and extensive application value. Rencent advances in the synthesis of C-glycosides through coupling reactions catalyzed by transition metal are summarized in this review. A summary of the advantages and disadavatages of different synthetic methods will be beneficial to the develepment of new synthetic method for C-glycosides.	Chem. Soc. Rev.	1524	Rana, S	FALSE	FALSE	FALSE	FALSE
13	10.1016/S0010-8545(03)00123-1	doi.org/10.1016/S0010-8545(03)00123-1	Transition metals in organic synthesis: highlights for the year 2001		Coord. Chem. Rev.	1515	Soderberg, BCG	FALSE	FALSE	FALSE	FALSE
14	10.1016/j.ccr.2006.02.031	doi.org/10.1016/j.ccr.2006.02.031	Transition metals in organic synthesis: Highlights for the year 2004		Coord. Chem. Rev.	1411	Soderberg, BCG	FALSE	FALSE	FALSE	FALSE
15	10.1021/cr900157q	doi.org/10.1021/cr900157q	Dendron-Mediated Self-Assembly, Disassembly, and Self-Organization of Complex Systems		Chem. Rev.	1352	Percec, V	FALSE	FALSE	FALSE	FALSE
16	10.1016/0022-328X(92)80047-2	doi.org/10.1016/0022-328X(92)80047-2	NICKEL, PALLADIUM AND PLATINUM, ANNUAL SURVEY, 1986		J. Organomet. Chem.	1222	CHALONER, PA	FALSE	FALSE	FALSE	FALSE
17	10.1021/cr020101a	doi.org/10.1021/cr020101a	Metalated heterocycles and their applications in synthetic organic chemistry		Chem. Rev.	1220	Chinchilla, R	FALSE	FALSE	FALSE	FALSE
18	10.1021/cr400230c	doi.org/10.1021/cr400230c	Sulfamic Acid and Its N- and O-Substituted Derivatives		Chem. Rev.	1211	Spillane, W	FALSE	FALSE	FALSE	FALSE
19	10.1021/cr1002276	doi.org/10.1021/cr1002276	Transmetalation of Unsaturated Carbon Nucleophiles from Boron-Containing Species to the Mid to Late d-Block Metals of Relevance to Catalytic C-X Coupling Reactions (X = C, F, N, O, Pb, S, Se, Te)		Chem. Rev.	1172	Partyka, DV	FALSE	FALSE	FALSE	FALSE
20	10.1016/S0010-8545(97)00067-2	doi.org/10.1016/S0010-8545(97)00067-2	Transition metals in organic synthesis: highlights for the year 1996		Coord. Chem. Rev.	1139	Hegedus, LS	FALSE	FALSE	FALSE	FALSE
21	10.1021/cr400689s	doi.org/10.1021/cr400689s	Single Electron Transfer in Radical Ion and Radical-Mediated Organic, Materials and Polymer Synthesis		Chem. Rev.	1072	Percec, V	FALSE	TRUE	FALSE	FALSE
22	10.1021/cr900074m	doi.org/10.1021/cr900074m	N-Heterocyclic Carbenes in Late Transition Metal Catalysis		Chem. Rev.	1048	Nolan, SP	FALSE	FALSE	FALSE	FALSE
23	10.1016/S0022-328X(00)95293-8	doi.org/10.1016/S0022-328X(00)95293-8	TRANSITION-METALS IN ORGANIC-SYNTHESIS - ANNUAL SURVEY COVERING THE YEAR 1980		J. Organomet. Chem.	1047	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
24	10.1070/RCR4795	doi.org/10.1070/RCR4795	Organoelement chemistry: promising growth areas and challenges		Russ. Chem. Rev.	1045	Abakumov, GA; Bochkarev, MN; Trifonov, AA	FALSE	FALSE	FALSE	FALSE
25	10.1016/S0010-8545(97)90135-1	doi.org/10.1016/S0010-8545(97)90135-1	Transition metals in organic synthesis. Highlights for the year 1995		Coord. Chem. Rev.	1044	Hegedus, LS	FALSE	FALSE	FALSE	FALSE
26	10.1016/0022-328X(94)88094-8	doi.org/10.1016/0022-328X(94)88094-8	TRANSITION-METALS IN ORGANIC-SYNTHESIS - ANNUAL SURVEY COVERING THE YEAR 1992		J. Organomet. Chem.	1026	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
27	10.1016/S0010-8545(99)00172-1	doi.org/10.1016/S0010-8545(99)00172-1	Transition metals in organic synthesis: highlights for the year 1998 - (25th Anniversary)		Coord. Chem. Rev.	994	Hegedus, LS	FALSE	FALSE	FALSE	FALSE
28	10.1016/0022-328X(90)80193-4	doi.org/10.1016/0022-328X(90)80193-4	TRANSITION-METALS IN ORGANIC-SYNTHESIS - ANNUAL SURVEY COVERING THE YEAR 1989		J. Organomet. Chem.	985	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
29	10.1016/1381-1169(95)00130-1	doi.org/10.1016/1381-1169(95)00130-1	PROGRESS IN HYDROFORMYLATION AND CARBONYLATION		J. Mol. Catal. A-Chem.	970		FALSE	FALSE	FALSE	FALSE
30	10.1016/0022-328X(87)87187-5	doi.org/10.1016/0022-328X(87)87187-5	NICKEL, PALLADIUM AND PLATINUM, ANNUAL SURVEY COVERING THE YEAR 1981		J. Organomet. Chem.	951	CHALONER, PA	FALSE	FALSE	FALSE	FALSE
31	10.1007/s41061-020-00316-4	doi.org/10.1007/s41061-020-00316-4	Alkynoates as Versatile and Powerful Chemical Tools for the Rapid Assembly of Diverse Heterocycles under Transition-Metal Catalysis: Recent Developments and Challenges	A convenient and general zinc-catalyzed borylation of aryl diazonium salts and aryltriazenes has been developed. With bis-( pinacolato) diboron as the borylation reagent, aryldiazonium tetrafluoroborate salts and aryltriazenes were transformed into the corresponding arylboronates in moderate to excellent yields under mild conditions. As a convenient and practical methodology, no additional ligands, base, or any other additives are required here.	Top. Curr. Chem.	918	Khan, I	FALSE	FALSE	FALSE	FALSE
32	10.1021/acs.chemrev.6b00193	doi.org/10.1021/acs.chemrev.6b00193	Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse		Chem. Rev.	916	Marder, TB	FALSE	FALSE	FALSE	FALSE
33	10.1021/acs.chemrev.5b00052	doi.org/10.1021/acs.chemrev.5b00052	Isomerization of Allylbenzenes		Chem. Rev.	908	van Otterlo, WAL	FALSE	FALSE	FALSE	FALSE
34	10.1016/0010-8545(95)00000-3	doi.org/10.1016/0010-8545(95)00000-3	Transition metals in organic synthesis highlights for the year 1994		Coord. Chem. Rev.	864	Hegedus, LS	FALSE	FALSE	FALSE	FALSE
35	10.1016/0022-328X(88)80176-1	doi.org/10.1016/0022-328X(88)80176-1	TRANSITION-METALS IN ORGANIC-SYNTHESIS - ANNUAL SURVEY COVERING THE YEAR 1986		J. Organomet. Chem.	839	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
36	10.1016/0022-328X(87)87149-8	doi.org/10.1016/0022-328X(87)87149-8	COBALT, RHODIUM AND IRIDIUM - ANNUAL SURVEY COVERING THE YEAR 1985		J. Organomet. Chem.	821	MAGUE, JT	FALSE	FALSE	FALSE	FALSE
37	10.1016/0022-328X(87)87150-4	doi.org/10.1016/0022-328X(87)87150-4	NICKEL, PALLADIUM AND PLATINUM - ANNUAL SURVEY COVERING THE YEAR 1980		J. Organomet. Chem.	817	CHALONER, PA	FALSE	FALSE	FALSE	FALSE
38	10.1016/S0022-328X(00)88927-5	doi.org/10.1016/S0022-328X(00)88927-5	TRANSITION-METALS IN ORGANIC-SYNTHESIS - ANNUAL SURVEY COVERING THE YEAR 1979		J. Organomet. Chem.	803	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
39	10.1021/acs.chemrev.6b00833	doi.org/10.1021/acs.chemrev.6b00833	Methods Utilizing First-Row Transition Metals in Natural Product Total Synthesis		Chem. Rev.	800	Newhouse, TR	FALSE	FALSE	FALSE	FALSE
40	10.1021/cr9403695	doi.org/10.1021/cr9403695	Ruthenium-catalyzed reactions for organic synthesis		Chem. Rev.	785	Murahashi, SI	FALSE	FALSE	FALSE	FALSE
41	10.1016/0022-328X(85)80001-2	doi.org/10.1016/0022-328X(85)80001-2	TRANSITION-METALS IN ORGANIC-SYNTHESIS ANNUAL SURVEY COVERING THE YEAR 1983		J. Organomet. Chem.	768	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
42	10.1021/acs.chemrev.8b00144	doi.org/10.1021/acs.chemrev.8b00144	Catalytic Glycosylations in Oligosaccharide Synthesis		Chem. Rev.	761	Pedersen, CM	FALSE	FALSE	FALSE	FALSE
43	10.1021/acs.chemrev.7b00234	doi.org/10.1021/acs.chemrev.7b00234	Recent Advances in the Chemical Synthesis of C-Glycosides		Chem. Rev.	760	Yang, Y	FALSE	FALSE	FALSE	FALSE
44	10.1016/S0022-328X(00)99425-7	doi.org/10.1016/S0022-328X(00)99425-7	TRANSITION-METALS IN ORGANIC-SYNTHESIS - CARBON-CARBON BOND FORMING REACTIONS AND FUNCTIONAL-GROUP PREPARATIONS - ANNUAL SURVEY COVERING THE YEAR 1981		J. Organomet. Chem.	746	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
45	10.1021/acs.chemrev.0c00736	doi.org/10.1021/acs.chemrev.0c00736	Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications		Chem. Rev.	739	Dieguez, M	FALSE	FALSE	FALSE	FALSE
46	10.1021/acs.chemrev.8b00361	doi.org/10.1021/acs.chemrev.8b00361	Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities		Chem. Rev.	733	Vogiatzis, KD	FALSE	FALSE	FALSE	FALSE
47	10.1002/anie.201007963	doi.org/10.1002/anie.201007963	Strategies and Tactics for the Metal-Directed Synthesis of Rotaxanes, Knots, Catenanes, and Higher Order Links		Angew. Chem.-Int. Edit.	720	Leigh, DA	FALSE	FALSE	FALSE	FALSE
48	10.1021/cr000664r	doi.org/10.1021/cr000664r	Aryl-aryl bond formation one century after the discovery of the Ullmann reaction		Chem. Rev.	720	Lemaire, M	FALSE	FALSE	FALSE	FALSE
49	10.1021/acs.chemrev.1c00255	doi.org/10.1021/acs.chemrev.1c00255	First-Row d-Block Element-Catalyzed Carbon-Boron Bond Formation and Related Processes		Chem. Rev.	717	Radius, U; Marder, TB	FALSE	FALSE	FALSE	FALSE
50	10.1021/acs.chemrev.6b00237	doi.org/10.1021/acs.chemrev.6b00237	Nonclassical Routes for Amide Bond Formation		Chem. Rev.	712	de Figueiredo, RM; Campagne, JM	FALSE	FALSE	FALSE	FALSE
51	10.1016/S0022-328X(00)83205-2	doi.org/10.1016/S0022-328X(00)83205-2	MAGNESIUM - ANNUAL SURVEY COVERING THE YEAR 1977		J. Organomet. Chem.	693	HILL, EA	FALSE	FALSE	FALSE	FALSE
52	10.1002/cctc.201200592	doi.org/10.1002/cctc.201200592	Biorelevant Metals in Sustainable Metal CatalysisA Survey		ChemCatChem	688	Plietker, B	FALSE	FALSE	FALSE	FALSE
53	10.1021/cr100346g	doi.org/10.1021/cr100346g	Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals		Chem. Rev.	678	Magano, J	FALSE	FALSE	FALSE	FALSE
54	10.1021/acs.chemrev.8b00505	doi.org/10.1021/acs.chemrev.8b00505	N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt		Chem. Rev.	632	Danopoulos, AA	FALSE	FALSE	FALSE	FALSE
55	10.1021/acs.chemrev.9b00495	doi.org/10.1021/acs.chemrev.9b00495	Bidentate Directing Groups: An Efficient Tool in C-H Bond Functionalization Chemistry for the Expedient Construction of C-C Bonds		Chem. Rev.	624	Chatani, N	FALSE	FALSE	FALSE	FALSE
56	10.1016/0010-8545(87)80017-6	doi.org/10.1016/0010-8545(87)80017-6	NICKEL		Coord. Chem. Rev.	623	FOULDS, G	FALSE	FALSE	FALSE	FALSE
57	10.1016/S0022-328X(00)92308-8	doi.org/10.1016/S0022-328X(00)92308-8	TRANSITION-METAL DERIVATIVES IN ORGANIC-SYNTHESIS - ANNUAL SURVEY COVERING YEAR 1977		J. Organomet. Chem.	606	HEGEDUS, LS	FALSE	FALSE	FALSE	FALSE
58	10.1021/cr800388c	doi.org/10.1021/cr800388c	C-F Bond Activation in Organic Synthesis		Chem. Rev.	600	Amii, H	FALSE	FALSE	FALSE	FALSE
59	10.1021/acs.chemrev.5b00163	doi.org/10.1021/acs.chemrev.5b00163	Computational Studies of Synthetically Relevant Homogeneous Organometallic Catalysis Involving Ni, Pd, Ir, and Rh: An Overview of Commonly Employed DFT Methods and Mechanistic Insights		Chem. Rev.	582	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
60	10.1016/B978-0-12-407777-5.00002-6	doi.org/10.1016/B978-0-12-407777-5.00002-6	Organometallic Complexes of Pyridines Together with Diverse Heterocycles as Ligands		Adv. Heterocycl. Chem.	576	Sadimenko, AP	FALSE	FALSE	FALSE	FALSE
61	10.1021/acs.chemrev.9b00682	doi.org/10.1021/acs.chemrev.9b00682	Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis	An efficient method for the C-S bond formation via the coupling reaction of arylboronic acids with dimethyldisulfide has been developed under the metal-free conditions. This novel protocol provides an attractive route for the synthesis of aryl methyl sulfides, due to its operational simplicity, satisfactory yields, excellent functional-group tolerance, as well as the mild reaction conditions.	Chem. Rev.	574	Louie, J	FALSE	FALSE	FALSE	FALSE
62	10.1021/acs.chemrev.5b00676	doi.org/10.1021/acs.chemrev.5b00676	Additive Effects on Asymmetric Catalysis		Chem. Rev.	574	Wang, R	FALSE	FALSE	FALSE	FALSE
63	10.1002/anie.201201666	doi.org/10.1002/anie.201201666	C-H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals		Angew. Chem.-Int. Edit.	573	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
64	10.1021/acs.chemrev.8b00555	doi.org/10.1021/acs.chemrev.8b00555	First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands		Chem. Rev.	569	Schneider, S	FALSE	FALSE	FALSE	FALSE
65	10.1016/j.ica.2014.11.005	doi.org/10.1016/j.ica.2014.11.005	Nickel N-heterocyclic carbene complexes and their utility in homogeneous catalysis		Inorg. Chim. Acta	569	Ghosh, P	FALSE	FALSE	FALSE	FALSE
66	10.1021/acs.chemrev.0c00844	doi.org/10.1021/acs.chemrev.0c00844	Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis		Chem. Rev.	567	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
67	10.1070/RCR4727	doi.org/10.1070/RCR4727	Gold as a catalyst. Part I. Nucleophilic addition to the triple bonds		Russ. Chem. Rev.	567	Alyabyev, SB	FALSE	FALSE	FALSE	FALSE
68	10.1021/cr9000836	doi.org/10.1021/cr9000836	Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp(3)-Hybridized C-H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides		Chem. Rev.	557	Rossi, R	FALSE	FALSE	FALSE	FALSE
69	10.1021/jacs.6b08856	doi.org/10.1021/jacs.6b08856	Radicals: Reactive Intermediates with Translational Potential		J. Am. Chem. Soc.	553	Baran, PS	FALSE	FALSE	FALSE	FALSE
70	10.1021/acs.chemrev.7b00588	doi.org/10.1021/acs.chemrev.7b00588	Bright Side of Lignin Depolymerization: Toward New Platform Chemicals		Chem. Rev.	548	Barta, K	FALSE	FALSE	FALSE	FALSE
71	10.1021/cr500036t	doi.org/10.1021/cr500036t	The Chemistry of Transition Metals with Three-Membered Ring Heterocycles		Chem. Rev.	543	Doyle, AG	FALSE	FALSE	FALSE	FALSE
72	10.1002/marc.200900063	doi.org/10.1002/marc.200900063	Suzuki Polycondensation: Polyarylenes a la Carte		Macromol. Rapid Commun.	539	Schluter, AD	FALSE	FALSE	FALSE	FALSE
73	10.1021/cr100327p	doi.org/10.1021/cr100327p	Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners		Chem. Rev.	531	Sigman, MS	FALSE	FALSE	FALSE	FALSE
74	10.1002/anie.201903726	doi.org/10.1002/anie.201903726	The Persistent Radical Effect in Organic Synthesis		Angew. Chem.-Int. Edit.	524	Studer, A	FALSE	FALSE	FALSE	FALSE
75	10.1021/acs.chemrev.5b00155	doi.org/10.1021/acs.chemrev.5b00155	Catalytic Transformation of Lignin for the Production of Chemicals and Fuels		Chem. Rev.	523	Zhang, T	FALSE	FALSE	FALSE	FALSE
76	10.1039/d0ra02272a	doi.org/10.1039/d0ra02272a	A decennary update on applications of metal nanoparticles (MNPs) in the synthesis of nitrogen- and oxygen-containing heterocyclic scaffolds	Pd(II) complexes appended with ONO pincer type ligand were synthesized, structurally characterized and successfully applied as catalysts for regieoselective C-2 arylation of 2-oxindole via in situ C (sp(2))-OH activation in aqueous-organic media under an open atmosphere at room-temperature. This catalyst was reused up to four cycles. Favourably, the present protocol doesn't require the addition of any external oxidant, additives or phase transfer agents. (C) 2016 Elsevier B.V. All rights reserved.	RSC Adv.	512	Dhameliya, TM	FALSE	FALSE	FALSE	FALSE
77	10.1021/cr200241f	doi.org/10.1021/cr200241f	Mechanisms of Nucleophilic Organocopper(I) Reactions		Chem. Rev.	510	Nakamura, E	FALSE	FALSE	FALSE	FALSE
78	10.1021/cr400709j	doi.org/10.1021/cr400709j	Vinyl Epoxides in Organic Synthesis		Chem. Rev.	508	Chiu, P	FALSE	FALSE	FALSE	FALSE
79	10.1021/cr00039a007	doi.org/10.1021/cr00039a007	PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF ORGANOBORON COMPOUNDS		Chem. Rev.	499	MIYAURA, N	FALSE	FALSE	FALSE	FALSE
80	10.1002/ejoc.201900098	doi.org/10.1002/ejoc.201900098	Recent Developments in Radical-Mediated Transformations of Organohalides		Eur. J. Org. Chem.	498	Qin, HL	FALSE	FALSE	FALSE	FALSE
81	10.1002/anie.200901317	doi.org/10.1002/anie.200901317	Chemoselectivity and the Curious Reactivity Preferences of Functional Groups		Angew. Chem.-Int. Edit.	493	Yudin, AK	FALSE	FALSE	FALSE	FALSE
82	10.1021/cr100347k	doi.org/10.1021/cr100347k	Transition-Metal-Catalyzed C-S, C-Se, and C-Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions		Chem. Rev.	489	Beletskaya, IP	FALSE	FALSE	FALSE	FALSE
83	10.1002/adsc.201800343	doi.org/10.1002/adsc.201800343	Development of the Applications of Palladium on Charcoal in Organic Synthesis		Adv. Synth. Catal.	479	Liu, X	FALSE	FALSE	FALSE	FALSE
84	10.1039/co9970400136	doi.org/10.1039/co9970400136	Main group organometallics in synthesis		Contemp. Org. Synth.	477	Coldham, I	FALSE	FALSE	FALSE	FALSE
85	10.1039/c7gc02949g	doi.org/10.1039/c7gc02949g	Decarboxylative reactions with and without light - a comparison		Green Chem.	473	Konig, B	FALSE	FALSE	FALSE	FALSE
86	10.1016/bs.adomc.2018.07.003	doi.org/10.1016/bs.adomc.2018.07.003	C-H Bond Activation Mediated by Inorganic and Organometallic Compounds of Main Group Metals		Adv. Organometal. Chem.	472	Silvestru, C	FALSE	FALSE	FALSE	FALSE
87	10.1021/cr100259t	doi.org/10.1021/cr100259t	Nickel-Catalyzed Cross-Couplings Involving Carbon-Oxygen Bonds		Chem. Rev.	472	Garg, NK	FALSE	FALSE	FALSE	FALSE
88	10.1002/open.201600043	doi.org/10.1002/open.201600043	Chemical O-Glycosylations: An Overview		ChemistryOpen	471	Das, R	FALSE	FALSE	FALSE	FALSE
89	10.1002/adsc.201801381	doi.org/10.1002/adsc.201801381	Catalytic Synthesis of 1,2,4,5-Tetrasubstituted 1H-Imidazole Derivatives: State of the Art		Adv. Synth. Catal.	462	Rossi, R; Lessi, M	FALSE	FALSE	FALSE	FALSE
90	10.1021/cr500257c	doi.org/10.1021/cr500257c	Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C-F Bond Activation To Access Fluorinated Building Blocks		Chem. Rev.	462	Braun, T	FALSE	FALSE	FALSE	FALSE
91	10.1021/acs.chemrev.5b00695	doi.org/10.1021/acs.chemrev.5b00695	Bronsted-Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes		Chem. Rev.	460	Morris, RH	FALSE	FALSE	FALSE	FALSE
92	10.1016/S0022-328X(00)90151-7	doi.org/10.1016/S0022-328X(00)90151-7	NICKEL, PALLADIUM AND PLATINUM, ANNUAL SURVEY COVERING THE YEAR 1979		J. Organomet. Chem.	457	ROUNDHILL, DM	FALSE	FALSE	FALSE	FALSE
93	10.1016/0022-328X(84)80563-X	doi.org/10.1016/0022-328X(84)80563-X	SILICON - THE SILICON-CARBON BOND - ANNUAL SURVEY FOR THE YEAR 1982		J. Organomet. Chem.	455	LARSON, GL	FALSE	FALSE	FALSE	FALSE
94	10.1002/anie.200460842	doi.org/10.1002/anie.200460842	Efficiency in nonenzymatic kinetic resolution		Angew. Chem.-Int. Edit.	443	Vedejs, E	FALSE	FALSE	FALSE	FALSE
95	10.1002/adsc.201000144	doi.org/10.1002/adsc.201000144	Regioselective Functionalization of the Imidazole Ring via Transition Metal-Catalyzed C-N and C-C Bond Forming Reactions		Adv. Synth. Catal.	442	Rossi, R	FALSE	FALSE	FALSE	FALSE
96	10.1002/cssc.202101184	doi.org/10.1002/cssc.202101184	Catalytic Reductive Alcohol Etherifications with Carbonyl-Based Compounds or CO2 and Related Transformations for the Synthesis of Ether Derivatives		ChemSusChem	442	Adam, R; Cabrero-Antonino, JR	FALSE	FALSE	FALSE	FALSE
97	10.1039/c9cs00571d	doi.org/10.1039/c9cs00571d	Metal-catalysed C-Het (F, O, S, N) and C-C bond arylation		Chem. Soc. Rev.	442	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
98	10.1021/acs.oprd.7b00285	doi.org/10.1021/acs.oprd.7b00285	Copper-Mediated C-X Functionalization of Aryl Halides		Org. Process Res. Dev.	437	Joseph, PJA	FALSE	FALSE	FALSE	FALSE
99	10.1021/acs.chemrev.9b00634	doi.org/10.1021/acs.chemrev.9b00634	N-Heterocyclic Carbene Complexes in C-H Activation Reactions	The synthesis and characterization of a series of Group 6 metal pentacarbonyl complexes of air stable primary, secondary, and tertiary phosphines containing ferrocenylethyl substituents are reported [M(CO)(5)L: M = Cr, Mo, W; L = PH2(CH(2)CH(2)Fc), PH(CH(2)CH(2)Fc)(2), P(CH(2)CH(2)Fc)(3)]. The structure and composition of the complexes were confirmed by multinuclear NMR spectroscopy, IR and UV-Vis absorption spectroscopy, mass spectrometry, X-ray crystallography, and elemental analysis. The solid-state structural data reported revealed trends in M-C and M-P bond lengths that mirrored those of the atomic radii of the Group 6 metals involved. UV-Vis absorption spectroscopy and cyclic voltammetry highlighted characteristics consistent with electronically isolated ferrocene units including wavelengths of maximum absorption between 435 and 441 nm and reversible one-electron (per ferrocene unit) oxidation waves between 10 and -5 mV relative to the ferrocene/ferrocenium redox couple. IR spectroscopy confirmed that the s donating ability of the phosphines increased as ferrocenylethyl substituents were introduced and that the tertiary phosphine ligand described is a stronger s donor than PPh3 and a weaker s donor than PEt3, respectively.	Chem. Rev.	434	Nolan, SP	FALSE	FALSE	FALSE	FALSE
100	10.1002/cctc.201902290	doi.org/10.1002/cctc.201902290	Metal-Terpyridine Complexes in Catalytic Application - A Spotlight on the Last Decade	A catalytic asymmetric total synthesis of CPZEN-45 (1), anti-XDR-TB agent, was accomplished using a direct aldol reaction of a glycine Schiff base (3) and uridine-derived aldehyde (4) catalyzed by Zn(II)-(R,R)-linked-BINOL complex to give the desired stereoisomer selectively. The diazepinone ring system, another key structural element, was successfully constructed by vinyl halide-amide coupling promoted by Cu(I) salt. (C) 2016 Elsevier Ltd. All rights reserved.	ChemCatChem	433	Schubert, US	FALSE	FALSE	FALSE	FALSE
101	10.1016/bs.aihch.2017.10.001	doi.org/10.1016/bs.aihch.2017.10.001	Recent Advances in the Synthesis of Piperidines: Functionalization of Preexisting Ring Systems		Adv. Heterocycl. Chem.	430	Opatz, T	FALSE	FALSE	FALSE	FALSE
102	10.1002/anie.200605113	doi.org/10.1002/anie.200605113	Metal-catalyzed enantioselective allylation in asymmetric synthesis		Angew. Chem.-Int. Edit.	430	Ma, SM	FALSE	FALSE	FALSE	FALSE
103	10.1021/acs.chemrev.5b00162	doi.org/10.1021/acs.chemrev.5b00162	Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds		Chem. Rev.	427	Reisman, SE	FALSE	FALSE	FALSE	FALSE
104	10.1016/j.ccr.2017.03.007	doi.org/10.1016/j.ccr.2017.03.007	Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis		Coord. Chem. Rev.	422	Charra, V; de Fremont, P; Braunstein, P	FALSE	FALSE	FALSE	FALSE
105	10.1021/cr4003243	doi.org/10.1021/cr4003243	Electron-Deficient Diphosphines: The Impact of DIFLUORPHOS in Asymmetric Catalysis		Chem. Rev.	418	Genet, JP	FALSE	TRUE	FALSE	FALSE
106	10.1021/cr00032a009	doi.org/10.1021/cr00032a009	CATALYTIC ASYMMETRIC DIHYDROXYLATION		Chem. Rev.	417		FALSE	FALSE	FALSE	FALSE
107	10.1016/j.ccr.2020.213683	doi.org/10.1016/j.ccr.2020.213683	Strategic evolution in transition metal-catalyzed directed C-H bond activation and future directions	A nickel-catalyzed conjunctive cross-coupling between non-conjugated alkenes, aryl iodides, and alkylzinc reagents is reported. Excellent regiocontrol is achieved utilizing an 8-aminoquinoline directing group that can be readily cleaved to unmask net beta,gamma-dicarbofunctionalized carboxylic acid products. Under optimized conditions, both terminal and internal alkene substrates provided the corresponding alkyl/aryl difunctionalized products in moderate to excellent yields. The methodology developed herein represents the first three-component 1,2-dicarbofunctionalization of non-conjugated alkenes involving a C(sp(3))-C(sp(3)) reductive elimination step.	Coord. Chem. Rev.	413	Chatani, N	FALSE	FALSE	FALSE	FALSE
108	10.1021/acs.chemrev.8b00506	doi.org/10.1021/acs.chemrev.8b00506	Iridium-Catalyzed Asymmetric Allylic Substitution Reactions		Chem. Rev.	413	You, SL	FALSE	FALSE	FALSE	FALSE
109	10.1002/adsc.201700875	doi.org/10.1002/adsc.201700875	Recent Advances in the Synthesis of Aryl Nitrile Compounds		Adv. Synth. Catal.	412	Yan, GB	FALSE	FALSE	FALSE	FALSE
110	10.1039/d0dt03593a	doi.org/10.1039/d0dt03593a	Recent advances in pincer-nickel catalyzed reactions		Dalton Trans.	412	Kumar, A	FALSE	FALSE	FALSE	FALSE
111	10.1039/a906654f	doi.org/10.1039/a906654f	Asymmetric catalysts		J. Chem. Soc.-Perkin Trans. 1	411	Wills, M	FALSE	FALSE	FALSE	FALSE
112	10.1039/c6cs00150e	doi.org/10.1039/c6cs00150e	Recent advances in well-defined, late transition metal complexes that make and/or break C-N, C-O and C-S bonds		Chem. Soc. Rev.	399	Love, JA	FALSE	FALSE	FALSE	FALSE
113	10.1002/anie.202003755	doi.org/10.1002/anie.202003755	Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C-C, C-B, C-H, and C-Si Bonds		Angew. Chem.-Int. Edit.	392	Hoveyda, AH; Torker, S	FALSE	FALSE	FALSE	FALSE
114	10.1002/anie.200900013	doi.org/10.1002/anie.200900013	Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds		Angew. Chem.-Int. Edit.	385	Beller, M	FALSE	FALSE	FALSE	FALSE
115	10.2174/1385272822666181015130207	doi.org/10.2174/1385272822666181015130207	A Decennary Review of 1,3-Dicarbonyls about Three Kinds of Mechanisms		Curr. Org. Chem.	383	Huang, DY; Yan, GB	FALSE	FALSE	FALSE	FALSE
116	10.1021/acs.chemrev.0c00088	doi.org/10.1021/acs.chemrev.0c00088	Transformations of Less-Activated Phenols and Phenol Derivatives via C-O Cleavage	The recent technological evolution of reaction monitoring techniques has not been paralleled by the development of modern kinetic analyses. The analyses currently used disregard part of the data acquired, thus requiring an increased number of experiments to obtain sufficient kinetic information for a given chemical reaction. Herein, we present a simple graphical analysis method that takes advantage of the data-rich results provided by modern reaction monitoring tools. This analysis uses a variable normalization of the time scale to enable the visual comparison of entire concentration reaction profiles. As a result, the order in each component of the reaction, as well as k(obs), is determined with just a few experiments using a simple and quick mathematical data treatment. This analysis facilitates the rapid extraction of relevant kinetic information and will be a valuable tool for the study of reaction mechanisms.	Chem. Rev.	382	Li, CJ	FALSE	FALSE	FALSE	FALSE
117	10.1039/c9gc00617f	doi.org/10.1039/c9gc00617f	Solvent effects in palladium catalysed cross-coupling reactions		Green Chem.	380	Sherwood, J	FALSE	FALSE	FALSE	FALSE
118	10.1002/aoc.1367	doi.org/10.1002/aoc.1367	Three characteristic reactions of alkynes with metal compounds in organic synthesis		Appl. Organomet. Chem.	379	Omae, I	FALSE	FALSE	FALSE	FALSE
119	10.1021/acs.chemrev.8b00096	doi.org/10.1021/acs.chemrev.8b00096	High-Oxidation-State 3d Metal (Ti-Cu) Complexes with N-Heterocyclic Carbene Ligation		Chem. Rev.	377	Deng, L	FALSE	FALSE	FALSE	FALSE
120	10.1016/j.rser.2021.111103	doi.org/10.1016/j.rser.2021.111103	Late transition metal nanocomplexes: Applications for renewable energy conversion and storage		Renew. Sust. Energ. Rev.	375	Lah, NAC	FALSE	FALSE	FALSE	FALSE
121	10.1016/S0040-4020(02)01188-2	doi.org/10.1016/S0040-4020(02)01188-2	Recent applications of the Suzuki-Miyaura cross-coupling reaction in organic synthesis		Tetrahedron	371	Kotha, S	FALSE	FALSE	FALSE	FALSE
122	10.3390/catal10101111	doi.org/10.3390/catal10101111	Recent Advancements and Future Prospects in Ultrathin 2D Semiconductor-Based Photocatalysts for Water Splitting	The first example of nickel-catalyzed hydroamination of allenes is reported. The new cationic [( 3-iminophosphine) nickel( allyl)](+)catalysts have been fully characterized and act regioselectively in the catalytic hydroamination of allenes with secondary amines at room temperature.	Catalysts	368	Ahuja, R	TRUE	FALSE	FALSE	FALSE
123	10.1021/cr400628s	doi.org/10.1021/cr400628s	Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon-Carbon Bonds		Chem. Rev.	368	Jiao, N	FALSE	FALSE	FALSE	FALSE
124	10.1021/cr00036a007	doi.org/10.1021/cr00036a007	MASTERING BETA-KETO-ESTERS		Chem. Rev.	368	BENETTI, S	FALSE	FALSE	FALSE	FALSE
125	10.3762/bjoc.17.126	doi.org/10.3762/bjoc.17.126	On the application of 3d metals for C-H activation toward bioactive compounds: The key step for the synthesis of silver bullets		Beilstein J. Org. Chem.	363	Jardim, GAM; da Silva, EN	FALSE	FALSE	FALSE	FALSE
126	10.1016/j.tet.2011.06.001	doi.org/10.1016/j.tet.2011.06.001	Highly selective palladium-catalyzed Suzuki-Miyaura monocoupling reactions of ethene and arene derivatives bearing two or more electrophilic sites		Tetrahedron	360	Rossi, R	FALSE	FALSE	FALSE	FALSE
127	10.1002/ijch.202100057	doi.org/10.1002/ijch.202100057	Helical Chirality of Supramolecular Columns and Spheres Self-Organizes Complex Liquid Crystals, Crystals, and Quasicrystals		Isr. J. Chem.	357	Percec, V	FALSE	FALSE	FALSE	FALSE
128	10.1070/RCR4999	doi.org/10.1070/RCR4999	Metal-catalyzed reactions for the C(sp(2))-N bond formation: achievements of recent years		Russ. Chem. Rev.	350	Beletskaya, IP	FALSE	FALSE	FALSE	FALSE
129	10.1021/acscatal.6b01001	doi.org/10.1021/acscatal.6b01001	Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions		ACS Catal.	346	Tang, WJ	FALSE	FALSE	FALSE	FALSE
130	10.1021/acs.chemrev.8b00715	doi.org/10.1021/acs.chemrev.8b00715	Organocobalt Complexes as Sources of Carbon-Centered Radicals for Organic and Polymer Chemistries		Chem. Rev.	343	Detrembleur, C	FALSE	FALSE	FALSE	FALSE
131	10.1039/c7cs00216e	doi.org/10.1039/c7cs00216e	Complexes of Ni(I): a rare'' oxidation state of growing importance		Chem. Soc. Rev.	343	Lin, CY; Power, PP	FALSE	FALSE	FALSE	FALSE
132	10.1021/acs.chemrev.6b00692	doi.org/10.1021/acs.chemrev.6b00692	Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes		Chem. Rev.	341	Cramer, N	FALSE	FALSE	FALSE	FALSE
133	10.1021/acs.chemrev.0c00709	doi.org/10.1021/acs.chemrev.0c00709	Chlorinated Solvents: Their Advantages, Disadvantages, and Alternatives in Organic and Medicinal Chemistry	A bidentate monoanionic NHC-C-Aryl ligand framework was synthesized, and a host of Ni(II) complexes were prepared. Addition of isocyanides to these complexes led to the formation of NHC-eta(2)-iminoacyl nickel complexes. These complexes were characterized by a suite of spectroscopic techniques, including X-ray crystallography. The eta(2)-iminoacyl was shown to be displaced from the nickel center with oxidant and could then be reattached with reductant.	Chem. Rev.	338	Jordan, A	FALSE	FALSE	FALSE	FALSE
134	10.1021/cr400543u	doi.org/10.1021/cr400543u	Synthesis and Applications of Vinylaziridines and Ethynylaziridines		Chem. Rev.	337	Ohno, H	FALSE	FALSE	FALSE	FALSE
135	10.1021/acs.chemrev.0c00153	doi.org/10.1021/acs.chemrev.0c00153	Selective Decarbonylation via Transition-Metal-Catalyzed Carbon- Carbon Bond Cleavage	A Cu-catalyzed method has been identified for selective oxidative arylation of benzylic C-H bonds with arylboronic esters. The resulting 1,1-diarylalkanes are accessed directly from inexpensive alkylarenes containing primary and secondary benzylic C-H bonds, such as toluene or ethylbenzene. All catalyst components are commercially available at low cost, and the arylboronic esters are either commercially available or easily accessible from the commercially available boronic acids. The potential utility of these methods in medicinal chemistry applications is highlighted.	Chem. Rev.	336	Wei, H	FALSE	FALSE	FALSE	FALSE
136	10.1002/anie.201304268	doi.org/10.1002/anie.201304268	The Cross-Dehydrogenative Coupling of C-sp3-H Bonds: A Versatile Strategy for C-C Bond Formations		Angew. Chem.-Int. Edit.	333	Li, CJ	FALSE	FALSE	FALSE	FALSE
137	10.1002/anie.201803797	doi.org/10.1002/anie.201803797	Catalytic Isofunctional Reactions-Expanding the Repertoire of Shuttle and Metathesis Reactions		Angew. Chem.-Int. Edit.	332	Morandi, B	FALSE	FALSE	FALSE	FALSE
138	10.1002/cctc.201403057	doi.org/10.1002/cctc.201403057	Recent Applications of Magnetically Recoverable Nanocatalysts in C-C and C-X Coupling Reactions		ChemCatChem	332	Karimi, B	FALSE	FALSE	FALSE	FALSE
139	10.1002/(SICI)1521-3773(19980302)37:4<402::AID-ANIE402>3.0.CO;2-9	doi.org/10.1002/(SICI)1521-3773(19980302)37:4<402::AID-ANIE402>3.0.CO;2-9	Electroluminescent conjugated polymers - Seeing polymers in a new light		Angew. Chem.-Int. Edit.	328	Holmes, AB	FALSE	TRUE	FALSE	FALSE
140	10.1016/S0040-4020(97)10233-2	doi.org/10.1016/S0040-4020(97)10233-2	Catalytic cross-coupling reactions in biaryl synthesis		Tetrahedron	325	Stanforth, SP	FALSE	FALSE	FALSE	FALSE
141	10.1002/chem.201803642	doi.org/10.1002/chem.201803642	Recent Advances in Methylation: A Guide for Selecting Methylation Reagents		Chem.-Eur. J.	323	Chen, YT	FALSE	FALSE	FALSE	FALSE
142	10.1002/cctc.201702019	doi.org/10.1002/cctc.201702019	Recent Advances in Catalysis with Transition-Metal Pincer Compounds		ChemCatChem	323	Morales-Morales, D	FALSE	FALSE	FALSE	FALSE
143	10.1002/anie.201107017	doi.org/10.1002/anie.201107017	Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize		Angew. Chem.-Int. Edit.	322	Colacot, TJ	FALSE	FALSE	FALSE	FALSE
144	10.1002/ejoc.202101440	doi.org/10.1002/ejoc.202101440	Mechanochemical C-X/C-H Functionalization: An Alternative Strategic Access to Pharmaceuticals		Eur. J. Org. Chem.	322	Yu, JB	FALSE	FALSE	FALSE	FALSE
145	10.1002/anie.201505090	doi.org/10.1002/anie.201505090	Catalysis of Radical Reactions: A Radical Chemistry Perspective		Angew. Chem.-Int. Edit.	321	Studer, A	FALSE	FALSE	FALSE	FALSE
146	10.1016/j.jorganchem.2018.02.023	doi.org/10.1016/j.jorganchem.2018.02.023	Buchwald-Hartwig reaction: An overview		J. Organomet. Chem.	320	Heravi, MM; Zadsirjan, V	FALSE	FALSE	FALSE	FALSE
147	10.1039/d1gc01983j	doi.org/10.1039/d1gc01983j	Organic reactions in aqueous media catalyzed by nickel		Green Chem.	320	Kumar, D	FALSE	FALSE	FALSE	FALSE
148	10.1016/bs.aihch.2019.06.001	doi.org/10.1016/bs.aihch.2019.06.001	1,3-Amino alcohols and their phenol analogs in heterocyclization reactions		Adv. Heterocycl. Chem.	318	Palchykov, VA	FALSE	FALSE	FALSE	FALSE
149	10.1055/s-0037-1611852	doi.org/10.1055/s-0037-1611852	Recent Advances in Photoredox Catalysis Enabled Functionalization of alpha-Amino Acids and Peptides: Concepts, Strategies and Mechanisms		Synthesis	316	Karkas, MD	TRUE	FALSE	FALSE	FALSE
150	10.1007/12_076	doi.org/10.1007/12_076	Polyphenylene-type emissive materials: Poly(para-phenylene)s, polyfluorenes, and ladder polymers		Adv. Polym. Sci.	316	Mullen, K	FALSE	FALSE	FALSE	FALSE
151	10.1055/s-0034-1379210	doi.org/10.1055/s-0034-1379210	Chelation-Assisted Regioselective Catalytic Functionalization of C-H, C-O, C-N and C-F Bonds		Synlett	314	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
152	10.1246/bcsj.79.981	doi.org/10.1246/bcsj.79.981	Design of high-performance heterogeneous metal catalysts for green and sustainable chemistry		Bull. Chem. Soc. Jpn.	314	Kaneda, K	FALSE	FALSE	FALSE	FALSE
153	10.1016/j.scp.2021.100551	doi.org/10.1016/j.scp.2021.100551	Aqueous extracts of biomass ash as an alternative class of Green Solvents for organic transformations: A review update		SUSTAIN. CHEM. PHARM.	311	Bora, U	FALSE	FALSE	FALSE	FALSE
154	10.1016/j.tet.2005.02.026	doi.org/10.1016/j.tet.2005.02.026	Palladium-catalysed reactions of alcohols. Part B: Formation of C-C and C-N bonds from unsaturated alcohols		Tetrahedron	309	Muzart, J	FALSE	FALSE	FALSE	FALSE
155	10.1021/acs.organomet.8b00720	doi.org/10.1021/acs.organomet.8b00720	Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future		Organometallics	308	Campeau, LC	FALSE	FALSE	FALSE	FALSE
156	10.1039/b922984a	doi.org/10.1039/b922984a	Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry		Chem. Commun.	308	Clavier, H	FALSE	FALSE	FALSE	FALSE
157	10.1021/acs.chemrev.0c00564	doi.org/10.1021/acs.chemrev.0c00564	Catalytic Enantioselective Alkylation of Prochiral Enolates		Chem. Rev.	307	Evans, PA	FALSE	FALSE	FALSE	FALSE
158	10.1021/acs.jafc.8b03792	doi.org/10.1021/acs.jafc.8b03792	Palladium-Catalyzed Cross-Coupling Reactions: A Powerful Tool for the Synthesis of Agrochemicals		J. Agric. Food Chem.	305	Yang, GF	FALSE	FALSE	FALSE	FALSE
159	10.1039/c9ob00817a	doi.org/10.1039/c9ob00817a	Strategies towards the synthesis of anti-tuberculosis drugs		Org. Biomol. Chem.	304	Chandrasekhar, S	FALSE	FALSE	FALSE	FALSE
160	10.1021/jacs.1c00750	doi.org/10.1021/jacs.1c00750	Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis		J. Am. Chem. Soc.	302	Dong, VM	FALSE	FALSE	FALSE	FALSE
161	10.1002/aoc.3820	doi.org/10.1002/aoc.3820	Synthesis of phenanthridine and phenanthridinone derivatives based on Pd-catalyzed C-H activation		Appl. Organomet. Chem.	301	Rafiee, F	FALSE	FALSE	FALSE	FALSE
162	10.1016/bs.adomc.2020.02.001	doi.org/10.1016/bs.adomc.2020.02.001	Low-coordinate M(0) complexes of group 10 stabilized by phosphorus(III) ligands and N-heterocyclic carbenes		Adv. Organometal. Chem.	300	Nicasio, MC	FALSE	FALSE	FALSE	FALSE
163	10.1039/c3cs60289c	doi.org/10.1039/c3cs60289c	Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development		Chem. Soc. Rev.	299	Sambiagio, C	FALSE	FALSE	FALSE	FALSE
164	10.1021/cr9900230	doi.org/10.1021/cr9900230	Non-symmetrically substituted 1,1 '-binaphthyls in enantioselective catalysis		Chem. Rev.	299	Kocovsky, P	FALSE	FALSE	FALSE	FALSE
165	10.1002/ijch.202000004	doi.org/10.1002/ijch.202000004	Merging Macromolecular and Supramolecular Chemistry into Bioinspired Synthesis of Complex Systems		Isr. J. Chem.	298	Percec, V	FALSE	FALSE	FALSE	FALSE
166	10.1016/bs.adomc.2015.02.002	doi.org/10.1016/bs.adomc.2015.02.002	Poly-NHC Complexes of Transition Metals: Recent Applications and New Trends		Adv. Organometal. Chem.	295	Biffis, A	FALSE	FALSE	FALSE	FALSE
167	10.2174/1570193X18666210713111447	doi.org/10.2174/1570193X18666210713111447	C-methylation of Organic Substrates: A Comprehensive Overview; Methanol as a Methylating Agent: A Case of Catalysis Versatility (Part III)#		Mini-Rev. Org. Chem.	295	Moulay, S	FALSE	FALSE	FALSE	FALSE
168	10.1002/adma.202105196	doi.org/10.1002/adma.202105196	Fiber-Based Biopolymer Processing as a Route toward Sustainability		Adv. Mater.	295	Li, CM; Kaplan, DL	FALSE	FALSE	FALSE	FALSE
169	10.1007/s13738-021-02350-5	doi.org/10.1007/s13738-021-02350-5	Synthesis of five-membered nitrogen-containing heterocycles using copper		J. Iran Chem. Soc.	295	Kaur, N	FALSE	FALSE	FALSE	FALSE
170	10.1080/07328303.2012.749264	doi.org/10.1080/07328303.2012.749264	Mechanism of Chemical Glycosylation: Focus on the Mode of Activation and Departure of Anomeric Leaving Groups		J. Carbohydr. Chem.	293	Demchenko, AV	FALSE	FALSE	FALSE	FALSE
171	10.1002/chem.201102888	doi.org/10.1002/chem.201102888	Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C?C Coupling and Other Reactions		Chem.-Eur. J.	292	Casares, JA	FALSE	FALSE	FALSE	FALSE
172	10.1002/chem.201002273	doi.org/10.1002/chem.201002273	Activation of Inert Alkenyl/Aryl C-O Bond and Its Application in Cross-Coupling Reactions		Chem.-Eur. J.	292	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
173	10.2174/1385272824666200211114540	doi.org/10.2174/1385272824666200211114540	Monodentate Trialkylphosphines: Privileged Ligands in Metal-catalyzed Cross-coupling Reactions		Curr. Org. Chem.	291	Shaughnessy, KH	FALSE	FALSE	FALSE	FALSE
174	10.1039/c9qo00747d	doi.org/10.1039/c9qo00747d	Applications of sulfuryl fluoride (SO2F2) in chemical transformations		Org. Chem. Front.	291	Qin, HL	FALSE	FALSE	FALSE	FALSE
175	10.1016/j.carres.2015.02.007	doi.org/10.1016/j.carres.2015.02.007	Common side reactions of the glycosyl donor in chemical glycosylation		Carbohydr. Res.	291	Oscarson, S	FALSE	FALSE	FALSE	FALSE
176	10.1039/c9cy01501a	doi.org/10.1039/c9cy01501a	Coordination chemistry and catalysis with secondary phosphine oxides		Catal. Sci. Technol.	287	Grabulosa, A	FALSE	FALSE	FALSE	FALSE
177	10.1021/acscatal.0c03334	doi.org/10.1021/acscatal.0c03334	Activation of C-O and C-N Bonds Using Non-Precious-Metal Catalysis	We report the development of a Pd-catalyzed process for the cross coupling of unactivated primary, secondary, and tertiary alkylcarbastannatrane nucleophiles with acyl electrophiles. Reactions involving optically active alkylcarbastannatranes occur with exceptional stereofidelity and with net retention of absolute configuration. Because the stereochemistry of the resulting products is entirely reagent-controlled, this process may be viewed as a general, alternative approach to the preparation of products typically accessed via asymmetric enolate methodologies. Additionally, we report a new method for the preparation of optically active alkylcarbastannatranes, which should facilitate their future use in stereospecific reactions.	ACS Catal.	285	Garg, NK	FALSE	FALSE	FALSE	FALSE
178	10.1016/j.ccr.2014.02.023	doi.org/10.1016/j.ccr.2014.02.023	DFT flavor of coordination chemistry		Coord. Chem. Rev.	285	Tsipis, AC	FALSE	FALSE	FALSE	FALSE
179	10.1016/S0040-4020(01)82073-1	doi.org/10.1016/S0040-4020(01)82073-1	RECENT ADVANCES IN ASYMMETRIC-SYNTHESIS .2.		Tetrahedron	284	APSIMON, JW	FALSE	FALSE	FALSE	FALSE
180	10.1016/j.apmt.2021.101125	doi.org/10.1016/j.apmt.2021.101125	Plasmon-mediated photochemical transformation of inorganic nanocrystals		Appl. Mater. Today	284	Lu, G	FALSE	FALSE	FALSE	FALSE
181	10.1055/s-0030-1259104	doi.org/10.1055/s-0030-1259104	Palladium-Catalyzed Synthesis of N- and O-Heterocycles Starting from Enol Phosphates		Synlett	283	Fuwa, H	FALSE	FALSE	FALSE	FALSE
182	10.1016/S0040-4020(03)00866-4	doi.org/10.1016/S0040-4020(03)00866-4	Palladium-catalysed oxidation of primary and secondary alcohols		Tetrahedron	283	Muzart, J	FALSE	FALSE	FALSE	FALSE
183	10.1021/acscatal.1c01421	doi.org/10.1021/acscatal.1c01421	Transition-Metal-Catalyzed Functionalization of Alkynes with Organoboron Reagents: New Trends, Mechanistic Insights, and Applications		ACS Catal.	283	Corpas, J; Arrayas, RG	FALSE	FALSE	FALSE	FALSE
184	10.1016/0022-328X(88)83167-X	doi.org/10.1016/0022-328X(88)83167-X	ANNUAL SURVEY OF RUTHENIUM AND OSMIUM FOR THE YEAR 1985		J. Organomet. Chem.	282	SHAPLEY, PA	FALSE	FALSE	FALSE	FALSE
185	10.1002/cplu.202000606	doi.org/10.1002/cplu.202000606	Emerging Concepts in Carbon Nitride Organic Photocatalysis	A large number of reports describe the formation of the fundamental C-N bond in homogeneous catalysis. Among them, only a few are able to introduce the unprotected amino group, despite the appealing insertion of this key functional group. Recently, a broad range of methods have been reported that enable direct access to the primary amine using either ammonia or other nitrogen sources. In this short re view, we illustrate the progress achieved in this field.	ChemPlusChem	281	Savateev, A	TRUE	FALSE	FALSE	FALSE
186	10.1021/acs.chemrev.5b00138	doi.org/10.1021/acs.chemrev.5b00138	Catalytic C-C Bond Activations via Oxidative Addition to Transition Metals		Chem. Rev.	281	Cramer, N	FALSE	FALSE	FALSE	FALSE
187	10.1039/c5cs00183h	doi.org/10.1039/c5cs00183h	New advances in nanographene chemistry		Chem. Soc. Rev.	280	Mullen, K	FALSE	FALSE	FALSE	FALSE
188	10.1002/anie.202010631	doi.org/10.1002/anie.202010631	The 2-Pyridyl Problem: Challenging Nucleophiles in Cross-Coupling Arylations	Transition metal-catalysed cross-coupling is one of the most powerful synthetic methods and has led to vast improvements in the synthesis of pharmaceuticals, agrochemicals and precursors for materials chemistry. A major advance in cross-coupling over the past 20 years is the utilization of well-defined, bench-stable Pd and Ni precatalysts that do not require the addition of free ancillary ligand, which can hinder catalysis by occupying open coordination sites on the metal. The development of precatalysts has resulted in new reactions and expanded substrate scopes, enabling transformations under milder conditions and with lower catalyst loadings. This Review highlights recent advances in the development of Pd and Ni precatalysts for cross-coupling, and provides a critical comparison between the state of the art in Pd- and Ni-based systems.	Angew. Chem.-Int. Edit.	279	Willis, MC	FALSE	FALSE	FALSE	FALSE
189	10.1016/j.arabjc.2015.06.012	doi.org/10.1016/j.arabjc.2015.06.012	Recent advances in 4-hydroxycoumarin chemistry. Part 1: Synthesis and reactions		Arab. J. Chem.	279	Abdou, MM	FALSE	FALSE	FALSE	FALSE
190	10.1055/s-0030-1257960	doi.org/10.1055/s-0030-1257960	Transition-Metal-Catalyzed C-P Cross-Coupling Reactions		Synthesis	279	Oestreich, M	FALSE	FALSE	FALSE	FALSE
191	10.1021/acsmaterialslett.0c00206	doi.org/10.1021/acsmaterialslett.0c00206	Recent Advances in C-H Activation for the Synthesis of pi-Extended Materials	This account summarizes our recent progress on the copper-catalyzed direct introduction of functionalized difluoromethylated building blocks, and more particularly, the CF2CO2Et motif. We also discuss how this work led us to develop new copper-mediated methodologies to introduce the CF2PO(OR)(2) motif, a valuable phosphate bioisostere. 1 Introduction 2 Copper-Catalyzed Introduction of the CF2CO2Et Residue 3 New Developments Toward the Introduction of the CF2PO(OEt)(2) Motif 4 Conclusion and Outlook	ACS Mater. Lett.	276	Itami, K	FALSE	FALSE	FALSE	FALSE
192	10.1021/cr400367p	doi.org/10.1021/cr400367p	Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds		Chem. Rev.	275	Mongin, F	FALSE	FALSE	FALSE	FALSE
193	10.1021/acs.joc.0c01691	doi.org/10.1021/acs.joc.0c01691	Nucleophilic Transformations of Lewis Acid-Activated Disubstituted Epoxides with Catalyst-Controlled Regioselectivity	The first continuous flow Tsuji-Trost coupling reaction between allylic compounds and various nucleophiles has been successfully achieved within only around 40 s during a single pass through a cartridge filled with palladium on carbon (Pd/C). Two methods have been designed by using the H-cube ThalesNano technology that enable the efficient production of added-value compounds on the gram scale with high productivity. Under the optimized conditions, the cartridge catalyst can be used for 60 min of continuous processing without a decrease in reactivity. A large range of substrates and nucleophiles have successfully been submitted to the standard methods, giving good-to-excellent yields and productivity.	J. Org. Chem.	274	Coates, GW	FALSE	FALSE	FALSE	FALSE
194	10.1016/j.tet.2013.11.064	doi.org/10.1016/j.tet.2013.11.064	Recent advances in the synthesis of chitooligosaccharides and congeners		Tetrahedron	273	Yang, Y	FALSE	FALSE	FALSE	FALSE
195	10.1039/d0ob02491k	doi.org/10.1039/d0ob02491k	Advances in deep eutectic solvents and water: applications in metal- and biocatalyzed processes, in the synthesis of APIs, and other biologically active compounds		Org. Biomol. Chem.	273	Perna, FM; Vitale, P; Capriati, V	FALSE	FALSE	FALSE	FALSE
196	10.1039/c2dt30118k	doi.org/10.1039/c2dt30118k	Aryl(hydro)boranes: versatile building blocks for boron-doped pi-electron materials		Dalton Trans.	271	Wagner, M	FALSE	FALSE	FALSE	FALSE
197	10.1016/j.ccr.2014.12.019	doi.org/10.1016/j.ccr.2014.12.019	Copper-NHC complexes in catalysis		Coord. Chem. Rev.	270	Cazin, CSJ	FALSE	FALSE	FALSE	FALSE
198	10.1016/S0040-4020(02)00076-5	doi.org/10.1016/S0040-4020(02)00076-5	Palladium-catalysed reactions of aryl halides with soft, non-organometallic nucleophiles		Tetrahedron	270	Prim, D	FALSE	FALSE	FALSE	FALSE
199	10.1002/adsc.202000210	doi.org/10.1002/adsc.202000210	Recent Developments in Enantioselective Multicatalyzed Tandem Reactions	A method for the reductive cross-coupling of conjugated arylalkenes and aryl bromides with hydrosilanes by cooperative palladium/copper catalysis was developed, thus resulting in the highly regioselective formation of various 1,1-diarylalkanes, including a biologically active molecule. Under the applied reaction conditions, high levels of functional-group tolerance were observed, and the reductive cross-coupling of internal alkynes with aryl bromides afforded trisubstituted alkenes.	Adv. Synth. Catal.	269	Pellissier, H	FALSE	FALSE	FALSE	FALSE
200	10.1002/ejoc.201600484	doi.org/10.1002/ejoc.201600484	Glycosylation via Transition-Metal Catalysis: Challenges and Opportunities		Eur. J. Org. Chem.	269	Zhu, JL	FALSE	FALSE	FALSE	FALSE
201	10.1016/j.apenergy.2018.09.006	doi.org/10.1016/j.apenergy.2018.09.006	Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes		Appl. Energy	267	Amin, NAS	FALSE	FALSE	FALSE	FALSE
202	10.1021/acscatal.0c03341	doi.org/10.1021/acscatal.0c03341	Recent Methodologies That Exploit Oxidative Addition of C-N Bonds to Transition Metals	Treatment of bis(2-dimethylaminoethyl) ether (BDMAE) with nickel acetate affor-ded a novel 3D nickel(II) complex [Ni(BDMAE)(H2O)(3)center dot(CH3COO)(2)center dot(H2O)(2)] under solvothermal conditions. Its crystal structure was characterized by elemental analysis, IR spectrum, PXRD and single-crystal X-ray diffraction analysis. The complex belongs to the orthorhombic system, space group C2221 with a = 8.823(2), b = 13.932(3), c = 17.563(4) angstrom, V = 2158.9(8) angstrom(3), Z = 4, C12H36N2NiO10, M-r = 427.14, D-c = 1.314 g/cm(3), F(000) = 920 and mu = 0.944 mm(-1). Single-crystal X-ray diffraction reveals that the mononuclear nickel(II) ion is six-coordinated to one oxygen, two nitrogen atoms of the BDMAE ligand and three oxygen atoms of coordinated water molecules. The complex exhibits a 3D supramolecular structure through a variety of intermolecular and intramolecular hydrogen bonding interactions. In addition, the complex has been investigated for catalytic properties towards the Henry reaction of nitromethane with p-nitrobenzaldehyde, and the results indicated that the 1-p-nitrophenyl-2-nitroethanol product was obtained in excellent yield under optimum conditions with the complex as the catalyst.	ACS Catal.	266	Bower, JF	FALSE	FALSE	FALSE	FALSE
203	10.1039/c4ra01341g	doi.org/10.1039/c4ra01341g	Synthetic methodologies of achiral diarylmethanols, diaryl and triarylmethanes (TRAMs) and medicinal properties of diaryl and triarylmethanes-an overview		RSC Adv.	265	Panda, G	FALSE	FALSE	FALSE	FALSE
204	10.1021/acs.chemrev.9b00384	doi.org/10.1021/acs.chemrev.9b00384	Methodologies and Strategies for Selective Borylation of C-Het and C-C Bonds	A Ni-mediated cascade to a stereoselective synthesis of trans-tetrahydronaphtho[2,3-b]furans is efficiently achieved for the first :time. The mild reductive system can be easily generated from inexpensive and air-stable materials and shows a broad positional tolerance of substituents that were previously difficult or impossible to access by other methods. Facile syntheses toward new analogues of therapeutic agents (iso)deoxypodophyllotoxin are also reported. In addition, the inherent substrate control is disclosed for the observed unique stereoselectivities during cyclizations.	Chem. Rev.	264	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
205	10.1016/bs.adomc.2016.07.001	doi.org/10.1016/bs.adomc.2016.07.001	Phenol Derivatives: Modern Electrophiles in Cross-Coupling Reactions		Adv. Organometal. Chem.	264	Martin, R	FALSE	TRUE	FALSE	FALSE
206	10.1021/acs.chemrev.0c00245	doi.org/10.1021/acs.chemrev.0c00245	Synergistic Dual Transition Metal Catalysis	A copper-mediated decarboxylative coupling of benzamides with ortho-nitrobenzoic acids by 8-aminoquinoline-directed C-H cleavage has been developed. This reaction proceeds smoothly with only a copper salt to produce the corresponding biaryl compounds in good yields. The products can be easily transformed into various nitrogen-containing heterocyclic compounds. Moreover, the combination of copper and a suitable base promotes a decarboxylative C-H arylation and cyclization sequence to deliver phenanthridinone derivatives in one pot.	Chem. Rev.	262	Lee, SG	FALSE	FALSE	FALSE	FALSE
207	10.1039/c8gc01276h	doi.org/10.1039/c8gc01276h	Key Green Chemistry research areas from a pharmaceutical manufacturers' perspective revisited		Green Chem.	261	Hayler, JD	FALSE	FALSE	FALSE	FALSE
208	10.1016/j.ccr.2019.01.012	doi.org/10.1016/j.ccr.2019.01.012	The Suzuki-Miyaura reaction after the Nobel prize		Coord. Chem. Rev.	260	Beletskaya, IP	FALSE	FALSE	FALSE	FALSE
209	10.1007/978-3-642-12073-2_3	doi.org/10.1007/978-3-642-12073-2_3	Organometallic Approaches to Carbon-Sulfur Bond Formation		Top. Organomet. Chem.	258	Love, JA	FALSE	FALSE	FALSE	FALSE
210	10.1021/cr000666b	doi.org/10.1021/cr000666b	Non-metathesis ruthenium-catalyzed C-C bond formation		Chem. Rev.	258	Trost, BM	FALSE	FALSE	FALSE	FALSE
211	10.1039/d1dt01754c	doi.org/10.1039/d1dt01754c	Trends in computational molecular catalyst design		Dalton Trans.	258	Szilvasi, T	FALSE	FALSE	FALSE	FALSE
212	10.1070/RCR4855	doi.org/10.1070/RCR4855	Cyclization of ortho-ethynylbiaryls as an emerging versatile tool for the construction of polycyclic arenes		Russ. Chem. Rev.	257	Pankova, AS	FALSE	FALSE	FALSE	FALSE
213	10.1002/aoc.1480	doi.org/10.1002/aoc.1480	Characteristic reactions of group 9 transition metal compounds in organic synthesis		Appl. Organomet. Chem.	257	Omae, I	FALSE	FALSE	FALSE	FALSE
214	10.3390/molecules27010095	doi.org/10.3390/molecules27010095	Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands		Molecules	257	Neshat, A	FALSE	FALSE	FALSE	FALSE
215	10.1039/d0cs00702a	doi.org/10.1039/d0cs00702a	Catalytic asymmetric transformations of oxa- and azabicyclic alkenes	A series of robust N-heterocyclic carbene palladacycles have been successfully developed. These showed high catalytic activity and selectivity toward the challenging amination of N-heteroaryl chlorides. Different primary and secondary amines were fully compatible with this catalytic system. Remarkably, no double amination products could be detected when primary amines were utilized in our catalytic transformation. Furthermore, the protocol has been successfully extended to synthesize rosiglitazone, a clinical drug for diabetes mellitus, highlighting its potential pharmaceutical feasibility.	Chem. Soc. Rev.	256	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
216	10.1002/chem.202004375	doi.org/10.1002/chem.202004375	Isoindolinone Synthesis via One-Pot Type Transition Metal Catalyzed C-C Bond Forming Reactions	An efficient visible-light-induced decarboxylative coupling between alpha, beta-unsaturated carboxylic acids and alkyl N-hydroxyphthalimide esters has been developed. A wide range of redox-active esters derived from aliphatic carboxylic acids (1 degrees, 2 degrees and 3 degrees) proved viable in this dual decarboxylation process, affording a broad scope of substituted alkenes in moderate to excellent yields with good E/Z selectivities. This redox-neutral procedure was highlighted by its mild conditions, operational simplicity, easy accessibility of carboxylic acids, and excellent functional-group tolerance.	Chem.-Eur. J.	256	Savela, R	FALSE	FALSE	FALSE	FALSE
217	10.1039/c8ra04481c	doi.org/10.1039/c8ra04481c	Scope and advances in the catalytic propargylic substitution reaction		RSC Adv.	256	Saha, S	FALSE	FALSE	FALSE	FALSE
218	10.1002/chem.202003580	doi.org/10.1002/chem.202003580	Organic Superbases in Recent Synthetic Methodology Research	Copper-catalyzed directed decarboxylative C-N cross-coupling, which is promoted by a hypervalent iodine oxidant, provides a new strategy for the site-selective formation of aliphatic C-N bonds. Despite the great synthetic potential, the mechanism of this reaction and especially the origin of the radical species still remain controversial. To resolve this problem, herein density functional theory (DFT) calculations have been employed to elucidate the mechanistic details of this reaction. As a result, a comprehensive reaction pathway involving I-III-O bond heterolysis, single electron transfer (SET), hydrogen atom transfer (HAT), decarboxylation, proton transfer, and reductive elimination is reported. Meanwhile, analyzing the necessity of the directing groups in realizing the site selectivity, we found that the chelation of the directing group to the Cu(III) center can remarkably facilitate the proton transfer process.	Chem.-Eur. J.	255	Bandar, JS	FALSE	FALSE	FALSE	FALSE
219	10.1002/cctc.202001951	doi.org/10.1002/cctc.202001951	Cooperative Effects in Multimetallic Complexes Applied in Catalysis		ChemCatChem	255	Maity, R	FALSE	FALSE	FALSE	FALSE
220	10.1007/s11426-016-0330-3	doi.org/10.1007/s11426-016-0330-3	Advances in theoretical study on transition-metal-catalyzed C-H activation		Sci. China-Chem.	255	Jiang, YY; Bi, SW	FALSE	FALSE	FALSE	FALSE
221	10.1039/d0cy01159b	doi.org/10.1039/d0cy01159b	Palladium-catalyzed cross-couplings by C-O bond activation	Ultrasound irradiation promoted the cyclocondensation of beta-keto esters and amidines in good to excellent yields to form sixteen highly substituted 4-pyrimidinols. Tosylation of these compounds, in another ultrasound-promoted conversion, formed 4-pyrimidyl tosylates in high yields. The use of the developed protocol as an alternative route to 4-arylpyrimidines was illustrated with three examples of the Suzuki-Miyaura cross-coupling of the prepared tosylates with phenylboronic acid.	Catal. Sci. Technol.	254	Szostak, M	FALSE	FALSE	FALSE	FALSE
222	10.1016/0040-4020(80)80203-1	doi.org/10.1016/0040-4020(80)80203-1	NUCLEOPHILIC AND ORGANOMETALLIC DISPLACEMENT-REACTIONS OF ALLYLIC COMPOUNDS - STEREOCHEMISTRY AND REGIOCHEMISTRY		Tetrahedron	254	MAGID, RM	FALSE	FALSE	FALSE	FALSE
223	10.1021/acscatal.6b02374	doi.org/10.1021/acscatal.6b02374	Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents		ACS Catal.	254	Minami, Y; Hiyama, T	FALSE	FALSE	FALSE	FALSE
224	10.1039/d0cs00843e	doi.org/10.1039/d0cs00843e	Recent advances in asymmetric borylation by transition metal catalysis		Chem. Soc. Rev.	253	Hu, JF; Marder, TB	FALSE	FALSE	FALSE	FALSE
225	10.1021/acscatal.9b04186	doi.org/10.1021/acscatal.9b04186	Machine Learning for Catalysis Informatics: Recent Applications and Prospects		ACS Catal.	252	Shimizu, K	FALSE	FALSE	FALSE	FALSE
226	10.2174/1385272023373545	doi.org/10.2174/1385272023373545	Advances in ruthenium catalysis. Novel catalytic reactions via eta(3)-allylruthenium intermediates		Curr. Org. Chem.	252	Kondo, T	FALSE	FALSE	FALSE	FALSE
227	10.1021/acs.chemrev.6b00731	doi.org/10.1021/acs.chemrev.6b00731	Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations		Chem. Rev.	252	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
228	10.1039/d0qo01194k	doi.org/10.1039/d0qo01194k	A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives		Org. Chem. Front.	251	Kapdi, AR	FALSE	FALSE	FALSE	FALSE
229	10.1002/chem.201605657	doi.org/10.1002/chem.201605657	Direct Functionalization of C-H Bonds by Iron, Nickel, and Cobalt Catalysis		Chem.-Eur. J.	251	Maulide, N	FALSE	FALSE	FALSE	FALSE
230	10.1039/d1qo00162k	doi.org/10.1039/d1qo00162k	Cyanation: a photochemical approach and applications in organic synthesis		Org. Chem. Front.	250	Sharma, A	FALSE	FALSE	FALSE	FALSE
231	10.1021/cs3002513	doi.org/10.1021/cs3002513	Recent Advances in Transition Metal-Catalyzed Glycosylation		ACS Catal.	249	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
232	10.1021/cr1002744	doi.org/10.1021/cr1002744	Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions		Chem. Rev.	249	Tunge, JA	FALSE	FALSE	FALSE	FALSE
233	10.1016/S0040-4020(97)10383-0	doi.org/10.1016/S0040-4020(97)10383-0	Allylic protecting groups and their use in a complex environment - Part II: Allylic protecting groups and their removal through catalytic palladium pi-allyl methodology		Tetrahedron	248	Guibe, F	FALSE	FALSE	FALSE	FALSE
234	10.1007/3418_2011_14	doi.org/10.1007/3418_2011_14	Selectivity in Palladium-Catalyzed Allylic Substitution		Top. Organomet. Chem.	246	Poli, G	FALSE	FALSE	FALSE	FALSE
235	10.1002/chem.200902797	doi.org/10.1002/chem.200902797	Mapping the Transformation [{Ru-II(CO)(3)Cl-2}(2)]->[Ru-2(I)(CO)(4)](2+): Implications in Binuclear Water Gas Shift Chemistry		Chem.-Eur. J.	246	Bera, JK	FALSE	FALSE	FALSE	FALSE
236	10.1021/acs.organomet.6b00655	doi.org/10.1021/acs.organomet.6b00655	C(sp(3))-H Alkenylation Catalyzed by Cationic Alkylhafnium Complexes: Stereoselective Synthesis of Trisubstituted Alkenes from 2,6-Dimethylpyridines and Internal Alkynes		Organometallics	246	Tsurugi, H; Mashima, K	FALSE	FALSE	FALSE	FALSE
237	10.1039/c3ra42480d	doi.org/10.1039/c3ra42480d	Recent advances in manganese(III) acetate mediated organic synthesis		RSC Adv.	245	Bora, U	FALSE	FALSE	FALSE	FALSE
238	10.1021/acscatal.1c04705	doi.org/10.1021/acscatal.1c04705	Nickel and Palladium Catalysis: Stronger Demand than Ever		ACS Catal.	244	Chernyshev, VM; Ananikov, VP	FALSE	FALSE	FALSE	FALSE
239	10.1070/RCR4977	doi.org/10.1070/RCR4977	Progress in the medicinal chemistry of organoboron compounds		Russ. Chem. Rev.	244	Tevyashova, AN	FALSE	FALSE	FALSE	FALSE
240	10.1039/c6cc09575e	doi.org/10.1039/c6cc09575e	Organometallic chemistry using partially fluorinated benzenes		Chem. Commun.	244	Pike, SD	FALSE	FALSE	FALSE	FALSE
241	10.1246/bcsj.20190310	doi.org/10.1246/bcsj.20190310	Molecular Renovation Strategy for Expeditious Synthesis of Molecular Probes		Bull. Chem. Soc. Jpn.	243	Niwa, T; Hosoya, T	FALSE	FALSE	FALSE	FALSE
242	10.1039/c3cs60197h	doi.org/10.1039/c3cs60197h	Selection of boron reagents for Suzuki-Miyaura coupling		Chem. Soc. Rev.	243	Lloyd-Jones, GC	FALSE	FALSE	FALSE	FALSE
243	10.1039/b500952a	doi.org/10.1039/b500952a	Fast, easy, clean chemistry by using water as a solvent and microwave heating: the Suzuki coupling as an illustration		Chem. Commun.	243	Leadbeater, NE	FALSE	FALSE	FALSE	FALSE
244	10.1002/actp.1996.010470401	doi.org/10.1002/actp.1996.010470401	Trends in polymer chemistry 1995		Acta Polym.	243	Frey, H	FALSE	FALSE	FALSE	FALSE
245	10.1070/RCR4881	doi.org/10.1070/RCR4881	Metal complex catalysis in the chemistry of lower diamondoids		Russ. Chem. Rev.	242	Khusnutdinov, RI	FALSE	FALSE	FALSE	FALSE
246	10.1002/ejoc.201101616	doi.org/10.1002/ejoc.201101616	Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds		Eur. J. Org. Chem.	241	Ruhland, K	FALSE	FALSE	FALSE	FALSE
247	10.1021/cr9902749	doi.org/10.1021/cr9902749	Metal-catalyzed carbon-sulfur bond formation		Chem. Rev.	241	Mitsudo, T	FALSE	FALSE	FALSE	FALSE
248	10.1016/B978-0-12-398484-5.00002-X	doi.org/10.1016/B978-0-12-398484-5.00002-X	New Applications of Isotope Effects in the Determination of Organic Reaction Mechanisms		Adv. Phys. Organ. Chem.	240	Meyer, MP	FALSE	FALSE	FALSE	FALSE
249	10.1002/adsc.202100992	doi.org/10.1002/adsc.202100992	Transition-Metal-Catalyzed Selective Alkynylation of C-H Bonds		Adv. Synth. Catal.	240	Maiti, D	FALSE	FALSE	FALSE	FALSE
250	10.1039/c3cs60116a	doi.org/10.1039/c3cs60116a	Synthesis of binaphthyl based phosphine and phosphite ligands		Chem. Soc. Rev.	239	Pereira, MM	FALSE	FALSE	FALSE	FALSE
251	10.1039/b705664h	doi.org/10.1039/b705664h	Convergent strategies for the total synthesis of polycyclic ether marine metabolites		Nat. Prod. Rep.	239	Sasaki, M	FALSE	FALSE	FALSE	FALSE
252	10.1080/02603590390464216	doi.org/10.1080/02603590390464216	Synthesis and uses of phosphines containing P-N bonds		Comments Inorganic Chem.	239	Woollins, JD	FALSE	FALSE	FALSE	FALSE
253	10.1016/S0022-328X(00)89671-0	doi.org/10.1016/S0022-328X(00)89671-0	MAGNESIUM - ANNUAL SURVEY COVERING THE YEAR 1979		J. Organomet. Chem.	239	VILLIERAS, J	FALSE	FALSE	FALSE	FALSE
254	10.1021/acs.chemrev.0c01236	doi.org/10.1021/acs.chemrev.0c01236	Photoinduced Borylation for the Synthesis of Organoboron Compounds Focus Review	2-Deoxy glycosides are widely presented in natural products and clinical reagents. The presence of 2-deoxy glycosides is essential for bioactivities of these compounds. This report provides an overview of the recent advances in the stereoselective synthesis of 2-deoxy glycosides. Particularly, the contents of this review covered the work published since the earlier reviews on this topic by Marzabadi (2000), Lowary (2009), Ding (2012) and Nagorny (2012).	Chem. Rev.	238	Guo, XN; Radius, U; Marder, TB	TRUE	FALSE	FALSE	FALSE
255	10.1002/anie.200463007	doi.org/10.1002/anie.200463007	Organosulfur compounds: Electrophilic reagents in transition-metal-catalyzed carbon-carbon bond-forming reactions		Angew. Chem.-Int. Edit.	238	Vogel, P	FALSE	TRUE	FALSE	FALSE
256	10.1023/A:1022685801622	doi.org/10.1023/A:1022685801622	Catalytic methods for building up phosphorus-carbon bond		Russ. J. Organ. Chem.	238	Beletskaya, IP	FALSE	FALSE	FALSE	FALSE
257	10.1016/j.poly.2021.115387	doi.org/10.1016/j.poly.2021.115387	Lanthanide complexes as anticancer agents: A review		Polyhedron	238	Chauhan, NPS	FALSE	FALSE	FALSE	FALSE
258	10.1055/s-0035-1560396	doi.org/10.1055/s-0035-1560396	Recent Advances in Direct Catalytic Dehydrative Substitution of Alcohols		Synthesis	238	Moran, J	FALSE	FALSE	FALSE	FALSE
259	10.1002/slct.202000764	doi.org/10.1002/slct.202000764	Recent Advances in the Protection of Amine Functionality: A Review	The construction of C-3-symmetric triarylbenzenes via cyclotrimerization of alkynes using Amberlyst-15/1-butyl-3-methylimidazolium hexafluorophosphate [Bmim][PF6] has been developed. The catalytic system works well for various substrates under milder reaction conditions. The developed methodology is operationally simple, and metal-free, solvent-free, and additive-free reactions with excellent yields make it good for synthetic utility. The recyclability of the Amberlyst-15/[Bmim][PF6] as well as 100% atom efficiency makes the developed protocol more green.	ChemistrySelect	237	Shankarling, GS	FALSE	FALSE	FALSE	FALSE
260	10.1002/cjoc.201900371	doi.org/10.1002/cjoc.201900371	Metal-Metal Cooperation in Dinucleating Complexes Involving Late Transition Metals Directed towards Organic Catalysis		Chin. J. Chem.	237	Zeng, R	FALSE	FALSE	FALSE	FALSE
261	10.1055/s-0034-1378672	doi.org/10.1055/s-0034-1378672	Preparation of Functionalized Lithium, Magnesium, Aluminum, Zinc, Manganese, and Indium Organometallics from Functionalized Organic Halides		Synthesis	237	Knochel, P	FALSE	FALSE	FALSE	FALSE
262	10.1007/s41061-016-0012-8	doi.org/10.1007/s41061-016-0012-8	C-Alkylation by Hydrogen Autotransfer Reactions		Top. Curr. Chem.	237	Obora, Y	FALSE	FALSE	FALSE	FALSE
263	10.1002/ejic.202000206	doi.org/10.1002/ejic.202000206	Phosphines and N-Heterocycles Joining Forces: an Emerging Structural Motif in PNP-Pincer Chemistry	Recent experiments with hexagonal boron nitride (h-BN) have shown the successful covalent and non-covalent functionalization of these boron nitride nanostructures, especially nanosheets (BNNS). This paper explores the synthesis of several thiophene-based polymers with conjugated pendant groups and their reactions with BNNSs. Specifically, two phenyl carboxylic acid functionalized polythiophene polymers, poly[3-(4-methoxycarbonylphenyl) thiophene] and poly[3-(4-benzoic acid) thiophene], have been prepared and reacted with exfoliated BNNSs. The resulting complexes between the conjugated polythiophene polymers and the BNNS are reported and characterized by their reaggregation stability and by spectroscopic methods.	Eur. J. Inorg. Chem.	236	Gade, LH	FALSE	FALSE	FALSE	FALSE
264	10.1039/c3cs35521g	doi.org/10.1039/c3cs35521g	Transition-metal-catalyzed Suzuki-Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts		Chem. Soc. Rev.	236	Han, FS	FALSE	FALSE	FALSE	FALSE
265	10.1021/om401204h	doi.org/10.1021/om401204h	Ruthenium-Catalyzed Ortho-Selective C-H Alkenylation of Aromatic Compounds with Alkenyl Esters and Ethers		Organometallics	235	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
266	10.1002/anie.201205449	doi.org/10.1002/anie.201205449	Asymmetric Ion-Pairing Catalysis		Angew. Chem.-Int. Edit.	234	Jacobsen, EN	FALSE	FALSE	FALSE	FALSE
267	10.1021/om010343l	doi.org/10.1021/om010343l	Iron-mediated allylic substitution reactions with chirality transfer. Stereochemistry of the formation of diastereo- and enantiomerically enriched olefinic and allylic tetracarbonyl iron complexes		Organometallics	234	Enders, D	FALSE	FALSE	FALSE	FALSE
268	10.1039/oc9797600323	doi.org/10.1039/oc9797600323	SYNTHETIC METHODS			234	BRETTLE, R	FALSE	FALSE	FALSE	FALSE
269	10.1002/tcr.202100165	doi.org/10.1002/tcr.202100165	First-Row Transition-Metal Catalyzed Acceptorless Dehydrogenation and Related Reactions: A Personal Account		Chem. Rec.	233	Balaraman, E	FALSE	FALSE	FALSE	FALSE
270	10.3390/molecules26020249	doi.org/10.3390/molecules26020249	Modern Synthetic Methods for the Stereoselective Construction of 1,3-Dienes	The three-coordinate Ni(0) N-heterocyclic carbene complex Ni(6-Mes)(PPh3)(2) (1; 6-Mes = 1,3-bis(2,4,6-trimethylphen-yl)-3,4,5,6-tetrahydropyrimidin-2-ylidene) is formed in the reaction of Ni(cod)2 with a 1:2 mixture of 6-Mes and PPh3 or upon reduction of Ni(6-Mes)(PPh3)Br (2) with (KOBu)-Bu-t. Facile substitution of PPh3 in 1 gave a range of Ni(6-Mes)(PPh3)(L) products (L = PhGEECMe (3), PhCH=CH2 (4), Ph2CO (5), PhCHO (6)). Oxidative addition of C6F6 gave Ni(6-Mes)(PPh3)(C6F5)F (7), while 1 was also oxidized by 4-BrC6H4F to afford a mixture of 2 and Ni(6-Mes)(PPh3)(C6H4F)Br (8). Surprisingly, 1 was also oxidized upon reaction with the small 5-membered ring NHC IMe4 to give the terminal Ni(II) phosphido complex Ni(IMe4)(2)(PPh2)Ph (9). Compounds 1 and 5 proved to be active as a precursors for the catalytic transfer hydrogenation of ketones.	Molecules	231	Soengas, RG; Rodriguez-Solla, H	FALSE	FALSE	FALSE	FALSE
271	10.1007/s00706-019-2364-6	doi.org/10.1007/s00706-019-2364-6	Advances in Kumada-Tamao-Corriu cross-coupling reaction: an update		Mon. Chem.	231	Heravi, MM	FALSE	FALSE	FALSE	FALSE
272	10.1007/3418_2015_153	doi.org/10.1007/3418_2015_153	Chiral Bimetallic Lewis Acids		Top. Organomet. Chem.	231	Shibasaki, M	FALSE	FALSE	FALSE	FALSE
273	10.1039/c5ob02212f	doi.org/10.1039/c5ob02212f	Transition-metal catalyzed valorization of lignin: the key to a sustainable carbon-neutral future		Org. Biomol. Chem.	231	Stephenson, CRJ	FALSE	FALSE	FALSE	FALSE
274	10.1002/jhet.3504	doi.org/10.1002/jhet.3504	Recent Advances in the Schiff Bases and N-Heterocyclic Carbenes as Ligands in the Cross-Coupling Reactions: A Comprehensive Review		J. Heterocycl. Chem.	230	Kumar, S	FALSE	FALSE	FALSE	FALSE
275	10.1021/acs.chemrev.7b00514	doi.org/10.1021/acs.chemrev.7b00514	Substrate Directed Asymmetric Reactions		Chem. Rev.	230	Bhadra, S	FALSE	FALSE	FALSE	FALSE
276	10.1021/cr9000786	doi.org/10.1021/cr9000786	Cobalt-Catalyzed Cross-Coupling Reactions		Chem. Rev.	230	Cahiez, G	FALSE	FALSE	FALSE	FALSE
277	10.2174/1389557516666160823143243	doi.org/10.2174/1389557516666160823143243	Recent Developments of Metal and Metal Oxide Nanocatalysts in Organic Synthesis		Mini-Rev. Med. Chem.	229	Lv, PC; Zhu, HL	FALSE	FALSE	FALSE	FALSE
278	10.1039/d1ob01153g	doi.org/10.1039/d1ob01153g	Metal-ligand cooperative approaches in homogeneous catalysis using transition metal complex catalysts of redox noninnocent ligands		Org. Biomol. Chem.	229	Paul, ND	FALSE	FALSE	FALSE	FALSE
279	10.1039/d1cs00216c	doi.org/10.1039/d1cs00216c	Wonderful fusion of organofluorine chemistry and decarboxylation strategy		Chem. Soc. Rev.	228	Bouillon, JP; Couve-Bonnaire, S	FALSE	FALSE	FALSE	FALSE
280	10.1016/j.tet.2019.02.001	doi.org/10.1016/j.tet.2019.02.001	Synthesis of symmetrical biaryl compounds by homocoupling reaction		Tetrahedron	227	Stefani, HA	FALSE	FALSE	FALSE	FALSE
281	10.1002/chem.201201125	doi.org/10.1002/chem.201201125	Titanium-Catalyzed Vinylic and Allylic C-F Bond Activation-Scope, Limitations and Mechanistic Insight		Chem.-Eur. J.	227	Lentz, D	FALSE	FALSE	FALSE	FALSE
282	10.1039/c9ob01559k	doi.org/10.1039/c9ob01559k	Recent trends in catalytic sp(3) C-H functionalization of heterocycles		Org. Biomol. Chem.	226	Van Humbeck, JF	FALSE	FALSE	FALSE	FALSE
283	10.1002/med.21625	doi.org/10.1002/med.21625	Design and synthesis of glycomimetics: Recent advances		Med. Res. Rev.	226	Bernardi, A	FALSE	FALSE	FALSE	FALSE
284	10.1007/s40010-016-0289-6	doi.org/10.1007/s40010-016-0289-6	Synthesis, Structure and Reactivity of Cyclometalated Nickel(II) Complexes: A Review and Perspective		Proc. Nat. Acad. Sci. India A	226	Klein, A	FALSE	FALSE	FALSE	FALSE
285	10.1002/tcr.201500250	doi.org/10.1002/tcr.201500250	Transition-Metal-Catalyzed Direct Addition of Aryl C-H Bonds to Unsaturated Electrophiles		Chem. Rec.	225	Shi, XY	FALSE	TRUE	FALSE	FALSE
286	10.1007/s13738-018-1400-5	doi.org/10.1007/s13738-018-1400-5	Nucleophilic ring-opening of epoxides: trends in beta-substituted alcohols synthesis		J. Iran Chem. Soc.	224	Kiasat, AR	FALSE	FALSE	FALSE	FALSE
287	10.1246/bcsj.20110307	doi.org/10.1246/bcsj.20110307	Mechanistic Consideration of Asymmetric C-N and C-C Bond Formations with Bifunctional Chiral Ir and Ru Catalysts		Bull. Chem. Soc. Jpn.	224	Ikariya, T	FALSE	FALSE	FALSE	FALSE
288	10.1021/om200115y	doi.org/10.1021/om200115y	Mechanisms of Reactions of a Lithium Boryl with Organohalides		Organometallics	224	Marder, TB	FALSE	FALSE	FALSE	FALSE
289	10.1021/ja3096174	doi.org/10.1021/ja3096174	Rhodium-Catalyzed Carbon-Silicon Bond Activation for Synthesis of Benzosilole Derivatives		J. Am. Chem. Soc.	223	Tobisu, M	FALSE	FALSE	FALSE	FALSE
290	10.1002/cjoc.201900468	doi.org/10.1002/cjoc.201900468	Ni-Catalyzed Chelation-Assisted Direct Functionalization of Inert C-H Bonds	The development of an intramolecular rhodium(I)-catalyzed Pauson-Khand reaction of alkoxyallene-ynes with a proximal alkoxy group is reported. This reaction, in the presence of a [Rh(cycloocta-1,5-diene)Cl](2)/propane-1,3-diylbis(diphenylphosphane) system under a CO atmosphere, constitutes a powerful tool for selectively accessing carbo- and heterobicyclo[5.3.0] frameworks featuring an enol ether moiety. Through this procedure, a straightforward access to guaiane skeletons with a tertiary hydroxy group at the C10 position was achieved.	Chin. J. Chem.	222	Shi, BF	FALSE	FALSE	FALSE	FALSE
291	10.1002/tcr.201700022	doi.org/10.1002/tcr.201700022	Recent Progress in Application of Graphene Supported Metal Nanoparticles in C-C and C-X Coupling Reactions		Chem. Rec.	222	Nasrollahzadeh, M	FALSE	FALSE	FALSE	FALSE
292	10.1021/cr00091a007	doi.org/10.1021/cr00091a007	ENANTIOSELECTIVE HOMOGENEOUS CATALYSIS INVOLVING TRANSITION-METAL ALLYL INTERMEDIATES		Chem. Rev.	222		FALSE	FALSE	FALSE	FALSE
293	10.1039/d0gc02404j	doi.org/10.1039/d0gc02404j	Sustainable flow approaches to active pharmaceutical ingredients	Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle.	Green Chem.	221	Vaccaro, L	FALSE	FALSE	FALSE	FALSE
294	10.1002/anie.201205343	doi.org/10.1002/anie.201205343	Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications		Angew. Chem.-Int. Edit.	221	List, B	FALSE	FALSE	FALSE	FALSE
295	10.1002/ejic.201700397	doi.org/10.1002/ejic.201700397	What Wanzlick Did Not Dare To Dream: Cyclic (Alkyl)(amino) carbenes (cAACs) as New Key Players in Transition-Metal Chemistry		Eur. J. Inorg. Chem.	221	Radius, U	FALSE	FALSE	FALSE	FALSE
296	10.1016/j.ccr.2006.02.033	doi.org/10.1016/j.ccr.2006.02.033	N-phosphino carboxylic acid amides, lactams and ureas: Synthesis, properties and applications		Coord. Chem. Rev.	220	Kuhl, O	FALSE	FALSE	FALSE	FALSE
297	10.1055/s-2005-923611	doi.org/10.1055/s-2005-923611	2-Pyridylsilyl group: A useful multifunctional group in organic synthesis		Synlett	220	Itami, K	FALSE	FALSE	FALSE	FALSE
298	10.2174/0929867033456738	doi.org/10.2174/0929867033456738	Diversity oriented synthesis and branching reaction pathway to generate natural product-like compounds		Curr. Med. Chem.	219	Yang, Z	FALSE	FALSE	FALSE	FALSE
299	10.5059/yukigoseikyokaishi.51.894	doi.org/10.5059/yukigoseikyokaishi.51.894	STEREOSELECTIVE SYNTHESES OF POLYSUBSTITUTED OLEFINS		J. Synth. Org. Chem. Jpn.	219	INOUE, S	FALSE	FALSE	FALSE	FALSE
300	10.1021/acs.chemrev.6b00772	doi.org/10.1021/acs.chemrev.6b00772	Iron-Catalyzed C-H Bond Activation		Chem. Rev.	219	Ilies, L; Nakamura, E	FALSE	FALSE	FALSE	FALSE
301	10.1021/acscatal.8b04357	doi.org/10.1021/acscatal.8b04357	Asymmetric Transition-Metal Catalysis in the Formation and Functionalization of Metal Enolates		ACS Catal.	218	Sebesta, R	FALSE	FALSE	FALSE	FALSE
302	10.1039/c8cc07093h	doi.org/10.1039/c8cc07093h	Asymmetric synthesis via stereospecific C-N and C-O bond activation of alkyl amine and alcohol derivatives		Chem. Commun.	218	Watson, MP	FALSE	FALSE	FALSE	FALSE
303	10.1021/jacs.1c12198	doi.org/10.1021/jacs.1c12198	Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions		J. Am. Chem. Soc.	218	Sigman, MS	FALSE	FALSE	FALSE	FALSE
304	10.1002/ejoc.202100517	doi.org/10.1002/ejoc.202100517	Recent Progress in the Synthesis of Heterocycles through Base Metal-Catalyzed Acceptorless Dehydrogenative and Borrowing Hydrogen Approach		Eur. J. Org. Chem.	218	Srimani, D	FALSE	FALSE	FALSE	FALSE
305	10.1039/d1dt02986j	doi.org/10.1039/d1dt02986j	Transmetalation of boronic acids and their derivatives: mechanistic elucidation and relevance to catalysis		Dalton Trans.	217	Osakada, K	FALSE	FALSE	FALSE	FALSE
306	10.1039/c5dt01516b	doi.org/10.1039/c5dt01516b	Bond and small-molecule activation with low-valent nickel complexes		Dalton Trans.	216	Garcia, JJ	FALSE	FALSE	FALSE	FALSE
307	10.2174/1570179417666210105121115	doi.org/10.2174/1570179417666210105121115	Chemistry of Unsymmetrical C1-Substituted Oxabenzonorbornadienes	Copper-catalyzed radical methylation of 1,3-diketones with tert-butyl peroxybenzoate in air is described, providing a general pathway to a-methyl 1,3-diketones in moderate to good yields. This protocol has been scaled up to 50 g, and one of the synthesized products can be used in the synthesis of medicine, Rosuvastatin. (C) 2017 Elsevier Ltd. All rights reserved.	Curr. Org. Synth.	215	Tam, W	FALSE	FALSE	FALSE	FALSE
308	10.1002/cssc.202000317	doi.org/10.1002/cssc.202000317	A Glimpse into Green Chemistry Practices in the Pharmaceutical Industry	C-H activation reactions have allowed us to react traditionally chemically inert bonds in molecules to develop new methods for cross-coupling reactions. This type of reactivity can be applied to conjugated polymer materials in an effort to improve existing synthetic difficulties including harsh reaction conditions, multiple monomer functionalization steps, and organometallic reagent waste. In this Viewpoint, we highlight some of the encouraging advances in direct arylation polymerization (DArP) as well as ongoing challenges for future improvement and utility.	ChemSusChem	215	Handa, S	FALSE	FALSE	FALSE	FALSE
309	10.1021/acs.chemrev.9b00491	doi.org/10.1021/acs.chemrev.9b00491	Mechanistic Development and Recent Applications of the Chan-Lam Amination		Chem. Rev.	215	Watson, AJB	FALSE	FALSE	FALSE	FALSE
310	10.6023/cjoc201804027	doi.org/10.6023/cjoc201804027	Application of Mesitylboronic Acid and Its Esters in Coupling Reactions		Chin. J. Org. Chem.	215	Yue, GZ	FALSE	FALSE	FALSE	FALSE
311	10.1021/acs.joc.1c01561	doi.org/10.1021/acs.joc.1c01561	p Reductive Amination Revisited: Reduction of Aldimines with Trichlorosilane Catalyzed by Dimethylformamide-Functional Group Tolerance, Scope, and Limitations		J. Org. Chem.	215	Kocovsky, P	FALSE	FALSE	FALSE	FALSE
312	10.1021/jacs.1c05701	doi.org/10.1021/jacs.1c05701	Dirhodium(II)/Xantphos-Catalyzed Relay Carbene Insertion and Allylic Alkylation Process: Reaction Development and Mechanistic Insights		J. Am. Chem. Soc.	215	Peng, Q	FALSE	FALSE	FALSE	FALSE
313	10.1039/c5cc08386a	doi.org/10.1039/c5cc08386a	Catalytic sigma-activation of carbon-carbon triple bonds: reactions of propargylic alcohols and alkynes		Chem. Commun.	215	Bi, XH	FALSE	FALSE	FALSE	FALSE
314	10.1021/acs.chemrev.9b00214	doi.org/10.1021/acs.chemrev.9b00214	Reactivity and Synthetic Applications of Multicomponent Petasis Reactions		Chem. Rev.	214	Wu, P	FALSE	FALSE	FALSE	FALSE
315	10.1016/S0040-4020(01)00087-4	doi.org/10.1016/S0040-4020(01)00087-4	Axially chiral bidentate ligands in asymmetric catalysis		Tetrahedron	214	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
316	10.1002/ejoc.201600578	doi.org/10.1002/ejoc.201600578	N-tert-Butylsulfinyl-3,3,3-trifluoroacetaldimine: Versatile Reagent for Asymmetric Synthesis of Trifluoromethyl-Containing Amines and Amino Acids of Pharmaceutical Importance		Eur. J. Org. Chem.	214	Han, JL	FALSE	FALSE	FALSE	FALSE
317	10.1016/S0020-1693(02)01571-2	doi.org/10.1016/S0020-1693(02)01571-2	Transition metal carbonyl clusters with ene-yne ligands		Inorg. Chim. Acta	213	Sappa, E	FALSE	FALSE	FALSE	FALSE
318	10.1021/cr100284m	doi.org/10.1021/cr100284m	Catalytic Asymmetric Propargylation		Chem. Rev.	212	Ding, CH	FALSE	FALSE	FALSE	FALSE
319	10.1002/chem.201800118	doi.org/10.1002/chem.201800118	Sulfones as Synthetic Linchpins: Transition-Metal-Free sp(3)-sp(2) and sp(2)-sp(2) Cross-Couplings Between Geminal Bis(sulfones) and Organolithium Compounds		Chem.-Eur. J.	211	Trost, BM	FALSE	FALSE	FALSE	FALSE
320	10.1016/j.eurpolymj.2016.11.016	doi.org/10.1016/j.eurpolymj.2016.11.016	The chemistry of poly(2-oxazoline)s		Eur. Polym. J.	211	Hoogenboom, R	FALSE	FALSE	FALSE	FALSE
321	10.1002/cssc.201701287	doi.org/10.1002/cssc.201701287	Iron-Catalyzed C-O Bond Activation: Opportunity for Sustainable Catalysis		ChemSusChem	210	Szostak, M	FALSE	FALSE	FALSE	FALSE
322	10.1002/adsc.201000975	doi.org/10.1002/adsc.201000975	The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes		Adv. Synth. Catal.	210	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
323	10.1002/chem.201904495	doi.org/10.1002/chem.201904495	Synergistic Pd/Cu Catalysis in Organic Synthesis		Chem.-Eur. J.	209	Huo, XH; Zhang, WB	FALSE	FALSE	FALSE	FALSE
324	10.1080/00397911.2016.1170148	doi.org/10.1080/00397911.2016.1170148	Recent trends in ring opening of epoxides by amines as nucleophiles		Synth. Commun.	209	Zahoor, AF	FALSE	FALSE	FALSE	FALSE
325	10.1039/c5sc00280j	doi.org/10.1039/c5sc00280j	Stereocontrolled 1,2-cis glycosylation as the driving force of progress in synthetic carbohydrate chemistry		Chem. Sci.	209	Demchenko, AV	FALSE	FALSE	FALSE	FALSE
326	10.1016/bs.adomc.2021.01.001	doi.org/10.1016/bs.adomc.2021.01.001	Bimetallic frustrated Lewis pairs	9,10-Dihydro-10-methylacridine (AcrH(2)), a NADH coenzyme model compound, as an organo-photoredox catalyst is demonstrated for the cross-coupling of aryl diazonium salts with (hetero)arenes. Under mild and operationally simple conditions, this new photocatalytic protocol has been applied to arylation of a wide variety of (hetero)arenes and tolerates various functional groups. (C) 2017 Elsevier Ltd. All rights reserved.	Adv. Organometal. Chem.	208	Campos, J	FALSE	FALSE	FALSE	FALSE
327	10.1055/s-0033-1338635	doi.org/10.1055/s-0033-1338635	rDeveiewsign and Development of Ligands for Palladium-Catalyzed Carbonylation Reactions		Synthesis	208	Tu, T	FALSE	FALSE	FALSE	FALSE
328	10.1039/c4dt01784f	doi.org/10.1039/c4dt01784f	Ferrocene phosphane-heteroatom/carbon bidentate ligands in asymmetric catalysis		Dalton Trans.	208	Sebesta, R	FALSE	FALSE	FALSE	FALSE
329	10.1021/cr00089a003	doi.org/10.1021/cr00089a003	CARBON CARBON BOND FORMATION THROUGH ORGANOMETALLIC ELIMINATION-REACTIONS		Chem. Rev.	208	BROWN, JM	FALSE	FALSE	FALSE	FALSE
330	10.1039/c3cy00118k	doi.org/10.1039/c3cy00118k	Recent progress of N-heterocyclic carbenes in heterogeneous catalysis		Catal. Sci. Technol.	207	Ranganath, KVS	FALSE	FALSE	FALSE	FALSE
331	10.1016/S0040-4020(00)00671-2	doi.org/10.1016/S0040-4020(00)00671-2	Perspectives on alkyl carbonates in organic synthesis		Tetrahedron	207	Jung, KW	FALSE	FALSE	FALSE	FALSE
332	10.1039/c8ob02140f	doi.org/10.1039/c8ob02140f	Non-toxic cyanide sources and cyanating agents		Org. Biomol. Chem.	206	Opatz, T	FALSE	FALSE	FALSE	FALSE
333	10.1002/ajoc.202000334	doi.org/10.1002/ajoc.202000334	Iron-Catalyzed Cross-Coupling Reactions for the Construction of Carbon-Heteroatom Bonds	The methods for the synthesis of pyridinyl trifluoromethanesulfonates are reviewed. Examples of their use in organic synthesis for the production of valuable products are presented.	Asian J. Org. Chem.	205	Feng, Z	FALSE	FALSE	FALSE	FALSE
334	10.1002/tcr.202000066	doi.org/10.1002/tcr.202000066	alpha-Aminonitriles: From Sustainable Preparation to Applications in Natural Product Synthesis	An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.	Chem. Rec.	205	Opatz, T	FALSE	FALSE	FALSE	FALSE
335	10.3390/polym14040716	doi.org/10.3390/polym14040716	pi-Conjugated Polymers and Their Application in Organic and Hybrid Organic-Silicon Solar Cells		Polymers	205	Mdluli, SB; Iwuoha, EI	FALSE	FALSE	FALSE	FALSE
336	10.3390/molecules24193523	doi.org/10.3390/molecules24193523	Indolylboronic Acids: Preparation and Applications		Molecules	204	Tobrman, T	FALSE	FALSE	FALSE	FALSE
337	10.2174/138527206778249847	doi.org/10.2174/138527206778249847	Asymmetric addition to ketones: Enantioselective formation of tertiary alcohols		Curr. Org. Chem.	204	Garcia, C	FALSE	FALSE	FALSE	FALSE
338	10.1055/s-1999-3435	doi.org/10.1055/s-1999-3435	Novel concepts in directed biaryl synthesis, part 78. The lactone concept: An efficient pathway to axially chiral natural products and useful reagents		Synthesis	204	Bringmann, G	FALSE	FALSE	FALSE	FALSE
339	10.1039/c6qo00192k	doi.org/10.1039/c6qo00192k	Non-stabilized enolates - versatile nucleophiles in transition metal-catalysed allylic alkylations		Org. Chem. Front.	204	Kazmaier, U	FALSE	FALSE	FALSE	FALSE
340	10.1039/d0qo01577f	doi.org/10.1039/d0qo01577f	Recent advances in sustainable synthesis of N-heterocycles following acceptorless dehydrogenative coupling protocol using alcohols	Thiophenes containing an adjacent C C group as ligands for Pd-II-promoted organic reactions are reported for the first time. These ligands were utilized as catalytic sites and integrated into the skeleton of conjugated microporous polymers. By employing these CMP materials as selective regulators, oxidative Heck reactions between arylboronic esters and electronically unbiased alkenes provide highly selective linear products.	Org. Chem. Front.	202	Kundu, S	FALSE	FALSE	FALSE	FALSE
341	10.1039/c8gc02860e	doi.org/10.1039/c8gc02860e	Recent advances in the Suzuki-Miyaura cross-coupling reaction using efficient catalysts in eco-friendly media		Green Chem.	202	Sedghi, R	FALSE	FALSE	FALSE	FALSE
342	10.1039/c8cs00036k	doi.org/10.1039/c8cs00036k	Mechanistic view of Ru-catalyzed C-H bond activation and functionalization: computational advances		Chem. Soc. Rev.	202	Lan, Y	FALSE	FALSE	FALSE	FALSE
343	10.1002/adsc.201100809	doi.org/10.1002/adsc.201100809	Iridium-Catalyzed Asymmetric Allylic Etherification and Ring-Closing Metathesis Reaction for Enantioselective Synthesis of Chromene and 2,5-Dihydrobenzo[b]oxepine Derivatives		Adv. Synth. Catal.	201	You, SL	FALSE	FALSE	FALSE	FALSE
344	10.1016/S0040-4020(01)89159-6	doi.org/10.1016/S0040-4020(01)89159-6	RECENT ADVANCES IN CATALYTIC ASYMMETRIC REACTIONS PROMOTED BY TRANSITION-METAL COMPLEXES		Tetrahedron	201	OJIMA, I	FALSE	FALSE	FALSE	FALSE
345	10.1021/acscatal.0c03127	doi.org/10.1021/acscatal.0c03127	Visible-Light-Driven Catalytic Reductive Carboxylation with CO2	A series of novel Zn, Cu, Fe supramolecular complexes were designed and synthesized. The structures of these compounds have been confirmed by IR, NMR, EA and X-ray crystallography. The complexes in combination with tetrabutylammonium bromide were studied as a binary catalyst system for CO2-fixation in the context of organic carbonate formation under solventless condition. The effects of various co-catalysts, co-catalyst concentration, reaction temperature, CO2 pressure, reaction time, various substituents on ligand and centre metal of complexes have been investigated systematically. The binary catalyst system also showed broad substrate scope of epoxide. The catalysts can be easily recovered and reused without significant loss of activity and selectivity. Comparison of different two-component dinuclear metal complexes catalysts reported by other scientists showed that the dinuclear metal complexes reported herein were competitive with most catalysts currently available. On the basis of the experimental results, the mechanism for the reaction was proposed. (C) 2017 Elsevier Ltd. All rights reserved.	ACS Catal.	200	Zhou, WJ; Yu, DG	FALSE	FALSE	FALSE	FALSE
346	10.1021/acs.chemrev.8b00588	doi.org/10.1021/acs.chemrev.8b00588	Computational Ligand Descriptors for Catalyst Design		Chem. Rev.	200	Fey, N	FALSE	FALSE	FALSE	FALSE
347	10.1002/ejic.201801179	doi.org/10.1002/ejic.201801179	A beta-Diketiminato-Based Pincer-Type Nickel(II) Complex: Synthesis and Catalytic Performance in the Cross-Coupling of Aryl Fluorides with Aryl Grignard Reagents		Eur. J. Inorg. Chem.	200	Yamaguchi, Y	FALSE	FALSE	FALSE	FALSE
348	10.2174/1570179416666190415110834	doi.org/10.2174/1570179416666190415110834	New Developments on the Hirao Reactions, Especially from Green Point of View		Curr. Org. Synth.	200	Keglevich, G	FALSE	FALSE	FALSE	FALSE
349	10.1039/c7np00065k	doi.org/10.1039/c7np00065k	Total synthesis of complex terpenoids employing radical cascade processes		Nat. Prod. Rep.	199	Maimone, TJ	FALSE	FALSE	FALSE	FALSE
350	10.1002/anie.200903424	doi.org/10.1002/anie.200903424	Metal-Catalyzed alpha-Arylation of Carbonyl and Related Molecules: Novel Trends in C-C Bond Formation by C-H Bond Functionalization		Angew. Chem.-Int. Edit.	199	Colacot, TJ	FALSE	FALSE	FALSE	FALSE
351	10.1021/jo980757x	doi.org/10.1021/jo980757x	Derivatives of 2-amino-2 '-diphenylphosphino-1,1 '-binaphthyl (MAP) and their application in asymmetric palladium(0)-catalyzed allylic substitution		J. Org. Chem.	199	Vyskocil, S	FALSE	FALSE	FALSE	FALSE
352	10.1016/j.jorganchem.2021.122147	doi.org/10.1016/j.jorganchem.2021.122147	N, O-polydentate ligands for palladium-catalyzed cross-coupling reactions (Part III)		J. Organomet. Chem.	199	Kumbhar, A	FALSE	FALSE	FALSE	FALSE
353	10.1002/anie.202003632	doi.org/10.1002/anie.202003632	Photocatalytic Difunctionalization of Vinyl Ureas by Radical Addition Polar Truce-Smiles Rearrangement Cascades	A new catalytic system based on Pd-NHC complex utilizing (4-pyridyl)bis(imidazolyl)methane as a bidentate NHC ligand supported on nano. silica is introduced. The catalyst was characterized by FT-IR spectroscopy, thermogravimetric analysis, field emission scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy and elemental analysis. This heterogeneous catalytic system exhibited excellent activity in the Suzuki-Miyaura coupling reaction of various aryl halides with phenylboronic acid, and was reusable several times without significant loss of its catalytic activity. (C) 2016 Elsevier B.V. All rights reserved.	Angew. Chem.-Int. Edit.	198	Clayden, J	TRUE	FALSE	FALSE	FALSE
354	10.1007/s10600-019-02705-8	doi.org/10.1007/s10600-019-02705-8	Recent Progress in the Synthesis of 4-Arylcoumarins		Chem. Nat. Compd.	198	Moskvina, VS	FALSE	FALSE	FALSE	FALSE
355	10.1002/ejoc.202101112	doi.org/10.1002/ejoc.202101112	2-Pyrone - A Privileged Heterocycle and Widespread Motif in Nature		Eur. J. Org. Chem.	198	Reiser, O	FALSE	FALSE	FALSE	FALSE
356	10.1002/asia.201801020	doi.org/10.1002/asia.201801020	Homogeneous Catalysis: A Powerful Technology for the Modification of Important Biomolecules		Chem.-Asian J.	197	Kapdi, AR	FALSE	FALSE	FALSE	FALSE
357	10.6023/cjoc202106021	doi.org/10.6023/cjoc202106021	Development of Nickel-Catalyzed Cross-Coupling of Alcohol Derivatives to Construct Carbon-Carbon Bonds		Chin. J. Org. Chem.	197	Zhang, WB	FALSE	FALSE	FALSE	FALSE
358	10.1039/c6ob01102k	doi.org/10.1039/c6ob01102k	Competing amination and C-H arylation pathways in Pd/xantphos-catalyzed transformations of binaphthyl triflates: switchable routes to chiral amines and helicene derivatives		Org. Biomol. Chem.	196	Slaughter, LM	FALSE	FALSE	FALSE	FALSE
359	10.1055/s-2004-830860	doi.org/10.1055/s-2004-830860	Total synthesis of polycyclic ether natural products based on Suzuki-Miyaura cross-coupling		Synlett	196	Sasaki, M	FALSE	FALSE	FALSE	FALSE
360	10.1002/ejoc.201402625	doi.org/10.1002/ejoc.201402625	Synthesis and Characterisation of 1,7-Di- and Inherently Chiral 1,12-Di- and 1,6,7,12-Tetraarylperylenetetracarbox-3,4:9,10-diimides		Eur. J. Org. Chem.	195	Hoffmann, N	FALSE	FALSE	FALSE	FALSE
361	10.1016/j.ccr.2015.02.004	doi.org/10.1016/j.ccr.2015.02.004	From models to lignin: Transition metal catalysis for selective bond cleavage reactions		Coord. Chem. Rev.	195	Barta, K	FALSE	FALSE	FALSE	FALSE
362	10.1021/jacs.7b05155	doi.org/10.1021/jacs.7b05155	Transition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings		J. Am. Chem. Soc.	194	Larrosa, I	FALSE	FALSE	FALSE	FALSE
363	10.1021/acs.chemrev.8b00306	doi.org/10.1021/acs.chemrev.8b00306	3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer		Chem. Rev.	193	Kempe, R	FALSE	FALSE	FALSE	FALSE
364	10.1002/chem.201302079	doi.org/10.1002/chem.201302079	Pyridine-Enhanced Head-to-Tail Dimerization of Terminal Alkynes by a Rhodium-N-Heterocyclic-Carbene Catalyst		Chem.-Eur. J.	193	Castarlenas, R	FALSE	FALSE	FALSE	FALSE
365	10.1021/ja205547h	doi.org/10.1021/ja205547h	Main Group Multiple C-H/N-H Bond Activation of a Diamine and Isolation of A Molecular Dilithium Zincate Hydride: Experimental and DFT Evidence for Alkali Metal-Zinc Synergistic Effects		J. Am. Chem. Soc.	193	Mulvey, RE	FALSE	FALSE	FALSE	FALSE
366	10.1002/ejic.201900244	doi.org/10.1002/ejic.201900244	Exploration of the Luminescence Properties of Organic Phosphate Salts of 3-Quinoline- and 5-Isoquinolineboronic Acid		Eur. J. Inorg. Chem.	192	Cruz-Enriquez, A	FALSE	FALSE	FALSE	FALSE
367	10.1007/3418_2015_127	doi.org/10.1007/3418_2015_127	Late Transition Metal Complexes with Pincer Ligands that Comprise N-Heterocyclic Carbene Donor Sites		Top. Organomet. Chem.	192	Albrecht, M	FALSE	FALSE	FALSE	FALSE
368	10.1021/jacs.1c08502	doi.org/10.1021/jacs.1c08502	An Accelerated Modular-Orthogonal Ni-Catalyzed Methodology to Symmetric and Nonsymmetric Constitutional Isomeric AB(2) to AB(9) Dendrons Exhibiting Unprecedented Self-Organizing Principles		J. Am. Chem. Soc.	191	Percec, V	FALSE	FALSE	FALSE	FALSE
369	10.1021/acs.joc.5b02077	doi.org/10.1021/acs.joc.5b02077	General Copper-Catalyzed Coupling of Alkyl-, Aryl-, and Alkynylaluminum Reagents with Organohalides		J. Org. Chem.	191	Giri, R	FALSE	FALSE	FALSE	FALSE
370	10.1002/anie.201904795	doi.org/10.1002/anie.201904795	The Buchwald-Hartwig Amination After 25 Years		Angew. Chem.-Int. Edit.	190	Dorel, R	FALSE	FALSE	FALSE	FALSE
371	10.1039/d1ob00465d	doi.org/10.1039/d1ob00465d	Synthesis and reactivity of alkynyl boron compounds		Org. Biomol. Chem.	190	Panda, S	FALSE	FALSE	FALSE	FALSE
372	10.1039/d0cy02059a	doi.org/10.1039/d0cy02059a	Suzuki-Miyaura cross coupling reaction: recent advancements in catalysis and organic synthesis	The Ni-catalyzed reaction of aromatic amides with alkynes in the presence of KOBut involves C-H/N-H oxidative annulation to give 1(2H)-isoquinolinones. A key to the success of the reaction is the use of a catalytic amount of strong base, such as KOBut. The reaction shows a high functional group compatibility. The reaction with unsymmetrical alkynes, such as 1-arylalkynes, gives the corresponding 1(2H)-isoquinolinones with a high level of regioselectivity. This discovery would lead to the development of Nicatalyzed chelation-assisted C-H functionalization reactions without the need for a specific chelation system.	Catal. Sci. Technol.	188	Kadu, BS	FALSE	FALSE	FALSE	FALSE
373	10.1002/chem.201402509	doi.org/10.1002/chem.201402509	Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds		Chem.-Eur. J.	188	Correa, A	FALSE	FALSE	FALSE	FALSE
374	10.1002/slct.201904819	doi.org/10.1002/slct.201904819	Sonogashira Coupling (Cu/Amine-Free) of ArBr/Cl in Aerobic Condition and N-Benzylation of Aniline with Benzyl Alcohol Catalyzed by Complexes of Pd(II) with Sulfated/Selenated NHCs	The first C(sp(3))-C(sp(2)) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.	ChemistrySelect	187	Singh, AK	FALSE	FALSE	FALSE	FALSE
375	10.1515/pteridines-2018-0002	doi.org/10.1515/pteridines-2018-0002	A concise treatment of pterins: some recent synthetic and methodology aspects and their applications in molecular sensors		Pteridines	187	Goswami, S	FALSE	FALSE	FALSE	FALSE
376	10.1002/anie.201403729	doi.org/10.1002/anie.201403729	Synthesis of Extended p-Systems through C-H Activation		Angew. Chem.-Int. Edit.	187	Segawa, Y	FALSE	FALSE	FALSE	FALSE
377	10.1021/cr00080a005	doi.org/10.1021/cr00080a005	HALF-SANDWICH CHIRAL RUTHENIUM COMPLEXES		Chem. Rev.	187	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
378	10.1039/c2dt32008h	doi.org/10.1039/c2dt32008h	Synthesis and chemistry of bis(triisopropylphosphine) nickel(I) and nickel(0) precursors		Dalton Trans.	186	Johnson, SA	FALSE	FALSE	FALSE	FALSE
379	10.1021/ja9039289	doi.org/10.1021/ja9039289	Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides		J. Am. Chem. Soc.	186	Nakamura, M	FALSE	FALSE	FALSE	FALSE
380	10.1246/bcsj.20140241	doi.org/10.1246/bcsj.20140241	Two-Step, Practical, and Diversity-Oriented Synthesis of Multisubstituted Benzofurans from Phenols through Pummerer Annulation Followed by Cross-coupling		Bull. Chem. Soc. Jpn.	185	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
381	10.1002/anie.200904306	doi.org/10.1002/anie.200904306	Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts-A Perfect Combination for Suzuki-Miyaura Coupling		Angew. Chem.-Int. Edit.	185	Molander, GA	FALSE	FALSE	FALSE	FALSE
382	10.1039/B316819K	doi.org/10.1039/B316819K	The syntheses and catalytic applications of unsymmetrical ferrocene ligands		Chem. Soc. Rev.	185	Gibson, VC	FALSE	FALSE	FALSE	FALSE
383	10.3390/catal7040098	doi.org/10.3390/catal7040098	Eco-Friendly Physical Activation Methods for Suzuki-Miyaura Reactions		Catalysts	185	Cravotto, G	FALSE	FALSE	FALSE	FALSE
384	10.1021/jacs.6b01656	doi.org/10.1021/jacs.6b01656	Potential of Metal-Catalyzed C-C Single Bond Cleavage for Organic Synthesis		J. Am. Chem. Soc.	185	Murakami, M	FALSE	FALSE	FALSE	FALSE
385	10.1039/d0cs01339k	doi.org/10.1039/d0cs01339k	Beyond hydrogen bonding: recent trends of outer sphere interactions in transition metal catalysis	A new method for the synthesis of terminal and internal alkynes from the nickel-catalyzed decarboxylative coupling of N-hydroxyphthalimide esters and bromoalkynes is presented. This reductive cross-electrophile coupling is the first to use a C(sp)-X electrophile, and appears to proceed via an alkynylnickel intermediate. The internal alkyne products are obtained in yields of 41-95% without the need for a photocatalyst, light, or a strong oxidant. The reaction displays a broad scope of carboxylic acid and alkyne coupling partners, and can tolerate an array of functional groups, including carbamate NH, halogen, nitrile, olefin, ketone, and ester moieties. Mechanistic studies suggest that this process does not involve an alkynylmanganese reagent and instead proceeds through nickel-mediated bond formation.	Chem. Soc. Rev.	184	Gramage-Doria, R	FALSE	FALSE	FALSE	FALSE
386	10.1002/ejoc.201900465	doi.org/10.1002/ejoc.201900465	Advances in The Catalytic Synthesis of Triarylmethanes (TRAMs)		Eur. J. Org. Chem.	184	Saha, S	FALSE	FALSE	FALSE	FALSE
387	10.1007/3418_2011_15	doi.org/10.1007/3418_2011_15	Allylic Substitutions Catalyzed by Miscellaneous Metals		Top. Organomet. Chem.	184	Plietker, B	FALSE	FALSE	FALSE	FALSE
388	10.1002/chem.200204657	doi.org/10.1002/chem.200204657	Highly selective palladium catalyzed kinetic resolution and enantioselective substitution of racemic allylic carbonates with sulfur nucleophiles: Asymmetric synthesis of allylic sulfides, allylic sulfones, and allylic alcohols		Chem.-Eur. J.	184	Gais, HJ	FALSE	FALSE	FALSE	FALSE
389	10.1021/cr9409804	doi.org/10.1021/cr9409804	Asymmetric transition metal-catalyzed allylic alkylations		Chem. Rev.	184	Trost, BM	FALSE	FALSE	FALSE	FALSE
390	10.1016/j.ccr.2021.214165	doi.org/10.1016/j.ccr.2021.214165	A new avenue for the preparation of organoboron compounds via nickel catalysis		Coord. Chem. Rev.	184	Panda, S	FALSE	FALSE	FALSE	FALSE
391	10.1039/d1cc01795k	doi.org/10.1039/d1cc01795k	Amide bond formation: beyond the dilemma between activation and racemisation		Chem. Commun.	184	Muramatsu, W; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
392	10.1016/j.ccr.2007.03.020	doi.org/10.1016/j.ccr.2007.03.020	Performances of symmetrical achiral ferrocenylphosphine ligands in palladium-catalyzed cross-coupling reactions: A review of syntheses, catalytic applications and structural properties		Coord. Chem. Rev.	183	Fihri, A	FALSE	FALSE	FALSE	FALSE
393	10.1021/acscentsci.1c00125	doi.org/10.1021/acscentsci.1c00125	Borrowing Hydrogen for Organic Synthesis		ACS Central Sci.	183	Morrill, LC	FALSE	FALSE	FALSE	FALSE
394	10.1038/s41570-017-0052	doi.org/10.1038/s41570-017-0052	The merger of transition metal and photocatalysis		Nat. Rev. Chem.	183	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
395	10.1016/j.ccr.2019.213038	doi.org/10.1016/j.ccr.2019.213038	Poly-N-heterocyclic carbene complexes with applications in aqueous media		Coord. Chem. Rev.	182	De, S; Joo, F	FALSE	FALSE	FALSE	FALSE
396	10.1002/chem.201001960	doi.org/10.1002/chem.201001960	Bimetallic Catalysis Involving Dipalladium(I) and Diruthenium(I) Complexes		Chem.-Eur. J.	182	Bera, JK	FALSE	FALSE	FALSE	FALSE
397	10.3390/molecules26165079	doi.org/10.3390/molecules26165079	Recent Progress Concerning the N-Arylation of Indoles		Molecules	182	Tobrman, T	FALSE	FALSE	FALSE	FALSE
398	10.1021/ja070321b	doi.org/10.1021/ja070321b	Studies on the heck reaction with alkenyl phosphates: Can the 1,2-migration be controlled? Scope and limitations		J. Am. Chem. Soc.	181	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
399	10.1002/chem.200400928	doi.org/10.1002/chem.200400928	Diaminocarbene- and Fischer-carbene complexes of palladium and nickel by oxidative insertion: Preparation, structure, and catalytic activity		Chem.-Eur. J.	181	Furstner, A	FALSE	FALSE	FALSE	FALSE
400	10.2174/1385272023374111	doi.org/10.2174/1385272023374111	The ring opening of oxabicyclic compounds controlled by a phenylsulfonyl group. Synthetic applications.		Curr. Org. Chem.	181	Plumet, J	FALSE	FALSE	FALSE	FALSE
401	10.1021/acs.joc.0c02151	doi.org/10.1021/acs.joc.0c02151	Strategic Advances in Sequential C-Arylations of Heteroarenes	An ionic 2,6-bis(imidazo[ 1,2-alpha] pyridin-2-yl) pyridine-based N<^>N<^>N pincer ruthenium(II) complex exhibited high efficiency in the C-N bond formation between amines and alcohols by the borrowing hydrogen (BH) or hydrogen autotransfer (HA) concept. The synthetic protocol selectively generated monoalkylated amines without formation of tertiary amines during the reaction. The unique selectivity enabled the formation of symmetrically and asymmetrically substituted diamines. This methodology features several advantages including a low catalyst loading (as low as 0.5 mol-%), a short reaction time (as short as 2 h), and excellent N-monoalkylation selectivity.	J. Org. Chem.	180	Tandon, V	FALSE	FALSE	FALSE	FALSE
402	10.1055/s-0040-1705972	doi.org/10.1055/s-0040-1705972	Nickel(II)- and Silver(I)-Catalyzed C-H Bond Halogenation of Anilides and Carbamates	The nickel-catalyzed deoxygenative deuteration of aryl/heteroaryl sulfamates has been developed, and the effective incorporation of deuterium into a variety of aromatic compounds was achieved with sufficient catalytic efficiency and high deuteration degree. This process tolerated reducible functional moieties and heterocyclic structures. Additionally, a double introduction of deuterium also successfully gave a desired product with a high yield and deuterium content.	Synthesis	180	Kianmehr, E	FALSE	FALSE	FALSE	FALSE
403	10.1002/ejoc.201901466	doi.org/10.1002/ejoc.201901466	Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods		Eur. J. Org. Chem.	180	Nagorny, P	FALSE	FALSE	FALSE	FALSE
404	10.3390/molecules20057528	doi.org/10.3390/molecules20057528	Recent Developments in the Suzuki-Miyaura Reaction: 2010-2014		Molecules	180	Navarro, O	FALSE	FALSE	FALSE	FALSE
405	10.1007/3418_2012_38	doi.org/10.1007/3418_2012_38	Hydro-, Carbo-, and Cycloalumination of Unsaturated Compounds		Top. Organomet. Chem.	179	D'yakonov, VA	FALSE	FALSE	FALSE	FALSE
406	10.6023/cjoc201208016	doi.org/10.6023/cjoc201208016	Recent Advances of Transition Metal-Catalyzed Aerobic Dehydrative Reactions of Alcohols and Amines and Related Researches		Chin. J. Org. Chem.	179	Xu, Q	FALSE	FALSE	FALSE	FALSE
407	10.1021/ma9717294	doi.org/10.1021/ma9717294	Application of transfer-free Suzuki coupling protocols toward the synthesis of unambiguously linear poly(p-phenylenes)		Macromolecules	179	Novak, BM	FALSE	FALSE	FALSE	FALSE
408	10.1021/acscatal.6b01725	doi.org/10.1021/acscatal.6b01725	Catalytic Asymmetric Reactions with N,O-Aminals		ACS Catal.	179	Huang, YY	FALSE	FALSE	FALSE	FALSE
409	10.1021/acscatal.6b01227	doi.org/10.1021/acscatal.6b01227	A Career in Catalysis: Masakatsu Shibasaki		ACS Catal.	179	Kumagai, N	FALSE	FALSE	FALSE	FALSE
410	10.1007/s41061-018-0203-6	doi.org/10.1007/s41061-018-0203-6	Engineered C-S Bond Construction		Top. Curr. Chem.	178	Lee, CF	FALSE	FALSE	FALSE	FALSE
411	10.1039/c6ob00936k	doi.org/10.1039/c6ob00936k	Modern advances in heterocyclic chemistry in drug discovery		Org. Biomol. Chem.	178	Taylor, AP	FALSE	FALSE	FALSE	FALSE
412	10.1007/3418_2011_10	doi.org/10.1007/3418_2011_10	Iridium-Catalyzed Asymmetric Allylic Substitutions		Top. Organomet. Chem.	178	You, SL	FALSE	FALSE	FALSE	FALSE
413	10.1039/c0cc00778a	doi.org/10.1039/c0cc00778a	Metal-catalyzed direct alkylations of (hetero)arenes via C-H bond cleavages with unactivated alkyl halides		Chem. Commun.	178	Ackermann, L	FALSE	FALSE	FALSE	FALSE
414	10.1021/acs.joc.5b00580	doi.org/10.1021/acs.joc.5b00580	Understanding the Effects of Bidentate Directing Groups: A Unified Rationale for sp(2) and sp(3) C-H Bond Activations		J. Org. Chem.	177	Chen, H	FALSE	FALSE	FALSE	FALSE
415	10.1002/ejoc.201403121	doi.org/10.1002/ejoc.201403121	Synthesis of [c]-Fused Bicyclic Proline Analogues		Eur. J. Org. Chem.	177	Cativiela, C	FALSE	FALSE	FALSE	FALSE
416	10.1016/j.jorganchem.2013.02.029	doi.org/10.1016/j.jorganchem.2013.02.029	A series of Se-ferrocenyl thiophene carboselenoates - Synthesis, solid-state structure and electrochemistry		J. Organomet. Chem.	177	Taher, D	FALSE	FALSE	FALSE	FALSE
417	10.1021/ja027190t	doi.org/10.1021/ja027190t	Iron-catalyzed cross-coupling reactions		J. Am. Chem. Soc.	177	Furstner, A	FALSE	FALSE	FALSE	FALSE
418	10.1002/tcr.201402058	doi.org/10.1002/tcr.201402058	Reductive Umpolung Reactions with Low-Valent Titanium Catalysts		Chem. Rec.	176	Streuff, J	FALSE	FALSE	FALSE	FALSE
419	10.1038/s41570-017-0025	doi.org/10.1038/s41570-017-0025	Well-defined nickel and palladium precatalysts for cross-coupling		Nat. Rev. Chem.	176	Hazari, N	FALSE	FALSE	FALSE	FALSE
420	10.1055/s-0040-1705986	doi.org/10.1055/s-0040-1705986	Transition-Metal-Catalyzed Cross-Coupling Reactions of Grignard Reagents	Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analyses. The cellulose supported heterogeneous Pd(II) complex showed high stability and catalytic activity towards Mizoroki-Heck reaction of aryl halides and arenediazonium tetrafluoroborate with a variety of olefins to give the corresponding cross-coupling products in up to 97% yield. The Pd(II) complex was separated from the reaction mixtures and repeatedly used up to seven times without any significant decrease of its catalytic performance. (C) 2017 Elsevier Ltd. All rights reserved.	Synthesis	174	Hell, Z	FALSE	FALSE	FALSE	FALSE
421	10.1039/d0ra08068c	doi.org/10.1039/d0ra08068c	Synthesis of polysubstituted arenes through organocatalytic benzannulation	A palladium-catalyzed reductive coupling between N-tosylhydrazones and aryl bromides has been developed. The reaction provides an efficient method for the synthesis of diarylmethanes and triarylmethanes via the formation of C(sp(2))-C(sp(3)) single bonds. This new methodology for the synthesis of diarylmethanes and triarylmethanes is featured by the ready availability of the starting materials, mild reaction conditions, and the tolerance of wide range of functional groups. The reaction follows a pathway including palladium carbene formation, migratory insertion, and reduction of the alkylpalladium(II) intermediate.	RSC Adv.	174	Han, B	FALSE	FALSE	FALSE	FALSE
422	10.1002/ajoc.201900625	doi.org/10.1002/ajoc.201900625	Recent Advances in Four-Coordinated Planar Cobalt Catalysis in Organic Synthesis		Asian J. Org. Chem.	174	Komeyama, K	FALSE	FALSE	FALSE	FALSE
423	10.1039/c8cy01860j	doi.org/10.1039/c8cy01860j	Regioselective C-H and N-H functionalization of purine derivatives and analogues: a synthetic and mechanistic perspective		Catal. Sci. Technol.	174	Mondal, M	FALSE	FALSE	FALSE	FALSE
424	10.1002/chem.201706102	doi.org/10.1002/chem.201706102	Diversifying Cross-Coupling Strategies, Catalysts and Monomers for the Controlled Synthesis of Conjugated Polymers		Chem.-Eur. J.	174	Noonan, KJT	FALSE	FALSE	FALSE	FALSE
425	10.1039/c8cs00080h	doi.org/10.1039/c8cs00080h	Catalytic peptide assemblies		Chem. Soc. Rev.	173	Korendovych, IV	FALSE	FALSE	FALSE	FALSE
426	10.1002/ajoc.202000422	doi.org/10.1002/ajoc.202000422	Transition-Metal-Catalyzed Propargylic Substitution of Propargylic Alcohol Derivatives Bearing an Internal Alkyne Group	A photoinduced esterification reaction has been developed. In this reaction, benzylsilane shows very nice reactivity and selectivity, affording the corresponding esters as the only products. Under photo irradiation, the highly active bromo radical can be generated from the pre-catalyst CBr4, which would promote the initial C-Si bond cleavage of benzylsilane via single electron transfer and the final transformation of acetal into ester via proton transfer. The existence of oxygen can not only oxidize the in situ generated benzyl radical into aldehyde intermediate, but also assist to regenerate bromo radical from bromine anion. (C) 2016 King Saud University. Production and hosting by Elsevier B.V.	Asian J. Org. Chem.	172	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
427	10.1021/ja511622e	doi.org/10.1021/ja511622e	Rhodium-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through Cleavage of the Carbon-Oxygen Bond: Borylative Removal of the Directing Group		J. Am. Chem. Soc.	172	Tobisu, M	FALSE	FALSE	FALSE	FALSE
428	10.1002/chem.202101360	doi.org/10.1002/chem.202101360	A Proton-Responsive Pyridyl(benzamide)-Functionalized NHC Ligand on Ir Complex for Alkylation of Ketones and Secondary Alcohols		Chem.-Eur. J.	172	Bera, JK	FALSE	FALSE	FALSE	FALSE
429	10.1039/d0cs00447b	doi.org/10.1039/d0cs00447b	Recent advances in chelation-assisted site- and stereoselective alkenyl C-H functionalization	Trifluoromethoxy-substituted stereogenic centers can be constructed with high enantioselectivity by a nickel-catalyzed Suzuki-Miyaura coupling of readily available alpha-bromobenzyl trifluoromethyl ethers with a variety of aryl pinacol boronates. The coupling proceeds under mild reaction conditions, and a variety of common functional groups, such as fluoride, chloride, bromide, ester, enolizable ketone, nitro, cyano, amino, and vinyl moieties, were well tolerated. Furthermore, the reaction can be easily scaled up to gram quantities without a decrease in enantioselectivity.	Chem. Soc. Rev.	171	Zhang, J; Zhong, GF	FALSE	FALSE	FALSE	FALSE
430	10.1016/bs.adomc.2021.04.003	doi.org/10.1016/bs.adomc.2021.04.003	Recent progress on group 10 metal complexes of pincer ligands: From synthesis to activities and catalysis	A variety of Ni-II complexes with a wide range of electronic and steric properties, bearing picolylimidazolidene ligands (a-g) and Cp (Cp = eta 5-C5H5; 2a-f) or Cp* (Cp* = eta(5)-C5Me5; 3a, c, g) groups, have been synthesised and characterised by using NMR spectroscopy and single-crystal X-ray crystallography. The complexes have been used as precatalysts for a wide range of catalytic transformations, which most likely involve a Ni-0/Ni-II catalytic cycle. In particular, the new welldefined 2a, 2c, 3a and 3c complexes have demonstrated great efficiency and versatility towards Suzuki-Miyaura coupling reactions, hydroamination of activated olefins and C-S cross-coupling reactions of aryl halides and thiols under mild conditions.	Adv. Organometal. Chem.	171	Ren, P	FALSE	FALSE	FALSE	FALSE
431	10.1021/acscatal.8b00230	doi.org/10.1021/acscatal.8b00230	Designing Pd and Ni Catalysts for Cross-Coupling Reactions by Minimizing Off-Cycle Species		ACS Catal.	171	Balcells, D; Nova, A	FALSE	FALSE	FALSE	FALSE
432	10.1002/anie.202112251	doi.org/10.1002/anie.202112251	Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C-C Bond Formation		Angew. Chem.-Int. Edit.	171	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
433	10.1021/jacs.8b09103	doi.org/10.1021/jacs.8b09103	The History of Palladium-Catalyzed Cross-Couplings Should Inspire the Future of Catalyst-Transfer Polymerization		J. Am. Chem. Soc.	170	McNeil, AJ	FALSE	FALSE	FALSE	FALSE
434	10.1021/jo400080y	doi.org/10.1021/jo400080y	Zinc Catalyzed and Mediated Asymmetric Propargylation of Trifluoromethyl Ketones with a Propargyl Boronate		J. Org. Chem.	170	Fandrick, DR	FALSE	FALSE	FALSE	FALSE
435	10.1002/ajoc.201700645	doi.org/10.1002/ajoc.201700645	Computational Insights into the Reaction Mechanisms of Nickel-Catalyzed Hydrofunctionalizations and Nickel-Dependent Enzymes		Asian J. Org. Chem.	169	Chung, LW	FALSE	FALSE	FALSE	FALSE
436	10.5059/yukigoseikyokaishi.59.170	doi.org/10.5059/yukigoseikyokaishi.59.170	Novel catalytic performance of ruthenium complexes for organic synthesis		J. Synth. Org. Chem. Jpn.	169	Kondo, T	FALSE	FALSE	FALSE	FALSE
437	10.1021/jacs.9b08342	doi.org/10.1021/jacs.9b08342	Selective Conversion of Carbon Dioxide to Formaldehyde via a Bis(silyl)acetal: Incorporation of Isotopically Labeled C-1 Moieties Derived from Carbon Dioxide into Organic Molecules		J. Am. Chem. Soc.	168	Parkin, G	FALSE	FALSE	FALSE	FALSE
438	10.1016/j.jorganchem.2015.03.023	doi.org/10.1016/j.jorganchem.2015.03.023	Recent advances in the application of group-10 transition metal based catalysts in C-H activation and functionalization		J. Organomet. Chem.	168	Raithby, PR	FALSE	FALSE	FALSE	FALSE
439	10.1002/ejoc.201901310	doi.org/10.1002/ejoc.201901310	N-Alkylation of Amines Catalyzed by a Ruthenium-Pincer Complex in the Presence of in situ Generated Sodium Alkoxide		Eur. J. Org. Chem.	167	Srivastava, HK; Kumar, A	FALSE	FALSE	FALSE	FALSE
440	10.1007/3418_2019_28	doi.org/10.1007/3418_2019_28	Process Economics and Atom Economy for Industrial Cross Coupling Applications via LnPd(0)-Based Catalysts		Top. Organomet. Chem.	167	Slack, ED; Colacot, TJ	FALSE	FALSE	FALSE	FALSE
441	10.1007/3418_2018_19	doi.org/10.1007/3418_2018_19	Metal-Catalyzed Aromatic C-O Bond Activation/Transformation		Top. Organomet. Chem.	167	Tobisu, M	FALSE	FALSE	FALSE	FALSE
442	10.1039/c8cc02499e	doi.org/10.1039/c8cc02499e	Homologation chemistry with nucleophilic -substituted organometallic reagents: chemocontrol, new concepts and (solved) challenges		Chem. Commun.	167	Pace, V	FALSE	FALSE	FALSE	FALSE
443	10.1039/d0cs01107j	doi.org/10.1039/d0cs01107j	Nickel-catalyzed formation of quaternary carbon centers using tertiary alkyl electrophiles		Chem. Soc. Rev.	167	Xue, WC; Gong, HG	FALSE	FALSE	FALSE	FALSE
444	10.1002/chem.201901163	doi.org/10.1002/chem.201901163	Cross-Coupling Reaction of Alkenyl Sulfoximines and Alkenyl Aminosulfoxonium Salts with Organozincs by Dual Nickel Catalysis and Lewis Acid Promotion		Chem.-Eur. J.	166	Gais, HJ	FALSE	FALSE	FALSE	FALSE
445	10.1002/ajoc.201700450	doi.org/10.1002/ajoc.201700450	Arylation of Aniline C(sp(3))-H Bonds with Phenols via an In Situ Activation Strategy		Asian J. Org. Chem.	166	Zhou, WJ; Yu, DG	FALSE	FALSE	FALSE	FALSE
446	10.2174/15701794113109990066	doi.org/10.2174/15701794113109990066	P-C Bond Formation by Coupling Reactions Utilizing > P(O)H Species as the Reagents		Curr. Org. Synth.	166	Keglevich, G	FALSE	FALSE	FALSE	FALSE
447	10.1039/d1qo00549a	doi.org/10.1039/d1qo00549a	Nickel-catalyzed defluorinative alkylation of C(sp(2))-F bonds		Org. Chem. Front.	166	Liu, XW	FALSE	FALSE	FALSE	FALSE
448	10.1002/ejoc.201600112	doi.org/10.1002/ejoc.201600112	Tailor-Made alpha-Amino Acids in the Pharmaceutical Industry: Synthetic Approaches to (1R,2S)-1-Amino-2-vinylcyclopropane-1-carboxylic Acid (Vinyl-ACCA)		Eur. J. Org. Chem.	166	Sato, T	FALSE	FALSE	FALSE	FALSE
449	10.1016/j.ccr.2015.11.010	doi.org/10.1016/j.ccr.2015.11.010	Schiff base-derived homogeneous and heterogeneous palladium catalysts for the Suzuki-Miyaura reaction		Coord. Chem. Rev.	166	Das, P	FALSE	FALSE	FALSE	FALSE
450	10.1055/s-0040-1707115	doi.org/10.1055/s-0040-1707115	Recent Advances in Triarylmethane Synthesis	A visible-light-promoted iridium photoredox and nickel dual-catalyzed cross-coupling procedure for the formation C-N bonds has been developed. With this method, various aryl amines were chemoselectively cross-coupled with electronically and sterically diverse aryl iodides and bromides to forge the corresponding C-N bonds, which are of high interest to the pharmaceutical industries. Aryl iodides were found to be a more efficient electrophilic coupling partner. The coupling reactions were carried out at room temperature without the rigorous exclusion of molecular oxygen, thus making this newly developed Ir-photoredox/Ni dual-catalyzed procedure very mild and operationally simple.	Synthesis	165	Zhang, L	FALSE	FALSE	FALSE	FALSE
451	10.1039/d0cs00149j	doi.org/10.1039/d0cs00149j	3d metallaelectrocatalysis for resource economical syntheses	A supramolecular ensemble having Ag@Cu2O core-shell nanoparticles stabilized by aggregates of a hexaphenylbenzene derivative has been developed which exhibits excellent photocatalytic efficiency in reactions involving preparation of imidazole and benzimidazole derivatives via C-H activation.	Chem. Soc. Rev.	165	Ackermann, L	FALSE	FALSE	FALSE	FALSE
452	10.1002/ejoc.201901140	doi.org/10.1002/ejoc.201901140	A Fe3O4@SiO2/Schiff Base/Pd Complex as an Efficient Heterogeneous and Recyclable Nanocatalyst for One-Pot Domino Synthesis of Carbamates and Unsymmetrical Ureas		Eur. J. Org. Chem.	165	Inaloo, ID	FALSE	FALSE	FALSE	FALSE
453	10.1021/acs.organomet.7b00613	doi.org/10.1021/acs.organomet.7b00613	Experimental and Computational Studies of High-Valent Nickel and Palladium Complexes		Organometallics	165	Sanford, MS	FALSE	FALSE	FALSE	FALSE
454	10.1002/anie.201500201	doi.org/10.1002/anie.201500201	Palladium-Catalyzed Enantioselective CH Arylation for the Synthesis of P-Stereogenic Compounds		Angew. Chem.-Int. Edit.	165	Duan, WL	FALSE	FALSE	FALSE	FALSE
455	10.1021/cs5014927	doi.org/10.1021/cs5014927	Nickel N-Heterocyclic Carbene-Catalyzed C-C Bond Formation: Reactions and Mechanistic Aspects		ACS Catal.	165	Ritleng, V	FALSE	FALSE	FALSE	FALSE
456	10.1002/anie.201303916	doi.org/10.1002/anie.201303916	Transition-Metal-Catalyzed Laboratory-Scale Carbon-Carbon Bond-Forming Reactions of Ethylene		Angew. Chem.-Int. Edit.	165	Sigman, MS	FALSE	FALSE	FALSE	FALSE
457	10.1246/bcsj.20120081	doi.org/10.1246/bcsj.20120081	Nickel/Lewis Acid-Catalyzed Carbocyanation of Unsaturated Compounds		Bull. Chem. Soc. Jpn.	165	Nakao, Y	FALSE	FALSE	FALSE	FALSE
458	10.1021/acscatal.6b00993	doi.org/10.1021/acscatal.6b00993	Manganese-Catalyzed C-H Activation		ACS Catal.	165	Ackermann, L	FALSE	FALSE	FALSE	FALSE
459	10.2174/1385272819666150423202719	doi.org/10.2174/1385272819666150423202719	Palladium Deposited on Naturally Occurring Supports as a Powerful Catalyst for Carbon-Carbon Bond Formation Reactions		Curr. Org. Chem.	165	Firouzabadi, H	FALSE	FALSE	FALSE	FALSE
460	10.1002/ejoc.202000169	doi.org/10.1002/ejoc.202000169	Bronsted Acid-Catalyzed Intramolecular alpha-Arylation of Ketones with Phenolic Nucleophiles via Oxy-Allyl Cation Intermediates	Nickel-based catalysis allows the efficient bis-allylation of soft nucleophiles with allylic alcohols. The reaction is best promoted by a combination of Ni(cod)(2) (cod = cyclooctadienyl) and diphenylphosphinobutane under additive-free conditions. Alternatively, nickel(II) precursors can be used provided that a reductant is used to generate the nickel(0) species. The NiCl2/Zn combination is particularly simple, and can advantageously replace the use of the more air-sensitive Ni(cod)(2) precursor. The scope of the reaction was studied with nucleophiles and allylic derivatives suitable for bis-allylation reactions.	Eur. J. Org. Chem.	164	Kano, T; Maruoka, K	FALSE	FALSE	FALSE	FALSE
461	10.1002/ajoc.201700591	doi.org/10.1002/ajoc.201700591	Synthesis and Chemical Transformations of Fluorosulfates		Asian J. Org. Chem.	164	Qin, HL	FALSE	FALSE	FALSE	FALSE
462	10.5059/yukigoseikyokaishi.72.797	doi.org/10.5059/yukigoseikyokaishi.72.797	Recent Progress of Chemical Glycosylations and Oligosaccharide Synthesis		J. Synth. Org. Chem. Jpn.	164	Nokami, T	FALSE	FALSE	FALSE	FALSE
463	10.1002/chem.201103882	doi.org/10.1002/chem.201103882	Theoretical Study on the Mechanism of Ni-Catalyzed Alkyl-Alkyl Suzuki Cross-Coupling		Chem.-Eur. J.	164	Fu, Y	FALSE	FALSE	FALSE	FALSE
464	10.1021/cr00098a001	doi.org/10.1021/cr00098a001	SYNTHETIC APPLICATIONS OF ENANTIOSELECTIVE ORGANOTRANSITION-METAL-MEDIATED REACTIONS		Chem. Rev.	164	BLYSTONE, SL	FALSE	FALSE	FALSE	FALSE
465	10.1002/ejoc.202100631	doi.org/10.1002/ejoc.202100631	Synthesis of N-Aryl- and N-Alkenylhydrazides through C(sp(2))-N Bond Construction		Eur. J. Org. Chem.	164	Lei, J	FALSE	FALSE	FALSE	FALSE
466	10.2174/1385272825666210531110403	doi.org/10.2174/1385272825666210531110403	Synthetic Approaches Toward Diversely Substituted 1,2,2-triarylethanones	Asymmetric allylic alkylation reaction of 1,3-dicarbonyl compounds is one of the most important methods for forming chiral carbon center. This review summarizes the progress on transition metal-catalyzed asymmetric allylic alkylation reaction of 1,3-dicarbonyl compounds. Different allylating reagents such as allylic esters, allylic alcohols, allylic halides, olefins, allenes and others for the synthesis of a-allyl substituted 1,3-dicarbonyl compounds are discussed.	Curr. Org. Chem.	163	Abonia, R	FALSE	FALSE	FALSE	FALSE
467	10.1021/acsami.0c15192	doi.org/10.1021/acsami.0c15192	Recent Advances in Plasmon-Promoted Organic Transformations Using Silver-Based Catalysts	Nonplanar, electronically destabilized amides have emerged as powerful, intermediates in organic synthesis. We report a highly selective method for transamidation of Common secondary amides under mild, metal-free conditions that relies on transient N-selective functionalization to weaken amidic resonance. The combination of rational modification of the amide bond with nucleophilic addition mechanism, and the thermodynamic collapse of the resultant tetrahedral intermediate transamidation of secondary amides under mild conditions. constitutes a two-step procedure to accomplish a Challenging	ACS Appl. Mater. Interfaces	163	Li, SW; Xu, P	FALSE	FALSE	FALSE	FALSE
468	10.1002/pi.5457	doi.org/10.1002/pi.5457	Poly(2-oxazoline)s: A comprehensive overview of polymer structures and their physical properties		Polym. Int.	163	Hoogenboom, R	FALSE	FALSE	FALSE	FALSE
469	10.1002/aoc.3289	doi.org/10.1002/aoc.3289	Iron-catalyzed cross-coupling of heteroaromatic tosylates with alkyl and aryl Grignard reagents		Appl. Organomet. Chem.	163	Wang, XC	FALSE	FALSE	FALSE	FALSE
470	10.1021/ja0208456	doi.org/10.1021/ja0208456	First comprehensive bakkane approach: Stereoselective and efficient dichloroketene-based total syntheses of (+/-)- and (-)-9-acetoxyfukinanolide, (+/-)- and (+)-bakkenolide A, (-)-bakkenolides III, B, C, H, L, V, and X, (+/-)- and (-)-homogynolide A, (+/-)-homogynolide B, and (+/-)-palmosalide C		J. Am. Chem. Soc.	163	Depres, JP	FALSE	FALSE	FALSE	FALSE
471	10.1039/d1ra08771a	doi.org/10.1039/d1ra08771a	Bakuchiol - a natural meroterpenoid: structure, isolation, synthesis and functionalization approaches		RSC Adv.	163	Krishna, TPA	FALSE	FALSE	FALSE	FALSE
472	10.1002/ejoc.202100695	doi.org/10.1002/ejoc.202100695	Borrowing Hydrogen and Acceptorless Dehydrogenative Coupling in the Multicomponent Synthesis of N-Heterocycles: A Comparison between Base and Noble Metal Catalysis		Eur. J. Org. Chem.	163	Hultzsch, KC	FALSE	FALSE	FALSE	FALSE
473	10.3390/molecules26216374	doi.org/10.3390/molecules26216374	A Journey from June 2018 to October 2021 with N,N-Dimethylformamide and N,N-Dimethylacetamide as Reactants		Molecules	163	Muzart, J	FALSE	FALSE	FALSE	FALSE
474	10.1039/d0cs00449a	doi.org/10.1039/d0cs00449a	Transition metal-catalyzed alkene isomerization as an enabling technology in tandem, sequential and domino processes	An asymmetric synthesis of (-)-6,7-dideoxysqualestatin H5 is reported. Key features of the synthesis include the following: (1) highly diastereoselective n-alkylation of a tartrate acetonide enolate and subsequent oxidation-hydrolysis to provide an asymmetric entry to a beta-hydroxy-alpha-ketoester motif; (2) facilitation of Rh(II)-catalyzed cyclic carbonyl ylide formation-cycloaddition by co-generation of keto and diazo functionality through ozonolysis of an unsaturated hydrazone; and (3) stereoretentive Ni-catalyzed Csp(3)-Csp(2) cross-electrophile coupling between tricarboxylate core and unsaturated side chain to complete the natural product.	Chem. Soc. Rev.	162	Mazet, C	FALSE	FALSE	FALSE	FALSE
475	10.1002/asia.201901179	doi.org/10.1002/asia.201901179	Synthetic Strategies for (-)-Cannabidiol and Its Structural Analogs		Chem.-Asian J.	162	Choi, IS	FALSE	FALSE	FALSE	FALSE
476	10.6023/cjoc201803053	doi.org/10.6023/cjoc201803053	Recent Progress in C-C Bond Construction Based on 2(5H)-Furanone		Chin. J. Org. Chem.	162	Wang, ZY	FALSE	FALSE	FALSE	FALSE
477	10.1021/om200998d	doi.org/10.1021/om200998d	Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)((Pr2PCH2CH2OCH3)-Pr-i)(2)]: C-F Bond Formation and Catalytic C-F Bond Activation Reactions		Organometallics	162	Braun, T	FALSE	FALSE	FALSE	FALSE
478	10.1016/S0957-4166(00)82091-1	doi.org/10.1016/S0957-4166(00)82091-1	SELECTIVITY IN PALLADIUM CATALYZED ALLYLIC SUBSTITUTION		Tetrahedron: Asymmetry	162		FALSE	FALSE	FALSE	FALSE
479	10.1007/s40843-021-1910-2	doi.org/10.1007/s40843-021-1910-2	Application of hierarchically porous metal-organic frameworks in heterogeneous catalysis: A review		Sci. China-Mater.	162	Yu, Y; Xi, HX	FALSE	FALSE	FALSE	FALSE
480	10.1021/acscatal.6b03277	doi.org/10.1021/acscatal.6b03277	Breaking Amides using Nickel Catalysis		ACS Catal.	162	Garg, NK	FALSE	FALSE	FALSE	FALSE
481	10.1021/acscatal.6b02964	doi.org/10.1021/acscatal.6b02964	An Adventure in Sustainable Cross-Coupling of Phenols and Derivatives via Carbon-Oxygen Bond Cleavage		ACS Catal.	162	Zeng, HY; Li, CJ	FALSE	FALSE	FALSE	FALSE
482	10.1515/pac-2019-0220	doi.org/10.1515/pac-2019-0220	Well-defined nickel(II) tetrazole-saccharinate complex as homogeneous catalyst on the reduction of aldehydes: scope and reaction mechanism		Pure Appl. Chem.	161	Frija, LMT	FALSE	FALSE	FALSE	FALSE
483	10.1002/asia.201200338	doi.org/10.1002/asia.201200338	Stereoselective Glycosylation of Glucosamine: The Role of the N-Protecting Group		Chem.-Asian J.	161	Marques, MMB	FALSE	FALSE	FALSE	FALSE
484	10.1002/anie.202115178	doi.org/10.1002/anie.202115178	Electrochemical Desaturative beta-Acylation of Cyclic N-Aryl Amines		Angew. Chem.-Int. Edit.	161	Qiu, YA	FALSE	TRUE	FALSE	FALSE
485	10.1002/chem.202101880	doi.org/10.1002/chem.202101880	Mechanistic Aspects of the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction		Chem.-Eur. J.	160	Poater, A	FALSE	FALSE	FALSE	FALSE
486	10.1002/adsc.202001053	doi.org/10.1002/adsc.202001053	Recent Developments in Remote Meta-C-H Bond Functionalizations	Six-membered pincer nickelacycle complexes have been synthesized and employed for the catalytic C-H bond alkylation of benzothiazole. The pincer nickelacycle, {kappa(P),kappa(C),kappa(P)-(2-Pr-i(2) POCH2-C6H3-6-(CH2OPPr2)-Pr-i)} NiBr, [(Pr-i(4)-POCCCOP) NiBr (2)] was synthesized by the reaction of 1,3-(Pr2POCH2)-Pr-i-C6H4-(CH2OPPr2)-Pr-i [(iPr(4)-POCCCOP) - H (1)] with (CH3CN)(2)NiBr2 in the presence of Et3N via the C(2)-H activation on ligand 1. Treatment of [(Pr-i(4)-POCCCOP) NiBr] (2) with AgOAc afforded the complex [(i Pr4-POCCCOP) Ni(OAc)] (3) in good yield. Both the complexes 2 and 3 were characterized by H-1, C-13 and P-31-NMR spectral analysis. Further, the molecular structures of complexes 2 and 3 were established by X-ray crystallography. The complex 2 was found to be an active catalyst for the C-H bond alkylation of benzothiazole with alkyl halides containing beta-hydrogen atoms.	Adv. Synth. Catal.	159	Ali, R	FALSE	FALSE	FALSE	FALSE
487	10.21577/0100-4042.20170701	doi.org/10.21577/0100-4042.20170701	RECENT ADVANCES IN SELECTIVE FUNCTIONALIZATION OF QUINOLINES.	A Truce-Smiles rearrangement of acyl-anion equivalents generated by N-heterocyclic carbene (NHC) catalysis has been achieved. The developed method includes C-Ar-O, C-Ar-S, or C-Ar-N bond cleavage for the formation of a C-Ar-C bond and enables access to 2-hydroxybenzophenones, an important structural motif that is present in several bioactive natural products. By utilizing this procedure, the alkaloid taxilamine was synthesized in three steps. DFT calculations and control experiments support a classical SNAr mechanism with a catalyst-bound Meisenheimer-type intermediate. The method features mild reaction conditions, excellent functional-group tolerance, and a broad substrate scope, including various classes of (hetero)arenes.	Quim. Nova	159	Clososki, GC	FALSE	FALSE	FALSE	FALSE
488	10.1021/acscatal.0c01356	doi.org/10.1021/acscatal.0c01356	Asymmetric Allylic Alkylation of beta-Ketoesters via C-N Bond Cleavage of N-Allyl-N-methylaniline Derivatives Catalyzed by a Nickel-Diphosphine System	The formal total synthesis of both the enantiomers of cyclophellitol and conduritol-B and synthesis of conduramine-B derivative have been achieved from a common intermediate, obtained by regio- and stereoselective vicinal functionalization of a diene utilizing an intramolecular sulfinyl group as a nucleophile, followed by stereoselective preparation of an allylic sulfide by reaction of vinylzinc bromide with an electrophilic a-chloro sulfide, and last by ring closing metathesis reaction as the key steps. The sulfoxide, sulfilimine, and sulfur ylid prepared from this common intermediate have been transformed into derivatives of conduritol-B, conduramine-B, and (-)-cyclophellitol, respectively. The silyl sulfide was converted via sila-Pummerer rearrangement, hydrolysis, and reduction in an one-pot operation to a hydroxymethyl group. [2,3]-Wittig Still rearrangement was employed for the synthesis of (+)-cyclophellitol. The potential utility of sulfur intermediates as nucleophilic and electrophilic partners in total synthesis is elegantly demonstrated.	ACS Catal.	159	Zhang, WB	FALSE	FALSE	FALSE	FALSE
489	10.1002/adsc.201701515	doi.org/10.1002/adsc.201701515	Rhodium(III)-Catalyzed Selective Direct Olefination of Imidazoles		Adv. Synth. Catal.	159	Xu, LJ	FALSE	FALSE	FALSE	FALSE
490	10.1002/chem.201303384	doi.org/10.1002/chem.201303384	Pd-Catalyzed Carbonylative alpha-Arylation of Aryl Bromides: Scope and Mechanistic Studies		Chem.-Eur. J.	159	Gogsig, TM	FALSE	FALSE	FALSE	FALSE
491	10.1002/asia.202100957	doi.org/10.1002/asia.202100957	Catalysis in Single Crystalline Materials: From Discrete Molecules to Metal-Organic Frameworks		Chem.-Asian J.	159	Shi, Q; Wang, XP; Wang, LY	FALSE	FALSE	FALSE	FALSE
492	10.1016/j.ccr.2021.213889	doi.org/10.1016/j.ccr.2021.213889	The role of organonickel reagents in organophosphorus chemistry		Coord. Chem. Rev.	159	Gafurov, ZN; Yakhvarov, DG	FALSE	FALSE	FALSE	FALSE
493	10.5059/yukigoseikyokaishi.76.1185	doi.org/10.5059/yukigoseikyokaishi.76.1185	Catalytic Synthesis of Heterocycles via the Cleavage of Carbon-Heteroatom Bonds		J. Synth. Org. Chem. Jpn.	158	Tobisu, M	FALSE	FALSE	FALSE	FALSE
494	10.1002/ajoc.201500105	doi.org/10.1002/ajoc.201500105	Reusable and Removable Directing Groups for C(sp(2))-H Bond Functionalization of Arenes		Asian J. Org. Chem.	158	Sahoo, AK	FALSE	FALSE	FALSE	FALSE
495	10.1016/S0065-3055(08)60016-7	doi.org/10.1016/S0065-3055(08)60016-7	CARBON-OXYGEN BOND ACTIVATION BY TRANSITION-METAL COMPLEXES		Adv. Organomet. Chem.	158	YAMAMOTO, A	FALSE	FALSE	FALSE	FALSE
496	10.1039/d0sc05555g	doi.org/10.1039/d0sc05555g	Recent development in transition metal-catalysed C-H olefination	Total synthesis of leucinostatinA, a modulator of tumor-stroma interactions, using asymmetric catalyses, a nitroaldol reaction, thioamide-aldol reaction, Strecker-type reaction, and alcoholysis of 3-methylglutaric anhydride, is described. We demonstrated the applicability of the established catalytic asymmetric processes to the synthesis of molecules with a complex structure. Careful analysis of the NMR data, HPLC profiles, and biological activity revealed that the correct structure of leucinostatinA is the epimeric form of the reported structure; the secondary alcohol within the AHMOD residue has an R configuration.	Chem. Sci.	157	Maiti, D	FALSE	FALSE	FALSE	FALSE
497	10.1021/acs.organomet.0c00233	doi.org/10.1021/acs.organomet.0c00233	Solvent-Free N-Alkylation and Dehydrogenative Coupling Catalyzed by a Highly Active Pincer-Nickel Complex	We prepared a series of dendrimers with a bidentate phosphine core ligand having carboxy groups at the peripheral layer. By employing the corresponding water-soluble dendritic phosphine palladium complex as a catalyst, the aqueous media Suzuki-Miyaura reaction and Tsuji-Trost reaction proceeded to provide the corresponding cross-coupling product.	Organometallics	157	Srivastava, HK; Kumar, A	FALSE	FALSE	FALSE	FALSE
498	10.1016/j.ccr.2019.03.006	doi.org/10.1016/j.ccr.2019.03.006	Half-sandwich Ni(II) complexes [Ni(Cp)(X)(NHC)]: From an underestimated discovery to a new chapter in organonickel chemistry		Coord. Chem. Rev.	157	Buchowicz, W	FALSE	FALSE	FALSE	FALSE
499	10.3390/molecules23112859	doi.org/10.3390/molecules23112859	Amide Activation in Ground and Excited States		Molecules	157	Mucsi, Z	FALSE	FALSE	FALSE	FALSE
500	10.1055/s-0033-1339435	doi.org/10.1055/s-0033-1339435	Organometallic Aspects of Fluoroalkylation Reactions with Copper and Nickel		Synlett	157	Vicic, DA	FALSE	FALSE	FALSE	FALSE
501	10.1021/acscatal.0c02990	doi.org/10.1021/acscatal.0c02990	Transition-Metal-Catalyzed Denitrative Coupling of Nitroarenes	The utilization of substoichiometric amounts of commercially available nickel(II) triflate as an activator in the reagent-controlled glycosylation reaction for the stereoselective construction of biologically relevant targets containing 1,2-cis-2-amino glycosidic linkages is reported. This straightforward and accessible methodology is mild, operationally simple and safe through catalytic activation by readily available Ni(OTf)(2) in comparison to systems employing our previously in-house prepared Ni(4-F-PhCN)(4)(OTf)(2). We anticipate that the bench-stable and inexpensive Ni(OTf)(2), coupled with little to no extra laboratory training to set up the glycosylation reaction and no requirement of specialized equipment, should make this methodology be readily adopted by non-carbohydrate specialists. This report further highlights the efficacy of Ni(OTf)(2) to prepare several bioactive motifs, such as blood type A-type V and VI antigens, heparin sulfate disaccharide repeating unit, aminooxy glycosides, and alpha-GalNAc-Serine conjugate, which cannot be achieved in high yield and a -selectivity utilizing in-house prepared Ni(4-F-PhCN)(4)(OTf)(2) catalyst. The newly-developed protocol eliminates the need for the synthesis of Ni(4-F-PhCN)(4)(OTf)(2) and is scalable and reproducible. Furthermore, computational simulations in combination with H-1 NMR studies analyzed the effects of various solvents on the intramolecular hydrogen bonding network of tumor-associated mucin Fmoc-protected GalNAc-threonine amino acid antigen derivative, verifying discrepancies found that were previously unreported. (C) 2016 Elsevier Ltd. All rights reserved.	ACS Catal.	156	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
502	10.1002/anie.202003104	doi.org/10.1002/anie.202003104	Asymmetric Guerbet Reaction to Access Chiral Alcohols	The use of different metals acting together in a synergistic way allows synthetic transformations that are not achievable by other means. Metal cooperation becomes important in catalytic processes for the synthesis of compounds with sophisticated structures or for difficult transformations. Rational design of multiple-metal-catalysed processes requires that the metal complexes and reaction conditions are compatible, which in general is not straightforward. A key feature for success found in all systems involving multimetallic processes is catalyst stability. The use of robust metal complexes increases the probability of success in the search for tandem catalytic processes. This microreview is based on the recent and most important findings of multiple-metal-catalysed processes that have involved (de-)hydrogenation reactions. The field constitutes a research area that is full of potential, and it can be foreseen that relevant applications will be described in the near future.	Angew. Chem.-Int. Edit.	156	Wang, C	FALSE	FALSE	FALSE	FALSE
503	10.1039/c9sc03672e	doi.org/10.1039/c9sc03672e	Rhodium(i)-catalyzed C6-selective C-H alkenylation and polyenylation of 2-pyridones with alkenyl and conjugated polyenyl carboxylic acids		Chem. Sci.	156	Xu, LJ	FALSE	FALSE	FALSE	FALSE
504	10.1039/c8cs00960k	doi.org/10.1039/c8cs00960k	The growing applications of SuFEx click chemistry		Chem. Soc. Rev.	156	Moses, JE	FALSE	FALSE	FALSE	FALSE
505	10.1021/ja2084509	doi.org/10.1021/ja2084509	Mild and Efficient Nickel-Catalyzed Heck Reactions with Electron-Rich Olefins		J. Am. Chem. Soc.	156	Norrby, PO	FALSE	TRUE	FALSE	FALSE
506	10.1002/adsc.200900566	doi.org/10.1002/adsc.200900566	Nine Times Fluoride can be Good for your Syntheses. Not just Cheaper: Nonafluorobutanesulfonates as Intermediates for Transition Metal-Catalyzed Reactions		Adv. Synth. Catal.	156	Reissig, HU	FALSE	FALSE	FALSE	FALSE
507	10.1080/00397911.2021.1949476	doi.org/10.1080/00397911.2021.1949476	TEMPO-mediated aerobic oxidative synthesis of 2-aryl benzoxazoles via ring-opening of benzoxazoles with benzylamines		Synth. Commun.	156	Hussain, S	FALSE	FALSE	FALSE	FALSE
508	10.1016/j.tet.2016.02.022	doi.org/10.1016/j.tet.2016.02.022	Recent advances of synthesis of fluorenone and fluorene containing natural products		Tetrahedron	156	Gao, SH	FALSE	FALSE	FALSE	FALSE
509	10.1002/anie.201905870	doi.org/10.1002/anie.201905870	Transition-Metal-Free Hydrogen Autotransfer: Diastereoselective N-Alkylation of Amines with Racemic Alcohols		Angew. Chem.-Int. Edit.	155	Xiao, JL; Wang, C	FALSE	FALSE	FALSE	FALSE
510	10.1021/acs.organomet.7b00446	doi.org/10.1021/acs.organomet.7b00446	Catalysis of Cross-Coupling and Homocoupling Reactions of Aryl Halides Utilizing Ni(0), Ni(I), and Ni(II) Precursors; Ni(0) Compounds as the Probable Catalytic Species but Ni(I) Compounds as Intermediates and Products		Organometallics	155	Baird, MC	FALSE	FALSE	FALSE	FALSE
511	10.1007/3418_2015_90	doi.org/10.1007/3418_2015_90	Activation and Formation of Aromatic C-F Bonds		Top. Organomet. Chem.	155	Love, JA	FALSE	FALSE	FALSE	FALSE
512	10.1055/a-1516-8745	doi.org/10.1055/a-1516-8745	Highly Efficient Synthesis of 2-Substituted Benzo[b]furan Derivatives from the Cross-Coupling Reactions of 2-Halobenzo[b]furans with Organoalane Reagents		Synthesis	155	Li, QH	FALSE	FALSE	FALSE	FALSE
513	10.1002/anie.202102769	doi.org/10.1002/anie.202102769	Nickel-Catalyzed Asymmetric Reductive Carbo-Carboxylation of Alkenes with CO2		Angew. Chem.-Int. Edit.	155	Yu, DG	FALSE	FALSE	FALSE	FALSE
514	10.1055/s-0040-1705999	doi.org/10.1055/s-0040-1705999	Modification of Azobenzenes by Cross-Coupling Reactions	A phosphorylation of alkenyl and aryl C-O bonds at room temperature via photoredox/nickel dual catalysis is reported. By starting from easily available and inexpensive sulfonates, a variety of important alkenyl phosphonates and aryl phosphine oxides are generated in moderate to excellent yields. This method features mild reaction Conditions, high selectivity, good functional group tolerance, wide substrate Scope, and easy scalability.	Synthesis	154	Staubitz, A	FALSE	FALSE	FALSE	FALSE
515	10.1021/jacs.0c01666	doi.org/10.1021/jacs.0c01666	An Improved P-III/P-V=O-Catalyzed Reductive C-N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps		J. Am. Chem. Soc.	154	Radosevich, AT	FALSE	FALSE	FALSE	FALSE
516	10.2174/1570193X16666190617160339	doi.org/10.2174/1570193X16666190617160339	An Overview of Solid Supported Palladium and Nickel Catalysts for C-C Cross Coupling Reactions		Mini-Rev. Org. Chem.	154	Baroliya, PK	FALSE	FALSE	FALSE	FALSE
517	10.1039/c8cs00253c	doi.org/10.1039/c8cs00253c	Catalytic activations of unstrained C-C bond involving organometallic intermediates		Chem. Soc. Rev.	154	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
518	10.1016/j.tet.2012.04.059	doi.org/10.1016/j.tet.2012.04.059	A stereocontrolled construction of 2-azido-2-deoxy-1,2-cis-alpha-galactosidic linkages utilizing 2-azido-4,6-O-benzylidene-2-deoxygalactopyranosyl diphenyl phosphates: stereoselective synthesis of mucin core 5 and core 7 structures		Tetrahedron	154	Hashimoto, S	FALSE	FALSE	FALSE	FALSE
519	10.1021/ja104264v	doi.org/10.1021/ja104264v	Alternative Mechanistic Explanation for Ligand-Dependent Selectivities in Copper-Catalyzed N- and O-Arylation Reactions		J. Am. Chem. Soc.	154	Fu, Y	FALSE	FALSE	FALSE	FALSE
520	10.1002/ejoc.201000928	doi.org/10.1002/ejoc.201000928	Transition-Metal-Catalyzed Direct C-H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes		Eur. J. Org. Chem.	154	Messaoudi, S	FALSE	FALSE	FALSE	FALSE
521	10.1039/b810973g	doi.org/10.1039/b810973g	Versatile tools in the construction of substituted 2,2 '-bipyridines-cross-coupling reactions with tin, zinc and boron compounds		Chem. Soc. Rev.	154	Lutzen, A	FALSE	FALSE	FALSE	FALSE
522	10.1039/co9960300277	doi.org/10.1039/co9960300277	Catalytic applications of transition metals in organic synthesis		Contemp. Org. Synth.	154	Dawson, GJ	FALSE	FALSE	FALSE	FALSE
523	10.1016/j.cclet.2020.04.005	doi.org/10.1016/j.cclet.2020.04.005	Recent advances in theoretical studies on ligand-controlled selectivity of nickel- and palladium-catalyzed cross-coupling reactions	Constructing products of high synthetic value from inexpensive and abundant starting materials is of great importance. Aryl iodides are essential building blocks for the synthesis of functional molecules, and efficient methods for their synthesis from chemical feedstocks are highly sought after. Here we report a low-cost decarboxylative iodination that occurs simply from readily available benzoic acids and 12. The reaction is scalable and the scope and robustness- of the reaction is thoroughly examined. Mechanistic studies suggest that this reaction does not proceed via a radical mechanism, which is in contrast to classical Hunsdiecker-type decarboxylative halogenations. In addition, DFT studies allow comparisons to be made between our procedure and current transition-metal-catalyzed decarboxylations. The utility of this procedure is demonstrated in its application to oxidative cross-couplings of aromatics via decarboxylative/C-H or double decarboxylative activations that use 12 as the terminal oxidant. This strategy allows the preparation of biaryls previously inaccessible via decarboxylative methods and holds other advantages over existing decarboxylative oxidative couplings, as stoichiometric transition metals are avoided.	Chin. Chem. Lett.	153	Xie, HJ	FALSE	FALSE	FALSE	FALSE
524	10.7536/PC200607	doi.org/10.7536/PC200607	Progresses of 1,10-Phenanthroline Type Ligands in Fe/Co/Ni Catalysis	A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via C-sp2-O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C-heteroatom bond formations.	Prog. Chem.	153	Zhu, SF	FALSE	FALSE	FALSE	FALSE
525	10.1021/acs.joc.5b01450	doi.org/10.1021/acs.joc.5b01450	Cobalt-Catalyzed Decarboxylative 2-Benzoylation of Oxazoles and Thiazoles with alpha-Oxocarboxylic Acids		J. Org. Chem.	153	Sun, H	FALSE	FALSE	FALSE	FALSE
526	10.1021/ma401314x	doi.org/10.1021/ma401314x	Conjugated Polymer Synthesis via Catalyst-Transfer Polycondensation (CTP): Mechanism, Scope, and Applications		Macromolecules	153	McNeil, AJ	FALSE	FALSE	FALSE	FALSE
527	10.6023/cjoc201301073	doi.org/10.6023/cjoc201301073	Recent Advances in the Synthesis of Stilbenes		Chin. J. Org. Chem.	153	Zhao, SC	FALSE	FALSE	FALSE	FALSE
528	10.1002/ajoc.202000631	doi.org/10.1002/ajoc.202000631	Recent Developments in Dehydrogenative Organic Transformations Catalyzed by Homogeneous Phosphine-Free Earth-Abundant Metal Complexes	A catalyst system capable of effecting the cross-coupling of ammonia or primary alkylamines with (hetero)aryl sulfamates, carbamates, or pivalates is reported for the first time. The air-stable nickel(II) pre-catalyst C1 tolerates a broad spectrum of heterocyclic functionality within both reaction partners, as well as ether, nitrile, pyrrole, trifluoromethyl, and boronate ester substituents. In the case of reactions involving primary alkylamines and (hetero)aryl sulfamates and carbamates, room-temperature cross-couplings were achieved.	Asian J. Org. Chem.	152	Takallou, A; Halimehjani, AZ	FALSE	FALSE	FALSE	FALSE
529	10.1055/s-0037-1611784	doi.org/10.1055/s-0037-1611784	Rhodium-Catalyzed Allylation Reactions		Synthesis	152	Kang, Q	FALSE	FALSE	FALSE	FALSE
530	10.1039/c7cc09675e	doi.org/10.1039/c7cc09675e	Diverse bimetallic mechanisms emerging from transition metal Lewis acid/base pairs: development of co-catalysis with metal carbenes and metal carbonyl anions		Chem. Commun.	152	Mankad, NP	FALSE	FALSE	FALSE	FALSE
531	10.1021/om5008743	doi.org/10.1021/om5008743	On the Feasibility of Nickel-Catalyzed Trifluoromethylation of Aryl Halides		Organometallics	152	Grushin, VV	FALSE	FALSE	FALSE	FALSE
532	10.1021/ja301769r	doi.org/10.1021/ja301769r	Replacing Conventional Carbon Nucleophiles with Electrophiles: Nickel-Catalyzed Reductive Alkylation of Aryl Bromides and Chlorides		J. Am. Chem. Soc.	152	Weix, DJ	FALSE	TRUE	FALSE	FALSE
533	10.1039/c2cs35024f	doi.org/10.1039/c2cs35024f	Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via pi-allylic species		Chem. Soc. Rev.	152	Bruneau, C	FALSE	FALSE	FALSE	FALSE
534	10.1039/d1cy01541a	doi.org/10.1039/d1cy01541a	Aerobic oxidation of primary amines to amides catalyzed by an annulated mesoionic carbene (MIC) stabilized Ru complex		Catal. Sci. Technol.	152	Bera, JK	FALSE	FALSE	FALSE	FALSE
535	10.1002/asia.201901490	doi.org/10.1002/asia.201901490	Nickel-Catalyzed Reductive Coupling for Transforming Unactivated Aryl Electrophiles into beta-Fluoroethylarenes		Chem.-Asian J.	151	Yang, Y; Liu, YL	FALSE	TRUE	FALSE	FALSE
536	10.1038/s41570-018-0040-8	doi.org/10.1038/s41570-018-0040-8	Comparing quantitative prediction methods for the discovery of small-molecule chiral catalysts		Nat. Rev. Chem.	151	Sigman, MS	FALSE	FALSE	FALSE	FALSE
537	10.1021/cs501366q	doi.org/10.1021/cs501366q	Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C-H Activation		ACS Catal.	151	Castarlenas, R	FALSE	FALSE	FALSE	FALSE
538	10.1002/ijch.201000043	doi.org/10.1002/ijch.201000043	Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations		Isr. J. Chem.	151	Ackermann, L	FALSE	FALSE	FALSE	FALSE
539	10.1055/a-1485-5156	doi.org/10.1055/a-1485-5156	Remote C-H Functionalizations by Ruthenium Catalysis		Synthesis	151	Ackermann, L	FALSE	FALSE	FALSE	FALSE
540	10.1002/anie.201608752	doi.org/10.1002/anie.201608752	Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles		Angew. Chem.-Int. Edit.	151	Wolf, C	FALSE	FALSE	FALSE	FALSE
541	10.1002/pep2.24210	doi.org/10.1002/pep2.24210	Recent developments in catalytic amide bond formation	The direct introduction of the valuable SCF3 moiety into organic molecules has received considerable attention. While it can be achieved successfully for aryl chlorides under catalysis with Ni degrees(cod)(2) and dppf, this report investigates the Ni-catalyzed functionalization of the seemingly more reactive aryl halides Arl and ArBr. Counterintuitively, the observed conversion triggered by dppf/Ni degrees is ArCI > ArBr > Arl, at odds with bond strength preferences. By a combined computational and experimental approach, the origin of this was identified to be due to the formation of (dppf)Ni-1, which favors beta-F elimination as a competing pathway over the productive cross-coupling, ultimately generating the inactive complex (dppf)Ni(SCF2) as a catalysis dead end. The complexes (dppf)Ni-1-Br and (dppf)Ni-1-I were isolated and resolved by X-ray crystallography. Their formation was found to be consistent with a ligand-exchange-induced comproportionation mechanism. In stark contrast to these phosphine-derived Ni complexes, the corresponding nitrogen-ligand-derived species were found to be likely competent catalysts in oxidation state I. Our computational studies of N-ligand derived Ni-1 complexes fully support productive Ni-1/Ni-111 catalysis, as the competing beta-F elimination is disfavored. Moreover, N-derived Ni-1 complexes are predicted to be more reactive than their Ni counterparts in catalysis. These data showcase fundamentally different roles of Ni-1 in carbon-heteroatom bond formation depending on the ligand sphere.	Pept. Sci.	150	Perrin, DM	FALSE	FALSE	FALSE	FALSE
542	10.1016/j.tet.2020.131388	doi.org/10.1016/j.tet.2020.131388	Metal-catalyzed cyanation of aromatic hydrocarbon with less toxic nitriles as a cyano source	Chemoselective Suzuki-Miyaura reactions on 3,5-and 4,6-dibromo-2-tosyloxypyridines have been studied for the preparation of trisubstituted pyridines. The optimized conditions allow for a facile access to 3,5-and 4,6-diaryl-2-tosyloxypyridines in yields of 8 to 99%. Further functionalization such as palladium-catalyzed amination and copper-free Sonogashira reaction of the tosylate group in the diarylpyridine derivatives obtained was accomplished for the synthesis of novel and biologically relevant tri-substituted pyridines. The formal synthesis of ficuseptine, a bioactive alkaloid, has also been achieved via the palladium-catalyzed cross-coupling reaction of 3,5-dibromo-2-tosyloxypyridine in 5 steps from 3,5-dibromo-2-hydroxypyridine with 50% overall yield.	Tetrahedron	150	Siddique, AM	FALSE	FALSE	FALSE	FALSE
543	10.1002/cjoc.202000224	doi.org/10.1002/cjoc.202000224	Nickel-CatalyzedDicarbofunctionalization of Alkenes(dagger)	A nickel-catalyzed phosphorylation of aryl triflates with P(O)-H compounds is disclosed. This reaction can proceed smoothly under a mild reaction condition, producing the corresponding aryl phosphorus compounds in good to high yields. (C) 2016 Elsevier B.V. All rights reserved.	Chin. J. Chem.	150	Zhang, XG	FALSE	FALSE	FALSE	FALSE
544	10.1038/s41557-018-0021-z	doi.org/10.1038/s41557-018-0021-z	Organic synthesis provides opportunities to transform drug discovery		Nat. Chem.	150	Rees, DC	FALSE	FALSE	FALSE	FALSE
545	10.1002/tcr.202100210	doi.org/10.1002/tcr.202100210	Transition Metal-Catalyzed Cross-Couplings of Benzylic Sulfone Derivatives		Chem. Rec.	150	Nambo, M; Crudden, CM	FALSE	FALSE	FALSE	FALSE
546	10.1007/s11426-018-9333-x	doi.org/10.1007/s11426-018-9333-x	Recent advances in Ni-Al bimetallic catalysis for unreactive bond transformation		Sci. China-Chem.	149	Ye, MC	FALSE	FALSE	FALSE	FALSE
547	10.1055/s-0036-1591853	doi.org/10.1055/s-0036-1591853	Recent Advances in Nickel Catalysis Enabled by Stoichiometric Metallic Reducing Agents		Synthesis	149	Richmond, E; Moran, J	FALSE	FALSE	FALSE	FALSE
548	10.1021/om301263s	doi.org/10.1021/om301263s	Mechanistic Study of Borylation of Nitriles Catalyzed by Rh-B and Ir-B Complexes via C-CN Bond Activation		Organometallics	149	Fu, Y	FALSE	FALSE	FALSE	FALSE
549	10.1039/c3ra22905j	doi.org/10.1039/c3ra22905j	A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates		RSC Adv.	149	Chow, WK	FALSE	FALSE	FALSE	FALSE
550	10.1246/bcsj.71.973	doi.org/10.1246/bcsj.71.973	Structure-reactivity relationship in allyl and 2-propynyl complexes of group 10 metals relevant to homogeneous catalysis		Bull. Chem. Soc. Jpn.	149	Kurosawa, H	FALSE	FALSE	FALSE	FALSE
551	10.1039/d1sc06038d	doi.org/10.1039/d1sc06038d	Direct synthesis and applications of solid silylzinc reagents		Chem. Sci.	149	Rasappan, R	FALSE	FALSE	FALSE	FALSE
552	10.1002/ejoc.202100066	doi.org/10.1002/ejoc.202100066	Diaryliodonium Salts in Transition-Metal-Catalyzed Chelation-Induced C(sp(2)/sp(3))-H Arylations	An efficient and redox-neutral naphthol synthesis has been realized via rhodium(III) catalyzed C-H activation of alpha-carbonyl nitrones and annulation with alkynes, where the nitrone group functioned as a traceless directing group.	Eur. J. Org. Chem.	148	Ranjan, D	FALSE	FALSE	FALSE	FALSE
553	10.1016/j.jorganchem.2018.01.019	doi.org/10.1016/j.jorganchem.2018.01.019	Computational studies on Ni-catalyzed C-O bond activation of esters		J. Organomet. Chem.	148	Hong, X	FALSE	FALSE	FALSE	FALSE
554	10.1002/chem.201705164	doi.org/10.1002/chem.201705164	Tsuji-Trost Reaction of Non-Derivatized Allylic Alcohols		Chem.-Eur. J.	148	Samec, JSM	FALSE	FALSE	FALSE	FALSE
555	10.1039/c3cc47587e	doi.org/10.1039/c3cc47587e	Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes		Chem. Commun.	148	Matsunaga, S	FALSE	FALSE	FALSE	FALSE
556	10.1002/chem.201001478	doi.org/10.1002/chem.201001478	The Aromatic Carbon-Carbon ipso-Substitution Reaction		Chem.-Eur. J.	148	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
557	10.5059/yukigoseikyokaishi.59.193	doi.org/10.5059/yukigoseikyokaishi.59.193	Synthetic studies on polyether natural products: New synthetic methods for construction of medium-sized cyclic ethers and convergent coupling of polyether fragments		J. Synth. Org. Chem. Jpn.	148	Sasaki, M	FALSE	FALSE	FALSE	FALSE
558	10.1016/j.chempr.2020.10.020	doi.org/10.1016/j.chempr.2020.10.020	Transition-metal-catalyzed C-H allylation reactions		Chem	148	Maiti, D	FALSE	FALSE	FALSE	FALSE
559	10.1016/j.tetlet.2017.05.083	doi.org/10.1016/j.tetlet.2017.05.083	Synthesis and structural characterization of a highly substituted triazine ring comprising a sterically flexible methylene linker and coordinating substituents		Tetrahedron Lett.	148	Werle, C; Meyer, K	FALSE	FALSE	FALSE	FALSE
560	10.1002/chem.201804805	doi.org/10.1002/chem.201804805	Filling a Niche in Ligand Space with Bulky, Electron-Poor Phosphorus(III) Alkoxides		Chem.-Eur. J.	147	Slattery, JM	FALSE	TRUE	FALSE	FALSE
561	10.1016/bs.aihch.2016.04.005	doi.org/10.1016/bs.aihch.2016.04.005	A Journey Through Metal-Catalyzed C-H Functionalization of Heterocycles: Insights and Trends		Adv. Heterocycl. Chem.	147	Maes, BUW	FALSE	FALSE	FALSE	FALSE
562	10.1021/ja5109084	doi.org/10.1021/ja5109084	Cobalt-Bisoxazoline-Catalyzed Asymmetric Kumada Cross-Coupling of Racemic alpha-Bromo Esters with Aryl Grignard Reagents		J. Am. Chem. Soc.	147	Zhong, JC	FALSE	FALSE	FALSE	FALSE
563	10.1016/j.tet.2013.05.001	doi.org/10.1016/j.tet.2013.05.001	Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters		Tetrahedron	147	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
564	10.1021/acscatal.7b01058	doi.org/10.1021/acscatal.7b01058	Revisitation of Organoaluminurn Reagents Affords a Versatile Protocol for C X (X = N, O, F) Bond-Cleavage Cross-Coupling: A Systematic Study		ACS Catal.	147	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
565	10.1039/d0nj01610a	doi.org/10.1039/d0nj01610a	N-Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst	Various aryl-, alkenyl-, and/or alkyllithium species reacted smoothly with aryl and/or benzyl ethers with cleavage of the inert C-O bond to afford cross-coupled products, catalyzed by commercially available [Ni(cod)(2)] (cod=1,5-cyclooctadiene) catalysts with N-heterocyclic carbene (NHC) ligands. Furthermore, the coupling reaction between the aryllithium compounds and aryl ammonium salts proceeded under mild conditions with C-N bond cleavage in the presence of a [Pd(PPh3)(2)Cl-2] catalyst. These methods enable selective sequential functionalizations of arenes having both C-N and C-O bonds in one pot.	New J. Chem.	146	Inaloo, ID	FALSE	FALSE	FALSE	FALSE
566	10.1002/chem.201800348	doi.org/10.1002/chem.201800348	Access to 3-Oxindoles from Allylic Alcohols and Indoles		Chem.-Eur. J.	146	Derien, S; Achard, M	FALSE	FALSE	FALSE	FALSE
567	10.1039/c7cs00182g	doi.org/10.1039/c7cs00182g	Cross-coupling of aromatic esters and amides		Chem. Soc. Rev.	146	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
568	10.1021/om500452c	doi.org/10.1021/om500452c	Mono- and Dinuclear Pincer Nickel Catalyzed Activation and Transformation of C-Cl, C-N, and C-O Bonds		Organometallics	146	Wang, ZX	FALSE	FALSE	FALSE	FALSE
569	10.1021/ic302854t	doi.org/10.1021/ic302854t	Complexes with Hybrid Phosphorus-NHC Ligands: Pincer-Type Ir Hydrides, Dinuclear Ag and Ir and Tetranuclear Cu and Ag Complexes		Inorg. Chem.	146	Braunstein, P	FALSE	FALSE	FALSE	FALSE
570	10.1016/S0040-4020(02)00045-5	doi.org/10.1016/S0040-4020(02)00045-5	A general strategy for the convergent synthesis of fused polycyclic ethers via B-alkyl Suzuki coupling: synthesis of the ABCD ring fragment of ciguatoxins		Tetrahedron	146	Sasaki, M	FALSE	FALSE	FALSE	FALSE
571	10.1039/d1ra06351k	doi.org/10.1039/d1ra06351k	Advances in Pd-catalyzed C-C bond formation in carbohydrates and their applications in the synthesis of natural products and medicinally relevant molecules		RSC Adv.	146	Hussain, N	FALSE	FALSE	FALSE	FALSE
572	10.3390/molecules25051141	doi.org/10.3390/molecules25051141	High-Valent Ni-III and Ni-IV Species Relevant to C-C and C-Heteroatom Cross-Coupling Reactions: State of the Art	Ketone is an important structural moiety in organic chemistry due to its wide occurrence in organic compounds and the highly transformable ability into other functionalities. Therefore, the efficient synthesis of ketones is of great significance. Recently, the ring-opening functionalization of tert-cyclobutanols represents one of the most important approaches to synthesize gamma-substituted alkyl ketones. A variety of functional groups can be efficiently introduced to the gamma-position of carbonyl via the regioselective C-C bond cleavage and a new chemical bond (C-C, C-N, C-O, C-F, etc.) formation. Two major pathways might be involved in the ring opening reactions of tert-cyclobutanols: a) transition metals, such as Pd(II) and Rh(I), catalyzed beta - carbon elimination of tert-cyclobutanols, and b) radical-mediated ring opening via the single electron oxidation of tert-cyclobutanols. The recent advances in the ring openings of tert-cyclobutanols and the related mechanistic details are described in this review.	Molecules	145	Nebra, N	FALSE	FALSE	FALSE	FALSE
573	10.1246/bcsj.20150180	doi.org/10.1246/bcsj.20150180	Alkynoxy-Directed C-H Functionalizations: Palladium(0)-Catalyzed Annulations of Alkynyl Aryl Ethers with Alkynes		Bull. Chem. Soc. Jpn.	145	Minami, Y	FALSE	FALSE	FALSE	FALSE
574	10.1039/c4cy01331j	doi.org/10.1039/c4cy01331j	RETRACTED: Monodisperse CuB23 nanoparticles grown on graphene as highly efficient catalysts for unactivated alkyl halide Heck coupling and levulinic acid hydrogenation (Publication with Expression of Concern. See vol. 9, pg. 1060, 2019) (Retracted article. See vol. 9, pg. 5160, 2019)		Catal. Sci. Technol.	145	Fu, SY	FALSE	FALSE	FALSE	FALSE
575	10.3762/bjoc.10.117	doi.org/10.3762/bjoc.10.117	Atherton-Todd reaction: mechanism, scope and applications		Beilstein J. Org. Chem.	145	Jaffres, PA	FALSE	FALSE	FALSE	FALSE
576	10.2174/138527205774913097	doi.org/10.2174/138527205774913097	Synthesis and coordination chemistry of cyano-substituted phosphines		Curr. Org. Chem.	145	Odinets, IL	FALSE	FALSE	FALSE	FALSE
577	10.1002/anie.202013976	doi.org/10.1002/anie.202013976	A Broad-Spectrum Catalytic Amidation of Sulfonyl Fluorides and Fluorosulfates**	Nickel(0)-catalyzed cross-coupling of methoxyarenes through C-O bond activation has been the subject of considerable research because of their favorable features compared with those of the cross-coupling of aryl halides, such as atom economy and efficiency. In 2008, we have reported nickel/PCy3-catalyzed cross-coupling of methoxyarenes with arylboronic esters in which the addition of a stoichiometric base such as CsF is essential for the reaction to proceed. Recently, we have also found that the scope of the substrate in the Suzuki Miyaura-type cross-coupling of methoxyarenes can be greatly expanded by using 1,3-dicyclohexylimidazol-2-ylidene (ICy) as the ligand. Interestingly, a stoichiometric amount of external base is not, required for the nickel/ICy-catalyzed cross-coupling. For the mechanism and origin elucidated, density functional theory calculations are conducted. In the nickel/PCy3-catalyzed reactions, the activation energy for the oxidative addition of the Caryl)-OMe bond is too high to occur under the catalytic conditions. However, the oxidative addition process becomes energetically feasible when CsF and an arylboronic ester interact with a Ni(PCy3)(2)/methoxyarene fragment to form a quaternary complex. In the nickel/ICy-catalyzed reactions, the oxidative addition of the Caryl)-OMe bond can proceed more easily without the aid of CsF because the nickel-ligand bonds are stronger and therefore stabilize the transition state. The subsequent transmetalation from an Ar-Ni-OMe intermediate is determined to proceed through a pathway with lower energies than those required for beta-hydrogen elimination. The overall driving force of the reaction is the reductive elimination to form the carbon carbon bond.	Angew. Chem.-Int. Edit.	144	Li, L	FALSE	FALSE	FALSE	FALSE
578	10.1021/acscatal.0c02454	doi.org/10.1021/acscatal.0c02454	P/N Heteroleptic Cu(I)-Photosensitizer-Catalyzed Deoxygenative Radical Alkylation of Aromatic Alkynes with Alkyl Aldehydes Using Dipropylamine as a Traceless Linker Agent	A transition-metal-free coupling of triorganoindium reagents with benzopyranyl acetals mediated by a Lewis acid has been developed. The reaction of R3In with chromene and isochroman acetals in the presence of BF3 center dot OEt2 afforded 2-substituted chromenes and 1-substituted isochromans, respectively, in good yields. The reactions proceed with a variety of triorganoindium reagents (aryl, heteroaryl, alkynyl, alkenyl, alkyl) using only 50 mol % of the organometallic, thus demonstrating the efficiency of these species. Preliminary mechanistic studies indicate the formation of an oxocarbenium ion intermediate in the presence of the Lewis acid.	ACS Catal.	144	Liu, YK	TRUE	FALSE	FALSE	FALSE
579	10.1002/cjoc.201900506	doi.org/10.1002/cjoc.201900506	Direct Transformation of Arenols Based on C-O Activation	An efficient nickel-catalyzed phosphorylation of phenol derivatives with P(O)-H compounds via C-O/P-H cross-coupling is described. Under the reaction conditions, various phenyl pivalates coupled readily with hydrogen phosphoryl compounds to afford the corresponding coupling products aryl phosphonates and aryl phosphine oxides in good to high yields.	Chin. J. Chem.	144	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
580	10.1055/s-0036-1590923	doi.org/10.1055/s-0036-1590923	Construction of Benzylic Stereogenic Carbon Centers through Enantioselective Arylation Reactions		Synlett	144	Jia, YX	FALSE	FALSE	FALSE	FALSE
581	10.1016/j.molcata.2014.10.031	doi.org/10.1016/j.molcata.2014.10.031	Nickel(II) complex incorporating methylene bridged tetradentate dicarbene ligand as an efficient catalyst toward C-C and C-N bond formation reactions		J. Mol. Catal. A-Chem.	144	Viswanathamurthi, P	FALSE	FALSE	FALSE	FALSE
582	10.1002/ejoc.201300850	doi.org/10.1002/ejoc.201300850	Palladium-Catalyzed Cross-Coupling Reaction of Functionalized Aryl- and Heteroarylbismuthanes with 2-Halo(or 2-Triflyl)azines and -diazines		Eur. J. Org. Chem.	144	Gagnon, A	FALSE	FALSE	FALSE	FALSE
583	10.1007/978-3-642-31081-2_2	doi.org/10.1007/978-3-642-31081-2_2	Noninnocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes		Top. Organomet. Chem.	144	Milstein, D	FALSE	FALSE	FALSE	FALSE
584	10.2174/157017911796957357	doi.org/10.2174/157017911796957357	Synthesis and Applications of Group 14-metalated Arylboranes		Curr. Org. Synth.	144	Lulinski, S	FALSE	FALSE	FALSE	FALSE
585	10.5059/yukigoseikyokaishi.74.885	doi.org/10.5059/yukigoseikyokaishi.74.885	Iridium-Catalyzed Enantioselective Allylic Substitution		J. Synth. Org. Chem. Jpn.	144	Takeuchi, R	FALSE	FALSE	FALSE	FALSE
586	10.1021/jacs.7b04973	doi.org/10.1021/jacs.7b04973	Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study		J. Am. Chem. Soc.	143	Hong, X	FALSE	FALSE	FALSE	FALSE
587	10.1002/chem.201500058	doi.org/10.1002/chem.201500058	Cobalt-Catalyzed Intermolecular C(sp(2))O Cross-Coupling		Chem.-Eur. J.	143	Ranu, BC	FALSE	FALSE	FALSE	FALSE
588	10.1021/ja3047816	doi.org/10.1021/ja3047816	Palladium-Catalyzed C(sp(3))-H Arylation of Diarylmethanes at Room Temperature: Synthesis of Triarylmethanes via Deprotonative-Cross-Coupling Processes		J. Am. Chem. Soc.	143	Dreher, SD	FALSE	FALSE	FALSE	FALSE
589	10.1039/c2cc17070a	doi.org/10.1039/c2cc17070a	Suzuki reactions of extended scope: the '9-MeO-9-BBN variant' as a complementary format for cross-coupling		Chem. Commun.	143	Furstner, A	FALSE	FALSE	FALSE	FALSE
590	10.1021/om800832r	doi.org/10.1021/om800832r	gamma-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R,S)-CyPF-t-Bu) Complex: Mechanistic Studies on Transmetalation and Enantioselection		Organometallics	143	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
591	10.1039/a803242d	doi.org/10.1039/a803242d	Catalytic applications of transition metals in organic synthesis		J. Chem. Soc.-Perkin Trans. 1	143	Tonks, L	FALSE	FALSE	FALSE	FALSE
592	10.1002/chem.19960021006	doi.org/10.1002/chem.19960021006	Stereoselective preparation of polyfunctional cyclopentane derivatives by radical nickel- or palladium-catalyzed carbozincations		Chem.-Eur. J.	143		FALSE	FALSE	FALSE	FALSE
593	10.5059/yukigoseikyokaishi.38.923	doi.org/10.5059/yukigoseikyokaishi.38.923	RECENT PROGRESS IN REGIOSELECTIVE CARBON-CARBON BOND FORMING REACTIONS INVOLVING AMBIDENT SUBSTRATES .2. THE REACTIONS OF AMBIDENT ELECTROPHILES		J. Synth. Org. Chem. Jpn.	143	ONO, M	FALSE	FALSE	FALSE	FALSE
594	10.1016/j.apcata.2015.11.044	doi.org/10.1016/j.apcata.2015.11.044	Cooperative effects of lanthanides when associated with palladium in novel, 3D Pd/Ln coordination polymers. Sustainable applications as water-stable, heterogeneous catalysts in carbon-carbon cross-coupling reactions		Appl. Catal. A-Gen.	143	Sun, YG	FALSE	FALSE	FALSE	FALSE
595	10.1039/d0dt00741b	doi.org/10.1039/d0dt00741b	Diamidophosphites from beta-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution	A regioselective pathway for the preparation of xanthones from 2-bromofluorobenzenes and salicylaldehydes has been developed. The reaction proceeded through palladium-catalyzed acylation-SNAr sequence. Good to moderate yields of the desired xanthones were prepared in one step. Based on the results of control experiments, a possible reaction mechanism has been proposed.	Dalton Trans.	142	Chuchelkin, IV	FALSE	FALSE	FALSE	FALSE
596	10.1002/anie.201812534	doi.org/10.1002/anie.201812534	High Throughput Strategies for the Discovery and Optimization of Catalytic Reactions		Angew. Chem.-Int. Edit.	142	Newman, SG	FALSE	FALSE	FALSE	FALSE
597	10.1166/jnn.2014.9013	doi.org/10.1166/jnn.2014.9013	Review on Palladium-Containing Perovskites: Synthesis, Physico-Chemical Properties and Applications in Catalysis		J. Nanosci. Nanotechnol.	142	El Kazzouli, S	FALSE	FALSE	FALSE	FALSE
598	10.1021/ja401466y	doi.org/10.1021/ja401466y	meta-Selective C-H Bond Alkylation with Secondary Alkyl Halides		J. Am. Chem. Soc.	142	Ackermann, L	FALSE	FALSE	FALSE	FALSE
599	10.1039/c0sc00234h	doi.org/10.1039/c0sc00234h	Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C-X bond formation		Chem. Sci.	142	Trost, BM	FALSE	FALSE	FALSE	FALSE
600	10.1134/S1070428009010011	doi.org/10.1134/S1070428009010011	Alkenylation of aromatic compounds		Russ. J. Organ. Chem.	142	Vasil'ev, AV	FALSE	FALSE	FALSE	FALSE
601	10.1021/jacs.1c06271	doi.org/10.1021/jacs.1c06271	Enantioselective Reductive Homocoupling of Allylic Acetates Enabled by Dual Photoredox/Palladium Catalysis: Access to C-2-Symmetrical 1,5-Dienes		J. Am. Chem. Soc.	142	Yu, SY	TRUE	FALSE	FALSE	FALSE
602	10.1021/acscatal.6b02269	doi.org/10.1021/acscatal.6b02269	Synthesis of Triazolylidene Nickel Complexes and Their Catalytic Application in Selective Aldehyde Hydrosilylation		ACS Catal.	142	Albrecht, M	FALSE	FALSE	FALSE	FALSE
603	10.1002/chem.202002849	doi.org/10.1002/chem.202002849	Stereoselective Remote Functionalization via Palladium-Catalyzed Redox-Relay Heck Methodologies	An iron(III) salt, (Z)-1,2-bis(diphenylphosphino)ethene or its electron-rich congener, (Z)-1,2-bis[bis(4-methoxyphenyl)phosphine]ethene, and a zinc(II) salt catalyze the arylation, heteroarylation, and alkenylation of propionamides possessing an 8-quinolylamide group with organoborate reagents in the presence of 1,2-dichlorobutane as oxidant at 70 degrees C. Stoichiometric experiments provided evidence for the involvement of an organoiron(III) species as a key intermediate for C-H activation and C -C bond formation.	Chem.-Eur. J.	141	Valette, D	FALSE	FALSE	FALSE	FALSE
604	10.2174/1385272824999200608135840	doi.org/10.2174/1385272824999200608135840	DFT Study of the Mechanisms of Transition-Metal-Catalyzed Reductive Coupling Reactions		Curr. Org. Chem.	141	Ren, QH	FALSE	FALSE	FALSE	FALSE
605	10.1021/jo3021192	doi.org/10.1021/jo3021192	Synthesis of 2-Phenyl-4,5-Substituted Oxazoles by Copper-Catalyzed Intramolecular Cyclization of Functionalized Enamides		J. Org. Chem.	141	Ila, H	FALSE	FALSE	FALSE	FALSE
606	10.1021/jo801985a	doi.org/10.1021/jo801985a	Synthesis of 2-Substituted Indoles and Indolines via Suzuki-Miyaura Coupling/5-endo-trig Cyclization Strategies		J. Org. Chem.	141	Fuwa, H	FALSE	FALSE	FALSE	FALSE
607	10.1002/ajoc.202200023	doi.org/10.1002/ajoc.202200023	Modern Development in Copper- and Nickel-Catalyzed Cross-Coupling Reactions: Formation of Carbon-Carbon and Carbon-Heteroatom bonds under Microwave Irradiation Conditions		Asian J. Org. Chem.	141	Salih, KSM	FALSE	FALSE	FALSE	FALSE
608	10.3762/bjoc.17.143	doi.org/10.3762/bjoc.17.143	Photoredox catalysis in nickel-catalyzed C-H functionalization		Beilstein J. Org. Chem.	141	Gandeepan, P	TRUE	FALSE	FALSE	FALSE
609	10.1002/tcr.202100142	doi.org/10.1002/tcr.202100142	Synthetic Applications of Nickel-Catalyzed Cross-Coupling and Cyclisation Reactions		Chem. Rec.	141	Durandetti, M	FALSE	FALSE	FALSE	FALSE
610	10.1002/tcr.201600039	doi.org/10.1002/tcr.201600039	Copper-Catalyzed Transformations Using Cu-H, Cu-B, and Cu-Si as Active Catalyst Species		Chem. Rec.	141	Tsuji, Y	FALSE	FALSE	FALSE	FALSE
611	10.1002/adsc.202000369	doi.org/10.1002/adsc.202000369	Iron-Mediated Cyanoalkylsulfonylation/Arylation of Active Alkenes with Cycloketone Oxime Derivatives via Sulfur Dioxide Insertion	Catalytic C-H functionalization using transition metals has received significant interest from organic chemists because it provides a new strategy to construct carbon-carbon bonds and carbon-heteroatom bonds in highly functionalized, complex molecules without pre-functionalization. Recently, inexpensive catalysts based on transition metals such as copper, iron, cobalt, and nickel have seen more use in the laboratory. This review describes recent progress in nickelcatalyzed aromatic C-H functionalization reactions classified by reaction types and reaction partners. Furthermore, some reaction mechanisms are described and cutting-edge syntheses of natural products and pharmaceuticals using nickel-catalyzed aromatic C-H functionalization are presented.	Adv. Synth. Catal.	140	Liu, Y	FALSE	FALSE	FALSE	FALSE
612	10.1002/anie.201914851	doi.org/10.1002/anie.201914851	P-III/P-V=O Catalyzed Cascade Synthesis of N-Functionalized Azaheterocycles		Angew. Chem.-Int. Edit.	140	Radosevich, AT	FALSE	FALSE	FALSE	FALSE
613	10.1039/c9cc01047e	doi.org/10.1039/c9cc01047e	Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations		Chem. Commun.	140	He, WM	FALSE	FALSE	FALSE	FALSE
614	10.1021/om500921d	doi.org/10.1021/om500921d	Theoretical Study on Homogeneous Hydrogen Activation Catalyzed by Cationic Ag(I) Complex		Organometallics	140	Fu, Y	FALSE	FALSE	FALSE	FALSE
615	10.1021/ic500258g	doi.org/10.1021/ic500258g	A Study on Zr-Ir Multiple Bonding Active for C-H Bond Cleavage		Inorg. Chem.	140	Suzuki, H	FALSE	FALSE	FALSE	FALSE
616	10.1021/ja2092954	doi.org/10.1021/ja2092954	Iridium-Catalyzed Allylic Vinylation and Asymmetric Allylic Amination Reactions with o-Aminostyrenes		J. Am. Chem. Soc.	140	You, SL	FALSE	FALSE	FALSE	FALSE
617	10.1246/cl.2011.330	doi.org/10.1246/cl.2011.330	Renaissance of Organic Synthesis Using Isocyanides		Chem. Lett.	140	Chatani, N	FALSE	FALSE	FALSE	FALSE
618	10.1039/d1nj03380h	doi.org/10.1039/d1nj03380h	Application of organometallic catalysts for the synthesis of o-tolyl benzonitrile, a key starting material for sartans		New J. Chem.	140	Swain, SP	FALSE	FALSE	FALSE	FALSE
619	10.1021/acscatal.5b02718	doi.org/10.1021/acscatal.5b02718	Recent Developments in Negishi Cross-Coupling Reactions		ACS Catal.	140	Knochel, P	FALSE	FALSE	FALSE	FALSE
620	10.1021/acscatal.5b02021	doi.org/10.1021/acscatal.5b02021	Nickel N-Heterocyclic Carbene-Catalyzed C-Heteroatom Bond Formation, Reduction, and Oxidation: Reactions and Mechanistic Aspects		ACS Catal.	140	Ritleng, V; Chetcuti, MJ	FALSE	FALSE	FALSE	FALSE
621	10.1021/jacs.0c03239	doi.org/10.1021/jacs.0c03239	Three-Component, Interrupted Radical Heck/Allylic Substitution Cascade Involving Unactivated Alkyl Bromides	A Ni catalytic system was developed for the decarboxylative coupling reaction of alkynyl carboxylic acids with organosilanes. Ni(acac)(2) and 1,10-phenanthroline showed the best result in the presence of CsF and CuF2 at 120 degrees C. This system tolerated the presence of alkyl, alkoxy, halogen, nitro, cyano, ketone, and ester functional groups. Moreover, the reaction with but-2-ynedioic acid and organosilane afforded the corresponding symmetrical diarylalkynes.	J. Am. Chem. Soc.	139	Glorius, F	FALSE	FALSE	FALSE	FALSE
622	10.1039/c2gc36455g	doi.org/10.1039/c2gc36455g	Organic synthesis via magnetic attraction: benign and sustainable protocols using magnetic nanoferrites		Green Chem.	139	Baig, RBN	FALSE	FALSE	FALSE	FALSE
623	10.1021/op300236f	doi.org/10.1021/op300236f	Ni- and Fe-Catalyzed Cross-Coupling Reactions of Phenol Derivatives		Org. Process Res. Dev.	139	Garg, NK	FALSE	FALSE	FALSE	FALSE
624	10.1002/ejoc.202001061	doi.org/10.1002/ejoc.202001061	One-Pot Controlled Reduction of Conjugated Amides by Sequential Double Hydrosilylation Catalyzed by an Iridium(III) Metallacycle	A regioselective one-pot synthesis of 2,3-diaryl-2H-1-benzopyrans from easily available various diary-lacetylenes and salicylaldehydes via Bronsted acid-catalyzed [4+2] cycloaddition has been developed. High regioselectivity was observed in the reaction to afford 2-(electron-rich aryl)-3-(electron-poor aryl)-2H-1-benzopyrans in good yields. The present reaction provides versatile access to functionalized 2,3-diaryl-2H-1-benzopyrans, which would be useful as key intermediates for the synthesis of biologically and photochemically active molecules. (C) 2016 Elsevier Ltd. All rights reserved.	Eur. J. Org. Chem.	138	Agbossou-Niedercorn, F; Michon, C	FALSE	FALSE	FALSE	FALSE
625	10.1021/acs.joc.0c01509	doi.org/10.1021/acs.joc.0c01509	Bulky-Yet-Flexible alpha-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air	Herein we present a novel strategy based on palladium-catalyzed allylic alkylation by taking advantage of the nucleophilic addition of external fluoride onto gem-difluoroalkenes as the initiation step. The merit of this protocol is highly appealing, as it enables a formal allylation of trifluoroethylarene derivatives through the in situ generation of beta-trifluorocarbanions, which otherwise are deemed to be problematic in deprotonative allylation. Furthermore, this strategy distinguishes itself by high modularity, operational simplicity, and wide substrate scope with respect to allyl carbonates, giving rise to a broad array of homoallyltrifluoromethane derivatives, which otherwise would not be easily obtained using existing synthetic methods.	J. Org. Chem.	138	Liu, FS	FALSE	FALSE	FALSE	FALSE
626	10.1007/s11164-020-04145-4	doi.org/10.1007/s11164-020-04145-4	A green and efficient Pd-free protocol for the Suzuki-Miyaura cross-coupling reaction using Fe3O4@APTMS@Cp2ZrClx(x=0, 1, 2) MNPs in PEG-400	A catalyst-free multicomponent CDC reaction is rarely reported, especially for the intermolecular tandem CDC cyclization, which represents an important strategy for constructing cyclic compounds. Herein, a three-component tandem CDC cyclization by a Pummerer-type rearrangement to afford biologically relevant isoindolinones from aromatic acids, amides, and DMSO, is described. This intermolecular tandem reaction undergoes a C(sp(2))-H/C(sp(3))-H cross-dehydrogenative coupling, C-N bond formation, and intramolecular amidation. A notable feature of this novel protocol is avoiding a catalyst and additive (apart from oxidant).	Res. Chem. Intermed.	138	Mousavi, H	FALSE	FALSE	FALSE	FALSE
627	10.1002/jccs.201900471	doi.org/10.1002/jccs.201900471	Directing group assists in transition metal-catalyzed site-selective C-H bond activation/transformations		J. Chin. Chem. Soc.	138	Wu, MJ	FALSE	FALSE	FALSE	FALSE
628	10.1016/j.tet.2018.10.025	doi.org/10.1016/j.tet.2018.10.025	Ligation state of nickel during C-O bond activation with monodentate phosphines		Tetrahedron	138	Neufeldt, SR	FALSE	FALSE	FALSE	FALSE
629	10.1002/chem.201202225	doi.org/10.1002/chem.201202225	Dual Hard/Soft Gold Catalysis: Intermolecular Friedel-Crafts-Type alpha-Amidoalkylation/Alkyne Hydroarylation Sequences by N-Acyliminium Ion Chemistry		Chem.-Eur. J.	138	Dalla, V	FALSE	FALSE	FALSE	FALSE
630	10.1002/adsc.201000311	doi.org/10.1002/adsc.201000311	Extremely Efficient Cross-Coupling of Benzylic Halides with Aryltitanium Tris(isopropoxide) Catalyzed by Low Loadings of a Simple Palladium(II) Acetate/Tris(p-tolyl)phosphine System		Adv. Synth. Catal.	138	Gau, HM	FALSE	FALSE	FALSE	FALSE
631	10.1002/ejoc.200700312	doi.org/10.1002/ejoc.200700312	Recent developments in catalytic aryl coupling reactions		Eur. J. Org. Chem.	138	Catellani, M	FALSE	FALSE	FALSE	FALSE
632	10.1021/om0108088	doi.org/10.1021/om0108088	Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)(2) and structural characterization of the product from aryl triflate addition in the presence of amine		Organometallics	138	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
633	10.1039/d1qm00792k	doi.org/10.1039/d1qm00792k	Porous cross-linked polymer copper and iridium catalyzed the synthesis of quinoxalines and functionalized ketones under solvent-free conditions		Mat. Chem. Front.	138	Wang, DW	FALSE	FALSE	FALSE	FALSE
634	10.1039/d1nj01442k	doi.org/10.1039/d1nj01442k	Recent advances in the transition metal catalyzed synthesis of quinoxalines: a review		New J. Chem.	138	Srivastava, S	FALSE	FALSE	FALSE	FALSE
635	10.1039/c7gc00067g	doi.org/10.1039/c7gc00067g	Biomass-derived solvents as effective media for cross-coupling reactions and C-H functionalization processes		Green Chem.	138	Vaccaro, L	FALSE	FALSE	FALSE	FALSE
636	10.1002/asia.202001032	doi.org/10.1002/asia.202001032	CuCl2-Mediated Oxidative Intramolecular alpha-Arylation of Ketones with Phenolic Nucleophiles via Oxy-Allyl Cation Intermediates	This paper is the first in a series of reviews of the state of-the-art in gold catalysis in organic synthesis and covers the literature over the past decade. The first review addresses the problem of the nucleophilic addition to the triple bond. Gold catalysts used in the hydroamination of alkynes and the addition of oxygen-containing nucleophiles and thiols are considered. The data concerning intra- and intermolecular types of transformations are given separately. The alpha,alpha-nucleophilic addition and Au carbene intermediates are discussed. The bibliography includes 568 reference	Chem.-Asian J.	137	Kano, T; Maruoka, K	FALSE	FALSE	FALSE	FALSE
637	10.1055/s-0040-1707101	doi.org/10.1055/s-0040-1707101	Non-Classical Amide Bond Formation: Transamidation and Amidation of Activated Amides and Esters by Selective N-C/O-C Cleavage	A nickel-catalyzed alkylation of polycyclic aromatic methyl ethers as well as methyl enol ethers with B-alkyl 9-BBN and trialkylborane reagents that involves the cleavage of stable C(sp(2))-OMe bonds is described. The transformation has a wide substrate scope and good chemoselectivity profile while proceeding under mild reaction conditions; it provides a versatile way to form C(sp(2))-C(sp(3)) bonds that does not suffer from -hydride elimination. Furthermore, a selective and sequential alkylation process by cleavage of inert C-O bonds is presented to demonstrate the advantage of this method.	Synthesis	137	Szostak, M	FALSE	FALSE	FALSE	FALSE
638	10.1002/asia.202000117	doi.org/10.1002/asia.202000117	Nickel or Palladium-Catalyzed Decarbonylative Transformations of Carboxylic Acid Derivatives	CuFe2O4 magnetic nanoparticles were prepared, characterized and used as a magnetically recoverable nanocatalyst for the one-pot synthesis of phenyl aryl/heteroaryl/benzyl sulfides through the crosscoupling reaction of phenylboronic acid with aryl/ heteroaryl/ benzyl halides in the presence of S-8 as a sulfur source in PEG400 as a reusable solvent at 80 degrees C. Also, the synthesis of symmetrical sulfides from aryl/ heteroaryl halides using S-8, KF and Cs2CO3 in PEG400 at 120 degrees C is described. The magnetic nanocatalyst was recycled up to 6 times with little loss of activity.	Chem.-Asian J.	137	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
639	10.1021/acscatal.9b04480	doi.org/10.1021/acscatal.9b04480	Catalytic Enantioselective alpha-Arylation of Carbonyl Enolates and Related Compounds		ACS Catal.	137	Zhou, Y	FALSE	FALSE	FALSE	FALSE
640	10.1039/c8dt01857j	doi.org/10.1039/c8dt01857j	Carbonyl and ester C-O bond hydrosilylation using kappa(4)-diimine nickel catalysts		Dalton Trans.	137	Trovitch, RJ	FALSE	FALSE	FALSE	FALSE
641	10.1002/chem.201404380	doi.org/10.1002/chem.201404380	Palladium-Catalyzed Cross-Coupling of Unactivated Aryl Sulfides with Arylzinc Reagents under Mild Conditions		Chem.-Eur. J.	137	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
642	10.1002/chem.201303249	doi.org/10.1002/chem.201303249	Mechanistic Study on Rh-Catalyzed Stereoselective C-C/C-H Activation of tert-Cyclobutanols		Chem.-Eur. J.	137	Dang, ZM	FALSE	FALSE	FALSE	FALSE
643	10.1039/b801888j	doi.org/10.1039/b801888j	Phosphate esters as ''tunable'' reagents in organic synthesis		Chem. Commun.	137	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
644	10.1002/chem.202102734	doi.org/10.1002/chem.202102734	Facile Synthesis of Alkylidene Phthalides by Rhodium-Catalyzed Domino C-H Acylation/Annulation of Benzamides with Aliphatic Carboxylic Acids		Chem.-Eur. J.	137	Shang, YP; Su, WP	FALSE	FALSE	FALSE	FALSE
645	10.1246/bcsj.20210248	doi.org/10.1246/bcsj.20210248	Synthesis of Difluoroalkenes from Thiocarbonyl Compounds via Difluorothiiranes: Electrophilic Counterpart to Wittig-Type Difluoromethylidenation		Bull. Chem. Soc. Jpn.	137	Ichikawa, J	FALSE	TRUE	FALSE	FALSE
646	10.1055/s-0035-1561198	doi.org/10.1055/s-0035-1561198	Polyfunctional Zinc and Magnesium Organometallics for Organic Synthesis: Some Perspectives		Synthesis	137	Knochel, P	FALSE	FALSE	FALSE	FALSE
647	10.1039/d0qo00820f	doi.org/10.1039/d0qo00820f	Access to 5H-benzo[a]carbazol-6-ols and benzo[6,7]cyclohepta[1,2-b]indol-6-olsviarhodium-catalyzed C-H activation/carbenoid insertion/aldol-type cyclization	Acylborons, as a growing class of boron reagents, were successfully applied to amide ligation and showed potential in chemoselective bioconjugation reactions in recent years. In this manuscript, a density functional theory (DFT) study was performed to investigate the mechanism of the amide formation between monofluoroacylboronates and hydroxylamines. An updated pathway was clarified herein, including water-assisted hemiaminal formation, pyridine ligand dissociation, elimination via a six-membered-ring transition state, and water-assisted tautomerization. The proposed mechanism was further examined by applying it to investigate the activation barriers of other monofluoroacylboronates, and the related calculations well reproduced the experimentally reported relative reactivities. On the basis of these results, we found that the ortho substitution of the pyridine ligand destabilizes the acylboron substrates and the hemiaminal intermediates by steric effects and thus lowers the energy demand of the ligand dissociation and elimination steps. By contrast, the para substitution of the pyridine ligand with an electron-donating group enhances the coordination of the ligand by electronic effects, which is a disadvantage to the ligand dissociation and elimination steps. The ligand bearing a rigid linkage blocks the rotation of the pyridine ligand and makes ligand dissociation difficult.	Org. Chem. Front.	136	Zhang, XF; Huang, QF	FALSE	FALSE	FALSE	FALSE
648	10.1021/acscatal.0c02115	doi.org/10.1021/acscatal.0c02115	Nickel-Catalyzed Dicarbofunctionalization of Alkenes	The development of glycobiology relies on the sources of particular oligosaccharides in their purest forms. As the isolation of the oligosaccharide structures from natural sources is not a reliable option for providing samples with homogeneity, chemical means become pertinent. The growing demand for diverse oligosaccharide structures has prompted the advancement of chemical strategies to stitch sugar molecules with precise stereo-and regioselectivity through the formation of glycosidic bonds. This Review will focus on the key developments towards chemical O-glycosylations in the current century. Synthesis of novel glycosyl donors and acceptors and their unique activation for successful glycosylation are discussed. This Review concludes with a summary of recent developments and comments on future prospects.	ACS Catal.	136	Diao, TN	FALSE	FALSE	FALSE	FALSE
649	10.3390/catal10030296	doi.org/10.3390/catal10030296	Recent Advances in Metal-Catalyzed Alkyl-Boron (C(sp(3))-C(sp(2))) Suzuki-Miyaura Cross-Couplings	In this paper, we report our results on the cyclization of (biphenyl-2-alkyne) derivatives to give two different types of phenanthrene derivatives, 9-iodo-10-organochalcogen-phenanthrenes and 9-organochalcogen-phenanthrenes. The strategy for the synthesis was based on the use of electrophilic cyclization for the preparation of 9-iodo-10-organochalcogen-phenanthrenes and iron(III) chloride/diorganyl diselenide-mediated intramolecular cyclization to prepare 9-organochalcogen-phenanthrenes. The effects of solvent, temperature, reaction time and stoichiometry on the efficiency of cyclization reactions were investigated. The standard reaction conditions were compatible with many functional groups in the substrates, such as methyl, chlorine, fluorine and methoxyl. This protocol was efficient for diorganyl diselenides and disulfides but ineffective for diorganyl ditellurides. The resulting phenanthrenes were further functionalized through Sonogashira reactions followed by the electrophilic cyclization reaction to give the selenophene-fused aromatic compounds.	Catalysts	136	Polychronopoulou, K	FALSE	FALSE	FALSE	FALSE
650	10.1021/jacs.8b06458	doi.org/10.1021/jacs.8b06458	Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation		J. Am. Chem. Soc.	136	Shenvi, RA	FALSE	FALSE	FALSE	FALSE
651	10.1021/acscatal.8b01879	doi.org/10.1021/acscatal.8b01879	Bisphosphines: A Prominent Ancillary Ligand Class for Application in Nickel-Catalyzed C-N Cross-Coupling		ACS Catal.	136	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
652	10.1039/c8dt01288a	doi.org/10.1039/c8dt01288a	Tailoring the structure, pH sensitivity and catalytic performance in Suzuki-Miyaura cross-couplings of Ln/Pd MOFs based on the 1,1-di(p-carboxybenzyl)-2,2-diimidazole linker		Dalton Trans.	136	Sun, YG	FALSE	FALSE	FALSE	FALSE
653	10.1055/s-0033-1339176	doi.org/10.1055/s-0033-1339176	Carbon-Sulfur Bond Formation via Metal-Catalyzed Allylations of Sulfur Nucleophiles		Synthesis	136	Zhao, XM	FALSE	FALSE	FALSE	FALSE
654	10.1002/chem.201201425	doi.org/10.1002/chem.201201425	Mechanism of the Pd-catalyzed Decarboxylative Allylation of alpha-Imino Esters: Decarboxylation via Free Carboxylate Ion		Chem.-Eur. J.	136	Chruma, JJ	FALSE	FALSE	FALSE	FALSE
655	10.1021/jo8024253	doi.org/10.1021/jo8024253	CuO Nanoparticles Catalyzed C-N, C-O, and C-S Cross-Coupling Reactions: Scope and Mechanism		J. Org. Chem.	136	Punniyamurthy, T	FALSE	FALSE	FALSE	FALSE
656	10.1021/ja00037a006	doi.org/10.1021/ja00037a006	NEW CYCLOPROPYL BUILDING BLOCKS FOR ORGANIC SYNTHESIS .9. NUCLEOPHILIC SUBSTITUTIONS OF 1-ALKENYLCYCLOPROPYL ESTERS AND 1-ALKYNYLCYCLOPROPYL CHLORIDES CATALYZED BY PALLADIUM(O)		J. Am. Chem. Soc.	136		FALSE	FALSE	FALSE	FALSE
657	10.1002/anie.198407821	doi.org/10.1002/anie.198407821	CHIRAL MACROCYCLES AS REAGENTS AND CATALYSTS		Angew. Chem.-Int. Edit. Engl.	136	KELLOGG, RM	FALSE	FALSE	FALSE	FALSE
658	10.1021/acs.organomet.1c00324	doi.org/10.1021/acs.organomet.1c00324	Palladium(II) Complexes of a Neutral CCC-Tris(N-heterocyclic carbene) Pincer Ligand: Synthesis and Catalytic Applications		Organometallics	136	Mendoza-Espinosa, D	FALSE	FALSE	FALSE	FALSE
659	10.1002/anie.202101682	doi.org/10.1002/anie.202101682	Transition-Metal-Free Synthesis of Polyfunctional Triarylmethanes and 1,1-Diarylalkanes by Sequential Cross-Coupling of Benzal Diacetates with Organozinc Reagents		Angew. Chem.-Int. Edit.	136	Knochel, P	FALSE	FALSE	FALSE	FALSE
660	10.1021/acs.joc.0c01233	doi.org/10.1021/acs.joc.0c01233	The Proven Versatility of Cp2TiCl	Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows rapid access to diverse nitroalkanes.	J. Org. Chem.	135	Martinez, AR	FALSE	FALSE	FALSE	FALSE
661	10.1002/chem.201803598	doi.org/10.1002/chem.201803598	Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines		Chem.-Eur. J.	135	Carmona, E	FALSE	FALSE	FALSE	FALSE
662	10.1039/c7sc04679k	doi.org/10.1039/c7sc04679k	Predictive and mechanistic multivariate linear regression models for reaction development		Chem. Sci.	135	Sigman, MS	FALSE	FALSE	FALSE	FALSE
663	10.1002/chem.201202950	doi.org/10.1002/chem.201202950	Three-Coordinate Nickel(I) Complexes Stabilised by Six-, Seven- and Eight-Membered Ring N-Heterocyclic Carbenes: Synthesis, EPR/DFT Studies and Catalytic Activity		Chem.-Eur. J.	135	Macgregor, SA	FALSE	FALSE	FALSE	FALSE
664	10.2174/138527211796150561	doi.org/10.2174/138527211796150561	The Meyers Reaction (1994-2010)		Curr. Org. Chem.	135	Mortier, J	FALSE	FALSE	FALSE	FALSE
665	10.1002/cctc.200900214	doi.org/10.1002/cctc.200900214	Catalytic Propargylic Substitution Reactions		ChemCatChem	135	Nishibayashi, Y	FALSE	FALSE	FALSE	FALSE
666	10.1021/ar00083a001	doi.org/10.1021/ar00083a001	PALLADIUM-CATALYZED OR NICKEL-CATALYZED CROSS COUPLING - A NEW SELECTIVE METHOD FOR CARBON CARBON BOND FORMATION		Accounts Chem. Res.	135	NEGISHI, EI	FALSE	FALSE	FALSE	FALSE
667	10.1021/acs.joc.1c00294	doi.org/10.1021/acs.joc.1c00294	Synthesis of 2-Aryl Acetophenones via Hydrobromination and Oxy-isomerization of (o-Arylethynyl)benzyl Alcohols		J. Org. Chem.	135	Hou, DR	FALSE	FALSE	FALSE	FALSE
668	10.1055/s-0036-1589008	doi.org/10.1055/s-0036-1589008	Recent Progress in the Cross-Coupling Reaction Using Triorganosilyl-Type Reagents		Synlett	135	Minami, Y; Hiyama, T	FALSE	FALSE	FALSE	FALSE
669	10.1002/tcr.201500305	doi.org/10.1002/tcr.201500305	Ni-Catalyzed Amination Reactions: An Overview		Chem. Rec.	135	Nicasio, MC	FALSE	FALSE	FALSE	FALSE
670	10.2533/chimia.2016.8	doi.org/10.2533/chimia.2016.8	Advances in Homogeneous Catalysis Using Secondary Phosphine Oxides (SPOs): Pre-ligands for Metal Complexes		Chimia	135	Achard, T	FALSE	FALSE	FALSE	FALSE
671	10.1039/d0gc02341h	doi.org/10.1039/d0gc02341h	Ligand-tuned cobalt-containing coordination polymers and applications in water	A nickel-catalyzed protocol for the conversion of aryl and heteroaryl alcohol derivatives to primary and secondary aromatic amines via C(sp(2))-O bond cleavage is described. The new amination protocol can be applied to a range of substrates bearing diverse functional groups and uses readily available benzophenone imines as an effective nitrogen source.	Green Chem.	134	Wang, DW	FALSE	FALSE	FALSE	FALSE
672	10.1021/jacs.0c07381	doi.org/10.1021/jacs.0c07381	Dialkyl Ether Formation at High-Valent Nickel	Herein, we describe the platinum-catalyzed borylation of aromatic C-H bonds. N-Heterocyclic carbene-ligated platinum catalysts are found to be efficient catalysts for the borylation of aromatic C(sp(2))-H bonds when bis(pinacolato)diboron is used as the boron source. The most remarkable feature of these Pt catalysts is their lack of sensitivity towards the degree of steric hindrance around the C-H bonds undergoing the borylation reaction. These Pt catalysts allow for the synthesis of sterically congested 2,6-disubstituted phenylboronic esters, which are otherwise difficult to synthesize using existing C-H borylation methods. Furthermore, platinum catalysis allows for the site-selective borylation of the C-H bonds ortho to fluorine substituents in fluoroarene systems. Preliminary mechanistic studies and work towards the synthetic application of this platinum catalyzed C-H borylation process are described.	J. Am. Chem. Soc.	134	Cornella, J	FALSE	FALSE	FALSE	FALSE
673	10.1021/acscatal.0c03237	doi.org/10.1021/acscatal.0c03237	A Widely Applicable Dual Catalytic System for Cross-Electrophile Coupling Enabled by Mechanistic Studies	A nickel-catalyzed stereoselective alkenylation of an unactivated beta-C(sp(3))-H bond in aliphatic amide with terminal alkynes using 8-aminoquinoline auxiliary is reported for the first time. This reaction displays excellent functional group tolerance with respect to both aliphatic amides and terminal alkynes and features a cheap nickel catalytic system. The 8-aminoquinolyl directing group could be smoothly removed, and the resultant beta-styrylcarboxylic acid derivatives could serve as versatile building blocks for further transformation.	ACS Catal.	134	Hazari, N	FALSE	TRUE	FALSE	FALSE
674	10.1007/s41061-020-0285-9	doi.org/10.1007/s41061-020-0285-9	Construction of Biologically Important Biaryl Scaffolds through Direct C-H Bond Activation: Advances and Prospects		Top. Curr. Chem.	134	Yu, B	FALSE	FALSE	FALSE	FALSE
675	10.1246/cl.190393	doi.org/10.1246/cl.190393	Ring-expanding and Ring-opening Transformations of Benzofurans and Indoles with Introducing Heteroatoms		Chem. Lett.	134	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
676	10.1039/c2cs35397k	doi.org/10.1039/c2cs35397k	Recent approaches for C-C bond formation via direct dehydrative coupling strategies		Chem. Soc. Rev.	134	Van der Eycken, EV	FALSE	FALSE	FALSE	FALSE
677	10.1021/ja205717f	doi.org/10.1021/ja205717f	Deacylative Allylation: Allylic Alkylation via Retro-Claisen Activation		J. Am. Chem. Soc.	134	Tunge, JA	FALSE	FALSE	FALSE	FALSE
678	10.1039/c0cy00069h	doi.org/10.1039/c0cy00069h	Superparamagnetic nanoparticles for asymmetric catalysis-a perfect match		Catal. Sci. Technol.	134	Ranganath, KVS	FALSE	FALSE	FALSE	FALSE
679	10.1016/j.tet.2008.11.007	doi.org/10.1016/j.tet.2008.11.007	Palladium-catalyzed desulfinylative C-C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters		Tetrahedron	134	Vogel, P	FALSE	FALSE	FALSE	FALSE
680	10.1021/jacs.1c10932	doi.org/10.1021/jacs.1c10932	Tunable and Practical Homogeneous Organic Reductants for Cross-Electrophile Coupling		J. Am. Chem. Soc.	134	Hazari, N	FALSE	TRUE	FALSE	FALSE
681	10.1016/j.jfluchem.2020.109652	doi.org/10.1016/j.jfluchem.2020.109652	New visible light organo(metal)-photocatalyzed fluoroalkylsulfanylation (RFS-) and fluoroalkylselenolation (RFSe-) reactions of organic substrates	We have developed an efficient strategy to prepare uniformly sized spherical NiNPs supported on chitosan surface via click chemistry. This heterogeneous catalyst has demonstrated promising catalytic activity for the Suzuki-Miyaura coupling. Furthermore, the obtained catalyst can be easily separated from the reaction mixture by centrifugation and reused several times with no significant loss of activity.	J. Fluor. Chem.	133	Barata-Vallejo, S; Postigo, A	FALSE	FALSE	FALSE	FALSE
682	10.1016/j.chempr.2020.04.005	doi.org/10.1016/j.chempr.2020.04.005	Nickel-Catalyzed C-H Functionalization Using A Non-directed Strategy	This study describes an efficient method for ortho-selective halogenation of N-arylcarbamates under mild conditions for the first time. Although being weakly coordinating, N-arylcarbamates act very well as a removable directing group for activation of C-H bonds. The developed procedure results in extremely valuable halogenated N-arylcarbmates that can further be hydrolyzed to halogenated anilines. The obtained reaction conditions showed broad scope and wide functional group tolerance. All the products were formed in good yields with extremely high selectivity.	Chem	133	Chatani, N	FALSE	FALSE	FALSE	FALSE
683	10.1021/jacs.9b02443	doi.org/10.1021/jacs.9b02443	Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes		J. Am. Chem. Soc.	133	Chirik, PJ	FALSE	FALSE	FALSE	FALSE
684	10.1055/s-0036-1591979	doi.org/10.1055/s-0036-1591979	Some Aspects of the Chemistry of Alkynylsilanes		Synthesis	133	Larson, GL	FALSE	FALSE	FALSE	FALSE
685	10.1021/acs.orglett.8b01021	doi.org/10.1021/acs.orglett.8b01021	Cross-Coupling of Amides with Alkylboranes via Nickel-Catalyzed C-N Bond Cleavage		Org. Lett.	133	Rueping, M	FALSE	FALSE	FALSE	FALSE
686	10.1002/adsc.201701452	doi.org/10.1002/adsc.201701452	A Heteroarylamine Library: Indium-Catalyzed Nucleophilic Aromatic Substitution of Alkoxyheteroarenes with Amines		Adv. Synth. Catal.	133	Tsuchimoto, T	FALSE	FALSE	FALSE	FALSE
687	10.2174/1570193X15666180220125122	doi.org/10.2174/1570193X15666180220125122	Recent Advance of Allylic Alcohol Reagents in Organic Synthesis		Mini-Rev. Org. Chem.	133	Liao, JH; Luo, RS	FALSE	FALSE	FALSE	FALSE
688	10.1021/ja411855d	doi.org/10.1021/ja411855d	NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides		J. Am. Chem. Soc.	133	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
689	10.1039/c2ob25395j	doi.org/10.1039/c2ob25395j	Transformations of diphenylphosphinothioic acid tertiary amides mediated by directed ortho metallation		Org. Biomol. Chem.	133	Ortiz, FL	FALSE	FALSE	FALSE	FALSE
690	10.1002/chem.201100967	doi.org/10.1002/chem.201100967	Synthetic Applications of the Nickel-Catalyzed Cyclization of Alkynes Combined with Addition Reactions in a Domino Process		Chem.-Eur. J.	133	Durandetti, M	FALSE	FALSE	FALSE	FALSE
691	10.1039/d1sc04011a	doi.org/10.1039/d1sc04011a	Transition metal-catalyzed organic reactions in undivided electrochemical cells		Chem. Sci.	133	Mei, TS	FALSE	FALSE	FALSE	FALSE
692	10.1039/d1nj03706d	doi.org/10.1039/d1nj03706d	Synthesis of ortho-arylated and alkenylated benzamides by palladium-catalyzed denitrogenative cross-coupling reactions of 1,2,3-benzotriazin-4(3H)-ones with organoboronic acids		New J. Chem.	133	Mannathan, S	FALSE	FALSE	FALSE	FALSE
693	10.1002/tcr.202100113	doi.org/10.1002/tcr.202100113	Nickel-Catalyzed C-H Bond Functionalization of Azoles and Indoles		Chem. Rec.	133	Punji, B	FALSE	FALSE	FALSE	FALSE
694	10.1021/acs.organomet.0c00775	doi.org/10.1021/acs.organomet.0c00775	16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp(2))- C(sp(3)) Kumada Cross-Couplings		Organometallics	133	Cornella, J	FALSE	TRUE	FALSE	FALSE
695	10.1016/j.jcou.2016.10.013	doi.org/10.1016/j.jcou.2016.10.013	Novel, recyclable supramolecular metal complexes for the synthesis of cyclic carbonates from epoxides and CO2 under solvent-free conditions		J. CO2 Util.	133	Yang, HJ	FALSE	FALSE	FALSE	FALSE
696	10.1002/chem.201603532	doi.org/10.1002/chem.201603532	Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines		Chem.-Eur. J.	133	Breit, B	FALSE	FALSE	FALSE	FALSE
697	10.1002/anie.202008854	doi.org/10.1002/anie.202008854	Enantioselective Nickel-Catalyzed Migratory Hydrocyanation of Nonconjugated Dienes	The palladium(0)-catalyzed, ligand-controlled, regioselective addition of diaryl acetonitrile pronucleophiles to propargylic carbonates is reported. Selective formation of either terminal 1,3-dienyl or propargylated products is proposed to arise from a change in reaction mechanism controlled by the denticity of the coordinating ligand.	Angew. Chem.-Int. Edit.	132	Fang, XJ	FALSE	FALSE	FALSE	FALSE
698	10.1002/asia.202000730	doi.org/10.1002/asia.202000730	Benzylic Methylene Functionalizations of Diarylmethanes	The highly enantioselective synthesis of a dibenzofuran-based C-2-symmetric chiral diol has been accomplished by the double enantioselective addition of diethylzinc to dibenzo[b,d]furan-4,6-dicarbaldehyde using a chiral 1,4-amino alcohol as a ligand. Among a series of chiral secondary diamines derived from the C-2-symmetric chiral diol, the chiral diamine with two pyrenyl groups can effectively separate enantiomeric H-1 NMR signals of various racemic acids.	Chem.-Asian J.	132	Laha, JK	FALSE	FALSE	FALSE	FALSE
699	10.3987/REV-19-914	doi.org/10.3987/REV-19-914	RECENT ADVANCES IN TRANSITION-METAL-CATALYZED SYNTHESIS OF 3-AND/OR 4-ARYL-2(1H)-QUINOLONES		Heterocycles	132	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
700	10.1021/acs.orglett.9b02398	doi.org/10.1021/acs.orglett.9b02398	Nickel-Catalyzed Decarbonylative Cyanation of Acyl Chlorides		Org. Lett.	132	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
701	10.1039/c8cc02325e	doi.org/10.1039/c8cc02325e	Synthesis of distorted nanographenes containing seven- and eight-membered carbocycles		Chem. Commun.	132	Campana, AG	FALSE	FALSE	FALSE	FALSE
702	10.1039/c6ob00084c	doi.org/10.1039/c6ob00084c	Palladium-catalyzed Suzuki-Miyaura coupling of amides by carbon-nitrogen cleavage: general strategy for amide N-C bond activation		Org. Biomol. Chem.	132	Szostak, M	FALSE	FALSE	FALSE	FALSE
703	10.1002/chem.201502101	doi.org/10.1002/chem.201502101	Palladium-Catalyzed Zinc-Amide-Mediated C-H Arylation of Fluoroarenes and Heteroarenes with Aryl Sulfides		Chem.-Eur. J.	132	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
704	10.1002/chem.201501453	doi.org/10.1002/chem.201501453	Dynamic Ligand Reactivity in a Rhodium Pincer Complex		Chem.-Eur. J.	132	van der Vlugt, JI	FALSE	FALSE	FALSE	FALSE
705	10.1021/acscatal.5b00606	doi.org/10.1021/acscatal.5b00606	Efficient Ruthenium-Catalyzed N-Methylation of Amines Using Methanol		ACS Catal.	132	Seayad, AM	FALSE	FALSE	FALSE	FALSE
706	10.1039/c4cc06445c	doi.org/10.1039/c4cc06445c	Pyridynes and indolynes as building blocks for functionalized heterocycles and natural products		Chem. Commun.	132	Garg, NK	FALSE	FALSE	FALSE	FALSE
707	10.1002/adsc.201400234	doi.org/10.1002/adsc.201400234	Multimetallic Iridium-Tin (Ir-Sn-3) Catalyst in N-Acyliminium Ion Chemistry: Synthesis of 3-Substituted Isoindolinones via Intra- and Intermolecular Amidoalkylation Reaction		Adv. Synth. Catal.	132	Roy, S	FALSE	FALSE	FALSE	FALSE
708	10.1039/c4ob00575a	doi.org/10.1039/c4ob00575a	Palladium-catalyzed tandem reaction of 2-hydroxyarylacetonitriles with sodium sulfinates: one-pot synthesis of 2-arylbenzofurans		Org. Biomol. Chem.	132	Su, WK	FALSE	FALSE	FALSE	FALSE
709	10.1039/c1dt10233h	doi.org/10.1039/c1dt10233h	Density functional studies on diimine chelated palladium complex catalyzed Suzuki-Miyaura cross-coupling reaction: the impact of Lewis base employed in transmetallation process		Dalton Trans.	132	Hong, FE	FALSE	FALSE	FALSE	FALSE
710	10.1016/S0022-328X(98)01055-9	doi.org/10.1016/S0022-328X(98)01055-9	Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995-1998		J. Organomet. Chem.	132	Suzuki, A	FALSE	FALSE	FALSE	FALSE
711	10.1002/chem.202104230	doi.org/10.1002/chem.202104230	Nickel-Catalyzed Arylative Cyclizations of Alkyne- and Allene-Tethered Electrophiles using Arylboron Reagents		Chem.-Eur. J.	132	Lam, HW	FALSE	TRUE	FALSE	FALSE
712	10.1021/acs.oprd.1c00410	doi.org/10.1021/acs.oprd.1c00410	Recent Advances in Nonprecious Metal Catalysis		Org. Process Res. Dev.	132	Haibach, MC	FALSE	FALSE	FALSE	FALSE
713	10.1002/hlca.202100175	doi.org/10.1002/hlca.202100175	New Access Routes to Privileged and Chiral Ligands for Transition-Metal Catalyzed Hydrogen Autotransfer (Borrowing Hydrogen), Dehydrogenative Condensation, and Alkene Isomerization Reactions		Helv. Chim. Acta	132	Hintermann, L	FALSE	FALSE	FALSE	FALSE
714	10.1021/jacs.1c03527	doi.org/10.1021/jacs.1c03527	Highly Regio- and Enantioselective Reductive Coupling of Alkynes and Aldehydes via Photoredox Cobalt Dual Catalysis		J. Am. Chem. Soc.	132	Xia, JB	TRUE	FALSE	FALSE	FALSE
715	10.1021/acscatal.7b00094	doi.org/10.1021/acscatal.7b00094	Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development		ACS Catal.	132	Molander, GA	TRUE	FALSE	FALSE	FALSE
716	10.1016/j.mencom.2019.01.001	doi.org/10.1016/j.mencom.2019.01.001	Triacetic acid lactone as a bioprivileged molecule in organic synthesis		Mendeleev Commun.	131	Sosnovskikh, VY	FALSE	FALSE	FALSE	FALSE
717	10.1021/acs.joc.8b01205	doi.org/10.1021/acs.joc.8b01205	Pd-PEPPSI-IPent(An) Promoted Deactivated Amination of Aryl Chlorides with Amines under Aerobic Conditions		J. Org. Chem.	131	Liu, FS	FALSE	FALSE	FALSE	FALSE
718	10.1080/00958972.2018.1439163	doi.org/10.1080/00958972.2018.1439163	Review: Recent advances of one-dimensional coordination polymers as catalysts		J. Coord. Chem.	131	Kostakis, GE	FALSE	FALSE	FALSE	FALSE
719	10.1021/jo402392t	doi.org/10.1021/jo402392t	Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds		J. Org. Chem.	131	Gao, YX	FALSE	FALSE	FALSE	FALSE
720	10.1002/ejoc.201201574	doi.org/10.1002/ejoc.201201574	Regio- and Stereoselective Olefination of Phenol Carbamates through C-H Bond Functionalization		Eur. J. Org. Chem.	131	Li, B	FALSE	FALSE	FALSE	FALSE
721	10.1002/adsc.201100646	doi.org/10.1002/adsc.201100646	Mizoroki-Heck Reactions Catalyzed by Dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium: Palladium Nanoparticle Formation Promoted by (Water-Induced) Ligand Degradation		Adv. Synth. Catal.	131	Frech, CM	FALSE	FALSE	FALSE	FALSE
722	10.1021/jo2003488	doi.org/10.1021/jo2003488	Structure and Reactivity of a Preactivated sp(2)-sp(3) Diboron Reagent: Catalytic Regioselective Boration of alpha,beta-Unsaturated Conjugated Compounds		J. Org. Chem.	131	Santos, WL	FALSE	FALSE	FALSE	FALSE
723	10.1002/tcr.20165	doi.org/10.1002/tcr.20165	Development of an Amphiphilic Resin-Dispersion of Nanopalladium and Nanoplatinum Catalysts: Design, Preparation, and Their Use in Green Organic Transformations		Chem. Rec.	131	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
724	10.1021/acs.organomet.1c00491	doi.org/10.1021/acs.organomet.1c00491	Formation of Allylpalladium Complexes and Asymmetric Allylation Involving Modular Bridging Diamidophosphite-Sulfides Based on 1,4-Thioether Alcohols		Organometallics	131	Chuchelkin, IV	FALSE	FALSE	FALSE	FALSE
725	10.1021/acs.organomet.7b00129	doi.org/10.1021/acs.organomet.7b00129	Stoichiometric and Catalytic Reactivity of Ni(6-Mes)(PPh3)(2)		Organometallics	131	Whittlesey, MK	FALSE	FALSE	FALSE	FALSE
726	10.1021/acs.chemrev.0c00301	doi.org/10.1021/acs.chemrev.0c00301	Metal-mediated C-CN Bond Activation in Organic Synthesis	A highly efficient copper catalyzed ligand-free C-S cross-coupling reaction of aryl halides with thiols has been performed in the presence of environmentally benign solvent glycerol. A variety of aryl thiols are prepared with good chemoselectivity and functional group tolerance. The catalytic system is found to be active for more challenging and less reactive aryl bromides. The catalyst and solvent are recyclable up to five cycles. The developed methodology is used for the synthesis of a sulfide precursor of Gemmacin B and Gemmacin antibiotics.	Chem. Rev.	130	Nakao, Y	FALSE	FALSE	FALSE	FALSE
727	10.1039/d0nj01996h	doi.org/10.1039/d0nj01996h	Recent advances in C-CN and C-H bond activation of green nitrile (MeCN) for organo-complexation, cyanation and cyanomethylation	Highly distorted polycyclic aromatic hydrocarbons (PAHs) are predicted to be attractive goals in nanoscience owing to the new properties they can exhibit. We have shown that a variety of functionalized distorted heptagon-containing nanographenes can be easily prepared from simple building blocks by a sequence of Co-catalyzed cyclotrimerization and cyclodehydrogenation reactions. The versatility of this strategy allows easy subsequent enlargement of these nanostructures by Ni-catalyzed cross-coupling and final cyclodehydrogenation reactions. Soluble extended distorted nanographenes 1 and 2 containing heptagon and an edge-shared pentagon-heptagon combination have been synthesized. High distortion of the polycyclic backbone of 2 caused by non-hexagonal rings and a helicene moiety was confirmed by X-ray crystallography. Experimental data reveal promising optical and electronic properties for distorted PAHs with long fluorescence lifetimes (up to 14.5 ns) and low band gaps (down to 2.27 eV). This straightforward and versatile synthetic strategy, the observed long fluorescence lifetimes and the small optical and electrochemical band gaps for the presented compounds may promote the future implementation of distorted graphene molecules in electronic devices.	New J. Chem.	130	Ahmad, MS	FALSE	FALSE	FALSE	FALSE
728	10.1021/acscatal.9b04586	doi.org/10.1021/acscatal.9b04586	Nickel-Catalyzed Cyanation of Aryl Halides and Hydrocyanation of Alkynes via C-CN Bond Cleavage and Cyano Transfer		ACS Catal.	130	Liao, XB	FALSE	FALSE	FALSE	FALSE
729	10.1039/c8dt02362j	doi.org/10.1039/c8dt02362j	Transformative 3d-4f coordination cluster carriers		Dalton Trans.	130	Kostakis, GE	FALSE	FALSE	FALSE	FALSE
730	10.1002/ejoc.201800175	doi.org/10.1002/ejoc.201800175	Forging Amides Through Metal-Catalyzed C-C Coupling with Isocyanates		Eur. J. Org. Chem.	130	Martin, R	FALSE	FALSE	FALSE	FALSE
731	10.1021/jo5025078	doi.org/10.1021/jo5025078	Transition-Metal-Free Access to Primary Anilines from Boronic Acids and a Common +NH2 Equivalent.		J. Org. Chem.	130	McCubbin, JA	FALSE	FALSE	FALSE	FALSE
732	10.1002/chem.201403356	doi.org/10.1002/chem.201403356	Nickel-Catalyzed Site-Selective Amidation of Unactivated C(sp(3))-H Bonds		Chem.-Eur. J.	130	Ge, HB	FALSE	FALSE	FALSE	FALSE
733	10.1021/jo402307x	doi.org/10.1021/jo402307x	Double Role of the Hydroxy Group of Phosphoryl in Palladium(II)-Catalyzed ortho-Olefination: A Combined Experimental and Theoretical Investigation		J. Org. Chem.	130	Zhu, J	FALSE	FALSE	FALSE	FALSE
734	10.1021/acs.organomet.1c00578	doi.org/10.1021/acs.organomet.1c00578	Dimenthylphosphine P-Oxide as a Synthetic Platform for Bulky and Chiral Ligands with Dimenthylphosphino Donor Groups		Organometallics	130	Hintermann, L	FALSE	FALSE	FALSE	FALSE
735	10.1016/j.chempr.2021.08.001	doi.org/10.1016/j.chempr.2021.08.001	Modern strategies for C-H functionalization of heteroarenes with alternative coupling partners		Chem	130	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
736	10.1007/s13738-021-02373-y	doi.org/10.1007/s13738-021-02373-y	3,3 '-((Arylmethylene)bis(4-methoxy-3,1-phenylene)) dipyridine derivatives as convenient ligands for Suzuki-Miyaura chemo- and homoselective cross-coupling reactions		J. Iran Chem. Soc.	130	Ranjbar-Karimi, R	FALSE	FALSE	FALSE	FALSE
737	10.3987/REV-16-SR(S)5	doi.org/10.3987/REV-16-SR(S)5	SYNTHESIS OF CAPRAZAMYCINS AND RELATED NATURAL PRODUCTS		Heterocycles	130	Watanabe, T	FALSE	FALSE	FALSE	FALSE
738	10.1002/adsc.202001493	doi.org/10.1002/adsc.202001493	Boron Reagents and Catalysts for the Functionalization of Strained Heterocycles	Despite their importance, the synthesis of alkylated heterocycles from the cross-coupling of Lewis basic nitrogen heteroaryl halides with alkyl halides remains a challenge. We report here a general solution to this challenge enabled by a new collection of ligands based around 2-pyridyl-N-cyanocarboxamidine and 2-pyridylcarboxamidine cores. Both primary and secondary alkyl halides can be coupled with 2-, 3-, and 4-pyridyl halides as well as other more complex heterocycles in generally good yields (41 examples, 69% ave yield).	Adv. Synth. Catal.	129	Pineschi, M	FALSE	FALSE	FALSE	FALSE
739	10.1002/anie.202009754	doi.org/10.1002/anie.202009754	Anti-Markovnikov Hydroamination of Racemic Allylic Alcohols to Access Chiral gamma-Amino Alcohols	The review summarizes data published in the last decade on the reactions of organic compounds involving N-acyliminium ions, including intramolecular arylation (cyclization), cross-coupling with nucleophiles and some other transformations to form new carbon carbon and carbon-heteroatom bonds. The stereo-and enantioselective versions of these reactions using chiral auxiliaries and asymmetric catalysts (organocatalysts) are considered. Examples of application of N-acyliminium ions for the synthesis of natural compounds and their analogues are presented. The bibliography includes 100 references.	Angew. Chem.-Int. Edit.	129	Wang, C	FALSE	FALSE	FALSE	FALSE
740	10.1039/c9sc03765a	doi.org/10.1039/c9sc03765a	New avenues for C-B bond formation via radical intermediates		Chem. Sci.	129	Studer, A	FALSE	FALSE	FALSE	FALSE
741	10.1021/acs.orglett.9b00692	doi.org/10.1021/acs.orglett.9b00692	Synthesis of gem-Difluoroalkenes by Merging Ni-Catalyzed C-F and C-C Bond Activation in Cross-Electrophile Coupling		Org. Lett.	129	Wang, C	FALSE	TRUE	FALSE	FALSE
742	10.1002/chem.201805987	doi.org/10.1002/chem.201805987	The Importance of Ligand-Induced Backdonation in the Stabilization of Square Planar d(10) Nickel -Complexes		Chem.-Eur. J.	129	Love, JA; Kennepohl, P	FALSE	FALSE	FALSE	FALSE
743	10.1002/cctc.201701601	doi.org/10.1002/cctc.201701601	Overview on the Recent Strategies for the Enantioselective Synthesis of 1,1-Diarylalkanes, Triarylmethanes and Related Molecules Containing the Diarylmethine Stereocenter		ChemCatChem	129	Panda, G	FALSE	FALSE	FALSE	FALSE
744	10.1039/c8cy00290h	doi.org/10.1039/c8cy00290h	Mechanism, selectivity, and reactivity of iridium- and rhodium-catalyzed intermolecular ketone alpha-alkylation with unactivated olefins via an enamide directing strategy		Catal. Sci. Technol.	129	Huang, GP	FALSE	FALSE	FALSE	FALSE
745	10.1021/acs.joc.8b00377	doi.org/10.1021/acs.joc.8b00377	Mechanism and Origins of Regio- and Enantioselectivities of Iridium-Catalyzed Hydroarylation of Alkenyl Ethers		J. Org. Chem.	129	Huang, GP	FALSE	FALSE	FALSE	FALSE
746	10.1002/cjoc.201700745	doi.org/10.1002/cjoc.201700745	Recent Advances in Transition Metal-Catalyzed Asymmetric Radical Reactions		Chin. J. Chem.	129	Kong, WQ	FALSE	FALSE	FALSE	FALSE
747	10.1002/ajoc.201500044	doi.org/10.1002/ajoc.201500044	Iron-Catalyzed Kumada Cross-Coupling Reactions of Pyrimidin-2-yl Phosphates: An Efficient Approach to C2-Functionalized Pyrimidines		Asian J. Org. Chem.	129	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
748	10.1021/jo101024f	doi.org/10.1021/jo101024f	Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides		J. Org. Chem.	129	Chatani, N	FALSE	FALSE	FALSE	FALSE
749	10.1002/ejic.202100820	doi.org/10.1002/ejic.202100820	Nickel-Catalyzed Allylic Substitution Reactions: An Evolving Alternative		Eur. J. Inorg. Chem.	129	Ghorai, D; Kleij, AW	FALSE	FALSE	FALSE	FALSE
750	10.1021/jacs.1c09797	doi.org/10.1021/jacs.1c09797	Nickel-Catalyzed Enantioselective Arylative Activation of Aromatic C-O Bond		J. Am. Chem. Soc.	129	Cao, ZC	FALSE	FALSE	FALSE	FALSE
751	10.6023/cjoc202103040	doi.org/10.6023/cjoc202103040	Research Progress of Suzuki-Miyaura Cross-Coupling Reaction Mechanism		Chin. J. Org. Chem.	129	Mo, FY	FALSE	FALSE	FALSE	FALSE
752	10.1002/ejoc.202100344	doi.org/10.1002/ejoc.202100344	Synthesis of Alkyl Fluorides by Silver-Catalyzed Radical Decarboxylative Fluorination of Cesium Oxalates		Eur. J. Org. Chem.	129	Brioche, J	FALSE	FALSE	FALSE	FALSE
753	10.1002/slct.201600411	doi.org/10.1002/slct.201600411	The Barbier-Type Allylation/Lactamization Cascade Route to Isoindolinones and the Heck-Type Annulation Route to Isoindolo[2,1-a] quinolines		ChemistrySelect	129	Babu, SA	FALSE	FALSE	FALSE	FALSE
754	10.1021/acs.organomet.6b00238	doi.org/10.1021/acs.organomet.6b00238	Efficient Approach To Construct Unsymmetrical Biaryls through Oxidative Coupling Reactions of Aromatic Primary Alcohols and Arylboronic Acids with a Rhodium Catalyst		Organometallics	129	Tian, Y; Wang, JH	FALSE	FALSE	FALSE	FALSE
755	10.1002/chem.201503090	doi.org/10.1002/chem.201503090	Near-IR BODIPY Dyes a la Carte-Programmed Orthogonal Functionalization of Rationally Designed Building Blocks		Chem.-Eur. J.	129	Pena-Cabrera, E	FALSE	FALSE	FALSE	FALSE
756	10.1038/s41557-020-00561-6	doi.org/10.1038/s41557-020-00561-6	Exploiting attractive non-covalent interactions for the enantioselective catalysis of reactions involving radical intermediates	A method for the catalytic enantioselective arylboration of alkenylarenes is disclosed. The reaction leads to the formation of 1,1-diarylalkanes that also incorporate an additional pinacol boronic ester which can be easily transformed to a variety of groups. The products are formed with excellent diastereoselectivities and enantioselectivities.	Nat. Chem.	128	Phipps, RJ	FALSE	FALSE	FALSE	FALSE
757	10.1021/acsomega.0c03415	doi.org/10.1021/acsomega.0c03415	Ligand Steric Effects of alpha-Diimine Nickel(II) and Palladium(II) Complexes in the Suzuki-Miyaura Cross-Coupling Reaction	The first nickel-catalyzed N-arylation of amides with (hetero) aryl (pseudo) halides is reported, enabled by use of the air-stable pre-catalyst (PAd-DalPhos) Ni(o-tolyl)Cl(C1). A range of structurally diverse primary amides and lactams were cross-coupled successfully with activated (hetero) aryl chloride, bromide, triflate, tosylate, mesylate, and sulfamate electrophiles.	ACS Omega	128	Stefan, MC	FALSE	FALSE	FALSE	FALSE
758	10.1039/d0sc00445f	doi.org/10.1039/d0sc00445f	Machine learning dihydrogen activation in the chemical space surrounding Vaska's complex	The first nucleophilic ring-opening reactions of cydopropanated 7-azabenzonorbornadienes have been achieved using organocuprates. Tricyclic or tetracyclic gamma-lactams were obtained as the sole product in good yields of up to 98% when alkoxycarbonyl groups occupied the N-substituent position. Successful conversions to lactams were observed for primary, secondary, tertiary, and aromatic nucleophiles, as well as for a variety of substrates functionalized on the benzene ring. A possible mechanism for these transformations is discussed.	Chem. Sci.	128	Aspuru-Guzik, A	FALSE	FALSE	FALSE	FALSE
759	10.1002/anie.201915386	doi.org/10.1002/anie.201915386	Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3-Diynes	The utility of N-heterocyclic carbene as a Bronsted base catalyst for the synthesis of functionalised unsymmetrical triarylmethanes from 2-naphthol and para-quinone methides is described. This protocol allows the installation of naphthyl substituents on p-quinone methides through 1,6-conjugate addition to deliver the unsymmetrical triarylmethanes in good to excellent yields. Mild reaction conditions and 100% atom economy make this method synthetically advantageous over the other hitherto known methods.	Angew. Chem.-Int. Edit.	128	Beller, M	FALSE	FALSE	FALSE	FALSE
760	10.1002/ijch.201900065	doi.org/10.1002/ijch.201900065	Kinetics and Mechanism of the Platinum(II)-Catalyzed Hydroarylation of Vinyl Arenes with 1,2-Dimethylindole		Isr. J. Chem.	128	Widenhoefer, RA	FALSE	FALSE	FALSE	FALSE
761	10.1055/s-0037-1610273	doi.org/10.1055/s-0037-1610273	The Directed ortho Metalation (D o M)-Cross-Coupling Connection: Synthesis of Polyfunctional Biaryls		Synthesis	128	Snieckus, V	FALSE	FALSE	FALSE	FALSE
762	10.1021/acs.organomet.8b00244	doi.org/10.1021/acs.organomet.8b00244	Reactions of the Ni(0) Compound Ni(PPh3)(4) with Unactivated Alkyl Halides: Oxidative Addition Reactions Involving Radical Processes and Nickel(I) Intermediates		Organometallics	128	Baird, MC	FALSE	FALSE	FALSE	FALSE
763	10.1002/adsc.201701596	doi.org/10.1002/adsc.201701596	Aqueous alpha-Arylation of Mono- and Diarylethanone Enolates at Low Catalyst Loading		Adv. Synth. Catal.	128	SanMartin, R; Dominguez, E	FALSE	FALSE	FALSE	FALSE
764	10.1039/c4qo00039k	doi.org/10.1039/c4qo00039k	Efficient synthesis of a library of heparin tri- and tetrasaccharides relevant to the substrate of heparanase		Org. Chem. Front.	128	Xu, P	FALSE	FALSE	FALSE	FALSE
765	10.1021/ja312464b	doi.org/10.1021/ja312464b	Cleavage of Ether, Ester, and Tosylate C(sp(3))-O Bonds by an Iridium Complex, Initiated by Oxidative Addition of C-H Bonds. Experimental and Computational Studies		J. Am. Chem. Soc.	128	Krogh-Jespersen, K	FALSE	FALSE	FALSE	FALSE
766	10.2174/138527207782418744	doi.org/10.2174/138527207782418744	Transmetallation reactions involving group 10 metals		Curr. Org. Chem.	128	Wendt, OF	FALSE	FALSE	FALSE	FALSE
767	10.1021/ja073714j	doi.org/10.1021/ja073714j	Expanding the structural diversity of self-assembling dendrons and supramolecular dendrimers via complex building blocks		J. Am. Chem. Soc.	128	Percec, V	FALSE	FALSE	FALSE	FALSE
768	10.1016/S0040-4020(01)87277-X	doi.org/10.1016/S0040-4020(01)87277-X	NEW GENERAL SYNTHETIC METHODS INVOLVING PI-ALLYLPALLADIUM COMPLEXES AS INTERMEDIATES AND NEUTRAL REACTION CONDITIONS		Tetrahedron	128	TSUJI, J	FALSE	FALSE	FALSE	FALSE
769	10.1002/tcr.202100204	doi.org/10.1002/tcr.202100204	Well-Defined NHC-Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross-Coupling Reactions		Chem. Rec.	128	Matsubara, K	FALSE	FALSE	FALSE	FALSE
770	10.1002/chem.202101484	doi.org/10.1002/chem.202101484	[Ni(NHC)(2)] as a Scaffold for Structurally Characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] Complexes		Chem.-Eur. J.	128	Whittlesey, MK	FALSE	FALSE	FALSE	FALSE
771	10.1002/anie.202103686	doi.org/10.1002/anie.202103686	Transition Metal Catalyst-Free, Base-Promoted 1,2-Additions of Polyfluorophenylboronates to Aldehydes and Ketones		Angew. Chem.-Int. Edit.	128	Radius, U; Marder, TB	FALSE	FALSE	FALSE	FALSE
772	10.1002/adsc.201600568	doi.org/10.1002/adsc.201600568	Catalytic C-2 Allylation of Indoles by Electronic Modulation of the Indole Ring and its Application to the Synthesis of Functionalized Carbazoles		Adv. Synth. Catal.	128	Joo, JM	FALSE	TRUE	FALSE	FALSE
773	10.1021/acscatal.0c03888	doi.org/10.1021/acscatal.0c03888	Switching from Biaryl Formation to Amidation with Convoluted Polymeric Nickel Catalysis	The preparation of a chiral derivative of [B(C6F5)(4)](-) in which the fluorine atom in the para position of each of the C6F5 groups is replaced by a 1,1'-binaphthalen-2-yl group is described. The new counteranion was isolated as its lithium, sodium, and trityl salts. The chiral trityl salt was then used as a catalyst in selected counteranion-directed Diels-Alder reactions and a Mukaiyama aldol addition, but no asymmetric induction was achieved. Application of the chiral trityl salt to the generation of silicon cations by silicon-to-carbon hydride transfer from hydrosilanes failed, presumably as a result of the incompatibility of the relatively electron-rich naphthyl groups in the borate and the cationic silicon electrophiles.	ACS Catal.	127	Yamada, YMA	FALSE	FALSE	FALSE	FALSE
774	10.1002/cssc.201901951	doi.org/10.1002/cssc.201901951	Transition Metal-Catalyzed Directing-Group-Assisted C-H Activation of Phenols		ChemSusChem	127	Luo, JF	FALSE	FALSE	FALSE	FALSE
775	10.1021/acs.organomet.8b00539	doi.org/10.1021/acs.organomet.8b00539	Phosphino-Triazole Ligands for Palladium-Catalyzed Cross-Coupling		Organometallics	127	Fossey, JS	FALSE	FALSE	FALSE	FALSE
776	10.1021/acs.joc.8b00728	doi.org/10.1021/acs.joc.8b00728	Evolution of a Strategy for the Enantioselective Total Synthesis of (+)-Psiguadial B		J. Org. Chem.	127	Reisman, SE	FALSE	FALSE	FALSE	FALSE
777	10.1055/s-0035-1560324	doi.org/10.1055/s-0035-1560324	Simple Solubilization of the Traditional 2,2 ':6 ',2 ''-Terpyridine Ligand in Organic Solvents by Substitution with 4,4 ''-Di-tert-butyl Groups		Synthesis	127	Hanan, GS	FALSE	FALSE	FALSE	FALSE
778	10.1021/jo502561m	doi.org/10.1021/jo502561m	Highly Enantioselective (-)-Sparteine-Mediated Lateral Metalation-Functionalization of Remote Silyl Protected ortho-Ethyl N,N-Dialkyl Aryl O-Carbamates		J. Org. Chem.	127	Snieckus, V	FALSE	FALSE	FALSE	FALSE
779	10.1021/jacs.5b00538	doi.org/10.1021/jacs.5b00538	Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed		J. Am. Chem. Soc.	127	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
780	10.1021/jo501886w	doi.org/10.1021/jo501886w	Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, Uphen)M(CH3)](+)		J. Org. Chem.	127	Ariafard, A	FALSE	FALSE	FALSE	FALSE
781	10.1002/anie.201303376	doi.org/10.1002/anie.201303376	Selective C-sp2-C-sp Bond Cleavage: The Nitrogenation of Alkynes to Amides		Angew. Chem.-Int. Edit.	127	Jiao, N	FALSE	FALSE	FALSE	FALSE
782	10.1021/ja309176h	doi.org/10.1021/ja309176h	Nickel-Catalyzed Reductive Conjugate Addition to Enones via Allylnickel Intermediates		J. Am. Chem. Soc.	127	Weix, DJ	FALSE	FALSE	FALSE	FALSE
783	10.1021/jo202012n	doi.org/10.1021/jo202012n	Synthesis of Benzo-fused Heterocycles by Intramolecular alpha-Arylation of Ketone Enolate Anions		J. Org. Chem.	127	Rossi, RA	FALSE	FALSE	FALSE	FALSE
784	10.1021/ja00182a018	doi.org/10.1021/ja00182a018	LIGAND DEPENDENCE OF MOLYBDENUM-CATALYZED ALKYLATIONS - MOLYBDENUM ISONITRILE COMPLEXES AS A NEW CLASS OF HIGHLY REACTIVE ALKYLATION CATALYSTS		J. Am. Chem. Soc.	127	TROST, BM	FALSE	FALSE	FALSE	FALSE
785	10.1002/anie.202114731	doi.org/10.1002/anie.202114731	From Esters to Ketones via a Photoredox-Assisted Reductive Acyl Cross-Coupling Strategy		Angew. Chem.-Int. Edit.	127	Yuan, WM	TRUE	FALSE	FALSE	FALSE
786	10.1039/d0py01507e	doi.org/10.1039/d0py01507e	Pairing Suzuki-Miyaura cross-coupling and catalyst transfer polymerization		Polym. Chem.	127	Noonan, KJT	FALSE	FALSE	FALSE	FALSE
787	10.1002/asia.202000763	doi.org/10.1002/asia.202000763	B(C6F5)(3)-Catalyzed Tandem Friedel-Crafts and C-H/C-O Coupling Reactions of Dialkylanilines	The prenyl group is an important component in bioactive compounds. Herein, we report the assembly of prenylated heteroarenes through a cascade Minisci reaction and acid-promoted dehydration sequence. The use of potassium (3-hydroxy-3-methylbut-1-yl)trifluoroborate as a new coupling reagent allows the direct introduction of prenyl and 3-hydroxy-3-methylbutyl groups to a wide variety of electron-deficient heteroarenes. Synthetic application is also demonstrated.	Chem.-Asian J.	126	Li, SH; Wu, YT; Hu, XB	FALSE	FALSE	FALSE	FALSE
788	10.1021/acs.joc.0c00788	doi.org/10.1021/acs.joc.0c00788	Metal-Free C-C Coupling of an Allenyl Sulfone with Picolyl Amides to Access Vinyl Sulfones via Pyridine-Initiated In Situ Generation of Sulfinate Anion	An efficient amidation method between readily available 1,1-dicyanoalkanes and either chiral or nonchiral amines was realized simply with molecular oxygen and a carbonate base. This oxidative protocol can be applied to both sterically and electronically challenging substrates in a highly chemoselective, practical, and rapid manner. The use of cyclopropyl and thioether substrates support the radical formation of alpha-peroxy malononitrile species, which can cyclize to dioxiranes that can monooxygenate malononitrile alpha-carbanions to afford activated acyl cyanides capable of reacting with amine nucleophiles.	J. Org. Chem.	126	Liu, P; Brummond, KM	FALSE	FALSE	FALSE	FALSE
789	10.1039/c9ob00699k	doi.org/10.1039/c9ob00699k	Clickable coupling of carboxylic acids and amines at room temperature mediated by SO2F2: a significant breakthrough for the construction of amides and peptide linkages		Org. Biomol. Chem.	126	Qin, HL	FALSE	FALSE	FALSE	FALSE
790	10.1021/jacs.8b02134	doi.org/10.1021/jacs.8b02134	Multicatalytic Stereoselective Synthesis of Highly Substituted Alkenes by Sequential Isomerization/Cross-Coupling Reactions		J. Am. Chem. Soc.	126	Mazet, C	FALSE	FALSE	FALSE	FALSE
791	10.1246/cl.150024	doi.org/10.1246/cl.150024	Nickel Catalysts/N,N '-Bidentate Directing Groups: An Excellent Partnership in Directed C-H Activation Reactions		Chem. Lett.	126	Chatani, N	FALSE	FALSE	FALSE	FALSE
792	10.1002/anie.201310272	doi.org/10.1002/anie.201310272	alpha-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed C-H Activation for the Synthesis of N-Heterocycles		Angew. Chem.-Int. Edit.	126	Glorius, F	FALSE	FALSE	FALSE	FALSE
793	10.1002/chem.201301869	doi.org/10.1002/chem.201301869	A Convenient Alumination of Functionalized Aromatics by Using the Frustrated Lewis Pair Et3Al and TMPMgCl center dot LiCl		Chem.-Eur. J.	126	Knochel, P	FALSE	FALSE	FALSE	FALSE
794	10.1016/j.jfluchem.2012.06.025	doi.org/10.1016/j.jfluchem.2012.06.025	Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions		J. Fluor. Chem.	126	Braun, T	FALSE	FALSE	FALSE	FALSE
795	10.1016/j.tet.2011.10.072	doi.org/10.1016/j.tet.2011.10.072	Insertion of arynes into the carbon-oxygen double bond of amides and its application into the sequential reactions		Tetrahedron	126	Miyabe, H	FALSE	FALSE	FALSE	FALSE
796	10.1021/op200090k	doi.org/10.1021/op200090k	Scale-Up of Microwave-Assisted Reactions in a Multimode Bench-Top Reactor		Org. Process Res. Dev.	126	Kappe, CO	FALSE	FALSE	FALSE	FALSE
797	10.1021/ja072446m	doi.org/10.1021/ja072446m	Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: Efficient synthesis of heterocycles via cascade migration/cycloisomerization approach		J. Am. Chem. Soc.	126	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
798	10.1002/chem.200600178	doi.org/10.1002/chem.200600178	Exploring and expanding the structural diversity of self-assembling dendrons through combinations of AB, constitutional isomeric AB(2), and AB(3) biphenyl-4-methyl ether building blocks		Chem.-Eur. J.	126	Percec, V	FALSE	FALSE	FALSE	FALSE
799	10.1021/ma970323o	doi.org/10.1021/ma970323o	Palladium-mediated soluble precursor route into poly(arylethynylenes) and poly(arylethylenes)		Macromolecules	126		FALSE	FALSE	FALSE	FALSE
800	10.1021/acs.inorgchem.1c02925	doi.org/10.1021/acs.inorgchem.1c02925	Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study		Inorg. Chem.	126	Gershoni-Poranne, R; de Ruiter, G	FALSE	FALSE	FALSE	FALSE
801	10.1021/acscatal.1c04235	doi.org/10.1021/acscatal.1c04235	Nickel-Catalyzed Domino Cross-Electrophile Coupling Dicarbofunctionalization Reaction To Afford Vinylcyclopropanes		ACS Catal.	126	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
802	10.1002/anie.202103269	doi.org/10.1002/anie.202103269	Palladium-Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand-Assisted Halide Exchange		Angew. Chem.-Int. Edit.	126	Morandi, B	FALSE	FALSE	FALSE	FALSE
803	10.1002/anie.202102481	doi.org/10.1002/anie.202102481	Diversity-Oriented Synthesis of Aliphatic Fluorides via Reductive C(sp(3))-C(sp(3)) Cross-Coupling Fluoroalkylation		Angew. Chem.-Int. Edit.	126	Wang, XS	FALSE	FALSE	FALSE	FALSE
804	10.1039/d1gc00720c	doi.org/10.1039/d1gc00720c	A practical and sustainable protocol for direct amidation of unactivated esters under transition-metal-free and solvent-free conditions		Green Chem.	126	Cheng, H	FALSE	FALSE	FALSE	FALSE
805	10.1002/tcr.201500242	doi.org/10.1002/tcr.201500242	Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate		Chem. Rec.	126	Yang, SD	FALSE	FALSE	FALSE	FALSE
806	10.3390/polym13060987	doi.org/10.3390/polym13060987	Thermoresponsive Poly(N,N-diethylacrylamide-co-glycidyl methacrylate) Copolymers and Its Catalytically Active alpha-Chymotrypsin Bioconjugate with Enhanced Enzyme Stability	The increasing climate changes and global warming are leading to colossal agricultural problems such as abatement of food production and quality. As stomatal development is considered to play a key role in crop plant productivity and water-use efficiency, studying stomatal development is useful for understanding the productivity of plant systems for both natural and agricultural systems. Herein, we report the first-in-class synthetic small molecules enhancing the number of stomata in Arabidopsis thaliana that have been discovered by screening of the chemical library and further optimized by the Pd-catalyzed C-H arylation reaction. The present study shows not only huge potential of small molecules to control the cellular and developmental processes of stomata without using genetically modified plants, but also the power of C-H functionalization chemistry to rapidly identify the optimized compounds.	Polymers	125	Kasza, G; Ivan, B	FALSE	FALSE	FALSE	FALSE
807	10.1002/ejic.202000782	doi.org/10.1002/ejic.202000782	Iron and Silver Complexes of 4-(Imidazol-1-yl)-2,6-di(pyrazol-1-yl)-pyridine (L), Including a [Fe-3(mu-F)(2)F6L8](+)Assembly	Among the fundamental transformations that comprise a catalytic cycle for cross coupling, transmetalation from the nucleophile to the metal catalyst is perhaps the least understood. Optimizing this elementary step has enabled the first example of a cobalt-catalyzed Suzuki-Miyaura cross coupling between aryl triflate electrophiles and heteroaryl boron nucleophiles. Key to this discovery was the preparation and characterization of a new class of tetrahedral, high-spin bis(phosphino) pyridine cobalt(I) alkoxide and aryloxide complexes, ((PNP)-P-iPr) CoOR, and optimizing their reactivity with 2-benzofuranylBPin (Pin = pinacolate). Cobalt compounds with small alkoxide substituents such as R = methyl and ethyl underwent swift transmetalation at 23 degrees C but also proved kinetically unstable toward beta-H elimination. Secondary alkoxides such as R = Pr-i or CH(Ph) Me balanced stability and reactivity. Isolation and structural characterization of the product following transmetalation, ((PNP)-P-iPr)Co(2-benzofuranyl), established a planar, diamagnetic cobalt(I) complex, demonstrating the high-and low-spin states of cobalt(I) rapidly interconvert during this reaction. The insights from the studies in this elementary step guided selection of appropriate reaction conditions to enable the first examples of cobalt-catalyzed C-C bond formation between neutral boron nucleophiles and aryl triflate electrophiles, and a model for the successful transmetalation reactivity is proposed.	Eur. J. Inorg. Chem.	125	Halcrow, MA	FALSE	FALSE	FALSE	FALSE
808	10.1002/aoc.5662	doi.org/10.1002/aoc.5662	Air-Stable Fe3O4@SiO2-EDTA-Ni(0) as an Efficient Recyclable Magnetic Nanocatalyst for Effective Suzuki-Miyaura and Heck Cross-Coupling via Aryl Sulfamates and Carbamates	Radical involved transformations are now considered as extremely important processes in modern organic synthetic chemistry. According to the demand by atom-economic and sustainable chemistry, direct C(sp(3))-H functionalization through radical oxidative coupling represents an appealing strategy for C-C bond formations. However, the selectivity control of reactive radical intermediates is still a great challenge in these transformations. Here we show a selective radical oxidative C(sp(3))-H/C(sp)-H cross-coupling of unactivated alkanes with terminal alkynes by using a combined Cu/Ni/Ag catalytic system. It provides a new way to access substituted alkynes from readily available materials. Preliminary mechanistic studies suggest that this reaction proceeds through a radical process and the C(sp(3))-H bond cleavage is the rate-limiting step. This study may have significant implications for controlling selective C-C bond formation of reactive radical intermediates by using multimetallic catalytic systems.	Appl. Organomet. Chem.	125	Inaloo, ID	FALSE	FALSE	FALSE	FALSE
809	10.1016/j.molstruc.2019.127668	doi.org/10.1016/j.molstruc.2019.127668	Palladium-carbene catalyzed direct arylation of five-membered heteroaromatics	A facile and modular synthesis of triarylmethanes was achieved in good yield via a two-step sequence in which the final step is the copper(II)-catalyzed arylation of diarylmethanols with arylboronic acids. By using this protocol a variety of symmetrical and unsymmetrical triarylmethanes were synthesized. As an application of the newly developed methodology, we demonstrate a high-yielding synthesis of the triarylmethane intermediate towards an anti-breast-cancer drug candidate.	J. Mol. Struct.	125	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
810	10.1055/s-0039-1690769	doi.org/10.1055/s-0039-1690769	Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism		Synthesis	125	Topczewski, JJ	FALSE	FALSE	FALSE	FALSE
811	10.5059/yukigoseikyokaishi.77.883	doi.org/10.5059/yukigoseikyokaishi.77.883	Defluoroborylation Reactions of Fluoroarenes		J. Synth. Org. Chem. Jpn.	125	Niwa, T	FALSE	FALSE	FALSE	FALSE
812	10.1039/c7ob02007d	doi.org/10.1039/c7ob02007d	B(C6F5)(3) catalysed reduction of para-quinone methides and fuchsones to access unsymmetrical diaryl- and triarylmethanes: elaboration to beclobrate		Org. Biomol. Chem.	125	Anand, RV	FALSE	FALSE	FALSE	FALSE
813	10.1002/asia.201301500	doi.org/10.1002/asia.201301500	Transition-Metal-Catalyzed C-S Bond Coupling Reaction		Chem.-Asian J.	125	Lee, CF	FALSE	FALSE	FALSE	FALSE
814	10.1080/00304948.2014.922376	doi.org/10.1080/00304948.2014.922376	Advances and New Variations of the Hirao Reaction		Org. Prep. Proced. Int.	125	Keglevich, G	FALSE	FALSE	FALSE	FALSE
815	10.1039/c2cy20505j	doi.org/10.1039/c2cy20505j	Direct C-H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles		Catal. Sci. Technol.	125	Kozhushkov, SI	FALSE	FALSE	FALSE	FALSE
816	10.2174/138527212804546705	doi.org/10.2174/138527212804546705	Synthetic Methods for the Hydrodehalogenation of Halogenated Heterocycles		Curr. Org. Chem.	125	Chelucci, G	FALSE	FALSE	FALSE	FALSE
817	10.1002/asia.200900744	doi.org/10.1002/asia.200900744	Heck-Type Reactions of Imine Derivatives: A DFT Study		Chem.-Asian J.	125	Liu, L	FALSE	FALSE	FALSE	FALSE
818	10.1021/jo070912k	doi.org/10.1021/jo070912k	Investigations on the Suzuki-Miyaura and Negishi couplings with alkenyl phosphates: Application to the synthesis of 1,1-disubstituted alkenes		J. Org. Chem.	125	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
819	10.1002/ejic.200300162	doi.org/10.1002/ejic.200300162	Palladium-catalyzed cyanation of aryl halides: Recent developments and perspectives		Eur. J. Inorg. Chem.	125	Beller, M	FALSE	FALSE	FALSE	FALSE
820	10.1055/s-2002-35576	doi.org/10.1055/s-2002-35576	Iridium complex-catalyzed highly selective organic synthesis		Synlett	125	Takeuchi, R	FALSE	FALSE	FALSE	FALSE
821	10.1016/S0040-4020(99)00965-5	doi.org/10.1016/S0040-4020(99)00965-5	Nickel catalyzed reactions of nucleophiles with unactivated and partially activated olefins and acetylenes		Tetrahedron	125	Houpis, IN	FALSE	FALSE	FALSE	FALSE
822	10.1021/acscatal.1c05801	doi.org/10.1021/acscatal.1c05801	Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Alkenes		ACS Catal.	125	Montgomery, J	FALSE	FALSE	FALSE	FALSE
823	10.1002/anie.202106412	doi.org/10.1002/anie.202106412	Direct Amidation of Esters by Ball Milling**		Angew. Chem.-Int. Edit.	125	Browne, DL	FALSE	FALSE	FALSE	FALSE
824	10.1002/anie.202104319	doi.org/10.1002/anie.202104319	Counterion Control of t-BuO-Mediated Single Electron Transfer to Nitrostilbenes to Construct N-Hydroxyindoles or Oxindoles		Angew. Chem.-Int. Edit.	125	Driver, TG	FALSE	TRUE	FALSE	FALSE
825	10.1002/chem.201603436	doi.org/10.1002/chem.201603436	Cross-Coupling of Organolithium with Ethers or Aryl Ammonium Salts by C-O or C-N Bond Cleavage		Chem.-Eur. J.	125	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
826	10.3390/molecules26061615	doi.org/10.3390/molecules26061615	Rate Dependence on Inductive and Resonance Effects for the Organocatalyzed Enantioselective Conjugate Addition of Alkenyl and Alkynyl Boronic Acids to beta-Indolyl Enones and beta-Pyrrolyl Enones	Here, we report a ligand- and reductant-free nickel-catalyzed N-vinylation of heteroaromatic amines using biorenewable p-cymene as a solvent. This unprecedented cross-coupling strategy has high functional group tolerance (halides, alkoxy, cyano, chiral motif, etc.) and proceeded via C-H bond activation.	Molecules	124	May, JA	FALSE	FALSE	FALSE	FALSE
827	10.1039/d0ob01458c	doi.org/10.1039/d0ob01458c	Aldehydes: magnificent acyl equivalents for direct acylation	A palladium-catalyzed decarbonylative alkynylation reaction of aromatic esters with terminal alkynes is reported. This reaction allows for halogen-free Sonogashira coupling, resulting in various aryl- and heteroarylalkynes. The utility of the reaction was demonstrated by orthogonal coupling reaction.	Org. Biomol. Chem.	124	Kumar, P	FALSE	FALSE	FALSE	FALSE
828	10.1021/acsomega.0c04181	doi.org/10.1021/acsomega.0c04181	Ni-Catalyzed Reductive and Merged Photocatalytic Cross-Coupling Reactions toward sp(3)/sp(2)-Functionalized Isoquinolones: Creating Diversity at C-6 and C-7 to Address Bioactive Analogues	We describe here a tandem catalytic route to prepare imidazoles in a single operation from aryl iodides, imines and CO. The reaction involves a catalytic carbonylation of aryl halides with imines to form 1,3-dipoles, which undergo spontaneous 1,3-dipolar cycloaddition. Overall, this offers an alternative to coupling reactions to construct the (hetero) aryl-imidazole motif, where variation of the building blocks can allow the synthesis of broad families of imidazoles with independent control of all substituents.	ACS Omega	124	Hanessian, S	TRUE	FALSE	FALSE	FALSE
829	10.1002/ejoc.202000416	doi.org/10.1002/ejoc.202000416	Ruthenium-Catalyzed Dehydrogenation of Alcohols with Carbodiimide via a Hydrogen Transfer Mechanism	A simple and efficient method for radical hydro-deiodination is reported. The novel approach uses electron catalysis. In situ generated Na-alcoholates are introduced as radical chain reducing reagents and reactions work with O-2 as cheap initiator. Hydrodeiodination works on aryl, alkenyl, alkynyl iodides and a tert-alkyl iodide also gets reduced applying the method. Albeit less general, the method is also applicable to the reduction of aryl bromides. The novel reagent is successfully used to conduct typical reductive radical cyclization reactions and mechanistic studies are reported.	Eur. J. Org. Chem.	124	Sueki, S; Anada, M	FALSE	FALSE	FALSE	FALSE
830	10.1002/anie.202000859	doi.org/10.1002/anie.202000859	Asymmetric Reductive and Alkynylative Heck Bicyclization of Enynes to Access Conformationally Restricted Aza[3.1.0]bicycles	A ligand- and base-free, Pd-catalyzed protocol to access a wide range of symmetrical and unsymmetrical biaryls from stable diaryliodonium salts was developed. The reaction involved the use of an effective and recyclable Pd/polyethylene glycol-400 catalyst system to harness the aryl moieties of two diaryliodonium salts; the ensuing biaryls may be utilized to synthesize an array of useful compounds, including 5-aryluracils, carbazoles, chromenones, fluorenones, phenathridines, and boscalid analogues.	Angew. Chem.-Int. Edit.	124	Zhou, JS	FALSE	FALSE	FALSE	FALSE
831	10.1134/S1070428019070017	doi.org/10.1134/S1070428019070017	Metal Complex Catalysis in the Synthesis of Ethers		Russ. J. Organ. Chem.	124	Khusnutdinov, RI	FALSE	FALSE	FALSE	FALSE
832	10.1002/ejoc.201801596	doi.org/10.1002/ejoc.201801596	S(N)2 Reaction of Diarylmethyl Anions at Secondary Alkyl and Cycloalkyl Carbons		Eur. J. Org. Chem.	124	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
833	10.6023/cjoc201507008	doi.org/10.6023/cjoc201507008	Advance on Applications of Microwave Technique in Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction		Chin. J. Org. Chem.	124	Li, QH	FALSE	FALSE	FALSE	FALSE
834	10.1002/chem.201200257	doi.org/10.1002/chem.201200257	Total Synthesis of Branimycin: An Evolutionary Approach		Chem.-Eur. J.	124	Mulzer, J	FALSE	FALSE	FALSE	FALSE
835	10.1021/om900460u	doi.org/10.1021/om900460u	Synthesis, Structures, and Characterizations of [ArTi(O-i-Pr)(3)](2) and Efficient Room-Temperature Aryl-Aryl Coupling of Aryl Bromides with [ArTi(O-i-Pr)(3)](2) Catalyzed by the Economic Pd(OAC)(2)/PCy3 System		Organometallics	124	Gau, HM	FALSE	FALSE	FALSE	FALSE
836	10.1021/ja078298h	doi.org/10.1021/ja078298h	Mechanisms of catalyst poisoning in palladium-catalyzed cyanation of haloarenes. Remarkably facile C-N bond activation in the [(Ph3P)(4)Pd]/[Bu4N](+) CN- system		J. Am. Chem. Soc.	124	Grushin, VV	FALSE	FALSE	FALSE	FALSE
837	10.1016/j.tet.2021.132513	doi.org/10.1016/j.tet.2021.132513	Recent advances in the generation and functionalization of C(alkenyl)-Pd species for synthesis of polysubstituted alkenes		Tetrahedron	124	Engle, KM	FALSE	FALSE	FALSE	FALSE
838	10.1021/acs.oprd.1c00241	doi.org/10.1021/acs.oprd.1c00241	Recent Advances in Nonprecious Metal Catalysis		Org. Process Res. Dev.	124	Hansen, EC	FALSE	FALSE	FALSE	FALSE
839	10.1002/chem.202101256	doi.org/10.1002/chem.202101256	Snapshot Trapping of Multiple Transient Azolyllithiums in Batch		Chem.-Eur. J.	124	Okano, K	FALSE	FALSE	FALSE	FALSE
840	10.1039/d0qo01630f	doi.org/10.1039/d0qo01630f	Catalytic asymmetric synthesis of monofluoroalkenes and gem-difluoroalkenes: advances and perspectives		Org. Chem. Front.	124	Cao, ZY; Xu, Y	FALSE	FALSE	FALSE	FALSE
841	10.1007/s11172-017-1920-7	doi.org/10.1007/s11172-017-1920-7	Nickel and palladium N-heterocyclic carbene complexes. Synthesis and application in cross-coupling reactions		Russ. Chem. Bull.	124	Yakhvarov, DG	FALSE	FALSE	FALSE	FALSE
842	10.1246/bcsj.20160391	doi.org/10.1246/bcsj.20160391	C-H Borylation by Platinum Catalysis		Bull. Chem. Soc. Jpn.	124	Tobisu, M; Chatani, N	FALSE	FALSE	FALSE	FALSE
843	10.1055/s-0036-1588371	doi.org/10.1055/s-0036-1588371	Recent Developments in the Direct Synthesis of Unprotected Primary Amines		Synthesis	124	Morandi, B	FALSE	FALSE	FALSE	FALSE
844	10.1016/j.isci.2020.100985	doi.org/10.1016/j.isci.2020.100985	Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage	The direct methylation of ortho C-H bonds in aromatic amides with dicumyl peroxide (DCP) using a nickel complex as the catalyst is reported. The reaction shows a high functional group tolerance and is inhibited by radical scavengers. In reactions of meta-substituted aromatic amides, the reaction proceeds in a highly selective manner at the less hindered C-H bonds.	iScience	123	Hong, X; Lu, Z	FALSE	FALSE	FALSE	FALSE
845	10.3987/REV-19-919	doi.org/10.3987/REV-19-919	ALKYL PYRIDINESULFONATES AND ALLYLIC PYRIDINECARboxYLATES, NEW BOOSTERS FOR THE SUBSTITUTION AT SECONDARY CARBONS	Schiff base metal complexes are well-known to intercalate DNA. The La(III) complexes have been synthesized such that they hinder with the role of the topoisomerases, which control the topology of DNA during the cell-division cycle. Although several promising chemotherapeutics have been developed, on the basis of Schiff base metal complex DNA intercalating system they did not proceed past clinical trials due to their dose-limiting toxicity. Herein, we discuss an alternative compound, the La(III) complex, [La(L-1)(2)Cl-3]center dot 7H(2)O based on a Schiff base ligand 2,3-dihydro-1H-indolo-[2,3-M-phenazin-4(5H)-ylidene)benzothiazole-2-amine (L-1), and report in vitro cell studies. Results of antitumor activity using cell viability assay, reactive oxygen species (ROS) generation and nuclear condensation in PC-3 (Human, prostate carcinoma) cells show that the metal complex is more potent than ligand. La(III) complexes have been synthesized by reaction of lanthanum(III) salt in 1:2 M ratio with ligands L-1 and 3-(ethoxymethylene)-2,3-dihydro-1H-indolo[2,3-b]-phenazin-4(5H)-ylidene)benzathiazole-2-amine (L-2) in methanol. The ligands and their La(III) complexes were characterized by molar conductance, magnetic susceptibility, elemental analyses, FT-IR, UV-Vis, H-1/C-13 NMR, thermogravimetric, XRD, and SEM analysis. (C) 2015 Elsevier BY. All rights reserved.	Heterocycles	123	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
846	10.2174/1570179417666200212113412	doi.org/10.2174/1570179417666200212113412	Review of the Syntheses and Activities of Some Sulfur-Containing Drugs		Curr. Org. Synth.	123	Domingues, NLD	FALSE	FALSE	FALSE	FALSE
847	10.1002/chem.201904095	doi.org/10.1002/chem.201904095	Synthesis of 2-Arylisoindoline Derivatives Catalyzed by Reusable 1,2,4-Triazole Iridium on Mesoporous Silica through a Cascade Borrowing Hydrogen Strategy		Chem.-Eur. J.	123	Wang, DW	FALSE	FALSE	FALSE	FALSE
848	10.3390/molecules23102417	doi.org/10.3390/molecules23102417	Recent Advances in Synthesis of 4-Arylcoumarins		Molecules	123	Yun, H	FALSE	FALSE	FALSE	FALSE
849	10.1002/anie.201505926	doi.org/10.1002/anie.201505926	Copper-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes		Angew. Chem.-Int. Edit.	123	Liao, J	FALSE	FALSE	FALSE	FALSE
850	10.1002/ejoc.201403125	doi.org/10.1002/ejoc.201403125	Direct Arylation of Benzo[b]furan and Other Benzo-Fused Heterocycles		Eur. J. Org. Chem.	123	Schnurch, M	FALSE	FALSE	FALSE	FALSE
851	10.1002/adsc.201200412	doi.org/10.1002/adsc.201200412	Dual Heterogeneous Catalysis for a Regioselective Three-Component Synthesis of Bi- and Tri(hetero)arylpyridines		Adv. Synth. Catal.	123	Constantieux, T	FALSE	FALSE	FALSE	FALSE
852	10.2174/157017905774322631	doi.org/10.2174/157017905774322631	Ten years of research on NOBIN chemistry		Curr. Org. Synth.	123	Ding, KL	FALSE	FALSE	FALSE	FALSE
853	10.1039/oc9777400175	doi.org/10.1039/oc9777400175	ALIPHATIC-COMPOUNDS .1. HYDROCARBONS			123	TAYLOR, DR	FALSE	FALSE	FALSE	FALSE
854	10.1016/j.ccr.2016.09.011	doi.org/10.1016/j.ccr.2016.09.011	Catalytic synthesis of chiral organoheteroatom compounds of silicon, phosphorus, and sulfur via asymmetric transition metal-catalyzed C-H functionalization		Coord. Chem. Rev.	123	Cui, YM; Xu, LW	FALSE	FALSE	FALSE	FALSE
855	10.1002/chem.201603481	doi.org/10.1002/chem.201603481	Palladium-Catalyzed Regiodivergent Substitution of Propargylic Carbonates		Chem.-Eur. J.	123	Tunge, JA	FALSE	FALSE	FALSE	FALSE
856	10.1007/s41061-016-0043-1	doi.org/10.1007/s41061-016-0043-1	Nickel-Catalyzed Cross-Coupling Reactions of Unreactive Phenolic Electrophiles via C-O Bond Activation		Top. Curr. Chem.	123	Tobisu, M	FALSE	TRUE	FALSE	FALSE
857	10.6023/cjoc202002035	doi.org/10.6023/cjoc202002035	Recent Advances in Ni-Catalyzed C-C Bond Activation Reactions	Olefins and carboxylic acids are among the most important feedstock compounds. They are commonly found in natural products and drug molecules. We report a new reaction of nickel-catalyzed decarboxylative olefin hydroalkylation, which provides a novel practical strategy for the construction of C(sp(3))-C(sp(3)) bonds. This reaction can tolerate a variety of synthetically relevant functional groups and shows good chemo-and regioselectivity. It enables cross-coupling of complex organic molecules containing olefin groups and carboxylic acid groups in a convergent fashion.	Chin. J. Org. Chem.	122	Bai, DC	FALSE	FALSE	FALSE	FALSE
858	10.1021/acs.orglett.0c01365	doi.org/10.1021/acs.orglett.0c01365	Directed Cobalt-Catalyzed anti-Markovnikov Hydroalkylation of Unactivated Alkenes Enabled by Co-H Catalysis	A series of mono- and bimetallic Ni alkyl complexes of a beta-oxo-delta-diimine (BODDI) ligand are reported. The monometallic-complexes have a second binding-pocket, of which the free arm can exist as either an enamine (e.g., 8, BODEI, beta-oxo-delta-enamineiminato) or imine (e.g., 3, BODII beta-oxo-delta-imineiminato) tautomer. The identity of the tautomer in. the secondary Ni coordination sphere hasa.significant effect on ethylene. polyMerizaimilbehavior: the enamine tautomer, which hydrogen bonds to-die central 0: atom and is in conjugation with :the N,O chelate, is significantly more electron rich and yields a much-lower molecular.weight polymer than the imine tautomer, which rotates away from Ni to a distal position and has little effect on polymerization. Deprotonation of the second binding pocket with M(HMDS) (M = Li, Na, K) yields the Ni-alkali metal heterobimetallic complexes 3Li, 3Na, and 3K. The deprotonated alkali metal enamides display ethylene polymerization behavior similar to the neutral imine complex because the enamide arm can also distally rotate to minimize interaction with the Ni coordination sphere upon activation.	Org. Lett.	122	Niu, JL; Song, MP	FALSE	FALSE	FALSE	FALSE
859	10.1021/acssuschemeng.9b05298	doi.org/10.1021/acssuschemeng.9b05298	Highly Dispersed Single-Phase Ni2P Nanoparticles on N,P-Codoped Porous Carbon for Efficient Synthesis of N-Heterocycles		ACS Sustain. Chem. Eng.	122	Song, T; Yang, Y	FALSE	FALSE	FALSE	FALSE
860	10.1016/bs.aihch.2020.02.001	doi.org/10.1016/bs.aihch.2020.02.001	Synthesis and reactivity of fluorinated heterocycles		Adv. Heterocycl. Chem.	122	Luzzio, FA	FALSE	FALSE	FALSE	FALSE
861	10.1016/j.jcat.2019.07.026	doi.org/10.1016/j.jcat.2019.07.026	Nickel-catalyzed cross-coupling reaction of carbamates with silylmagnesium reagents		J. Catal.	122	Rasappan, R	FALSE	FALSE	FALSE	FALSE
862	10.1021/acscatal.8b01286	doi.org/10.1021/acscatal.8b01286	Catalytic Reactions of Terminal Alkynes Using Rhodium(I) Complexes Bearing 8-Quinolinolate Ligands		ACS Catal.	122	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
863	10.1021/acscatal.5b01075	doi.org/10.1021/acscatal.5b01075	Computational Exploration of Mechanism and Selectivities of (NHC)Nickel(II)hydride-Catalyzed Hydroalkenylations of Styrene with alpha-Olefins		ACS Catal.	122	Ho, CY	FALSE	FALSE	FALSE	FALSE
864	10.1039/c4ob00604f	doi.org/10.1039/c4ob00604f	A facile and convenient sequential homobimetallic catalytic approach towards beta-methylstyrenes. A one-pot Stille cross-coupling/isomerization strategy		Org. Biomol. Chem.	122	Kaufman, TS	FALSE	FALSE	FALSE	FALSE
865	10.1055/s-0033-1339509	doi.org/10.1055/s-0033-1339509	Convenient Syntheses of Enantiopure 1,2-Oxazin-4-yl Nonaflates and Phosphates and Their Palladium-Catalyzed Cross-Couplings		Synthesis	122	Zimmer, R	FALSE	FALSE	FALSE	FALSE
866	10.1002/chem.201101037	doi.org/10.1002/chem.201101037	Negishi Cross-Coupling Reactions Catalyzed by an Aminophosphine-Based Nickel System: A Reliable and General Applicable Reaction Protocol for the High-Yielding Synthesis of Biaryls		Chem.-Eur. J.	122	Frech, CM	FALSE	FALSE	FALSE	FALSE
867	10.1039/c0sc00394h	doi.org/10.1039/c0sc00394h	Metallacycle-mediated cross-coupling with substituted and electronically unactivated alkenes		Chem. Sci.	122	Micalizio, GC	FALSE	FALSE	FALSE	FALSE
868	10.6023/cjoc202108006	doi.org/10.6023/cjoc202108006	Synthesis of gem-Difluoroalkenes through Nickel-Promoted Electrochemical Reductive Cross-Coupling		Chin. J. Org. Chem.	122	Lu, X; Fu, Y	FALSE	TRUE	FALSE	FALSE
869	10.1039/d1dt01704g	doi.org/10.1039/d1dt01704g	Unveiling the catalytic nature of palladium-N-heterocyclic carbene catalysts in the alpha-alkylation of ketones with primary alcohols		Dalton Trans.	122	Gulcemal, S	FALSE	FALSE	FALSE	FALSE
870	10.1007/s11426-016-9010-9	doi.org/10.1007/s11426-016-9010-9	Recent progress on the synthesis of 2-deoxy glycosides		Sci. China-Chem.	122	Wan, Q	FALSE	FALSE	FALSE	FALSE
871	10.1021/acscatal.7b01330	doi.org/10.1021/acscatal.7b01330	Pd-Catalyzed Regioselective Decarboxylative/C-H alpha-Alkoxyalkenylation of Heterocycles Using alpha-Carboxyvinylethers		ACS Catal.	122	Hoarau, C	FALSE	FALSE	FALSE	FALSE
872	10.1021/acscatal.7b00159	doi.org/10.1021/acscatal.7b00159	Recent Advances in Catalytic C(sp(2))-H Allylation Reactions		ACS Catal.	122	Kim, IS	FALSE	FALSE	FALSE	FALSE
873	10.1021/acscatal.6b02477	doi.org/10.1021/acscatal.6b02477	Diverting C-H Annulation Pathways: Nickel-Catalyzed Dehydrogenative Homologation of Aromatic Amides		ACS Catal.	122	Huang, Y	FALSE	FALSE	FALSE	FALSE
874	10.1002/adsc.201600590	doi.org/10.1002/adsc.201600590	Nickel- or Iron-Catalyzed Cross-Coupling of Aryl Carbamates with Arylsilanes		Adv. Synth. Catal.	122	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
875	10.1021/acs.joc.6b00767	doi.org/10.1021/acs.joc.6b00767	Synthesis of Highly Functionalized Triarylbismuthines by Functional Group Manipulation and Use in Palladium- and Copper-Catalyzed Arylation Reactions		J. Org. Chem.	122	Gagnon, A	FALSE	FALSE	FALSE	FALSE
876	10.1016/bs.aihch.2016.04.002	doi.org/10.1016/bs.aihch.2016.04.002	Metal-Catalyzed Coupling with Heterocycles		Adv. Heterocycl. Chem.	122	Badenock, JC	FALSE	FALSE	FALSE	FALSE
877	10.1021/acs.orglett.0c02672	doi.org/10.1021/acs.orglett.0c02672	CuI/2-Aminopyridine 1-Oxide Catalyzed Amination of Aryl Chlorides with Aliphatic Amines	Since the introduction of 2-methyltetrahydrofuran as an useful alternative to the classical tetrahydrofuran, there has been a continuous interest in the synthetic community operating at academic and industrial towards it. In particular, the much higher stability that basic organometallic reagents display in 2-methyltetrahydrofuran makes it suitable for processes involving such sensitive species including asymmetric transformations. The easy formation of an azeotropic mixture with water, the substantial immiscibility with water, and the fact it derives from natural sources (corncobs or bagasse), allow to consider it in agreement with the Anastas' Geen Chemistry principles. In this minireview, selected examples of its employment in organometallic transformations ranging from carbanions to radical and transition metal-catalyzed processes are provided.	Org. Lett.	121	Wang, DP	FALSE	FALSE	FALSE	FALSE
878	10.1039/d0ob00956c	doi.org/10.1039/d0ob00956c	Synthesis and practical applications of 2-(2-nitroalkyl)pyrroles	Homogeneous conditions for the palladium-catalyzed cyanation of aryl halides were developed. This new system features a broad scope of aryl chlorides and bromides, uses 2-propanol or 1-butanol as solvent, and is readily scalable. The same conditions can also provide simple benzonitriles using the recently developed (TMEDA)NiCl(o-tolyl) precatalyst in conjunction with 1,1'-bis(diphenylphosphino)ferrocene (dppf) as a ligand.	Org. Biomol. Chem.	121	Petrini, M	FALSE	FALSE	FALSE	FALSE
879	10.1007/s41061-020-0300-1	doi.org/10.1007/s41061-020-0300-1	Direct Amination of Aromatic C-H Bonds with Free Amines	A series of bulky amine palladium complexes {[(Ar-NH2)(2)PdCl2]} were synthesized and characterized. The catalytic activity of the palladium complexes was evaluated via the direct C-H arylation of thiazoles with aryl bromides in aerobic conditions at 80-100 degrees C. Under the optimal conditions, 0.5-0.05 mol% of the bulky palladium complexes were found to be very efficient and produced the desired cross-coupling products in high yields. (C) 2015 Elsevier B.V. All rights reserved.	Top. Curr. Chem.	121	Zhang, DQ	FALSE	FALSE	FALSE	FALSE
880	10.1002/anie.201912882	doi.org/10.1002/anie.201912882	Sequence-Dependent Stereodivergent Allylic Alkylation/Fluorination of Acyclic Ketones		Angew. Chem.-Int. Edit.	121	You, SL	FALSE	FALSE	FALSE	FALSE
881	10.1055/s-0037-1610267	doi.org/10.1055/s-0037-1610267	Mn(II)-Catalyzed N-Acylation of Amines		Synthesis	121	Gong, H	FALSE	FALSE	FALSE	FALSE
882	10.1055/s-0037-1609941	doi.org/10.1055/s-0037-1609941	Retaining Alkyl Nucleophile Regiofidelity in Transition-Metal-Mediated Cross-Couplings to Aryl Electrophiles		Synthesis	121	Cornella, J	FALSE	TRUE	FALSE	FALSE
883	10.1039/c2ob25225b	doi.org/10.1039/c2ob25225b	Nickel-catalyzed C-P coupling of aryl mesylates and tosylates with H(O)(PRR2)-R-1		Org. Biomol. Chem.	121	Zhang, WB	FALSE	FALSE	FALSE	FALSE
884	10.1021/om900100f	doi.org/10.1021/om900100f	Selective Platinum-Catalyzed C-F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers		Organometallics	121	Love, JA	FALSE	FALSE	FALSE	FALSE
885	10.6023/cjoc201512017	doi.org/10.6023/cjoc201512017	Progress on the Sulfonylation and Desulfonylative Reactions of Sulfonyl Chlorides		Chin. J. Org. Chem.	121	Fu, Y	FALSE	FALSE	FALSE	FALSE
886	10.1016/j.tet.2016.01.004	doi.org/10.1016/j.tet.2016.01.004	Chromatography with silver nitrate: part 2		Tetrahedron	121	Williams, CM	FALSE	FALSE	FALSE	FALSE
887	10.1039/c9nj02810b	doi.org/10.1039/c9nj02810b	Carbon dioxide utilization in the efficient synthesis of carbamates by deep eutectic solvents (DES) as green and attractive solvent/catalyst systems		New J. Chem.	120	Inaloo, ID	FALSE	FALSE	FALSE	FALSE
888	10.1002/asia.201801862	doi.org/10.1002/asia.201801862	Investigating the Mechanism of Palladium-Catalyzed Radical Oxidative C(sp(3))-H Carbonylation: A DFT Study		Chem.-Asian J.	120	Lan, Y; Bai, RP	FALSE	FALSE	FALSE	FALSE
889	10.1002/cssc.201801382	doi.org/10.1002/cssc.201801382	Ligand-Free Bioinspired Suzuki-Miyaura Coupling Reactions using Aryltrifluoroborates as Effective Partners in Deep Eutectic Solvents		ChemSusChem	120	Perna, FM; Capriati, V	FALSE	FALSE	FALSE	FALSE
890	10.1002/ejoc.201300657	doi.org/10.1002/ejoc.201300657	Reductive Deoxygenation of Alcohols: Catalytic Methods Beyond Barton-McCombie Deoxygenation		Eur. J. Org. Chem.	120	Konig, B	FALSE	FALSE	FALSE	FALSE
891	10.1039/c2dt12187e	doi.org/10.1039/c2dt12187e	Novel saccharinate-bridged palladium complexes for efficient C-O bond activation displaying promising luminescence properties		Dalton Trans.	120	Kapdi, AR	FALSE	FALSE	FALSE	FALSE
892	10.1021/ja200398c	doi.org/10.1021/ja200398c	Suzuki-Miyaura Cross-Coupling of Aryl Carbamates and Sulfamates: Experimental and Computational Studies		J. Am. Chem. Soc.	120	Houk, KN	FALSE	FALSE	FALSE	FALSE
893	10.1002/chem.200601142	doi.org/10.1002/chem.200601142	9-fluorenylphosphines for the Pd-catalyzed Sonogashira, Suzuki, and Buchwald-Hartwig coupling reactions in organic solvents and water		Chem.-Eur. J.	120	Plenio, H	FALSE	FALSE	FALSE	FALSE
894	10.5059/yukigoseikyokaishi.38.633	doi.org/10.5059/yukigoseikyokaishi.38.633	C-H AND C-O BOND ACTIVATION BY TRANSITION-METAL COMPLEXES - OXIDATIVE ADDITION AND REDUCTIVE ELIMINATION		J. Synth. Org. Chem. Jpn.	120	KOMIYA, S	FALSE	FALSE	FALSE	FALSE
895	10.1021/acscatal.1c03980	doi.org/10.1021/acscatal.1c03980	Nickel-Catalyzed Reductive Deoxygenation of Diverse C-O Bond-Bearing Functional Groups		ACS Catal.	120	Newman, SG	FALSE	FALSE	FALSE	FALSE
896	10.1021/acscatal.1c04143	doi.org/10.1021/acscatal.1c04143	Synthesis of Multisubstituted Allenes via Nickel-Catalyzed Cross-Electrophile Coupling		ACS Catal.	120	Wang, C	FALSE	TRUE	FALSE	FALSE
897	10.1016/j.tet.2021.132415	doi.org/10.1016/j.tet.2021.132415	Functionalization of C(sp(3))-H bonds adjacent to heterocycles catalyzed by earth abundant transition metals		Tetrahedron	120	Bhadra, S	FALSE	FALSE	FALSE	FALSE
898	10.1002/anie.202106356	doi.org/10.1002/anie.202106356	Activation of Aryl Carboxylic Acids by Diboron Reagents towards Nickel-Catalyzed Direct Decarbonylative Borylation		Angew. Chem.-Int. Edit.	120	Su, WP	FALSE	FALSE	FALSE	FALSE
899	10.1039/c7ra09006d	doi.org/10.1039/c7ra09006d	Theoretical study on homolytic B-B cleavages of diboron(4) compounds		RSC Adv.	120	Zheng, WR	FALSE	FALSE	FALSE	FALSE
900	10.1055/s-0040-1707342	doi.org/10.1055/s-0040-1707342	Reductive Cross-Coupling of Vinyl Electrophiles	An enantioselective Ni-catalyzed cross-coupling of NT-hyciroxyphthalimide esters with Vinyl bromides is reported. The reaction proceeds under mild conditions and uses tetralds(N,N-dimethylamino)ethylene as a terminal organic reductant. Good functional group tolerance is demonstrated, with over 20 examples of reactions that proceed with >90% ee.	Synthesis	119	Shu, XZ	FALSE	TRUE	FALSE	FALSE
901	10.1002/anie.202004116	doi.org/10.1002/anie.202004116	Nickel-Mediated Trifluoromethylation of Phenol Derivatives by Aryl C-O Bond Activation	A cross-coupling reaction between air- and moisture-stable aryl- or alkyl(triorgano)silanes and aryl tosylates was developed by cooperative palladium/copper catalysis. In order to obtain the coupling products in high yields, the presence of the P,N-heterobidentate ligand 1-[2-(dicyclohexylphosphanyl)phenyl]-N,N-dimethylmethanamine (L1) is crucial. This protocol tolerates a variety of functional groups such as acetyl, cyano, chloro, formyl, and alkoxycarbonyl moieties.	Angew. Chem.-Int. Edit.	119	Qing, FL	FALSE	FALSE	FALSE	FALSE
902	10.1039/d0sc02542a	doi.org/10.1039/d0sc02542a	Ru-catalyzed isomerization of omega-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequentin situfunctionalization	We have developed a conceptually and methodologically novel self-assembled multilayer nickel nanoparticle (NP) catalyst - sulfur-modified gold-supported Ni NPs (SANi) - for organic synthesis. The SANi catalyst was easily prepared through a three-step procedure involving simultaneous in situ metal NP and nanospace organization. This unique method does not require any conventional preformed template for immobilizing and stabilizing NPs. SANi catalyzes carbon-carbon bond-forming cross-coupling, Kumada coupling, and Negishi coupling reactions under ligand-free conditions and can be used repeatedly for these reactions. Physical analysis of SANi showed that the active species in these reactions are self-assembled multilayer zerovalent Ni NPs with a size of similar to 3 nm.	Chem. Sci.	119	Marek, I	FALSE	FALSE	FALSE	FALSE
903	10.1021/jacs.9b09373	doi.org/10.1021/jacs.9b09373	Remote Functionalization of alpha,beta-Unsaturated Carbonyls by Multimetallic Sequential Catalysis		J. Am. Chem. Soc.	119	Mazet, C	FALSE	FALSE	FALSE	FALSE
904	10.1021/acs.organomet.9b00131	doi.org/10.1021/acs.organomet.9b00131	Phosphine-Free Well-Defined Mn(I) Complex-Catalyzed Synthesis of Amine, Imine, and 2,3-Dihydro-1H-perimidine via Hydrogen Autotransfer or Acceptorless Dehydrogenative Coupling of Amine and Alcohol		Organometallics	119	Srivastava, HK; Srimani, D	FALSE	FALSE	FALSE	FALSE
905	10.1002/cctc.201900132	doi.org/10.1002/cctc.201900132	Phosphite-thioether/selenoether Ligands from Carbohydrates: An Easily Accessible Ligand Library for the Asymmetric Hydrogenation of Functionalized and Unfunctionalized Olefins		ChemCatChem	119	Pamies, O; Dieguez, M	FALSE	FALSE	FALSE	FALSE
906	10.1021/acs.joc.5b02098	doi.org/10.1021/acs.joc.5b02098	C-C Activation by Retro-Aldol Reaction of Two beta-Hydroxy Carbonyl Compounds: Synergy with Pd-Catalyzed Cross-Coupling To Access Mono-alpha-arylated Ketones and Esters		J. Org. Chem.	119	Zhang, SL	FALSE	FALSE	FALSE	FALSE
907	10.1002/anie.201507623	doi.org/10.1002/anie.201507623	Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution		Angew. Chem.-Int. Edit.	119	Breit, B	FALSE	FALSE	FALSE	FALSE
908	10.1021/jacs.5b09980	doi.org/10.1021/jacs.5b09980	Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides		J. Am. Chem. Soc.	119	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
909	10.1021/acscatal.5b00909	doi.org/10.1021/acscatal.5b00909	Recent Advances in the Synthesis of Triarylmethanes by Transition Metal Catalysis		ACS Catal.	119	Nambo, M	FALSE	FALSE	FALSE	FALSE
910	10.1002/adsc.201401153	doi.org/10.1002/adsc.201401153	Amine-Borane Complexes: Air-and Moisture-Stable Partners for Palladium-Catalyzed Borylation of Aryl Bromides and Chlorides		Adv. Synth. Catal.	119	Pucheault, M	FALSE	FALSE	FALSE	FALSE
911	10.1021/cs501498f	doi.org/10.1021/cs501498f	Catalytic Hydrogenolysis of Aryl Ethers: A Key Step in Lignin Valorization to Valuable Chemicals		ACS Catal.	119	Kempe, R	FALSE	FALSE	FALSE	FALSE
912	10.1021/jo4024123	doi.org/10.1021/jo4024123	Synthesis of Heteroaryl Compounds through Cross-Coupling Reaction of Aryl Bromides or Benzyl Halides with Thienyl and Pyridyl Aluminum Reagents		J. Org. Chem.	119	Zhou, SL	FALSE	FALSE	FALSE	FALSE
913	10.1002/ejoc.201200918	doi.org/10.1002/ejoc.201200918	Room-Temperature Suzuki-Miyaura Coupling of Heteroaryl Chlorides and Tosylates		Eur. J. Org. Chem.	119	Zhou, JR	FALSE	FALSE	FALSE	FALSE
914	10.1016/j.ccr.2011.10.018	doi.org/10.1016/j.ccr.2011.10.018	Allylic ruthenium(IV) complexes in catalysis		Coord. Chem. Rev.	119	Bruneau, C	FALSE	FALSE	FALSE	FALSE
915	10.1080/07328303.2012.683910	doi.org/10.1080/07328303.2012.683910	Recent Advances in Transition Metal-Catalyzed O-Glycosylations		J. Carbohydr. Chem.	119	Zhu, JL	FALSE	FALSE	FALSE	FALSE
916	10.1002/chem.201101489	doi.org/10.1002/chem.201101489	Calcium-Mediated Dearomatization, C-H Bond Activation, and Allylation of Alkylated and Benzannulated Pyridine Derivatives		Chem.-Eur. J.	119	Okuda, J	FALSE	FALSE	FALSE	FALSE
917	10.2174/138527211797248021	doi.org/10.2174/138527211797248021	Pd-catalyzed alpha-Arylation of Carbonyl and Related Compounds: Recent Developments and Perspectives		Curr. Org. Chem.	119	Martin, R	FALSE	FALSE	FALSE	FALSE
918	10.1021/ja102686u	doi.org/10.1021/ja102686u	Arrested Catalysis: Controlling Kumada Coupling Activity via a Redox-Active N-Heterocyclic Carbene		J. Am. Chem. Soc.	119	Bielawski, CW	FALSE	FALSE	FALSE	FALSE
919	10.1002/aoc.6551	doi.org/10.1002/aoc.6551	4,5-Dihydro-imidazol-2-ylidene-linked palladium complexes as catalysts for the direct C-H bond arylation of azoles		Appl. Organomet. Chem.	119	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
920	10.1021/jacs.7b03548	doi.org/10.1021/jacs.7b03548	Computational Study of Ni-Catalyzed C-H Functionalization: Factors That Control the Competition of Oxidative Addition and Radical Pathways		J. Am. Chem. Soc.	119	Liu, P	FALSE	FALSE	FALSE	FALSE
921	10.1016/j.jorganchem.2016.12.029	doi.org/10.1016/j.jorganchem.2016.12.029	Organonickel complexes encumbering bis-imidazolylidene carbene ligands: Synthesis, X-ray structure and catalytic insights on Buchwald-Hartwig amination reactions		J. Organomet. Chem.	119	Viswanathamurthi, P	FALSE	FALSE	FALSE	FALSE
922	10.1007/s41061-016-0067-6	doi.org/10.1007/s41061-016-0067-6	Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles		Top. Curr. Chem.	119	Kambe, N	FALSE	TRUE	FALSE	FALSE
923	10.1002/chem.201601584	doi.org/10.1002/chem.201601584	Modular Construction of Fluoroarenes from a New Difluorinated Building Block by Cross-Coupling/Electrocyclisation/Dehydrofluorination Reactions		Chem.-Eur. J.	119	Percy, JM	FALSE	TRUE	FALSE	FALSE
924	10.1002/ajoc.202000686	doi.org/10.1002/ajoc.202000686	Ruthenium-Catalyzed Synthesis of alpha-Alkylated Ketones and Quinolines in an Aqueous Medium via a Hydrogen-Borrowing Strategy Using Ketones and Alcohols	The first synthesis of cyclic (alkyl)(amino) carbenes (cAACs) was reported in 2005, and since then this class of carbenes has been on a victory tour in main-group-element and transition-metal chemistry. CAACs are easy to synthesize and among the most nucleophilic (sigma-donating) and simultaneously most electrophilic (pi-accepting) carbenes known to date. These properties have led to a vast number of applications of cAACs in main-group-element chemistry in, for example, the activation of small-molecule compounds and enthalpically strong bonds, as well as in the stabilization of highly reactive main-group-element compounds. They also proved to possess outstanding ligand properties in transition-metal chemistry in, for example, the stabilization of unusual low-valent transition-metal complexes, leading to enormously highly active but robust catalysts. Here a brief overview of cAAC-ligated transition-metal compounds, mainly in low oxidation states, with an emphasis on nickel complexes, is provided, and a personal account of some of the recent developments in the use of cAACs in coordination chemistry and catalysis is given.	Asian J. Org. Chem.	118	Elias, AJ	FALSE	FALSE	FALSE	FALSE
925	10.1055/a-1349-3543	doi.org/10.1055/a-1349-3543	Biaryl Construction Based on Nickel-Catalyzed C-O Bond Activation	The first example of a diazo palladium adduct is reported. The complexes [(ArNHC-PPh2) M(eta(N2C)-N-2(Ph) CO2Et)] (M = Ni, 3; M = Pd, 4; ArNHC-PPh2 = 3-(2,6-diisopropylphenyl)- 1-[(diphenylphosphino)ethyl] imidazol-2-ylidene) were prepared by ligand exchange with styrene-coordinated precursors [(ArNHC @ PPh2) M(styrene)] (M = Ni, 1; M = Pd, 2). Complex 4 was fully characterized, including X-ray analyses; this constitutes the first example of a diazo adduct compound with palladium, thereby closing the gap between Groups 8 and 10 regarding this type of compounds.	Synlett	118	Liu, F	FALSE	FALSE	FALSE	FALSE
926	10.1021/acs.orglett.0c03782	doi.org/10.1021/acs.orglett.0c03782	Generation of Organozinc Reagents from Arylsulfonium Salts Using a Nickel Catalyst and Zinc Dust	High thermally and thermo-oxidatively stable poly(phenylene-carborane) (PPB) was synthesized via Ni(0)-catalyzed polymerization of bis(aryl chloride) monomer containing carborane. This polymer was soluble in THF and NMP at room temperature, thus allowing molecular weight and spectroscopic analysis. Number-average molecular weight determined by H-1-NMR spectroscopy was 5.4 x 103 g/mol. The crystalline character of PPB was verified by XRD analysis. This polymer exhibited excellent thermal and thermo-oxidative stability with 5% weight loss temperature to be 707 degrees C and > 1000 degrees C in nitrogen and air, respectively. High char yields of 93.2% and 97.9% were obtained at 1000 degrees C in nitrogen and air, respectively. Additionally, PPB has proven to be excellent sing-source precursor to boron-carbide/carbon ceramic materials with high ceramic yields in the range of 91.1%-92.6%. According to XRD analysis, boron carbide crystallization for PPB occurred between 1000 and 1200 degrees C. (C) 2017 Published by Elsevier Ltd.	Org. Lett.	118	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
927	10.1002/anie.202011231	doi.org/10.1002/anie.202011231	Nickel-Catalyzed Migratory Hydrocyanation of Internal Alkenes: Unexpected Diastereomeric-Ligand-Controlled Regiodivergence	A one-pot method for the synthesis of 2-alkyl(aryl, benzyl)-1-phenylboriranes has been developed via the reaction of alpha-olefins with PhBCl2 in the presence of Cp2TiCl2 as the catalyst. The method implies the formation of boriranes as the result of transmetalation of titanacyclopropane intermediates generated in the reaction of alpha-olefins with Cp2TiCl2. Individual 1-phenyl-2-substituted boriranes were isolated and their structures confirmed by NMR spectral methods. (C) 2017 Elsevier B.V. All rights reserved.	Angew. Chem.-Int. Edit.	118	Fang, XJ	FALSE	FALSE	FALSE	FALSE
928	10.1002/chem.202001253	doi.org/10.1002/chem.202001253	Control of Absolute Stereochemistry in Transition-Metal-Catalysed Hydrogen-Borrowing Reactions	Ring-opening reactions of strained heterocyclic compounds provide efficient routes to various organic frameworks. In this work, the ability of carboxylic acid nucleophiles to promote ring-opening of cyclopropanated 7-oxabenzonorbornadienes was investigated. Reactions proceeded smoothly to yield 2-naphthylmethyl esters in moderate yields, and optimal conditions were found with the use of 10 mol% p-toluenesulfonic acid monohydrate in dichloroethane heated to 90 degrees C. The amount of nucleophile could be decreased from a large excess to 8 equivalents without diminishing the yield. When varying the structure of the acid catalyst or carboxylic acid nucleophile, reaction rates showed a marked dependence on acidity of these species. Ring-opening was well tolerated by functionalized substrates, with substitution on the bridgehead or aromatic portions of the molecule. The present work is the second account of this type of reaction, and provides a new route to 2-naphthylmethyl esters. The transformations observed in this work should be useful in predicting the reactivity of similar fused-ring systems.	Chem.-Eur. J.	118	Armstrong, RJ; Donohoe, TJ	FALSE	FALSE	FALSE	FALSE
929	10.3390/catal10010136	doi.org/10.3390/catal10010136	Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki-Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids		Catalysts	118	Wolfson, A; Levy-Ontman, O	FALSE	FALSE	FALSE	FALSE
930	10.1039/c9qo00726a	doi.org/10.1039/c9qo00726a	Rigid hindered N-heterocyclic carbene palladium precatalysts: synthesis, characterization and catalytic amination		Org. Chem. Front.	118	Yao, HG; Liu, FS	FALSE	FALSE	FALSE	FALSE
931	10.1002/adsc.201900545	doi.org/10.1002/adsc.201900545	C-N Cross-Coupling Reactions Under Mild Conditions Using Singlet Di-Radical Nickel(II)-Complexes as Catalyst: N-Arylation and Quinazoline Synthesis		Adv. Synth. Catal.	118	Paul, ND	FALSE	FALSE	FALSE	FALSE
932	10.1039/c8dt03882a	doi.org/10.1039/c8dt03882a	Synthesis, characterization, and catalytic application in aldehyde hydrosilylation of half-sandwich nickel complexes bearing ((1)-C)- and hemilabile ((2)-C,S)-thioether-functionalised NHC ligands		Dalton Trans.	118	Chetcuti, MJ; Ritleng, V	FALSE	FALSE	FALSE	FALSE
933	10.1021/jacs.7b12865	doi.org/10.1021/jacs.7b12865	Ligand-Controlled Chemoselective C(acyl)-O Bond vs Caryl)-C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp(2))-C(sp(3)) Cross-Couplings		J. Am. Chem. Soc.	118	Rueping, M	FALSE	FALSE	FALSE	FALSE
934	10.1021/ja5116452	doi.org/10.1021/ja5116452	Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C-H Bond Functionalization/Addition/Cyclization Cascades		J. Am. Chem. Soc.	118	Ellman, JA	FALSE	FALSE	FALSE	FALSE
935	10.1016/j.tet.2012.05.030	doi.org/10.1016/j.tet.2012.05.030	A mild robust generic protocol for the Suzuki reaction using an air stable catalyst		Tetrahedron	118	Moseley, JD	FALSE	FALSE	FALSE	FALSE
936	10.1021/ja207759e	doi.org/10.1021/ja207759e	Nickel-Catalyzed Suzuki-Miyaura Reaction of Aryl Fluorides		J. Am. Chem. Soc.	118	Tobisu, M	FALSE	FALSE	FALSE	FALSE
937	10.1002/chem.201002354	doi.org/10.1002/chem.201002354	Palladium-Catalyzed Direct Arylation of Heteroarenes with Aryl Mesylates		Chem.-Eur. J.	118	Kwong, FY	FALSE	FALSE	FALSE	FALSE
938	10.1021/ja0112036	doi.org/10.1021/ja0112036	Iridium complex-catalyzed allylic amination of allylic esters		J. Am. Chem. Soc.	118	Takeuchi, R	FALSE	FALSE	FALSE	FALSE
939	10.1021/jo960458c	doi.org/10.1021/jo960458c	Nickel-catalyzed coupling reaction of 1,3-disubstituted secondary allylic carbonates and lithium aryl- and alkenylborates		J. Org. Chem.	118	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
940	10.1016/j.ica.2021.120747	doi.org/10.1016/j.ica.2021.120747	Substituted N-heterocyclic carbene PEPPSI-type palladium complexes with different N-coordinated ligands: Involvement in the direct C-H bond activation of heteroarenes derivatives with aryl bromide and their antimicrobial, anti-inflammatory and antioxidant activities		Inorg. Chim. Acta	118	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
941	10.1021/acscatal.1c02010	doi.org/10.1021/acscatal.1c02010	Recent Progress in Methyl-Radical-Mediated Methylation or Demethylation Reactions		ACS Catal.	118	Chen, ZY	FALSE	FALSE	FALSE	FALSE
942	10.1246/bcsj.20160365	doi.org/10.1246/bcsj.20160365	Toward an Ideal Synthesis of (Bio) molecules through Direct Arene Assembling Reactions		Bull. Chem. Soc. Jpn.	118	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
943	10.1039/c5sc03704b	doi.org/10.1039/c5sc03704b	Nickel-catalyzed arylation of heteroaryl-containing diarylmethanes: exceptional reactivity of the Ni(NIXANTPHOS)-based catalyst		Chem. Sci.	118	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
944	10.1039/d0gc03912h	doi.org/10.1039/d0gc03912h	Metal-free approach for hindered amide-bond formation with hypervalent iodine(III) reagents: application to hindered peptide synthesis	Enantioselective nickel-catalyzed arylative cyclizations of substrates containing a Z-allylic phosphate tethered to an alkyne are described. These reactions give multisubstituted chiral aza- and carbocycles, and are initiated by the addition of an arylboronic acid to the alkyne, followed by cyclization of the resulting alkenylnickel species onto the allylic phosphate. The reversible E/Z isomerization of the alkenylnickel species is essential for the success of the reactions.	Green Chem.	117	Maruoka, K	FALSE	FALSE	FALSE	FALSE
945	10.1021/acs.orglett.0c02303	doi.org/10.1021/acs.orglett.0c02303	General Synthesis of Cyclopropanols via Organometallic Addition to 1-Sulfonylcyclopropanols as Cyclopropanone Precursors	A unified strategy for cobalt-catalyzed ortho-C-H bond alkynylation of benzylamines is reported. Simple, commercially available CoBr2 was used as a cobalt source. The developed alkynylation strategy is robust and efficient and has a broad substrate scope including 1 degrees, 2 degrees, and 3 degrees benzylamines. The mechanistic study shows that C-H bond cleavage is reversible, and the kinetic study illustrates that the rate of reaction depends solely on the catalyst.	Org. Lett.	117	Lindsay, VNG	FALSE	FALSE	FALSE	FALSE
946	10.1002/anie.202005019	doi.org/10.1002/anie.202005019	Cooperative Ni/Cu-Catalyzed Asymmetric Propargylic Alkylation of Aldimine Esters	The influence of the alcohol, as the hydrogen donor, on the efficiency and selectivity of the asymmetric transfer hydrogenation (ATH) of imines is reported for the first time. This discovery not only leads to a highly enantioselective access to N-aryl and N-alkyl amines, but also provides new insight into the mechanism of the ATH of imines. Both experimental and computational studies provide support for the reaction pathway involving an iridium alkoxide as the reducing species.	Angew. Chem.-Int. Edit.	117	Guo, C	FALSE	FALSE	FALSE	FALSE
947	10.1002/ejoc.201901895	doi.org/10.1002/ejoc.201901895	Axially Chiral 1,1'-Binaphthyl-2-Carboxylic Acid (BINA-Cox) as Ligands for Titanium-Catalyzed Asymmetric Hydroalkoxylation	We report the first catalytic method for activating the acyl C-O bonds of methyl esters through an oxidative-addition process. The oxidative-addition adducts, formed using nickel catalysis, undergo in situ trapping to provide anilide products. DFT calculations are used to support the proposed reaction mechanism, to understand why decarbonylation does not occur competitively, and to elucidate the beneficial role of the substrate structure and the Al(OtBu)(3) additive on the kinetics and thermodynamics of the reaction.	Eur. J. Org. Chem.	117	Hintermann, L	FALSE	FALSE	FALSE	FALSE
948	10.1002/slct.202000164	doi.org/10.1002/slct.202000164	Microwave-Assisted/Pd-Catalyzed Domino Synthesis of 2,3,4-Triiodoanisole from 3-Anisic Acid: A Superior Substrate for Regioselective Synthesis of 2,3-Diiodobiphenyls	This review discusses the use of nickel catalysts and N,N'-bidentate directing groups, such as 2-pyridinylmethylamine, 8-aminoquinoline, and derivatives thereof, which constitute a powerful combination for the chelation-assisted functionalization of C-H bonds.	ChemistrySelect	117	Al-Zoubi, RM	FALSE	FALSE	FALSE	FALSE
949	10.1002/anie.201906781	doi.org/10.1002/anie.201906781	A Celebration of Science amidst Nature: The 54th Burgenstock Conference		Angew. Chem.-Int. Edit.	117	Barath, E	FALSE	FALSE	FALSE	FALSE
950	10.1039/c9nj01748h	doi.org/10.1039/c9nj01748h	Metal-free thioesterification of amides generating acyl thioesters		New J. Chem.	117	Chen, TQ	FALSE	FALSE	FALSE	FALSE
951	10.1021/jacs.9b02238	doi.org/10.1021/jacs.9b02238	A Radical Approach to Anionic Chemistry: Synthesis of Ketones, Alcohols, and Amines		J. Am. Chem. Soc.	117	Baran, PS	FALSE	FALSE	FALSE	FALSE
952	10.1002/ejoc.201801173	doi.org/10.1002/ejoc.201801173	Transition-Metal-Free Approach for the Direct Arylation of Thiophene: Experimental and Theoretical Investigations towards the (Het)-Aryne Route		Eur. J. Org. Chem.	117	Ingrosso, F; Comoy, C	FALSE	FALSE	FALSE	FALSE
953	10.1039/c8nj05503c	doi.org/10.1039/c8nj05503c	Nickel-catalyzed cross-coupling of O,N-chelated diarylborinates with aryl chlorides and mesylates		New J. Chem.	117	Zou, G	FALSE	FALSE	FALSE	FALSE
954	10.1039/c4qo00321g	doi.org/10.1039/c4qo00321g	Highly efficient pincer nickel catalyzed cross-coupling of aryltrimethylammonium triflates with arylzinc reagents		Org. Chem. Front.	117	Wu, D	FALSE	FALSE	FALSE	FALSE
955	10.1021/jo400128c	doi.org/10.1021/jo400128c	Fluorescence Enhancement of Pyrene Chromophores Induced by Alkyl Groups through sigma-pi Conjugation: Systematic Synthesis of Primary, Secondary, and Tertiary Alkylated Pyrenes at the 1, 3, 6, and 8 Positions and Their Photophysical Properties		J. Org. Chem.	117	Konishi, G	TRUE	FALSE	FALSE	FALSE
956	10.1055/s-0032-1316846	doi.org/10.1055/s-0032-1316846	Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts		Synthesis	117	Matsunaga, S	FALSE	FALSE	FALSE	FALSE
957	10.1039/b608410a	doi.org/10.1039/b608410a	Reactivity of a palladium fluoro complex towards silanes and Bu3SnCH = CH2: catalytic derivatisation of pentafluoropyridine based on carbon-fluorine bond activation reactions		Dalton Trans.	117	Braun, T	FALSE	FALSE	FALSE	FALSE
958	10.1002/anie.202117114	doi.org/10.1002/anie.202117114	Catalytic Enantioconvergent Allenylation of Aldehydes with Propargyl Halides		Angew. Chem.-Int. Edit.	117	Wang, ZB	FALSE	FALSE	FALSE	FALSE
959	10.1021/acscatal.1c04128	doi.org/10.1021/acscatal.1c04128	Y Enantioselective Cobalt-Catalyzed Reductive Cross-Coupling for the Synthesis of Axially Chiral Phosphine-Olefin Ligands		ACS Catal.	117	Yang, SD	FALSE	FALSE	FALSE	FALSE
960	10.1002/chem.201604496	doi.org/10.1002/chem.201604496	Decarboxylation as the Key Step in C-C Bond-Forming Reactions		Chem.-Eur. J.	117	Maiti, D	FALSE	FALSE	FALSE	FALSE
961	10.1002/cssc.201700321	doi.org/10.1002/cssc.201700321	Expeditious and Solvent-Free Nickel-Catalyzed C-H Arylation of Arenes and Indoles		ChemSusChem	117	Punji, B	FALSE	FALSE	FALSE	FALSE
962	10.17159/0379-4350/2017/v70a10	doi.org/10.17159/0379-4350/2017/v70a10	Great South African Molecules: The Case For Mycothiol		South Afr. J. Chem.-Suid-Afr. Tydskr. Chem.	117	Nkambule, CM	FALSE	FALSE	FALSE	FALSE
963	10.1021/jacs.0c10832	doi.org/10.1021/jacs.0c10832	Modular Cyclopentenone Synthesis through the Catalytic Molecular Shuffling of Unsaturated Acid Chlorides and Alkynes	Bench-stable nickel fluoride complexes bearing NNN pincer ligands have been employed as precursors for the regioselective hydrosilylation of epoxides at room temperature. A nickel hydride assisted epoxide opening is followed by the cleavage of the newly formed nickel oxygen bond by sigma-bond metathesis with a silane.	J. Am. Chem. Soc.	116	Morandi, B	FALSE	FALSE	FALSE	FALSE
964	10.1039/d0cc02542a	doi.org/10.1039/d0cc02542a	Recent advances of dinuclear nickel- and palladium-complexes in homogeneous catalysis	The highly enantioselective copper(I)/N-heterocyclic carbene (NHC) catalyzed synthesis of di- and triarylated all-carbon quaternary stereocenters via asymmetric allylic arylation (AAAr) with aryl organolithium compounds is demonstrated. The use of readily available or easily accessible aryl organolithium reagents in combination with trisubstituted ally) bromides, in the presence of a copper/NHC catalyst, affords important di- and triarylated all-carbon quaternary stereocenters in good yields and enantioselectivities. This method tolerates a wide range of alkyl and substituted aryl groups in the starting allyl bromides, including less common biaryl moieties, which, in combination with diverse organolithium reagents, delivers a broad scope of products in an operationally straightforward and efficient manner.	Chem. Commun.	116	Xie, J	FALSE	FALSE	FALSE	FALSE
965	10.1039/c9cc10057a	doi.org/10.1039/c9cc10057a	Visible-light photoredox-catalyzed dual C-C bond cleavage: synthesis of 2-cyanoalkylsulfonylated 3,4-dihydronaphthalenes through the insertion of sulfur dioxide	We demonstrate that a simple cobalt complex can regioselectively couple epoxides and aziridines with alkenes to generate valuable homoallylic alcohols and amines. The intramolecular reaction exhibits complete atom economy and, in contrast to traditional Mizoroki-Heck reactions, does not require stoichiometric amounts of base. An indole derivative was also shown to be a suitable coupling partner. Finally, promising results regarding the development of an intermolecular process using both epoxides and aziridines are reported, as well as preliminary mechanistic studies suggesting a radical mechanism.	Chem. Commun.	116	Liu, Y; Li, H; Tang, KW	FALSE	FALSE	FALSE	FALSE
966	10.1002/cctc.201900254	doi.org/10.1002/cctc.201900254	Nickel-Catalyzed Dehydrogenative Couplings		ChemCatChem	116	De Sarkar, S	FALSE	FALSE	FALSE	FALSE
967	10.1002/open.201900104	doi.org/10.1002/open.201900104	Self-Suspended Nanoparticles for N-Alkylation Reactions: A New Concept for Catalysis		ChemistryOpen	116	Sarno, M	FALSE	FALSE	FALSE	FALSE
968	10.6023/cjoc201809037	doi.org/10.6023/cjoc201809037	Recent Advances in Ni-Catalyzed Allylic Substitution Reactions		Chin. J. Org. Chem.	116	You, SL	FALSE	FALSE	FALSE	FALSE
969	10.1055/s-0037-1610222	doi.org/10.1055/s-0037-1610222	Merging Transition-Metal Catalysis with Photoredox Catalysis: An Environmentally Friendly Strategy for C-H Functionalization		Synthesis	116	Zhou, WJ	TRUE	FALSE	FALSE	FALSE
970	10.1002/slct.201701438	doi.org/10.1002/slct.201701438	Copper-Exchanged Magnetic-FAp: Surface Catalysis in Decarboxylative Coupling of alpha-Oxocarboxylic Acids with Formamides		ChemistrySelect	116	Mamaghani, M; Sheykhan, M	FALSE	FALSE	FALSE	FALSE
971	10.1246/bcsj.20130332	doi.org/10.1246/bcsj.20130332	Theoretical Studies of Rhodium-Catalyzed Borylation of Nitriles through Cleavage of Carbon-Cyano Bonds		Bull. Chem. Soc. Jpn.	116	Tobisu, M	FALSE	FALSE	FALSE	FALSE
972	10.1039/c4cs00206g	doi.org/10.1039/c4cs00206g	Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity		Chem. Soc. Rev.	116	Martin, R	FALSE	FALSE	FALSE	FALSE
973	10.1021/jo8010254	doi.org/10.1021/jo8010254	Studies on the mechanism of allylic coupling reactions: A hammett analysis of the coupling of aryl silicate derivatives		J. Org. Chem.	116	DeShong, P	FALSE	FALSE	FALSE	FALSE
974	10.1039/p19950002083	doi.org/10.1039/p19950002083	NICKEL-CATALYZED COUPLING OF ALLYLAMINES AND BORONIC ACIDS		J. Chem. Soc.-Perkin Trans. 1	116	TROST, BM	FALSE	FALSE	FALSE	FALSE
975	10.1002/cctc.202101168	doi.org/10.1002/cctc.202101168	Highly Efficient and Recyclable Porous Organic Polymer Supported Iridium Catalysts for Dehydrogenation and Borrowing Hydrogen Reactions in Water		ChemCatChem	116	Wang, DW	FALSE	FALSE	FALSE	FALSE
976	10.1002/anie.202106273	doi.org/10.1002/anie.202106273	Radical 1,4-Aryl Migration Enabled Remote Cross-Electrophile Coupling of alpha-Amino-beta-Bromo Acid Esters with Aryl Bromides		Angew. Chem.-Int. Edit.	116	Tang, S	FALSE	TRUE	FALSE	FALSE
977	10.1016/j.jorganchem.2015.12.009	doi.org/10.1016/j.jorganchem.2015.12.009	A convenient phosphine-free palladium-catalyzed direct arylation of thiazole under mild aerobic conditions		J. Organomet. Chem.	116	Huang, J	FALSE	FALSE	FALSE	FALSE
978	10.1039/c6ob00164e	doi.org/10.1039/c6ob00164e	Aminoquinoline-assisted vinylic C-H arylation of unsubstituted acrylamide for the selective synthesis of Z olefins		Org. Biomol. Chem.	116	Jiang, C	FALSE	FALSE	FALSE	FALSE
979	10.1039/c9ob01224a	doi.org/10.1039/c9ob01224a	Transition-metal free oxidative C-H etherification of acylanilines with alcohols through a radical pathway		Org. Biomol. Chem.	115	Xia, CC	FALSE	FALSE	FALSE	FALSE
980	10.1002/chem.201900886	doi.org/10.1002/chem.201900886	Photoinduced C(sp(3))-N Bond Cleavage Leading to the Stereoselective Syntheses of Alkenes		Chem.-Eur. J.	115	Wang, C; Uchiyama, M	TRUE	FALSE	FALSE	FALSE
981	10.1002/slct.201803626	doi.org/10.1002/slct.201803626	Effect of Confined Spaces in the Catalytic Activity of 1D and 2D Heterogeneous Carbon-Based Catalysts for Synthesis of 1,3,5-Triarylbenzenes: RGO-SO3H vs. MWCNTs-SO3H		ChemistrySelect	115	Golestanzadeh, M; Naeimi, H	FALSE	FALSE	FALSE	FALSE
982	10.1016/j.jorganchem.2018.04.036	doi.org/10.1016/j.jorganchem.2018.04.036	Iridium(III)- benzoxazolyl and benzothiazolyl phosphine ligands catalyzed versatile alkylation reactions with alcohols and the synthesis of quinolines and indole		J. Organomet. Chem.	115	Hou, XF	FALSE	FALSE	FALSE	FALSE
983	10.1055/s-0034-1379890	doi.org/10.1055/s-0034-1379890	Transition-Metal-Catalyzed Direct C-H Functionalization under External-Oxidant-Free Conditions		Synthesis	115	Cui, XL	FALSE	FALSE	FALSE	FALSE
984	10.1016/j.tet.2014.07.022	doi.org/10.1016/j.tet.2014.07.022	Rhodium-catalyzed direct oxidative cross-coupling of 2-aryl pyridine with benzothiazoles		Tetrahedron	115	Yuan, Y	FALSE	FALSE	FALSE	FALSE
985	10.1021/om200557c	doi.org/10.1021/om200557c	Synthesis, Coordination Behavior, and Structural Features of Chiral Amino-, Pyrazolyl-, and Phosphino-Substituted Ferrocenyloxazolines and Their Application in Asymmetric Hydrogenations		Organometallics	115	Weissensteiner, W	FALSE	FALSE	FALSE	FALSE
986	10.1016/j.tetlet.2009.10.096	doi.org/10.1016/j.tetlet.2009.10.096	An efficient route to 4-substituted coumarins, 2(5H)-furanones, and pyrones via palladium-catalyzed couplings of alkenyl tosylates with organoindium reagents		Tetrahedron Lett.	115	Peng, YY	FALSE	FALSE	FALSE	FALSE
987	10.1021/ja8079548	doi.org/10.1021/ja8079548	Diels-Alder Exo Selectivity in Terminal-Substituted Dienes and Dienophiles: Experimental Discoveries and Computational Explanations		J. Am. Chem. Soc.	115	Gouverneur, V	FALSE	FALSE	FALSE	FALSE
988	10.1002/chem.200800858	doi.org/10.1002/chem.200800858	Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: From basic research to industrial applications		Chem.-Eur. J.	115	Beller, M	FALSE	FALSE	FALSE	FALSE
989	10.1039/d1cy00660f	doi.org/10.1039/d1cy00660f	Origins of Lewis acid acceleration in nickel-catalysed C-H, C-C and C-O bond cleavage		Catal. Sci. Technol.	115	Lu, G	FALSE	FALSE	FALSE	FALSE
990	10.1021/acscatal.1c01351	doi.org/10.1021/acscatal.1c01351	Chiral Carboxylic Acid Assisted Enantioselective C-H Activation with Achiral (CpMIII)-M-x (M = Co, Rh, Ir) Catalysts		ACS Catal.	115	Yoshino, T; Matsunaga, S	FALSE	FALSE	FALSE	FALSE
991	10.1039/c7cc00078b	doi.org/10.1039/c7cc00078b	Aromatic metamorphosis: conversion of an aromatic skeleton into a different ring system		Chem. Commun.	115	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
992	10.1021/acscatal.6b02988	doi.org/10.1021/acscatal.6b02988	A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis		ACS Catal.	115	Iwai, T; Sawamura, M	FALSE	FALSE	FALSE	FALSE
993	10.1021/acs.joc.6b02093	doi.org/10.1021/acs.joc.6b02093	Mechanism of Nickel-Catalyzed Selective C-N Bond Activation in Suzuki-Miyaura Cross-Coupling of Amides: A Theoretical Investigation		J. Org. Chem.	115	Zhae, YF	FALSE	FALSE	FALSE	FALSE
994	10.1007/s41061-016-0053-z	doi.org/10.1007/s41061-016-0053-z	Nickel-Catalyzed Aromatic C-H Functionalization		Top. Curr. Chem.	115	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
995	10.1021/acs.inorgchem.5b02936	doi.org/10.1021/acs.inorgchem.5b02936	A DFT-Elucidated Comparison of the Solution-Phase and SAM Electrochemical Properties of Short-Chain Mercaptoalkylferrocenes: Synthetic and Spectroscopic Aspects, and the Structure of Fc-CH2CH2-S-S-CH2CH2-Fc		Inorg. Chem.	115	Swarts, JC	FALSE	TRUE	FALSE	FALSE
996	10.1021/jacs.0c02876	doi.org/10.1021/jacs.0c02876	Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids	Examples of the palladium- and nickel-catalyzed amination of aryl fluorosulfonates with aromatic and alkyl amines are described. Aniline is coupled to a diverse series of aryl fluorosulfonates catalyzed by the combination of CpPd(cinammyl) and Xantphos, and the relative reactivity of aryl fluorosulfonates to undergo Pd-catalyzed amination was compared with other common aryl electrophiles. In addition, we report the direct amination of a phenol by in situ formation of an aryl fluorosulfonate by reaction with sulfuryl fluoride and base followed by subsequent amination to form a new C-N bond. Finally, we report examples of the nickel-catalyzed amination of aryl fluorosulfonates catalyzed by the combination of Ni(COD)(2) and DPPF in the presence of MeCN. The high reactivity of the aryl fluorosulfonate electrophile with generic palladium and nickel catalyst systems, combined with its simple preparation from sulfuryl fluoride will enable commercial amination reactions of abundant phenolic raw materials.	J. Am. Chem. Soc.	114	Qian, H; Zhang, JL; Ma, SM	FALSE	FALSE	FALSE	FALSE
997	10.1039/c9ob02328c	doi.org/10.1039/c9ob02328c	Peroxide-mediated site-specific C-H methylation of imidazo[1,2-a]pyridines and quinoxalin-2(1H)-ones under metal-free conditions		Org. Biomol. Chem.	114	Lin, S; Yan, ZH	FALSE	FALSE	FALSE	FALSE
998	10.1016/j.tet.2019.06.034	doi.org/10.1016/j.tet.2019.06.034	Nickel-mediated reductive coupling of neopentyl bromides with activated alkenes at room temperature and its synthetic application		Tetrahedron	114	Peng, Y; Li, WDZ	FALSE	FALSE	FALSE	FALSE
999	10.1002/anie.201902509	doi.org/10.1002/anie.201902509	Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis		Angew. Chem.-Int. Edit.	114	Kojima, M; Matsunaga, S	FALSE	FALSE	FALSE	FALSE
1000	10.1002/chem.201900276	doi.org/10.1002/chem.201900276	Synthetic Routes towards Multifunctional Cyclopentadienes		Chem.-Eur. J.	114	Frei, A	FALSE	FALSE	FALSE	FALSE
1001	10.1021/acs.joc.8b00583	doi.org/10.1021/acs.joc.8b00583	Asymmetric Rhodium-Catalyzed Allylic Substitution Reactions: Discovery, Development and Applications to Target-Directed Synthesis		J. Org. Chem.	114	Evans, PA	FALSE	FALSE	FALSE	FALSE
1002	10.1016/j.tetlet.2018.02.043	doi.org/10.1016/j.tetlet.2018.02.043	Metal-free S-methylation of diaryl disulfides with di-tert-butyl peroxide		Tetrahedron Lett.	114	Wu, XM	FALSE	FALSE	FALSE	FALSE
1003	10.1039/c7cy01382e	doi.org/10.1039/c7cy01382e	Mechanism and reactivity of catalytic propargylic substitution reactions via metal-allenylidene intermediates: a theoretical perspective		Catal. Sci. Technol.	114	Sakata, K	FALSE	FALSE	FALSE	FALSE
1004	10.1039/c7sc03912c	doi.org/10.1039/c7sc03912c	Ex situ generation of stoichiometric HCN and its application in the Pd-catalysed cyanation of aryl bromides: evidence for a transmetallation step between two oxidative addition Pd-complexes		Chem. Sci.	114	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
1005	10.1002/ejoc.201500263	doi.org/10.1002/ejoc.201500263	Synthesis of Diiodinated Biphenyls and Iodinated meta-Terphenyls by Regioselective Suzuki-Miyaura Cross-Coupling Reactions of 5-Substituted 1,2,3-Triiodobenzenes		Eur. J. Org. Chem.	114	Al-Zoubi, RM	FALSE	FALSE	FALSE	FALSE
1006	10.1039/c4ra07455f	doi.org/10.1039/c4ra07455f	Palladium-catalyzed desulfitative cross-coupling of arylsulfinates with arylboronic acids		RSC Adv.	114	Qi, CZ	FALSE	FALSE	FALSE	FALSE
1007	10.1021/jo302112a	doi.org/10.1021/jo302112a	Palladium-Catalyzed Sonogashira-Coupling Conjoined C-H Activation: A Regioselective Tandem Strategy to Access Indolo- and Pyrrolo[1,2-a]quinolines		J. Org. Chem.	114	Verma, AK	FALSE	FALSE	FALSE	FALSE
1008	10.1016/j.tetlet.2009.07.100	doi.org/10.1016/j.tetlet.2009.07.100	Bromodimethylsulfonium bromide (BDMS): a useful reagent for conversion of aldoximes and primary amides to nitriles		Tetrahedron Lett.	114	Yadav, LDS	FALSE	FALSE	FALSE	FALSE
1009	10.1021/acs.joc.1c00260	doi.org/10.1021/acs.joc.1c00260	Practical Electro-Oxidative Sulfonylation of Phenols with Sodium Arenesulfinates Generating Arylsulfonate Esters		J. Org. Chem.	114	Chen, TQ	FALSE	TRUE	FALSE	FALSE
1010	10.1039/c6nj02887j	doi.org/10.1039/c6nj02887j	Computational study on C-B homolytic bond dissociation enthalpies of organoboron compounds		New J. Chem.	114	Zheng, WR	FALSE	FALSE	FALSE	FALSE
1011	10.1021/acs.orglett.0c03507	doi.org/10.1021/acs.orglett.0c03507	Catalytic C(sp(2))-C(sp(3)) Bond Formation of Methoxyarenes by the Organic Superbase t-Bu-P4	The asymmetric ring opening reactions of bicyclic alkenes with boronic acids were accomplished by using a highly active palladium/zinc co-catalytic system that was suitable for both azabenzonorbornadienes and oxabenzonorbornadienes, which were transformed to the corresponding chiral hydronaphthalene products in high yields (up to 99%) and high optical purifies (up to 98% ee). The reaction protocol is general and mild and displays good functional group tolerance.	Org. Lett.	113	Shigeno, M; Kondo, Y	FALSE	FALSE	FALSE	FALSE
1012	10.1021/acs.orglett.0c02609	doi.org/10.1021/acs.orglett.0c02609	C-F Activation for C(sp(2))-C(sp(3)) Cross-Coupling by a Secondary Phosphine Oxide (SPO)-Nickel Complex	Treatment of benzofurans with bis(pinacolato)diboron and Cs2CO3 under nickel-NHC catalysis resulted in the insertion of a boron atom into the C-2-O bond of benzofurans to afford the corresponding oxaborins. The scope of benzofuran substrates is wide, and the reactions proceeded without loss of functional groups such as fluoro, methoxy, and ester that are potentially reactive under nickel catalysis. The boron inserted products proved to be useful building blocks and subsequently underwent a series of transformations, one of which led to the synthesis of fluorescent pi-expanded oxaborins.	Org. Lett.	113	Ackermann, L	FALSE	FALSE	FALSE	FALSE
1013	10.1002/ejoc.202000966	doi.org/10.1002/ejoc.202000966	Shining Light on Ti(IV)Complexes: Exceptional Tools for Metallaphotoredox Catalysis	We have developed a nickel-catalyzed cross-coupling reaction of cyclic alkenyl ethers with arylboronic esters that leads to the formation of unsaturated alcohols via ring-opening by the cleavage of a C(sp(2))-O bond. The use of 1,3-dicyclohexylimidazol-2-ylidene as the ligand is essential to promote this cross-coupling process.	Eur. J. Org. Chem.	113	Fermi, A; Gualandi, A; Bergamini, G	FALSE	FALSE	FALSE	FALSE
1014	10.6023/cjoc202002038	doi.org/10.6023/cjoc202002038	Recent Advances in Transition-Metal Catalyzed Defunctionalization Reaction	Nickel or iron salts catalyzing the selective synthesis of 3,3-indolyl disulfide (diselenide) and 3,3-indolyl thioether (selenide) directly from indole through C-H activation are reported. The effect of iodine element was beneficial in the novel metal-catalyzed circulation system. A wide variety of functional groups could be tolerated under the reaction conditions.	Chin. J. Org. Chem.	113	Jin, WW; Liu, CJ	FALSE	FALSE	FALSE	FALSE
1015	10.1002/anie.201913367	doi.org/10.1002/anie.201913367	Enantioselective Difunctionalization of Alkenes by a Palladium-Catalyzed Heck/Sonogashira Sequence		Angew. Chem.-Int. Edit.	113	Zhang, ZM; Zhang, JL	FALSE	FALSE	FALSE	FALSE
1016	10.1039/c9gc02694k	doi.org/10.1039/c9gc02694k	Amine-catalyzed and functional group-controlled chemo- and regioselective synthesis of multi-functionalized CF3-benzene via a metal-free process		Green Chem.	113	He, G	FALSE	FALSE	FALSE	FALSE
1017	10.1021/acs.orglett.9b02308	doi.org/10.1021/acs.orglett.9b02308	CuH-Catalyzed Asymmetric 1,6-Conjugate Reduction of p-Quinone Methides: Enantioselective Synthesis of Triarylmethanes and 1,1,2-Triarylethanes		Org. Lett.	113	Chu, WD; Liu, QZ	FALSE	FALSE	FALSE	FALSE
1018	10.1016/j.chempr.2019.01.006	doi.org/10.1016/j.chempr.2019.01.006	Recent Advances in the Catalytic Synthesis of 4-Quinolones		Chem	113	Zhang, PF	FALSE	FALSE	FALSE	FALSE
1019	10.1002/adsc.201801661	doi.org/10.1002/adsc.201801661	Direct C(sp(2))-H Amination to Synthesize Primary 3-aminoquinoxalin-2(1H)-ones under Simple and Mild Conditions		Adv. Synth. Catal.	113	Zhang, HY; Zhang, YC	FALSE	FALSE	FALSE	FALSE
1020	10.3390/catal8010023	doi.org/10.3390/catal8010023	Pd-Catalyzed Mizoroki-Heck Reactions Using Fluorine-Containing Agents as the Cross-Coupling Partners		Catalysts	113	Zhao, HW; Zhang, CP	FALSE	FALSE	FALSE	FALSE
1021	10.1055/s-0036-1590985	doi.org/10.1055/s-0036-1590985	Chemoselective Ruthenium-Catalyzed C-O Bond Activation: Orthogonality of Nickel- and Palladium-Catalyzed Reactions for the Synthesis of Polyaryl Fluorenones		Synlett	113	Snieckus, V	FALSE	FALSE	FALSE	FALSE
1022	10.1021/acscatal.5b00026	doi.org/10.1021/acscatal.5b00026	Catalytic Synthesis of 2H-Chromenes		ACS Catal.	113	de Bruin, B	FALSE	FALSE	FALSE	FALSE
1023	10.1021/acscatal.5b00072	doi.org/10.1021/acscatal.5b00072	Nickel: The Spirited Horse of Transition Metal Catalysis		ACS Catal.	113	Ananikov, VP	FALSE	FALSE	FALSE	FALSE
1024	10.1039/c4ra09450f	doi.org/10.1039/c4ra09450f	Selective approach to thioesters and thioethers via sp(3) C-H activation of methylarenes		RSC Adv.	113	Cai, C	FALSE	FALSE	FALSE	FALSE
1025	10.1021/om400711d	doi.org/10.1021/om400711d	Bis(diisopropylphosphinomethyl)amine Nickel(II) and Nickel(0) Complexes: Coordination Chemistry, Reactivity, and Catalytic Decarbonylative C-H Arylation of Benzoxazole		Organometallics	113	Gade, LH	FALSE	FALSE	FALSE	FALSE
1026	10.1021/ol400444g	doi.org/10.1021/ol400444g	Indoles Synthesized from Amines via Copper Catalysis		Org. Lett.	113	May, JA	FALSE	FALSE	FALSE	FALSE
1027	10.1021/ja806545e	doi.org/10.1021/ja806545e	Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes		J. Am. Chem. Soc.	113	Whittlesey, MK	FALSE	FALSE	FALSE	FALSE
1028	10.1021/om0608004	doi.org/10.1021/om0608004	Rhodium-catalyzed hydroallylation of activated alkenes		Organometallics	113	Matsuda, I	FALSE	FALSE	FALSE	FALSE
1029	10.1021/cr020027w	doi.org/10.1021/cr020027w	Asymmetric transition-metal-catalyzed allylic alkylations: Applications in total synthesis		Chem. Rev.	113	Trost, BM	FALSE	FALSE	FALSE	FALSE
1030	10.1021/jo961464b	doi.org/10.1021/jo961464b	Nickel- and palladium-catalyzed homocoupling of aryl triflates. Scope, limitation, and mechanistic aspects		J. Org. Chem.	113	Jutand, A	FALSE	FALSE	FALSE	FALSE
1031	10.1039/d1sc03865f	doi.org/10.1039/d1sc03865f	Cu(i) catalysis for selective condensation/bicycloaromatization of two different arylalkynes: direct and general construction of functionalized C-N axial biaryl compounds		Chem. Sci.	113	Zhou, YB	FALSE	FALSE	FALSE	FALSE
1032	10.1016/j.tet.2021.132564	doi.org/10.1016/j.tet.2021.132564	Cross-coupling reaction of organoalane reagents with 2-mercaptobenzo-5-membered heterocycles for efficient synthesis of benzo-5-membered heterocycle sulfides		Tetrahedron	113	Li, QH	FALSE	FALSE	FALSE	FALSE
1033	10.1002/ejoc.202100642	doi.org/10.1002/ejoc.202100642	Nickel-Catalyzed Asymmetric Hydrogenation of Hydrazones		Eur. J. Org. Chem.	113	Zhang, WB	FALSE	FALSE	FALSE	FALSE
1034	10.3389/fchem.2021.613633	doi.org/10.3389/fchem.2021.613633	Highly Diastereoselective Construction of Carbon- Heteroatom Quaternary Stereogenic Centers in the Synthesis of Analogs of Bioactive Compounds: From Monofluorinated Epoxyalkylphosphonates to alpha-Fluoro-, beta-, or gamma-Amino Alcohol Derivatives of Alkylphosphonates		Front. Chem.	113	Rapp, M	FALSE	FALSE	FALSE	FALSE
1035	10.1002/anie.201609654	doi.org/10.1002/anie.201609654	Iridium-Catalyzed Intermolecular Asymmetric Dearomatization of beta-Naphthols with Allyl Alcohols or Allyl Ethers		Angew. Chem.-Int. Edit.	113	You, SL	FALSE	FALSE	FALSE	FALSE
1036	10.1021/acs.organomet.6b00723	doi.org/10.1021/acs.organomet.6b00723	Pd-PEPPSI Complexes Bearing Bulky [(1,2-Di-(tert-butyl)acenaphthyl] (DtBu-An) on N-Heterocarbene Backbones: Highly Efficient for Suzuki-Miyaura Cross-Coupling under Aerobic Conditions		Organometallics	113	Liu, FS	FALSE	FALSE	FALSE	FALSE
1037	10.1002/chem.201600865	doi.org/10.1002/chem.201600865	Catalyst-Free Three-Component Tandem CDC Cyclization: Convenient Access to Isoindolinones from Aromatic Acid, Amides, and DMSO by a Pummerer-Type Rearrangement		Chem.-Eur. J.	113	Shi, XY	FALSE	FALSE	FALSE	FALSE
1038	10.1016/j.tetlet.2021.152862	doi.org/10.1016/j.tetlet.2021.152862	Enantioselective synthesis of hetero-triarylmethanes by chiral phosphoric acid-catalyzed 1,4-addition of 3-substituted indoles with azadienes	Cu(II)-catalyzed C-H functionalization for the synthesis of O-arylcarbamates in a model pincer-like arene substrate using CO2 gas as C1-synthon is shown to proceed via aryl-Cu(III) intermediate species at room temperature. Indeed, stoichiometric experiments have been performed starting from an isolated Cu(III) complex and carbamic ammonium salts. A catalytic version has been then developed using a model arene substrate and a Cu(II) salt through C-H activation. Finally, effective Cu(II)-catalyzed C-H functionalization was achieved by in situ generation of carbamates from amines and CO2 gas. (C) 2017 Elsevier B.V. All rights reserved.	Tetrahedron Lett.	112	Liao, LH	FALSE	FALSE	FALSE	FALSE
1039	10.1007/s11426-020-9910-2	doi.org/10.1007/s11426-020-9910-2	Recent advances in the synthesis of 1,1-diarylalkanes by transition-metal catalysis	Thermal reactions of quinolyl-substituted thiophenes (2-(8'-quinolyl)thiophene (QT), 2-methy1-5-(8'-quinolyl)thiophene (MeQT), 2-(8'-quinolyl)-5(trimethylsily)thiophene (TMSQT)) with [Fe-3(CO)(12)] gave the corresponding thiolate-bridged diiron complexes [Fe-2(mu-L-R)(CO)(5)] (R = H, Me, SiMe3), where L-H, L-Me, and L-TMS are dianionic N,C,S-tridentate ligands (SC(R)CHCHC(Q)(2-), Q=8-quinolyl) formed by the oxidative addition of the C-S bond in QT, MeQT, and TMSQT, respectively. In contrast, the formation of photoreaction products of the quinolyl-substituted thiophenes with [Fe(CO)(5)] was dependent on the R group of the thiophene ring. The photoreaction of QT gave the sulfur-free diiron complex [Fe-2{CHCHCHC(Q)}(CO)(5)], whereas the photoreactions of MeQT and TMSQT gave the thiolate-bridged triiron complex [Fe-3(mu-L-R)(CO)(8)] and diiron complex [Fe-2(mu-L-TMS)(CO)(5)], respectively, as the major products. In the triiron complexes [Fe-3(mu-L-R)(CO)(8)], an Fe(CO)(3) unit is bound to the C(R)CHCH moiety in the S-metallacycle of the diiron complexes [Fe-2(mu-L-R)(CO)(5)]. The difference in the photoreaction products is described on the basis of the reactivity of the thiolate complexes [Fe-2(mu-L-R)(CO)(5)] and [Fe-3(mu-L-R)(CO)(8)]. Although the photoreactions of the diiron complexes [Fe-2(mu-L-R)(CO)(5)] with [Fe(CO)(5)] produced the corresponding triiron complexes [Fe-3(mu-L-R)(CO)(8)], desulfurization leading to the formation of [Fe-2{CHCHCHC(Q)}(CO)(5)] was predominant for R = H, and a fast conversion of the triiron complex to a CO elimination product was observed for R = SiMe3.	Sci. China-Chem.	112	Yin, GY	FALSE	FALSE	FALSE	FALSE
1040	10.1002/anie.202012048	doi.org/10.1002/anie.202012048	Reductive Arylation of Amides via a Nickel-Catalyzed Suzuki-Miyaura-Coupling and Transfer-Hydrogenation Cascade	Asymmetric transfer hydrogenation of oxabenzonorbornadienes was realized by using alcohols as hydrogen sources under a co-catalytic system of palladium and zinc. Both primary and secondary alcohols could serve as reductants and afforded enantiomerically enriched 1,2-dihydronaphth-1-ol products with high optical purities.	Angew. Chem.-Int. Edit.	112	Garg, NK	FALSE	FALSE	FALSE	FALSE
1041	10.1021/acscatal.0c01842	doi.org/10.1021/acscatal.0c01842	Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions	The recent years have witnessed the development of metal-catalyzed reductive carboxylation of organic (pseudo)halides with CO2 as C1 source, representing potential powerful alternatives to existing methodologies for preparing carboxylic acids, privileged motifs in a myriad of pharmaceuticals and molecules displaying significant biological properties. While originally visualized as exotic cross-coupling reactions, a close look into the literature data indicates that these processes have become a fertile ground, allowing for the utilization of a variety of coupling partners, even with particularly challenging substrate combinations. As for other related cross-electrophile scenarios, the vast majority of reductive carboxylation of organic (pseudo)halides are characterized by their simplicity, mild conditions, and a broad functional group compatibility, suggesting that these processes could be implemented in late-stage diversification. This perspective describes the evolution of metal-catalyzed reductive carboxylation of organic (pseudo)halides from its inception in the pioneering stoichiometric work of Osakada to the present. Specific emphasis is devoted to the reactivity of these coupling processes, with substrates ranging from aryl-, vinyl-, benzyl- to unactivated alkyl (pseudo)halides. Despite the impressive advances realized, a comprehensive study detailing the mechanistic intricacies of these processes is still lacking. Some recent empirical evidence reveal an intriguing dichotomy exerted by the substitution pattern on the ligands utilized; still, however, some elementary steps within the catalytic cycle of these reactions remain speculative, in many instances invoking a canonical cross-coupling process. Although tentative, we anticipate that these processes might fall into more than one distinct mechanistic category depending on the substrate utilized, suggesting that investigations aimed at unraveling the mechanistic underpinnings of these processes will likely bring new and innovative research grounds in this vibrant area of expertise.	ACS Catal.	112	Reisman, SE	FALSE	FALSE	FALSE	FALSE
1042	10.1039/d0qo00282h	doi.org/10.1039/d0qo00282h	Access to cyano-substituted pyrazolines through copper-catalyzed cascade cyanation/cyclization of unactivated olefins	Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpensive and nontoxic bismuth salts. Triarylbismuthines are particularly interesting due to their air and moisture stability and high functional group tolerance. We report herein a detailed study on the preparation of highly functionalized triarylbismuth reagents by triple functional group manipulation and their use in palladium- and copper-catalyzed C-, N-, and O-arylation reactions.	Org. Chem. Front.	112	Zhang, HL; Zhu, YG	FALSE	FALSE	FALSE	FALSE
1043	10.1002/anie.202002271	doi.org/10.1002/anie.202002271	Nickel-Catalyzed Synthesis of Dialkyl Ketones from the Coupling of N-Alkyl Pyridinium Salts with Activated Carboxylic Acids	The use of electron-poor, fluoro-containing arylboronic acids as general coupling partners for nickel(0)/tricyclohexylphosphine-catalyzed cross-coupling of aryl arenesulfonates is described. Electron-poor fluoro-containing arylboronic acids were found to react faster than electron-rich/neutral arylboronic acids, with (4-methoxyphenyl)(4-methylbenzenesulfonato-O)bis(tricyclohexylphosphine)nickel. Bis(1,5-cyclooctadiene)nickel(0)/tricyclohexylphosphine, (4-methoxyphenyl)(4-methylbenzenesulfonato-O)bis(tricyclohexylphosphine)nickel and bis(tricyclohexylphosphine)nickel(II) bromide were all found to be efficient catalysts/catalyst precursors.	Angew. Chem.-Int. Edit.	112	Weix, DJ	FALSE	FALSE	FALSE	FALSE
1044	10.1021/acs.organomet.9b00834	doi.org/10.1021/acs.organomet.9b00834	[(dcpp)Ni(eta(2)-Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki-Miyaura Reaction	A range of chiral quinazolinol ligands were efficiently synthesized and subsequently investigated for catalytic chiral induction in both the asymmetric phenylation of aryl aldehydes and the asymmetric epoxidation of chalcones. Encouragingly, high enantioselectivities (up to 95%) and yields (up to 98%) were achieved under the optimized reaction conditions.	Organometallics	112	Mezailles, N	FALSE	FALSE	FALSE	FALSE
1045	10.1002/anie.202000016	doi.org/10.1002/anie.202000016	Asymmetric Electrochemical Transformations	Vinyl boronic esters were synthesized from aryl alkynyl carboxylic acids and bis(pinacolato)diboron using a copper-catalyzed decarboxylative reaction. The reaction was conducted with CuI (10 mol%), bis-[2-(diphenylphosphino)phenyl]ether(20 mol%), and LiOMe (20 mol%) in DMSO at 50 degrees C for 16 h. This method provided the desired vinyl boronic esters in good-to-moderate yields and showed good functional group tolerance.	Angew. Chem.-Int. Edit.	112	Guo, C	FALSE	TRUE	FALSE	FALSE
1046	10.1039/d0ob00244e	doi.org/10.1039/d0ob00244e	Room temperature nickel-catalyzed cross-coupling of aryl-boronic acids with thiophenols: synthesis of diarylsulfides	A novel method for the mild photoredox-mediated tandem radical acylarylation and tandem acylation/semipinacol rearrangement has been developed. The synthesis of highly functionalized ketones bearing all-carbon - or -quaternary centers has been achieved using easily available symmetric aromatic carboxylic anhydrides as the acyl radical source. The method allows for a straightforward introduction of the keto functionality and concomitant construction of molecular complexity in a single operation.	Org. Biomol. Chem.	112	Fernandes, RA	FALSE	FALSE	FALSE	FALSE
1047	10.1002/chem.201904987	doi.org/10.1002/chem.201904987	One-Pot Generation of Benzynes from Phenols: Formation of Primary Anilines by the Deoxyamination of Phenols	The catalytic feasibility of [PNP]PdCl, where [PNP](-) = bis(2-diphenylphosphinophenyl)amide, on biaryl syntheses from Suzuki-type cross-coupling reactions is demonstrated. A number of electronically activated, unactivated, and deactivated (hetero)aryl bromides and iodides is viable to react with arylboronic acids. Of particular note of this catalysis is its success in the high yield production of sterically encumbered tri-ortho-substituted biaryls and its operative compatibility under aerobic conditions in aqueous solutions. (C) 2015 Elsevier B.V. All rights reserved.	Chem.-Eur. J.	112	Ikawa, T; Akai, S	FALSE	FALSE	FALSE	FALSE
1048	10.1002/ejoc.201901865	doi.org/10.1002/ejoc.201901865	Palladium-Catalyzed Direct Decarbonylative Phosphorylation of Benzoic Acids with P(O)-H Compounds		Eur. J. Org. Chem.	112	Chen, TQ	FALSE	FALSE	FALSE	FALSE
1049	10.1021/jacs.9b10771	doi.org/10.1021/jacs.9b10771	Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization		J. Am. Chem. Soc.	112	Minteer, SD; Sigman, MS	FALSE	TRUE	FALSE	FALSE
1050	10.1002/slct.201902860	doi.org/10.1002/slct.201902860	Copper-Mediated Decarboxylative C-H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary		ChemistrySelect	112	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
1051	10.1002/ijch.201900072	doi.org/10.1002/ijch.201900072	Tackling Remote sp(3) C-H Functionalization via Ni-Catalyzed chain-walking Reactions		Isr. J. Chem.	112	Martin, R	FALSE	FALSE	FALSE	FALSE
1052	10.1002/adsc.201801496	doi.org/10.1002/adsc.201801496	Rhodium(III)-Catalyzed Direct C7 Allylation of Indolines via Sequential C-H and C-C Activation		Adv. Synth. Catal.	112	Zhu, X; Song, MP	FALSE	FALSE	FALSE	FALSE
1053	10.1021/acs.joc.8b02567	doi.org/10.1021/acs.joc.8b02567	Base-Promoted Amidation and Esterification of Imidazolium Salts via Acyl C-C bond Cleavage: Access to Aromatic Amides and Esters		J. Org. Chem.	112	Gandhi, T	FALSE	FALSE	FALSE	FALSE
1054	10.1002/tcr.201800045	doi.org/10.1002/tcr.201800045	My Twenty Years in Microwave Chemistry: From Kitchen Ovens to Microwaves that aren't Microwaves		Chem. Rec.	112	Kappe, CO	FALSE	FALSE	FALSE	FALSE
1055	10.1021/acs.orglett.8b01382	doi.org/10.1021/acs.orglett.8b01382	Merging Anti-Baldwin 3-Exo-Dig Cyclization with 1,2-Alkynyl Migration for Radical Alkylalkynylation of Unactivated Olefins		Org. Lett.	112	Hao, WJ; Tu, SJ; Jiang, B	FALSE	FALSE	FALSE	FALSE
1056	10.1002/ijch.201000031	doi.org/10.1002/ijch.201000031	2-Pyridyl Tosylate Derivatives-Building Blocks for Structural Diversity via Transition Metal Catalysis		Isr. J. Chem.	112	Lindhardt, AT	FALSE	FALSE	FALSE	FALSE
1057	10.1002/ejoc.200801004	doi.org/10.1002/ejoc.200801004	Phosphonium Coupling in the Direct Bond Formations of Tautomerizable Heterocycles via C-OH Bond Activation		Eur. J. Org. Chem.	112	Kang, FA	FALSE	FALSE	FALSE	FALSE
1058	10.1002/chem.200701418	doi.org/10.1002/chem.200701418	Insights into Sonogashira cross-coupling by high-throughput kinetics and descriptor modeling		Chem.-Eur. J.	112	Plenio, H	FALSE	FALSE	FALSE	FALSE
1059	10.1021/ja035293l	doi.org/10.1021/ja035293l	Palladium-catalyzed asymmetric arylation, vinylation, and allenylation of tert-cyclobutanois via enantioselective C-C bond cleavage		J. Am. Chem. Soc.	112	Uemura, S	FALSE	FALSE	FALSE	FALSE
1060	10.1021/ja981560p	doi.org/10.1021/ja981560p	Iridium complex-catalyzed allylic alkylation of allylic esters and allylic alcohols: Unique regio- and stereoselectivity		J. Am. Chem. Soc.	112	Takeuchi, R	FALSE	FALSE	FALSE	FALSE
1061	10.1002/ajoc.202100310	doi.org/10.1002/ajoc.202100310	Unsymmetrical Pyrazoly-Pyridinyl-Triazole Promoted High Active Copper Composites on Mesoporous Materials and Catalytic Applications		Asian J. Org. Chem.	112	Wang, DW	FALSE	FALSE	FALSE	FALSE
1062	10.1002/tcr.202100117	doi.org/10.1002/tcr.202100117	Regio- and Stereoselective Functionalization Enabled by Bidentate Directing Groups		Chem. Rec.	112	Hong, S	FALSE	FALSE	FALSE	FALSE
1063	10.1002/ajoc.201700218	doi.org/10.1002/ajoc.201700218	Efficient Bronsted-Acid-Catalyzed Deuteration of Arenes and Their Transformation to Functionalized Deuterated Products		Asian J. Org. Chem.	112	Duttwyler, S	FALSE	FALSE	FALSE	FALSE
1064	10.1002/chem.201605476	doi.org/10.1002/chem.201605476	Fe-Catalyzed Amination of (Hetero)Arenes with a Redox-Active Aminating Reagent under Mild Conditions		Chem.-Eur. J.	112	Jiao, N	FALSE	FALSE	FALSE	FALSE
1065	10.1002/chem.201602683	doi.org/10.1002/chem.201602683	Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand		Chem.-Eur. J.	112	Mulvey, RE	FALSE	FALSE	FALSE	FALSE
1066	10.1055/s-0035-1562784	doi.org/10.1055/s-0035-1562784	Introduction of Functionalized Difluoromethylated Building Blocks Mediated or Catalyzed by Copper		Synlett	112	Poisson, T	FALSE	FALSE	FALSE	FALSE
1067	10.1002/ejoc.201501559	doi.org/10.1002/ejoc.201501559	Indium-Catalyzed Reductive Sulfidation of Esters by Using Thiols: An Approach to the Diverse Synthesis of Sulfides		Eur. J. Org. Chem.	112	Sakai, N	FALSE	FALSE	FALSE	FALSE
1068	10.1021/acs.orglett.0c04039	doi.org/10.1021/acs.orglett.0c04039	Interrupting the Barton-McCombie Reaction: Aqueous Deoxygenative Trifluoromethylation of O-Alkyl Thiocarbonates	The direct asymmetric copper hydride (CuH)-catalyzed coupling of alpha,beta-unsaturated carboxylic acids to aryl alkenes to access chiral alpha-aryl dialkyl ketones is reported. A variety of substrate substitution patterns, sensitive functional groups, and heterocycles are tolerated in this reaction, which significantly expands the range of accessible products compared with existing hydroacylation methodology. Although mechanistic studies are ongoing, we propose that CuH-catalyzed silylation of unsaturated acids occurs to access a uniquely effective acyl electrophilic coupling partner.	Org. Lett.	111	Cook, SP	FALSE	FALSE	FALSE	FALSE
1069	10.6023/cjoc202005008	doi.org/10.6023/cjoc202005008	Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions via Synergetic Catalysis	Caprazamycins are the lead compound for CPZEN-45, which exhibits activity against extensively drug resistant tuberculosis (XDR-TB) and is currently under preclinical studies. The development of an efficient synthetic route to caprazamycins and related compounds is expected to facilitate structure-activity relationship studies on anti-TB agents. This review summarizes current synthetic strategies for caprazamycins, liposidomycins, caprazol, and CPZEN-45, with a particular focus on stereocontrol and diazepanone ring formation.	Chin. J. Org. Chem.	111	Yang, WL; Deng, WP	FALSE	FALSE	FALSE	FALSE
1070	10.1002/ejoc.201901877	doi.org/10.1002/ejoc.201901877	Direct Stereoselective beta-Arylation of Enol Ethers by a Decarboxylative Heck-Type Reaction	In the presence of catalytic amounts of platinum(II) chloride and silver(I) hexafluoroantimonate, (Z)-alkenylsilanes reacted with various carbon electrophiles (acetals, aminals, carboxylic anhydrides, alkyl chlorides, etc.) at the -position to give allylation products. A plausible mechanism for the platinum-catalyzed allylation involves alkene migration of alkenylsilanes to allylsilanes and subsequent allylation of carbon electrophiles, both of which are catalyzed by a cationic platinum(II) species.	Eur. J. Org. Chem.	111	Schneider, C; Hoarau, C	FALSE	FALSE	FALSE	FALSE
1071	10.1002/ejoc.201801888	doi.org/10.1002/ejoc.201801888	Construction of Di(hetero)arylmethanes Through Pd-Catalyzed Direct Dehydroxylative Cross-Coupling of Benzylic Alcohols and Aryl Boronic Acids Mediated by Sulfuryl Fluoride (SO2F2)		Eur. J. Org. Chem.	111	Qin, HL	FALSE	FALSE	FALSE	FALSE
1072	10.1002/cctc.201801625	doi.org/10.1002/cctc.201801625	Recent Progress in Transition Metal-Catalyzed Regioselective Functionalization of Unactivated Alkenes/Alkynes Assisted by Bidentate Directing Groups		ChemCatChem	111	Lin, C	FALSE	FALSE	FALSE	FALSE
1073	10.1021/acscentsci.8b00628	doi.org/10.1021/acscentsci.8b00628	Acyl Glycosides through Stereospecific Glycosyl Cross-Coupling: Rapid Access to C(sp(3))-Linked Glycomimetics		ACS Central Sci.	111	Walczak, MA	FALSE	FALSE	FALSE	FALSE
1074	10.1002/ajoc.201800094	doi.org/10.1002/ajoc.201800094	Applications of Pybox Complexes in Asymmetric Catalysis		Asian J. Org. Chem.	111	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
1075	10.1039/c5cy02235e	doi.org/10.1039/c5cy02235e	Recent developments in low-cost TM-catalyzed Heck-type reactions (TM = transition metal, Ni, Co, Cu, and Fe)		Catal. Sci. Technol.	111	Yang, GY	FALSE	FALSE	FALSE	FALSE
1076	10.1021/acs.joc.5b01005	doi.org/10.1021/acs.joc.5b01005	Generating Active L-Pd(0) via Neutral or Cationic pi-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines: Synthetic, Mechanistic, and Structure Activity Studies in Challenging Cross-Coupling Reactions		J. Org. Chem.	111	Colacot, TJ	FALSE	FALSE	FALSE	FALSE
1077	10.1002/ajoc.201500062	doi.org/10.1002/ajoc.201500062	Unimolecular 4-Hydroxypiperidines: New Ligands for Copper-Catalyzed N-Arylation		Asian J. Org. Chem.	111	Fernandes, RA	FALSE	FALSE	FALSE	FALSE
1078	10.1039/c5ra01363a	doi.org/10.1039/c5ra01363a	Pd-catalyzed desulfitative and denitrogenative Suzuki-type reaction of arylsulfonyl hydrazides		RSC Adv.	111	Dou, S	FALSE	FALSE	FALSE	FALSE
1079	10.1021/om500484q	doi.org/10.1021/om500484q	Nickel(II) Benzimidazolin-2-ylidene Complexes with Thioether-Functionalized Side Chains as Catalysts for Suzuki-Miyaura Cross-Coupling		Organometallics	111	Huynh, HV	FALSE	FALSE	FALSE	FALSE
1080	10.1039/c3sc52929k	doi.org/10.1039/c3sc52929k	Bimetatlic catalysis in the highly enantioselective ring-opening reactions of aziridines		Chem. Sci.	111	Parquette, JR	FALSE	FALSE	FALSE	FALSE
1081	10.1007/128_2013_494	doi.org/10.1007/128_2013_494	Catalytic C-CN Bond Activation		Top. Curr. Chem.	111	Nakao, Y	FALSE	FALSE	FALSE	FALSE
1082	10.1016/j.tet.2013.05.060	doi.org/10.1016/j.tet.2013.05.060	Template-induced macrocycle diversity through large ring-forming alkylations of tryptophan		Tetrahedron	111	Harran, PG	FALSE	FALSE	FALSE	FALSE
1083	10.1002/chem.201202798	doi.org/10.1002/chem.201202798	Palladium- and Nickel-Catalyzed Alkenylation of Enolates		Chem.-Eur. J.	111	Helquist, P	FALSE	FALSE	FALSE	FALSE
1084	10.1021/om201101g	doi.org/10.1021/om201101g	Synthesis and Catalytic Activity in Suzuki Coup Ding of Nickel Complexes Bearing n-Butyl- and Triethoxysilylpropyl-Substituted NHC Ligands: Toward the Heterogenization of Molecular Catalysts		Organometallics	111	Ritleng, V	FALSE	FALSE	FALSE	FALSE
1085	10.1021/om100302g	doi.org/10.1021/om100302g	Iridium Complexes of CCC-Pincer N-Heterocyclic Carbene Ligands: Synthesis and Catalytic C-H Functionalization		Organometallics	111	Chianese, AR	FALSE	FALSE	FALSE	FALSE
1086	10.1055/s-0029-1217032	doi.org/10.1055/s-0029-1217032	Palladium-Catalyzed Cross-Coupling Reaction of AlArEt2(THF) with Aryl Bromides		Synthesis	111	Gau, HM	FALSE	FALSE	FALSE	FALSE
1087	10.1021/jo0620359	doi.org/10.1021/jo0620359	Directed ortho metalation-boronation and Suzuki-Miyaura cross coupling of pyridine derivatives: A one-pot protocol to substituted azabiaryls		J. Org. Chem.	111	Snieckus, V	FALSE	FALSE	FALSE	FALSE
1088	10.1039/d1sc05605k	doi.org/10.1039/d1sc05605k	DFT insight into asymmetric alkyl-alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefins		Chem. Sci.	111	Chen, XY; Wang, ZX	FALSE	FALSE	FALSE	FALSE
1089	10.1055/s-0041-1737882	doi.org/10.1055/s-0041-1737882	Biaryl Coupling of Aryldiazonium Salts and Arylboronic Acids Catalysed by Gold		Synthesis	111	Porcel, IMMS	FALSE	FALSE	FALSE	FALSE
1090	10.1021/acscatal.1c05338	doi.org/10.1021/acscatal.1c05338	Metal-Catalyzed One-Pot On-DNA Syntheses of Diarylmethane and Thioether Derivatives		ACS Catal.	111	Xu, HT; Yang, G	FALSE	FALSE	FALSE	FALSE
1091	10.1007/s11244-021-01527-9	doi.org/10.1007/s11244-021-01527-9	Role of Additives in Transition Metal Catalyzed C-H Bond Activation Reactions: A Computational Perspective		Top. Catal.	111	Sunoj, RB	FALSE	FALSE	FALSE	FALSE
1092	10.1002/anie.202105354	doi.org/10.1002/anie.202105354	Light-Driven Carbene Catalysis for the Synthesis of Aliphatic and alpha-Amino Ketones		Angew. Chem.-Int. Edit.	111	Scheidt, KA	FALSE	FALSE	FALSE	FALSE
1093	10.1002/adsc.202100596	doi.org/10.1002/adsc.202100596	Rh(I)-Catalyzed Direct C6-H Arylation of 2-Pyridones with Aryl Carboxylic Acids		Adv. Synth. Catal.	111	Xu, LJ	FALSE	FALSE	FALSE	FALSE
1094	10.1002/anie.202103465	doi.org/10.1002/anie.202103465	Rhenium-Catalyzed Arylation-Acyl Cyclization between Enol Lactones and Organomagnesium Halides: Facile Synthesis of Indenones		Angew. Chem.-Int. Edit.	111	Li, J	FALSE	FALSE	FALSE	FALSE
1095	10.1039/d0cc08389e	doi.org/10.1039/d0cc08389e	Cross-coupling reactions with esters, aldehydes, and alcohols		Chem. Commun.	111	Newman, SG	FALSE	FALSE	FALSE	FALSE
1096	10.1021/acscatal.6b01956	doi.org/10.1021/acscatal.6b01956	Nickel-Catalyzed Decarbonylative Borylation and Silylation of Esters		ACS Catal.	111	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
1097	10.1002/chem.201503926	doi.org/10.1002/chem.201503926	Direct Carboxylation of Aryl Tosylates by CO2 Catalyzed by In situ-Generated Ni-0		Chem.-Eur. J.	111	Durandetti, M	FALSE	FALSE	FALSE	FALSE
1098	10.1002/chem.201904842	doi.org/10.1002/chem.201904842	Hydride Transfer Enables the Nickel-Catalyzed ipso-Borylation and Silylation of Aldehydes		Chem.-Eur. J.	110	Rueping, M	FALSE	FALSE	FALSE	FALSE
1099	10.1021/acscatal.9b00566	doi.org/10.1021/acscatal.9b00566	Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies		ACS Catal.	110	Hazari, N	FALSE	FALSE	FALSE	FALSE
1100	10.1021/acs.inorgchem.8b02877	doi.org/10.1021/acs.inorgchem.8b02877	Iron-Catalyzed/Mediated C-N Bond Formation: Competition between Substrate Amination and Ligand Amination		Inorg. Chem.	110	Paul, ND	FALSE	FALSE	FALSE	FALSE
1101	10.1016/j.tetlet.2018.11.071	doi.org/10.1016/j.tetlet.2018.11.071	Cu-catalyzed direct ortho-chlorination/-oxygenation of aryls: Switching of oxidant, control the diversity of products		Tetrahedron Lett.	110	Malapaka, C	FALSE	FALSE	FALSE	FALSE
1102	10.1002/anie.201811139	doi.org/10.1002/anie.201811139	Palladium-Catalyzed Decarbonylative Difluoromethylation of Acid Chlorides at Room Temperature		Angew. Chem.-Int. Edit.	110	Ritter, T	FALSE	FALSE	FALSE	FALSE
1103	10.1021/jacs.7b09541	doi.org/10.1021/jacs.7b09541	Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates		J. Am. Chem. Soc.	110	Movassaghi, M	FALSE	FALSE	FALSE	FALSE
1104	10.1002/anie.201411402	doi.org/10.1002/anie.201411402	Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones		Angew. Chem.-Int. Edit.	110	Breit, B	FALSE	FALSE	FALSE	FALSE
1105	10.1039/c5dt03794h	doi.org/10.1039/c5dt03794h	1,1 '-Bis(di-tert-butylphosphino)ferrocene copper(I) complex catalyzed C-H activation and carboxylation of terminal alkynes		Dalton Trans.	110	Trivedi, M	FALSE	FALSE	FALSE	FALSE
1106	10.1039/c5dt03135d	doi.org/10.1039/c5dt03135d	A series of phenyl sulfonate metal coordination polymers as catalysts for one-pot Biginelli reactions under solvent-free conditions		Dalton Trans.	110	Tang, GM	FALSE	FALSE	FALSE	FALSE
1107	10.1002/aoc.3227	doi.org/10.1002/aoc.3227	Suzuki-Miyaura reactions promoted by a PdCl2/sulfonate-tagged phenanthroline precatalyst in water		Appl. Organomet. Chem.	110	Li, HX	FALSE	FALSE	FALSE	FALSE
1108	10.1016/j.tetlet.2014.08.077	doi.org/10.1016/j.tetlet.2014.08.077	Isoquinoline skeleton synthesis via chelation-assisted C-H activation		Tetrahedron Lett.	110	Wang, CY	FALSE	FALSE	FALSE	FALSE
1109	10.1021/cs4009946	doi.org/10.1021/cs4009946	Nickel-Catalyzed Cross-Coupling of Diarylborinic Acids with Aryl Chlorides		ACS Catal.	110	Zou, G	FALSE	FALSE	FALSE	FALSE
1110	10.1039/c4ob00475b	doi.org/10.1039/c4ob00475b	Synthesis of 1,4-dihydroquinoline derivatives under transition-metal-free conditions and their diverse applications		Org. Biomol. Chem.	110	Xu, XP	FALSE	FALSE	FALSE	FALSE
1111	10.1039/c3ra47813k	doi.org/10.1039/c3ra47813k	Pd-catalyzed ligand-free Suzuki reaction of beta-substituted allylic halides with arylboronic acids in water		RSC Adv.	110	Xu, LJ	FALSE	FALSE	FALSE	FALSE
1112	10.5059/yukigoseikyokaishi.67.584	doi.org/10.5059/yukigoseikyokaishi.67.584	Recent Progress in Asymmetric Allylic Substitutions Catalyzed by Transition Metal Complexes		J. Synth. Org. Chem. Jpn.	110	Onitsuka, K	FALSE	FALSE	FALSE	FALSE
1113	10.1021/om800327j	doi.org/10.1021/om800327j	Synthesis and reactivity of tungsten- and molybdenum-dinitrogen complexes bearing ferrocenyldiphosphines toward protonolysis		Organometallics	110	Nishibayashi, Y	FALSE	FALSE	FALSE	FALSE
1114	10.1039/b710668h	doi.org/10.1039/b710668h	Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions		Chem. Commun.	110	Ding, KL	FALSE	FALSE	FALSE	FALSE
1115	10.1246/bcsj.75.203	doi.org/10.1246/bcsj.75.203	Total synthesis of bioactive marine terpenoids		Bull. Chem. Soc. Jpn.	110	Yamada, Y	FALSE	FALSE	FALSE	FALSE
1116	10.1021/ja016838j	doi.org/10.1021/ja016838j	Catalytic, enantioselective alkylation of alpha-amino esters: The synthesis of nonnatural alpha-amino acid derivatives		J. Am. Chem. Soc.	110	Lectka, T	FALSE	FALSE	FALSE	FALSE
1117	10.1016/S0040-4020(00)00941-8	doi.org/10.1016/S0040-4020(00)00941-8	Efficient oxidative biaryl coupling reaction of phenol ether derivatives using hypervalent iodine(III) reagents		Tetrahedron	110	Kita, Y	FALSE	FALSE	FALSE	FALSE
1118	10.1021/jo982178y	doi.org/10.1021/jo982178y	Molybdenum(II)-catalyzed allylation of electron-rich aromatics and heteroaromatics		J. Org. Chem.	110	Kocovsky, P	FALSE	FALSE	FALSE	FALSE
1119	10.5059/yukigoseikyokaishi.56.511	doi.org/10.5059/yukigoseikyokaishi.56.511	Synthesis of new optically active phosphine ligands and their use in catalytic asymmetric reactions		J. Synth. Org. Chem. Jpn.	110	Imamoto, T	FALSE	FALSE	FALSE	FALSE
1120	10.1016/S0022-328X(96)06161-X	doi.org/10.1016/S0022-328X(96)06161-X	Synthesis of highly diastereo- and enantiomerically enriched tetracarbonyl(eta(3)-allyl)iron(1+) complexes for allylic substitutions with silyl enol ethers and silyl ketene acetals		J. Organomet. Chem.	110	Enders, D	FALSE	FALSE	FALSE	FALSE
1121	10.1039/d1nj05143a	doi.org/10.1039/d1nj05143a	Diverse roof shaped chiral diamidophosphites: palladium coordination and catalytic applications		New J. Chem.	110	Gavrilov, KN	FALSE	FALSE	FALSE	FALSE
1122	10.1055/a-1507-4153	doi.org/10.1055/a-1507-4153	Chromium-Catalyzed Cross-Coupling Reactions by Selective Activation of Chemically Inert Aromatic C-O, C-N, and C-H Bonds		Synlett	110	Zeng, XM	FALSE	FALSE	FALSE	FALSE
1123	10.1002/adsc.202100116	doi.org/10.1002/adsc.202100116	Recent Advances in Metal-Catalyzed Functionalization of Indoles		Adv. Synth. Catal.	110	Szostak, M	FALSE	FALSE	FALSE	FALSE
1124	10.1039/d1ob00472g	doi.org/10.1039/d1ob00472g	Recent advances in the functionalization of polyfluoro(aza)aromatics via C-C coupling strategies		Org. Biomol. Chem.	110	Varaksin, MV	FALSE	FALSE	FALSE	FALSE
1125	10.1039/c7ob01466j	doi.org/10.1039/c7ob01466j	Palladium-catalyzed decarboxylative, decarbonylative and dehydrogenative C(sp(2))-H acylation at room temperature		Org. Biomol. Chem.	110	Jana, R	FALSE	FALSE	FALSE	FALSE
1126	10.1039/c6sc05556g	doi.org/10.1039/c6sc05556g	Bimetallic catalysis for C-C and C-X coupling reactions		Chem. Sci.	110	Mankad, NP	FALSE	FALSE	FALSE	FALSE
1127	10.3866/PKU.WHXB201810052	doi.org/10.3866/PKU.WHXB201810052	Theoretical Advances of Transition Metals Mediated C-H Bonds Cleavage		Acta Phys.-Chim. Sin.	109	Shan, CH	FALSE	FALSE	FALSE	FALSE
1128	10.1021/acs.joc.8b00649	doi.org/10.1021/acs.joc.8b00649	Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand-Promoted Ruthenium-Catalyzed Deaminative Coupling Reaction of Primary Amines		J. Org. Chem.	109	Yi, CS	FALSE	FALSE	FALSE	FALSE
1129	10.1002/ajoc.201500113	doi.org/10.1002/ajoc.201500113	Effective Synthesis of alpha-D-GlcN-(1 -> 4)-D-GlcA/L-IdoA Glycosidic Linkage under Gold(I) Catalysis		Asian J. Org. Chem.	109	Yu, BA	FALSE	FALSE	FALSE	FALSE
1130	10.1002/cctc.201500102	doi.org/10.1002/cctc.201500102	Asymmetric Carbon-Carbon Bond Formation under Solventless Conditions in Ball Mills		ChemCatChem	109	Soloshonok, VA	FALSE	FALSE	FALSE	FALSE
1131	10.1021/ja511011m	doi.org/10.1021/ja511011m	Co(III)-Catalyzed C-H Activation/Formal S-N-Type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation		J. Am. Chem. Soc.	109	Glorius, F	FALSE	FALSE	FALSE	FALSE
1132	10.1002/anie.201404355	doi.org/10.1002/anie.201404355	Palladium-Catalyzed Amination of Aryl Sulfides with Anilines		Angew. Chem.-Int. Edit.	109	Murakami, K	FALSE	FALSE	FALSE	FALSE
1133	10.1002/tcr.201402004	doi.org/10.1002/tcr.201402004	Pyranosides with 2,3-trans Carbamate Groups: Exocyclic or Endocyclic Cleavage Reaction?		Chem. Rec.	109	Manabe, S	FALSE	FALSE	FALSE	FALSE
1134	10.1002/anie.201307789	doi.org/10.1002/anie.201307789	Catalytic Enantioselective Amination of Alcohols by the Use of Borrowing Hydrogen Methodology: Cooperative Catalysis by Iridium and a Chiral Phosphoric Acid		Angew. Chem.-Int. Edit.	109	Zhao, Y	FALSE	FALSE	FALSE	FALSE
1135	10.1021/ol403304t	doi.org/10.1021/ol403304t	Versatile Oxidative Approach to Carbazoles and Related Compounds Using MoCl5		Org. Lett.	109	Waldvogel, SR	FALSE	FALSE	FALSE	FALSE
1136	10.1021/ja311940s	doi.org/10.1021/ja311940s	Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C-O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates		J. Am. Chem. Soc.	109	Gomez-Bengoa, E	FALSE	FALSE	FALSE	FALSE
1137	10.1002/chem.201202623	doi.org/10.1002/chem.201202623	Mechanistic Origin of Cross-Coupling Selectivity in Ni-Catalysed Tishchenko Reactions		Chem.-Eur. J.	109	Fu, Y	FALSE	FALSE	FALSE	FALSE
1138	10.1021/om9010802	doi.org/10.1021/om9010802	Mechanism of the Palladium-Catalyzed Borylation of Aryl Halides with Pinacolborane		Organometallics	109	Marder, TB	FALSE	FALSE	FALSE	FALSE
1139	10.1002/chem.200901432	doi.org/10.1002/chem.200901432	Deprotonative Metalation of Functionalized Aromatics Using Mixed Lithium-Cadmium, Lithium-Indium, and Lithium-Zinc Species		Chem.-Eur. J.	109	Uchiyama, M	FALSE	FALSE	FALSE	FALSE
1140	10.1039/d1cy01219c	doi.org/10.1039/d1cy01219c	Zirconium-catalysed direct substitution of alcohols: enhancing the selectivity by kinetic analysis		Catal. Sci. Technol.	109	Lundberg, H	FALSE	FALSE	FALSE	FALSE
1141	10.1039/d1sc03366b	doi.org/10.1039/d1sc03366b	Stereodivergent synthesis of beta-iodoenol carbamates with CO(2)via photocatalysis		Chem. Sci.	109	Qi, CR; Jiang, HF	FALSE	FALSE	FALSE	FALSE
1142	10.1039/d1ob00496d	doi.org/10.1039/d1ob00496d	Recent developments in asymmetric Heck type cyclization reactions for constructions of complex molecules		Org. Biomol. Chem.	109	Reznikov, AN	FALSE	FALSE	FALSE	FALSE
1143	10.1039/d1ob00080b	doi.org/10.1039/d1ob00080b	Recent advances in nickel-catalyzed C-C and C-N bond formation via HA and ADC reactions		Org. Biomol. Chem.	109	Balaraman, E	FALSE	FALSE	FALSE	FALSE
1144	10.1002/ejoc.201700486	doi.org/10.1002/ejoc.201700486	An Efficient Homogenized Ruthenium(II) Pincer Complex for N-Monoalkylation of Amines with Alcohols		Eur. J. Org. Chem.	109	Song, B; Zhu, XJ	FALSE	FALSE	FALSE	FALSE
1145	10.1002/open.201700036	doi.org/10.1002/open.201700036	Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions		ChemistryOpen	109	Wu, XF	FALSE	FALSE	FALSE	FALSE
1146	10.1002/ejic.202001129	doi.org/10.1002/ejic.202001129	Redox Instability of Copper(II) Complexes of a Triazine-Based PNP Pincer	An exceptionally general electrophilic amination, which directly transforms commercially available nitroarenes into alkylated aromatic aminoboranes with zinc organyl compounds was developed. The reaction starts with a two-step partial reduction of the nitro group to a nitrenoid, which is used in situ as the electrophilic amination reagent. To facilitate isolation, the resulting air-and moisture-sensitive aminoboranes were reacted with a range of electrophiles. The method not only represents a direct transformation of nitro compounds into electrophilic amination reagents but also provides an elegant alternative to dehydrocoupling methods for the generation of aminoboranes.	Eur. J. Inorg. Chem.	108	Mohammadnezhad, G	FALSE	FALSE	FALSE	FALSE
1147	10.1002/chem.202004437	doi.org/10.1002/chem.202004437	Chemodivergence between Electrophiles in Cross-Coupling Reactions	A Cu/Pd-catalyzed allylboration of alkynes with allyl carbonates and bis(pinacolato)diboron to afford borylated skipped dienes is reported. Synergistic Cu and Pd catalysis enables this protocol to work for a wide array of alkynes and allyl carbonates under mild conditions with total regio- and stereocontrol. This transformation features the catalytic generation of beta-borylalkenylcopper intermediates and their use in Pd-catalyzed allylic substitution of allyl carbonates. The utility of this method is highlighted by the synthesis of (Z,E)-alpha-homofarnesene (pheromone) and the terpenoid precursor of Merochlorins (potent antibiotic agents).	Chem.-Eur. J.	108	Neufeldt, SR	FALSE	TRUE	FALSE	FALSE
1148	10.1021/acs.orglett.0c01537	doi.org/10.1021/acs.orglett.0c01537	O-Phosphination of Aldehydes/Ketones toward Phosphoric Esters: Experimental and Mechanistic Studies	Valuable 1-azabicycloalkane derivatives have been synthesized through a novel gold(I)-catalyzed desulfonylative cyclization strategy. An ammoniumation reaction of ynones substituted at the 1-position with an N-sulfonyl azacycle took place in the presence of a gold cation by intramolecular cyclization of the disubstituted sulfonamide moiety onto the triple bond. Depending on the size of the heterocyclic ring and substitution of the substrates, two unprecedented forms of nucleophilic attack on the sulfonyl group were exploited, that is, a N-desulfonylation in the presence of an external protic O nucleophile (37-87%, 10 examples) and a unique N-to-O 1,5-sulfonyl migration (60-98%, 9 examples).	Org. Lett.	108	Li, ZM; Zhang, JL	FALSE	FALSE	FALSE	FALSE
1149	10.1021/jacs.9b11507	doi.org/10.1021/jacs.9b11507	Oriented External Electric Fields and Ionic Additives Elicit Catalysis and Mechanistic Crossover in Oxidative Addition Reactions	Substitution of secondary allylic phosphates with the anions derived from Ar2CH2 with BuLi or LDA proceeded regioselectively and stereoselectively without a metal catalyst, affording inversion products in good yield. Similarly, propargylic phosphates gave propargylic products selectively.	J. Am. Chem. Soc.	108	Joy, J; Shaik, S	FALSE	TRUE	FALSE	FALSE
1150	10.1016/j.trechm.2019.08.004	doi.org/10.1016/j.trechm.2019.08.004	Mechanisms of Nickel-Catalyzed Cross-Coupling Reactions		Trends Chem.	108	Diao, TN	FALSE	FALSE	FALSE	FALSE
1151	10.1021/acs.orglett.8b03542	doi.org/10.1021/acs.orglett.8b03542	Catalyst-Free Transamidation of Aromatic Amines with Formamide Derivatives and Tertiary Amides with Aliphatic Amines		Org. Lett.	108	Gong, H	FALSE	FALSE	FALSE	FALSE
1152	10.1021/acscatal.8b03770	doi.org/10.1021/acscatal.8b03770	Bimetallic Nickel Complexes for Aniline C-H Alkylations		ACS Catal.	108	Ackermann, L	FALSE	FALSE	FALSE	FALSE
1153	10.1002/adsc.201800729	doi.org/10.1002/adsc.201800729	Ni-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Unactivated Phenol and Phenylmethanol Derivatives		Adv. Synth. Catal.	108	Le, ZP; Yan, ZH; Zhang, H	FALSE	FALSE	FALSE	FALSE
1154	10.1002/ajoc.201700419	doi.org/10.1002/ajoc.201700419	Synthesis of Indolizine-Containing Diaryl- and Triarylmethanes through a Cu-Catalyzed Domino Cyclization of 2-(2-Enynyl)pyridines		Asian J. Org. Chem.	108	Anand, RV	FALSE	FALSE	FALSE	FALSE
1155	10.1021/om500319h	doi.org/10.1021/om500319h	Iron-Catalyzed Hydromagnesiation: Synthesis and Characterization of Benzylic Grignard Reagent Intermediate and Application in the Synthesis of Ibuprofen		Organometallics	108	Thomas, SP	FALSE	FALSE	FALSE	FALSE
1156	10.1021/jo501291y	doi.org/10.1021/jo501291y	N-Heterocyclic Carbene-Assisted, Bis(phosphine)nickel-Catalyzed Cross-Couplings of Diarylborinic Acids with Aryl Chlorides, Tosylates, and Sulfamates		J. Org. Chem.	108	Zou, G	FALSE	FALSE	FALSE	FALSE
1157	10.1002/anie.201403046	doi.org/10.1002/anie.201403046	Catalytic Asymmetric Synthesis of 3,3 '-Diaryloxindoles as Triarylmethanes with a Chiral All-Carbon Quaternary Center: Phase-Transfer-Catalyzed SNAr Reaction		Angew. Chem.-Int. Edit.	108	Maruoka, K	FALSE	FALSE	FALSE	FALSE
1158	10.1002/adsc.201200704	doi.org/10.1002/adsc.201200704	Stereospecific AllylAryl Coupling Catalyzed by in situ Generated Palladium Nanoparticles in Water under Ambient Conditions		Adv. Synth. Catal.	108	Zhang, YJ	FALSE	FALSE	FALSE	FALSE
1159	10.1039/c3dt31898b	doi.org/10.1039/c3dt31898b	Computational study on mechanism of Rh(III)-catalyzed oxidative Heck coupling of phenol carbamates with alkenes		Dalton Trans.	108	Huang, Y	FALSE	FALSE	FALSE	FALSE
1160	10.1007/128_2012_322	doi.org/10.1007/128_2012_322	Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones		Top. Curr. Chem.	108	Wang, JB	FALSE	FALSE	FALSE	FALSE
1161	10.3390/molecules16010590	doi.org/10.3390/molecules16010590	Transition Metal Catalyzed Synthesis of Aryl Sulfides		Molecules	108	Stambuli, JP	FALSE	FALSE	FALSE	FALSE
1162	10.1002/anie.201007733	doi.org/10.1002/anie.201007733	Stereospecific Copper-Catalyzed C-H Allylation of Electron-Deficient Arenes with Allyl Phosphates		Angew. Chem.-Int. Edit.	108	Hirano, K	FALSE	TRUE	FALSE	FALSE
1163	10.1002/aoc.1270	doi.org/10.1002/aoc.1270	The development of a 'safety-catch' arylgermane for biaryl synthesis by palladium-catalysed germyl-Stille cross-coupling		Appl. Organomet. Chem.	108	Spivey, AC	FALSE	FALSE	FALSE	FALSE
1164	10.1039/b706846h	doi.org/10.1039/b706846h	Hydrodefluorination of pentafluoropyridine at rhodium using dihydrogen: detection of unusual rhodium hydrido complexes		Dalton Trans.	108	Braun, T	FALSE	FALSE	FALSE	FALSE
1165	10.1021/ja038742q	doi.org/10.1021/ja038742q	Ruthenium-catalyzed Heck-type olefination and Suzuki coupling reactions: Studies on the nature of catalytic species		J. Am. Chem. Soc.	108	Chang, S	FALSE	FALSE	FALSE	FALSE
1166	10.1039/d1ob02349g	doi.org/10.1039/d1ob02349g	An efficient and straightforward approach for accessing thionoesters via palladium-catalyzed C-N cleavage of thioamides		Org. Biomol. Chem.	108	Zeng, Z	FALSE	FALSE	FALSE	FALSE
1167	10.1021/jacs.1c12199	doi.org/10.1021/jacs.1c12199	Radical Carbonyl Umpolung Arylation via Dual Nickel Catalysis		J. Am. Chem. Soc.	108	Glorius, F	FALSE	FALSE	FALSE	FALSE
1168	10.1021/jacs.1c09214	doi.org/10.1021/jacs.1c09214	Regio- and Stereoselective Alkylboration of Endocyclic Olefins Enabled by Nickel Catalysis		J. Am. Chem. Soc.	108	Yin, GY	FALSE	FALSE	FALSE	FALSE
1169	10.1039/d1dt03331j	doi.org/10.1039/d1dt03331j	Reductively disilylated N-heterocycles as versatile organosilicon reagents		Dalton Trans.	108	Majumdar, M	FALSE	FALSE	FALSE	FALSE
1170	10.1039/d1qo01500a	doi.org/10.1039/d1qo01500a	Insight into the mechanism of the arylation of arenes via norbornene relay palladation through meta- to para-selectivity		Org. Chem. Front.	108	Liu, JB; Chen, DZ	FALSE	FALSE	FALSE	FALSE
1171	10.1002/adsc.202100585	doi.org/10.1002/adsc.202100585	Recent Advances in Transformations Involving Electron-Rich Alkenes: Functionalization, Cyclization, and Cross-Metathesis Reactions		Adv. Synth. Catal.	108	Wu, WQ	FALSE	TRUE	FALSE	FALSE
1172	10.1007/s10562-021-03787-2	doi.org/10.1007/s10562-021-03787-2	Synthesis of Quinoxaline-Linked Bis(Benzimidazolium) Salts and Their Catalytic Application in Palladium-Catalyzed Direct Arylation of Heteroarenes		Catal. Lett.	108	Dusunceli, SD	FALSE	FALSE	FALSE	FALSE
1173	10.1002/anie.202101517	doi.org/10.1002/anie.202101517	Catalytic Diastereo- and Enantioconvergent Synthesis of Vicinal Diamines from Diols through Borrowing Hydrogen		Angew. Chem.-Int. Edit.	108	Yang, BM; Zhao, Y	FALSE	FALSE	FALSE	FALSE
1174	10.1021/acs.oprd.1c00053	doi.org/10.1021/acs.oprd.1c00053	Recent Advances in Nonprecious Metal Catalysis		Org. Process Res. Dev.	108	Haddad, N	FALSE	FALSE	FALSE	FALSE
1175	10.1021/acscatal.1c02144	doi.org/10.1021/acscatal.1c02144	Kinetically Controlled Stereoselective Access to Branched 1,3-Dienes by Ru-Catalyzed Remote Conjugative Isomerization		ACS Catal.	108	Mazet, C	FALSE	FALSE	FALSE	FALSE
1176	10.1021/acscatal.1c01626	doi.org/10.1021/acscatal.1c01626	Mechanistic Study of Ni and Cu Dual Catalyst for Asymmetric C-C Bond Formation; Asymmetric Coupling of 1,3-Dienes with C-nucleophiles to Construct Vicinal Stereocenters		ACS Catal.	108	Mashima, K	FALSE	FALSE	FALSE	FALSE
1177	10.1002/asia.201700313	doi.org/10.1002/asia.201700313	Mechanism of Nickel-Catalyzed Suzuki-Miyaura Coupling of Amides		Chem.-Asian J.	108	Fu, Y	FALSE	FALSE	FALSE	FALSE
1178	10.1021/acscatal.6b03631	doi.org/10.1021/acscatal.6b03631	Hollow Hyper-Cross-Linked Nanospheres with Acid and Base Sites as Efficient and Water-Stable Catalysts for One-Pot Tandem Reactions		ACS Catal.	108	Tan, B; Gu, YL	FALSE	FALSE	FALSE	FALSE
1179	10.1002/chem.201604061	doi.org/10.1002/chem.201604061	Unlocking Mizoroki-Heck-Type Reactions of Aryl Cyanides Using Transfer Hydrocyanation as a Turnover-Enabling Step		Chem.-Eur. J.	108	Morandi, B	FALSE	FALSE	FALSE	FALSE
1180	10.1021/acs.inorgchem.6b01162	doi.org/10.1021/acs.inorgchem.6b01162	Arene C(sp(2))-H Metalation at Ni-II Modeled with a Reactive PONCPh Ligand		Inorg. Chem.	108	van der Vlugt, JI	FALSE	FALSE	FALSE	FALSE
1181	10.1007/s41061-016-0042-2	doi.org/10.1007/s41061-016-0042-2	Nickel-Catalyzed Reductive Couplings		Top. Curr. Chem.	108	Gong, HG	FALSE	FALSE	FALSE	FALSE
1182	10.1039/d0nj02630a	doi.org/10.1039/d0nj02630a	Preparation of aromatic gamma-hydroxyketones by means of Heck coupling of aryl halides and 2,3-dihydrofuran, catalyzed by a palladium(ii) glycine complex under microwave irradiation	Photochemical reactions have become an important tool for organic chemists. Visible (solar) light can be conveniently adopted, however, only when using colored organic compounds or in photocatalyzed processes induced by visible light absorbing photocatalysts. Herein we demonstrate that a photolabile, colored moiety could be incorporated in a colorless organic compound with the aim of generating highly reactive intermediates upon exposure to visible (solar) light. Arylazo sulfones, colored thermally stable derivatives of aryl diazonium salts, were used as valuable substrates for the photoinduced metal-free synthesis of (hetero)biaryls with no need of a (photo)catalyst or of other additives to promote the reaction. Noteworthy, selective generation of aryl radicals and aryl cations can be attained at will by varying the irradiation conditions (visible light for the former and UVA light for the latter).	New J. Chem.	107	Avina-Verduzco, J	FALSE	FALSE	TRUE	TRUE
1183	10.1021/acs.orglett.0c01582	doi.org/10.1021/acs.orglett.0c01582	Pd-Catalyzed Cyanoselenylation of Internal Alkynes: Access to Tetrasubstituted Selenoenol Ethers	A range of bromothiopheneS reacted with lithium boranato(tert-butyl)methylphosphide in the absence of transition metal catalysts under mild conditions to provide the same 2,5-disubstituted and 2-monosubstituted products regardless of the substitution patterns of the starting bromothiophenes.	Org. Lett.	107	Werz, DB	FALSE	FALSE	FALSE	FALSE
1184	10.1021/acsomega.9b03989	doi.org/10.1021/acsomega.9b03989	Exploring Possible Surrogates for Kobayashi's Aryne Precursors		ACS Omega	107	Raminelli, C	FALSE	FALSE	FALSE	FALSE
1185	10.1021/acs.orglett.9b03102	doi.org/10.1021/acs.orglett.9b03102	Reductive Allylic Defluorinative Cross-Coupling Enabled by Ni/Ti Cooperative Catalysis		Org. Lett.	107	Wang, C	FALSE	FALSE	FALSE	FALSE
1186	10.1021/acs.orglett.9b02870	doi.org/10.1021/acs.orglett.9b02870	Nickel-Catalyzed Reductive Arylalkylation via a Migratory Insertion/Decarboxylative Cross-Coupling Cascade		Org. Lett.	107	Wang, C	FALSE	FALSE	FALSE	FALSE
1187	10.1021/acs.joc.9b01227	doi.org/10.1021/acs.joc.9b01227	A Computational Mechanistic Study of Pd(II)-Catalyzed Enantioselective C(sp(3))-H Borylation: Roles of APAO Ligands		J. Org. Chem.	107	Liu, JB; Chen, DZ	FALSE	FALSE	FALSE	FALSE
1188	10.1002/ajoc.201900163	doi.org/10.1002/ajoc.201900163	Catalytic Strategies to Convert 2-Halopyridines to 2-Alkylpyridines		Asian J. Org. Chem.	107	Roizen, JL	FALSE	FALSE	FALSE	FALSE
1189	10.1039/c9sc00554d	doi.org/10.1039/c9sc00554d	Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations		Chem. Sci.	107	Yang, Y	FALSE	FALSE	FALSE	FALSE
1190	10.1021/acs.organomet.9b00026	doi.org/10.1021/acs.organomet.9b00026	Stable Nickel(I) Complexes with Electron-Rich, Sterically-Hindered, Innocent PNP Pincer Ligands		Organometallics	107	Khusnutdinova, JR	FALSE	TRUE	FALSE	FALSE
1191	10.3390/catal9010053	doi.org/10.3390/catal9010053	Recent Advances in Acyl Suzuki Cross-Coupling		Catalysts	107	Szostak, M	FALSE	FALSE	FALSE	FALSE
1192	10.1021/jacs.8b08596	doi.org/10.1021/jacs.8b08596	Discovery of a Photoinduced Dark Catalytic Cycle Using in Situ LED-NMR Spectroscopy		J. Am. Chem. Soc.	107	Lehnherr, D; Ji, YN	TRUE	FALSE	FALSE	FALSE
1193	10.1002/anie.201804479	doi.org/10.1002/anie.201804479	Thorpe-Ingold Effect in Branch-Selective Alkylation of Unactivated Aryl Fluorides		Angew. Chem.-Int. Edit.	107	Cornella, J	FALSE	FALSE	FALSE	FALSE
1194	10.1002/chem.201704670	doi.org/10.1002/chem.201704670	Transition-Metal-Catalyzed Decarbonylative Coupling Reactions: Concepts, Classifications, and Applications		Chem.-Eur. J.	107	Rueping, M	FALSE	FALSE	FALSE	FALSE
1195	10.1021/acscatal.8b00933	doi.org/10.1021/acscatal.8b00933	Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation		ACS Catal.	107	Perego, LA; Grimaud, L	FALSE	FALSE	FALSE	FALSE
1196	10.1021/acs.joc.7b03180	doi.org/10.1021/acs.joc.7b03180	Substrate-Directed Catalytic Selective Chemical Reactions		J. Org. Chem.	107	Sawano, T; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
1197	10.1021/acscatal.8b00856	doi.org/10.1021/acscatal.8b00856	Elucidating the Mechanism of Aryl Aminations Mediated by NHC-Supported Nickel Complexes: Evidence for a Nonradical Ni(0)/Ni(II) Pathway		ACS Catal.	107	Fructos, MR; Belderrain, TR	FALSE	FALSE	FALSE	FALSE
1198	10.1016/j.tet.2015.06.103	doi.org/10.1016/j.tet.2015.06.103	Recyclable palladium catalyst on grapheme oxide for the C-C/C-N cross-coupling reactions of heteroaromatic sulfonates		Tetrahedron	107	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
1199	10.1039/c5ra12512j	doi.org/10.1039/c5ra12512j	Synthesis of benzochromenes and dihydrophenanthridines with helical motifs using Garratt-Braverman and Buchwald-Hartwig reactions		RSC Adv.	107	Basak, A	FALSE	FALSE	FALSE	FALSE
1200	10.2174/157017941206150828102108	doi.org/10.2174/157017941206150828102108	Application of Bio-Based Solvents in Catalysis		Curr. Org. Synth.	107	Correa, AG	FALSE	FALSE	FALSE	FALSE
1201	10.1002/asia.201100971	doi.org/10.1002/asia.201100971	Catalytic Arylation of a C?H Bond in Pyridine and Related Six-Membered N-Heteroarenes Using Organozinc Reagents		Chem.-Asian J.	107	Tobisu, M	FALSE	FALSE	FALSE	FALSE
1202	10.1021/ja9944599	doi.org/10.1021/ja9944599	Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)(2) and Pd(DPPF)(2): An unusual case of zero-order kinetic behavior and product inhibition		J. Am. Chem. Soc.	107	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
1203	10.1016/S0010-8545(98)00088-5	doi.org/10.1016/S0010-8545(98)00088-5	The aminophosphine-phosphinites and related ligands: synthesis, coordination chemistry and enantioselective catalysis		Coord. Chem. Rev.	107	Agbossou, F	FALSE	FALSE	FALSE	FALSE
1204	10.1021/acscatal.1c03896	doi.org/10.1021/acscatal.1c03896	The Directing Group: A Tool for Efficient and Selective C-F Bond Activation		ACS Catal.	107	Chatani, N	FALSE	FALSE	FALSE	FALSE
1205	10.1021/jacs.1c07851	doi.org/10.1021/jacs.1c07851	Nickel-Catalyzed Multicomponent Coupling: Synthesis of alpha-Chiral Ketones by Reductive Hydrocarbonylation of Alkenes		J. Am. Chem. Soc.	107	Zhu, SL	FALSE	FALSE	FALSE	FALSE
1206	10.1002/anie.202103803	doi.org/10.1002/anie.202103803	Low-Temperature Nickel-Catalyzed C-N Cross-Coupling via Kinetic Resolution Enabled by a Bulky and Flexible Chiral N-Heterocyclic Carbene Ligand		Angew. Chem.-Int. Edit.	107	Shi, SL	FALSE	FALSE	FALSE	FALSE
1207	10.1039/d1ra01940f	doi.org/10.1039/d1ra01940f	The graphite-catalyzed ipso-functionalization of arylboronic acids in an aqueous medium: metal-free access to phenols, anilines, nitroarenes, and haloarenes		RSC Adv.	107	Dandia, A; Parewa, V	FALSE	FALSE	FALSE	FALSE
1208	10.1021/jacs.6b11412	doi.org/10.1021/jacs.6b11412	Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species		J. Am. Chem. Soc.	107	Hazari, N	FALSE	FALSE	FALSE	FALSE
1209	10.1007/s13738-021-02212-0	doi.org/10.1007/s13738-021-02212-0	A review on the syntheses of Dronabinol and Epidiolex as classical cannabinoids with various biological activities including those against SARS-COV2	A new protocol for the NiCl2-catalyzed cross-electrophile coupling of aryl bromides with pyrimidin-2-yl tosylates to give the corresponding C2-arylation pyrimidine derivatives has been developed. This study provides an improvement over previous methods by using pyrimidin-2-yl tosylates instead of halides as coupling partners that are stable and easily available.	J. Iran Chem. Soc.	106	Ramazani, A	FALSE	FALSE	FALSE	FALSE
1210	10.1039/c9qo01428d	doi.org/10.1039/c9qo01428d	Reductive coupling of imines with redox-active esters by visible light photoredox organocatalysis		Org. Chem. Front.	106	Rueping, M	FALSE	FALSE	FALSE	FALSE
1211	10.1007/s41061-019-0255-2	doi.org/10.1007/s41061-019-0255-2	Task-Specific Properties and Prospects of Ionic Liquids in Cross-Coupling Reactions		Top. Curr. Chem.	106	Basu, B	FALSE	FALSE	FALSE	FALSE
1212	10.1002/anie.201911268	doi.org/10.1002/anie.201911268	Catalytic Enantioselective Methylene C(sp(3))-H Amidation of 8-Alkylquinolines Using a Cp*Rh-III/Chiral Carboxylic Acid System		Angew. Chem.-Int. Edit.	106	Yoshino, T; Matsunaga, S	FALSE	FALSE	FALSE	FALSE
1213	10.1002/anie.201909928	doi.org/10.1002/anie.201909928	Cobalt-Catalyzed Asymmetric Hydrogenation of C=N Bonds Enabled by Assisted Coordination and Nonbonding Interactions		Angew. Chem.-Int. Edit.	106	Zhang, WB	FALSE	FALSE	FALSE	FALSE
1214	10.1002/adsc.201900745	doi.org/10.1002/adsc.201900745	Advances in Transition Metal-Catalyzed Selective Functionalization of Inert C-O Bonds Assisted by Directing Groups		Adv. Synth. Catal.	106	Lin, C; Shen, L	FALSE	FALSE	FALSE	FALSE
1215	10.1039/C7SC04675H	doi.org/10.1039/C7SC04675H	Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions		Chem. Sci.	106	Iwasaki, T; Kambe, N	FALSE	FALSE	FALSE	FALSE
1216	10.1039/c7sc03404k	doi.org/10.1039/c7sc03404k	Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)		Chem. Sci.	106	Liao, J	FALSE	FALSE	FALSE	FALSE
1217	10.1021/acs.joc.7b01711	doi.org/10.1021/acs.joc.7b01711	Bulky Yet Flexible Pd-PEPPSI-IPent(An) for the Synthesis of Sterically Hindered Biaryls in Air		J. Org. Chem.	106	Liu, FS	FALSE	FALSE	FALSE	FALSE
1218	10.1039/c6dt00252h	doi.org/10.1039/c6dt00252h	Cyclopentadienyl nickel(II) N,C-chelating benzothiazolyl NHC complexes: synthesis, characterization and application in catalytic C-C bond formation reactions		Dalton Trans.	106	Hor, TSA; Zhao, J	FALSE	FALSE	FALSE	FALSE
1219	10.1039/c6ob00607h	doi.org/10.1039/c6ob00607h	Density functional theory investigation on Pd-catalyzed cross-coupling of azoles with aryl thioethers		Org. Biomol. Chem.	106	Yu, HZ	FALSE	FALSE	FALSE	FALSE
1220	10.1021/acs.organomet.5b00710	doi.org/10.1021/acs.organomet.5b00710	Aryl Ether Cleavage by Group 9 and 10 Transition Metals: Stoichiometric Studies of Selectivity and Mechanism		Organometallics	106	Agapie, T	FALSE	FALSE	FALSE	FALSE
1221	10.1021/acs.joc.5b00669	doi.org/10.1021/acs.joc.5b00669	Nickel-Catalyzed Alkynylation of a C(sp(2))-H Bond Directed by an 8-Aminoquinoline Moiety		J. Org. Chem.	106	Li, FW	FALSE	FALSE	FALSE	FALSE
1222	10.1002/chem.201002386	doi.org/10.1002/chem.201002386	Well-Defined Air-Stable Palladium HASPO Complexes for Efficient Kumada-Corriu Cross-Couplings of (Hetero)Aryl or Alkenyl Tosylates		Chem.-Eur. J.	106	Ackermann, L	FALSE	FALSE	FALSE	FALSE
1223	10.1007/978-3-642-15334-1_7	doi.org/10.1007/978-3-642-15334-1_7	Iridium-Catalyzed Allylic Substitution		Top. Organomet. Chem.	106	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
1224	10.1021/om900771v	doi.org/10.1021/om900771v	Synthesis of Arylphosphonates via Palladium-Catalyzed Coupling Reactions of Aryl Imidazolylsulfonates with H-Phosphonate Diesters		Organometallics	106	Wu, J	FALSE	FALSE	FALSE	FALSE
1225	10.1055/s-2008-1077903	doi.org/10.1055/s-2008-1077903	Optically active chiral ligands, ferrocenyloxazolinylphosphines (FOXAPs): Development and application to catalytic asymmetric reactions		Synlett	106	Nishibayashi, Y	FALSE	FALSE	FALSE	FALSE
1226	10.1055/a-1647-5978	doi.org/10.1055/a-1647-5978	Palladium-Catalyzed Cross-Coupling of 4-(Tosyloxy)quinazolines with H-Phosphonates and Phosphine Oxides: An Efficient Access to 2-(Hetero)aryl-4-phosphorylated Quinazolines		Synthesis	106	Peng, YY	FALSE	FALSE	FALSE	FALSE
1227	10.1039/d1cc04370f	doi.org/10.1039/d1cc04370f	Chain-walking reactions of transition metals for remote C-H bond functionalization of olefinic substrates		Chem. Commun.	106	Chatterjee, I	FALSE	FALSE	FALSE	FALSE
1228	10.1002/chem.202102805	doi.org/10.1002/chem.202102805	Continuous Flow Acylation of (Hetero)aryllithiums with Polyfunctional N,N-Dimethylamides and Tetramethylurea in Toluene		Chem.-Eur. J.	106	Knochel, P	FALSE	FALSE	FALSE	FALSE
1229	10.1002/chem.202100475	doi.org/10.1002/chem.202100475	Accessing C2-Functionalized 1,3-(Benz)azoles through Transition Metal-Catalyzed C-H Activation		Chem.-Eur. J.	106	Maiti, D	FALSE	FALSE	FALSE	FALSE
1230	10.1002/asia.202100277	doi.org/10.1002/asia.202100277	Alkyl Enol Ethers: Development in Intermolecular Organic Transformation		Chem.-Asian J.	106	Khan, FA	FALSE	FALSE	FALSE	FALSE
1231	10.1002/adsc.201601407	doi.org/10.1002/adsc.201601407	Aldehydes as Carbon Radical Acceptors: Silver Nitrate Catalyzed Cascade Decarboxylation and Oxidative Cyclization toward Dihydroflavonoid Derivatives		Adv. Synth. Catal.	106	Wu, L	FALSE	FALSE	FALSE	FALSE
1232	10.1002/cssc.201700452	doi.org/10.1002/cssc.201700452	Polycyclization Enabled by Relay Catalysis: One-Pot Manganese-Catalyzed C-H Allylation and Silver-Catalyzed Povarov Reaction		ChemSusChem	106	Li, QJ; Wang, HG	FALSE	FALSE	FALSE	FALSE
1233	10.1021/acs.joc.6b01709	doi.org/10.1021/acs.joc.6b01709	Synthesis of Ketones and Esters from Heteroatom-Functionalized Alkenes by Cobalt-Mediated Hydrogen Atom Transfer		J. Org. Chem.	106	Herzon, SB	FALSE	FALSE	FALSE	FALSE
1234	10.1016/j.jorganchem.2016.05.017	doi.org/10.1016/j.jorganchem.2016.05.017	Infrared irradiation or microwave assisted cross-coupling reactions using sulfur-containing ferrocenyl-palladacycles		J. Organomet. Chem.	106	Ortega-Alfaro, MC	FALSE	FALSE	FALSE	FALSE
1235	10.1002/ejic.201600181	doi.org/10.1002/ejic.201600181	Preparation of Secondary Phosphine Oxide Ligands through Nucleophilic Attack on Imines and Their Applications in Palladium-Catalyzed Catellani Reactions		Eur. J. Inorg. Chem.	106	Hong, FE	FALSE	FALSE	FALSE	FALSE
1236	10.1002/anie.201510743	doi.org/10.1002/anie.201510743	A General Strategy for the Nickel-Catalyzed C-H Alkylation of Anilines		Angew. Chem.-Int. Edit.	106	Ackermann, L	FALSE	FALSE	FALSE	FALSE
1237	10.1246/bcsj.20200321	doi.org/10.1246/bcsj.20200321	Development of Organosilicon Peroxides as Practical Alkyl Radical Precursors and Their Applications to Transition Metal Catalysis	A novel method for the synthesis of trisubstituted oxazoles via a one-pot oxazole synthesis/Suzuki-Miyaura coupling sequence has been developed. One-pot formation of 5-(triazinyloxy) oxazoles using carboxylic acids, amino acids and a dehydrative condensing reagent, DMT-MM, followed by Ni-catalyzed Suzuki-Miyaura coupling with boronic acids provided the corresponding 2,4,5-trisubstituted oxazoles in good yields.	Bull. Chem. Soc. Jpn.	105	Matsumoto, A; Maruoka, K	FALSE	FALSE	FALSE	FALSE
1238	10.1021/acscatal.0c03343	doi.org/10.1021/acscatal.0c03343	Redox-Triggered Ruthenium-Catalyzed Remote C-H Acylation with Primary Alcohols	Previous reports in the literature have established the utility of 1,1'-bis(diphenylphosphino)ferrocene (DPPF, L-Ph) in the nickel-catalyzed cross-coupling of (hetero)aryl electrophiles with primary or secondary amines. In an effort to evaluate the effect of varying the PR2-donor groups On catalytic performance in such transformations, a series of 10 structurally varied 1,1'-bis(bis(alkyl/aryl)phosphino)ferrocene ancillary ligands (L-X) were systematically examined in selected competitive test cross couplings of (hetero)aryl halides with furfurylamine, morpholine, and indole employing Ni(COD)(2)/L-X catalyst mixtures. In addition to the excellent performance observed for the parent ligand LPh in a number of the test transformations explored, selected dialkylphosphino (e.g., DiPPF, L-iPr) and meta-disubstituted diarylphosphino variants of L-Ph also proved highly effective. In particular, the electron-deficient ligand variant L-CF3 featuring 3,5-bis(trifluoromethyl)phenyl groups on phosphorus was found to exhibit superior catalytic performance relative to L-Ph in most of the test transformations involving the N-arylation of indole. Our efforts to prepare Ni(II) precatalysts of the type (L-X)Ni(o-tolyl)Cl) in analogy with known (L-Ph)Ni(o-tolyl)Cl, by employing several literature methods met with mixed results. Whereas ((LNi)-Ni-iPr(o-tolyl)Cl was prepared straightforwardly and was crystallographically characterized, the use of L-CF3 or ligands featuring tert-butyl (L-tBu, o-tolyl (Lo-tol), or 4-methoxy-3,5dirnethylphenyl (L-OMe) groups on phosphorus under similar conditions resulted in poor conversion to product and/or the formation of poorly soluble materials, highlighting the limitations of this commonly used precatalyst design.	ACS Catal.	105	Xia, JB	FALSE	FALSE	FALSE	FALSE
1239	10.1021/jacs.0c04074	doi.org/10.1021/jacs.0c04074	Achieving Site-Selectivity for C-H Activation Processes Based on Distance and Geometry: A Carpenter's Approach	Detailed in this Communication is the enantioselective synthesis of 1,1-diarylalkanes, a structure found in a range of pharmaceutical drug agents and natural products, through the employment of copper(I) hydride and palladium catalysis. Judicious choice of ligand for both Cu and Pd enabled this hydroarylation protocol to work for an extensive array of aryl bromides and styrenes, including beta-substituted vinylarenes and six-membered heterocycles, under relatively mild conditions.	J. Am. Chem. Soc.	105	Yu, JQ	FALSE	FALSE	FALSE	FALSE
1240	10.1002/cssc.202000576	doi.org/10.1002/cssc.202000576	Sustainable and Selective Alkylation of Deactivated Secondary Alcohols to Ketones by Non-bifunctional Pincer N-heterocyclic Carbene Manganese	The Suzuki-Miyaura cross-coupling is one of the most often utilized reactions in the synthesis of pharmaceutical compounds and conjugated materials. In its most common form, the reaction joins two sp(2)-functionalized carbon atoms to make a biaryl or diene/polyene unit. These substructures are widely found in natural products and small molecules and thus the Suzuki-Miyaura cross-coupling has been proposed as the key reaction for the automated assembly of such molecules, using protecting group chemistry to affect iterative coupling. We present herein, a significant advance in this approach, in which multiply functionalized cross-coupling partners can be employed in iterative coupling without the use of protecting groups. To accomplish this, the orthogonal reactivity of different boron substituents towards the boron-to-palladium transmetalation reaction is exploited. The approach is illustrated in the preparation of chiral enantioenriched compounds, which are known to be privileged structures in active pharmaceutical compounds.	ChemSusChem	105	Ke, ZF	FALSE	FALSE	FALSE	FALSE
1241	10.1016/j.ica.2019.119285	doi.org/10.1016/j.ica.2019.119285	Ruthenium(II) complexes of pyridine-carboxamide ligands bearing appended benzothiazole/benzimidazole rings: Structural diversity and catalysis	Iron-catalyzed C-H bond activation followed by C-C bond formation has received much attention in recent years, motivated by the environmental and economical merits of iron, as well as the scientific challenge in controlling and understanding the reactivity of iron species. This review describes the utilization of iron as a catalyst for directed C-H bond activation, followed by C-C bond formation. Catalytic activation of C(sp(2))-H and C(sp(3)-H) bonds, followed by oxidative reaction with nucleophiles, or reaction with electrophiles is described. Reactions of substrates possessing a directing group are mainly discussed, but other substrates are also presented. Carbon-heteroatom bond formation is also briefly discussed.	Inorg. Chim. Acta	105	Gupta, R	FALSE	FALSE	FALSE	FALSE
1242	10.1021/jacs.9b12297	doi.org/10.1021/jacs.9b12297	Direct Access to Chiral Secondary Amides by Copper-Catalyzed Borylative Carboxamidation of Vinylarenes with Isocyanates		J. Am. Chem. Soc.	105	Mazet, C	FALSE	FALSE	FALSE	FALSE
1243	10.1002/anie.201902903	doi.org/10.1002/anie.201902903	Transition-Metal-Free Cross-Coupling of Benzothiophenes and Styrenes in a Stereoselective Synthesis of Substituted (E,Z)-1,3-Dienes		Angew. Chem.-Int. Edit.	105	Procter, DJ	FALSE	FALSE	FALSE	FALSE
1244	10.1002/adsc.201801446	doi.org/10.1002/adsc.201801446	Enantioselective Synthesis of Triarylmethanes via Organocatalytic 1,6-Addition of Arylboronic Acids to Para-Quinone Methides		Adv. Synth. Catal.	105	Weng, J; Lu, G	FALSE	FALSE	FALSE	FALSE
1245	10.1039/c8ob03091j	doi.org/10.1039/c8ob03091j	N-Alkyl amide synthesis via N-alkylation of amides with alcohols		Org. Biomol. Chem.	105	Shi, F	FALSE	FALSE	FALSE	FALSE
1246	10.1016/j.tet.2018.12.013	doi.org/10.1016/j.tet.2018.12.013	Cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on the catalytic generation of organocopper nucleophiles		Tetrahedron	105	Semba, K; Nakao, Y	FALSE	FALSE	FALSE	FALSE
1247	10.1055/s-0036-1591495	doi.org/10.1055/s-0036-1591495	Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway		Synlett	105	Rueping, M	FALSE	FALSE	FALSE	FALSE
1248	10.1039/c7dt02532g	doi.org/10.1039/c7dt02532g	Why different ligands can control stereochemistry selectivity of Ni-catalyzed Suzuki-Miyaura cross-coupling of benzylic carbamates with arylboronic esters: a mechanistic study		Dalton Trans.	105	Xie, HJ	FALSE	FALSE	FALSE	FALSE
1249	10.1002/chem.201406100	doi.org/10.1002/chem.201406100	Convenient and Highly Efficient Routes to 2H-Chromene and 4-Chromanone Derivatives: Iodine-Promoted and p-Toluenesulfonic Acid Catalyzed Cascade Cyclizations of Propynols		Chem.-Eur. J.	105	Liang, YM	FALSE	FALSE	FALSE	FALSE
1250	10.1021/ja510653n	doi.org/10.1021/ja510653n	Ni-Catalyzed Reductive Coupling of Alkyl Acids with Unactivated Tertiary Alkyl and Glycosyl Halides		J. Am. Chem. Soc.	105	Gong, HG	FALSE	FALSE	FALSE	FALSE
1251	10.1002/ajoc.201400013	doi.org/10.1002/ajoc.201400013	C2-Arylation of Substituted Pyridine N-oxides with Heteroaryl Carboxylic Acids by Palladium-Catalyzed Decarboxylative Coupling		Asian J. Org. Chem.	105	Muthusubramanian, S	FALSE	FALSE	FALSE	FALSE
1252	10.1002/ejoc.201200914	doi.org/10.1002/ejoc.201200914	Recent Progress in Nickel-Catalyzed Biaryl Coupling		Eur. J. Org. Chem.	105	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
1253	10.1002/ejoc.201101284	doi.org/10.1002/ejoc.201101284	Substituted Functional Olefins Through Lateral Sequential Lithiation/Silylation/Condensation of Tertiary Aromatic Amides: A Ligand for Phosphane-Free Palladium-Catalyzed Suzuki Coupling Reactions		Eur. J. Org. Chem.	105	Xu, LW	FALSE	FALSE	FALSE	FALSE
1254	10.1002/ejoc.201100044	doi.org/10.1002/ejoc.201100044	Cooperative Catalytic Reactions Using Lewis Acids and Organocatalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols Bearing an Internal Alkyne with Aldehydes		Eur. J. Org. Chem.	105	Nishibayashi, Y	FALSE	FALSE	FALSE	FALSE
1255	10.1021/jo1003373	doi.org/10.1021/jo1003373	Palladium Nanoparticle Catalyzed Hiyama Coupling Reaction of Benzyl Halides		J. Org. Chem.	105	Sarkar, A	FALSE	FALSE	FALSE	FALSE
1256	10.1002/chem.200902927	doi.org/10.1002/chem.200902927	Radical Arylation of Phenols, Phenyl Ethers, and Furans		Chem.-Eur. J.	105	Heinrich, MR	FALSE	FALSE	FALSE	FALSE
1257	10.1016/j.tet.2006.05.006	doi.org/10.1016/j.tet.2006.05.006	Nickel-catalyzed coupling of terminal allenes, aldehydes, and silanes		Tetrahedron	105	Jamison, TF	FALSE	FALSE	FALSE	FALSE
1258	10.1016/j.ccr.2006.01.001	doi.org/10.1016/j.ccr.2006.01.001	Metal complexes of chelating diarylamido phosphine ligands		Coord. Chem. Rev.	105	Liang, LC	FALSE	FALSE	FALSE	FALSE
1259	10.5059/yukigoseikyokaishi.44.499	doi.org/10.5059/yukigoseikyokaishi.44.499	ASYMMETRIC-SYNTHESIS BY MEANS OF CHIRAL METAL-COMPLEX CATALYSTS		J. Synth. Org. Chem. Jpn.	105	OJIMA, I	FALSE	FALSE	FALSE	FALSE
1260	10.1021/acscatal.1c05073	doi.org/10.1021/acscatal.1c05073	Radical Addition-Triggered Remote Migratory Isomerization of Unactivated Alkenes to Difluoromethylene-Containing Alkenes Enabled by Bimetallic Catalysis		ACS Catal.	105	Zhang, Q; Xiong, T	FALSE	FALSE	FALSE	FALSE
1261	10.1002/hlca.202100200	doi.org/10.1002/hlca.202100200	Development and Molecular Understanding of a Pd-Catalyzed Cyanation of Aryl Boronic Acids Enabled by High-Throughput Experimentation and Data Analysis		Helv. Chim. Acta	105	Coperet, C; Togni, A	FALSE	FALSE	FALSE	FALSE
1262	10.1002/anie.202110459	doi.org/10.1002/anie.202110459	Ni-Catalyzed Arylbenzylation of Alkenylarenes: Kinetic Studies Reveal Autocatalysis by ZnX2**		Angew. Chem.-Int. Edit.	105	Giri, R	FALSE	FALSE	FALSE	FALSE
1263	10.1002/ejoc.202100660	doi.org/10.1002/ejoc.202100660	Nickel-Catalyzed Cascade Reactions		Eur. J. Org. Chem.	105	Ghosh, T	FALSE	FALSE	FALSE	FALSE
1264	10.1002/anie.202104051	doi.org/10.1002/anie.202104051	Enantioselective Total Synthesis of the Archaeal Lipid Parallel GDGT-0 (Isocaldarchaeol)**		Angew. Chem.-Int. Edit.	105	Burns, NZ	FALSE	FALSE	FALSE	FALSE
1265	10.1039/d1sc01217g	doi.org/10.1039/d1sc01217g	Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines		Chem. Sci.	105	Maity, P	FALSE	FALSE	FALSE	FALSE
1266	10.1021/acs.joc.1c00573	doi.org/10.1021/acs.joc.1c00573	Reduced Phenalenyl in Catalytic Dehalogenative Deuteration and Hydrodehalogenation of Aryl Halides		J. Org. Chem.	105	Mandal, SK	FALSE	FALSE	FALSE	FALSE
1267	10.1039/d1sc00943e	doi.org/10.1039/d1sc00943e	Photoactive electron donor-acceptor complex platform for Ni-mediated C(sp(3))-C(sp(2)) bond formation		Chem. Sci.	105	Molander, GA	TRUE	FALSE	FALSE	FALSE
1268	10.1039/d1qo00370d	doi.org/10.1039/d1qo00370d	Rhodium(i)/bisoxazolinephosphine-catalyzed regio- and enantioselective amination of allylic carbonates: a computational study		Org. Chem. Front.	105	Huang, GP	FALSE	FALSE	FALSE	FALSE
1269	10.1039/c6qo00533k	doi.org/10.1039/c6qo00533k	AgNO3-catalyzed direct C-H arylation of quinolines by oxidative decarboxylation of aromatic carboxylic acids		Org. Chem. Front.	105	Yuan, JW; Qu, LB	FALSE	FALSE	FALSE	FALSE
1270	10.1039/c6ob02224c	doi.org/10.1039/c6ob02224c	Cobalt-promoted selective arylation of benzamides and acrylamides with arylboronic acids		Org. Biomol. Chem.	105	Tan, Z	FALSE	FALSE	FALSE	FALSE
1271	10.1016/j.tet.2015.12.040	doi.org/10.1016/j.tet.2015.12.040	Iron-catalyzed C-C bond formation via cross dehydrative coupling reaction of N-heterocyclic aminols with electron rich arenes: facile access to C4-aryl-dihydroquinazolines		Tetrahedron	105	Reddy, KR	FALSE	FALSE	FALSE	FALSE
1272	10.1055/a-1335-7070	doi.org/10.1055/a-1335-7070	Synthesis of Chiral Amines via Asymmetric Hydrogen Borrowing	Carbasugar sodium-glucose cotransporter 2 (SGLT2) inhibitors are highly promising drug candidates for the treatment of Type 2 diabetes mellitus (T2DM). However, the clinical usage of carbasugar SGLT2 inhibitors has been underexplored, due to the lengthy synthetic routes and the lack of structure-activity relationship (SAR) studies of these compounds. Herein, we report a concise and stereodivergent synthetic route towards some novel carbasugar SGLT2 inhibitors, featuring an underexploited, regioselective, and stereospecific palladium-catalyzed allyl-aryl coupling reaction. This synthetic strategy, together with computational modeling, revealed the unexpected SAR of these carbasugar SGLT2 inhibitors, and enabled the discovery of a highly selective and potent SGLT2 inhibitor.	Synlett	104	Wang, C	FALSE	FALSE	FALSE	FALSE
1273	10.1021/jacs.0c12462	doi.org/10.1021/jacs.0c12462	Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis	A mild and efficient, approach for highly regio- and enantioselective copper-catalyzed hydroboration of 1,1-diaryl substituted alkenes with bis(pinacolato)diboron (B(2)Pin(2)) was developed for the first time, providing facile access to a series of valuable beta,beta-diaryl substituted boronic esters with high enantiometric purity. Moreover, this approach could also be suitable for hydroboration of alpha-alkyl styrenes for the synthesis of enantioenriched beta,beta-arylalkyl substituted boronic esters. Gram-scale reaction, stereospecific derivatizations, and the application of important antimuscarinic drug (R)-tolterodine for concise enantioselective synthesis further highlighted :the attractiveness of this new approach.	J. Am. Chem. Soc.	104	Shu, XZ	FALSE	TRUE	FALSE	FALSE
1274	10.1002/anie.202012614	doi.org/10.1002/anie.202012614	Nickel-Catalyzed, Regio- and Enantioselective Benzylic Alkenylation of Olefins with Alkenyl Bromide	A quick access toward a 1,2-dialkyl-5-trifluoromethylbenzimidazoles library by a three-step synthesis sequence starting from 1chloro- 2-nitro-4-(trifluoromethyl) benzene is described. The synthesis proceed via o-phenylendiamines eficiently isolated, which also are key synthetic intermediates of another valuable heterocyclic compounds. Likewise, the trifluoromethyl group is part of the obtained benzimidazoles, affording an important structural feature for their possible applications. The advantages of this methodology are the modular lipophilicity of products, easy work-up, up to 83% overall yield, the convenient use of microwave-assisted reactions, and the production of compounds (intermediates and products) of high-added value using cheap reagents and simple protocols.	Angew. Chem.-Int. Edit.	104	Gong, HG	FALSE	FALSE	FALSE	FALSE
1275	10.1007/s11426-020-9838-x	doi.org/10.1007/s11426-020-9838-x	Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes	Aryl halides are very useful electrophiles for synthesizing various substituted aromatic compounds via metal-catalyzed cross-coupling reactions. Because of the high cost associated with their synthesis and the stoichiometric halide waste produced when using aryl halide feedstocks, cheaper and more sustainable alternatives have been explored, such as phenols. However, phenols have a very reactive hydroxyl group and a C-O bond with high dissociation energy. To overcome such challenges, earlier studies focused on finding ways to reduce the energy of the C-O bond while removing the active proton by transforming phenols into phenol derivatives (e.g., sulfonates, esters, carbamates, ethers, and metal salts). A greater ambition is to directly cross-couple phenols with nucleophiles via C-O cleavage. In this Perspective, we briefly summarize efforts and accomplishments concerning the cross-coupling of phenol derivatives and phenols.	Sci. China-Chem.	104	Lu, X; Fu, Y	FALSE	FALSE	FALSE	FALSE
1276	10.1021/acscatal.0c01436	doi.org/10.1021/acscatal.0c01436	Cobalta-Electrocatalyzed C-H Allylation with Unactivated Alkenes	A new tandem process is reported that provides access to -hydroxyamides from epoxides for the first time. Herein, we explore InCl3-mediated tandem rearrangement of epoxides to aldehydes and -addition of TosMIC to in situ derived aldehydes. An unprecedented C-C bond-forming reaction is disclosed that features mild conditions, high yields, and shorter reaction times.	ACS Catal.	104	Ackermann, L	FALSE	TRUE	FALSE	FALSE
1277	10.1021/acscatal.0c01232	doi.org/10.1021/acscatal.0c01232	Direct Allylic C(sp(3))-H Thiolation with Disulfides via Visible Light Photoredox Catalysis		ACS Catal.	104	Hong, SH	TRUE	FALSE	FALSE	FALSE
1278	10.1039/c9nj02542a	doi.org/10.1039/c9nj02542a	The N-alkylation of sulfonamides with alcohols in water catalyzed by a water-soluble metal-ligand bifunctional iridium complex [Cp*Ir(biimH(2))(H2O)][OTf](2)		New J. Chem.	104	Li, F	FALSE	FALSE	FALSE	FALSE
1279	10.1021/acs.joc.9b00598	doi.org/10.1021/acs.joc.9b00598	Regioselective Functionalization of 9,9-Dimethyl-9-silafluorenes by Borylation, Bromination, and Nitration		J. Org. Chem.	104	Murai, M; Takai, K	FALSE	FALSE	FALSE	FALSE
1280	10.1021/jacs.8b12495	doi.org/10.1021/jacs.8b12495	Cu(I)-Catalyzed 6-endo-dig Cyclization of Terminal Alkynes, 2-Bromoaryl Ketones, and Amides toward 1-Naphthylamines: Applications and Photophysical Properties		J. Am. Chem. Soc.	104	Dong, JY; Yuan, L; Zhou, YB	TRUE	FALSE	FALSE	FALSE
1281	10.1021/acs.organomet.8b00394	doi.org/10.1021/acs.organomet.8b00394	Synthesis and Characterization of [(NHC)Ni(styrene)(2)] Complexes: Isolation of Monocarbene Nickel Complexes and Benchmarking of %V-Bur in (NHC)Ni-pi Systems		Organometallics	104	Louie, J	FALSE	FALSE	FALSE	FALSE
1282	10.1021/acs.joc.8b00027	doi.org/10.1021/acs.joc.8b00027	Synthesis of 1,1 '-Diarylethanes and Related Systems by Displacement of Trichloroacetimidates with Trimethylaluminum		J. Org. Chem.	104	Chisholm, JD	FALSE	FALSE	FALSE	FALSE
1283	10.1002/anie.201505981	doi.org/10.1002/anie.201505981	Asymmetric Bronsted Acid Catalyzed Synthesis of Triarylmethanes-Construction of Communesin and Spiroindoline Scaffolds		Angew. Chem.-Int. Edit.	104	Rueping, M	FALSE	FALSE	FALSE	FALSE
1284	10.1002/chem.201501543	doi.org/10.1002/chem.201501543	Cobalt-Catalyzed Cross-Coupling of 3-and 4-Iodopiperidines with Grignard Reagents		Chem.-Eur. J.	104	Guerinot, A	FALSE	FALSE	FALSE	FALSE
1285	10.1016/j.jorganchem.2014.05.022	doi.org/10.1016/j.jorganchem.2014.05.022	Synthesis of pincer-type N-heterocyclic carbene palladium complexes with a hemilabile ligand and their application in cross-coupling catalysis		J. Organomet. Chem.	104	Albrecht, M	FALSE	FALSE	FALSE	FALSE
1286	10.1039/c4dt01856g	doi.org/10.1039/c4dt01856g	Synthesis of DMF-protected Au NPs with different size distributions and their catalytic performance in the Ullmann homocoupling of aryl iodides		Dalton Trans.	104	Li, HX	FALSE	FALSE	FALSE	FALSE
1287	10.1021/ja5099935	doi.org/10.1021/ja5099935	The Role of Aryne Distortions, Steric Effects, and Charges in Regioselectivities of Aryne Reactions		J. Am. Chem. Soc.	104	Garg, NK	FALSE	FALSE	FALSE	FALSE
1288	10.1002/anie.201309546	doi.org/10.1002/anie.201309546	Site-Differentiated Polyboron Arenes Prepared by Direct C-H Borylation and Their Highly Selective Suzuki-Miyaura Cross-Coupling Reactions		Angew. Chem.-Int. Edit.	104	Li, PF	FALSE	FALSE	FALSE	FALSE
1289	10.1055/s-0033-1339666	doi.org/10.1055/s-0033-1339666	Microwave-Assisted Efficient Synthesis of Aryl Thioethers through C-H Functionalization of Arenes		Synlett	104	Lee, CF	FALSE	FALSE	FALSE	FALSE
1290	10.1002/chem.201102644	doi.org/10.1002/chem.201102644	Palladium-Catalyzed Desulfitative C?H Arylation of Heteroarenes with Sodium Sulfinates		Chem.-Eur. J.	104	You, JS	FALSE	FALSE	FALSE	FALSE
1291	10.3762/bjoc.7.171	doi.org/10.3762/bjoc.7.171	Directed aromatic functionalization in natural-product synthesis: Fredericamycin A, nothapodytine B, and topopyrones B and D		Beilstein J. Org. Chem.	104	Ciufolini, MA	FALSE	FALSE	FALSE	FALSE
1292	10.1002/ejoc.201100175	doi.org/10.1002/ejoc.201100175	Sequential ATRA/Reductive Cyclopropanation Reactions with a Ruthenium Catalyst in the Presence of Manganese		Eur. J. Org. Chem.	104	Severin, K	FALSE	FALSE	FALSE	FALSE
1293	10.1039/b612235c	doi.org/10.1039/b612235c	Insights into the mechanism of the site-selective sequential palladium-catalyzed cross-coupling reactions of dibromothiophenes/dibromothiazoles and arylboronic acids. Synthesis of PPAR beta/delta agonists		Org. Biomol. Chem.	104	de Lera, AR	FALSE	FALSE	FALSE	FALSE
1294	10.1021/jo0257804	doi.org/10.1021/jo0257804	Synthesis and application of arylmonophosphinoferrocene ligands: Ultrafast asymmetric hydrosilylation of styrene		J. Org. Chem.	104	Johannsen, M	FALSE	FALSE	FALSE	FALSE
1295	10.1016/0040-4020(96)00246-3	doi.org/10.1016/0040-4020(96)00246-3	Preparation of polyfunctional aryl and alkenyl zinc halides from functionalized unsaturated organolithiums and their reactivity in cross-coupling and conjugated addition reactions		Tetrahedron	104		FALSE	FALSE	FALSE	FALSE
1296	10.1021/acscatal.1c02277	doi.org/10.1021/acscatal.1c02277	Pd-Catalyzed Ring-Closing/Ring-Opening Cross Coupling Reactions: Enantioselective Diarylation of Unactivated Olefins		ACS Catal.	104	Liu, LT	FALSE	FALSE	FALSE	FALSE
1297	10.1515/pac-2021-0110	doi.org/10.1515/pac-2021-0110	The exploration of deoxygenation reactions for alcohols and derivatives using earth-abundant reagents		Pure Appl. Chem.	104	Liu, MX	FALSE	FALSE	FALSE	FALSE
1298	10.1039/d1sc02547c	doi.org/10.1039/d1sc02547c	Photoinduced 1,2-dicarbofunctionalization of alkenes with organotrifluoroborate nucleophiles via radical/polar crossover		Chem. Sci.	104	Molander, GA	TRUE	FALSE	FALSE	FALSE
1299	10.1002/anie.202103327	doi.org/10.1002/anie.202103327	Direct Synthesis of Ketones from Methyl Esters by Nickel-Catalyzed Suzuki-Miyaura Coupling		Angew. Chem.-Int. Edit.	104	Newman, SG	FALSE	FALSE	FALSE	FALSE
1300	10.1002/asia.202100003	doi.org/10.1002/asia.202100003	Hydroboration of Nitriles, Esters, and Carbonates Catalyzed by Simple Earth-Abundant Metal Triflate Salts		Chem.-Asian J.	104	de Ruiter, G	FALSE	FALSE	FALSE	FALSE
1301	10.1002/anie.201705356	doi.org/10.1002/anie.201705356	Electrophilic Amination with Nitroarenes		Angew. Chem.-Int. Edit.	104	Niggemann, M	FALSE	TRUE	FALSE	FALSE
1302	10.1016/j.tet.2017.04.034	doi.org/10.1016/j.tet.2017.04.034	Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine		Tetrahedron	104	Ren, ZG; Lang, JP	FALSE	FALSE	FALSE	FALSE
1303	10.1002/chem.201600229	doi.org/10.1002/chem.201600229	Photocatalytic/Cu-Promoted C-H Activations: Visible-light-Induced ortho-Selective Perfluoroalkylation of Benzamides		Chem.-Eur. J.	104	Tan, Z	TRUE	FALSE	FALSE	FALSE
1304	10.1021/jacs.0c13093	doi.org/10.1021/jacs.0c13093	Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides	The Suzuki-Miyaura cross-coupling has been widely recognized as one of the most important methods for the construction of C-C bonds. However, in contrast to traditional aryl halide or pseudohalide electrophiles, coupling reactions with unactivated C-N and C-O electrophiles have proven significantly more challenging. Here we report the first general palladium-catalyzed Suzuki-Miyaura cross-coupling of both common amides and aryl esters through the selective cleavage of the C-N and C-O bonds under exceedingly mild conditions. Notably, for the first time we demonstrate selective C(acyl)-N and C(acyl)-O cleavage/cross-coupling under the same reaction conditions. The reaction uses a commercially available, bench-stable and operationally-convenient (eta(3)-1-t-Bu-indenyl) Pd(IPr)(Cl) precatalyst. Furthermore, we demonstrate that the reactivity of generic amides and aryl esters can be correlated with barriers to isomerization around the C(acyl)-X (X = N, O) bond, thus providing a blueprint for the development of a broad range of novel coupling reactions of ester and amide electrophiles by the selective activation of C-O and C-N bonds.	J. Am. Chem. Soc.	103	Li, C	FALSE	TRUE	FALSE	FALSE
1305	10.1016/j.molliq.2020.115174	doi.org/10.1016/j.molliq.2020.115174	Competition between the Hiyama and Suzuki-Miyaura Pd-catalyzed cross-coupling reaction mechanisms for the formation of some regioselective derivatives of quinoxaline and benzofuran; Which reaction mechanism is more favorable?	Non-precious-metal-catalyzed reactions are of increasing importance in chemistry due to the outstanding ecological and economic properties of these metals. In the subfield of metal-catalyzed direct C-H functionalization reactions, recent years have shown an increasing number of publications dedicated to this topic. Nickel, cobalt, and last but not least iron, have started to enter a field which was long dominated by precious metals such as palladium, rhodium, ruthenium, and iridium. The present review article summarizes the development of iron-, nickel-, and cobalt-catalyzed C-H functionalization reactions until the end of 2016, and discusses the scope and limitations of these transformations.	J. Mol. Liq.	103	Bayat, M	FALSE	FALSE	FALSE	FALSE
1306	10.1002/anie.202008262	doi.org/10.1002/anie.202008262	Design and Synthesis of TY-Phos and Application in Palladium-Catalyzed Enantioselective Fluoroarylation ofgem-Difluoroalkenes	Catalytic hydrophosphination is a useful technique for the synthesis of phosphines, however, the phosphine products have been little exploited as ligands in catalysis. We have selected three phosphines prepared by iron catalyzed hydrophosphination and used them as ligands in a series of cross-coupling reactions: Heck, Suzuki-Miyaura and Buchwald-Hartwig. Rather than limit the chemistry to simple cross-coupling partners which are almost guaranteed to perform well in these transformations, industrially relevant substrates which are challenging from and electronic and/or steric perspective, along with substrates which contain several heteroatoms, were explored in order to gauge the true potential of these phosphine ligands. (C) 2016 Elsevier Ltd. All rights reserved.	Angew. Chem.-Int. Edit.	103	Li, ZM; Zhang, JL	FALSE	FALSE	FALSE	FALSE
1307	10.1021/acs.joc.0c01732	doi.org/10.1021/acs.joc.0c01732	Experimental and Computational Study of the 1,5-O -> N Carbamoyl Snieckus-Fries-Type Rearrangement	A new calcium chloride mediated C-F bond cleavage in electron deficient fluoroarenes followed by functionalisation via C-Se/Te bond formation has been achieved in the absence of any additive/ligand/organometallic reagent. A series of functionalised organo-selenides and -tellurides were obtained in high yields by this procedure. The precise role of calcium and the possible mechanism have been proposed based on DFT analysis.	J. Org. Chem.	103	Sanz, R	FALSE	FALSE	FALSE	FALSE
1308	10.1016/j.trechm.2020.08.001	doi.org/10.1016/j.trechm.2020.08.001	Amide Bond Activation: The Power of Resonance	We describe the unprecedented formation of allenes by Ni-catalyzed cross-coupling of propargyl bromides with alkylzinc halides. The reaction regioselectivity is complementary to the previously reported formation of propargyl-coupled compounds. Experiments support the formation of Ni-I complexes as the active species and the participation of radical intermediates. Kinetic studies showed that the reaction is first order with respect to the electrophile, zero-order with respect to the nucleophile (fast transmetalation), and one-half order with respect to the metal catalyst. Mechanistic studies support a bimetallic Ni-I-based pathway that involves fast homolytic cleavage of the C-Br bond by an alkyl-Ni-I complex, followed by radical coordination to NiI that determines the observed regioselectivity.	Trends Chem.	103	Szostak, M	FALSE	FALSE	FALSE	FALSE
1309	10.1021/jacs.0c06904	doi.org/10.1021/jacs.0c06904	The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp(3))-O Arylation	A series of new biphenyl N,P-monophosphine ligands L have been developed by introduction of two methoxy groups to the biphenyl backbone. The ligands were found to be much more effective than their counterpart Buchwald ligands in Suzuki-Miyaura coupling reactions of sterically hindered and electron-rich aryl chlorides with aryl boronic acids. A variety of tri-ortho-substituted or tetraortho-substituted biaryls or hetero-biaryls were conveniently prepared in up to 99% yield by using L1-[Pd-2(dba)(3)] (dba = dibenzylideneacetone) as the catalyst.	J. Am. Chem. Soc.	103	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
1310	10.1002/chem.202001180	doi.org/10.1002/chem.202001180	Metal- and Reagent-Free Electrochemical Synthesis of Alkyl Arylsulfonates in a Multi-Component Reaction	The Ni-catalyzed reductive coupling of alkyl/aryl with other electrophiles has evolved to be an important protocol for the construction of C-C bonds. This chapter first emphasizes the recent progress on the Ni-catalyzed alkylation, arylation/vinylation, and acylation of alkyl electrophiles. A brief overview of CO2 fixation is also addressed. The chemoselectivity between the electrophiles and the reactivity of the alkyl substrates will be detailed on the basis of different Ni-catalyzed conditions and mechanistic perspective. The asymmetric formation of C(sp(3))-C(sp(2)) bonds arising from activated alkyl halides is next depicted followed by allylic carbonylation. Finally, the coupling of aryl halides with other C(sp(2))-electrophiles is detailed at the end of this chapter.	Chem.-Eur. J.	103	Waldvogel, SR	FALSE	TRUE	FALSE	FALSE
1311	10.1002/anie.202003288	doi.org/10.1002/anie.202003288	Palladium-Catalyzed Enantioselective Heck Carbonylation with a Monodentate Phosphoramidite Ligand: Asymmetric Synthesis of (+)-Physostigmine, (+)-Physovenine, and (+)-Folicanthine	Monocarba-closo-dodecaborate (1; [closo-CB11H12](-) or C1-carborane anion) is a symmetrical, stable anionic cluster, which possesses low nucleophilicity/basicity and exhibits three-dimensional aromaticity. In contrast to the rich applications of C2-carborane molecules (C2B10H12), the chemistry of the C1-carborane anion as a platform for functional molecules has not been thoroughly studied thus far due to the lack of its efficient functionalization. In particular, no efficient general methods are available for the introduction of aryl and sp(2)/sp-carbon groups at the carbon vertex of the C1-carborane anion. The unique electronic structure and potential applications of the C1-carborane anion prompted us to investigate methods to functionalize it. We developed a general, efficient C-C cross-coupling reaction of 1 under palladium catalysis which yields a variety of 1-C-functionalized C1-carborane derivatives. The use of copper (I) or lithium species as a transmetalating partner facilitated the cross-coupling process of the sterically hindered C1-carborane anion. The potential application of 1-C-arylated C1-carborane anion derivatives thus obtained were explored, some of which showed potential as pharmacophores and ionic liquid crystal behavior. Furthermore, conjugation between sigma- and pi-aromatic moieties in 1-C-arylated monocarba-closo-dodecaborate anion derivatives was identified by means of kinetic experimental studies combined with theoretical calculations.	Angew. Chem.-Int. Edit.	103	Guan, ZH	FALSE	FALSE	FALSE	FALSE
1312	10.1002/anie.202001571	doi.org/10.1002/anie.202001571	Alkyl Carbazates for Electrochemical Deoxygenative Functionalization of Heteroarenes	Room-temperature azole C-H arylations were accomplished with inexpensive copper(I) compounds by means of photoinduced catalysis. The expedient copper catalysis set the stage for site-selective C-H arylations of non-aromatic oxazolines under mild reaction conditions, and provides step-economical access to the alkaloid natural products balsoxin and texamine.	Angew. Chem.-Int. Edit.	103	Wang, Y	FALSE	TRUE	FALSE	FALSE
1313	10.1021/acs.organomet.0c00034	doi.org/10.1021/acs.organomet.0c00034	Silylpalladium Cations Enable the Cleavage of Nitrile C-CN Bonds	We report a strategy that combines alkene hydroacylation and enantioselective alpha-(hetero)arylation reactions to form a wide variety of nitrogen-containing heterocyclic ketones bearing alpha-chiral quaternary stereogenic centers. Exo-selective, intramolecular Ni-catalyzed hydroacylations of N-homoallylindole- and N-homoallylpyrrole-2-carboxaldehydes form alpha-substituted six-membered heterocyclic ketones in up to 95% yield, while N-heterocyclic carbene (NHC) catalyzed hydroacylations of N-allylindole- and N-allylpyrrole-2-carboxaldehydes form alpha-substituted five-membered heterocyclic ketones in up to 99% yield. The racemic five- and six-membered products of Ni- and NHC-catalyzed hydroacylation reactions are readily transformed into heterocyclic ketones containing an alpha-chiral quaternary stereogenic center by enantioselective Ni-catalyzed alpha-arylation and alpha-heteroarylation reactions. The chiral, nonracemic products formed through a combination of alkene hydroacylation and alpha-(hetero)arylation reactions are formed in moderate to high yields (4499%) with excellent enantioselectivities (typically >95% ee). The identity of the precatalyst for Ni-catalyzed alpha-(hetero)arylation is dictated by the identity of the alpha-substituted heterocyclic ketone starting material. alpha-(Hetero)arylations of six-membered heterocyclic ketones occur at 65-85 C in the presence of a catalyst generated in situ from Ni(COD)(2) and (R)-BINAP or (R)-DIFLUORPHOS. alpha-(Hetero)arylation of five-membered heterocyclic ketones must be conducted at room temperature in the presence of an [((R)-BINAP)Ni(eta(2)-NC-Ph)] precatalyst or a catalyst generated in situ from Ni(COD)(2), (R)-DIFLUORPHOS, and benzonitrile.	Organometallics	103	Lowe, J; Romano, N	FALSE	FALSE	FALSE	FALSE
1314	10.1021/jacs.0c00073	doi.org/10.1021/jacs.0c00073	Multistep Engineering of Synergistic Catalysts in a Metal-Organic Framework for Tandem C-O Bond Cleavage	The atom economical borrowing hydrogen methodology enables the use of alcohols as alkylating agents for selective C-C bond formation. A bifunctional 2-(2-pyridyl-2-ol)-1,10-phenanthroline (phenpy-OH) based Ru(II) complex (2) was found to be a highly efficient catalyst for the one-pot beta-alkylation of secondary alcohols with primary alcohols and double alkylation of cyclopentanol with different primary alcohols. Exploiting the metal-ligand cooperativity in complex 2, several aromatic, aliphatic and heteroatom substituted alcohols were selectively cross-coupled in high yields using significantly low catalyst loading (0.1 mol%). An outer-sphere mechanism is proposed for this system as exogenous PPh3 has no significant effect on the rate of the reaction. Notably, this is a rare one-pot strategy for beta-alkylation of secondary alcohols using a bifunctional Ru(II)-complex. Moreover, this atom-economical methodology displayed the highest cumulative turn over frequency (TOF) among all the reported transition metal complexes in cross coupling of alcohols.	J. Am. Chem. Soc.	103	Lin, WB	FALSE	FALSE	FALSE	FALSE
1315	10.1021/jacs.9b06608	doi.org/10.1021/jacs.9b06608	Three-Component Ruthenium-Catalyzed Direct Meta-Selective C-H Activation of Arenes: A New Approach to the Alkylarylation of Alkenes		J. Am. Chem. Soc.	103	Liang, YM	FALSE	FALSE	FALSE	FALSE
1316	10.1002/chem.201900582	doi.org/10.1002/chem.201900582	Palladium-Catalyzed Decarboxylative Alkynylation of alpha-Acyloxyketones by C(sp(3))-O Bond Cleavage		Chem.-Eur. J.	103	Doi, R; Sato, Y	FALSE	FALSE	FALSE	FALSE
1317	10.1039/c8sc05063e	doi.org/10.1039/c8sc05063e	Nickel-catalyzed oxidative C-H/N-H annulation of N-heteroaromatic compounds with alkynes		Chem. Sci.	103	Chatani, N	FALSE	FALSE	FALSE	FALSE
1318	10.1002/anie.201712520	doi.org/10.1002/anie.201712520	Regiospecific ortho-C-H Allylation of Benzoic Acids		Angew. Chem.-Int. Edit.	103	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
1319	10.1055/s-0037-1609732	doi.org/10.1055/s-0037-1609732	Bronsted Acid Catalyzed Dehydrative Arylation of 4-Indolylmethanols with Indoles: Efficient Access to Indolyl-Substituted Triarylmethanes		Synthesis	103	Du, BX; Mei, GJ; Shi, F	FALSE	FALSE	FALSE	FALSE
1320	10.1039/c7sc04604a	doi.org/10.1039/c7sc04604a	The mechanism of directed Ni(II)-catalyzed C-H iodination with molecular iodine		Chem. Sci.	103	Musaev, DG	FALSE	FALSE	FALSE	FALSE
1321	10.1002/ejoc.201701654	doi.org/10.1002/ejoc.201701654	Iron-Catalyzed C(sp(2))-C(sp(3)) Cross-Coupling of Alkyl Grignard Reagents with Polyaromatic Tosylates		Eur. J. Org. Chem.	103	Szostak, M	FALSE	FALSE	FALSE	FALSE
1322	10.1016/j.tetlet.2017.09.022	doi.org/10.1016/j.tetlet.2017.09.022	New C-2-symmetric six-membered carbene ligands incorporating two hydroxyl groups for palladium-catalyzed deprotonative-cross-coupling processes (DCCP) of sp(3) C-H bonds in diarylmethanes		Tetrahedron Lett.	103	Li, J	FALSE	FALSE	FALSE	FALSE
1323	10.1007/s11164-014-1880-6	doi.org/10.1007/s11164-014-1880-6	Synthetic journey towards transition metal-free arylations		Res. Chem. Intermed.	103	Roopan, SM	FALSE	FALSE	FALSE	FALSE
1324	10.1021/ja511236d	doi.org/10.1021/ja511236d	Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration		J. Am. Chem. Soc.	103	Tantillo, DJ	FALSE	FALSE	FALSE	FALSE
1325	10.1039/c5dt00435g	doi.org/10.1039/c5dt00435g	Solid state and solution studies of lithium tris(n-butyl)magnesiates stabilised by Lewis donors		Dalton Trans.	103	O'Hara, CT	FALSE	FALSE	FALSE	FALSE
1326	10.1515/pac-2014-5038	doi.org/10.1515/pac-2014-5038	Beyond C-H and C-O activation: the evolution of components in cross-coupling reactions		Pure Appl. Chem.	103	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
1327	10.1021/ja413131m	doi.org/10.1021/ja413131m	Nickel-Catalyzed Site-Selective Alkylation of Unactivated C(sp(3))-H Bonds		J. Am. Chem. Soc.	103	Ge, HB	FALSE	FALSE	FALSE	FALSE
1328	10.1039/c4ob01041h	doi.org/10.1039/c4ob01041h	P,N,N-Pincer nickel-catalyzed cross-coupling of aryl fluorides and chlorides		Org. Biomol. Chem.	103	Wang, ZX	FALSE	FALSE	FALSE	FALSE
1329	10.1021/om800711g	doi.org/10.1021/om800711g	Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni-2(mu-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides		Organometallics	103	Chen, WZ	FALSE	FALSE	FALSE	FALSE
1330	10.1055/s-2005-918455	doi.org/10.1055/s-2005-918455	A concise account of recent S(N)2 ' Grignard coupling reactions in organic synthesis		Synthesis	103	Kar, A	FALSE	FALSE	FALSE	FALSE
1331	10.1016/S0010-8545(02)00201-1	doi.org/10.1016/S0010-8545(02)00201-1	Group 10 metal indenyl complexes		Coord. Chem. Rev.	103	Zargarian, D	FALSE	FALSE	FALSE	FALSE
1332	10.1021/ja00271a037	doi.org/10.1021/ja00271a037	PALLADIUM-CATALYZED COUPLING OF VINYL TRIFLATES WITH ORGANOSTANNANES - SYNTHETIC AND MECHANISTIC STUDIES		J. Am. Chem. Soc.	103		FALSE	FALSE	FALSE	FALSE
1333	10.1021/acs.inorgchem.1c01720	doi.org/10.1021/acs.inorgchem.1c01720	Using J(PP) to Identify Ni Bidentate Phosphine Complexes In Situ		Inorg. Chem.	103	Zimmerman, PM	FALSE	FALSE	FALSE	FALSE
1334	10.1039/c7sc01556a	doi.org/10.1039/c7sc01556a	Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylation		Chem. Sci.	103	Hou, GH	FALSE	FALSE	FALSE	FALSE
1335	10.1021/acscatal.6b02124	doi.org/10.1021/acscatal.6b02124	Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2		ACS Catal.	103	Martin, R	FALSE	FALSE	FALSE	FALSE
1336	10.1002/adsc.201600654	doi.org/10.1002/adsc.201600654	Tandem C(sp(3))-H Arylation/Oxidation and Arylation/Allylic Substitution of Isoindolinones		Adv. Synth. Catal.	103	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
1337	10.1021/acs.joc.6b00203	doi.org/10.1021/acs.joc.6b00203	Nickel-Catalyzed Regioselective Cleavage of C-sp2-S Bonds: Method for the Synthesis of Tri- and Tetrasubstituted Alkenes		J. Org. Chem.	103	Xu, XH; Qiu, RH	FALSE	FALSE	FALSE	FALSE
1338	10.1002/adsc.201500884	doi.org/10.1002/adsc.201500884	Copper-Mediated ortho-Arylation of Benzamides with Arylboronic Acid		Adv. Synth. Catal.	103	Tan, Z	FALSE	FALSE	FALSE	FALSE
1339	10.1021/acs.joc.5b02557	doi.org/10.1021/acs.joc.5b02557	Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C-N Bond Cleavage		J. Org. Chem.	103	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
1340	10.1039/c5ob02178b	doi.org/10.1039/c5ob02178b	Rawal's catalyst as an effective stimulant for the highly asymmetric Michael addition of beta-keto esters to functionally rich nitro-olefins		Org. Biomol. Chem.	103	Ramachary, DB	FALSE	FALSE	FALSE	FALSE
1341	10.1021/acs.joc.0c02346	doi.org/10.1021/acs.joc.0c02346	Substituted 9-Diethylaminobenzo[a]phenoxazin-5-ones (Nile Red Analogues): Synthesis and Photophysical Properties	Despite the wide use of aryl radicals in organic synthesis, current methods to prepare them from aryl halides, carboxylic acids, boronic acids, and diazonium salts suffer from limitations. Aryl triflates, easily obtained from phenols, are promising aryl radical progenitors but remain elusive in this regard. Inspired by the single electron transfer process for aryl halides to access aryl radicals, we developed a simple and efficient protocol to convert aryl triflates to aryl radicals. Our success lies in exploiting sodium iodide as the soft electron donor assisted by light. This strategy enables the scalable synthesis of two types of important organic molecules, i.e., aryl boronates and aryl iodides, in good to high yields, with broad functional group compatibility in a transition-metal-free manner at room temperature. This protocol is anticipated to find potential applications in other aryl-radical-involved reactions by using aryl triflates as aryl radical precursors.	J. Org. Chem.	102	Hornum, M	TRUE	FALSE	FALSE	FALSE
1342	10.1002/cctc.202001347	doi.org/10.1002/cctc.202001347	Cobalt-NHC Catalyzed C(sp(2))-C(sp(3)) and C(sp(2))-C(sp(2)) Kumada Cross-Coupling of Aryl Tosylates with Alkyl and Aryl Grignard Reagents	A polystyrene-cross-linking bisphosphine PSDPPBz was synthesized through radical emulsion copolymer-ization between 4-t-butylstyrene as a monomer and tetraviny-lated 1,2-bis(diphenylphosphino)benzene (DPPBz) as a 4-fold cross-linker. The location of the DPPBz bisphosphine moiety at the branching points of the cross-linked network organic polymer allowed controlled bisphosphine monochelation to transition metals under conditions where homogeneous ligands may form bischelated single metal complexes or multinuclear complexes. PS-DPPBz showed high ligand performance in first-row transition metal catalysis, enabling challenging molecular Alkyl transformations that were not possible through the screening of existing homogeneous ligands. In the Ni-catalyzed amination of aryl chlorides with N-alkyl-substituted primary amines, the substrate scope has been expanded to include 2,6-disubstituted aryl chlorides and N-tertiary-alkyl-substituted primary amines. PS-DPPBz was effective for the Ni-catalyzed C-H/C-O coupling between 1,3-azoles and monocyclic aryl pivalates, which showed poor reactivity in the reported homogeneous catalytic system based on 1,2-bis(dicyclohexylphosphino)ethane (DCYPE). The usefulness of the polymer-cross-linking strategy was also demonstrated in alkene hydroboration reactions catalyzed by Cu or Co.	ChemCatChem	102	Szostak, M	FALSE	FALSE	FALSE	FALSE
1343	10.3390/molecules25214970	doi.org/10.3390/molecules25214970	Recent Developments in Transition-Metal Catalyzed Direct C-H Alkenylation, Alkylation, and Alkynylation of Azoles	While chemoselectivities in Pd-0-catalyzed coupling reactions are frequently non-intuitive and a result of a complex interplay of ligand/catalyst, substrate, and reaction conditions, we herein report a general method based on Pd-I that allows for an a priori predictable chemoselective C-sp2-C-sp2 coupling at C-Br in preference to C-OTf and C-Cl bonds, regardless of the electronic or steric bias of the substrate. The C-C bond formations are extremely rapid (<5min at RT) and are catalyzed by an air- and moisture-stable Pd-I dimer under open-flask conditions.	Molecules	102	Van der Eycken, EV; Sharma, UK	FALSE	FALSE	FALSE	FALSE
1344	10.1021/acs.organomet.0c00021	doi.org/10.1021/acs.organomet.0c00021	Radical Capture at Nickel(II) Complexes: C-C, C-N, and C-O Bond Formation	Peracetic acid promoted C-Se coupling reaction of arenes with diselenides under metal-free and solvent-free conditions has been described. The resulting selenide ethers were obtained in good to excellent yields. Peracetic acid provided the selenide ethers via sp(2) C-H selenation whereas previously in case of DTBP sp(3) C-H selenation was observed.	Organometallics	102	Warren, TH	FALSE	FALSE	FALSE	FALSE
1345	10.1021/acs.biomac.9b01765	doi.org/10.1021/acs.biomac.9b01765	Me-6-TREN/TREN Mixed-Ligand Effect During SET-LRP in the Catalytically Active DMSO Revitalizes TREN into an Excellent Ligand	A user-friendly Ni-catalyzed reductive carboxylation of benzylic C-N bonds with CO2 is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as homodimerization or -hydride elimination, thus leading to new knowledge in cross-electrophile reactions.	Biomacromolecules	102	Lligadas, G; Percec, V	FALSE	FALSE	FALSE	FALSE
1346	10.1055/s-0039-1691487	doi.org/10.1055/s-0039-1691487	Suzuki-Miyaura Cross-Couplings under Acidic Conditions	A catalytic system consisting of 5 mol% CoCl2 and 10 mol% isoquinoline allows a convenient cross-coupling of benzylic zinc reagents with various aryl and heteroaryl bromides or chlorides leading to poly-functionalized diaryl-and aryl-heteroaryl-methane derivatives.	Synthesis	102	Schmidt, A	FALSE	FALSE	FALSE	FALSE
1347	10.1002/asia.201900968	doi.org/10.1002/asia.201900968	Base-Mediated O-Arylation of Alcohols and Phenols by Triarylsulfonium Triflates		Chem.-Asian J.	102	Zhang, CP	FALSE	FALSE	FALSE	FALSE
1348	10.1126/science.aaw3254	doi.org/10.1126/science.aaw3254	Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes		Science	102	Konig, B	FALSE	FALSE	FALSE	FALSE
1349	10.1002/cssc.201900914	doi.org/10.1002/cssc.201900914	Sustainable Knowledge-Driven Approaches in Transition-Metal-Catalyzed Transformations		ChemSusChem	102	Perez-Temprano, MH	FALSE	FALSE	FALSE	FALSE
1350	10.1002/cssc.201900799	doi.org/10.1002/cssc.201900799	Iron-Catalyzed Borrowing Hydrogen C-Alkylation of Oxindoles with Alcohols		ChemSusChem	102	Morrill, LC	FALSE	FALSE	FALSE	FALSE
1351	10.1002/adsc.201801586	doi.org/10.1002/adsc.201801586	Nickel-Catalyzed C(sp(2))-C(sp(3)) Kumada Cross-Coupling of Aryl Tosylates with Alkyl Grignard Reagents		Adv. Synth. Catal.	102	Szostak, M	FALSE	FALSE	FALSE	FALSE
1352	10.1002/cjoc.201800575	doi.org/10.1002/cjoc.201800575	Stereoselective Synthesis of Vinylboronates by Rh-Catalyzed Borylation of Stereoisomeric Mixtures		Chin. J. Chem.	102	Zhao, WX	FALSE	FALSE	FALSE	FALSE
1353	10.1021/acscatal.9b00521	doi.org/10.1021/acscatal.9b00521	Migratory Reductive Acylation between Alkyl Halides or Alkenes and Alkyl Carboxylic Acids by Nickel Catalysis		ACS Catal.	102	Zhu, SL; Wang, Y	FALSE	FALSE	FALSE	FALSE
1354	10.1055/s-0037-1611659	doi.org/10.1055/s-0037-1611659	Transition-Metal-Catalyzed Alkyl Heck-Type Reactions		Synthesis	102	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
1355	10.1021/acs.orglett.9b00100	doi.org/10.1021/acs.orglett.9b00100	Synthesis of 3-(Methylsulfonyl)benzo[b]thiophenes from Methyl(2-alkynylphenyl)sulfanes and Sodium Metabisulfite via a Radical Relay Strategy		Org. Lett.	102	Ye, SQ; Wu, J	FALSE	FALSE	FALSE	FALSE
1356	10.1021/acs.joc.8b03114	doi.org/10.1021/acs.joc.8b03114	Copper Catalyzed Oxidative C-C Bond Cleavage of 1,2-Diketones: A Divergent Approach to 1,8-Naphthalimides, Biphenyl-2,2 '-dicarboxamides, and N-Heterocyclic Amides		J. Org. Chem.	102	Kaliappan, KP	FALSE	FALSE	FALSE	FALSE
1357	10.1246/bcsj.20180333	doi.org/10.1246/bcsj.20180333	Iron-Catalyzed Cross Coupling of Aryl Chlorides with Alkyl Grignard Reagents: Synthetic Scope and Fe-II/Fe-IV Mechanism Supported by X-ray Absorption Spectroscopy and Density Functional Theory Calculations		Bull. Chem. Soc. Jpn.	102	Nakamura, M	FALSE	FALSE	FALSE	FALSE
1358	10.1021/jacs.7b08326	doi.org/10.1021/jacs.7b08326	Enantiospecific and Iterative Suzuki-Miyaura Cross-Couplings		J. Am. Chem. Soc.	102	Crudden, CM	FALSE	FALSE	FALSE	FALSE
1359	10.1039/c5ee03256c	doi.org/10.1039/c5ee03256c	Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism		Energy Environ. Sci.	102	Marks, TJ	FALSE	FALSE	FALSE	FALSE
1360	10.1002/ejoc.201500610	doi.org/10.1002/ejoc.201500610	Copper/Selectfluor-System-Catalyzed Dehydration-Oxidation of Tertiary Cycloalcohols: Access to beta-Substituted Cyclohex-2-enones, 4-Arylcoumarins, and Biaryls		Eur. J. Org. Chem.	102	Liu, YK	FALSE	FALSE	FALSE	FALSE
1361	10.1021/om500593s	doi.org/10.1021/om500593s	Mesoionic Triazolylidene Nickel Complexes: Synthesis, Ligand Lability, and Catalytic C-C Bond Formation Activity		Organometallics	102	Albrecht, M	FALSE	FALSE	FALSE	FALSE
1362	10.1021/ja412547r	doi.org/10.1021/ja412547r	Chemo-, Regio-, and Stereoselective Silver-Catalyzed Aziridination of Dienes: Scope, Mechanistic Studies, and Ring-Opening Reactions		J. Am. Chem. Soc.	102	Diaz-Requejo, MM	FALSE	FALSE	FALSE	FALSE
1363	10.1016/j.tetlet.2013.06.009	doi.org/10.1016/j.tetlet.2013.06.009	Rhodium-catalyzed hydroaroylation of alpha,beta-unsaturated esters using aroyl chlorides and Et2MeSiH		Tetrahedron Lett.	102	Ueno, K	FALSE	FALSE	FALSE	FALSE
1364	10.1002/ejoc.201101378	doi.org/10.1002/ejoc.201101378	A Cyclobutene-1,2-bis(imidazolium) Salt as Preligand for Palladium-Catalyzed Cross-Coupling Reactions: Properties and Applications		Eur. J. Org. Chem.	102	Schmidt, A	FALSE	FALSE	FALSE	FALSE
1365	10.1021/om200864z	doi.org/10.1021/om200864z	Synthesis and Structural Characterization of Half-Sandwich Nickel Complexes Bearing Two Different N-Heterocyclic Carbene Ligands		Organometallics	102	Ritleng, V	FALSE	FALSE	FALSE	FALSE
1366	10.1002/ejoc.200901101	doi.org/10.1002/ejoc.200901101	Green Synthesis of Vicinal Dithioethers and Alkenyl Thioethers from the Reaction of Alkynes and Thiols in Water		Eur. J. Org. Chem.	102	Hammond, GB	FALSE	FALSE	FALSE	FALSE
1367	10.1016/j.tet.2007.10.091	doi.org/10.1016/j.tet.2007.10.091	Naphthidine di(radical cation)s-stabilized palladium nanoparticles for efficient catalytic Suzuki-Miyaura cross-coupling reactions		Tetrahedron	102	Schneider, R	FALSE	FALSE	FALSE	FALSE
1368	10.1039/b803172j	doi.org/10.1039/b803172j	Nickel-catalysed reactions with trialkylboranes and silacyclobutanes		Chem. Commun.	102	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
1369	10.1021/om700796g	doi.org/10.1021/om700796g	Synthesis and structural characterization of nickel(II) complexes supported by pyridine-functionalized N-heterocyclic carbene ligands and their catalytic acitivities for Suzuki coupling		Organometallics	102	Chen, WZ	FALSE	FALSE	FALSE	FALSE
1370	10.1021/om0602759	doi.org/10.1021/om0602759	Zerovalent N-heterocyclic carbene complexes of palladium and nickel dimethyl fumarate: Synthesis, structure, and dynamic behavior		Organometallics	102	Cavell, KJ	FALSE	FALSE	FALSE	FALSE
1371	10.1039/d1sc06364b	doi.org/10.1039/d1sc06364b	Phosphine-catalyzed divergent domino processes between gamma-substituted allenoates and carbonyl-activated alkenes		Chem. Sci.	102	Lu, YX	FALSE	FALSE	FALSE	FALSE
1372	10.1021/jacs.1c09705	doi.org/10.1021/jacs.1c09705	Palladium-Catalyzed Remote Diborylative Cyclization of Dienes with Diborons via Chain Walking		J. Am. Chem. Soc.	102	Kochi, T	FALSE	FALSE	FALSE	FALSE
1373	10.1002/chem.202103093	doi.org/10.1002/chem.202103093	Case Study of N-Pr-i versus N-Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC)(2)]		Chem.-Eur. J.	102	Radius, U	FALSE	FALSE	FALSE	FALSE
1374	10.1039/d1ob01707a	doi.org/10.1039/d1ob01707a	Transition metal-catalyzed arylation of unstrained C-C single bonds		Org. Biomol. Chem.	102	Zhou, XG	FALSE	FALSE	FALSE	FALSE
1375	10.1002/chem.202101906	doi.org/10.1002/chem.202101906	Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C-S/C-N Couplings		Chem.-Eur. J.	102	Nicasio, MC	FALSE	FALSE	FALSE	FALSE
1376	10.6023/cjoc201702013	doi.org/10.6023/cjoc201702013	Progress on Transition Metal-Catalyzed Asymmetric Allylic Alkylation Reaction of 1,3-Dicarbonyl Compounds		Chin. J. Org. Chem.	102	Song, WZ	FALSE	FALSE	FALSE	FALSE
1377	10.1002/chem.201602202	doi.org/10.1002/chem.201602202	Efficient Synthesis of Diaryl Ketones by Nickel-Catalyzed Negishi Cross-Coupling of Amides by Carbon-Nitrogen Bond Cleavage at Room Temperature Accelerated by a Solvent Effect		Chem.-Eur. J.	102	Szostak, M	FALSE	FALSE	FALSE	FALSE
1378	10.1039/c5dt04429d	doi.org/10.1039/c5dt04429d	NHC-based pincer ligands: carbenes with a bite		Dalton Trans.	102	Chaplin, AB	FALSE	FALSE	FALSE	FALSE
1379	10.6023/cjoc202005050	doi.org/10.6023/cjoc202005050	Applications of (NHC)Ni(II) Catalyzed [3+2] Hydroalkenylation-Rearrangement Cascades	Metal-catalyzed transformations that forge carbon heteroatom bonds are of central importance in organic synthesis. Despite the formidable potential of aryl methyl ethers as coupling partners, the scarcity of metal-catalyzed C-heteroatom bond formations via C-OMe cleavage is striking, with isolated precedents requiring specialized, yet expensive, ligands, high temperatures, and pi-extended backbones. We report an unprecedented catalytic ipso-silylation of aryl methyl ethers under mild conditions and without recourse to external ligands. The method is distinguished by its wide scope, which includes the use of benzyl methyl ethers, vinyl methyl ethers, and unbiased anisole derivatives, thus representing a significant step forward for designing new C-heteroatom bond formations via C-OMe scission. Applications of this transformation in orthogonal silylation techniques as well as in further derivatizations are also described. Preliminary mechanistic experiments suggest the intermediacy of Ni(0)-ate complexes, leaving some doubt that a canonical catalytic cycle consisting of an initial oxidative addition of the C-OMe bond to Ni(0) species comes into play.	Chin. J. Org. Chem.	101	Huang, JQ; He, ZY	FALSE	FALSE	FALSE	FALSE
1380	10.1021/acs.inorgchem.9b03049	doi.org/10.1021/acs.inorgchem.9b03049	Ruthenium(II) Complexes of Heteroditopic N-Heterocyclic Carbene Ligands: Efficient Catalysts for C-N Bond Formation via a Hydrogen-Borrowing Strategy under Solvent-Free Conditions		Inorg. Chem.	101	Rit, A	FALSE	FALSE	FALSE	FALSE
1381	10.1021/acs.joc.9b02785	doi.org/10.1021/acs.joc.9b02785	Nature of the Nucleophilic Oxygenation Reagent Is Key to Acid-Free Gold-Catalyzed Conversion of Terminal and Internal Alkynes to 1,2-Dicarbonyls		J. Org. Chem.	101	Dubovtsev, AY; Kukushkin, VY	FALSE	FALSE	FALSE	FALSE
1382	10.2174/1385272824999200914111246	doi.org/10.2174/1385272824999200914111246	Microwave-assisted Amination Reactions: An Overview		Curr. Org. Chem.	101	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
1383	10.1002/aoc.5385	doi.org/10.1002/aoc.5385	CuI-catalyzed direct synthesis of diaryl thioethers from aryl boronic acids and arylsulfonyl chlorides		Appl. Organomet. Chem.	101	Liu, JB	FALSE	FALSE	FALSE	FALSE
1384	10.1002/anie.201908029	doi.org/10.1002/anie.201908029	Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents		Angew. Chem.-Int. Edit.	101	Morken, JP	FALSE	FALSE	FALSE	FALSE
1385	10.1016/j.isci.2019.08.021	doi.org/10.1016/j.isci.2019.08.021	Synthesis of Biaryls via Decarbonylative Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Carboxylic Acids		iScience	101	Szostak, M	FALSE	FALSE	FALSE	FALSE
1386	10.1002/asia.201900960	doi.org/10.1002/asia.201900960	A Cascade Synthesis of Hetero-arylated Triarylmethanes Through a Double 5-endo-dig Cyclization Sequence		Chem.-Asian J.	101	Anand, RV	FALSE	FALSE	FALSE	FALSE
1387	10.1021/jacs.9b05224	doi.org/10.1021/jacs.9b05224	Reductive Coupling between C-N and C-O Electrophiles		J. Am. Chem. Soc.	101	Shu, XZ	FALSE	TRUE	FALSE	FALSE
1388	10.1002/anie.201906954	doi.org/10.1002/anie.201906954	Asymmetric Synthesis of Enantioenriched 2-Aryl-2,3-Dihydrobenzofurans by a Lewis Acid Catalyzed Cyclopropanation/Intramolecular Rearrangement Sequence		Angew. Chem.-Int. Edit.	101	Ryu, DH	FALSE	FALSE	FALSE	FALSE
1389	10.1002/anie.201906199	doi.org/10.1002/anie.201906199	Stereoconvergent, Redox-Neutral Access to Tetrahydroquinoxalines through Relay Epoxide Opening/Amination of Alcohols		Angew. Chem.-Int. Edit.	101	Zhang, Y; Xia, LX	FALSE	FALSE	FALSE	FALSE
1390	10.1021/jacs.9b00939	doi.org/10.1021/jacs.9b00939	Ni(I)-X Complexes Bearing a Bulky alpha-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals		J. Am. Chem. Soc.	101	Chirik, PJ	FALSE	FALSE	FALSE	FALSE
1391	10.1002/ejoc.201801290	doi.org/10.1002/ejoc.201801290	Facile Synthesis of 1,3,5-Triarylbenzenes and 4-Aryl-NH-1,2,3-Triazoles Using Mesoporous Pd-MCM-41 as Reusable Catalyst		Eur. J. Org. Chem.	101	Banerjee, S	FALSE	FALSE	FALSE	FALSE
1392	10.1021/acs.oprd.8b00182	doi.org/10.1021/acs.oprd.8b00182	N-Acyl-5,5-dimethylhydantoin, a New Mild Acyl-Transfer Reagent in Pd Catalysis: Highly Efficient Synthesis of Functionalized Ketones		Org. Process Res. Dev.	101	Zeng, Z	FALSE	FALSE	FALSE	FALSE
1393	10.1021/acs.organomet.7b00894	doi.org/10.1021/acs.organomet.7b00894	Theoretical Investigation on Ni-Catalyzed C(sp(3))-F Activation and Ring Contraction of Tetrahydropyrans: Exploration of an S(N)2 Pathway		Organometallics	101	Jiang, JL; Fu, Y	FALSE	FALSE	FALSE	FALSE
1394	10.1039/c7gc02627g	doi.org/10.1039/c7gc02627g	Stable and reusable nanoscale Fe2O3-catalyzed aerobic oxidation process for the selective synthesis of nitriles and primary amides		Green Chem.	101	Jagadeesh, RV	FALSE	FALSE	FALSE	FALSE
1395	10.1002/cjoc.201700596	doi.org/10.1002/cjoc.201700596	Rh/Lewis Acid Catalyzed Regio-, Diastereo- and Enantioselective Addition of 2-Acyl Imidazoles with Allenes		Chin. J. Chem.	101	Kang, Q	FALSE	FALSE	FALSE	FALSE
1396	10.1021/acs.joc.5b01978	doi.org/10.1021/acs.joc.5b01978	Zinc-Mediated Allylation and Benzylation of Phenylazocarboxylic Esters		J. Org. Chem.	101	Heinrich, MR	FALSE	FALSE	FALSE	FALSE
1397	10.1080/17415993.2015.1057512	doi.org/10.1080/17415993.2015.1057512	Synthesis and reactivity of imidazole-1-sulfonate esters (imidazylates) in substitution, elimination, and metal-catalyzed cross-coupling reactions: a review		J. Sulfur Chem.	101	Saeidian, H	FALSE	FALSE	FALSE	FALSE
1398	10.1002/ajoc.201402154	doi.org/10.1002/ajoc.201402154	Transition-Metal-Free Syntheses of Pyridine-Containing Thioethers Through Two-Fold C-S Bond Formation		Asian J. Org. Chem.	101	Lee, CF	FALSE	FALSE	FALSE	FALSE
1399	10.1039/c4ob00669k	doi.org/10.1039/c4ob00669k	Design and synthesis of (S)- and (R)-alpha-(phenyl)-ethylamine-derived NH-type ligands and their application for the chemical resolution of alpha-amino acids		Org. Biomol. Chem.	101	Acena, JL	FALSE	FALSE	FALSE	FALSE
1400	10.1002/chem.201403103	doi.org/10.1002/chem.201403103	Water-Soluble Luminescent Cyclometalated Gold(III) Complexes with cis-Chelating Bis(N-Heterocyclic Carbene) Ligands: Synthesis and Photophysical Properties		Chem.-Eur. J.	101	Che, CM	TRUE	FALSE	FALSE	FALSE
1401	10.1039/c3ob41560k	doi.org/10.1039/c3ob41560k	Preparations of SF5- and CF3-substituted arenes utilizing the 7-oxabicyclo[2.2.1]hept-2-ene synthones		Org. Biomol. Chem.	101	Ponomarenko, MV	FALSE	FALSE	FALSE	FALSE
1402	10.1021/ol4011757	doi.org/10.1021/ol4011757	Programmed Selective sp(2) C-O Bond Activation toward Multiarylated Benzenes		Org. Lett.	101	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
1403	10.1002/chem.201200039	doi.org/10.1002/chem.201200039	Aromatic-Amide-Derived Olefins as a Springboard: Isomerization-Initiated Palladium-Catalyzed Hydrogenation of Olefins and Reductive Decarbonylation of Acyl Chlorides with Hydrosilane		Chem.-Eur. J.	101	Xu, LW	FALSE	FALSE	FALSE	FALSE
1404	10.1002/anie.201100631	doi.org/10.1002/anie.201100631	Allyl-, Allenyl-, and Propargyl-Transfer Reactions through Cleavage of C-C Bonds Catalyzed by an N-Heterocyclic Carbene/Copper Complex: Synthesis of Multisubstituted Pyrroles		Angew. Chem.-Int. Edit.	101	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
1405	10.1016/j.tet.2009.04.005	doi.org/10.1016/j.tet.2009.04.005	Synthesis of chiral oxime ethers based on regio- and enantioselective allylic substitution catalyzed by iridium-pybox complex		Tetrahedron	101	Miyabe, H	FALSE	FALSE	FALSE	FALSE
1406	10.1039/b306635e	doi.org/10.1039/b306635e	C-F activation and hydrodefluorination of fluorinated alkenes at rhodium		Dalton Trans.	101	Braun, T	FALSE	FALSE	FALSE	FALSE
1407	10.1021/jo991686k	doi.org/10.1021/jo991686k	Coupling reactions of alkynylsilanes mediated by a Cu(I) salt: Novel syntheses of conjugate diynes and disubstituted ethynes		J. Org. Chem.	101	Mori, A	FALSE	FALSE	FALSE	FALSE
1408	10.1002/anie.202201370	doi.org/10.1002/anie.202201370	Nickel-Catalyzed Intermolecular Asymmetric Addition of Aryl Iodides across Aldehydes		Angew. Chem.-Int. Edit.	101	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
1409	10.3390/molecules26226968	doi.org/10.3390/molecules26226968	Electrochemical Organic Synthesis of Electron-Rich Biaryl Scaffolds: An Update		Molecules	101	Medici, F; Benaglia, M	FALSE	TRUE	FALSE	FALSE
1410	10.1016/j.tet.2021.132479	doi.org/10.1016/j.tet.2021.132479	Iron catalyzed metal-ligand cooperative approaches towards sustainable synthesis of quinolines and quinazolin-4(3H)-ones		Tetrahedron	101	Paul, ND	FALSE	FALSE	FALSE	FALSE
1411	10.3390/catal11080972	doi.org/10.3390/catal11080972	Acenaphthene-Based N-Heterocyclic Carbene Metal Complexes: Synthesis and Application in Catalysis		Catalysts	101	Michalak, M	FALSE	FALSE	FALSE	FALSE
1412	10.1021/acscatal.1c01929	doi.org/10.1021/acscatal.1c01929	A Bulky and Electron-Rich N-Heterocyclic Carbene-Palladium Complex (SIPr)Pd-Ph2(cin)Cl: Highly Efficient and Versatile for the Buchwald-Hartwig Amination of (Hetero)aryl Chlorides with (Hetero)aryl Amines at Room Temperature		ACS Catal.	101	Qiu, LQ	FALSE	TRUE	FALSE	FALSE
1413	10.1126/science.abg5526	doi.org/10.1126/science.abg5526	Boron insertion into alkyl ether bonds via zinc/nickel tandem catalysis		Science	101	Dong, GB	FALSE	FALSE	FALSE	FALSE
1414	10.1002/anie.202016310	doi.org/10.1002/anie.202016310	Nickel-Catalyzed N-Arylation of NH-Sulfoximines with Aryl Halides via Paired Electrolysis		Angew. Chem.-Int. Edit.	101	Mei, TS	FALSE	TRUE	FALSE	FALSE
1415	10.1021/acs.joc.7b01377	doi.org/10.1021/acs.joc.7b01377	Metal-Free Oxidative C-C Coupling of Arylamines Using a Quinone-Based Organic Oxidant		J. Org. Chem.	101	Venkatakrishnan, P	FALSE	FALSE	FALSE	FALSE
1416	10.1021/acs.organomet.7b00109	doi.org/10.1021/acs.organomet.7b00109	Synthesis and Reactivity of Cyclic (Alkyl)(Amino)Carbene Stabilized Nickel Carbonyl Complexes		Organometallics	101	Radius, U	FALSE	FALSE	FALSE	FALSE
1417	10.1021/acs.joc.5b02873	doi.org/10.1021/acs.joc.5b02873	Decarboxylative Halogenation and Cyanation of Electron-Deficient Aryl Carboxylic Acids via Cu Mediator as Well as Electron-Rich Ones through Pd Catalyst under Aerobic Conditions		J. Org. Chem.	101	Cai, H	FALSE	TRUE	FALSE	FALSE
1418	10.1016/j.mcat.2020.111359	doi.org/10.1016/j.mcat.2020.111359	Sandwich structured aryl-diimine Pd (II)/Co (II) monolayer-Fabrication, catalytic performance, synergistic effect and mechanism investigation	Treatment of urea or carbamate derived benzomorpholines with lithium diisopropylamide generates N-vinyl ureas or N-vinyl carbamates by elimination of a phenoxide anion, cleaving the benzomorpholine ring. Simultaneous formation of a carbanion a to a stabilising aryl or nitrile group allows migration of the newly formed N-vinyl substituent to the carbanionic centre, in some cases with high enantiospecificity. Mild hydrolysis of the resulting urea or carbamate returns a C-vinylated amine, alcohol or hydantoin, in some cases with high enantiomeric purity. This 'masked' vinylation strategy avoids the need to use the reactive and volatile vinyl isocyanate as a starting material. (C) 2017 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.	Mol. Catal.	100	Li, TS; Wu, YJ	FALSE	FALSE	FALSE	FALSE
1419	10.1021/acs.orglett.0c03703	doi.org/10.1021/acs.orglett.0c03703	Electron Donor-Acceptor Complex-Initiated Photochemical Cyanation for the Preparation of alpha-Amino Nitriles	Treatment of the N-heterocyclic chlorophosphine precursor (PPP) Cl (1) with two equivalents of nickelocene (NiCp2) affords the phosphorus-bridged dimer [(mu-PPP)Ni2Cp2] Cl (2). In contrast, an equimolar mixture of 1 and NiCp2 in the presence of PPh3 generates a different product, (PP(C5H5)P)NiCl2 (3), in which a cyclopentadienyl anion has migrated to the N-heterocyclic phosphenium center. The phosphorus- bound Cp ring in complex 3 has undergone a [1,5]-hydride shift to afford a vinylic C5H5 ring, and can be subsequently deprotonated to produce [(PP(C5H4)P)NiCl] (4). (C) 2016 Elsevier B.V. All rights reserved.	Org. Lett.	100	Zhang, WH	TRUE	TRUE	FALSE	FALSE
1420	10.1002/adsc.202000499	doi.org/10.1002/adsc.202000499	Zinc-Catalyzed N-Alkylation of Aromatic Amines with Alcohols: A Ligand-Free Approach	Polystyrene-supported NHC-Pd(II) complex based on theophylline as a sustainable NHC precursor was employed in the Suzuki-Miyaura cross-coupling reaction of substituted arenediazonium tetrafluoroborate salts with a variety of arylboronic acids to afford functionalized biaryl derivatives in good to excellent yields without using base or additive as promoters. The catalyst was easily recovered by filtration and reused for six successive cycles. (C) 2016 Elsevier B. V. All rights reserved.	Adv. Synth. Catal.	100	Sivakumar, B; Mannathan, S	FALSE	FALSE	FALSE	FALSE
1421	10.1002/anie.202005891	doi.org/10.1002/anie.202005891	Palladium-Catalyzed Chlorocarbonylation of Aryl (Pseudo)Halides Through In Situ Generation of Carbon Monoxide	Alcohols are among the most abundant and commonly used organic feedstock in industrial processes and academic research. The first tandem O-H insertion/[1,3]-alkyl shift reaction reported is between benzylic alcohols and rhodium azavinyl carbenoids derived from N-sulfonyl-1,2,3-triazoles, which provides a strategically novel way of cleaving C-OH bonds and forming C-C bonds. The substrate scope is broad, capable of covering 1 degrees-, 2 degrees-, and 3 degrees-benzylic alcohols. Moreover, it constitutes a new and powerful synthetic method for constructing alpha-aminoketones. Mechanistic studies suggest that a [1,3]-alkyl shift of oxonium ylides is responsible for cleavage of the COH bonds.	Angew. Chem.-Int. Edit.	100	Morandi, B	FALSE	FALSE	FALSE	FALSE
1422	10.1021/acs.joc.0c01277	doi.org/10.1021/acs.joc.0c01277	Organometal-Free Arylation and Arylation/Trifluoroacetylation of Quinolines by Their Reaction with CF3-ynones and Base-Induced Rearrangement	This Perspective illustrates the defining characteristics of free radical chemistry, beginning with its rich and storied history. Studies from our laboratory are discussed :along with recent developments emanating from others in this burgeoning area. The practicality and chemoselectivity of radical reactions enable rapid access to Molecules of relevance to drug discovery, agrochemistry, material science, and other disciplines. Thus, these reactive intermediates possess inherent translational potential; as they can he widely used to expedite scientific endeavors for the bettemnent of humankind.	J. Org. Chem.	100	Trofimov, BA	FALSE	FALSE	FALSE	FALSE
1423	10.1002/anie.202001742	doi.org/10.1002/anie.202001742	Ligand-Enabled Nickel-Catalyzed Redox-Relay Migratory Hydroarylation of Alkenes with Arylborons	The direct alpha-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols using Amberlyst-15/[Bmim] [PF6] ionic liquid as an affordable catalytic system has been developed. This protocol provides a simple, mild, metal free method for the synthesis of alkylated carbonyl compounds in good to excellent yields. Further, the developed methodology is moisture-stable and operationally simple and can be recycled up to four cycles without much significant loss in its catalytic activity.	Angew. Chem.-Int. Edit.	100	Zhu, SL	FALSE	FALSE	FALSE	FALSE
1424	10.1016/j.ica.2019.119358	doi.org/10.1016/j.ica.2019.119358	Synthesis and characterization of N,N-chelate manganese complexes and applications in C-N coupling reactions	Palladium catalysts supported on different inorganic materials have been reported to catalyze C-C bond formation reactions and extensive review articles are available in the literature considering this issue. However, in order to increase the capacity of the supports to bind palladium as the active catalyst, the surface of a large number of solids has been modified with organic moieties. The negative aspects of these modifications are that they are time-consuming and sometimes tedious procedures. In addition, they increase the cost of the reactions which is not desirable in economic point of view. On the other hand, naturally occurring organic solids which are inexpensive, available and abundant in nature are good alternative to inorganic supports despite their relatively lower thermal stabilities. The surface of these solids fully covered by chelating groups and often the surface modifications are not needed. In a recent perspective article, the application of palladium supported on polysaccharides in coupling reactions has been reviewed by Molnar and Papp. In the present review, we have focused our attention to the endeavors utilizing palladium particles supported on natural organic solids for the construction of C-C bonds by Mizoroki-Heck, Sonogashira-Hagihara, Suzuki-Miyaura and homocoupling reactions which are the most important palladium-catalyzed reactions.	Inorg. Chim. Acta	100	Maji, B	FALSE	FALSE	FALSE	FALSE
1425	10.1016/j.apcatb.2019.117936	doi.org/10.1016/j.apcatb.2019.117936	Valorization of wood biomass-lignin via selective bond scission: A minireview		Appl. Catal. B-Environ.	100	Gazi, S	FALSE	FALSE	FALSE	FALSE
1426	10.1002/adsc.201900819	doi.org/10.1002/adsc.201900819	Selective C-N Bond Cleavage of N-Acylisatins: Towards High Performance Acylation/Arylation/Transamination Reagents		Adv. Synth. Catal.	100	Zeng, Z	FALSE	FALSE	FALSE	FALSE
1427	10.1002/anie.201907840	doi.org/10.1002/anie.201907840	Enantioselective Dicarbofunctionalization of Unactivated Alkenes by Palladium-Catalyzed Tandem Heck/Suzuki Coupling Reaction		Angew. Chem.-Int. Edit.	100	Zhang, JL	FALSE	FALSE	FALSE	FALSE
1428	10.1021/acs.joc.9b01879	doi.org/10.1021/acs.joc.9b01879	Photoarylation of Pyridines Using Aryldiazonium Salts and Visible Light: An EDA Approach		J. Org. Chem.	100	de Oliveira, KT	TRUE	FALSE	FALSE	FALSE
1429	10.1039/c9qo00066f	doi.org/10.1039/c9qo00066f	Nickel-catalyzed fluoroethylation of arylboronic acids via Suzuki-type coupling		Org. Chem. Front.	100	Yang, Y; Liu, YL	FALSE	FALSE	FALSE	FALSE
1430	10.1002/anie.201809112	doi.org/10.1002/anie.201809112	Umpolung of Carbonyl Groups as Alkyl Organometallic Reagent Surrogates for Palladium-Catalyzed Allylic Alkylation		Angew. Chem.-Int. Edit.	100	Li, CJ	FALSE	FALSE	FALSE	FALSE
1431	10.1039/c8dt01295d	doi.org/10.1039/c8dt01295d	Acetylacetonato-based pincer-type nickel(II) complexes: synthesis and catalysis in cross-couplings of aryl chlorides with aryl Grignard reagents		Dalton Trans.	100	Yamaguchi, Y	FALSE	FALSE	FALSE	FALSE
1432	10.1039/c7nj04701k	doi.org/10.1039/c7nj04701k	o-Iodoxybenzoic acid mediated generation of aryl free radicals: synthesis of stilbenes through C-C cross-coupling with -nitrostyrenes		New J. Chem.	100	Akamanchi, KG	FALSE	FALSE	FALSE	FALSE
1433	10.1021/acscatal.5b02089	doi.org/10.1021/acscatal.5b02089	Mechanism of Ni-NHC Catalyzed Hydrogenolysis of Aryl Ethers: Roles of the Excess Base		ACS Catal.	100	Chung, LW	FALSE	FALSE	FALSE	FALSE
1434	10.1021/jacs.5b09223	doi.org/10.1021/jacs.5b09223	Mechanism of the Ti-III-Catalyzed Acyloin-Type Umpolung: A Catalyst-Controlled Radical Reaction		J. Am. Chem. Soc.	100	Streuff, J	FALSE	FALSE	FALSE	FALSE
1435	10.1007/978-3-319-13054-5_7	doi.org/10.1007/978-3-319-13054-5_7	At the Forefront of the Suzuki-Miyaura Reaction: Advances in Stereoselective Cross-Couplings		Top. Organomet. Chem.	100	Hall, DG	FALSE	FALSE	FALSE	FALSE
1436	10.1038/nature13274	doi.org/10.1038/nature13274	Recent advances in homogeneous nickel catalysis		Nature	100	Jamison, TF	FALSE	FALSE	FALSE	FALSE
1437	10.1021/jo402626u	doi.org/10.1021/jo402626u	Ti/Ni-Mediated Inter- and Intramolecular Conjugate Addition of Aryl and Alkenyl Halides and Inflates		J. Org. Chem.	100	Campana, AG	FALSE	FALSE	FALSE	FALSE
1438	10.1021/om200246k	doi.org/10.1021/om200246k	Intramolecular Nitrile C-H Bond Activation in Nickel NHC Complexes: A Route to New Nickelacycles		Organometallics	100	Ritleng, V	FALSE	FALSE	FALSE	FALSE
1439	10.1002/ejoc.200900877	doi.org/10.1002/ejoc.200900877	Catalyzed Propargylic Substitution		Eur. J. Org. Chem.	100	van Maarseveen, JH	FALSE	FALSE	FALSE	FALSE
1440	10.1021/om034381b	doi.org/10.1021/om034381b	3,5-dialkyl effect on enantioselectivity in Pd chemistry: Applications involving both bidentate and monodentate auxiliaries		Organometallics	100	Pregosin, PS	FALSE	FALSE	FALSE	FALSE
1441	10.1016/S0022-328X(02)01173-7	doi.org/10.1016/S0022-328X(02)01173-7	Pyridylsilyl group-driven cross-coupling reactions		J. Organomet. Chem.	100	Yoshida, J	FALSE	FALSE	FALSE	FALSE
1442	10.1021/acscatal.1c05441	doi.org/10.1021/acscatal.1c05441	Regio- and Stereoselective Diarylation of 1,3-Dienes via Ni/Cr Cocatalysis		ACS Catal.	100	Chen, QA	FALSE	FALSE	FALSE	FALSE
1443	10.1002/ejoc.202101196	doi.org/10.1002/ejoc.202101196	Recent Advances in Chemical Modifications of Nitriles		Eur. J. Org. Chem.	100	Wu, WQ	FALSE	FALSE	FALSE	FALSE
1444	10.1039/d1ob02214h	doi.org/10.1039/d1ob02214h	N-Alkylation of organonitrogen compounds catalyzed by methylene-linked bis-NHC half-sandwich ruthenium complexes		Org. Biomol. Chem.	100	Botubol-Ares, JM	FALSE	FALSE	FALSE	FALSE
1445	10.1002/slct.202103003	doi.org/10.1002/slct.202103003	Pd(II)-Catalyzed Chelation-Induced C(sp(2))-H Acylation of (Hetero)Arenes Using Toluenes as Aroyl Surrogate		ChemistrySelect	100	De, SR	FALSE	FALSE	FALSE	FALSE
1446	10.1002/adsc.202100762	doi.org/10.1002/adsc.202100762	Base Metal-Catalyzed C-Methylation Reactions Using Methanol		Adv. Synth. Catal.	100	Natte, K	FALSE	FALSE	FALSE	FALSE
1447	10.1021/acssuschemeng.1c05237	doi.org/10.1021/acssuschemeng.1c05237	Multicomponent Bifunctionalization of Methyl Ketones Enabled by Heterogeneous Catalysis and Solar Photocatalysis in Water		ACS Sustain. Chem. Eng.	100	Zhang, PF	TRUE	FALSE	FALSE	FALSE
1448	10.1016/j.jcat.2021.08.038	doi.org/10.1016/j.jcat.2021.08.038	From selective transfer hydrogenation to selective hydrogen auto-transfer process: An efficient method for the synthesis of alkenyl ketones via iridium-catalyzed alpha-alkylation of ketones with alkenyl alcohols		J. Catal.	100	Yang, JZ; Li, F	FALSE	FALSE	FALSE	FALSE
1449	10.1002/anie.202104979	doi.org/10.1002/anie.202104979	Synthesis of N-Heterocycles via Oxidant-Free Dehydrocyclization of Alcohols Using Heterogeneous Catalysts		Angew. Chem.-Int. Edit.	100	Lu, GP	FALSE	FALSE	FALSE	FALSE
1450	10.1002/asia.202100432	doi.org/10.1002/asia.202100432	Enantioselective Synthesis of Quaternary Carbon Stereocenters by Asymmetric Allylic Alkylation: A Review		Chem.-Asian J.	100	Yang, YW	FALSE	FALSE	FALSE	FALSE
1451	10.1039/d0qi01241f	doi.org/10.1039/d0qi01241f	Observing the three-dimensional dynamics of supported metal complexes		Inorg. Chem. Front.	100	Perras, FA	FALSE	FALSE	FALSE	FALSE
1452	10.1039/d0qi01411g	doi.org/10.1039/d0qi01411g	Different effects of metal-NHC bond cleavage on the Pd/NHC and Ni/NHC catalyzed alpha-arylation of ketones with aryl halides		Inorg. Chem. Front.	100	Chernyshev, VM; Ananikov, VP	FALSE	FALSE	FALSE	FALSE
1453	10.1002/adsc.201600974	doi.org/10.1002/adsc.201600974	Rhodium(III)-Catalyzed Regioselective Decarboxylative Cyclization for the Synthesis of 4H-Furo[3,2-c]chromen-4-one Derivatives		Adv. Synth. Catal.	100	Li, HJ; Wang, L	FALSE	FALSE	FALSE	FALSE
1454	10.1070/RCR4628	doi.org/10.1070/RCR4628	The progress in the chemistry of N-acyliminium ions and their use in stereoselective organic synthesis		Russ. Chem. Rev.	100	Vinogradov, MG	FALSE	FALSE	FALSE	FALSE
1455	10.1016/j.tet.2016.06.031	doi.org/10.1016/j.tet.2016.06.031	Imidodiphosphoric acid catalysis		Tetrahedron	100	Langdon, SM	FALSE	FALSE	FALSE	FALSE
1456	10.1055/s-0035-1562499	doi.org/10.1055/s-0035-1562499	Metal-Free, DTBP-Mediated Methylthiolation of Arylboronic Acids with Dimethyldisulfide		Synlett	100	Wu, XM	FALSE	FALSE	FALSE	FALSE
1457	10.1016/j.jorganchem.2016.02.005	doi.org/10.1016/j.jorganchem.2016.02.005	Verstile silver(I) and nickel(II) NHC complexes bearing benzotriazole-function: Synthesis, fluorescence and catalytic property		J. Organomet. Chem.	100	Qin, DB	FALSE	FALSE	FALSE	FALSE
1458	10.1021/acs.joc.0c02722	doi.org/10.1021/acs.joc.0c02722	Equivalent Loading of Directed Arenes in Pd(II)-Catalyzed Oxidative Cross-Coupling of Aryl C-H Bonds at Room Temperature	An additive-free nickel-catalyzed alpha-allylation of aldehydes with allyl alcohol is reported. The reaction is promoted by 1 mol% of in situ formed nickel complex in methanol, and water is the sole by-product of the reaction. The experimental conditions allow the conversion of various alpha-branched aldehydes and alpha, beta-unsaturated aldehydes as nucleophiles. The same catalyst and reaction conditions enabled a tandem aldol condensation of aldehyde/alpha-allylation reaction.	J. Org. Chem.	99	Lu, WJ	FALSE	FALSE	FALSE	FALSE
1459	10.1055/s-0040-1707208	doi.org/10.1055/s-0040-1707208	Recent Advances in the Synthesis and Applications of 2-Arylbenzothiazoles	A nickel-catalyzed intramolecular Grignard-type addition of aryl bromides to C=O was developed. By using Ni(dppe) Br-2 as a catalyst and zinc powder as a reducing agent, the reactions of 2-((2-bromophenyl) amino)-1-arylethanones proceeded smoothly in 1,2-dimethoxyethane solvent to afford 3-hydroxyindolines as intermediates, which underwent dehydration reaction to furnish a range of indole derivatives in moderate to excellent yields (up to 90%).	Synthesis	99	Luo, PY	FALSE	FALSE	FALSE	FALSE
1460	10.1002/anie.202008350	doi.org/10.1002/anie.202008350	Oxidative Addition of Water, Alcohols, and Amines in Palladium Catalysis	A novel two-step synthesis of multisubstituted beta-prolinols has been developed, featuring a [3+2] cycloaddition of azomethine ylides and a programmed reduction triggered by the combination of borane and lithium aluminum hydride (LAH). beta-Prolinols are shown to be valuable building blocks for polyheterocycles. (C) 2016 Elsevier Ltd. All rights reserved.	Angew. Chem.-Int. Edit.	99	Munz, D	FALSE	FALSE	FALSE	FALSE
1461	10.1126/science.aba2419	doi.org/10.1126/science.aba2419	Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides	The development of a sustainable, carbon-neutral biorefinery has emerged as a prominent scientific and engineering goal of the 21st century. As petroleum has become less accessible, biomass-based carbon sources have been investigated for utility in fuel production and commodity chemical manufacturing. One underutilized biomaterial is lignin; however, its highly crosslinked and randomly polymerized composition have rendered this biopolymer recalcitrant to existing chemical processing. More recently, insight into lignin's molecular structure has reinvigorated chemists to develop catalytic methods for lignin depolymerization. This review examines the development of transition-metal catalyzed reactions and the insights shared between the homogeneous and heterogeneous catalytic systems towards the ultimate goal of valorizing lignin to produce value-added products.	Science	99	Julia, F; Leonori, D	FALSE	FALSE	FALSE	FALSE
1462	10.1016/j.heliyon.2020.e03446	doi.org/10.1016/j.heliyon.2020.e03446	A review of thermal homogeneous catalytic deoxygenation reactions for valuable products		Heliyon	99	Guan, QQ; Ning, P	FALSE	FALSE	FALSE	FALSE
1463	10.1002/anie.201913733	doi.org/10.1002/anie.201913733	Ruthenium(II)-Catalyzed Asymmetric Inert C-H Bond Activation Assisted by a Chiral Transient Directing Group		Angew. Chem.-Int. Edit.	99	Wang, J	FALSE	FALSE	FALSE	FALSE
1464	10.2174/1385272824666200221114707	doi.org/10.2174/1385272824666200221114707	Stereoselective Synthesis of Multisubstituted alpha-fluoro-beta-lactams		Curr. Org. Chem.	99	Omote, M	FALSE	FALSE	FALSE	FALSE
1465	10.1002/anie.201913743	doi.org/10.1002/anie.201913743	Nickel-Catalyzed Asymmetric Reductive 1,2-Carboamination of Unactivated Alkenes		Angew. Chem.-Int. Edit.	99	Wang, Y; Zhu, SL	FALSE	FALSE	FALSE	FALSE
1466	10.6023/cjoc201908020	doi.org/10.6023/cjoc201908020	Recent Progress in the Suzuki-Miyaura Cross-Coupling Reactions in Water		Chin. J. Org. Chem.	99	Duan, XH	FALSE	FALSE	FALSE	FALSE
1467	10.1039/c9nj03345a	doi.org/10.1039/c9nj03345a	The alpha-alkylation of ketones with alcohols in pure water catalyzed by a water-soluble Cp*Ir complex bearing a functional ligand		New J. Chem.	99	Li, F	FALSE	FALSE	FALSE	FALSE
1468	10.1002/anie.201905021	doi.org/10.1002/anie.201905021	Palladium-Catalyzed Dearomative syn-1,4-Carboamination with Grignard Reagents		Angew. Chem.-Int. Edit.	99	Sarlah, D	FALSE	FALSE	FALSE	FALSE
1469	10.1039/c9nj01061k	doi.org/10.1039/c9nj01061k	A theoretical study on one-electron redox potentials of organotrifluoroborate anions		New J. Chem.	99	Zheng, WR	FALSE	FALSE	FALSE	FALSE
1470	10.1016/j.poly.2019.01.060	doi.org/10.1016/j.poly.2019.01.060	A green and cost-effective approach for the production of gold nanoparticles using corn silk extract: A recoverable catalyst for Suzuki-Miyaura reaction and adsorbent for removing of dye pollutants		Polyhedron	99	Khodaei, MM	FALSE	FALSE	FALSE	FALSE
1471	10.1002/ejoc.201801825	doi.org/10.1002/ejoc.201801825	2-Azidoethane-1-sulfonylfluoride (ASF): A Versatile Bis-clickable Reagent for SuFEx and CuAAC Click Reactions		Eur. J. Org. Chem.	99	Qin, HL	FALSE	FALSE	FALSE	FALSE
1472	10.1002/cctc.201800629	doi.org/10.1002/cctc.201800629	Visible-Light-Driven Photocatalytic Oxidation of Organic Chlorides Using Air and an Inorganic-Ligand Supported Nickel-Catalyst Without Photosensitizers		ChemCatChem	99	Yu, H; Han, S	TRUE	FALSE	FALSE	FALSE
1473	10.1002/chem.201705463	doi.org/10.1002/chem.201705463	Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic alpha-Bromo Esters with Arylzincs		Chem.-Eur. J.	99	Bian, QH	FALSE	FALSE	FALSE	FALSE
1474	10.1021/acscatal.7b02599	doi.org/10.1021/acscatal.7b02599	Zn-Catalyzed tert-Butyl Nicotinate-Directed Amide Cleavage as a Biomimic of Metallo-Exopeptidase Activity		ACS Catal.	99	Maes, BUW	FALSE	FALSE	FALSE	FALSE
1475	10.1021/acscatal.7b03465	doi.org/10.1021/acscatal.7b03465	Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents		ACS Catal.	99	Watson, DA	FALSE	FALSE	FALSE	FALSE
1476	10.1016/j.jorganchem.2017.07.026	doi.org/10.1016/j.jorganchem.2017.07.026	Organometallic chemistry of bis(N-heterocyclic carbene) ligands containing a heteroarene spacer		J. Organomet. Chem.	99	Chen, WZ	FALSE	FALSE	FALSE	FALSE
1477	10.1016/j.tet.2012.05.054	doi.org/10.1016/j.tet.2012.05.054	Preparation of N-arylamines from 2-oxo-7-azobicyclo[4.1.0]heptanes		Tetrahedron	99	Maycock, CD	FALSE	FALSE	FALSE	FALSE
1478	10.1002/ejic.201101283	doi.org/10.1002/ejic.201101283	Binuclear Copper Complexes and Their Catalytic Evaluation		Eur. J. Inorg. Chem.	99	Bera, JK	FALSE	FALSE	FALSE	FALSE
1479	10.1021/jo200023r	doi.org/10.1021/jo200023r	An Investigation into the One-Pot Heck Olefination-Hydrogenation Reaction		J. Org. Chem.	99	Evans, P	FALSE	FALSE	FALSE	FALSE
1480	10.1021/om0604223	doi.org/10.1021/om0604223	Nickel(0) complexes of N-alkyl-substituted N-heterocyclic carbenes and their use in the catalytic carbon-carbon bond activation of biphenylene		Organometallics	99	Radius, U	FALSE	FALSE	FALSE	FALSE
1481	10.1002/ejoc.200500279	doi.org/10.1002/ejoc.200500279	Solid-phase synthesis of biphenyls and terphenyls by the traceless multifunctional cleavage of polymer-bound arenesulfonates		Eur. J. Org. Chem.	99	Cho, CH	FALSE	FALSE	FALSE	FALSE
1482	10.1021/jo0106501	doi.org/10.1021/jo0106501	Universal solid-phase approach for the immobilization, derivatization, and resin-to-resin transfer reactions of boronic acids		J. Org. Chem.	99	Hall, DG	FALSE	FALSE	FALSE	FALSE
1483	10.1021/jacs.1c10907	doi.org/10.1021/jacs.1c10907	A General, Multimetallic Cross-Ullmann Biheteroaryl Synthesis from Heteroaryl Halides and Heteroaryl Triflates		J. Am. Chem. Soc.	99	Weix, DJ	FALSE	FALSE	FALSE	FALSE
1484	10.1021/acscatal.1c03564	doi.org/10.1021/acscatal.1c03564	The Resurrection of Murahashi Coupling after Four Decades		ACS Catal.	99	Handa, S	FALSE	FALSE	FALSE	FALSE
1485	10.1021/jacs.1c05661	doi.org/10.1021/jacs.1c05661	Catalytic Aldehyde and Alcohol Arylation Reactions Facilitated by a 1,5-Diaza-3,7-diphosphacyclooctane Ligand		J. Am. Chem. Soc.	99	Newman, SG	FALSE	FALSE	FALSE	FALSE
1486	10.1021/acs.joc.1c00858	doi.org/10.1021/acs.joc.1c00858	Manganese-Catalyzed Achmatowicz Rearrangement Using Green Oxidant H2O2		J. Org. Chem.	99	Yu, BX	FALSE	FALSE	FALSE	FALSE
1487	10.1002/anie.202100288	doi.org/10.1002/anie.202100288	(-)-Isoscopariusin A, a Naturally Occurring Immunosuppressive Meroditerpenoid: Structure Elucidation and Scalable Chemical Synthesis		Angew. Chem.-Int. Edit.	99	Puno, PT	FALSE	FALSE	FALSE	FALSE
1488	10.1021/jacs.0c13057	doi.org/10.1021/jacs.0c13057	Pd-Catalyzed ipso,meta-Dimethylation of ortho-Substituted Iodoarenes via a Base-Controlled C-H Activation Cascade with Dimethyl Carbonate as the Methyl Source		J. Am. Chem. Soc.	99	Zhang, YH	FALSE	FALSE	FALSE	FALSE
1489	10.1002/chem.202005397	doi.org/10.1002/chem.202005397	One-Pot Dual C-C Coupling Reaction via Site Selective Cascade Formation by Pd-II-Cryptate of an Amino-Ether Heteroditopic Macrobicycle		Chem.-Eur. J.	99	Ghosh, P	FALSE	FALSE	FALSE	FALSE
1490	10.1039/d1ob00086a	doi.org/10.1039/d1ob00086a	Nickel-catalyzed coupling of R2P(O)Me (R = aryl or alkoxy) with (hetero)arylmethyl alcohols		Org. Biomol. Chem.	99	Wang, ZX	FALSE	FALSE	FALSE	FALSE
1491	10.1021/acs.inorgchem.7b01616	doi.org/10.1021/acs.inorgchem.7b01616	Palladium(II) Chloride Complexes of N,N'-Disubstituted Imidazole-2-thiones: Syntheses, Structures, and Catalytic Performances in Suzuki-Miyaura and Sonogashira Coupling Reactions		Inorg. Chem.	99	Li, HX; Wang, Y; Lang, JP	FALSE	FALSE	FALSE	FALSE
1492	10.1021/jacs.7b03538	doi.org/10.1021/jacs.7b03538	Simple and Efficient Generation of Aryl Radicals from Aryl Triflates: Synthesis of Aryl Boronates and Aryl Iodides at Room Temperature		J. Am. Chem. Soc.	99	Li, CJ	FALSE	FALSE	FALSE	FALSE
1493	10.1055/s-0036-1588705	doi.org/10.1055/s-0036-1588705	Pd(OAc)(2)-Catalyzed Desulfinative Cross-Coupling of Sodium Sulfinates with beta-Bromostyrenes: Synthesis of Tamoxifen		Synthesis	99	Chang, MY	FALSE	FALSE	FALSE	FALSE
1494	10.1021/jacs.6b10255	doi.org/10.1021/jacs.6b10255	Nickel-Catalyzed Boron Insertion into the C-2-O Bond of Benzofurans		J. Am. Chem. Soc.	99	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
1495	10.1016/j.jorganchem.2021.121754	doi.org/10.1016/j.jorganchem.2021.121754	Synthesis, structure and characterization of picolyl and benzyl linked biphenyl nickel NHC complexes and their catalytic activity in Suzuki-Miyaura cross-coupling reactions	A new class of palladium catalysts, based on heterocyclic diphosphines, was rationally designed and synthesized. Application of one of these catalysts allows novel Markovnikov-selective carbonylation of non-activated alkynes with heteroarenes to give the corresponding branched ,alpha,beta-unsaturated ketones in excellent yields (up to 97%) and regioselectivities (b/l up to 99:1). In addition to heteroarenes, other common nucloephiles (alcohol, phenol, amine, and amide) furnish the desired carbonylation products smoothly in high yields.	J. Organomet. Chem.	98	Sabiah, S	FALSE	FALSE	FALSE	FALSE
1496	10.1002/ajoc.202100016	doi.org/10.1002/ajoc.202100016	Synthesis of 1-Naphthol-based Unsymmetrical Triarylmethanes: Heck-type Desulfitative Reaction of Arylsulfonyl Chlorides with Tetralone-derived Chalcones	The silicon-based cross-coupling reaction has attracted much attention over recent decades because there are many advantages in using organosilicon compounds. However, the use of reagents with a triorganosilyl group as a key function remains to be established. This account summarizes our recent progress in cross-coupling chemistry with such silyl reagents. 1 Introduction 2 Preparation of HOMSi Reagents from Aryl Bromides and Disilanes 3 HOMSi Reagents from Heteroaromatics and Hydrosilanes 4 Cross-Coupling Polymerization with HOMSi Reagents 5 Cross-Coupling with Aryl(triethyl) silanes 6 Amination of Aryl Halides with N-TMS-Amines 7 Conclusion and Perspective	Asian J. Org. Chem.	98	Babu, SA	FALSE	FALSE	FALSE	FALSE
1497	10.1016/j.mcat.2020.110915	doi.org/10.1016/j.mcat.2020.110915	Efficient nickel(II) immobilized on EDTA-modified Fe3O4@SiO2 nanospheres as a novel nanocatalyst for amination of heteroaryl carbamates and sulfamates through the cleavage of C-O bond	An operationally simple, one-pot, catalyst-free method was developed for the synthesis of pharmaceutically important substituted isoindolinones by a three-component reaction of 2-formylbenzoic acid, a primary amine, and a 1,3-dione in ethanol under dielectric heating.	Mol. Catal.	98	Inaloo, ID	FALSE	FALSE	FALSE	FALSE
1498	10.1016/j.trechm.2020.06.002	doi.org/10.1016/j.trechm.2020.06.002	Light Up the Transition Metal-Catalyzed Single-Electron Allylation	The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(alpha-bromoacetyl) thiophene with triethylamine-activated phosphorus decasulfide (Et3N-P2S5) was elaborated by utilizing DFT calculations.	Trends Chem.	98	Lu, LQ; Xiao, WJ	FALSE	TRUE	FALSE	FALSE
1499	10.1039/d0sc00964d	doi.org/10.1039/d0sc00964d	Chromium-catalyzed cyclopropanation of alkenes with bromoform in the presence of 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-dihydropyrazine	Sodium hydride (NaH) is widely used as a BrOnsted base in chemical synthesis and reacts with various BrOnsted acids, whereas it rarely behaves as a reducing reagent through delivery of the hydride to polar electrophiles. This study presents a series of reduction reactions of nitriles, amides, and imines as enabled by NaH in the presence of LiI or NaI. This remarkably simple protocol endows NaH with unprecedented and unique hydride-donor chemical reactivity.	Chem. Sci.	98	Tsurugi, H; Mashima, K	FALSE	FALSE	FALSE	FALSE
1500	10.6023/cjoc201911016	doi.org/10.6023/cjoc201911016	Nickel-Catalyzed Negishi Coupling of Cyclobutanone Oxime Esters with Aryl Zinc Reagents	CONSPECTUS: Control of regio- and stereoselectivity of chemical reactions is the central theme in synthetic chemistry. Regioselective and enantiospecific ring opening of readily available enantioenriched epoxides precursors provides a straightforward access to diverse highly functionalized molecules which can serve as chiral building blocks for synthesis of biologically active compounds. However, prior to our research work, the scope of catalytic highly regioselective ring opening of epoxides is limited to structurally or electronically biased epoxides, such as terminal and aromatic epoxides. Regioselective ring opening of epoxides with substituents on both sides demonstrating similar steric and electronic effects is still a formidable challenge for organic chemists. To address this challenge, our approach is to use the readily available functional moiety incorporated in an epoxide as a directing group to realize the regioselective nucleophilic attack on the oxirane ring. Alternatively, asymmetric ring-opening of epoxides can also provide the ring-opening products in highly enantioenriched form. However, excellent results are usually obtained in the case of the kinetic resolution of terminal epoxides or the desymmetrization of meso-epoxides. In these cases, the issue of regiocontrol of the ring-opening is circumvented or minimized. Based on our successful results of regioselective ring-opening of functionalized epoxides by implementing the directed ring-opening strategy, we also investigated the enantioselective ring-opening of internal epoxides bearing a functional moiety as directing group. This Account summarizes our research on metal-catalyzed directed ring-opening reactions of epoxides, which encompasses the following breakthroughs: (1) highly regioselective ring-opening of various substrates including epoxy allylic alcohols, epoxy homoallylic alcohols and epoxy allylic sulfonamides with a variety of N-, O-, and halide-nucleophiles catalyzed by W-, Mo-, or Ni-salt; (2) first kinetic resolutions of epoxy allylic alcohols, epoxy homoallylic alcohols, and epoxy allylic sulfonamides with various amines as nucleophiles, which were catalyzed by W-bishydroxamic acid (W-BHA), nickel-BINAM, and Gd-N,N'-dioxide catalytic system, respectively; (3) successful implementation of the strategy of combined asymmetric syntheses by the combination of the enantioselective epoxidation and the enantioselective ring -opening of 2,3-epoxy alcohols establishing a new entry to prepare amino alcohols in regio-, diastereo-, and enantiomerically pure form.	Chin. J. Org. Chem.	98	Fang, P; Mei, TS	FALSE	FALSE	FALSE	FALSE
1501	10.1002/anie.201912739	doi.org/10.1002/anie.201912739	Synthesis of Chiral Triarylmethanes Bearing All-Carbon Quaternary Stereocenters: Catalytic Asymmetric Oxidative Cross-Coupling of 2,2-Diarylacetonitriles and (Hetero)arenes		Angew. Chem.-Int. Edit.	98	Liu, L	FALSE	FALSE	FALSE	FALSE
1502	10.2174/1574893615666200129110450	doi.org/10.2174/1574893615666200129110450	Sequence-based Identification of Arginine Amidation Sites in Proteins Using Deep Representations of Proteins and PseAAC		Curr. Bioinform.	98	Naseer, S	FALSE	FALSE	FALSE	FALSE
1503	10.1002/ejoc.201901189	doi.org/10.1002/ejoc.201901189	Expanding the Family of Fluorescent Coumarin[4]arenes: Improved Synthesis, pi-Extension, and Characterization		Eur. J. Org. Chem.	98	Venkatakrishnan, P	FALSE	FALSE	FALSE	FALSE
1504	10.1002/ajoc.201900223	doi.org/10.1002/ajoc.201900223	Reaction Medium as the Installing Reservoir for Key Functionalities in the Molecules		Asian J. Org. Chem.	98	Verma, PK; Sawant, SD	FALSE	FALSE	FALSE	FALSE
1505	10.1021/acs.joc.7b03107	doi.org/10.1021/acs.joc.7b03107	Mechanism and Rate-Determining Factors of Amide Bond Formation through Acyl Transfer of Mixed Carboxylic-Carbamic Anhydrides: A Computational Study		J. Org. Chem.	98	Jiang, YY; Bi, SW	FALSE	FALSE	FALSE	FALSE
1506	10.1021/acs.organomet.7b00657	doi.org/10.1021/acs.organomet.7b00657	Palladium-Catalyzed Reductive Cross-Coupling Reaction of Aryl Chromium(0) Fischer Carbene Complexes with Aryl Iodides		Organometallics	98	Wang, JB	FALSE	FALSE	FALSE	FALSE
1507	10.1021/acs.orglett.7b03551	doi.org/10.1021/acs.orglett.7b03551	Oxy-Difluoroalkylation of Allylamines with CO2 via Visible-Light Photoredox Catalysis		Org. Lett.	98	Yu, DG	TRUE	FALSE	FALSE	FALSE
1508	10.1021/acs.oprd.5b00314	doi.org/10.1021/acs.oprd.5b00314	Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations		Org. Process Res. Dev.	98	Schranck, J	FALSE	FALSE	FALSE	FALSE
1509	10.1002/anie.201503888	doi.org/10.1002/anie.201503888	Cp*Rh-III-Catalyzed Arylation of C(sp(3))-H Bonds		Angew. Chem.-Int. Edit.	98	Glorius, F	FALSE	FALSE	FALSE	FALSE
1510	10.1039/c5cc01427a	doi.org/10.1039/c5cc01427a	A one-pot domino C-H, C-C activation in coumarins: a fast track to 2,3-diaryl benzo[b]furans		Chem. Commun.	98	Shafiee, A	FALSE	FALSE	FALSE	FALSE
1511	10.1039/c5ra03334a	doi.org/10.1039/c5ra03334a	A Pd complex of a NNN pincer ligand supported on gamma-Fe2O3@SiO2 as the first magnetically recoverable heterogeneous catalyst for C-P bond forming reactions		RSC Adv.	98	Sobhani, S	FALSE	FALSE	FALSE	FALSE
1512	10.1039/c5qo00236b	doi.org/10.1039/c5qo00236b	Pincer CNC bis-N-heterocyclic carbenes: robust ligands for palladium-catalysed Suzuki-Miyaura arylation of bromoanthracene and related substrates		Org. Chem. Front.	98	Zende, VM	FALSE	FALSE	FALSE	FALSE
1513	10.1039/c4dt02313g	doi.org/10.1039/c4dt02313g	Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines		Dalton Trans.	98	Garcia, JJ	FALSE	FALSE	FALSE	FALSE
1514	10.1002/anie.201402695	doi.org/10.1002/anie.201402695	Double C-F Bond Activation through beta-Fluorine Elimination: Nickel-Mediated [3+2] Cycloaddition of 2-Trifluoromethyl-1-alkenes with Alkynes		Angew. Chem.-Int. Edit.	98	Ichikawa, J	FALSE	FALSE	FALSE	FALSE
1515	10.1021/ja410883p	doi.org/10.1021/ja410883p	Ni-Catalyzed Carboxylation of C(sp(2))- and C(sp(3))-O Bonds with CO2		J. Am. Chem. Soc.	98	Martin, R	FALSE	FALSE	FALSE	FALSE
1516	10.1007/3418_2013_72	doi.org/10.1007/3418_2013_72	New Formulas for Zincate Chemistry: Synergistic Effect and Synthetic Applications of Hetero-bimetal Ate Complexes		Top. Organomet. Chem.	98	Uchiyama, M	FALSE	FALSE	FALSE	FALSE
1517	10.1039/c3sc22242j	doi.org/10.1039/c3sc22242j	Cross coupling of thioethers with aryl boroxines to construct biaryls via Rh catalyzed C-S activation		Chem. Sci.	98	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
1518	10.1021/ol9001587	doi.org/10.1021/ol9001587	Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates		Org. Lett.	98	Itami, K	FALSE	FALSE	FALSE	FALSE
1519	10.3987/COM-08-S(N)40	doi.org/10.3987/COM-08-S(N)40	TOTAL SYNTHESIS OF ISOINDOLOBENZAZEPINE ALKALOIDS, LENNOXAMINE AND CHILENINE, BASED ON PALLADIUM-CATALYZED REDUCTION OF ALKENYL PHOSPHATES		Heterocycles	98	Fuwa, H	FALSE	FALSE	FALSE	FALSE
1520	10.1021/jo071117+	doi.org/10.1021/jo071117+	General and efficient route for the synthesis of 3,4-disubstituted coumarins via Pd-catalyzed site-selective cross-coupling reactions		J. Org. Chem.	98	Wu, H	FALSE	FALSE	FALSE	FALSE
1521	10.1055/s-2006-950290	doi.org/10.1055/s-2006-950290	Cobalt-catalyzed cross-coupling reactions of heterocyclic chlorides with arylmagnesium halides and of polyfunctionalized arylcopper reagents with aryl bromides, chlorides, fluorides and tosylates		Synthesis	98	Knochel, P	FALSE	FALSE	FALSE	FALSE
1522	10.1021/ja021244h	doi.org/10.1021/ja021244h	Design of N-spiro C-2-symmetric chiral quaternary ammonium bromides as novel chiral phase-transfer catalysts: Synthesis and application to practical asymmetric synthesis of alpha-amino acids		J. Am. Chem. Soc.	98	Maruoka, K	FALSE	FALSE	FALSE	FALSE
1523	10.1039/d1qo01412a	doi.org/10.1039/d1qo01412a	Recent advances in sustainable organic transformations using methanol: expanding the scope of hydrogen-borrowing catalysis		Org. Chem. Front.	98	Banerjee, D	FALSE	FALSE	FALSE	FALSE
1524	10.1002/anie.202107820	doi.org/10.1002/anie.202107820	Chemoselective, Scalable Nickel-Electrocatalytic O-Arylation of Alcohols		Angew. Chem.-Int. Edit.	98	Baran, PS	FALSE	TRUE	FALSE	FALSE
1525	10.1055/s-0040-1720406	doi.org/10.1055/s-0040-1720406	Enantioselective Intermolecular Murai-Type Alkene Hydroarylation Reactions		Synthesis	98	Bower, JF	FALSE	FALSE	FALSE	FALSE
1526	10.1002/anie.202102192	doi.org/10.1002/anie.202102192	Triarylmethanes and their Medium-Ring Analogues by Unactivated Truce-Smiles Rearrangement of Benzanilides		Angew. Chem.-Int. Edit.	98	Clayden, J	FALSE	FALSE	FALSE	FALSE
1527	10.1002/anie.202101668	doi.org/10.1002/anie.202101668	Enantioselective alpha-Carbonylative Arylation for Facile Construction of Chiral Spirocyclic beta,beta '-Diketones		Angew. Chem.-Int. Edit.	98	Tang, WJ	FALSE	FALSE	FALSE	FALSE
1528	10.1002/anie.201706781	doi.org/10.1002/anie.201706781	Reductive Decarboxylative Alkynylation of N-Hydroxyphthalimide Esters with Bromoalkynes		Angew. Chem.-Int. Edit.	98	Weix, DJ	FALSE	FALSE	FALSE	FALSE
1529	10.1021/acs.joc.7b01637	doi.org/10.1021/acs.joc.7b01637	Mechanism of Amide Bond Formation from Carboxylic Acids and Amines Promoted by 9-Silafluorenyl Dichloride Derivatives		J. Org. Chem.	98	Jiang, YY; Bi, SW	FALSE	FALSE	FALSE	FALSE
1530	10.1021/acs.orglett.7b01561	doi.org/10.1021/acs.orglett.7b01561	Phosphorylation of Alkenyl and Aryl C-O Bonds via Photoredox/Nickel Dual Catalysis		Org. Lett.	98	Yu, DG	TRUE	FALSE	FALSE	FALSE
1531	10.1021/acscatal.7b00941	doi.org/10.1021/acscatal.7b00941	Nickel-Catalyzed C-O Bond-Cleaving Alkylation of Esters: Direct Replacement of the Ester Moiety by Functionalized Alkyl Chains		ACS Catal.	98	Rueping, M	FALSE	FALSE	FALSE	FALSE
1532	10.1002/adsc.201601105	doi.org/10.1002/adsc.201601105	Nickel-Catalyzed Deoxygenative Deuteration of Aryl Sulfamates		Adv. Synth. Catal.	98	Kuriyama, M; Onomura, O	FALSE	FALSE	FALSE	FALSE
1533	10.1002/adsc.201601302	doi.org/10.1002/adsc.201601302	Palladium-Catalyzed Addition of Arylboronic Acids to para-Quinone Methides for Preparation of Diarylacetates		Adv. Synth. Catal.	98	Yang, GQ; Zhang, WB	FALSE	FALSE	FALSE	FALSE
1534	10.1021/acs.joc.6b01836	doi.org/10.1021/acs.joc.6b01836	Synthesis of o-Alkenylated 2-Arylbenzoxazoles via Rh-Catalyzed Oxidative Olefination of 2-Arylbenzoxazoles: Scope Investigation, Structural Features, and Mechanism Studies		J. Org. Chem.	98	Hou, XF	FALSE	FALSE	FALSE	FALSE
1535	10.1002/ejoc.201600933	doi.org/10.1002/ejoc.201600933	ortho-Lithiation Reactions of O-(3,n-Dihalophenyl) N,N-Diethylcarbamates: Synthesis of Dihalosalicylamides and 2,3,n-Trihalophenol Derivatives		Eur. J. Org. Chem.	98	Sanz, R	FALSE	FALSE	FALSE	FALSE
1536	10.1021/acs.joc.6b01619	doi.org/10.1021/acs.joc.6b01619	Wavelength Selective Generation of Aryl Radicals and Aryl Cations for Metal-Free Photoarylations		J. Org. Chem.	98	Protti, S; Fagnoni, M	TRUE	FALSE	FALSE	FALSE
1537	10.1021/acs.organomet.6b00161	doi.org/10.1021/acs.organomet.6b00161	Cobalt-Catalyzed Borylation of Aryl Halides and Pseudohalides		Organometallics	98	Hu, AG	FALSE	FALSE	FALSE	FALSE
1538	10.1016/j.jorganchem.2015.12.032	doi.org/10.1016/j.jorganchem.2015.12.032	Catalytic Suzuki couplings by an amido pincer complex of palladium		J. Organomet. Chem.	98	Liang, LC	FALSE	FALSE	FALSE	FALSE
1539	10.1021/acs.organomet.0c00813	doi.org/10.1021/acs.organomet.0c00813	Dual Photoredox-/Palladium-Catalyzed Cross-Electrophile Couplings of Polyfluoroarenes with Aryl Halides and Triflates	The couplings of carboxylic acids and amines promoted by dichlorosilane derivatives provide a promising tool for amide synthesis and peptide coupling, in which an unprecedented mechanism was proposed for the amide bond formation process. To investigate this mechanistic proposal and enrich the understanding of this novel reaction, a theoretical study was conducted herein. The formation and interconversion of silylamine and silyl ester intermediates were calculated to be kinetically feasible under the experiment conditions. However, the subsequent amidation via direct elimination on the AcO-Si(L)(L')-NHMe intermediate was found to involve a high energy barrier due to the formation of an unstable silanone. By contrast, the in situ generated salts can promote the amidation process by generating a silanol as the temporary product. Similarly, the anhydride formation mechanism can proceed via direct elimination or salt-assisted elimination on the AcO-Si(L)(L')-OAc intermediate but is less favorable. Finally, we found that the intermolecular nucleophilic addition on the AcO-Si(L)(L')-Cl intermediate is the most favorable mechanism among all the candidates considered. In this mechanism, carboxylic acids or bases can act as self-catalysts to promote the amide bond formation via hydrogen bonding, and the formation of the unstable silanone or anhydride is avoided.	Organometallics	97	Chu, LL	TRUE	TRUE	FALSE	FALSE
1540	10.1021/acscatal.0c03903	doi.org/10.1021/acscatal.0c03903	Cobalt-Catalyzed C(sp(2))-CN Bond Activation: Cross-Electrophile Coupling for Biaryl Formation and Mechanistic Insight	Transition-metal-free dehalogenation of various aryl halides (iodides and bromides) can take place efficiently at 70-110 degrees C in the presence of a catalytic amount of 1, 10-phenanthroline and t-BuOK using THF or Dioxane as solvent. Control experiments indicated that radical transfer occurred between aryl radical and alkyl C-H bond to generate alkyl radical. (C) 2017 Elsevier Ltd. All rights reserved.	ACS Catal.	97	Gandon, V; Gosmini, C	FALSE	TRUE	FALSE	FALSE
1541	10.1002/adsc.202000537	doi.org/10.1002/adsc.202000537	Palladium-Catalyzed Regioselective Domino Spirocyclization of Carbamoyl Chlorides with Alkynes and Benzynes	A simple and operationally easy protocol for the regioselective synthesis of internal alkenes through a dehydrative cross-coupling and direct coupling procedure has been described using the environmentally benign Ca(II) catalyst. Several alkenes and alcohols underwent the coupling reaction under solvent-free conditions in a short time to produce the desired alkenes. This method is further extended to show the application in the synthesis of novel benzopyran molecules through a cascade strategy. (C) 2016 Elsevier Ltd. All rights reserved.	Adv. Synth. Catal.	97	Qu, JP; Chen, YF	FALSE	FALSE	FALSE	FALSE
1542	10.1039/d0sc01349h	doi.org/10.1039/d0sc01349h	Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents	We herein report a transition-metal-free cross-coupling between secondary alkyl halides/mesylates and aryl/alkenylboronic acid, providing expedited access to a series of nonchiral/chiral coupling products in moderate to good yields. Stereospecific S(N)2-type coupling is developed for the first time with alkenylboronic adds as pure nucleophiles, offering an attractive alternative to the stereospecific transition-metal-catalyzed C(sp(2))-C(sp(3)) cross-coupling.	Chem. Sci.	97	Hevia, E	FALSE	FALSE	FALSE	FALSE
1543	10.1021/acscatal.9b04823	doi.org/10.1021/acscatal.9b04823	Zinc-Catalyzed Hydroxyl-Directed Regioselective Ring Opening of Aziridines in S(N)2 Reaction Pathway		ACS Catal.	97	Wang, C	FALSE	FALSE	FALSE	FALSE
1544	10.1021/acs.oprd.8b00325	doi.org/10.1021/acs.oprd.8b00325	Process Development for a Locally Acting SGLT1 Inhibitor, LX2761, Utilizing sp(3)-sp(2) Suzuki Coupling of a Benzyl Carbonate		Org. Process Res. Dev.	97	Wuo, WX	FALSE	FALSE	FALSE	FALSE
1545	10.1016/j.tet.2018.08.050	doi.org/10.1016/j.tet.2018.08.050	Highly efficient synthesis of 1,2-disubstituted acetylenes derivatives from the cross-coupling reactions of 1-bromoalkynes with organoalane reagents		Tetrahedron	97	Li, QH	FALSE	FALSE	FALSE	FALSE
1546	10.5059/yukigoseikyokaishi.76.781	doi.org/10.5059/yukigoseikyokaishi.76.781	Catalytic Asymmetric Synthesis of Natural Products Directed Toward Development of Novel Anti-infective and Anti-cancer Medicines		J. Synth. Org. Chem. Jpn.	97	Watanabe, T	FALSE	FALSE	FALSE	FALSE
1547	10.1021/jacs.7b12806	doi.org/10.1021/jacs.7b12806	(Guanidine)copper Complex-Catalyzed Enantioselective Dynamic Kinetic Allylic Alkynylation under Biphasic Condition		J. Am. Chem. Soc.	97	Tan, CH	FALSE	FALSE	FALSE	FALSE
1548	10.1021/acs.organomet.7b00642	doi.org/10.1021/acs.organomet.7b00642	DFT Investigation of Suzuki-Miyaura Reactions with Aryl Sulfamates Using a Dialkylbiarylphosphine-Ligated Palladium Catalyst		Organometallics	97	Hazari, N	FALSE	FALSE	FALSE	FALSE
1549	10.1021/acs.joc.5b01300	doi.org/10.1021/acs.joc.5b01300	Directed Metalation-Suzuki-Miyaura Cross-Coupling Strategies: Regioselective Synthesis of Hydroxylated 1-Methyl-phenanthrenes		J. Org. Chem.	97	Jorgensen, KB	FALSE	FALSE	FALSE	FALSE
1550	10.1039/c5sc01589h	doi.org/10.1039/c5sc01589h	Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp(3))-H bonds		Chem. Sci.	97	Nolan, SP	FALSE	FALSE	FALSE	FALSE
1551	10.1021/jo501321m	doi.org/10.1021/jo501321m	Nickel-Catalyzed Decarboxylative C-P Cross-Coupling of Alkenyl Acids with P(O)H Compounds		J. Org. Chem.	97	Gao, YX	FALSE	FALSE	FALSE	FALSE
1552	10.1021/om401141r	doi.org/10.1021/om401141r	Density Functional Theory Study of the Mechanisms of Iron-Catalyzed Aminohydroxylation Reactions		Organometallics	97	Ren, QH	FALSE	FALSE	FALSE	FALSE
1553	10.1021/ja4118413	doi.org/10.1021/ja4118413	Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)-O and C(acyl)-O Activation of Aryl Esters with Phosphine Ligands		J. Am. Chem. Soc.	97	Houk, KN	FALSE	FALSE	FALSE	FALSE
1554	10.1039/c4sc00006d	doi.org/10.1039/c4sc00006d	Carbon-fluorine bond cleavage in fluoroarenes via a niobium(III) imido complex: from stoichiometric to catalytic hydrodefluorination		Chem. Sci.	97	Bergman, RG	FALSE	FALSE	FALSE	FALSE
1555	10.1055/s-0033-1340061	doi.org/10.1055/s-0033-1340061	Direct Carboxylative Reactions for the Transformation of Carbon Dioxide into Carboxylic Acids and Derivatives		Synthesis	97	Cai, XH	FALSE	FALSE	FALSE	FALSE
1556	10.1039/c3ra23188g	doi.org/10.1039/c3ra23188g	Synthesis of coumarins via PIDA/I-2-mediated oxidative cyclization of substituted phenylacrylic acids		RSC Adv.	97	Li, JM	FALSE	FALSE	FALSE	FALSE
1557	10.1016/j.tetlet.2012.09.028	doi.org/10.1016/j.tetlet.2012.09.028	Ferrous salt-promoted homocoupling of arenediazonium tetrafluoroborates under mild conditions		Tetrahedron Lett.	97	Qi, CZ	FALSE	FALSE	FALSE	FALSE
1558	10.1039/c1sc00368b	doi.org/10.1039/c1sc00368b	Nickel-catalyzed cross coupling of non-activated alkyl halides: a mechanistic perspective		Chem. Sci.	97	Hu, XL	FALSE	FALSE	FALSE	FALSE
1559	10.1039/c1cs15100b	doi.org/10.1039/c1cs15100b	Transition metal-catalysed cross-coupling reactions of P-activated enols		Chem. Soc. Rev.	97	Sellars, JD	FALSE	FALSE	FALSE	FALSE
1560	10.1021/om100816d	doi.org/10.1021/om100816d	Mechanistic Insights into C-S Cross-Coupling Reactions Catalyzed by Nickel Bis(phosphinite) Pincer Complexes		Organometallics	97	Guan, HR	FALSE	FALSE	FALSE	FALSE
1561	10.1021/om1003072	doi.org/10.1021/om1003072	Dehalogenation and Hydrogenation of Aromatic Compounds Catalyzed by Nanoparticles Generated from Rhodium Bis(imino)pyridine Complexes		Organometallics	97	Esteruelas, MA	FALSE	FALSE	FALSE	FALSE
1562	10.1002/chem.200900575	doi.org/10.1002/chem.200900575	Preparation of Polyfunctional Arylmagnesium, Arylzinc, and Benzylic Zinc Reagents by Using Magnesium in the Presence of LiCl		Chem.-Eur. J.	97	Knochel, P	FALSE	FALSE	FALSE	FALSE
1563	10.1021/jo026136s	doi.org/10.1021/jo026136s	Cross-coupling reactions of phenylmagnesium halides with fluoroazines and fluorodiazines		J. Org. Chem.	97	Mongin, F	FALSE	FALSE	FALSE	FALSE
1564	10.1021/ar010068z	doi.org/10.1021/ar010068z	On inventing reactions for atom economy		Accounts Chem. Res.	97	Trost, BM	FALSE	FALSE	FALSE	FALSE
1565	10.1021/acscatal.1c05586	doi.org/10.1021/acscatal.1c05586	Cobalt-Catalyzed C(sp(2))-C(sp(3)) Suzuki-Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands		ACS Catal.	97	Chirik, PJ	FALSE	FALSE	FALSE	FALSE
1566	10.1002/anie.202113209	doi.org/10.1002/anie.202113209	Nickel-Catalyzed Stereo- and Enantioselective Cross-Coupling of gem-Difluoroalkenes with Carbon Electrophiles by C-F Bond Activation		Angew. Chem.-Int. Edit.	97	Shi, ZZ	FALSE	TRUE	FALSE	FALSE
1567	10.1039/d1gc03724b	doi.org/10.1039/d1gc03724b	Chemical recovery of thermosetting unsaturated polyester resins		Green Chem.	97	Xu, SM; Wang, YZ	FALSE	FALSE	FALSE	FALSE
1568	10.1021/jacs.1c08399	doi.org/10.1021/jacs.1c08399	Stereoconvergent and -divergent Synthesis of Tetrasubstituted Alkenes by Nickel-Catalyzed Cross-Couplings		J. Am. Chem. Soc.	97	Sigman, MS	FALSE	FALSE	FALSE	FALSE
1569	10.3390/molecules26216579	doi.org/10.3390/molecules26216579	Recent Advances in the Synthesis of Polyamine Derivatives and Their Applications		Molecules	97	Maslov, M	FALSE	FALSE	FALSE	FALSE
1570	10.1039/d1qo00309g	doi.org/10.1039/d1qo00309g	Ni/NHC catalysis in C-H functionalization using air-tolerant nickelocene and sodium formate for in situ catalyst generation		Org. Chem. Front.	97	Chernyshev, VM; Ananikov, VP	FALSE	FALSE	FALSE	FALSE
1571	10.1039/c7ob00911a	doi.org/10.1039/c7ob00911a	Phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes		Org. Biomol. Chem.	97	Liu, L; Zhang, JL	FALSE	FALSE	FALSE	FALSE
1572	10.1021/jacs.7b02389	doi.org/10.1021/jacs.7b02389	Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation		J. Am. Chem. Soc.	97	Watson, MP	FALSE	TRUE	FALSE	FALSE
1573	10.1002/anie.201609693	doi.org/10.1002/anie.201609693	Enantioselective Dearomatization of Naphthol Derivatives with Allylic Alcohols by Cooperative Iridium and Bronsted Acid Catalysis		Angew. Chem.-Int. Edit.	97	Zeng, XF; Zhong, GF	FALSE	FALSE	FALSE	FALSE
1574	10.1002/asia.201600972	doi.org/10.1002/asia.201600972	Fe-Catalyzed Cross-Coupling Reaction of Vinylic Ethers with Aryl Grignard Reagents		Chem.-Asian J.	97	Iwasaki, T; Kambe, N	FALSE	FALSE	FALSE	FALSE
1575	10.1002/cctc.201600456	doi.org/10.1002/cctc.201600456	Base-Free Palladium-Catalyzed Borylation of Aryl Chlorides with Diborons		ChemCatChem	97	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
1576	10.1016/j.ica.2016.02.004	doi.org/10.1016/j.ica.2016.02.004	Adaptation of guest molecules: A simple system that amplifies the gentle perturbation of host lattices from nickel(II) to cobalt(II)		Inorg. Chim. Acta	97	Tseng, TW	FALSE	FALSE	FALSE	FALSE
1577	10.1039/d0cy01886d	doi.org/10.1039/d0cy01886d	Chemoselective heterogeneous iridium catalyzed hydrogenation of cinnamalaniline	Chlorination of the coumarin framework was achieved by using trichloroisocyanuric acid, which has several advantages over N-chlorosuccinimide, particularly with respect to cost-effectiveness and toxicity. The Suzuki-Miyaura cross-coupling of the chlorinated 4-alkoxycoumarins with a range of aryl- and heteroarylboronic acids was then carried out in the presence of Pd(OAc)(2) and 2-(dicyclohexylphosphino)-2,6-dimethoxybiphenyl (SPhos) in an environmentally benign solvent. This transformation afforded the coupled products in yields up to 99%. Sensitive functional groups such as aldehydes and nitriles were tolerated under the reaction conditions, and the protocol could be performed on a gram scale. The cross-coupling method was also successfully extended to related 2-pyrone, 2-pyridone, and 2-quinolone derivatives to give yields up to 96%. This is the first time cross-coupling conditions have been shown to be general across this range of heterocyclic substrates. The demethylation of the Suzuki-Miyaura products allowed for access to 3-aryl-4-hydroxycoumarins.	Catal. Sci. Technol.	96	Savela, R	FALSE	FALSE	FALSE	FALSE
1578	10.1002/tcr.202000148	doi.org/10.1002/tcr.202000148	Employing Photocatalysis for the Design and Preparation of DNA-encoded Libraries: A Case Study	An efficient nickel-catalyzed decarbonylative cyanation reaction which allows the direct functional-group interconversion of readily available esters into the corresponding nitriles was developed. This reaction successfully offers access to structurally diverse nitriles with high efficiency and excellent functional-group tolerance and provides a good alternative to classical synthetic pathways from diazonium salts, or organic halide compounds.	Chem. Rec.	96	Kolmel, DK	TRUE	FALSE	FALSE	FALSE
1579	10.1021/acs.joc.0c02328	doi.org/10.1021/acs.joc.0c02328	Cu-Catalyzed Oxidative Thioesterification of Aroylhydrazides with Disulfides	The control of stereoselectivity in radical reactions is of great importance to organic synthesis. Hence, new concepts and strategies for controlling stereochemistry of radical reactions are emerging continuously. This Review highlights the recent remarkable progress in enantioselective radical cyclization reactions. Initially, the chiral Lewis acid-catalyzed method became a field of central importance for enantioselective radical cyclizations. In recent years, significant progress has been made in enantioselective organocatalysis. In contrast to intermolecular reactions, the successful examples for enantioselective radical cyclizations are still limited. In this Review, the radical cyclizations controlled by chiral Lewis acids, chiral metallic reagents, chiral imidazolidinone catalysts, chiral non-covalent organocatalysts, and chiral thiols are summarized.	J. Org. Chem.	96	Dong, JY	FALSE	FALSE	FALSE	FALSE
1580	10.1021/acs.oprd.0c00367	doi.org/10.1021/acs.oprd.0c00367	Recent Advances in Nonprecious Metal Catalysis	An efficient enantioselective Friedel-Crafts alkylation reaction of electron-rich beta-naphthol with in situ generated ortho-quinone methides catalyzed by chiral bifunctional amine-squaramide catalysts has been developed. The chiral triarylmethane derivatives were obtained in good to high yields (up to 97% yield) with high enantioselectivities (up to 97% ee) for most substrates under mild conditions. This study also revealed that the oil-water biphase could significantly improve the efficiency of this catalytic system.	Org. Process Res. Dev.	96	Shekhar, S	FALSE	FALSE	FALSE	FALSE
1581	10.1016/j.ica.2020.119864	doi.org/10.1016/j.ica.2020.119864	Ru(II) complexes containing (2-(pyren-1-ylmethylene)hydrazinyl) benzothiazole: Synthesis, solid-state structure, computational study and catalysis in N-alkylation reactions	Pyridine-bridged bis-benzimidazolylidene nickel complexes exhibited very high catalytic activity toward cross coupling of inactive (hetero)aryl benzylic ammonium salts with (hetero)aryl and alkenyl boronic acids under mild reaction conditions. Even at 2 mol% catalyst loading, a wide range of substrates for both coupling partners with different steric and electronic properties were well tolerated. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.	Inorg. Chim. Acta	96	Viswanathamurthi, P	FALSE	FALSE	FALSE	FALSE
1582	10.6023/A20070335	doi.org/10.6023/A20070335	Advances on Nickel-Catalyzed C(sp(3))-C(sp(3)) Bond Formation	A simple and efficient protocol for the direct reductive cross-coupling between alkenyl and benzyl halides using a Co/Mn system has been developed. This reaction proceeds smoothly in the presence of [CoBr2(PPh3)(2)] as the catalyst, with NaI as an additive in acetonitrile with a broad scope of functionalized alkenyl and benzyl halides. Different functional groups are tolerated on both coupling partners, thus, significantly extending the general scope of transition-metal-catalyzed benzylation of alkenyl halides. Moderate to excellent yields were also obtained. From a mechanistic point of view, a radical chain mechanism was proposed. This reaction is stereospecific and some studies suggest the retention of the double-bond configuration.	Acta Chim. Sin.	96	Zhou, QL	FALSE	FALSE	FALSE	FALSE
1583	10.1021/acscatal.0c02468	doi.org/10.1021/acscatal.0c02468	Dynamic Kinetic Asymmetric Amination of Alcohols Assisted by Microwave: Stereoconvergent Access to Tetralin- and Indane-Derived Chiral Amines	A two-step (nucleophilic substitution/palladation by oxidative addition) sequence provides a high-yielding access to a non-symmetrical palladium NNC pincer complex. A number of terminal and internal alkynoic acids with different substitution patterns at the alpha- and beta-positions are regioand diastereoselectively cycloisomerized to the corresponding exocyclic enol lactones in the presence of exceedingly low amounts of the latter palladium complex, so that unprecedented turnover numbers and frequencies ranging from 1,000,000 to 700,000 and from 41,667 to 9722 h(-1), respectively, are achieved. The optimized protocol, based on the use of a catalytic amount of triethylamine as base, allows an easy real-time monitoring of the reaction by NMR spectroscopy. Several pieces of evidence in favor of the direct participation of the above pincer complex as the catalyst of the reaction have been gathered from kinetic and poisoning experiments	ACS Catal.	96	Lan, Y	FALSE	FALSE	FALSE	FALSE
1584	10.1055/s-0040-1708003	doi.org/10.1055/s-0040-1708003	Pd(0)-Catalyzed Direct Inter- and Intramolecular C-H Functionalization of 4-Carboxyimidazoles	Over the past two decades, there have been major developments in transition metal-catalyzed aminations of aryl halides to form anilines, a common structure found in drug agents, natural product isolates, and fine chemicals. Many of these approaches have enabled highly efficient and selective coupling through the design of specialized ligands, which facilitate reductive elimination from a destabilized metal center. We postulated that a general and complementary method for carbon-nitrogen bond formation could be developed through the destabilization of a metal amido complex via photoredox catalysis, thus providing an alternative approach to the use of structurally complex ligand systems. Here, we report the development of a distinct mechanistic paradigm for aryl amination using ligand-free nickel(II) salts, in which facile reductive elimination from the nickel metal center is induced via a photoredox-catalyzed electron-transfer event.	Synlett	96	Baudequin, C; Hoarau, C	FALSE	FALSE	FALSE	FALSE
1585	10.1021/acs.orglett.9b04220	doi.org/10.1021/acs.orglett.9b04220	Synthesis of 2-Arylpiperidines via Pd-Catalyzed Arylation of Aza-Achmatowicz Rearrangement Products with Arylboronic Acids		Org. Lett.	96	Tong, RB	FALSE	FALSE	FALSE	FALSE
1586	10.1002/slct.201903251	doi.org/10.1002/slct.201903251	Base-Promoted Direct Chalcogenylation of 2-Naphthols		ChemistrySelect	96	Rampon, DS	FALSE	FALSE	FALSE	FALSE
1587	10.1002/adsc.201901188	doi.org/10.1002/adsc.201901188	2-Methyltetrahydrofuran (2-MeTHF): A Green Solvent for Pd-NHC-Catalyzed Amide and Ester Suzuki-Miyaura Cross-Coupling by N-C/O-C Cleavage		Adv. Synth. Catal.	96	Lei, P	FALSE	FALSE	FALSE	FALSE
1588	10.1002/anie.201911372	doi.org/10.1002/anie.201911372	Nickel-Catalyzed Domino Heck-Type Reactions Using Methyl Esters as Cross-Coupling Electrophiles		Angew. Chem.-Int. Edit.	96	Newman, SG	FALSE	TRUE	FALSE	FALSE
1589	10.1021/acs.joc.9b01556	doi.org/10.1021/acs.joc.9b01556	Nickel-Catalyzed Hydroarylation of Alkynes under Reductive Conditions with Aryl Bromides and Water		J. Org. Chem.	96	Wilger, DJ	FALSE	FALSE	FALSE	FALSE
1590	10.1039/c9cy00752k	doi.org/10.1039/c9cy00752k	Intermetallic species in the Negishi coupling and their involvement in inhibition pathways		Catal. Sci. Technol.	96	Polynski, MV; Pidko, EA	FALSE	FALSE	FALSE	FALSE
1591	10.1016/j.tet.2019.07.007	doi.org/10.1016/j.tet.2019.07.007	A SO2F2 mediated mild, practical, and gram-scale dehydroxylative transforming primary alcohols to quaternary ammonium salts		Tetrahedron	96	Zha, GF; Qin, HL	FALSE	FALSE	FALSE	FALSE
1592	10.1021/acs.organomet.9b00060	doi.org/10.1021/acs.organomet.9b00060	Scope and Mechanistic Aspect of Nickel-Catalyzed Alkenylation of Benzothiazoles and Related Azoles with Styryl Bromides		Organometallics	96	Punji, B	FALSE	FALSE	FALSE	FALSE
1593	10.1002/adsc.201801527	doi.org/10.1002/adsc.201801527	Alkynyl-B(dan)s in Various Palladium-Catalyzed Carbon-Carbon Bond-Forming Reactions Leading to Internal Alkynes, 1,4-Enynes, Ynones, and Multiply Substituted Alkenes		Adv. Synth. Catal.	96	Tsuchimoto, T	FALSE	FALSE	FALSE	FALSE
1594	10.1016/j.ccr.2019.01.005	doi.org/10.1016/j.ccr.2019.01.005	Terpyridine-metal complexes: Applications in catalysis and supramolecular chemistry		Coord. Chem. Rev.	96	Shi, XD; Song, ZG	FALSE	FALSE	FALSE	FALSE
1595	10.1039/c8ob02312c	doi.org/10.1039/c8ob02312c	Chemoselective reduction of isothiocyanates to thioformamides mediated by the Schwartz reagent		Org. Biomol. Chem.	96	Pace, V	FALSE	FALSE	FALSE	FALSE
1596	10.1039/c8gc02611d	doi.org/10.1039/c8gc02611d	Copper immobilized at a covalent organic framework: an efficient and recyclable heterogeneous catalyst for the Chan-Lam coupling reaction of aryl boronic acids and amines		Green Chem.	96	Zhang, ZH	FALSE	FALSE	FALSE	FALSE
1597	10.6023/cjoc201803013	doi.org/10.6023/cjoc201803013	Progress on Transition-Metal-Catalyzed Cross-Coupling Reactions of Ammonium Salts via C-N Bond Cleavage		Chin. J. Org. Chem.	96	Chen, Y	FALSE	FALSE	FALSE	FALSE
1598	10.1039/c7sc03140h	doi.org/10.1039/c7sc03140h	Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols		Chem. Sci.	96	Shu, XZ	FALSE	FALSE	FALSE	FALSE
1599	10.1080/00268976.2015.1023751	doi.org/10.1080/00268976.2015.1023751	The (A)over-tilde(2) Delta(5/2) <- (X)over-tilde(2) Delta(5/2) electronic band system of nickel acetylide, NiCCH		Mol. Phys.	96	Morse, MD	FALSE	FALSE	FALSE	FALSE
1600	10.1002/chem.201501568	doi.org/10.1002/chem.201501568	Construction of a Chiral Silicon Center by Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation		Chem.-Eur. J.	96	Naganawa, Y	FALSE	FALSE	FALSE	FALSE
1601	10.1039/c5dt00032g	doi.org/10.1039/c5dt00032g	Nickel complexes for catalytic C-H bond functionalization		Dalton Trans.	96	Johnson, SA	FALSE	FALSE	FALSE	FALSE
1602	10.1002/adsc.201400442	doi.org/10.1002/adsc.201400442	Palladium-Catalyzed Suzuki Carbonylative Reaction of alpha-Halomethyl Oxime Ethers: A Regioselective Route to Unsymmetrical 1,3-Oxyiminoketones		Adv. Synth. Catal.	96	Medio-Simon, M	FALSE	FALSE	FALSE	FALSE
1603	10.1016/j.molcata.2014.02.006	doi.org/10.1016/j.molcata.2014.02.006	Synthesis and characterization of magnetic copper ferrite nanoparticles and their catalytic performance in one-pot odorless carbon-sulfur bond formation reactions		J. Mol. Catal. A-Chem.	96	Gholinejad, M	FALSE	FALSE	FALSE	FALSE
1604	10.1039/c3ob42050g	doi.org/10.1039/c3ob42050g	Recent trends in Pd-catalyzed remote functionalization of carbonyl compounds		Org. Biomol. Chem.	96	Mazet, C	FALSE	FALSE	FALSE	FALSE
1605	10.1002/jhet.1712	doi.org/10.1002/jhet.1712	An Innovative Protocol for the Synthesis of 3-(Pyridin-2-yl)-5-sec-aminobiphenyl-4-carbonitriles and 9,10-Dihydro-3-(pyridine-2-yl)-1-sec-aminophenanthrene-2-carbonitriles		J. Heterocycl. Chem.	96	Mahulikar, PP	FALSE	FALSE	FALSE	FALSE
1606	10.1021/jo301086k	doi.org/10.1021/jo301086k	Synthesis of Substituted Coumarins via Bronsted Acid Mediated Condensation of Allenes with Substituted Phenols or Anisoles		J. Org. Chem.	96	Lee, PH	FALSE	FALSE	FALSE	FALSE
1607	10.3987/REV-12-736	doi.org/10.3987/REV-12-736	TRANSITION-METAL-CATALYZED BORYLATION OF ORGANIC HALIDES WITH HYDROBORANES		Heterocycles	96	Murata, M	FALSE	FALSE	FALSE	FALSE
1608	10.1002/adsc.201100151	doi.org/10.1002/adsc.201100151	Room Temperature Nickel(II) Complexes [(4-MeOC6H4)Ni-(PCy3)(2)OTs and Ni(PCy3)(2)X-2]-Catalyzed Cross-Coupling Reactions of Aryl/Alkenyl Sulfonates with Arylboronic Acids		Adv. Synth. Catal.	96	Hu, QS	FALSE	FALSE	FALSE	FALSE
1609	10.1039/c0dt00540a	doi.org/10.1039/c0dt00540a	Cross coupling reactions of polyfluoroarenes via C-F activation		Dalton Trans.	96	Love, JA	FALSE	FALSE	FALSE	FALSE
1610	10.1021/ja0002058	doi.org/10.1021/ja0002058	Versatile catalysts for the Suzuki cross-coupling of arylboronic acids with aryl and vinyl halides and triflates under mild conditions		J. Am. Chem. Soc.	96	Fu, GC	FALSE	FALSE	FALSE	FALSE
1611	10.1016/j.scib.2021.08.001	doi.org/10.1016/j.scib.2021.08.001	Semi-heterogeneous photo-Cu-dual-catalytic cross-coupling reactions using polymeric carbon nitrides		Sci. Bull.	96	Su, CL	FALSE	FALSE	FALSE	FALSE
1612	10.1021/jacs.1c11170	doi.org/10.1021/jacs.1c11170	Nickel-Catalyzed Decarboxylative Coupling of Redox-Active Esters with Aliphatic Aldehydes		J. Am. Chem. Soc.	96	Montgomery, J	FALSE	FALSE	FALSE	FALSE
1613	10.1002/chem.202103700	doi.org/10.1002/chem.202103700	Preparation of Polyfunctionalized Aromatic Nitriles from Aryl Oxazolines		Chem.-Eur. J.	96	Knochel, P	FALSE	FALSE	FALSE	FALSE
1614	10.1021/acs.organomet.1c00328	doi.org/10.1021/acs.organomet.1c00328	Pincer-Nickel Catalyzed Selective Guerbet-Type Reactions		Organometallics	96	Kumar, A	FALSE	FALSE	FALSE	FALSE
1615	10.1039/d1nj01654g	doi.org/10.1039/d1nj01654g	Biorenewable carbon-supported Ru catalyst for N-alkylation of amines with alcohols and selective hydrogenation of nitroarenes		New J. Chem.	96	Natte, K	FALSE	FALSE	FALSE	FALSE
1616	10.1039/d1qo00824b	doi.org/10.1039/d1qo00824b	Decarbonylative sulfide synthesis from carboxylic acids and thioesters via cross-over C-S activation and acyl capture		Org. Chem. Front.	96	Liu, CW; Szostak, M	FALSE	FALSE	FALSE	FALSE
1617	10.1002/anie.202014991	doi.org/10.1002/anie.202014991	Diastereoselective Synthesis of Aryl C-Glycosides from Glycosyl Esters via C-O Bond Homolysis		Angew. Chem.-Int. Edit.	96	Diao, TN	FALSE	FALSE	FALSE	FALSE
1618	10.1002/ejic.201700057	doi.org/10.1002/ejic.201700057	Nickel(II) N-Heterocyclic Carbene Complexes: Versatile Catalysts for C-C, C-S and C-N Coupling Reactions		Eur. J. Inorg. Chem.	96	Puerta, MC; Valerga, P	FALSE	FALSE	FALSE	FALSE
1619	10.1002/anie.201612624	doi.org/10.1002/anie.201612624	Selective Reductive Removal of Ester and Amide Groups from Arenes and Heteroarenes through Nickel-Catalyzed C-O and C-N Bond Activation		Angew. Chem.-Int. Edit.	96	Rueping, M	FALSE	FALSE	FALSE	FALSE
1620	10.1021/acs.joc.6b02769	doi.org/10.1021/acs.joc.6b02769	Regioselective 1,4-Conjugate Addition of Grignard Reagents to alpha,beta-Dienones and alpha,beta-gamma,delta-Dienyl Thiol Esters		J. Org. Chem.	96	Dieter, RK	FALSE	FALSE	FALSE	FALSE
1621	10.1002/anie.201512027	doi.org/10.1002/anie.201512027	Photoinduced Copper-Catalyzed C-H Arylation at Room Temperature		Angew. Chem.-Int. Edit.	96	Ackermann, L	TRUE	FALSE	FALSE	FALSE
1622	10.1021/acs.joc.5b02830	doi.org/10.1021/acs.joc.5b02830	Copper(I)/Ligand-Catalyzed 5-endo Radical Cyclization - Aromatization of 2,2,2-Trichloroethyl Vinyl Ethers: Synthesis of 2,3-Difunctionalized 4-Chlorofurans		J. Org. Chem.	96	Gupta, DK; Soni, VK	FALSE	FALSE	FALSE	FALSE
1623	10.1021/acscatal.5b02619	doi.org/10.1021/acscatal.5b02619	Direct Asymmetric Synthesis of beta-Bis-Aryl-alpha-Amino Acid Esters via Enantioselective Copper-Catalyzed Addition of p-Quinone Methides		ACS Catal.	96	Deng, WP	FALSE	FALSE	FALSE	FALSE
1624	10.1039/c6cc07032a	doi.org/10.1039/c6cc07032a	Traceless directing group mediated branched selective alkenylation of unbiased arenes		Chem. Commun.	96	Maiti, D	FALSE	FALSE	FALSE	FALSE
1625	10.1021/acs.chemrev.0c01115	doi.org/10.1021/acs.chemrev.0c01115	Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts	This manuscript describes the Ni-Catalyzed coupling of azoles with aromatic nitriles. The use of BPh3 promotes these arylations with electronically diverse azoles and benzonitriles. While the nickel catalyst is necessary for the arylations of phenyl oxazoles, arylation of benzoxazoles With some nitriles affords the arylated products even in the absence of the Ni-catalyst albeit in lower yield than the catalyzed process The Ni- catalyzed process exhibits higher rates and a broader scope than the uncatalyzed transformation.	Chem. Rev.	95	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
1626	10.1021/acscatal.0c03771	doi.org/10.1021/acscatal.0c03771	Practical Synthesis of Allyl, Allenyl, and Benzyl Boronates through S(N)1 '-Type Borylation under Heterogeneous Gold Catalysis	In this article a successful protocol was developed to construct carbon carbon bonds by the extrusion of the O atom of ethers-via nickel catalysis in the presence of reductants. This methodology is featured as a highly economic route to construct sp(3)-sp(3) C-C bonds through dual C-O activation of ethers with good functional group tolerance.	ACS Catal.	95	Miura, H; Shishido, T	FALSE	FALSE	FALSE	FALSE
1627	10.1002/ejoc.202001382	doi.org/10.1002/ejoc.202001382	Diversified Syntheses of Tetrathia[7]helicenes by Metal-Catalyzed Cross-Coupling Reactions	Nickel(II) can be used to catalyze the hetero [2+2+1] cycloaddition of 2-alkynylaryl iso-thiocyanates and isonitriles in 2-methyltetrahydrofuran (2-MeTHF) to give a wide array of thieno[2,3-b]indoles in excellent yields. The reaction is featured by employing as little as 0.3 mol% nickel(II) acetylacetonate [Ni(acac) 2] under air conditions in the absence of any additives (additional reducing agents and external ligands). This is the first successful example to apply nickel(II) directly in hetero [2+2+1] cycloadditions.	Eur. J. Org. Chem.	95	Cauteruccio, S	FALSE	FALSE	FALSE	FALSE
1628	10.1021/acs.orglett.0c03210	doi.org/10.1021/acs.orglett.0c03210	Nickel-Catalyzed Three-Component Reductive Alkylacylation of Electron-Deficient Activated Alkenes	A three-step protocol toward 1,1,2-triarylethanes 1 starting with beta-ketosulfones 2 is developed. A facile process is carried out for the (1) reduction of 2 with NaBH4, (2) BF3 center dot OEt2-mediated Friedel-Crafts reactions of the resulting beta-hydroxy sulfones 3, and (3) palladium-catalyzed desulfonylative cross-coupling of the corresponding 5 with aryl iodides 4 in the presence of t-BuOK under warming DMF in acceptable yields. A facile synthesis of CDP-840 (1v) has been studied. (C) 2017 Elsevier Ltd. All rights reserved.	Org. Lett.	95	Wang, C	FALSE	TRUE	FALSE	FALSE
1629	10.1039/d0ob01549k	doi.org/10.1039/d0ob01549k	Selective construction of alkaloid scaffolds by alcohol-based direct and mild aerobic oxidative Pictet-Spengler reactions	Various unsymmetrical aryl sulfides were synthesized by nickel-catalyzed C-S bond formation in good to excellent yields. The reactions employed arylsulfonyl chlorides as an aryl thiol source and Mn dust as a reducing agent. The scope and versatility of the method have been successfully demonstrated with 42 examples. Mechanistic studies revealed the existence of an intermediate disulfide substance. A catalytic cycle was proposed including a three-step reduction by Mn for the achievement of the reaction, and Ni(0) and Ni(I) species were supposed to be involved in the reaction mechanism.	Org. Biomol. Chem.	95	Liu, JP; Xu, Q	FALSE	FALSE	FALSE	FALSE
1630	10.1039/d0ob01083a	doi.org/10.1039/d0ob01083a	Recent advances in P-III-assisted deoxygenative reactions under photochemical or electrochemical conditions	The syntheses of ten new Ni(II) complexes 5a-5j with H2L tridentate (ONO) Schiff-base ligand (2-((2-oxybenzylidene)amino)phenolate) have been described and fully characterized by means of elemental analysis, FT-IR, electronic, H-1 NMR and C-13 NMR spectroscopy and single-crystal X-ray diffraction. In all [Ni(L)B] complexes (where B are imidazole, 4-benzylpyridine, 2-methyl-5-ethylpyridine, 3-hydroxymethylpyridine, 2-methylbenzimidazole, 2,6-dimethylpyridine, 4-methylpyridine, 2-isopropylbenzimidazole, 4-methylpiperidine or triphenylphosphine) the Schiff base completely deprotonates and coordinates to the metal ion as a dianionic tridentate ligand via the donor oxygens and nitrogen atoms. The coordination number of Ni(II) atoms is four with distorted square-planar stereochemistry. This is in a good agreement with the ligand field band position in their electronic spectra, as well as with the X-ray structure analysis for all complexes under study. Six selected complexes are used as catalysts for Kumada-Corriu cross-coupling reactions and exhibit a moderate to good catalytic activity in the synthesis of biaryl derivatives. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Biomol. Chem.	95	Tian, LF; Wang, YH	FALSE	FALSE	FALSE	FALSE
1631	10.1002/chem.202000289	doi.org/10.1002/chem.202000289	Hydroboration of Alkenes Catalysed by a Nickel N-Heterocyclic Carbene Complex: Reaction and Mechanistic Aspects	We developed an acylative kinetic resolution of secondary carbinols using a binaphthyl-based N,N-4-dimethylaminopyridine (DMAP) derivative 1d with tert-alcohol substituents. The reaction proceeded with a wide range of carbinols with moderate to high selectivity (s) (up to s = 79.5). Kinetic studies revealed that catalyst 1d was more catalytically active than the corresponding bis-methyl ether 1d' or DMAP. Hydrogen bonding between tert-alcohols of the catalyst and secondary carbinols was responsible for the enhanced reaction rate and high enantioselectivity.	Chem.-Eur. J.	95	Chetcuti, MJ; Ritleng, V	FALSE	FALSE	FALSE	FALSE
1632	10.1002/anie.201907185	doi.org/10.1002/anie.201907185	Rapid Access to Highly Functionalized Alkyl Boronates by NiH-Catalyzed Remote Hydroarylation of Boron-Containing Alkenes		Angew. Chem.-Int. Edit.	95	Zhu, SL	FALSE	FALSE	FALSE	FALSE
1633	10.1002/adsc.201900447	doi.org/10.1002/adsc.201900447	Ligand-Free and Reusable Palladium Nanoparticles-Catalyzed Alkylation of 2-Alkylazaarenes with Activated Ketones under Neutral Conditions		Adv. Synth. Catal.	95	Sekar, G	FALSE	FALSE	FALSE	FALSE
1634	10.1002/cctc.201900230	doi.org/10.1002/cctc.201900230	A Free-Radical Reduction and Cyclization of Alkyl Halides Mediated by FeCl2		ChemCatChem	95	Rasappan, R	FALSE	FALSE	FALSE	FALSE
1635	10.1021/acscatal.9b00884	doi.org/10.1021/acscatal.9b00884	Methyl Esters as Cross-Coupling Electrophiles: Direct Synthesis of Amide Bonds		ACS Catal.	95	Newman, SG	FALSE	TRUE	FALSE	FALSE
1636	10.1039/c8sc04335c	doi.org/10.1039/c8sc04335c	Nickel-catalyzed allylic defluorinative alkylation of trifluoromethyl alkenes with reductive decarboxylation of redox-active esters		Chem. Sci.	95	Lu, X; Fu, Y	FALSE	FALSE	FALSE	FALSE
1637	10.1021/acs.joc.8b01320	doi.org/10.1021/acs.joc.8b01320	1,3-Dioxa-[3,3]-sigmatropic Oxo-Rearrangement of Substituted Allylic Carbamates: Scope and Mechanistic Studies		J. Org. Chem.	95	Cossio, FP	FALSE	FALSE	FALSE	FALSE
1638	10.1021/jacs.8b10874	doi.org/10.1021/jacs.8b10874	Directed Copper-Catalyzed Intermolecular Heck-Type Reaction of Unactivated Olefins and Alkyl Halides		J. Am. Chem. Soc.	95	Fu, JK; Guan, W; Bi, XH	FALSE	FALSE	FALSE	FALSE
1639	10.3390/molecules23102435	doi.org/10.3390/molecules23102435	Efficient Suzuki-Miyaura C-C Cross-Couplings Induced by Novel Heterodinuclear Pd-bpydc-Ln Scaffolds		Molecules	95	Ding, F	FALSE	FALSE	FALSE	FALSE
1640	10.1021/acscatal.8b02784	doi.org/10.1021/acscatal.8b02784	Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Allylic Defluorinative Reductive Cross-Coupling		ACS Catal.	95	Wang, C	FALSE	FALSE	FALSE	FALSE
1641	10.1055/s-0037-1609718	doi.org/10.1055/s-0037-1609718	Facile Protocols towards C2-Arylated Benzoxazoles using Fe(III)-Catalyzed C(sp(2)-H) Functionalization and Metal-Free Domino Approach		Synlett	95	Malakar, CC	FALSE	FALSE	FALSE	FALSE
1642	10.1021/acs.joc.7b03198	doi.org/10.1021/acs.joc.7b03198	Synthesis of Polysubstituted Quinolines from alpha-2-Aminoaryl Alcohols Via Nickel-Catalyzed Dehydrogenative Coupling		J. Org. Chem.	95	De Sarkar, S	FALSE	FALSE	FALSE	FALSE
1643	10.1021/acscatal.7b03688	doi.org/10.1021/acscatal.7b03688	Nickel-Catalyzed Suzuki-Miyaura Coupling of Aliphatic Amides		ACS Catal.	95	Garg, NK	FALSE	FALSE	FALSE	FALSE
1644	10.1055/s-0034-1379878	doi.org/10.1055/s-0034-1379878	Copper Nanopowder Catalyzed Cross-Coupling of Diaryl Disulfides with Aryl Iodides in PEG-400		Synlett	95	Wu, XM	FALSE	FALSE	FALSE	FALSE
1645	10.1021/om5007177	doi.org/10.1021/om5007177	Nickel(II) Pincer Carbene Complexes: Oxidative Addition of an Aryl C-H Bond to Form a Ni(II) Hydride		Organometallics	95	Fout, AR	FALSE	FALSE	FALSE	FALSE
1646	10.1007/s10562-014-1449-4	doi.org/10.1007/s10562-014-1449-4	High-Valent Co(III)- and Ni(II)-Catalyzed C-H Activation		Catal. Lett.	95	Hyster, TK	FALSE	FALSE	FALSE	FALSE
1647	10.1063/1674-0068/27/06/640-646	doi.org/10.1063/1674-0068/27/06/640-646	Density Functional Theory Calculations on Ni-Ligand Bond Dissociation Enthalpies		Chin. J. Chem. Phys.	95	Yu, HZ	FALSE	FALSE	FALSE	FALSE
1648	10.1002/asia.201300251	doi.org/10.1002/asia.201300251	Catalytic Asymmetric Synthesis of Spirooxindoles via Addition of Isothiocyanato Oxindoles to Aldehydes Under Dinuclear Nickel Schiff Base Catalysis		Chem.-Asian J.	95	Kanai, M	FALSE	FALSE	FALSE	FALSE
1649	10.1021/ja209572m	doi.org/10.1021/ja209572m	A Water-Soluble Pybox Derivative and Its Highly Luminescent Lanthanide Ion Complexes		J. Am. Chem. Soc.	95	de Bettencourt-Dias, A	FALSE	FALSE	FALSE	FALSE
1650	10.1002/chem.201102936	doi.org/10.1002/chem.201102936	Cyanation of Aryl Bromides with K4[Fe(CN)6] Catalyzed by Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a Molecular Source of Nanoparticles, and the Reactions Involved in the Catalyst-Deactivation Processes		Chem.-Eur. J.	95	Frech, CM	FALSE	FALSE	FALSE	FALSE
1651	10.1002/ejic.201101036	doi.org/10.1002/ejic.201101036	Nickel-Catalyzed Cross-Coupling with Pincer Ligandsz		Eur. J. Inorg. Chem.	95	Wang, ZX	FALSE	FALSE	FALSE	FALSE
1652	10.1016/j.jorganchem.2011.01.003	doi.org/10.1016/j.jorganchem.2011.01.003	Stoichiometric and catalytic C-Cl activation of Aryl Chlorides using an NHC-stabilized nickel(0) complex		J. Organomet. Chem.	95	Radius, U	FALSE	FALSE	FALSE	FALSE
1653	10.1002/chem.200600502	doi.org/10.1002/chem.200600502	Nickel(II) complexes of bidentate N-heterocyclic carbene/phosphine ligands: Efficient catalysts for Suzuki coupling of aryl chlorides		Chem.-Eur. J.	95	Lee, HM	FALSE	FALSE	FALSE	FALSE
1654	10.1016/S0957-4166(03)00520-2	doi.org/10.1016/S0957-4166(03)00520-2	Planar chiral 2-ferrocenyloxazolines and 1,1 '-bis(oxazolinyl)ferrocenes-syntheses and applications in asymmetric catalysis		Tetrahedron-Asymmetry	95	Bryce, MR	FALSE	FALSE	FALSE	FALSE
1655	10.1002/anie.202114365	doi.org/10.1002/anie.202114365	Photoredox Activation of Inert Alkyl Chlorides for the Reductive Cross-Coupling with Aromatic Alkenes		Angew. Chem.-Int. Edit.	95	Lloret-Fillol, J	TRUE	FALSE	FALSE	FALSE
1656	10.1002/anie.202116725	doi.org/10.1002/anie.202116725	Selective Fluoromethyl Couplings of Alkynes via Nickel Catalysis		Angew. Chem.-Int. Edit.	95	Chu, LL	FALSE	FALSE	FALSE	FALSE
1657	10.1039/d1dt03353k	doi.org/10.1039/d1dt03353k	Theoretical mechanistic study of 4CzIPN/Ni-0-metallaphotoredox catalyzed enantioselective desymmetrization of cyclic meso-anhydrides		Dalton Trans.	95	Sun, GY; Su, ZM	FALSE	FALSE	FALSE	FALSE
1658	10.1039/d1gc03060d	doi.org/10.1039/d1gc03060d	Photoinduced remote heteroaryl migration accompanied by cyanoalkylacylation in continuous flow		Green Chem.	95	Qiu, JK; Guo, K	TRUE	FALSE	FALSE	FALSE
1659	10.1021/acs.joc.1c00910	doi.org/10.1021/acs.joc.1c00910	Combined Experimental and Computational Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cross-Coupling of Sodium Benzoates with Chloroarenes		J. Org. Chem.	95	Topczewski, JJ	FALSE	FALSE	FALSE	FALSE
1660	10.1002/ejoc.202100367	doi.org/10.1002/ejoc.202100367	Propargyl Radicals in Organic Synthesis		Eur. J. Org. Chem.	95	Green, JR	FALSE	FALSE	FALSE	FALSE
1661	10.1002/chem.202100018	doi.org/10.1002/chem.202100018	Synergistic Effect of NiLDH@YZ Hybrid and Mechanochemical Agitation on Glaser Homocoupling Reaction		Chem.-Eur. J.	95	Mokhtar, M	FALSE	FALSE	FALSE	FALSE
1662	10.1039/d1ob00259g	doi.org/10.1039/d1ob00259g	The transition-metal-catalyzed stereoselective ring-expansion of vinylaziridines and vinyloxiranes		Org. Biomol. Chem.	95	Punniyamurthy, T	FALSE	FALSE	FALSE	FALSE
1663	10.1021/jacs.1c02629	doi.org/10.1021/jacs.1c02629	Cobalt-Catalyzed Markovnikov-Selective Radical Hydroacylation of Unactivated Alkenes with Acylphosphonates		J. Am. Chem. Soc.	95	Li, CZ	FALSE	FALSE	FALSE	FALSE
1664	10.1002/chem.201702608	doi.org/10.1002/chem.201702608	Cobalt-Catalyzed Esterification of Amides		Chem.-Eur. J.	95	Gosmini, C; Danoun, G	FALSE	FALSE	FALSE	FALSE
1665	10.1016/j.tetlet.2016.08.017	doi.org/10.1016/j.tetlet.2016.08.017	One-pot synthesis of 3-naphtho[2,1-b]furanyl-2-oxindoles from 3-(arylethyny1)-3-hydroxyindolin-2-ones and 2-naphthols		Tetrahedron Lett.	95	Kim, JN	FALSE	FALSE	FALSE	FALSE
1666	10.1002/chem.201603092	doi.org/10.1002/chem.201603092	Nickel-Catalyzed C-H Chalcogenation of Anilines		Chem.-Eur. J.	95	Ackermann, L	FALSE	FALSE	FALSE	FALSE
1667	10.1016/j.ica.2020.119887	doi.org/10.1016/j.ica.2020.119887	Synthesis and structural characterization of facile ruthenium(II) hydrazone complexes: Efficient catalysts in alpha-alkylation of ketones with primary alcohols via hydrogen auto transfer	A series of NHC-iridium coordination polymers have proven to be robust, efficient and recyclable solid molecular catalysts toward the hydrogenation of biomass levulinic acid (LA) to gamma-valerolactone. Along with quantitative yields attained at 0.01 mol% catalyst loading under 50 atm of H2, the solid molecular catalyst was readily recovered and reused for 12 runs without obvious loss of the selectivity and activity. Remarkably, up to 1.2 X 10(5) TON, an unprecedented value could be achieved in this important transformation. In addition, a number of LA homologues, analogues and derivatives were well tolerated to deliver various intriguing and functional lactones in good to excellent yields, which further confirmed the feasibility of the solid molecular catalysts.	Inorg. Chim. Acta	94	Viswanathamurthi, P	FALSE	FALSE	FALSE	FALSE
1668	10.1002/slct.202002270	doi.org/10.1002/slct.202002270	A Practical Approach to Ureas and Thiocarbamates: SO2F2-Promoted Lossen Rearrangement of Hydroxamic Acid	Advances in nickel catalysis have enabled the employment of the widely available and environmentally benign phenol derivatives as aryl electrophiles in Suzuki-Miyaura cross-coupling reactions. Ni-II-phosphine complexes such as (NiCl2)-Cl-II(PPh3)(2), (NiCl2)-Cl-II(dppf), (NiCl2)-Cl-II(dppe), (NiCl2)-Cl-II(dppp), (NiCl2)-Cl-II(PCy3)(2) and pi-Ni-0 complexes, the classic being Ni(COD)(2)/PCy3, both classes mostly in the presence of a mixed ligand, are some of the most successful precatalysts employed in the cross-coupling of aryl mesylates, sulfamates, carboxylic esters, carbonates, carbamates and methyl ethers with aryl boronic acids, boroxines and neopentylglycolboronates. Here we report that the highly reactive but bench-stable sigma-Ni-II complex, (NiCl)-Cl-II(1-naphthyl)(PCy3)(2) (where sigma refers to the Ni-C bond), exhibits higher efficiency than all previously reported precatalysts and facilitates the quantitative cross-coupling of all six C-O electrophiles mentioned above in reaction times of 0.5 to 24 hours.	ChemistrySelect	94	Ding, CR	FALSE	FALSE	FALSE	FALSE
1669	10.1021/jacs.0c03184	doi.org/10.1021/jacs.0c03184	Overcoming Selectivity Issues in Reversible Catalysis: A Transfer Hydrocyanation Exhibiting High Kinetic Control	Nitrogen-containing organic compounds are valuable in many fields of science and industry. The most reliable method for the construction of C(sp(2))-N bonds is undoubtedly palladium-catalyzed amination. In spite of the great achievements made in this area, the use of expensive Pd-based catalysts constitutes an important limitation for large-scale applications. Since nickel is the least expensive and most abundant among the group 10 metals, the interest in Ni-based catalysts for processes typically catalyzed by palladium has grown considerably over the last few years. Herein, we revise the development of Ni-catalyzed amination reactions, emphasizing the most relevant and recent advances in the field.	J. Am. Chem. Soc.	94	Morandi, B	FALSE	FALSE	FALSE	FALSE
1670	10.1002/anie.202005058	doi.org/10.1002/anie.202005058	Stereoselective Access to Fully Substituted Aldehyde-Derived Silyl Enol Ethers by Iridium-Catalyzed Alkene Isomerization	A copper-catalyzed direct propargylation of polyfluoroarenes with secondary propargyl phosphates has been developed. The reaction proceeds under mild reaction conditions with high efficiency and regioselectivity and provides a concise and straightforward method for the synthesis of polyfluoroarylated derivatives of interest in both life and materials science.	Angew. Chem.-Int. Edit.	94	Marek, I	FALSE	FALSE	FALSE	FALSE
1671	10.1021/acs.joc.0c00640	doi.org/10.1021/acs.joc.0c00640	Methoxylation of Acyl Fluorides with Tris(2,4,6-trimethoxyphenyl)phosphine via C-OMe Bond Cleavage under Metal-Free Conditions	Functionalized tetrahydrofluorenes were synthesized using a normal electron-demand Diels-Alder cycloaddition reaction between 2-vinylindenes and various dienophiles. Electron rich 2-vinylindenes bearing methoxy groups at the 4- and 7- positions were accessed through their corresponding 2-indenylpivalates obtained using a Pt-catalyzed cycloisomerization reaction. DFT calculations were used to rationalize the observed regioselectivity in the Diels-Alder reaction, and the cycloadditions were extended to a 2-allenylindene substrate. (C) 2016 Elsevier Ltd. All rights reserved.	J. Org. Chem.	94	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
1672	10.1039/d0ra02912b	doi.org/10.1039/d0ra02912b	Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols	A new method for the decarboxylative coupling of alkyl N-hydroxyphthalimide esters (NHP esters) with aryl iodides is presented. In contrast to previous studies that form alkyl radicals from carboxylic acid derivatives, no photocatalyst, light, or arylmetal reagent is needed, only nickel and a reducing agent (Zn). Methyl, primary, and secondary alkyl groups can all be coupled in good yield (77% ave yield). One coupling with an acid chloride is also presented. Stoichiometric reactions of (dtbbpy)Ni(2-tolyl)I with an NHP ester show for the first time that arylnickel(II) complexes can directly react with NHP esters to form alkylated arenes.	RSC Adv.	94	Wang, JY	FALSE	FALSE	FALSE	FALSE
1673	10.1002/adsc.201901670	doi.org/10.1002/adsc.201901670	Selective Formation of 2-(2-Aminophenyl)benzothiazoles via Copper-Catalyzed Aerobic C-C Bond Cleavage of Isatins	A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched -arylated ketones without the use of transition metals from readily accessible alkenes.	Adv. Synth. Catal.	94	Huang, HW	FALSE	FALSE	FALSE	FALSE
1674	10.1016/j.isci.2020.100966	doi.org/10.1016/j.isci.2020.100966	Suzuki-Miyaura Coupling Enabled by Aryl to Vinyl 1,4-Palladium Migration	A Nickel-catalyzed reductive process is described for the direct amidation of benzyl and aryl halides using carbodiimides as the amidating agent. Moreover, aryl and benzyl C-O electrophiles such as triflate, acetate, tosylate, trityl ether, and pivalate were converted into amides using this method. The insitu-generated Ni-0 acts as a catalyst for the reaction at room temperature for benzylic substrates, and 70 degrees C for aryl electrophiles. This new nickel-catalyzed reductive coupling protocol provides a general and operationally simple method for the synthesis of diverse amides using carbodiimides. Amides bearing bulky substituents can be synthesized by this strategy in high yield, which demonstrates its effectiveness in amide synthesis.	iScience	94	Feng, CG; Lin, GQ	FALSE	FALSE	FALSE	FALSE
1675	10.1002/ejoc.201901851	doi.org/10.1002/ejoc.201901851	Nickel-Catalyzed C-O Cross-Coupling Reaction at Low Catalytic Loading with Weak Base Participation		Eur. J. Org. Chem.	94	Chen, HJ	FALSE	FALSE	FALSE	FALSE
1676	10.1002/chem.201904545	doi.org/10.1002/chem.201904545	Generation of Organozinc Reagents by Nickel Diazadiene Complex Catalyzed Zinc Insertion into Aryl Sulfonates		Chem.-Eur. J.	94	Hintermann, L	FALSE	FALSE	FALSE	FALSE
1677	10.1039/c9ob02129a	doi.org/10.1039/c9ob02129a	HClO4 catalysed aldol-type reaction of fluorinated silyl enol ethers with acetals or ketals toward fluoroalkyl ethers		Org. Biomol. Chem.	94	Zhou, Y; Zhou, J	FALSE	FALSE	FALSE	FALSE
1678	10.1073/pnas.1909972116	doi.org/10.1073/pnas.1909972116	SuFEx-enabled, agnostic discovery of covalent inhibitors of human neutrophil elastase		Proc. Natl. Acad. Sci. U. S. A.	94	Sharpless, KB	FALSE	FALSE	FALSE	FALSE
1679	10.1021/acs.orglett.9b01849	doi.org/10.1021/acs.orglett.9b01849	CuH-Catalyzed Synthesis of 3-Hydroxyindolines and 2-Aryl-3H-indol-3-ones from o-Alkynylnitroarenes, Using Nitro as Both the Nitrogen and Oxygen Source		Org. Lett.	94	Yin, BL	FALSE	FALSE	FALSE	FALSE
1680	10.1021/acs.orglett.9b02145	doi.org/10.1021/acs.orglett.9b02145	Controllable alpha- or beta-Functionalization of alpha-Diazoketones with Aromatic Amides via Cobalt-Catalyzed C-H Activation: A Regioselective Approach to Isoindolinones		Org. Lett.	94	Li, YZ	FALSE	FALSE	FALSE	FALSE
1681	10.3390/inorganics7060078	doi.org/10.3390/inorganics7060078	Bulky-Yet-Flexible Carbene Ligands and Their Use in Palladium Cross-Coupling		Inorganics	94	Cazin, CSJ	FALSE	FALSE	FALSE	FALSE
1682	10.1021/acs.organomet.8b00878	doi.org/10.1021/acs.organomet.8b00878	Nickel(II)- and Palladium(II)-NHC Complexes from Hydroxypyridine Functionalized C,O Chelate Type Ligands: Synthesis, Structure, and Catalytic Activity toward Kumada-Tamao-Corriu Reaction		Organometallics	94	Anantharaman, G	FALSE	FALSE	FALSE	FALSE
1683	10.1021/acscatal.9b00744	doi.org/10.1021/acscatal.9b00744	Nickel-Catalyzed Stille Cross Coupling of C-O Electrophiles		ACS Catal.	94	Neufeldt, SR	FALSE	TRUE	FALSE	FALSE
1684	10.1002/chem.201802635	doi.org/10.1002/chem.201802635	N-Boc-Amides in Cross-Coupling Reactions		Chem.-Eur. J.	94	Danoun, G	FALSE	FALSE	FALSE	FALSE
1685	10.24820/ark.5550190.p010.866	doi.org/10.24820/ark.5550190.p010.866	Cobalt-, copper- and chromium-catalyzed carbon-carbon coupling reactions using a broad spectrum of Grignard reagents as reaction partners		Arkivoc	94	Dahadha, AA	FALSE	FALSE	FALSE	FALSE
1686	10.1002/adsc.201801135	doi.org/10.1002/adsc.201801135	An Efficient Ga(OTf)(3)/Isopropanol Catalytic System for Direct Reduction of Benzylic Alcohols		Adv. Synth. Catal.	94	Sai, M	FALSE	FALSE	FALSE	FALSE
1687	10.1021/acs.orglett.8b02109	doi.org/10.1021/acs.orglett.8b02109	Palladium-Catalyzed Carbonylative Synthesis of alpha,beta-Unsaturated Amides from Styrenes and Nitroarenes		Org. Lett.	94	Peng, JB; Wu, XF	FALSE	FALSE	FALSE	FALSE
1688	10.1021/acs.organomet.8b00011	doi.org/10.1021/acs.organomet.8b00011	Ni(I)-Hydride Catalyst for Hydrosilylation of Carbon Dioxide and Dihydrogen Generation: Theoretical Prediction and Exploration of Full Catalytic Cycle		Organometallics	94	Deshmukh, MM	FALSE	FALSE	FALSE	FALSE
1689	10.1002/adsc.201701506	doi.org/10.1002/adsc.201701506	Ni-Catalyzed C-F Bond Functionalization of Unactivated Aryl Fluorides and Corresponding Coupling with Oxazoles		Adv. Synth. Catal.	94	Zhang, H	FALSE	FALSE	FALSE	FALSE
1690	10.1002/cctc.201701709	doi.org/10.1002/cctc.201701709	On the Generality of Molecular Volcano Plots		ChemCatChem	94	Corminboeuf, C	FALSE	FALSE	FALSE	FALSE
1691	10.1039/c6dt02995g	doi.org/10.1039/c6dt02995g	Alkyl Grignard cross-coupling of aryl phosphates catalyzed by new, highly active ionic iron(II) complexes containing a phosphine ligand and an imidazolium cation		Dalton Trans.	94	Sun, HM	FALSE	FALSE	FALSE	FALSE
1692	10.1039/c6ra18510j	doi.org/10.1039/c6ra18510j	N-Heterocyclic carbene copper(I) complex-catalyzed synthesis of 2-aryl benzoxazoles and benzothiazoles		RSC Adv.	94	Tapia, RA	FALSE	FALSE	FALSE	FALSE
1693	10.1021/jacs.5b10119	doi.org/10.1021/jacs.5b10119	Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C-F Bond Functionalizations		J. Am. Chem. Soc.	94	Niwa, T	FALSE	FALSE	FALSE	FALSE
1694	10.1021/ja510980d	doi.org/10.1021/ja510980d	Organocatalytic Asymmetric Synthesis of 1,1-Diarylethanes by Transfer Hydrogenation		J. Am. Chem. Soc.	94	Zhu, GY	FALSE	FALSE	FALSE	FALSE
1695	10.1039/c5cs00144g	doi.org/10.1039/c5cs00144g	Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates		Chem. Soc. Rev.	94	Zhang, WB	FALSE	FALSE	FALSE	FALSE
1696	10.1002/chem.201403141	doi.org/10.1002/chem.201403141	Harnessing the ortho-Directing Ability of the Azetidine Ring for the Regioselective and Exhaustive Functionalization of Arenes		Chem.-Eur. J.	94	Degennaro, L	FALSE	FALSE	FALSE	FALSE
1697	10.1016/j.tet.2014.02.011	doi.org/10.1016/j.tet.2014.02.011	Calculated linear free energy relationships in the course of the Suzuki-Miyaura coupling reaction		Tetrahedron	94	Santelli, M	FALSE	FALSE	FALSE	FALSE
1698	10.1039/c3dt53012d	doi.org/10.1039/c3dt53012d	Synthesis of heteroboroxines with MB2O3 core (M = Sb, Bi, Sn)-an influence of the substitution of parent boronic acids		Dalton Trans.	94	Jambor, R	FALSE	FALSE	FALSE	FALSE
1699	10.1021/om400784w	doi.org/10.1021/om400784w	Use of Base Control To Provide High Selectivity between Diaryl Thioether and Diaryl Disulfide for C-S Coupling Reactions of Aryl Halides and Sulfur and a Mechanistic Study		Organometallics	94	Chen, HY	FALSE	FALSE	FALSE	FALSE
1700	10.1021/jo102338a	doi.org/10.1021/jo102338a	Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)(2)/Pyridine		J. Org. Chem.	94	Stahl, SS	FALSE	FALSE	FALSE	FALSE
1701	10.1021/ja1083392	doi.org/10.1021/ja1083392	Exploring Chromium(III)-Alkyl Bond Homolysis with CpCr[(ArNCMe)(2)CH](R) Complexes		J. Am. Chem. Soc.	94	Smith, KM	FALSE	FALSE	FALSE	FALSE
1702	10.1002/cssc.200800256	doi.org/10.1002/cssc.200800256	Molecular-Weight-Enlarged Multiple-Pincer Ligands: Synthesis and Application in Palladium-Catalyzed Allylic Substitution Reactions		ChemSusChem	94	Ronde, NJ	FALSE	FALSE	FALSE	FALSE
1703	10.1039/d1cc05899a	doi.org/10.1039/d1cc05899a	Recent advances on non-precious metal-catalyzed C-H functionalization of N-heteroarenes		Chem. Commun.	94	Banerjee, D	FALSE	FALSE	FALSE	FALSE
1704	10.1039/d1sc04071e	doi.org/10.1039/d1sc04071e	Nickel-catalyzed enantioselective 1,2-vinylboration of styrenes		Chem. Sci.	94	Ye, Y; Xie, T; Ye, XY	FALSE	FALSE	FALSE	FALSE
1705	10.1002/cjoc.201600330	doi.org/10.1002/cjoc.201600330	One-Pot Synthesis of Triarylmethanes via Metal-Free Reductive Coupling of Diaryl Ketones, Tosylhydrazide, and Arylboronic Acids		Chin. J. Chem.	94	Liu, P; Liu, Y	FALSE	FALSE	FALSE	FALSE
1706	10.1002/anie.201510497	doi.org/10.1002/anie.201510497	Lewis Acid Assisted Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers by C-O Bond-Cleaving Alkylation: Prevention of Undesired -Hydride Elimination		Angew. Chem.-Int. Edit.	94	Schoenebeck, F; Rueping, M	FALSE	FALSE	FALSE	FALSE
1707	10.1021/acs.orglett.6b00846	doi.org/10.1021/acs.orglett.6b00846	Cp*Co-III-Catalyzed Dehydrative C-H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols		Org. Lett.	94	Yoshino, T; Matsunaga, S	FALSE	FALSE	FALSE	FALSE
1708	10.1021/acs.joc.0c02605	doi.org/10.1021/acs.joc.0c02605	Visible Light Mediated Photocatalytic N-Radical Cascade Reactivity of gamma,delta-Unsaturated N-Arylsulfonylhydrazones: A General Approach to Structurally Diverse Tetrahydropyridazines	A series of O, N-chelated diarylborinates have been prepared and tested as arylboron counterpart alternative to oxygen-labile diarylborinic acids in palladium catalyzed Suzuki coupling of aryl chlorides. 3-Dimethylaminopropyl diarylborinates (B-5a), featuring a six-membered O, N-chelated boron ring that was confirmed by single crystal X-ray diffraction, displayed a delicately balanced stability and reactivity. Their cross-coupling with structurally various aryl chlorides could be effected as efficiently as that of the parent diarylborinic acids by using 0.1 similar to 1mol% Pd(OAc)(2)/lPr/P(OPh)(3) as catalyst system, to provide the corresponding biaryls in good to excellent yields. (C) 2017 Elsevier B.V. All rights reserved.	J. Org. Chem.	93	Deagostino, A	TRUE	FALSE	FALSE	FALSE
1709	10.1016/j.tetlet.2020.152604	doi.org/10.1016/j.tetlet.2020.152604	Bidentate geometry-constrained iminopyridyl nickel-catalyzed synthesis of amines or imines via borrowing hydrogen or dehydrogenative condensation	A Pd-catalyzed ring-opening of beta-lactones with various types of amines (primary, secondary, and aryl) to provide beta-hydroxy amides with excellent selectivity toward acyl C-O bond cleavage is reported. The utility of this protocol is demonstrated in an asymmetric kinetic resolution providing enantioenriched a-methylene-beta-lactones.	Tetrahedron Lett.	93	Jin, LQ	FALSE	FALSE	FALSE	FALSE
1710	10.1021/acs.orglett.0c01892	doi.org/10.1021/acs.orglett.0c01892	[n]Dendralenes as a Platform for Selective Catalysis: Ligand-Controlled Cu-Catalyzed Chemo-, Regio-, and Enantioselective Borylations	Here, we describe a photoredox-assisted catalytic system for the direct reductive coupling of two carbon electrophiles. Recent advances have shown that nickel catalysts are active toward the coupling of sp(3)-carbon electrophiles and that well-controlled, light-driven coupling systems are possible. Our system, composed of a nickel catalyst, an iridium photosensitizer, and an amine electron donor, is capable of coupling halocarbons with high yields. Spectroscopic studies support a mechanism where under visible light irradiation the Ir photosensitizer in conjunction with triethanolamine are capable of reducing a nickel catalyst and activating the catalyst toward cross coupling of carbon electrophiles. The synthetic methodology developed here operates at low 1 mol % catalyst and photosensitizer loadings. The catalytic system also operates without reaction additives such as inorganic salts or bases. A general and effective sp(2)-sp(3) cross-coupling scheme has been achieved that exhibits tolerance to a wide array of functional groups.	Org. Lett.	93	Mazet, C	FALSE	FALSE	FALSE	FALSE
1711	10.1002/anie.202000704	doi.org/10.1002/anie.202000704	Access to 1,3-Dinitriles by Enantioselective Auto-tandem Catalysis: Merging Allylic Cyanation with Asymmetric Hydrocyanation	1,3-Diarylisobenzofuran-DMAD adducts upon reaction with BF3 center dot OEt2 in DCM at room temperature underwent a regiospecific 1,2-aryl migration followed by the Krapcho decarboxylation to give tri-substituted alpha-naphthols in good yields.	Angew. Chem.-Int. Edit.	93	Fang, XJ	FALSE	FALSE	FALSE	FALSE
1712	10.1021/acs.orglett.9b03434	doi.org/10.1021/acs.orglett.9b03434	Ni-Catalyzed Suzuki-Miyaura Cross-Coupling of Aliphatic Amides on the Benchtop		Org. Lett.	93	Garg, NK	FALSE	FALSE	FALSE	FALSE
1713	10.1002/anie.201909543	doi.org/10.1002/anie.201909543	Visible-Light-Enabled Stereodivergent Synthesis of E- and Z-Configured 1,4-Dienes by Photoredox/Nickel Dual Catalysis		Angew. Chem.-Int. Edit.	93	Chu, LL	TRUE	FALSE	FALSE	FALSE
1714	10.1021/acs.joc.9b01103	doi.org/10.1021/acs.joc.9b01103	Palladium-Catalyzed Decarbonylative Suzuki-Miyaura Coupling of Amides To Achieve Biaryls via C-N Bond Cleavage		J. Org. Chem.	93	Zhu, YL; Zeng, Z	FALSE	FALSE	FALSE	FALSE
1715	10.1021/acs.joc.9b01113	doi.org/10.1021/acs.joc.9b01113	Generation of Aryl Radicals from Aryl Halides: Rongalite-Promoted Transition-Metal-Free Arylation		J. Org. Chem.	93	Wang, YH	FALSE	FALSE	FALSE	FALSE
1716	10.1021/acs.orglett.9b01755	doi.org/10.1021/acs.orglett.9b01755	Cu-Catalyzed Cross-Dehydrogenative Coupling of Heteroaryl C(sp(2))-H and Tertiary C(sp(3))-H Bonds for the Construction of All-Carbon Triaryl Quaternary Centers		Org. Lett.	93	Qiu, RH; Kambe, N	FALSE	FALSE	FALSE	FALSE
1717	10.1039/c9cy00009g	doi.org/10.1039/c9cy00009g	Recent advances and prospects in nickel-catalyzed C-H activation		Catal. Sci. Technol.	93	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
1718	10.1021/acs.jpcc.8b08357	doi.org/10.1021/acs.jpcc.8b08357	Thermally Activated Delayed Fluorescence (Green) in Undoped Film and Exciplex Emission (Blue) in Acridone-Carbazole Derivatives for OLEDs		J. Phys. Chem. C	93	Agarwal, N	FALSE	FALSE	FALSE	FALSE
1719	10.1002/anie.201810145	doi.org/10.1002/anie.201810145	Palladium-Catalyzed Decarbonylative Borylation of Carboxylic Acids: Tuning Reaction Selectivity by Computation		Angew. Chem.-Int. Edit.	93	Szostak, M	FALSE	FALSE	FALSE	FALSE
1720	10.1039/c8ob01832d	doi.org/10.1039/c8ob01832d	Decarbonylative cross-coupling of amides		Org. Biomol. Chem.	93	Szostak, M	FALSE	FALSE	FALSE	FALSE
1721	10.1002/asia.201800575	doi.org/10.1002/asia.201800575	A General Palladium-Phosphine Complex To Explore Aryl Tosylates in the N-Arylation of Amines: Scope and Limitations		Chem.-Asian J.	93	So, CM; Kwong, FY	FALSE	FALSE	FALSE	FALSE
1722	10.1002/cctc.201701617	doi.org/10.1002/cctc.201701617	Expedient Synthesis of N-Methyl- and N-Alkylamines by Reductive Amination using Reusable Cobalt Oxide Nanoparticles		ChemCatChem	93	Jagadeesh, RV	FALSE	FALSE	FALSE	FALSE
1723	10.1039/c7dt04560c	doi.org/10.1039/c7dt04560c	Displacement of eta(5)-cyclopentadienyl ligands from half-sandwich C,C-(NHC-cyanoalkyl)-nickel(II) metallacycles: further insight into the structure of the resulting Cp-free nickelacycles and a catalytic activity study		Dalton Trans.	93	Chetcuti, MJ; Ritleng, V	FALSE	FALSE	FALSE	FALSE
1724	10.1002/ejoc.201701142	doi.org/10.1002/ejoc.201701142	Directed ortho-Metalation of O-Aryl N,N-Dialkylcarbamates: Methodology, Anionic ortho-Fries Rearrangement, and Lateral Metalation		Eur. J. Org. Chem.	93	Miah, MAJ	FALSE	FALSE	FALSE	FALSE
1725	10.1039/c7gc02540h	doi.org/10.1039/c7gc02540h	H-Bonding-promoted radical addition of simple alcohols to unactivated alkenes		Green Chem.	93	Liu, ZQ	FALSE	FALSE	FALSE	FALSE
1726	10.1039/c6sc01120a	doi.org/10.1039/c6sc01120a	Palladium-catalyzed regioselective and stereo-invertive ring-opening borylation of 2-arylaziridines with bis(pinacolato) diboron: experimental and computational studies		Chem. Sci.	93	Takeda, Y; Minakata, S	FALSE	FALSE	FALSE	FALSE
1727	10.1016/j.jorganchem.2015.03.007	doi.org/10.1016/j.jorganchem.2015.03.007	Nickel complexes of 1,2,4-triazole derived amido-functionalized N-heterocyclic carbene ligands: Synthesis, theoretical studies and catalytic application		J. Organomet. Chem.	93	Ghosh, P	FALSE	FALSE	FALSE	FALSE
1728	10.1039/c4ra12658k	doi.org/10.1039/c4ra12658k	Asymmetric synthesis of (1R,2S)-1-amino-2-vinylcyclopropanecarboxylic acid by sequential S(N)2-S(N)2 ' dialkylation of (R)-N-(benzyl)proline-derived glycine Schiff base Ni(II) complex		RSC Adv.	93	Han, JL	FALSE	FALSE	FALSE	FALSE
1729	10.1021/jo400435z	doi.org/10.1021/jo400435z	Trineopentylphosphine: A Conformationally Flexible Ligand for the Coupling of Sterically Demanding Substrates in the Buchwald-Hartwig Amination and Suzuki-Miyaura Reaction		J. Org. Chem.	93	Shaughnessy, KH	FALSE	FALSE	FALSE	FALSE
1730	10.1021/jo4002382	doi.org/10.1021/jo4002382	Studies for the Total Synthesis of Amphidinolide P		J. Org. Chem.	93	Williams, DR	FALSE	FALSE	FALSE	FALSE
1731	10.1002/asia.201000875	doi.org/10.1002/asia.201000875	Nickel-Catalyzed Allylic Substitution of Simple Alkenes		Chem.-Asian J.	93	Jamison, TF	FALSE	FALSE	FALSE	FALSE
1732	10.1002/ijch.201000033	doi.org/10.1002/ijch.201000033	Pd-, Ni-, Fe-, and Co-Catalyzed Cross-Couplings Using Functionalized Zn-, Mg-, Fe-, and In-Organometallics		Isr. J. Chem.	93	Knochel, P	FALSE	FALSE	FALSE	FALSE
1733	10.1021/jo101023t	doi.org/10.1021/jo101023t	Neopentylglycolborylation of ortho-Substituted Aryl Halides Catalyzed by NiCl2-Based Mixed-Ligand Systems		J. Org. Chem.	93	Percec, V	FALSE	FALSE	FALSE	FALSE
1734	10.1055/s-0029-1218756	doi.org/10.1055/s-0029-1218756	Metal-Catalyzed Allylation of Organoboranes and Organoboronic Acids		Synthesis	93	Pigge, FC	FALSE	FALSE	FALSE	FALSE
1735	10.1002/aoc.1547	doi.org/10.1002/aoc.1547	Synthesis and characterization of transition metal complexes of thiophene-2-methylamine: X-ray crystal structure of palladium (II) and platinum (II) complexes and use of palladium(II) complexes as pre-catalyst in Heck and Suzuki cross-coupling reactions		Appl. Organomet. Chem.	93	Baysal, A	FALSE	FALSE	FALSE	FALSE
1736	10.1016/j.jorganchem.2009.02.019	doi.org/10.1016/j.jorganchem.2009.02.019	Phosphine free diamino-diol based palladium catalysts and their application in Suzuki-Miyaura cross-coupling reactions		J. Organomet. Chem.	93	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
1737	10.1021/jo801445y	doi.org/10.1021/jo801445y	Palladium-phosphinous acid-catalyzed cross-coupling of aryl and acyl halides with aryl-, alkyl-, and vinylzinc reagents		J. Org. Chem.	93	Wolf, C	FALSE	FALSE	FALSE	FALSE
1738	10.1055/s-2002-32945	doi.org/10.1055/s-2002-32945	Metalated sulfonamides and their synthetic applications		Synlett	93	Familoni, OB	FALSE	FALSE	FALSE	FALSE
1739	10.1246/bcsj.75.137	doi.org/10.1246/bcsj.75.137	Synthesis of unsymmetrical ketones by palladium-catalyzed cross-coupling reaction of carboxylic anhydrides with organoboron compounds		Bull. Chem. Soc. Jpn.	93	Yamamoto, A	FALSE	FALSE	FALSE	FALSE
1740	10.1021/ma960557s	doi.org/10.1021/ma960557s	Solubilization of regioregular and regioirregular poly(p-phenylene)s via CF3 and OCF3 substituents to generate a model for rigid-rod polymers		Macromolecules	93		FALSE	FALSE	FALSE	FALSE
1741	10.1002/anie.202201142	doi.org/10.1002/anie.202201142	Direct Dehydrogenative Access to Unsymmetrical Phenones		Angew. Chem.-Int. Edit.	93	Patureau, FW	FALSE	FALSE	FALSE	FALSE
1742	10.1016/j.chempr.2021.10.023	doi.org/10.1016/j.chempr.2021.10.023	Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol		Chem	93	Leboeuf, D; Moran, J	FALSE	FALSE	FALSE	FALSE
1743	10.1021/acscatal.1c04314	doi.org/10.1021/acscatal.1c04314	Stereodivergent Synthesis of Both Z- and E-Alkenes by Photoinduced, Ni-Catalyzed Enantioselective C(sp(3))-H Alkenylation		ACS Catal.	93	Huo, HH	TRUE	FALSE	FALSE	FALSE
1744	10.1002/tcr.202100224	doi.org/10.1002/tcr.202100224	Direct Access to Amides from Nitro-Compounds via Aminocarbonylation and Amidation Reactions: A Minireview		Chem. Rec.	93	Batra, S	FALSE	FALSE	FALSE	FALSE
1745	10.1021/acs.organomet.1c00085	doi.org/10.1021/acs.organomet.1c00085	Synthesis of Triarylmethanes via Palladium-Catalyzed Suzuki-Miyaura Reactions of Diarylmethyl Esters		Organometallics	93	Hazari, N	FALSE	FALSE	FALSE	FALSE
1746	10.1002/anie.202101634	doi.org/10.1002/anie.202101634	Stereoselective Sc(OTf)(3)-Catalyzed Aldol Reactions of Disubstituted Silyl Enol Ethers of Aldehydes with Acetals		Angew. Chem.-Int. Edit.	93	Marek, I	FALSE	FALSE	FALSE	FALSE
1747	10.1016/j.tetlet.2017.03.003	doi.org/10.1016/j.tetlet.2017.03.003	Iron-catalyzed C-sp3-C-sp3 bond formation via dehydrative cross coupling reaction: Facile access to new hybrid dihydroquinazolines having quinoline, isoquinoline, quinoxaline and azoles		Tetrahedron Lett.	93	Reddy, KR	FALSE	FALSE	FALSE	FALSE
1748	10.1002/anie.201700433	doi.org/10.1002/anie.201700433	Enantioselective Iridium-Catalyzed Allylic Substitution with 2-Methylpyridines		Angew. Chem.-Int. Edit.	93	You, SL	FALSE	FALSE	FALSE	FALSE
1749	10.1002/asia.201601712	doi.org/10.1002/asia.201601712	Reductive Homocoupling of Organohalides Using Nickel(II) Chloride and Samarium Metal		Chem.-Asian J.	93	Liu, YJ	FALSE	FALSE	FALSE	FALSE
1750	10.1002/chem.201605445	doi.org/10.1002/chem.201605445	Access to Enantiopure Triarylmethanes and 1,1-Diarylalkanes by NHC-Catalyzed Acylative Desymmetrization		Chem.-Eur. J.	93	Wong, MW; Zhao, Y	FALSE	FALSE	FALSE	FALSE
1751	10.2174/1570179413666160624092044	doi.org/10.2174/1570179413666160624092044	Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by Supported Palladium Under Microwave Irradiation		Curr. Org. Synth.	93	Li, QH	FALSE	FALSE	FALSE	FALSE
1752	10.1002/adsc.201600492	doi.org/10.1002/adsc.201600492	Palladium NNC Pincer Complex as an Efficient Catalyst for the Cycloisomerization of Alkynoic Acids		Adv. Synth. Catal.	93	SanMartin, R; Dominguez, E	FALSE	FALSE	FALSE	FALSE
1753	10.1002/anie.201604025	doi.org/10.1002/anie.201604025	Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor		Angew. Chem.-Int. Edit.	93	Zhao, Y	FALSE	FALSE	FALSE	FALSE
1754	10.1055/s-0035-1561302	doi.org/10.1055/s-0035-1561302	Nano-Pd/Al(OH)(3)-Catalyzed Suzuki-Miyaura Coupling Reaction of Potassium Aryl- and Heteroaryltrifluoroborates with Electrophiles in Alcohols		Synlett	93	Li, X; Wei, WL	FALSE	TRUE	FALSE	FALSE
1755	10.1039/c5sc03359d	doi.org/10.1039/c5sc03359d	Nickel-catalyzed trifluoromethylthiolation of Csp(2)-O bonds		Chem. Sci.	93	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
1756	10.1055/s-0040-1706000	doi.org/10.1055/s-0040-1706000	Regioselective Oxidative Cross-Coupling Reaction: Synthesis of Imidazo[1,2-a]pyridine Fluorophores	One palladium dichloride adduct of a phosphine-pyridine ligand N-diphenylphosphanyl-2-aminopyridine (L-1) [(L-1)PdCl2] (1) has been prepared and structurally characterized. Compound 1 can be used as an effective catalyst for the Suzuki-Miyaura cross-coupling reactions of unreactive aryl chlorides with aryl boronic acids, and worked much better than its mono- or bidentate phosphine ligands. The reactions with a wide scope of substrates proceeded to give desired products in good to excellent yields. (C) 2017 Elsevier Ltd. All rights reserved.	Synthesis	92	Ma, C	FALSE	FALSE	FALSE	FALSE
1757	10.1021/acs.jcim.0c01041	doi.org/10.1021/acs.jcim.0c01041	tmQM Dataset-Quantum Geometries and Properties of 86k Transition Metal Complexes	The N-heterocyclic carbene catalyzed [3 + 3] annulation of indolin-2-imines and bromoenals was developed to give dihydropyridinone-fused indoles in good to high yields, which were transformed to alpha-carbolines with different 2-subsituents by a process of dehydrogenation, tosylation, and palladium catalyzed C-C or C-N coupling reaction.	J. Chem Inf. Model.	92	Balcells, D	FALSE	FALSE	FALSE	FALSE
1758	10.1055/s-0040-1707131	doi.org/10.1055/s-0040-1707131	Copper-Catalyzed Methylthiolation of Aryl Iodides and Bromides with Dimethyl Disulfide in Water	Aryl-aryl bond formation constitutes one of the most important subjects in organic synthesis. The recent developments in direct arylation reactions forming aryl-aryl bond have emerged as very attractive alternatives to traditional cross-coupling reactions. Here, we describe a general palladium-catalyzed direct arylation and cyclization of o-iodobiaryls to build a library of tetraphenylenes. This transformation represents one of the very few examples of C-H activation process that involves simultaneous formation of two aryl-aryl bonds. Oxygen plays a vital role by ensuring high reactivity, with air as the promoter furnished the best results. We anticipate this ligand-free and aerobic catalytic system will simplify the synthesis of tetraphenylenes as many of the reported methods involve use of preformed organometallic reagents and will lead to the discovery of highly efficient new direct arylation process.	Synlett	92	Wu, XM	FALSE	FALSE	FALSE	FALSE
1759	10.1039/d0ra02195d	doi.org/10.1039/d0ra02195d	Terpyridine-based Pd(ii)/Ni(ii) organometallic framework nano-sheets supported on graphene oxide-investigating the fabrication, tuning of catalytic properties and synergetic effects	In this paper, we report the construction of pharmacologically relevant isoindolinones and isoindolo[2,1-a] quinolines through the Zn-mediated Barbier-type allylation/lactamization sequential reactions and intramolecular Heck annulation reactions, respectively. The Zn-mediated Barbier-type allylation/lactamization sequential reactions of imine systems derived from alkyl 2-formylbenzoates afforded a library of N-substituted 3-allyl-isoindolinone scaffolds. Then, this route was applied to assemble various N-(2-haloaryl)-3-allyl-isoindolinone derivatives, which were subsequently subjected to the Pd-catalyzed intramolecular Heck-type annulation reaction to afford the corresponding isoindolo[2,1-a] quinoline frameworks. We have shown a formal synthesis of the bio-active isoindolo[2,1-a] quinoline system 1g by synthesizing the dione system 12, which was an intermediate in the Ishihara's scheme pertaining to the synthesis of the bio-active isoindolo[2,1-a] quinoline system 1g.	RSC Adv.	92	Li, TS; Wu, YJ	FALSE	FALSE	FALSE	FALSE
1760	10.1021/acs.orglett.0c00960	doi.org/10.1021/acs.orglett.0c00960	Titanocene-Catalyzed Reductive Domino Epoxide Ring Opening/Defluorinative Cross-Coupling Reaction	Organocatalyzed highly stereoselective 1,4-thia-Michael addition of mercaptans to linear 2,4-dienones and 2-en-4-ynones was developed using Cinchona alkaloid-based squaramides. Application of only 0.5-1mol% loading afforded products in up to 98:2 e.r. and above 99:1 after a single recrystallization. The adducts of allyl mercaptan can be conveniently further transformed to new chiral 2-substituted 2,5-dihydrothiophenes by ring-closing metathesis.	Org. Lett.	92	Wang, C	FALSE	FALSE	FALSE	FALSE
1761	10.1021/acs.accounts.0c00032	doi.org/10.1021/acs.accounts.0c00032	Mechanisms of Nickel-Catalyzed Coupling Reactions and Applications in Alkene Functionalization	PBr3-mediated reductive deoxygenation of alpha-aryl-pyridinemethanols to provide arylmethylpyridines is described, the alcohol substrate scope is explored, free radical trap TEMPO (2,2;6,6-tetramethyl-1-piperidinyloxy) is introduced, and the hydrogen source of the methylene product is defined. The unexpected reaction enabled us to prepare previously inaccessible, novel EP1 antagonists. (C) 2016 Elsevier Ltd. All rights reserved.	Accounts Chem. Res.	92	Diao, T	FALSE	FALSE	FALSE	FALSE
1762	10.1021/acs.orglett.9b04497	doi.org/10.1021/acs.orglett.9b04497	Nickel-Catalyzed Deaminative Acylation of Activated Aliphatic Amines with Aromatic Amides via C-N Bond Activation		Org. Lett.	92	Matsuo, Y	FALSE	FALSE	FALSE	FALSE
1763	10.1021/acs.joc.9b02816	doi.org/10.1021/acs.joc.9b02816	Boron-Catalyzed N-Alkylation of Arylamines and Arylamides with Benzylic Alcohols		J. Org. Chem.	92	Maji, B	FALSE	FALSE	FALSE	FALSE
1764	10.1002/adsc.201901009	doi.org/10.1002/adsc.201901009	Transition-Metal-Free Three-Component Synthesis of Tertiary Aryl Amines from Nitro Compounds, Boronic Acids, and Trialkyl Phosphites		Adv. Synth. Catal.	92	Csaky, AG	FALSE	FALSE	FALSE	FALSE
1765	10.1039/c9sc03347e	doi.org/10.1039/c9sc03347e	Ni-catalyzed cross-electrophile coupling between vinyl/aryl and alkyl sulfonates: synthesis of cycloalkenes and modification of peptides		Chem. Sci.	92	Shu, XZ	FALSE	FALSE	FALSE	FALSE
1766	10.1021/acs.orglett.9b02034	doi.org/10.1021/acs.orglett.9b02034	Enantioselective Synthesis of 4-Aminotetrahydroquinolines via 1,2-Reductive Dearomatization of Quinolines and Copper(I) Hydride-Catalyzed Asymmetric Hydroamination		Org. Lett.	92	Xiao, Z; You, SL	FALSE	FALSE	FALSE	FALSE
1767	10.1002/anie.201902405	doi.org/10.1002/anie.201902405	A Facile Enantioselective Alkynylation of Chromones		Angew. Chem.-Int. Edit.	92	Aponick, A	FALSE	FALSE	FALSE	FALSE
1768	10.1021/acs.orglett.9b01048	doi.org/10.1021/acs.orglett.9b01048	Nickel-Catalyzed Decarboxylative Alkenylation of Anhydrides with Vinyl Triflates or Halides		Org. Lett.	92	Liao, XB	FALSE	FALSE	FALSE	FALSE
1769	10.1021/jacs.9b00615	doi.org/10.1021/jacs.9b00615	Iron-Catalyzed Aerobic Dehydrogenative Kinetic Resolution of Cyclic Secondary Amines		J. Am. Chem. Soc.	92	Liu, L	FALSE	FALSE	FALSE	FALSE
1770	10.1039/c8sc05677c	doi.org/10.1039/c8sc05677c	Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp(3))-H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis		Chem. Sci.	92	Mitsunuma, H; Kanai, M	FALSE	FALSE	FALSE	FALSE
1771	10.6023/cjoc201809027	doi.org/10.6023/cjoc201809027	Nano-Gold Catalyzed Transesterification of (Hetero)aryl Esters with Alkyl Halides via C-O Activation		Chin. J. Org. Chem.	92	Bao, YS	FALSE	FALSE	FALSE	FALSE
1772	10.1002/anie.201813222	doi.org/10.1002/anie.201813222	NiH-Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic -Bromo Amides		Angew. Chem.-Int. Edit.	92	Zhu, SL	FALSE	FALSE	FALSE	FALSE
1773	10.3390/molecules24040696	doi.org/10.3390/molecules24040696	Electrochemical Umpolung of Bromide: Transition-Metal-Free Bromination of Indole C-H Bond		Molecules	92	Chen, JB	FALSE	TRUE	FALSE	FALSE
1774	10.1002/ajoc.201800535	doi.org/10.1002/ajoc.201800535	Palladium-Catalyzed Direct Methylation and Benzylation of Enamides Using Iodomethane and Benzyl Halides with Retention of Alkenyl Moiety		Asian J. Org. Chem.	92	Ding, R	FALSE	FALSE	FALSE	FALSE
1775	10.1039/c8cy00996a	doi.org/10.1039/c8cy00996a	Light-activated Ullmann homocoupling of aryl halides catalyzed using gold nanoparticle-functionalized potassium niobium oxides		Catal. Sci. Technol.	92	Hallett-Tapley, GL	FALSE	FALSE	FALSE	FALSE
1776	10.1021/acsomega.8b02155	doi.org/10.1021/acsomega.8b02155	Nickel-Catalyzed Decarbonylative Alkylation of Aroyl Fluorides Assisted by Lewis-Acidic Organoboranes		ACS Omega	92	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
1777	10.1021/acs.orglett.8b02351	doi.org/10.1021/acs.orglett.8b02351	Nickel-Catalyzed Csp(2)-Csp(3) Bond Formation via C-F Bond Activation		Org. Lett.	92	Rueping, M	FALSE	FALSE	FALSE	FALSE
1778	10.1002/anie.201805396	doi.org/10.1002/anie.201805396	An Interrupted Pummerer/Nickel-Catalysed Cross-Coupling Sequence		Angew. Chem.-Int. Edit.	92	Procter, DJ	FALSE	FALSE	FALSE	FALSE
1779	10.1002/ejoc.201800330	doi.org/10.1002/ejoc.201800330	Branched-Selective Decarboxylative Heck Reaction with Electronically Unbiased Olefins		Eur. J. Org. Chem.	92	Zhang, M; Su, WP	FALSE	TRUE	FALSE	FALSE
1780	10.1002/chem.201705842	doi.org/10.1002/chem.201705842	Nickel-Catalyzed C-S Bond Formation via Decarbonylative Thioetherification of Esters, Amides and Intramolecular Recombination Fragment Coupling of Thioesters		Chem.-Eur. J.	92	Rueping, M	FALSE	FALSE	FALSE	FALSE
1781	10.1039/c7ob02318a	doi.org/10.1039/c7ob02318a	Differentiation of enantiomeric anions by NMR spectroscopy with chiral bisurea receptors		Org. Biomol. Chem.	92	Ito, S; Asami, M	FALSE	FALSE	FALSE	FALSE
1782	10.1002/anie.201711155	doi.org/10.1002/anie.201711155	Photocatalytic Oxygen Evolution from Functional Triazine-Based Polymers with Tunable Band Structures		Angew. Chem.-Int. Edit.	92	Wang, XC	TRUE	FALSE	FALSE	FALSE
1783	10.1021/acs.joc.7b02004	doi.org/10.1021/acs.joc.7b02004	Design, Synthesis, and Application of Polymer-Supported Silicon-Transfer Agents for Cross-Coupling Reactions with Organolithium Reagents		J. Org. Chem.	92	Smith, AB	FALSE	FALSE	FALSE	FALSE
1784	10.1039/c5qo00395d	doi.org/10.1039/c5qo00395d	Nickel catalyzed reduction of arenols under mild conditions		Org. Chem. Front.	92	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
1785	10.1055/s-0034-1378871	doi.org/10.1055/s-0034-1378871	Synthesis of Polyfunctional Secondary Amines by the Reaction of Functionalized Organomagnesium Reagents with Tertiary Nitroalkanes		Synthesis	92	Dhayalan, V	FALSE	FALSE	FALSE	FALSE
1786	10.1002/anie.201408199	doi.org/10.1002/anie.201408199	Chiral Counteranion Strategy for Asymmetric Oxidative C(sp(3))-H/C(sp(3))-H Coupling: Enantioselective alpha-Allylation of Aldehydes with Terminal Alkenes		Angew. Chem.-Int. Edit.	92	Gong, LZ	FALSE	FALSE	FALSE	FALSE
1787	10.6023/cjoc201307014	doi.org/10.6023/cjoc201307014	Recent Advances in Transition Metal Catalyzed Decarboxylative Coupling Reactions of Alkyl Carboxylic Acid		Chin. J. Org. Chem.	92	Dai, JJ	FALSE	FALSE	FALSE	FALSE
1788	10.1002/ejoc.201300592	doi.org/10.1002/ejoc.201300592	Palladium(II) Catalyzed Suzuki/Sonogashira Cross-Coupling Reactions of Sulfonates: An Efficient Approach to C2-Functionalized Pyrimidines and Pyridines		Eur. J. Org. Chem.	92	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
1789	10.1002/chem.201203666	doi.org/10.1002/chem.201203666	Mechanistic Study on Ligand-Controlled Cobalt-Catalyzed Regioselectivity-Switchable Hydroarylation of Styrenes		Chem.-Eur. J.	92	Fu, Y	FALSE	FALSE	FALSE	FALSE
1790	10.1016/j.jorganchem.2012.05.027	doi.org/10.1016/j.jorganchem.2012.05.027	Alkynylboron compounds in organic synthesis		J. Organomet. Chem.	92	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
1791	10.1021/ja310351e	doi.org/10.1021/ja310351e	Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes		J. Am. Chem. Soc.	92	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
1792	10.1021/ja307045r	doi.org/10.1021/ja307045r	Direct Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of Grignard Reagents via Ni-, Fe-, or Co-Catalyzed sp(3) C-O Bond Activation		J. Am. Chem. Soc.	92	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
1793	10.1016/j.tet.2012.03.072	doi.org/10.1016/j.tet.2012.03.072	Palladium-catalyzed coupling reactions of (ArCH2)Ti(O-i-Pr)(3) with aromatic or heteroaromatic bromides		Tetrahedron	92	Gau, HM	FALSE	FALSE	FALSE	FALSE
1794	10.1039/c2sc20103h	doi.org/10.1039/c2sc20103h	Theoretical study of Pd(0)-catalyzed carbohalogenation of alkenes: mechanism and origins of reactivities and selectivities in alkyl halide reductive elimination from Pd(II) species		Chem. Sci.	92	Lautens, M	FALSE	FALSE	FALSE	FALSE
1795	10.1021/jm2010404	doi.org/10.1021/jm2010404	Synthesis and Biochemical Evaluation of Delta(2)-Isoxazoline Derivatives as DNA Methyltransferase 1 Inhibitors		J. Med. Chem.	92	Kuck, D	FALSE	FALSE	FALSE	FALSE
1796	10.1002/anie.201007464	doi.org/10.1002/anie.201007464	Rhodium-Catalyzed Direct Addition of Aryl C-H Bonds to N-Sulfonyl Aldimines		Angew. Chem.-Int. Edit.	92	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
1797	10.1021/om800460h	doi.org/10.1021/om800460h	Osmium-catalyzed allylic alkylation		Organometallics	92	Esteruelas, MA	FALSE	FALSE	FALSE	FALSE
1798	10.1021/ic0518273	doi.org/10.1021/ic0518273	Group 10 metal aminopyridinato complexes: Synthesis, structure, and application as aryl-Cl activation and hydrosilane polymerization catalysts		Inorg. Chem.	92	Kempe, R	FALSE	FALSE	FALSE	FALSE
1799	10.1021/jo00106a031	doi.org/10.1021/jo00106a031	ARYL MESYLATES IN METAL-CATALYZED HOMOCOUPLING AND CROSS-COUPLING REACTIONS .1. FUNCTIONAL SYMMETRICAL BIARYLS FROM PHENOLS VIA NICKEL-CATALYZED HOMOCOUPLING OF THEIR MESYLATES		J. Org. Chem.	92	PERCEC, V	FALSE	FALSE	FALSE	FALSE
1800	10.1021/jo00364a002	doi.org/10.1021/jo00364a002	COUPLING OF ARYL CHLORIDES BY NICKEL AND REDUCING METALS		J. Org. Chem.	92	COLON, I	FALSE	FALSE	FALSE	FALSE
1801	10.1002/cctc.202101579	doi.org/10.1002/cctc.202101579	C-F Bond Activation and Functionalizations Enabled by Metal-free NHCs and Their Metal Complexes		ChemCatChem	92	Gandhi, T	FALSE	FALSE	FALSE	FALSE
1802	10.1021/acscatal.1c04538	doi.org/10.1021/acscatal.1c04538	Visible-Light-Promoted Iron-Catalyzed N-Arylation of Dioxazolones with Arylboronic Acids		ACS Catal.	92	Yu, XQ; Bao, M	FALSE	FALSE	FALSE	FALSE
1803	10.1126/science.abj4213	doi.org/10.1126/science.abj4213	Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis		Science	92	Doyle, AG	FALSE	FALSE	FALSE	FALSE
1804	10.1021/acs.inorgchem.1c02157	doi.org/10.1021/acs.inorgchem.1c02157	Bottom-Up Approach for the Rational Loading of Linear Oligomers and Polymers with Lanthanides		Inorg. Chem.	92	Piguet, C	FALSE	FALSE	FALSE	FALSE
1805	10.1002/anie.202108336	doi.org/10.1002/anie.202108336	Enantioselective Lactonization by pi-Acid-Catalyzed Allylic Substitution: A Complement to pi-Allylmetal Chemistry		Angew. Chem.-Int. Edit.	92	Aponick, A	FALSE	FALSE	FALSE	FALSE
1806	10.1055/a-1577-7638	doi.org/10.1055/a-1577-7638	Transition-Metal-Catalyzed Nucleophilic Dearomatization of Electron-Deficient Heteroarenes		Synthesis	92	Xia, Y	FALSE	TRUE	FALSE	FALSE
1807	10.1021/jacs.1c03827	doi.org/10.1021/jacs.1c03827	Ni-Catalyzed Ligand-Controlled Regiodivergent Reductive Dicarbofunctionalization of Alkenes		J. Am. Chem. Soc.	92	Kong, WQ	FALSE	FALSE	FALSE	FALSE
1808	10.1039/d1sc02575a	doi.org/10.1039/d1sc02575a	Stereoselective tandem iridium-catalyzed alkene isomerization-cope rearrangement of omega-diene epoxides: efficient access to acyclic 1,6-dicarbonyl compounds		Chem. Sci.	92	Marek, I	FALSE	FALSE	FALSE	FALSE
1809	10.1021/acs.organomet.1c00017	doi.org/10.1021/acs.organomet.1c00017	The Mechanism and Origin of Enantioselectivity in the Rhodium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabicyclic Alkenes with Organoboronic Acids: A DFT Investigation		Organometallics	92	Chen, LD	FALSE	FALSE	FALSE	FALSE
1810	10.1002/poc.4250	doi.org/10.1002/poc.4250	Metal-free catalytic activation and borylation of the -H bond of 1-methyl pyrrole using adamantane-derived aminoborane frustrated Lewis pairs: A density functional theory study		J. Phys. Org. Chem.	92	Ganguly, B	FALSE	FALSE	FALSE	FALSE
1811	10.1039/d1cy00374g	doi.org/10.1039/d1cy00374g	Reactions of nickel(0) with organochlorides, organobromides, and organoiodides: mechanisms and structure/reactivity relationships		Catal. Sci. Technol.	92	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
1812	10.1021/jacs.7b05574	doi.org/10.1021/jacs.7b05574	Nickel-Catalyzed C-H Silylation of Arenes with Vinylsilanes: Rapid and Reversible beta-Si Elimination		J. Am. Chem. Soc.	92	Johnson, SA	FALSE	FALSE	FALSE	FALSE
1813	10.1039/c6qo00515b	doi.org/10.1039/c6qo00515b	Calcium mediated C-F bond substitution in fluoroarenes towards C-chalcogen bond formation		Org. Chem. Front.	92	Ranu, BC	FALSE	FALSE	FALSE	FALSE
1814	10.1021/acscatal.6b01816	doi.org/10.1021/acscatal.6b01816	Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins		ACS Catal.	92	Maiti, D	FALSE	FALSE	FALSE	FALSE
1815	10.1002/ejoc.201501570	doi.org/10.1002/ejoc.201501570	Sequential Synthesis of Organosilicon-Linked 2-Methoxypyridines by Non-Cryogenic ortho-Metallation Using the nBu(2)TMPMg center dot Li Reagent and Hydrosilylation		Eur. J. Org. Chem.	92	Sosnicki, JG	FALSE	FALSE	FALSE	FALSE
1816	10.1039/d0ob02518f	doi.org/10.1039/d0ob02518f	Revisiting the synthesis of aryl nitriles: a pivotal role of CAN	Ni-mediated trifluoromethylation of an aryl-Br bond in model macrocyclic ligands (L-n-Br) has been thoroughly studied, starting with an oxidative addition at Ni-0 to obtain well-defined aryl-Ni-II-Br complexes ([L-n-Ni-II]Br). Abstraction of the halide with AgX (X=OTf- or ClO4-) thereafter provides [L-n-Ni-II](OTf). The nitrate analogue has been obtained through a direct C-H activation of an aryl-H bond using Ni-II salts, and this route has been studied by X-ray absorption spectroscopy (XAS). Crystallographic XRD and XAS characterization has shown a tight macrocyclic coordination in the aryl-Ni-II complex, which may hamper direct reaction with nucleophiles. On the contrary, enhanced reactivity is observed with oxidants, and the reaction of [L-n-Ni-II](OTf) with CF3+ sources afforded L-n-CF3 products in quantitative yield. A combined experimental and theoretical mechanistic study provides new insights into the operative mechanism for this transformation. Computational analysis indicates the occurrence of an initial single electron transfer (SET) to 5-(trifluoromethyl)dibenzothiophenium triflate (TDTT), producing a transient L-1-Ni-III/CF3 center dot adduct, which rapidly recombines to form a [L-1-Ni-IV-CF3](X)(2) intermediate species. A final facile reductive elimination affords L-1-CF3. The well-defined square-planar model system studied here permits to gain fundamental knowledge on the rich redox chemistry of nickel, which is sought to facilitate the development of new Ni-based trifluoromethylation methodologies.	Org. Biomol. Chem.	91	Bora, U	FALSE	FALSE	FALSE	FALSE
1817	10.1021/acs.joc.0c02478	doi.org/10.1021/acs.joc.0c02478	Manganese Catalyzed Direct Amidation of Esters with Amines	The applicability of computational descriptors extracted from metal pyridine-oxazoline complexes to relate both site and enantioselectivity to structural diversity was investigated. A group of computationally derived features (e.g., metal NBO charges, steric descriptors, torsion angles) were acquired for a library of pyridine-oxazoline ligands. Correlation studies were employed to examine steric/electronic features described by each descriptor, followed by application of the said descriptors in modeling the results of two reaction types, the site-selective redox-relay Heck reaction and the enantioselective Carroll rearrangement, affording simple, well-validated models. Through experimental validation and extrapolation, parameters derived from ground state metal complexes were found to be advantageous over those from the free ligand.	J. Org. Chem.	91	Liu, N	FALSE	FALSE	FALSE	FALSE
1818	10.1021/acs.joc.0c02400	doi.org/10.1021/acs.joc.0c02400	Efficient alpha-Alkylation of Arylacetonitriles with Secondary Alcohols Catalyzed by a Phosphine-Free Air-Stable Iridium(III) Complex	Photoredox catalysis has experienced a revitalized interest from the synthesis community during the past decade. For example, photoredox/Ni dual catalysis protocols have been developed to overcome several inherent limitations of palladium-catalyzed cross-couplings by invoking a single-electron transmetalation pathway. This Perspective highlights advances made by our laboratory since the inception of the photoredox/Ni cross-coupling of benzyltrifluoroborates with aryl bromides. In addition to broadening the scope of trifluoroborate coupling partners, research using readily oxidized hypervalent silicates as radical precursors that demonstrate functional group compatibility is highlighted. The pursuit of electrophilic coupling partners beyond (hetero)aryl bromides has also led to the incorporation of several new classes of C(sp(2))-hybridized substrates into light-mediated cross-coupling. Advances to expand the radical toolbox by utilizing feedstock chemicals (e.g., aldehydes) to access radicals that were previously inaccessible from trifluoroborates and silicates are also emphasized. Additionally, several organic photocatalysts have been investigated as replacements for their expensive iridium- and ruthenium-based counterparts. Lastly, the net C H functionalization of the radical partner in an effort to improve atom economy is presented. An underlying theme in all of these studies is the value of generating radicals in a catalytic manner, rather than stoichiometrically.	J. Org. Chem.	91	Bagh, B	FALSE	FALSE	TRUE	TRUE
1819	10.1021/jacs.0c09949	doi.org/10.1021/jacs.0c09949	Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of Unactivated Alkenes	A convenient and efficient approach for the formation of nitrogen heterocycle-fused imidazo[1,2-a]pyridine and benzo[b]selenophenes has been developed through copper-catalyzed direct selenylation of readily available 2-(2-bromophenyl)imidazo[1,2-a]pyridines via regioselective cleavage of C(sp(2)) Br and C(sp(2)) H bonds using readily available selenium powder as the selenylating reagents under ligand-and base-free conditions in air. Preliminary mechanistic investigations indicated that radical species were involved in the present transformation. [GRAPHICS]	J. Am. Chem. Soc.	91	Luan, YX; Ye, MC	FALSE	FALSE	FALSE	FALSE
1820	10.1021/acs.orglett.0c02528	doi.org/10.1021/acs.orglett.0c02528	Carboxyl-Assisted meta-Selective C-H Functionalizations of Benzylsulfonamides	This report describes the synthesis and characterization of a family of unsymmetrical NCN pincer Ni(II) complexes 2-8 with NHC-triazole arms. All of these complexes have been fully characterized by X-ray single crystal analysis, NMR spectroscopy, and elemental analysis. Complexes 2 and 4-6 were square planar with a chloride trans to the carbene carbon atoms. Complex 3 was a paramagnetic octahedral complex with its central metal surrounded by two NCN pincer ligands. Complexes 7 and 8 contain [(NHC)(2)Ni-2-OH] moieties bearing a OH bridge. Both the [(NHC)(2)Ni-2-OH] complexes 7 and 8 and [(NCNHCN)Ni-Cl] complexes 2 and 4-6 were synthesized similarly via the reactions of the in situ formed Ag-NHCs from the corresponding imidazolium salts with [NiCl2(PPh3)(2)]. The catalytic activities of all complexes for Suzuki-Miyaura cross-coupling were examined. Under the optimized conditions, complex 4 was active in the Suzuki-Miyaura cross-coupling reactions of aryl iodides and aryl bromides at 110 degrees C. Aryl chlorides were successfully coupled in the presence of triphenylphosphine as an additive.	Org. Lett.	91	Li, SD; Li, G	FALSE	FALSE	FALSE	FALSE
1821	10.1002/ejoc.202000623	doi.org/10.1002/ejoc.202000623	Exploring the Versatility of 7-Alkynylcycloheptatriene Scaffolds Under pi-Acid Catalysis	A novel and efficient TMSCl-mediated cyclization reaction of easily prepared 2-propynolphenols/anilines is developed to give 4-chloro-2H-chromenes and 1,2-dihydroquinolines in good to efficient yields. It is noted that TMSCl acts not only as a promoter in this reaction, and also as the chloro source. Both tertiary and secondary propargylic alcohols with diverse functional groups were tolerated under mild conditions. Moreover, this method can be enlarged to gram scale (yield up to 90%). (C) 2016 Elsevier Ltd. All rights reserved.	Eur. J. Org. Chem.	91	Bour, C; Gandon, V	FALSE	FALSE	FALSE	FALSE
1822	10.1021/jacs.0c04670	doi.org/10.1021/jacs.0c04670	Sulfonate Versus Sulfonate: Nickel and Palladium Multimetallic Cross-Electrophile Coupling of Aryl Triflates with Aryl Tosylates	The Heck reaction between arenes and allyl acetate has led to cinnamyl derivatives and allyl. products depending on the regioselectivity of beta-elimination. The regioselectivity can be controlled by the solvent in the Rh(III)-catalyzed arene allyl acetate coupling via C-H activation: (1) in THF, cinnamyl derivatives via beta-H elimination were generated; (2) in MeOH, allyl products via beta-OAc elimination were produced. Both routes have advantages such as excellent gamma-selectivity toward allyl acetate, good to excellent yields, and broad substrate scope.	J. Am. Chem. Soc.	91	Weix, DJ	FALSE	TRUE	FALSE	FALSE
1823	10.1039/d0sc01471k	doi.org/10.1039/d0sc01471k	Sequential C-O decarboxylative vinylation/C-H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade	(1R,2S)-1-Amino-2-vinylcyclopropane-1-carboxylic acid (vinyl-ACCA) is the essential pharmacophoric unit in a new generation of highly potent hepatitis C virus (HCV) NS3/4A protease inhibitors. Currently, there are over a dozen drugs under development that use the special properties of this highly sterically constrained tailor-made amino acid, underscoring the extremely high demand for the asymmetric synthesis of (1R,2S)-vinyl-ACCA. This work presents a comprehensive overview of methods that have been developed to date for the preparation of (1R,2S)-vinyl-ACCA and its optical isomers. The presented data are grouped in three sections based on the biocatalytic, catalytic, and stoichiometric source of chirality. Aspects of operational convenience, practicality, and scalability are critically discussed.	Chem. Sci.	91	Chu, LL	FALSE	FALSE	FALSE	FALSE
1824	10.1002/ejoc.201901853	doi.org/10.1002/ejoc.201901853	The Binomial Copper-Catalysis and Asymmetric Ring Opening of Strained Heterocycles: Past and Future Challenges	A representative substrate scope investigation for an enantioselective catalytic ketone-reduction has been performed as a single reaction on a mixture containing equimolar amounts of nine (9) prototypical compounds. The resulting analyte pool containing 18 potential products from nine different reactions could all be completely resolved in a single chromatographic injection using comprehensive two-dimensional gas chromatography (GCxGC) with time-of-flight mass spectrometry, allowing for simultaneous determination of percent conversion and enantiomeric excess for each substrate. The results obtained for an enantioselective iron-catalyzed asymmetric transfer hydrogenation using this one-pot/single-analysis approach were similar to those reported for the individualized reactions, demonstrating the utility of this strategy for streamlining substrate scope investigations. Moreover, for this particular catalyst, activity and selectivity were not greatly affected by the presence of other ketones or enantioenriched reduced products. This approach allows for faster and greener analyses that are central to new reaction development, as well as an opportunity to gain further insights into other established transformations.	Eur. J. Org. Chem.	91	Pineschi, M	FALSE	FALSE	FALSE	FALSE
1825	10.1039/c9qo01391a	doi.org/10.1039/c9qo01391a	Catalytic asymmetric 1,4-type Friedel-Crafts (hetero)arylations of 1-azadienes: the highly enantioselective syntheses of chiral hetero-triarylmethanes		Org. Chem. Front.	91	Deng, YH; Shao, ZH	FALSE	FALSE	FALSE	FALSE
1826	10.1039/c9cc07710c	doi.org/10.1039/c9cc07710c	Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: activation of C-O bonds		Chem. Commun.	91	Chatani, N	FALSE	FALSE	FALSE	FALSE
1827	10.1021/acscatal.9b03366	doi.org/10.1021/acscatal.9b03366	Decarboxylative Phosphine Synthesis: Insights into the Catalytic, Autocatalytic, and Inhibitory Roles of Additives and Intermediates		ACS Catal.	91	Larionov, OV	FALSE	FALSE	FALSE	FALSE
1828	10.1021/jacs.9b07857	doi.org/10.1021/jacs.9b07857	Modular Dual-Tasked C-H Methylation via the Catellani Strategy		J. Am. Chem. Soc.	91	Zhou, QH	FALSE	FALSE	FALSE	FALSE
1829	10.1002/anie.201906264	doi.org/10.1002/anie.201906264	Regioselective Synthesis of Fused Furans by Decarboxylative Annulation of alpha,beta-Alkenyl Carboxylic Acid with Cyclic Ketone: Synthesis of Di-Heteroaryl Derivatives		Angew. Chem.-Int. Edit.	91	Lahiri, GK; Maiti, D	FALSE	FALSE	FALSE	FALSE
1830	10.1002/anie.201904774	doi.org/10.1002/anie.201904774	A Bulky Chiral N-Heterocyclic Carbene Nickel Catalyst Enables Enantioselective C-H Functionalizations of Indoles and Pyrroles		Angew. Chem.-Int. Edit.	91	Cramer, N	FALSE	FALSE	FALSE	FALSE
1831	10.1055/s-0037-1611518	doi.org/10.1055/s-0037-1611518	Direct Synthesis of Deuterium-Labeled O -, S -, N -Vinyl Derivatives from Calcium Carbide		Synthesis	91	Ananikov, VP	FALSE	FALSE	FALSE	FALSE
1832	10.1016/j.cclet.2019.04.008	doi.org/10.1016/j.cclet.2019.04.008	Recent progress in transition metal catalyzed cross coupling of nitroarenes		Chin. Chem. Lett.	91	Peng, LF; Tang, ZL	FALSE	FALSE	FALSE	FALSE
1833	10.1002/anie.201903377	doi.org/10.1002/anie.201903377	Cobalt-Catalyzed Enantioselective Hydroboration/Cyclization of 1,7-Enynes: Asymmetric Synthesis of Chiral Quinolinones Containing Quaternary Stereogenic Centers		Angew. Chem.-Int. Edit.	91	Ge, SZ	FALSE	FALSE	FALSE	FALSE
1834	10.1021/jacs.9b00097	doi.org/10.1021/jacs.9b00097	A Unified Explanation for Chemoselectivity and Stereospecificity of Ni-Catalyzed Kumada and Cross-Electrophile Coupling Reactions of Benzylic Ethers: A Combined Computational and Experimental Study		J. Am. Chem. Soc.	91	Hong, X	FALSE	TRUE	FALSE	FALSE
1835	10.1021/jacs.9b00931	doi.org/10.1021/jacs.9b00931	Regio- and Enantioselective C-H Cyclization of Pyridines with Alkenes Enabled by a Nickel/N-Heterocyclic Carbene Catalysis		J. Am. Chem. Soc.	91	Shi, SL	FALSE	FALSE	FALSE	FALSE
1836	10.6023/cjoc201810020	doi.org/10.6023/cjoc201810020	Theoretical Advances on the Mechanism of Transition Metal-Catalyzed C-F Functionalization		Chin. J. Org. Chem.	91	Lan, Y	FALSE	FALSE	FALSE	FALSE
1837	10.1002/jhet.3280	doi.org/10.1002/jhet.3280	A Highly Efficient Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction of 5-(5-chloropyridin-3-yl)-3-methyl-1,3,4-oxadiazol-2(3H)-one		J. Heterocycl. Chem.	91	Padusha, MSA	FALSE	FALSE	FALSE	FALSE
1838	10.3389/fcimb.2018.00230	doi.org/10.3389/fcimb.2018.00230	The Pseudomonas Quinolone Signal (PQS): Not Just for Quorum Sensing Anymore		Front. Cell. Infect. Microbiol.	91	Lin, JS	FALSE	FALSE	FALSE	FALSE
1839	10.1002/adsc.201800150	doi.org/10.1002/adsc.201800150	Application of 7-Indolylmethanols in Catalytic Asymmetric Arylations with Tryptamines: Enantioselective Synthesis of 7-indolylmethanes		Adv. Synth. Catal.	91	Mei, GJ; Shi, F	FALSE	FALSE	FALSE	FALSE
1840	10.1002/anie.201713278	doi.org/10.1002/anie.201713278	Alkenylation of C(sp(3))-H Bonds by Zincation/Copper-Catalyzed Cross-Coupling with Iodonium Salts		Angew. Chem.-Int. Edit.	91	Wang, Q	FALSE	FALSE	FALSE	FALSE
1841	10.1021/acs.joc.7b01468	doi.org/10.1021/acs.joc.7b01468	Hypervalent Iodine-Mediated Oxidative Rearrangement of N-H Ketimines: An Umpolung Approach to Amides		J. Org. Chem.	91	Zhao, JF	FALSE	FALSE	FALSE	FALSE
1842	10.1021/jacs.7b08064	doi.org/10.1021/jacs.7b08064	Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH		J. Am. Chem. Soc.	91	Zhu, SL	FALSE	TRUE	FALSE	FALSE
1843	10.1002/ejoc.201500630	doi.org/10.1002/ejoc.201500630	Nickel-Catalyzed Decarbonylative Coupling of Aryl Esters and Arylboronic Acids		Eur. J. Org. Chem.	91	Love, JA	FALSE	FALSE	FALSE	FALSE
1844	10.1021/acs.joc.5b00647	doi.org/10.1021/acs.joc.5b00647	(Z)-Selective Enol Triflation of alpha-Alkoxyacetoaldehydes: Application to Synthesis of (Z)-Allylic Alcohols via Cross-Coupling Reaction and [1,2-Wittig Rearrangement		J. Org. Chem.	91	Ukaji, Y	FALSE	FALSE	FALSE	FALSE
1845	10.1515/pac-2014-1108	doi.org/10.1515/pac-2014-1108	Gas-phase studies of metal catalyzed decarboxylative cross-coupling reactions of esters		Pure Appl. Chem.	91	O'Hair, RAJ	FALSE	FALSE	FALSE	FALSE
1846	10.1039/c5ob00958h	doi.org/10.1039/c5ob00958h	Benzyllithiums bearing aldehyde carbonyl groups. A flash chemistry approach		Org. Biomol. Chem.	91	Yoshida, J	FALSE	FALSE	FALSE	FALSE
1847	10.1080/00397911.2014.880789	doi.org/10.1080/00397911.2014.880789	PALLADIUM-CATALYZED SELECTIVE alpha-ARYLATION OF ORTHO-BROMOACETOPHENONES		Synth. Commun.	91	Satyanarayana, G	FALSE	FALSE	FALSE	FALSE
1848	10.1021/jo400803s	doi.org/10.1021/jo400803s	Mild Negishi Cross-Coupling Reactions Catalyzed by Acenaphthoimidazolylidene Palladium Complexes at Low Catalyst Loadings		J. Org. Chem.	91	Tu, T	FALSE	FALSE	FALSE	FALSE
1849	10.1021/ja4034999	doi.org/10.1021/ja4034999	Functional-Group-Tolerant, Nickel-Catalyzed Cross-Coupling Reaction for Enantioselective Construction of Tertiary Methyl-Bearing Stereocenters		J. Am. Chem. Soc.	91	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
1850	10.1021/jo3018878	doi.org/10.1021/jo3018878	Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation		J. Org. Chem.	91	Mo, FY	FALSE	FALSE	FALSE	FALSE
1851	10.1021/om300205c	doi.org/10.1021/om300205c	[Pd(IPr*(acac)Cl]: An Easily Synthesized, Bulky Precatalyst for C-N Bond Formation		Organometallics	91	Nolan, SP	FALSE	FALSE	FALSE	FALSE
1852	10.1002/ejoc.201101527	doi.org/10.1002/ejoc.201101527	Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids		Eur. J. Org. Chem.	91	Scrivanti, A	FALSE	FALSE	FALSE	FALSE
1853	10.1248/cpb.59.714	doi.org/10.1248/cpb.59.714	Regio- and Enantioselective Allylic Substitution with Less Active N- or O-Nucleophiles Catalyzed by Iridium-Complex of Bis(oxazolinyl)pyridine		Chem. Pharm. Bull.	91	Miyabe, H	FALSE	FALSE	FALSE	FALSE
1854	10.1021/om9006399	doi.org/10.1021/om9006399	N-Heterocyclic Carbene-Based Nickel Complexes: Synthesis and Catalysis in Cross-Couplings of Aryl Chlorides with ArMX (M = Mg or Zn)		Organometallics	91	Wang, ZX	FALSE	FALSE	FALSE	FALSE
1855	10.1021/jo9714674	doi.org/10.1021/jo9714674	Synthesis of alpha- and beta-C-aryl Delta(2)-glycopyranosides from p-tert-butylphenyl Delta(2)-glycopyranosides via Grignard reagents		J. Org. Chem.	91	Sinou, D	FALSE	FALSE	FALSE	FALSE
1856	10.1039/d1ra08961g	doi.org/10.1039/d1ra08961g	Four- and five-coordinate nickel(II) complexes bearing new diphosphine-phosphonite and triphosphine-phosphite ligands: catalysts for N-alkylation of amines		RSC Adv.	91	Mani, G	FALSE	FALSE	FALSE	FALSE
1857	10.1021/acsanm.1c03169	doi.org/10.1021/acsanm.1c03169	Proline-Cu Complex Based 1,3,5-Triazine Coated on Fe3O4 Magnetic Nanoparticles: A Nanocatalyst for the Knoevenagel Condensation of Aldehyde with Malononitrile		ACS Appl. Nano Mater.	91	Ramazani, A	FALSE	FALSE	FALSE	FALSE
1858	10.1021/acscatal.1c04533	doi.org/10.1021/acscatal.1c04533	Nickel- and Palladium-Catalyzed Cross-Coupling of Stibines with Organic Halides: Site-Selective Sequential Reactions with Polyhalogenated Arenes		ACS Catal.	91	Yin, SF; Qiu, RH	FALSE	FALSE	FALSE	FALSE
1859	10.1039/d1qo01269j	doi.org/10.1039/d1qo01269j	Ruthenium-catalysed chemoselective alkytation of nitroarenes with alkanols		Org. Chem. Front.	91	Xu, BH	FALSE	FALSE	FALSE	FALSE
1860	10.1002/adsc.202100594	doi.org/10.1002/adsc.202100594	Copper-Catalysed Electrophilic Amination of Aryl(alkenyl) Boronic Acids with Nitrogen-Containing Hypervalent Iodine (III) Reagent		Adv. Synth. Catal.	91	Yuan, WM	FALSE	TRUE	FALSE	FALSE
1861	10.1039/d1ob00955a	doi.org/10.1039/d1ob00955a	Recent developments in catalytic cross-couplings with unsaturated carboxylates		Org. Biomol. Chem.	91	Li, J	FALSE	FALSE	FALSE	FALSE
1862	10.1002/anie.202104430	doi.org/10.1002/anie.202104430	Stereoselective Synthesis of C-Vinyl Glycosides via Palladium-Catalyzed C-H Glycosylation of Alkenes		Angew. Chem.-Int. Edit.	91	He, G; Chen, G	FALSE	FALSE	FALSE	FALSE
1863	10.1021/acs.joc.1c01057	doi.org/10.1021/acs.joc.1c01057	(DiMeIHept(Cl))Pd: A Low-Load Catalyst for Solvent-Free (Melt) Amination		J. Org. Chem.	91	Organ, MG	FALSE	FALSE	FALSE	FALSE
1864	10.1039/d1nj01698a	doi.org/10.1039/d1nj01698a	Achiral and chiral NNN-pincer nickel complexes with oxazolinyl backbones: application in transfer hydrogenation of ketones		New J. Chem.	91	Punji, B	FALSE	FALSE	FALSE	FALSE
1865	10.1002/anie.202100949	doi.org/10.1002/anie.202100949	Bimetallic Cooperative Catalysis for Decarbonylative Heteroarylation of Carboxylic Acids via C-O/C-H Coupling		Angew. Chem.-Int. Edit.	91	Szostak, M	FALSE	FALSE	FALSE	FALSE
1866	10.1039/c7dt01805c	doi.org/10.1039/c7dt01805c	Phosphine-functionalized NHC Ni(II) and Ni(0) complexes: synthesis, characterization and catalytic properties		Dalton Trans.	91	Fructos, MR; Belderrain, TR	FALSE	FALSE	FALSE	FALSE
1867	10.1039/c7cc00255f	doi.org/10.1039/c7cc00255f	Quantifying and understanding the steric properties of N-heterocyclic carbenes		Chem. Commun.	91	Nolan, SP	FALSE	FALSE	FALSE	FALSE
1868	10.1002/hc.21360	doi.org/10.1002/hc.21360	One-pot green synthesis of benzoxazole derivatives through molecular sieve-catalyzed oxidative cyclization reaction		Heteroatom Chem.	91	Huang, YZ	FALSE	FALSE	FALSE	FALSE
1869	10.1002/jhet.2652	doi.org/10.1002/jhet.2652	Selective and Efficient Formylation of Indoles (C3) and Pyrroles (C2) Using 2,4,6-Trichloro-1,3,5-Triazine/Dimethylformamide (TCT/DMF) Mixed Reagent		J. Heterocycl. Chem.	91	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
1870	10.1002/tcr.201600078	doi.org/10.1002/tcr.201600078	Renovation of Optically Active Phenanthrolines as Powerful Chiral Ligands for Versatile Asymmetric Metal Catalysis		Chem. Rec.	91	Naganawa, Y; Nishiyama, H	FALSE	FALSE	FALSE	FALSE
1871	10.1016/j.mcat.2020.111344	doi.org/10.1016/j.mcat.2020.111344	DFT study on the mechanism of palladium(0)-catalyzed reaction of o-iodoanilines, CO2, and CO	A formal synthesis of fumagillol, a congener of fumagillin that possesses varied biological activity, is disclosed. Initial attempts at preparing an allylic sulfide via an a-chloro sulfide met with failure. The successful route involves a carbonyl-ene reaction, one-pot stannyl cupration, methylation of resulting alkenyl copper and further Stille-coupling of the alkenyl stannane as the key steps. (C) 2017 Elsevier Ltd. All rights reserved.	Mol. Catal.	90	Wang, MY; Liu, JY	FALSE	FALSE	FALSE	FALSE
1872	10.1002/anie.202010386	doi.org/10.1002/anie.202010386	Enantio- and Regioselective NiH-Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl Iodides	Efficient Bronsted acid-catalyzed allylation of benzhydryl alcohols has been developed. The reaction occurs within 5 min in the presence of sub-stoichiometric amounts of HBF4 center dot OEt2 to afford the desired products in good to excellent yields. A variety of functional groups were tolerated under the developed conditions including amides, aldehydes, hydroxyl and carboxylic acid. (C) 2016 Elsevier Ltd. All rights reserved.	Angew. Chem.-Int. Edit.	90	Zhu, SL	FALSE	FALSE	FALSE	FALSE
1873	10.1021/jacs.0c07126	doi.org/10.1021/jacs.0c07126	Quinim: A New Ligand Scaffold Enables Nickel-Catalyzed Enantioselective Synthesis of alpha-Alkylated gamma-Lactam	The transmetal-catalyzed enantioselective cross-coupling reaction of secondary benzylic electrophiles with organoaluminum reagents has been developed. The reaction of secondary benzylic electrophiles with alkynylaluminum reagents provides a mild way for the chiral propargyl compounds bearing aromatic group in high yields with good enantioselectivities using NiBr2 diglyrne and (R)-iPr-Pybox as the catalytic system. The reaction of secondary benzylic electrophiles with alkenylaluminum reagents affords the corresponding chiral aryl alkenes in moderate yields with excellent stereoselectivities using commercially available PdCl2 and (R)-BINAP as the catalytic system.	J. Am. Chem. Soc.	90	Qu, JP; Chen, YF	FALSE	FALSE	FALSE	FALSE
1874	10.1021/acs.joc.0c01274	doi.org/10.1021/acs.joc.0c01274	Ni-Catalyzed Iterative Alkyl Transfer from Nitrogen Enabled by the In Situ Methylation of Tertiary Amines	The synthesis and structure of the first 1,2-bis(NHSi)-substituted ortho-carborane [(LSi:)C](2)B10H10 (termed SiCCSi) is reported (NHSi=N-heterocyclic silylene; L=PhC(NtBu)(2)). Its suitability to serve as a reliable bis(silylene) chelating ligand for transition metals is demonstrated by the formation of [SiCCSi]NiBr2 and [SiCCSi]Ni(CO)(2) complexes. The CO stretching vibration modes of the latter indicate that the Si-II atoms in the SiCCSi ligand are even stronger sigma donors than the P-III atoms in phosphines and C-II atoms in N-heterocyclic carbene (NHC) ligands. Moreover, the strong donor character of the [SiCCSi] ligand enables [SiCCSi]NiBr2 to act as an outstanding precatalyst (0.5mol% loading) in the catalytic aminations of arenes, surpassing the activity of previously known molecular Ni-based precatalysts (1-10mol%).	J. Org. Chem.	90	Roberts, AG	FALSE	FALSE	FALSE	FALSE
1875	10.1021/acs.joc.0c00561	doi.org/10.1021/acs.joc.0c00561	Manganese(I)-Catalyzed Sustainable Synthesis of Quinoxaline and Quinazoline Derivatives with the Liberation of Dihydrogen	An efficient Suzuki-Miyaura cross-coupling reaction of perfluorinated arenes with aryl boronate esters using NHC nickel complexes as catalysts is described. The efficiencies of different boronate esters (p-tolyl-Beg, p-tolyl-Bneop, p-tolyl-Bpin, p-tolyl-Bcat) and the corresponding boronic acid (p-tolyl-B(OH)(2)) in this type of cross-coupling reaction were evaluated (eg, ethyleneglycolato; neop, neopentylglycolato; pin, pinacolato; cat, catecholato). Aryl-Beg was shown to be the most reactive boronate ester among those studied. The use of CsF as an additive is essential for an efficient reaction of hexafluorobenzene with aryl neopentylglycolboronates.	J. Org. Chem.	90	Balaraman, E	FALSE	FALSE	FALSE	FALSE
1876	10.1055/s-0039-1691590	doi.org/10.1055/s-0039-1691590	Difluorocarbene-Based Cyanation of Aryl Iodides	Instead of using aryl halides, aryl sulfides, typically poisonous to transition-metal catalysts, were found to serve as aryl electrophiles in the catalytic -arylation of ketimines, a class of carbonyl derivatives. Low catalyst loadings (down to 0.5mol%) of a palladium-NHC complex are sufficient for efficient arylation. -Arylated ketimine products are useful for the synthesis of various azaarenes, including 2,3-diarylpyrroles, an indole, and pyrrolediones.	Synlett	90	Guo, Y; Yao, X; Zheng, X	FALSE	FALSE	FALSE	FALSE
1877	10.1021/acs.orglett.0c00554	doi.org/10.1021/acs.orglett.0c00554	Nickel-Catalyzed Cross-Coupling of Alkyl Carboxylic Acid Derivatives with Pyridinium Salts via C-N Bond Cleavage	An economical, and practical copper(II) triflate-catalyzed aerobic oxidative C-H functionalization of glycine derivatives with olefins and organoboranes has been established. The mild reaction has an excellent functional group tolerance, and exhibits a broad scope with respect to both glycine derivatives and the two types of nucleophilic components, allowing for the facile synthesis of diverse substituted quinolines and glycine derivatives bearing various patterns of functionalities in the alpha-position.	Org. Lett.	90	Rasappan, R	FALSE	FALSE	FALSE	FALSE
1878	10.1039/c9qi00975b	doi.org/10.1039/c9qi00975b	In situ transformation of a tridentate to a tetradentate unsymmetric Schiff base ligand via deaminative coupling in Ni(ii) complexes: crystal structures, magnetic properties and catecholase activity study		Inorg. Chem. Front.	90	Ghosh, A	FALSE	FALSE	FALSE	FALSE
1879	10.1002/adsc.201901136	doi.org/10.1002/adsc.201901136	Ligand-Controlled C-O Bond Coupling of Carboxylic Acids and Aryl Iodides: Experimental and Computational Insights		Adv. Synth. Catal.	90	Zhang, XH; Chen, J; Huang, Y	FALSE	FALSE	FALSE	FALSE
1880	10.1021/acs.joc.9b01957	doi.org/10.1021/acs.joc.9b01957	Palladium-Catalyzed syn-Stereocontrolled Ring Opening of Oxabicyclic Alkenes with Arylsulfonyl Hydrazides		J. Org. Chem.	90	Yang, DQ	FALSE	FALSE	FALSE	FALSE
1881	10.1248/cpb.c19-00215	doi.org/10.1248/cpb.c19-00215	Chemical Studies on Bioactive Natural Products Directed toward Development of Novel Antiinfective and Anticancer Medicines		Chem. Pharm. Bull.	90	Watanabe, T	FALSE	FALSE	FALSE	FALSE
1882	10.1002/ejoc.201800849	doi.org/10.1002/ejoc.201800849	Iron-Catalyzed Coupling of Propargyl Bromides and Alkyl Grignard Reagents		Eur. J. Org. Chem.	90	Cardenas, DJ	FALSE	FALSE	FALSE	FALSE
1883	10.1002/cctc.201800609	doi.org/10.1002/cctc.201800609	Copper-(II) Catalyzed N-Formylation and N-Acylation of Aromatic, Aliphatic, and Heterocyclic Amines and a Preventive Study in the C-N Cross Coupling of Amines with Aryl Halides		ChemCatChem	90	Jagtap, SV	FALSE	FALSE	FALSE	FALSE
1884	10.1002/anie.201704513	doi.org/10.1002/anie.201704513	Visible-Light-Driven Palladium-Catalyzed Radical Alkylation of C-H Bonds with Unactivated Alkyl Bromides		Angew. Chem.-Int. Edit.	90	Yu, DG	FALSE	FALSE	FALSE	FALSE
1885	10.1021/jacs.7b09482	doi.org/10.1021/jacs.7b09482	Factors Controlling the Reactivity and Chemoselectivity of Resonance Destabilized Amides in Ni-Catalyzed Decarbonylative and Nondecarbonylative Suzuki-Miyaura Coupling		J. Am. Chem. Soc.	90	Hong, X	FALSE	FALSE	FALSE	FALSE
1886	10.1021/acs.biomac.7b01049	doi.org/10.1021/acs.biomac.7b01049	Glycosidase Inhibition by Multivalent Presentation of Heparan Sulfate Saccharides on Bottlebrush Polymers		Biomacromolecules	90	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
1887	10.1039/c6ra19069c	doi.org/10.1039/c6ra19069c	B(C6F5)(3) catalysed 1,6-conjugate allylation of para-quinone methides: expedient access to allyl diarylmethanes		RSC Adv.	90	Anand, RV	FALSE	FALSE	FALSE	FALSE
1888	10.1002/cctc.201500724	doi.org/10.1002/cctc.201500724	Palladium-Catalyzed Carboxylation of Benzyl Chlorides with Atmospheric Carbon Dioxide in Combination with Manganese/Magnesium Chloride		ChemCatChem	90	Yu, A	FALSE	FALSE	FALSE	FALSE
1889	10.1002/ejoc.201500734	doi.org/10.1002/ejoc.201500734	An Air-Stable Nickel(0) Phosphite Precatalyst for Primary Alkylamine C-N Cross-Coupling Reactions		Eur. J. Org. Chem.	90	Stewart, SG	FALSE	FALSE	FALSE	FALSE
1890	10.1021/acs.accounts.5b00223	doi.org/10.1021/acs.accounts.5b00223	Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers and Esters		Accounts Chem. Res.	90	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
1891	10.1055/s-0034-1379206	doi.org/10.1055/s-0034-1379206	Microwave-Assisted Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides in Water		Synthesis	90	Chen, YA	FALSE	FALSE	FALSE	FALSE
1892	10.1002/chem.201402433	doi.org/10.1002/chem.201402433	Investigations of Scope and Mechanism of Nickel-Catalyzed Transformations of Glycosyl Trichloroacetimidates to Glycosyl Trichloroacetamides and Subsequent, Atom-Economical, One-Step Conversion to alpha-Urea-Glycosides		Chem.-Eur. J.	90	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
1893	10.3987/COM-14-12996	doi.org/10.3987/COM-14-12996	NICKEL-CATALYZED LIGAND-FREE SYNTHESIS OF BENZOXAZOLES AND OXAZOLINES VIA ISOCYANIDE INSERTION		Heterocycles	90	Wang, JM	FALSE	FALSE	FALSE	FALSE
1894	10.1016/j.tet.2014.01.035	doi.org/10.1016/j.tet.2014.01.035	Construction of polyaromatics via photocyclization of 2-(fur-3-yl) ethenylarenes, using a 3-furyl group as an isopropenyl equivalent synthon		Tetrahedron	90	Ho, JH	FALSE	FALSE	FALSE	FALSE
1895	10.1016/j.tet.2013.09.060	doi.org/10.1016/j.tet.2013.09.060	One-pot synthesis of multisubstituted quaterphenyls and cyclopropanes		Tetrahedron	90	Chang, MY	FALSE	FALSE	FALSE	FALSE
1896	10.1002/adsc.201200929	doi.org/10.1002/adsc.201200929	A DeacetylationDiazotationCoupling Sequence: Palladium- Catalyzed CC Bond Formation with Acetanilides as Formal Leaving Groups		Adv. Synth. Catal.	90	Schmidt, B	FALSE	FALSE	FALSE	FALSE
1897	10.1016/j.tet.2012.06.037	doi.org/10.1016/j.tet.2012.06.037	Stereoselective photoinduced electrocyclic ring closure of aromatic enehydrazides. Asymmetric synthesis of 3-aryl dihydroisoquinolones and tetrahydroisoquinolines		Tetrahedron	90	Couture, A	FALSE	FALSE	FALSE	FALSE
1898	10.1021/ol203043h	doi.org/10.1021/ol203043h	Regioselective Pd-Catalyzed Aerobic Aza-Wacker Cyclization for Preparation of Isoindolinones and Isoquinolin-1(2H)-ones		Org. Lett.	90	Zhang, WB	FALSE	FALSE	FALSE	FALSE
1899	10.1021/jo101917x	doi.org/10.1021/jo101917x	Cu-Catalyzed Carbon-Heteroatom Coupling Reactions under Mild Conditions Promoted by Resin-Bound Organic Ionic Bases		J. Org. Chem.	90	Fu, Y	FALSE	FALSE	FALSE	FALSE
1900	10.1021/jo100391e	doi.org/10.1021/jo100391e	Ligand-Controlled Selectivity in the Desymmetrization of meso Cyclopenten-1,4-diols via Rhodium(I)-Catalyzed Addition of Arylboronic Acids		J. Org. Chem.	90	Lautens, M	FALSE	FALSE	FALSE	FALSE
1901	10.1039/b809676g	doi.org/10.1039/b809676g	Palladium- (and nickel-) catalyzed vinylation of aryl halides		Chem. Commun.	90	Denmark, SE	FALSE	FALSE	FALSE	FALSE
1902	10.1016/j.tet.2007.10.081	doi.org/10.1016/j.tet.2007.10.081	An inexpensive and highly stable ligand 1,4-bis(2-hydroxy-3,5-di-tert-butylbenzyl)piperazine for Mizoroki-Heck and room temperature Suzuki-Miyaura cross-coupling reactions		Tetrahedron	90	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
1903	10.1021/om070094m	doi.org/10.1021/om070094m	1-indenyldialkylphosphines and cyclopentadienyldialkylphosphines as ligands for high-activity palladium-catalyzed cross-coupling reactions with aryl chlorides		Organometallics	90	Plenio, H	FALSE	FALSE	FALSE	FALSE
1904	10.1021/jo0498866	doi.org/10.1021/jo0498866	Selective iron-catalyzed cross-coupling reactions of Grignard reagents with enol triflates, acid chlorides, and dichloroarenes		J. Org. Chem.	90	Furstner, A	FALSE	FALSE	FALSE	FALSE
1905	10.1021/jo026449n	doi.org/10.1021/jo026449n	Nickel(0)-catalyzed cross-coupling of alkyl arenesulfonates with aryl Grignard reagents		J. Org. Chem.	90	Park, K	FALSE	FALSE	FALSE	FALSE
1906	10.1021/ja00181a043	doi.org/10.1021/ja00181a043	TRANSITION-METAL PROMOTED REACTIONS .34. UNIFIED SYNTHESIS OF VINYLSILANES AND SILYLATED BUTADIENES - NICKEL-CATALYZED OLEFINATION AND SILYLOLEFINATION OF DITHIOACETALS		J. Am. Chem. Soc.	90		FALSE	FALSE	FALSE	FALSE
1907	10.1002/anie.202107127	doi.org/10.1002/anie.202107127	Synergistic Catalysis by Bronsted Acid/Carbodicarbene Mimicking Frustrated Lewis Pair-Like Reactivity		Angew. Chem.-Int. Edit.	90	Ong, TG	FALSE	FALSE	FALSE	FALSE
1908	10.1002/chem.201702867	doi.org/10.1002/chem.201702867	Synthesis of Amidines from Amides Using a Nickel-Catalyzed Decarbonylative Amination through CO Extrusion Intramolecular Recombination Fragment Coupling		Chem.-Eur. J.	90	Rueping, M	FALSE	FALSE	FALSE	FALSE
1909	10.1007/s12039-017-1338-7	doi.org/10.1007/s12039-017-1338-7	Synthesis and characterization of six-membered pincer nickelacycles and application in alkylation of benzothiazole		J. Chem. Sci.	90	Punji, B	FALSE	FALSE	FALSE	FALSE
1910	10.1002/chem.201702200	doi.org/10.1002/chem.201702200	Visible-Light-Mediated Dual Decarboxylative Coupling of Redox-Active Esters with alpha, beta-Unsaturated Carboxylic Acids		Chem.-Eur. J.	90	Duan, XH	FALSE	FALSE	FALSE	FALSE
1911	10.1039/c7cy01040k	doi.org/10.1039/c7cy01040k	A new route to pi-extended polycyclic aromatic hydrocarbons via cross-dehydrogenative coupling		Catal. Sci. Technol.	90	Jafarpour, F	FALSE	FALSE	FALSE	FALSE
1912	10.1002/anie.201611162	doi.org/10.1002/anie.201611162	An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition of C-H, N-H, and O-H Bonds to Cobalt(I) Complexes		Angew. Chem.-Int. Edit.	90	Deng, L	FALSE	FALSE	FALSE	FALSE
1913	10.1021/acscatal.6b00801	doi.org/10.1021/acscatal.6b00801	Nickel-Catalyzed C-sp2-C-sp3 Cross-Coupling via C-O Bond Activation		ACS Catal.	90	Rueping, M	FALSE	FALSE	FALSE	FALSE
1914	10.1002/anie.202010840	doi.org/10.1002/anie.202010840	Ligand-Controlled Regiodivergence in Nickel-Catalyzed Hydroarylation and Hydroalkenylation of Alkenyl Carboxylic Acids	To date, cleavage of the C-N bond in aromatic amides has been achieved in molecules with a distorted constitutional framework around the nitrogen atom. In this report, a nickel-catalyzed reduction of planar amides to the corresponding lower hydrocarbon homologue has been reported. This involves a one-pot reductive cleavage of the C-N bond followed by a tandem C-CO bond break in the presence of a hydride source. Substrate scope circumscribes deamidation examples which proceed via oxidative addition of nickel in the amide bonds of nontwisted amides. Mechanistic studies involving isolation and characterization of involved intermediates via different spectroscopic techniques reveal a deeper introspection into the plausible catalytic cycle for the methodology.	Angew. Chem.-Int. Edit.	89	Engle, KM	FALSE	FALSE	FALSE	FALSE
1915	10.1002/ejoc.202000296	doi.org/10.1002/ejoc.202000296	H-*BEA Zeolite-Catalyzed Nucleophilic Substitution in Allyl Alcohols Using Sulfonamides, Amides, and Anilines	Described herein is the development of Ir(III)-catalyzed direct C-H amidation using azidoformates as a readily deprotectable amino source. Substrates with unactivated methyl C(sp(3))-H and aromatic or olefinic C(sp(2)) -H bonds were smoothly reacted by the iridium-based catalyst system to provide the corresponding primary alkylamines and anilines upon the subsequent removal of N-protecting groups, such as Boc, Fmoc, Cbz, pNZ, or Troc. A brief mechanistic study and synthetic applications are also presented.	Eur. J. Org. Chem.	89	Ohtsuki, A; Okumura, K	FALSE	FALSE	FALSE	FALSE
1916	10.1021/acs.joc.0c00458	doi.org/10.1021/acs.joc.0c00458	Lewis Acid Mediated Electrophilic Cyanation of 2,2 '-Biphenols	Coordination of the reactive phosphinitopyridylphenyl PONCPh ligand L-H to NiBr2 initially yields paramagnetic brown NiBr2(LH) (1), but addition of triethylamine results in fast and facile cyclometalation at Ni-II, giving NiBr(kappa(3)-P,N,C-L) (2) as well-defined species. This is a rare example of direct cydometalation at Ni-II from a C-H bond in a ligand structure other than encumbering ligands (e.g., ECE pincers). Diamagnetic yellow complex 2 reacts instantaneously with HBF4 to give purple [NiBr(kappa(3)-P,N-LH)]BF4 (3). A very unusual (an)agostic Ni(C-Ph-H) interaction in the solid-state structure of 3 was unequivocally demonstrated using single-crystal X-ray crystallography and was interpreted by density functional theory calculations (quantum theory of atoms in molecules and electron localization function analysis). These compounds may be viewed as models for key intermediates in the Ni-catalyzed C-H functionalization of arenes.	J. Org. Chem.	89	Zhao, WX	FALSE	TRUE	FALSE	FALSE
1917	10.1002/ejoc.202000142	doi.org/10.1002/ejoc.202000142	Metal Free, Direct and Selective Deoxygenation of alpha-Hydroxy Carbonyl Compounds: Access to alpha,alpha-Diaryl Carbonyl Compounds	A method for the phosphanylation of 1-tert-butyl-1H-pyrrole was developed which allowed selective preparation of the 3,4-bis(dibromophosphanyl)-1H-pyrrole derivative - the key intermediate in the synthesis of pyrrole-derived diphosphanes which are useful in coordination chemistry and catalysis. These compounds were isolated and characterized, and their structures unambiguously confirmed by single crystal X-ray analysis. (C) 2016 Elsevier Ltd. All rights reserved.	Eur. J. Org. Chem.	89	Kumar, A	FALSE	FALSE	FALSE	FALSE
1918	10.1021/acs.jchemed.9b00753	doi.org/10.1021/acs.jchemed.9b00753	Environmentally Friendly Organic Chemistry Laboratory Experiments for the Undergraduate Curriculum: A Literature Survey and Assessment	A highly enantioselective rhodium(I)-catalyzed dearomative arylation or alkenylation of easily available N-alkylquinolinium salts is reported, thus providing an effective and practical approach to the synthesis of dihydroquinolines in up to 99%ee. This reaction tolerates a wide range of functional groups with respect to both the organic boronic acids and the quinoline starting materials. Moreover, the synthetic utility of this protocol is demonstrated in the formal asymmetric synthesis of bioactive tetrahydroquinoline and the total syntheses of (-)-angustureine and (+)-cuspareine.	J. Chem. Educ.	89	Mohan, RS	FALSE	FALSE	FALSE	FALSE
1919	10.1002/ejoc.201901730	doi.org/10.1002/ejoc.201901730	Water Phase, Room Temperature, Ligand-Free Suzuki-Miyaura Cross-Coupling: A Green Gateway to Aryl Ketones by C-N Bond Cleavage	N,N,O-Tridentate palladium(II) complexes [Pd(OAc){R-C4H8N2(CH2Ar)}] (R = Ph, Ar = 4-tBu-C6H3-OH (4a)) and [2,4-di-tBu-C6H2-OH, R = benzyl (4b)] 4a and 4b have been synthesized from the corresponding 2-((4-arylpiperazin-1-yl) methyl) phenol ligands 3a and 3b in quantitative yields. The synthesized ligands and their palladium(II) complexes were characterized by NMR, IR and HRMS analyses. Complex 4a has been used as an efficient catalyst for the Suzuki cross-coupling reaction of 5-iodovanillin and 5-bromosalicylaldehyde with various arylboronic acids in low catalytic amounts (0.01-0.05 mol% of 4a). Moreover, this catalytic system is even applicable for Suzuki coupling reactions of deactivated aryl bromides and aryl chlorides, affording the cross-coupling products in good to excellent yields with a broad substrate scope.	Eur. J. Org. Chem.	89	Liu, TT; Zhu, YL; Zeng, Z	FALSE	FALSE	FALSE	FALSE
1920	10.1002/ajoc.202000007	doi.org/10.1002/ajoc.202000007	Copper-Catalyzed Cross-Coupling of Benzylic Bromides with Arylboronic Acids: Synthesis of Diarylalkanes and Preliminary Antifungal Evaluation Against Magnaporthe Grisea		Asian J. Org. Chem.	89	Wang, ZH; Tang, RY; Li, ZD	FALSE	FALSE	FALSE	FALSE
1921	10.1002/ejoc.201901471	doi.org/10.1002/ejoc.201901471	Ruthenium(II) Catalysed Highly Regioselective C-3 Alkenylation of Indolizines and Pyrrolo[1,2-a]quinolines		Eur. J. Org. Chem.	89	Dawande, SG	FALSE	FALSE	FALSE	FALSE
1922	10.1021/acscatal.9b03012	doi.org/10.1021/acscatal.9b03012	Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands		ACS Catal.	89	Shekhar, S	FALSE	FALSE	FALSE	FALSE
1923	10.1021/acscatal.9b03352	doi.org/10.1021/acscatal.9b03352	Nickel/Cobalt-Catalyzed C(sp(3))-C(sp(3)) Cross-Coupling of Alkyl Halides with Alkyl Tosylates		ACS Catal.	89	Komeyama, K	FALSE	FALSE	FALSE	FALSE
1924	10.1002/cssc.201900990	doi.org/10.1002/cssc.201900990	alpha-Alkylation of Ketones with Secondary Alcohols Catalyzed by Well-Defined Cp*Co-III-Complexes		ChemSusChem	89	Sundararaju, B	FALSE	FALSE	FALSE	FALSE
1925	10.1021/jacs.9b02220	doi.org/10.1021/jacs.9b02220	Total Synthesis of Caprazamycin A: Practical and Scalable Synthesis of syn-beta-Hydroxyamino Acids and Introduction of a Fatty Acid Side Chain to 1,4-Diazepanone		J. Am. Chem. Soc.	89	Tsukano, C; Takemoto, Y	FALSE	FALSE	FALSE	FALSE
1926	10.1002/adsc.201801085	doi.org/10.1002/adsc.201801085	New Aspects of Recently Developed Rhodium(N-Heterocyclic Carbene)-Catalyzed Organic Transformations		Adv. Synth. Catal.	89	Kim, M	FALSE	FALSE	FALSE	FALSE
1927	10.3390/molecules24071234	doi.org/10.3390/molecules24071234	An Efficient, One-Pot Transamidation of 8-Aminoquinoline Amides Activated by Tertiary-Butyloxycarbonyl		Molecules	89	Yi, J; Yuan, RX	FALSE	FALSE	FALSE	FALSE
1928	10.1021/acs.joc.8b03078	doi.org/10.1021/acs.joc.8b03078	Mechanism of Rhodium(III)-Catalyzed C-H Activation/Annulation of Aromatic Amide with alpha-Allenol: A Computational Study		J. Org. Chem.	89	Li, Y	FALSE	FALSE	FALSE	FALSE
1929	10.1039/c8ob02856g	doi.org/10.1039/c8ob02856g	The roles of Lewis acidic additives in organotransition metal catalysis		Org. Biomol. Chem.	89	Dobereiner, GE	FALSE	FALSE	FALSE	FALSE
1930	10.1055/s-0037-1610379	doi.org/10.1055/s-0037-1610379	Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective		Synthesis	89	Gong, LZ	FALSE	FALSE	FALSE	FALSE
1931	10.1039/c8qo01044g	doi.org/10.1039/c8qo01044g	Ni-Catalyzed 1,2-iminoacylation of alkenes via a reductive strategy		Org. Chem. Front.	89	Wang, C	FALSE	FALSE	FALSE	FALSE
1932	10.1021/acscatal.8b02815	doi.org/10.1021/acscatal.8b02815	Acyl and Decarbonylative Suzuki Coupling of N-Acetyl Amides: Electronic Tuning of Twisted, Acyclic Amides in Catalytic Carbon-Nitrogen Bond Cleavage		ACS Catal.	89	Szostak, M	FALSE	TRUE	FALSE	FALSE
1933	10.1039/c8ob01481g	doi.org/10.1039/c8ob01481g	Nickel-catalyzed direct C-H bond sulfenylation of acylhydrazines		Org. Biomol. Chem.	89	Weng, J; Lu, G	FALSE	FALSE	FALSE	FALSE
1934	10.1002/anie.201806790	doi.org/10.1002/anie.201806790	Nickel-Catalyzed Amination of Silyloxyarenes through C-O Bond Activation		Angew. Chem.-Int. Edit.	89	Montgomery, J	FALSE	FALSE	FALSE	FALSE
1935	10.1039/c8sc00827b	doi.org/10.1039/c8sc00827b	Cu-catalyzed enantioselective synthesis of tertiary benzylic copper complexes and their in situ addition to carbonyl compounds		Chem. Sci.	89	Meng, FK	FALSE	FALSE	FALSE	FALSE
1936	10.1021/acs.joc.8b00228	doi.org/10.1021/acs.joc.8b00228	Cooperative Catalysis-Enabled Asymmetric alpha-Arylation of Aldehydes Using 2-Indolylmethanols as Arylation Reagents		J. Org. Chem.	89	Shi, F	FALSE	FALSE	FALSE	FALSE
1937	10.1021/acs.orglett.8b00583	doi.org/10.1021/acs.orglett.8b00583	Acceptorless Dehydrogenation of Hydrocarbons by Noble-Metal-Free Hybrid Catalyst System		Org. Lett.	89	Kanai, M	FALSE	FALSE	FALSE	FALSE
1938	10.1021/acs.orglett.7b03713	doi.org/10.1021/acs.orglett.7b03713	Nickel-Catalyzed Domino Heck Cyclization/Suzuki Coupling for the Synthesis of 3,3-Disubstituted Oxindoles		Org. Lett.	89	Kong, WQ	FALSE	FALSE	FALSE	FALSE
1939	10.1016/j.tetlet.2017.11.049	doi.org/10.1016/j.tetlet.2017.11.049	A green synthesis of unsymmetrical triarylmethanes via indium (III) triflate catalyzed Friedel Crafts alkylation of o-hydroxy bisbenzylic alcohols under solvent free conditions		Tetrahedron Lett.	89	Panda, G	FALSE	FALSE	FALSE	FALSE
1940	10.1055/s-0036-1589057	doi.org/10.1055/s-0036-1589057	Hydrogen-Bond-Promoted Friedel-Crafts Reaction of Secondary Propargylic Fluorides: Preparation of 1-Alkyl-1-aryl-2-alkynes		Synlett	89	Paquin, JF	FALSE	FALSE	FALSE	FALSE
1941	10.1055/s-0036-1588508	doi.org/10.1055/s-0036-1588508	Copper-Catalyzed C-S Bond Formation via the Cleavage of C-O Bonds in the Presence of S-8 as the Sulfur Source		Synthesis	89	Rostami, A	FALSE	FALSE	FALSE	FALSE
1942	10.1002/tcr.201700017	doi.org/10.1002/tcr.201700017	Cascades of Interrupted Pummerer Reaction-Sigmatropic Rearrangement		Chem. Rec.	89	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
1943	10.1016/j.jcou.2014.11.002	doi.org/10.1016/j.jcou.2014.11.002	An effective Ni/Zn catalyst system for the chemical fixation of carbon dioxide with epoxides		J. CO2 Util.	89	Yang, HJ	FALSE	FALSE	FALSE	FALSE
1944	10.1016/j.tetlet.2014.11.112	doi.org/10.1016/j.tetlet.2014.11.112	Recent advances in copper-catalyzed propargylic substitution		Tetrahedron Lett.	89	Hu, XP	FALSE	FALSE	FALSE	FALSE
1945	10.1039/c4cc08846h	doi.org/10.1039/c4cc08846h	Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes		Chem. Commun.	89	Knochel, P	FALSE	FALSE	FALSE	FALSE
1946	10.1039/c5nj01354b	doi.org/10.1039/c5nj01354b	Theoretical study on homolytic C(sp(2))-O cleavage in ethers and phenols		New J. Chem.	89	Zheng, WR	FALSE	FALSE	FALSE	FALSE
1947	10.1002/chem.201404398	doi.org/10.1002/chem.201404398	Palladium-Catalysed Direct Cross-Coupling of Organolithium Reagents with Aryl and Vinyl Triflates		Chem.-Eur. J.	89	Feringa, BL	FALSE	FALSE	FALSE	FALSE
1948	10.1016/j.jct.2014.01.006	doi.org/10.1016/j.jct.2014.01.006	Thermodynamic properties of 1-phenylnaphthalene and 2-phenylnaphthalene		J. Chem. Thermodyn.	89	Chirico, RD	FALSE	FALSE	FALSE	FALSE
1949	10.1002/chem.201304861	doi.org/10.1002/chem.201304861	Borylation of Unactivated Aryl Chlorides under Mild Conditions by Using Diisopropylaminoborane as a Borylating Reagent		Chem.-Eur. J.	89	Pucheault, M	FALSE	FALSE	FALSE	FALSE
1950	10.1021/ja210249h	doi.org/10.1021/ja210249h	Nickel-Catalyzed C-H/C-O Coupling of Azoles with Phenol Derivatives		J. Am. Chem. Soc.	89	Itami, K	FALSE	FALSE	FALSE	FALSE
1951	10.1021/om201190v	doi.org/10.1021/om201190v	Scope and Mechanistic Study of the Coupling Reaction of alpha,beta-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling Pathways		Organometallics	89	Yi, CS	FALSE	TRUE	FALSE	FALSE
1952	10.1039/c2sc00923d	doi.org/10.1039/c2sc00923d	Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes		Chem. Sci.	89	Lei, ZQ	FALSE	FALSE	FALSE	FALSE
1953	10.1002/anie.201202136	doi.org/10.1002/anie.201202136	Enantioselective Rhodium-Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic Imines		Angew. Chem.-Int. Edit.	89	Lam, HW	FALSE	FALSE	FALSE	FALSE
1954	10.1021/ol200101x	doi.org/10.1021/ol200101x	Pd-Catalyzed Desulfitative Heck Coupline with Dioxygen as the Terminal Oxidant		Org. Lett.	89	Deng, GJ	FALSE	FALSE	FALSE	FALSE
1955	10.1002/pola.24046	doi.org/10.1002/pola.24046	Disassembly via an Environmentally Friendly and Efficient Fluorous Phase Constructed with Dendritic Architectures		J. Polym. Sci. Pol. Chem.	89	Percec, V	FALSE	FALSE	FALSE	FALSE
1956	10.1039/c0dt00021c	doi.org/10.1039/c0dt00021c	Half-sandwich NHC-nickel(II) complexes as pre-catalysts for the fast Suzuki coupling of aryl halides: a comparative study		Dalton Trans.	89	Ritleng, V	FALSE	FALSE	FALSE	FALSE
1957	10.1021/ja907882n	doi.org/10.1021/ja907882n	Predicting the Structure of Supramolecular Dendrimers via the Analysis of Libraries of AB(3) and Constitutional Isomeric AB(2) Biphenylpropyl Ether Self-Assembling Dendrons		J. Am. Chem. Soc.	89	Percec, V	FALSE	FALSE	FALSE	FALSE
1958	10.1002/chem.200801879	doi.org/10.1002/chem.200801879	Enantioselective Iridium-Catalyzed Allylic Arylation		Chem.-Eur. J.	89	Alexakis, A	FALSE	FALSE	FALSE	FALSE
1959	10.1021/jo00126a047	doi.org/10.1021/jo00126a047	ARYL MESYLATES IN METAL-CATALYZED HOMO-COUPLING AND CROSS-COUPLING REACTIONS .4. SCOPE AND LIMITATIONS OF ARYL MESYLATES IN NICKEL-CATALYZED CROSS-COUPLING REACTIONS		J. Org. Chem.	89	PERCEC, V	FALSE	FALSE	FALSE	FALSE
1960	10.1039/d2qo00041e	doi.org/10.1039/d2qo00041e	Amine-directed Mizoroki-Heck arylation of free allylamines		Org. Chem. Front.	89	Landge, VG; Young, MC	FALSE	FALSE	FALSE	FALSE
1961	10.1039/d1cc01132d	doi.org/10.1039/d1cc01132d	Base promoted gem-difluoroolefination of alkyl triflones		Chem. Commun.	89	Xu, B	FALSE	FALSE	FALSE	FALSE
1962	10.1002/slct.201700684	doi.org/10.1002/slct.201700684	Glycerol as a Recyclable Solvent for Copper-Mediated Ligand-Free C-S Cross-Coupling Reaction: Application to Synthesis of Gemmacin Precursor		ChemistrySelect	89	Kumar, AV	FALSE	FALSE	FALSE	FALSE
1963	10.1021/jacs.6b12329	doi.org/10.1021/jacs.6b12329	Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Esters		J. Am. Chem. Soc.	89	Newman, SG	FALSE	FALSE	FALSE	FALSE
1964	10.1002/adsc.201600689	doi.org/10.1002/adsc.201600689	Air Stable Iron(II) PNP Pincer Complexes as Efficient Catalysts for the Selective Alkylation of Amines with Alcohols		Adv. Synth. Catal.	89	Kirchner, K	FALSE	FALSE	FALSE	FALSE
1965	10.1021/acs.joc.6b00667	doi.org/10.1021/acs.joc.6b00667	Palladium-Catalyzed syn-Stereocontrolled Ring-Opening of Oxabicyclic Alkenes with Sodium Arylsulfinates		J. Org. Chem.	89	Yang, DQ	FALSE	FALSE	FALSE	FALSE
1966	10.1002/anie.201600697	doi.org/10.1002/anie.201600697	Nickel-Catalyzed Carboxylation of Benzylic C-N Bonds with CO2		Angew. Chem.-Int. Edit.	89	Martin, R	FALSE	FALSE	FALSE	FALSE
1967	10.1039/c6dt01183g	doi.org/10.1039/c6dt01183g	Coordination reactions of 2-pyridinecarboxaldehyde-phenylhydrazonatolithium with selected transition metal (Zn, Sn, Fe, Co, Ni and Zr) chlorides and its coupling reaction with dichloromethane		Dalton Trans.	89	Liu, DS	FALSE	FALSE	FALSE	FALSE
1968	10.1007/3418_2015_129	doi.org/10.1007/3418_2015_129	Iron-Catalyzed C-H Bond Activation		Top. Organomet. Chem.	89	Ilies, L; Nakamura, E	FALSE	FALSE	FALSE	FALSE
1969	10.1021/acs.joc.0c02441	doi.org/10.1021/acs.joc.0c02441	Synthesis of Polysubstituted Isoindolinones via Radical Cyclization of 1,3-Dicarbonyl Ugi-4CR Adducts Using Tetrabutylammonium Persulfate and TEMPO	An intermolecular, three-component reductive dicarbofunctionalization of alkenes is presented here. The combination of Ni catalysis with TDAE as final reductant enables the direct formation of Csp(3)-Csp(3) and Csp(3)-Csp(2) bonds across a variety of pi-systems using two different electrophiles that are sequentially activated with exquisite selectivity under mild reaction conditions.	J. Org. Chem.	88	Polindara-Garcia, LA	FALSE	FALSE	FALSE	FALSE
1970	10.1021/jacs.0c09545	doi.org/10.1021/jacs.0c09545	Iron-Ceatalyzed Highly para-Selective Difluoromethylation of Arenes	An enantioselective Pd-II/Bronsted acid-catalyzed carbonylative carbocyclization of enallenes ending with a cross-dehydrogenative coupling (CDC) with a terminal alkyne was developed. VAPOL phosphoric acid was found as the best co-catalyst among the examined 28 chiral acids, for inducing the enantioselectivity of alpha-chiral ketones. As a result, a number of chiral cyclopentenones were easily synthesized in good to excellent enantiomeric ratio with good yields.	J. Am. Chem. Soc.	88	Ji, SJ; Zhao, YS	FALSE	FALSE	FALSE	FALSE
1971	10.1039/d0ob01928c	doi.org/10.1039/d0ob01928c	An aerobic and green C-H cyanation of terminal alkynes	A decarboxylative coupling reaction with an alkynyl carboxylic acid and aryl iodides in the presence of a nickel catalyst was developed. When the reaction was conducted with NiCl2 (10 mol%), Xantphos (15 mol Mn (1.0 equiv), and Cs2CO3 (1.5 equiv), the desired diaryl alkynes were formed in moderated to good yields. Furthermore, this method does not produce the diyne, which is formed in the homocoupling of alkynyl carboxylic acids. (C) 2017 Elsevier Ltd. All rights reserved.	Org. Biomol. Chem.	88	Zhang, SL	FALSE	FALSE	FALSE	FALSE
1972	10.1055/s-0040-1705966	doi.org/10.1055/s-0040-1705966	Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles	A novel asymmetric radical trifluoromethylarylation of alkenes has been developed, which provides an efficient approach to access chiral CF3-containing 1,1-diarylmethane derivatives with good to excellent enantio-selectivity. Various vinyl arenes and aryl boronic acids are compatible with these conditions. The utility of the method is demonstrated by accessing modified bioactive molecules.	Synthesis	88	Fu, JK	FALSE	TRUE	FALSE	FALSE
1973	10.1002/adsc.202000370	doi.org/10.1002/adsc.202000370	Recent Progress on Reductive Coupling of Nitroarenes by Using Organosilanes as Convenient Reductants	The direct C-H amination of arenes is an important strategy to streamline the discovery and preparation of functional molecules. Herein, we report an operationally simple arene C-H amination reaction that, in contrast to most literature precedent, affords directly the synthetically versatile primary aniline products without relying on protecting group manipulations. Inexpensive Fe(II)-sulfate serves as a convenient catalyst for the transformation. The reaction tolerates a wide scope of arenes, including structurally complex drugs. Importantly, the arene substrates are used as limiting reagents in the transformation. This operationally simple transformation should considerably accelerate the discovery of medicines and functional molecules.	Adv. Synth. Catal.	88	Gao, Y	FALSE	FALSE	FALSE	FALSE
1974	10.1021/acscatal.0c00618	doi.org/10.1021/acscatal.0c00618	Revealing the Strong Relationships between Ligand Conformers and Activation Barriers: A Case Study of Bisphosphine Reductive Elimination	A method for the arylboration of 1-arylalkenes with bis(pinacolato)diboron and aryl chlorides or tosylates by cooperative Ni/CU catalysis has been developed, which affords 2-bory1-1,1-diarylalkanes in high regio- and stereoselectivity. Under the applied conditions, this method is tolerant toward various functional groups, including silyl ether, alkoxycarbonyl, and aminocarbonyl moieties.	ACS Catal.	88	Jugovic, TME	FALSE	FALSE	FALSE	FALSE
1975	10.1002/anie.201912753	doi.org/10.1002/anie.201912753	Nickel-Catalyzed Electrochemical Reductive Relay Cross-Coupling of Alkyl Halides to Aryl Halides		Angew. Chem.-Int. Edit.	88	Mei, TS	FALSE	TRUE	FALSE	FALSE
1976	10.1039/c9nj04436a	doi.org/10.1039/c9nj04436a	Recyclable bimetallic CuMoO4 nanoparticles for C-N cross-coupling reaction under mild conditions		New J. Chem.	88	Rout, L	FALSE	FALSE	FALSE	FALSE
1977	10.1039/c9ob01244c	doi.org/10.1039/c9ob01244c	Copper-catalysed borylation of aryl chlorides		Org. Biomol. Chem.	88	Radius, U; Marder, TB	FALSE	FALSE	FALSE	FALSE
1978	10.1021/acs.joc.9b00632	doi.org/10.1021/acs.joc.9b00632	Iridium(I)-Catalyzed C-C and C-N Bond Formation Reactions via the Borrowing Hydrogen Strategy		J. Org. Chem.	88	Gulcemal, S; Gulcemal, D	FALSE	FALSE	FALSE	FALSE
1979	10.1021/jacs.9b02312	doi.org/10.1021/jacs.9b02312	Ni-Catalyzed Suzuki-Miyaura Cross-Coupling of alpha-Oxo-vinylsulfones To Prepare C-Aryl Glycals and Acyclic Vinyl Ethers		J. Am. Chem. Soc.	88	Niu, DW	FALSE	FALSE	FALSE	FALSE
1980	10.1080/00397911.2019.1582065	doi.org/10.1080/00397911.2019.1582065	Transition metal- and oxidant-free sulfonylation of 1-sulfonyl-1H-1,2,3-triazoles to enols for the synthesis of sulfonate derivatives		Synth. Commun.	88	He, XW	FALSE	FALSE	FALSE	FALSE
1981	10.1002/cjoc.201800500	doi.org/10.1002/cjoc.201800500	Free Radical Pathway Cleavage of C-O Bonds for the Synthesis of Alkylboron Compounds		Chin. J. Chem.	88	Fu, Y	FALSE	FALSE	FALSE	FALSE
1982	10.1002/cssc.201801443	doi.org/10.1002/cssc.201801443	Ni-Catalyzed alpha-Alkylation of Unactivated Amides and Esters with Alcohols by Hydrogen Auto-Transfer Strategy		ChemSusChem	88	Balaraman, E	FALSE	FALSE	FALSE	FALSE
1983	10.1039/c8qo00799c	doi.org/10.1039/c8qo00799c	DDQ-mediated regioselective C-S bond formation: efficient access to allylic sulfides		Org. Chem. Front.	88	Jiang, HF	FALSE	FALSE	FALSE	FALSE
1984	10.1021/acs.joc.8b00510	doi.org/10.1021/acs.joc.8b00510	Ligand-Free Iron-Catalyzed Carbon(sp(2))-Carbon(sp(2)) Cross-Coupling of Alkenyllithium with Vinyl Halides		J. Org. Chem.	88	Peng, XS; Wong, HNC	FALSE	FALSE	FALSE	FALSE
1985	10.1002/cctc.201701710	doi.org/10.1002/cctc.201701710	Improving the Thermodynamic Profiles of Prospective Suzuki-Miyaura Cross-Coupling Catalysts by Altering the Electrophilic Coupling Component		ChemCatChem	88	Corminboeuf, C	FALSE	TRUE	FALSE	FALSE
1986	10.1002/ajoc.201700464	doi.org/10.1002/ajoc.201700464	Nickel-Catalyzed C-N Cross-Coupling of Primary Imines with Subsequent InSitu [2+2] Cycloaddition or Alkylation		Asian J. Org. Chem.	88	Stewart, SG	FALSE	FALSE	FALSE	FALSE
1987	10.1039/c6ob01638c	doi.org/10.1039/c6ob01638c	Facile synthesis of nonsymmetrical heteroaryl-substituted triarylmethanes via the FeCl3 center dot 6H(2)O-catalyzed two-step Friedel-Crafts-type reaction		Org. Biomol. Chem.	88	Jaratjaroonphong, J	FALSE	FALSE	FALSE	FALSE
1988	10.1021/jacs.5b01913	doi.org/10.1021/jacs.5b01913	Mono-Oxidation of Bidentate Bis-phosphines in Catalyst Activation: Kinetic and Mechanistic Studies of a Pd/Xantphos-Catalyzed C-H Functionalization		J. Am. Chem. Soc.	88	Eastgate, MD	FALSE	FALSE	FALSE	FALSE
1989	10.1021/acs.orglett.5b01030	doi.org/10.1021/acs.orglett.5b01030	Expedient Access to Unsymmetrical Diarylindolylmethanes through Palladium-Catalyzed Domino Electrophilic Cyclization-Extended Conjugate Addition Approach		Org. Lett.	88	Anand, RV	FALSE	TRUE	FALSE	FALSE
1990	10.1002/chem.201500652	doi.org/10.1002/chem.201500652	beta-Hydrogen Elimination Reactions of Nickel and Palladium Methoxides Stabilised by PCP Pincer Ligands		Chem.-Eur. J.	88	Campora, J	FALSE	FALSE	FALSE	FALSE
1991	10.1021/jacs.5b04404	doi.org/10.1021/jacs.5b04404	Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines with Alcohols: Site-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines		J. Am. Chem. Soc.	88	Krische, MJ	FALSE	FALSE	FALSE	FALSE
1992	10.1021/jo502446k	doi.org/10.1021/jo502446k	Copper-Catalyzed C(sp(3))-OH Cleavage with Concomitant C-C Coupling: Synthesis of 3-Substituted Isoindolinones		J. Org. Chem.	88	Rao, HSP	FALSE	FALSE	FALSE	FALSE
1993	10.1039/c5nj00867k	doi.org/10.1039/c5nj00867k	One-pot odorless thia-Michael reaction by copper ferrite nanoparticle-catalyzed reaction of elemental sulfur, aryl halides and electron-deficient alkenes		New J. Chem.	88	Gholinejad, M	FALSE	FALSE	FALSE	FALSE
1994	10.3390/ecsoc-19-a031	doi.org/10.3390/ecsoc-19-a031	Asymmetric photoinduced electrocyclic ring closure of chiral aromatic enehydrazides. Application to the asymmetric synthesis of 3-aryl dihydroisoquinolones and tetrahydroisoquinolines.			88	Deniau, E	FALSE	FALSE	FALSE	FALSE
1995	10.1039/c4cy01736f	doi.org/10.1039/c4cy01736f	Magnetically retrievable silica-based nickel nanocatalyst for Suzuki-Miyaura cross-coupling reaction		Catal. Sci. Technol.	88	Sharma, RK	FALSE	FALSE	FALSE	FALSE
1996	10.1039/c5ra09765g	doi.org/10.1039/c5ra09765g	C-C/C-N cross-coupling reactions of aryl sulfonates catalyzed by an eco-friendly and reusable heterogeneous catalyst: wool-Pd complex		RSC Adv.	88	Wang, XC	FALSE	FALSE	FALSE	FALSE
1997	10.1002/anie.201407083	doi.org/10.1002/anie.201407083	Practical and Highly Selective C-H Functionalization of Structurally Diverse Ethers		Angew. Chem.-Int. Edit.	88	Liu, L	FALSE	FALSE	FALSE	FALSE
1998	10.1016/j.jorganchem.2013.07.068	doi.org/10.1016/j.jorganchem.2013.07.068	Exploring the reactivity of nickel complexes in hydrodecyanation reactions		J. Organomet. Chem.	88	Enthaler, S	FALSE	FALSE	FALSE	FALSE
1999	10.6023/A12110984	doi.org/10.6023/A12110984	Roles of Bases in Transition-Metal Catalyzed Organic Reactions		Acta Chim. Sin.	88	Ouyang, KB	FALSE	FALSE	FALSE	FALSE
2000	10.1016/j.tet.2012.02.054	doi.org/10.1016/j.tet.2012.02.054	Allylic activation across an Ir-Sn heterobimetallic catalyst: nucleophilic substitution and disproportionation of allylic alcohol		Tetrahedron	88	Roy, S	FALSE	FALSE	FALSE	FALSE
2001	10.1055/s-0031-1289687	doi.org/10.1055/s-0031-1289687	Noncryogenic Synthesis of Functionalized 2-Methoxypyridines by Halogen-Magnesium Exchange Using Lithium Dibutyl(isopropyl) magnesate(1-) and Lithium Chloride		Synthesis	88	Sosnicki, JG	FALSE	FALSE	FALSE	FALSE
2002	10.1021/ic201849u	doi.org/10.1021/ic201849u	Electrochemical Illumination of Intramolecular Communication in Ferrocene-Containing tris-beta-Diketonato Aluminum(III) Complexes; Cytotoxicity of Al(FcCOCHCOCF(3))(3)		Inorg. Chem.	88	Swarts, JC	FALSE	TRUE	FALSE	FALSE
2003	10.1021/ol2020847	doi.org/10.1021/ol2020847	Enantioselective Conjugate Addition of Alkenylboronic Acids to Indole-Appended Enones		Org. Lett.	88	May, JA	FALSE	FALSE	FALSE	FALSE
2004	10.1246/cl.2011.894	doi.org/10.1246/cl.2011.894	Cross-coupling Reactions of Organoboranes: An Easy Method for C-C Bonding		Chem. Lett.	88	Suzuki, A	FALSE	FALSE	FALSE	FALSE
2005	10.1016/j.tetlet.2010.08.100	doi.org/10.1016/j.tetlet.2010.08.100	Carbamic acid 2-trimethylsilylethyl ester as a new ammonia equivalent for palladium-catalyzed amination of aryl halides		Tetrahedron Lett.	88	Selvakumar, K	FALSE	FALSE	FALSE	FALSE
2006	10.1016/S1872-2067(09)60089-9	doi.org/10.1016/S1872-2067(09)60089-9	N-Heterocyclic Carbenes: Versatile Reagents for Nickel-Catalyzed Coupling Reactions		Chin. J. Catal.	88	Chen, WZ	FALSE	FALSE	FALSE	FALSE
2007	10.1021/cg9010746	doi.org/10.1021/cg9010746	Structural Features in Crystals of Derivatives of Benzene with Multiple Contiguous Phenyl Substituents		Cryst. Growth Des.	88	Wuest, JD	FALSE	FALSE	FALSE	FALSE
2008	10.1021/jo0625655	doi.org/10.1021/jo0625655	Synthesis of optically active bifunctional building blocks through enantioselective copper-catalyzed allylic alkylation using Grignard reagents		J. Org. Chem.	88	Feringa, BL	FALSE	FALSE	FALSE	FALSE
2009	10.1002/anie.200500099	doi.org/10.1002/anie.200500099	Cobalt(II)-catalyzed cross-coupling of polyfunctional aryl copper reagents with aryl bromides and chlorides		Angew. Chem.-Int. Edit.	88	Knochel, P	FALSE	FALSE	FALSE	FALSE
2010	10.1007/s10904-022-02340-x	doi.org/10.1007/s10904-022-02340-x	Magnetically Recoverable Palladium Nanocatalyst [Pd(II)-Benz-Am-Fe3O4@SiO2] for Ullmann Type Homocoupling of Aryl halides with N2H4 as an Efficient Reductant		J. Inorg. Organomet. Polym. Mater.	88	Pore, DM	FALSE	FALSE	FALSE	FALSE
2011	10.1021/acscatal.1c04479	doi.org/10.1021/acscatal.1c04479	Entering Chemical Space with Theoretical Underpinning of the Mechanistic Pathways in the Chan-Lam Amination		ACS Catal.	88	Koley, D	FALSE	FALSE	FALSE	FALSE
2012	10.6023/cjoc202105016	doi.org/10.6023/cjoc202105016	Progress in the Synthesis of C(sp(2))-C(sp(3)) Bond by Reductive Heck Reactions of Alkenes		Chin. J. Org. Chem.	88	Liu, JC	FALSE	FALSE	FALSE	FALSE
2013	10.1039/d1ra04947j	doi.org/10.1039/d1ra04947j	Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki-Miyaura cross-coupling reactions		RSC Adv.	88	Maumela, MC	FALSE	FALSE	FALSE	FALSE
2014	10.1002/aoc.6364	doi.org/10.1002/aoc.6364	Chitosan nanoparticles functionalized poly-2-hydroxyaniline supported CuO nanoparticles: An efficient heterogeneous and recyclable nanocatalyst for N-arylation of amines with phenylboronic acid at ambient temperature		Appl. Organomet. Chem.	88	Seyedi, N	FALSE	FALSE	FALSE	FALSE
2015	10.1002/hlca.202100056	doi.org/10.1002/hlca.202100056	Fe-Catalyzed Intramolecular Cross-Dehydrogenative Arylation (CDA), Efficient Synthesis of 1-Arylnaphthalenes and 4-Arylcoumarins		Helv. Chim. Acta	88	Liu, F	FALSE	FALSE	FALSE	FALSE
2016	10.1016/j.tetlet.2017.04.001	doi.org/10.1016/j.tetlet.2017.04.001	NADH coenzyme model compound as photocatalyst for the direct arylation of (hetero)arenes		Tetrahedron Lett.	88	Xu, HJ	FALSE	FALSE	FALSE	FALSE
2017	10.1021/acscatal.7b00397	doi.org/10.1021/acscatal.7b00397	Ligand-Promoted Direct C-H Arylation of Simple Arenes: Evidence for a Cooperative Bimetallic Mechanism		ACS Catal.	88	Hong, SH	FALSE	FALSE	FALSE	FALSE
2018	10.1002/chem.201604893	doi.org/10.1002/chem.201604893	Alternative Mechanistic Strategy for Enzyme Catalysis in a Ni-Dependent Lactate Racemase (LarA): Intermediate Destabilization by the Cofactor		Chem.-Eur. J.	88	Chung, LW	FALSE	FALSE	FALSE	FALSE
2019	10.1021/acs.organomet.6b00532	doi.org/10.1021/acs.organomet.6b00532	N-Heterocyclic Carbene Based Nickel and Palladium Complexes: A DFT Comparison of the Mizoroki-Heck Catalytic Cycles		Organometallics	88	Cundari, TR	FALSE	FALSE	FALSE	FALSE
2020	10.1021/acs.organomet.6b00473	doi.org/10.1021/acs.organomet.6b00473	Reaction of Phenyl Iso(thio)cyanate with N-Heterocyclic Carbene-Supported Nickel Complexes: Formation of Nickelacycles		Organometallics	88	Wolf, R	FALSE	FALSE	FALSE	FALSE
2021	10.1021/jacs.6b05788	doi.org/10.1021/jacs.6b05788	Directing Group in Decarboxylative Cross-Coupling: CopperCatalyzed Site-Selective C-N Bond Formation from Nonactivated Aliphatic Carboxylic Acids		J. Am. Chem. Soc.	88	Xiao, B; Fu, Y	FALSE	FALSE	FALSE	FALSE
2022	10.1021/acs.joc.6b00002	doi.org/10.1021/acs.joc.6b00002	Open-Shell Phenalenyl in Transition Metal-Free Catalytic C-H Functionalization		J. Org. Chem.	88	Mandal, SK	FALSE	FALSE	FALSE	FALSE
2023	10.1002/chem.201504844	doi.org/10.1002/chem.201504844	Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents		Chem.-Eur. J.	88	Wirth, T	FALSE	FALSE	FALSE	FALSE
2024	10.1021/jacs.5b11889	doi.org/10.1021/jacs.5b11889	Discovery and Computational Rationalization of Diminishing Alternation in [n]Dendralenes		J. Am. Chem. Soc.	88	Sherburn, MS	FALSE	FALSE	FALSE	FALSE
2025	10.1021/jacs.0c10471	doi.org/10.1021/jacs.0c10471	Direct Enantioselective C(sp(3))-H Acylation for the Synthesis of alpha-Amino Ketones	As we celebrate the 50th birthday of the discovery of poly(2-alkyl/aryl-2-oxazoline)s (PAOx) this year we see a research field that is rapidly expanding after some lesser academic activity in the nineties. This renewed interest in PAOx stems from the fact that this polymer class combines high synthetic versatility with good biocompatibility, opening up the way to highly functional (biocompatible) materials. PAOx are prepared by living cationic ring-opening polymerization (CROP) of 2-oxazolines, which will be the in-depth focus off this review. The variety of 2-oxazoline monomers that are readily available or can easily be synthesized, allows for tuning of polymer properties and introduction of diverse functionalities as well as provides access to different polymer architectures. Moreover, thanks to the living nature of the CROP, well-defined polymers with narrow molar mass distribution and high end-group fidelity can be obtained. (C) 2016 Elsevier Ltd. All rights reserved.	J. Am. Chem. Soc.	87	Huo, HH	FALSE	FALSE	FALSE	FALSE
2026	10.1002/anie.202010244	doi.org/10.1002/anie.202010244	Divergent Coupling of Benzocyclobutenones with Indoles via C-H and C-C Activations	We report the first copper-catalyzed/mediated borylative ring opening reaction of epoxides. This process represents a direct borylative C(sp(3))-O bond cleavage of terminal epoxide substrates with commercially available diboron reagents. A wide range of epoxides with different functional groups are involved, and were subsequently converted to the corresponding beta-hydroxyl boronic esters smoothly. Moreover, the ring opening product beta-pinacol boronate alcohol provided a more beneficial approach for the formation of C-C and C-N bonds.	Angew. Chem.-Int. Edit.	87	Wei, H	FALSE	FALSE	FALSE	FALSE
2027	10.1016/j.jorganchem.2020.121411	doi.org/10.1016/j.jorganchem.2020.121411	Hydrazone complexes of ruthenium(II): Synthesis, crystal structures and catalytic applications in N-alkylation reactions	A set of synthetic approaches was developed and applied to the synthesis of eight frame-shifted isoprenoid diphosphate analogues. These analogues were designed to increase or decrease the methylene units between the double bonds and/or the pyrophosphate moieties of the isoprenoid structure. Evaluation of mammalian GGTase-I and FTase revealed that small structural changes can result in substantial changes in substrate activity.	J. Organomet. Chem.	87	Viswanathamurthi, P	FALSE	FALSE	FALSE	FALSE
2028	10.1002/anie.202007668	doi.org/10.1002/anie.202007668	Stereoinduction in Metallaphotoredox Catalysis	The first example of site-selective silylation of C(sp(3))-H bonds mediated by a [1,5]-hydrogen transfer is reported. This reaction occurs selectively at the alpha-position of benzamides with a combination of tert-butylmagnesium chloride and a catalytic amount of 4,4'-di-tert-butylbipyridine (dtbpy) ligand and provides a facile route for the creation of biologically interesting alpha-sila benzamides. Late-stage functionalization of the incorporated silyl moieties facilitates the synthesis of N-formyl, cis-enamine, beta-hydroxyl, amino, and pyrrole-containing derivatives.	Angew. Chem.-Int. Edit.	87	Molander, GA	FALSE	FALSE	FALSE	FALSE
2029	10.1021/acs.joc.0c00530	doi.org/10.1021/acs.joc.0c00530	Nickel(II)-(NNO)-N-Lambda-O-Lambda Pincer Type Complex-Catalyzed N-alkylation of Amines with Alcohols via the Hydrogen Autotransfer Reaction	A novel methodology for the efficient synthesis of 3-aryloxindoles from isatin derivatives was developed. The methodology involves the formation of an oxindole having a phosphate moiety at the C-3 position via the [1,2]-phospha-Brook rearrangement under BrOnsted base catalysis followed by palladium-catalyzed cross-coupling with aryl boron reagents. The one-pot synthesis of 3-aryloxindoles from isatin derivatives is also described.	J. Org. Chem.	87	Ramesh, R	FALSE	FALSE	FALSE	FALSE
2030	10.1021/jacs.9b13117	doi.org/10.1021/jacs.9b13117	Enantioselective Ni-Catalyzed Electrochemical Synthesis of Biaryl Atropisomers	Unsymmetrical biaryls were synthesized by oxidative coupling reactions, between aromatic primary alcohols and arylboronic acids through the C-C bond cleavage of the primary alcohols chelated With a rhodium catalyst. The desired unsymmetrical biaryl products were obtained in good to excellent yields under the optimized reaction conditions. A wide variety of functionalities are compatible with the reaction under the optimized conditions. This new coupling strategy provides a favorable method to construct valuable biaryl compounds from aromatic primary alcohols which are cheap; environmentally friendly, and easily accessible substrates.	J. Am. Chem. Soc.	87	Mei, TS	FALSE	TRUE	FALSE	FALSE
2031	10.1016/j.mcat.2020.110841	doi.org/10.1016/j.mcat.2020.110841	Novel iota carrageenan-based RhCl3 as an efficient and recyclable catalyst in Suzuki cross coupling	Phosphonium salt-activated, Pd-catalyzed Suzuki-Miyaura and Sonogashira cross-coupling reactions of cyclic 1,3-diones in the synthesis of beta-substituted cyclic enones are described. These transformations exhibit good isolated yield and high generality with respect to both substrates and coupling partners. Extension of the substrate scope to cyclic 1,3-dione equivalents, such as 2-cyanocyclohexanone (4), is also briefly examined.	Mol. Catal.	87	Wolfson, A; Levy-Ontman, O	FALSE	FALSE	FALSE	FALSE
2032	10.1016/j.cclet.2019.08.049	doi.org/10.1016/j.cclet.2019.08.049	The synthesis and structure of pyridine-oxadiazole iridium complexes and catalytic applications: Non-coordinating-anion-tuned selective C-N bond formation	Deuterium labeled aromatic and heteroaromatic compounds are synthesized in good to excellent yields with >98% deuterium purity via palladium catalyzed deuterodehalogenation reaction using commercially available and inexpensive reagents. Selective deuteration of bromoaniline is also demonstrated without H/D exchange in an amino N-H group.	Chin. Chem. Lett.	87	Wang, DW	FALSE	FALSE	FALSE	FALSE
2033	10.1002/anie.201915840	doi.org/10.1002/anie.201915840	NiH-Catalyzed Migratory Defluorinative Olefin Cross-Coupling: Trifluoromethyl-Substituted Alkenes as Acceptor Olefins to Form gem-Difluoroalkenes		Angew. Chem.-Int. Edit.	87	Zhu, SL	FALSE	FALSE	FALSE	FALSE
2034	10.1039/c9qo01402k	doi.org/10.1039/c9qo01402k	A combined experimental and computational study of NHC-promoted desulfonylation of tosylated aldimines		Org. Chem. Front.	87	Li, TJ; Yao, CS	FALSE	FALSE	FALSE	FALSE
2035	10.1021/acs.biomac.9b01282	doi.org/10.1021/acs.biomac.9b01282	Replacing Cu(II)Br-2 with Me-6-TREN in Biphasic Cu(0)/TREN Catalyzed SET-LRP Reveals the Mixed-Ligand Effect		Biomacromolecules	87	Percec, V	FALSE	FALSE	FALSE	FALSE
2036	10.1021/jacs.9b10026	doi.org/10.1021/jacs.9b10026	Mechanism of Ni-Catalyzed. Reductive 1,2-Dicarbofunctionalization of Alkenes		J. Am. Chem. Soc.	87	Diao, TN	FALSE	FALSE	FALSE	FALSE
2037	10.1021/acs.joc.9b02068	doi.org/10.1021/acs.joc.9b02068	Direct Amidation of Carboxylic Acids with Nitroarenes		J. Org. Chem.	87	Cheung, CW; Ma, JA	FALSE	FALSE	FALSE	FALSE
2038	10.1002/anie.201910168	doi.org/10.1002/anie.201910168	Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling		Angew. Chem.-Int. Edit.	87	Melchiorre, P	TRUE	FALSE	FALSE	FALSE
2039	10.7536/PC181037	doi.org/10.7536/PC181037	Acylation Using Carboxylic Acids as Acylating Agents: Applications in Organic Synthesis		Prog. Chem.	87	Chang, JB	FALSE	FALSE	FALSE	FALSE
2040	10.1021/acs.inorgchem.8b02960	doi.org/10.1021/acs.inorgchem.8b02960	Assessing the Metal-Metal Interactions in a Series of Heterobimetallic Nb/M Complexes (M = Fe, Co, Ni, Cu) and Their Effect on Multielectron Redox Properties		Inorg. Chem.	87	Thomas, CM	FALSE	FALSE	FALSE	FALSE
2041	10.1021/acs.joc.8b02588	doi.org/10.1021/acs.joc.8b02588	Amination of Aromatic Halides and Exploration of the Reactivity Sequence of Aromatic Halides		J. Org. Chem.	87	Gong, H	FALSE	FALSE	FALSE	FALSE
2042	10.1021/acs.orglett.8b03627	doi.org/10.1021/acs.orglett.8b03627	Iridium-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates		Org. Lett.	87	Yang, YR	FALSE	FALSE	FALSE	FALSE
2043	10.1021/acscatal.8b03930	doi.org/10.1021/acscatal.8b03930	Nickel-Catalyzed Reductive Electrophilic Ring Opening of Cycloketone Oxime Esters with Aroyl Chlorides		ACS Catal.	87	Wang, C	FALSE	TRUE	FALSE	FALSE
2044	10.1039/c8sc01741g	doi.org/10.1039/c8sc01741g	Carboxylate-directed C-H allylation with allyl alcohols or ethers		Chem. Sci.	87	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
2045	10.1039/c8ob00687c	doi.org/10.1039/c8ob00687c	Promoter free allylation of trichloroacetimidates with allyltributylstannanes under thermal conditions to access the common 1,1-diarylbutyl pharmacophore		Org. Biomol. Chem.	87	Chisholm, JD	FALSE	FALSE	FALSE	FALSE
2046	10.1021/acs.orglett.7b03440	doi.org/10.1021/acs.orglett.7b03440	Weakly Coordinating, Ketone-Directed Cp*Co(III)-Catalyzed C-H Allylation on Arenes and Indoles		Org. Lett.	87	Maji, MS	FALSE	FALSE	FALSE	FALSE
2047	10.1021/acscatal.7b02817	doi.org/10.1021/acscatal.7b02817	An Efficient and Selective Nickel-Catalyzed Direct N-Alkylation of Anilines with Alcohols		ACS Catal.	87	Banerjee, D	FALSE	FALSE	FALSE	FALSE
2048	10.1002/anie.201707906	doi.org/10.1002/anie.201707906	Electrochemically Enabled, Nickel-Catalyzed Amination		Angew. Chem.-Int. Edit.	87	Baran, PS	FALSE	TRUE	FALSE	FALSE
2049	10.1002/anie.201706581	doi.org/10.1002/anie.201706581	Tritopic NHC Precursors: Unusual Nickel Reactivity and Ethylene Insertion into a C(sp(3))-H Bond		Angew. Chem.-Int. Edit.	87	Wesolek, M; Braunstein, P	FALSE	FALSE	FALSE	FALSE
2050	10.1021/acs.organomet.5b00874	doi.org/10.1021/acs.organomet.5b00874	Mixed NHC/Phosphine Ni(II) Complexes: Synthesis and Their Applications as Versatile Catalysts for Selective Cross-Couplings of ArMgX with Aryl Chlorides, Fluorides, and Methyl Ethers		Organometallics	87	Sun, HM	FALSE	FALSE	FALSE	FALSE
2051	10.1021/acs.joc.5b01787	doi.org/10.1021/acs.joc.5b01787	Unified Protocol for Cobalt-Catalyzed Oxidative Assembly of Two Aryl Metal Reagents Using Oxygen as an Oxidant		J. Org. Chem.	87	Duan, XF	FALSE	FALSE	FALSE	FALSE
2052	10.1021/acs.joc.5b01248	doi.org/10.1021/acs.joc.5b01248	Copper-Catalyzed Thioetherification Reactions of Alkyl Halides, Triphenyltin Chloride, and Arylboronic Acids with Nitroarenes in the Presence of Sulfur Sources		J. Org. Chem.	87	Rostami, A	FALSE	FALSE	FALSE	FALSE
2053	10.1021/jacs.5b05076	doi.org/10.1021/jacs.5b05076	Unsymmetrical Diarylmethanes by Ferroceniumboronic Acid Catalyzed Direct Friedel-Crafts Reactions with Deactivated Benzylic Alcohols: Enhanced Reactivity due to Ion-Pairing Effects		J. Am. Chem. Soc.	87	McCubbin, JA	FALSE	FALSE	FALSE	FALSE
2054	10.1002/ejoc.201500156	doi.org/10.1002/ejoc.201500156	Dithiooxamide as an Effective Sulfur Surrogate for Odorless High-Yielding Carbon-Sulfur Bond Formation in Wet PEG200 as an Eco-Friendly, Safe, and Recoverable Solvent		Eur. J. Org. Chem.	87	Firouzabadi, H	FALSE	FALSE	FALSE	FALSE
2055	10.1002/ajoc.201402275	doi.org/10.1002/ajoc.201402275	Organocatalyzed Asymmetric Alkylation of Stable Aryl or Heteroaryl(3-indolyl)methylium o-Benzenedisulfonimides		Asian J. Org. Chem.	87	Barbero, M	FALSE	FALSE	FALSE	FALSE
2056	10.1039/C5QO00243E	doi.org/10.1039/C5QO00243E	Direct borylation of benzyl alcohol and its analogues in the absence of bases		Org. Chem. Front.	87	Cao, ZC	FALSE	FALSE	FALSE	FALSE
2057	10.1002/chem.201404692	doi.org/10.1002/chem.201404692	Lewis and Bronsted Acid Cocatalyzed Reductive Deoxyallenylation of Propargylic Alcohols with 2-Nitrobenzenesulfonylhydrazide		Chem.-Eur. J.	87	Bi, XH	FALSE	FALSE	FALSE	FALSE
2058	10.1021/ja5076426	doi.org/10.1021/ja5076426	Stereospecific Cross-Coupling Reactions of Aryl-Substituted Tetrahydrofurans, Tetrahydropyrans, and Lactones		J. Am. Chem. Soc.	87	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
2059	10.1002/chem.201404310	doi.org/10.1002/chem.201404310	Alkene Carboboration Enabled by Synergistic Catalysis		Chem.-Eur. J.	87	Brown, MK	FALSE	FALSE	FALSE	FALSE
2060	10.1021/ol501887a	doi.org/10.1021/ol501887a	Palladium-Catalyzed Allylic Esterification via C-C Bond Cleavage of a Secondary Homoallyl Alcohol		Org. Lett.	87	Kang, Q	FALSE	FALSE	FALSE	FALSE
2061	10.1002/chem.201303809	doi.org/10.1002/chem.201303809	Nickel-Catalyzed Csp(2)-Csp(3) Bond Formation by Carbon-Fluorine Activation		Chem.-Eur. J.	87	Love, JA	FALSE	FALSE	FALSE	FALSE
2062	10.1039/c4ob00677a	doi.org/10.1039/c4ob00677a	Nickel-catalyzed substitution reactions of propargyl halides with organotitanium reagents		Org. Biomol. Chem.	87	Li, QH	FALSE	FALSE	FALSE	FALSE
2063	10.1595/147106713X672311	doi.org/10.1595/147106713X672311	The Directed ortho Metallation-Cross-Coupling Fusion: Development and Application in Synthesis Platinum group metals catalytic synthetic strategy for pharmaceutical, agrochemical and other industrial products		Platin. Met. Rev.	87	Board, J	FALSE	FALSE	FALSE	FALSE
2064	10.1002/ejoc.201201463	doi.org/10.1002/ejoc.201201463	Ruthenium-Catalyzed Selective Aerobic Oxidative ortho-Alkenylation of Substituted Phenols with Alkenes through C-H Bond Activation		Eur. J. Org. Chem.	87	Jeganmohan, M	FALSE	FALSE	FALSE	FALSE
2065	10.1039/c3sc52142g	doi.org/10.1039/c3sc52142g	Prediction of suitable catalyst by H-1 NMR: asymmetric synthesis of multisubstituted biaryls by chiral phosphoric acid catalyzed asymmetric bromination		Chem. Sci.	87	Akiyama, T	FALSE	FALSE	FALSE	FALSE
2066	10.1021/om3006036	doi.org/10.1021/om3006036	Electron Transfer Studies on Ferrocenylthiophenes: Synthesis, Properties, and Electrochemistry		Organometallics	87	Lang, H	FALSE	TRUE	FALSE	FALSE
2067	10.1021/jo3005149	doi.org/10.1021/jo3005149	Cobalt-Catalyzed Vinylation of Aromatic Halides Using beta-Halostyrene: Experimental and DFT Studies		J. Org. Chem.	87	Gosmini, C	FALSE	FALSE	FALSE	FALSE
2068	10.1021/ja205167e	doi.org/10.1021/ja205167e	En Route to a Molecular Sheaf: Active Metal Template Synthesis of a [3]Rotaxane with Two Axles Threaded through One Ring		J. Am. Chem. Soc.	87	Leigh, DA	FALSE	FALSE	FALSE	FALSE
2069	10.1021/ja2039248	doi.org/10.1021/ja2039248	Enantioselective Construction of All-Carbon Quaternary Centers by Branch-Selective Pd-Catalyzed Allyl Allyi Cross-Coupling		J. Am. Chem. Soc.	87	Morken, JP	FALSE	FALSE	FALSE	FALSE
2070	10.1021/jo1018969	doi.org/10.1021/jo1018969	Palladium-Catalyzed Indole, Pyrrole, and Furan Arylation by Aryl Chlorides		J. Org. Chem.	87	Daugulis, O	FALSE	FALSE	FALSE	FALSE
2071	10.1002/adsc.200900790	doi.org/10.1002/adsc.200900790	Copper-Catalyzed Asymmetric Allylic Alkylation of Racemic Cyclic Substrates: Application of Dynamic Kinetic Asymmetric Transformation (DYKAT)		Adv. Synth. Catal.	87	Alexakis, A	FALSE	FALSE	FALSE	FALSE
2072	10.1002/ejoc.200900067	doi.org/10.1002/ejoc.200900067	N-Heterocyclic Carbene Derived Nickel-Pincer Complexes: Efficient and Applicable Catalysts for Suzuki-Miyaura Coupling Reactions of Aryl/Alkenyl Tosylates and Mesylates		Eur. J. Org. Chem.	87	Inamoto, K	FALSE	FALSE	FALSE	FALSE
2073	10.1021/op8000178	doi.org/10.1021/op8000178	UnyLinker: An efficient and scaleable synthesis of oligonucleotides utilizing a universal linker molecule: A novel approach to enhance the purity of drugs		Org. Process Res. Dev.	87	Ravikumar, VT	FALSE	FALSE	FALSE	FALSE
2074	10.1002/chem.200702030	doi.org/10.1002/chem.200702030	Ruthenium-catalyzed synthesis of allylic alcohols: Boronic acid as a hydroxide source		Chem.-Eur. J.	87	Carreaux, F	FALSE	FALSE	FALSE	FALSE
2075	10.1002/anie.200604629	doi.org/10.1002/anie.200604629	alpha-Oxygenated crotyltitanium and dyotropic rearrangement in the total synthesis of discodermolide		Angew. Chem.-Int. Edit.	87	Betzer, JF	FALSE	FALSE	FALSE	FALSE
2076	10.1021/jo0520994	doi.org/10.1021/jo0520994	Synthesis of functionalized benzylsilanes from arylzinc compounds and (iodomethyl)trimethylsilane by means of a novel Rh catalysis		J. Org. Chem.	87	Takagi, K	FALSE	FALSE	FALSE	FALSE
2077	10.1002/cber.19861190324	doi.org/10.1002/cber.19861190324	STEREOSELECTIVE SYNTHESIS OF ALCOHOLS .22. E/Z-SELECTIVITY ON ADDITION OF ALPHA-SUBSTITUTED ALLYLBORONATES TO ALDEHYDES		Chem. Ber.-Recl.	87	HOFFMANN, RW	FALSE	FALSE	FALSE	FALSE
2078	10.1021/ja00300a031	doi.org/10.1021/ja00300a031	ELIMINATION-REACTIONS OF ALPHA,BETA-DIHYDROXYSILANES - STEREOSPECIFIC SYNTHESIS OF SILYL ENOL ETHERS FROM VINYLSILANES		J. Am. Chem. Soc.	87	HUDRLIK, PF	FALSE	FALSE	FALSE	FALSE
2079	10.1002/anie.202200215	doi.org/10.1002/anie.202200215	Nickel-Catalyzed Reductive C(sp(2))-Si Coupling of Chlorohydrosilanes via Si-Cl Cleavage		Angew. Chem.-Int. Edit.	87	Shu, XZ	FALSE	FALSE	FALSE	FALSE
2080	10.1002/anie.202117843	doi.org/10.1002/anie.202117843	Design and Synthesis of Tunable Chiral 2,2 '-Bipyridine Ligands: Application to the Enantioselective Nickel-Catalyzed Reductive Arylation of Aldehydes		Angew. Chem.-Int. Edit.	87	Li, PF	FALSE	FALSE	FALSE	FALSE
2081	10.1039/d2qo00004k	doi.org/10.1039/d2qo00004k	Redox-neutral dehydrogenative cross-coupling of alcohols and amines enabled by nickel catalysis		Org. Chem. Front.	87	Rong, ZQ	FALSE	FALSE	FALSE	FALSE
2082	10.1002/adsc.202101388	doi.org/10.1002/adsc.202101388	Cross-Electrophile Coupling between Aryl/Vinyl Triflates and Vinyl Tosylates for the Synthesis of gem-Difluoroalkenes via Ni/Pd Cooperative Catalysis		Adv. Synth. Catal.	87	Zhang, XM; Lian, Z	FALSE	TRUE	FALSE	FALSE
2083	10.6023/cjoc202104049	doi.org/10.6023/cjoc202104049	Progress in the Synthesis of Aroyl Compounds		Chin. J. Org. Chem.	87	Zeng, M	FALSE	FALSE	FALSE	FALSE
2084	10.1038/s41467-021-25702-4	doi.org/10.1038/s41467-021-25702-4	Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations		Nat. Commun.	87	Wu, XS	FALSE	FALSE	FALSE	FALSE
2085	10.1021/acs.inorgchem.0c03664	doi.org/10.1021/acs.inorgchem.0c03664	Recovering the Thermally Activated Delayed Fluorescence in Aggregation-Induced Emitters of Carborane		Inorg. Chem.	87	Tao, SL	FALSE	FALSE	FALSE	FALSE
2086	10.1055/s-0036-1588845	doi.org/10.1055/s-0036-1588845	Nickel-Catalyzed Negishi Cross-Coupling of N-Acylsuccinimides: Stable, Amide-Based, Twist-Controlled Acyl-Transfer Reagents via N-C Activation		Synthesis	87	Szostak, M	FALSE	FALSE	FALSE	FALSE
2087	10.1021/acs.orglett.7b00447	doi.org/10.1021/acs.orglett.7b00447	Palladium-Catalyzed Formylation of Arylzinc Reagents with S-Phenyl Thioformate		Org. Lett.	87	Haraguchi, R; Fukuzawa, S	FALSE	FALSE	FALSE	FALSE
2088	10.1016/j.carres.2016.10.008	doi.org/10.1016/j.carres.2016.10.008	Utilization of bench-stable and readily available nickel(II) triflate for access to 1,2-cis-2-aminoglycosides		Carbohydr. Res.	87	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
2089	10.1021/acscatal.6b01681	doi.org/10.1021/acscatal.6b01681	Enantioselective Synthesis of Di- and Tri-Arylated All-Carbon Quaternary Stereocenters via Copper-Catalyzed Allylic Arylations with Organolithium Compounds		ACS Catal.	87	Feringa, BL	FALSE	FALSE	FALSE	FALSE
2090	10.1246/bcsj.20160135	doi.org/10.1246/bcsj.20160135	Kinetic Resolution of Secondary Carbinols by a Chiral N,N-4-Dimethylaminopyridine Derivative Containing a 1,1 '- Binaphthyl Unit: Hydrogen Bonding Affects Catalytic Activity and Enantioselectivity		Bull. Chem. Soc. Jpn.	87	Mandai, H; Suga, S	FALSE	FALSE	FALSE	FALSE
2091	10.1021/acscatal.6b01120	doi.org/10.1021/acscatal.6b01120	Nickel-Catalyzed C-H Alkynylation of Anilines: Expedient Access to Functionalized Indoles and Purine Nucleobases		ACS Catal.	87	Ackermann, L	FALSE	FALSE	FALSE	FALSE
2092	10.1055/s-0035-1561408	doi.org/10.1055/s-0035-1561408	Peracetic Acid Mediated sp(2) C-H Selenation of Arenes		Synlett	87	Lee, CF	FALSE	FALSE	FALSE	FALSE
2093	10.1021/acs.joc.6b00329	doi.org/10.1021/acs.joc.6b00329	Palladium-Catalyzed Carbamate-Directed Regioselective Halogenation: A Route to Halogenated Anilines		J. Org. Chem.	87	Moghaddam, FM	FALSE	FALSE	FALSE	FALSE
2094	10.1002/anie.201511487	doi.org/10.1002/anie.201511487	Photosensitizer-Free Visible-Light-Mediated Gold-Catalyzed 1,2-Difunctionalization of Alkynes		Angew. Chem.-Int. Edit.	87	Hashmi, ASK	TRUE	FALSE	FALSE	FALSE
2095	10.1002/anie.201600248	doi.org/10.1002/anie.201600248	alpha-Arylation of Ketimines with Aryl Sulfides at a Low Palladium Catalyst Loading		Angew. Chem.-Int. Edit.	87	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
2096	10.1021/acs.organomet.1c00009	doi.org/10.1021/acs.organomet.1c00009	Manganese-Catalyzed C(alpha)-Alkylation of Oxindoles with Secondary Alcohols via Borrowing Hydrogen	Despite advances in organometallic cross-coupling of alkyl electrophiles, there are few stereoselective reactions of chiral, nonracemic substrates. Herein we report a stereospecific carbonylative coupling of alkyl tosylates and dienes producing enantioenriched dienones. This catalytic process proceeds under low pressure and mild conditions using a simple cobalt catalyst and extends to diverse tosylate and diene coupling partners. The transformation constitutes a unique, convergent approach to the asymmetric synthesis of valuable carbonyl compounds from easily accessed starting materials.	Organometallics	86	Madhu, V	FALSE	FALSE	FALSE	FALSE
2097	10.1021/acs.orglett.0c03542	doi.org/10.1021/acs.orglett.0c03542	Nickel-Catalyzed Regioselective Hydroarylation of Internal Enamides	C-H (hetero) arylation of aromatic compounds using transition-metal catalysts has garnered much attention from the synthetic chemistry community as a next-generation coupling method for constructing (hetero) biaryl motifs. This account describes our recent achievements in transitionmetal-catalyzed aromatic C-H arylation and its applications to the synthesis of bioactive molecules.	Org. Lett.	86	Chen, YF	FALSE	FALSE	FALSE	FALSE
2098	10.1021/jacs.0c09275	doi.org/10.1021/jacs.0c09275	Aryl Amination Using Soluble Weak Base Enabled by a Water-Assisted Mechanism	The case is made for transitioning organic chemistry from a developed discipline that remains highly dependent upon organic solvents to one that will be sustainable, based on water as the reaction medium. Processes in hand that today achieve the same bond constructions characteristic of traditional organic synthesis, but can be accomplished under environmentally responsible conditions, are discussed as representative of the potential that lies ahead.	J. Am. Chem. Soc.	86	Carrow, BP	FALSE	FALSE	FALSE	FALSE
2099	10.1016/j.jcat.2020.07.032	doi.org/10.1016/j.jcat.2020.07.032	Controllable preparation of Ni-CeO2 nanoparticles anchored on Al-Mg oxide spheres (AMO) by hydrophobic driving mechanism for dehydrogenative homo-coupling of pyridines	The present study demonstrates the utilization of insitu generated supramolecular ensemble of aggregates of pentacenequinone derivative 3 and cadmium nanoparticles (CdNPs) as an efficient catalytic system for (1) oxidant free, controlled and selective monofunctionalization and hetero/homo difunctionalization of 1,4-benzoquinone by C-H activation at room temperature (2) photocatalytic C-H functionalization of azoles with bromoarenes and (3) C-H functionalization of benzothiazole with simple arenes in ecofriendly conditions under visible light irradiations. Thus, a range of C2-arylated quinone and azole derivatives are synthesized from simple substrates using this newly developed catalytic/photocatalytic system under economic and ecofriendly conditions.	J. Catal.	86	Zhou, YM; Zhang, YW; Hu, YJ	FALSE	FALSE	FALSE	FALSE
2100	10.1155/2020/1543081	doi.org/10.1155/2020/1543081	Synthesis of Phenols via Metal-Free Hydroxylation of Aryl Boronic Acids with Aqueous TBHP	A facile and straightforward synthesis of unsymmetrical triary-lmethanes and stereogenic methanes have been realized through the Friedel-Crafts type alkylation of arenes with alkoxyalu-minium intermediate generated in situ from aldehyde, arene and AlBr3 at room temperature in presence of catalytic quantity of AlBr3. This protocol is successful with diversity of starting materials and desired products were obtained in moderate to good yields. The displacement of -OAlBr2 with catalytic quantity of AlBr3 generated the reactive carbocation like intermediate which underwent subsequent reaction with another nucleophile (either -C, -S or -O nucleophile) and furnished the corresponding substituted products. The mechanism of the controlled, sequential reaction has been investigated by density functional theory calculations. Our model suggests that the involvement of penta coordinate complex in which the cleavage of C - OAlBr2 bond is favoured over N - AlBr2 bond at room temperature, in presence of additional catalyst.	J. Chem.	86	Shaikh, TM	FALSE	FALSE	FALSE	FALSE
2101	10.1002/ejoc.202000167	doi.org/10.1002/ejoc.202000167	Ruthenium Catalyzed N-Alkylation of Cyclic Amines with Primary Alcohols	We report nickel-catalyzed cross-coupling of methoxyarenes with alkylmagnesium halides, in which a methoxy group is eliminated. A wide range of alkyl groups, including those bearing beta-hydrogens, can be introduced directly at the ipso position of anisole derivatives. We demonstrate that the robustness of a methoxy group allows this alkylation protocol to be used to synthesize elaborate molecules by combining it with traditional cross coupling reactions or oxidative transformation. The success of this method is dependent on the use of alkylmagnesium iodides, but not chlorides or bromides, which highlights the importance of the halide used in developing catalytic reactions using Grignard reagents.	Eur. J. Org. Chem.	86	Savela, R	FALSE	FALSE	FALSE	FALSE
2102	10.1002/ejoc.202000077	doi.org/10.1002/ejoc.202000077	Selective Conversion of Benzylic Phosphates into Diarylmethanes Through Al(OTf)(3)-Catalyzed Friedel-Crafts-Type Benzylation	New carbon-carbon bond formation reactions expand our horizon of retrosynthetic analysis for the synthesis of complex organic molecules. Although many methods are now available for the formation of C(sp(2))-C(sp(3)) and C(sp(3))-C(sp(3)) bonds via transition metal-catalyzed cross-coupling of alkyl organometallic reagents, direct use of readily available olefins in a formal fashion of hydrocarbonation to make C(sp(2))-C(sp(3)) and C(sp(3))-C(sp(3)) bonds remains to be developed. Here we report the discovery of a general process for the intermolecular reductive coupling of unactivated olefins with alkyl or aryl electrophiles under the promotion of a simple nickel catalyst system. This new reaction presents a conceptually unique and practical strategy for the construction of C(sp(2))-C(sp(3)) and C(sp(3))-C(sp(3)) bonds without using any organometallic reagent. The reductive olefin hydrocarbonation also exhibits excellent compatibility with varieties of synthetically important functional groups and therefore, provides a straightforward approach for modification of complex organic molecules containing olefin groups.	Eur. J. Org. Chem.	86	Yurino, T; Ohkuma, T	FALSE	FALSE	FALSE	FALSE
2103	10.1021/acscatal.0c00789	doi.org/10.1021/acscatal.0c00789	Engaging alpha-Fluorocarboxylic Acids Directly in Decarboxylative C-C Bond Formation	Memory of chirality' (MOC) is an important concept for the development of efficient asymmetric transformations. However, the phenomenon of MOC in C-H functionalization is still rare. In the past decades, three types of intramolecular C-H amination involving C-H insertion of metal nitrenoids, 1-aza-2-azoniaallene salts, and benzamides to construct N-heterocyclic compounds have been developed in Du Bois, Brewer, and our group, respectively. In these reactions, the formation of a C-N bond does not result in the loss of stereochemical information at the stereogenic center. Here, we discuss the scope, mechanism, and application of these transformations and provide a perspective on the development of this field in future.	ACS Catal.	86	Koh, MJ	FALSE	FALSE	FALSE	FALSE
2104	10.1016/j.chempr.2019.12.010	doi.org/10.1016/j.chempr.2019.12.010	Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes	Nickel(0)-catalyzed cross-coupling of heteroaryl-containing diarylmethanes with both aryl bromides and chlorides has been achieved. The success of this reaction relies on the introduction of a unique nickel/NIXANTPHOS-based catalyst system, which provides a direct route to triarylmethanes from heteroaryl-containing diarylmethanes. Reactivity studies indicate the Ni(NIXANTPHOS)-based catalyst exhibits enhanced reactivity over XANTPHOS derivatives and other Ni(phosphine)-based catalysts in the reactions examined.	Chem	86	Jiang, C	FALSE	FALSE	FALSE	FALSE
2105	10.1021/acs.orglett.0c00199	doi.org/10.1021/acs.orglett.0c00199	Photoredox/Nickel Dual-Catalyzed Reductive Cross Coupling of Aryl Halides Using an Organic Reducing Agent		Org. Lett.	86	Rueping, M	TRUE	FALSE	FALSE	FALSE
2106	10.1002/anie.201906148	doi.org/10.1002/anie.201906148	Synthesis of Arylacetaldehydes by Iridium-Catalyzed Arylation of Vinylene Carbonate with Arylboronic Acids		Angew. Chem.-Int. Edit.	86	Hayashi, T	FALSE	FALSE	FALSE	FALSE
2107	10.1002/cssc.201900784	doi.org/10.1002/cssc.201900784	Nickel-Catalyzed Stereodivergent Synthesis of E- and Z-Alkenes by Hydrogenation of Alkynes		ChemSusChem	86	Jagadeesh, RV; Beller, M	FALSE	FALSE	FALSE	FALSE
2108	10.1002/ejoc.201900478	doi.org/10.1002/ejoc.201900478	A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2		Eur. J. Org. Chem.	86	Sun, B; Qin, HL	FALSE	FALSE	FALSE	FALSE
2109	10.1055/s-0037-1611793	doi.org/10.1055/s-0037-1611793	1,10-Phenanthroline- or Electron-Promoted Cyanation of Aryl Iodides		Synlett	86	Mitsudo, K; Suga, S	FALSE	TRUE	FALSE	FALSE
2110	10.1002/chem.201900498	doi.org/10.1002/chem.201900498	Phosphazene Base tBu-P4 Catalyzed Methoxy-Alkoxy Exchange Reaction on (Hetero)Arenes		Chem.-Eur. J.	86	Shigeno, M; Kondo, Y	FALSE	FALSE	FALSE	FALSE
2111	10.1021/acscatal.8b04787	doi.org/10.1021/acscatal.8b04787	Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis		ACS Catal.	86	Wang, J	FALSE	FALSE	FALSE	FALSE
2112	10.1021/jacs.8b12063	doi.org/10.1021/jacs.8b12063	A Mild and Direct Site-Selective sp(2) C-H Silylation of (Poly)Azines		J. Am. Chem. Soc.	86	Martin, R	FALSE	FALSE	FALSE	FALSE
2113	10.1002/anie.201809003	doi.org/10.1002/anie.201809003	Copper-Catalyzed Ring Opening of Benzofurans and an Enantioselective Hydroamination Cascade		Angew. Chem.-Int. Edit.	86	Zhang, X; You, SL	FALSE	FALSE	FALSE	FALSE
2114	10.1055/s-0037-1611062	doi.org/10.1055/s-0037-1611062	Direct Conversion of Benzyl Ethers into Aryl Nitriles		Synlett	86	Wang, JJ	FALSE	FALSE	FALSE	FALSE
2115	10.1002/anie.201805611	doi.org/10.1002/anie.201805611	A Simple, Broad-Scope Nickel(0) Precatalyst System for the Direct Amination of Allyl Alcohols		Angew. Chem.-Int. Edit.	86	Sweeney, JB	FALSE	FALSE	FALSE	FALSE
2116	10.1021/acs.orglett.8b01600	doi.org/10.1021/acs.orglett.8b01600	Regioselective Copper-Catalyzed Oxidative Coupling of alpha-Alkylated Styrenes with Tertiary Alkyl Radicals		Org. Lett.	86	Hu, XH; Loh, TP	FALSE	FALSE	FALSE	FALSE
2117	10.1021/jacs.8b03163	doi.org/10.1021/jacs.8b03163	Ni-Catalyzed Regioselective beta,delta-Diarylation of Unactivated Olefins in Ketimines via Ligand-Enabled Contraction of Transient Nickellacycles: Rapid Access to Remotely Diarylated Ketones		J. Am. Chem. Soc.	86	Giri, R	FALSE	FALSE	FALSE	FALSE
2118	10.1021/jacs.8b02547	doi.org/10.1021/jacs.8b02547	Enantioselective Ni-Al Bimetallic Catalyzed exo-Selective C-H Cyclization of Imidazoles with Alkenes		J. Am. Chem. Soc.	86	Ye, MC	FALSE	FALSE	FALSE	FALSE
2119	10.6023/cjoc201709041	doi.org/10.6023/cjoc201709041	Recent Advance of Palladium-Catalyzed Cross-Coupling Reactions of Organoalanes with Electrophiles Reagents		Chin. J. Org. Chem.	86	Li, QH	FALSE	TRUE	FALSE	FALSE
2120	10.1021/acs.orglett.8b00080	doi.org/10.1021/acs.orglett.8b00080	Decarbonylative C-P Bond Formation Using Aromatic Esters and Organophosphorus Compounds		Org. Lett.	86	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
2121	10.1002/anie.201707134	doi.org/10.1002/anie.201707134	Nickel-Catalyzed Asymmetric Reductive Heck Cyclization of Aryl Halides to Afford Indolines		Angew. Chem.-Int. Edit.	86	Zhou, JS	FALSE	FALSE	FALSE	FALSE
2122	10.1021/acscatal.7b02540	doi.org/10.1021/acscatal.7b02540	Site-Selective C-H/C-N Activation by Cooperative Catalysis: Primary Amides as Arylating Reagents in Directed C-H Arylation		ACS Catal.	86	Szostak, M	FALSE	FALSE	FALSE	FALSE
2123	10.1002/ejic.201500852	doi.org/10.1002/ejic.201500852	1,2,4-Triazole-Based N-Heterocyclic Carbene Nickel Complexes - Synthesis and Catalytic Application		Eur. J. Inorg. Chem.	86	Sortais, JB	FALSE	FALSE	FALSE	FALSE
2124	10.1021/acs.orglett.5b02380	doi.org/10.1021/acs.orglett.5b02380	Transition-Metal-Free Cross-Coupling of Aryl and N-Heteroaryl Cyanides with Benzylic Zinc Reagents		Org. Lett.	86	Knochel, P	FALSE	FALSE	FALSE	FALSE
2125	10.1021/acs.orglett.5b01229	doi.org/10.1021/acs.orglett.5b01229	Directed Amination of Aryl Methyl Ethers Mediated by Ti(NMe2)(4) at Room Temperature		Org. Lett.	86	Li, YH	FALSE	FALSE	FALSE	FALSE
2126	10.1021/acs.joc.5b00364	doi.org/10.1021/acs.joc.5b00364	Enantioselective Copper-Catalyzed Alkynylation of Benzopyranyl Oxocarbenium Ions		J. Org. Chem.	86	Watson, MP	FALSE	FALSE	FALSE	FALSE
2127	10.1002/adsc.201400970	doi.org/10.1002/adsc.201400970	Nickel-Catalyzed Reductive Benzylation of Aldehydes with Benzyl Halides and Pseudohalides		Adv. Synth. Catal.	86	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
2128	10.6023/cjoc201409007	doi.org/10.6023/cjoc201409007	Advances in the Synthetic Methods of Terphenyls		Chin. J. Org. Chem.	86	Shi, W	FALSE	FALSE	FALSE	FALSE
2129	10.1002/anie.201410322	doi.org/10.1002/anie.201410322	Nickel-Catalyzed Dehydrogenative Cross-Coupling: Direct Transformation of Aldehydes into Esters and Amides		Angew. Chem.-Int. Edit.	86	Dong, VM	FALSE	FALSE	FALSE	FALSE
2130	10.1039/c5ra06753g	doi.org/10.1039/c5ra06753g	Synthesis of new surfactant-like triazine-functionalized ligands for Pd-catalyzed Heck and Sonogashira reactions in water		RSC Adv.	86	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
2131	10.1002/anie.201409450	doi.org/10.1002/anie.201409450	Rhodium(III)/Copper(II)-Promoted trans-Selective Heteroaryl Acyloxylation of Alkynes: Stereodefined Access to trans-Enol Esters		Angew. Chem.-Int. Edit.	86	Cramer, N	FALSE	FALSE	FALSE	FALSE
2132	10.1021/ol502815p	doi.org/10.1021/ol502815p	Oxidant-Switchable Selective Synthesis of 2-Aminobenzimidazoles via C-H Amination/Acetoxylation of Guanidines		Org. Lett.	86	Zhang, WX	FALSE	FALSE	FALSE	FALSE
2133	10.1016/j.ica.2014.05.023	doi.org/10.1016/j.ica.2014.05.023	Synthesis of Ni(II) complexes with unsymmetric [O,N,O ']-pincer ligands and their use as precatalysts in carbon-carbon bond formations to access diarylmethanes		Inorg. Chim. Acta	86	Enthaler, S	FALSE	FALSE	FALSE	FALSE
2134	10.1002/adsc.201300720	doi.org/10.1002/adsc.201300720	Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl Acetates		Adv. Synth. Catal.	86	Morken, JP	FALSE	FALSE	FALSE	FALSE
2135	10.1021/ol4027073	doi.org/10.1021/ol4027073	Reigoselective Arylation of Thiazole Derivatives at 5-Position via Pd Catalysis under Ligand-Free Conditions		Org. Lett.	86	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
2136	10.1021/ol400295z	doi.org/10.1021/ol400295z	Palladium-Catalyzed Desulfitative Cross-Coupling Reaction of Sodium Sulfinates with Benzyl Chlorides		Org. Lett.	86	Deng, GJ	FALSE	FALSE	FALSE	FALSE
2137	10.1021/jo3027824	doi.org/10.1021/jo3027824	Palladium-Catalyzed Cross-Coupling of Aziridinylmetal Species, Generated by Sulfinyl-Magnesium Exchange, with Aryl Bromides: Reaction Optimization, Scope, and Kinetic Investigations		J. Org. Chem.	86	Bull, JA	FALSE	FALSE	FALSE	FALSE
2138	10.1002/aoc.2871	doi.org/10.1002/aoc.2871	Bi(III)-catalyzed C-S cross-coupling reaction		Appl. Organomet. Chem.	86	Chakraborty, D	FALSE	FALSE	FALSE	FALSE
2139	10.1039/c1dt10426h	doi.org/10.1039/c1dt10426h	Bis(imidate)palladium(II) complexes with labile ligands. Mimics of classical precursors?		Dalton Trans.	86	Serrano, JL	FALSE	FALSE	FALSE	FALSE
2140	10.1002/chem.201001201	doi.org/10.1002/chem.201001201	[Pd(Cl)(2){P(NC5H10)(C6H11)(2)}(2)]-A Highly Effective and Extremely Versatile Palladium-Based Negishi Catalyst that Efficiently and Reliably Operates at Low Catalyst Loadings		Chem.-Eur. J.	86	Frech, CM	FALSE	FALSE	FALSE	FALSE
2141	10.1002/ejoc.200900252	doi.org/10.1002/ejoc.200900252	Binaphthalene-Derived Iminium Salt Catalysts for Highly Enantioselective Asymmetric Epoxidation		Eur. J. Org. Chem.	86	Page, PCB	FALSE	FALSE	FALSE	FALSE
2142	10.1021/cg8004163	doi.org/10.1021/cg8004163	Formation of Infinite Linear Mercury Metal Chains Assisted by Face-to-Face pi-pi (Aryl-Aryl) Stacking Interactions		Cryst. Growth Des.	86	Lu, KL	FALSE	FALSE	FALSE	FALSE
2143	10.5059/yukigoseikyokaishi.65.761	doi.org/10.5059/yukigoseikyokaishi.65.761	Development of optically active chiral Ligands ferrocenyloxazolinylphosphines (FOXAP) and their application to catalytic asymmetric reactions		J. Synth. Org. Chem. Jpn.	86	Nishibayashi, Y	FALSE	FALSE	FALSE	FALSE
2144	10.1246/bcsj.76.1233	doi.org/10.1246/bcsj.76.1233	Metallation reactions on 2,2 '-bis(diphenylphosphinoyl)-1,1 '-binaphthyl [BINAP(O)(2)]		Bull. Chem. Soc. Jpn.	86	Widhalm, M	FALSE	FALSE	FALSE	FALSE
2145	10.1021/ja00252a029	doi.org/10.1021/ja00252a029	PALLADIUM-CATALYZED COUPLING OF ARYL TRIFLATES WITH ORGANOSTANNANES		J. Am. Chem. Soc.	86		FALSE	FALSE	FALSE	FALSE
2146	10.1021/acs.accounts.1c00329	doi.org/10.1021/acs.accounts.1c00329	Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions		Accounts Chem. Res.	86	Giri, R	FALSE	FALSE	FALSE	FALSE
2147	10.1002/chem.202101090	doi.org/10.1002/chem.202101090	1,2-Carbopentafluorophenylation of Alkynes: The Metallomimetic Pull-Push Reactivity of Tris(pentafluorophenyl)borane		Chem.-Eur. J.	86	Shibuya, M	FALSE	FALSE	FALSE	FALSE
2148	10.1002/anie.202100810	doi.org/10.1002/anie.202100810	sp(3) Bis-Organometallic Reagents via Catalytic 1,1-Difunctionalization of Unactivated Olefins		Angew. Chem.-Int. Edit.	86	Martin, R	FALSE	FALSE	FALSE	FALSE
2149	10.1021/acscatal.7b00300	doi.org/10.1021/acscatal.7b00300	Modular Synthesis of Enantioenriched 1,1,2-Triarylethanes by an Enantioselective Arylboration and Cross-Coupling Sequence		ACS Catal.	86	Liao, J	FALSE	FALSE	FALSE	FALSE
2150	10.1016/j.tet.2017.01.050	doi.org/10.1016/j.tet.2017.01.050	n-Butyllithium-mediated synthesis of N-aryl tertiary amines by reactions of fluoroarenes with secondary amines at room temperature		Tetrahedron	86	Cao, S	FALSE	FALSE	FALSE	FALSE
2151	10.1002/ajoc.201600596	doi.org/10.1002/ajoc.201600596	Construction of Tertiary Amides: Ni-II-Catalyzed N-Arylation of Secondary Acyclic Amides (2-Picolinamides) with Aryl Halides		Asian J. Org. Chem.	86	Babu, SA	FALSE	FALSE	FALSE	FALSE
2152	10.1055/s-0035-1561673	doi.org/10.1055/s-0035-1561673	Synthesis of Thioethers Using Triethylamine-Activated Phosphorus Decasulfide (P4S10)		Synthesis	86	Cinar, ME; Ozturk, T	FALSE	FALSE	FALSE	FALSE
2153	10.1002/ajoc.201600319	doi.org/10.1002/ajoc.201600319	Palladium-Catalyzed Suzuki-Miyaura Coupling Reactions of Boronic Acid Derivatives with Aryl Chlorides		Asian J. Org. Chem.	86	Qiu, LQ	FALSE	FALSE	FALSE	FALSE
2154	10.1002/chem.201504718	doi.org/10.1002/chem.201504718	Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters		Chem.-Eur. J.	86	Murai, M; Takai, K	FALSE	FALSE	FALSE	FALSE
2155	10.1016/j.saa.2015.10.015	doi.org/10.1016/j.saa.2015.10.015	In vitro anticancer activities of Schiff base and its lanthanum complex		Spectroc. Acta Pt. A-Molec. Biomolec. Spectr.	86	Kumar, D	FALSE	FALSE	FALSE	FALSE
2156	10.5059/yukigoseikyokaishi.74.45	doi.org/10.5059/yukigoseikyokaishi.74.45	Ruthenium-Catalyzed Stereoselective Allylic Substitutions		J. Synth. Org. Chem. Jpn.	86	Kawatsura, M	FALSE	FALSE	FALSE	FALSE
2157	10.1016/j.ica.2020.120043	doi.org/10.1016/j.ica.2020.120043	Synthesis, characterization and catalytic activity of PEPPSI-type palladium-NHC complexes	Catalytic C-H bond activation, which was an elusive subject of chemical research until the 1990s, has now become a standard synthetic method for the formation of new C-C and C-heteroatom bonds. The synthetic potential of C-H activation was first described for ruthenium catalysis and is now widely exploited by the use of various precious metals. Driven by the increasing interest in chemical utilization of ubiquitous metals that are abundant and nontoxic, iron catalysis has become a rapidly growing area of research, and iron-catalyzed C-H activation has been most actively explored in recent years. In this review, we summarize the development of stoichiometric C-H activation, which has a long history, and catalytic C-H functionalization, which emerged about 10 years ago. We focus in this review on reactions that take place via reactive organoiron intermediates, and we excluded those that use iron as a Lewis acid or radical initiator. The contents of this review are categorized by the type of C-H bond cleaved and the type of bond formed thereafter, and it covers, the reactions of simple substrates and substrates possessing a directing group that anchors the catalyst to the substrate, providing an overview of iron-mediated and iron-catalyzed C-H activation reported in the literature by October 2016.	Inorg. Chim. Acta	85	Hamdi, N	FALSE	FALSE	FALSE	FALSE
2158	10.1055/a-1337-5153	doi.org/10.1055/a-1337-5153	Homogeneous Palladium-Catalyzed Selective Reduction of 2,2 '-Biphenols Using HCO2H as Hydrogen Source	The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis, has recently emerged as a versatile platform for the development of new, highly enabling synthetic methodologies. Photoredox catalysis provides access to reactive radical species under mild conditions from abundant, native functional groups, and, when combined with transition metal catalysis, this feature allows direct coupling of non-traditional nucleophile partners. In addition, photocatalysis can aid fundamental organometallic steps through modulation of the oxidation state of transition metal complexes or through energy-transfer-mediated excitation of intermediate catalytic species. Metallaphotocatalysis provides access to distinct activation modes, which are complementary to those traditionally used in the field of transition metal catalysis, thereby enabling reaction development through entirely new mechanistic paradigms. This Review discusses key advances in the field of metallaphotocatalysis over the past decade and demonstrates how the unique mechanistic features permit challenging, or previously elusive, transformations to be accomplished.	Synthesis	85	Yang, W; Zhao, WX	FALSE	FALSE	TRUE	TRUE
2159	10.1039/d0qo00785d	doi.org/10.1039/d0qo00785d	The present and future synthetic strategies of structural modifications of sinomenine	The iron-catalyzed methylation of arylboron compounds has been developed for the first time using iodomethane (CH3I) as the electrophile. In the presence of catalytic amounts of an iron-bisphosphine complex and MgBr2, Suzuki-Miyaura-type cross-coupling reactions of CH3I with various arylboron compounds proceed smoothly under mild conditions to afford the corresponding methylated aromatic compounds in good yields.	Org. Chem. Front.	85	Liu, L; Wong, VKW	FALSE	FALSE	FALSE	FALSE
2160	10.1021/acs.orglett.0c03757	doi.org/10.1021/acs.orglett.0c03757	Palladium-Catalyzed Directed Atroposelective C-H Allylation via beta-H Elimination: 1,1-Disubstituted Alkenes as Allyl Surrogates	A new route for the direct cross-coupling of alkyl and allylic halides using electrochemical technique has been developed in aqueous media under air. Catalyzed by Pd(OAc)(2), the Zn-mediated allylic alkylations proceed smoothly between a full range of alkyl halides (primary, secondary, and tertiary) and substituted allylic halides. Protectiondeprotection of acidic hydrogen in the substrates is avoided.	Org. Lett.	85	Shi, BF	FALSE	FALSE	FALSE	FALSE
2161	10.1016/j.mcat.2020.111048	doi.org/10.1016/j.mcat.2020.111048	Development and application of palladium nanoparticles on renewable polysaccharides as catalysts for the Suzuki cross-coupling of halobenzenes and phenylboronic acids	A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C-O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.	Mol. Catal.	85	Levy-Ontman, O	FALSE	FALSE	FALSE	FALSE
2162	10.1016/j.tet.2020.131103	doi.org/10.1016/j.tet.2020.131103	Steric effects on deprotonative generation of cyclohexynes and 1,2-cyclohexadienes from cyclohexenyl triflates by magnesium amides	Palladium-catalyzed syn-stereocontrolled ring opening reactions of oxabenzonorbornadienes with a wide range of sodium arylsulfinates were investigated, affording the desired products in good to excellent yields under an air atmosphere. This protocol provides a low-cost new viable and convenient method toward the synthesis of cis-2-aryl-1,2-dihydronaphthalen-1-ol with good functional group tolerance. In addition, the cis configuration of 3da was established by X-ray diffraction analysis, and a plausible mechanism, for the ring opening reaction was proposed.	Tetrahedron	85	Okano, K	FALSE	FALSE	FALSE	FALSE
2163	10.1002/anie.202004758	doi.org/10.1002/anie.202004758	Room-Temperature Guerbet Reaction with Unprecedented Catalytic Efficiency and Enantioselectivity	The presented work describes the synthesis of new six-and seven-membered haloamidinium salts and their reaction with different metals. The isolated metal complexes were tested in a catalytic reaction. Two different synthetic routes were applied to prepare five different salts. Chloroamidinium salts were very water-sensitive in comparison to their corresponding bromoamidinium salts. Hence, the preparation of the less sensitive bromoamidinium salts was higher prioritized. The formed salts were converted with metal sources to N-heterocyclic carbene (NHC) metal complexes through an oxidative insertion into the C-X bond. This type of formation is less examined for the synthesis of extended NHC metal complexes. Pd(PPh3)(4) and cobalt powder were applied as metal sources, whereby two palladium complexes were isolated, characterized, and their crystal and molecular structures determined. The palladium complexes were investigated in the Suzuki-Miyaura reaction and showed promising catalytic activity.	Angew. Chem.-Int. Edit.	85	Zhao, Y	FALSE	FALSE	FALSE	FALSE
2164	10.1080/00397911.2020.1761392	doi.org/10.1080/00397911.2020.1761392	Ni-Catalyzed desilylative annulation of benzamides and acrylamides with alkynylsilanes: Access to 3-Methyleneisoindolin-1-one and 5-Methylene-1H-pyrrol-2(5H)-one derivatives	Methods that can directly arylate pyridines have significant potential in synthetic chemistry. Herein, we present palladium catalyzed C-H arylation of pyridines with aryl triflates that occurs regioselectively at the C3 positions of the pyridine core. A variety of aryl triflates and pyridines were applicable to the reaction to provide C3-arylated pyridines regardless of sterics or electronics of the pyridine cores.	Synth. Commun.	85	Lin, C	FALSE	FALSE	FALSE	FALSE
2165	10.1021/jacs.0c02405	doi.org/10.1021/jacs.0c02405	Exhaustive Reduction of Esters Enabled by Nickel Catalysis	Two dinuclear complexes [Ni-2(mu-bpym)(fum)(2)(H2O)(6)]center dot 5H(2)O (1, bpym = 2,2'-bipyrimidine, fum = trans-fumarate) and [Co-2(mu-bpym)(fum)(2)(H2O)(6)]center dot 2H(2)O (2) were assembled from MCl2 center dot 6H(2)O (M = Ni, Co), 2,2'-bipyrimidine, and trans-fumaric acid at ambient temperature. In particular, compounds 1 and 2 adopt almost the same molecular structure, but 1 hosts an infinite water chain while 2 traps a discrete tetrameric water cluster. It would arise from the guest water aggregates and would depend on the very slight differences in the coordination chemistry of the Ni(II) and Co(II) centers. The significant influence of metal ions on the resulting structures and the reversible dehydration/rehydration of the complexes further detailed. Photoluminescence spectra of 1 and 2 in the solid state at room temperature were obtained and studied. Magnetic studies showed that both of 1 and 2 afforded a dominant antiferromagnetic coupling between the metal ions. (C) 2016 Elsevier B.V. All rights reserved.	J. Am. Chem. Soc.	85	Newman, SG	FALSE	FALSE	TRUE	TRUE
2166	10.1021/acs.inorgchem.0c00153	doi.org/10.1021/acs.inorgchem.0c00153	Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Chromium and Cobalt Complexes	Nickel catalysed Suzuki reactions of phenyl boronic acids with aryl diazonium salts in glycerol as a reaction medium are reported. Various aryl diazonium salts were efficiently reacted with aryl boronic acids under optimized conditions to give the respective diaryl compounds in good to excellent yields. The base free conditions and use of glycerol as a solvent, which can be recycled successfully for up to five consecutive cycles, make the present protocol environmentally benign in nature.	Inorg. Chem.	85	Ye, SF	FALSE	FALSE	FALSE	FALSE
2167	10.1021/acs.joc.9b03104	doi.org/10.1021/acs.joc.9b03104	Nickel-Catalyzed Direct Synthesis of Quinoxalines from 2-Nitroanilines and Vicinal Diols: Identifying Nature of the Active Catalyst		J. Org. Chem.	85	Kundu, S	FALSE	FALSE	FALSE	FALSE
2168	10.1002/ejoc.201901362	doi.org/10.1002/ejoc.201901362	LiI/TBHP Mediated Oxidative Cross-Coupling of P(O)-H Compounds with Phenols and Various Nucleophiles: Direct Access to the Synthesis of Organophosphates		Eur. J. Org. Chem.	85	Reddy, KR	FALSE	FALSE	FALSE	FALSE
2169	10.1021/acs.orglett.9b03147	doi.org/10.1021/acs.orglett.9b03147	Nickel-Catalyzed Reductive 1,2-Dialkynylation of Alkenes Bearing an 8-Aminoquinoline Directing Group		Org. Lett.	85	Yao, HQ; Lin, AJ	FALSE	FALSE	FALSE	FALSE
2170	10.1021/jacs.9b08586	doi.org/10.1021/jacs.9b08586	Chromium(II)-Catalyzed Diastereoselective and Chemoselective Csp(2)-Csp(3) Cross-Couplings Using Organomagnesium Reagents		J. Am. Chem. Soc.	85	Li, J; Knochel, P	FALSE	FALSE	FALSE	FALSE
2171	10.1055/s-0037-1611898	doi.org/10.1055/s-0037-1611898	Deuterated Aryl Alkyl Ethers Synthesis via Nucleophilic Etherification of Aryl Alkyl Ethers and Thioethers with Deuterated Alcohols		Synlett	85	Wang, XQ	FALSE	FALSE	FALSE	FALSE
2172	10.1016/j.jorganchem.2019.06.003	doi.org/10.1016/j.jorganchem.2019.06.003	Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands		J. Organomet. Chem.	85	Moreno, JJ; Carmona, E	FALSE	FALSE	FALSE	FALSE
2173	10.1021/acs.joc.9b00649	doi.org/10.1021/acs.joc.9b00649	Nickel-Catalyzed Cross-Coupling of Umpolung Carbonyls and Alkyl Halides		J. Org. Chem.	85	Li, CJ	FALSE	FALSE	FALSE	FALSE
2174	10.1016/j.jorganchem.2019.01.017	doi.org/10.1016/j.jorganchem.2019.01.017	Anionic Bismuth(III) chloride cluster with diselenide countercations: Application in C-S cross coupling reactions		J. Organomet. Chem.	85	Ganesan, P	FALSE	FALSE	FALSE	FALSE
2175	10.1021/acs.orglett.8b04030	doi.org/10.1021/acs.orglett.8b04030	Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed Asymmetric Reverse Prenylation		Org. Lett.	85	Li, CK	FALSE	FALSE	FALSE	FALSE
2176	10.1021/jacs.8b12142	doi.org/10.1021/jacs.8b12142	Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction		J. Am. Chem. Soc.	85	Ma, DW	FALSE	FALSE	FALSE	FALSE
2177	10.1055/s-0037-1610084	doi.org/10.1055/s-0037-1610084	Vinylation of Benzylic Amines via C-N Bond Functionalization of Benzylic Pyridinium Salts		Synthesis	85	Watson, MP	FALSE	FALSE	FALSE	FALSE
2178	10.1002/chem.201801541	doi.org/10.1002/chem.201801541	Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates		Chem.-Eur. J.	85	Mulvey, RE	FALSE	FALSE	FALSE	FALSE
2179	10.1039/c8sc01538d	doi.org/10.1039/c8sc01538d	Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes		Chem. Sci.	85	Mazet, C	FALSE	FALSE	FALSE	FALSE
2180	10.1021/acs.organomet.7b00651	doi.org/10.1021/acs.organomet.7b00651	Counteranion-Controlled Ag2O-Mediated Benzimidazolium Ring Opening and Its Application in the Synthesis of Palladium Pincer-Type Complexes		Organometallics	85	Liu, N; Dai, B	FALSE	FALSE	FALSE	FALSE
2181	10.1021/acs.organomet.7b00632	doi.org/10.1021/acs.organomet.7b00632	Mild sp(2)Carbon-Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory		Organometallics	85	Crimmin, MR	FALSE	FALSE	FALSE	FALSE
2182	10.1039/c6ob01171c	doi.org/10.1039/c6ob01171c	A practical oxidative C-H functionalization of N-carbamoyl tetrahydro-beta-carbolines with diverse potassium trifluoroborates		Org. Biomol. Chem.	85	Liu, L	FALSE	FALSE	FALSE	FALSE
2183	10.1021/acs.orglett.5b01701	doi.org/10.1021/acs.orglett.5b01701	Cobalt(III)-Catalyzed Directed C-H Allylation		Org. Lett.	85	Glorius, F	FALSE	FALSE	FALSE	FALSE
2184	10.1246/bcsj.20140387	doi.org/10.1246/bcsj.20140387	The Nickel(II)-Catalyzed Direct Benzylation, Allylation, Alkylation, and Methylation of C-H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as the Directing Group		Bull. Chem. Soc. Jpn.	85	Chatani, N	FALSE	FALSE	FALSE	FALSE
2185	10.1002/chem.201404618	doi.org/10.1002/chem.201404618	Experimental and Theoretical Approaches to the Influence of the Addition of Pyrene to a Series of Pd and Ni NHC-Based Complexes: Catalytic Consequences		Chem.-Eur. J.	85	Poyatos, M	FALSE	FALSE	FALSE	FALSE
2186	10.1021/jo502485u	doi.org/10.1021/jo502485u	alpha-Allenyl Ethers as Starting Materials for Palladium Catalyzed Suzuki Miyaura Couplings of Allenylphosphine Oxides with Arylboronic Acids		J. Org. Chem.	85	Wu, L	FALSE	FALSE	FALSE	FALSE
2187	10.1021/jo501665e	doi.org/10.1021/jo501665e	Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation		J. Org. Chem.	85	Blanchet, J	FALSE	FALSE	FALSE	FALSE
2188	10.1021/jo500840s	doi.org/10.1021/jo500840s	[Bmim]PF6-Promoted Ligandless Suzuki-Miyaura Coupling Reaction of Potassium Aryltrifluoroborates in Water		J. Org. Chem.	85	Liu, LF	FALSE	FALSE	FALSE	FALSE
2189	10.1002/cjoc.201400015	doi.org/10.1002/cjoc.201400015	Accurate Prediction of Ir-H Bond Dissociation Enthalpies by Density Functional Theory Methods		Chin. J. Chem.	85	Yu, HZ	FALSE	FALSE	FALSE	FALSE
2190	10.1039/c3ob42088d	doi.org/10.1039/c3ob42088d	Selective synthesis of indazoles and indoles via triazene-alkyne cyclization switched by different metals		Org. Biomol. Chem.	85	Yu, HZ	FALSE	FALSE	FALSE	FALSE
2191	10.1039/c3ra45178j	doi.org/10.1039/c3ra45178j	Transformations of X (C, O, N)-CN bonds: cases of selective X (C, O, N)-C activation		RSC Adv.	85	Wang, R	FALSE	FALSE	FALSE	FALSE
2192	10.1039/c4qo00097h	doi.org/10.1039/c4qo00097h	Palladium-catalyzed direct C-H allylation of arenes without directing groups		Org. Chem. Front.	85	Ying, CH	FALSE	FALSE	FALSE	FALSE
2193	10.1021/ol402494e	doi.org/10.1021/ol402494e	Palladium-Catalyzed sp(2) and sp(3) C-H Bond Activation and Addition to Isatin toward 3-Hydroxy-2-oxindoles		Org. Lett.	85	Yang, SD	FALSE	FALSE	FALSE	FALSE
2194	10.1016/j.jorganchem.2013.05.006	doi.org/10.1016/j.jorganchem.2013.05.006	Structural influences on the electrochemistry of 1,1 '-di(hydroxyalkyl) ferrocenes. Structure of [Fe{eta(5)-C5H4-CH(OH)-(CH2)(3)OH}(2)]		J. Organomet. Chem.	85	Swarts, JC	FALSE	FALSE	FALSE	FALSE
2195	10.1021/om400370v	doi.org/10.1021/om400370v	Mechanistic Study of Palladium-Catalyzed Chemoselective C(sp(3))-H Activation of Carbamoyl Chloride		Organometallics	85	Fu, Y	FALSE	FALSE	FALSE	FALSE
2196	10.1016/j.tet.2011.07.048	doi.org/10.1016/j.tet.2011.07.048	Rapid access to 4-substituted-pyrones and 2(5H)-furanones via a palladium-catalyzed C-OH bond activation		Tetrahedron	85	Peng, YY	FALSE	FALSE	FALSE	FALSE
2197	10.1039/c0dt01211d	doi.org/10.1039/c0dt01211d	Heterobimetallic complexes containing an N-heterocyclic carbene based multidentate ligand and catalyzed tandem click/Sonogashira reactions		Dalton Trans.	85	Chen, WZ	FALSE	FALSE	FALSE	FALSE
2198	10.1055/s-0030-1258116	doi.org/10.1055/s-0030-1258116	Transition-Metal-Catalyzed Cross-Couplings of Aryl Tosylates or Mesylates with Organoindium Reagents		Synlett	85	Wu, J	FALSE	FALSE	FALSE	FALSE
2199	10.1016/j.tetlet.2009.12.033	doi.org/10.1016/j.tetlet.2009.12.033	Ni(COD)(2)/4-ClC6H4COR-catalyzed addition reactions of arylboroxines with aldehydes		Tetrahedron Lett.	85	Hu, QS	FALSE	FALSE	FALSE	FALSE
2200	10.1002/anie.200804146	doi.org/10.1002/anie.200804146	Modular Approach to Silicon-Bridged Biaryls: Palladium-Catalyzed Intramolecular Coupling of 2-(Arylsilyl)aryl Triflates		Angew. Chem.-Int. Edit.	85	Shimizu, M	FALSE	FALSE	FALSE	FALSE
2201	10.5059/yukigoseikyokaishi.63.312	doi.org/10.5059/yukigoseikyokaishi.63.312	Recent developments of biaryl synthesis via cross-coupling reactions of areneboronic acid derivatives		J. Synth. Org. Chem. Jpn.	85	Suzuki, A	FALSE	FALSE	FALSE	FALSE
2202	10.5059/yukigoseikyokaishi.62.314	doi.org/10.5059/yukigoseikyokaishi.62.314	Carbon-carbon bond formations using acylzirconocene chloride complexes as a donor of nucleophilic acyl group		J. Synth. Org. Chem. Jpn.	85	Hanzawa, Y	FALSE	FALSE	FALSE	FALSE
2203	10.1055/s-0041-1737762	doi.org/10.1055/s-0041-1737762	Nickel-Catalyzed Reductive Cross-Coupling of Benzylic Sulfonium Salts with Aryl Iodides		Synlett	85	Wu, F	FALSE	FALSE	FALSE	FALSE
2204	10.1021/acsomega.1c06430	doi.org/10.1021/acsomega.1c06430	Bulky Di(1-adamantyl)phosphinous Acid-Ligated Pd(II) Precatalysts for Suzuki Reactions of Unreactive Aryl Chlorides		ACS Omega	85	Chang, YC	FALSE	FALSE	FALSE	FALSE
2205	10.1002/cssc.202101924	doi.org/10.1002/cssc.202101924	Electrochemical Reductive Arylation of Nitroarenes with Arylboronic Acids		ChemSusChem	85	Yi, H; Lei, AW	FALSE	TRUE	FALSE	FALSE
2206	10.1039/d1cc05257h	doi.org/10.1039/d1cc05257h	Nickel-catalyzed enantioselective umpolung hydrogenation for stereoselective synthesis of beta-amido esters		Chem. Commun.	85	Zhou, JS	FALSE	FALSE	FALSE	FALSE
2207	10.6023/cjoc202102025	doi.org/10.6023/cjoc202102025	t-BuOK-Mediated Reductive Desulfonylation/Dehydrogenation for the Synthesis of 2-Substituted 1,3-Dienes and Their [4+2] Cycloaddition Reactions		Chin. J. Org. Chem.	85	Miao, T; Wang, L	FALSE	FALSE	FALSE	FALSE
2208	10.1021/acs.accounts.1c00075	doi.org/10.1021/acs.accounts.1c00075	Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations		Accounts Chem. Res.	85	Qi, XT; Lan, Y	FALSE	FALSE	FALSE	FALSE
2209	10.1021/acs.joc.1c00577	doi.org/10.1021/acs.joc.1c00577	Nickelocene as an Air- and Moisture-Tolerant Precatalyst in the Regioselective Synthesis of Multisubstituted Pyridines		J. Org. Chem.	85	Hong, SY	FALSE	FALSE	FALSE	FALSE
2210	10.1002/ejic.202100148	doi.org/10.1002/ejic.202100148	Stereoelectronic Characterization and Catalytic Potential of a 1,3-Bis(2,6-terphenyl)-Substituted N-Heterocyclic Carbene		Eur. J. Inorg. Chem.	85	McKay, AI	FALSE	FALSE	FALSE	FALSE
2211	10.6023/cjoc202009048	doi.org/10.6023/cjoc202009048	Transamidation of N-Benzyl-N-Boc-amides under Transition Metal-Free and Base-Free Conditions		Chin. J. Org. Chem.	85	Lei, CAH	FALSE	FALSE	FALSE	FALSE
2212	10.1039/d0nj05711h	doi.org/10.1039/d0nj05711h	A post-synthetically modified metal-organic framework for copper catalyzed denitrative C-N coupling of nitroarenes under heterogeneous conditions		New J. Chem.	85	Koner, S	FALSE	FALSE	FALSE	FALSE
2213	10.1248/cpb.c17-00487	doi.org/10.1248/cpb.c17-00487	Ethereal C O Bond Cleavage Mediated by Ni(0)-Ate Complex: A DFT Study		Chem. Pharm. Bull.	85	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
2214	10.1002/slct.201700580	doi.org/10.1002/slct.201700580	Agro-Waste Extract Based Solvents: Emergence of Novel Green Solvent for the Design of Sustainable Processes in Catalysis and Organic Chemistry		ChemistrySelect	85	Mondal, M; Bora, U	FALSE	FALSE	FALSE	FALSE
2215	10.1002/chem.201603124	doi.org/10.1002/chem.201603124	Progress in Enantioselective Radical Cyclizations		Chem.-Eur. J.	85	Miyabe, H	FALSE	FALSE	FALSE	FALSE
2216	10.1002/ajoc.201600535	doi.org/10.1002/ajoc.201600535	Selective C(sp(2))-H Functionalization of Arenes for Amination Reactions by Using Photoredox Catalysis		Asian J. Org. Chem.	85	Pandey, G	TRUE	FALSE	FALSE	FALSE
2217	10.1021/acs.orglett.6b02656	doi.org/10.1021/acs.orglett.6b02656	Practical Cross-Coupling between O-Based Electrophiles and Aryl Bromides via Ni Catalysis		Org. Lett.	85	Shi, ZJ	FALSE	TRUE	FALSE	FALSE
2218	10.1039/c5nj02227d	doi.org/10.1039/c5nj02227d	Immobilized Pd(0) nanoparticles on phosphine-functionalized graphene as a highly active catalyst for Heck, Suzuki and N-arylation reactions		New J. Chem.	85	Fareghi-Alamdari, R	FALSE	FALSE	FALSE	FALSE
2219	10.1016/j.ica.2020.120191	doi.org/10.1016/j.ica.2020.120191	Ni(II) complexes of tripodal N4 ligands as catalysts for alkane hydroxylation and O-arylation of phenol: Structural and reactivity effects induced by fluoro substitution	The electrochemical synthesis of pyrazolidine-3,5-diones and benzoxazoles by N-N bond formation and C,O linkage, respectively, represents an easy access to medicinally relevant structures. Electrochemistry as a key technology ensures a safe and sustainable approach. We gained insights in the mechanism of these reactions by combining cyclovoltammetric and synthetic studies. The electron-transfer behavior of anilides and dianilides was studied and led to the following conclusion: The N N bond formation involves a diradical as intermediate, whereas the benzoxazole formation is based on a cationic mechanism. Besides these studies, we developed a synthetic route to mixed dianilides as starting materials for the N N coupling. The compatibility with valuable functionalities like triflates and mesylates for follow-up reactions as well as the comparison of different electrochemical setups also enhanced the applicability of this method.	Inorg. Chim. Acta	84	Kumar, S	FALSE	FALSE	FALSE	FALSE
2220	10.1021/acs.chemrev.0c00157	doi.org/10.1021/acs.chemrev.0c00157	Carbon-Carbon Bond Cleavage at Allylic Positions: Retro-allylation and Deallylation	We report an efficient means of sp(2)-sp(3) cross coupling for a variety of terminal monosubstituted olefins with aryl electrophiles using Pd and CuH catalysis. In addition to its applicability to a range of aryl bromide substrates, this process was also suitable for electron-deficient aryl chlorides, furnishing higher yields than the corresponding aryl bromides in these cases. The optimized protocol does not require the use of a glovebox and employs air-stable Cu and Pd complexes as precatalysts. A reaction on 10 mmol scale further highlighted the practical utility of this protocol. Employing a similar protocol, a series of cyclic alkenes were also examined. Cyclopentene was shown to undergo efficient coupling under these conditions. Lastly, deuterium-labeling studies indicate that deuterium scrambling does not take place in this sp(2)-sp(3) cross coupling, implying that beta-hydride elimination is not a significant process in this transformation.	Chem. Rev.	84	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
2221	10.1016/j.mcat.2020.111366	doi.org/10.1016/j.mcat.2020.111366	Pd-catalyzed oxidative homocoupling of arylboronic acids in WEPA: A sustainable access to symmetrical biaryls under added base and ligand-free ambient conditions	We report a C-F reductive elimination from a characterized first-row aryl metal fluoride complex. Reductive elimination from the presented nickel(III) complexes is faster than C-F bond formation from any other characterized aryl metal fluoride complex.	Mol. Catal.	84	Venkateswarlu, K	FALSE	FALSE	FALSE	FALSE
2222	10.1021/acs.orglett.0c03947	doi.org/10.1021/acs.orglett.0c03947	Chiral Phosphoric Acid-Catalyzed Enantioselective Construction of 2,3-Disubstituted Indolines	C-C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its potency to generate similar organometallic intermediates after decarboxylation. This Review provides an overview on the most recent progress in the field of C-C bond formation involving decarboxylation as a key step. Different important developments, which are not included in earlier Reviews in this area, have been summarized with representative examples and discussions on their reaction mechanisms.	Org. Lett.	84	Masson, G	FALSE	FALSE	FALSE	FALSE
2223	10.1039/d0cy01679a	doi.org/10.1039/d0cy01679a	Phosphine-free pincer-ruthenium catalyzed biofuel production: high rates, yields and turnovers of solventless alcohol alkylation	Nine Ni(II)-NHC complexes of the type [CpNiBr(NHC)], each containing either a symmetric or asymmetric alkyl/benzyl/phenylethyl imidazolium ligand, effectively catalysed the anaerobic oxidation of a series of secondary alcohols, including 1-phenylethanol to yield acetophenone. Catalytic reactions performed using (KOBu)-Bu-t as a mild base and 1,2-dibromobenzene as both oxidant and solvent cleanly converted secondary alcohols to their corresponding ketones in high yield using conventional heating, and almost quantitatively using microwave heating. Catalytic activity of the nine [CpNiBr(NHC)] complexes were evaluated separately under optimized conditions, where the more electron-donating NHC-bearing Ni complexes (1, 2, and 5) proved to be more efficient than the electron-witdrawing NHC ligand analogues (6, 8, and 9). Substrate screening studies revealed that secondary alcohols bearing electron-withdrawing functional groups were less efficiently oxidized. Catalyst concentration optimization studies were aimed at finding a catalyst concentration to limit the effects of catalyst deactivation, while also maintaining reasonable TONs. Additional characterization of selected Ni(II) complexes have been included, comprising three single crystal X-ray structure determinations, and a DFT study on the mechanistic reaction pathways of the alcohol oxidation reaction as well as alpha-ketone arylation, a potential secondary competitive catalytic reaction. (C) 2017 Elsevier B.V. All rights reserved.	Catal. Sci. Technol.	84	Kumar, A	FALSE	FALSE	FALSE	FALSE
2224	10.1039/d0dt02937h	doi.org/10.1039/d0dt02937h	C-C coupling formation using nitron complexes	A Pd-catalyzed enantioselective C-H arylation of phosphinamides with aryl boronic acids is presented. With readily affordable amino acid derivatives as chiral ligands, the reaction proceeded efficiently to afford the P-stereogenic phosphinamides in up to 75% yield and with 99% ee under mild conditions. Most importantly, the reaction could be performed on a large scale for various substrates. This method provides an alternative and reliable way for accessing P-stereogenic phosphinamides. (C) 2017 Elsevier Ltd. All rights reserved.	Dalton Trans.	84	Turkmen, H	FALSE	FALSE	FALSE	FALSE
2225	10.1002/adsc.202000985	doi.org/10.1002/adsc.202000985	Nickel-Catalyzed Direct Trifluoroethylation of Aryl Iodides with 1,1,1-Trifluoro-2-Iodoethane via Reductive Coupling	A novel and efficient Fe-catalyzed direct C-H amination (NH2) of arenes is reported using a new redox-active aminating reagent. The reaction is simple, and can be performed under air, mild, and redox-neutral conditions. This protocol has a broad substrate scope and could be used in the late-stage modification of bioactive compounds. Mechanistic studies demonstrate that a radical pathway could be involved in this transformation.	Adv. Synth. Catal.	84	Wang, XS	FALSE	FALSE	FALSE	FALSE
2226	10.1055/s-0040-1707356	doi.org/10.1055/s-0040-1707356	Palladium-Catalyzed Cross-Coupling Reactions of 4-Tosyl-oxyquinazolines with Indoles: An Efficient Approach to 4-(1H-Indol-1-yl)quinazolines	Stereoselective allyl isomerization and regiospecific allyl arylation reactions of allylarenes with a catalytic system comprising nickel(II) with an aryl Grignard reagent were studied. Both reactions are triggered by allylic internal C(sp(2))-H activation by in-situ-formed Ni-0, which is inserted into the C-H bond at the 2-position of the allyl moiety without a directing group. The isomerization of allylarene to 1-propenylarene favors the E isomer and proceeds with quantitative conversion. The arylation takes place through oxidative cross-coupling of allylarenes with excess Grignard reagent. It occurs regiospecifically at the position of C(sp(2))-H activation and represents a new method for the synthesis of 1,1-disubstituted olefins. The results of deuterium labeling experiments reveal an alkenyl/alkyl mechanism involving allylic internal C(sp(2))-H activation and multiple intermolecular 1,2-, 1,3-, and 2,3-hydride shifts. These methods represent new approaches to the functionalization of olefins, and the mechanistic investigations could be helpful for the discovery and design of new strategies for olefin functionalization.	Synthesis	84	Peng, YY	FALSE	FALSE	FALSE	FALSE
2227	10.1021/jacs.0c05254	doi.org/10.1021/jacs.0c05254	Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling	Highly enantioselective, copper-catalyzed ring opening of bicyclic hydrazines using a diboron reagent was accomplished with (R,R)-taniaphos as a chiral ligand. Desymmetrization of various bicyclic hydrazines by boryl substitution afforded 3-Bpin-4-hydrazino-cyclopentene derivatives with enantioselectivity up to >99% under mild conditions. The resulting allylic boron products were utilized in further organic transformations. Kinetic resolution of a racemic bicyclic oxazine gave useful information about the relative rates of C-O and C-N bond cleavage.	J. Am. Chem. Soc.	84	Nevado, C	FALSE	FALSE	FALSE	FALSE
2228	10.1021/acs.inorgchem.0c01115	doi.org/10.1021/acs.inorgchem.0c01115	Phosphorus Analogues of [Ni(bpy)(2)]: Synthesis and Application in Carbon-Halogen Bond Activation	A robust copper-catalyzed or transition-metal-free cross-coupling of gem-difluoroalkenes with tertiary, secondary, and primary alkyl Grignard reagents has been developed. Remarkably, the tertiary and secondary alkylation of gem-difluoroalkenes proceeded very smoothly in the presence of 2S mol % of CuCN or under transition-metal-free conditions, affording the tertiary and secondary alkyl-substituted fluoroalkenes in good to excellent yields with excellent Z stereoselectivity.	Inorg. Chem.	84	Wolf, R	FALSE	FALSE	FALSE	FALSE
2229	10.1002/anie.202006322	doi.org/10.1002/anie.202006322	Nickel-Catalyzed Allylmethylation of Alkynes with Allylic Alcohols and AlMe3: Facile Access to Skipped Dienes and Trienes	Cross-electrophile coupling of aryl halides with alkyl halides has thus far been primarily conducted with stoichiometric metallic reductants in amide solvents. This report demonstrates that the use of tetrakis(dimethylamino) ethylene (TDAE) as an organic reductant enables the use of non-amide solvents, such as acetonitrile or propylene oxide, for the coupling of benzyl chlorides and alkyl iodides with aryl halides. Furthermore, these conditions work for several electron-poor heterocycles that are easily reduced by manganese. Finally, we demonstrate that TDAE addition can be used as a control element to 'hold' a reaction without diminishing yield or catalyst activity.	Angew. Chem.-Int. Edit.	84	Li, WF	FALSE	FALSE	FALSE	FALSE
2230	10.1039/d0sc01084g	doi.org/10.1039/d0sc01084g	General and selective synthesis of primary amines using Ni-based homogeneous catalysts	A visible-light-induced and copper-promoted perfluoroalkylation of benzamides was successfully developed under the assistance of an 8-aminoquinoline directing group. It provides a straightforward method for the synthesis of ortho-perfluoroalkyl-substituted benzoic acid derivatives. The reaction employs a cheap organic dye eosin Y as the photoredox catalyst and is run under the irradiation of a 26 W fluorescent LED light bulb.	Chem. Sci.	84	Jiao, H; Beller, M; Jagadeesh, RV	FALSE	FALSE	FALSE	FALSE
2231	10.1021/jacs.0c01475	doi.org/10.1021/jacs.0c01475	General C(sp(2))-C(sp(3)) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts	The [n]dendralenes are a family of acyclic hydrocarbons which, by virtue of their ability to rapidly generate structural complexity, have attracted significant recent synthetic attention. [3]Dendralene through [8]dendralene have been previously prepared but no higher member of the family has been reported to date. Here, we describe the first chemical syntheses of the higher dendralenes, [9]dendralene through [12]dendralene. We also report a detailed investigation into the spectroscopic properties and chemical reactivity of the complete family of fundamental hydrocarbons, [3]dendralene to [12]dendralene. These studies reveal the first case of diminishing alternation in behavior in a series of related structures. We also report a comprehensive series of computational studies, which trace this dampening oscillatory effect in both spectroscopic measurements and chemical reactivity to conformational preferences.	J. Am. Chem. Soc.	84	Sevov, CS	FALSE	TRUE	FALSE	FALSE
2232	10.1016/j.tet.2020.130925	doi.org/10.1016/j.tet.2020.130925	Metal-catalyzed C-H bond functionalization of phenol derivatives	Transition-metal-catalyzed C-H activation represents one of most attractive research fields in modern organic chemistry while theoretical studies have become a popular and effective tool for elucidating mechanism nowadays. The recent achievements in the cross field of the two orientations are reviewed in this article. The first part introduced the advances in theoretical study on transition-metal-catalyzed C-H activation. The elegant work reported mainly in and after 2013, classified according to the mechanisms of C-H activation, were covered. The second part provided an analysis on the distribution of quantum-chemical methods, solvation models and basis sets in the collected theoretical studies.	Tetrahedron	84	Al Mamari, HH	FALSE	FALSE	FALSE	FALSE
2233	10.1002/anie.201915790	doi.org/10.1002/anie.201915790	A Neutral and Aromatic Boron-Rich Inorganic Benzene	While in the early days of palladium-catalyzed allylic alkylations mainly stabilized carbanions, such as malonates, have been used as standard nucleophiles, during the last 10-15 years also non stabilized enolates became more and more popular. Efficient protocols have been developed allowing their highly regio- as well as stereoselective allylations. In addition, catalysts based on other transition metals enlarge the synthetic potential of these valuable transformations, since each metal (complex) shows its own, typical reaction behaviour. This review will cover the new developments in this fast developing field.	Angew. Chem.-Int. Edit.	84	Kinjo, R	FALSE	FALSE	FALSE	FALSE
2234	10.1002/anie.201913281	doi.org/10.1002/anie.201913281	Rhodium-Catalyzed Remote C(sp(3))-H Borylation of Silyl Enol Ethers		Angew. Chem.-Int. Edit.	84	Zhao, WX	FALSE	FALSE	FALSE	FALSE
2235	10.1021/acscatal.9b03172	doi.org/10.1021/acscatal.9b03172	Nickel-Catalyzed Enantioselective Reductive Aryl Fluoroalkenylation of Alkenes		ACS Catal.	84	Kong, WQ	FALSE	FALSE	FALSE	FALSE
2236	10.1002/anie.201904156	doi.org/10.1002/anie.201904156	Iridium-Catalyzed Asymmetric Allylic Aromatization Reaction		Angew. Chem.-Int. Edit.	84	You, SL	FALSE	FALSE	FALSE	FALSE
2237	10.1039/c9cy00938h	doi.org/10.1039/c9cy00938h	Metal-catalysed radical carbonylation reactions		Catal. Sci. Technol.	84	Mankad, NP	FALSE	FALSE	FALSE	FALSE
2238	10.1021/acs.orglett.9b01373	doi.org/10.1021/acs.orglett.9b01373	Copper(I)-Catalyzed Intramolecular Asymmetric Double C-Arylation for the Formation of Chiral Spirocyclic Bis-oxindoles		Org. Lett.	84	Zhou, GX; Cai, Q	FALSE	FALSE	FALSE	FALSE
2239	10.1016/j.tet.2018.11.073	doi.org/10.1016/j.tet.2018.11.073	A simple, direct synthesis of 3-vinylindoles from the carbocation-catalysed dehydrative cross-coupling of ketones and indoles. A combined experimental and computational study		Tetrahedron	84	Barbero, M; Ghigo, G	FALSE	FALSE	FALSE	FALSE
2240	10.1039/c8nj05288c	doi.org/10.1039/c8nj05288c	Vilsmeier-Haack reagent mediated synthetic transformations with an immobilized iridium complex photoredox catalyst		New J. Chem.	84	Shen, YM	FALSE	FALSE	FALSE	FALSE
2241	10.1021/acs.organomet.8b00723	doi.org/10.1021/acs.organomet.8b00723	Stepwise versus Concerted Reductive Elimination Mechanisms in the Carbon-Iodide Bond Formation of (DPEphos)RhMeI2 Complex		Organometallics	84	Hong, X	FALSE	FALSE	FALSE	FALSE
2242	10.1002/adsc.201800783	doi.org/10.1002/adsc.201800783	Mild Access to N-Formylation of Primary Amines using Ethers as C1 Synthons under Metal-Free Conditions		Adv. Synth. Catal.	84	Wang, JJ	FALSE	FALSE	FALSE	FALSE
2243	10.1021/jacs.8b08190	doi.org/10.1021/jacs.8b08190	Ni-Catalyzed Enantioselective Reductive Diarylation of Activated Alkenes by Domino Cyclization/Cross-Coupling		J. Am. Chem. Soc.	84	Kong, WQ	FALSE	FALSE	FALSE	FALSE
2244	10.1016/j.jfluchem.2018.07.008	doi.org/10.1016/j.jfluchem.2018.07.008	Recent advances towards sulfur (VI) fluoride exchange (SuFEx) click chemistry		J. Fluor. Chem.	84	Fattah, TA; Saeed, A	FALSE	FALSE	FALSE	FALSE
2245	10.1016/j.jorganchem.2018.02.030	doi.org/10.1016/j.jorganchem.2018.02.030	A sustainable heterogenized palladium catalyst for Suzuki-Miyaura cross coupling reaction of azaheteroaryl halides in aqueous media		J. Organomet. Chem.	84	Karvembu, R	FALSE	FALSE	FALSE	FALSE
2246	10.1002/ejoc.201701143	doi.org/10.1002/ejoc.201701143	Directed ortho-Metalation of Aryl Amides, O-Carbamates, and Methoxymethoxy Systems: Directed Metalation Group Competition and Cooperation		Eur. J. Org. Chem.	84	Miah, MAJ; Snieckus, V	FALSE	FALSE	FALSE	FALSE
2247	10.1021/acs.orglett.7b03669	doi.org/10.1021/acs.orglett.7b03669	Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters		Org. Lett.	84	Rueping, M	FALSE	FALSE	FALSE	FALSE
2248	10.1021/acssuschemeng.7b02739	doi.org/10.1021/acssuschemeng.7b02739	Magnetically Recoverable Heterobimetallic Co2Mn3O8: Selective and Sustainable Oxidation and Reduction Reactions		ACS Sustain. Chem. Eng.	84	Pratihar, S	FALSE	FALSE	FALSE	FALSE
2249	10.1016/j.jorganchem.2015.04.017	doi.org/10.1016/j.jorganchem.2015.04.017	Synthesis of arylboronates by boron-induced ipso-deantimonation of triarylstibanes with boron trihalides and its application in one-pot two-step transmetallation/cross-coupling reactions		J. Organomet. Chem.	84	Yasuike, S	FALSE	FALSE	FALSE	FALSE
2250	10.1021/acs.inorgchem.5b00893	doi.org/10.1021/acs.inorgchem.5b00893	From Stiba- and Bismaheteroboroxines to N,C,N-Chelated Diorganoantimony(III) and Bismuth(III) Cations-An Unexpected Case of Aryl Group Migration		Inorg. Chem.	84	Dostal, L	FALSE	FALSE	FALSE	FALSE
2251	10.1002/adsc.201500030	doi.org/10.1002/adsc.201500030	C-N Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor		Adv. Synth. Catal.	84	Belderrain, TR	FALSE	FALSE	FALSE	FALSE
2252	10.1021/ja511730k	doi.org/10.1021/ja511730k	Synthesis, Characterization, and Unique Catalytic Activities of a Fluorinated Nickel Enolate		J. Am. Chem. Soc.	84	Ohashi, M	FALSE	FALSE	FALSE	FALSE
2253	10.1002/chem.201402825	doi.org/10.1002/chem.201402825	[(p-Cymene) RuCl2](2): An Efficient Catalyst for Highly Regioselective Allylic Alkylations of Chelated Amino Acid Ester Enolates		Chem.-Eur. J.	84	Kazmaier, U	FALSE	FALSE	FALSE	FALSE
2254	10.1039/c4dt00815d	doi.org/10.1039/c4dt00815d	Palladium dichloride adduct of N,N-bis-(diphenylphosphanylmethyl)-2-aminopyridine: synthesis, structure and catalytic performance in the decarboxylative cross-coupling of 4-picolinic acid with aryl bromide		Dalton Trans.	84	Ren, ZG	FALSE	FALSE	FALSE	FALSE
2255	10.1021/ol403028a	doi.org/10.1021/ol403028a	Pd(II)-Catalyzed C(sp(2))-H Hydroxylation with R-2(O)P-Coordinating Group		Org. Lett.	84	Yang, SD	FALSE	FALSE	FALSE	FALSE
2256	10.1002/adsc.201201022	doi.org/10.1002/adsc.201201022	Copper-Catalyzed C-Arylation and Denitrogenation of Tetrazoles: Domino Synthesis of 1,3-Diaminoisoquinoline Derivatives		Adv. Synth. Catal.	84	Fu, H	FALSE	FALSE	FALSE	FALSE
2257	10.1016/j.apcata.2012.09.048	doi.org/10.1016/j.apcata.2012.09.048	Superb efficient and recycle polymer-anchored systems for palladium catalyzed Suzuki cross-coupling reactions in water		Appl. Catal. A-Gen.	84	Temel, H	FALSE	FALSE	FALSE	FALSE
2258	10.1021/ic2027219	doi.org/10.1021/ic2027219	Experimental Fingerprints for Redox-Active Terpyridine in [Cr(tpy)(2)] (PF6)(n) (n=3-0), and the Remarkable Electronic Structure of [Cr(tpy)(2)](1-)		Inorg. Chem.	84	Sproules, S	FALSE	TRUE	FALSE	FALSE
2259	10.1021/om2005904	doi.org/10.1021/om2005904	Iron-Catalyzed Cross-Coupling Reactions between Arylzinc Reagents and Alkyl Halides Bearing beta-Fluorines		Organometallics	84	Qing, FL	FALSE	FALSE	FALSE	FALSE
2260	10.1021/jo201339z	doi.org/10.1021/jo201339z	Cyclization Reaction for the Synthesis of Polysubstituted Naphthalenes in the Presence of Au(I) Precatalysts		J. Org. Chem.	84	Youn, SW	FALSE	FALSE	FALSE	FALSE
2261	10.1021/jo1022052	doi.org/10.1021/jo1022052	Transition-Metal-Free O-, S-, and N-Arylation of Alcohols, Thiols, Amides, Amines, and Related Heterocycles		J. Org. Chem.	84	Ramon, DJ	FALSE	FALSE	FALSE	FALSE
2262	10.1016/j.jorganchem.2010.08.047	doi.org/10.1016/j.jorganchem.2010.08.047	Nickel-catalyzed, base-mediated amination/hydroamination reaction sequence for a modular synthesis of indoles		J. Organomet. Chem.	84	Ackermann, L	FALSE	FALSE	FALSE	FALSE
2263	10.1016/j.jorganchem.2008.08.008	doi.org/10.1016/j.jorganchem.2008.08.008	Towards asymmetric Au-catalyzed hydroxy- and alkoxycyclization of 1,6-enynes		J. Organomet. Chem.	84	Michelet, V	FALSE	FALSE	FALSE	FALSE
2264	10.1016/j.jorganchem.2006.02.042	doi.org/10.1016/j.jorganchem.2006.02.042	Development of an amphiphilic resin-dispersion of nanopalladium catalyst: Design, preparation, and its use in aquacatalytic hydrodechlorination and aerobic oxidation		J. Organomet. Chem.	84	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
2265	10.1021/ja980222l	doi.org/10.1021/ja980222l	The stereochemical dichotomy in palladium(0)- and nickel(0)-catalyzed allylic substitution		J. Am. Chem. Soc.	84	Kocovsky, P	FALSE	FALSE	FALSE	FALSE
2266	10.1021/jo970362y	doi.org/10.1021/jo970362y	Rapid fluorous Stille coupling reactions conducted under microwave irradiation		J. Org. Chem.	84		FALSE	FALSE	FALSE	FALSE
2267	10.1021/ma00124a005	doi.org/10.1021/ma00124a005	SYNTHESIS OF FUNCTIONAL POLYPHENYLENES FROM SUBSTITUTED HYDROQUINONES VIA NICKEL(0)-CATALYZED POLYMERIZATION OF THEIR BISMESYLATES		Macromolecules	84	PERCEC, V	FALSE	FALSE	FALSE	FALSE
2268	10.1002/adsc.202101469	doi.org/10.1002/adsc.202101469	Gold-Catalyzed Reaction of Anthranils with Alkynyl Sulfones for the Regioselective Formation of 3-Hydroxyquinolines		Adv. Synth. Catal.	84	Wu, YF	FALSE	FALSE	FALSE	FALSE
2269	10.1021/acs.joc.1c02580	doi.org/10.1021/acs.joc.1c02580	<p>Pd-Catalyzed Coupling of N-Tosylhydrazones with Benzylic Phosphates: Toward the Synthesis of Di- or Tri-Substituted Alkenes</p>		J. Org. Chem.	84	Tran, C; Hamze, A	FALSE	FALSE	FALSE	FALSE
2270	10.1002/anie.202114556	doi.org/10.1002/anie.202114556	Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis		Angew. Chem.-Int. Edit.	84	Shu, XZ	FALSE	FALSE	FALSE	FALSE
2271	10.1002/cctc.202101013	doi.org/10.1002/cctc.202101013	Stable Pd(0) Complexes with Ferrocene Bisphosphanes Bearing Phosphatrioxaadamantyl Substituents Efficiently Catalyze Selective C-H Arylation of Benzoxazoles by Aryl Chlorides		ChemCatChem	84	Stepnicka, P	FALSE	FALSE	FALSE	FALSE
2272	10.1021/acs.joc.1c00570	doi.org/10.1021/acs.joc.1c00570	Construction of gem-Difluoroenol Esters through Catalytic O-Selective Addition of Difluoroenoxysilanes to Ketenes		J. Org. Chem.	84	Pan, BW; Zhou, Y	FALSE	FALSE	FALSE	FALSE
2273	10.1016/j.ica.2021.120300	doi.org/10.1016/j.ica.2021.120300	Structural and catalytic properties of the [Ni(BIPHEP)X-2] complexes, BIPHEP=2,2-diphenylphosphino-1,1-biphenyl; X = Cl, Br		Inorg. Chim. Acta	84	Kyritsis, P	FALSE	FALSE	FALSE	FALSE
2274	10.1021/acs.joc.7b01566	doi.org/10.1021/acs.joc.7b01566	Synthesis of 3-Arylbenzofuran-2-ylphosphines via Rhodium Catalyzed Redox-Neutral C-H Activation and Their Applications in Palladium-Catalyzed Cross-Coupling of Aryl Chlorides		J. Org. Chem.	84	Li, B	FALSE	FALSE	FALSE	FALSE
2275	10.1039/c7qo00318h	doi.org/10.1039/c7qo00318h	Metal-free phosphonation of benzoxazoles and benzothiazoles under oxidative conditions		Org. Chem. Front.	84	Guo, SM; Cai, H	FALSE	FALSE	FALSE	FALSE
2276	10.1039/c7ob01337j	doi.org/10.1039/c7ob01337j	Synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids		Org. Biomol. Chem.	84	Zhang, XX; Rao, WD	FALSE	FALSE	FALSE	FALSE
2277	10.1002/anie.201603068	doi.org/10.1002/anie.201603068	Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C-N Bond Activation		Angew. Chem.-Int. Edit.	84	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
2278	10.1016/j.jorganchem.2016.03.027	doi.org/10.1016/j.jorganchem.2016.03.027	(Ferrocenylthienyl) phosphines: Synthesis, electrochemistry and their use in Suzuki-Miyaura C, C coupling		J. Organomet. Chem.	84	Lang, H	FALSE	FALSE	FALSE	FALSE
2279	10.1016/j.tet.2016.04.018	doi.org/10.1016/j.tet.2016.04.018	Synthesis of 1,1-diarylethylenes		Tetrahedron	84	Chang, MY	FALSE	FALSE	FALSE	FALSE
2280	10.1021/acs.organomet.6b00059	doi.org/10.1021/acs.organomet.6b00059	A Transmetalation Reaction Enables the Synthesis of [F-18]5-Fluorouracil from [F-18]Fluoride for Human PET Imaging		Organometallics	84	Ritter, T	FALSE	FALSE	FALSE	FALSE
2281	10.1039/c6ra11116e	doi.org/10.1039/c6ra11116e	Expedient access to unsymmetrical triarylmethanes through N-heterocyclic carbene catalysed 1,6-conjugate addition of 2-naphthols to para-quinone methides		RSC Adv.	84	Anand, RV	FALSE	FALSE	FALSE	FALSE
2282	10.1039/c6cc02412b	doi.org/10.1039/c6cc02412b	Highly mono-selective ortho-trifluoromethylation of benzamides via 8-aminoquinoline assisted Cu-promoted C-H activations		Chem. Commun.	84	Tan, Z	FALSE	FALSE	FALSE	FALSE
2283	10.2174/1570179418666210224124931	doi.org/10.2174/1570179418666210224124931	Applications of Nickel(II) Compounds in Organic Synthesis	An efficient solvent-free nickel-catalyzed method for C-H bond arylation of arenes and indoles has been developed, which proceeds expeditiously through chelation assistance. The reaction is highly selective for mono-arylation and tolerates sensitive and structurally diverse functionalities, such as halides, ethers, amines, indole, pyrrole and carbazole. This reaction represents the first example of a nickel-catalyzed C-H arylation by monochelate assistance and symbolizes a rare precedent in solvent-free C-H arylation. Mechanistic investigations by various controlled reactions, kinetic studies, and deuterium labeling experiments suggest that the arylation follows a single electron transfer (SET) pathway involving the turnover-limiting C-H nickelation process.	Curr. Org. Synth.	83	De, SK	FALSE	FALSE	FALSE	FALSE
2284	10.1021/acs.joc.9b01851	doi.org/10.1021/acs.joc.9b01851	C-N Bond Activation of N,N '-Dialkylacylhydrazines Mediated by beta-Fragmentation of Nitrogen-Centered Radical		J. Org. Chem.	83	Yuan, Y; Jia, XD	FALSE	FALSE	FALSE	FALSE
2285	10.1007/s11164-018-3671-y	doi.org/10.1007/s11164-018-3671-y	Ni-0 NPs anchored on acid-activated montmorillonite (Ni-0-Mont) as a highly efficient and reusable nanocatalyst for synthesis of biscoumarins and bisdimedones		Res. Chem. Intermed.	83	Zeynizadeh, B	FALSE	FALSE	FALSE	FALSE
2286	10.1021/jacs.8b11868	doi.org/10.1021/jacs.8b11868	Cyclometalated Iridium-PhanePhos Complexes Are Active Catalysts in Enantioselective Allene-Fluoral Reductive Coupling and Related Alcohol-Mediated Carbonyl Additions That Form Acyclic Quaternary Carbon Stereocenters		J. Am. Chem. Soc.	83	Krische, MJ	FALSE	FALSE	FALSE	FALSE
2287	10.1002/anie.201809889	doi.org/10.1002/anie.201809889	Nickel as a Lewis Base in a T-Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand		Angew. Chem.-Int. Edit.	83	Roesler, R	FALSE	FALSE	FALSE	FALSE
2288	10.1021/acs.organomet.8b00589	doi.org/10.1021/acs.organomet.8b00589	Modifications to the Aryl Group of dppf-Ligated Ni sigma-Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions		Organometallics	83	Hazari, N	FALSE	FALSE	FALSE	FALSE
2289	10.1021/jacs.8b08605	doi.org/10.1021/jacs.8b08605	Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors		J. Am. Chem. Soc.	83	Lin, S	FALSE	FALSE	FALSE	FALSE
2290	10.1039/c8qo00591e	doi.org/10.1039/c8qo00591e	One-pot transition-metal free transamidation to sterically hindered amides		Org. Chem. Front.	83	Zeng, Z	FALSE	FALSE	FALSE	FALSE
2291	10.1002/anie.201802434	doi.org/10.1002/anie.201802434	Metal-Catalyzed Remote Functionalization of omega-Ene Unsaturated Ethers: Towards Functionalized Vinyl Species		Angew. Chem.-Int. Edit.	83	Marek, I	FALSE	FALSE	FALSE	FALSE
2292	10.1002/chem.201800765	doi.org/10.1002/chem.201800765	Cooperative Iodide Pd(0)-Catalysed Coupling of Alkoxyallenes and N-Tosylhydrazones: A Selective Synthesis of Conjugated and Skipped Dienes		Chem.-Eur. J.	83	Deagostino, A	FALSE	FALSE	FALSE	FALSE
2293	10.1002/ajoc.201800002	doi.org/10.1002/ajoc.201800002	Copper-Catalyzed Direct C-H Bond Arylation of Benzoxazoles with Anilines		Asian J. Org. Chem.	83	Wang, CW	FALSE	FALSE	FALSE	FALSE
2294	10.1246/cl.171212	doi.org/10.1246/cl.171212	Copper-mediated Decarboxylative Coupling of Benzamides with Potassium Malonate Monoesters via Directed C-H Cleavage		Chem. Lett.	83	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
2295	10.1002/ajoc.201700446	doi.org/10.1002/ajoc.201700446	Nickel-Catalyzed C-H Heteroarylation of Chiral Oxazolines		Asian J. Org. Chem.	83	Lu, Z	FALSE	FALSE	FALSE	FALSE
2296	10.1021/acs.orglett.8b00114	doi.org/10.1021/acs.orglett.8b00114	Nickel-Catalyzed Desymmetrizing Cross-Electrophile Coupling of Cyclic Meso-Anhydrides		Org. Lett.	83	Mao, JY; Walsh, PJ	FALSE	TRUE	FALSE	FALSE
2297	10.1021/jacs.7b08579	doi.org/10.1021/jacs.7b08579	Low-Valent, High-Spin Chromium-Catalyzed Cleavage of Aromatic Carbon Nitrogen Bonds at Room Temperature: A Combined Experimental and Theoretical Study		J. Am. Chem. Soc.	83	Zeng, XM	FALSE	FALSE	FALSE	FALSE
2298	10.3762/bjoc.11.280	doi.org/10.3762/bjoc.11.280	Recent advances in copper-catalyzed asymmetric coupling reactions		Beilstein J. Org. Chem.	83	Zhou, FT	FALSE	FALSE	FALSE	FALSE
2299	10.1002/anie.201412319	doi.org/10.1002/anie.201412319	CH Alkenylations with Alkenyl Acetates, Phosphates, Carbonates, and Carbamates by Cobalt Catalysis at 23 degrees C		Angew. Chem.-Int. Edit.	83	Ackermann, L	FALSE	FALSE	FALSE	FALSE
2300	10.1002/anie.201411518	doi.org/10.1002/anie.201411518	Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings		Angew. Chem.-Int. Edit.	83	Tang, WJ	FALSE	FALSE	FALSE	FALSE
2301	10.1246/cl.141084	doi.org/10.1246/cl.141084	Rhodium-catalyzed Borylation of Aryl and Alkenyl Pivalates through the Cleavage of Carbon-Oxygen Bonds		Chem. Lett.	83	Tobisu, M	FALSE	FALSE	FALSE	FALSE
2302	10.1021/jo5024393	doi.org/10.1021/jo5024393	Transition-Metal-Free Synthesis of Carbazoles by Photostimulated Reactions of 2 '-Halo[1,1 '-biphenyI]-2-amines		J. Org. Chem.	83	Pierini, AB	TRUE	FALSE	FALSE	FALSE
2303	10.1016/j.poly.2014.07.018	doi.org/10.1016/j.poly.2014.07.018	Synthesis, spectral characterization and crystal structure of Ni(II) pyridoxal thiosemicarbazone complexes and their recyclable catalytic application in the nitroaldol (Henry) reaction in ionic liquid media		Polyhedron	83	Viswanathamurthi, P	FALSE	FALSE	FALSE	FALSE
2304	10.1039/c4ra10203g	doi.org/10.1039/c4ra10203g	C-N and C-P bond formation via cross dehydrative coupling reaction: an efficient synthesis of novel 3,4-dihydroquinazolines		RSC Adv.	83	Reddy, KR	FALSE	FALSE	FALSE	FALSE
2305	10.1021/jo402106q	doi.org/10.1021/jo402106q	Base-Promoted Formal Arylation of Benzo[d]oxazoles with Acyl Chloride		J. Org. Chem.	83	Cheng, J	FALSE	FALSE	FALSE	FALSE
2306	10.6023/cjoc201301020	doi.org/10.6023/cjoc201301020	Research and Progress in Chiral Binuclear Catalyst of First Row Transition Metal and Corresponding Nonlinear Effect		Chin. J. Org. Chem.	83	Zhu, YL	FALSE	FALSE	FALSE	FALSE
2307	10.1016/j.poly.2013.02.059	doi.org/10.1016/j.poly.2013.02.059	Intramolecular electronic communication in ferrocene-based beta-diketonato copper(II) complexes as observed by an electrochemical study		Polyhedron	83	Lang, H	FALSE	FALSE	FALSE	FALSE
2308	10.1021/ol4007162	doi.org/10.1021/ol4007162	One-Pot Synthesis of Diarylamines from Two Aromatic Amines via Oxidative Dearomatization-Imino Exchange-Reductive Aromatization		Org. Lett.	83	Wang, WB	FALSE	FALSE	FALSE	FALSE
2309	10.1002/adsc.201200364	doi.org/10.1002/adsc.201200364	Microwave-Promoted Suzuki-Miyaura Cross-Coupling of Aryl Imidazolylsulfonates in Water		Adv. Synth. Catal.	83	Alonso, DA	FALSE	FALSE	FALSE	FALSE
2310	10.1002/chem.201200305	doi.org/10.1002/chem.201200305	Phosphine-Mediated Domino Benzannulation Strategy for the Construction of Highly Functionalized Multiaryl Skeletons		Chem.-Eur. J.	83	Huang, Y	FALSE	FALSE	FALSE	FALSE
2311	10.1021/ar200055y	doi.org/10.1021/ar200055y	Organogold Reactivity with Palladium, Nickel, and Rhodium: Transmetalation, Cross-Coupling, and Dual Catalysis		Accounts Chem. Res.	83	Blum, SA	FALSE	FALSE	FALSE	FALSE
2312	10.1039/c1ob05597f	doi.org/10.1039/c1ob05597f	Nano-CuFe2O4 as a magnetically separable and reusable catalyst for the synthesis of diaryl/aryl alkyl sulfides via cross-coupling process under ligand-free conditions		Org. Biomol. Chem.	83	Nageswar, YVD	FALSE	FALSE	FALSE	FALSE
2313	10.1016/S0065-2725(10)09902-2	doi.org/10.1016/S0065-2725(10)09902-2	Heterocyclic BINAP Analogues		Adv. Heterocycl. Chem.	83	Arshad, N	FALSE	FALSE	FALSE	FALSE
2314	10.1246/bcsj.82.778	doi.org/10.1246/bcsj.82.778	Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective Organic Synthesis		Bull. Chem. Soc. Jpn.	83	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
2315	10.1039/d2sc00174h	doi.org/10.1039/d2sc00174h	A reactivity model for oxidative addition to palladium enables quantitative predictions for catalytic cross-coupling reactions		Chem. Sci.	83	Paci, I; Leitch, DC	FALSE	FALSE	FALSE	FALSE
2316	10.1039/d2sc00147k	doi.org/10.1039/d2sc00147k	Me-2(CH2 = CH)SiCN: a bifunctional ethylene equivalent for Diels-Alder reaction based controllable tandem synthesis		Chem. Sci.	83	Yu, JS	FALSE	FALSE	FALSE	FALSE
2317	10.1021/acscatal.1c02307	doi.org/10.1021/acscatal.1c02307	Nickel-Catalyzed Reductive Cross-Coupling of Heteroaryl Chlorides and Aryl Chlorides		ACS Catal.	83	Lautens, M	FALSE	FALSE	FALSE	FALSE
2318	10.1002/aoc.6430	doi.org/10.1002/aoc.6430	Advances in non-palladium-catalysed Stille couplings		Appl. Organomet. Chem.	83	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
2319	10.1021/jacs.1c07230	doi.org/10.1021/jacs.1c07230	Conversion of Primary Alcohols and Butadiene to Branched Ketones via Merged Transfer Hydrogenative Carbonyl Addition-Redox Isomerization Catalyzed by Rhodium		J. Am. Chem. Soc.	83	Krische, MJ	FALSE	FALSE	FALSE	FALSE
2320	10.1055/a-1503-6330	doi.org/10.1055/a-1503-6330	C-O-Selective Cross-Coupling of Chlorinated Phenol Derivatives		Synlett	83	Neufeldt, SR	FALSE	FALSE	FALSE	FALSE
2321	10.1021/acs.orglett.1c00626	doi.org/10.1021/acs.orglett.1c00626	Stereo- and Regioselective cis-Hydrophosphorylation of 1,3-Enynes Enabled by the Visible-Light Irradiation of NiCl2(PPh3)(2)		Org. Lett.	83	Hou, H; Zhu, SQ	FALSE	FALSE	FALSE	FALSE
2322	10.1002/adsc.201700654	doi.org/10.1002/adsc.201700654	Iron-Mediated Oxidative C-H Alkylation of S,S-Functionalized Internal Olefins via C(sp(2))-H/C(sp(3))-H Cross-Coupling		Adv. Synth. Catal.	83	Yu, ZK	FALSE	FALSE	FALSE	FALSE
2323	10.1021/jacs.6b12653	doi.org/10.1021/jacs.6b12653	Isolable and Readily Handled Halophosphonium Pre-reagents for Hydro- and Deuteriohalogenation		J. Am. Chem. Soc.	83	Snyder, SA	FALSE	FALSE	FALSE	FALSE
2324	10.1021/acs.organomet.7b00208	doi.org/10.1021/acs.organomet.7b00208	Oxidative Addition of Aryl Electrophiles to a Prototypical Nickel(0) Complex: Mechanism and Structure/Reactivity Relationships		Organometallics	83	Nelson, DJ	FALSE	TRUE	FALSE	FALSE
2325	10.1021/acs.joc.6b02595	doi.org/10.1021/acs.joc.6b02595	CuCl-Catalyzed Ullmann-Type C-N Cross-Coupling Reaction of Carbazoles and 2-Bromopyridine Derivatives		J. Org. Chem.	83	She, YB; Li, GJ	FALSE	FALSE	FALSE	FALSE
2326	10.1002/anie.201606513	doi.org/10.1002/anie.201606513	Nickel- and Photoredox-Catalyzed Cross-Coupling Reactions of Aryl Halides with 4-Alkyl-1,4-dihydropyridines as Formal Nucleophilic Alkylation Reagents		Angew. Chem.-Int. Edit.	83	Nishibayashi, Y	TRUE	FALSE	FALSE	FALSE
2327	10.1039/c5ra26182a	doi.org/10.1039/c5ra26182a	Polymeric beta-alanine incarcerated Pd(II) catalyzed allylic etherification in water: a mild and efficient method for the formation of C(sp(3))-O bonds		RSC Adv.	83	Islam, SM	FALSE	FALSE	FALSE	FALSE
2328	10.1016/j.ica.2021.120294	doi.org/10.1016/j.ica.2021.120294	Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions	A novel method of nucleophilic ring-opening of meso-epoxides with 4-aryl-NH-1,2,3-triazoles has been developed under metal-free conditions. The epoxide-ring opening process were carried out in the presence of organic bases (DABCO/Et3N) in acetonitrile at 85 degrees C to afford a regioisomeric mixture of trans-2-(4-aryl-2H-1,2,3-triazol-2yl) cycloalkanols (2,4-disubstituted triazoles) as major adducts and trans-2-(4-aryl-1H-1,2,3-triazol-1-yl)cycloalkanols (1,4-disubstituted triazoles) as minor adducts in excellent combined chemical yields (isolated yield up to 99%).	Inorg. Chim. Acta	82	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
2329	10.1021/jacs.0c08823	doi.org/10.1021/jacs.0c08823	General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis	An enantioselective iridium-catalyzed allylic substitution with a set of highly unstabilized nucleophiles generated in situ from 2-methylpyridines is described. Enantioen-riched 2-substituted pyridines,which are frequently encountered in natural products and pharmaceuticals, could be easily constructed by this simple method in good yields and excellent enantioselectivity. The synthetic utility of the pyridine products is demonstrated through the synthesis of a key intermediate of a reported Na+/H+ exchanger inhibitor and the total synthesis of (-)-lycopladine A.	J. Am. Chem. Soc.	82	Chu, LL	TRUE	FALSE	FALSE	FALSE
2330	10.1016/j.tet.2020.131648	doi.org/10.1016/j.tet.2020.131648	Isosterically designed chiral catalysts: Rationale, optimization and their application in enantioselective nucleophilic addition to aldehydes	Because diaryl ethers are present as an important motif in pharmaceuticals and natural products, extensive studies for the development of novel methods have been conducted. A conventional method for the construction of the diaryl ether moiety is the intermolecular cross-coupling reaction of aryl halides and phenols with a copper or palladium catalyst. We developed a catalytic decarbonylative etherification of aromatic esters using a palladium or nickel catalyst with our enabling diphosphine ligand to give the corresponding diaryl ethers. The present reaction can be conducted on grain scale in excellent yield. This reaction not only functions in an intramolecular setting but also allows for a crossetherification using other phenols.	Tetrahedron	82	Li, YM	FALSE	FALSE	FALSE	FALSE
2331	10.1021/acscatal.0c03993	doi.org/10.1021/acscatal.0c03993	Nickel-Catalyzed Cross-Electrophile Coupling Reactions for the Synthesis of gem-Difluorovinyl Arenes	A palladium-catalyzed cross-coupling between aryl esters and anilines is reported, enabling access to diverse amides. The reaction takes place via activation of the C-O bond by oxidative addition with a Pd-NHC complex, which enables the use of relatively non-nucleophilic anilines that otherwise require stoichiometric activation with strong bases in order to react. High yields of aromatic, aliphatic, and heterocyclic products are obtained. A range of activated esters are evaluated in the presence and absence of catalyst, demonstrating that the catalytic methodology substantially increases the types of electrophiles that can be utilized for amide bond formation the absence of harsh bases.	ACS Catal.	82	Lian, Z	FALSE	TRUE	FALSE	FALSE
2332	10.1055/s-0040-1707166	doi.org/10.1055/s-0040-1707166	Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes	Chemical transformations that result in either the formation or cleavage of carbon-heteroatom bonds are among the most important processes in the chemical sciences. Herein, we present a review on the reactivity of well-defined, late-transition metal complexes that result in the making and breaking of C-N, C-O and C-S bonds via fundamental organometallic reactions, i.e. oxidative addition, reductive elimination, insertion and elimination reactions. When appropriate, emphasis is placed on structural and spectroscopic characterization techniques, as well as mechanistic data.	Synthesis	82	Li, T; Zhao, WX	FALSE	FALSE	FALSE	FALSE
2333	10.1021/acs.orglett.0c02752	doi.org/10.1021/acs.orglett.0c02752	Cobalt-Catalyzed Defluorosilylation of Aryl Fluorides via Grignard Reagent Formation	This manuscript describes the design, synthesis, characterization, and reactivity studies of organometallic Ni-III complexes of general structure TpNi(III)(R)(R-1) (Tp = tris(pyrazolyl)borate). With appropriate selection of the R and R-1 ligands, the complexes are stable at room temperature and can be characterized by cyclic voltammetry, EPR spectroscopy, and X-ray crystallography. Upon heating, many of these Ni-III compounds undergo C(sp(2))-C(sp(2)) or C(sp(3))-C(sp(2)) bond-forming reactions that are challenging at lower oxidation states of nickel.	Org. Lett.	82	Lee, E	FALSE	FALSE	FALSE	FALSE
2334	10.1002/aoc.5828	doi.org/10.1002/aoc.5828	Immobilization of Au nanoparticles on poly(glycidyl methacrylate)-functionalized magnetic nanoparticles for enhanced catalytic application in the reduction of nitroarenes and Suzuki reaction	A novel procedure for the synthesis of functionalized symmetrical biaryl compounds is described. The reaction proceeds via the oxidative homocoupling of arylzinc species formed by cobalt catalysis in the presence of air or p-benzoquinone depending on the nature of the functional group.	Appl. Organomet. Chem.	82	Pourjavadi, A	FALSE	FALSE	FALSE	FALSE
2335	10.1021/jacs.0c03708	doi.org/10.1021/jacs.0c03708	Enantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling	A 1,6-addition arylation reaction of para-quinone methides with alpha-isocyanoacetamides and electron-rich aromatic compounds under metal-free conditions has been developed. BF3 center dot Et2O plays two roles in the reaction: catalyzing the cyclization of alpha-isocyanoacetamides to give oxazoles, and activating the para-quinone methides to achieve the 1,6-addition arylation process. The reaction shows good functional group tolerance, scalability, and regioselectivity. It is a consice protocol for the synthesis of diverse unsymmetrical triarylmethanes. Further transformation of the resulting triarylmethanes provides an efficient route to some functionalized molecules.	J. Am. Chem. Soc.	82	Chu, LL	FALSE	TRUE	FALSE	FALSE
2336	10.1002/adsc.202000122	doi.org/10.1002/adsc.202000122	Suzuki-Miyaura Cross-Coupling of Amides using Well-Defined, Air-Stable [(PR3)(2)Pd(II)X-2] Precatalysts	A simple and general synthesis of a series of quinoline-based isoindolin-l-ones, namely N-substituted 7-bromo-2,3-dihydro-1H-pyrrolo-[3,4-b]quinolin-1-ones through a one-pot reaction of ethyl 6-bromo-2-(chloromethyl)quinoline-3-carboxylate with various amines in refluxing EtOH-AcOH (v/v, 10:1) solvent system was described. A mechanism involving consecutive Williamson-type reaction of the 2-chloromethyl group with amine followed by intramolecular C-N bond cyclization process is proposed.	Adv. Synth. Catal.	82	Szostak, M	FALSE	FALSE	FALSE	FALSE
2337	10.3390/nano10040632	doi.org/10.3390/nano10040632	Ultrasound-Assisted Hydrazine Reduction Method for the Preparation of Nickel Nanoparticles, Physicochemical Characterization and Catalytic Application in Suzuki-Miyaura Cross-Coupling Reaction	Palladium catalyzed, nondirected C3-selective arylation of pyridines with arenes and heteroarenes in the presence of 1,10-phenanthroline as the ligand has been developed. The optimized conditions allow for a highly C3-selective arylation of pyridines, affording various 3,3'-bipyridines and 3-arylpyridines.	Nanomaterials	82	Palinko, I	FALSE	FALSE	FALSE	FALSE
2338	10.1021/acs.joc.9b02705	doi.org/10.1021/acs.joc.9b02705	Nickel-Catalyzed Transformation of Alkene-Tethered Oxime Ethers to Nitriles by a Traceless Directing Group Strategy		J. Org. Chem.	82	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
2339	10.1021/jacs.9b12554	doi.org/10.1021/jacs.9b12554	Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes		J. Am. Chem. Soc.	82	Wang, C	TRUE	FALSE	FALSE	FALSE
2340	10.1021/acs.joc.9b02465	doi.org/10.1021/acs.joc.9b02465	Recent Advances in Titanium Radical Redox Catalysis		J. Org. Chem.	82	Lin, S	FALSE	FALSE	FALSE	FALSE
2341	10.1021/acs.orglett.9b02990	doi.org/10.1021/acs.orglett.9b02990	General Synthesis of N-Alkylation of Amines with Secondary Alcohols via Hydrogen Autotransfer		Org. Lett.	82	Balaraman, E	FALSE	FALSE	FALSE	FALSE
2342	10.1002/anie.201907375	doi.org/10.1002/anie.201907375	A Mechanistic Analysis of the Palladium-Catalyzed Formation of Branched Allylic Amines Reveals the Origin of the Regio- and Enantioselectivity through a Unique Inner-Sphere Pathway		Angew. Chem.-Int. Edit.	82	Huang, GP	FALSE	FALSE	FALSE	FALSE
2343	10.1021/acs.joc.9b01438	doi.org/10.1021/acs.joc.9b01438	Sulfur-Mediated Allylic C-H Arylation, Epoxidation, and Aziridination		J. Org. Chem.	82	Li, PF	FALSE	FALSE	FALSE	FALSE
2344	10.1039/c9qo00536f	doi.org/10.1039/c9qo00536f	Visible light driven, nickel-catalyzed aryl esterification using a triplet photosensitiser thioxanthen-9-one		Org. Chem. Front.	82	Li, HX; Lang, JP	FALSE	FALSE	FALSE	FALSE
2345	10.1021/acs.orglett.9b01968	doi.org/10.1021/acs.orglett.9b01968	Ammonia as Ultimate Amino Source in Synthesis of Primary Amines via Nickel-Promoted C-H Bond Amination		Org. Lett.	82	Tan, Z	FALSE	FALSE	FALSE	FALSE
2346	10.1039/c9cc02199j	doi.org/10.1039/c9cc02199j	PdCl2(CH3CN)(2)-catalyzed regioselective C-H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes		Chem. Commun.	82	Cui, YM; Xu, LW	FALSE	FALSE	FALSE	FALSE
2347	10.1039/c9sc00633h	doi.org/10.1039/c9sc00633h	Bronsted acid and Pd-PHOX dual-catalysed enantioselective addition of activated C-pronucleophiles to internal dienes		Chem. Sci.	82	Malcolmson, SJ	FALSE	FALSE	FALSE	FALSE
2348	10.1021/acscatal.9b00688	doi.org/10.1021/acscatal.9b00688	Palladium-Catalyzed Remote 1,n-Arylamination of Unactivated Terminal Alkenes		ACS Catal.	82	Lin, AJ; Yao, HQ	FALSE	FALSE	FALSE	FALSE
2349	10.1021/jacs.8b13652	doi.org/10.1021/jacs.8b13652	Rhodium-Catalyzed Aldehyde Arylation via Formate-Mediated Transfer Hydrogenation: Beyond Metallic Reductants in Grignard/Nozaki-Hiyami-Kishi-Type Addition		J. Am. Chem. Soc.	82	Krische, MJ	FALSE	FALSE	FALSE	FALSE
2350	10.1002/ajoc.201800569	doi.org/10.1002/ajoc.201800569	Pd/Zn Co-catalyzed Asymmetric Ring-Opening Reactions of Aza/Oxabicyclic Alkenes with Oximes		Asian J. Org. Chem.	82	Fan, BM	FALSE	FALSE	FALSE	FALSE
2351	10.1021/acs.joc.8b02666	doi.org/10.1021/acs.joc.8b02666	Nickel-Catalyzed Synthesis of N-Substituted Pyrroles Using Diols with Aryl- and Alkylamines		J. Org. Chem.	82	Banerjee, D	FALSE	FALSE	FALSE	FALSE
2352	10.1021/acs.orglett.8b02854	doi.org/10.1021/acs.orglett.8b02854	Catalytic sp(3)C-CN Bond Cleavage: Ni-Mediated Phosphorylation of Alkylnitriles		Org. Lett.	82	Chen, TQ	FALSE	FALSE	FALSE	FALSE
2353	10.1002/cssc.201801641	doi.org/10.1002/cssc.201801641	Metal-Organic-Framework-Derived Co3S4 Hollow Nanoboxes for the Selective Reduction of Nitroarenes		ChemSusChem	82	Queen, WL	FALSE	FALSE	FALSE	FALSE
2354	10.1002/anie.201803668	doi.org/10.1002/anie.201803668	Divergent Synthesis of CF3-Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2-and 1,4-Addition to 1,3-Enynes		Angew. Chem.-Int. Edit.	82	Liu, GS	FALSE	FALSE	FALSE	FALSE
2355	10.1002/aoc.4273	doi.org/10.1002/aoc.4273	Chitosan-Supported Ni particles: An Efficient Nanocatalyst for Direct Amination of Phenols		Appl. Organomet. Chem.	82	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
2356	10.6023/cjoc201708058	doi.org/10.6023/cjoc201708058	Progress in the Synthesis of Arylated Coumarin Derivatives		Chin. J. Org. Chem.	82	Yuan, JW	FALSE	FALSE	FALSE	FALSE
2357	10.1021/acscatal.7b03215	doi.org/10.1021/acscatal.7b03215	Transition-Metal-Catalyzed Monoarylation of Ammonia		ACS Catal.	82	Schranck, J	FALSE	FALSE	FALSE	FALSE
2358	10.1021/acs.joc.7b02560	doi.org/10.1021/acs.joc.7b02560	Hydroxy-Assisted Regio- and Stereoselective Synthesis of Functionalized 4-Methylenepyrrolidine Derivatives via Phosphine-Catalyzed [3+2] Cycloaddition of Allenoates with o-Hydroxyaryl Azomethine Ylides		J. Org. Chem.	82	Zhou, QF	FALSE	FALSE	FALSE	FALSE
2359	10.1002/anie.201506437	doi.org/10.1002/anie.201506437	Selective Alkenylation and Hydroalkenylation of Enol Phosphates through Direct C-H Functionalization		Angew. Chem.-Int. Edit.	82	Loh, TP	FALSE	FALSE	FALSE	FALSE
2360	10.1002/chem.201501811	doi.org/10.1002/chem.201501811	Perfluoroalkyl and -aryl Zinc Ate Complexes: Generation, Reactivity, and Synthetic Application		Chem.-Eur. J.	82	Hirano, K	FALSE	FALSE	FALSE	FALSE
2361	10.1016/j.tet.2015.02.088	doi.org/10.1016/j.tet.2015.02.088	Rhodium-catalyzed cross-coupling of aryl carbamates with arylboron reagents		Tetrahedron	82	Tobisu, M	FALSE	FALSE	FALSE	FALSE
2362	10.1021/acs.orglett.5b01127	doi.org/10.1021/acs.orglett.5b01127	C-sp(3)-C-sp(3) Bond Cleavage in the Palladium-Catalyzed Aminohydroxylation of Allylic Hydrazones Using Atmospheric Oxygen as the Sole Oxidant		Org. Lett.	82	Loh, TP	FALSE	FALSE	FALSE	FALSE
2363	10.1021/jacs.5b02212	doi.org/10.1021/jacs.5b02212	Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure alpha-Branched Amines		J. Am. Chem. Soc.	82	Zhao, Y	FALSE	FALSE	FALSE	FALSE
2364	10.1002/anie.201410875	doi.org/10.1002/anie.201410875	Nickel-Catalyzed Monoarylation of Ammonia		Angew. Chem.-Int. Edit.	82	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
2365	10.1039/c5cc02254a	doi.org/10.1039/c5cc02254a	Ni(II)/BINOL-catalyzed alkenylation of unactivated C(sp(3))-H bonds		Chem. Commun.	82	Shi, BF	FALSE	FALSE	FALSE	FALSE
2366	10.1039/c4dt03320e	doi.org/10.1039/c4dt03320e	Tetragonal Cu2Se nanoflakes: synthesis using selenated propylamine as Se source and activation of Suzuki and Sonogashira cross coupling reactions		Dalton Trans.	82	Singh, AK	FALSE	FALSE	FALSE	FALSE
2367	10.1039/c5cc02256h	doi.org/10.1039/c5cc02256h	Asymmetric synthesis of quaternary alpha-fluoro-beta-keto-amines via detrifluoroacetylative Mannich reactions		Chem. Commun.	82	Han, JL	FALSE	FALSE	FALSE	FALSE
2368	10.1039/c4ob02488e	doi.org/10.1039/c4ob02488e	Direct construction of 2-alkylbenzo-1,3-azoles via C-H activation of alkanes for C-C and C-X (X = O, S) bond formation		Org. Biomol. Chem.	82	Yadav, LDS	FALSE	FALSE	FALSE	FALSE
2369	10.1021/jo501697n	doi.org/10.1021/jo501697n	Nickel(II)-Catalyzed Direct Arylation of C-H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group		J. Org. Chem.	82	Chatani, N	FALSE	FALSE	FALSE	FALSE
2370	10.1016/j.saa.2014.04.185	doi.org/10.1016/j.saa.2014.04.185	Microwave assisted synthesis, characterization and biocidal activities of some new chelates of carbazole derived Schiff bases of cadmium and tin metals		Spectroc. Acta Pt. A-Molec. Biomolec. Spectr.	82	Kumar, D	FALSE	FALSE	FALSE	FALSE
2371	10.1021/jo501406v	doi.org/10.1021/jo501406v	Asymmetric Organocatalytic Cascade Reaction of Aldehydes with 2-Amino-beta-nitrostyrenes: Synthesis of Chiral Tetrahydroquinolines and Dihydroquinolines		J. Org. Chem.	82	Kim, SG	FALSE	FALSE	FALSE	FALSE
2372	10.1021/om401028d	doi.org/10.1021/om401028d	N-Heterocyclic Carbene-Palladium(II)-4,5-Dihydrooxazole Complexes: Synthesis and Catalytic Activity toward Amination of Aryl Chlorides		Organometallics	82	Lu, JM	FALSE	FALSE	FALSE	FALSE
2373	10.1016/j.tetlet.2013.10.071	doi.org/10.1016/j.tetlet.2013.10.071	Synthesis of highly soluble fluorescent pi-extended 2-(2-thienyl)benzothiazole derivatives via oxidative cyclization of 2-thienylthioanilide as the key step		Tetrahedron Lett.	82	Konishi, G	FALSE	FALSE	FALSE	FALSE
2374	10.1002/chem.201302621	doi.org/10.1002/chem.201302621	Sustainable Catalysis: Rational Pd Loading on MIL-101Cr-NH2 for More Efficient and Recyclable Suzuki-Miyaura Reactions		Chem.-Eur. J.	82	Zou, XD	FALSE	FALSE	FALSE	FALSE
2375	10.1002/anie.201307028	doi.org/10.1002/anie.201307028	Formal Ring-Opening/Cross-Coupling Reactions of 2-Pyrones: Iron-Catalyzed Entry into Stereodefined Dienyl Carboxylates		Angew. Chem.-Int. Edit.	82	Furstner, A	FALSE	FALSE	FALSE	FALSE
2376	10.1002/pola.26473	doi.org/10.1002/pola.26473	Synthesis, surface property, micellization and pH responsivity of fluorinated gradient copolymers		J. Polym. Sci. Pol. Chem.	82	Luo, ZH	FALSE	FALSE	FALSE	FALSE
2377	10.1039/c3ra44884c	doi.org/10.1039/c3ra44884c	Kumada-Tamao-Corriu cross-coupling reaction of O-based electrophiles with Grignard reagents via C-O bond activation		RSC Adv.	82	Wang, ZL	FALSE	FALSE	FALSE	FALSE
2378	10.1007/3418_2012_42	doi.org/10.1007/3418_2012_42	Catalytic Transformations Involving the Activation of sp(2) Carbon-Oxygen Bonds		Top. Organomet. Chem.	82	Tobisu, M	FALSE	FALSE	FALSE	FALSE
2379	10.1021/ol300671y	doi.org/10.1021/ol300671y	Well-Defined Ruthenium(II) Carboxylate as Catalyst for Direct C-H/C-O Bond Arylations with Phenols in Water		Org. Lett.	82	Ackermann, L	FALSE	FALSE	FALSE	FALSE
2380	10.1016/j.ica.2011.02.058	doi.org/10.1016/j.ica.2011.02.058	Diferrocenes containing thiadiazole connectivities		Inorg. Chim. Acta	82	Lang, H	FALSE	FALSE	FALSE	FALSE
2381	10.1016/j.tet.2010.11.042	doi.org/10.1016/j.tet.2010.11.042	Silica supported palladium-phosphine complex: recyclable catalyst for Suzuki-Miyaura cross-coupling reactions at ambient temperature		Tetrahedron	82	Li, PH	FALSE	FALSE	FALSE	FALSE
2382	10.1039/c1ra00406a	doi.org/10.1039/c1ra00406a	Reusable and efficient CoCl2 center dot 6H(2)O/cationic 2,2 '-bipyridyl system-catalyzed S-arylation of aryl halides with thiols in water under air		RSC Adv.	82	Lan, MT	FALSE	FALSE	FALSE	FALSE
2383	10.1016/j.tetlet.2009.03.108	doi.org/10.1016/j.tetlet.2009.03.108	Ruthenium N-heterocyclic carbene catalysts for selective reduction of nitriles to primary amines		Tetrahedron Lett.	82	Beller, M	FALSE	FALSE	FALSE	FALSE
2384	10.1055/s-0028-1087347	doi.org/10.1055/s-0028-1087347	Synthesis of Unsymmetrical Heterobiaryls Using Palladium-Catalyzed Cross-Coupling Reactions of Lithium Organozincates		Synlett	82	Mongin, F	FALSE	FALSE	FALSE	FALSE
2385	10.1021/jo020297e	doi.org/10.1021/jo020297e	Nickel-on-charcoal-catalyzed aromatic aminations and Kumada couplings: Mechanistic and synthetic aspects		J. Org. Chem.	82	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
2386	10.1016/S0040-4020(01)00560-9	doi.org/10.1016/S0040-4020(01)00560-9	Synthetic use of 1,1,2,2-tetraphenyldisilane for the preparation of biaryls through the intramolecular free radical ipso-substitution of N-(2-bromoaryl) arenesulfonamides		Tetrahedron	82	Togo, H	FALSE	FALSE	FALSE	FALSE
2387	10.1002/1521-3765(20001016)6:20<3706::AID-CHEM3706>3.3.CO;2-G	doi.org/10.1002/1521-3765(20001016)6:20<3706::AID-CHEM3706>3.3.CO;2-G	Nickel-catalyzed [2+2] cycloaddition of alkynes with activated cyclic alkenes: Synthesis and novel ring expansion studies of cyclobutene products		Chem.-Eur. J.	82	Cheng, CH	FALSE	FALSE	FALSE	FALSE
2388	10.1135/cccc20000729	doi.org/10.1135/cccc20000729	Stereoconservative cyanation of [1,1 '-binaphthalene]2,2 '-dielectrophiles. An alternative approach to homochiral C-2-symmetric [1,1 '-binaphthalene]2,2 '-dicarbonitrile and its transformations		Collect. Czech. Chem. Commun.	82	Putala, M	FALSE	FALSE	FALSE	FALSE
2389	10.1021/jacs.1c12203	doi.org/10.1021/jacs.1c12203	Using Data Science To Guide Aryl Bromide Substrate Scope Analysis in a Ni/Photoredox-Catalyzed Cross-Coupling with Acetals as Alcohol-Derived Radical Sources		J. Am. Chem. Soc.	82	Doyle, AG	TRUE	FALSE	FALSE	FALSE
2390	10.1021/jacs.1c10368	doi.org/10.1021/jacs.1c10368	Nickel-Catalyzed Ipso/Ortho Difunctionalization of Aryl Bromides with Alkynes and Alkyl Bromides via a Vinyl-to-Aryl 1,4-Hydride Shift		J. Am. Chem. Soc.	82	Zhu, SL	FALSE	FALSE	FALSE	FALSE
2391	10.1016/j.tet.2021.132539	doi.org/10.1016/j.tet.2021.132539	Acylative kinetic resolution of 1,1 '-binaphthyl-8,8 '-diamines by organocatalysis		Tetrahedron	82	Kawabata, T	FALSE	FALSE	FALSE	FALSE
2392	10.1039/d1qo01579f	doi.org/10.1039/d1qo01579f	Ni(ii)-Catalyzed intermolecular selective Heck-type arylation of unactivated alkenes with arylboronic acids		Org. Chem. Front.	82	Lin, C	FALSE	FALSE	FALSE	FALSE
2393	10.6023/cjoc202105053	doi.org/10.6023/cjoc202105053	Transition Metal-Catalyzed C-P Bond Activation		Chin. J. Org. Chem.	82	Luan, YX; Ye, MC	FALSE	FALSE	FALSE	FALSE
2394	10.1039/d1cc03404a	doi.org/10.1039/d1cc03404a	Recent advances in transition metal-catalyzed (1,n) annulation using (de)-hydrogenative coupling with alcohols		Chem. Commun.	82	Banerjee, D	FALSE	FALSE	FALSE	FALSE
2395	10.1055/a-1545-7563	doi.org/10.1055/a-1545-7563	Iridium-Catalyzed Transfer Hydrogenation for Construction of Quinolines from 2-Aminobenzyl Alcohols with Enones in Water		Synthesis	82	Luo, RS	FALSE	FALSE	FALSE	FALSE
2396	10.1016/j.jorganchem.2021.121925	doi.org/10.1016/j.jorganchem.2021.121925	Palladium(II) Complexes Bearing a Mixed Set of aNHC/Py/PR3/I-2 Ligands: Applications in alpha-Arylation of Amide and Suzuki-Miyaura Coupling Reactions		J. Organomet. Chem.	82	Maity, R	FALSE	FALSE	FALSE	FALSE
2397	10.1021/acscatal.1c00951	doi.org/10.1021/acscatal.1c00951	Redox-Neutral Nickel-Catalyzed Cross-Coupling Reactions of (Homo)allylic Alcohols and Aryltriflates		ACS Catal.	82	Rong, ZQ	FALSE	FALSE	FALSE	FALSE
2398	10.1039/d1sc01430g	doi.org/10.1039/d1sc01430g	Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C-H anagostic interactions and B-H agostic bonds		Chem. Sci.	82	Weller, AS	FALSE	FALSE	FALSE	FALSE
2399	10.1002/ejoc.202100194	doi.org/10.1002/ejoc.202100194	Amination of Aryl Halides Mediated by Electrogenerated Nickel from Sacrificial Anode		Eur. J. Org. Chem.	82	Sengmany, S; Leonel, E	FALSE	TRUE	FALSE	FALSE
2400	10.1039/d1qo00140j	doi.org/10.1039/d1qo00140j	A simple removable aliphatic nitrile template 2-cyano-2,2-di-isobutyl acetic acid for remote meta-selective C-H functionalization		Org. Chem. Front.	82	Satyanarayana, G	FALSE	FALSE	FALSE	FALSE
2401	10.1002/ejoc.201700514	doi.org/10.1002/ejoc.201700514	N-Methylpyrrolidin-2-one-Promoted Formation of Functional Esters through C-O Bond Cleavage		Eur. J. Org. Chem.	82	Liu, JM; Tang, QH	FALSE	FALSE	FALSE	FALSE
2402	10.1002/ejoc.201601311	doi.org/10.1002/ejoc.201601311	Green and Scalable Palladium-on-Carbon-Catalyzed Tsuji-Trost Coupling Reaction Using an Efficient and Continuous Flow System		Eur. J. Org. Chem.	82	Len, C	FALSE	FALSE	FALSE	FALSE
2403	10.1021/jacs.6b10998	doi.org/10.1021/jacs.6b10998	A Mild and Ligand-Free Ni-Catalyzed Silylation via C-OMe Cleavage		J. Am. Chem. Soc.	82	Martin, R	FALSE	FALSE	FALSE	FALSE
2404	10.1039/c6cc09685a	doi.org/10.1039/c6cc09685a	Coupling of C(sp(3))-H bonds with C(sp(2))-O electrophiles: mild, general and selective		Chem. Commun.	82	Yu, DG	FALSE	FALSE	FALSE	FALSE
2405	10.1039/c6dt03241a	doi.org/10.1039/c6dt03241a	Platinum(0)-mediated C-O bond activation of ethers via an S(N)2 mechanism		Dalton Trans.	82	Lledos, A	FALSE	FALSE	FALSE	FALSE
2406	10.1016/j.tet.2016.10.059	doi.org/10.1016/j.tet.2016.10.059	Amidation via ligand-free direct oxidative C(sp(3))-H/N-H coupling with Cu-CPO-27 metal-organic framework as a recyclable heterogeneous catalyst		Tetrahedron	82	Phan, NTS	FALSE	FALSE	FALSE	FALSE
2407	10.1016/j.tetlet.2016.04.089	doi.org/10.1016/j.tetlet.2016.04.089	Palladium-catalyzed double C-H functionalization of 2-aryl-1,3-dicarbonyl compounds: a facile access to alkenylated benzopyrans		Tetrahedron Lett.	82	Bollikolla, HB	FALSE	FALSE	FALSE	FALSE
2408	10.1080/00397911.2016.1192651	doi.org/10.1080/00397911.2016.1192651	Use of 2,4,6-trichloro-1,3,5-triazine (TCT) as organic catalyst in organic synthesis		Synth. Commun.	82	Jain, S	FALSE	FALSE	FALSE	FALSE
2409	10.1039/d0ob02348e	doi.org/10.1039/d0ob02348e	Mild and efficient copper-catalyzed oxidative cyclization of oximes with 2-aminobenzyl alcohols at room temperature: synthesis of polysubstituted quinolines	The development of the site-selective Suzuki-Miyaura cross-coupling of dibromoanthracene as an efficient strategy toward organic light emitting diodes (OLEDs) is disclosed in this article. An unprecedented step-economic palladacycle-promoted triple Suzuki coupling protocol allowed the synthesis of three new OLED emitters and could prove to be a useful general strategy for researchers working in this field. Characterization of the synthesized molecules by UV-vis spectroscopy and thermogravimetric analysis-differential scanning calorimetry followed by density functional theory studies of the different properties strongly confirms the derivatives possess more significant hole mobility character than electron transfer capability.	Org. Biomol. Chem.	81	Liu, YL	FALSE	FALSE	FALSE	FALSE
2410	10.1002/tcr.202000108	doi.org/10.1002/tcr.202000108	Catalytic Asymmetric Total Synthesis of Leucinostatin A	A pillar[5]arene-based N-heterocyclic carbene ligand was prepared by reaction of bromoethoxy pillar[5]arene with excess 1-methylimidazole at 130 A degrees C in the absence of solvent and used as a catalyst for the Suzuki coupling reaction. Excellent yields were obtained when the Suzuki reactions were carried out under ambient atmosphere in ethanol, employing 0.2 mol% ligand, 1 mol% PdCl2(CH3CN)(2) and 1.5 mmol of K2CO3. The novel pillar[5]arene-based imidazolium salt is a promising material for the construction of highly active supramolecular catalytic systems.	Chem. Rec.	81	Watanabe, T; Shibasaki, M	FALSE	FALSE	FALSE	FALSE
2411	10.1002/cctc.202000876	doi.org/10.1002/cctc.202000876	Nickel-Catalyzed Synthesis ofN-(Hetero)aryl Carbamates from Cyanate Salts and Phenols Activated with Cyanuric Chloride	Using a recently discovered precatalyst, the first Pd-catalyzed Suzuki-Miyaura reactions using aryl sulfamates that occur at room temperature are reported. In complementary work, it is demonstrated that a related precatalyst can facilitate the coupling of aryl silanolates, which are less toxic and reactive nucleophiles than boronic acids with aryl chlorides. By combining our results using modern electrophiles and nucleophiles, the first Hiyama-Denmark reactions using aryl sulfamates are reported.	ChemCatChem	81	Inaloo, ID; Esmaeilpour, M	FALSE	FALSE	FALSE	FALSE
2412	10.1021/jacs.0c06139	doi.org/10.1021/jacs.0c06139	Development of an Aryl Amination Catalyst with Broad Scope Guided by Consideration of Catalyst Stability	A system consisting of catalytic amounts of [(p-cym)RuCl2](2)/PEt3 center dot HBF4, K2CO3 as the base, and NMP as the solvent efficiently mediates the ortho-C-H arylation of benzoic acids with aryl bromides at 100 degrees C. Replacing the phosphine ligand with the amino acid dl-pipecolinic acid enables the analogous transformation with aryl chlorides. The key advantage of this broadly applicable transformation is the use of an inexpensive ruthenium catalyst in combination with simple carboxylates as directing groups, which can either be tracelessly removed or used as anchor points for decarboxylative ipso substitutions.	J. Am. Chem. Soc.	81	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
2413	10.1039/d0ob00711k	doi.org/10.1039/d0ob00711k	Recent development in the synthesis ofC-glycosides involving glycosyl radicals	A decarboxylative Mizoroki-Heck coupling of aryl halides with cinnamic acids has been developed in which the carboxylate group directs the arylation into its -position before being tracelessly removed through protodecarboxylation. In the presence of a copper/palladium catalyst, both electron-rich and electron-deficient aryl bromides and chlorides bearing numerous functionalities were successfully coupled with broadly available cinnamates, with selective formation of 1,1-disubstituted alkenes. This reaction concept, in which the carboxylate acts as a deciduous directing group, ideally complements traditional 1,2-selective Heck reactions of styrenes.	Org. Biomol. Chem.	81	Hu, XG	FALSE	FALSE	FALSE	FALSE
2414	10.1021/jacs.0c04812	doi.org/10.1021/jacs.0c04812	Cross-Electrophile Coupling of Unactivated Alkyl Chlorides	In the presence of a diatylborinic acid catalyst, glycosyl methanesulfonates engage in regio- and; stereoselective couplings, with partially protected pyranoside and furanoside acceptors. The methanesulfonate donors are prepared in situ from glycosyl hemiacetals, and are coupled under mild, operationally simple conditions (amine base, organoboron catalyst, room temperature). The borinic acid: catalyst not only influences site-selectivity via activation of 1,2- or 1,3-diol motifs, but also has a pronounced effect on the stereochemical outcome: 1,2-trans-linked disaccharides are obtained selectively in the absence of neighboring group participation. Reaction progress kinetic analysis was used to obtain insight into the mechanism of glycosylation, both in the presence of catalyst and in its absence, while rates of interconversion of methanesulfonate anomers were determined by NMR exchange spectroscopy (EXSY): Together, the results suggest that although the uncatalyzed and catalyzed reactions give rise to opposite stereochemical outcomes, both proceed by associative mechanisms.	J. Am. Chem. Soc.	81	MacMillan, DWC	FALSE	TRUE	FALSE	FALSE
2415	10.1246/cl.200190	doi.org/10.1246/cl.200190	Synthesis of Thioxanthones through Formal C-H Thiolation of Benzoic Acid Esters and Acid-mediated Direct Cyclization	A cross-coupling reaction between enol derivatives and silyl ketene acetals catalyzed by GaBr3 took place to give the corresponding a-alkenyl esters. GaBr3 showed the most effective catalytic ability, whereas other metal salts such as BF3 center dot OEt2, AlCl3, PdCl2, and lanthanide triflates were not effective. Various types of enol ethers and vinyl carboxylates as enol derivatives are amenable to this coupling. The scope of the reaction with silyl ketene acetals was also broad. We successfully observed an alkylgallium intermediate by using NMR spectroscopy, suggesting a mechanism involving anti-carbogallation among GaBr3, an enol derivative, and a silyl ketene acetal, followed by syn-beta-alkoxy elimination from the alkylgallium. Based on kinetic studies, the turnover-limiting step of the reaction using a vinyl ether and a vinyl carboxylate involved syn-beta-alkoxy elimination and anti-carbogallation, respectively. Therefore, the leaving group had a significant effect on the progress of the reaction. Theoretical calculations analysis suggest that the moderate Lewis acidity of gallium would contribute to a flexible conformational change of the alkylgallium intermediate and to the cleavage of the carbon-oxygen bond in the beta-alkoxy elimination process, which is the turnover-limiting step in the reaction between a vinyl ether and a silyl ketene acetal.	Chem. Lett.	81	Yoshida, S	FALSE	FALSE	FALSE	FALSE
2416	10.1021/acs.orglett.0c00108	doi.org/10.1021/acs.orglett.0c00108	Dehydrative Cross-Coupling of Allylic Alcohols with Alkynes		Org. Lett.	81	Xie, PZ; Loh, TP	FALSE	FALSE	FALSE	FALSE
2417	10.1002/anie.201914175	doi.org/10.1002/anie.201914175	Nickel/Photoredox-Catalyzed Asymmetric Reductive Cross-Coupling of Racemic alpha-Chloro Esters with Aryl Iodides		Angew. Chem.-Int. Edit.	81	Mao, JY	TRUE	FALSE	FALSE	FALSE
2418	10.1002/anie.201916534	doi.org/10.1002/anie.201916534	Nickel-Catalyzed Asymmetric Hydrogenation of 2-Amidoacrylates		Angew. Chem.-Int. Edit.	81	Zhang, WB	FALSE	FALSE	FALSE	FALSE
2419	10.1021/acs.orglett.9b04392	doi.org/10.1021/acs.orglett.9b04392	Cu-Catalyzed Alkylarylation of Vinylarenes with Masked Alkyl Electrophiles		Org. Lett.	81	Li, YJ; Bao, HL	FALSE	TRUE	FALSE	FALSE
2420	10.1002/anie.201912803	doi.org/10.1002/anie.201912803	Iridium-Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis		Angew. Chem.-Int. Edit.	81	Morandi, B	FALSE	FALSE	FALSE	FALSE
2421	10.1021/acscatal.9b04390	doi.org/10.1021/acscatal.9b04390	Enantioselective Access to gamma-All-Carbon Quaternary Center-Containing Cyclohexanones by Palladium-Catalyzed Desymmetrization		ACS Catal.	81	Liu, WB	FALSE	FALSE	FALSE	FALSE
2422	10.1002/chem.201903668	doi.org/10.1002/chem.201903668	Vinyl Triflate-Aldehyde Reductive Coupling-Redox Isomerization Mediated by Formate: Rhodium-Catalyzed Ketone Synthesis in the Absence of Stoichiometric Metals		Chem.-Eur. J.	81	Krische, MJ	FALSE	FALSE	FALSE	FALSE
2423	10.1021/acs.orglett.9b02572	doi.org/10.1021/acs.orglett.9b02572	Reductive C-O, C-N, and C-S Cleavage by a Zirconium Catalyzed Hydrometalation/beta-Elimination Approach		Org. Lett.	81	Streuff, J	FALSE	FALSE	FALSE	FALSE
2424	10.1002/anie.201907045	doi.org/10.1002/anie.201907045	Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters		Angew. Chem.-Int. Edit.	81	Hu, XL	FALSE	FALSE	FALSE	FALSE
2425	10.1039/c9cc03975a	doi.org/10.1039/c9cc03975a	Nickel-catalyzed borrowing hydrogen annulations: access to diversified N-heterocycles		Chem. Commun.	81	Yang, P; Ma, Y; Tang, B	FALSE	FALSE	FALSE	FALSE
2426	10.1021/acs.joc.9b00703	doi.org/10.1021/acs.joc.9b00703	Palladium-Catalyzed C(sp(2))-N Bond Cross-Coupling with Triaryl Phosphates		J. Org. Chem.	81	So, CM	FALSE	FALSE	FALSE	FALSE
2427	10.1002/adsc.201801351	doi.org/10.1002/adsc.201801351	Palladium Catalyzed Controllable Mono- or Di-Allylic Substitution Reaction of Benzothiazolylacetate with Allylic Alcohols		Adv. Synth. Catal.	81	Zeng, XF; Zhong, GF	FALSE	FALSE	FALSE	FALSE
2428	10.1021/acs.joc.8b02609	doi.org/10.1021/acs.joc.8b02609	Nickel-Catalyzed Alkylation of Ketone Enolates: Synthesis of Monoselective Linear Ketones		J. Org. Chem.	81	Banerjee, D	FALSE	FALSE	FALSE	FALSE
2429	10.1021/acs.joc.8b02180	doi.org/10.1021/acs.joc.8b02180	Carboxylic Acid-Promoted Single-Step Indole Construction from Simple Anilines and Ketones via Aerobic Cross-Dehydrogenative Coupling		J. Org. Chem.	81	Xiao, ZY	FALSE	FALSE	FALSE	FALSE
2430	10.1039/c8qo00764k	doi.org/10.1039/c8qo00764k	Ni-Catalyzed dehydrogenative coupling of primary and secondary alcohols with methyl-N-heteroaromatics		Org. Chem. Front.	81	Balaraman, E	FALSE	FALSE	FALSE	FALSE
2431	10.1002/ejoc.201801132	doi.org/10.1002/ejoc.201801132	Synthesis of Functionalized Arenopyrans and Arenylsulfanes by Reacting Nitroallylic Acetates with Arenols and Arenethiols		Eur. J. Org. Chem.	81	Namboothiri, INN	FALSE	FALSE	FALSE	FALSE
2432	10.1002/anie.201803228	doi.org/10.1002/anie.201803228	Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Monofluoroalkyl Halides for Late-Stage Monofluoroalkylation		Angew. Chem.-Int. Edit.	81	Wang, XS	FALSE	FALSE	FALSE	FALSE
2433	10.1021/acs.joc.8b00340	doi.org/10.1021/acs.joc.8b00340	C-Glycosidation of Unprotected Di- and Trisaccharide Aldopyranoses with Ketones Using Pyrrolidine-Boric Acid Catalysis		J. Org. Chem.	81	Tanaka, F	FALSE	FALSE	FALSE	FALSE
2434	10.1021/acs.orglett.8b00413	doi.org/10.1021/acs.orglett.8b00413	Photochemical Nickel-Catalyzed Reductive Migratory Cross-Coupling of Alkyl Bromides with Aryl Bromides		Org. Lett.	81	Yin, GY	TRUE	FALSE	FALSE	FALSE
2435	10.1039/c7qo00934h	doi.org/10.1039/c7qo00934h	Nickel-catalyzed direct difluoromethylation of aryl boronic acids with BrCF2H		Org. Chem. Front.	81	Wang, XS	FALSE	FALSE	FALSE	FALSE
2436	10.1515/pac-2017-0706	doi.org/10.1515/pac-2017-0706	The coupling of carbon dioxide with ethene to produce acrylic acid sodium salt in one pot by using Ni(II) and Pd(II)-phosphine complexes as precatalysts		Pure Appl. Chem.	81	Vavasori, A	FALSE	FALSE	FALSE	FALSE
2437	10.1039/c7ob01793f	doi.org/10.1039/c7ob01793f	Oxidative C-H functionalization of N-carbamoyl 1,2-dihydroquinolines		Org. Biomol. Chem.	81	Liu, L	FALSE	FALSE	FALSE	FALSE
2438	10.1021/acs.joc.5b01977	doi.org/10.1021/acs.joc.5b01977	Transition-Metal-Free Synthesis of Carbonyl-Containing Oxindoles from N-Arylacrylamides and alpha-Diketones via TBHP- or Oxone-Mediated Oxidative Cleavage of C(sp(2))-C(sp(2)) Bonds		J. Org. Chem.	81	Guo, CC	FALSE	FALSE	FALSE	FALSE
2439	10.1016/j.jfluchem.2015.01.004	doi.org/10.1016/j.jfluchem.2015.01.004	Synthesis of alpha,alpha-difluoro-beta-amino carbonyl-containing sulfonamides and related compounds		J. Fluor. Chem.	81	Han, JL	FALSE	FALSE	FALSE	FALSE
2440	10.1039/c5ob01874a	doi.org/10.1039/c5ob01874a	A diphenyl ether derived bidentate secondary phosphine oxide as a preligand for nickel-catalyzed C-S cross-coupling reactions		Org. Biomol. Chem.	81	Guan, HR	FALSE	FALSE	FALSE	FALSE
2441	10.1021/om500637k	doi.org/10.1021/om500637k	Exceptional Behavior of Ni2O2 Species Revealed by ESI-MS and MS/MS Studies in Solution. Application of Superatomic Core To Facilitate New Chemical Transformations		Organometallics	81	Ananikov, VP	FALSE	FALSE	FALSE	FALSE
2442	10.1002/chem.201405246	doi.org/10.1002/chem.201405246	A Stereoselective Switch: Enantiodivergent Approach to the Synthesis of Isoflavanones		Chem.-Eur. J.	81	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
2443	10.1002/anie.201402922	doi.org/10.1002/anie.201402922	Metal-Catalyzed Dealkoxylative C-aryl-C-sp3 Cross-Coupling-Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile		Angew. Chem.-Int. Edit.	81	Rueping, M	FALSE	FALSE	FALSE	FALSE
2444	10.1021/jo500507s	doi.org/10.1021/jo500507s	Cross-Electrophile Coupling: Principles of Reactivity and Selectivity		J. Org. Chem.	81	Weix, DJ	FALSE	TRUE	FALSE	FALSE
2445	10.1021/ar500035q	doi.org/10.1021/ar500035q	Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts		Accounts Chem. Res.	81	Ryu, I	FALSE	FALSE	FALSE	FALSE
2446	10.1039/c3ra45790g	doi.org/10.1039/c3ra45790g	Ultrasound-assisted C-C coupling reactions catalyzed by unique SPION-A-Pd(EDTA) as a robust nanocatalyst		RSC Adv.	81	Khosropour, AR	FALSE	FALSE	FALSE	FALSE
2447	10.1039/c4ra12251h	doi.org/10.1039/c4ra12251h	Suzuki-Miyaura coupling of phosphinoyl-alpha-allenic alcohols with arylboronic acids catalyzed by a palladium complex on water: an efficient method to generate phosphinoyl 1,3-butadienes and derivatives		RSC Adv.	81	Wu, L	FALSE	FALSE	FALSE	FALSE
2448	10.1002/anie.201304492	doi.org/10.1002/anie.201304492	C-H Alkenylation of Azoles with Enols and Esters by Nickel Catalysis		Angew. Chem.-Int. Edit.	81	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
2449	10.1002/ejoc.201300558	doi.org/10.1002/ejoc.201300558	Reaction of Two Differently Functionalized Oxiranes with Nickel Perchlorate: A Modular Entry to Highly Substituted 1,3-Dioxolanes		Eur. J. Org. Chem.	81	Zhang, JL	FALSE	FALSE	FALSE	FALSE
2450	10.1021/jo400539x	doi.org/10.1021/jo400539x	Tandem Synthesis of Pyrroloacridones via [3+2] Alkyne Annulation/Ring-Opening with Concomitant Intramolecular Aldol Condensation		J. Org. Chem.	81	Verma, AK	FALSE	FALSE	FALSE	FALSE
2451	10.1002/cjoc.201200753	doi.org/10.1002/cjoc.201200753	Accurate Prediction of AuP Bond Strengths by Density Functional Theory Methods		Chin. J. Chem.	81	Fu, Y	FALSE	FALSE	FALSE	FALSE
2452	10.1021/jo301335x	doi.org/10.1021/jo301335x	Cross-Coupling of Diarylborinic Acids and Anhydrides with Arylhalides Catalyzed by a Phosphite/N-Heterocyclic Carbene Co-supported Palladium Catalyst System		J. Org. Chem.	81	Zou, G	FALSE	FALSE	FALSE	FALSE
2453	10.1021/jo301270t	doi.org/10.1021/jo301270t	N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex-Catalyzed Suzuki-Miyaura Coupling of Aryl Sulfonates with Arylboronic Acids		J. Org. Chem.	81	Shao, LX	FALSE	FALSE	FALSE	FALSE
2454	10.1002/anie.201205987	doi.org/10.1002/anie.201205987	Direct Pd-Catalyzed Cross-Coupling of Functionalized Organoaluminum Reagents		Angew. Chem.-Int. Edit.	81	Knochel, P	FALSE	FALSE	FALSE	FALSE
2455	10.1002/chem.201103050	doi.org/10.1002/chem.201103050	Biphenyl-Based Diaminophosphine Oxides as Air-Stable Preligands for the Nickel-Catalyzed Kumada-Tamao-Corriu Coupling of Deactivated Aryl Chlorides, Fluorides, and Tosylates		Chem.-Eur. J.	81	Jin, Z	FALSE	FALSE	FALSE	FALSE
2456	10.1002/chem.201101930	doi.org/10.1002/chem.201101930	Nickel-Catalyzed C-P Cross-Coupling by C-CN Bond Cleavage		Chem.-Eur. J.	81	Yang, SD	FALSE	FALSE	FALSE	FALSE
2457	10.1002/chem.201001943	doi.org/10.1002/chem.201001943	Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed C-O Activation		Chem.-Eur. J.	81	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
2458	10.1039/c1cs15122c	doi.org/10.1039/c1cs15122c	Silicon-based cross-coupling reaction: an environmentally benign version		Chem. Soc. Rev.	81	Nakao, Y	FALSE	FALSE	FALSE	FALSE
2459	10.1002/chem.201002653	doi.org/10.1002/chem.201002653	A General Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Triflates		Chem.-Eur. J.	81	Beller, M	FALSE	FALSE	FALSE	FALSE
2460	10.1021/ja106682m	doi.org/10.1021/ja106682m	Nickel-Catalyzed Stereoselective Glycosylation with C(2)-N-Substituted Benzylidene D-Glucosamine and Galactosamine Trichloroacetimidates for the Formation of 1,2-cis-2-Amino Glycosides. Applications to the Synthesis of Heparin Disaccharides, GPI Anchor Pseudodisaccharides, and alpha-GalNAc		J. Am. Chem. Soc.	81	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
2461	10.1002/anie.201002782	doi.org/10.1002/anie.201002782	Asymmetric Nanocatalysis: N-Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles		Angew. Chem.-Int. Edit.	81	Glorius, F	FALSE	FALSE	FALSE	FALSE
2462	10.1055/s-2008-1067194	doi.org/10.1055/s-2008-1067194	Iron-catalyzed alkenylation of Grignard reagents by enol phosphates		Synthesis	81	Cahiez, G	FALSE	FALSE	FALSE	FALSE
2463	10.1016/j.tetlet.2007.05.119	doi.org/10.1016/j.tetlet.2007.05.119	Phosphinite- and phosphite-based type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, alpha,beta-unsaturated ketones, alpha-ketoesters, and aldimines		Tetrahedron Lett.	81	Hu, QS	FALSE	FALSE	FALSE	FALSE
2464	10.1021/om049455d	doi.org/10.1021/om049455d	Catalytic transmetalation of alkoxychromium(0) carbenes to late transition metals: Self-dimerization and cyclopropanation reactions		Organometallics	81	Sierra, MA	FALSE	FALSE	FALSE	FALSE
2465	10.1021/jo035834p	doi.org/10.1021/jo035834p	Cross-coupling and dehalogenation reactions catalyzed by (N-heterocyclic carbene)Pd(allyl)Cl complexes		J. Org. Chem.	81	Nolan, SP	FALSE	FALSE	FALSE	FALSE
2466	10.1063/5.0079574	doi.org/10.1063/5.0079574	Quantum chemistry-augmented neural networks for reactivity prediction: Performance, generalizability, and explainability		J. Chem. Phys.	81	Coley, CW	FALSE	FALSE	FALSE	FALSE
2467	10.1002/anie.202115592	doi.org/10.1002/anie.202115592	Alkyl-GeMe3: Neutral Metalloid Radical Precursors upon Visible-Light Photocatalysis		Angew. Chem.-Int. Edit.	81	Xiao, B	TRUE	FALSE	FALSE	FALSE
2468	10.1021/acs.inorgchem.1c03042	doi.org/10.1021/acs.inorgchem.1c03042	Magnetic Silica-Coated Picolylamine Copper Complex [Fe3O4@SiO2@GP/Picolylamine-Cu(II)]-Catalyzed Biginelli Annulation Reaction		Inorg. Chem.	81	Ramazani, A	FALSE	FALSE	FALSE	FALSE
2469	10.1055/s-0040-1707817	doi.org/10.1055/s-0040-1707817	Nickel-Catalyzed Negishi-Type Arylation of Trialkylsulfonium Salts		Synlett	81	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
2470	10.1021/acs.joc.1c01724	doi.org/10.1021/acs.joc.1c01724	Fluoride-Triggered Synthesis of 1-Aryl-2,2-difluoroalkenes via Desilylative Defluorination of (1-Aryl)-2,2,2-trifluoroethyl-silanes		J. Org. Chem.	81	Ollevier, T	FALSE	FALSE	FALSE	FALSE
2471	10.1021/jacs.1c05670	doi.org/10.1021/jacs.1c05670	Enantioselective Reductive Divinylation of Unactivated Alkenes by Nickel-Catalyzed Cyclization Coupling Reaction		J. Am. Chem. Soc.	81	Shu, XZ	FALSE	FALSE	FALSE	FALSE
2472	10.1002/anie.202106109	doi.org/10.1002/anie.202106109	Palladium/TY-Phos-Catalyzed Asymmetric Intermolecular alpha-Arylation of Aldehydes with Aryl Bromides		Angew. Chem.-Int. Edit.	81	Zhang, JL	FALSE	FALSE	FALSE	FALSE
2473	10.1021/acs.joc.6b02865	doi.org/10.1021/acs.joc.6b02865	Copper-Catalyzed Selenylation of Imidazo[1,2-a]pyridines with Selenium Powder via a Radical Pathway		J. Org. Chem.	81	Yang, DD; Wang, H	FALSE	FALSE	FALSE	FALSE
2474	10.1016/j.tet.2016.11.058	doi.org/10.1016/j.tet.2016.11.058	Iron catalysis for the synthesis of ligands: Exploring the products of hydrophosphination as ligands in cross-coupling		Tetrahedron	81	Webster, RL	FALSE	FALSE	FALSE	FALSE
2475	10.1007/s00706-016-1879-3	doi.org/10.1007/s00706-016-1879-3	Recent advancements on the use of 2-methyltetrahydrofuran in organometallic chemistry		Mon. Chem.	81	Pace, V	FALSE	FALSE	FALSE	FALSE
2476	10.1039/c7ra04817c	doi.org/10.1039/c7ra04817c	Regio- and stereoselective syntheses of allylic thioethers under metal free conditions		RSC Adv.	81	Badsara, SS	FALSE	FALSE	FALSE	FALSE
2477	10.1002/chem.201605095	doi.org/10.1002/chem.201605095	Nickel-Catalyzed N-Arylation of Primary Amides and Lactams with Activated (Hetero)aryl Electrophiles		Chem.-Eur. J.	81	Stradiotto, M	FALSE	TRUE	FALSE	FALSE
2478	10.1002/anie.201606979	doi.org/10.1002/anie.201606979	A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes		Angew. Chem.-Int. Edit.	81	Driess, M	FALSE	FALSE	FALSE	FALSE
2479	10.1021/acs.organomet.6b00457	doi.org/10.1021/acs.organomet.6b00457	Cobalt Phosphino-alpha-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis		Organometallics	81	Rauchfuss, TB	FALSE	FALSE	FALSE	FALSE
2480	10.1002/anie.201605744	doi.org/10.1002/anie.201605744	Branched Arylalkenes from Cinnamates: Selectivity Inversion in Heck Reactions by Carboxylates as Deciduous Directing Groups		Angew. Chem.-Int. Edit.	81	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
2481	10.1021/acscatal.6b01869	doi.org/10.1021/acscatal.6b01869	A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C-H Amidation Using Azidoformates		ACS Catal.	81	Chang, S	FALSE	FALSE	FALSE	FALSE
2482	10.1021/jacs.6b06943	doi.org/10.1021/jacs.6b06943	Borinic Acid Catalyzed Stereo- and Regioselective Couplings of Glycosyl Methanesulfonates		J. Am. Chem. Soc.	81	Taylor, MS	FALSE	FALSE	FALSE	FALSE
2483	10.1021/acs.orglett.6b01837	doi.org/10.1021/acs.orglett.6b01837	Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Alkyl Bromides: Et3N as the Terminal Reductant		Org. Lett.	81	Li, W; Lei, AW	FALSE	FALSE	FALSE	FALSE
2484	10.1016/j.tet.2016.02.033	doi.org/10.1016/j.tet.2016.02.033	Intramolecular carbonyl-ene reactions in the synthesis of peri-oxygenated hydroaromatics		Tetrahedron	81	Mal, D	FALSE	FALSE	FALSE	FALSE
2485	10.1039/d0cc07783f	doi.org/10.1039/d0cc07783f	C-CN bond formation: an overview of diverse strategies	Pincer complexes can act as efficient catalysts for many industrially important organic transformations under environmentally benign and mild conditions. The NNN pincer ligands have been prepared from the reactions between pyridine-2,6-dicarbonyldichloride and benzylamine or its derivatives in the presence of 4-dimethylaminopyridine (DMAP). Pd(II) complexes containing NNN pincer ligand and acetonitrile/triphenylphosphine have been synthesized and characterized by analytical, spectroscopic (FT-IR, UV-Visible, H-1, C-13 & P-31 NMR and Mass) and single crystal X-ray diffraction techniques. Single crystal X-ray analysis reveals a distorted square planar geometry around Pd in all the complexes. These pincer complexes have been used as catalysts in Suzuki-Miyaura cross-coupling reaction. The effect of ancillary ligands (CH3CN and PPh3) in the complexes has been investigated towards the coupling reaction. The conversions have been determined from GC analyses. Scope of the system has been extended with various substituted halides. (C) 2017 Elsevier B.V. All rights reserved.	Chem. Commun.	80	Maiti, D	FALSE	FALSE	FALSE	FALSE
2486	10.1002/ajoc.202000634	doi.org/10.1002/ajoc.202000634	Atom-Economic Alk(en)ylations of Esters, Amides, and Methyl Heteroarenes Utilizing Alcohols Following Dehydrogenative Strategies	A nickel-catalyzed coupling of azaarylmethylamines with aryl chlorides has been achieved. NIXANTPHOS together with low cost NiBr2 was successfully developed and optimized to exhibit high reactivity at 2.5 mol% loading. Under optimized reaction conditions, aryl(azaaryl)methylamine products were afforded in good to excellent yields (22 examples, up to 98% yield).	Asian J. Org. Chem.	80	Rit, A	FALSE	FALSE	FALSE	FALSE
2487	10.1002/ejoc.202001458	doi.org/10.1002/ejoc.202001458	C(sp(2))-Si Bond Functionalization through Intramolecular Activation by Alkoxides	Palladium-catalyzed intramolecular direct C-H arylations for the synthesis of hitherto unknown fused hetero systems containing an incorporated pyrrolo[2,3-d]pyrimidine scaffold are described. Pyrimido[5', 4': 4,5] pyrrolo[2,1-a]isoindoles were synthesized from 2,4-diarylpyrrolo[2,3-d]pyrimidines and o-bromobenzyl bromides by using a cascade N-benzylation/C-H arylation reaction sequence. A series of pyrimido[5', 4': 4,5]pyrrolo[1,2-f]phenanthridines were successfully assembled via a domino process involving the palladium-catalyzed direct double C-H arylation reactions of 2,4,7-triarylpyrrolo[2,3-d]pyrimidines with o-bromoiodobenzenes.	Eur. J. Org. Chem.	80	Oble, J; Perez-Luna, A	FALSE	FALSE	FALSE	FALSE
2488	10.1002/adsc.202000794	doi.org/10.1002/adsc.202000794	A Strategy for Accessing Aldehydes via Palladium-Catalyzed C-O/C-N Bond Cleavage in the Presence of Hydrosilanes	A simple and efficient Ru(II)-catalyzed transfer hydrodehalogenation of organic halides using 2-propanol solvent as the hydride source was reported. This methodology is applicable for hydrodehalogenation of a variety of aromatic halides and alpha-haloesters and amides without additional ligand, and quantitative yields were achieved in many cases. The potential synthetic application of this method was demonstrated by efficient gram-scale transformation with catalyst loading as low as 0.5 mol %.	Adv. Synth. Catal.	80	Liu, TT; Zeng, Z	FALSE	FALSE	FALSE	FALSE
2489	10.1002/ajoc.202000443	doi.org/10.1002/ajoc.202000443	Palladium-Catalyzed Direct C-H Arylation of Arenes Promoted by Quaternary Ammonium Salt	The reaction mechanism of Ni(COD)(2) catalyzed hydrodesulfurization of aryl sulfide PhSMe with HSiMe3 as the reducing agent has been studied by using density functional theory methods. Both PhSMe-coordinated pathway and ligandless pathway have been identified and compared. It is found that these two reaction pathways are kinetically competitive and the s-complex assisted metathesis (s-CAM) transition state is the highest point on each energy profile for both pathways. Moreover, both the singlet and triplet reaction pathways of ligand substitutions have been compared and found that both singlet and triplet reaction mechanisms are competitive for the ligand substitution of COD with PhSMe on PhSMe-coordinated pathway while the triplet mechanism holds a distinct advantage over singlet one for that of COD with HSiMe3 on ligandless pathway.	Asian J. Org. Chem.	80	Hong, SH	FALSE	FALSE	FALSE	FALSE
2490	10.3390/catal10091084	doi.org/10.3390/catal10091084	Syntheses of 3,3-Disubstituted Dihydrobenzofurans, Indolines, Indolinones and Isochromanes by Palladium-Catalyzed Tandem Reaction Using Pd(PPh3)(2)Cl-2/(+/-)-BINAP as a Catalytic System	Nickel-catalyzed Buchwald-Hartwig amination of pyrimidin-2-yl tosylates with indole and benzimidazole was achieved using Ni (dppp)Cl-2 as catalyst, yielding a variety of novel C2-substituted pyrimidine derivatives in good yields. This reaction proved to be tolerant of various pyrimidin-2-yl tosylates bearing either electron-donating or electron-withdrawing groups as well as nucleophiles including indole, benzimidazole and 1,2,4-triazole. Copyright (C) 2016 John Wiley & Sons, Ltd.	Catalysts	80	Yue, GZ	FALSE	FALSE	FALSE	FALSE
2491	10.1021/acs.orglett.0c02271	doi.org/10.1021/acs.orglett.0c02271	Nickel-Catalyzed Dehydrogenation of N-Heterocycles Using Molecular Oxygen	New forms of click chemistry present new opportunities in materials science. Sulfur(VI) fluoride exchange (SuFEx) is a recently discovered click reaction between molecules containing SOxF groups and silyl ethers, two functionalities that are orthogonal to all other known click chemistries, that generates sulfate or sulfonate connections upon the addition of certain organobases or fluoride sources. SuFEx also has several important advantages over other click reactions in that it is insensitive to ambient oxygen and water, and its precursor materials, especially SOxF, are chemically, UV, and thermally inert. This Concept article focuses on the unique reactivity of SuFEx and its relation to building high molecular weight polymers and surface coatings, both of which make it a powerful new tool for materials science.	Org. Lett.	80	Banerjee, D	FALSE	FALSE	FALSE	FALSE
2492	10.1016/j.jorganchem.2020.121337	doi.org/10.1016/j.jorganchem.2020.121337	Recent advances and prospects in the nickel- catalyzed cyanation	Synthesis of triarylmethanes via metal-free reductive coupling of diaryl ketone, tosylhydrazide, and arylboronic acids has been developed. This methodology is realized via one-pot two-step reactions involving the preparation of N-tosylhydrazones by reacting tosylhydrazide with diaryl ketone derivatives, followed by the reductive coupling with arylboronic acid in the presence of potassium carbonate to afford various triarylmethanes analogues in moderate to good yields. Importantly, the system presented here enables the use of easily accessible starting materials and a series of substrates with diverse functional group could be tolerant in this reaction. This approach could also be particularly useful for the synthesis of triaryl-substituted carbazolyl compounds.	J. Organomet. Chem.	80	Mathew, TV	FALSE	FALSE	FALSE	FALSE
2493	10.1021/acs.organomet.0c00387	doi.org/10.1021/acs.organomet.0c00387	Theoretical Study on the Formation of Ni(PR3)(Aryl)F Complexes Observed in Ni-Catalyzed Decarbonylative C-C Coupling of Acyl Fluorides	3-Naphthofuranyl-2-oxindoles were synthesized by the reaction of 3-(arylethynyl)-3-hydroxyindolin-2-ones and 2-naphthols via Friedel-Crafts reaction and a following Michael type 5-exo-dig cyclization. In addition, dihydrofuranyl-spirooxindoles were synthesized from 3-(ortho-hydroxyaryl)-2-oxindoles by base-catalyzed cyclization reaction. (C) 2016 Elsevier Ltd. All rights reserved.	Organometallics	80	Stirling, A	FALSE	FALSE	FALSE	FALSE
2494	10.1021/jacs.0c03298	doi.org/10.1021/jacs.0c03298	Catalytic and Photochemical Strategies to Stabilized Radicals Based on Anomeric Nucleophiles	Nickel-catalyzed cross-coupling reactions of aryl esters, carbamates, carbonates, ethers and arenols are reviewed. Carbon-oxygen bonds in these phenol derivatives cannot be activated by palladium, a typical cross-coupling catalyst, but a low valent nickel species in conjunction with a strong sigma-donor ligand is uniquely effective for achieving this. The review is organized primarily by substrate class and secondarily by coupling partners, encompassing organometallics, heteroatom nucleophiles, C-H bonds and many others. Although the reactions in this category are covered thoroughly, each reaction is described only briefly, so that it is possible to quickly overview the spectrum of nickel-catalyzed cross-coupling reactions of inert phenol derivatives. The robustness of inert phenol derivatives under typically used catalytic conditions as well as their utility as a directing group allow unique synthetic applications of these new C-O cross-coupling reactions, which is also included in cases where appropriate. Mechanistic aspects of C-O bond activation by nickel are also summarized, highlighting their diversity compared with the C-X bond activation involved in conventional cross-coupling processes.	J. Am. Chem. Soc.	80	Hong, X	TRUE	FALSE	FALSE	FALSE
2495	10.1021/acscatal.0c00393	doi.org/10.1021/acscatal.0c00393	Nickel-Catalyzed Amination of Aryl Thioethers: A Combined Synthetic and Mechanistic Study	Herein, we report an efficient, ligand-free, and additive-free Suzuki-Miyaura coupling that is compatible with the aromatic sulfonyl fluoride functional group. The protocol proceeds at room temperature, on water, and offers facile access to a wide range of biaryl sulfonyl fluorides as bioorthogonal click reagents.	ACS Catal.	80	Morandi, B	FALSE	FALSE	FALSE	FALSE
2496	10.1002/anie.201912408	doi.org/10.1002/anie.201912408	Enantioselective Synthesis of Isoxazolines Enabled by Palladium-Catalyzed Carboetherification of Alkenyl Oximes		Angew. Chem.-Int. Edit.	80	Zhang, JL	FALSE	FALSE	FALSE	FALSE
2497	10.1039/c9ob02258a	doi.org/10.1039/c9ob02258a	The impact of cation structure upon the acidity of triazolium salts in dimethyl sulfoxide		Org. Biomol. Chem.	80	Harper, JB	FALSE	FALSE	FALSE	FALSE
2498	10.1016/j.tet.2019.130640	doi.org/10.1016/j.tet.2019.130640	Ligand-controlled phosphine-free Co(II)-catalysed cross-coupling of secondary and primary alcohols		Tetrahedron	80	Li, HX	FALSE	FALSE	FALSE	FALSE
2499	10.1021/acs.orglett.9b02820	doi.org/10.1021/acs.orglett.9b02820	Palladium-Catalyzed Highly Regioselective Aromatic Substitution of Benzylic Ammonium Salts with Amines		Org. Lett.	80	Tian, SK	FALSE	FALSE	FALSE	FALSE
2500	10.1021/acscatal.9b02641	doi.org/10.1021/acscatal.9b02641	Rhodium-Catalyzed Synthesis of Amides from Functionalized Blocked Isocyanates		ACS Catal.	80	Beauchemin, AM	FALSE	FALSE	FALSE	FALSE
2501	10.1002/ajoc.201900435	doi.org/10.1002/ajoc.201900435	A Highly Stable Porous Viologen Polymer for the Catalysis of Debromination Coupling of Benzyl Bromides with High Recyclability		Asian J. Org. Chem.	80	Zhang, DW; Li, ZT	FALSE	FALSE	FALSE	FALSE
2502	10.1021/jacs.9b03863	doi.org/10.1021/jacs.9b03863	Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes		J. Am. Chem. Soc.	80	Shu, XZ	FALSE	TRUE	FALSE	FALSE
2503	10.1021/acs.orglett.9b00774	doi.org/10.1021/acs.orglett.9b00774	Direct Transformation of Aryl 2-Pyridyl Esters to Secondary Benzylic Alcohols by Nickel Relay Catalysis		Org. Lett.	80	Qu, JP; Chen, YF	FALSE	FALSE	FALSE	FALSE
2504	10.1055/s-0037-1609636	doi.org/10.1055/s-0037-1609636	Nickel-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylates with Aryl Tosylates and Mesylates		Synthesis	80	Kalyani, D	FALSE	FALSE	FALSE	FALSE
2505	10.1016/j.tetlet.2018.12.043	doi.org/10.1016/j.tetlet.2018.12.043	Iron-catalyzed delta-selective conjugate addition of methyl and cyclopropyl Grignard reagents to alpha,beta,gamma,delta-unsaturated esters and amides		Tetrahedron Lett.	80	Urabe, H	FALSE	FALSE	FALSE	FALSE
2506	10.1039/c8qo01389f	doi.org/10.1039/c8qo01389f	Cp*Co(iii)-catalyzed N-alkylation of amines with secondary alcohols		Org. Chem. Front.	80	Sundararaju, B	FALSE	FALSE	FALSE	FALSE
2507	10.6023/cjoc201806038	doi.org/10.6023/cjoc201806038	Recent Advance in Ni-Catalyzed Reductive Cross-Coupling to Construct C(sp(2))-C(sp(2)) and C(sp(2))-C(sp(3)) Bonds		Chin. J. Org. Chem.	80	Jia, QF	FALSE	FALSE	FALSE	FALSE
2508	10.1021/acs.joc.8b02191	doi.org/10.1021/acs.joc.8b02191	Metal-Free Regioselective Monocyanation of Hydroxy-, Alkoxy-, and Benzyloxyarenes by Potassium Thiocyanate and Silica Sulfuric Acid as a Cyanating Agent		J. Org. Chem.	80	Sardarian, AR	FALSE	FALSE	FALSE	FALSE
2509	10.2174/1570179416666191104093533	doi.org/10.2174/1570179416666191104093533	Application of Palladium-Catalyzed Cross-Coupling Reactions in Organic Synthesis		Curr. Org. Synth.	80	Dwivedi, J	FALSE	FALSE	FALSE	FALSE
2510	10.1080/00958972.2018.1540779	doi.org/10.1080/00958972.2018.1540779	Synthesis, characterization, and catalytic activity of a new series of Ni(II), Cu(II), and Zn(II) complexes of N,N-O,O mixed-bidentate ligands for C-C cross-coupling reactions		J. Coord. Chem.	80	Bharathi, KS	FALSE	FALSE	FALSE	FALSE
2511	10.1002/slct.201802644	doi.org/10.1002/slct.201802644	NCN Nickel(II) Pincer Complexes of 5-tert-Butyl-1,3-bis(N-substituted benzimidazol-2 '-yl)benzenes: Solid and Solution State Behaviour		ChemistrySelect	80	Singh, HB	FALSE	FALSE	FALSE	FALSE
2512	10.1039/c8nj02184h	doi.org/10.1039/c8nj02184h	One-step highly selective borylation/Suzuki cross-coupling of two distinct aryl bromides in pure water		New J. Chem.	80	Duan, XH	FALSE	FALSE	FALSE	FALSE
2513	10.1002/ejoc.201800253	doi.org/10.1002/ejoc.201800253	Cobalt(II)-Catalyzed N-Acylation of Amines through a Transamidation Reaction		Eur. J. Org. Chem.	80	Gong, H	FALSE	FALSE	FALSE	FALSE
2514	10.1016/j.apcata.2018.04.031	doi.org/10.1016/j.apcata.2018.04.031	Stilbene synthesis through decarboxylative cross-coupling of substituted cinnamic acids with aryl halides		Appl. Catal. A-Gen.	80	Djakovitch, L	FALSE	FALSE	FALSE	FALSE
2515	10.1002/anie.201712829	doi.org/10.1002/anie.201712829	Stereospecific Nucleophilic Substitution with Arylboronic Acids as Nucleophiles in the Presence of a CONH Group		Angew. Chem.-Int. Edit.	80	Tang, WJ	FALSE	FALSE	FALSE	FALSE
2516	10.1002/asia.201701766	doi.org/10.1002/asia.201701766	Programmable Self-Assembly of Heterometallic Palladium(II)-Copper(II) 1D Grid-Chain using Dinuclear Palladium(II) Corners with Pyrazole-Carboxylic Acid Ligands		Chem.-Asian J.	80	Tong, J; Yu, SY	FALSE	FALSE	FALSE	FALSE
2517	10.1021/acs.organomet.8b00046	doi.org/10.1021/acs.organomet.8b00046	Ni(COD)(2)-Catalyzed ipso-Silylation of 2-Methoxynaphthalene: A Density Functional Theory Study		Organometallics	80	Avasare, V	FALSE	FALSE	FALSE	FALSE
2518	10.1039/c8sc00210j	doi.org/10.1039/c8sc00210j	Copper-catalyzed formylation of alkenyl C-H bonds using BrCHCl2 as a stoichiometric formylating reagent		Chem. Sci.	80	Wang, XS	FALSE	FALSE	FALSE	FALSE
2519	10.1055/s-0037-1609093	doi.org/10.1055/s-0037-1609093	Recent Progress in Methylation of (Hetero)Arenes by Cross-Coupling or C-H Activation		Synlett	80	Liao, XB	FALSE	FALSE	FALSE	FALSE
2520	10.1021/acs.joc.7b02588	doi.org/10.1021/acs.joc.7b02588	Rapidly Activating Pd-Precatalyst for Suzuki-Miyaura and Buchwald-Hartwig Couplings of Aryl Esters		J. Org. Chem.	80	Hazari, N	FALSE	FALSE	FALSE	FALSE
2521	10.1002/asia.201701342	doi.org/10.1002/asia.201701342	Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents		Chem.-Asian J.	80	Wang, ZX	FALSE	FALSE	FALSE	FALSE
2522	10.1021/acs.orglett.7b02983	doi.org/10.1021/acs.orglett.7b02983	Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones		Org. Lett.	80	Li, XW	FALSE	FALSE	FALSE	FALSE
2523	10.1007/s10904-017-0636-3	doi.org/10.1007/s10904-017-0636-3	Silica Functionalized Magnetic Nickel Ferrite Nanoparticles as an Efficient Recyclable Catalyst for S-Arylation in Aqueous Medium		J. Inorg. Organomet. Polym. Mater.	80	Islam, SM	FALSE	FALSE	FALSE	FALSE
2524	10.1021/acs.joc.5b00825	doi.org/10.1021/acs.joc.5b00825	Ascorbic Acid Promoted Oxidative Arylation of Vinyl Arenes to 2-Aryl Acetophenones without Irradiation at Room Temperature under Aerobic Conditions		J. Org. Chem.	80	Ranu, BC	FALSE	FALSE	FALSE	FALSE
2525	10.1002/ejoc.201500321	doi.org/10.1002/ejoc.201500321	The Aza-Achmatowicz Reaction: Facile Entry into Functionalized Piperidinones		Eur. J. Org. Chem.	80	Rutjes, FPJT	FALSE	FALSE	FALSE	FALSE
2526	10.1021/ja510563d	doi.org/10.1021/ja510563d	Traceless Directing Groups in Radical Cascades: From Oligoalkynes to Fused Helicenes without Tethered Initiators		J. Am. Chem. Soc.	80	Alabugin, IV	FALSE	FALSE	FALSE	FALSE
2527	10.1039/c4cc09899d	doi.org/10.1039/c4cc09899d	Rhodium-catalysed direct C-H allylation of N-sulfonyl ketimines with allyl carbonates		Chem. Commun.	80	Qin, OY	FALSE	FALSE	FALSE	FALSE
2528	10.1002/ejoc.201402919	doi.org/10.1002/ejoc.201402919	Nickel-Catalyzed Desulfitative Suzuki-Miyaura Cross-Coupling of N,N-Disulfonylmethylamines and Arylboronic Acids		Eur. J. Org. Chem.	80	Yu, JJ	FALSE	FALSE	FALSE	FALSE
2529	10.1021/ja5029793	doi.org/10.1021/ja5029793	Ni-Catalyzed Direct Reductive Amidation via C-O Bond Cleavage		J. Am. Chem. Soc.	80	Martin, R	FALSE	FALSE	FALSE	FALSE
2530	10.1039/c4sc01257g	doi.org/10.1039/c4sc01257g	A synthetic and mechanistic investigation into the cobalt(I) catalyzed amination of aryl halides		Chem. Sci.	80	Fout, AR	FALSE	FALSE	FALSE	FALSE
2531	10.1039/c4ra08517e	doi.org/10.1039/c4ra08517e	Monodisperse amorphous CuB23 alloy short nanotubes: novel efficient catalysts for Heck coupling of inactivated alkyl halides and alkenes		RSC Adv.	80	Tong, DG	FALSE	FALSE	FALSE	FALSE
2532	10.1039/c3ob41376d	doi.org/10.1039/c3ob41376d	Efficient cross-coupling of aryl Grignard reagents with alkyl halides by recyclable ionic iron(III) complexes bearing a bis(phenop-functionalized benzimidazolium cation		Org. Biomol. Chem.	80	Sun, HM	FALSE	FALSE	FALSE	FALSE
2533	10.1016/j.tetlet.2013.07.043	doi.org/10.1016/j.tetlet.2013.07.043	Nickel-catalyzed decarboxylative cycloaddition of isatoic anhydrides with alkenes		Tetrahedron Lett.	80	Yang, SD	FALSE	FALSE	FALSE	FALSE
2534	10.1021/ja401344e	doi.org/10.1021/ja401344e	Nickel-Catalyzed Direct Alkylation of C-H Bonds in Benzamides and Acrylamides with Functionalized Alkyl Halides via Bidentate-Chelation Assistance		J. Am. Chem. Soc.	80	Chatani, N	FALSE	FALSE	FALSE	FALSE
2535	10.1002/adsc.201200771	doi.org/10.1002/adsc.201200771	Lewis Acid-Catalyzed Ring-Opening Functionalizations of 1,4-Epoxy-1,4-dihydronaphthalenes		Adv. Synth. Catal.	80	Sawama, Y	FALSE	FALSE	FALSE	FALSE
2536	10.1021/ja302640p	doi.org/10.1021/ja302640p	alpha-Glycosylation by D-Glucosamine-Derived Donors: Synthesis of Heparosan and Heparin Analogues That Interact with Mycobacterial Heparin-Binding Hemagglutinin		J. Am. Chem. Soc.	80	Chyan, CL	FALSE	FALSE	FALSE	FALSE
2537	10.1021/om300154m	doi.org/10.1021/om300154m	Pd(eta(3)-1-PhC3H4)(eta(5)-C5H5), an Unusually Effective Catalyst Precursor for Suzuki-Miyaura Cross-Coupling Reactions Catalyzed by Bis-Phosphine Palladium(0) Compounds		Organometallics	80	Baird, MC	FALSE	FALSE	FALSE	FALSE
2538	10.1039/c2dt30886j	doi.org/10.1039/c2dt30886j	Nickel complexes supported by quinoline-based ligands: synthesis, characterization and catalysis in the cross-coupling of arylzinc reagents and aryl chlorides or aryltrimethylammonium salts		Dalton Trans.	80	Wang, ZX	FALSE	FALSE	FALSE	FALSE
2539	10.1039/c1sc00230a	doi.org/10.1039/c1sc00230a	Nickel-catalyzed amination of aryl carbamates and sequential site-selective cross-couplings		Chem. Sci.	80	Garg, NK	FALSE	FALSE	FALSE	FALSE
2540	10.1039/c0sc00498g	doi.org/10.1039/c0sc00498g	Ru-catalyzed activation of sp(3) C-O bonds: O- to N-alkyl migratory rearrangement in pyridines and related heterocycles		Chem. Sci.	80	Dong, VM	FALSE	FALSE	FALSE	FALSE
2541	10.1002/ejoc.200901084	doi.org/10.1002/ejoc.200901084	Nickel-Catalyzed Solvent-Free Three-Component Coupling of Aldehyde, Alkyne and Amine		Eur. J. Org. Chem.	80	Pitchumani, K	FALSE	FALSE	FALSE	FALSE
2542	10.1021/jo025822o	doi.org/10.1021/jo025822o	Remote electronic effects in the rhodium-catalyzed nucleophilic ring opening of oxabenzonorbornadienes		J. Org. Chem.	80	Lautens, M	FALSE	FALSE	FALSE	FALSE
2543	10.1016/S0040-4020(02)00857-8	doi.org/10.1016/S0040-4020(02)00857-8	Pd-catalyzed regioselective acylation of alpha,beta-unsaturated ketone derivatives by acylzirconocene chloride as an acyl group donor		Tetrahedron	80	Hanzawa, Y	FALSE	FALSE	FALSE	FALSE
2544	10.1016/S0040-4020(01)87666-3	doi.org/10.1016/S0040-4020(01)87666-3	REGIOCHEMICAL DIVERSITY IN ALLYLIC ALKYLATIONS VIA MOLYBDENUM CATALYSTS		Tetrahedron	80	TROST, BM	FALSE	FALSE	FALSE	FALSE
2545	10.1002/anie.202112876	doi.org/10.1002/anie.202112876	Nickel-Catalyzed Reductive C-Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes		Angew. Chem.-Int. Edit.	80	Shu, XZ	FALSE	TRUE	FALSE	FALSE
2546	10.1039/d1sc05451a	doi.org/10.1039/d1sc05451a	Ligand-controlled regioselective and chemodivergent defluorinative functionalization of gem-difluorocyclopropanes with simple ketones		Chem. Sci.	80	Lv, LY; Li, ZP	FALSE	FALSE	FALSE	FALSE
2547	10.1021/acs.joc.1c01930	doi.org/10.1021/acs.joc.1c01930	pH-Mediated Selective Synthesis of N-Allylic Alkylation or N-Alkylation Amines with Allylic Alcohols via an Iridium Catalyst in Water		J. Org. Chem.	80	Luo, RS	FALSE	FALSE	FALSE	FALSE
2548	10.1038/s41467-021-24031-w	doi.org/10.1038/s41467-021-24031-w	Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation		Nat. Commun.	80	Shibata, N	FALSE	FALSE	FALSE	FALSE
2549	10.1039/d0ra10248b	doi.org/10.1039/d0ra10248b	Biradical o-iminobenzosemiquinonato(1-) complexes of nickel(ii): catalytic activity in three-component coupling of aldehydes, amines and alkynes		RSC Adv.	80	Safaei, E	FALSE	FALSE	FALSE	FALSE
2550	10.1246/cl.200793	doi.org/10.1246/cl.200793	Synthesis of Polymers with Regulated Repeating Structures by Utilizing Chain Walking Strategy		Chem. Lett.	80	Takeuchi, D	FALSE	FALSE	FALSE	FALSE
2551	10.1002/anie.202101076	doi.org/10.1002/anie.202101076	Diverse Synthesis of Chiral Trifluoromethylated Alkanes via Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Fluoroalkylation		Angew. Chem.-Int. Edit.	80	Wang, XS	FALSE	FALSE	FALSE	FALSE
2552	10.1021/acs.jpcc.7b06972	doi.org/10.1021/acs.jpcc.7b06972	First-Principles Molecular Dynamics Analysis of Ligand-Free Suzuki-Miyaura Cross-Coupling in Water: Transmetalation and Reductive Elimination		J. Phys. Chem. C	80	Hirakawa, T; Morikawa, Y	FALSE	FALSE	FALSE	FALSE
2553	10.1002/anie.201703704	doi.org/10.1002/anie.201703704	Enantioselective Synthesis of Tetrahydroquinolines by Borrowing Hydrogen Methodology: Cooperative Catalysis by an Achiral Iridacycle and a Chiral Phosphoric Acid		Angew. Chem.-Int. Edit.	80	Yu, Z	FALSE	FALSE	FALSE	FALSE
2554	10.1002/anie.201703174	doi.org/10.1002/anie.201703174	Mizoroki-Heck Cyclizations of Amide Derivatives for the Introduction of Quaternary Centers		Angew. Chem.-Int. Edit.	80	Garg, NK	FALSE	FALSE	FALSE	FALSE
2555	10.1021/acs.orglett.7b00556	doi.org/10.1021/acs.orglett.7b00556	Nickel-Catalyzed Synthesis of Primary Aryl and Heteroaryl Amines via C-O Bond Cleavage		Org. Lett.	80	Rueping, M	FALSE	FALSE	FALSE	FALSE
2556	10.1002/chem.201700680	doi.org/10.1002/chem.201700680	Mild, Aqueous -Arylation of Ketones: Towards New Diversification Tools for Halogenated Metabolites and Drug Molecules		Chem.-Eur. J.	80	Marelli, E; Goss, RJM	FALSE	FALSE	FALSE	FALSE
2557	10.1002/open.201600096	doi.org/10.1002/open.201600096	Direct Assembly of Prenylated Heteroarenes through a Cascade Minisci Reaction/Dehydration Sequence		ChemistryOpen	80	Wang, HG	FALSE	FALSE	FALSE	FALSE
2558	10.1021/acscatal.6b02323	doi.org/10.1021/acscatal.6b02323	Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Amides via Site-Selective N-C Bond Cleavage by Cooperative Catalysis		ACS Catal.	80	Szostak, M	FALSE	FALSE	FALSE	FALSE
2559	10.1039/c6nj01118g	doi.org/10.1039/c6nj01118g	Earth abundant metal complexes of donor functionalised N-heterocyclic carbene ligands: synthesis, characterisation and application as amination catalysts		New J. Chem.	80	Bala, MD	FALSE	FALSE	FALSE	FALSE
2560	10.6023/cjoc201601007	doi.org/10.6023/cjoc201601007	Progress in Iron Complexes-Catalyzed Organic Reactions		Chin. J. Org. Chem.	80	He, XW	FALSE	FALSE	FALSE	FALSE
2561	10.1016/j.tet.2015.11.016	doi.org/10.1016/j.tet.2015.11.016	Efficient and practical catalyst-free-like dehydrative N-alkylation of amines and sulfinamides with alcohols initiated by aerobic oxidation of alcohols under air		Tetrahedron	80	Xu, Q	FALSE	FALSE	FALSE	FALSE
2562	10.1039/d1gc00141h	doi.org/10.1039/d1gc00141h	Metal-free amino-controlled electrochemical intramolecular C-O and C-N couplings by site-selective activation of aryl C-N and C-O bonds	A palladium-catalyzed C(sp(3))-C(sp(2)) Suzuki-Miyaura cross-coupling of aryl boronic acids and alpha-(trifluoromethyl)benzyl tosylates is reported. A readily available, air-stable palladium catalyst was employed to access a wide range of functionalized 1,1-diaryl-2,2,2-trifluoroethanes. Enantioenriched alpha-(trifluoromethyl)benzyl tosylates were found to undergo cross-coupling to give the corresponding enantioenriched cross-coupled products with an overall inversion in configuration. The crucial role of the CF3 group in promoting this transformation is demonstrated by comparison with non-fluorinated derivatives.	Green Chem.	79	Li, JH	FALSE	FALSE	FALSE	FALSE
2563	10.1016/j.ica.2020.120182	doi.org/10.1016/j.ica.2020.120182	Unsymmetrical nickel (PCN) pincer complexes with a benzothiazole side-arm: Synthesis, characterization and electrochemical properties	Transition-metal-catalyzed or metal-free azide alkyne cycloadditions are methods to access 1,4 or 1,5-disubstituted 1,2,3-triazoles. Although the copper catalyzed cycloaddition to access 1,4-disubstituted products has been applied to biomolecular reaction systems, the azide alkyne cycloaddition to access the complementary 1,5-regioisomers under aqueous and ambient conditions remains a challenge due to limited substrate scope or moisture-/air-sensitive catalysts. Herein, we report a method to access 1,5-disubstituted 1,2,3-triazoles using a Cp2Ni/Xantphos catalytic system. The reaction proceeds both in water and organic solvents at room temperature. This protocol is simple and scalable with a broad substrate scope including both aliphatic and aromatic substrates. Moreover, triazoles attached with carbohydrates or amino acids are prepared via this cycloaddition.	Inorg. Chim. Acta	79	Luconi, L; Rossin, A	FALSE	FALSE	FALSE	FALSE
2564	10.1039/d0ob02489a	doi.org/10.1039/d0ob02489a	Highly enantioselective one-pot sequential synthesis of valerolactones and pyrazolones bearing all-carbon quaternary stereocentres	Pd/C was found to be an efficient and convenient metal catalyst in the homocoupling reaction for the synthesis of symmetrical biaryl diamides. The catalyst system Pd/C-KOAc showed high catalytic activity, and a variety of symmetrical biaryl diamides were conveniently synthesized from 2-halo-N-phenylbenzamides in moderate to good yields.	Org. Biomol. Chem.	79	Da, CS	FALSE	FALSE	FALSE	FALSE
2565	10.1002/anie.202011036	doi.org/10.1002/anie.202011036	Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel	The first example of palladium-catalyzed direct fotmylation,a arylzinc reagents using S-phenyl thioformate is reported. The reaction proceeded: under mild conditions, allowing high functional group tolerance. In: addition, the developed fotmylation method was used to prepare deuterated and C-13-labeled aryl aldehydes from isotope-labeled S-phenyl;., thioformates. Moreover, this procedure was applied to an alkenylzinc halide, affording the corresponding end.	Angew. Chem.-Int. Edit.	79	Zhou, JS	FALSE	FALSE	FALSE	FALSE
2566	10.1002/aoc.5983	doi.org/10.1002/aoc.5983	Palladium-catalyzed cross-coupling reactions of coumarin derivatives: An overview	A new method for the synthesis of 2-arylquinazolin-4-(3H)-ones that involves a three-component coupling reaction of 2-bromobenzamide, aryl aldehydes, and aqueous ammonia has been developed. This protocol employs Cu-Mn spinel oxide as a heterogeneous catalyst and does not require the presence of a ligand or external oxidant. Key features of the reaction include a recyclable catalyst, ligand-free conditions, and a wide scope of possible substrates. The mechanism begins with the replacement of the bromine atom with NH2 from aqueous ammonia followed by imine formation, intramolecular ring cyclization (C-N bond formation), and aromatization.	Appl. Organomet. Chem.	79	Mathew, TV	FALSE	FALSE	FALSE	FALSE
2567	10.1021/acs.orglett.0c02215	doi.org/10.1021/acs.orglett.0c02215	Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates	Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to become radical precursors in a net redox-neutral C-sp(3)-C-sp(2) cross-coupling with a broad range of aryl halides. This alcohol-activation coupling is successfully applied to the functionalization of a naturally occurring steroid and the expedient synthesis of a medicinally relevant drug lead.	Org. Lett.	79	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
2568	10.1039/d0gc01194k	doi.org/10.1039/d0gc01194k	Palladium nano-particles as a recyclable catalyst for C-O bond formation under solvent free conditions	The cobalt-catalyzed chelation assisted ortho C-H allylation of aromatic amides with unactivated aliphatic alkenes is reported. The reaction proceeds in air under mild reaction conditions, providing allylated products in good to excellent yields with high E-selectivities. This operationally simple method shows a high functional group tolerance.	Green Chem.	79	Khan, A	FALSE	FALSE	FALSE	FALSE
2569	10.1039/d0ob00881h	doi.org/10.1039/d0ob00881h	Synthesis of quinazoin-4-ones through an acid ion exchange resin mediated cascade reaction	Aryl carbamates were for the first time applied as electrophiles in the cross-coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non-sensitivity to steric hindrance on both aryl carbamates and arylsilanes.	Org. Biomol. Chem.	79	Li, WM	FALSE	FALSE	FALSE	FALSE
2570	10.1007/s11426-019-9732-5	doi.org/10.1007/s11426-019-9732-5	Photoredox/palladium-cocatalyzed enantioselective alkylation of secondary benzyl carbonates with 4-alkyl-1,4-dihydropyridines	2-Methallyl aromatic aldehydes, synthesized by Suzuki coupling of 2-formylphenylboronic acids, are shown to provide cycloalkylidene ene products under acidic conditions. Susceptibility of the products to aromatization is manoeuvred by varying the reaction conditions and catalysts including binol-derived Brensted acid catalysts. A peri-effect is identified as a controlling factor for the aromatizations. Several oxidative transformations of an ene product are carried out as model studies of hydroaromatic polyketide natural products. (C) 2016 Elsevier Ltd. All rights reserved.	Sci. China-Chem.	79	Yu, SY	TRUE	FALSE	FALSE	FALSE
2571	10.1021/acs.orglett.0c00551	doi.org/10.1021/acs.orglett.0c00551	Rhodium(III) Catalyzed Regioselective and Stereospecific Allylic Arylation in Water by beta-Fluorine Elimination of the Allylic Fluoride: Toward the Synthesis of Z-Alkenyl-Unsaturated Amides	A highly enantioselective copper/N-heterocyclic carbene catalyzed allylic arylation with organolithium compounds is presented. The use of commercial or readily prepared aryllithium reagents in the reaction with allyl bromides affords a variety of chiral diarylvinylmethanes, comprising a privileged structural motif in pharmaceuticals, in high yields with good to excellent regio- and enantioselectivities. The versatility of this new transformation is illustrated in the formal synthesis of the marketed drug tolterodine (Detrol).	Org. Lett.	79	Bouzbouz, S	FALSE	FALSE	FALSE	FALSE
2572	10.1002/anie.201916014	doi.org/10.1002/anie.201916014	Migratory Hydrogenation of Terminal Alkynes by Base/Cobalt Relay Catalysis	Copper-catalyzed electrophilic amination of a triarylboroxin using an N-methoxyamine to give quick access to a variety of anilines was reported. The reaction was especially useful for syntheses of functionalized anilines when combined with our previously reported nucleophilic addition to N-methoxyamides.	Angew. Chem.-Int. Edit.	79	Liu, Q	FALSE	FALSE	FALSE	FALSE
2573	10.1002/anie.201915864	doi.org/10.1002/anie.201915864	Asymmetric Three-Component Heck Arylation/Amination of Nonconjugated Cyclodienes		Angew. Chem.-Int. Edit.	79	Zhou, JS	FALSE	FALSE	FALSE	FALSE
2574	10.1021/jacs.9b12328	doi.org/10.1021/jacs.9b12328	Potent Reductants via Electron-Primed Photoredox Catalysis: Unlocking Aryl Chlorides for Radical Coupling		J. Am. Chem. Soc.	79	Wickens, ZK	TRUE	TRUE	FALSE	FALSE
2575	10.1002/anie.201911012	doi.org/10.1002/anie.201911012	Synthesis of All-Carbon Quaternary Centers by Palladium-Catalyzed Olefin Dicarbofunctionalization		Angew. Chem.-Int. Edit.	79	Glorius, F	FALSE	FALSE	FALSE	FALSE
2576	10.1021/jacs.9b08961	doi.org/10.1021/jacs.9b08961	Mechanism and Scope of Nickel-Catalyzed Decarbonylative Borylation of Carboxylic Acid Fluorides		J. Am. Chem. Soc.	79	Sanford, MS	FALSE	FALSE	FALSE	FALSE
2577	10.1039/c9dt02876e	doi.org/10.1039/c9dt02876e	Computational assessment on the Tolman cone angles for P-ligands		Dalton Trans.	79	Jover, J	FALSE	FALSE	FALSE	FALSE
2578	10.1021/acs.orglett.9b02577	doi.org/10.1021/acs.orglett.9b02577	Nickel-Catalyzed Asymmetric Intramolecular Reductive Heck Reaction of Unactivated Alkenes		Org. Lett.	79	Wang, C	FALSE	FALSE	FALSE	FALSE
2579	10.1021/acsomega.9b00567	doi.org/10.1021/acsomega.9b00567	Base Metal-Catalyzed Direct Olefinations of Alcohols with Sulfones		ACS Omega	79	Maji, B	FALSE	FALSE	FALSE	FALSE
2580	10.1002/slct.201803770	doi.org/10.1002/slct.201803770	Copper Immobilized on Isonicotinic Acid Hydrazide Functionalized Nano-Magnetite as a Novel Recyclable Catalyst for Direct Synthesis of Phenols and Anilines		ChemistrySelect	79	Soleiman-Beigi, M	FALSE	FALSE	FALSE	FALSE
2581	10.1039/c8qo01425f	doi.org/10.1039/c8qo01425f	Ruthenium(ii)-catalyzed C-O/C-S cyclization for the synthesis of 5-membered O-containing and S-containing heterocycles		Org. Chem. Front.	79	Hu, LH	FALSE	FALSE	FALSE	FALSE
2582	10.1002/aoc.4691	doi.org/10.1002/aoc.4691	NiFe2O4 as a magnetically recoverable nanocatalyst for odourless C-S bond formation via the cleavage of C-O bond in the presence of S-8 under mild and green conditions		Appl. Organomet. Chem.	79	Zolfigol, MA	FALSE	FALSE	FALSE	FALSE
2583	10.1016/j.tet.2019.01.015	doi.org/10.1016/j.tet.2019.01.015	Practical and scalable preparation of Minodronic acid and Zolpidem from 2-chloroimidazole[1,2-a]pyridines		Tetrahedron	79	Lei, XS	FALSE	FALSE	FALSE	FALSE
2584	10.1039/c8sc04996c	doi.org/10.1039/c8sc04996c	Direct N-O bond formation via oxidation of amines with benzoyl peroxide		Chem. Sci.	79	Banerjee, A; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
2585	10.1002/slct.201803144	doi.org/10.1002/slct.201803144	Ligand-Free Cu-Catalyzed Suzuki Coupling of Alkynyl Bromides with Boronic Acids in Ethanol Under Microwave Irradiation		ChemistrySelect	79	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
2586	10.1021/jacs.8b12634	doi.org/10.1021/jacs.8b12634	Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates		J. Am. Chem. Soc.	79	Sigman, MS; Minteer, SD	FALSE	TRUE	FALSE	FALSE
2587	10.1039/c8ob02539h	doi.org/10.1039/c8ob02539h	Efficient synthesis of esters through oxone- catalyzed dehydrogenation of carboxylic acids and alcohols		Org. Biomol. Chem.	79	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
2588	10.1126/science.aat2299	doi.org/10.1126/science.aat2299	Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization		Science	79	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
2589	10.1021/jacs.8b09849	doi.org/10.1021/jacs.8b09849	A Highly Reduced Ni-Li-Olefin Complex for Catalytic Kumada-Corriu Cross-Couplings		J. Am. Chem. Soc.	79	Cornella, J	FALSE	FALSE	FALSE	FALSE
2590	10.1002/adsc.201701563	doi.org/10.1002/adsc.201701563	Pd-PEPPSI: Water-Assisted Suzuki-Miyaura Cross-Coupling of Aryl Esters at Room Temperature using a Practical Palladium-NHC (NHC=N-Heterocyclic Carbene) Precatalyst		Adv. Synth. Catal.	79	Szostak, M	FALSE	FALSE	FALSE	FALSE
2591	10.1186/s12915-017-0427-x	doi.org/10.1186/s12915-017-0427-x	A Drosophila female pheromone elicits species-specific long-range attraction via an olfactory channel with dual specificity for sex and food		BMC Biol.	79	Lebreton, S; Becher, PG; Witzgall, P	FALSE	FALSE	FALSE	FALSE
2592	10.1021/jacs.5b08103	doi.org/10.1021/jacs.5b08103	Ni-Catalyzed Borylation of Aryl Fluorides via C-F Cleavage		J. Am. Chem. Soc.	79	Martin, R	FALSE	FALSE	FALSE	FALSE
2593	10.1002/anie.201502379	doi.org/10.1002/anie.201502379	Ligand-Free Copper-Catalyzed Negishi Coupling of Alkyl-, Aryl-, and Alkynylzinc Reagents with Heteroaryl Iodides		Angew. Chem.-Int. Edit.	79	Giri, R	FALSE	FALSE	FALSE	FALSE
2594	10.1039/c5cc01163a	doi.org/10.1039/c5cc01163a	A sustainable and simple catalytic system for direct alkynylation of C(sp(2))-H bonds with low nickel loadings		Chem. Commun.	79	Shi, BF	FALSE	FALSE	FALSE	FALSE
2595	10.1039/c4cc10431e	doi.org/10.1039/c4cc10431e	Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes		Chem. Commun.	79	Lu, HJ	FALSE	FALSE	FALSE	FALSE
2596	10.1002/chem.201404705	doi.org/10.1002/chem.201404705	[(IPent) PdCl2(morpholine)]: A Readily Activated Precatalyst for Room-Temperature, Additive-Free Carbon-Sulfur Coupling		Chem.-Eur. J.	79	Organ, MG	FALSE	FALSE	FALSE	FALSE
2597	10.1021/ol503004a	doi.org/10.1021/ol503004a	Structurally Diverse alpha-Substituted Benzopyran Synthesis through a Practical Metal-Free C(sp(3))-H Functionalization		Org. Lett.	79	Lou, HX	FALSE	FALSE	FALSE	FALSE
2598	10.1021/jo501361k	doi.org/10.1021/jo501361k	Cobalt-Catalyzed C-H Arylations, Benzylations, and Alkylations with Organic Electrophiles and Beyond		J. Org. Chem.	79	Ackermann, L	FALSE	TRUE	FALSE	FALSE
2599	10.1055/s-0033-1339108	doi.org/10.1055/s-0033-1339108	Copper-Catalyzed Cross-Coupling of Aryl- and Heteroaryltriethoxysilanes with Aryl and Heteroaryl Iodides and Bromides		Synthesis	79	Giri, R	FALSE	FALSE	FALSE	FALSE
2600	10.1021/jo500619f	doi.org/10.1021/jo500619f	Nickel-Catalyzed Cross-Coupling of Aryl Fluorides and Organozinc Reagents		J. Org. Chem.	79	Wang, ZX	FALSE	FALSE	FALSE	FALSE
2601	10.1021/ol500292c	doi.org/10.1021/ol500292c	Synthesis of Chiral alpha-Diarylacetic Esters by Stereospecific 1,2-Aryl Migration Promoted by in Situ Generated Acetals from Benzoins		Org. Lett.	79	Balamurugan, R	FALSE	FALSE	FALSE	FALSE
2602	10.1002/chem.201303637	doi.org/10.1002/chem.201303637	Copper-Catalyzed Aromatic C-H Bond Cyanation by C-CN Bond Cleavage of Inert Acetonitrile		Chem.-Eur. J.	79	Shen, ZM	FALSE	FALSE	FALSE	FALSE
2603	10.1055/s-0033-1339918	doi.org/10.1055/s-0033-1339918	Palladium-Catalyzed Cyanation of Quinazoline-4-tosylates for Access to 4-CN-Functionalized Quinazolines		Synthesis	79	Peng, YY	FALSE	FALSE	FALSE	FALSE
2604	10.1021/ja407589e	doi.org/10.1021/ja407589e	Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides		J. Am. Chem. Soc.	79	Weix, DJ	FALSE	TRUE	FALSE	FALSE
2605	10.1002/ejoc.201201635	doi.org/10.1002/ejoc.201201635	Desymmetrization and Switching of Stereoselectivity in Direct Organocatalytic Michael Addition of Ketones to 1,1-Bis(phenylsulfonyl)ethylene		Eur. J. Org. Chem.	79	Chen, KM	FALSE	FALSE	FALSE	FALSE
2606	10.1021/ic302153s	doi.org/10.1021/ic302153s	Synthesis and Structural Characterization of Heteroboroxines with MB2O3 Core (M = Sb, Bi, Sn)		Inorg. Chem.	79	De Proft, F	FALSE	FALSE	FALSE	FALSE
2607	10.1002/ejoc.201201263	doi.org/10.1002/ejoc.201201263	Metal-Free Synthesis of Secondary Arylamines: An Aliphatic-to-Aromatic Transformation		Eur. J. Org. Chem.	79	Maycock, CD	FALSE	FALSE	FALSE	FALSE
2608	10.1002/adsc.201200280	doi.org/10.1002/adsc.201200280	Bronsted Acid-Promoted Divergent Reactions of Enaminones: Efficient Synthesis of Fused Pyrroles with Different Substitution Patterns		Adv. Synth. Catal.	79	Jiang, B	FALSE	FALSE	FALSE	FALSE
2609	10.1002/chem.201201394	doi.org/10.1002/chem.201201394	Palladium-Catalyzed Mono-alpha-Arylation of Acetone with Aryl Imidazolylsulfonates		Chem.-Eur. J.	79	Ackermann, L	FALSE	FALSE	FALSE	FALSE
2610	10.1021/cs300028y	doi.org/10.1021/cs300028y	Iron-Catalyzed Direct Suzuki-Miyaura Reaction: Theoretical and Experimental Studies on the Mechanism and the Regioselectivity		ACS Catal.	79	Hu, CW	FALSE	FALSE	FALSE	FALSE
2611	10.1039/c1ob06743e	doi.org/10.1039/c1ob06743e	Copper-catalyzed N-alkylation of amides and amines with alcohols employing the aerobic relay race methodology		Org. Biomol. Chem.	79	Xu, Q	FALSE	FALSE	FALSE	FALSE
2612	10.1002/adsc.201100165	doi.org/10.1002/adsc.201100165	Synthesis of Arylated Quinolines by Chemo- and Site-selective Suzuki-Miyaura Reactions of 5,7-Dibromo-8-(trifluoromethanesulfonyloxy)quinoline		Adv. Synth. Catal.	79	Langer, P	FALSE	FALSE	FALSE	FALSE
2613	10.1016/j.tetlet.2010.11.133	doi.org/10.1016/j.tetlet.2010.11.133	Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates: development and optimization of a mild and stereospecific coupling process		Tetrahedron Lett.	79	Denmark, SE	FALSE	FALSE	FALSE	FALSE
2614	10.1039/c1cc11930c	doi.org/10.1039/c1cc11930c	One pot iridium-catalyzed asymmetrical double allylations of sodium sulfide: a fast and economic way to construct chiral C-2-symmetric bis(1-substituted-allyl)sulfane		Chem. Commun.	79	Zhao, XM	FALSE	FALSE	FALSE	FALSE
2615	10.1002/ijch.201000032	doi.org/10.1002/ijch.201000032	Cobalt-Catalyzed Cross-Coupling Reactions Aryl Halides		Isr. J. Chem.	79	Gosmini, C	FALSE	FALSE	FALSE	FALSE
2616	10.1055/s-0029-1218275	doi.org/10.1055/s-0029-1218275	Tunable, Regioselective Control of Iodine-Catalyzed Allylic Substitution of Cyclic Baylis-Hillman Adducts with Indoles		Synlett	79	Liu, L	FALSE	FALSE	FALSE	FALSE
2617	10.1016/j.tet.2007.06.043	doi.org/10.1016/j.tet.2007.06.043	Catalytic, asymmetric alkylation of imines		Tetrahedron	79	Ferraris, D	FALSE	FALSE	FALSE	FALSE
2618	10.1016/j.jorganchem.2007.01.021	doi.org/10.1016/j.jorganchem.2007.01.021	Electron transfer, in organonickel complexes of alpha-diimines: Versatile redox catalysts for C-C or C-P coupling reactions - A review		J. Organomet. Chem.	79	Klein, A	FALSE	TRUE	FALSE	FALSE
2619	10.1002/adsc.200505409	doi.org/10.1002/adsc.200505409	Nickel(0)/imidazolium carbene catalyst system for efficient cross-coupling of aryl bromides and chlorides with organomanganese reagents		Adv. Synth. Catal.	79	Schneider, R	FALSE	FALSE	FALSE	FALSE
2620	10.1016/j.tet.2005.03.078	doi.org/10.1016/j.tet.2005.03.078	Pd-2(dba)(3)/Xantphos-catalyzed cross-coupling of thiols and aryl bromides/triflates		Tetrahedron	79	Perrio, S	FALSE	FALSE	FALSE	FALSE
2621	10.1016/j.tetasy.2004.06.052	doi.org/10.1016/j.tetasy.2004.06.052	In situ enzymatic screening (ISES) of P,N-ligands for Ni(0)-mediated asymmetric intramolecular allylic amination		Tetrahedron-Asymmetry	79	Berkowitz, DB	FALSE	FALSE	FALSE	FALSE
2622	10.1016/j.tet.2003.06.001	doi.org/10.1016/j.tet.2003.06.001	Synthesis and reactivity of lithium tri(quinolinyl)magnesates		Tetrahedron	79	Mongin, F	FALSE	FALSE	FALSE	FALSE
2623	10.1016/0022-328X(95)06042-U	doi.org/10.1016/0022-328X(95)06042-U	Regio- and stereoselective a(4)-umpolung reactions of alpha,beta-unsaturated esters to 1,6-dicarbonyl compounds by addition of enantiopure nucleophiles to racemic tetracarbonyl(eta(3)-allyl)iron(1+) complexes		J. Organomet. Chem.	79	Enders, D	FALSE	FALSE	FALSE	FALSE
2624	10.5059/yukigoseikyokaishi.46.356	doi.org/10.5059/yukigoseikyokaishi.46.356	MOLECULAR-BASIS OF CATALYTIC REACTIONS INVOLVING OLEFIN AND ALLYL COMPLEXES OF GROUP-10 METALS		J. Synth. Org. Chem. Jpn.	79	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
2625	10.1002/chem.202103653	doi.org/10.1002/chem.202103653	Regioselective Fluorination of Acenes: Tailoring of Molecular Electronic Levels and Solid-State Properties		Chem.-Eur. J.	79	Witte, G	FALSE	TRUE	FALSE	FALSE
2626	10.1002/aoc.6549	doi.org/10.1002/aoc.6549	DFT study on the mechanisms of alpha-C cross coupling of pi-bonds catalyzed by iron complexes		Appl. Organomet. Chem.	79	Ren, QH	FALSE	FALSE	FALSE	FALSE
2627	10.1002/cctc.202101455	doi.org/10.1002/cctc.202101455	Nickel(II)-Catalyzed Selective (E)-Olefination of Methyl Heteroarenes Using Benzyl Alcohols via Acceptorless Dehydrogenative Coupling Reaction		ChemCatChem	79	Ramesh, R	FALSE	FALSE	FALSE	FALSE
2628	10.1039/d1cc05949a	doi.org/10.1039/d1cc05949a	Contrasteric coupling of allenes and tetrahydroisoquinolines by iron-catalysed allenic C(sp(2))-H functionalisation		Chem. Commun.	79	Wang, YD; Wang, YM	FALSE	FALSE	FALSE	FALSE
2629	10.1021/acs.joc.1c00613	doi.org/10.1021/acs.joc.1c00613	Stereoselective Synthesis of cis-2-Ene-1,4-diones via Aerobic Oxidation of Substituted Furans Catalyzed by ABNO/HNO3		J. Org. Chem.	79	Zhang, ZG; Xie, XM	FALSE	FALSE	FALSE	FALSE
2630	10.3390/molecules26175390	doi.org/10.3390/molecules26175390	Porphyrin N-Pincer Pd(II)-Complexes in Water: A Base-Free and Nature-Inspired Protocol for the Oxidative Self-Coupling of Potassium Aryltrifluoroborates in Open-Air		Molecules	79	Venkateswarlu, K	FALSE	FALSE	FALSE	FALSE
2631	10.1055/a-1581-0934	doi.org/10.1055/a-1581-0934	Nickel-Catalyzed Paired Electrochemical Cross-Coupling of Aryl Halides with Nucleophiles		Synthesis	79	Li, C	FALSE	TRUE	FALSE	FALSE
2632	10.1021/acs.joc.1c01325	doi.org/10.1021/acs.joc.1c01325	N,N,N',N'-Tetramethylethylenediamine-Enabled PhotoredoxCatalyzed C-H Methylation of N-Heteroarenes		J. Org. Chem.	79	Chen, K; Xiang, HY; Yang, H	TRUE	FALSE	FALSE	FALSE
2633	10.1002/chem.202102347	doi.org/10.1002/chem.202102347	ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand		Chem.-Eur. J.	79	Wang, Y	FALSE	TRUE	FALSE	FALSE
2634	10.1246/bcsj.20210148	doi.org/10.1246/bcsj.20210148	YCatalyzed Intramolecular Aromatic C-H Acylation of 2-Arylbenzoyl Fluorides		Bull. Chem. Soc. Jpn.	79	Ogiwara, Y; Sakai, N	FALSE	FALSE	FALSE	FALSE
2635	10.1021/acs.orglett.7b01631	doi.org/10.1021/acs.orglett.7b01631	Chiral Cyclic Ligand-Enabled Iridium-Catalyzed Asymmetric Arylation of Unactivated Racemic Allylic Alcohols with Anilines		Org. Lett.	79	Fu, H	FALSE	FALSE	FALSE	FALSE
2636	10.1002/chem.201701665	doi.org/10.1002/chem.201701665	Lanthanide Ions Coupled with Photoinduced Electron Transfer Generate Strong Reduction Potentials from Visible Light		Chem.-Eur. J.	79	Konig, B	TRUE	TRUE	FALSE	FALSE
2637	10.1002/anie.201610203	doi.org/10.1002/anie.201610203	NHC-Organocatalyzed C-Ar-O Bond Cleavage: Mild Access to 2-Hydroxybenzophenones		Angew. Chem.-Int. Edit.	79	Glorius, F	FALSE	FALSE	FALSE	FALSE
2638	10.1055/s-0036-1588893	doi.org/10.1055/s-0036-1588893	Synthesis of Di- and Triarylmethanes through Palladium-Catalyzed Reductive Coupling of N-Tosylhydrazones and Aryl Bromides		Synthesis	79	Wang, JB	FALSE	FALSE	FALSE	FALSE
2639	10.1021/jacs.7b00268	doi.org/10.1021/jacs.7b00268	Facile Route to Quadruply Annulated Borepins		J. Am. Chem. Soc.	79	Wagner, M	FALSE	FALSE	FALSE	FALSE
2640	10.1016/j.tet.2016.12.068	doi.org/10.1016/j.tet.2016.12.068	One-pot reductive coupling reactions of acetyl naphthalene derivatives, tosylhydrazide, with arylboronic acids		Tetrahedron	79	Liu, P; Liu, Y	FALSE	FALSE	FALSE	FALSE
2641	10.1002/anie.201604696	doi.org/10.1002/anie.201604696	Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes		Angew. Chem.-Int. Edit.	79	Rueping, M	FALSE	FALSE	FALSE	FALSE
2642	10.1021/acs.orglett.6b02236	doi.org/10.1021/acs.orglett.6b02236	Nickel-Catalyzed Ortho-Arylation of Unactivated (Hetero)aryl C-H Bonds with Arylsilanes Using a Removable Auxiliary		Org. Lett.	79	Shi, BF	FALSE	FALSE	FALSE	FALSE
2643	10.1039/c6cc04410g	doi.org/10.1039/c6cc04410g	Atom-economical cobalt-catalysed regioselective coupling of epoxides and aziridines with alkenes		Chem. Commun.	79	Morandi, B	FALSE	FALSE	FALSE	FALSE
2644	10.1016/j.apcatb.2020.119425	doi.org/10.1016/j.apcatb.2020.119425	Size and stability modulation of Pd nanoparticles on porous hypercrosslinked ionic polymer for heterogeneous aerobic oxidative coupling of diaryl ether	Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (S(N)1 and S(N)2) have limited scope and are not generally amenable to enantioselective variants that employ readily available racemic electrophiles. Radical-based pathways catalyzed by chiral transition-metal complexes provide an attractive approach to addressing these limitations.	Appl. Catal. B-Environ.	78	Wang, J	FALSE	FALSE	FALSE	FALSE
2645	10.1021/acs.orglett.0c03342	doi.org/10.1021/acs.orglett.0c03342	Nickel-Catalyzed Directed Cross-Electrophile Coupling of Phenolic Esters with Alkyl Bromides	An efficient silver-catalyzed intermolecular decarboxylative arylation of quinolines has been developed using cheap aromatic carboxylic acids as arylating reagents under microwave irradiation. The reaction demonstrates a broad substrate scope and excellent functional group tolerance. This method provided an effective and easy way to synthesize arylated quinoline derivatives. The radical trapping experiments showed that this process involved the radical mechanism.	Org. Lett.	78	Wang, C	FALSE	TRUE	FALSE	FALSE
2646	10.1002/chem.202004132	doi.org/10.1002/chem.202004132	Directing Group-Promoted Inert C-O Bond Activation Using Versatile Boronic Acid as a Coupling Agent	An one-pot approach to benzoxazole ring from 2-aminophenol and aldehydes utilizing molecular sieve as the catalyst have been developed. The new oxidative cyclization reaction excluded the usage of hazardous chemical reagents, transition-metal catalysts, chemical oxidants, or strong acids, and, therefore, reduced the production of toxic chemical waste. This offers an environmentally friendly pathway for the synthesis of various benzoxazole derivatives. [GRAPHICS] .	Chem.-Eur. J.	78	Ong, TG	FALSE	FALSE	FALSE	FALSE
2647	10.1016/j.jorganchem.2020.121543	doi.org/10.1016/j.jorganchem.2020.121543	Synthesis and structures of amido-functionalized N-heterocyclic nickel(II) carbene complexes	A nickel-based catalyst was employed for the first time in the crossing-coupling of indenoindoles with bromo-/iodoarenes. A simple and practical method was provided for the synthesis of N-aryl substituted indenoindole and the mechanism of this reaction was discussed. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.	J. Organomet. Chem.	78	Liu, FC	FALSE	FALSE	FALSE	FALSE
2648	10.1039/d0qo01016b	doi.org/10.1039/d0qo01016b	Palladium-catalyzed tandem reaction of epoxynitriles with arylboronic acids in aqueous medium: divergent synthesis of furans and pyrroles	A two-step synthesis sequence furnishes quadruply annulated borepins in high yields. The first step involves a nucleophilic substitution reaction between aryl-BF3K salts (aryl = mesityl, phenyl) and lithiated bromonapthalene derivatives LiNaph(Br,R) (HNaph(Br,R) = 8-bromonaphthalene (a), 5-bromoacenaphthene (b), 5-bromoacenaphthylene (c)). In the second step, the resulting heteroleptic triarylboranes aryl-B(Naph(Br,R)), (3a-c) are subjected to an intramolecular Ni-mediated Yamamoto reaction to close the seven-membered rings and create the borepins 4a-c. Only in the case of 3b is the Yamamoto reaction accompanied by a C-H activation reaction furnishing the 7-hydro-7-borabenzo[de]anthracene derivative 5. The product ratio 4b/5 can be influenced by control of the local Ni(0) concentration. The borepins 4a-c are benchtop stable and highly soluble even in hexane. Compounds 4a-c undergo reversible one-electron reduction; 4c is also able to accept a second electron in a reversible manner and already at moderate potential values (E-1/2 = -1.49 V and -1.84 V (vs FcH/FcH(+))). 4a, 4b, and 5 show photoluminescence in the blue-green region of the spectrum, while 4c is nonfluorescent, which is likely attributable to an intramolecular charge-transfer transition.	Org. Chem. Front.	78	Lv, NN; Chen, JX	FALSE	FALSE	FALSE	FALSE
2649	10.1055/s-0040-1705954	doi.org/10.1055/s-0040-1705954	Nickel-Catalyzed Decarbonylative Alkynylation of Acyl Fluorides with Terminal Alkynes under Copper-Free Conditions	The development of fluorinated sulfone derivatives as versatile electrophiles for Suzuki Miyaura cross-coupling reactions is described. Introducing electron-withdrawing groups on the aryl ring of the sulfone facilitates the Pd-catalyzed activation of C-SO2 bonds. Cross-coupling reactions with fluorinated sulfone electrophiles are reported, leading to a variety of multiply arylated products in good yields. The reactivity of this unusual electrophile is benchmarked versus common electrophiles and its use in iterative cross-couplings for concise synthesis of biologically active molecules is described.	Synlett	78	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
2650	10.1002/ajoc.202000485	doi.org/10.1002/ajoc.202000485	Facile Construction of 3,4-dihydro-2H-1,2,4-Benzothiadiazine 1,1-Dioxides via Redox-Neutral Cascade Condensation/[1,7]-Hydride Transfer/Cyclization	The widespread and large scale use of platinum group metals, especially palladium, in a wide variety of industrial applications has seen their levels in wastewater streams, roadside dust and even pharmaceuticals significantly rise over recent years. Due to the possible environmental damage and potential health risk this may cause, there is now substantial demand for inexpensive, efficient and robust methods for the detection of palladium. Based upon self-immolative linker technologies, we have designed and synthesised a number of allyl ether-functionalised electrochemical probes to determine the optimum probe structure required to deliver a ratiometric electrochemical detection method capable of achieving a limit of detection of<1mg/mL within 20min through the use of disposable screen-printed carbon electrodes. Combined with an enzymatic assay, this method was then used to achieve a proof-of-principle ratiometric electrochemical molecular logic gate. [GRAPHICS]	Asian J. Org. Chem.	78	Wang, L; Li, SS	FALSE	FALSE	FALSE	FALSE
2651	10.1039/d0qo00479k	doi.org/10.1039/d0qo00479k	Computational study of catalyst-controlled regiodivergent pathways in hydroboration of 1,3-dienes: mechanism and origin of regioselectivity	A new transfer hydrofunctionalization strategy to turnover H-M-II-X complexes has enabled both intra- and intermolecular Mizoroki-Heck (MH)-type reactions of aryl cyanides that are challenging to realize under traditional, basic conditions. Initially, a cascade carbonickelation/MH reaction of 2-cyanostyrenes was achieved using a key alkyne transfer hydrocyanation step. Mechanistic experiments supported the proposed catalytic cycle, including the turnover-enabling transfer hydrocyanation step. The reactivity was then extended to the intermolecular MH reaction of benzonitriles and styrenes.	Org. Chem. Front.	78	Li, J	FALSE	FALSE	FALSE	FALSE
2652	10.1002/ejoc.202000672	doi.org/10.1002/ejoc.202000672	Intramolecular Nickel-Catalyzed Ring-Opening Reactions of Oxabenzonorbornadienes with C-1-Tethered Aryl Halides: An Improvement of Method	A facile method that allows for Ni(cod)(2) to be used on the benchtop is reported. The procedure involves the preparation of paraffin Ni(cod)(2) capsules, which are stable to air and moisture. It is demonstrated that these readily available capsules can be used to promote a range of Ni(cod)(2)-catalyzed transformations. These studies are expected to promote the further use of Ni(cod)(2) in organic synthesis.	Eur. J. Org. Chem.	78	Tam, W	FALSE	FALSE	FALSE	FALSE
2653	10.1021/jacs.0c02860	doi.org/10.1021/jacs.0c02860	Gold-Catalyzed Chemoselective Couplings of Polyfluoroarenes with Aryl Germanes and Downstream Diversification	The most important methods for the preparation of polyfunctional Zn and Mg reagents are highlighted. New perspectives for increasing the synthetic potential of these reagents including the use of Lewis acid catalysis, in situ trapping reactions, continuous flow conditions, and solid, air-stable zinc organometallics are described.	J. Am. Chem. Soc.	78	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
2654	10.1021/acs.joc.9b03500	doi.org/10.1021/acs.joc.9b03500	Acyl Cyanides as Bifunctional Reagent: Application in Copper-Catalyzed Cyanoamidation and Cyanoesterification Reaction	A new strategy for the synthesis of acyl beta-C-glycosides is described. The reactivity of glyconitriles toward organometallic reagents such as organomagnesium or organolithium derivatives was studied, affording acyl beta-C-glycosides in moderate to good yields. In this study, glycal formation was efficiently prevented by deprotonating the hydroxyl group in position 2 of the glyconitriles during the process.	J. Org. Chem.	78	Chen, ZW; Ye, M	FALSE	FALSE	FALSE	FALSE
2655	10.1016/j.chempr.2020.01.009	doi.org/10.1016/j.chempr.2020.01.009	Access to Chiral Bisphenol Ligands (BPOL) through Desymmetrizing Asymmetric Ortho-Selective Halogenation	Easily reachable electron-poor/rich primary and secondary benzylic phosphates are suitably used as substrates for Friedel-Crafts benzylation reactions with only 1.2 equiv activated/deactivated arenes (no additional solvent) to access structurally and electronically diverse polyarylated alkanes with excellent yields and selectivities at room temperature. Specifically,. diversely substituted di/triarylmethanes are generated within 2-30 min using this approach. A wide number of electron-poor polyarylated alkanes are easily accomplished through this route by just tuning the phosphates.	Chem	78	Tse, YLS; Yeung, YY	FALSE	FALSE	FALSE	FALSE
2656	10.6023/cjoc201909015	doi.org/10.6023/cjoc201909015	Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C-H Functionalization of Arenes	This study details Ni-catalyzed cross coupling of aryl Grignard reagents with aryl halides in toluene, a nonpolar solvent with a high boiling point. The reaction was applied for the synthesis of various biaryls in good yields without the introduction of a large steric ligand. The Kumada-Tamao-Corriu(KTC) reaction in toluene was then successfully modified to proceed under neat conditions for the efficient syntheses of symmetrical biaryls, particularly in large-scale preparations. Unactivated aryl chlorides show higher reactivity than aryl bromides, particularly under neat conditions. Mechanistic investigations suggest a radical procedure for the catalytic cycle, and the origin of the radical intermediates being aryl halides.	Chin. J. Org. Chem.	78	He, YQ	FALSE	FALSE	FALSE	FALSE
2657	10.1021/jacs.9b08734	doi.org/10.1021/jacs.9b08734	Ni-Catalyzed Asymmetric Allylation of Secondary Phosphine Oxides		J. Am. Chem. Soc.	78	Zhang, QW	FALSE	FALSE	FALSE	FALSE
2658	10.1016/j.tetlet.2019.07.029	doi.org/10.1016/j.tetlet.2019.07.029	Nondissociative chain walking as a strategy in catalytic organic synthesis		Tetrahedron Lett.	78	Kochi, T	FALSE	FALSE	FALSE	FALSE
2659	10.1039/c9sc00892f	doi.org/10.1039/c9sc00892f	Highly-chemoselective step-down reduction of carboxylic acids to aromatic hydrocarbons via palladium catalysis		Chem. Sci.	78	Szostak, M	FALSE	FALSE	FALSE	FALSE
2660	10.1021/acscatal.9b00336	doi.org/10.1021/acscatal.9b00336	Palladium-Catalyzed Stereospecific C-Glycosylation of Glycals with Vinylogous Acceptors		ACS Catal.	78	Zhang, Q	FALSE	FALSE	FALSE	FALSE
2661	10.1021/acscatal.8b04444	doi.org/10.1021/acscatal.8b04444	Are Bronsted Acids the True Promoter of Metal-Triflate-Catalyzed Glycosylations? A Mechanistic Probe into 1,2-cis-Aminoglycoside Formation by Nickel Triflate		ACS Catal.	78	Schlegel, HB; Nguyen, HM	FALSE	FALSE	FALSE	FALSE
2662	10.1021/acs.joc.8b02701	doi.org/10.1021/acs.joc.8b02701	Combination of PhI(OAc)(2) and 2-Nitropropane as the Source of Methyl Radical in Room-Temperature Metal-Free Oxidative Decarboxylation/Cyclization: Construction of 6-Methyl Phenanthridines and 1-Methyl Isoquinolines		J. Org. Chem.	78	Xu, S	FALSE	FALSE	FALSE	FALSE
2663	10.1021/acscatal.8b03436	doi.org/10.1021/acscatal.8b03436	Nickel-Catalyzed Heteroarenes Cross Coupling via Tandem C-H/C-O Activation		ACS Catal.	78	Ong, TG	FALSE	FALSE	FALSE	FALSE
2664	10.1021/acs.orglett.8b03167	doi.org/10.1021/acs.orglett.8b03167	Cobalt-Catalyzed C-F Bond Borylation of Aryl Fluorides		Org. Lett.	78	Lee, E	FALSE	FALSE	FALSE	FALSE
2665	10.1021/acs.orglett.8b02771	doi.org/10.1021/acs.orglett.8b02771	Aerobic Catalytic Features in Photoredox- and Copper-Catalyzed Iodolactonization Reactions		Org. Lett.	78	Li, W	TRUE	FALSE	FALSE	FALSE
2666	10.1002/anie.201807302	doi.org/10.1002/anie.201807302	Efficient Synthesis of (-)-Corynoline by Enantioselective Palladium-Catalyzed alpha-Arylation with Sterically Hindered Substrates		Angew. Chem.-Int. Edit.	78	Tang, WJ	FALSE	FALSE	FALSE	FALSE
2667	10.1021/jacs.8b04479	doi.org/10.1021/jacs.8b04479	Intermediacy of Ni-Ni Species in sp(2) C-O Bond Cleavage of Aryl Esters: Relevance in Catalytic C-Si Bond Formation		J. Am. Chem. Soc.	78	Martin, R	FALSE	FALSE	FALSE	FALSE
2668	10.1002/ajoc.201800057	doi.org/10.1002/ajoc.201800057	Salicylate-Directed C-O Bond Cleavage: Iron-Catalyzed Allylic Substitution with Grignard Reagents		Asian J. Org. Chem.	78	Li, ZP	FALSE	FALSE	FALSE	FALSE
2669	10.1021/jacs.7b12582	doi.org/10.1021/jacs.7b12582	Synthesis of Allylic Alcohols via Cu-Catalyzed Hydrocarbonylative Coupling of Alkynes with Alkyl Halides		J. Am. Chem. Soc.	78	Mankad, NP	FALSE	FALSE	FALSE	FALSE
2670	10.1002/adsc.201701368	doi.org/10.1002/adsc.201701368	Copper-Catalyzed Dehydrative Cyclization of 1-(2-Hydroxyphenyl)propargyl Alcohols with P(O)H Compounds for the Synthesis of 2-Phosphorylmethylbenzofurans		Adv. Synth. Catal.	78	Shen, RW	FALSE	FALSE	FALSE	FALSE
2671	10.1002/chem.201702015	doi.org/10.1002/chem.201702015	Ligand- and Solvent-Tuned Chemoselective Carbonylation of Bromoaryl Triflates		Chem.-Eur. J.	78	Jiao, HJ; Wu, XF	FALSE	FALSE	FALSE	FALSE
2672	10.1021/acs.orglett.5b03072	doi.org/10.1021/acs.orglett.5b03072	Organocatalytic Asymmetric Nucleophilic Addition to o-Quinone Methides by Alcohols		Org. Lett.	78	Sun, JW	FALSE	FALSE	FALSE	FALSE
2673	10.1002/anie.201507848	doi.org/10.1002/anie.201507848	Enantioselective Copper-Catalyzed Quinoline Alkynylation		Angew. Chem.-Int. Edit.	78	Aponick, A	FALSE	FALSE	FALSE	FALSE
2674	10.1002/chem.201502689	doi.org/10.1002/chem.201502689	Base-Promoted Coupling of Carbon Dioxide, Amines, and Diaryliodonium Salts: A Phosgene- and Metal-Free Route to O-Aryl Carbamates		Chem.-Eur. J.	78	Qi, CR	FALSE	FALSE	FALSE	FALSE
2675	10.1021/acs.joc.5b01240	doi.org/10.1021/acs.joc.5b01240	Toward a Unified Mechanism for Oxoammonium Salt-Mediated Oxidation Reactions: A Theoretical and Experimental Study Using a Hydride Transfer Model		J. Org. Chem.	78	Leadbeater, NE	FALSE	FALSE	FALSE	FALSE
2676	10.1002/adsc.201401176	doi.org/10.1002/adsc.201401176	Asymmetric One-Pot Synthesis of 1,4-Dihydroquinolines via an Organocatalytic Aza-Michael/Michael Cascade Strategy		Adv. Synth. Catal.	78	Kim, SG	FALSE	FALSE	FALSE	FALSE
2677	10.1002/ejoc.201403404	doi.org/10.1002/ejoc.201403404	Palladium-Catalyzed Desulfitative Arylation of 5-Alkoxy-3,4-dibromo-2(5H)-furanone with Sodium Arylsulfinates		Eur. J. Org. Chem.	78	Wang, ZY	FALSE	FALSE	FALSE	FALSE
2678	10.1016/j.tetlet.2014.11.118	doi.org/10.1016/j.tetlet.2014.11.118	Chemoselective Suzuki-cross coupling reactions of 5-bromoquinolin-8-yl trifluoromethanesulfonate		Tetrahedron Lett.	78	Langer, P	FALSE	FALSE	FALSE	FALSE
2679	10.1039/c5nj01597a	doi.org/10.1039/c5nj01597a	Palladium catalyzed decarboxylative acylation of arylboronic acid with ethyl cyanoacetate as a new acylating agent: synthesis of alkyl aryl ketones		New J. Chem.	78	Adhikari, S	FALSE	FALSE	FALSE	FALSE
2680	10.1021/jo5010636	doi.org/10.1021/jo5010636	Synthesis of Triarylmethanes by Palladium-Catalyzed C-H/C-O Coupling of Oxazoles and Diarylmethanol Derivatives		J. Org. Chem.	78	Hirano, K	FALSE	FALSE	FALSE	FALSE
2681	10.1021/ol500531m	doi.org/10.1021/ol500531m	Direct C-H Bond Arylation of (Benzo)oxazoles with Aryl Chlorides Catalyzed by N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex		Org. Lett.	78	Shao, LX	FALSE	FALSE	FALSE	FALSE
2682	10.1002/cjoc.201300830	doi.org/10.1002/cjoc.201300830	Efficient C-S Cross-Coupling of Thiols with Aryl Iodides Catalyzed by Cu(OAc)(2)center dot H2O and 2,2'- Biimidazole		Chin. J. Chem.	78	Zeng, RS	FALSE	FALSE	FALSE	FALSE
2683	10.1021/ja410118m	doi.org/10.1021/ja410118m	A Computational Mechanistic Study of an Unprecedented Heck-Type Relay Reaction: Insight into the Origins of Regio- and Enantioselectivities		J. Am. Chem. Soc.	78	Wang, ZX	FALSE	FALSE	FALSE	FALSE
2684	10.1039/c3ob41918e	doi.org/10.1039/c3ob41918e	Nickel-catalyzed dimerization of pyrrolidinoindoline scaffolds: systematic access to chimonanthines, folicanthines and (+)-WIN 64821		Org. Biomol. Chem.	78	Oguri, H	FALSE	FALSE	FALSE	FALSE
2685	10.1002/chem.201303474	doi.org/10.1002/chem.201303474	Significant Substituent Effect on the Anomerization of Pyranosides: Mechanism of Anomerization and Synthesis of a 1,2-cis Glucosamine Oligomer from the 1,2-trans Anomer		Chem.-Eur. J.	78	Manabe, S	FALSE	FALSE	FALSE	FALSE
2686	10.6023/A13040455	doi.org/10.6023/A13040455	DFT Study on Mechanism of Ruthenium-catalyzed meta Sulfonation		Acta Chim. Sin.	78	Liu, DJ	FALSE	FALSE	FALSE	FALSE
2687	10.1021/om300566m	doi.org/10.1021/om300566m	Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)(2) in the Amination of Aryl Tosylates		Organometallics	78	Belderrain, TR	FALSE	FALSE	FALSE	FALSE
2688	10.1039/c2sc20277h	doi.org/10.1039/c2sc20277h	Hindered biaryls by C-H coupling: bisoxazoline-Pd catalysis leading to enantioselective C-H coupling		Chem. Sci.	78	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
2689	10.1002/ejoc.201101121	doi.org/10.1002/ejoc.201101121	A Highly Efficient Method for the Copper-Catalyzed Selective Synthesis of Diaryl Chalcogenides from Easily Available Chalcogen Sources		Eur. J. Org. Chem.	78	Li, YM	FALSE	FALSE	FALSE	FALSE
2690	10.1016/j.tet.2009.12.004	doi.org/10.1016/j.tet.2009.12.004	New 1,2,4,5-tetrakis-(N-imidazoliniummethyl)benzene and 1,2,4,5-tetrakis(N-benzimidazoliummethyl)benzene salts as N-heterocyclic tetracarbene precursors: synthesis and involvement in ruthenium-catalyzed allylation reactions		Tetrahedron	78	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
2691	10.1039/c0dt00104j	doi.org/10.1039/c0dt00104j	Hydrofluoroarylation of alkynes with fluoroarenes		Dalton Trans.	78	Nakao, Y	FALSE	FALSE	FALSE	FALSE
2692	10.1002/ejoc.200900104	doi.org/10.1002/ejoc.200900104	New and Efficient Iron Halide Mediated Synthesis of Alkenyl Halides through Coupling of Alkynes and Alcohols		Eur. J. Org. Chem.	78	Jana, U	FALSE	FALSE	FALSE	FALSE
2693	10.1073/pnas.0307271101	doi.org/10.1073/pnas.0307271101	Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Catalyst and substrate studies leading to a mechanistic working model		Proc. Natl. Acad. Sci. U. S. A.	78	Lautens, M	FALSE	FALSE	FALSE	FALSE
2694	10.1016/S0040-4039(03)00786-X	doi.org/10.1016/S0040-4039(03)00786-X	First cross-coupling reactions of arylmagnesates: a convenient access to heteroarylquinolines		Tetrahedron Lett.	78	Mongin, F	FALSE	FALSE	FALSE	FALSE
2695	10.1021/jo00069a041	doi.org/10.1021/jo00069a041	REACTION OF ARYL TRIFLATES WITH HETEROARYLLITHIUMS VIA ARYNE INTERMEDIATES		J. Org. Chem.	78		FALSE	FALSE	FALSE	FALSE
2696	10.1021/jo00390a013	doi.org/10.1021/jo00390a013	TARTARIC ACID, AN EFFICIENT CHIRAL AUXILIARY - NEW ASYMMETRIC-SYNTHESIS OF 2-ALKYL-2-ARYLACETIC ACIDS		J. Org. Chem.	78	CASTALDI, G	FALSE	FALSE	FALSE	FALSE
2697	10.1016/0022-328X(86)80547-2	doi.org/10.1016/0022-328X(86)80547-2	CATALYZED SUBSTITUTIONS OF ACETATE NICKEL AND ALLYLIC SULFONES		J. Organomet. Chem.	78	CUVIGNY, T	FALSE	FALSE	FALSE	FALSE
2698	10.1080/07328303.2022.2031207	doi.org/10.1080/07328303.2022.2031207	Recent advances in glycosylation involving novel anomeric radical precursors		J. Carbohydr. Chem.	78	Zhu, F	FALSE	FALSE	FALSE	FALSE
2699	10.1002/ejoc.202101211	doi.org/10.1002/ejoc.202101211	Selective Palladium-Catalyzed alpha,beta-Homodiarylation of Vinyl Esters in Aqueous Medium		Eur. J. Org. Chem.	78	Ostaszewski, R	FALSE	FALSE	FALSE	FALSE
2700	10.6023/A21070345	doi.org/10.6023/A21070345	Advances on Asymmetric Construction of Diarylmethine Stereocenters		Acta Chim. Sin.	78	Xiao, J; Peng, Y	FALSE	FALSE	FALSE	FALSE
2701	10.1016/j.chempr.2021.10.015	doi.org/10.1016/j.chempr.2021.10.015	A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral alpha-aryl alkylboronates		Chem	78	Liang, Y; Zhu, SL	FALSE	FALSE	FALSE	FALSE
2702	10.1021/jacs.1c05902	doi.org/10.1021/jacs.1c05902	Nickel-Catalyzed Dearomative Arylboration of Indoles: Regioselective Synthesis of C2-and C3-Borylated Indolines		J. Am. Chem. Soc.	78	Brown, MK	FALSE	FALSE	FALSE	FALSE
2703	10.1002/slct.202101755	doi.org/10.1002/slct.202101755	Advantage of Using NaH2PO2 over Alkali Metal Formates as a Hydrogen Source for Pd-gC(3)N(4) Catalyzed Hydro-Dehalogenation of Aryl Halides		ChemistrySelect	78	Chakraborty, S; Bahuguna, A	FALSE	FALSE	FALSE	FALSE
2704	10.1021/acs.inorgchem.1c01432	doi.org/10.1021/acs.inorgchem.1c01432	Way to Enforce Selectivity via Steric Hindrance: Improvement of Am(III)/Eu(III) Solvent Extraction by Loaded Diphosphonic Acid Esters		Inorg. Chem.	78	Shi, WQ	FALSE	FALSE	FALSE	FALSE
2705	10.1002/ejoc.202100717	doi.org/10.1002/ejoc.202100717	Carboxylic Acid Promoted, Redox-Neutral Ru-Catalyzed C-H Allylation of Aromatic Ketones		Eur. J. Org. Chem.	78	Dethe, DH	FALSE	FALSE	FALSE	FALSE
2706	10.1021/acscatal.1c02790	doi.org/10.1021/acscatal.1c02790	Identifying the Imperative Role of Metal-Olefin Interactions in Catalytic C-O Reductive Elimination from Nickel(II)		ACS Catal.	78	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
2707	10.1021/jacs.1c05764	doi.org/10.1021/jacs.1c05764	Lewis Basic Salt-Promoted Organosilane Coupling Reactions with Aromatic Electrophiles		J. Am. Chem. Soc.	78	Bandar, JS	FALSE	TRUE	FALSE	FALSE
2708	10.1055/a-1548-8362	doi.org/10.1055/a-1548-8362	Nickel-Catalyzed Hydrodeoxygenation of Aryl Sulfamates with Alcohols as Mild Reducing Agents		Synthesis	78	Kuriyama, M; Onomura, O	FALSE	FALSE	FALSE	FALSE
2709	10.1021/acscatal.1c01077	doi.org/10.1021/acscatal.1c01077	Cross-Coupling of Ketone Enolates with Grignard and Zinc Reagents with First-Row Transition Metal Catalysts		ACS Catal.	78	Cossy, J	FALSE	FALSE	FALSE	FALSE
2710	10.1002/adsc.201700260	doi.org/10.1002/adsc.201700260	A Sequential Suzuki Coupling Approach to Unsymmetrical Aryl s-Triazines from Cyanuric Chloride		Adv. Synth. Catal.	78	Zou, G	FALSE	FALSE	FALSE	FALSE
2711	10.1021/jacs.7b04374	doi.org/10.1021/jacs.7b04374	Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation		J. Am. Chem. Soc.	78	Krische, MJ	FALSE	FALSE	FALSE	FALSE
2712	10.1002/anie.201701918	doi.org/10.1002/anie.201701918	Copper-Mediated Decarboxylative Coupling of Benzamides with ortho-Nitrobenzoic Acids by Directed C-H Cleavage		Angew. Chem.-Int. Edit.	78	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
2713	10.1039/c7ra05711c	doi.org/10.1039/c7ra05711c	Highly efficient heterogeneous copper-catalyzed decarboxylative cross-coupling of potassium polyfluorobenzoates with aryl halides leading to polyfluorobiaryls		RSC Adv.	78	Zhao, H	FALSE	FALSE	FALSE	FALSE
2714	10.1021/jacs.6b06862	doi.org/10.1021/jacs.6b06862	Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon-Carbon Bond Formation Reactions		J. Am. Chem. Soc.	78	Mirica, LM	FALSE	FALSE	FALSE	FALSE
2715	10.1021/acs.orglett.6b02229	doi.org/10.1021/acs.orglett.6b02229	Olefination of Electron-Deficient Alkenes with Allyl Acetate: Stereo- and Regioselective Access to (2Z,4E)-Dienamides		Org. Lett.	78	Zhang, J; Zhong, GF	FALSE	TRUE	FALSE	FALSE
2716	10.1021/acscatal.6b00365	doi.org/10.1021/acscatal.6b00365	Coupling Catalytic Alkene Hydroacylation and alpha-Arylation: Enantioselective Synthesis of Heterocyclic Ketones with alpha-Chiral Quaternary Stereocenters		ACS Catal.	78	Stanley, LM	FALSE	FALSE	FALSE	FALSE
2717	10.1021/acscatal.0c05481	doi.org/10.1021/acscatal.0c05481	Copper-Catalyzed Meta-Selective Arylation of Phenol Derivatives: An Easy Access to m-Aryl Phenols	A convenient method to perdeuterate aromatic compounds is reported. Commercially available nonaflic acid (C4F9SO3H) in combination with C6D6 as the deuterium source provided access to a series of highly labeled arenes. Some of them were then used as building blocks for the preparation of functionalized deuterated products. A wide range of synthetic procedures were investigated. They involved traditional methods such as halogenation or nucleophilic substitution, but also metal-catalyzed cross coupling and C-X bond activation. The transformations comprised redox-neutral, oxidative as well as reductive reactions, and mechanistically, ionic, radical and pericyclic processes were covered. Under many conditions, the overall degree of deuteration remained high; in C-X activation reactions, a more pronounced re-protonation was observed.	ACS Catal.	77	Loh, TP	FALSE	FALSE	FALSE	FALSE
2718	10.1016/j.tetlet.2020.152801	doi.org/10.1016/j.tetlet.2020.152801	Visible-light-induced direct construction of amide bond from carboxylic acids with amines in aqueous solution	This paper reports a room temperature, nickel-catalyzed Negishi cross-coupling of N-acylsuccinimides with arylzinc reagents via selective N-C bond cleavage enabled by amide bond twist. The reaction proceeds using a commercially available, air-stable Ni(II) precatalyst in the absence of additives under exceedingly mild conditions. Of broad interest, this report introduces N-acylsuccinimides as stable, crystalline, electrophilic, cost-effective, benign, amide-based acyl transfer reagents via acyl metal intermediates. The reaction selectivity is governed by half-twist of the amide bond in N-acylsuccinimides, thus opening the door for applications in metal-catalyzed manifolds via redox-neutral reaction pathways tuneable by amide bond distortion.	Tetrahedron Lett.	77	Xu, XZ	FALSE	FALSE	FALSE	FALSE
2719	10.1021/acs.orglett.0c03377	doi.org/10.1021/acs.orglett.0c03377	m-C-Ar-H Bond Alkylations and Difluoromethylation of Tertiary Phosphines Using a Ruthenium Catalyst	Transition-metal-free hydrodehalogenation of aryl halides (eg. bromides) can take place efficiently in the presence of green polyethylene glycol (PEG-800) and t-BuOK without adding any extra solvents and additives. A radical mechanism is proposed for this transition-metal-free dehalogenation of aryl halides and the role of polyethylene glycol is both reaction promotor and activated alkyl C-H donor. (C) 2017 Elsevier Ltd. All rights reserved.	Org. Lett.	77	Li, G	FALSE	FALSE	FALSE	FALSE
2720	10.1055/a-1306-3228	doi.org/10.1055/a-1306-3228	C-O Bond Activation as a Strategy in Palladium-Catalyzed Cross-Coupling	Recently, a lactate racemase was discovered as a new Ni-dependent enzyme with a unique tethered NAD-like cofactor. We report the first computational study aimed at deciphering the previously unclear role of the Ni-tethered cofactor in reactions of the lactate racemase. Our calculations revealed that the cofactor increases the dehydrogenation barriers. The formation of a metastable NADH-like pyruvate intermediate and two nearby histidine bases are proposed as the key factors in the racemization reaction. Such destabilization of intermediates by the cofactor is uncommon in enzymatic catalysis. This result provides new insight into the design of a reactive metal-tethered NADH-like complex for synthetic hydrogenations.	Synlett	77	Leitch, DC	FALSE	FALSE	FALSE	FALSE
2721	10.1002/ejoc.202001306	doi.org/10.1002/ejoc.202001306	Water-Promoted Dehydrative Tsuji-Trost Reaction of Non-Derivatized Allylic Alcohols with Sulfinic Acids	Au(III)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(III) species are described and their key role in 2 electron-redox Au(I)/Au(III) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides.	Eur. J. Org. Chem.	77	Ma, XT	FALSE	FALSE	FALSE	FALSE
2722	10.6023/cjoc202005072	doi.org/10.6023/cjoc202005072	C(sp(3))-C(sp(3)) Bond Formation via Transition-Metal Mediated and Catalyzed Reductive Homocouplings	The Suzuki-Miyaura coupling is among the most important C-C bond-forming reactions available due to its reliability, chemoselectivity, and diversity. Aryl halides and pseudohalides such as iodides, bromides, and triflates are traditionally used as the electrophilic coupling partner. The expansion of the reaction scope to nontraditional electrophiles is an ongoing challenge to enable an even greater number of useful products to be made from simple starting materials. Herein, we present how an NHC-based Pd catalyst can enable Suzuki-Miyaura coupling where the C(acyl)-O bond of aryl esters takes on the role of electrophile, allowing the synthesis of various ketone-containing products. This contrasts known reactions of similar esters that provide biaryls via nickel catalysis. The underlying cause of this mechanistic divergence is investigated by DFT calculations, and the robustness of esters compared to more electrophilic acylative coupling partners is analyzed.	Chin. J. Org. Chem.	77	Zhao, YC	FALSE	FALSE	FALSE	FALSE
2723	10.1021/acscatal.0c02584	doi.org/10.1021/acscatal.0c02584	alpha-Tertiary Dialkyl Ether Synthesis via Reductive Photocatalytic alpha-Functionalization of Alkyl Enol Ethers	Two upper-rim-functionalised calix[4] arenes, 5-diphenylphosphino- 25,26,27,28-tetra-benzyloxycalix[4] arene and 5-diphenylphosphino-25,26,27,28-tetra-(p-anisyl) methyloxy calix[4] arene, were investigated in the nickel-catalysed crosscoupling of phenylboronic acid with aryl bromides. The catalytic activities are higher than those observed for other triarylphosphanes, notably PPh3 and P(o-tolyl)(3) as well as the Buchwald-type ligand o-biph-PPh2 [TOFs up to 2600 mol(ArPh) mol(Ni)(-1) h(-1)], but the production of large amounts of dehalogenation product could not be avoided, thus strongly contrasting with the classical Pd-catalysed reaction. Good activities were also obtained with aryl chlorides, even at room temperature. The higher efficiency of 1 and 2 relative to that of the Buchwald ligand 3 probably arises from the ease with which these two calix-phosphanes may form appropriate monophosphine complexes before the oxidative addition step.	ACS Catal.	77	Dixon, DJ	TRUE	FALSE	FALSE	FALSE
2724	10.1021/jacs.0c06882	doi.org/10.1021/jacs.0c06882	Stereochemistry of Transition Metal Complexes Controlled by the Metallo-Anomeric Effect	A magnesium salt promoted synthesis of ketones via tandem nucleophilic addition-Oppenauer oxidation of aldehydes using organozinc chemistry was demonstrated. Magnesium salts concomitantly generated via magnesium metal mediated organohalide zincation exhibit high efficacy for nucleophilic addition of organozinc reagents to aromatic aldehydes and thereafter Oppenauer oxidation whereby ketones are formed in high to excellent yields.	J. Am. Chem. Soc.	77	Walczak, MA	FALSE	FALSE	FALSE	FALSE
2725	10.1002/chem.202001757	doi.org/10.1002/chem.202001757	Ultrasound-Facilitated Direct meta-C-H Functionalization of Arenes: A Time-Economical Strategy under Ambient Temperature with Improved Yield and Selectivity	Much effort has been devoted to developing new methods using Ni catalysts for the cross-coupling reaction of alkyl electrophiles with organometallic reagents, and significant achievements in this area have emerged during the past two decades. Nickel catalysts have enabled the coupling reaction of not only primary alkyl electrophiles, but also sterically hindered secondary and tertiary alkyl electrophiles possessing beta-hydrogens with various organometallic reagents to construct carbon skeletons. In addition, Ni catalysts opened a new era of asymmetric cross-coupling reaction using alkyl halides. Recent progress in nickel-catalyzed cross-coupling reaction of alkyl electrophiles with sp(3)-, sp(2)-, and sp-hybridized organometallic reagents including asymmetric variants as well as mechanistic insights of nickel catalysis are reviewed in this chapter.	Chem.-Eur. J.	77	Maiti, D	FALSE	FALSE	FALSE	FALSE
2726	10.1016/j.ijbiomac.2020.04.003	doi.org/10.1016/j.ijbiomac.2020.04.003	Green synthesis of a palladium nanocatalyst anchored on magnetic lignin-chitosan beads for synthesis of biaryls and aryl halide cyanation	Three classes of Ni precatalysts based on pi-Ni-II, pi-Ni-0 and sigma-Ni-II complexes have been elaborated and employed in different laboratories for the functionalization and cross-coupling of otherwise inert aryl C-O, C-Cl, and C-F electrophiles. Various Ni precatalysts, ligands, boron sources, and reaction conditions that were developed in various research groups, necessitated the selection of the most suitable conditions for desired cross-coupling partners. Here a universal, bench-stable, easily prepared (NiCl)-Cl-II(1-naphthyl)(PCy3)(2)/PCy3 sigma-complex, for efficient and quantitative cross-coupling of aryl chlorides, bromides, iodides, mesylates, and fluorides with aryl neopentylglycolboronates is reported. This precatalyst will most probably help to advance the applications of Ni catalysis in organic, supramolecular, and macromolecular synthesis and will provide an easier access to the selection of reaction conditions for various transformations.	Int. J. Biol. Macromol.	77	Baran, T	FALSE	FALSE	FALSE	FALSE
2727	10.1007/s10562-019-03070-5	doi.org/10.1007/s10562-019-03070-5	Co-II Immobilized on Aminated Magnetic-Based Metal-Organic Framework: An Efficient Heterogeneous Nanostructured Catalyst for the C-O Cross-Coupling Reaction in Solvent-Free Conditions		Catal. Lett.	77	Akhlaghinia, B	FALSE	FALSE	FALSE	FALSE
2728	10.1021/acs.joc.9b02042	doi.org/10.1021/acs.joc.9b02042	Formation of Enol Ethers by Radical Decarboxylation of alpha-Alkoxy beta-Phenylthio Acids		J. Org. Chem.	77	Clive, DLJ	FALSE	FALSE	FALSE	FALSE
2729	10.1002/asia.201900641	doi.org/10.1002/asia.201900641	Catalyst-Free Synthesis of alpha-Functionalized 2H-Chromenes in Water: A Tandem Self-Promoted pseudo-Substitution and Decarboxylation Process		Chem.-Asian J.	77	Wang, TL	FALSE	FALSE	FALSE	FALSE
2730	10.1039/c9qo00352e	doi.org/10.1039/c9qo00352e	Bimolecular oxidative C-H alkynylation of alpha-substituted isochromans		Org. Chem. Front.	77	Liu, L	FALSE	FALSE	FALSE	FALSE
2731	10.1002/anie.201810160	doi.org/10.1002/anie.201810160	Domino Synthesis of alpha,beta-Unsaturated gamma-Lactams by Stereoselective Amination of alpha-Tertiary Allylic Alcohols		Angew. Chem.-Int. Edit.	77	Kleij, AW	FALSE	FALSE	FALSE	FALSE
2732	10.1055/s-0037-1611053	doi.org/10.1055/s-0037-1611053	Directed ortho Metalation (D o M)-Linked Corriu-Kumada, Negishi, and Suzuki-Miyaura Cross-Coupling Protocols: A Comparative Study		Synthesis	77	Snieckus, V	FALSE	FALSE	FALSE	FALSE
2733	10.3390/molecules23102681	doi.org/10.3390/molecules23102681	Computational Study of Mechanism and Thermodynamics of Ni/IPr-Catalyzed Amidation of Esters		Molecules	77	Hong, X	FALSE	FALSE	FALSE	FALSE
2734	10.1016/j.tet.2018.07.001	doi.org/10.1016/j.tet.2018.07.001	Formal carbene insertion into C=O double bond: A facile approach to the synthesis of 2H-chromenes		Tetrahedron	77	Liu, SY	FALSE	FALSE	FALSE	FALSE
2735	10.1002/adsc.201800724	doi.org/10.1002/adsc.201800724	Pd-Catalyzed Decarboxylative Asymmetric Protonation of Sterically Hindered -Aryl Lactones and Dihydrocoumarins		Adv. Synth. Catal.	77	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
2736	10.1002/anie.201802563	doi.org/10.1002/anie.201802563	Iron-Catalyzed Ring-Closing C-O/C-O Metathesis of Aliphatic Ethers		Angew. Chem.-Int. Edit.	77	Morandi, B	FALSE	FALSE	FALSE	FALSE
2737	10.1002/ejoc.201800155	doi.org/10.1002/ejoc.201800155	Microwave-Assisted Domino Palladium Catalysis in Water: A Diverse Synthesis of 3,3 '-Disubstituted Heterocyclic Compounds		Eur. J. Org. Chem.	77	Satyanarayana, G	FALSE	FALSE	FALSE	FALSE
2738	10.1002/chem.201800585	doi.org/10.1002/chem.201800585	Asymmetric Benzylic Allylic Alkylation Reaction of 3-Furfural Derivatives by Dearomatizative Dienamine Activation		Chem.-Eur. J.	77	Chen, YC	FALSE	FALSE	FALSE	FALSE
2739	10.1002/slct.201702278	doi.org/10.1002/slct.201702278	Regioselective Synthesis of 1,4 & 1,5-Enynes through a Ca(II)- Catalyzed Cross-Dehydrative-Coupling of Styrenes and Propargyl alcohols		ChemistrySelect	77	Yaragorla, S	FALSE	FALSE	FALSE	FALSE
2740	10.1055/s-0036-1589100	doi.org/10.1055/s-0036-1589100	Nickel-Catalyzed Electrochemical Reductive Homocouplings of Aryl and Heteroaryl Halides: A Useful Route to Symmetrical Biaryls		Synthesis	77	Sengmany, S; Leonel, E	FALSE	TRUE	FALSE	FALSE
2741	10.1021/acs.joc.7b02375	doi.org/10.1021/acs.joc.7b02375	Ir-4(CO)(12)-Catalyzed Benzylic C(sp(3))-H Silylation of 2-Alkylpyridines with Hydrosilanes Leading to 2-(1-Silylalkyl)pyridines		J. Org. Chem.	77	Fukumoto, Y	FALSE	FALSE	FALSE	FALSE
2742	10.1055/s-0036-1589126	doi.org/10.1055/s-0036-1589126	Arylation of Amide and Urea C(sp(3))-H Bonds with Aryl Tosylates Generated In Situ from Phenols		Synlett	77	Zhou, WJ; Yu, DG	FALSE	FALSE	FALSE	FALSE
2743	10.1002/anie.201706597	doi.org/10.1002/anie.201706597	Efficient Aryl Migration from an Aryl Ether to a Carboxylic Acid Group To Form an Ester by Visible-Light Photoredox Catalysis		Angew. Chem.-Int. Edit.	77	Cao, XP	TRUE	FALSE	FALSE	FALSE
2744	10.1002/ejoc.201500962	doi.org/10.1002/ejoc.201500962	Modular Synthesis of Biaryl-Substituted Phosphine Ligands: Application in Microwave-Assisted Palladium-Catalyzed C-N Cross-Coupling Reactions		Eur. J. Org. Chem.	77	Kumar, P	FALSE	FALSE	FALSE	FALSE
2745	10.1002/chem.201502114	doi.org/10.1002/chem.201502114	How and Why Does Ni-0 Promote Smooth Etheric C-O Bond Cleavage and C-C Bond Formation? A Theoretical Study		Chem.-Eur. J.	77	Wang, C	FALSE	FALSE	FALSE	FALSE
2746	10.1021/jacs.5b02277	doi.org/10.1021/jacs.5b02277	Iron-Catalyzed Enantioselective Cross-Coupling Reactions of alpha-Chloroesters with Aryl Grignard Reagents		J. Am. Chem. Soc.	77	Nakamura, M	FALSE	FALSE	FALSE	FALSE
2747	10.1021/ol503560e	doi.org/10.1021/ol503560e	Nickel-Catalyzed One-Pot Deoxygenation and Reductive Homocoupling of Phenols via C-O Activation Using TCT Reagent		Org. Lett.	77	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
2748	10.3998/ark.5550190.p008.915	doi.org/10.3998/ark.5550190.p008.915	Recent advances in nickel-catalyzed C-H bond functionalized reactions		Arkivoc	77	Cai, XH	FALSE	FALSE	FALSE	FALSE
2749	10.1039/c5ra07771k	doi.org/10.1039/c5ra07771k	Facile synthesis of 2,2 '-dinitrosubstituted biaryls through Cu-catalyzed ligand-free decarboxylative homocoupling of ortho-nitrobenzoic acids		RSC Adv.	77	Cai, H	FALSE	FALSE	FALSE	FALSE
2750	10.1039/c5ob00149h	doi.org/10.1039/c5ob00149h	Nickel-catalyzed synthesis of diarylsulfides and sulfones via C-H bond functionalization of arylamides		Org. Biomol. Chem.	77	Kambe, N	FALSE	FALSE	FALSE	FALSE
2751	10.1002/asia.201403052	doi.org/10.1002/asia.201403052	Regioselective C-H Imidation of Five-Membered Heterocyclic Compounds through a Metal Catalytic or Organocatalytic Approach		Chem.-Asian J.	77	Sun, K	FALSE	FALSE	FALSE	FALSE
2752	10.1002/adsc.201400405	doi.org/10.1002/adsc.201400405	Asymmetric Synthesis of alpha-Amino Acids under Operationally Convenient Conditions		Adv. Synth. Catal.	77	Bolm, C	FALSE	FALSE	FALSE	FALSE
2753	10.1021/ol501434d	doi.org/10.1021/ol501434d	Copper-Catalyzed Regio- and Stereoselective O-Arylation of Enolates		Org. Lett.	77	Liu, JT	FALSE	FALSE	FALSE	FALSE
2754	10.1021/ol5005565	doi.org/10.1021/ol5005565	Asymmetric Chlorination/Ring Expansion for the Synthesis of alpha-Quaternary Cycloalkanones		Org. Lett.	77	You, SL	FALSE	FALSE	FALSE	FALSE
2755	10.1007/s10562-013-1136-x	doi.org/10.1007/s10562-013-1136-x	Iridium-Catalyzed Asymmetric Ring-Opening of Oxabicyclic Alkenes with Carboxylic Acids		Catal. Lett.	77	Yang, DQ	FALSE	FALSE	FALSE	FALSE
2756	10.1021/jo402723e	doi.org/10.1021/jo402723e	Enabling the Use of Heterocyclic Arynes in Chemical Synthesis		J. Org. Chem.	77	Garg, NK	FALSE	FALSE	FALSE	FALSE
2757	10.1039/c4ra04059g	doi.org/10.1039/c4ra04059g	Superacid BF3-H2O promoted benzylation of arenes with benzyl alcohols and acetates initiated by trace water		RSC Adv.	77	Xiong, Y	FALSE	FALSE	FALSE	FALSE
2758	10.1016/j.tetlet.2013.10.031	doi.org/10.1016/j.tetlet.2013.10.031	Preparation of C-arylglycals via Suzuki-Miyaura cross-coupling of dihydropyranylphosphates		Tetrahedron Lett.	77	Pongdee, R	FALSE	FALSE	FALSE	FALSE
2759	10.1016/j.molcata.2013.05.012	doi.org/10.1016/j.molcata.2013.05.012	Copper(I) iodide catalyzes odorless thioarylation of phenolic esters with alkyl derivatives using thiourea in wet polyethylene glycol (PEG 200)		J. Mol. Catal. A-Chem.	77	Firouzabadi, H	FALSE	FALSE	FALSE	FALSE
2760	10.1016/j.tet.2013.05.011	doi.org/10.1016/j.tet.2013.05.011	Bimolecular coupling reactions through oxidatively generated aromatic cations: scope and stereocontrol		Tetrahedron	77	Floreancig, PE	FALSE	FALSE	FALSE	FALSE
2761	10.1002/aoc.3014	doi.org/10.1002/aoc.3014	Palladium nanoparticles supported on silica diphenylphosphinite as efficient catalyst for C-O and C-S arylation of aryl halides		Appl. Organomet. Chem.	77	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
2762	10.3998/ark.5550190.0014.219	doi.org/10.3998/ark.5550190.0014.219	Benzotriazol-1-ylmethanol: An excellent bidentate ligand for the copper/palladium-catalyzed C-N and C-C coupling reaction		Arkivoc	77	Verma, AK	FALSE	FALSE	FALSE	FALSE
2763	10.1039/c3sc51098k	doi.org/10.1039/c3sc51098k	Nickel-catalyzed cross-coupling of unactivated alkyl halides using bis(pinacolato)diboron as reductant		Chem. Sci.	77	Gong, HG	FALSE	FALSE	FALSE	FALSE
2764	10.1002/ejoc.201101773	doi.org/10.1002/ejoc.201101773	Synthesis of Benzothiazoles through Copper-Catalyzed One-Pot Three-Component Reactions with Use of Sodium Hydrosulfide as a Sulfur Surrogate		Eur. J. Org. Chem.	77	Song, KH	FALSE	FALSE	FALSE	FALSE
2765	10.1021/om201271y	doi.org/10.1021/om201271y	Nickel(0) Complexes of Polyunsaturated Azamacrocyclic Ligands		Organometallics	77	Roglans, A	FALSE	FALSE	FALSE	FALSE
2766	10.1039/c2ob06795a	doi.org/10.1039/c2ob06795a	Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions		Org. Biomol. Chem.	77	Xu, HJ	FALSE	FALSE	FALSE	FALSE
2767	10.1021/ja205174c	doi.org/10.1021/ja205174c	Expanded Substrate Scope and Improved Reactivity of Ether-Forming Cross-Coupling Reactions of Organotrifluoroborates and Acetals		J. Am. Chem. Soc.	77	Bode, JW	FALSE	FALSE	FALSE	FALSE
2768	10.1002/ejoc.201000134	doi.org/10.1002/ejoc.201000134	Palladium-Catalyzed Synthesis of 4-Arylcoumarins Using Triarylbismuth Compounds as Atom-Efficient Multicoupling Organometallic Nucleophiles		Eur. J. Org. Chem.	77	Rao, MLN	FALSE	FALSE	FALSE	FALSE
2769	10.1016/S0076-6879(10)78020-4	doi.org/10.1016/S0076-6879(10)78020-4	THE SYNTHESIS OF 1,2-CIS-AMINO CONTAINING OLIGOSACCHARIDES TOWARD BIOLOGICAL INVESTIGATION		Methods Enzymol.	77	Manabe, S	FALSE	FALSE	FALSE	FALSE
2770	10.1021/om049448p	doi.org/10.1021/om049448p	Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative addition at palladium, P-C and C-F activation at platinum		Organometallics	77	Braun, T	FALSE	FALSE	FALSE	FALSE
2771	10.5059/yukigoseikyokaishi.51.1087	doi.org/10.5059/yukigoseikyokaishi.51.1087	THE DEVELOPMENT AND APPLICATION OF A NEW CLASS OF MONODENTATE OPTICALLY-ACTIVE PHOSPHINES (MOPS) - ASYMMETRIC HYDROSILYLATION OF OLEFINS CATALYZED BY PALLADIUM-MOP COMPLEXES		J. Synth. Org. Chem. Jpn.	77	UOZUMI, Y	FALSE	FALSE	FALSE	FALSE
2772	10.1016/S0040-4020(01)87621-3	doi.org/10.1016/S0040-4020(01)87621-3	ASYMMETRIC NICKEL-CATALYZED CROSS-COUPLING REACTION OF ALLYLIC SUBSTRATES WITH GRIGNARD-REAGENTS		Tetrahedron	77	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
2773	10.1021/acsinfecdis.1c00611	doi.org/10.1021/acsinfecdis.1c00611	Quaternary Phosphonium Compounds: An Examination of Non-Nitrogenous Cationic Amphiphiles That Evade Disinfectant Resistance		ACS Infect. Dis.	77	Minbiole, KPC; Wuest, WM	FALSE	FALSE	FALSE	FALSE
2774	10.1021/acs.joc.1c02446	doi.org/10.1021/acs.joc.1c02446	Benzylic Aroylation of Toluenes Mediated by a LiN(SiMe3)(2)/Cs+ System		J. Org. Chem.	77	Mao, JY	FALSE	FALSE	FALSE	FALSE
2775	10.1002/anie.202112454	doi.org/10.1002/anie.202112454	The Formal Cross-Coupling of Amines and Carboxylic Acids to Form sp(3)-sp(3) Carbon-Carbon Bonds		Angew. Chem.-Int. Edit.	77	Cernak, T	FALSE	FALSE	FALSE	FALSE
2776	10.1039/d1cc04189d	doi.org/10.1039/d1cc04189d	Recent advances in radical-based C-F bond activation of polyfluoroarenes and gem-difluoroalkenes		Chem. Commun.	77	Wang, JL; Li, HQ	FALSE	FALSE	FALSE	FALSE
2777	10.1021/acscatal.1c02851	doi.org/10.1021/acscatal.1c02851	Stereo- and Enantioselective Benzylic C-H Alkenylation via Photoredox/Nickel Dual Catalysis		ACS Catal.	77	Lu, Z	TRUE	FALSE	FALSE	FALSE
2778	10.1002/anie.202106514	doi.org/10.1002/anie.202106514	Tandem Catalytic Indolization/Enantioconvergent Substitution of Alcohols by Borrowing Hydrogen to Access Tricyclic Indoles		Angew. Chem.-Int. Edit.	77	Liu, YB; Zhao, Y	FALSE	FALSE	FALSE	FALSE
2779	10.1002/ejoc.202100677	doi.org/10.1002/ejoc.202100677	A Mild Glycosylation Protocol with Glycosyl 1-Methylimidazole-2-carboxylates as Donors		Eur. J. Org. Chem.	77	Tang, Y; Yu, BA	FALSE	FALSE	FALSE	FALSE
2780	10.1021/jacs.1c03563	doi.org/10.1021/jacs.1c03563	Nickel-Catalyzed Radical Migratory Coupling Enables C-2 Arylation of Carbohydrates		J. Am. Chem. Soc.	77	Ngai, MY	FALSE	FALSE	FALSE	FALSE
2781	10.1039/d1sc01731d	doi.org/10.1039/d1sc01731d	Pd-catalyzed cross-electrophile Coupling/C-H alkylation reaction enabled by a mediator generated via C(sp(3))-H activation		Chem. Sci.	77	Zhang, YH	FALSE	FALSE	FALSE	FALSE
2782	10.1039/d0sc06666d	doi.org/10.1039/d0sc06666d	Benzylic C(sp(3))-C(sp(2)) cross-coupling of indoles enabled by oxidative radical generation and nickel catalysis		Chem. Sci.	77	Lee, HG	FALSE	FALSE	FALSE	FALSE
2783	10.1039/d1cc00634g	doi.org/10.1039/d1cc00634g	Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates		Chem. Commun.	77	Zhou, JS	FALSE	FALSE	FALSE	FALSE
2784	10.1002/anie.201706868	doi.org/10.1002/anie.201706868	Enantioselective Construction of Trifluoromethoxylated Stereogenic Centers by a Nickel-Catalyzed Asymmetric Suzuki-Miyaura Coupling of Secondary Benzyl Bromides		Angew. Chem.-Int. Edit.	77	Shen, QL	FALSE	FALSE	FALSE	FALSE
2785	10.1039/c7cc05595a	doi.org/10.1039/c7cc05595a	A catalytic asymmetric construction of a tetrahydroquinoline-based spirooxindole framework via a diastereo- and enantioselective decarboxylative [4+2] cycloaddition		Chem. Commun.	77	Mei, GJ; Shi, F	FALSE	FALSE	FALSE	FALSE
2786	10.1021/acs.orglett.7b01199	doi.org/10.1021/acs.orglett.7b01199	Decarbonylative Cyanation of Amides by Palladium Catalysis		Org. Lett.	77	Szostak, M	FALSE	FALSE	FALSE	FALSE
2787	10.1016/j.tetlet.2017.03.016	doi.org/10.1016/j.tetlet.2017.03.016	Polyethylene glycol (PEG) promoted hydrodehalogenation of aryl halides		Tetrahedron Lett.	77	Liu, W	FALSE	FALSE	FALSE	FALSE
2788	10.1021/acscatal.6b02912	doi.org/10.1021/acscatal.6b02912	C-O Bond Activation by Nickel-Palladium Hetero-Bimetallic Nanoparticles for Suzuki-Miyaura Reaction of Bioactive Heterocycle-Tethered Sterically Hindered Aryl Carbonates		ACS Catal.	77	Chakraborti, AK	FALSE	FALSE	FALSE	FALSE
2789	10.1021/acs.organomet.6b00769	doi.org/10.1021/acs.organomet.6b00769	Three Reaction Channels with Signature Proton Transfers in the Ni(I)-Catalyzed Decomposition of Ethyl Acetate		Organometallics	77	Lopez, CS	FALSE	FALSE	FALSE	FALSE
2790	10.1021/acs.jpcb.6b08644	doi.org/10.1021/acs.jpcb.6b08644	First-Principles Molecular Dynamics Analysis of Ligand-Free Suzuki-Miyaura Cross-Coupling in Water Solvent: Oxidative Addition Step		J. Phys. Chem. B	77	Hirakawa, T; Morikawa, Y	FALSE	FALSE	FALSE	FALSE
2791	10.1021/acs.orglett.6b02146	doi.org/10.1021/acs.orglett.6b02146	Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones		Org. Lett.	77	Li, XW	FALSE	FALSE	FALSE	FALSE
2792	10.1055/s-0035-1562342	doi.org/10.1055/s-0035-1562342	An Indefinitely Air-Stable sigma-Ni-II Precatalyst for Quantitative Cross-Coupling of Unreactive Aryl Halides and Mesylates with Aryl Neopentylglycolboronates		Synthesis	77	Percec, V	FALSE	FALSE	FALSE	FALSE
2793	10.1016/j.jcat.2020.12.016	doi.org/10.1016/j.jcat.2020.12.016	Ruthenium-catalyzed acceptorless dehydrogenative coupling of o-aminobenzyl alcohols with ketones to quinolines in the presence of carbonate salt	A variety of 3,4-disubstituted pyridine derivatives with a tertbutyl group in the 4-position were synthesized in a transition-metal-free, two-step reaction sequence from 3-substituted pyridine precursors. Highly regioselective addition of t-Bu2Mg to TIPS-activated pyridines and an efficient microwave-assisted aromatization with sulfur as oxidant afforded the desired 3,4-disubstituted pyridine derivatives in moderate to excellent yields. The method is compatible with many functional groups such as ester, amide, halide, nitrile or alkyne groups present in the 3-position.	J. Catal.	76	Yang, JZ; Li, F	FALSE	FALSE	FALSE	FALSE
2794	10.1038/s41467-020-18658-4	doi.org/10.1038/s41467-020-18658-4	Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals	The successful enantioselective Henry reaction of nitromethane to brominated and fluorinated benzaldehydes was achieved using a chiral bisoxazoline (unbridged)-Cu(II) complex as a catalyst. Nitroalcohols were obtained in excellent yields (up to 99%) and with enantioselectivities up to >99%. Theoretical calculations support the idea that the unbridged bisoxazoline-Cu(II) complex behaves similarly to the privileged bisoxazolines as catalysts in the Henry reaction. (C) 2016 Elsevier Ltd. All rights reserved.	Nat. Commun.	76	Feng, C	FALSE	FALSE	FALSE	FALSE
2795	10.1039/d0ra04362a	doi.org/10.1039/d0ra04362a	Ancillary ligand electro-activity effects towards phenyl acetylene homocoupling reaction by a nickel(ii) complex of a non-innocentO-amino phenol ligand: a mechanistic insight	Nickel(0)-catalyzed direct N-allylation of amides and p-toluenesulfonamide with allylic alcohols took place in the presence of Ni-0-diphosphine complexes. The corresponding N-allylated (and/or N, N-diallylated) products were obtained in moderate to high yields under neutral conditions.	RSC Adv.	76	Safaei, E	FALSE	FALSE	FALSE	FALSE
2796	10.1039/d0ra02631j	doi.org/10.1039/d0ra02631j	SO2F2-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)	An emerging area of homogeneous catalysis is the use of catalysts featuring two closely associated metal sites. This approach complements the traditional focus on single-site catalysts and makes available new parameters with which to optimize catalytic behavior. Single-site catalysts are optimized through changing 1) the identity of the metal, and 2) the steric and electronic properties of the ligands. Bimetallic catalysts introduce new optimization parameters such as 3) catalyst nuclearity (mononuclear vs. binuclear), and 4) bimetallic pairing (relative compatibility of two metal sites). In order to harness these new optimization parameters in developing systems, it is necessary to first understand the origin of bimetallic selectivity effects that already have been documented. This Concept article highlights bimetallic effects on the chemo-, regio-, and stereoselectivity of catalytic transformations, using selected case studies from the recent literature as illustrative examples.	RSC Adv.	76	Zhang, GF; Ding, CR	FALSE	FALSE	FALSE	FALSE
2797	10.1021/jacs.9b12343	doi.org/10.1021/jacs.9b12343	Base-Promoted C-C Bond Activation Enables Radical Allylation with Homoallylic Alcohols		J. Am. Chem. Soc.	76	Pratt, DA	FALSE	FALSE	FALSE	FALSE
2798	10.1002/adsc.201901099	doi.org/10.1002/adsc.201901099	Catalytic Reductions Without External Hydrogen Gas: Broad Scope Hydrogenations with Tetrahydroxydiboron and a Tertiary Amine		Adv. Synth. Catal.	76	Zajc, B; Lakshman, MK	FALSE	FALSE	FALSE	FALSE
2799	10.1002/cctc.201900561	doi.org/10.1002/cctc.201900561	Selective Synthesis of Secondary and Tertiary Amines by Reductive N-Alkylation of Nitriles and N-Alkylation of Amines and Ammonium Formate Catalyzed by Ruthenium Complex		ChemCatChem	76	Nikonov, GI	FALSE	FALSE	FALSE	FALSE
2800	10.1002/open.201900246	doi.org/10.1002/open.201900246	Efficient Protocol for Synthesis of beta-Hydroxy(alkoxy)selenides via Electrochemical Iodide-Catalyzed Oxyselenation of Styrene Derivatives with Dialkyl(aryl)diselenides		ChemistryOpen	76	Chen, JY; Shi, JW	FALSE	TRUE	FALSE	FALSE
2801	10.1021/jacs.9b02973	doi.org/10.1021/jacs.9b02973	Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights		J. Am. Chem. Soc.	76	Nevado, C	FALSE	FALSE	FALSE	FALSE
2802	10.1039/c9ob01355e	doi.org/10.1039/c9ob01355e	Stereoselective deconjugation of macrocyclic alpha,beta-unsaturated esters by sequential amidation and olefin transposition: application to enantioselective phase-transfer catalysis		Org. Biomol. Chem.	76	Lacour, J	FALSE	FALSE	FALSE	FALSE
2803	10.1039/c9cc00768g	doi.org/10.1039/c9cc00768g	Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides		Chem. Commun.	76	Wang, T	FALSE	FALSE	FALSE	FALSE
2804	10.1039/c9ob00313d	doi.org/10.1039/c9ob00313d	Direct C-S bond formation via C-O bond activation of phenols in a crossover Pd/Cu dual-metal catalysis system		Org. Biomol. Chem.	76	Khakyzadeh, V	FALSE	FALSE	FALSE	FALSE
2805	10.1002/anie.201814197	doi.org/10.1002/anie.201814197	Catalyst-Free Reductive Coupling of Aromatic and Aliphatic Nitro Compounds with Organohalides		Angew. Chem.-Int. Edit.	76	Niggemann, M	FALSE	FALSE	FALSE	FALSE
2806	10.1021/jacs.9b02158	doi.org/10.1021/jacs.9b02158	Mechanistically Guided Predictive Models for Ligand and Initiator Effects in Copper-Catalyzed Atom Transfer Radical Polymerization (Cu-ATRP)		J. Am. Chem. Soc.	76	Liu, P	FALSE	FALSE	FALSE	FALSE
2807	10.1021/acs.joc.9b00151	doi.org/10.1021/acs.joc.9b00151	Unified Protocol for Fe-Based Catalyzed Biaryl Cross-Couplings between Various Aryl Electrophiles and Aryl Grignard Reagents		J. Org. Chem.	76	Duan, XF	FALSE	TRUE	FALSE	FALSE
2808	10.1039/c9gc00305c	doi.org/10.1039/c9gc00305c	Recyclable nickel-catalyzed C-H/O-H dual functionalization of phenols with mandelic acids for the synthesis of 3-aryl benzofuran-2(3H)-ones under solvent-free conditions		Green Chem.	76	Qiu, RH; Yin, SF	FALSE	FALSE	FALSE	FALSE
2809	10.1039/c9cc00469f	doi.org/10.1039/c9cc00469f	Copper-catalyzed intermolecular oxidative trifluoromethyl-arylation of styrenes with NaSO2CF3 and indoles involving C-H functionalization		Chem. Commun.	76	Song, RJ; Li, JH	FALSE	FALSE	FALSE	FALSE
2810	10.1021/acs.inorgchem.8b02991	doi.org/10.1021/acs.inorgchem.8b02991	Synthetic Designs and Structural Investigations of Biomimetic Ni-Fe Thiolates		Inorg. Chem.	76	Rauchfuss, TB	FALSE	FALSE	FALSE	FALSE
2811	10.1021/acs.organomet.8b00566	doi.org/10.1021/acs.organomet.8b00566	A Pharmaceutical Industry Perspective on Sustainable Metal Catalysis		Organometallics	76	Leahy, DK	FALSE	FALSE	FALSE	FALSE
2812	10.1021/acs.joc.8b01762	doi.org/10.1021/acs.joc.8b01762	Reactions of Arylsulfonate Electrophiles with NMe4F: Mechanistic Insight, Reactivity, and Scope		J. Org. Chem.	76	Sanford, MS	FALSE	TRUE	FALSE	FALSE
2813	10.1002/anie.201713165	doi.org/10.1002/anie.201713165	Potassium-Zincate-Catalyzed Benzylic C-H Bond Addition of Diarylmethanes to Styrenes		Angew. Chem.-Int. Edit.	76	Guan, BT	FALSE	FALSE	FALSE	FALSE
2814	10.1002/chem.201801241	doi.org/10.1002/chem.201801241	Catalytic C-C Bond Formation Using a Simple Nickel Precatalyst System: Base- and Activator-Free Direct C-Allylation by Alcohols and Amines		Chem.-Eur. J.	76	Sweeney, JB	FALSE	FALSE	FALSE	FALSE
2815	10.1038/s41598-018-21366-1	doi.org/10.1038/s41598-018-21366-1	In vitro cytotoxicity activity of novel Schiff base ligand-lanthanide complexes		Sci Rep	76	Deivanayagam, E; Kim, HS; Vikraman, D	FALSE	FALSE	FALSE	FALSE
2816	10.1039/c7ob02947k	doi.org/10.1039/c7ob02947k	Nickel-catalyzed cross-coupling of ss-carbonyl alkenyl pivalates with arylzinc chlorides		Org. Biomol. Chem.	76	Wang, ZX	FALSE	FALSE	FALSE	FALSE
2817	10.24820/ark.5550190.p010.746	doi.org/10.24820/ark.5550190.p010.746	Nickel and palladium catalyzed Kumada-Tamao-Corriu cross-coupling reactions: scope and recent advances		Arkivoc	76	Dahadha, AA	FALSE	FALSE	FALSE	FALSE
2818	10.1039/c7ob02531a	doi.org/10.1039/c7ob02531a	Efficient cross-coupling of aryl/alkenyl triflates with acyclic secondary alkylboronic acids		Org. Biomol. Chem.	76	Xu, B	FALSE	FALSE	FALSE	FALSE
2819	10.1021/acscatal.7b02618	doi.org/10.1021/acscatal.7b02618	Mild and Efficient Ni-Catalyzed Biaryl Synthesis with Polyfluoroaryl Magnesium Species: Verification of the Arrest State, Uncovering the Hidden Competitive Second Transmetalation and Ligand-Accelerated Highly Selective Monoarylation		ACS Catal.	76	Huang, ZY	FALSE	FALSE	FALSE	FALSE
2820	10.1021/acs.orglett.7b02823	doi.org/10.1021/acs.orglett.7b02823	Nickel(II)-Catalyzed Site-Selective C-H Bond Trifluoromethylation of Arylamine in Water through a Coordinating Activation Strategy		Org. Lett.	76	Zhang, PF	FALSE	FALSE	FALSE	FALSE
2821	10.1039/c5nj02734a	doi.org/10.1039/c5nj02734a	Eco-friendly Suzuki-Miyaura coupling of arylboronic acids to aromatic ketones catalyzed by the oxime-palladacycle in biosolvent 2-MeTHF		New J. Chem.	76	Bora, U	FALSE	FALSE	FALSE	FALSE
2822	10.1016/j.tetlet.2015.04.004	doi.org/10.1016/j.tetlet.2015.04.004	Copper-catalyzed site-selective S-S and C-C homocoupling of alpha-enolic dithioesters: straightforward and efficient access to 1,2-dithiols		Tetrahedron Lett.	76	Singh, MS	FALSE	FALSE	FALSE	FALSE
2823	10.1021/acs.jpca.5b00569	doi.org/10.1021/acs.jpca.5b00569	Homolytic C-O Cleavage in Phosphates and Sulfonates		J. Phys. Chem. A	76	Zheng, WR	FALSE	FALSE	FALSE	FALSE
2824	10.1021/ol503707m	doi.org/10.1021/ol503707m	Nickel-Catalyzed Alkynylation of Anisoles via C-O Bond Cleavage		Org. Lett.	76	Tobisu, M	FALSE	FALSE	FALSE	FALSE
2825	10.1021/ol503213z	doi.org/10.1021/ol503213z	The Concise Synthesis of Unsymmetric Triarylacetonitriles via Pd-Catalyzed Sequential Arylation: A New Synthetic Approach to Tri- and Tetraarylmethanes		Org. Lett.	76	Nambo, M	FALSE	FALSE	FALSE	FALSE
2826	10.1039/c5cy00876j	doi.org/10.1039/c5cy00876j	Nickel N-heterocyclic carbene-catalyzed cross-coupling reaction of aryl aldehydes with organozinc reagents to produce aryl ketones		Catal. Sci. Technol.	76	Jin, C	FALSE	FALSE	FALSE	FALSE
2827	10.1021/jo501615a	doi.org/10.1021/jo501615a	Silver-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Ynol Ethers		J. Org. Chem.	76	Zhu, GG	FALSE	FALSE	FALSE	FALSE
2828	10.1002/ajoc.201402084	doi.org/10.1002/ajoc.201402084	Copper(I)-Oxide-Mediated Cyanation of Arenediazonium Tetrafluoroborates with Trimethylsilyl Cyanide: A Method for Synthesizing Aromatic Nitriles		Asian J. Org. Chem.	76	Li, JZ	FALSE	FALSE	FALSE	FALSE
2829	10.1002/anie.201405857	doi.org/10.1002/anie.201405857	Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition of beta-Ketoesters with Propargylic Esters		Angew. Chem.-Int. Edit.	76	Hu, XP	FALSE	FALSE	FALSE	FALSE
2830	10.1002/chem.201403093	doi.org/10.1002/chem.201403093	Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation		Chem.-Eur. J.	76	Jiang, XF	FALSE	FALSE	FALSE	FALSE
2831	10.1002/ejoc.201402120	doi.org/10.1002/ejoc.201402120	Suzuki-Miyaura Coupling of Aryl Sulfonates with Arylboronic Acids Using a Morpholine-Pd(OAc)2 Catalyst System		Eur. J. Org. Chem.	76	Abe, T	FALSE	FALSE	FALSE	FALSE
2832	10.1016/j.tet.2013.05.138	doi.org/10.1016/j.tet.2013.05.138	Cyanide as a powerful catalyst for facile synthesis of benzofused heteroaromatic compounds via aerobic oxidation		Tetrahedron	76	Cheon, CH	FALSE	FALSE	FALSE	FALSE
2833	10.1016/j.tet.2013.04.096	doi.org/10.1016/j.tet.2013.04.096	Nickel-catalyzed intramolecular C-H arylation using aryl pivalates as electrophiles		Tetrahedron	76	Kalyani, D	FALSE	FALSE	FALSE	FALSE
2834	10.1021/om300671j	doi.org/10.1021/om300671j	Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl Aziridines		Organometallics	76	Blum, SA	FALSE	FALSE	FALSE	FALSE
2835	10.1016/j.tet.2012.05.075	doi.org/10.1016/j.tet.2012.05.075	Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes		Tetrahedron	76	Huang, KW	FALSE	FALSE	FALSE	FALSE
2836	10.1002/ejoc.201200368	doi.org/10.1002/ejoc.201200368	Oxime-Palladacycle-Catalyzed Suzuki-Miyaura Arylation and Alkenylation of Aryl Imidazolesulfonates under Aqueous and Phosphane-Free Conditions		Eur. J. Org. Chem.	76	Alonso, DA	FALSE	FALSE	FALSE	FALSE
2837	10.1002/adsc.201100770	doi.org/10.1002/adsc.201100770	Nickel/Zinc Chloride-Promoted Domino Reaction of Enynes and Enones Including Unstrained C?C Bond Cleavage		Adv. Synth. Catal.	76	Ikeda, S	FALSE	FALSE	FALSE	FALSE
2838	10.1016/j.ica.2011.07.056	doi.org/10.1016/j.ica.2011.07.056	Aminophosphine-palladium(II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactions		Inorg. Chim. Acta	76	Aydemir, M	FALSE	FALSE	FALSE	FALSE
2839	10.1016/j.tet.2010.10.075	doi.org/10.1016/j.tet.2010.10.075	Synthesis of gamma-amino alcohols from aldehydes, enamines, and trichlorosilane using Lewis base catalysts		Tetrahedron	76	Sugiura, M	FALSE	FALSE	FALSE	FALSE
2840	10.1002/ejoc.201001112	doi.org/10.1002/ejoc.201001112	An Efficient Synthesis of Polysubstituted Naphthalene Derivatives by Gold-Catalyzed Cyclization of 1-Arylalka-2,3-dienyl Acetates		Eur. J. Org. Chem.	76	Ma, SM	FALSE	FALSE	FALSE	FALSE
2841	10.1055/s-2008-1078425	doi.org/10.1055/s-2008-1078425	Recent developments on hemilabile P,O-Type Ligands in cross-coupling reactions		Synlett	76	Kwong, FY	FALSE	FALSE	FALSE	FALSE
2842	10.1055/s-2006-926379	doi.org/10.1055/s-2006-926379	Copper-catalyzed ring-opening of heterobicyclic alkenes with Grignard reagents: Remarkably high anti-stereocontrol		Synthesis	76	Arrayas, RG	FALSE	FALSE	FALSE	FALSE
2843	10.1021/om049786q	doi.org/10.1021/om049786q	Dehalogenation of hexachlorocyclohexanes and simultaneous chlorination of triethylsilane catalyzed by rhodium and ruthenium complexes		Organometallics	76	Esteruelas, MA	FALSE	FALSE	FALSE	FALSE
2844	10.1002/slct.202103723	doi.org/10.1002/slct.202103723	Mechanism of Ligand-Controlled Chemoselectivity-Switchable Ni-Catalyzed C-N Cross-Coupling of Amine		ChemistrySelect	76	Deng, W; Xu, ZY	FALSE	FALSE	FALSE	FALSE
2845	10.1039/d1cy02159a	doi.org/10.1039/d1cy02159a	Ligand-free Guerbet-type reactions in air catalyzed by in situ formed complexes of base metal salt cobaltous chloride		Catal. Sci. Technol.	76	Kumar, A	FALSE	FALSE	FALSE	FALSE
2846	10.1002/asia.202101208	doi.org/10.1002/asia.202101208	Nickel-Catalyzed Asymmetric Hydrogenation for the Synthesis of a Key Intermediate of Sitagliptin		Chem.-Asian J.	76	Punji, B	FALSE	FALSE	FALSE	FALSE
2847	10.1039/d1sc05316g	doi.org/10.1039/d1sc05316g	Rapid and column-free syntheses of acyl fluorides and peptides using ex situ generated thionyl fluoride		Chem. Sci.	76	Sammis, GM	FALSE	FALSE	FALSE	FALSE
2848	10.3390/molecules26195947	doi.org/10.3390/molecules26195947	Nickel-Catalyzed Kumada Cross-Coupling Reactions of Benzylic Sulfonamides		Molecules	76	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
2849	10.1021/acs.joc.1c01625	doi.org/10.1021/acs.joc.1c01625	Dual Photoredox/Nickel-Promoted Alkylation of Heteroaryl Halides with Redox-Active Esters		J. Org. Chem.	76	Herrmann, AT	TRUE	FALSE	FALSE	FALSE
2850	10.1021/jacs.1c05988	doi.org/10.1021/jacs.1c05988	Non-innocent Radical Ion Intermediates in Photoredox Catalysis: Parallel Reduction Modes Enable Coupling of Diverse Aryl Chlorides		J. Am. Chem. Soc.	76	Wickens, ZK	TRUE	FALSE	FALSE	FALSE
2851	10.1021/acs.orglett.1c01765	doi.org/10.1021/acs.orglett.1c01765	Synthesis of alpha-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols		Org. Lett.	76	Gulcemal, D	FALSE	FALSE	FALSE	FALSE
2852	10.1038/s41598-021-89561-1	doi.org/10.1038/s41598-021-89561-1	A nickel phosphide nanoalloy catalyst for the C-3 alkylation of oxindoles with alcohols		Sci Rep	76	Mitsudome, T	FALSE	FALSE	FALSE	FALSE
2853	10.1002/tcr.202100053	doi.org/10.1002/tcr.202100053	Recent Advances in Transition-metal-catalyzed C-C Bond Formation via C(sp(2))-F Bond Cleavage		Chem. Rec.	76	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
2854	10.1039/c7sc02692g	doi.org/10.1039/c7sc02692g	Suzuki-Miyaura cross-coupling of amides and esters at room temperature: correlation with barriers to rotation around C-N and C-O bonds		Chem. Sci.	76	Szostak, M	FALSE	FALSE	FALSE	FALSE
2855	10.6023/cjoc201702001	doi.org/10.6023/cjoc201702001	Recent Advances in Chan-Evans-Lam Coupling Reaction		Chin. J. Org. Chem.	76	Mo, DL	FALSE	FALSE	FALSE	FALSE
2856	10.1055/s-0036-1588356	doi.org/10.1055/s-0036-1588356	Solvent-Directed Epoxide Opening with Primary Amines for the Synthesis of beta-Amino Alcohols		Synthesis	76	Moura-Letts, G	FALSE	FALSE	FALSE	FALSE
2857	10.1039/c6cc08759k	doi.org/10.1039/c6cc08759k	Ni(II)-catalyzed asymmetric addition of arylboronic acids to cyclic imines		Chem. Commun.	76	Yang, GQ; Zhang, WB	FALSE	FALSE	FALSE	FALSE
2858	10.1002/adsc.201600686	doi.org/10.1002/adsc.201600686	Rhodium-Catalyzed Asymmetric Allenylation of Sulfonylimines and Application to the Stereospecific Allylic Allenylation		Adv. Synth. Catal.	76	Sieber, JD	FALSE	FALSE	FALSE	FALSE
2859	10.1055/s-0035-1562343	doi.org/10.1055/s-0035-1562343	(NiCl)-Cl-II(1-Naphthyl)(PCy3)(2), An Air-Stable sigma-Ni-II Precatalyst for Quantitative Cross-Coupling of Aryl C-O Electrophiles with Aryl Neopentylglycolboronates		Synthesis	76	Percec, V	FALSE	TRUE	FALSE	FALSE
2860	10.1002/anie.201604406	doi.org/10.1002/anie.201604406	Nickel-Catalyzed Methylation of Aryl Halides with Deuterated Methyl Iodide		Angew. Chem.-Int. Edit.	76	Liao, XB	FALSE	FALSE	FALSE	FALSE
2861	10.1021/jacs.6b03384	doi.org/10.1021/jacs.6b03384	Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates		J. Am. Chem. Soc.	76	Morken, JP	FALSE	FALSE	FALSE	FALSE
2862	10.1063/5.0038672	doi.org/10.1063/5.0038672	Effects of linker flexibility on phase behavior and structure of linked colloidal gels	A variety of arylamines are shown to undergo oxidative C-C bond formation using quinone-based chloranil/H+ reagent as the recyclable organic (metal free) oxidant system to afford benzidines/naphthidines. Arylamines (3 degrees/2 degrees) designed with various substituents were employed to understand the steric as well as electronic preferences of oxidative dimerization, and a mechanism involving amine radical cation has been proposed. The tetraphenylbenzidine derivative obtained via oxidative C-C coupling has been further converted to blue-emissive hole-transporting material via a simple chemical transformation. This study highlights the preparation of novel HTMs in a simple, economic, and efficient manner.	J. Chem. Phys.	75	Truskett, TM	FALSE	FALSE	FALSE	FALSE
2863	10.1021/acs.accounts.0c00694	doi.org/10.1021/acs.accounts.0c00694	Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp(3))-H Cross-Coupling	Tricyclic biaryls are important scaffold structures in many natural products and lead compounds in drug discovery. The formation of a biaryl unit is often the key step for the synthesis of tricyclic biaryls. Despite significant progress toward the synthesis of biaryl compounds in recent years, the direct cross-coupling of two different aryl halides is still challenging and robust methods are lacking. Herein we report a direct cross-coupling of two different aryl halides in the presence of a palladium catalyst and boron ester, which provides a new and useful complementary method to synthesize tricyclic biaryls.	Accounts Chem. Res.	75	Doyle, AG	TRUE	FALSE	FALSE	FALSE
2864	10.1039/d0ra09639c	doi.org/10.1039/d0ra09639c	Highly economical and direct amination of sp(3) carbon using low-cost nickel pincer catalyst	A palladium-catalyzed monoselective C3 arylation of 2-oxindoles with aryl tosylates is described. With the Pd/CM-phos catalyst system, the corresponding 3-arylated oxindoles can be obtained in good to excellent yields (<= 97%). The reaction conditions are mild (using 0.5 mol % Pd in general and KF as a base), and functional groups such as methyl ester, NH amido, and enolizable keto moieties are found to be compatible.	RSC Adv.	75	Ghosh, A	FALSE	FALSE	FALSE	FALSE
2865	10.1021/acs.orglett.0c03466	doi.org/10.1021/acs.orglett.0c03466	Asymmetric alpha-Pentadienylation of Aldehydes with Cyclopropylacetylenes	A copper/borinic acid dual catalytic reaction enabled the enantioselective propargylation of aliphatic polyols. Readily available reagents and catalysts were used in this transformation, which displayed good to excellent chemo- and stereoselectivity for a broad array of substrates. The method was also applicable to the desymmetrization of meso 1,2-diols to furnish products with three stereogenic centers and a terminal alkyne group in one operation.	Org. Lett.	75	Han, ZY; Gong, LZ	FALSE	FALSE	FALSE	FALSE
2866	10.1021/jacs.0c09922	doi.org/10.1021/jacs.0c09922	Chemoselective Union of Olefins, Organohalides, and Redox-Active Esters Enables Regioselective Alkene Dialkylation	A task-specific functionalized hyper-cross linked polymer (HCP) with hollow spherical structure was synthesized by an easily accessible Friedel-Crafts reaction based approach. A harmonious coexistence of acid (sulfonic acid) and base (amine) sites on a microporous organic material was achieved. The acid base bifunctional HCP catalyst (HCP-A-B) structure was fully characterized by many physicochemical methods. In the subsequent tandem reactions (hydrolysis/Henry and hydrolysis/Knoevenagel reactions), the HCP-A-B catalyst displayed high catalytic efficiency and chemical stability toward water or organic solvent. These HCP-A-B catalyst characteristics led to the development of a previously unreported transformation of 2-ethoxy-3,4-dihydropyran derivative to a 2-cyclohexen-1-one derivative through a tandem reaction involving water-assisted ring opening hydrolysis of the dihydropyran, an intramolecular aldol reaction, and a dehydration reaction. In all of these reactions, the bifunctional HCP-A-B catalyst can be recovered and reused more than 10 times without significant loss of activity.	J. Am. Chem. Soc.	75	Koh, MJ	FALSE	FALSE	FALSE	FALSE
2867	10.1039/d0sc04326e	doi.org/10.1039/d0sc04326e	Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C-C bonds	The first catalytic asyminetric alpha-arylation of pyrazol-5-ones has been established by using 2-indolylinethahols as direct electrophilic arylation reagents,under the cooperative catalysis of Pd(0) and a chiral phosphoric acid; which afforded the alpha-arylation products of pyrazol-5-ones in generally high yields and good enantioselectivities (up to 99% yield, >99% ee).	Chem. Sci.	75	Wei, H	FALSE	FALSE	FALSE	FALSE
2868	10.1002/ejoc.202001109	doi.org/10.1002/ejoc.202001109	Cu-TEMPO Catalyzed Dehydrogenative Friedlander Annulation/sp(3) C-H Functionalization/Spiroannulation towards Spiro[indoline-3,3'-pyrrolizin]-2'-yl)-4-phenylquinoline-3-Carboxylates	New four coordinated homoleptic bis(diimidazolylidene)nickel(II) complexes (C1 & C2) were synthesized and characterized by elemental analysis, NMR (H-1 and C-13) as well as ESI-Mass spectrometry. The molecular structure of the complex C1 was identified by means of single-crystal X-ray diffraction analysis, which revealed that the complexes possess a distorted square planar geometry with chelating bis(diimidazolylidene) NHC ligands and two non coordinating bromide counter ions in tetradentate C4 fashion. A survey of their catalytic activity in Buchwald-Hartwig amination has been performed. The newly synthesized complexes also catalyzed the amination of aryl chlorides in the presence of (KOBu)-Bu-t. Various aryl chlorides and amines can react smoothly to give the corresponding aminated products in moderate to high yields. The scope of the reaction encompasses electronically varied aryl chlorides and nitrogen-containing heteroaryl chlorides, including pyridine and quinoline derivatives. Both secondary and primary amines are well tolerated under the optimal reaction conditions. (C) 2016 Elsevier B.V. All rights reserved.	Eur. J. Org. Chem.	75	Khan, FRN	FALSE	FALSE	FALSE	FALSE
2869	10.1039/d0qo00903b	doi.org/10.1039/d0qo00903b	How does the nickel catalyst control the doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles? The rebound mechanism	A new method for free radical methylation of pyrimidinones and pyridinones with dicumyl peroxide (DCP) under metal-free conditions is introduced. A 50 g-scale reaction could be performed safely at the desired concentration. The reaction solvent and DCP derivative were readily recovered by distillation. The product was purified by crystallization to minimize the amount of waste.	Org. Chem. Front.	75	Chen, XY; Wang, ZX	FALSE	FALSE	FALSE	FALSE
2870	10.1038/s41467-020-19194-x	doi.org/10.1038/s41467-020-19194-x	Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides	Based on many transition-metal-catalyzed Suzuki-Miyaura cross-coupling reactions of organoboron compounds in which C-B cleavages are involved, it is meaningful to understand one of the thermodynamic properties of the C-B bond, the strength of the C-B bond, which can be measured using homolytic bond dissociation enthalpies (BDEs). To this end, we first calculated 64 C-B BDEs of organoboron compounds by theoretical methods including composite high-level ab initio methods of G3, G4, G3B3, CBS-Q, CBS-QB3, and CBS-4M and 34 density functional theory (DFT) methods. The results show that it is reasonable and credible to regard the average values of six composite high-level methods as the standard C-B BDE values. By comparing the DFT methods, it is found that the M06-HF method provides the most accurate results and the root mean square error (RMSE) is the smallest of 6.4 kJ mol(-1). Therefore, the C-B BDEs including C(sp)-B, C(sp(2))-B and C(sp(3))-B of organoboron compounds such as boronic acids, trifluoroborate salts, boronate esters, etc. as well as the substituent effects were investigated by using the M06-HF method. The results indicated that the different substituents including electrondonating groups (EDGs), electron-withdrawing groups (EWGs) and conjugated effect groups (CEGs) exhibit different effects on different types of C-B BDEs. Moreover, the natural bond orbital (NBO) analysis was performed in order to further disclose the essence of BDE change patterns.	Nat. Commun.	75	Mao, JY	FALSE	FALSE	FALSE	FALSE
2871	10.1021/acs.orglett.0c02756	doi.org/10.1021/acs.orglett.0c02756	Ruthenium-Catalyzed Enantioselective Hydrogenation of Hydrazones	South Africa has one of the oldest chemical societies in the world and has a long history of natural products, synthetic, and medicinal chemistry yet the visibility of molecules discovered or synthesized in South Africa is very low. Is this because South African scientists are incapable of discovering influential and celebrated molecules, or is there inadequate publicity of such discoveries? Perspective profiles on the discovery and scope of research on 'Great South African Molecules' should be a good start to redress this state of affairs. One such molecule deserving publicity is the antioxidant mycothiol which is produced by mycobacteria. This is a molecule of interest not only because of its medicinal potential in the fight against tuberculosis, but also from synthetic methodology and enzyme inhibition studies. This review aims to illuminate the scope of research in mycothiol chemistry for the purpose of promoting multidisciplinary investigations related to this South African molecule.	Org. Lett.	75	Schuster, CH	FALSE	FALSE	FALSE	FALSE
2872	10.1021/jacs.0c07634	doi.org/10.1021/jacs.0c07634	Modular and Stereoselective Synthesis of C-Aryl Glycosides via Catellani Reaction	Two different kinds of Al2O3-ZrO2 have been prepared by the alkoxide sol-gel process: bulky-shaped and formed into spherical granules with the diameter of 2-3 mm. The catalysts have been obtained either by impregnating the support with the metal precursor (Pd or Ni salt solution) or by simultaneous addition of the precursor during synthesis of the support (the co-precipitation technique). The catalysts have been characterized structurally with scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption studies and successfully applied in the Suzuki-Miyaura cross-coupling of phenylboronic acid with different kinds of aryl halides (2-bromotoluene, 4-bromotoluene, 4-bromoanisole or 4-iodoanisole). Our experiments have shown that nickel species supported on Al2O3-ZrO2 can be successfully employed as the catalyst in the SuzukiMiyaura process. (C) 2016 Elsevier B.V. All rights reserved.	J. Am. Chem. Soc.	75	Cheng, GL	FALSE	FALSE	FALSE	FALSE
2873	10.1016/j.isci.2020.101377	doi.org/10.1016/j.isci.2020.101377	[Pd(NHC)(mu-Cl)Cl](2): Versatile and Highly Reactive Complexes for Cross-Coupling Reactions that Avoid Formation of Inactive Pd(I) Off-Cycle Products	The N-arylation of amines with arylhydrazines has been developed, achieving the selective cross coupling of aryl radicals with amines to form N-aryl amines. The reaction uses air as an oxidant, CoPc and Cu(OAc)(2) as catalysts. The reaction proceeds under mild conditions in air through a relay process, arylhydrazines are oxidized to aryldiazenes by CoPc, further oxidized to aryl radicals by air (O-2), which are trapped by Cu(OAc)(2)-amine complex, followed by reduction-elimination reaction to form N-aryl amines. Arylamines and arylhydrazines give the highest yields, but N-aryl-N-alkylamines and N-alkyl amines can be used as well. (C) 2016 Elsevier Ltd. All rights reserved.	iScience	75	Szostak, M	FALSE	FALSE	FALSE	FALSE
2874	10.1021/acs.joc.0c00139	doi.org/10.1021/acs.joc.0c00139	Photochemically Mediated Nickel-Catalyzed Synthesis of N-(Hetero)aryl Sulfamides	Herein we report an atom- and step economic aromatic cyanoalkylation reaction that employs nitriles as building blocks and proceeds through C-sp(2)-H and C-sp(3)-H bond activation steps mediated by Ni-III. In addition to cyanomethylation with MeCN, regioselective alpha-cyanoalkylation was observed with various nitrile substrates to generate secondary and tertiary nitriles. Importantly, to the best of our knowledge these are the first examples of C-H bond activation reactions occurring at a Ni-III center, which may exhibit different reactivity and selectivity profiles than those corresponding to analogous Ni-II centers. These studies provide guiding principles to design catalytic C-H activation and functionalization reactions involving high-valent Ni species.	J. Org. Chem.	75	Roizen, JL	TRUE	FALSE	FALSE	FALSE
2875	10.1246/cl.200099	doi.org/10.1246/cl.200099	Recent Progress towards the Use of Benzophenone Imines as an Ammonia Equivalent	The imidazolium salts, 1-(2,4,6-trimethylphenyl)-3-[(1R,2S,5R)-(-)-menthoxymethyl] imidazolium chloride (Mes-NHC-CH(2)OMent center dot HCl) (1a) and 1-(2,6-diisopropylphenyl)-3-[(1R, 2S, 5R)-(-)-menthoxymethyl] imidazolium chloride (iPr(2)Ph-NHC-CH(2)OMent center dot HCl) (1b), are readily accessible from inexpensive (1R,2S,5R)-(-)-menthol. They react with nickelocene to give two new chiral nickel-N-heterocyclic carbene (NHC) complexes, [Ni(Mes-NHC-CH(2)OMent)ClCp] (2a) and [Ni(iPr(2)Ph-NHC-CH(2)OMent)ClCp] (2b), in good yields. The new complexes were fully characterized by standard spectroscopic techniques and by a single crystal X-ray diffraction study on complex 2b. Complex 2b crystallizes in the chiral spacegroup P1, with two independent molecules in the unit cell, which are slightly different from each other. Preliminary studies show that these complexes are effective catalysts for the hydrosilylation of ketones. However no chiral induction was observed. (C) 2016 Elsevier B.V. All rights reserved.	Chem. Lett.	75	Morimoto, H; Ohshima, T	FALSE	FALSE	FALSE	FALSE
2876	10.1021/acs.organomet.0c00082	doi.org/10.1021/acs.organomet.0c00082	Mechanistic Investigation of the Nickel-Catalyzed Carbonylation of Alcohols	The development of a palladacyclic precatalyst supported by a new biaryl(dialkyl)phosphine ligand (VPhos) in combination with octanoic acid/sodium octanoate as a simple and effective surfactant system provided an improved catalyst system for the rapid construction of a broad spectrum of alkylated scaffolds from alkyl zinc reagents generated in situ.	Organometallics	75	Schaub, T	FALSE	FALSE	FALSE	FALSE
2877	10.1039/c9cy02080b	doi.org/10.1039/c9cy02080b	Buchwald-Hartwig cross-coupling of amides (transamidation) by selective N-C(O) cleavage mediated by air- and moisture-stable [Pd(NHC)(allyl)Cl] precatalysts: catalyst evaluation and mechanism		Catal. Sci. Technol.	75	Szostak, M	FALSE	FALSE	FALSE	FALSE
2878	10.1002/chem.201904845	doi.org/10.1002/chem.201904845	Design, Synthesis and Characterization of Nickel-Functionalized Covalent Organic Framework NiCl@RIO-12 for Heterogeneous Suzuki-Miyaura Catalysis		Chem.-Eur. J.	75	Esteves, PM	FALSE	FALSE	FALSE	FALSE
2879	10.1021/acs.orglett.9b04119	doi.org/10.1021/acs.orglett.9b04119	Catalytic Sulfamoylation of Alcohols with Activated Aryl Sulfamates		Org. Lett.	75	Miller, SJ	FALSE	FALSE	FALSE	FALSE
2880	10.1021/acs.joc.9b02582	doi.org/10.1021/acs.joc.9b02582	Rhodium(III)-Catalyzed Diastereoselective Ring-Opening of 7-Azabenzonorbornadienes with Aromatic Ketoximes: Synthesis of Benzophenanthridine Derivatives		J. Org. Chem.	75	Jeganmohan, M	FALSE	FALSE	FALSE	FALSE
2881	10.1002/chem.201904288	doi.org/10.1002/chem.201904288	Formal Aniline Synthesis from Phenols through Deoxygenative N-Centered Radical Substitution		Chem.-Eur. J.	75	Schmidt, VA	FALSE	FALSE	FALSE	FALSE
2882	10.1039/c9cc05807a	doi.org/10.1039/c9cc05807a	Chelation-directed remote meta-C-H functionalization of aromatic aldehydes and ketones		Chem. Commun.	75	Xu, XH; Jin, Z	FALSE	FALSE	FALSE	FALSE
2883	10.1002/ejoc.201900909	doi.org/10.1002/ejoc.201900909	An Insight into Nitromethane as an Organic Nitrile Alternative Source towards the Synthesis of Aryl Nitriles		Eur. J. Org. Chem.	75	Thakur, AJ; Bora, U	FALSE	FALSE	FALSE	FALSE
2884	10.1055/s-0037-1611853	doi.org/10.1055/s-0037-1611853	An Old Dog with New Tricks: Enjoin Wolff-Kishner Reduction for Alcohol Deoxygenation and C-C Bond Formations		Synlett	75	Li, CJ	FALSE	FALSE	FALSE	FALSE
2885	10.1039/c9gc01180c	doi.org/10.1039/c9gc01180c	Synthesis of amides from acid chlorides and amines in the bio-based solvent Cyrene (TM)		Green Chem.	75	Camp, JE	FALSE	FALSE	FALSE	FALSE
2886	10.1002/anie.201902315	doi.org/10.1002/anie.201902315	Electrochemical [4+2] Annulation-Rearrangement-Aromatization of Styrenes: Synthesis of Naphthalene Derivatives		Angew. Chem.-Int. Edit.	75	Ye, JX	FALSE	TRUE	FALSE	FALSE
2887	10.1039/c8gc03895c	doi.org/10.1039/c8gc03895c	Four-component thiazole formation from simple chemicals under metal-free conditions		Green Chem.	75	Huang, HW; Deng, GJ	FALSE	FALSE	FALSE	FALSE
2888	10.1002/anie.201813148	doi.org/10.1002/anie.201813148	Direct Carbohydroxylation of Arylalkenes with Allylic Alcohols: Cooperative Catalysis of Copper, Silver, and a Bronsted Acid		Angew. Chem.-Int. Edit.	75	Bao, M	FALSE	FALSE	FALSE	FALSE
2889	10.1039/c8sc04437f	doi.org/10.1039/c8sc04437f	Nickel-catalyzed cyanation of aryl halides and triflates using acetonitrile via C-CN bond cleavage assisted by 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine		Chem. Sci.	75	Tsurugi, H; Mashima, K	FALSE	FALSE	FALSE	FALSE
2890	10.1039/c8cc08504h	doi.org/10.1039/c8cc08504h	Nickel-catalysed decarbonylative borylation of aroyl fluorides		Chem. Commun.	75	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
2891	10.1021/acs.joc.8b01763	doi.org/10.1021/acs.joc.8b01763	Nickel-Catalyzed Cyanation of Benzylic and Allylic Pivalate Esters		J. Org. Chem.	75	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
2892	10.1002/asia.201800759	doi.org/10.1002/asia.201800759	Ruthenium-Pincer-Catalyzed Hydrogenation of Lactams to Amino Alcohols		Chem.-Asian J.	75	Tu, T	FALSE	FALSE	FALSE	FALSE
2893	10.1039/c8qo00585k	doi.org/10.1039/c8qo00585k	Transition-metal-catalyzed decarbonylation of carboxylic acids to olefins: exploiting acyl C-O activation for the production of high value products		Org. Chem. Front.	75	Szostak, M	FALSE	FALSE	FALSE	FALSE
2894	10.1016/j.chempr.2018.04.008	doi.org/10.1016/j.chempr.2018.04.008	Remote sp(3) C-H Amination of Alkenes with Nitroarenes		Chem	75	Zhu, SL	FALSE	FALSE	FALSE	FALSE
2895	10.1021/acs.joc.7b03215	doi.org/10.1021/acs.joc.7b03215	Nickel-Catalyzed Phosphine Free Direct N-Alkylation of Amides with Alcohols		J. Org. Chem.	75	Banerjee, D	FALSE	FALSE	FALSE	FALSE
2896	10.1039/c7qo00850c	doi.org/10.1039/c7qo00850c	Ni(I)- Ni(III) vs. Ni(II)-Ni(IV): mechanistic study of Ni-catalyzed alkylation of benzamides with alkyl halides		Org. Chem. Front.	75	Bai, RP; Lan, Y	FALSE	FALSE	FALSE	FALSE
2897	10.1002/ejoc.201701300	doi.org/10.1002/ejoc.201701300	Room Temperature Ni-0/PCy3-Catalyzed Coupling Reactions of Aryl Arenesulfonates with Bis(pinacolato)diboron		Eur. J. Org. Chem.	75	Hu, QS	FALSE	FALSE	FALSE	FALSE
2898	10.1021/acs.joc.7b02363	doi.org/10.1021/acs.joc.7b02363	N,N '-Bisoxalamides Enhance the Catalytic Activity in Cu-Catalyzed Coupling of (Hetero)Aryl Bromides with Anilines and Secondary Amines		J. Org. Chem.	75	Ma, DW	FALSE	FALSE	FALSE	FALSE
2899	10.1002/anie.201506751	doi.org/10.1002/anie.201506751	Formal Direct Cross-Coupling of Phenols with Amines		Angew. Chem.-Int. Edit.	75	Li, CJ	FALSE	FALSE	FALSE	FALSE
2900	10.1016/j.tet.2015.08.056	doi.org/10.1016/j.tet.2015.08.056	Iodine-promoted sequential Michael and oxidative dehydrogenation processes: synthesis of trisubstituted methanes containing a coumarin and a chromone ring		Tetrahedron	75	Kong, LY	FALSE	FALSE	FALSE	FALSE
2901	10.1021/jacs.5b03340	doi.org/10.1021/jacs.5b03340	Ni-Catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2		J. Am. Chem. Soc.	75	Martin, R	FALSE	FALSE	FALSE	FALSE
2902	10.1016/j.tet.2015.01.046	doi.org/10.1016/j.tet.2015.01.046	Allyl-aryl coupling of allylic carbonates with arylboronic acids catalyzed by palladium nanoparticles in ionic liquid		Tetrahedron	75	Zhang, YJ	FALSE	FALSE	FALSE	FALSE
2903	10.1039/c5ra00724k	doi.org/10.1039/c5ra00724k	Iodine-induced synthesis of sulfonate esters from sodium sulfinates and phenols under mild conditions		RSC Adv.	75	Yuan, GQ	FALSE	FALSE	FALSE	FALSE
2904	10.1039/c4cc08187k	doi.org/10.1039/c4cc08187k	Nickel catalyzed dealkoxylative C-sp2-C-sp3 cross coupling reactions - stereospecific synthesis of allylsilanes from enol ethers		Chem. Commun.	75	Rueping, M	FALSE	FALSE	FALSE	FALSE
2905	10.1039/c5sc02942b	doi.org/10.1039/c5sc02942b	C-H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C-H activation		Chem. Sci.	75	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
2906	10.1002/ejoc.201403240	doi.org/10.1002/ejoc.201403240	Trimethylsilyl Iodide Mediated One-Pot Synthesis of 2-Allyl-2H-chromenes		Eur. J. Org. Chem.	75	Mohapatra, DK	FALSE	FALSE	FALSE	FALSE
2907	10.1039/c5ob00289c	doi.org/10.1039/c5ob00289c	Dendrimer-encapsulated Pd nanoparticles as catalysts for C-C cross-couplings in flow microreactors		Org. Biomol. Chem.	75	Verboom, W	FALSE	FALSE	FALSE	FALSE
2908	10.1002/adsc.201400460	doi.org/10.1002/adsc.201400460	Direct Nickel-Catalyzed Amination of Phenols via C-O Bond Activation using 2,4,6-Trichloro-1,3,5-triazine (TCT) as Reagent		Adv. Synth. Catal.	75	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
2909	10.1039/c4ob01011f	doi.org/10.1039/c4ob01011f	Stereoselective one-pot synthesis of beta-alkylsulfide enol esters. Base-triggered rearrangement under mild conditions		Org. Biomol. Chem.	75	Bisogno, FR	FALSE	FALSE	FALSE	FALSE
2910	10.1002/anie.201304884	doi.org/10.1002/anie.201304884	Twofold Unsymmetrical C-H Functionalization of PyrDipSi-Substituted Arenes: A General Method for the Synthesis of Substituted meta-Halophenols		Angew. Chem.-Int. Edit.	75	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
2911	10.1002/ejoc.201300738	doi.org/10.1002/ejoc.201300738	Organocatalytic Asymmetric Allylic Alkylation of Morita-Baylis-Hillman Carbonates with Phosphorus Ylides: Synthesis of Chiral 3-Substituted 2,4-Functionalized 1,4-Pentadienes		Eur. J. Org. Chem.	75	Zhu, CJ	FALSE	FALSE	FALSE	FALSE
2912	10.6023/cjoc201212033	doi.org/10.6023/cjoc201212033	Recent Progress in the Research of Transition-Metal-Catalyzed C-CN Bond Cleavage		Chin. J. Org. Chem.	75	Kou, XZ	FALSE	FALSE	FALSE	FALSE
2913	10.1002/chem.201301033	doi.org/10.1002/chem.201301033	Synthesis of Arylacetates from Benzylic Alcohols and Oxalate Esters through Decarboxylative Coupling		Chem.-Eur. J.	75	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
2914	10.1002/cssc.201200804	doi.org/10.1002/cssc.201200804	C-C Cross-Coupling of Primary and Secondary Benzylic Alcohols Using Supported Gold-Based Bimetallic Catalysts		ChemSusChem	75	Liu, X	FALSE	FALSE	FALSE	FALSE
2915	10.1002/anie.201300481	doi.org/10.1002/anie.201300481	Weak Arene C-H center dot center dot center dot O Hydrogen Bonding in Palladium-Catalyzed Arylation and Vinylation of Lactones		Angew. Chem.-Int. Edit.	75	Zhou, JR	FALSE	FALSE	FALSE	FALSE
2916	10.1002/chem.201202824	doi.org/10.1002/chem.201202824	Copper- and Phosphine-Ligand-Free Palladium-Catalyzed Direct Allylation of Electron-Deficient Polyfluoroarenes with Allylic Chlorides		Chem.-Eur. J.	75	Zhang, XG	FALSE	TRUE	FALSE	FALSE
2917	10.1002/pola.26273	doi.org/10.1002/pola.26273	PEG-b-PtBA-b-PHEMA well-defined amphiphilic triblock copolymer: Synthesis, self-assembly, and application in drug delivery		J. Polym. Sci. Pol. Chem.	75	Yang, D	FALSE	FALSE	FALSE	FALSE
2918	10.1021/om300399j	doi.org/10.1021/om300399j	C-Br Activation of Aryl Bromides at Ni-0(NHC)(2): Stoichiometric Reactions, Catalytic Application in Suzuki-Miyaura Cross-Coupling, and Catalyst Degradation		Organometallics	75	Radius, U	FALSE	FALSE	FALSE	FALSE
2919	10.1039/b920285d	doi.org/10.1039/b920285d	Synthesis of phalluside-1 and Sch II using 1,2-metallate rearrangements		Org. Biomol. Chem.	75	Kocienski, PJ	FALSE	FALSE	FALSE	FALSE
2920	10.1002/anie.201005121	doi.org/10.1002/anie.201005121	A Mild and Efficient Palladium-Catalyzed Cyanation of Aryl Mesylates in Water or tBuOH/Water		Angew. Chem.-Int. Edit.	75	Kwong, FY	FALSE	FALSE	FALSE	FALSE
2921	10.1016/j.tet.2009.09.011	doi.org/10.1016/j.tet.2009.09.011	Indirect regioselective heteroarylation of indoles through a Friedel-Crafts reaction with (E)-1,4-diaryl-2-buten-1,4-diones		Tetrahedron	75	Pedro, JR	FALSE	FALSE	FALSE	FALSE
2922	10.1021/jo802426g	doi.org/10.1021/jo802426g	New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents		J. Org. Chem.	75	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
2923	10.1016/j.tet.2008.11.062	doi.org/10.1016/j.tet.2008.11.062	Copper(I)-catalyzed S-arylation of thiols with activated aryl chlorides on water		Tetrahedron	75	Dominguez, E	FALSE	FALSE	FALSE	FALSE
2924	10.1021/ic0606227	doi.org/10.1021/ic0606227	Heterometallic dithiolene complexes formed by stepwise displacement of cyclopentadienyl ligands from nickelocene with CpMo(S2C2Ph2)(2)		Inorg. Chem.	75	Morris, MJ	FALSE	FALSE	FALSE	FALSE
2925	10.1021/cc0600066	doi.org/10.1021/cc0600066	Revisiting benzenesulfonyl linker for the deoxygenation and multifunctionalization of phenols		J. Comb. Chem.	75	Tsukamoto, H	FALSE	FALSE	FALSE	FALSE
2926	10.1039/b514635f	doi.org/10.1039/b514635f	Molecular iodine: a highly efficient catalyst in the synthesis of quinolines via Friedlander annulation		Org. Biomol. Chem.	75	Wu, J	FALSE	FALSE	FALSE	FALSE
2927	10.1021/om050224w	doi.org/10.1021/om050224w	Synthesis, structural characterization, computational study, and catalytic activity of metal complexes based on tetradentate pyridine/N-heterocyclic carbene ligand		Organometallics	75	Lee, HM	FALSE	FALSE	FALSE	FALSE
2928	10.1016/j.tet.2004.03.072	doi.org/10.1016/j.tet.2004.03.072	Preparation of unsymmetrical terphenyls via the nickel-catalyzed cross-coupling of alkyl biphenylsulfonates with aryl Grignard reagents		Tetrahedron	75	Park, KY	FALSE	FALSE	FALSE	FALSE
2929	10.1246/bcsj.73.985	doi.org/10.1246/bcsj.73.985	Home-coupling reactions of alkenyl- and arylfluorosilanes mediated by a copper(I) salt		Bull. Chem. Soc. Jpn.	75	Mori, A	FALSE	FALSE	FALSE	FALSE
2930	10.1021/jo991337q	doi.org/10.1021/jo991337q	Palladium-catalyzed borylation of aryl halides or triflates with dialkoxyborane: A novel and facile synthetic route to arylboronates		J. Org. Chem.	75	Masuda, Y	FALSE	FALSE	FALSE	FALSE
2931	10.1246/bcsj.69.1065	doi.org/10.1246/bcsj.69.1065	Activation of C-O and C-N bonds in allylic alcohols and amines by palladium complexes promoted by CO2. Synthetic applications to allylation of nucleophiles, carbonylation, and allylamine disproportionation		Bull. Chem. Soc. Jpn.	75		FALSE	FALSE	FALSE	FALSE
2932	10.3891/acta.chem.scand.50-0259	doi.org/10.3891/acta.chem.scand.50-0259	Asymmetric hydrosilylation of olefins catalyzed by MOP-palladium complexes		Acta Chem. Scand.	75	Hayashi, T	FALSE	FALSE	FALSE	FALSE
2933	10.1021/jo00012a043	doi.org/10.1021/jo00012a043	TRANSITION-METAL PROMOTED REACTIONS .33. NICKEL-CATALYZED OLEFINATION OF CYCLIC BENZYLIC DITHIOACETALS BY GRIGNARD-REAGENTS - SCOPE AND MECHANISM		J. Org. Chem.	75		FALSE	FALSE	FALSE	FALSE
2934	10.1021/ja00313a032	doi.org/10.1021/ja00313a032	DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM-(II) - AN EFFECTIVE CATALYST FOR CROSS-COUPLING OF SECONDARY AND PRIMARY ALKYL GRIGNARD AND ALKYLZINC REAGENTS WITH ORGANIC HALIDES		J. Am. Chem. Soc.	75	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
2935	10.1016/j.tet.2021.132549	doi.org/10.1016/j.tet.2021.132549	Simple and efficient nickel-catalyzed cross-coupling reaction of alkenylalanes with alkynyl halides for synthesis of conjugated enynes		Tetrahedron	75	Li, QH	FALSE	FALSE	FALSE	FALSE
2936	10.1039/d1qo01580j	doi.org/10.1039/d1qo01580j	A mechanistic study on the regioselective Ni-catalyzed methylation-alkenylation of alkyne with AlMe3 and allylic alcohol		Org. Chem. Front.	75	Shi, J	FALSE	FALSE	FALSE	FALSE
2937	10.1002/ejoc.202101114	doi.org/10.1002/ejoc.202101114	An Environmentally Benign, Catalyst-Free N-C Bond Cleavage/Formation of Primary, Secondary, and Tertiary Unactivated Amides		Eur. J. Org. Chem.	75	Karpoormath, R	FALSE	FALSE	FALSE	FALSE
2938	10.1021/jacs.1c08695	doi.org/10.1021/jacs.1c08695	Cobalt-Catalyzed Enantiospecific Dynamic Kinetic Cross-Electrophile Vinylation of Allylic Alcohols with Vinyl Triflates		J. Am. Chem. Soc.	75	Shu, XZ	FALSE	TRUE	FALSE	FALSE
2939	10.1039/d1ob00797a	doi.org/10.1039/d1ob00797a	Pd(ii)-Catalyzed oxidative alkenylation of 4-hydroxycoumarin with maleimide via a C-H bond activation strategy		Org. Biomol. Chem.	75	Gogoi, P	FALSE	FALSE	FALSE	FALSE
2940	10.1021/acs.joc.1c00806	doi.org/10.1021/acs.joc.1c00806	Molecular Spin State Switching and Photochromism in the Red and Near Infrared with Ni(II) Chlorin and Ni(II) Bacteriochlorin		J. Org. Chem.	75	Herges, R	TRUE	FALSE	FALSE	FALSE
2941	10.6023/cjoc202009029	doi.org/10.6023/cjoc202009029	Research Progress of Cross-Coupling Reactions of Alkylaluminums with Electrophiles Reagents		Chin. J. Org. Chem.	75	Li, QH	FALSE	TRUE	FALSE	FALSE
2942	10.1039/d0nj06208a	doi.org/10.1039/d0nj06208a	NiFe2O4@SiO2@ZrO2/SO42-/Cu/Co nanoparticles: a novel, efficient, magnetically recyclable and bimetallic catalyst for Pd-free Suzuki, Heck and C-N cross-coupling reactions in aqueous media		New J. Chem.	75	Alavi, GSA	FALSE	FALSE	FALSE	FALSE
2943	10.1021/acs.accounts.1c00050	doi.org/10.1021/acs.accounts.1c00050	Mechanism and Selectivity Control in Ni- and Pd-Catalyzed Cross-Couplings Involving Carbon-Oxygen Bond Activation		Accounts Chem. Res.	75	Hong, X	FALSE	FALSE	FALSE	FALSE
2944	10.1021/acs.organomet.1c00096	doi.org/10.1021/acs.organomet.1c00096	Ni-Catalyzed Coupling of Butadiene, Aldimines, and Arylboronic Acids to Homoallylic Amines under Base-Free Conditions		Organometallics	75	Shi, SL	FALSE	FALSE	FALSE	FALSE
2945	10.1039/d0qo01465f	doi.org/10.1039/d0qo01465f	Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes		Org. Chem. Front.	75	Zhang, WZ	FALSE	FALSE	FALSE	FALSE
2946	10.1021/acs.orglett.7b01135	doi.org/10.1021/acs.orglett.7b01135	Copper-Catalyzed Asymmetric Hydroboration of 1,1-Disubstituted Alkenes		Org. Lett.	75	Xiong, T	FALSE	FALSE	FALSE	FALSE
2947	10.1021/acs.organomet.7b00095	doi.org/10.1021/acs.organomet.7b00095	Mechanistic Study of Copper-Catalyzed Decarboxylative C-N Cross-Coupling with Hypervalent Iodine Oxidant		Organometallics	75	Jiang, JL; Shi, J	FALSE	FALSE	FALSE	FALSE
2948	10.1002/slct.201700623	doi.org/10.1002/slct.201700623	Efficient Access to o-Phenylendiamines and Their Use in the Synthesis of a 1,2-Dialkyl-5-trifluoromethylbenzimidazoles Library Under Microwave Conditions		ChemistrySelect	75	Portilla, J	FALSE	FALSE	FALSE	FALSE
2949	10.1021/acscatal.7b00245	doi.org/10.1021/acscatal.7b00245	A Cross-Coupling Approach to Amide Bond Formation from Esters		ACS Catal.	75	Newman, SG	FALSE	FALSE	FALSE	FALSE
2950	10.1021/acs.joc.6b02354	doi.org/10.1021/acs.joc.6b02354	Cobalt-Catalyzed Biaryl Couplings via C-F Bond Activation in the Absence of Phosphine or NHC Ligands		J. Org. Chem.	75	Duan, XF	FALSE	FALSE	FALSE	FALSE
2951	10.1016/j.tetlet.2016.10.087	doi.org/10.1016/j.tetlet.2016.10.087	Catalyst free, three-component approach for unsymmetrical triarylmethanes (TRAMs)		Tetrahedron Lett.	75	Baire, B	FALSE	FALSE	FALSE	FALSE
2952	10.1021/acs.orglett.6b03090	doi.org/10.1021/acs.orglett.6b03090	Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes		Org. Lett.	75	Montgomery, J	FALSE	FALSE	FALSE	FALSE
2953	10.1002/anie.201606529	doi.org/10.1002/anie.201606529	Nickel Catalysis Enables Oxidative C(sp(2))-H/C(sp(2))-H Cross-Coupling Reactions between Two Heteroarenes		Angew. Chem.-Int. Edit.	75	You, JS	FALSE	FALSE	FALSE	FALSE
2954	10.1002/hc.21309	doi.org/10.1002/hc.21309	Straightforward Diastereoselective Synthesis of P-Chirogenic (1R )-1,8,8-Trimethyl-2,4-diaza-3-phosphabicyclo[3.2.1]octane 3-Oxides: Application as Chiral NMR Solvating Agents		Heteroatom Chem.	75	Wilhelm, R	FALSE	FALSE	FALSE	FALSE
2955	10.1246/cl.150913	doi.org/10.1246/cl.150913	Branch Selective Mural-type Alkene Hydroarylation Reactions		Chem. Lett.	75	Bower, JF	FALSE	FALSE	FALSE	FALSE
2956	10.1039/c6ob01307d	doi.org/10.1039/c6ob01307d	Nickel-catalyzed Chan-Lam cross-coupling: chemoselective N-arylation of 2-aminobenzimidazoles		Org. Biomol. Chem.	75	Das, P	FALSE	FALSE	FALSE	FALSE
2957	10.1016/j.tet.2020.131804	doi.org/10.1016/j.tet.2020.131804	Cu-mediated or metal-free alkylation of gem-dibromoalkenes with tertiary, secondary and primary alkyl Grignard reagents	The ubiquitous use of pi-rich five-membered heterocycles has driven the development of new methods for their synthesis for more than a century. Here, we disclose a general and reliable reaction manifold for the construction of highly substituted heterocycles through a facile Lewis-acid-catalyzed oxetane rearrangement. Notably, this methodology employs a keto-oxetane motif as a 1,4-dicarbonyl surrogate, which can be synthesized using robust alkylation or alkenylation reactions, and thus obviates the need to access 1,4-dicarbonyl compounds via umpoled starting materials. We harnessed this reactivity to generate a broad range of substituted furans and pyrroles, and extended this methodology to produce benzo-fused versions thereof.	Tetrahedron	74	Cao, S	FALSE	FALSE	FALSE	FALSE
2958	10.1021/acs.joc.0c02556	doi.org/10.1021/acs.joc.0c02556	Nickel-Catalyzed Asymmetric Hydroarylation of Vinylarenes: Direct Enantioselective Synthesis of Chiral 1,1-Diarylethanes	The first catalytic, regioselective cross-coupling of 3,4-epoxyalcohol with aryl iodides is reported. The combination of NiCl2 center dot DME and a newly developed C-2-symmetric oxazoline ligand plays a key role in selective ring opening of several 3,4-epoxy alcohols at the C4 position. This general protocol furnishes a new type of enantioenriched 4,4-diaryl alkane which also incorporates an additional 1,3-diol that can be easily transformed to a variety of functional groups. The products are formed with excellent regioselectivity (>99:1), diastereoselectivity (up to 99:1), and enantiopurity (up to >99.9% ee).	J. Org. Chem.	74	Stanley, LM	FALSE	FALSE	FALSE	FALSE
2959	10.1021/acs.organomet.0c00726	doi.org/10.1021/acs.organomet.0c00726	Synthesis of NHC-Iridium(III) Complexes Based on N-Iminoimidazolium Ylides and Their Use for the Amine Alkylation by Borrowing Hydrogen Catalysis	Transition-metal-catalyzed cyanation of aryl halides is' a process of significant importance in the preparation pharmaceuticals, organic materials and agrochemicals. Here, we demonstrate a palladium-catalyzed decarbonylative cyanation of amides by highly selective carbon nitrogen bond cleavage for the synthesis of a wide range aryl nitriles. The utility of this technology is demonstrated by the synthesis of isotopically labeled aryl nitriles and orthogonal cross-coupling reactions of bench-stable amides, to establish cross-coupling synthons with opposite polarity.	Organometallics	74	Legault, CY	FALSE	FALSE	FALSE	FALSE
2960	10.1021/acscatal.0c03939	doi.org/10.1021/acscatal.0c03939	Iterative Supervised Principal Component Analysis Driven Ligand Design for Regioselective Ti-Catalyzed Pyrrole Synthesis	A copper-catalyzed selective C-N cross-coupling has been developed based on chelation-assisted amidation of readily available aryl boronic acids at room-temperature under open-flask conditions. The reaction is scalable and tolerates a wide spectrum of functional groups delivering fully substituted unsymmetrical amides in high yields (up to 96%). The C-N cross coupling also established with aryl silanes, extending the palette of coupling partners of this strategy.	ACS Catal.	74	Reiner, BR; Tonks, IA	FALSE	FALSE	FALSE	FALSE
2961	10.1021/acs.organomet.0c00140	doi.org/10.1021/acs.organomet.0c00140	Effect of Aryl Ligand Identity on Catalytic Performance of Trineopentylphosphine Arylpalladium Complexes in N-Arylation Reactions	This contribution describes a regioselective cyclization of hypervalent iodine reagents (HIR) with propiolic acids in the presence of a rhodium catalyst. The mild decarboxylation can tolerate a wide range of groups and generates 4H-furo[3,2-c] chro-men-4-one derivatives in good isolated yields.	Organometallics	74	Shaughnessy, KH	FALSE	FALSE	FALSE	FALSE
2962	10.1039/d0dt02964e	doi.org/10.1039/d0dt02964e	Versatility of the bis(iminopyrrolylmethyl)amine ligand: tautomerism, protonation, helical chirality, and the secondary coordination sphere with halogen bonds in the formation of copper(II) and nickel(II) complexes	Herein we report the first example of (hetero)-arylation of ammonia using a monoligated palladium-NHC complex. The new, rationally designed, precatalyst (DiMeIHept(Cl))Pd(allyl)Cl featuring highly branched alkyl chains has been shown to be effective in selective aminations across a range of challenging substrates, including nitrogen containing heterocycles and those featuring base-sensitive functionality. The less bulky Pd-PEPPSI-IPent(Cl) precatalyst performs well for ortho-substituted aryl halides, giving monoarylated products in high yield with good selectivity.	Dalton Trans.	74	Mani, G	FALSE	FALSE	FALSE	FALSE
2963	10.1021/jacs.0c06177	doi.org/10.1021/jacs.0c06177	Copper-Catalyzed Enantioselective Radical 1,4-Difunctionalization of 1,3-Enynes	A CuCl-catalyzed Ullmann-type C-N cross coupling reaction of carbazoles and 2-bromopyridine deriva tives has been developed for the synthesis of N-heteroarylcarbazole derivatives employing 1-methyl-imidazole and t-BuOLi as ligand and base, respectively, both of which are found to significantly promote the reaction. Low cost and low loading of both catalyst and ligand, together with high reaction yields, render this practical reaction to be suitable for large-scale preparations and could be useful in material science.	J. Am. Chem. Soc.	74	Bao, HL	FALSE	FALSE	FALSE	FALSE
2964	10.1039/d0qo00632g	doi.org/10.1039/d0qo00632g	Indium-mediated difunctionalization of iodoalkyl-tethered unactivated alkenes via an intramolecular cyclization and an ensuing palladium-catalyzed cross-coupling reaction with aryl halides	A direct and efficient approach to 1,3,5-trisubstituted benzenes has been developed via N-heterocyclic carbene-catalyzed [2 + 4] annulation of alpha-bromoenals and alpha-cyano-beta-methylenones. The reaction worked well for both aryl- and alkylenones.	Org. Chem. Front.	74	Han, GZ; Shen, ZL	FALSE	FALSE	FALSE	FALSE
2965	10.1002/slct.202001578	doi.org/10.1002/slct.202001578	Application ofN-Aryl Ethanolamines asN,O-Ligand in Nickel(II)-Catalyzed Carbon-Carbon Bond Formation in Heck Coupling Reactions	A series of well-defined iron(II) complexes of the types [Fe(PNP)Br-2] and [Fe(PNP)(CO)Br-2] with PNP pincer ligands based on triazine and pyridine backbones were prepared and fully characterized. These complexes were tested as catalysts for the alkylation of amines by alcohols. The high-spin complexes [Fe(PNP)Br-2] are catalytically inactive. The low-spin complexes [Fe(PNP)(CO)Br-2] bearing a carbonyl co-ligand efficiently and selectively convert primary alcohols and aromatic and benzylic amines selectively into mono-N-alkylated amines in good to excellent isolated yields. A mechanistic proposal is given.	ChemistrySelect	74	Jagtap, SV	FALSE	FALSE	FALSE	FALSE
2966	10.1002/cctc.202000882	doi.org/10.1002/cctc.202000882	Isothiourea-Catalyzed Synthesis of Pyrrole- and Indole-Functionalized Tetrasubstituted Pyridines	The cross-coupling reaction between arylboronic acids and various benzylic halides proceeded without using a transition-metal catalyst to give the corresponding diarylmethanes in moderate to good yields. (C) 2016 Elsevier Ltd. All rights reserved.	ChemCatChem	74	Smith, AD	FALSE	FALSE	FALSE	FALSE
2967	10.1021/jacs.0c04905	doi.org/10.1021/jacs.0c04905	Magnesiation of Aryl Fluorides Catalyzed by a Rhodium-Aluminum Complex	Systematic studies of the coupling of benzylic with aryl halides are presented. The optimized reaction conditions for electron-deficient aryl halides cannot be applied to the electron-rich or neutral counterparts, and vice versa. The excellent functional group tolerance and broad substrate scope may enable the current work to be useful for the construction of diaryl methane products.	J. Am. Chem. Soc.	74	Sakaki, S	FALSE	FALSE	FALSE	FALSE
2968	10.1039/d0sc02439b	doi.org/10.1039/d0sc02439b	Silanol: a bifunctional group for peptide synthesis and late-stage functionalization	A new protocol for the direct reductive cobalt-catalyzed arylation of benzyl chlorides has been developed in order to form functionalized diarylmethanes. A variety of reactive groups either on the aryl or the benzyl halide was employed. This represents the first cobalt-catalyzed reductive cross-coupling which does not require any ligand and pyridine. A reaction pathway is proposed involving a radical benzyl species.	Chem. Sci.	74	Xiong, XF	FALSE	FALSE	FALSE	FALSE
2969	10.1021/acs.orglett.9b03730	doi.org/10.1021/acs.orglett.9b03730	Alkaline-Earth Metal Catalyzed Dehydrative Allylic Alkylation		Org. Lett.	74	Xie, PZ; Loh, TP	FALSE	FALSE	FALSE	FALSE
2970	10.1002/ejoc.201901606	doi.org/10.1002/ejoc.201901606	A Borrowing Hydrogen Strategy for Dehydrative Coupling of Aminoisoquinolines with Benzyl Alcohols in Water		Eur. J. Org. Chem.	74	Hikawa, H; Azumaya, I	FALSE	FALSE	FALSE	FALSE
2971	10.1021/acs.jmedchem.9b00864	doi.org/10.1021/acs.jmedchem.9b00864	Structure-Kinetic Profiling of Haloperidol Analogues at the Human Dopamine D-2 Receptor		J. Med. Chem.	74	Mistry, SN	FALSE	FALSE	FALSE	FALSE
2972	10.1021/jacs.9b07022	doi.org/10.1021/jacs.9b07022	Matching Glycosyl Donor Reactivity to Sulfonate Leaving Group Ability Permits S(N)2 Glycosylations		J. Am. Chem. Soc.	74	Bennett, CS	FALSE	FALSE	FALSE	FALSE
2973	10.1039/c9cc05763c	doi.org/10.1039/c9cc05763c	Computational studies on Ni-catalyzed amide C-N bond activation		Chem. Commun.	74	Zhang, SQ; Hong, X	FALSE	FALSE	FALSE	FALSE
2974	10.1021/acs.orglett.9b02727	doi.org/10.1021/acs.orglett.9b02727	Selective Ketone Formations via Cobalt-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols		Org. Lett.	74	Ding, KY	FALSE	FALSE	FALSE	FALSE
2975	10.1021/jacs.9b07253	doi.org/10.1021/jacs.9b07253	Ni-Catalyzed Enantioselective Intermolecular Hydroamination of Branched 1,3-Dienes Using Primary Aliphatic Amines		J. Am. Chem. Soc.	74	Mazet, C	FALSE	FALSE	FALSE	FALSE
2976	10.1002/chem.201900822	doi.org/10.1002/chem.201900822	Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes		Chem.-Eur. J.	74	Sawamura, M	FALSE	FALSE	FALSE	FALSE
2977	10.1002/anie.201903890	doi.org/10.1002/anie.201903890	Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes		Angew. Chem.-Int. Edit.	74	Yin, GY	FALSE	TRUE	FALSE	FALSE
2978	10.1039/c9sc00640k	doi.org/10.1039/c9sc00640k	Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to beta-cyano ketone		Chem. Sci.	74	Peng, YG; Liu, TL	FALSE	FALSE	FALSE	FALSE
2979	10.1021/jacs.9b03978	doi.org/10.1021/jacs.9b03978	Tandem Decarboxylative Cyclization/Alkenylation Strategy for Total Syntheses of (+)-Longirabdiol, (-)-Longirabdolactone, and (-)-Effusin		J. Am. Chem. Soc.	74	Li, C	FALSE	FALSE	FALSE	FALSE
2980	10.1039/c9ob00572b	doi.org/10.1039/c9ob00572b	Synthesis of benzoxazoles via the copper-catalyzed hydroamination of alkynones with 2-aminophenols		Org. Biomol. Chem.	74	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
2981	10.1002/adsc.201801606	doi.org/10.1002/adsc.201801606	Efficient Synthesis of Functionalized Indene Derivatives via Rh (III)-Catalyzed Cascade Reaction between Oxadiazoles and Allylic Alcohols		Adv. Synth. Catal.	74	Dong, AL	FALSE	FALSE	FALSE	FALSE
2982	10.1080/00958972.2019.1590562	doi.org/10.1080/00958972.2019.1590562	MgFe2O4@SiO2-PrNH2/Pd/bimenthonoxime core-shell magnetic nanoparticles as a recyclable green catalyst for heterogeneous Suzuki cross-coupling in aqueous ethanol		J. Coord. Chem.	74	Mehdipour, E	FALSE	FALSE	FALSE	FALSE
2983	10.1002/anie.201814558	doi.org/10.1002/anie.201814558	Metal-Catalyzed Sequential Formation of Distant Bonds in Organic Molecules: Palladium-Catalyzed Hydrosilylation/Cyclization of 1,n-Dienes by Chain Walking		Angew. Chem.-Int. Edit.	74	Kochi, T	FALSE	FALSE	FALSE	FALSE
2984	10.1021/acs.orglett.9b00122	doi.org/10.1021/acs.orglett.9b00122	Copper-Catalyzed C-H Carbamoyloxylation of Aryl Carboxamides with CO2 and Amines at Ambient Conditions		Org. Lett.	74	Zou, Y	FALSE	FALSE	FALSE	FALSE
2985	10.1002/adsc.201801266	doi.org/10.1002/adsc.201801266	Dehydrative Synthesis of Functionalized Skipped Dienes from Stabilized Phosphonium Ylides and Allylic Alcohols in Water		Adv. Synth. Catal.	74	Ma, XT; Tang, L	FALSE	FALSE	FALSE	FALSE
2986	10.1021/acs.orglett.9b00242	doi.org/10.1021/acs.orglett.9b00242	Nickel-Catalyzed Kumada Coupling of Boc-Activated Aromatic Amines via Nondirected Selective Aryl C-N Bond Cleavage		Org. Lett.	74	Xia, JB	FALSE	FALSE	FALSE	FALSE
2987	10.1021/jacs.8b05143	doi.org/10.1021/jacs.8b05143	Cation-pi Interactions in the Benzylic Arylation of Toluenes with Bimetallic Catalysts		J. Am. Chem. Soc.	74	Kozlowski, MC; Walsh, PJ	FALSE	FALSE	FALSE	FALSE
2988	10.1002/adsc.201800596	doi.org/10.1002/adsc.201800596	Exploring Green Solvents Associated to Pd/C as Heterogeneous Catalyst for Direct Arylation of Heteroaromatics with Aryl Bromides		Adv. Synth. Catal.	74	Soule, JF; Doucet, H	FALSE	FALSE	FALSE	FALSE
2989	10.1021/acs.accounts.8b00023	doi.org/10.1021/acs.accounts.8b00023	Decarbonylative Cross-Couplings: Nickel Catalyzed Functional Group Interconversion Strategies for the Construction of Complex Organic Molecules		Accounts Chem. Res.	74	Rueping, M	FALSE	FALSE	FALSE	FALSE
2990	10.1016/j.comptc.2018.03.025	doi.org/10.1016/j.comptc.2018.03.025	Theoretical insights on the C-C bond reductive elimination from Co(III) center		Comput. Theor. Chem.	74	Ahmad, K	FALSE	FALSE	FALSE	FALSE
2991	10.1002/anie.201712145	doi.org/10.1002/anie.201712145	SuFEx Chemistry of Thionyl Tetrafluoride (SOF4) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates		Angew. Chem.-Int. Edit.	74	Sharpless, KB	FALSE	FALSE	FALSE	FALSE
2992	10.1039/c7sc04351a	doi.org/10.1039/c7sc04351a	Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles		Chem. Sci.	74	Giri, R	FALSE	FALSE	FALSE	FALSE
2993	10.1021/acs.orglett.7b03052	doi.org/10.1021/acs.orglett.7b03052	Visible-Light-Driven alpha-Allenylic C-O Bond Cleavage and Alkenyl C-S Formation: Metal-Free and Oxidant-Free Thiolation of Allenyl Phosphine Oxides		Org. Lett.	74	Wu, L; Zhang, WH	FALSE	FALSE	FALSE	FALSE
2994	10.1021/acs.orglett.7b03023	doi.org/10.1021/acs.orglett.7b03023	Direct Allylic Amination of Allylic Alcohol Catalyzed by Palladium Complex Bearing Phosphine Borane Ligand		Org. Lett.	74	Onodera, G; Kimura, M	FALSE	FALSE	FALSE	FALSE
2995	10.1039/c7dt02498c	doi.org/10.1039/c7dt02498c	The selective hydrogenolysis of C-O bonds in lignin model compounds by Pd-Ni bimetallic nanoparticles in ionic liquids		Dalton Trans.	74	Lu, GP	FALSE	FALSE	FALSE	FALSE
2996	10.3390/molecules201219748	doi.org/10.3390/molecules201219748	Iridium-Catalyzed Asymmetric Ring-Opening of Oxabenzonorbornadienes with N-Substituted Piperazine Nucleophiles		Molecules	74	Yang, DQ	FALSE	FALSE	FALSE	FALSE
2997	10.1002/chem.201502534	doi.org/10.1002/chem.201502534	Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole		Chem.-Eur. J.	74	Mulvey, RE	FALSE	FALSE	FALSE	FALSE
2998	10.1002/adsc.201500515	doi.org/10.1002/adsc.201500515	Copper-Catalyzed Aerobic Oxidative C(aryl)-OH Bond Functionalization of Catechols with Amines Affording Benzoxazoles		Adv. Synth. Catal.	74	Chen, XL	FALSE	FALSE	FALSE	FALSE
2999	10.1016/j.tetlet.2015.06.071	doi.org/10.1016/j.tetlet.2015.06.071	One-pot organocatalytic enantioselective Michael addition and aza-cyclization/dehydration cascade reaction strategy: asymmetric synthesis of highly functionalized 1,4-dihydroquinolines		Tetrahedron Lett.	74	Kim, SG	FALSE	FALSE	FALSE	FALSE
3000	10.1021/cs502011x	doi.org/10.1021/cs502011x	2-Aminobiphenyl Palladacycles: The Most Powerful Precatalysts in C-C and C-Heteroatom Cross-Couplings		ACS Catal.	74	Alami, M	FALSE	FALSE	FALSE	FALSE
3001	10.1039/c4cc10084k	doi.org/10.1039/c4cc10084k	Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis		Chem. Commun.	74	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
3002	10.1039/c5gc01170a	doi.org/10.1039/c5gc01170a	Synthesis of 2-phenylnaphthalenes from styrene oxides using a recyclable Bronsted acidic [HNMP]+HSO4- ionic liquid		Green Chem.	74	Wagh, KV	FALSE	FALSE	FALSE	FALSE
3003	10.1016/j.jorganchem.2014.09.016	doi.org/10.1016/j.jorganchem.2014.09.016	Syntheses, characterization, and electrochemistry of compounds containing 1-diphenylphosphino-1 '-(di-tert-butylphosphino) ferrocene (dppdtbpf)		J. Organomet. Chem.	74	Trivedi, M	FALSE	FALSE	FALSE	FALSE
3004	10.1021/ol5024344	doi.org/10.1021/ol5024344	Iron-Catalyzed Coupling of Aryl Sulfannates and Aryl/Vinyl Tosylates with Aryl Grignards		Org. Lett.	74	Cook, SP	FALSE	FALSE	FALSE	FALSE
3005	10.1002/anie.201403288	doi.org/10.1002/anie.201403288	Practical, Modular, and General Synthesis of Benzofurans through Extended Pummerer Annulation/Cross-Coupling Strategy		Angew. Chem.-Int. Edit.	74	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
3006	10.1039/c3ra45547e	doi.org/10.1039/c3ra45547e	Chemoselective one-pot synthesis of beta-keto sulfones from ketones		RSC Adv.	74	Sreedhar, B	FALSE	FALSE	FALSE	FALSE
3007	10.1016/j.tet.2013.10.089	doi.org/10.1016/j.tet.2013.10.089	Palladium-catalyzed domino protodecarboxylation/oxidative Heck reaction: regioselective arylation of coumarin-3-carboxylic acids		Tetrahedron	74	Jafarpour, F	FALSE	FALSE	FALSE	FALSE
3008	10.1016/j.tet.2013.10.043	doi.org/10.1016/j.tet.2013.10.043	Generation of 4-substituted coumarins via C-H bond activation under palladium bromide-copper(I) bromide cooperative catalysis		Tetrahedron	74	Wu, J	FALSE	FALSE	FALSE	FALSE
3009	10.1002/asia.201300688	doi.org/10.1002/asia.201300688	Mechanistic Insight into the Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids: Potassium Phosphate is Not a Spectator Base but is Involved in the Transmetalation Step in the Suzuki-Miyaura Reaction		Chem.-Asian J.	74	Zhu, J	FALSE	FALSE	FALSE	FALSE
3010	10.1016/j.inoche.2013.08.010	doi.org/10.1016/j.inoche.2013.08.010	New dimeric phosphine ylide copper (I) complexes: Synthesis, coordination behavior, and application in Suzuki cross-coupling reactions		Inorg. Chem. Commun.	74	Sabounchei, SJ	FALSE	FALSE	FALSE	FALSE
3011	10.1021/ja402922w	doi.org/10.1021/ja402922w	Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic alpha,alpha-Disubstituted Ketones		J. Am. Chem. Soc.	74	Reisman, SE	FALSE	FALSE	FALSE	FALSE
3012	10.1016/j.jorganchem.2013.01.014	doi.org/10.1016/j.jorganchem.2013.01.014	Nickel-catalyzed hydrodehalogenation of aryl halides		J. Organomet. Chem.	74	Enthaler, S	FALSE	FALSE	FALSE	FALSE
3013	10.1016/j.tetlet.2012.12.091	doi.org/10.1016/j.tetlet.2012.12.091	Facile synthesis of diverse isoindolinone derivatives via Ugi-4CR followed by Cu-catalyzed deamidative C(sp(2))-C(sp(3)) coupling		Tetrahedron Lett.	74	Chauhan, PMS	FALSE	FALSE	FALSE	FALSE
3014	10.1021/ol303222s	doi.org/10.1021/ol303222s	Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines		Org. Lett.	74	Hirano, K	FALSE	TRUE	FALSE	FALSE
3015	10.1002/chem.201200190	doi.org/10.1002/chem.201200190	Nickel-Mediated Inter- and Intramolecular Reductive Cross-Coupling of Unactivated Alkyl Bromides and Aryl Iodides at Room Temperature		Chem.-Eur. J.	74	Peng, Y	FALSE	FALSE	FALSE	FALSE
3016	10.1002/chem.201103784	doi.org/10.1002/chem.201103784	Aryl Ether as a Negishi Coupling Partner: An Approach for Constructing C-C Bonds under Mild Conditions		Chem.-Eur. J.	74	Wang, C	FALSE	FALSE	FALSE	FALSE
3017	10.1002/ejoc.201101506	doi.org/10.1002/ejoc.201101506	Palladium-Catalyzed Selective Synthesis of Naphthalenes and Indenones and Their Luminescent Properties		Eur. J. Org. Chem.	74	Lu, P	FALSE	FALSE	FALSE	FALSE
3018	10.1002/anie.201205969	doi.org/10.1002/anie.201205969	Nickel-Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones		Angew. Chem.-Int. Edit.	74	Li, JH	FALSE	FALSE	FALSE	FALSE
3019	10.1039/c2ob26270c	doi.org/10.1039/c2ob26270c	Palladium-catalyzed desulfitative arylation of azoles with arylsulfonyl hydrazides		Org. Biomol. Chem.	74	Li, XW	FALSE	FALSE	FALSE	FALSE
3020	10.1002/anie.201007187	doi.org/10.1002/anie.201007187	Highly Diastereoselective Iron-Mediated C(sp(2))-C(sp(3)) Cross-Coupling Reactions between Aryl Grignard Reagents and Cyclic Iodohydrine Derivatives		Angew. Chem.-Int. Edit.	74	Knochel, P	FALSE	FALSE	FALSE	FALSE
3021	10.1021/jo101718v	doi.org/10.1021/jo101718v	Zero-Valent Metals Accelerate the Neopentylglycolborylation of Aryl Halides Catalyzed by NiCl2-Based Mixed-Ligand Systems		J. Org. Chem.	74	Percec, V	FALSE	FALSE	FALSE	FALSE
3022	10.1021/ol1002576	doi.org/10.1021/ol1002576	Palladium-Catalyzed Direct Benzylation of Azoles with Benzyl Carbonates		Org. Lett.	74	Miura, M	FALSE	FALSE	FALSE	FALSE
3023	10.1021/ja808652a	doi.org/10.1021/ja808652a	Modular Synthesis of Indoles from Imines and o-Dihaloarenes or o-Chlorosulfonates by a Pd-Catalyzed Cascade Process		J. Am. Chem. Soc.	74	Barluenga, J	FALSE	FALSE	FALSE	FALSE
3024	10.1021/jo0521201	doi.org/10.1021/jo0521201	Suzuki-Miyaura, alpha-ketone arylation and dehalogenation reactions catalyzed by a versatile N-heterocyclic carbene-palladacycle complex		J. Org. Chem.	74	Nolan, SP	FALSE	FALSE	FALSE	FALSE
3025	10.1055/s-2005-918479	doi.org/10.1055/s-2005-918479	Catalysts on functionalized polymer chips (PC) as recyclable entities		Synthesis	74	Bannwarth, W	FALSE	FALSE	FALSE	FALSE
3026	10.1007/s10563-005-9161-4	doi.org/10.1007/s10563-005-9161-4	Heterogeneous asymmetric aquacatalysis with polymer-supported palladium complexes		Catal. Surv. Asia	74	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
3027	10.1021/jo9916986	doi.org/10.1021/jo9916986	Scope and limitations of the Pd/BINAP-catalyzed amination of aryl bromides		J. Org. Chem.	74	Wolfe, JP	FALSE	FALSE	FALSE	FALSE
3028	10.1021/ja980787h	doi.org/10.1021/ja980787h	Catalytic asymmetric synthesis of quaternary carbon centers. Exploratory studies of intramolecular Heck reactions of (Z)-alpha,beta-unsaturated anilides and mechanistic investigations of asymmetric Heck reactions proceeding via neutral intermediates		J. Am. Chem. Soc.	74	Overman, LE	FALSE	FALSE	FALSE	FALSE
3029	10.1021/jo00028a051	doi.org/10.1021/jo00028a051	PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF HIGHLY HINDERED, ELECTRON-RICH PHENOL TRIFLATES AND ORGANOSTANNANES		J. Org. Chem.	74	SAA, JM	FALSE	FALSE	FALSE	FALSE
3030	10.1016/0022-328X(87)80053-0	doi.org/10.1016/0022-328X(87)80053-0	MOLECULAR-BASIS OF CATALYTIC REACTIONS INVOLVING ETA-3-ALLYL COMPLEXES OF GROUP-10 METALS AS KEY INTERMEDIATES		J. Organomet. Chem.	74	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
3031	10.1021/ja00293a038	doi.org/10.1021/ja00293a038	ASYMMETRIC-SYNTHESIS - ASYMMETRIC CATALYTIC ALLYLATION USING PALLADIUM CHIRAL PHOSPHINE COMPLEXES		J. Am. Chem. Soc.	74		FALSE	FALSE	FALSE	FALSE
3032	10.1002/ejoc.202101384	doi.org/10.1002/ejoc.202101384	Low-Cost Transition Metal-Catalyzed Heck-Type Reactions: An Overview		Eur. J. Org. Chem.	74	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
3033	10.1039/d1ob02051j	doi.org/10.1039/d1ob02051j	Buchwald-Hartwig amination of aryl esters and chlorides catalyzed by the dianisole-decorated Pd-NHC complex		Org. Biomol. Chem.	74	Yao, HG; Xu, C	FALSE	FALSE	FALSE	FALSE
3034	10.1021/acscatal.1c05530	doi.org/10.1021/acscatal.1c05530	Ti-Catalyzed Reductive Dehydroxylative Vinylation of Tertiary Alcohols		ACS Catal.	74	Shu, XZ	FALSE	FALSE	FALSE	FALSE
3035	10.1021/acscatal.1c04800	doi.org/10.1021/acscatal.1c04800	Nickel-Catalyzed Kumada Vinylation of Enol Phosphates: A Comparative Mechanistic Study		ACS Catal.	74	Mazet, C	FALSE	FALSE	FALSE	FALSE
3036	10.1002/ejoc.202100937	doi.org/10.1002/ejoc.202100937	Synthesis of 2-(Chlorodifluoromethyl)indoles for Nucleophilic Halogen Exchange with [F-18]Fluoride		Eur. J. Org. Chem.	74	Heinrich, MR	FALSE	FALSE	FALSE	FALSE
3037	10.1007/s12039-021-01950-1	doi.org/10.1007/s12039-021-01950-1	Highly efficient aqueous-phase Sonogashira coupling catalyzed by Pd-PEEPSI/PPh3 under aerobic condition		J. Chem. Sci.	74	Das, P	FALSE	FALSE	FALSE	FALSE
3038	10.1055/s-0041-1737275	doi.org/10.1055/s-0041-1737275	Synthesis of Indole/Benzofuran-Containing Diarylmethanes through Palladium-Catalyzed Reaction of Indolylmethyl or Benzofuranylmethyl Acetates with Boronic Acids		Synthesis	74	Goggiamani, A	FALSE	FALSE	FALSE	FALSE
3039	10.1039/d1qo01460a	doi.org/10.1039/d1qo01460a	Electrochemical synthesis of functionalized gem-difluoroalkenes with diverse alkyl sources via a defluorinative alkylation process		Org. Chem. Front.	74	Guo, L; Xia, WJ	FALSE	TRUE	FALSE	FALSE
3040	10.1021/acs.joc.1c01790	doi.org/10.1021/acs.joc.1c01790	Titanium(IV)-Mediated Ring-Opening/Dehydroxylative Cross-Coupling of Diaryl-Substituted Methanols with Cyclopropanol Derivatives		J. Org. Chem.	74	Shen, ZL	FALSE	FALSE	FALSE	FALSE
3041	10.1002/aoc.3671	doi.org/10.1002/aoc.3671	Ionic iron(III) complexes bearing a dialkylbenzimidazolium cation: Efficient catalysts for magnesium-mediated cross-couplings of aryl phosphates with alkyl bromides		Appl. Organomet. Chem.	74	Sun, HM	FALSE	FALSE	FALSE	FALSE
3042	10.1021/acsomega.7b00725	doi.org/10.1021/acsomega.7b00725	Palladacycle-Catalyzed Triple Suzuki Coupling Strategy for the Synthesis of Anthracene-Based OLED Emitters		ACS Omega	74	Kapdi, AR	FALSE	FALSE	FALSE	FALSE
3043	10.1021/acs.orglett.7b00831	doi.org/10.1021/acs.orglett.7b00831	Ni-Catalyzed Reductive Cross-Coupling of Amides with Aryl Iodide Electrophiles via C-N Bond Activation		Org. Lett.	74	Han, JL	FALSE	TRUE	FALSE	FALSE
3044	10.1021/acscatal.6b03344	doi.org/10.1021/acscatal.6b03344	When Weaker Can Be Tougher: The Role of Oxidation State (I) in P-vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides		ACS Catal.	74	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
3045	10.1039/c6sc04371b	doi.org/10.1039/c6sc04371b	A palladium-catalyzed synthesis of (hetero)aryl-substituted imidazoles from aryl halides, imines and carbon monoxide		Chem. Sci.	74	Arndtsen, BA	FALSE	FALSE	FALSE	FALSE
3046	10.1039/c6dt03944h	doi.org/10.1039/c6dt03944h	Unsymmetrical NCN-pincer mononuclear and dinuclear nickel(II) complexes of N-heterocyclic carbene (NHC): synthesis, structure and catalysis for Suzuki-Miyaura cross-coupling		Dalton Trans.	74	Gu, SJ	FALSE	FALSE	FALSE	FALSE
3047	10.1002/adsc.201600950	doi.org/10.1002/adsc.201600950	Synthesis of Trisubstituted Pyridines via Chemoselective Suzuki-Miyaura Coupling of 3,5-and 4,6-Dibromo-2-tosyloxypyridines		Adv. Synth. Catal.	74	Kim, WS	FALSE	FALSE	FALSE	FALSE
3048	10.1039/c6qo00479b	doi.org/10.1039/c6qo00479b	Cobalt(III)-catalyzed cross-coupling of enamides with allyl acetates/maleimides		Org. Chem. Front.	74	Zhang, YH	FALSE	FALSE	FALSE	FALSE
3049	10.1021/acs.orglett.6b02862	doi.org/10.1021/acs.orglett.6b02862	Ruthenium-Catalyzed C-H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides		Org. Lett.	74	Weix, DJ	FALSE	FALSE	FALSE	FALSE
3050	10.1021/jacs.6b08507	doi.org/10.1021/jacs.6b08507	Branch-Selective Hydroarylation: Iodoarene-Olefin Cross-Coupling		J. Am. Chem. Soc.	74	Shenvi, RA	FALSE	FALSE	FALSE	FALSE
3051	10.1021/acs.orglett.6b02058	doi.org/10.1021/acs.orglett.6b02058	Transition-Metal-Free Cross-Coupling of Indium Organometallics with Chromene and Isochroman Acetals Mediated by BF3 center dot OEt2		Org. Lett.	74	Sestelo, JP; Sarandeses, LA	FALSE	FALSE	FALSE	FALSE
3052	10.1002/ejoc.201600500	doi.org/10.1002/ejoc.201600500	Nickel(0)-Catalyzed N-Allylation of Amides and p-Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions		Eur. J. Org. Chem.	74	Sauthier, M	FALSE	FALSE	FALSE	FALSE
3053	10.1002/chem.201504959	doi.org/10.1002/chem.201504959	Exploring Regioselective Bond Cleavage and Cross-Coupling Reactions using a Low-Valent Nickel Complex		Chem.-Eur. J.	74	Love, JA	FALSE	FALSE	FALSE	FALSE
3054	10.1002/ejoc.201501551	doi.org/10.1002/ejoc.201501551	Rh-III-Catalyzed C-H Allylation of Amides and Domino Cycling Synthesis of 3,4-Dihydroisoquinolin-1(2H)-ones with N-Bromosuccinimide		Eur. J. Org. Chem.	74	Yan, H	FALSE	FALSE	FALSE	FALSE
3055	10.1039/c6ob02010k	doi.org/10.1039/c6ob02010k	Bifunctional Ru(II) complex catalysed carbon-carbon bond formation: an eco-friendly hydrogen borrowing strategy		Org. Biomol. Chem.	74	Kundu, S	FALSE	FALSE	FALSE	FALSE
3056	10.1039/c5ob02167g	doi.org/10.1039/c5ob02167g	Copper-catalyzed electrophilic amination using N-methoxyamines		Org. Biomol. Chem.	74	Sato, T	FALSE	FALSE	FALSE	FALSE
3057	10.1016/j.tet.2021.131931	doi.org/10.1016/j.tet.2021.131931	Dehydrohalogenation of halobenzenes and C(sp(3))-X (X = F, OPh) bond activation by a molecular calcium hydride	Pyridone 1, a key intermediate in the preparation of ERK inhibitor GDC-0994, was synthesized via a cross-coupling/hydrolysis sequence from commercially available starting materials. C-C bond formation was achieved via an efficient palladium catalyzed Kumada Corriu cross-coupling reaction. However, the 4-pyridylmagnesium halide reagent generated in situ was found to be unstable at the reaction temperature, leading to inconsistent results on scale. In order to address process robustness issues associated with the cross-coupling reaction, we investigated both flow chemistry and a low temperature Kumada Corriu coupling reaction. Finally, a basic hydrolysis process of 2-fluoropyridine was developed to avoid formation of toxic and corrosive hydrofluoric acid, resulting in a safe and scalable process toward 1.	Tetrahedron	73	Hill, MS	FALSE	FALSE	FALSE	FALSE
3058	10.1021/acs.joc.0c02992	doi.org/10.1021/acs.joc.0c02992	Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bond Formation via C-N Cleavage of Benzyl Ammonium Salts	Palladium-catalyzed reductive homocoupling of aryl sulfonates has been successfully achieved under mild conditions. This transformation is a new method for the homocoupling reaction of aryl sulfonates at room temperature via the cleavage of CO bonds, thus providing an alternative synthesis of symmetric biaryls. The reported reductive homocoupling reaction is tolerant of many common functional groups regardless of electron-donating or electron-withdrawing nature, making this newly developed transformation important for complementing Ullmann coupling. Experimental Section. Typical procedure for the products.	J. Org. Chem.	73	Chen, TQ	FALSE	FALSE	FALSE	FALSE
3059	10.1016/j.mcat.2021.111415	doi.org/10.1016/j.mcat.2021.111415	Cooperative catalysis of molybdenum with organocatalysts for distribution of products between amines and imines	Water extract of agro-waste ash (AWEs) has emerged as an efficient non-conventional solvent for practicing green reactions in catalysis and organic chemistry. The recent advancements made in the field of agro-waste-derived reaction media have witnessed a major advancement in reactions like SuzukiMiyaura, Sonogashira, Dakin, Henry, peptide synthesis and ipsohydroxylation. Traditionally, these reactions were conducted in conventional volatile organic solvents (VOCs) derived from non-renewable petroleum sources. During the course of these reactions AWEs displays distinct properties, such as, in situ base, homogeneous catalyst, nano reactor and reducing agent. This review summarizes the recent developments made in the application of AWEs in important reactions emphasizing on the key utilities and limitations in order to facilitate the further progress of this exciting area of research.	Mol. Catal.	73	Liu, N	FALSE	FALSE	FALSE	FALSE
3060	10.1021/acs.orglett.0c03819	doi.org/10.1021/acs.orglett.0c03819	Silver(I)-Catalyzed Enyne Cyclization/Aromatization of Alkyne-Tethered Cyclohexadienones to Access Meta-Substituted Phenols	Using an iridium catalyst modified by PhanePhos, CF3-allenes react with methanol to form branched products of hydrohydroxymethylation as single regioisomers with excellent levels of enantiomeric enrichment. This hydrogen autotransfer process enables catalytic enantioselective formation of acyclic CF3-bearing all carbon quaternary stereocenters in the absence of stoichiometric metals or byproducts.	Org. Lett.	73	Chegondi, R	FALSE	FALSE	FALSE	FALSE
3061	10.1055/a-1353-7605	doi.org/10.1055/a-1353-7605	Asymmetric Synthesis of alpha-Alkylated gamma-Lactam via Nickel/8-Quinim-Catalyzed Reductive Alkyl-Carbamoylation of Unactivated Alkene	Reductive cross-coupling of aryl halides with ubiquitous alkyl tosylates was developed using a combination of nickel and vitamin B-12 (VB12: cyanocobalamin) catalysts. The tosylate was activated by reduced VB12 to form alkyl cobalt(III), which served as a good alkylating agent for aryl-nickel species, leading to C(sp(3))- C(sp(2)) bond formation.	Synlett	73	Chen, YF	FALSE	FALSE	FALSE	FALSE
3062	10.1021/jacs.0c10055	doi.org/10.1021/jacs.0c10055	Diastereo- and Enantioselective Construction of Spirocycles by Nickel-Catalyzed Cascade Borrowing Hydrogen Cyclization	The first catalytic asymmetric construction of the tryptanthrin skeleton has been established, taking advantage of a palladium(0)/chiral ligand-catalyzed enantioselective decarboxylative [4 + 2] cyclization of vinyl benzoxazinanones with isatins. This reaction has not only provided a direct and efficient method for constructing chiral tryptanthrin skeleta in high yields and excellent enantioselectivities (up to 97% yield, >99% ee) but also represents the first catalytic asymmetric decarboxylative cyclization of vinyl benzoxazinanones with isatins.	J. Am. Chem. Soc.	73	Kong, WQ	FALSE	FALSE	FALSE	FALSE
3063	10.1016/j.tetlet.2020.152624	doi.org/10.1016/j.tetlet.2020.152624	Rapid synthesis of acyl fluorides from carboxylic acids with Cu(O2CCF2SO2F)(2)	Aromatic skeletons are generally regarded as being uncleavable because of their aromatic stabilization energy. Compared to exocyclic functionalizations of aromatic compounds, much less attention has been paid to substitutions of endocyclic atoms in aromatic cores through partial disassembly of the cyclic skeletons and subsequent ring reconstruction. In this Feature Article, we describe our endeavours to establish aromatic metamorphosis'', where general aromatic compounds such as dibenzothiophenes, dibenzofurans, and benzofurans are transformed into different ring systems using a multi-step strategy or ideally in one step.	Tetrahedron Lett.	73	Hu, XJ; Liu, C	FALSE	FALSE	FALSE	FALSE
3064	10.1021/acs.joc.0c02145	doi.org/10.1021/acs.joc.0c02145	Direct Synthesis of Pyrrolo[1,2-alpha]quinoxalines via Iron-Catalyzed Transfer Hydrogenation between 1-(2-Nitrophenyl)pyrroles and Alcohols	An enantioselective Cu/Pd-catalyzed borylative coupling of styrenes with aryl/alkenyl iodides was realized using a chiral sulfoxide-phosphine (SOP) ligand. Enantioenriched 1,1-diarylethyl and beta-arylhomoallylic boronates are readily prepared. A streamlined procedure merging arylboration and subsequent Pd-catalyzed Suzuki-Miyaura cross-coupling enables the modular assembly of enantioenriched 1,1,2-triarylethanes, including two medicinally important chiral small-molecule targets.	J. Org. Chem.	73	Hong, SC	FALSE	FALSE	FALSE	FALSE
3065	10.1039/d0ob01838d	doi.org/10.1039/d0ob01838d	Copper- and DMF-mediated switchable oxidative C-H cyanation and formylation of imidazo[1,2-a]pyridines using ammonium iodide	Alkyl Grignard reagents (Et, Bu-n, Pr-i, cyclohexyl), with the exception of (BuMgCl)-Bu-t, undergo exclusive or exceptionally highly regioselective 1,4-addition reactions to alpha,beta-gamma,delta-unsaturated ketones, while aryl and heteroaryl Grignard reagents give mixed results ranging from exclusive 1,4-addition (1-naphthyl, 2-N-methylpyrrolyl) to regioselective 1,2-addition (2-furyl, 2:1). All alkyl, aryl, and heteroaryl Grignard reagents examined gave exclusive 1,4-addition reactions with alpha,beta-gamma,delta-unsaturated thiol esters, with the exception of (BuMgCl)-Bu-t, which gave an 80:20 mixture of 1,4:1,6-addition products. The high chemo- and regioselectivity observed for these reactions is attributed to a radical or radical-like pathway for the alkyl Grignard reagents and possibly a carbanion pathway for aryl Grignard reagents. The alpha,gamma-dienyl thiol esters provide for a one-pot tandem 1,4-addition-nucleophilic acyl substitution reaction sequence to afford 3-substituted 4-enone moieties.	Org. Biomol. Chem.	73	Jiang, GB; Ji, FH	FALSE	FALSE	FALSE	FALSE
3066	10.1021/acsomega.0c04192	doi.org/10.1021/acsomega.0c04192	Cyclometalated Iridium Complex-Catalyzed N-Alkylation of Amines with Alcohols via Borrowing Hydrogen in Aqueous Media	Heck coupling reaction catalysed directly by ligand-free nickel nanoparticles (NPs) has been reported in heterogeneous processes. The nickel NPs with similar to 25 nm in size showed good results in the arylation of olefins with iodoarenes in the presence of K2CO3 and n-Bu4NCl in DMF solvent at high temperature (130 degrees C). Bromobenzene showed low conversion (<14%) during the Heck reaction. Electron-donating group-substituted iodoarenes exhibited better performance in the Heck reaction compared with the non-reactive electron-withdrawing group-substituted iodoarenes. Supported nickel NPs on metal oxide and activated carbon exhibited simple work-up and good reusability at least five runs without dramatically decreasing their catalytic reactivity.	ACS Omega	73	Luo, RS	FALSE	FALSE	FALSE	FALSE
3067	10.1039/d0ra07472a	doi.org/10.1039/d0ra07472a	Formation of trisubstituted buta-1,3-dienes and alpha,beta-unsaturated ketones via the reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents	A transition metal-free, direct one-pot domino allylation reaction of 2-pyridinyl Grignard reagents with polysubstituted allyl chlorides for the regioselective synthesis of pyridinyl-substituted 1,5-diene derivatives has been disclosed. The reaction presumably proceeded through the coupling of polysubstituted allyl chloride to 2-PyMgX, which was in situ generated from 2-bromopyridine with i-PrMgClLiCl.	RSC Adv.	73	Tobrman, T	FALSE	FALSE	FALSE	FALSE
3068	10.1002/anie.202008866	doi.org/10.1002/anie.202008866	Efficient Pd-Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents	The mechanism of the iridium-catalyzed functionalization of a primary C-H bond at the gamma position of an alcohol5 is investigated by density functional theory (DFT) calculations. A new Ir-III-Ir-V mechanism is found to be more feasible than the previously reported Ir-I-Ir-III mechanism. 10 In the Ir-III-Ir-V mechanism, the reaction begins with the initial formation of (Me(4)phen) Ir-III(H)[Si(OR) Et-2](2) from the catalyst precursor, [Ir(cod) OMe](2) (cod = 1,5-cyclooctadiene). The catalytic cycle includes five steps: (1) the insertion of norbornene into the Ir-H bond to produce (Me(4)phen) IrIII(norbornyl)[Si(OR) Et-2](2) (R = -CH(C2H5) C3H7); (2) the Si-H oxidative addition of HSi(OR) Et-2 to form (Me(4)phen) IrVH(norbornyl)[Si(OR) Et-2](3); (3) the reductive elimination of norbornane to furnish (Me(4)phen) IrIII[Si(OR) Et-2](3); (4) the intramolecular C-H activation of the primary C-H bond at the gamma position; and (5) the Si-C reductive elimination to produce the final product and regenerate the catalyst. The highest barrier in the IrIII-IrV mechanism is 7.3 kcal/mol lower than that of the Ir-I-Ir-III mechanism. In addition, the regioselectivity of the C-H activation predicted by this new Ir-III-Ir-V mechanism is consistent with experimental observation.	Angew. Chem.-Int. Edit.	73	Gessner, VH	FALSE	FALSE	FALSE	FALSE
3069	10.1039/d0sc01813a	doi.org/10.1039/d0sc01813a	Concerted aryl-sulfur reductive elimination from PNP pincer-supported Co(iii) and subsequent Co(i)/Co(iii) comproportionation	A cobalt-catalyzed regioselective C-3 alkylation of coumarins was realized under mild reaction conditions, during which a variety of substituted coumarins including those containing sensitive functional groups could smoothly undergo the selective C(sp(2))-C(sp(3)) bond formation with a series of cyclic or straight-chain alkyl ethers.	Chem. Sci.	73	Ozerov, OV	FALSE	FALSE	FALSE	FALSE
3070	10.1002/aoc.5716	doi.org/10.1002/aoc.5716	Direct synthesis of completely unsymmetrical triarylmethanes via Fe(III) salt-mediated in situ o-quinone methides process	The present study reports the development of a palladium-catalyzed oxidative annulation/nucleophilic substitution sequence affording a library of alkenylated benzopyrans using 2-aryl-1,3-dicarbonyl compounds and allylic acetate. The process is compatible to a wide range of substrates with good functional group tolerance producing the desired heterocycles in moderate to good yields. (C) 2016 Elsevier Ltd. All rights reserved.	Appl. Organomet. Chem.	73	Xu, DZ	FALSE	FALSE	FALSE	FALSE
3071	10.1016/j.tetlet.2020.151758	doi.org/10.1016/j.tetlet.2020.151758	Bi(OTf)(3)-catalysed regioselective arylation of Morita-Baylis-Hillman type allylic electrophiles	Selective Pd-catalyzed C(sp(2))-H oxygenation of 4-substituted 1,2,3-triazoles is described. Unlike previous metal catalyzed C-H functionalization events, which preferentially occur at the activated heterocyclic C-H bond, the regioselective oxygenation of the arene/alkene moiety is now achieved featuring the unconventional role of a simple triazole scaffold as a modular and selective directing group.	Tetrahedron Lett.	73	Poulain-Martini, S	FALSE	FALSE	FALSE	FALSE
3072	10.1021/acs.joc.9b03346	doi.org/10.1021/acs.joc.9b03346	Catalytic Oxidative Cleavage Reactions of Arylalkenes by tert-Butyl Hydroperoxide - A Mechanistic Assessment	In the coming decades major changes are expected in the chemical industry regarding the utilized raw material inputs. Depleting fossil resources will gradually be replaced by renewable feedstocks wherever possible. Because of this transition, new and efficient methodologies are required that enable depolymerization and defunctionalization of these complex, highly oxygenated biopolymers. Additionally, utilization of all components of lignocellulose is of great importance. In particular, depolymerization of lignin into its aromatic subunits or defined aromatic platform chemicals has proven challenging. Various approaches to overcome these difficulties have been attempted and resulted in new and exciting developments in many fields. In this review we will give an overview of bond cleavage strategies relevant for lignin depolymerization using homogeneous catalysts, focusing especially on reductive and hydrogen transfer methods. (C) 2015 Published by Elsevier B.V.	J. Org. Chem.	73	Doyle, MP	FALSE	FALSE	FALSE	FALSE
3073	10.1021/acs.orglett.0c00561	doi.org/10.1021/acs.orglett.0c00561	Iron-Catalyzed Reductive Vinylation of Tertiary Alkyl Oxalates with Activated Vinyl Halides	While nickel catalysts have previously been shown to activate even the least reactive Csp(2)-O bonds, i.e. aryl ethers, in the context of C-C bond formation, little is known about the reactivity limits and molecular requirements for the introduction of valuable functional groups under homogeneous nickel catalysis. We identified that due to the high reactivity of Ni-catalysts, they are also prone to react with existing or installed functional groups, which ultimately causes catalyst deactivation. The scope of the Ni-catalyzed coupling protocol will therefore be dictated by the reactivity of the functional groups towards the catalyst. Herein, we showed that the application of computational tools allowed the identification of matching functional groups in terms of suitable leaving groups and tolerated functional groups. This allowed for the development of the first efficient protocol to trifluoromethylthiolate Csp(2)-O bonds, giving the mild and operationally simple C-SCF3 coupling of a range of aryl, vinyl triflates and nonaflates. The novel methodology was also applied to biologically active and pharmaceutical relevant targets, showcasing its robustness and wide applicability.	Org. Lett.	73	Gong, HG	FALSE	FALSE	FALSE	FALSE
3074	10.1021/acs.joc.9b02554	doi.org/10.1021/acs.joc.9b02554	Palladium-Catalyzed Hiyama Coupling of Benzylic Ammonium Salts via C-N Bond Cleavage		J. Org. Chem.	73	Zhao, JF	FALSE	FALSE	FALSE	FALSE
3075	10.1002/anie.201911465	doi.org/10.1002/anie.201911465	Site-Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO2F) Enabled by an Air-Stable Pd-I Dimer		Angew. Chem.-Int. Edit.	73	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
3076	10.1002/aoc.5323	doi.org/10.1002/aoc.5323	Well-defined N-heterocyclic carbene/ruthenium complexes for the alcohol amidation with amines: The dual role of cesium carbonate and improved activities applying an added ligand		Appl. Organomet. Chem.	73	Chen, C; Verpoort, F	FALSE	FALSE	FALSE	FALSE
3077	10.1021/acs.orglett.9b02728	doi.org/10.1021/acs.orglett.9b02728	Sulfinate-Engaged Nucleophilic Addition Induced Allylic Alkylation of Allenoates		Org. Lett.	73	Feng, C	FALSE	FALSE	FALSE	FALSE
3078	10.1002/anie.201909852	doi.org/10.1002/anie.201909852	Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers		Angew. Chem.-Int. Edit.	73	Oestreich, M	FALSE	FALSE	FALSE	FALSE
3079	10.1021/acs.orglett.9b02392	doi.org/10.1021/acs.orglett.9b02392	Intramolecular Remote C-H Activation via Sequential 1,4-Palladium Migration To Access Fused Polycycles		Org. Lett.	73	Yao, HQ; Lin, AJ	FALSE	FALSE	FALSE	FALSE
3080	10.1002/ejoc.201900850	doi.org/10.1002/ejoc.201900850	Balancing Bulkiness in Gold(I) Phosphino-triazole Catalysis		Eur. J. Org. Chem.	73	Fossey, JS	FALSE	FALSE	FALSE	FALSE
3081	10.1021/acs.joc.9b00446	doi.org/10.1021/acs.joc.9b00446	Palladium-Catalyzed Direct alpha-C(sp3) Heteroarylation of Ketones under Microwave Irradiation		J. Org. Chem.	73	Ma, LL	FALSE	FALSE	FALSE	FALSE
3082	10.1002/anie.201810885	doi.org/10.1002/anie.201810885	Catalytic C-1 Alkylation with Methanol and Isotope-Labeled Methanol		Angew. Chem.-Int. Edit.	73	El-Sepelgy, O; Rueping, M	FALSE	FALSE	FALSE	FALSE
3083	10.1021/jacs.8b10766	doi.org/10.1021/jacs.8b10766	Enantioselective Allylic Alkylation with 4-Alkyl-1,4-dihydropyridines Enabled by Photoredox/Palladium Cocatalysis		J. Am. Chem. Soc.	73	Yu, SY	TRUE	FALSE	FALSE	FALSE
3084	10.1039/c8cc07781a	doi.org/10.1039/c8cc07781a	Difunctionalization of ketones via gem-bis(boronates) to synthesize quaternary carbon with high selectivity		Chem. Commun.	73	Zhao, XM; Xu, T	FALSE	FALSE	FALSE	FALSE
3085	10.1002/chem.201804402	doi.org/10.1002/chem.201804402	Zinc Oxide-Catalyzed Dehydrogenation of Primary Alcohols into Carboxylic Acids		Chem.-Eur. J.	73	Madsen, R	FALSE	FALSE	FALSE	FALSE
3086	10.1039/c8qo00729b	doi.org/10.1039/c8qo00729b	Nickel catalyzed regio- and stereoselective arylation and methylation of allenamides via coupling reactions. An experimental and computational study		Org. Chem. Front.	73	Bandini, M	FALSE	FALSE	FALSE	FALSE
3087	10.1021/acs.orglett.8b02824	doi.org/10.1021/acs.orglett.8b02824	Enol Ester Synthesis via Cobalt-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Alkynes		Org. Lett.	73	Li, CK	FALSE	FALSE	FALSE	FALSE
3088	10.1021/acs.joc.8b02104	doi.org/10.1021/acs.joc.8b02104	Chromium-Catalyzed Regioselective Kumada Arylative Cross-Coupling of C(aryl)-O Bonds with a Traceless Activation Strategy		J. Org. Chem.	73	Luo, MM; Zeng, XM	FALSE	FALSE	FALSE	FALSE
3089	10.1002/anie.201804955	doi.org/10.1002/anie.201804955	Catalytic Alkyne Arylation Using Traceless Directing Groups		Angew. Chem.-Int. Edit.	73	Park, JW; Dong, VM	FALSE	FALSE	FALSE	FALSE
3090	10.1002/cjoc.201800237	doi.org/10.1002/cjoc.201800237	Nickel-Catalyzed Direct Coupling of Allylic Alcohols with Organoboron Reagents		Chin. J. Chem.	73	Liu, YH	FALSE	FALSE	FALSE	FALSE
3091	10.1039/c8qo00510a	doi.org/10.1039/c8qo00510a	Transition-metal-free photoredox intermolecular -arylation of ketones		Org. Chem. Front.	73	Pandey, G	FALSE	FALSE	FALSE	FALSE
3092	10.1002/adsc.201800616	doi.org/10.1002/adsc.201800616	Copper-Catalysed (Diacetoxyiodo)benzene-Promoted Aerobic Esterification Reaction: Synthesis of Oxamates from Acetoacetamides		Adv. Synth. Catal.	73	Zhang, ZG; Zhang, GS	FALSE	FALSE	FALSE	FALSE
3093	10.1021/acs.orglett.8b00169	doi.org/10.1021/acs.orglett.8b00169	Stereospecific Decarboxylative Benzylation of Enolates: Development and Mechanistic Insight		Org. Lett.	73	Tunge, JA	FALSE	FALSE	FALSE	FALSE
3094	10.1021/acscatal.8b00546	doi.org/10.1021/acscatal.8b00546	Nickel(I) Aryl Species: Synthesis, Properties, and Catalytic Activity		ACS Catal.	73	Hazari, N	FALSE	FALSE	FALSE	FALSE
3095	10.1002/adsc.201701217	doi.org/10.1002/adsc.201701217	Organocatalytic Enantioselective Functionalization of Hydroxyquinolines through an Aza-Friedel-Crafts Alkylation with Isatin-derived Ketimines		Adv. Synth. Catal.	73	Vila, C; Pedro, JR	FALSE	FALSE	FALSE	FALSE
3096	10.1021/jacs.7b12212	doi.org/10.1021/jacs.7b12212	Ni-Catalyzed Carbon-Carbon Bond-Forming Reductive Amination		J. Am. Chem. Soc.	73	Doyle, AG	FALSE	FALSE	FALSE	FALSE
3097	10.1039/c8ra07834c	doi.org/10.1039/c8ra07834c	Thioether-functionalized trifluoromethyl-alkynes, 1,3-dienes and allenes: divergent synthesis from reaction of 2-trifluoromethyl-1,3-conjugated enynes with sulfur nucleophiles		RSC Adv.	73	Xiao, YJ	FALSE	FALSE	FALSE	FALSE
3098	10.1002/ajoc.201700515	doi.org/10.1002/ajoc.201700515	Rhodium-Catalyzed Alkenyl C-H Activation and Oxidative Coupling with Allylic Alcohols		Asian J. Org. Chem.	73	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3099	10.1002/adsc.201700838	doi.org/10.1002/adsc.201700838	Palladium-Catalyzed One-Pot Synthesis of via 1H-indole-3-sulfonates Generated in Situ from 2-Alkynyl Arylazides and Sulfonic Acids		Adv. Synth. Catal.	73	Zhang, XX; Rao, WD	FALSE	FALSE	FALSE	FALSE
3100	10.1002/anie.201708920	doi.org/10.1002/anie.201708920	Isoquinoline-1-Carboxylate as a Traceless Leaving Group for Chelation-Assisted Glycosylation under Mild and Neutral Reaction Conditions		Angew. Chem.-Int. Edit.	73	Tang, WP	FALSE	FALSE	FALSE	FALSE
3101	10.1002/chem.201502329	doi.org/10.1002/chem.201502329	Pentacoordinated Carboxylate pi-Allyl Nickel Complexes as Key Intermediates for the Ni-Catalyzed Direct Amination of Allylic Alcohols		Chem.-Eur. J.	73	Carpentier, JF	FALSE	FALSE	FALSE	FALSE
3102	10.1002/ejoc.201500987	doi.org/10.1002/ejoc.201500987	Pincer-Nickel-Catalyzed Cross-Coupling of Aryl Sulfamates with Arylzinc Chlorides		Eur. J. Org. Chem.	73	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3103	10.1002/anie.201503704	doi.org/10.1002/anie.201503704	Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*Co-III] Catalysis		Angew. Chem.-Int. Edit.	73	Matsunaga, S	FALSE	FALSE	FALSE	FALSE
3104	10.1002/adsc.201400850	doi.org/10.1002/adsc.201400850	Copper-Catalyzed Regio- and Stereoselective Ring-Opening of Cyclic Sulfamidates with Grignard Reagents assisted by Lithium Chloride		Adv. Synth. Catal.	73	Lee, KI	FALSE	FALSE	FALSE	FALSE
3105	10.1039/c5gc01002k	doi.org/10.1039/c5gc01002k	Eco-friendly chemoselective N-functionalization of isatins mediated by supported KF in 2-MeTHF		Green Chem.	73	Pace, V	FALSE	FALSE	FALSE	FALSE
3106	10.1039/c4dt02158d	doi.org/10.1039/c4dt02158d	P,C-bond cleavage in the ligand sphere of a nickel(II) complex		Dalton Trans.	73	Thiel, WR	FALSE	FALSE	FALSE	FALSE
3107	10.1021/ja50711741	doi.org/10.1021/ja50711741	Key Mechanistic Features of Ni-Catalyzed C-H/C-O Biaryl Coupling of Azoles and Naphthalen-2-yl Pivalates		J. Am. Chem. Soc.	73	Itami, K	FALSE	FALSE	FALSE	FALSE
3108	10.1021/ol5016724	doi.org/10.1021/ol5016724	Enantiospecific, Nickel-Catalyzed Cross-Couplings of Allylic Pivalates and Arylboroxines		Org. Lett.	73	Watson, MP	FALSE	FALSE	FALSE	FALSE
3109	10.1021/jo500821m	doi.org/10.1021/jo500821m	Nickel-Catalyzed Asymmetric Ring Opening of Oxabenzonorbornadienes with Arylboronic Acids		J. Org. Chem.	73	Yang, DQ	FALSE	FALSE	FALSE	FALSE
3110	10.1002/chem.201402302	doi.org/10.1002/chem.201402302	Reductive Cross-Coupling Reactions between Two Electrophiles		Chem.-Eur. J.	73	Gosmini, C	FALSE	TRUE	FALSE	FALSE
3111	10.1016/j.tet.2014.02.051	doi.org/10.1016/j.tet.2014.02.051	Synthesis, characterization and X-ray structures of N-heterocyclic carbene palladium complexes based on calix[4]arenes: highly efficient catalysts towards Suzuki-Miyaura cross-coupling reactions		Tetrahedron	73	Bonnamour, I	FALSE	FALSE	FALSE	FALSE
3112	10.1002/anie.201310193	doi.org/10.1002/anie.201310193	Practical Metal- Free C( sp(3))-H Functionalization: Construction of Structurally Diverse a- Substituted N- Benzyl and N-Allyl Carbamates		Angew. Chem.-Int. Edit.	73	Liu, L	FALSE	FALSE	FALSE	FALSE
3113	10.6023/cjoc201310035	doi.org/10.6023/cjoc201310035	Advanced in the Synthesis of Triarylmethanes		Chin. J. Org. Chem.	73	Li, ZX	FALSE	FALSE	FALSE	FALSE
3114	10.1021/ja4111336	doi.org/10.1021/ja4111336	Metalloradical Approach to 2H-Chromenes		J. Am. Chem. Soc.	73	de Bruin, B	FALSE	FALSE	FALSE	FALSE
3115	10.1002/anie.201307019	doi.org/10.1002/anie.201307019	Modular Synthesis of Triarylmethanes through Palladium-Catalyzed Sequential Arylation of Methyl Phenyl Sulfone		Angew. Chem.-Int. Edit.	73	Nambo, M	FALSE	FALSE	FALSE	FALSE
3116	10.1039/c4ob01061b	doi.org/10.1039/c4ob01061b	C-H arylation of azaheterocycles: a direct ligand-free and Cu-catalyzed approach using diaryliodonium salts		Org. Biomol. Chem.	73	Kumar, D	FALSE	FALSE	FALSE	FALSE
3117	10.1039/c3sc52199k	doi.org/10.1039/c3sc52199k	Programmed synthesis of arylthiazoles through sequential C-H couplings		Chem. Sci.	73	Itami, K	FALSE	FALSE	FALSE	FALSE
3118	10.1039/c3dt52412d	doi.org/10.1039/c3dt52412d	Ni(II) tetraphosphine complexes as catalysts/initiators in the ring opening polymerization of epsilon-caprolactone		Dalton Trans.	73	Ren, ZG	FALSE	FALSE	FALSE	FALSE
3119	10.1002/anie.201303602	doi.org/10.1002/anie.201303602	Chiral Scandium(III)-Catalyzed Enantioselective alpha-Arylation of N-Unprotected 3-Substituted Oxindoles with Diaryliodonium Salts		Angew. Chem.-Int. Edit.	73	Feng, XM	FALSE	FALSE	FALSE	FALSE
3120	10.1021/jo401104y	doi.org/10.1021/jo401104y	Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B-2(OH)(4)]		J. Org. Chem.	73	Molander, GA	FALSE	FALSE	FALSE	FALSE
3121	10.1021/jo302425x	doi.org/10.1021/jo302425x	Cross-Coupling of ArX with ArMgBr Catalyzed by N-Heterocyclic Carbene-Based Nickel Complexes		J. Org. Chem.	73	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3122	10.1039/c3dt51119g	doi.org/10.1039/c3dt51119g	Keggin type mono Ni(II)-substituted phosphomolybdate: a sustainable, homogeneous and reusable catalyst for Suzuki-Miyaura cross-coupling		Dalton Trans.	73	Patel, A	FALSE	FALSE	FALSE	FALSE
3123	10.1039/c3gc40162f	doi.org/10.1039/c3gc40162f	An eco-benign and highly efficient access to 3-heterocyclic-substituted isoindolinones in ammonia water		Green Chem.	73	Shen, SC	FALSE	FALSE	FALSE	FALSE
3124	10.1002/ejoc.201200104	doi.org/10.1002/ejoc.201200104	Rhodium-Catalyzed Allylic Substitution Reactions with Indium(III) Organometallics		Eur. J. Org. Chem.	73	Riveiros, R	FALSE	FALSE	FALSE	FALSE
3125	10.1021/ja301243t	doi.org/10.1021/ja301243t	Stereocontrolled 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay toward Highly Functionalized 1,3-Dienes		J. Am. Chem. Soc.	73	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
3126	10.1002/chem.201101557	doi.org/10.1002/chem.201101557	Preparation of Mononuclear, Homodinuclear, and Heterotrinuclear Complexes by Salicylaldiminato-Functionalized Imidazolium Salt: Approach to Multifunctional Catalysts		Chem.-Eur. J.	73	Hou, XF	FALSE	FALSE	FALSE	FALSE
3127	10.1002/chem.201101083	doi.org/10.1002/chem.201101083	A General Cyclocarbonylation of Aryl Bromides and Triflates with Acetylenes: Palladium-Catalyzed Synthesis of 3-Alkylidenefuran-2-ones		Chem.-Eur. J.	73	Beller, M	FALSE	FALSE	FALSE	FALSE
3128	10.1039/c1cc14206b	doi.org/10.1039/c1cc14206b	Simple and efficient nickel-catalyzed cross-coupling reaction of alkynylalanes with benzylic and aryl bromides		Chem. Commun.	73	Gau, HM	FALSE	FALSE	FALSE	FALSE
3129	10.1002/anie.201008174	doi.org/10.1002/anie.201008174	Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes		Angew. Chem.-Int. Edit.	73	Zhang, XG	FALSE	TRUE	FALSE	FALSE
3130	10.1016/j.tet.2009.06.089	doi.org/10.1016/j.tet.2009.06.089	Copper-free Sonogashira reactions of 4-hydroxycoumarins with alkynes		Tetrahedron	73	Wu, J	FALSE	FALSE	FALSE	FALSE
3131	10.1021/jo801824e	doi.org/10.1021/jo801824e	Studies on the 1,2-Migrations in Pd-Catalyzed Negishi Couplings with JosiPhos Ligands		J. Org. Chem.	73	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
3132	10.1002/chem.200800608	doi.org/10.1002/chem.200800608	Classical Reagents: New Surprises in Palladium-Catalyzed C-C Coupling Reactions		Chem.-Eur. J.	73	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
3133	10.1016/j.tetlet.2006.03.101	doi.org/10.1016/j.tetlet.2006.03.101	Palladium-catalyzed desulfinylative Negishi C-C bond forming cross-couplings of sulfonyl and organozine chlorides		Tetrahedron Lett.	73	Vogel, P	FALSE	FALSE	FALSE	FALSE
3134	10.1021/om990533k	doi.org/10.1021/om990533k	Ruthenium-catalyzed allylic substitution of cyclic allyl carbonates with nucleophiles. Stereoselectivity and scope of the reaction		Organometallics	73	Kondo, T	FALSE	FALSE	FALSE	FALSE
3135	10.1002/masy.19971210106	doi.org/10.1002/masy.19971210106	Progress in controlled polymerization and design of novel polymer architectures		Macromol. Symp.	73		FALSE	FALSE	FALSE	FALSE
3136	10.1021/ja00068a092	doi.org/10.1021/ja00068a092	PALLADIUM-CATALYZED IODINE-ZINC EXCHANGE REACTIONS - A NEW PALLADIUM-MEDIATED INTRAMOLECULAR CARBOZINCATION OF ALKENES		J. Am. Chem. Soc.	73		FALSE	FALSE	FALSE	FALSE
3137	10.1055/a-1735-6250	doi.org/10.1055/a-1735-6250	Iodine-Promoted Formal [5+1] Annulation of 2-Vinylanilines and Thiurams: A Facile Approach to the Synthesis of 2-Aminoquinolines		Synlett	73	Zhang, ZP	FALSE	FALSE	FALSE	FALSE
3138	10.3390/polym14020231	doi.org/10.3390/polym14020231	Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for beta-Alkylation of Secondary Alcohols with Primary Alcohols		Polymers	73	Li, HX	FALSE	FALSE	FALSE	FALSE
3139	10.1002/chem.202103341	doi.org/10.1002/chem.202103341	Buchwald-Hartwig Amination of Coordinating Heterocycles Enabled by Large-but-Flexible Pd-BIAN-NHC Catalysts**		Chem.-Eur. J.	73	Liu, FS	FALSE	FALSE	FALSE	FALSE
3140	10.1039/d1sc05113j	doi.org/10.1039/d1sc05113j	Ligand-field transition-induced C-S bond formation from nickelacycles		Chem. Sci.	73	Park, K	FALSE	FALSE	FALSE	FALSE
3141	10.1002/cjoc.202100508	doi.org/10.1002/cjoc.202100508	Tunable System for Electrochemical Reduction of Ketones and Phthalimides		Chin. J. Chem.	73	Wang, YX	FALSE	TRUE	FALSE	FALSE
3142	10.1039/d1qo01106e	doi.org/10.1039/d1qo01106e	Palladium catalyzed desulfurative coupling of allyl sulfides with organoboronic acids		Org. Chem. Front.	73	Wen, ZK	FALSE	FALSE	FALSE	FALSE
3143	10.1039/d1ob01154e	doi.org/10.1039/d1ob01154e	Nickel catalyzed sustainable synthesis of benzazoles and purines via acceptorless dehydrogenative coupling and borrowing hydrogen approach		Org. Biomol. Chem.	73	Paul, ND	FALSE	FALSE	FALSE	FALSE
3144	10.1002/cctc.202100803	doi.org/10.1002/cctc.202100803	Organophotoredox-Catalyzed Decarboxylative N-Alkylation of Sulfonamides		ChemCatChem	73	Nagao, K; Ohmiya, H	FALSE	FALSE	FALSE	FALSE
3145	10.1016/j.tetlet.2021.153108	doi.org/10.1016/j.tetlet.2021.153108	Iridium-catalyzed enantioselective hydroalkynylation via alkene isomerization		Tetrahedron Lett.	73	Li, BJ	FALSE	FALSE	FALSE	FALSE
3146	10.1021/acscatal.1c01416	doi.org/10.1021/acscatal.1c01416	Photoinduced Nickel-Catalyzed Deaminative Cross-Electrophile Coupling for C(sp(2))-C(sp(3)) and C(sp(3))-C(sp(3)) Bond Formation		ACS Catal.	73	Koh, MJ	TRUE	TRUE	FALSE	FALSE
3147	10.1055/a-1504-8366	doi.org/10.1055/a-1504-8366	Regio- and Stereoselective (S(N)2) N-, O-, C- and S-Alkylation Using Trialkyl Phosphates		Synthesis	73	Banerjee, A; Hattori, T; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
3148	10.1021/acscentsci.7b00212	doi.org/10.1021/acscentsci.7b00212	Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to S(N)1 and S(N)2 Processes		ACS Central Sci.	73	Fu, GC	FALSE	FALSE	FALSE	FALSE
3149	10.1002/anie.201703380	doi.org/10.1002/anie.201703380	Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization		Angew. Chem.-Int. Edit.	73	Lam, HW	FALSE	FALSE	FALSE	FALSE
3150	10.1021/acscatal.7b00739	doi.org/10.1021/acscatal.7b00739	Developing Comprehensive Computational Parameter Sets To Describe the Performance of Pyridine-Oxazoline and Related Ligands		ACS Catal.	73	Sigman, MS	FALSE	FALSE	FALSE	FALSE
3151	10.1021/jacs.7b00049	doi.org/10.1021/jacs.7b00049	Decarbonylative Diaryl Ether Synthesis by Pd and Ni Catalysis		J. Am. Chem. Soc.	73	Itami, K	FALSE	FALSE	FALSE	FALSE
3152	10.1002/chem.201604452	doi.org/10.1002/chem.201604452	Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling		Chem.-Eur. J.	73	Rueping, M	TRUE	FALSE	FALSE	FALSE
3153	10.1002/ejoc.201600955	doi.org/10.1002/ejoc.201600955	Nickel-Catalyzed Allylic C(sp(2))-H Activation: Stereoselective Allyl Isomerization and Regiospecific Allyl Arylation of Allylarenes		Eur. J. Org. Chem.	73	Kang, CQ	FALSE	FALSE	FALSE	FALSE
3154	10.1021/acs.orglett.6b02274	doi.org/10.1021/acs.orglett.6b02274	A Free-Radical-Promoted Site-Specific Cross-Dehydrogenative-Coupling of N-Heterocycles with Fluorinated Alcohols		Org. Lett.	73	Liu, ZQ	FALSE	FALSE	FALSE	FALSE
3155	10.1021/acs.joc.6b01041	doi.org/10.1021/acs.joc.6b01041	NHC Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions of Aryl Boronate Esters with Perfluorobenzenes		J. Org. Chem.	73	Marder, TB; Radius, U	FALSE	FALSE	FALSE	FALSE
3156	10.1021/acs.inorgchem.5b02664	doi.org/10.1021/acs.inorgchem.5b02664	Mechanism of Pd-Catalyzed Decarbonylation of Biomass-Derived Hydrocinnamic Acid to Styrene following Activation as an Anhydride		Inorg. Chem.	73	Ortuno, MA; Cramer, CJ	FALSE	FALSE	FALSE	FALSE
3157	10.1021/acs.orglett.6b00195	doi.org/10.1021/acs.orglett.6b00195	Triazole-Directed Pd-Catalyzed C(sp(2))-H Oxygenation of Arenes and Alkenes		Org. Lett.	73	Correa, A	FALSE	FALSE	FALSE	FALSE
3158	10.1002/chem.201504985	doi.org/10.1002/chem.201504985	Visible-Light-Mediated Photocatalytic Difunctionalization of Olefins by Radical Acylarylation and Tandem Acylation/Semipinacol Rearrangement		Chem.-Eur. J.	73	Wallentin, CJ	TRUE	FALSE	FALSE	FALSE
3159	10.1016/j.mcat.2021.111500	doi.org/10.1016/j.mcat.2021.111500	One-pot synthesis of sulfones via Ni(II)-catalyzed sulfonylation of boronic acids, Na2S2O5 and benzylic ammonium salts	We investigated the transmetalation step of the Suzuki Miyaura cross coupling reaction (SMR) catalyzed by ligand-free Pd atom or Pd-X- (X = Cl or Br) using first -principles molecular dynamics simulations with an explicit solvent model. When starting from the single Pd atom, the halogen anion bound to the Pd was not replaced by organoboronate species and instead remained bound to the Pd throughout the transmetalation step. However, when starting from the Pd-X- catalyst, one of the two halogen anions was released from the first coordination sphere of the Pd during transmetalation. Therefore, the products after the transmetalation starting with either the single Pd atom or the PdX- were the same. We concluded that Pd-X- is the active species of the ligand-free Pd catalyst for the SMR. The overall activation free energies for transmetalation and reductive elimination were relatively low, estimated to be at most, 8.1 kcal/mol for X = Br and 8.4 kcal/mol for X = Cl, respectively, leading to the efficient turnover of the SMR. We ascribe the origin for the suppression of the catalytic reactivity of the ligand-free SMR for PhCl to the larger activation barrier in the oxidative addition step, which causes the aggregation of Pd catalysts.	Mol. Catal.	72	Zhu, HB; Xie, ZB; Le, ZG	FALSE	FALSE	FALSE	FALSE
3160	10.1002/ajoc.202100043	doi.org/10.1002/ajoc.202100043	Intermolecular Amination of Ketoximes with Anthranils by Rh-Catalyzed C-H Bond Activation in Air	An efficient protocol for C-O and C-S bonds formation by the cross-coupling reaction of 1,2-di(pyrimidin-2-yl) disulfides with phenols/thiophenols promoted by copper(I) chloride was established. It was discovered that variously substituted di(hetero)aryl disulfides and phenols were well tolerated. This strategy is the conversion of disulfides into hetero-aryl ethers and thioethers by a copper-promoted chemoselective C-S bond cleavage of disulfides.	Asian J. Org. Chem.	72	Wu, YC	FALSE	FALSE	FALSE	FALSE
3161	10.1016/j.tetlet.2020.152749	doi.org/10.1016/j.tetlet.2020.152749	Copper-promoted cyanation of aryl iodides with N,N-dimethyl aminomalononitrile	An sp(3) C-H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert-butyl hydroperoxide at 80 degrees C.	Tetrahedron Lett.	72	Wang, SH	FALSE	FALSE	FALSE	FALSE
3162	10.1021/acssuschemeng.0c08262	doi.org/10.1021/acssuschemeng.0c08262	Borrowing Carbonate-Enabled Allylic Amination Reactions under Additive- and Reductant-Free Nickel Catalysis Employing Allylic Alcohols	An efficient Pd-catalyzed three components reaction involving the 1,2-diarylation of vinylarenes has been disclosed. This reaction introduces two different aryl groups across vinylarenes at ambient temperature giving rise to multi-aryl substituted ethanes which are biologically relevant compounds prevailing in organic chemistry, medicinal chemistry and materials science.	ACS Sustain. Chem. Eng.	72	Kumar, D	FALSE	FALSE	FALSE	FALSE
3163	10.1021/jacs.0c11172	doi.org/10.1021/jacs.0c11172	Dual Catalytic Strategy for Forging sp(2)-sp(3) and sp(3)-sp(3) Architectures via beta-Scission of Aliphatic Alcohol Derivatives	Cyclic (alkyl)(amino)carbenes cAAC(cy) (1b) and cAAC(menthyl) (1c) react with [Ni(CO)(4)] to give the 18 VE complexes [Ni(CO)(3)(cAAC(cy))] (2b) and [Ni(CO)(3)(cAAC(menthyl))] (2c). With these in hand, the donor-strength and the steric profile of the respective cAAC ligands were evaluated. CAAC(cy) and cAAC(menthyl) possess similar overall-donating properties (Tolman electronic parameter (TEP) = 2046 (1b) and 2042 (1c)) as common NHCs, though they are also known to be better pi-acceptors. 3,3-Diamino-2-aryloxyacrylimidamide 3b, arising from the reaction of cAAC(cy) (1b) with released CO molecules, was obtained as side-product of CO substitution reactions at nickel carbonyls. In contrast to cAAC(menthyl) (%V-bur = 42), the sterically less encumbered cAAC(cy) (% V-bur = 38) undergoes a subsequent CO substitution at [Ni(CO)(3)(cAAC(cy))] (2b) to afford the 16 VE complex [Ni(CO)(cAAC(cy))(2)] (4b). Treatment of both [Ni(CO)(3)(cAAC(menthyl))] (2a) and [Ni(CO)(cAAC(menthyl))(2)] (4a) with allyl bromides led to the formation of cAAC-stabilized allyl nickel complexes [NiBr(eta(3)-H2C=CH-CH2)(cAAC(menthyl))] (5a) and [NiBr(eta(3)-H2C=CH-CMe2)(cAAC(menthyl))] (5b). The chloro complex [NiCl(eta(3)-H2C=CMe-CH2)(cAAC(menthyl))] (6) was synthesized from [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) by consecutive treatment with allyl chloride and cAAC. The allyl halide complexes 5 and 6 are thermally labile and decompose in solution already within a few hours at room temperature. One of the decomposition products, the dinuclear nickel complex [Ni-2(mu-Br)(2)(eta(3)-(cAAC(menthyl))=CH-CH(CH3))(2)] (7), was crystallographically characterized.	J. Am. Chem. Soc.	72	Martin, R	FALSE	FALSE	FALSE	FALSE
3164	10.1055/s-0040-1707885	doi.org/10.1055/s-0040-1707885	Nickel-Catalyzed anti-Selective Alkyne Functionalization Reactions	The first example of palladium-catalysed selective mono-alpha-alkenylation of ketones with alkenyl tosylates is described. In the presence of a Pd/XPhos catalyst system (0.1-1.0 mol%), the reaction provides mono-alpha-alkenylated ketones in good yields and exhibits excellent substrate tolerance. Highly congested, tri- and tetra-substituted alkenyl tosylates react smoothly and even problematic heteroaryl and aliphatic ketones are applicable substrates. Notably, small beta,gamma-unsaturated ketones are successfully prepared using acetone as a simple three-carbon feedstock.	Synthesis	72	Wilger, DJ	FALSE	FALSE	FALSE	FALSE
3165	10.1002/cctc.202001041	doi.org/10.1002/cctc.202001041	Amidation of Aldehydes with Amines under Mild Conditions Using Metal-Organic Framework Derived NiO@Ni Mott-Schottky Catalyst	Synthetic methods for the preparation of compounds containing trifluoromethyl groups are in extremely high demand in nearly every sector of the chemical industry. Over the last several years the chemistry of N-tert-butylsulfinyl-3,3,3-trifluoroacetaldimine has undergone particular development. Currently, it is commonly used as a versatile reagent for general asymmetric synthesis of trifluoromethyl-containing amines and amino acids of pharmaceutical potential. This review provides a critical and comprehensive overview of synthetic applications of this reagent as well as of several relevant analogues, such as aldimines containing -CHF2, -CClF2, -CBrF2, and -CF2P(O)(OEt)(2) groups and N-tert-butylsulfinyl-3,3,3-trifluoromethyl-substituted ketimines. Where it is possible, we emphasize the structural novelty and pharmaceutic value of the products obtainable by application of these reagents.	ChemCatChem	72	Jain, SK	FALSE	FALSE	FALSE	FALSE
3166	10.1021/acs.orglett.0c02429	doi.org/10.1021/acs.orglett.0c02429	Ni-Catalyzed Direct Carboxylation of an Unactivated C-H Bond with CO2	Dibenzylhafnium complexes 3a d, supported by dianionic bidentate or tridentate ligands, upon activation via abstraction by either [Ph3C][B(C6F5)(4)] or B(C6F5)(3) served as catalysts for the C(sp(3))-H alkenylation of 2,6-dimethylpyridines with dialkylalkynes to give corresponding C(sp(3))-H alkenylated products 6. Complex 3c, containing a pyridine arm in the ligand skeleton, exhibited the highest catalytic activity among 3a d; initial addition of 2,6-dimethylpyridine (4a) to the C6D5Br solution of 3c followed by [Ph3C][B(C6F5)(4)] and 3-hexyne (5a) produced trisubstituted alkene 6aa in stereoselective manner in up to 50% yield without any byproducts, while the addition of 5a prior to 4a and [Ph3C][B(C6F5)(4)] to the C6D5Br solution of 3c generated 6aa, together with the formation of byproduct (E)-(2-ethylpent-2-en-1-yl)benzene (7). When an asymmetrical pyridine, 3-bromo-2,6-dimethylpyridine, was used as the coupling partner, the corresponding trisubstituted alkene was obtained selectively. Catalytically active cationic benzylhafnium complexes 8a-d, which were prepared by the reactions of 3a-d and B(C6F5)(3), respectively, were characterized by H-1, C-13, and F-19 NMR spectroscopy. Kinetic studies of the catalytic reaction between 4a and 4-octyne (5b) using 3c and [Ph3C][B(C6F5)(4)] in C6D5Br revealed that the catalytic reaction was zero-order for both 4a and 5b, indicating that the rate-determining step involved the C(sp3)-H bond activation of 4a by vinylhafnium intermediate 11c.	Org. Lett.	72	Wang, BQ	FALSE	FALSE	FALSE	FALSE
3167	10.1021/acsomega.0c01002	doi.org/10.1021/acsomega.0c01002	New Nanomagnetic Heterogeneous Cobalt Catalyst for the Synthesis of Aryl Nitriles and Biaryls Hadis	Inspired by the mechanistic studies of rhodium-catalyzed atom-economic addition of carboxylate acids to allenes, a rhodium-catalyzed dynamic kinetic asymmetric allylation of different nucleophiles with racemic allylic carbonates has been developed. High regio- and enantioselectivities can be obtained under neutral conditions and, furthermore, the chemoselectivities can be controlled by different diphosphine ligands. (R,R)-QuinoxP* leads to selective O-allylation of phenols, whereas when embedding (S,S)-DIOP as the ligand, 2-naphthol is ortho-C-allylated for the first time in high enantioselectivity. To this end, hydroxypyridines can be N-allylated by Rh-I/(S)-DTBM-Segphos via the same intermediate as in the previously reported atom-economic addition to allenes.	ACS Omega	72	Sobhani, S	FALSE	FALSE	FALSE	FALSE
3168	10.1039/d0qo00543f	doi.org/10.1039/d0qo00543f	Iridium-catalyzed arylation of sulfoxonium ylides and arylboronic acids: a straightforward preparation of alpha-aryl ketones	Asymmetric desymmetrization of sigma-symmetric acid anhydrides was achieved with chiral phosphoric acid as a Bronsted acid catalyst. The key of success was finding of benzhydrol and 2,2-diphenylethanol as the nucleophiles of choice. The corresponding half esters were obtained in good yields with high selectivity. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Chem. Front.	72	Zhang, LY; Zhang, SS	FALSE	FALSE	FALSE	FALSE
3169	10.1039/d0sc01585g	doi.org/10.1039/d0sc01585g	Photoinduced transition-metal- and external-photosensitizer-free intramolecular aryl rearrangement via C(Ar)-O bond cleavage	A highly enantioselective Pd-catalysed decarboxylative asymmetric allylic alkylation of cyclopentanone derived alpha-aryl-beta-keto esters employing the (R,R)-ANDEN-phenyl Trost ligand has been developed. The product (S)-alpha-allyl-alpha-arylcyclopentanones were obtained in excellent yields and enantioselectivities (up to > 99.9% ee). This represents one of the most highly enantioselective formations of an all-carbon quaternary stereogenic center reported to date. This reaction was demonstrated on a 4.0 mmol scale without any deterioration of enantioselectivity and was exploited as the key enantioselective transformation in an asymmetric formal synthesis of the natural product (+)-tanikolide.	Chem. Sci.	72	Zeng, HY	TRUE	FALSE	FALSE	FALSE
3170	10.1021/jacs.0c02673	doi.org/10.1021/jacs.0c02673	Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Chlorides with Primary Alkyl Chlorides	It has been established that the oxidative sp(2) C-H bond allylation with aliphatic alkenes proceeds under mild conditions by using heteroarenes as directing groups and an (electron-deficient eta(5)-cyclopentadienyl)rhodium(III) complex, [(CpRhCl2)-Rh-E](2), as a precatalyst. In sharp contrast, the use of [Cp*RhCl2](2) instead of [(CpRhCl2)-Rh-E](2) led to a complex mixture of products under the same reaction conditions.	J. Am. Chem. Soc.	72	Weix, DJ	FALSE	TRUE	FALSE	FALSE
3171	10.1002/anie.201913132	doi.org/10.1002/anie.201913132	Synthesis and Functionalization of Allenes by Direct Pd-Catalyzed Organolithium Cross-Coupling	A nickel catalyst promoted the polymerization between various Grignard reagents with 2-phenyl-4,6-bi(4-fluorophenyl)-1,3,5-triazine. The reaction scope was thoroughly investigated and fully characterized. The Sp(2)-C - F bond was successfully activated by the triazine group in Kumada coupling reactions. Also, di-Grignard reagents showed higher activity than mono-Grignard reagents. The reaction scope results reveal that a Grignard reagent with strong nucleophilicity and aryl fluoride with strong electrophilicity are necessary to lead to Kumada polycondensation of oligothiophenes with aryl fluoride. In this work, polymerization between di-functionalized oligothiophene Grignard reagents with aryl fluoride was first conducted. The weight-average molecular weight is high, up to 14.8 kDa. The -conjugated polymers obtained exhibit emission colours of blue, green and yellow with efficient photoluminescence. (c) 2016 Society of Chemical Industry	Angew. Chem.-Int. Edit.	72	Feringa, BL	FALSE	FALSE	FALSE	FALSE
3172	10.1021/acs.orglett.0c00688	doi.org/10.1021/acs.orglett.0c00688	Nickel-Catalyzed Asymmetric Reductive Arylbenzylation of Unactivated Alkenes	A simple, mild and efficient method is developed for the synthesis of 5-substituted 1H-tetrazoles. Out of three used Pb(II) catalysts, lead chloride (PbCl2) has been found to be an efficient catalyst for [3+2] cycloaddition of NaN3 with aromatic and aliphatic nitriles to afford 5-substituted 1H-tetrazoles. The catalyst is reusable up to four cycles with consistent activity. The cost effectiveness and easy availability of the catalyst, simple methodology, excellent yield and easy work-up are the additional advantages. (C) 2015 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.	Org. Lett.	72	Wang, C	FALSE	FALSE	FALSE	FALSE
3173	10.1021/acs.joc.0c00008	doi.org/10.1021/acs.joc.0c00008	Nickel-Catalyzed Alkylation or Reduction of Allylic Alcohols with Alkyl Grignard Reagents	The non-cryogenic synthesis of 5/6- and/or 3-silyl-functionalised 2-methoxypyridines by a 5-Br/Mg exchange process using nBu(2)/PrMg Li and LiCl and involving C-3 metallation using a novel nBu(2)TMPMg Li reagent is described. Furthermore, the usefulness of nBu(2)TMPMg Li in the functionalisation of 2-methoxypyridine at the 3-position with a wide range of electrophiles was successfully tested. The above achievements have allowed the construction of organosilicon-linked 2-meth-oxypyridines composed of two, three and four rings by the hydrosilylation of 5- and/or 3-SiH(or alkenyl) derivatives using the hitherto rarely applied [Pt(cod)Me-2] catalyst. Additionally, the synthesis of a one-chain oligomer consisting of eight 2-methoxypyridines obtained by the hydrosilylation/polymerisation approach, followed by protodesilylation of the SiHMe2 group was also achieved by manipulating the amount of catalyst in the reactions.	J. Org. Chem.	72	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3174	10.1002/ejoc.201901601	doi.org/10.1002/ejoc.201901601	Pd-Catalyzed Regioselective Hydroesterification of Olefins with 2,2,2-Trifluoroethyl Formate	A general approach to asymmetric synthesis of highly substituted dihydroquinolines was achieved through neighboring ortho-amino group engaged sequential Michael/amination/dehydration reactions on (E)-2-(2-nitrovinyl) anilines with cyclic and acyclic beta-keto esters in the presence of a catalytic amount of Rawal's quinidine-NH-benzyl squaramide followed by TFA.	Eur. J. Org. Chem.	72	Shi, Y	FALSE	FALSE	FALSE	FALSE
3175	10.1021/acs.joc.9b02933	doi.org/10.1021/acs.joc.9b02933	Visible-Light-Promoted C2 Selective Arylation of Quinoline and Pyridine N-Oxides with Diaryliodonium Tetrafluoroborate		J. Org. Chem.	72	Song, JZ	FALSE	FALSE	FALSE	FALSE
3176	10.1002/anie.201914221	doi.org/10.1002/anie.201914221	Versatile Glycosyl Sulfonates in beta-Selective C-Glycosylation		Angew. Chem.-Int. Edit.	72	Bennett, CS	FALSE	FALSE	FALSE	FALSE
3177	10.24820/ark.5550190.p011.417	doi.org/10.24820/ark.5550190.p011.417	Advances in nitroarene reductive amidations		Arkivoc	72	Moshapo, PT	FALSE	FALSE	FALSE	FALSE
3178	10.1039/c9sc03169c	doi.org/10.1039/c9sc03169c	Palladium-catalyzed decarbonylative Suzuki-Miyaura cross-coupling of amides by carbon-nitrogen bond activation		Chem. Sci.	72	Szostak, M	FALSE	FALSE	FALSE	FALSE
3179	10.1002/chem.201903696	doi.org/10.1002/chem.201903696	Synthesis of Diverse Functionalized Quinoxalines by Oxidative Tandem Dual C-H Amination of Tetrahydroquinoxalines with Amines		Chem.-Eur. J.	72	Zhang, M	FALSE	FALSE	FALSE	FALSE
3180	10.1016/j.molliq.2019.111454	doi.org/10.1016/j.molliq.2019.111454	Abraham model correlations for solute transfer into 2-methyl-2-butanol based on measured activity coefficient and solubility data at 298.15 K		J. Mol. Liq.	72	Acree, WE	FALSE	FALSE	FALSE	FALSE
3181	10.1021/acs.orglett.9b02050	doi.org/10.1021/acs.orglett.9b02050	Palladium-Catalyzed Chemoselective Negishi Cross-Coupling of Bis[(pinacolato)boryl]methylzinc Halides with Aryl (Pseudo)Halides		Org. Lett.	72	Cho, SH	FALSE	FALSE	FALSE	FALSE
3182	10.1021/jacs.9b05461	doi.org/10.1021/jacs.9b05461	LiCl-Accelerated Multimetallic Cross-Coupling of Aryl Chlorides with Aryl Triflates		J. Am. Chem. Soc.	72	Weix, DJ	FALSE	FALSE	FALSE	FALSE
3183	10.1039/c8dt05020a	doi.org/10.1039/c8dt05020a	Manganese-catalyzed direct C-C coupling of -C-H bonds of amides and esters with alcohols via hydrogen autotransfer		Dalton Trans.	72	Balaraman, E	FALSE	FALSE	FALSE	FALSE
3184	10.1021/acs.orglett.9b01053	doi.org/10.1021/acs.orglett.9b01053	[Pd(NHC)(acac)Cl]: Well-Defined, Air-Stable, and Readily Available Precatalysts for Suzuki and Buchwald-Hartwig Cross-coupling (Transamidation) of Amides and Esters by N-C/O-C Activation		Org. Lett.	72	Szostak, M	FALSE	FALSE	FALSE	FALSE
3185	10.1021/jacs.9b03280	doi.org/10.1021/jacs.9b03280	Ketone Synthesis by a Nickel-Catalyzed Dehydrogenative Cross-Coupling of Primary Alcohols		J. Am. Chem. Soc.	72	Newman, SG	FALSE	FALSE	FALSE	FALSE
3186	10.1055/s-0037-1610410	doi.org/10.1055/s-0037-1610410	Nickel-Catalyzed Highly Atom-Economical C-C Coupling Reactions with Components		Synlett	72	Ye, MC; Zhou, QL	FALSE	FALSE	FALSE	FALSE
3187	10.1039/c8ob02141d	doi.org/10.1039/c8ob02141d	Boronic acid-catalysed C-3 selective ring opening of 3,4-epoxy alcohols with thiophenols and thiols		Org. Biomol. Chem.	72	Wang, CA	FALSE	FALSE	FALSE	FALSE
3188	10.1021/jacs.8b12568	doi.org/10.1021/jacs.8b12568	Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of beta-Fluoroamines		J. Am. Chem. Soc.	72	Gouverneur, V	FALSE	FALSE	FALSE	FALSE
3189	10.1002/cctc.201801350	doi.org/10.1002/cctc.201801350	Investigation on Electron Distribution and Synergetic to Enhance Catalytic Activity in Bimetallic Ni(II)/Pd(II) Molecular Monolayer		ChemCatChem	72	Li, TS; Wu, YJ	FALSE	TRUE	FALSE	FALSE
3190	10.1021/acs.joc.8b02498	doi.org/10.1021/acs.joc.8b02498	Nickel-Catalyzed Cyanation of Phenol Derivatives with Zn(CN)(2) Involving C-O Bond Cleavage		J. Org. Chem.	72	Liu, YH	FALSE	FALSE	FALSE	FALSE
3191	10.1021/acscatal.8b02009	doi.org/10.1021/acscatal.8b02009	Nickel-Catalyzed Reductive Cleavage of Carbon-Oxygen Bonds in Anisole Derivatives Using Diisopropylaminoborane		ACS Catal.	72	Chatani, N; Tobisu, M	FALSE	FALSE	FALSE	FALSE
3192	10.1039/c8sc00609a	doi.org/10.1039/c8sc00609a	Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis		Chem. Sci.	72	Shu, XZ	FALSE	FALSE	FALSE	FALSE
3193	10.1021/acs.orglett.8b00674	doi.org/10.1021/acs.orglett.8b00674	Rhodium-Catalyzed C-O Bond Alkynylation of Aryl Carbamates with Propargyl Alcohols		Org. Lett.	72	Chatani, N; Tobisu, M	FALSE	FALSE	FALSE	FALSE
3194	10.1002/anie.201712428	doi.org/10.1002/anie.201712428	Nickel-Catalyzed Umpolung Arylation of Ambiphilic -Bromoalkyl Boronic Esters		Angew. Chem.-Int. Edit.	72	Martin, R	FALSE	FALSE	FALSE	FALSE
3195	10.1021/acs.orglett.7b03191	doi.org/10.1021/acs.orglett.7b03191	General Method for the Suzuki-Miyaura Cross-Coupling of Primary Amide-Derived Electrophiles Enabled by [Pd(NHC)(cin)Cl] at Room Temperature		Org. Lett.	72	Szostak, M	FALSE	TRUE	FALSE	FALSE
3196	10.1016/j.mcat.2017.10.004	doi.org/10.1016/j.mcat.2017.10.004	Catalytic cross-coupling reaction of aryl iodides with triarylbismuths by an N-heterocyclic carbene-PdCl2 based on benzo-9-crown-3 catalyst at room temperature		Mol. Catal.	72	Wang, JW	FALSE	FALSE	FALSE	FALSE
3197	10.1002/anie.201708573	doi.org/10.1002/anie.201708573	A Redox Modulatory Mn3O4 Nanozyme with Multi-Enzyme Activity Provides Efficient Cytoprotection to Human Cells in a Parkinson's Disease Model		Angew. Chem.-Int. Edit.	72	Mugesh, G	FALSE	FALSE	FALSE	FALSE
3198	10.1007/s40242-017-6455-9	doi.org/10.1007/s40242-017-6455-9	Heterogeneous h-BN@Cyclodextrin@Pd(II) Nanomaterial: Fabrication, Characterization and Application as a Highly Efficient and Recyclable Catalyst for C-C Coupling Reactions		Chem. Res. Chin. Univ.	72	Hai, L; Wu, Y	FALSE	FALSE	FALSE	FALSE
3199	10.1039/c5ob02125a	doi.org/10.1039/c5ob02125a	Hg/Pt-catalyzed conversion of bromo alkynamines/alkynols to saturated and unsaturated gamma-butyrolactams/lactones via intramolecular electrophilic cyclization		Org. Biomol. Chem.	72	Reddy, MS	FALSE	FALSE	FALSE	FALSE
3200	10.1016/j.jorganchem.2015.07.009	doi.org/10.1016/j.jorganchem.2015.07.009	Palladium-catalyzed acylative cross-coupling of amides with diarylborinic acids and sodium tetraarylborates		J. Organomet. Chem.	72	Zou, G	FALSE	FALSE	FALSE	FALSE
3201	10.1021/acs.joc.5b01540	doi.org/10.1021/acs.joc.5b01540	General Ambient Temperature Benzylic Metalations Using Mixed-Metal Li/K-TMP Amide		J. Org. Chem.	72	O'Shea, DF	FALSE	FALSE	FALSE	FALSE
3202	10.1002/hc.21267	doi.org/10.1002/hc.21267	Ni-Catalyzed Cross-Coupling Reaction: The Direct Synthesis of Symmetrical Disulfanes from Aryl and Primary Alkyl Halides		Heteroatom Chem.	72	Soleiman-Beigi, M	FALSE	FALSE	FALSE	FALSE
3203	10.1016/j.tetlet.2015.05.025	doi.org/10.1016/j.tetlet.2015.05.025	Cp*Co(III)-catalyzed direct functionalization of aromatic C-H bonds with alpha-diazomalonates		Tetrahedron Lett.	72	Wang, HG	FALSE	FALSE	FALSE	FALSE
3204	10.1021/acs.joc.5b00794	doi.org/10.1021/acs.joc.5b00794	Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis		J. Org. Chem.	72	Overman, LE	TRUE	FALSE	FALSE	FALSE
3205	10.1016/S1872-2067(14)60217-5	doi.org/10.1016/S1872-2067(14)60217-5	Recent advances in mechanistic studies on Ni catalyzed cross-coupling reactions		Chin. J. Catal.	72	Liu, L	FALSE	FALSE	FALSE	FALSE
3206	10.1039/c4cc08367a	doi.org/10.1039/c4cc08367a	Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions		Chem. Commun.	72	Jiang, XF	FALSE	FALSE	FALSE	FALSE
3207	10.1021/ja512040c	doi.org/10.1021/ja512040c	Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane		J. Am. Chem. Soc.	72	Tsuji, Y	FALSE	FALSE	FALSE	FALSE
3208	10.1021/om500938u	doi.org/10.1021/om500938u	Ortho Derivatization of Phenols through C-H Nickelation: Synthesis, Characterization, and Reactivities of Ortho-Nickelated Phosphinite Complexes		Organometallics	72	Zargarian, D	FALSE	FALSE	FALSE	FALSE
3209	10.1016/j.jaap.2014.08.002	doi.org/10.1016/j.jaap.2014.08.002	The mechanism for the formation of levoglucosenone during pyrolysis of beta-D-glucopyranose and cellobiose: A density functional theory study		J. Anal. Appl. Pyrolysis	72	Lu, Q	FALSE	FALSE	FALSE	FALSE
3210	10.1016/j.jorganchem.2014.01.037	doi.org/10.1016/j.jorganchem.2014.01.037	Synthesis, spectral and structural studies of silver and gold(I) complexes containing some symmetrical diphosphine ligands		J. Organomet. Chem.	72	Trivedi, M	FALSE	FALSE	FALSE	FALSE
3211	10.1039/c4ob00978a	doi.org/10.1039/c4ob00978a	Palladium-catalyzed direct addition of arylboronic acids to 2-aminobenzonitrile derivatives: synthesis, biological evaluation and in silico analysis of 2-aminobenzophenones, 7-benzoyl-2-oxoindolines, and 7-benzoylindoles		Org. Biomol. Chem.	72	Su, WK	FALSE	FALSE	FALSE	FALSE
3212	10.1039/c4ra08675a	doi.org/10.1039/c4ra08675a	Recent advances in transition-metal-catalyzed C-CN bond activations		RSC Adv.	72	Lu, P	FALSE	FALSE	FALSE	FALSE
3213	10.1002/ejic.201300287	doi.org/10.1002/ejic.201300287	Di- and Trinuclear Zinc and Cobalt Complexes and Their Reactivity towards Dioxygen		Eur. J. Inorg. Chem.	72	Siewert, I	FALSE	FALSE	FALSE	FALSE
3214	10.1002/asia.201300045	doi.org/10.1002/asia.201300045	Manganese-Catalyzed Cross-Coupling of Thiols with Aryl Iodides		Chem.-Asian J.	72	Lee, CF	FALSE	FALSE	FALSE	FALSE
3215	10.1039/c3sc50806d	doi.org/10.1039/c3sc50806d	Access to congested quaternary centers by Pd-catalyzed intermolecular gamma-arylation of unactivated alpha,beta-unsaturated aldehydes		Chem. Sci.	72	Mazet, C	FALSE	FALSE	FALSE	FALSE
3216	10.1021/jo3018507	doi.org/10.1021/jo3018507	Iridium-Catalyzed Asymmetric Ring-Opening of Oxabenzonorbornadienes with Phenols		J. Org. Chem.	72	Yang, DQ	FALSE	FALSE	FALSE	FALSE
3217	10.1021/om300329z	doi.org/10.1021/om300329z	Mechanistic Origin of Regioselectivity in Nickel-Catalyzed Olefin Hydroheteroarylation through C-H Activation		Organometallics	72	Shi, J	FALSE	FALSE	FALSE	FALSE
3218	10.1021/ol2032784	doi.org/10.1021/ol2032784	N-Directing Group Assisted Rhodium-Catalyzed Aryl C-H Addition to Aryl Aldehydes		Org. Lett.	72	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
3219	10.1002/jhet.845	doi.org/10.1002/jhet.845	Palladium-catalyzed dehalogenation of 5-halopyrazoles		J. Heterocycl. Chem.	72	Wong, FF	FALSE	FALSE	FALSE	FALSE
3220	10.1021/jo201630e	doi.org/10.1021/jo201630e	Direct Aminoalkylation of Arenes, Heteroarenes, and Alkenes via Ni-Catalyzed Negishi Cross-Coupling Reactions		J. Org. Chem.	72	Knochel, P	FALSE	FALSE	FALSE	FALSE
3221	10.1016/j.tetasy.2011.08.017	doi.org/10.1016/j.tetasy.2011.08.017	Application of novel enantiopure hydroxymethyl-substituted pyridine derivatives in asymmetric catalysis		Tetrahedron-Asymmetry	72	Reissig, HU	FALSE	FALSE	FALSE	FALSE
3222	10.1002/aoc.1804	doi.org/10.1002/aoc.1804	A comparative homocoupling reaction of aryl halides using monomeric orthopalladated complex of 4-methoxybenzoylmethylenetriphenylphosphorane under conventional and microwave irradiation conditions		Appl. Organomet. Chem.	72	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
3223	10.1039/c1cs15114b	doi.org/10.1039/c1cs15114b	Palladium-catalyzed cross-coupling reactions of aryl mesylates		Chem. Soc. Rev.	72	Kwong, FY	FALSE	FALSE	FALSE	FALSE
3224	10.1021/jo1015135	doi.org/10.1021/jo1015135	Reactivity and Selectivity in Hydrovinylation of Strained Alkenes		J. Org. Chem.	72	RajanBabu, TV	FALSE	FALSE	FALSE	FALSE
3225	10.1016/j.tetlet.2009.12.028	doi.org/10.1016/j.tetlet.2009.12.028	Ultrasound-assisted synthesis of symmetrical biaryls by palladium-catalyzed detelluration of 1,2-diaryiditellanes		Tetrahedron Lett.	72	Stefani, HA	FALSE	FALSE	FALSE	FALSE
3226	10.1021/ja810157e	doi.org/10.1021/ja810157e	Mechanism of Ni-Catalyzed Selective C-O Bond Activation in Cross-Coupling of Aryl Esters		J. Am. Chem. Soc.	72	Liu, L	FALSE	FALSE	FALSE	FALSE
3227	10.1002/adsc.200800624	doi.org/10.1002/adsc.200800624	Iodine-Catalyzed Suzuki-Miyaura Coupling Performed in Air		Adv. Synth. Catal.	72	Mao, JC	FALSE	FALSE	FALSE	FALSE
3228	10.1021/ol802493z	doi.org/10.1021/ol802493z	Palladium - Indolylphosphine-Catalyzed Hiyama Cross-Coupling of Aryl Mesylates		Org. Lett.	72	Kwong, FY	FALSE	FALSE	FALSE	FALSE
3229	10.1002/chem.200902221	doi.org/10.1002/chem.200902221	Palladium(0) versus Nickel(0) Catalysis in Selective Functional-Group-Tolerant sp(3)-sp(3) Carbon-Carbon Bond Formations		Chem.-Eur. J.	72	Kobayashi, S	FALSE	FALSE	FALSE	FALSE
3230	10.1021/jo8018686	doi.org/10.1021/jo8018686	Efficient Negishi Coupling Reactions of Aryl Chlorides Catalyzed by Binuclear and Mononuclear Nickel-N-Heterocyclic Carbene Complexes		J. Org. Chem.	72	Chen, WZ	FALSE	FALSE	FALSE	FALSE
3231	10.1246/bcsj.81.1183	doi.org/10.1246/bcsj.81.1183	Heterogeneous Asymmetric Catalysis in Water with Amphiphilic Polymer-Supported Homochiral Palladium Complexes		Bull. Chem. Soc. Jpn.	72	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
3232	10.1021/jo800444y	doi.org/10.1021/jo800444y	Synthesis of 5-fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling		J. Org. Chem.	72	Kung, HF	FALSE	FALSE	FALSE	FALSE
3233	10.1002/anie.200803814	doi.org/10.1002/anie.200803814	Cross-Coupling of Aryl/Alkenyl Pivalates with Organozinc Reagents through Nickel-Catalyzed C-O Bond Activation under Mild Reaction Conditions		Angew. Chem.-Int. Edit.	72	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
3234	10.1002/adsc.200404191	doi.org/10.1002/adsc.200404191	Palladium- and nickel-catalyzed coupling reactions of alpha-bromoalkenylphosphonates with arylboronic acids and lithium alkenylborates		Adv. Synth. Catal.	72	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
3235	10.1021/jo035880p	doi.org/10.1021/jo035880p	Asymmetric synthesis of axially chiral biaryls by nickel-catalyzed grignard cross-coupling of dibenzothiophenes		J. Org. Chem.	72	Hayashi, T	FALSE	FALSE	FALSE	FALSE
3236	10.1002/1521-3773(20020503)41:9<1603::AID-ANIE1603>3.0.CO;2-D	doi.org/10.1002/1521-3773(20020503)41:9<1603::AID-ANIE1603>3.0.CO;2-D	In situ enzymatic screening (ISES): A tool for catalyst discovery and reaction development		Angew. Chem.-Int. Edit.	72	Berkowitz, DB	FALSE	FALSE	FALSE	FALSE
3237	10.1021/jo980249n	doi.org/10.1021/jo980249n	Highly regioselective palladium-catalyzed internal arylation of allyltrimethylsilane with aryl triflates		J. Org. Chem.	72	Hallberg, A	FALSE	FALSE	FALSE	FALSE
3238	10.1080/10601329608014921	doi.org/10.1080/10601329608014921	Self-assembly of viruses as models for the design of new macromolecular and supramolecular architectures		J. Macromol. Sci.-Pure Appl. Chem.	72	Percec, V	FALSE	FALSE	FALSE	FALSE
3239	10.1039/d2ob00003b	doi.org/10.1039/d2ob00003b	BF3 center dot OEt2 catalyzed decarbonylative arylation/C-H functionalization of diazoamides with arylaldehydes: synthesis of substituted 3-aryloxindoles		Org. Biomol. Chem.	72	Muthusamy, S	FALSE	FALSE	FALSE	FALSE
3240	10.1016/j.xcrp.2021.100574	doi.org/10.1016/j.xcrp.2021.100574	Regioselective nickel-catalyzed dicarbofunctionalization of unactivated alkenes enabled by picolinamide auxiliary		Cell Rep. Phys. Sci.	72	Wang, C	FALSE	FALSE	FALSE	FALSE
3241	10.1039/d1ce01282g	doi.org/10.1039/d1ce01282g	A tryptophan-based copper(ii) coordination polymer: catalytic activity towards Suzuki-Miyaura cross-coupling reactions		Crystengcomm	72	Husain, A	FALSE	FALSE	FALSE	FALSE
3242	10.1039/d1ob01410b	doi.org/10.1039/d1ob01410b	Visible-light-promoted olefinic trifluoromethylation of enamides with CF3SO2Na		Org. Biomol. Chem.	72	Chen, K; Yang, H	FALSE	FALSE	FALSE	FALSE
3243	10.1021/acs.joc.1c00474	doi.org/10.1021/acs.joc.1c00474	FeTPPCl/FeCl3 Co-Catalyzed One-Pot Green Synthesis of alpha-Diaryl-beta-alkynol Derivatives via Propargylic Carbocation Chemistry		J. Org. Chem.	72	Liu, SY	FALSE	FALSE	FALSE	FALSE
3244	10.1021/jacs.1c04254	doi.org/10.1021/jacs.1c04254	Aryl Radical Activation of C-O Bonds: Copper-Catalyzed Deoxygenative Difluoromethylation of Alcohols		J. Am. Chem. Soc.	72	Liu, W	FALSE	FALSE	FALSE	FALSE
3245	10.1039/d1qo00759a	doi.org/10.1039/d1qo00759a	Palladium-catalyzed direct reductive cross-coupling of aryltrimethylammonium salts with aryl bromides		Org. Chem. Front.	72	Shen, ZL	FALSE	FALSE	FALSE	FALSE
3246	10.1002/anie.202104050	doi.org/10.1002/anie.202104050	Cooperative Bond Activation and Facile Intramolecular Aryl Transfer of Nickel-Aluminum Pincer-type Complexes		Angew. Chem.-Int. Edit.	72	Lu, CC	FALSE	FALSE	FALSE	FALSE
3247	10.1021/acs.organomet.1c00147	doi.org/10.1021/acs.organomet.1c00147	Switchable beta-alkylation of Secondary Alcohols with Primary Alcohols by a Well-Defined Cobalt Catalyst		Organometallics	72	Ding, KY	FALSE	FALSE	FALSE	FALSE
3248	10.1021/acscatal.1c00571	doi.org/10.1021/acscatal.1c00571	Atroposelective Transfer Hydrogenation of Biaryl Aminals via Dynamic Kinetic Resolution. Synthesis of Axially Chiral Diamines		ACS Catal.	72	Lassaletta, JM; Hornillos, V	FALSE	FALSE	FALSE	FALSE
3249	10.1002/anie.201706631	doi.org/10.1002/anie.201706631	Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Secondary alpha-(Trifluoromethyl)benzyl Tosylates		Angew. Chem.-Int. Edit.	72	Tredwell, M	FALSE	FALSE	FALSE	FALSE
3250	10.1021/acscatal.7b01833	doi.org/10.1021/acscatal.7b01833	Synergistic Copper/Palladium Catalysis for the Regio- and Stereoselective Synthesis of Borylated Skipped Dienes		ACS Catal.	72	Fananas-Mastral, M	FALSE	FALSE	FALSE	FALSE
3251	10.1016/j.tet.2017.02.021	doi.org/10.1016/j.tet.2017.02.021	Nickel-catalyzed C-H arylation of benzoxazoles and oxazoles: Benchmarking the influence of electronic, steric and leaving group variations in phenolic electrophiles		Tetrahedron	72	Kalyani, D	FALSE	FALSE	FALSE	FALSE
3252	10.1016/j.tetasy.2017.03.008	doi.org/10.1016/j.tetasy.2017.03.008	Pd-catalyzed enantioselective C-H arylation of phosphinamides with boronic acids for the synthesis of P-stereogenic compounds		Tetrahedron-Asymmetry	72	Han, FS	FALSE	FALSE	FALSE	FALSE
3253	10.1039/c6nj03789e	doi.org/10.1039/c6nj03789e	Novel triazole-modified chitosan@nickel nanoparticles: efficient and recoverable catalysts for Suzuki reaction		New J. Chem.	72	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
3254	10.1039/c6ob01668e	doi.org/10.1039/c6ob01668e	Magnesium salt promoted tandem nucleophilic addition-Oppenauer oxidation of aldehydes with organozinc reagents		Org. Biomol. Chem.	72	Fu, Y	FALSE	FALSE	FALSE	FALSE
3255	10.1021/acs.orglett.6b02549	doi.org/10.1021/acs.orglett.6b02549	Expedient Cobalt-Catalyzed C-H Alkynylation of (Enantiopure) Benzylamines		Org. Lett.	72	Balaraman, E	FALSE	FALSE	FALSE	FALSE
3256	10.1002/ejoc.201600772	doi.org/10.1002/ejoc.201600772	Remote C-H Selenylation of 8-Amidoquinolines via Copper-Catalyzed Radical Cross-Coupling		Eur. J. Org. Chem.	72	Baidya, M	FALSE	FALSE	FALSE	FALSE
3257	10.1021/acs.orglett.6b00547	doi.org/10.1021/acs.orglett.6b00547	Story of an Age-Old Reagent: An Electrophilic Chlorination of Arenes and Heterocycles by 1-Chloro-1,2-benziodoxol-3-one		Org. Lett.	72	Xue, D	FALSE	TRUE	FALSE	FALSE
3258	10.1016/j.tet.2016.02.047	doi.org/10.1016/j.tet.2016.02.047	Metal-free allylation of electron-rich heteroaryl boronic acids with allylic alcohols		Tetrahedron	72	Cheng, L	FALSE	FALSE	FALSE	FALSE
3259	10.1002/adsc.201501015	doi.org/10.1002/adsc.201501015	Copper(II) Triflate-Catalyzed Aerobic Oxidative C-H Functionalization of Glycine Derivatives with Olefins and Organoboranes		Adv. Synth. Catal.	72	Liu, L	FALSE	FALSE	FALSE	FALSE
3260	10.1002/chem.201505214	doi.org/10.1002/chem.201505214	Iron-Catalyzed Allylic Amination Directly from Allylic Alcohols		Chem.-Eur. J.	72	Sundararaju, B	FALSE	FALSE	FALSE	FALSE
3261	10.1002/anie.201510638	doi.org/10.1002/anie.201510638	Practical Direct alpha-Arylation of Cyclopentanones by Palladium/Enamine Cooperative Catalysis		Angew. Chem.-Int. Edit.	72	Dong, GB	FALSE	FALSE	FALSE	FALSE
3262	10.1039/c6ob00193a	doi.org/10.1039/c6ob00193a	Catalytic selective deuteration of halo(hetero) arenes		Org. Biomol. Chem.	72	Peruncheralathan, S	FALSE	FALSE	FALSE	FALSE
3263	10.1021/acs.orglett.1c00488	doi.org/10.1021/acs.orglett.1c00488	Regio- and Trans-Selective Ni-Catalyzed Coupling of Butadiene, Carbonyls, and Arylboronic Acids to Homoallylic Alcohols under Base-Free Conditions	A catalytic asymmetric decarboxylative [4+2] cycloaddition of vinyl benzoxazinanones with methyleneindolinones has been established, which provided a series of chiral tetrahydroquinoline-based 3,3'-spirooxindoles in high yields (up to 96%) and with excellent diastereo- and enantioselectivities (all >95 : 5 d.r., up to 99% ee). This reaction not only represents the first example of catalytic enantioselective [4+2] cycloaddition between methyleneindolinones and Pd-containing 1,4-dipoles, but also demonstrates the great practicability of catalytic asymmetric decarboxylative cycloadditions in the synthesis of enantio-enriched polycyclic compounds.	Org. Lett.	71	Shi, SL	FALSE	FALSE	FALSE	FALSE
3264	10.1039/d0sc06529c	doi.org/10.1039/d0sc06529c	Iridium-promoted deoxyglycoside synthesis: stereoselectivity and mechanistic insight	Low-valent nickel is shown to preferentially isomerize mono-or disubstituted epoxides into their corresponding aldehydes. Experiments with tetrasubstituted epoxides demonstrate that these reactions proceed via reactive 2-nickelaoxetane intermediates, and that the oxidative addition step likely occurs with retention of configuration. The monosubstituted aldehyde isomerization products were found to rapidly react with HBpin to form boronate esters. These hydroboration reactions could be performed catalytically.	Chem. Sci.	71	Liu, XW	FALSE	FALSE	FALSE	FALSE
3265	10.1055/a-1389-1203	doi.org/10.1055/a-1389-1203	Functionalized Cyclopropanes as Versatile Intermediates for the Diversity-Oriented Synthesis of gamma-Lactones, gamma-Lactams and delta-Lactams	Recognizing the importance of all-carbon, quaternary stereocenters in complex molecule synthesis, a stereospecific, nickel-catalyzed cross-coupling of allylic pivalates with arylboroxines to deliver products equipped with quaternary stereocenters and internal alkenes was developed. The enantioenriched allylic pivalate starting materials are readily prepared, and a variety of functional groups can be incorporated on both the allylic pivalate and the arylboroxine. Additional advantages include the use of a commercially available and air-stable Ni(II) salt and BISBI ligand, mild reaction conditions, and high yields and ee's. The observed stereoinversion of this reaction is consistent with an open transition state in the oxidative addition step.	Synthesis	71	Sa, MM	FALSE	FALSE	FALSE	FALSE
3266	10.1055/a-1379-1584	doi.org/10.1055/a-1379-1584	Nickel-Catalyzed Ligand-Free Hiyama Coupling of Aryl Bromides and Vinyltrimethoxysilane	The construction of quaternary centers is a common challenge in the synthesis of complex materials and natural products. Current cross-coupling strategies that can be generalized for setting these centers are sparse and, when known, are typically predicated on the use of reactive organometallic reagents. To address this shortcoming a new, photoredox-Ni dual catalytic strategy for the cross-coupling of tertiary organoboron reagents with aryl halides is reported. In addition to details on the cross coupling scope and limitations, full screening efforts and mechanistic experiments are communicated.	Synlett	71	Mao, YJ; Shi, SL	FALSE	FALSE	FALSE	FALSE
3267	10.1002/aoc.6158	doi.org/10.1002/aoc.6158	Magnetic covalently immobilized nickel complex: A new and efficient method for the Suzuki cross-coupling reaction	A highly efficient kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylation has been realized for the first time. Under mild conditions, a variety of chiral 3-boryl-1,2,3,4-tetrahydroquinolines containing two vicinal stereogenic centers as well as the recovered 2-substituted 1,2-dihydroquinolines were afforded after 30 minutes in high yields with up to 99% ee (dr > 99 : 1) and over 98% ee values, respectively, corresponding to kinetic selectivity factors of up to 569. Moreover, this protocol was successfully applied to the asymmetric synthesis of a selective estrogen receptor modulator.	Appl. Organomet. Chem.	71	Shiri, A	FALSE	FALSE	FALSE	FALSE
3268	10.1002/anie.202010737	doi.org/10.1002/anie.202010737	Cross-Electrophile C(sp(2))-Si Coupling of Vinyl Chlorosilanes	We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C-N bond activation of an amine with an unactivated alkyl group. This reaction enjoys broad scope and functional group tolerance. Primary and secondary alkyl groups can be installed. Preliminary studies suggest a Ni-I/Ni-II catalytic cycle.	Angew. Chem.-Int. Edit.	71	Shu, XZ	FALSE	TRUE	FALSE	FALSE
3269	10.1038/s41467-020-19717-6	doi.org/10.1038/s41467-020-19717-6	Alkyl halides as both hydride and alkyl sources in catalytic regioselective reductive olefin hydroalkylation		Nat. Commun.	71	Yang, T; Koh, MJ	FALSE	FALSE	FALSE	FALSE
3270	10.1016/j.chempr.2020.09.004	doi.org/10.1016/j.chempr.2020.09.004	Compatibility Score for Rational Electrophile Selection in Pd/NBE Cooperative Catalysis	Enantioselective carbonyl-directable Heck reactions using aryldiazonium salts were developed with the aim to construct chiral quaternary spiro centers in an efficient manner. Five-and six-membered spirooxindoles, spirolactones, and spirolactams (36 examples) were obtained in good to excellent isolated yields with diastereoselectivities ranging from 13:1 to >20:1, and enantiomeric excesses up to 99% in short reaction times (1.0-1.5 h) under mild conditions (40 degrees C). A rationale for the diastereo- and enantioselectivity based on an unprecedented non-covalent carbonyl group directing effect is also presented, and supported by computational calculations.	Chem	71	Liu, P	FALSE	TRUE	FALSE	FALSE
3271	10.1055/s-0040-1707269	doi.org/10.1055/s-0040-1707269	Deoxygenative Transition-Metal-Promoted Reductive Coupling and Cross-Coupling of Alcohols and Epoxides	Organosilicon compounds act as a nucleophile upon activation by an appropriate base and behave in a manner similar to main-group organometallic reagents. In the last decades, structurally divergent organosilicon reagents are available and have become more employed for synthetic transformation with the aid of transition-metal complexes, because organosilicon compounds are in general superior to other organometallic compounds in view of stability, solubility, nontoxicity, and easy-handling. Particularly, cross-coupling of organosilicon reagents with organic halides or pseudohalides has been considered to be a useful tool for constructing the carbon frameworks of various target molecules such as pharmaceuticals and pi-conjugated functional materials. Perfluoroalkylsilicon compounds such as CF3SiEt3 have found use as reagents for the metal-catalyzed introduction of perfluoroalkyl groups into many substrates. In addition, functionalized organosilicon reagents are readily accessible by catalytic approach starting with appropriate hydrocarbons such as alkenes, alkynes, alkanes, and arenes. This article reviews recent advances in transition metal-catalyzed transformations of organosilicon reagents according to the type of synthetic transformation and metal catalyst.	Synthesis	71	Nicholas, KM	FALSE	FALSE	FALSE	FALSE
3272	10.1002/chem.202001374	doi.org/10.1002/chem.202001374	Palladium-Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion	A nickel-catalyzed cross-coupling reaction between methoxy-substituted carbazoles and MeMgBr has been developed. This protocol for the cleavage of the C(aryl)-OMe was used to efficiently assemble various methyl-substituted carbazoles and successfully applied to the total synthesis of the antitumor agent ellipticine.	Chem.-Eur. J.	71	Ogiwara, Y; Sakai, N	FALSE	FALSE	FALSE	FALSE
3273	10.1002/anie.202006586	doi.org/10.1002/anie.202006586	Palladium-Catalyzed Cross-Coupling of Alkenyl Carboxylates	The reaction of 1-(trifluoromethyl)alkenes (CF3CH=CHR) with arylboroxines (ArBO)(3) in the presence of a chiral diene-rhodium catalyst gave high yields of chiral 1,1-difluoroalkenes (CF2=CHC*HArR) with high enantioselectivity (>= 95% ee). The reaction is assumed to proceed through beta-fluoride elimination of a beta,beta,beta-trifluoroalkylrhodium intermediate that is generated by arylrhodation of the 1-(trifluoromethyl)alkene.	Angew. Chem.-Int. Edit.	71	Leitch, DC	FALSE	FALSE	FALSE	FALSE
3274	10.1002/ejoc.202000781	doi.org/10.1002/ejoc.202000781	Ruthenium Catalyzed Divergent Alkylation and Olefination of Methyl 1,3,5-Triazines with Alcohols	A C-C formation of an electron-rich N-hetero cycle with fluorinated alcohol is developed. Through this radical-triggered cross-dehydrogenatiye coupling strategy, a wide range of useful building blocks such as C3 hydroxyfluoroalkylated indoles and pyrroles can be site specifically synthesized. Mechanistic studies indicate a single-electron transfer initiated radical cycle would be involved.	Eur. J. Org. Chem.	71	Zhang, C; Cui, DM	FALSE	FALSE	FALSE	FALSE
3275	10.1021/jacs.0c05730	doi.org/10.1021/jacs.0c05730	Reductive Cross-Coupling between Unactivated C(aryl)-N and C(aryl)-O Bonds by Chromium Catalysis Using a Bipyridyl Ligand	Ni(II)-catalyzed ortho-arylation of aromatic and heteroaromatic carboxamides with triethoxy(aryl)silanes assisted by a removable bidentate auxiliary is reported. This transformation features a broad substrate scope, good functional group tolerance, and compatibility with heterocyclic substrates. Compared to the well-established Ni(II)-catalyzed C-H arylation with ArX or aryliodonium salts via oxidative addition, this reaction proceeded via a fluoride-promoted transmetalation.	J. Am. Chem. Soc.	71	Zeng, XM	FALSE	FALSE	FALSE	FALSE
3276	10.1080/00397911.2020.1794657	doi.org/10.1080/00397911.2020.1794657	A simple method for the synthesis of sulfonic esters	We have developed a stereospecific, nickel-catalyzed Miyaura borylation of allylic pivalates, which delivers highly enantioenriched alpha-stereogenic gamma-aryl allylboronates with good yields and regioselectivities. Our complementary sets of conditions enable access to either enantiomer of allylboronate product from a single enantiomer of readily prepared allylic pivalate substrate. Excellent functional group tolerance, yields, regioselectivities, and stereochemical fidelities are observed. The stereochemical switch from stereoretention to stereoinversion largely depends upon solvent and can be explained by competitive pathways for the oxidative addition step. Our mechanistic investigations support a stereoretentive pathway stemming from a directed oxidative addition and a stereoinvertive pathway that is dominant when MeCN blocks coordination of the directing group by binding the nickel catalyst.	Synth. Commun.	71	Bhatthula, BKG	FALSE	FALSE	FALSE	FALSE
3277	10.1002/ejoc.202000716	doi.org/10.1002/ejoc.202000716	Iridium-Catalyzed Carbenoid Insertion of Sulfoxonium Ylides for Synthesis of Quinoxalines and beta-Keto Thioethers in Water	Co(III)-catalyzed mild C-C couplings of arenes with strained rings such as 7-oxabenzonorbomadienes and 2-vinyloxirane have been realized. The transformation is proposed to undergo ortho C-H activation, olefin insertion, and subsequent beta-oxygen elimination. A broad range of synthetically useful functional groups are compatible, thus providing a new entry to access diversely 2-functionalized indoles.	Eur. J. Org. Chem.	71	Hai, L; Wu, Y	FALSE	FALSE	FALSE	FALSE
3278	10.1002/anie.202004177	doi.org/10.1002/anie.202004177	A Concise Total Synthesis of (+)-Waihoensene Guided by Quaternary Center Analysis	A copper-catalyzed chelation-controlled remote C-H halogenation of quinolines is developed. The reaction is scalable and proceeded with excellent C5-regioselectivity offering halogensubstituted 8-aminoquinolines in very high yields (up to 97%). The products were further utilized for various cross-coupling reactions en route to highly C5-functinonalized quinolines. As an application, synthesis of a bioactive compound having tumor- suppressor activity was accomplished.	Angew. Chem.-Int. Edit.	71	Snyder, SA	FALSE	FALSE	FALSE	FALSE
3279	10.1002/anie.202003359	doi.org/10.1002/anie.202003359	Light-Promoted Nickel Catalysis: Etherification of Aryl Electrophiles with Alcohols Catalyzed by a Ni-II-Aryl Complex	Manganese is found in the active center of numerous enzymes that operate by an outer-sphere homolytic C-H cleavage. Thus, a plethora of bioinspired radical-based C-H functionalizations by manganese catalysis have been devised during the past decades. In contrast, organometallic C-H activation by means of manganese catalysis has emerged only recently as an increasingly viable tool in organic synthesis. These manganese(I)-catalyzed processes enabled a variety of C-H functionalizations with ample scope, which very recently set the stage for substitutive C- H functionalizations. The versatile manganese catalysis largely operates by an isohypsic, thus redox-neutral, mode of action through chelation assistance, and provided step-economical access to structurally divers compounds of relevance to inter alia bioorganic, agrochemical, and medicinal chemistry as well as the material sciences.	Angew. Chem.-Int. Edit.	71	Xue, D	FALSE	TRUE	FALSE	FALSE
3280	10.1021/acscatal.0c01414	doi.org/10.1021/acscatal.0c01414	Expanding Ligand Space: Preparation, Characterization, and Synthetic Applications of Air-Stable, Odorless Di-tert-alkylphosphine Surrogates	We report a newly developed carbazoyl-derived P,N-type phosphine ligand (L1) for the monoarylation of acetone with aryl chlorides. The proposed Pd(dba)(2)/L1 catalyst exhibited remarkable catalytic reactivity toward highly electron rich and sterically congested aryl chlorides, with catalyst loading as low as 0.1 mol % of Pd along with excellent chemoselectivity. A reaction rate study of the system using electronically diverse aryl chlorides determined the mechanisms regarding the rate-limiting steps in this reaction. The oxidative addition adduct of Pd-PhenCar-Phos with p-chlorotoluene showed the participation of N-Pd coordination in the metal complex. The isolated palladium complex C1 could be utilized as a precatalyst in the transformation and achieved performance comparable to that of the in situ generated palladium species.	ACS Catal.	71	Ball, LT	FALSE	FALSE	FALSE	FALSE
3281	10.1021/acscatal.0c01174	doi.org/10.1021/acscatal.0c01174	Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis	A scandium-triflate-catalyzed arylative desulfonation of diarylmethyl phenyl sulfones with arenes and heteroarenes was established. A variety of both sulfone and arene substrates were reacted to afford symmetric and nonsymmetric triarylmethanes in good yields. Further transformations of the resulting triarylmethanes and application to the concise synthesis of a bactericidal agent analogue were also demonstrated.	ACS Catal.	71	Massad, I; Marek, I	FALSE	FALSE	FALSE	FALSE
3282	10.1021/acscatal.0c00394	doi.org/10.1021/acscatal.0c00394	Catalytic Conversion of N-Heteroaromatics to Functionalized Arylamines by Merging Hydrogen Transfer and Selective Coupling	Catalytic C-H borylation of arenes has been widely used in organic synthesis because it allows the introduction of a versatile boron functionality directly onto simple, unfunctionalized arenes. We report herein the use of diisopropylaminoborane as a boron source in C-H borylation of arenes. An iridium(I) complex with 1,3-dicyclohexylimidazol-2-ylidene is found to efficiently catalyze the borylation of arenes and heteroarenes. The resulting aminoborylated products can be converted to the corresponding boronic acid derivatives simply by treatment with suitable diols or diamines.	ACS Catal.	71	Zhang, M	FALSE	FALSE	FALSE	FALSE
3283	10.1002/asia.201901621	doi.org/10.1002/asia.201901621	Advances in Protecting Groups for Oligosaccharide Synthesis		Chem.-Asian J.	71	Kulkarni, SS	FALSE	FALSE	FALSE	FALSE
3284	10.1021/acscatal.9b03827	doi.org/10.1021/acscatal.9b03827	Reactivity of Transition-Metal Complexes in Excited States: C-O Bond Coupling Reductive Elimination of a Ni(II) Complex Is Elicited by the Metal-to-Ligand Charge Transfer State		ACS Catal.	71	Chen, H	FALSE	FALSE	FALSE	FALSE
3285	10.1021/acs.orglett.9b03517	doi.org/10.1021/acs.orglett.9b03517	Pd-Catalyzed Enantioselective Double Heck Reaction		Org. Lett.	71	Chen, SG; Kong, WQ	FALSE	FALSE	FALSE	FALSE
3286	10.1021/acscatal.9b04212	doi.org/10.1021/acscatal.9b04212	Pd-Catalyzed Alkenyl Thioether Synthesis from Thioesters and N-Tosylhydrazones		ACS Catal.	71	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
3287	10.1002/ejoc.201901472	doi.org/10.1002/ejoc.201901472	TBN-Catalyzed Dehydrative N-Alkylation of Anilines with 4-Hydroxybutan-2-one		Eur. J. Org. Chem.	71	Ren, LH; Song, WG	FALSE	FALSE	FALSE	FALSE
3288	10.1021/acs.orglett.9b02788	doi.org/10.1021/acs.orglett.9b02788	Ni-Catalyzed Reductive Arylacylation of Alkenes toward Carbonyl-Containing Oxindoles		Org. Lett.	71	Kong, WQ	FALSE	FALSE	FALSE	FALSE
3289	10.1039/c9cc05325e	doi.org/10.1039/c9cc05325e	Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides		Chem. Commun.	71	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
3290	10.1002/adsc.201900686	doi.org/10.1002/adsc.201900686	Catalytic Transfer Hydrodebenzylation with Low Palladium Loading		Adv. Synth. Catal.	71	Ananikov, VP	FALSE	FALSE	FALSE	FALSE
3291	10.1002/ajoc.201900299	doi.org/10.1002/ajoc.201900299	Synthesis of alpha-Quaternary Aldehydes via a Stereoselective Semi-Pinacol Rearrangement of Optically Active Epoxy Alcohols		Asian J. Org. Chem.	71	Sakamoto, R; Maruoka, K	FALSE	FALSE	FALSE	FALSE
3292	10.1021/acs.oprd.9b00226	doi.org/10.1021/acs.oprd.9b00226	A Convenient Preparation Method for Benzophenone Imine Catalyzed by Tetrabutylammonium Fluoride		Org. Process Res. Dev.	71	Morimoto, H; Ohshima, T	FALSE	FALSE	FALSE	FALSE
3293	10.1021/acs.joc.9b00669	doi.org/10.1021/acs.joc.9b00669	Exploration of Aryl Phosphates in Palladium-Catalyzed Mono-alpha-arylation of Aryl and Heteroaryl Ketones		J. Org. Chem.	71	So, CM	FALSE	FALSE	FALSE	FALSE
3294	10.1021/acs.jpca.9b00846	doi.org/10.1021/acs.jpca.9b00846	Theoretical Investigations into the Electron and Ambipolar Transport Properties of Anthracene-Based Derivatives		J. Phys. Chem. A	71	Ren, AM	FALSE	TRUE	FALSE	FALSE
3295	10.1039/c8sc05261a	doi.org/10.1039/c8sc05261a	Tandem Peterson olefination and chemoselective asymmetric hydrogenation of -hydroxy silanes		Chem. Sci.	71	Andersson, PG	FALSE	FALSE	FALSE	FALSE
3296	10.1021/acs.joc.8b02063	doi.org/10.1021/acs.joc.8b02063	Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution		J. Org. Chem.	71	Ji, HT	FALSE	FALSE	FALSE	FALSE
3297	10.1021/acs.oprd.8b00237	doi.org/10.1021/acs.oprd.8b00237	Evaluating the Impact of a Decade of Funding from the Green Chemistry Institute Pharmaceutical Roundtable		Org. Process Res. Dev.	71	Wells, AS	FALSE	FALSE	FALSE	FALSE
3298	10.1021/jacs.8b06966	doi.org/10.1021/jacs.8b06966	Carboiodination Catalyzed by Nickel		J. Am. Chem. Soc.	71	Lautens, M	FALSE	FALSE	FALSE	FALSE
3299	10.1021/acs.inorgchem.8b01565	doi.org/10.1021/acs.inorgchem.8b01565	Syntheses, Structures, and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition		Inorg. Chem.	71	Rose, MJ	FALSE	TRUE	FALSE	FALSE
3300	10.1021/acscatal.8b01863	doi.org/10.1021/acscatal.8b01863	Merging Photoredox and Copper Catalysis: Enantioselective Radical Cyanoalkylation of Styrenes		ACS Catal.	71	Mei, HB; Han, JL	TRUE	FALSE	FALSE	FALSE
3301	10.1002/adsc.201800333	doi.org/10.1002/adsc.201800333	Palladium (II)-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling: Direct Synthesis of meta-Substituted Biaryls from Aromatic Acids		Adv. Synth. Catal.	71	Shi, XY	FALSE	FALSE	FALSE	FALSE
3302	10.1021/acs.orglett.8b00053	doi.org/10.1021/acs.orglett.8b00053	Unmasking Dipole Character of Acyl Ketene Dithioacetals via a Cascade Reaction with Arynes: Synthesis of Benzo[b]thiophenes		Org. Lett.	71	Singh, A	FALSE	FALSE	FALSE	FALSE
3303	10.1080/00397911.2018.1431280	doi.org/10.1080/00397911.2018.1431280	Facial strategy for radical species through Ag(I)-mediated oxidation of the alkyl trifluoroborates		Synth. Commun.	71	Miao, ZC	FALSE	FALSE	FALSE	FALSE
3304	10.1002/anie.201709411	doi.org/10.1002/anie.201709411	Enantioselective Copper-Catalyzed Alkylation of Quinoline N-Oxides with Vinylarenes		Angew. Chem.-Int. Edit.	71	Ge, SZ	FALSE	FALSE	FALSE	FALSE
3305	10.1002/anie.201706236	doi.org/10.1002/anie.201706236	Efficient Access to All-Carbon Quaternary and Tertiary alpha-Functionalized Homoallyl-type Aldehydes from Ketones		Angew. Chem.-Int. Edit.	71	Pace, V	FALSE	FALSE	FALSE	FALSE
3306	10.1039/c6qo00149a	doi.org/10.1039/c6qo00149a	Nickel(II)-catalyzed direct arylation of aryl C-H bonds with aryl-boron reagents directed by a removable bidentate auxiliary		Org. Chem. Front.	71	Shi, BF	FALSE	FALSE	FALSE	FALSE
3307	10.1080/00958972.2016.1186800	doi.org/10.1080/00958972.2016.1186800	Syntheses, characterization, and antimicrobial properties of nickel(II) dithiocarbamate complexes containing NiS4 and NiS2PN moieties		J. Coord. Chem.	71	Onwudiwe, DC	FALSE	FALSE	FALSE	FALSE
3308	10.1039/c5dt04973c	doi.org/10.1039/c5dt04973c	Mechanism of iridium-catalysed branched-selective hydroarylation of vinyl ethers: a computational study		Dalton Trans.	71	Huang, GP	FALSE	FALSE	FALSE	FALSE
3309	10.1039/c5ra27859g	doi.org/10.1039/c5ra27859g	Computational study on alkenyl/aryl C(sp(2))-O homolytic cleavage of carboxylates and carbamates		RSC Adv.	71	Zheng, WR	FALSE	FALSE	FALSE	FALSE
3310	10.1021/jacs.5b08621	doi.org/10.1021/jacs.5b08621	Regio- and Chemoselective Kumada Tamao Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium Under Mild Conditions		J. Am. Chem. Soc.	71	Zeng, XM	FALSE	FALSE	FALSE	FALSE
3311	10.1021/jacs.5b08448	doi.org/10.1021/jacs.5b08448	Deoxygenative C-C Bond-Forming Processes via a Net Four-Electron Reductive Coupling		J. Am. Chem. Soc.	71	Montgomery, J	FALSE	TRUE	FALSE	FALSE
3312	10.1002/anie.201502942	doi.org/10.1002/anie.201502942	C-H Activation Generates Period-Shortening Molecules That Target Cryptochrome in the Mammalian Circadian Clock		Angew. Chem.-Int. Edit.	71	Irle, S	FALSE	FALSE	FALSE	FALSE
3313	10.1039/c5qo00093a	doi.org/10.1039/c5qo00093a	Conditions for palladium-catalyzed direct arylations of 4-bromo and 4-iodo N-substituted pyrazoles without C-Br or C-I bond cleavage		Org. Chem. Front.	71	Brahim, M	FALSE	FALSE	FALSE	FALSE
3314	10.1039/c5cc01436k	doi.org/10.1039/c5cc01436k	Nickel-catalyzed direct thiolation of unactivated C(sp(3))-H bonds with disulfides		Chem. Commun.	71	Shi, BF	FALSE	FALSE	FALSE	FALSE
3315	10.1002/chem.201405296	doi.org/10.1002/chem.201405296	Expedient Synthesis of Chiral alpha-Amino Acids through Nickel-Catalyzed Reductive Cross-Coupling		Chem.-Eur. J.	71	Xiao, B	FALSE	FALSE	FALSE	FALSE
3316	10.1021/jo5022234	doi.org/10.1021/jo5022234	Palladium- and Nickel-Catalyzed Kumada Cross-Coupling Reactions of gem-Difluoroalkenes and Monofluoroalkenes with Grignard Reagents		J. Org. Chem.	71	Wu, JJ	FALSE	FALSE	FALSE	FALSE
3317	10.1021/jo500675a	doi.org/10.1021/jo500675a	Suzuki-Miyaura Coupling of Halophenols and Phenol Boronic Acids: Systematic Investigation of Positional Isomer Effects and Conclusions for the Synthesis of Phytoalexins from Pyrinae		J. Org. Chem.	71	Schmidt, B	FALSE	FALSE	FALSE	FALSE
3318	10.1515/pac-2014-5032	doi.org/10.1515/pac-2014-5032	Pd-catalyzed reactions of unactivated C-sp3-I bonds		Pure Appl. Chem.	71	Jiang, XF	FALSE	FALSE	FALSE	FALSE
3319	10.1039/c3dt52985a	doi.org/10.1039/c3dt52985a	C-Cl bond activation and catalytic hydrodechlorination of hexachlorobenzene by cobalt and nickel complexes with sodium formate as a reducing agent		Dalton Trans.	71	Hu, QP	FALSE	FALSE	FALSE	FALSE
3320	10.1021/jp409794a	doi.org/10.1021/jp409794a	Novel Supramolecular Thixotropic Metallohydrogels Consisting of Rare Metal-Organic Nanoparticles: Synthesis, Characterization, and Mechanism of Aggregation		J. Phys. Chem. C	71	Tu, T	FALSE	FALSE	FALSE	FALSE
3321	10.1021/ja400325w	doi.org/10.1021/ja400325w	Isomerization of Terminal Epoxides by a [Pd-H] Catalyst: A Combined Experimental and Theoretical Mechanistic Study		J. Am. Chem. Soc.	71	Mazet, C	FALSE	FALSE	FALSE	FALSE
3322	10.1055/s-0032-1318331	doi.org/10.1055/s-0032-1318331	A Simple and Efficient Microwave-Assisted Synthesis of Substituted Isoindolinone Derivatives via Ligand-Free Pd-Catalyzed Domino C-C/C-N Coupling Reaction		Synlett	71	Chauhan, PMS	FALSE	FALSE	FALSE	FALSE
3323	10.1021/jp3045498	doi.org/10.1021/jp3045498	Density Functional Theory Study of the Mechanisms of Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents		J. Phys. Chem. A	71	Ren, QH	FALSE	FALSE	FALSE	FALSE
3324	10.1021/ja3116718	doi.org/10.1021/ja3116718	Simplifying Nickel(0) Catalysis: An Air-Stable Nickel Precatalyst for the Internally Selective Benzylation of Terminal Alkenes		J. Am. Chem. Soc.	71	Jamison, TF	FALSE	FALSE	FALSE	FALSE
3325	10.1002/pola.26320	doi.org/10.1002/pola.26320	A Novel Poly(p-phenylene) Containing Alternating Poly(perfluorooctylethyl acrylate-co-methyl methacrylate) and Polystyrene Grafts by Combination of Atom Transfer Radical Polymerization and Suzuki Coupling Processes		J. Polym. Sci. Pol. Chem.	71	Yagci, Y	FALSE	FALSE	FALSE	FALSE
3326	10.1021/jo302086g	doi.org/10.1021/jo302086g	Selective Cross-Coupling of Organic Halides with Allylic Acetates		J. Org. Chem.	71	Weix, DJ	FALSE	FALSE	FALSE	FALSE
3327	10.1002/chem.201201267	doi.org/10.1002/chem.201201267	Origin of Selectivity of Tsuji-Trost Allylic Alkylation of Lactones: Highly Ordered Transition States with Lithium-Containing Enolates		Chem.-Eur. J.	71	Thiel, W	FALSE	FALSE	FALSE	FALSE
3328	10.1039/c2ob06821d	doi.org/10.1039/c2ob06821d	A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite		Org. Biomol. Chem.	71	Zhang, SL	FALSE	FALSE	FALSE	FALSE
3329	10.1002/chem.201103304	doi.org/10.1002/chem.201103304	Gold(I)-Catalyzed Stereoselective Synthesis of Alkenyl Phosphates by Hydrophosphoryloxylation		Chem.-Eur. J.	71	Nolan, SP	FALSE	FALSE	FALSE	FALSE
3330	10.1021/jo202037x	doi.org/10.1021/jo202037x	Ni(COD)(2)/PCy3 Catalyzed Cross-Coupling of Aryl and Heteroaryl Neopentylglycolboronates with Aryl and Heteroaryl Mesylates and Sulfamates in THF at Room Temperature		J. Org. Chem.	71	Percec, V	FALSE	FALSE	FALSE	FALSE
3331	10.1016/j.ica.2011.08.005	doi.org/10.1016/j.ica.2011.08.005	Mixed-ligand thiosemicarbazone complexes of nickel: Synthesis, structure and catalytic activity		Inorg. Chim. Acta	71	Bhattacharya, S	FALSE	FALSE	FALSE	FALSE
3332	10.1016/j.jorganchem.2011.07.047	doi.org/10.1016/j.jorganchem.2011.07.047	Microwave synthesis of bis(tetrazolato)-Pd-II complexes with PPh3 and water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA). The first example of C-CN bond cleavage of propionitrile by a Pd-II Centre		J. Organomet. Chem.	71	Lasri, J	FALSE	FALSE	FALSE	FALSE
3333	10.1021/om2003706	doi.org/10.1021/om2003706	Hydrodehalogenation of Aryl Chlorides and Aryl Bromides Using a Microwave-Assisted, Copper-Catalyzed Concurrent Tandem Catalysis Methodology		Organometallics	71	Lin, S	FALSE	FALSE	FALSE	FALSE
3334	10.1021/om200090d	doi.org/10.1021/om200090d	N-Heterocyclic Carbene Bound Nickel(1) Complexes and Their Roles in Catalysis		Organometallics	71	Louie, J	FALSE	FALSE	FALSE	FALSE
3335	10.1002/ejic.201100007	doi.org/10.1002/ejic.201100007	The Relationship between the Electrochemical and Chemical Oxidation of Ferrocene-Containing Carbonyl-Phosphane-beta-Diketonato-Rhodium(I) Complexes - Cytotoxicity of [Rh(FcCOCHCOPh)(CO)(PPh3)]		Eur. J. Inorg. Chem.	71	Swarts, JC	FALSE	TRUE	FALSE	FALSE
3336	10.1002/asia.201000601	doi.org/10.1002/asia.201000601	Nickel(0) Complexes with Fluorinated Alkyne Ligands and their Reactivity towards Semihydrogenation and Hydrodefluorination with Water		Chem.-Asian J.	71	Garcia, JJ	FALSE	FALSE	FALSE	FALSE
3337	10.1021/ja100783c	doi.org/10.1021/ja100783c	Palladium-Catalyzed Ortho-Arylation of O-Phenylcarbamates with Simple Arenes and Sodium Persulfate		J. Am. Chem. Soc.	71	Dong, VM	FALSE	FALSE	FALSE	FALSE
3338	10.1021/jo902185c	doi.org/10.1021/jo902185c	Chelation-Assisted Palladium-Catalyzed Cascade Bromination/Cyanation Reaction of 2-Arylpyridine and 1-Arylpyrazole C-H Bonds		J. Org. Chem.	71	Cheng, J	FALSE	FALSE	FALSE	FALSE
3339	10.1021/jm8001795	doi.org/10.1021/jm8001795	Synthesis and evaluation of estrogen agonism of diaryl 4,5-dihydroisoxazoles, 3-hydroxyketones, 3-methoxyketones, and 1,3-diketones: A compound set forming a 4D molecular library		J. Med. Chem.	71	Pulkkinen, JT	FALSE	FALSE	FALSE	FALSE
3340	10.1016/j.tetlet.2008.03.096	doi.org/10.1016/j.tetlet.2008.03.096	Highly efficient and economic synthesis of new substituted amino-bispyridyl derivatives via copper and palladium catalysis		Tetrahedron Lett.	71	Fischmeister, C	FALSE	FALSE	FALSE	FALSE
3341	10.1021/jo991196s	doi.org/10.1021/jo991196s	The fluorine atom as a cation-stabilizing auxiliary in biomimetic polyene cyclizations: Total synthesis of dl-dammarenediol		J. Org. Chem.	71	Bartlett, WR	FALSE	FALSE	FALSE	FALSE
3342	10.5059/yukigoseikyokaishi.52.900	doi.org/10.5059/yukigoseikyokaishi.52.900	MOP - A MONODENTATE CHIRAL PHOSPHINE LIGAND FOR CATALYTIC ASYMMETRIC REACTIONS		J. Synth. Org. Chem. Jpn.	71	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
3343	10.1039/d1sc06422c	doi.org/10.1039/d1sc06422c	Synergistic Bronsted/Lewis acid catalyzed aromatic alkylation with unactivated tertiary alcohols or di-tert-butylperoxide to synthesize quaternary carbon centers		Chem. Sci.	71	Gottemann, L; Kou, KGM	FALSE	FALSE	FALSE	FALSE
3344	10.1002/ejic.202100870	doi.org/10.1002/ejic.202100870	Pincer-Type Mesoionic Carbene Nickel(II) Complexes: Synthesis, Properties, Reactions, and Catalytic Application to the Suzuki-Miyaura Coupling Reaction of Aryl Bromides		Eur. J. Inorg. Chem.	71	Matsubara, K	FALSE	FALSE	FALSE	FALSE
3345	10.1016/j.tet.2021.132526	doi.org/10.1016/j.tet.2021.132526	Reductive N-alkylation of primary amides using nickel-nanoparticles		Tetrahedron	71	Jagadeesh, RV	FALSE	FALSE	FALSE	FALSE
3346	10.1016/j.mcat.2021.111987	doi.org/10.1016/j.mcat.2021.111987	Visible light-driven direct synthesis of ketones from aldehydes via C-H bond activation using NiCu nanoparticles adorned on carbon nano onions		Mol. Catal.	71	Heydari, A	FALSE	FALSE	FALSE	FALSE
3347	10.1016/j.tet.2021.132451	doi.org/10.1016/j.tet.2021.132451	Switching between borrowing hydrogen and acceptorless dehydrogenative coupling by base transition-metal catalysts		Tetrahedron	71	Ding, KY	FALSE	FALSE	FALSE	FALSE
3348	10.1002/anie.202107356	doi.org/10.1002/anie.202107356	N-Atom Deletion in Nitrogen Heterocycles		Angew. Chem.-Int. Edit.	71	Lu, HJ	FALSE	FALSE	FALSE	FALSE
3349	10.1021/acscatal.1c02956	doi.org/10.1021/acscatal.1c02956	Enhanced Hydride Donation Achieved Molybdenum Catalyzed Direct N-Alkylation of Anilines or Nitroarenes with Alcohols: From Computational Design to Experiment		ACS Catal.	71	Ke, ZF	FALSE	FALSE	FALSE	FALSE
3350	10.1055/a-1523-3228	doi.org/10.1055/a-1523-3228	Nickel-Catalyzed Regiodivergent Reductive Hydroarylation of Styrenes		Synlett	71	He, YL; Zhu, SL	FALSE	FALSE	FALSE	FALSE
3351	10.1021/jacs.1c03459	doi.org/10.1021/jacs.1c03459	Site-Selective C-H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence		J. Am. Chem. Soc.	71	Ritter, T	FALSE	FALSE	FALSE	FALSE
3352	10.1039/d0qo01589j	doi.org/10.1039/d0qo01589j	Lithium-bromine exchange reaction on C-60: first theoretical proposal of a stable singlet fullerene carbene without the heteroatom		Org. Chem. Front.	71	Zhao, X	FALSE	FALSE	FALSE	FALSE
3353	10.1021/jacs.1c00618	doi.org/10.1021/jacs.1c00618	Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis		J. Am. Chem. Soc.	71	Zuo, ZW	TRUE	FALSE	FALSE	FALSE
3354	10.1021/acsomega.7b01165	doi.org/10.1021/acsomega.7b01165	Palladium-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylic Acids with Aryl Tosylates		ACS Omega	71	Lee, S	FALSE	FALSE	FALSE	FALSE
3355	10.1021/acs.orglett.7b01486	doi.org/10.1021/acs.orglett.7b01486	Asymmetric Syntheses of Amaryllidaceae Alkaloids (-)-Crinane and (+)-4a-Dehydroxycrinamabine		Org. Lett.	71	Wang, YQ	FALSE	FALSE	FALSE	FALSE
3356	10.1039/c7cc03037a	doi.org/10.1039/c7cc03037a	A cascade Claisen rearrangement/o-quinone methide formation/electrocyclization approach to 2H-chromenes		Chem. Commun.	71	Song, LY	FALSE	FALSE	FALSE	FALSE
3357	10.1002/anie.201611720	doi.org/10.1002/anie.201611720	Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage		Angew. Chem.-Int. Edit.	71	Martin, R	FALSE	FALSE	FALSE	FALSE
3358	10.1002/anie.201609930	doi.org/10.1002/anie.201609930	Stereospecific Palladium-Catalyzed Acylation of Enantioenriched Alkylcarbastannatranes: A General Alternative to Asymmetric Enolate Reactions		Angew. Chem.-Int. Edit.	71	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
3359	10.1021/jacs.6b11610	doi.org/10.1021/jacs.6b11610	Palladium-Catalyzed Asymmetric alpha-Arylation of Alkylnitriles		J. Am. Chem. Soc.	71	Zhou, JR	FALSE	FALSE	FALSE	FALSE
3360	10.1002/ejoc.201601024	doi.org/10.1002/ejoc.201601024	Bimetallic Cu-Mn-Catalyzed Synthesis of 2-Arylquinazolin-4(3H)-ones: Aqueous Ammonia as Source of a Ring Nitrogen Atom		Eur. J. Org. Chem.	71	Bharate, SB	FALSE	FALSE	FALSE	FALSE
3361	10.1016/j.tet.2016.08.058	doi.org/10.1016/j.tet.2016.08.058	CoPc/Cu(OAc)(2)-catalyzed N-arylation of amines with arylhydrazines leading to N-aryl amines		Tetrahedron	71	Zou, JP	FALSE	FALSE	FALSE	FALSE
3362	10.1021/acs.orglett.6b02265	doi.org/10.1021/acs.orglett.6b02265	Cyanation of Phenol Derivatives with Aminoacetonitriles by Nickel Catalysis		Org. Lett.	71	Itami, K	FALSE	FALSE	FALSE	FALSE
3363	10.1021/jacs.6b06285	doi.org/10.1021/jacs.6b06285	Transition-Metal-Free Stereospecific Cross-Coupling with Alkenylboronic Acids as Nucleophiles		J. Am. Chem. Soc.	71	Tang, WJ	FALSE	FALSE	FALSE	FALSE
3364	10.1039/c6cc05330k	doi.org/10.1039/c6cc05330k	Cobalt-catalyzed chelation assisted C-H allylation of aromatic amides with unactivated olefins		Chem. Commun.	71	Chatani, N	FALSE	FALSE	FALSE	FALSE
3365	10.1002/chem.201602150	doi.org/10.1002/chem.201602150	Coupling Reaction of Enol Derivatives with Silyl Ketene Acetals Catalyzed by Gallium Trihalides		Chem.-Eur. J.	71	Nishimoto, Y	FALSE	FALSE	FALSE	FALSE
3366	10.1021/acs.orglett.6b01745	doi.org/10.1021/acs.orglett.6b01745	Chemo- and Regioselective Functionalization of Polyols through Catalytic C(sp(3))-C(sp(3)) Kumada-Type Coupling of Cyclic Sulfate Esters		Org. Lett.	71	Morandi, B	FALSE	FALSE	FALSE	FALSE
3367	10.1021/jacs.6b03855	doi.org/10.1021/jacs.6b03855	Direct Hydroxylation and Amination of Arenes via Deprotonative Cupration		J. Am. Chem. Soc.	71	Hirano, K; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
3368	10.1002/adsc.201500743	doi.org/10.1002/adsc.201500743	The Barbier-Grignard-Type Arylation of Ketones and Unexpected Cross-Coupling of Phenolic Ketones using Unactivated Aryl Bromides		Adv. Synth. Catal.	71	Tang, Y; Zhang, YM	FALSE	FALSE	FALSE	FALSE
3369	10.1021/acscatal.5b02524	doi.org/10.1021/acscatal.5b02524	Copper-Catalyzed Boron-Selective C(sp(2))-C(sp(3)) Oxidative Cross-Coupling of Arylboronic Acids and Alkyltrifluoroborates Involving a Single-Electron Transmetalation Process		ACS Catal.	71	Li, PF	FALSE	TRUE	FALSE	FALSE
3370	10.1039/c6ra12557c	doi.org/10.1039/c6ra12557c	Aryl diazonium salt and thioacetamide: a catalyst free, efficient blend of an inexpensive arylating agent with S surrogate for sulphide synthesis		RSC Adv.	71	Nagarkar, JM	FALSE	FALSE	FALSE	FALSE
3371	10.1039/c6qo00011h	doi.org/10.1039/c6qo00011h	Low-valent cobalt-catalyzed C-H allylation		Org. Chem. Front.	71	Zeng, XM	FALSE	FALSE	FALSE	FALSE
3372	10.1038/s41467-020-20888-5	doi.org/10.1038/s41467-020-20888-5	NiH-catalyzed asymmetric hydroarylation of N-acyl enamines to chiral benzylamines	The Pd-catalyzed desulfonative cross-coupling reaction of benzylic sulfone derivatives with 1,3-oxazoles via a deprotonative pathway has been developed. Broad substrate scope for both sulfone and 1,3-oxazole partners is observed, affording a variety of 1,3-oxazole-containing triarylmethanes. Sulfone partners that are primary benzylic, secondary benzylic, and benzhydryl are all effective. Using this method, the straightforward synthesis of multiply arylated structures has been demonstrated.	Nat. Commun.	70	Zhu, SL	FALSE	FALSE	FALSE	FALSE
3373	10.1021/acs.orglett.0c03865	doi.org/10.1021/acs.orglett.0c03865	Palladium-Catalyzed Allyl-Allyl Reductive Coupling of Allylamines or Allylic Alcohols with H-2 as Sole Reductant	A switchable site-selective catalytic carboxylation of allylic alcohols has been developed in which CO2 is used with dual roles, both facilitating C-OH cleavage and as a C-1 source. This protocol is characterized by its mild reaction conditions, absence of stoichiometric amounts of organometallic reagents, broad scope, and exquisite regiodivergency which can be modulated by the type of ligand employed.	Org. Lett.	70	Huang, HM	FALSE	FALSE	FALSE	FALSE
3374	10.1021/acscatal.0c04199	doi.org/10.1021/acscatal.0c04199	FMPhos: Expanding the Catalytic Capacity of Small-Bite-Angle Bisphosphine Ligands in Regioselective Alkene Hydrofunctionalizations	A novel iridium-catalyzed ring-opening reaction of azabicyclic alkenes with a variety of fluoroalkylamines was developed. The reaction gave a series of fluorinated trans-1,2-diamine derivatives in good to excellent yields (up to 98%) under relatively mild conditions. The effects of various ligands, catalyst loading, solvents, and temperatures on the yield of the reaction were also investigated. This is the first time that fluorinated compounds were synthesized by incorporating a series of fluoroalkylamines into hydronaphthalene skeleton.	ACS Catal.	70	Dong, GB	FALSE	FALSE	FALSE	FALSE
3375	10.1039/d0ob01874k	doi.org/10.1039/d0ob01874k	Probing the versatility of metallo-electro hybrid catalysis: enabling access towards facile C-N bond formation	Copper-catalyzed regioselective C-H sulfonyloxylation of electron-rich arenes with p-toluenesulfonic acid has been developed. Electron-rich benzene derivatives and heteroarenes can undergo this C-H sulfonyloxylation reaction to generate aryl tosylates. Furthermore, sulfonyloxylation of aryl(mesityl)iodonium sulfonates has also been investigated. Both aryl(mesityl)iodonium tosylates and triflates can react smoothly to get aryl sulfonates. The formed aryl sulfonates can be converted to phenols, as well as used as good partners of cross-coupling reactions. [GRAPHICS]	Org. Biomol. Chem.	70	Roy, SR	FALSE	FALSE	FALSE	FALSE
3376	10.1016/j.saa.2020.118667	doi.org/10.1016/j.saa.2020.118667	Synthesis of novel xanthene based analogues: Their optical properties, jack bean urease inhibition and molecular modelling studies	Amides have been widely studied for decades, but their synthetic utility has remained limited in reactions that proceed with rupture of the amide C-N bond. Using Ni catalysis, we have found that amides can now be strategically employed in several important transformations: esterification, transamidation, Suzuki-Miyaura couplings, and Negishi couplings. These methodologies provide exciting new tools to build C-heteroatom and C-C bonds using an unconventional reactant (i.e., the amide), which is ideally suited for use in multi-step synthesis. It is expected that the area of amide C-N bond activation using nonprecious metals will continue to flourish and, in turn, will promote the growing use of amides as synthons in organic synthesis.	Spectroc. Acta Pt. A-Molec. Biomolec. Spectr.	70	Lee, KH	FALSE	FALSE	FALSE	FALSE
3377	10.1021/acs.orglett.0c02462	doi.org/10.1021/acs.orglett.0c02462	Palladium-Catalyzed Decarbonylative Heck Coupling of Aromatic Carboxylic Acids with Terminal Alkenes	This work emphasizes the synthesis of substituted vinyl arenes by reductive coupling of aryl halides with vinyl bromides under mild and easy-to-operate nickel-catalyzed reaction conditions. A broad range of aryl halides, including heteroaromatics, and vinyl bromides were employed to yielding products in moderate to excellent yields with high functional- group tolerance. The nickel-catalytic system displays good chemoselectivity between the two C(sp(2))-halide coupling partners, thus demonstrating a mechanistic pathway distinct from other stepwise protocols.	Org. Lett.	70	Chen, TQ	FALSE	FALSE	FALSE	FALSE
3378	10.1039/d0cc02697b	doi.org/10.1039/d0cc02697b	Nickel-catalyzed allyl-allyl coupling reactions between 1,3-dienes and allylboronates	A copper-catalyzed regioselective C-H selenylation of quinolines with readily available diaryl diselenides is developed based on a chelation-controlled radical cross-coupling strategy. The reaction is scalable, tolerates a wide spectrum of functional groups, and proceeds with excellent C5 regioselectivity to deliver selenoquinolines in high yields (up to 98 %). A single electron transfer (SET) mediated mechanism is proposed.	Chem. Commun.	70	Chen, QA	FALSE	FALSE	FALSE	FALSE
3379	10.1039/d0cc02851g	doi.org/10.1039/d0cc02851g	A directing group-assisted ruthenium-catalyzed approach to accessmeta-nitrated phenols	The nickel(I) complex [(eta(5)-Cp)Ni(IPr)] (Cp = cyclopentadienyl, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) reacts with phenyl isothiocyanate to afford the new heteronickelacycle [(IPr)NiSC(NPh)N(Ph)CS] (1), which contains the novel bidentate and dianionic ligand {SC(NPh)N(Ph)CS}(2-). Complex 1 is also obtained from the nickel(0) compound [(IPr)-Ni(styrene)(2)] with two equivalents of PhNCS. The gamma-lactam-nickelacycle [(IPr)NiN(Ph)C(O)CH2CH(Ph) (3) is formed from [(IPr)Ni(styrene)(2)] and one equivalent of phenyl isocyanate. Complex 3 is a rare example of a nickel(II) complex with a T-shaped structure. Compounds 1 and 3 were characterized by X-ray crystallography, H-1 and C-13 NMR spectroscopy, UV-vis spectroscopy, and elemental analysis.	Chem. Commun.	70	Lahiri, GK; Maiti, D	FALSE	FALSE	FALSE	FALSE
3380	10.1021/acs.orglett.0c01747	doi.org/10.1021/acs.orglett.0c01747	Reciprocal-Activation Strategy for Allylic Sulfination with Unactivated Allylic Alcohols	The first Negishi cross-coupling of amides for the synthesis of versatile diaryl ketones by selective C-N bond activation under exceedingly mild conditions is reported. The cross-coupling was accomplished with bench-stable, inexpensive precatalyst [Ni(PPh3)(2)Cl-2] that shows high functional-group tolerance and enables the synthesis of highly functionalized diaryl ketone motifs. The coupling occurred with excellent chemoselectivity favoring the ketone (cf. biaryl) products. Notably, this process represents the mildest conditions for amide N-C bond activation accomplished to date (room temperature, <10min). Considering the versatile role of polyfunctional biaryl ketone linchpins in modern organic synthesis, availability, and excellent functional-group tolerance of organozinc reagents, this strategy provides a new platform for amide N-C bond/organozinc cross-coupling under mild conditions.	Org. Lett.	70	Xie, PZ; Loh, TP	FALSE	FALSE	FALSE	FALSE
3381	10.1021/acs.orglett.0c01123	doi.org/10.1021/acs.orglett.0c01123	Tetraethylphosphorodiamidate-Directed Metalation Group: Directed Ortho and Remote Metalation, Cross Coupling, and Remote Phospha Anionic Fries Rearrangement Reactions	Iron-catalyzed allylic substitution of allylic ethers with Grignard reagents is reported. Phenoxy group is successfully applied as a leaving group in iron-catalyzed allylic substitution reactions with Grignard reagents. (C) 2016 Published by Elsevier Ltd.	Org. Lett.	70	Snieckus, V	FALSE	FALSE	FALSE	FALSE
3382	10.1021/acsomega.9b04450	doi.org/10.1021/acsomega.9b04450	Nickel(II) Nanoparticles Immobilized on EDTA-Modified Fe3O4@SiO2 Nanospheres as Efficient and Recyclable Catalysts for Ligand-Free Suzuki-Miyaura Coupling of Aryl Carbamates and Sulfamates	A Rh-III-catalyzed C-H allylation of electron-deficient arenes, heteroarenes, and alkenes at room temperature was developed with allyl bromide. The reaction was carried out in diethyl ether without dehydration, and C-H activation was assisted by the directing anionic nitrogen of the aniline-derived amide. Following the allylation, a domino cycling synthesis of 3,4-dihydroisoquinolin-1(2H)-ones with N-bromosuccinimide (NBS) through intramolecular aminobromination of the introduced double bond was achieved.	ACS Omega	70	Inaloo, ID	FALSE	FALSE	FALSE	FALSE
3383	10.1021/acs.orglett.0c00633	doi.org/10.1021/acs.orglett.0c00633	C-O Bond Silylation Catalyzed by Iron: A General Method for the Construction of Csp(2)-Si Bonds	A direct route to enantio- and diastereopure nitrogen-substituted phosphine oxides has been developed. The desired P-stereogenic compounds were obtained in good yields and high purity. The starting point of the synthesis was (+)-camphor, which is a readily available compound from the chiral pool. The new nitrogen-substituted phosphine oxides could be transformed from their pentavalent state to their trivalent form with N,O-bis(trimethylsilyl)acetamide, which makes them potential chiral ligands. It was possible to apply these compounds as chiral-solvating agents in chiral recognition experiments with a racemic alcohol and acid.	Org. Lett.	70	Feng, Z	FALSE	FALSE	FALSE	FALSE
3384	10.3390/molecules25071590	doi.org/10.3390/molecules25071590	A Simple Iron-Catalyst for Alkenylation of Ketones Using Primary Alcohols	We report the first example of a very general Cu-catalyzed cross-coupling of organoaluminum reagents with organohalides. The reactions proceed for the couplings of alkyl-, aryl-, and alkynylaluminum reagents with aryl and heteroaryl halides and vinyl bromides, affording the cross-coupled products in good to excellent yields. Both primary and secondary alkylaluminum reagents can be utilized as organometallic coupling partners. These reactions are not complicated by beta-hydride elimination, and as a result rearranged products are not observed with secondary alkylaluminum reagents even for couplings with heteroaryl halides under ligand-free conditions. Radical clock experiment with a radical probe and relative reactivity study of Ph3Al with two haloarenes, 1-bromonaphthalene and 4-chlorobenzonitrile, having two different redox potentials indicates that the reaction does not involve free aryl radicals and radical anions as intermediates. These results combined with the result of the Hammett plot obtained by reacting Ph(3)A1 with iodoarenes containing p-H, p-Me, p-F, and p-CF3 substituents, which shows a linear curve (R-2 = 0.99) with a p value of +1.06, suggest that the current transformation follows an oxidative addition reductive elimination pathway.	Molecules	70	Banerjee, D	FALSE	FALSE	FALSE	FALSE
3385	10.1039/c9cp06802c	doi.org/10.1039/c9cp06802c	Strategy used to synthesize high activity and low Pd catalyst for Suzuki coupling reaction: an experimental and theoretical investigation	Perovskite LaFeO3/montmorillonite nanocomposites (LaFeO3/MMT) have been successfully prepared via assembling LaFeO3 nanoparticles on the surface of montmorillonite with citric acid assisted sol-gel method. The results indicated that the uniform LaFeO3 nanoparticles were densely deposited onto the surface of montmorillonite, mainly ranging in diameter from 10 nm to 15 nm. The photocatalytic activity of LaFeO3/MMT was evaluated by the degradation of Rhodamine B (RhB) under visible light irradiation, indicating that LaFeO3/MMT exhibited remarkable adsorption efficiency and excellent photocatalytic activity with the overall removal rate of RhB up to 99.34% after visible light irradiation lasting for 90 min. The interface characteristic and possible degradation mechanism were explored. The interface characterization of LaFeO3/MMT suggested that LaFeO3 nanoparticles could be immobilized on the surface of montmorillonite with the Si-O-Fe bonds. The abundant hydroxyl groups of montmorillonite, semiconductor photocatalysis of LaFeO3 and Fenton-like reaction could enhance the photocatalytic degradation through a synergistic effect. Therefore, the LaFeO3/MMT is a very promising photocatalyst in future industrial application to treat effectively wastewater of dyes.	Phys. Chem. Chem. Phys.	70	Hu, JP	FALSE	FALSE	FALSE	FALSE
3386	10.1016/j.tet.2020.130968	doi.org/10.1016/j.tet.2020.130968	MnO2 mediated sequential oxidation/olefination of alkyl-substituted heteroarenes with alcohols	Pd-Catalyzed C(sp(3))-C(sp(2)) cross-coupling of Y(CH2SiMe3)(3)(THF)(2) with vinyl bromides and triflates has been developed for efficient synthesis of various allyltrimethylsilanes. The cross-coupling reaction was conducted at room temperature with low catalyst loading of either Pd(PPh3)(4) or Pd(PPh3)(2)Cl-2, and exhibited high efficiency and a broad substrate scope. In combination with the cross-coupling by the Lewis-acid catalyzed Hosomi-Sakurai reaction, a novel three-component one-pot cascade reaction was then accomplished to deliver homoallylic alcohols and ethers with high regioselectivity and diastereoselectivity. The three-component reaction defined the yttrium complex as a novel one-carbon synthon, which could either trigger bifunctionalization of alkenes or link two electrophiles and would find applications in organic synthesis.	Tetrahedron	70	Zhang, GY	FALSE	FALSE	FALSE	FALSE
3387	10.1055/s-0039-1690740	doi.org/10.1055/s-0039-1690740	Transition-Metal-Catalyzed Suzuki-Miyaura-Type Cross-Coupling Reactions of pi-Activated Alcohols	The incorporation of N-heterocyclic carbenes into the well-established pincer ligand platform entails a number of attractive benefits. For example, NHCs are strong donors, and the metal-carbene bond is often remarkably robust towards oxidative and hydrolytic conditions and thus sustains in air, moisture, and even highly acidic environments. Moreover, NHCs can be readily functionalized and modulated and thus provide excellent opportunities for fine-tuning the properties of a coordinated metal center. As a consequence, the combination of the concepts of pincer ligands and of NHCs has much appeal and continues to attract considerable interest. This chapter summarizes accomplishments over the last 5 years in the domain of pincer carbene complexes containing Group 8-10 metals, including synthetic aspects as well as application of these complexes, which has included in particular catalysis and to a lesser extent materials science and medicinal areas.	Synthesis	70	Samec, JSM	FALSE	FALSE	FALSE	FALSE
3388	10.1038/s41467-020-14799-8	doi.org/10.1038/s41467-020-14799-8	Organocatalytic asymmetric N-sulfonyl amide C-N bond activation to access axially chiral biaryl amino acids		Nat. Commun.	70	Fu, ZQ; Huang, W	FALSE	FALSE	FALSE	FALSE
3389	10.1007/s11426-019-9679-6	doi.org/10.1007/s11426-019-9679-6	Palladium-catalyzed regioselective cascade reaction of carbon dioxide, amines and allenes for the synthesis of functionalized carbamates		Sci. China-Chem.	70	Qi, CR; Jiang, HF	FALSE	FALSE	FALSE	FALSE
3390	10.1021/acs.organomet.9b00672	doi.org/10.1021/acs.organomet.9b00672	The Synthesis and Catalytic Activity of New Mixed NHC-Phosphite Nickel(0) Complexes		Organometallics	70	Dorta, R; Stewart, SG	FALSE	FALSE	FALSE	FALSE
3391	10.1021/acs.orglett.9b03633	doi.org/10.1021/acs.orglett.9b03633	Ni-Catalyzed Intermolecular Allylic Dearomatization Reaction of Tryptophols and Tryptamines		Org. Lett.	70	You, SL	FALSE	FALSE	FALSE	FALSE
3392	10.1002/anie.201912629	doi.org/10.1002/anie.201912629	Ligand-Controlled Regiodivergent Hydroalkylation of Pyrrolines		Angew. Chem.-Int. Edit.	70	Hu, XL	FALSE	FALSE	FALSE	FALSE
3393	10.1021/acs.organomet.9b00386	doi.org/10.1021/acs.organomet.9b00386	Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PCcarbeneS Pincer Ligand		Organometallics	70	Gessner, VH	FALSE	FALSE	FALSE	FALSE
3394	10.1055/s-0039-1690017	doi.org/10.1055/s-0039-1690017	Construction of Esters through Sulfuryl Fluoride (SO (2) F (2) ) Mediated Dehydrative Coupling of Carboxylic Acids with Alcohols at Room Temperature		Synthesis	70	Qin, HL	FALSE	FALSE	FALSE	FALSE
3395	10.3390/inorganics7100121	doi.org/10.3390/inorganics7100121	Successive Activation of C-H and C-O Bonds of Vinyl Ethers by a Diphosphine and Hydrido-Bridged Diiridium Complex		Inorganics	70	Fujita, K	FALSE	FALSE	FALSE	FALSE
3396	10.1038/s41467-019-11392-6	doi.org/10.1038/s41467-019-11392-6	Enantioselective benzylic C-H arylation via photoredox and nickel dual catalysis		Nat. Commun.	70	Lu, Z	FALSE	FALSE	FALSE	FALSE
3397	10.1021/acs.orglett.9b02130	doi.org/10.1021/acs.orglett.9b02130	Asymmetric Hydroarylation of Enones via Nickel-Catalyzed 5-Endo-Trig Cyclization		Org. Lett.	70	Zhou, JRS	FALSE	FALSE	FALSE	FALSE
3398	10.1021/jacs.9b03991	doi.org/10.1021/jacs.9b03991	Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies		J. Am. Chem. Soc.	70	Brown, MK	FALSE	FALSE	FALSE	FALSE
3399	10.1038/s41467-019-09783-w	doi.org/10.1038/s41467-019-09783-w	Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols		Nat. Commun.	70	Zhu, SL	FALSE	FALSE	FALSE	FALSE
3400	10.1039/c9dt00205g	doi.org/10.1039/c9dt00205g	Effects of the number of cyclometalated rings and ancillary ligands on the rate of MeI oxidative addition to platinum(ii)-pincer complexes		Dalton Trans.	70	Nabavizadeh, SM	FALSE	FALSE	FALSE	FALSE
3401	10.1038/s42004-019-0132-5	doi.org/10.1038/s42004-019-0132-5	Theoretical study of FMO adjusted C-H cleavage and oxidative addition in nickel catalysed C-H arylation		Comm. Chem.	70	Bai, RP; Lan, Y	FALSE	FALSE	FALSE	FALSE
3402	10.1002/anie.201811343	doi.org/10.1002/anie.201811343	Enantiospecific Synthesis of ortho-Substituted 1,1-Diarylalkanes by a 1,2-Metalate Rearrangement/anti-S(N)2 ' Elimination/Rearomatizing Allylic Suzuki-Miyaura Reaction Sequence		Angew. Chem.-Int. Edit.	70	Aggarwal, VK	FALSE	FALSE	FALSE	FALSE
3403	10.1016/j.poly.2018.11.004	doi.org/10.1016/j.poly.2018.11.004	An efficient protocol for the synthesis of thioethers via iron-catalyzed cross-coupling reaction and its mechanistic investigation		Polyhedron	70	Abi, TG	FALSE	FALSE	FALSE	FALSE
3404	10.1021/acscatal.8b02998	doi.org/10.1021/acscatal.8b02998	Manganese Catalyzed alpha-Alkylation of Nitriles with Primary Alcohols		ACS Catal.	70	Maji, B	FALSE	FALSE	FALSE	FALSE
3405	10.1055/s-0037-1610161	doi.org/10.1055/s-0037-1610161	A High-Throughput Approach to Discovery: Heck-Type Reactivity with Aldehydes		Synlett	70	Newman, SG	FALSE	FALSE	FALSE	FALSE
3406	10.1002/cctc.201800677	doi.org/10.1002/cctc.201800677	Molybdenum-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines		ChemCatChem	70	Madsen, R	FALSE	FALSE	FALSE	FALSE
3407	10.1021/acs.orglett.8b01772	doi.org/10.1021/acs.orglett.8b01772	Nickel-Catalyzed Intramolecular Arylcyanation for the Synthesis of 3,3-Disubstituted Oxindoles		Org. Lett.	70	Lautens, M	FALSE	FALSE	FALSE	FALSE
3408	10.1021/acs.joc.8b00160	doi.org/10.1021/acs.joc.8b00160	Esterification of Aryl and Alkyl Amides Enabled by Tailor-Made and Proposed Nickel Catalyst: Insights from Theoretical Investigation		J. Org. Chem.	70	Dang, L	FALSE	FALSE	FALSE	FALSE
3409	10.1038/s41467-018-03928-z	doi.org/10.1038/s41467-018-03928-z	Cross-coupling polycondensation via C-O or C-N bond cleavage		Nat. Commun.	70	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
3410	10.1021/acscatal.7b03432	doi.org/10.1021/acscatal.7b03432	Nickel-Catalyzed 1,2-Aminoarylation of Oxime Ester-Tethered Alkenes with Boronic Acids		ACS Catal.	70	Selander, N	FALSE	FALSE	FALSE	FALSE
3411	10.1039/c6ra15665g	doi.org/10.1039/c6ra15665g	A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions		RSC Adv.	70	Xu, LW	FALSE	FALSE	FALSE	FALSE
3412	10.1039/c6cc06048j	doi.org/10.1039/c6cc06048j	Efficient nickel-catalyzed phosphinylation of C-S bonds forming C-P bonds		Chem. Commun.	70	Chen, TQ; Yin, SF	FALSE	FALSE	FALSE	FALSE
3413	10.6023/cjoc201503007	doi.org/10.6023/cjoc201503007	Recent Advances of Transition Metal-Catalyzed C(sp(3))-C(sp(3)) Cross-Coupling Reactions of Non-activated Alkyl Halides		Chin. J. Org. Chem.	70		FALSE	FALSE	FALSE	FALSE
3414	10.1021/acs.orglett.5b00353	doi.org/10.1021/acs.orglett.5b00353	Rearrangement of Dypnones to 1,3,5-Triarylbenzenes		Org. Lett.	70	Li, HJ	FALSE	FALSE	FALSE	FALSE
3415	10.1021/ar500345f	doi.org/10.1021/ar500345f	Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations		Accounts Chem. Res.	70	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
3416	10.1039/c4ob01627k	doi.org/10.1039/c4ob01627k	Trifluoromethanesulfonyloxy-group-directed regioselective (3+2) cycloadditions of benzynes for the synthesis of functionalized benzo-fused heterocycles		Org. Biomol. Chem.	70	Ikawa, T	FALSE	FALSE	FALSE	FALSE
3417	10.1039/c5sc00505a	doi.org/10.1039/c5sc00505a	Palladium-catalyzed cross-coupling of alpha-bromocarbonyls and allylic alcohols for the synthesis of alpha-aryl dicarbonyl compounds		Chem. Sci.	70	Tambar, UK	FALSE	FALSE	FALSE	FALSE
3418	10.1021/ol500701n	doi.org/10.1021/ol500701n	Synthesis of Arylglycines from CO2 through alpha-Amino Organomanganese Species		Org. Lett.	70	Mita, T	FALSE	FALSE	FALSE	FALSE
3419	10.1021/jo402798k	doi.org/10.1021/jo402798k	Copper-Catalyzed Oxidative Coupling of Formamides with Salicylaldehydes: Synthesis of Carbamates in the Presence of a Sensitive Aldehyde Group		J. Org. Chem.	70	Wang, JJ	FALSE	FALSE	FALSE	FALSE
3420	10.1021/ol500258q	doi.org/10.1021/ol500258q	Using Rh(III)-Catalyzed C-H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules		Org. Lett.	70	Glorius, F	FALSE	FALSE	FALSE	FALSE
3421	10.1021/ja412107b	doi.org/10.1021/ja412107b	A Mild Ni/Cu-Catalyzed Silylation via C-O Cleavage		J. Am. Chem. Soc.	70	Martin, R	FALSE	FALSE	FALSE	FALSE
3422	10.1016/j.tetlet.2014.01.001	doi.org/10.1016/j.tetlet.2014.01.001	One-pot synthesis of aryl alkyl thioethers and diaryl disulfides using carbon disulfide as a sulfur surrogate in the presence of diethylamine catalyzed by copper(I) iodide in polyethylene glycol (PEG200)		Tetrahedron Lett.	70	Firouzabadi, H	FALSE	FALSE	FALSE	FALSE
3423	10.1002/adsc.201300485	doi.org/10.1002/adsc.201300485	Nickel-Catalyzed Coupling of Fluoroarenes and Amines		Adv. Synth. Catal.	70	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3424	10.1021/jo401936v	doi.org/10.1021/jo401936v	Ni-Catalyzed Reductive Homocoupling of Unactivated Alkyl Bromides at Room Temperature and Its Synthetic Application		J. Org. Chem.	70	Peng, Y	FALSE	FALSE	FALSE	FALSE
3425	10.1021/jo4007046	doi.org/10.1021/jo4007046	Transition-Metal-Free Arylations via Photogenerated Triplet 4-Alkyl- and 4-Trimethylsilylphenyl Cations		J. Org. Chem.	70	Protti, S	TRUE	FALSE	FALSE	FALSE
3426	10.1016/j.tet.2012.12.030	doi.org/10.1016/j.tet.2012.12.030	[Pd(PPh3)(2)(saccharinate)(2)]-general catalyst for Suzuki-Miyaura, Negishi cross-coupling and C-H bond functionalization of coumaryl and pyrone substrates		Tetrahedron	70	Kapdi, AR	FALSE	FALSE	FALSE	FALSE
3427	10.1002/anie.201209457	doi.org/10.1002/anie.201209457	Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols		Angew. Chem.-Int. Edit.	70	Stahl, SS	FALSE	FALSE	FALSE	FALSE
3428	10.1021/jo302088t	doi.org/10.1021/jo302088t	Synthesis of Aryl Thioethers through the N-Chlorosuccinimide-Promoted Cross-Coupling Reaction of Thiols with Grignard Reagents		J. Org. Chem.	70	Lee, CF	FALSE	FALSE	FALSE	FALSE
3429	10.1055/s-0032-1316738	doi.org/10.1055/s-0032-1316738	Challenges and Achievements in the Transition-Metal-Catalyzed Asymmetric alpha-Arylation of Aldehydes		Synlett	70	Mazet, C	FALSE	FALSE	FALSE	FALSE
3430	10.1002/ejoc.200900538	doi.org/10.1002/ejoc.200900538	A General and Efficient Suzuki-Miyaura Cross-Coupling Protocol Using Weak Base and No Water: The Essential Role of Acetate		Eur. J. Org. Chem.	70	Wang, B	FALSE	FALSE	FALSE	FALSE
3431	10.1021/ol702122d	doi.org/10.1021/ol702122d	Nickel(0) triethyl phosphite complex-catalyzed allylic substitution with retention of regio- and stereochemistry		Org. Lett.	70	Yatsumonji, Y	FALSE	FALSE	FALSE	FALSE
3432	10.1016/j.tetlet.2006.07.085	doi.org/10.1016/j.tetlet.2006.07.085	Rh(I)-catalyzed cross-coupling reactions of alkenyl tosylates with potassium aryltrifluoroborates		Tetrahedron Lett.	70	Wu, J	FALSE	FALSE	FALSE	FALSE
3433	10.1002/chem.200600173	doi.org/10.1002/chem.200600173	Pentamethylcyclopentadienyl-ruthenium catalysts for regio- and enantioselective allylation of nucleophiles		Chem.-Eur. J.	70	Bruneau, C	FALSE	FALSE	FALSE	FALSE
3434	10.1246/bcsj.77.347	doi.org/10.1246/bcsj.77.347	Hydroesterification of vinylarenes catalyzed by palladium complexes of dialkylmonoaryl- and monoalkyldiarylphosphines		Bull. Chem. Soc. Jpn.	70	Nozaki, K	FALSE	FALSE	FALSE	FALSE
3435	10.1021/jo0351318	doi.org/10.1021/jo0351318	Stereospecific Pd(0)-catalyzed arylation of an allylic hydroxy phosphonate derivative: Formal synthesis of (S)-(+)-ar-Turmerone		J. Org. Chem.	70	Spilling, CD	FALSE	FALSE	FALSE	FALSE
3436	10.3998/ark.5550190.0004.608	doi.org/10.3998/ark.5550190.0004.608	Facile and efficient oxidation of sulfides to sulfoxides in water using hypervalent iodine reagents		Arkivoc	70	Kita, Y	FALSE	FALSE	FALSE	FALSE
3437	10.1016/S0040-4020(01)86035-X	doi.org/10.1016/S0040-4020(01)86035-X	SYNTHESIS OF ALPHA-AMINO-ACIDS USING TRANSITION-METAL CATALYSIS-ALKYLATION OF SCHIFF-BASES DERIVED FROM ALPHA - AMINO-ACID ESTERS (REGIO, STEREO - SELECTIVITY		Tetrahedron	70	GENET, JP	FALSE	FALSE	FALSE	FALSE
3438	10.1002/chem.202200280	doi.org/10.1002/chem.202200280	Direct gem-Difluoroalkenylation of X-H Bonds with Trifluoromethyl Ketone N-Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem-Difluoroalkenes		Chem.-Eur. J.	70	Bi, XH	FALSE	FALSE	FALSE	FALSE
3439	10.1021/acscatal.1c05271	doi.org/10.1021/acscatal.1c05271	Catalytic Formal Conjugate Addition: Direct Synthesis of delta-Hydroxynitriles from Nitriles and Allylic Alcohols		ACS Catal.	70	Gunanathan, C	FALSE	FALSE	FALSE	FALSE
3440	10.1021/jacs.1c12654	doi.org/10.1021/jacs.1c12654	Empirical Guidelines for the Development of Remote Directing Templates through Quantitative and Experimental Analyses		J. Am. Chem. Soc.	70	Yu, JQ	FALSE	FALSE	FALSE	FALSE
3441	10.1002/ejoc.202101535	doi.org/10.1002/ejoc.202101535	Palladium-Catalyzed Benzylic Silylation of Diarylmethyl Carbonates with Silylboranes under Base-Free Conditions		Eur. J. Org. Chem.	70	Hirano, K	FALSE	FALSE	FALSE	FALSE
3442	10.1021/acsanm.1c03736	doi.org/10.1021/acsanm.1c03736	Metal-Organic Framework-Derived p-Type Cu3P/Hexagonal Boron Nitride Nanostructures for Photocatalytic Oxidative Coupling of Aryl Halides to Biphenyl Derivatives		ACS Appl. Nano Mater.	70	Majid, K	TRUE	FALSE	FALSE	FALSE
3443	10.1039/d1ra04572e	doi.org/10.1039/d1ra04572e	Effects of the halogenido ligands on the Kumada-coupling catalytic activity of [Ni{tBuN(PPh2)2-kappa 2P}X2], X = Cl, Br, I, complexes		RSC Adv.	70	Kyritsis, P	FALSE	FALSE	FALSE	FALSE
3444	10.1039/d1qo01153g	doi.org/10.1039/d1qo01153g	Mechanisms and origins of regioselectivities of nickel-catalyzed beta,delta-vinylarylation of alkenyl esters with vinyl triflates and arylzinc reagents		Org. Chem. Front.	70	Li, J	FALSE	FALSE	FALSE	FALSE
3445	10.1002/anie.202110785	doi.org/10.1002/anie.202110785	The Anionic Pathway in the Nickel-Catalysed Cross-Coupling of Aryl Ethers		Angew. Chem.-Int. Edit.	70	Borys, AM; Hevia, E	FALSE	FALSE	FALSE	FALSE
3446	10.1039/d1qo01219c	doi.org/10.1039/d1qo01219c	Nickel-catalyzed electrochemical reductive relay cross-coupling of alkyl halides with alkyl carboxylic acids		Org. Chem. Front.	70	Cheng, B	FALSE	FALSE	FALSE	FALSE
3447	10.1021/acs.accounts.1c00480	doi.org/10.1021/acs.accounts.1c00480	Nickel-Catalyzed Reductive Carboxylation and Amidation Reactions		Accounts Chem. Res.	70	Martin, R	FALSE	FALSE	FALSE	FALSE
3448	10.1038/s41467-021-25696-z	doi.org/10.1038/s41467-021-25696-z	gamma-Selective C(sp(3))-H amination via controlled migratory hydroamination		Nat. Commun.	70	Hong, S	FALSE	FALSE	FALSE	FALSE
3449	10.1002/ejoc.202100866	doi.org/10.1002/ejoc.202100866	Chroman-4-one-Based Amino Bidentate Ligand: An Efficient Ligand for Suzuki-Miyaura and Mizoroki-Heck Coupling Reactions in Aqueous Medium		Eur. J. Org. Chem.	70	Khan, D	FALSE	FALSE	FALSE	FALSE
3450	10.1038/s41467-021-25127-z	doi.org/10.1038/s41467-021-25127-z	Facile access to C-glycosyl amino acids and peptides via Ni-catalyzed reductive hydroglycosylation of alkynes		Nat. Commun.	70	Xu, P; Yu, BA	FALSE	FALSE	FALSE	FALSE
3451	10.1080/00397911.2021.1955931	doi.org/10.1080/00397911.2021.1955931	Based on C-O bond activation: Palladium catalysts in cross-coupling reactions		Synth. Commun.	70	Yu, H	FALSE	FALSE	FALSE	FALSE
3452	10.1021/acscatal.1c02088	doi.org/10.1021/acscatal.1c02088	Photoredox-Catalyzed Stereoselective Synthesis of C-Nucleoside Analogues from Glycosyl Bromides and Heteroarenes		ACS Catal.	70	Yu, SY	TRUE	FALSE	FALSE	FALSE
3453	10.1002/slct.202101388	doi.org/10.1002/slct.202101388	Metal-Free Synthesis of Diarylmethanes through Visible-Light Induced Radical Reactions with Arylamines		ChemistrySelect	70	Deng, C	FALSE	FALSE	FALSE	FALSE
3454	10.1002/ejoc.202100286	doi.org/10.1002/ejoc.202100286	Use of Isopropyl Alcohol as a Reductant for Catalytic Dehydoxylative Dimerization of Benzylic Alcohols Utilizing Ti-O Bond Photohomolysis		Eur. J. Org. Chem.	70	Iwasawa, N	TRUE	FALSE	FALSE	FALSE
3455	10.1021/acs.orglett.1c00892	doi.org/10.1021/acs.orglett.1c00892	Enantio- and Regioselective CuH-Catalyzed Conjugate Reduction of Yne-Allenones		Org. Lett.	70	Li, GG	FALSE	FALSE	FALSE	FALSE
3456	10.1039/d1ob00610j	doi.org/10.1039/d1ob00610j	Ni-Catalyzed radical cyclization of vinyl azides with cyclobutanone oxime esters to access cyanoalkyl containing quinoxalin-2(1H)-ones		Org. Biomol. Chem.	70	Zhou, NN	FALSE	FALSE	FALSE	FALSE
3457	10.1002/chem.202100390	doi.org/10.1002/chem.202100390	Synthesis of Spirocycles via Ni-Catalyzed Intramolecular Coupling of Thioesters and Olefins		Chem.-Eur. J.	70	Wei, H	FALSE	FALSE	FALSE	FALSE
3458	10.1021/acs.organomet.1c00018	doi.org/10.1021/acs.organomet.1c00018	Diaryl Ether Formation Merging Photoredox and Nickel Catalysis		Organometallics	70	Nevado, C	TRUE	FALSE	FALSE	FALSE
3459	10.1039/c7sc01204g	doi.org/10.1039/c7sc01204g	Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction		Chem. Sci.	70	Maiti, D	FALSE	FALSE	FALSE	FALSE
3460	10.1002/anie.201703029	doi.org/10.1002/anie.201703029	Enantioselective Propargylation of Polyols and Desymmetrization of meso 1,2-Diols by Copper/Borinic Acid Dual Catalysis		Angew. Chem.-Int. Edit.	70	Niu, DW	FALSE	FALSE	FALSE	FALSE
3461	10.1055/s-0036-1588734	doi.org/10.1055/s-0036-1588734	Fused Pyrrolo[2,3-d]pyrimidines (7-Deazapurines) by Palladium-Catalyzed Direct N-H and C-H Arylation Reactions		Synthesis	70	Dodonova, J	FALSE	FALSE	FALSE	FALSE
3462	10.6023/cjoc201612031	doi.org/10.6023/cjoc201612031	Applications of Transition Metal Catalyzed Coupling Reactions in the Synthesis of C-Glycosides		Chin. J. Org. Chem.	70	Sun, JS	FALSE	FALSE	FALSE	FALSE
3463	10.1002/anie.201702857	doi.org/10.1002/anie.201702857	Switchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2		Angew. Chem.-Int. Edit.	70	Martin, R	FALSE	FALSE	FALSE	FALSE
3464	10.1002/anie.201612385	doi.org/10.1002/anie.201612385	Enantioselective Palladium-Catalyzed Carbonylative Carbocyclization of Enallenes via Cross-Dehydrogenative Coupling with Terminal Alkynes: Efficient Construction of alpha-Chirality of Ketones		Angew. Chem.-Int. Edit.	70	Zhu, C; Backvall, JE	FALSE	FALSE	FALSE	FALSE
3465	10.1021/acs.joc.7b00010	doi.org/10.1021/acs.joc.7b00010	When Does Organic Chemistry Follow Nature's Lead and Make the Switch?		J. Org. Chem.	70	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
3466	10.1021/acscentsci.6b00283	doi.org/10.1021/acscentsci.6b00283	Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki-Miyaura Cross Coupling		ACS Central Sci.	70	Chirik, PJ	FALSE	FALSE	FALSE	FALSE
3467	10.1002/anie.201605162	doi.org/10.1002/anie.201605162	Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides		Angew. Chem.-Int. Edit.	70	Martin, R	FALSE	FALSE	FALSE	FALSE
3468	10.1016/j.ica.2016.06.023	doi.org/10.1016/j.ica.2016.06.023	Synthesis, characterization and catalytic activity of gold complexes with pyridine-based selone ligands		Inorg. Chim. Acta	70	Jia, WG	FALSE	FALSE	FALSE	FALSE
3469	10.1002/anie.201510793	doi.org/10.1002/anie.201510793	Desilylation-Activated Propargylic Transformation: Enantioselective Copper-Catalyzed [3+2] Cycloaddition of Propargylic Esters with -Naphthol or Phenol Derivatives		Angew. Chem.-Int. Edit.	70	Hu, XP	FALSE	FALSE	FALSE	FALSE
3470	10.1039/c5ob02094h	doi.org/10.1039/c5ob02094h	Direct synthesis of C-glycosides from unprotected 2-N-acyl-aldohexoses via aldol condensation-oxa-Michael reactions with unactivated ketones		Org. Biomol. Chem.	70	Tanaka, F	FALSE	FALSE	FALSE	FALSE
3471	10.1007/s11426-020-9930-7	doi.org/10.1007/s11426-020-9930-7	Stereodivergent synthesis of C-glycosamino acids via Pd/Cu dual catalysis	We disclose a strategy for Ni-catalyzed dicarbofunctionalization of olefins in styrenes by intercepting Heck C(sp(3))-NiX intermediates with arylzinc reagents. This approach utilizes a readily removable imine as a coordinating group that plays a dual role of intercepting oxidative addition species derived from aryl halides and triflates to promote Heck carbometalation and stabilizing the Heck C(sp(3))-NiX intermediates as transient metallacycles to suppress beta-hydride elimination and facilitate transmetalation/reductive elimination steps. This method affords diversely substituted 1,1,2-triarylethyl products that occur as structural motifs in various natural products.	Sci. China-Chem.	69	Liu, J; Wang, XL	FALSE	FALSE	FALSE	FALSE
3472	10.1039/d0sc03304a	doi.org/10.1039/d0sc03304a	Pyridylic anions are soft nucleophiles in the palladium-catalyzed C(sp(3))-H allylation of 4-alkylpyridines	A constant-current electrochemical method for reducing catalytic nickel complexes in sp(2)-sp(3) cross-electrophile coupling reactions has been developed. The electrochemical reduction provides reliable nickel catalyst activation and turnover and offers a tunable parameter for reaction optimization, in contrast to more standard activated metal powder reductants. The electrochemical reactions give yields (i.e., 51-86%) and selectivities as high or superior to those using metal powder reductants and provide access to a wider substrate Scope.	Chem. Sci.	69	Orellana, A	FALSE	FALSE	FALSE	FALSE
3473	10.1002/anie.202011491	doi.org/10.1002/anie.202011491	Nickel- and Palladium-Catalyzed Cross-Coupling Reactions of Organostibines with Organoboronic Acids	A metal and solvent free strategy to functionalize aryl methyl ethers through direct nucleophilic substitution of aryl C-OMe bond has been described. A wide range of O, S, N, and C-centered uncharged nucleophiles has been successfully employed. Using this protocol, functional derivatives of bisthiophene have been synthesized in a straightforward way. The reactions are highly atom-efficient and generate methanol as the only byproduct.	Angew. Chem.-Int. Edit.	69	Qiu, RH; Kambe, N	FALSE	FALSE	FALSE	FALSE
3474	10.1038/s41467-020-19944-x	doi.org/10.1038/s41467-020-19944-x	Visible-light photoredox-catalyzed C-O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature	A palladium-catalyzed addition of arylboronic acids to para-quinone methides has been developed. The catalytic system employing 4,4'-dimethoxy- 2,2'-bipyridine (DMeO-BPy) as ligand and trifluoroethanol (TFE) as solvent provides diarylacetate products in high yields. A wide range of functionalized arylboronic acids can be used and the method tolerates some variation in the scope of the para-quinone methides.	Nat. Commun.	69	Li, Y	FALSE	FALSE	FALSE	FALSE
3475	10.1002/cctc.202001338	doi.org/10.1002/cctc.202001338	Palladium-Ruthenium Catalyst Complementarity Strengthens Ortho-Directed C-H Bond Arylation of 2-Arylpyrazines	The development of catalytic reactions for synthesizing different compounds from alcohols to save fossil carbon feedstock and reduce CO2 emissions is of high importance. Replacing rare noble metals with abundantly available 3d metals is equally important. We report a manganese-complex-catalyzed multicomponent synthesis of pyrimidines from amidines and up to three alcohols. Our reaction proceeds through condensation and dehydrogenation steps, permitting selective C-C and C-N bond formations. -Alkylation reactions are used to multiply alkylate secondary alcohols with two different primary alcohols to synthesize fully substituted pyrimidines in a one-pot process. Our PN5P-Mn-pincer complexes efficiently catalyze this multicomponent process. A comparison of our manganese catalysts with related cobalt catalysts indicates that manganese shows a reactivity similar to that of iridium but not cobalt. This analogy could be used to develop further (de)hydrogenation reactions with manganese complexes.	ChemCatChem	69	Doucet, H; Soule, JF	FALSE	FALSE	FALSE	FALSE
3476	10.1021/acs.orglett.0c01466	doi.org/10.1021/acs.orglett.0c01466	Transition-Metal-Free Site-Selective gamma-C(sp(2))-H Monoiodination of Arenes Directed by an Aliphatic Keto Group	Vinyl benzoxazinanone was applied as an electrophilic allylating reagent for a series of arenes under redox-neutral Rh(III) catalysis. This reaction occurs in high efficiency under mild conditions to afford allylarenes bearing a sulfonamide functionality in exclusively E-selectivity. This allylation system combines C-H activation of arenes and scission of an unstrained six-membered ring.	Org. Lett.	69	Zhang, FM	FALSE	FALSE	FALSE	FALSE
3477	10.1021/acs.joc.0c00560	doi.org/10.1021/acs.joc.0c00560	One-Pot Multicomponent Reaction of Catechols, Ammonium Acetate, and Aldehydes for the Synthesis of Benzoxazole Derivatives Using the Fe(III)-Salen Complex	2-Azido-2-deoxy-1-thioglucoside donors with an electron withdrawing group at position 6 were employed to study the stereoselectivity of the glycosylation reaction with several acceptors, ranging from unhindered small primary alcohols to other sugars and steroids, using NIS/TfOH as promoter. p-Tolyl 2-azido3,4- di-O-benzyl-6-O-chloroacetyl-2-deoxy-1-thio-alpha/beta-D-glucopyranoside afforded the higher alpha-selectivity, showing that a stronger electron withdrawing ester at O-6 influenced the anomeric selectivity towards the 1,2-cis glucosides. The anomeric stereoselectivity was highly dependent on the acceptor. (C) 2016 Elsevier Ltd. All rights reserved.	J. Org. Chem.	69	Sharghi, H	FALSE	FALSE	FALSE	FALSE
3478	10.1021/acs.joc.0c00141	doi.org/10.1021/acs.joc.0c00141	Cu/Ni-Catalyzed Cyanomethylation of Alkenes with Acetonitrile for the Synthesis of beta,gamma-Unsaturated Nitriles	Under visible-light irradiation, the gold-catalyzed intermolecular difunctionalization of alkynes with aryl diazonium salts in methanol affords a variety of -aryl ketones in moderate to good yields. In contrast to previous reports on gold-catalyzed reactions that involve redox cycles, no external oxidants or photosensitizers are required. The reaction proceeds smoothly under mild reaction conditions and shows broad functional-group tolerance. Further applications of this method demonstrate the general applicability of the arylation of a vinyl gold intermediate instead of the commonly used protodemetalation step. This step provides facile access to functionalized products in one-pot processes. With a P,N-bidentate ligand, a stable aryl gold(III) species was obtained, which constitutes the first direct experimental evidence for the commonly postulated direct oxidative addition of an aryl diazonium salt to a pyridine phosphine gold(I) complex.	J. Org. Chem.	69	Shen, ZM	FALSE	FALSE	FALSE	FALSE
3479	10.1021/acscatal.9b05525	doi.org/10.1021/acscatal.9b05525	Highly Efficient and Selective N-Alkylation of Amines with Alcohols Catalyzed by in Situ Rehydrated Titanium Hydroxide	An efficient allylation of C-H bonds promoted by a simple cobalt salt combined with a Grignard reagent has been developed. This reaction provides an alternative protocol to the build-up of fundamentally interesting allylated aromatics at room temperature. Mechanistically different from the (CpCo)-Co-star(III)-promoted transformation, a low-valent cobalt complex that was formed in situ by the reduction with a Grignard reagent can be considered as the catalytically active species, allowing the C-H activation to proceed effectively followed by straightforward coupling with an allylic electrophile to give the product.	ACS Catal.	69	Khodakov, AY	FALSE	FALSE	FALSE	FALSE
3480	10.1021/acs.joc.9b02603	doi.org/10.1021/acs.joc.9b02603	Engaging Sulfonamides: Intramolecular Cross-Electrophile Coupling Reaction of Sulfonamides with Alkyl Chlorides		J. Org. Chem.	69	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
3481	10.1002/chem.201905224	doi.org/10.1002/chem.201905224	Catalyst-Free Decarboxylation of Carboxylic Acids and Deoxygenation of Alcohols by Electro-Induced Radical Formation		Chem.-Eur. J.	69	Wang, P	FALSE	TRUE	FALSE	FALSE
3482	10.1016/j.jcat.2019.12.012	doi.org/10.1016/j.jcat.2019.12.012	Scalable preparation of stable and reusable silica supported palladium nanoparticles as catalysts for N-alkylation of amines with alcohols		J. Catal.	69	Jagadeesh, RV	FALSE	FALSE	FALSE	FALSE
3483	10.3390/molecules25010230	doi.org/10.3390/molecules25010230	Iron-Catalyzed C(sp(2))-C(sp(3)) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents		Molecules	69	Bisz, E; Szostak, M	FALSE	FALSE	FALSE	FALSE
3484	10.1021/acs.joc.9b02431	doi.org/10.1021/acs.joc.9b02431	Nickel-Catalyzed Thiolation and Selenylation of Cycloketone Oxime Esters with Thiosulfonate or Seleniumsulfonate		J. Org. Chem.	69	Wang, SY; Ji, SJ	FALSE	FALSE	FALSE	FALSE
3485	10.1016/j.tet.2019.130624	doi.org/10.1016/j.tet.2019.130624	Iron(III)-catalyzed synthesis of selenoesters from alpha-amino carbonyl derivatives at room temperature		Tetrahedron	69	Majee, A	FALSE	FALSE	FALSE	FALSE
3486	10.1016/j.tet.2019.130550	doi.org/10.1016/j.tet.2019.130550	Transformation of aromatic bromides into aromatic nitriles with n-BuLi, pivalonitrile, and iodine under metal cyanide-free conditions		Tetrahedron	69	Togo, H	FALSE	FALSE	FALSE	FALSE
3487	10.1021/acs.organomet.9b00340	doi.org/10.1021/acs.organomet.9b00340	Heteroaryl Backbone Strategy in Bisphosphine Monoxide Palladium-Catalyzed Ethylene Polymerization and Copolymerization with Polar Monomers		Organometallics	69	Mu, HL; Wang, Z; Jian, ZB	FALSE	FALSE	FALSE	FALSE
3488	10.1021/acs.oprd.9b00196	doi.org/10.1021/acs.oprd.9b00196	Palladium-Catalyzed Amidation and Amination of (Hetero)aryl Chlorides under Homogeneous Conditions Enabled by a Soluble DBU/NaTFA Dual-Base System		Org. Process Res. Dev.	69	Simmons, EM	FALSE	FALSE	FALSE	FALSE
3489	10.1021/acscatal.9b02230	doi.org/10.1021/acscatal.9b02230	An Electrochemically Promoted, Nickel-Catalyzed Mizoroki-Heck Reaction		ACS Catal.	69	Sevov, CS	FALSE	TRUE	FALSE	FALSE
3490	10.1002/chem.201900921	doi.org/10.1002/chem.201900921	Pd/C as Heterogeneous Catalyst for the Direct Arylation of (Poly)fluorobenzenes		Chem.-Eur. J.	69	Soule, JF; Doucet, H	FALSE	FALSE	FALSE	FALSE
3491	10.1021/jacs.9b05671	doi.org/10.1021/jacs.9b05671	Organotitanium Nucleophiles in Asymmetric Cross-Coupling Reaction: Stereoconvergent Synthesis of Chiral alpha-CF3 Thioethers		J. Am. Chem. Soc.	69	Gandelman, M	FALSE	FALSE	FALSE	FALSE
3492	10.1002/cssc.201900433	doi.org/10.1002/cssc.201900433	Pd-Catalyzed Stereodivergent Allylic Amination of alpha-Tertiary Allylic Alcohols towards alpha,beta-Unsaturated gamma-Amino Acids		ChemSusChem	69	Kleij, AW	FALSE	FALSE	FALSE	FALSE
3493	10.1080/08927022.2019.1572892	doi.org/10.1080/08927022.2019.1572892	Structural and electronic properties of chemically modified fullerenes		Mol. Simul.	69	Deshpande, PA	FALSE	FALSE	FALSE	FALSE
3494	10.1021/acs.orglett.9b00600	doi.org/10.1021/acs.orglett.9b00600	Nickel-Catalyzed Intramolecular Direct Arylation of lmines toward Diverse Indoles		Org. Lett.	69	Wu, B; Tian, X	FALSE	FALSE	FALSE	FALSE
3495	10.1039/c8qo01365a	doi.org/10.1039/c8qo01365a	Three-component bis-heterocycliation for synthesis of 2-aminobenzo[4,5]thieno[3,2-d]thiazoles		Org. Chem. Front.	69	Huang, HW; Ji, XC	FALSE	FALSE	FALSE	FALSE
3496	10.1039/c9ob00418a	doi.org/10.1039/c9ob00418a	Reaction condition controlled nickel(ii)-catalyzed C-C cross-coupling of alcohols		Org. Biomol. Chem.	69	Li, HX; Lang, JP	FALSE	FALSE	FALSE	FALSE
3497	10.1002/ejic.201801477	doi.org/10.1002/ejic.201801477	NHC Nickel Catalyzed Hiyama- and Negishi-Type Cross-Coupling of Aryl Fluorides and Investigations on the Stability of Nickel(II) Fluoroaryl Alkyl Complexes		Eur. J. Inorg. Chem.	69	Radius, U	FALSE	FALSE	FALSE	FALSE
3498	10.1039/c8qo01274a	doi.org/10.1039/c8qo01274a	Nickel-catalyzed regioselective C-H oxygenation: new routes for versatile C-O bond formation		Org. Chem. Front.	69	Cai, C	FALSE	FALSE	FALSE	FALSE
3499	10.1002/ejoc.201900109	doi.org/10.1002/ejoc.201900109	New Insights into the Reaction Capabilities of Ionic Organic Bases in Cu-Catalyzed Amination		Eur. J. Org. Chem.	69	Davies, RP	FALSE	FALSE	FALSE	FALSE
3500	10.1002/anie.201900228	doi.org/10.1002/anie.201900228	Nickel-Catalyzed Asymmetric Reductive Diarylation of Vinylarenes		Angew. Chem.-Int. Edit.	69	Diao, TN	FALSE	FALSE	FALSE	FALSE
3501	10.1021/acs.orglett.9b00072	doi.org/10.1021/acs.orglett.9b00072	Iridium-Catalyzed Three-component Coupling Reaction of Carbon Dioxide, Amines, and Sulfoxonium Ylides		Org. Lett.	69	Jiang, HF	FALSE	FALSE	FALSE	FALSE
3502	10.1016/j.apsusc.2018.09.154	doi.org/10.1016/j.apsusc.2018.09.154	Self-assembly 3D needle-like nickel nanostructure growth on carbon fibers by regulating prepare conditions and exploited as bifunctional material		Appl. Surf. Sci.	69	Bai, J	FALSE	FALSE	FALSE	FALSE
3503	10.1039/c8gc02298d	doi.org/10.1039/c8gc02298d	A bifunctional strategy for N-heterocyclic carbene-stabilized iridium complex-catalyzed N-alkylation of amines with alcohols in aqueous media		Green Chem.	69	Ke, ZF	FALSE	FALSE	FALSE	FALSE
3504	10.1002/ajoc.201800610	doi.org/10.1002/ajoc.201800610	Silver-Nanowire-Catalyzed Three-Component Coupling of Carbon Dioxide, Amines and Propargylic Alcohols for the Synthesis of beta-Oxopropyl Carbamates		Asian J. Org. Chem.	69	Qi, CR; Hu, JQ	FALSE	FALSE	FALSE	FALSE
3505	10.1002/chem.201804415	doi.org/10.1002/chem.201804415	Transition-Metal-Free Synthesis of Biarylmethanes from Aryl Iodides and Benzylic Ketones		Chem.-Eur. J.	69	Taillefer, M	FALSE	FALSE	FALSE	FALSE
3506	10.1021/acs.joc.8b01396	doi.org/10.1021/acs.joc.8b01396	Water-Promoted Ir-Catalyzed Ring-Opening of Oxa(aza)benzonorbornadienes with Fluoroalkylamines		J. Org. Chem.	69	Yang, DQ	FALSE	FALSE	FALSE	FALSE
3507	10.1021/acs.joc.8b00264	doi.org/10.1021/acs.joc.8b00264	Palladium(II)/N-Heterocyclic Carbene Catalyzed One-Pot Sequential alpha-Arylation/Alkylation: Access to 3,3-Disubstituted Oxindoles		J. Org. Chem.	69	Gandhi, T	FALSE	FALSE	FALSE	FALSE
3508	10.1039/c8sc00742j	doi.org/10.1039/c8sc00742j	Efficient cleavage of aryl ether C-O linkages by Rh-Ni and Ru-Ni nanoscale catalysts operating in water		Chem. Sci.	69	Dyson, PJ	FALSE	FALSE	FALSE	FALSE
3509	10.1039/c8qo00227d	doi.org/10.1039/c8qo00227d	Transition-metal-free arylation of benzoxazoles with aryl nitriles		Org. Chem. Front.	69	Zhang, H	FALSE	FALSE	FALSE	FALSE
3510	10.1039/c7cc08709h	doi.org/10.1039/c7cc08709h	Efficient and selective hydrogenation of C-O bonds with a simple sodium formate catalyzed by nickel		Chem. Commun.	69	Chen, TQ	FALSE	FALSE	FALSE	FALSE
3511	10.1055/s-0036-1589116	doi.org/10.1055/s-0036-1589116	Palladium-Catalyzed Copper-Promoted Hiyama-Type Carbon-Carbon Cross-Coupling Reactions of Dihetaryl Disulfides as Electrophiles		Synlett	69	Quan, ZJ; Wang, XC	FALSE	TRUE	FALSE	FALSE
3512	10.1007/s11426-015-5364-3	doi.org/10.1007/s11426-015-5364-3	Ru(II)-catalyzed ortho-amidation and decarboxylation of aromatic acids: a versatile route to meta-substituted N-aryl benzamides		Sci. China-Chem.	69	Shi, XY	FALSE	FALSE	FALSE	FALSE
3513	10.1016/j.molcata.2015.03.002	doi.org/10.1016/j.molcata.2015.03.002	Magnetic nanoparticle-supported Pd(II)-cryptand 22 complex: An efficient and reusable heterogeneous precatalyst in the Suzuki-Miyaura coupling and the formation of aryl-sulfur bonds		J. Mol. Catal. A-Chem.	69	Movassagh, B	FALSE	FALSE	FALSE	FALSE
3514	10.1002/ejoc.201500226	doi.org/10.1002/ejoc.201500226	Palladium-Catalyzed Amination of Aryl Sulfides with Aliphatic Amines		Eur. J. Org. Chem.	69	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
3515	10.1021/ol502120q	doi.org/10.1021/ol502120q	Efficient Synthesis of Aryl Boronates via Zinc-Catalyzed Cross-Coupling of Alkoxy Diboron Reagents with Aryl Halides at Room Temperature		Org. Lett.	69	Marder, TB	FALSE	FALSE	FALSE	FALSE
3516	10.1016/j.ceramint.2013.12.017	doi.org/10.1016/j.ceramint.2013.12.017	Nickel silicide,nanocrystal-containing magnetoceramics from the bulk pyrolysis of polysilazane and nickelocene		Ceram. Int.	69	Kong, J	FALSE	FALSE	FALSE	FALSE
3517	10.1021/ja5024749	doi.org/10.1021/ja5024749	Organometallic Nickel(III) Complexes Relevant to Cross-Coupling and Carbon-Heteroatom Bond Formation Reactions		J. Am. Chem. Soc.	69	Mirica, LM	FALSE	FALSE	FALSE	FALSE
3518	10.1021/jo400949p	doi.org/10.1021/jo400949p	Catalytic Formation of Ketones from Unactivated Esters through Rhodium Chelation-Assisted C-O Bond Activation		J. Org. Chem.	69	Tian, Y	FALSE	FALSE	FALSE	FALSE
3519	10.1021/om200937d	doi.org/10.1021/om200937d	R-Allyl Nickel(II) Complexes with Chelating N-Heterocyclic Carbenes: Synthesis, Structural Characterization, and Catalytic Activity		Organometallics	69	Puerta, MC	FALSE	FALSE	FALSE	FALSE
3520	10.1002/chem.201102984	doi.org/10.1002/chem.201102984	Ni-Catalyzed Reductive Allylation of Unactivated Alkyl Halides with Allylic Carbonates		Chem.-Eur. J.	69	Gong, HG	FALSE	FALSE	FALSE	FALSE
3521	10.1021/jo201821g	doi.org/10.1021/jo201821g	Kumada Coupling of Aryl, Heteroaryl, and Vinyl Chlorides Catalyzed by Amido Pincer Nickel Complexes		J. Org. Chem.	69	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3522	10.1002/adsc.201000747	doi.org/10.1002/adsc.201000747	Copper(I)-Mediated Cyanation of Boronic Acids		Adv. Synth. Catal.	69	Hu, ML	FALSE	FALSE	FALSE	FALSE
3523	10.1002/anie.201101191	doi.org/10.1002/anie.201101191	Nickel-Catalyzed Cross-Coupling of Styrenyl Epoxides with Boronic Acids		Angew. Chem.-Int. Edit.	69	Doyle, AG	FALSE	FALSE	FALSE	FALSE
3524	10.1002/adsc.200900501	doi.org/10.1002/adsc.200900501	Palladium on Charcoal as a Recyclable Catalyst for C-S Cross-Coupling of Thiols with Aryl Halides under Ligand-Free Conditions		Adv. Synth. Catal.	69	Lin, XF	FALSE	FALSE	FALSE	FALSE
3525	10.1016/j.tetlet.2009.02.116	doi.org/10.1016/j.tetlet.2009.02.116	Palladium-catalyzed direct arylation of 4-hydroxycoumarins with arylboronic acids via C-OH bond activation		Tetrahedron Lett.	69	Wu, J	FALSE	FALSE	FALSE	FALSE
3526	10.1039/b807258b	doi.org/10.1039/b807258b	Synthesis of new dipyridinylamine and dipyridinylmethane ligands and their coordination chemistry with Mg(II) and Zn(II)		New J. Chem.	69	Thomas, CM	FALSE	FALSE	FALSE	FALSE
3527	10.1002/adsc.200700081	doi.org/10.1002/adsc.200700081	Synthesis of symmetrical bisquinolones via nickel(0)-catalyzed homocoupling of 4-chloroquinolones		Adv. Synth. Catal.	69	Kappe, CO	FALSE	FALSE	FALSE	FALSE
3528	10.1002/anie.200702439	doi.org/10.1002/anie.200702439	Dual catalysis: A combined enantioselective bronsted acid and metal-catalyzed reaction-metal catalysis with chiral counterions		Angew. Chem.-Int. Edit.	69	Rueping, M	FALSE	FALSE	FALSE	FALSE
3529	10.1002/ejoc.200300356	doi.org/10.1002/ejoc.200300356	A mild and versatile method for palladium-catalyzed cross-coupling of aryl halides in water and surfactants		Eur. J. Org. Chem.	69	Arcadi, A	FALSE	FALSE	FALSE	FALSE
3530	10.1088/0954-0083/11/4/307	doi.org/10.1088/0954-0083/11/4/307	Aromatic and heterocyclic polymers - what future?		High Perform. Polym.	69	Sillion, B	FALSE	FALSE	FALSE	FALSE
3531	10.1351/pac198355111781	doi.org/10.1351/pac198355111781	ORGANOMETALLIC CATALYSIS IN ASYMMETRIC-SYNTHESIS		Pure Appl. Chem.	69	PINO, P	FALSE	FALSE	FALSE	FALSE
3532	10.1039/d2sc00341d	doi.org/10.1039/d2sc00341d	Torsional strain inversed chemoselectivity in a Pd-catalyzed atroposelective carbonylation reaction of dibenzothiophenium		Chem. Sci.	69	Gu, ZH	FALSE	FALSE	FALSE	FALSE
3533	10.1055/s-0041-1737761	doi.org/10.1055/s-0041-1737761	Synthesis of Aryl Nitriles via Aerobic Oxidative Cleavage of Aryl C=C Bonds with (NH (4) ) (2) CO (3) as the Nitrogen Source		Synlett	69	Ren, YL	FALSE	FALSE	FALSE	FALSE
3534	10.1021/acsomega.1c05770	doi.org/10.1021/acsomega.1c05770	trans-Dichlorobis(XPhos)palladium(II) Precatalyst for Suzuki-Miyaura Cross-Coupling Reactions of Aryl/Vinyl Sulfonates/Halides: Scope, Mechanistic Study, and Synthetic Applications		ACS Omega	69	Blanc, A	FALSE	FALSE	FALSE	FALSE
3535	10.1039/d1ra08015f	doi.org/10.1039/d1ra08015f	Benzyl thioether formation merging copper catalysis		RSC Adv.	69	Ye, Y; Xie, T; Ye, XY	FALSE	FALSE	FALSE	FALSE
3536	10.1021/jacs.1c09341	doi.org/10.1021/jacs.1c09341	Time-Resolved EPR Revealed the Formation, Structure, and Reactivity of N-Centered Radicals in an Electrochemical C(sp(3))-H Arylation Reaction		J. Am. Chem. Soc.	69	Qi, XT; Lei, AW	FALSE	TRUE	FALSE	FALSE
3537	10.1021/acs.orglett.1c03390	doi.org/10.1021/acs.orglett.1c03390	Glycosyl-Radical-Based Synthesis of C-Alkyl Glycosides via Photomediated Defluorinative gem-Difluoroallylation		Org. Lett.	69	Li, CY	TRUE	FALSE	FALSE	FALSE
3538	10.1038/s41467-021-27028-7	doi.org/10.1038/s41467-021-27028-7	Asymmetric construction of acyclic quaternary stereocenters via direct enantioselective additions of alpha-alkynyl ketones to allenamides		Nat. Commun.	69	Yang, XY	FALSE	FALSE	FALSE	FALSE
3539	10.1038/s41467-021-25836-5	doi.org/10.1038/s41467-021-25836-5	Efficient synthesis of primary and secondary amides via reacting esters with alkali metal amidoboranes		Nat. Commun.	69	Chen, XN	FALSE	FALSE	FALSE	FALSE
3540	10.1021/acs.orglett.1c03066	doi.org/10.1021/acs.orglett.1c03066	Nickel-Catalyzed Etherification of Phenols and Aryl Halides through Visible-Light-Induced Energy Transfer		Org. Lett.	69	Li, HX	FALSE	FALSE	FALSE	FALSE
3541	10.1038/s41467-021-26194-y	doi.org/10.1038/s41467-021-26194-y	Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines		Nat. Commun.	69	Shi, H	FALSE	FALSE	FALSE	FALSE
3542	10.1021/acs.orglett.1c02887	doi.org/10.1021/acs.orglett.1c02887	Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Bromides and Chlorosilanes		Org. Lett.	69	Zhang, C	FALSE	FALSE	FALSE	FALSE
3543	10.1039/d1qo00530h	doi.org/10.1039/d1qo00530h	Transition-metal-free decarbonylative alkylation towards N-aryl alpha-hydroxy amides via triple C-C bond cleavages and their selective deuteration		Org. Chem. Front.	69	Li, H	FALSE	FALSE	FALSE	FALSE
3544	10.6023/cjoc202010023	doi.org/10.6023/cjoc202010023	Palladium-Catalyzed C8 Alkylation of 1-Naphthylamides and Its Application to the Synthesis of the Core Sturctures of Aporphine and Aristolactam Alkaloids		Chin. J. Org. Chem.	69	Huang, LH	FALSE	FALSE	FALSE	FALSE
3545	10.1039/d1qo00490e	doi.org/10.1039/d1qo00490e	Practical allylation with unactivated allylic alcohols under mild conditions		Org. Chem. Front.	69	Xie, PZ; Loh, TP	FALSE	FALSE	FALSE	FALSE
3546	10.1002/anie.201706794	doi.org/10.1002/anie.201706794	Markovnikov-Selective Palladium Catalyst for Carbonylation of Alkynes with Heteroarenes		Angew. Chem.-Int. Edit.	69	Beller, M	FALSE	FALSE	FALSE	FALSE
3547	10.1039/c7cc04526c	doi.org/10.1039/c7cc04526c	Discovery of synthetic small molecules that enhance the number of stomata: C-H functionalization chemistry for plant biology		Chem. Commun.	69	Itami, K; Torii, KU	FALSE	FALSE	FALSE	FALSE
3548	10.1002/chem.201702168	doi.org/10.1002/chem.201702168	Trifluoromethylation of a Well-Defined Square-Planar Aryl-Ni-II Complex involving Ni-III/CF3 center dot and Ni-IV-CF3 Intermediate Species		Chem.-Eur. J.	69	Luis, JM; Ribas, X	FALSE	FALSE	FALSE	FALSE
3549	10.1021/acs.joc.7b01215	doi.org/10.1021/acs.joc.7b01215	Hypervalent Iodine(III)-Promoted Phenyl Transfer Reaction from Phenyl Hydrazides to Nitriles		J. Org. Chem.	69	Zhang, ZG; Zhang, GS	FALSE	FALSE	FALSE	FALSE
3550	10.1021/acscatal.7b00860	doi.org/10.1021/acscatal.7b00860	Acenaphthoimidazolylidene Gold Complex-Catalyzed Alkylsulfonylation of Boronic Acids by Potassium Metabisulfite and Alkyl Halides: A Direct and Robust Protocol To Access Sulfones		ACS Catal.	69	Tu, T	FALSE	FALSE	FALSE	FALSE
3551	10.1021/acs.orglett.7b01208	doi.org/10.1021/acs.orglett.7b01208	Regioselective Ni-Catalyzed Carboxylation of Allylic and Propargylic Alcohols with Carbon Dioxide		Org. Lett.	69	Mei, TS	FALSE	FALSE	FALSE	FALSE
3552	10.1021/acs.joc.6b02222	doi.org/10.1021/acs.joc.6b02222	Transfer Hydro-dehalogenation of Organic Halides Catalyzed by Ruthenium(II) Complex		J. Org. Chem.	69	Xia, YZ	FALSE	FALSE	FALSE	FALSE
3553	10.1002/anie.201611318	doi.org/10.1002/anie.201611318	Manganese-Catalyzed Multicomponent Synthesis of Pyrimidines from Alcohols and Amidines		Angew. Chem.-Int. Edit.	69	Kempe, R	FALSE	FALSE	FALSE	FALSE
3554	10.1016/j.tetlet.2016.11.035	doi.org/10.1016/j.tetlet.2016.11.035	Synthesis of beta-prolinols via [3+2] cycloaddition and one-pot programmed reduction: Valuable building blocks for polyheterocycles		Tetrahedron Lett.	69	Zhang, YD	FALSE	FALSE	FALSE	FALSE
3555	10.1021/acs.joc.6b01748	doi.org/10.1021/acs.joc.6b01748	Generation, Stability, and Utility of Lithium 4,4 '-Di-tert-butylbiphenylide (LiDBB)		J. Org. Chem.	69	Rychnovsky, SD	FALSE	FALSE	FALSE	FALSE
3556	10.1038/ncomms12937	doi.org/10.1038/ncomms12937	Stille coupling via C-N bond cleavage		Nat. Commun.	69	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
3557	10.1021/jacs.6b00016	doi.org/10.1021/jacs.6b00016	Bimetallic C-C Bond-Forming Reductive Elimination from Nickel		J. Am. Chem. Soc.	69	Diao, TN	FALSE	FALSE	FALSE	FALSE
3558	10.1021/acs.orglett.6b00658	doi.org/10.1021/acs.orglett.6b00658	Dicumyl Peroxide as a Methylating Reagent in the Ni-Catalyzed Methylation of Ortho C-H Bonds in Aromatic Amides		Org. Lett.	69	Chatani, N	FALSE	FALSE	FALSE	FALSE
3559	10.1016/j.tet.2015.12.028	doi.org/10.1016/j.tet.2015.12.028	Me2AlCl-mediated carboxylation, ethoxycarbonylation, and carbamoylation of indoles		Tetrahedron	69	Tanaka, S; Hattori, T	FALSE	FALSE	FALSE	FALSE
3560	10.1002/anie.202015021	doi.org/10.1002/anie.202015021	Fast Enantio- and Chemoselective Arylation of Ketones with Organoboronic Esters Enabled by Nickel/N-Heterocyclic Carbene Catalysis	The development of enantioselective carbon carbon bond couplings catalyzed by nonprecious metals is highly desirable in terms of cost efficiency and, sustainability. The first nickel-catalyzed enantioselective Mizoroki Heck coupling is reported. This transformation is accomplished via mild reaction conditions, leveraging on QuinoxP* as a chiral ligand to;afford oxindoles containing quaternary stereocenters. Good reactivity and selectivity are observed in the presence of various functional groups. Computational studies suggest that the oxidative addition assembles an atropisomeric intermediate responsible for the facial selectivity of the insertion step.	Angew. Chem.-Int. Edit.	68	Shi, SL	FALSE	FALSE	FALSE	FALSE
3561	10.1016/j.tet.2020.131757	doi.org/10.1016/j.tet.2020.131757	Diastereoselective sulfur ylide rearrangements from gold catalyzed oxidation of ynamides	Herein, we report the integration of simple linear regressions with gold(I) catalysis to interrogate the influence of phosphine structure on metal-catalyzed organic transformations. We demonstrate that observed product ratios in [4 + 3]/[4 + 2] cycloisomerization processes are influenced by both steric and electronic properties of the phosphine, which can be represented by the Au-CI distance. In contrast, the observed selectivity of a similar [2 + 3]/[2 + 2] cycloisomerization is governed by L/B1, a steric parameter. Using this correlation, we were able to accurately predict the selectivity of a previously untested, Buchwald-type ligand to enhance selectivity for the same transformation. This ligand found further utility in increasing the selectivity of a previously reported gold-catalyzed cycloisomerization/arylation of 1,6-enynes by similar to 1 kcal/mol.	Tetrahedron	68	Davies, PW	FALSE	FALSE	FALSE	FALSE
3562	10.1055/s-0040-1705961	doi.org/10.1055/s-0040-1705961	Nickel-Catalyzed Reductive Allylation of Aldehydes with Allyl Acetates	An inexpensive nickel(II) catalyst and a hydrosilane were used for the efficient reductive defunctionalization of aryl and heteroaryl esters through a decarbonylative pathway. This versatile method could be used for the removal of ester and amide functional groups from various organic molecules. Moreover, a scale-up experiment and a synthetic application based on the use of a removable carboxylic acid directing group highlight the usefulness of this reaction.	Synthesis	68	Yamaguchi, E; Itoh, A	FALSE	FALSE	FALSE	FALSE
3563	10.1055/s-0040-1705943	doi.org/10.1055/s-0040-1705943	Decarbonylative Synthesis of Aryl Nitriles from Aromatic Esters and Organocyanides by a Nickel Catalyst	We investigated the oxidative addition of PhX (X = Cl, Br) to a single Pd(0) atom or a PdX- complex in water using first-principles molecular dynamics simulations, with solvent H2O molecules explicitly included in the calculation models, to clarify the origin of the extremely high reactivity of a ligand-free Pd catalyst in an aqueous solution for the Suzuki-Miyaura reaction. The free-energy profiles are estimated using blue moon ensemble sampling to include the entropy effect in chemical reactions in a water solvent. The free-energy barrier of the oxidative addition step is quite low for PhBr, whereas the barrier for PhCl is sizable, indicating that the reaction can proceed at room temperature with a high rate for PhBr but a rather low rate for PhCl. We also investigated the effect of the additional halogen anion on the Pd catalyst as a supporting ligand. The activation barrier of the oxidative addition step is not affected by the supporting halogen ligand, but the final state is significantly destabilized, which should be important for the following transmetalation step. The solvent effect has also been investigated and discussed.	Synlett	68	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
3564	10.1021/acs.orglett.0c02861	doi.org/10.1021/acs.orglett.0c02861	Cleavage of Aromatic C-O Bonds via Intramolecular SNAr Reaction and Preparation of P,C,Axial-Stereogenic Menthyl Phosphine Derivatives	A new alpha-Fe2O3 nanocluster/graphene oxide catalyst is found to be efficient in parts-per-million for Suzuki-Miyaura coupling and 4-nitrophenol reduction in aqueous solution, and this catalyst is recycled at least 4 times in good yields.	Org. Lett.	68	Li, Q; Zhao, CQ	FALSE	FALSE	FALSE	FALSE
3565	10.1039/d0cy01380c	doi.org/10.1039/d0cy01380c	Kinetic analysis of the asymmetric hydrogenation of (E)-2,3-diphenylpropenoic acid over cinchonidine derivative-modified Pd/C: quinoline ring modification	A series of cobalt complexes with tridentate pincer ligands were synthesized to study their catalytic activity in Suzuki-Miyaura coupling reactions. Cobalt complexes, C-1, C-2, C-3 bearing asymmetrical PNCOP pincer ligand [C6H4-1-(NHPPh2)-3-(OPPh2)] (L-1) and symmetrical PNCNP, PNNNP pincer ligands [C6H4-2,6-(NHPPh2)(2)] (L-2) and [C5H3N-2,6-(NHPPh2)(2)] (L-3) were synthesized by the reaction of diphenylchlorophosphine with m-aminophenol, m-phenylenediamine and 2,6-diaminopyridine respectively in a 1: 2 ratio in the presence of triethylamine as a base and tetrahydrofuran as solvent media. The synthesized complexes were examined for their C-C coupling efficiency in cross-coupling between phenyl boronic acid and para substituted bromobenzenes. Effect of variation of the ligand on the catalytic activity of cobalt pincer complex was explored based on the coupling yields. It is observed that as the number of 'N' atoms increases in the side arm of the ligand, the donating ability of the ligand increases which leads to the increased catalytic activity of the complex. The symmetrical PNNNP pincer complex (C-3) was found to be more effective as a catalyst among the complexes synthesized and reported in the present study. (C) 2016 Elsevier B.V. All rights reserved.	Catal. Sci. Technol.	68	Okamoto, Y; Sugimura, T	FALSE	FALSE	FALSE	FALSE
3566	10.1002/cjoc.202000019	doi.org/10.1002/cjoc.202000019	Expedient Synthesis of KetonesviaN-HeterocyclicCarbene/Nickel-Catalyzed Redox-EconomicalCoupling of Alcohols and Alkynes(dagger)	Titanium tetrachloride-mediated transformation of five- and six-membered cyclic ethers to the corresponding N-aryl-substituted azacycles is conducted in moderate to good yields under mild reaction conditions. Computational studies suggested a mechanism involving a Lewis acid-assisted ring-opening, a seven-membered metallacycle intermediate and a ring-closing process facilitated by direct participation of the metal center.	Chin. J. Chem.	68	Shi, SL	FALSE	FALSE	FALSE	FALSE
3567	10.1016/j.mcat.2020.111045	doi.org/10.1016/j.mcat.2020.111045	Mechanisms and origin of regioselectivity on N-heterocyclic carbene-catalyzed [3+2]/[4+2] annulations of C(60 )with alpha,beta-unsaturated aldehydes	Synthesis of alkylated amines is an important and attractive task in organic chemistry. Herein, we demonstrate a general protocol to produce alkylated amines via the catalytic coupling of amines with aromatic ethers or phenols. This transformation is performed in the presence of a heterogeneous palladium catalyst, and the key to its success is the use of a Lewis acid (LA) co-catalyst. This method shows broad substrate scope and a variety of phenols, including lignin-derived fragments, can be converted to the desired products smoothly. Preliminary mechanistic investigations reveal that this straightforward domino transformation occurs via a hydrogenolysis/reduction/condensation/reduction process.	Mol. Catal.	68	Li, X; Chang, JB	FALSE	FALSE	FALSE	FALSE
3568	10.1039/d0sc02054k	doi.org/10.1039/d0sc02054k	Nickel-catalyzed three-component olefin reductive dicarbofunctionalization to access alkylborates	Cobalt bis(acetylacetonate) is shown to Mediate hydrogen atom transfer to a broad range of functionalized alkenes; in situ oxidation of the resulting alkylradical intermediates, followed by hydrolysis, provides expedient access to ketones and esters. By modification of the alcohol solvent, different alkyl ester products may be obtained. The method is compatible with a number of functional groups including alkenyl halides, sulfides, triflates, and phosphonates and provides a mild and practical alternative to the Tamao-Fleming oxidation of vinylsilanes and the Arndt-Eistert homologation.	Chem. Sci.	68	Lu, X; Fu, Y	FALSE	FALSE	FALSE	FALSE
3569	10.6023/cjoc202004028	doi.org/10.6023/cjoc202004028	Nickel(II)-Catalyzed Aerobic Cross-Dehydrogenative Coupling for the Synthesis of N-Aryl Tetrahydroisoquinolines	A nickel-catalyzed Heck cyclization for the construction of quaternary stereocenters is reported. This transformation is demonstrated in the synthesis of 3,3-disubstituted oxindoles, which are prevalent motifs seen in numerous biologically active molecules. The method shows broad scope, proceeds in synthetically useful yields, and provides a rare means to construct stereochemically complex frameworks by nonprecious-metal catalysis.	Chin. J. Org. Chem.	68	Zhou, WY	FALSE	FALSE	FALSE	FALSE
3570	10.1002/adsc.202000186	doi.org/10.1002/adsc.202000186	In Situ Ring-Closing Strategy for Direct Synthesis of N-Heterocyclic Carbene Nickel Complexes and Their Application in Coupling of Allylic Alcohols with Aryl Boronic Acids	(Ferrocenylthienyl)phosphines of type 2-PR2-5-Fc-(C4H2S)-C-c (R = Ph (3a), Bu-t (3b)) and 2-PR2-3,4-Fc(2)-(C4HS)-C-c (R = Ph (4a), Bu-t (4b); Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)) and their selenium derivatives were synthesized by consecutive synthetic methodologies. The molecular structure of 3a and 4a, b in the solid state show inter-and intramolecular (T-shaped) pep interactions for 3a and 4a, resulting in dimeric and 1D polymeric structures. Phosphines 3a, b and 4a, b were applied in the Pd-catalyzed Suzuki-Miyaura C,C cross coupling reaction of aryl halides and boronic acids yielding the respective biaryls. Compound 3b shows a higher activity in C, C cross coupling reactions as compared to 3a and previously published thiophene-based phosphines and aminophosphines. Moreover sterically hindered and deactivated aryl bromides could be coupled at Pd loadings as low as 0.05 mol-% and at temperatures between 25 degrees C and 50 degrees C. However, the application of diferrocenylthienylphosphines 4a, b in Suzuki-Miyaura reactions resulted in decreased yields of the corresponding biaryls. In the context of electrochemical investigations on these compounds, a strong dependency of the individual electrode reactions on the phosphorus substituents were found. During UV-Vis/NIR spectroelectrochemical studies, only a very limited iron-iron electronic interaction in 4a-Se+ could be detected. Thus, 4a-Se+ corresponds to a very weak coupled class II system according to the classification of Robin and Day. (C) 2016 Elsevier B.V. All rights reserved.	Adv. Synth. Catal.	68	Dai, B; Liu, N	FALSE	FALSE	FALSE	FALSE
3571	10.1055/s-0037-1610756	doi.org/10.1055/s-0037-1610756	Nickel-Catalyzed Annulation of Aliphatic Amides with Alkynylsilanes: An Expeditious Approach to Five-Membered Lactams	The first nickel-catalyzed, magnesium-mediated reductive cross-coupling between benzyl chlorides and aryl chlorides or fluorides is reported. A variety of diarylmethanes can be prepared in good to excellent yields in a one-pot manner using easy-to-access mixed PPh3/NHC Ni(II) complexes of Ni(PPh3)(NHC)Br-2 (NHC = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr, 1a; 1,3-di-tert-butylimidazol-2-ylidene, ItBu, 1b) as catalyst precursors. Activation of polychloroarenes or chemoselective cross-coupling based on the difference in catalytic activity between 1a and 1b is used to construct oligo-diarylmethane motifs.	Synlett	68	Lin, C; Shen, L	FALSE	FALSE	FALSE	FALSE
3572	10.1002/anie.201916398	doi.org/10.1002/anie.201916398	General Paradigm in Photoredox Nickel-Catalyzed Cross-Coupling Allows for Light-Free Access to Reactivity	The first catalytic enantioselective total synthesis of riccardiphenol B, a sesquiterpene derivative isolated from a Japanese collection of the liver-wort Riccardia crassa, has been achieved. A copper-catalyzed asymmetric conjugate addition of trimethylaluminum was used at an early stage to generate the quaternary stereogenic center with high enantiomeric excess. The corresponding sterically en-cumbered aluminum enolate was directly trapped with an alpha-amino ether, allowing after oxidation, the release of a key intermediate in the total synthesis of the target natural product.	Angew. Chem.-Int. Edit.	68	Nocera, DG	TRUE	FALSE	FALSE	FALSE
3573	10.1002/ajoc.201900759	doi.org/10.1002/ajoc.201900759	Transition-Metal-Free Approaches to Arylsulfones using Benzylic Ammonium Salts through C-N Bond Cleavage		Asian J. Org. Chem.	68	Zhu, HB; Jiang, GF; Le, ZG	FALSE	FALSE	FALSE	FALSE
3574	10.1002/adsc.201901152	doi.org/10.1002/adsc.201901152	Water-Promoted Palladium-Catalyzed Asymmetric Ring-Opening of Oxabenzonorbornadienes with Alkoxysilanes		Adv. Synth. Catal.	68	Yang, DQ	FALSE	FALSE	FALSE	FALSE
3575	10.1039/c9cc05707b	doi.org/10.1039/c9cc05707b	Dioxygen-triggered oxidative cleavage of the C-S bond towards C-N bond formation		Chem. Commun.	68	Lei, AW	FALSE	FALSE	FALSE	FALSE
3576	10.1039/c9cy01285k	doi.org/10.1039/c9cy01285k	Entropic corrections for the evaluation of the catalytic activity in the Al(iii) catalysed formation of cyclic carbonates from CO2 and epoxides A data set of input files and computational results is available in the ioChem-BD repository and can be accessed via; http://dx.doi.org/10.19061/iochem-bd-1-110.Electronic supplementary information (ESI) available: A detailed description of the methods used for including entropic corrections in solution. See DOI: 10.1039/c9cy01285k		Catal. Sci. Technol.	68	Bo, C	FALSE	TRUE	FALSE	FALSE
3577	10.1021/acscatal.9b02977	doi.org/10.1021/acscatal.9b02977	Borrowing Hydrogen-Mediated N-Alkylation Reactions by a Well-Defined Homogeneous Nickel Catalyst		ACS Catal.	68	Adhikari, D	FALSE	FALSE	FALSE	FALSE
3578	10.1021/acs.joc.9b01692	doi.org/10.1021/acs.joc.9b01692	N-Heterocyclic Carbene Ligand-Controlled Chemodivergent Suzuki-Miyaura Cross Coupling		J. Org. Chem.	68	Neufeldt, SR	FALSE	FALSE	FALSE	FALSE
3579	10.1002/ejoc.201900769	doi.org/10.1002/ejoc.201900769	Palladium-Catalyzed Direct Oxidative Coupling of Iodoarenes with Primary Alcohols Leading to Ketones: Application to the Synthesis of Benzofuranones and Indenones		Eur. J. Org. Chem.	68	Satyanarayana, G	FALSE	FALSE	FALSE	FALSE
3580	10.1055/s-0037-1611732	doi.org/10.1055/s-0037-1611732	Palladium-Catalyzed Amination of Aryl Sulfides and Sulfoxides with Azaarylamines of Poor Nucleophilicity		Synthesis	68	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
3581	10.1002/anie.201901927	doi.org/10.1002/anie.201901927	Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9-BBN-Derived Ate Complexes		Angew. Chem.-Int. Edit.	68	Morken, JP	FALSE	FALSE	FALSE	FALSE
3582	10.1021/acs.oprd.9b00048	doi.org/10.1021/acs.oprd.9b00048	Basic Anion-Exchange Resin-Catalyzed Aldol Condensation of Aromatic Ketones with Aldehydes in Continuous Flow		Org. Process Res. Dev.	68	Kobayashi, S	FALSE	FALSE	FALSE	FALSE
3583	10.1021/acs.orglett.9b00889	doi.org/10.1021/acs.orglett.9b00889	Palladium Catalyzed Hydrodefluorination of Fluoro-(hetero)arenes		Org. Lett.	68	Grey, RL	FALSE	FALSE	FALSE	FALSE
3584	10.1002/anie.201814233	doi.org/10.1002/anie.201814233	Four Oxidation States in a Single Photoredox Nickel-Based Catalytic Cycle: A Computational Study		Angew. Chem.-Int. Edit.	68	Maseras, F	TRUE	FALSE	FALSE	FALSE
3585	10.1021/jacs.8b13534	doi.org/10.1021/jacs.8b13534	Ni-Catalyzed Reductive Liebeskind-Srogl Alkylation of Heterocycles		J. Am. Chem. Soc.	68	Cornella, J	FALSE	FALSE	FALSE	FALSE
3586	10.1002/anie.201812537	doi.org/10.1002/anie.201812537	Water and Sodium Chloride: Essential Ingredients for Robust and Fast Pd-Catalysed Cross-Coupling Reactions between Organolithium Reagents and (Hetero)aryl Halides		Angew. Chem.-Int. Edit.	68	Capriati, V	FALSE	FALSE	FALSE	FALSE
3587	10.1021/acs.joc.8b02911	doi.org/10.1021/acs.joc.8b02911	Manganese-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohols With Sulfones: A Tool To Access Highly Substituted Vinyl Sulfones		J. Org. Chem.	68	Maji, B	FALSE	FALSE	FALSE	FALSE
3588	10.1002/celc.201800498	doi.org/10.1002/celc.201800498	Anodic Formation of Aryl Mesylates through Dehydrogenative Coupling Reaction		ChemElectroChem	68	Waldvogel, SR	FALSE	FALSE	FALSE	FALSE
3589	10.3906/kim-1811-6	doi.org/10.3906/kim-1811-6	Progress in the chemistry of 3-amino-9-ethylcarbazole		Turk. J. Chem.	68	Bondock, S	FALSE	FALSE	FALSE	FALSE
3590	10.1021/acs.accounts.8b00408	doi.org/10.1021/acs.accounts.8b00408	Upgrading Cross-Coupling Reactions for Biaryl Syntheses		Accounts Chem. Res.	68	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
3591	10.1002/adsc.201801000	doi.org/10.1002/adsc.201801000	Bench-Stable Sulfoxide-Based Boronates: Preparation and Application in a Tandem Suzuki Reaction		Adv. Synth. Catal.	68	Tobrman, T	FALSE	FALSE	FALSE	FALSE
3592	10.1021/jacs.8b09401	doi.org/10.1021/jacs.8b09401	Synergistic Bimetallic Ni/Ag and Ni/Cu Catalysis for Regioselective gamma,delta-Diarylation of Alkenyl Ketimines: Addressing beta-H Elimination by in Situ Generation of Cationic Ni(II) Catalysts		J. Am. Chem. Soc.	68	Giri, R	FALSE	FALSE	FALSE	FALSE
3593	10.1021/jacs.8b07597	doi.org/10.1021/jacs.8b07597	General and Practical Potassium Methoxide/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides		J. Am. Chem. Soc.	68	Liu, WB	FALSE	FALSE	FALSE	FALSE
3594	10.1039/c8cc03665a	doi.org/10.1039/c8cc03665a	Ni-Catalyzed cross-coupling of aryl thioethers with alkyl Grignard reagents via C-S bond cleavage		Chem. Commun.	68	Shi, L	FALSE	FALSE	FALSE	FALSE
3595	10.1021/jacs.8b05374	doi.org/10.1021/jacs.8b05374	Ni-Catalyzed Regioselective Alkylarylation of Vinylarenes via C(sp(3))-C(sp(3))/C(sp(3))-C(sp(2)) Bond Formation and Mechanistic Studies		J. Am. Chem. Soc.	68	Giri, R	FALSE	FALSE	FALSE	FALSE
3596	10.1021/jacs.8b05743	doi.org/10.1021/jacs.8b05743	Cu-Catalyzed Enantioselective Ring Opening of Cyclic Diaryliodoniums toward the Synthesis of Chiral Diarylmethanes		J. Am. Chem. Soc.	68	Gu, ZH	FALSE	FALSE	FALSE	FALSE
3597	10.1021/acs.orglett.8b01696	doi.org/10.1021/acs.orglett.8b01696	Metal-Free Etherification of Aryl Methyl Ether Derivatives by C-OMe Bond Cleavage		Org. Lett.	68	Wang, XQ; Zhao, WX	FALSE	FALSE	FALSE	FALSE
3598	10.1039/c8qo00295a	doi.org/10.1039/c8qo00295a	Pd-Catalyzed one-pot dehydroxylative coupling of phenols with K-4[Fe(CN)(6)] mediated by SO2F2: a practical method for the direct conversion of phenols to aryl nitriles		Org. Chem. Front.	68	Qin, HL	FALSE	FALSE	FALSE	FALSE
3599	10.1039/c8gc00318a	doi.org/10.1039/c8gc00318a	A nitrogen-ligated nickel-catalyst enables selective intermolecular cyclisation of beta- and gamma-amino alcohols with ketones: access to five and six-membered N-heterocycles		Green Chem.	68	Banerjee, D	FALSE	FALSE	FALSE	FALSE
3600	10.1021/acs.orglett.8b00646	doi.org/10.1021/acs.orglett.8b00646	Catalyst-Directed Chemoselective Double Amination of Bromo-chloro(hetero)arenes: A Synthetic Route toward Advanced Amino-aniline Intermediates		Org. Lett.	68	Colacot, TJ	FALSE	FALSE	FALSE	FALSE
3601	10.1002/cjoc.201700664	doi.org/10.1002/cjoc.201700664	Methylation of Arenols through Ni-catalyzed CO Activation with Methyl Magnesium Bromide		Chin. J. Chem.	68	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
3602	10.1002/anie.201711813	doi.org/10.1002/anie.201711813	Stereoselective Construction of Halogenated Quaternary Carbon Centers by Bronsted Base Catalyzed [4+2] Cycloaddition of alpha-Haloaldehydes		Angew. Chem.-Int. Edit.	68	Li, JL	FALSE	FALSE	FALSE	FALSE
3603	10.1039/c7gc03106h	doi.org/10.1039/c7gc03106h	Selectfluor-mediated regioselective nucleophilic functionalization of N-heterocycles under metal- and base-free conditions		Green Chem.	68	He, WM	FALSE	FALSE	FALSE	FALSE
3604	10.1021/acs.orglett.7b03753	doi.org/10.1021/acs.orglett.7b03753	Nickel(0)-Catalyzed Inert C-O Bond Functionalization: Organo Rare-Earth Metal Complex as the Coupling Partner		Org. Lett.	68	Li, XF	FALSE	FALSE	FALSE	FALSE
3605	10.1021/acs.joc.7b02296	doi.org/10.1021/acs.joc.7b02296	Metal-Free Blue Dye Synthesis: Oxidative Coupling of Benzylamines and N,N-Dimethylanilines to Yield 4,4 '-Diaminotriarylmethanes in the Presence of Salicylic Acid as a Co-oxidant		J. Org. Chem.	68	Ogawa, A	FALSE	FALSE	FALSE	FALSE
3606	10.1002/asia.201701132	doi.org/10.1002/asia.201701132	Organozinc-Mediated Direct C-C Bond Formation via C-N Bond Cleavage of Ammonium Salts		Chem.-Asian J.	68	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
3607	10.1021/acscatal.5b02165	doi.org/10.1021/acscatal.5b02165	Iridium-Catalyzed Direct C-H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle		ACS Catal.	68	Chang, S	FALSE	FALSE	FALSE	FALSE
3608	10.1016/j.tet.2015.07.060	doi.org/10.1016/j.tet.2015.07.060	A simple and efficient synthesis of isoindolinone derivatives based on reaction of ortho-lithiated aromatic imines with CO		Tetrahedron	68	Tang, LF	FALSE	FALSE	FALSE	FALSE
3609	10.1021/jacs.5b03277	doi.org/10.1021/jacs.5b03277	Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines		J. Am. Chem. Soc.	68	Hayashi, T	FALSE	FALSE	FALSE	FALSE
3610	10.1016/j.tet.2015.04.052	doi.org/10.1016/j.tet.2015.04.052	Versatile palladium(II)-catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand		Tetrahedron	68	Lang, JP	FALSE	FALSE	FALSE	FALSE
3611	10.1002/adsc.201400957	doi.org/10.1002/adsc.201400957	Organoselenium-Catalyzed Baeyer-Villiger Oxidation of alpha,beta-Unsaturated Ketones by Hydrogen Peroxide to Access Vinyl Esters		Adv. Synth. Catal.	68	Yu, L	FALSE	FALSE	FALSE	FALSE
3612	10.1039/c4qo00331d	doi.org/10.1039/c4qo00331d	Copper-catalysed cross-couplings of arylboronate esters with aryl and heteroaryl iodides and bromides		Org. Chem. Front.	68	Gurung, SK	FALSE	FALSE	FALSE	FALSE
3613	10.1002/ejoc.201402751	doi.org/10.1002/ejoc.201402751	Iron(III)-Catalyzed C-H Functionalization: ortho-Benzoyloxylation of N,N-Dialkylanilines and Its Application to 1,4-Benzoxazepines		Eur. J. Org. Chem.	68	Chandrasekharam, M	FALSE	FALSE	FALSE	FALSE
3614	10.1002/ejoc.201402713	doi.org/10.1002/ejoc.201402713	Asymmetric Mannich Reaction of Malonates with Aldimines Using Yb-III-Pybox Complexes Supported on Self-Assembled Organic-Inorganic Hybrid Silica with an Imidazolium Framework		Eur. J. Org. Chem.	68	Karimi, B	FALSE	FALSE	FALSE	FALSE
3615	10.1021/ja505576g	doi.org/10.1021/ja505576g	A Well-Defined (POCOP)Rh Catalyst for the Coupling of Aryl Halides with Thiols		J. Am. Chem. Soc.	68	Ozerov, OV	FALSE	FALSE	FALSE	FALSE
3616	10.1021/jo501835u	doi.org/10.1021/jo501835u	Iridium-Catalyzed Annulative Coupling of 2-Arylbenzoyl Chlorides with Alkynes: Selective Formation of Phenanthrene Derivatives		J. Org. Chem.	68	Miura, M	FALSE	FALSE	FALSE	FALSE
3617	10.1021/jo4028598	doi.org/10.1021/jo4028598	Chemoselective C-Benzylation of Unprotected Anilines with Benzyl Alcohols Using Re2O7 Catalyst		J. Org. Chem.	68	Ghorai, P	FALSE	FALSE	FALSE	FALSE
3618	10.1246/cl.130919	doi.org/10.1246/cl.130919	Synthesis of HOMSi Reagents by Pd/Cu-Catalyzed Silylation of Bromoarenes with Disilanes		Chem. Lett.	68	Minami, Y	FALSE	FALSE	FALSE	FALSE
3619	10.1021/ic401296f	doi.org/10.1021/ic401296f	Metal-Ligand Synergistic Effects in the Complex Ni(eta(2)-TEMPO)(2): Synthesis, Structures, and Reactivity		Inorg. Chem.	68	Webster, CE	FALSE	FALSE	FALSE	FALSE
3620	10.1002/anie.201304770	doi.org/10.1002/anie.201304770	Cross-Coupling Reaction of a Highly Strained Molecule: Synthesis of sigma-pi Conjugated Tetrahedranes		Angew. Chem.-Int. Edit.	68	Sekiguchi, A	FALSE	FALSE	FALSE	FALSE
3621	10.3762/bjoc.9.175	doi.org/10.3762/bjoc.9.175	A reductive coupling strategy towards ripostatin A		Beilstein J. Org. Chem.	68	Jamison, TF	FALSE	FALSE	FALSE	FALSE
3622	10.1002/pola.26519	doi.org/10.1002/pola.26519	Nascent Cu(0) nanoparticles-mediated single electron transfer living radical polymerization of acrylonitrile at ambient temperature		J. Polym. Sci. Pol. Chem.	68	Liu, XH	FALSE	FALSE	FALSE	FALSE
3623	10.1002/cctc.201200417	doi.org/10.1002/cctc.201200417	Magnetic Fe-Ni Alloy Catalyzed Suzuki Cross-Coupling Reactions of Aryl Halides with Phenylboronic Acid		ChemCatChem	68	Sun, W	FALSE	FALSE	FALSE	FALSE
3624	10.1021/ol2031608	doi.org/10.1021/ol2031608	Terminal Alkyne Addition to Diazodicarboxylates: Synthesis of Hydrazide Linked Alkynes (Ynehydrazides)		Org. Lett.	68	Batey, RA	FALSE	FALSE	FALSE	FALSE
3625	10.1021/jo200065d	doi.org/10.1021/jo200065d	Linear Heterocyclic Aromatic Fluorescence Compounds Having Various Donor-Acceptor Spacers Prepared by the Combination of Carbon-Carbon Bond and Carbon-Nitrogen Bond Cross-Coupling Reactions		J. Org. Chem.	68	Huang, W	FALSE	FALSE	FALSE	FALSE
3626	10.1016/j.tetlet.2008.08.063	doi.org/10.1016/j.tetlet.2008.08.063	Highly stereoselective allylic ethylation with alkoxytitanacyclopropane reagents. Synthesis of (1R/S,7R)-1,7-dimethylnonyl propanoate, the Western corn rootworm sex attractant		Tetrahedron Lett.	68	Kulinkovich, OG	FALSE	FALSE	FALSE	FALSE
3627	10.1021/jo052061r	doi.org/10.1021/jo052061r	Suzuki-Miyaura cross-coupling reactions of aryl tellurides with potassium aryltrifluoroborate salts		J. Org. Chem.	68	Stefani, HA	FALSE	FALSE	FALSE	FALSE
3628	10.1002/anie.200462013	doi.org/10.1002/anie.200462013	Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents		Angew. Chem.-Int. Edit.	68	Sapountzis, I	FALSE	FALSE	FALSE	FALSE
3629	10.1016/j.tet.2004.07.093	doi.org/10.1016/j.tet.2004.07.093	PS-PEG resin-supported palladium-MOP complexes. Application in asymmetric pi-allylic reduction		Tetrahedron	68	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
3630	10.1002/anie.202112533	doi.org/10.1002/anie.202112533	Direct and Unified Access to Carbon Radicals from Aliphatic Alcohols by Cost-Efficient Titanium-Mediated Homolytic C-H Bond Cleavage		Angew. Chem.-Int. Edit.	68	Suga, T; Ukaji, Y	FALSE	FALSE	FALSE	FALSE
3631	10.3390/ph15010104	doi.org/10.3390/ph15010104	Coumarin Derivatives Exert Anti-Lung Cancer Activity by Inhibition of Epithelial-Mesenchymal Transition and Migration in A549 Cells		Pharmaceuticals	68	Mendonca, FJB	FALSE	FALSE	FALSE	FALSE
3632	10.1021/jacs.1c11623	doi.org/10.1021/jacs.1c11623	Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids		J. Am. Chem. Soc.	68	Li, C	FALSE	FALSE	FALSE	FALSE
3633	10.1002/adsc.202101241	doi.org/10.1002/adsc.202101241	Nickel-Catalyzed Decarbonylative Cycloaddition of Benzofuran-2,3-diones with Alkynes to Flavones		Adv. Synth. Catal.	68	Qiu, LQ	FALSE	FALSE	FALSE	FALSE
3634	10.1021/acs.joc.1c02188	doi.org/10.1021/acs.joc.1c02188	Palladium-Catalyzed Methylsulfonylation of Alkyl Halides Using Dimethyl Sulfite as SO2 Surrogate and Methyl Source		J. Org. Chem.	68	Zhang, XG; Deng, CL	FALSE	FALSE	FALSE	FALSE
3635	10.1039/d1sc02967c	doi.org/10.1039/d1sc02967c	Reductive electrophilic C-H alkylation of quinolines by a reusable iridium nanocatalyst		Chem. Sci.	68	Zhang, M	FALSE	FALSE	FALSE	FALSE
3636	10.1039/d1ra05405h	doi.org/10.1039/d1ra05405h	Selective oxidation of alcohol-d(1) to aldehyde-d(1) using MnO2		RSC Adv.	68	Shinada, T	FALSE	FALSE	FALSE	FALSE
3637	10.1039/d1cc02837e	doi.org/10.1039/d1cc02837e	Nickel-catalyzed reductive monofluoroakylation of alkyl tosylate with bromofluoromethane to primary alkyl fluoride		Chem. Commun.	68	Wang, XS	FALSE	FALSE	FALSE	FALSE
3638	10.1002/adsc.202100554	doi.org/10.1002/adsc.202100554	Ruthenium-Catalyzed Three-Component Alkylation: A Tandem Approach to the Synthesis of Nonsymmetric N,N-Dialkyl Acyl Hydrazides with Alcohols		Adv. Synth. Catal.	68	Renaud, JL	FALSE	FALSE	FALSE	FALSE
3639	10.1021/jacs.1c04215	doi.org/10.1021/jacs.1c04215	Ni-Catalyzed Aryl Sulfide Synthesis through an Aryl Exchange Reaction		J. Am. Chem. Soc.	68	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
3640	10.1002/chem.202101101	doi.org/10.1002/chem.202101101	Tetrasubstituted Peropyrenes Formed by Reductive Aromatization: Synthesis, Functionalization and Characterization		Chem.-Eur. J.	68	Sundermeyer, J	FALSE	FALSE	FALSE	FALSE
3641	10.1039/d1sc01681d	doi.org/10.1039/d1sc01681d	Mimicking transition metals in borrowing hydrogen from alcohols		Chem. Sci.	68	Mandal, SK	FALSE	FALSE	FALSE	FALSE
3642	10.1016/j.tetlet.2021.152950	doi.org/10.1016/j.tetlet.2021.152950	Nickel-catalyzed oxidative dehydrogenative coupling of alkane with thiol for C(sp(3))-S bond formation		Tetrahedron Lett.	68	Qian, B; Huang, HM	FALSE	FALSE	FALSE	FALSE
3643	10.1021/acs.orglett.7b02012	doi.org/10.1021/acs.orglett.7b02012	Combinatorial Nickel-Catalyzed Monofluoroalkylation of Aryl Boronic Acids with Unactivated Fluoroalkyl Iodides		Org. Lett.	68	Wang, XS	FALSE	FALSE	FALSE	FALSE
3644	10.1002/anie.201704119	doi.org/10.1002/anie.201704119	A Direct Synthesis of Highly Substituted pi-Rich Aromatic Heterocycles from Oxetanes		Angew. Chem.-Int. Edit.	68	Vanderwal, CD	FALSE	FALSE	FALSE	FALSE
3645	10.1021/acs.orglett.7b01905	doi.org/10.1021/acs.orglett.7b01905	Nickel-Catalyzed C-CN Bond Formation via Decarbonylative Cyanation of Esters, Amides, and Intramolecular Recombination Fragment Coupling of Acyl Cyanides		Org. Lett.	68	Rueping, M	FALSE	FALSE	FALSE	FALSE
3646	10.1021/acs.joc.7b01034	doi.org/10.1021/acs.joc.7b01034	Nickel-Catalyzed Reductive Cycloisomerization of Enynes with CO2		J. Org. Chem.	68	Diao, TN	FALSE	FALSE	FALSE	FALSE
3647	10.1002/bkcs.11127	doi.org/10.1002/bkcs.11127	One-Pot Synthesis of 3-(Benzo[e]indol-2-yl)-2-oxindoles from Isatin-derived Propargylic Alcohols and N-Acetyl-2-aminonaphthalenes		Bull. Korean Chem. Soc.	68	Kim, JN	FALSE	FALSE	FALSE	FALSE
3648	10.1021/acs.organomet.6b00638	doi.org/10.1021/acs.organomet.6b00638	Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids		Organometallics	68	Jiang, GX	FALSE	FALSE	FALSE	FALSE
3649	10.1002/ejoc.201600677	doi.org/10.1002/ejoc.201600677	Nickel-Catalyzed Construction of Chiral 1-[6]Helicenols and Application in the Synthesis of [6]Helicene-Based Phosphinite Ligands		Eur. J. Org. Chem.	68	Tsujihara, T; Kawano, T	FALSE	FALSE	FALSE	FALSE
3650	10.1002/chem.201602486	doi.org/10.1002/chem.201602486	Formation of C(sp(3))-C(sp(3)) Bonds through Nickel-Catalyzed Decarboxylative Olefin Hydroalkylation Reactions		Chem.-Eur. J.	68	Fu, Y	FALSE	FALSE	FALSE	FALSE
3651	10.1021/acs.organomet.6b00415	doi.org/10.1021/acs.organomet.6b00415	Nickel Catalysts for the Dehydrative Decarbonylation of Carboxylic Acids to Alkenes		Organometallics	68	Cramer, CJ; Tolman, WB	FALSE	FALSE	FALSE	FALSE
3652	10.1002/chem.201601911	doi.org/10.1002/chem.201601911	Stereoselective Synthesis and Retentive Trapping of alpha-Chiral Secondary Alkyllithiums Leading to Stereodefined alpha,beta-Dimethyl Carboxylic Esters		Chem.-Eur. J.	68	Knochel, P	FALSE	FALSE	FALSE	FALSE
3653	10.1002/anie.201601914	doi.org/10.1002/anie.201601914	Synthesis of Biaryls through Nickel-Catalyzed Suzuki-Miyaura Coupling of Amides by Carbon-Nitrogen Bond Cleavage		Angew. Chem.-Int. Edit.	68	Szostak, M	FALSE	FALSE	FALSE	FALSE
3654	10.1021/acs.orglett.6b01250	doi.org/10.1021/acs.orglett.6b01250	Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage		Org. Lett.	68	Hosoya, T	FALSE	FALSE	FALSE	FALSE
3655	10.1002/ejoc.201600242	doi.org/10.1002/ejoc.201600242	Ligand- and Base-Free Access to Diverse Biaryls by the Reductive Coupling of Diaryliodonium Salts		Eur. J. Org. Chem.	68	Kumar, D	FALSE	FALSE	FALSE	FALSE
3656	10.1021/acs.joc.5b02441	doi.org/10.1021/acs.joc.5b02441	Benzylic Phosphates in Friedel-Crafts Reactions with Activated and Unactivated Arenes: Access to Polyarylated Alkanes		J. Org. Chem.	68	Chakravartya, M	FALSE	FALSE	FALSE	FALSE
3657	10.1002/ejoc.201501349	doi.org/10.1002/ejoc.201501349	Nickel-Catalyzed Reductive Addition of Aryl/Benzyl Halides and Pseudohalides to Carbodiimides for the Synthesis of Amides		Eur. J. Org. Chem.	68	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
3658	10.1039/c5dt03961d	doi.org/10.1039/c5dt03961d	Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines		Dalton Trans.	68	Gilroy, JB	FALSE	FALSE	FALSE	FALSE
3659	10.1039/d0sc06446g	doi.org/10.1039/d0sc06446g	Redox-active benzimidazolium sulfonamides as cationic thiolating reagents for reductive cross-coupling of organic halides	A combinatorial nickel-catalyzed cross-coupling between arylboronic acids and unactived 1-fluoro-1-iodoalkanes has been developed, which demonstrated high efficiency, mild conditions, and excellent functional-group compatibility. Readily available nitrogen and phosphine ligands were combined with a nitrogen source, which in situ generated a variety of easily tunable catalysts to promote the fluoroalkylation for broad scopes of both coupling partners. This new strategy on combinatorial catalysis offers new solutions for nickel-catalyzed cross-coupling reactions.	Chem. Sci.	67	Wang, Y	FALSE	FALSE	FALSE	FALSE
3660	10.1021/acs.orglett.0c04178	doi.org/10.1021/acs.orglett.0c04178	Nitrogen-Centered Radical-Mediated Cascade Amidoglycosylation of Glycals	An efficient catalytic system for the reduction of nitroarenes to amines was developed using a well-defined nickel-NHC (N-heterocyclic carbene) complex as catalyst and phenylsilane as reducing agent. The excellent activity of the catalyst provides access to anilines containing a wide array of reactive function-alities at 20 degrees C, and without using ny base or additive. Notably, the catalytic system allows the reduction of 5,10,15,20tetra-(nitrophenyl) porphyrin (TNPP) and Cu-II beta-nitroporphyrin to the corresponding aminoporphyrins.	Org. Lett.	67	Xia, CF	FALSE	FALSE	FALSE	FALSE
3661	10.6023/cjoc202004015	doi.org/10.6023/cjoc202004015	Synthesis of 1, 2-Dihydroquinolines by Reduction of Quinolines with Sodium Cyanoborohydride	The cross-coupling reactions of arylsilatranes with readily available and inexpensive aryl chlorides were carried out in toluene/THF at 100 degrees C for 3 h in the presence of tetrabutylammonium fluoride as an activator for smooth transmetalation and catalytic amounts of palladium(II) acetate and XPhos.	Chin. J. Org. Chem.	67	You, SL	FALSE	FALSE	FALSE	FALSE
3662	10.1039/d0sc02948c	doi.org/10.1039/d0sc02948c	Radical condensation between benzylic alcohols and acetamides to form 3-arylpropanamides	Transition-metal-free LiCl-promoted cross-coupling reactions of tetraphenyltin, trichlorophenyl-, dichlorodiphenyl-, and chlorotriphenylstannanes with aryl halides in DMF provided access to biaryls in good to high yields. Up to four phenyl groups were transferred from the organostannanes substrates. The aryls bearing electron-withdrawing groups in either halides or organotin substrates gave coupling products in higher yields. The methodology has been applied for the efficient synthesis of ipriflavones.	Chem. Sci.	67	Madsen, R	FALSE	FALSE	FALSE	FALSE
3663	10.1007/s11030-019-09988-7	doi.org/10.1007/s11030-019-09988-7	Development of green methodologies for Heck, Chan-Lam, Stille and Suzuki cross-coupling reactions	Two 1-[6]helicenol derivatives were synthesized by Ni-catalyzed [2+2+2] cycloaddition on a multigram scale. Both enantiomers of the 1-[6]helicenols could be efficiently prepared by simple optical resolution. As a synthetic application of helically chiral 1-[6]helicenols, a novel class of [6]helicene-based phosphinites was developed; these compounds represent the first examples of helically chiral phosphinite ligands. Up to 90 % ee was obtained for the Pd-catalyzed asymmetric allylic alkylation reaction.	Mol. Divers.	67	Zahoor, AF	FALSE	FALSE	FALSE	FALSE
3664	10.1039/c9cc10089j	doi.org/10.1039/c9cc10089j	Expedient iron-catalyzed stereospecific synthesis of triazines via cycloaddition of aziridines with diaziridines	We report the chemo-and regioselective hydrogenolysis of the C-O bonds in di-ortho-substituted diaryl ethers under the catalysis of a supported nickel catalyst. The catalyst comprises heterogeneous nickel particles supported on activated carbon and furnishes arenes and phenols in high yields without hydrogenation. The high thermal stability of the embedded metal particles allows C-O bond cleavage to occur in highly substituted diaryl ether units akin to those in lignin. Preliminary mechanistic experiments show that this catalyst undergoes sintering less readily than previously reported catalyst particles that form from a solution of [Ni(cod)(2)].	Chem. Commun.	67	Punniyamurthy, T	FALSE	FALSE	FALSE	FALSE
3665	10.1039/d0ra01043j	doi.org/10.1039/d0ra01043j	The synthesis of quinolines via denitrogenative palladium-catalyzed cascade reaction of o-aminocinnamonitriles with arylhydrazines	A convenient methodology for the regioselective C-H arylation of 1,2,4-triazole ring was developed. Using a benchtop stable Cu-diamine catalyst system, C-H functionalization of a simple 1,2,4-triazole substrate with various aryl bromides was regioselectively accomplished at the C5 position of the triazole ring.	RSC Adv.	67	Ye, XT	FALSE	FALSE	FALSE	FALSE
3666	10.1038/s41467-020-14320-1	doi.org/10.1038/s41467-020-14320-1	Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide		Nat. Commun.	67	Qu, JP; Chen, YF	FALSE	FALSE	FALSE	FALSE
3667	10.1002/asia.201901442	doi.org/10.1002/asia.201901442	Nickel-Catalyzed Tandem Reaction of Functionalized Arylacetonitriles with Arylboronic Acids in 2-MeTHF: Eco-Friendly Synthesis of Aminoisoquinolines and Isoquinolones		Chem.-Asian J.	67	Chen, JX	FALSE	FALSE	FALSE	FALSE
3668	10.1039/c9cy01365b	doi.org/10.1039/c9cy01365b	Nickel-catalyzed aryl trifluoromethyl sulfide synthesis: a DFT study		Catal. Sci. Technol.	67	Jover, J	FALSE	FALSE	FALSE	FALSE
3669	10.1021/acs.joc.9b01600	doi.org/10.1021/acs.joc.9b01600	Iron-Catalyzed Ligand Free alpha-Alkylation of Methylene Ketones and beta-Alkylation of Secondary Alcohols Using Primary Alcohols		J. Org. Chem.	67	Banerjee, D	FALSE	FALSE	FALSE	FALSE
3670	10.1021/acscatal.9b03038	doi.org/10.1021/acscatal.9b03038	Borane-Catalyzed Chemoselectivity-Controllable N-Alkylation and ortho C-Alkylation of Unprotected Arylamines Using Benzylic Alcohols		ACS Catal.	67	Meng, SS; Zhao, JL; Chan, ASC	FALSE	FALSE	FALSE	FALSE
3671	10.1021/acscatal.9b02081	doi.org/10.1021/acscatal.9b02081	Ni-Catalyzed Regio- and Enantioselective Domino Reductive Cyclization: One-Pot Synthesis of 2,3-Fused Cyclopentannulated Indolines		ACS Catal.	67	Kong, WQ	FALSE	FALSE	FALSE	FALSE
3672	10.1016/j.jcat.2019.07.002	doi.org/10.1016/j.jcat.2019.07.002	A strategy of two-step tandem catalysis towards direct N-alkylation of nitroarenes with ethanol via facile fabricated novel Co-based catalysts derived from coordination polymers		J. Catal.	67	Li, WZ; Li, GM	FALSE	FALSE	FALSE	FALSE
3673	10.1002/chem.201900937	doi.org/10.1002/chem.201900937	Stoichiometric and Catalytic Aryl-Cl Activation and Borylation using NHC-stabilized Nickel(0) Complexes		Chem.-Eur. J.	67	Marder, TB; Radius, U	FALSE	FALSE	FALSE	FALSE
3674	10.1021/jacs.9b04993	doi.org/10.1021/jacs.9b04993	Bimetallic Radical Redox-Relay Catalysis for the Isomerization of Epoxides to Allylic Alcohols		J. Am. Chem. Soc.	67	Lin, S	FALSE	FALSE	FALSE	FALSE
3675	10.1039/c9cc02956g	doi.org/10.1039/c9cc02956g	Direct oxidative dearomatization of indoles: access to structurally diverse 2,2-disubstituted indolin-3-ones		Chem. Commun.	67	Zhang, H	FALSE	FALSE	FALSE	FALSE
3676	10.1016/j.synthmet.2019.04.001	doi.org/10.1016/j.synthmet.2019.04.001	Synthesis and properties of a P3HT-based ABA triblock copolymer containing a perfluoropolyether central segment		Synth. Met.	67	Ameduri, B; Clement, S	FALSE	FALSE	FALSE	FALSE
3677	10.1021/acs.orglett.9b00888	doi.org/10.1021/acs.orglett.9b00888	Ruthenium-Catalyzed Gram-Scale Preferential C-H Arylation of Tertiary Phosphine		Org. Lett.	67	Liu, YJ; Zeng, MH	FALSE	FALSE	FALSE	FALSE
3678	10.1002/ejic.201801570	doi.org/10.1002/ejic.201801570	Homo- and Heterobimetallic Complexes Bearing NHC Ligands: Applications in -Arylation of Amide, Suzuki-Miyaura Coupling Reactions, and Tandem Catalysis		Eur. J. Inorg. Chem.	67	Maity, R	FALSE	FALSE	FALSE	FALSE
3679	10.1021/acs.orglett.9b00836	doi.org/10.1021/acs.orglett.9b00836	Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl Fluorosulfates Using Carbon Dioxide		Org. Lett.	67	Mei, TS	FALSE	FALSE	FALSE	FALSE
3680	10.1016/j.ica.2018.12.020	doi.org/10.1016/j.ica.2018.12.020	Synthesis, structural characterization and MMA polymerization studies of dimeric 5-coordinate copper(II), cadmium(II), and monomeric 4-coordinate zinc(II) complexes supported by N-methyl-N-((pyridine-2-yl)methyl) benzeneamine		Inorg. Chim. Acta	67	Lee, H	FALSE	FALSE	FALSE	FALSE
3681	10.1021/acscatal.9b00118	doi.org/10.1021/acscatal.9b00118	A Tandem Iridium-Catalyzed Chain-Walking/Cope Rearrangement Sequence		ACS Catal.	67	Marek, I	FALSE	FALSE	FALSE	FALSE
3682	10.1055/s-0037-1610664	doi.org/10.1055/s-0037-1610664	Catalyst-Free, Metal-Free, and Chemoselective Transamidation of Activated Secondary Amides		Synthesis	67	Chandrasekaran, S	FALSE	FALSE	FALSE	FALSE
3683	10.2174/1570179416666181122094643	doi.org/10.2174/1570179416666181122094643	Recent Advances in Transition Metal-Catalyzed Reactions of Oxabenzonorbornadiene		Curr. Org. Synth.	67	Tam, W	FALSE	FALSE	FALSE	FALSE
3684	10.1021/acs.orglett.8b03427	doi.org/10.1021/acs.orglett.8b03427	Metal-Free Direct Construction of 2-(Oxazol-5-yl)phenols from N-Phenoxyamides and Alkynylbenziodoxolones via Sequential [3,3]-Rearrangement/Cyclization		Org. Lett.	67	Li, M; Wen, LR	FALSE	FALSE	FALSE	FALSE
3685	10.1002/ejoc.201801286	doi.org/10.1002/ejoc.201801286	Rapid Access to Bi- and Tri-Functionalized Dibenzofurans and their Application in Selective Suzuki-Miyaura Cross Coupling Reactions		Eur. J. Org. Chem.	67	Konig, B	FALSE	FALSE	FALSE	FALSE
3686	10.1021/acs.orglett.8b01758	doi.org/10.1021/acs.orglett.8b01758	Nucleophilic Amination and Etherification of Aryl Alkyl Thioethers		Org. Lett.	67	Zhao, WX; Wang, XQ	FALSE	FALSE	FALSE	FALSE
3687	10.1021/acs.joc.8b00592	doi.org/10.1021/acs.joc.8b00592	Buchwald-Hartwig Amination of Phosphinines and the Effect of Amine Substituents on Optoelectronic Properties of the Resulting Coupling Products		J. Org. Chem.	67	Nagahora, N	FALSE	FALSE	FALSE	FALSE
3688	10.1016/j.isci.2018.04.020	doi.org/10.1016/j.isci.2018.04.020	HOTf-Catalyzed Alkyl-Heck-type Reaction		iScience	67	Li, CS; Bao, HL	FALSE	FALSE	FALSE	FALSE
3689	10.1021/acs.orglett.8b01062	doi.org/10.1021/acs.orglett.8b01062	Transforming Benzylic Amines into Diarylmethanes: Cross-Couplings of Benzylic Pyridinium Salts via C-N Bond Activation		Org. Lett.	67	Watson, MP	FALSE	FALSE	FALSE	FALSE
3690	10.1016/j.jorganchem.2018.03.030	doi.org/10.1016/j.jorganchem.2018.03.030	A new poly(N-heterocyclic carbene Pd complex) immobilized on nano silica: An efficient and reusable catalyst for Suzuki-Miyaura, Sonogashira and Heck-Mizoroki C-C coupling reactions		J. Organomet. Chem.	67	Moghadam, M	FALSE	FALSE	FALSE	FALSE
3691	10.1021/acs.joc.8b00016	doi.org/10.1021/acs.joc.8b00016	Nickel-Catalyzed C(sp(3))-H Arylation of Diarylmethane Derivatives with Aryl Fluorides		J. Org. Chem.	67	Li, J	FALSE	FALSE	FALSE	FALSE
3692	10.1002/anie.201711599	doi.org/10.1002/anie.201711599	Photocatalytic Aerobic Phosphatation of Alkenes		Angew. Chem.-Int. Edit.	67	Breder, A	TRUE	FALSE	FALSE	FALSE
3693	10.1039/c7qo00731k	doi.org/10.1039/c7qo00731k	Cross-coupling of sulfonic acid derivatives via aryl-radical transfer (ART) using TTMSS or photoredox		Org. Chem. Front.	67	Lambert, TH	FALSE	FALSE	FALSE	FALSE
3694	10.1002/adsc.201700957	doi.org/10.1002/adsc.201700957	Cadmium(II) Chloride-Catalyzed Dehydrative C-P Coupling of Propargyl Alcohols with Diarylphosphine Oxides to Afford Allenylphosphine Oxides		Adv. Synth. Catal.	67	Shen, RW	FALSE	FALSE	FALSE	FALSE
3695	10.1055/s-0036-1588572	doi.org/10.1055/s-0036-1588572	Palladium-Catalyzed Decarboxylation of Benzyl Fluorobenzoates		Synlett	67	Kuwano, R	FALSE	FALSE	FALSE	FALSE
3696	10.1039/c7cc07055a	doi.org/10.1039/c7cc07055a	Nickel-catalyzed acetamidation and lactamization of arylboronic acids		Chem. Commun.	67	Cui, SL	FALSE	FALSE	FALSE	FALSE
3697	10.6023/cjoc201704051	doi.org/10.6023/cjoc201704051	Recent Progress on the Nickel/Photoredox Dual Catalysis		Chin. J. Org. Chem.	67	Wu, S; Sun, J	TRUE	FALSE	FALSE	FALSE
3698	10.1071/CH15496	doi.org/10.1071/CH15496	Photoinitiated Synthesis of Sulfides in Water		Aust. J. Chem.	67	Baumgartner, MT	TRUE	FALSE	FALSE	FALSE
3699	10.1039/c6ra13584f	doi.org/10.1039/c6ra13584f	An efficient synthesis of 1,3-dimethyl-5-(2-phenyl-4H-chromen-4-ylidene) pyrimidine-2,4,6(1H,3H,5H)-triones and investigation of their interactions with beta-lactoglobiulin		RSC Adv.	67	Mallik, AK	FALSE	FALSE	FALSE	FALSE
3700	10.1039/c6cc08182g	doi.org/10.1039/c6cc08182g	Synthesis of stilbene derivatives via visible-light-induced cross-coupling of aryl diazonium salts with nitroalkenes using -NO2 as a leaving group		Chem. Commun.	67	Quan, ZJ; Wang, XC	FALSE	FALSE	FALSE	FALSE
3701	10.3762/bjoc.11.261	doi.org/10.3762/bjoc.11.261	Copper-catalyzed arylation of alkyl halides with arylaluminum reagents		Beilstein J. Org. Chem.	67	Giri, R	FALSE	FALSE	FALSE	FALSE
3702	10.1002/chem.201503647	doi.org/10.1002/chem.201503647	Stereospecific Pd-Catalyzed Intermolecular C(sp(3))-C(sp) Cross-Coupling of Diarylmethyl Carbonates and Terminal Alkynes Under Base-Free Conditions		Chem.-Eur. J.	67	Hirano, K	FALSE	FALSE	FALSE	FALSE
3703	10.1021/acs.organomet.5b00632	doi.org/10.1021/acs.organomet.5b00632	Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity		Organometallics	67	Deng, L	FALSE	FALSE	FALSE	FALSE
3704	10.1055/s-0034-1378720	doi.org/10.1055/s-0034-1378720	A Straightforward Approach towards Functionalized Amino Acids and Pipecolinic Acids via Ruthenium-Catalyzed Allylic Alkylation		Synlett	67	Kazmaier, U	FALSE	FALSE	FALSE	FALSE
3705	10.1002/ejoc.201500784	doi.org/10.1002/ejoc.201500784	Cobalt-Catalyzed Reductive Alkylation of Heteroaryl Bromides: One-Pot Access to Alkylthiophenes, -furans, -selenophenes, and -pyrroles		Eur. J. Org. Chem.	67	Liu, CY	FALSE	FALSE	FALSE	FALSE
3706	10.1016/j.tet.2015.05.068	doi.org/10.1016/j.tet.2015.05.068	Copper(I)-catalyzed coupling reaction of aryl boronic acids with N,O-acetals and N,N-aminals under atmosphere leading to alpha-aryl glycine derivatives and diarylmethylamine derivatives		Tetrahedron	67	Sakai, N	FALSE	FALSE	FALSE	FALSE
3707	10.1002/chem.201500639	doi.org/10.1002/chem.201500639	Carboxylate Assisted Ni-Catalyzed CH Bond Allylation of Benzamides		Chem.-Eur. J.	67	Sundararaju, B	FALSE	FALSE	FALSE	FALSE
3708	10.1021/jacs.5b03955	doi.org/10.1021/jacs.5b03955	Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C-OMe Cleavage		J. Am. Chem. Soc.	67	Martin, R	FALSE	FALSE	FALSE	FALSE
3709	10.1021/jacs.5b01909	doi.org/10.1021/jacs.5b01909	Enantioselective Cross-Coupling of meso-Epoxides with Aryl Halides		J. Am. Chem. Soc.	67	Weix, DJ	FALSE	FALSE	FALSE	FALSE
3710	10.1021/ja512498u	doi.org/10.1021/ja512498u	C-P Bond-Forming Reactions via C-O/P-H Cross-Coupling Catalyzed by Nickel		J. Am. Chem. Soc.	67	Chen, TQ	FALSE	FALSE	FALSE	FALSE
3711	10.1039/c5cc04390e	doi.org/10.1039/c5cc04390e	Palladium-catalyzed oxalyl amide assisted direct ortho-alkynylation of arylalkylamine derivatives at delta and epsilon positions		Chem. Commun.	67	Zeng, RS	FALSE	FALSE	FALSE	FALSE
3712	10.1039/c5cc02094h	doi.org/10.1039/c5cc02094h	Carbonylative coupling of allylic acetates with aryl boronic acids		Chem. Commun.	67	Xue, D	FALSE	FALSE	FALSE	FALSE
3713	10.1039/c4cc10446c	doi.org/10.1039/c4cc10446c	Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides		Chem. Commun.	67	Shi, BF	FALSE	FALSE	FALSE	FALSE
3714	10.1021/jo502078c	doi.org/10.1021/jo502078c	Stereocontrolled O-Glycosylation with Palladium-Catalyzed Decarboxylative Allylation		J. Org. Chem.	67	Liu, XW	FALSE	FALSE	FALSE	FALSE
3715	10.1002/aoc.3191	doi.org/10.1002/aoc.3191	Highly active recyclable heterogeneous nanonickel ferrite catalyst for cyanation of aryl and heteroaryl halides		Appl. Organomet. Chem.	67	Moghaddam, FM	FALSE	FALSE	FALSE	FALSE
3716	10.1016/j.ejmech.2014.02.063	doi.org/10.1016/j.ejmech.2014.02.063	Isoxazoline containing natural products as anticancer agents: A review		Eur. J. Med. Chem.	67	Kumar, V	FALSE	FALSE	FALSE	FALSE
3717	10.1021/ja501093m	doi.org/10.1021/ja501093m	Direct C-N Coupling of Imidazoles with Aromatic and Benzylic Compounds via Electrooxidative C-H Functionalization		J. Am. Chem. Soc.	67	Yoshida, J	FALSE	TRUE	FALSE	FALSE
3718	10.1039/c3qi00086a	doi.org/10.1039/c3qi00086a	Catalytic Sonogashira couplings mediated by an amido pincer complex of palladium		Inorg. Chem. Front.	67	Hung, YT	FALSE	FALSE	FALSE	FALSE
3719	10.1039/c4sc00221k	doi.org/10.1039/c4sc00221k	Regioselective alkyl transfer from phosphonium ylides to functionalized polyfluoroarenes		Chem. Sci.	67	Wu, HC	FALSE	FALSE	FALSE	FALSE
3720	10.1002/ejoc.201301264	doi.org/10.1002/ejoc.201301264	Reissert-Type Acylation with Acylzirconocene Chloride Complexes		Eur. J. Org. Chem.	67	Saito, A	FALSE	FALSE	FALSE	FALSE
3721	10.1021/ja4051923	doi.org/10.1021/ja4051923	Bimetallic Oxidative Addition Involving Radical Intermediates in Nickel-Catalyzed Alkyl-Alkyl Kumada Coupling Reactions		J. Am. Chem. Soc.	67	Hu, XL	FALSE	FALSE	FALSE	FALSE
3722	10.1021/ol401727y	doi.org/10.1021/ol401727y	Nickel-Catalyzed Suzuki-Miyaura Couplings in Green Solvents		Org. Lett.	67	Garg, NK	FALSE	FALSE	FALSE	FALSE
3723	10.1021/ol401449b	doi.org/10.1021/ol401449b	Copper-Catalyzed Enantioselective Intramolecular N-Arylation, an Efficient Method for Kinetic Resolutions		Org. Lett.	67	Cai, Q	FALSE	FALSE	FALSE	FALSE
3724	10.1016/j.tetlet.2012.12.027	doi.org/10.1016/j.tetlet.2012.12.027	An efficient transformation of ethers to N,N '-disubstituted ureas in a Ritter type reaction		Tetrahedron Lett.	67	Sureshbabu, VV	FALSE	FALSE	FALSE	FALSE
3725	10.1039/c3cc44562c	doi.org/10.1039/c3cc44562c	Nickel-catalyzed hydrogenolysis of unactivated carbon-cyano bonds		Chem. Commun.	67	Maiti, D	FALSE	FALSE	FALSE	FALSE
3726	10.1021/jo301185h	doi.org/10.1021/jo301185h	Aromatic Cations from Oxidative Carbon-Hydrogen Bond Cleavage in Bimolecular Carbon-Carbon Bond Forming Reactions		J. Org. Chem.	67	Floreancig, PE	FALSE	FALSE	FALSE	FALSE
3727	10.1055/s-0031-1289680	doi.org/10.1055/s-0031-1289680	An Easy Approach for the Synthesis of N-Substituted Isoindolin-1-ones		Synthesis	67	Ordonez, M	FALSE	FALSE	FALSE	FALSE
3728	10.1007/s12039-011-0092-5	doi.org/10.1007/s12039-011-0092-5	Recyclable nickel catalysed Suzuki-Miyaura reaction in the presence of polyethyleneimine under phosphine-free conditions in ethylene glycol		J. Chem. Sci.	67	Goudarzian, N	FALSE	FALSE	FALSE	FALSE
3729	10.1021/om200142p	doi.org/10.1021/om200142p	Site-Directed Anchoring of an N-Heterocyclic Carbene on a Dimetal Platform: Evaluation of a Pair of Diruthenium(I) Catalysts for Carbene-Transfer Reactions from Ethyl Diazoacetate		Organometallics	67	Bera, JK	FALSE	FALSE	FALSE	FALSE
3730	10.1055/s-0030-1258324	doi.org/10.1055/s-0030-1258324	Synthesis and Reactivity of beta,gamma-Dihalogenated Unsaturated Acids: Application to the Synthesis of 4-Substituted 5H-Furan-2-ones		Synthesis	67	Thibonnet, J	FALSE	FALSE	FALSE	FALSE
3731	10.1039/c1cc11603g	doi.org/10.1039/c1cc11603g	The palladium-catalyzed cyanation of indole C-H bonds with the combination of NH4HCO3 and DMSO as a safe cyanide source		Chem. Commun.	67	Ren, XY	FALSE	FALSE	FALSE	FALSE
3732	10.1016/j.jasms.2010.03.040	doi.org/10.1016/j.jasms.2010.03.040	Studies on Gas-phase Cyclometalations of [ArNi(PPh3)(n)](+) (n=1 or 2) by Electrospray Ionization Tandem Mass Spectrometry		J. Am. Soc. Mass Spectrom.	67	Xu, MH	FALSE	TRUE	FALSE	FALSE
3733	10.1021/ol100697a	doi.org/10.1021/ol100697a	Novel Axially Chiral Phosphine Ligand with a Fluoro Alcohol Moiety for Rh-Catalyzed Asymmetric Arylation of Aromatic Aldehydes		Org. Lett.	67	Amii, H	FALSE	FALSE	FALSE	FALSE
3734	10.1021/ol9028308	doi.org/10.1021/ol9028308	Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions		Org. Lett.	67	Shi, ZJ	FALSE	TRUE	FALSE	FALSE
3735	10.1039/c0cc01943g	doi.org/10.1039/c0cc01943g	Decarboxylative homocoupling of (hetero) aromatic carboxylic acids		Chem. Commun.	67	Larrosa, I	FALSE	FALSE	FALSE	FALSE
3736	10.1002/chem.200900654	doi.org/10.1002/chem.200900654	Synthetic, Mechanistic, and Theoretical Studies on the Generation of Iridium Hydride Alkylidene and Iridium Hydride Alkene Isomers		Chem.-Eur. J.	67	Carmona, E	FALSE	FALSE	FALSE	FALSE
3737	10.1021/jo701384n	doi.org/10.1021/jo701384n	Sequential Cu-catalyzed amidation-base-mediated camps cyclization: A two-step synthesis of 2-aryl-4-quinolones from o-halophenones		J. Org. Chem.	67	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
3738	10.1002/adsc.200600527	doi.org/10.1002/adsc.200600527	Friedlander synthesis of quinolines using a Lewis acid-surfactant-combined catalyst in water		Adv. Synth. Catal.	67	Wu, J	FALSE	FALSE	FALSE	FALSE
3739	10.1002/ejoc.200600469	doi.org/10.1002/ejoc.200600469	RhCl(PPh3)(3)/DPPF: A useful and efficient catalyst for cross-coupling reactions of activated alkenyl tosylates with arylboronic acids		Eur. J. Org. Chem.	67	Wu, J	FALSE	FALSE	FALSE	FALSE
3740	10.1002/chem.200501180	doi.org/10.1002/chem.200501180	Phosphoramidite Ligands in iridium-catalyzed allylic substitution		Chem.-Eur. J.	67	Alexakis, A	FALSE	FALSE	FALSE	FALSE
3741	10.1002/chem.200500231	doi.org/10.1002/chem.200500231	Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complex		Chem.-Eur. J.	67	Radius, U	FALSE	FALSE	FALSE	FALSE
3742	10.1055/s-2004-832819	doi.org/10.1055/s-2004-832819	Pt(0)-catalyzed alkynylation of aryl iodides with lithium alkynyl-triisopropoxy borates		Synlett	67	Oh, CH	FALSE	FALSE	FALSE	FALSE
3743	10.1016/j.molcata.2004.05.008	doi.org/10.1016/j.molcata.2004.05.008	Bis(triphenylphosphine)palladium(II)phthalimide - an easily prepared precatalyst for efficient Suzuki-Miyaura coupling of aryl bromides		J. Mol. Catal. A-Chem.	67	Fairlamb, IJS	FALSE	FALSE	FALSE	FALSE
3744	10.1039/a907654i	doi.org/10.1039/a907654i	Stereoselective [2+2+2] cocyclotrimerization of oxa- and azabenzonorbornadienes with alkynes catalyzed by nickel complexes: first transition metal-mediated synthesis of isobenzofuran and isoindole precursors		J. Chem. Soc.-Perkin Trans. 1	67	Cheng, CH	FALSE	FALSE	FALSE	FALSE
3745	10.1021/jo990805t	doi.org/10.1021/jo990805t	Palladium/P,O-ligand-catalyzed Suzuki cross-coupling reactions of arylboronic acids and aryl chlorides. Isolation and structural characterization of (P,O)-Pd(dba) complex		J. Org. Chem.	67	Bei, XH	FALSE	FALSE	FALSE	FALSE
3746	10.1021/jo9707848	doi.org/10.1021/jo9707848	Synthesis of biaryls via a nickel(0)-catalyzed cross-coupling reaction of chloroarenes with arylboronic acids		J. Org. Chem.	67		FALSE	FALSE	FALSE	FALSE
3747	10.1021/acscatal.2c00133	doi.org/10.1021/acscatal.2c00133	Depolymerization of Lignin via a Microscopic Reverse Biosynthesis Pathway		ACS Catal.	67	Diao, TN	FALSE	FALSE	FALSE	FALSE
3748	10.1002/chem.202103555	doi.org/10.1002/chem.202103555	Sterically Crowded Tris(2-(trimethylsilyl)phenyl)phosphine - Is it Still a Ligand?		Chem.-Eur. J.	67	Englert, U	FALSE	FALSE	FALSE	FALSE
3749	10.1021/acscatal.1c04766	doi.org/10.1021/acscatal.1c04766	N-Heterocyclic Carbene-Nickel-Catalyzed Regioselective Diarylation of Aliphatic-1,3-Dienes		ACS Catal.	67	Koh, MJ	FALSE	FALSE	FALSE	FALSE
3750	10.1002/chem.202103643	doi.org/10.1002/chem.202103643	Nickel-Catalyzed Reductive Allyl-Aryl Cross-Electrophile Coupling via Allylic C-F Bond Activation		Chem.-Eur. J.	67	Fujita, T; Ichikawa, J	FALSE	TRUE	FALSE	FALSE
3751	10.1002/adsc.202101285	doi.org/10.1002/adsc.202101285	Ni-Catalyzed Direct Carboxylation of Aryl C-H Bonds in Benzamides with CO2		Adv. Synth. Catal.	67	Wang, BQ	FALSE	FALSE	FALSE	FALSE
3752	10.1021/acs.orglett.1c03048	doi.org/10.1021/acs.orglett.1c03048	Arylketones as Aryl Donors in Palladium-Catalyzed Suzuki-Miyaura Couplings		Org. Lett.	67	Dai, HX	FALSE	FALSE	FALSE	FALSE
3753	10.1055/a-1560-5245	doi.org/10.1055/a-1560-5245	Transition-Metal-Catalyzed Enantioselective alpha-Arylation of Carbonyl Compounds to Give Tertiary Stereocenters		Synthesis	67	Orlandi, M	FALSE	FALSE	FALSE	FALSE
3754	10.1002/aoc.6378	doi.org/10.1002/aoc.6378	Nickel/beta-CD-catalyzed Suzuki-Miyaura cross-coupling of aryl boronic acids with aryl halides in water		Appl. Organomet. Chem.	67	Kaboudin, B	FALSE	FALSE	FALSE	FALSE
3755	10.1002/chem.202101082	doi.org/10.1002/chem.202101082	Enantioselective CO2 Fixation Via a Heck-Coupling/Carboxylation Cascade Catalyzed by Nickel		Chem.-Eur. J.	67	Bandini, M	FALSE	FALSE	FALSE	FALSE
3756	10.1021/acs.accounts.1c00096	doi.org/10.1021/acs.accounts.1c00096	Mechanistic Diversity of Low-Valent Chromium Catalysis: Cross-Coupling and Hydrofunctionalization		Accounts Chem. Res.	67	Zeng, XM	FALSE	FALSE	FALSE	FALSE
3757	10.1039/d1sc00972a	doi.org/10.1039/d1sc00972a	Nickel-catalyzed enantioselective vinylation of aryl 2-azaallyl anions		Chem. Sci.	67	Zhang, HB; Yang, XD	FALSE	FALSE	FALSE	FALSE
3758	10.1039/d1ob00362c	doi.org/10.1039/d1ob00362c	Ruthenium(II) complexes with N-heterocyclic carbene-phosphine ligands for the N-alkylation of amines with alcohols		Org. Biomol. Chem.	67	Huang, M	FALSE	FALSE	FALSE	FALSE
3759	10.6023/cjoc201702036	doi.org/10.6023/cjoc201702036	Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes		Chin. J. Org. Chem.	67	Bao, HL	FALSE	FALSE	FALSE	FALSE
3760	10.1246/cl.170079	doi.org/10.1246/cl.170079	Iron-catalyzed Methylation of Arylboron Compounds with Iodomethane		Chem. Lett.	67	Nakamura, M	FALSE	FALSE	FALSE	FALSE
3761	10.1002/adsc.201600814	doi.org/10.1002/adsc.201600814	Bifunctional Amine-Squaramide Catalyzed Friedel-Crafts Alkylation Based on ortho-Quinone Methides in Oil-Water Phases: Enantioselective Synthesis of Triarylmethanes		Adv. Synth. Catal.	67	Xu, DQ	FALSE	FALSE	FALSE	FALSE
3762	10.1002/anie.201611974	doi.org/10.1002/anie.201611974	Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids		Angew. Chem.-Int. Edit.	67	Niwa, T; Hosoya, T	FALSE	FALSE	FALSE	FALSE
3763	10.1002/chem.201603758	doi.org/10.1002/chem.201603758	Ni-I Catalyzes the Regioselective Cross-Coupling of Alkylzinc Halides and Propargyl Bromides to Allenes		Chem.-Eur. J.	67	Cardenas, DJ	FALSE	FALSE	FALSE	FALSE
3764	10.1021/acs.organomet.6b00371	doi.org/10.1021/acs.organomet.6b00371	SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps		Organometallics	67	Cavallo, L	FALSE	FALSE	FALSE	FALSE
3765	10.1021/acs.orglett.6b01288	doi.org/10.1021/acs.orglett.6b01288	Heteroarene-Directed Oxidative sp(2) C-H Bond Allylation with Aliphatic Alkenes Catalyzed by an (Electron-Deficient eta(5)-Cyclopentadienyl)rhodium(III) Complex		Org. Lett.	67	Tanaka, K	FALSE	TRUE	FALSE	FALSE
3766	10.1007/s00706-015-1613-6	doi.org/10.1007/s00706-015-1613-6	Efficient and simple preparation of functionalized 1,1-dibromoenol phosphates		Mon. Chem.	67	Tobrman, T	FALSE	FALSE	FALSE	FALSE
3767	10.1002/anie.202014080	doi.org/10.1002/anie.202014080	Rhodium-Catalyzed Enantioselective Synthesis of beta-Amino Alcohols via Desymmetrization of gem-Dimethyl Groups	We report Ti-catalyzed radical formal [3+2] cycloadditions of N-acylaziridines and alkenes. This method provides an efficient approach to the synthesis of pyrrolidines, structural units prevalent in bioactive compounds and organocatalysts, from readily available starting materials. The overall redox-neutral reaction was achieved via a redox-relay mechanism, which harnesses radical intermediates for selective C-N bond cleavage and formation.	Angew. Chem.-Int. Edit.	66	Liu, BX; Chang, JB; Li, XW	FALSE	FALSE	FALSE	FALSE
3768	10.1021/acs.orglett.1c00313	doi.org/10.1021/acs.orglett.1c00313	Ni-Catalyzed Cross-Electrophile Coupling of Aryl Triflates with Thiocarbonates via C-O/C-O Bond Cleavage	A one-pot Pd-catalyzed carbonylation of phenols into their corresponding aryl carboxylic acids and esters through the insertion of carbon monoxide has been developed. This procedure offers a direct synthesis of aryl carboxylic acids and esters from inexpensive and abundant starting materials (phenols, SO2F2 and CO) under mild conditions. This method tolerates a broad range of functional groups and is also applicable for the modification of complicated natural products.	Org. Lett.	66	Xue, WC; Gong, HG	FALSE	TRUE	FALSE	FALSE
3769	10.1039/d0sc05425a	doi.org/10.1039/d0sc05425a	Halogenated salt assisted Cu-catalyzed asymmetric 1,4-borylstannation of 1,3-enynes: enantioselective synthesis of allenylstannes	A catalytic synthesis of amidines from amides has been established for the first time. The newly developed CO extrusion recombination process takes advantage of an inexpensive nickel(II) catalyst and provides the corresponding amidines with high efficiency. The intramolecular fragment coupling shows excellent chemoselectivity, starts from readily available amides, and provides a valuable alternative amidine synthesis protocol.	Chem. Sci.	66	Liao, J	FALSE	FALSE	FALSE	FALSE
3770	10.1021/acs.orglett.0c03058	doi.org/10.1021/acs.orglett.0c03058	Alcohol Etherification via Alkoxy Radicals Generated by Visible-Light Photoredox Catalysis	A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.	Org. Lett.	66	Wallentin, CJ	TRUE	FALSE	FALSE	FALSE
3771	10.1021/acs.inorgchem.0c02127	doi.org/10.1021/acs.inorgchem.0c02127	Two Isostructural URJC-4 Materials: From Hydrogen Physisorption to Heterogeneous Reductive Amination through Hydrogen Molecule Activation at Low Pressure	Oxetanes bearing all-carbon quaternary stereocenters are readily prepared through the iridium-catalyzed anti-diastereo-and enantioselective C-C coupling of primary alcohols and isoprene oxide. Based on this methodology, an oxetane containing analogue of haloperidol was prepared. A related azetidine formation is also described.	Inorg. Chem.	66	Calleja, G	FALSE	FALSE	FALSE	FALSE
3772	10.1021/acs.orglett.0c02909	doi.org/10.1021/acs.orglett.0c02909	Nickel-Catalyzed Mizoroki-Heck/Amination Cascade Reactions of o-Dihaloarenes with Allylamines: Synthesis of Indoles	The heterogeneous decarboxylative cross-coupling reaction of potassium polyfluorobenzoates with aryl iodides and bromides was achieved in diglyme or DMAc at 130 or 160 degrees C in the presence of 10-20 mol% of a 1,10-phenanthroline-functionalized MCM-41-immobilized copper(I) complex, [MCM-41-Phen-CuI], yielding a variety of polyfluorobiaryls in good to excellent yields. This heterogeneous copper(I) complex could easily be prepared via a simple procedure from commercially readily available and inexpensive reagents, exhibited the same catalytic activity as the homogeneous CuI/Phen system, and was recovered by filtration of the reaction solution and recycled at least 8 times without significant loss of catalytic activity.	Org. Lett.	66	Tian, X	FALSE	FALSE	FALSE	FALSE
3773	10.1016/j.tet.2020.131493	doi.org/10.1016/j.tet.2020.131493	Palladium-catalyzed reaction of gamma-silylated allyl acetates proceeding through 1,2-shift of a substituent on silicon	Kumada-Corriu and Negishi cross-coupling reactions, catalyzed efficiently by a Ni(II) PNP pincer complex containing a triazine backbone, are described. The catalyst is able to react with both activated and inactivated aryl halides including chlorides as well as phenol derivatives such as tosylates and mesylates to give the corresponding cross-coupling products in good to excellent isolated yields. A high diversity of substrates was tested under moderate conditions for both types of reactions.	Tetrahedron	66	Horino, Y	FALSE	FALSE	FALSE	FALSE
3774	10.1021/acs.orglett.0c02515	doi.org/10.1021/acs.orglett.0c02515	Palladium-Catalyzed Secondary Benzylic Imidoylative Reactions	The Pd-catalyzed Suzuki-Miyaura cross-coupling of alkyl- and fluoroalkyl(diphenyl)sulfonium triflates with arylboronic acids was compared. The fluorine substitution on the alkyl groups of [Ph2SR][OTf] had a big influence on the reaction. Perfluoroalkyl(diphenyl)sulfonium triflates (2b-d) were unsuccessful participants in the Pd-catalyzed phenylation of arylboronic acid under the standard conditions because of the strong electronegativity of the long-chain perfluoroalkyl groups, which underwent S-R-fn bond cleavage instead. Polyfluoroalkyl(diphenyl)sulfonium triflates (2f-h) reacted with arylboronic acid to afford the phenylation product in very low yields due to the tendency of deprotonation and beta-F elimination of the sulfonium salts. Eventually, (2,2,2-trifluoroethyl)diphenylsulfonium triflate (2e), methyl- or ethyl(diphenyl)sulfonium triflate (2i or 2j), and triphenylsulfonium triflate (2m) were found to be more effective reagents than other tested phenylsulfounium salts for Pd-catalyzed phenylation, which provided much higher yields of the desired products under mild conditions. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Lett.	66	Qu, JP; Chen, YF	FALSE	FALSE	FALSE	FALSE
3775	10.1016/j.isci.2020.101419	doi.org/10.1016/j.isci.2020.101419	Light-Driven Metal-Free Direct Deoxygenation of Alcohols under Mild Conditions	A series of 2,4-diarylquinazolines have been successfully synthesized via the Ni-catalyzed cross-coupling reaction of quinazoline-4-tosylates and aryl Grignard reagents, which provided alternative straightforward approaches for the introduction of aryl groups to quinazolines at C-4 position.	iScience	66	Li, CJ	FALSE	FALSE	FALSE	FALSE
3776	10.1002/aoc.5966	doi.org/10.1002/aoc.5966	Nb((PrNPMe2)-Pr-i)(3)Fe-PMe3: A potential high reactivity heterobimetallic catalyst for acetylene cycloadditions	The first palladium-catalyzed decarbonylative coupling of phenyl 2-azinecarboxylates and arylboronic acids is presented. The key for the development of this decarbonylative coupling is the use of Pd/dcype as a catalyst. A wide range of 2-azinecarboxylates can undergo the present coupling reaction to afford 2-arylazines. By combination with previously reported nickel-catalyzed decarbonylative coupling, we achieved a chemoselective sequential decarbonylative coupling of pyridine dicarboxylate to synthesize 2,4-diarylpyridine.	Appl. Organomet. Chem.	66	Li, XY	FALSE	FALSE	FALSE	FALSE
3777	10.1002/adsc.202000799	doi.org/10.1002/adsc.202000799	Palladium/Norbornene-Catalyzed Sequentialortho-Acylation andipso-Alkenylation with Carboxylic Acid: Access to Polysubstituted Aryl Ketones	By fine tuning the combinations of chiral palladium catalysts and Lewis acids, both the additional and reductive asymmetric ring-opening reactions of azabenzonorbornadienes with alcohols were accomplished with good chemoselectivity, regioselectivity, and enantioselectivity. It was proven that the reductive ring-opening products were generated through a transfer hydrogenation process with alcohols as hydrogen source.	Adv. Synth. Catal.	66	Sun, FG	FALSE	FALSE	FALSE	FALSE
3778	10.1039/d0ob00737d	doi.org/10.1039/d0ob00737d	Lewis acid-promoted site-selective cyanation of phenols	Chiral monophosphorus ligands are playing an important role for the recent advances in asymmetric catalysis. This review summarizes the latest progress in various asymmetric catalytic reactions with the employment of chiral monophosphorus ligands including asymmetric allylic substitution, asymmetric dearomative arylation, asymmetric Heck reaction, asymmetric cross-coupling, asymmetric C-H bond functionalization, asymmetric coupling of pi systems, asymmetric addition, asymmetric hydrogenation, and asymmetric organocatalytic reactions. The new reactivity, selectivity, and reaction mechanism enabled by these chiral monophosphorus ligands are discussed.	Org. Biomol. Chem.	66	Yang, W; Zhao, WX	FALSE	FALSE	FALSE	FALSE
3779	10.1021/acs.oprd.0c00104	doi.org/10.1021/acs.oprd.0c00104	Recent Advances in Nonprecious Metal Catalysis	The base-free palladium-catalyzed borylation of aryl chlorides with diborons was achieved. The base-free conditions offered acceptable functional group compatibility. Based on experimental and computational studies, it was shown that smooth boryl transfer from the diborons to the arylpalladium chloride was promoted by strong interaction between the Lewis acidic boron and the chlorine atom on palladium.	Org. Process Res. Dev.	66	Hansen, EC	FALSE	FALSE	FALSE	FALSE
3780	10.1016/j.chempr.2020.04.006	doi.org/10.1016/j.chempr.2020.04.006	Cyclometalated Ruthenium Catalyst Enables Ortho-Selective C-H Alkylation with Secondary Alkyl Bromides	The remarkable activity displayed by copper(I)-phosphinite complexes of general formula [CuBr(L)] in two challenging cycloadditions is reported: a) the one-pot azidonation/ cycloaddition of boronic acids, NaN3, and terminal alkynes; b) the cycloaddition of azides and iodoalkynes. These air-stable catalysts led to very good results in both cases and the expected triazoles could be isolated in pure form under 'Click-suitable' conditions.	Chem	66	Larrosa, I	FALSE	FALSE	FALSE	FALSE
3781	10.1021/acscatal.0c01605	doi.org/10.1021/acscatal.0c01605	Zirconium-Catalyzed Remote Defunctionalization of Alkenes	The nickel-catalyzed addition and coupling reaction between aryl triflates and aldehydes were developed. The reactions proceed smoothly in the presence of zinc powder with the use of 10 mol% Ni(dppe)Br-2 as a catalyst. A range of aryl methanols and aryl ketones were isolated respectively in moderate to good yields in MeOH and THE solvent via direct addition or coupling reactions. Aliphatic and aromatic aldehydes were involved in this reaction, showing a broad substrate scope.	ACS Catal.	66	Streuff, J	FALSE	FALSE	FALSE	FALSE
3782	10.1039/d0qo00072h	doi.org/10.1039/d0qo00072h	A Co(ii)-catalyzed asymmetric ring opening reaction of spiro-epoxyoxindoles with allylboron	Asymmetric allylic alkylation of -ketoesters with allylic alcohols catalyzed by [Ni(cod)(2)]/(S)-H-8-BINAP was found to be a superior synthetic protocol for constructing quaternary chiral centers at the -position of -ketoesters. The reaction proceeded in high yield and with high enantioselectivity using various -ketoesters and allylic alcohols, without any additional activators. The versatility of this methodology for accessing useful and enantioenriched products was demonstrated.	Org. Chem. Front.	66	Chen, JZ; Zhang, WB	FALSE	FALSE	FALSE	FALSE
3783	10.1021/jacs.0c01330	doi.org/10.1021/jacs.0c01330	Nickel-Catalyzed Alkyl-Alkyl Cross-Electrophile Coupling Reaction of 1,3-Dimesylates for the Synthesis of Alkylcyclopropanes	Catalytic functionalization of organic compounds, leading to the formation of new carbonecarbon bonds, remains one of the more transformative reactions found in modern organic chemistry. Fueled by the emergence of more efficient and sustainable transition metal catalysts, traditional coupling methods such as the Suzuki-Miyaura, Negishi, Heck, and Stille reactions have given way to more direct approaches which significantly reduce the waste associated with prefunctionalizations. This review provides an overview of the recent innovations in transition metal couplings, involving each of the major classes of heterocyclic compounds, reported in the literature from 2014 until the present. Particular emphasis is given to novel catalyst systems which result in direct alkylation and (hetero) arylation products. The chemo-, regio-, and stereoselectivity observed in these coupling reactions have also been highlighted.	J. Am. Chem. Soc.	66	Hong, X	FALSE	TRUE	FALSE	FALSE
3784	10.1021/jacs.0c00286	doi.org/10.1021/jacs.0c00286	The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C-N Cross-Coupling	In this study, a phosphine group was chemically grafted to the surface of graphene in order to prepare a reusable ligand with high surface area, incorporating a phosphine moiety. The treatment of graphene oxide (GO) with hydroxide followed by an aqueous work-up yields an OH-functionalized graphene material (GOH) via ring-opening of the epoxide groups. Reaction of GOH with chlorodiphenylphosphine (ClPPh2) gives a new material, GOPPh(2) (PFG), which can be used for stabilization of metal nanoparticles or complexation of transition metals in order to prepare a reusable metal catalyst. Stabilization of palladium nanoparticles on the surface of GOPPh(2) resulted in the production of an efficient heterogeneous Pd catalyst (PFG Pd) for application in C-C and C-N bond formation reactions. The PFG Pd catalyst was characterized using some different microscopic and spectroscopic techniques such as FT-IR, XRD, TEM, SEM, EDX, and ICP analysis. The applicability of the PFG Pd catalyst was evaluated in Heck, Suzuki and N-arylation reactions. The catalyst system showed high catalyst activity in these processes and the target products were obtained in high isolated yields. The PFG Pd catalyst was reusable in these reactions for at least 5 times with no significant decrease in its catalytic activity.	J. Am. Chem. Soc.	66	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
3785	10.1039/d0re00036a	doi.org/10.1039/d0re00036a	An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C-N couplings	By developing a mild Ni-catalyzed system, a method for direct borylation of sp(2) and sp(3) C-N bonds has been established. The key to this hightly efficient C-N bond borylative cleavage depends on the appropriate choice of the nickel catalyst Ni(COD)(2), ICy center dot HCl as a ligand, and the use of 2-ethoxyethanol as the cosolvent. This transformation shows good functional group compatibility and can serve as powerful synthetic tool for gram-scale synthesis and late-stage C-N borylation of complex compounds.	REACT. CHEM. ENG.	66	Kappe, CO	FALSE	FALSE	FALSE	FALSE
3786	10.1002/anie.201914215	doi.org/10.1002/anie.201914215	Regio- and Stereoselective Thianthrenation of Olefins To Access Versatile Alkenyl Electrophiles		Angew. Chem.-Int. Edit.	66	Ritter, T	FALSE	TRUE	FALSE	FALSE
3787	10.1038/s41467-019-14016-1	doi.org/10.1038/s41467-019-14016-1	Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki-Miyaura cross-coupling		Nat. Commun.	66	Yin, GY	FALSE	FALSE	FALSE	FALSE
3788	10.1002/ejoc.201901331	doi.org/10.1002/ejoc.201901331	Acid-Catalyzed Synthesis of Quinoline Derivatives from 2-Methylquinolines and 2-Aryloxy/Alkoxybenzaldehyde in Aqueous Medium		Eur. J. Org. Chem.	66	Tang, XD	FALSE	FALSE	FALSE	FALSE
3789	10.1039/c9gc02464f	doi.org/10.1039/c9gc02464f	Copper and cobalt co-catalyzed aerobic oxidative cross-dehydrogenative coupling reaction of (benzo)azoles		Green Chem.	66	Lu, HJ; Li, GG	FALSE	FALSE	FALSE	FALSE
3790	10.1021/acs.orglett.9b02779	doi.org/10.1021/acs.orglett.9b02779	Nickel-Catalyzed Selective Reduction of Carboxylic Acids to Aldehydes		Org. Lett.	66	Iosub, AV; Bergman, J	FALSE	FALSE	FALSE	FALSE
3791	10.1039/c9sc02431j	doi.org/10.1039/c9sc02431j	Enantioselective palladium/copper-catalyzed C-C sigma-bond activation synergized with Sonogashira-type C(sp(3))-C(sp) cross-coupling alkynylation		Chem. Sci.	66	Cao, J; Xu, LW	FALSE	FALSE	FALSE	FALSE
3792	10.1039/c9ob00903e	doi.org/10.1039/c9ob00903e	SO2F2 mediated transformation of pyrazolones into pyrazolyl fluorosulfates		Org. Biomol. Chem.	66	Qin, HL	FALSE	FALSE	FALSE	FALSE
3793	10.1039/c9qo00092e	doi.org/10.1039/c9qo00092e	Cross coupling of alkylsilicates with acyl chlorides via photoredox/nickel dual catalysis: a new synthesis method for ketones		Org. Chem. Front.	66	Ollivier, C; Fensterbank, L	FALSE	FALSE	FALSE	FALSE
3794	10.1021/jacs.9b01886	doi.org/10.1021/jacs.9b01886	Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications		J. Am. Chem. Soc.	66	Baran, PS	FALSE	TRUE	FALSE	FALSE
3795	10.1039/c9dt00443b	doi.org/10.1039/c9dt00443b	P-Chiral 1,7-diphosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards applications in asymmetric catalysis		Dalton Trans.	66	Zagidullin, AA	FALSE	FALSE	FALSE	FALSE
3796	10.1021/acs.organomet.8b00883	doi.org/10.1021/acs.organomet.8b00883	A Highly Active Catalyst System for Suzuki-Miyaura Coupling of Aryl Chlorides		Organometallics	66	Liu, GY	FALSE	FALSE	FALSE	FALSE
3797	10.1021/acs.inorgchem.8b03389	doi.org/10.1021/acs.inorgchem.8b03389	Carbon-Rich Trinuclear Octamethylferrocenophanes		Inorg. Chem.	66	Roemer, M; Koutsantonis, GA	FALSE	FALSE	FALSE	FALSE
3798	10.1016/j.mcat.2018.09.022	doi.org/10.1016/j.mcat.2018.09.022	Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides		Mol. Catal.	66	Prikhod'ko, SA; Adonin, NY	FALSE	FALSE	FALSE	FALSE
3799	10.1002/anie.201809919	doi.org/10.1002/anie.201809919	Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insights		Angew. Chem.-Int. Edit.	66	Molander, GA	TRUE	TRUE	FALSE	FALSE
3800	10.1021/acs.jpcc.8b07538	doi.org/10.1021/acs.jpcc.8b07538	Donor/Acceptor Concepts for Developing Efficient Suzuki Cross-Coupling Catalysts Using Graphene-Supported Ni, Cu, Fe, Pd, and Bimetallic Pd/Ni Clusters		J. Phys. Chem. C	66	Khanna, SN	FALSE	FALSE	FALSE	FALSE
3801	10.1002/qua.25723	doi.org/10.1002/qua.25723	Computational exploration of Pd-catalyzed C-H bond activation reactions		Int. J. Quantum Chem.	66	She, YB	FALSE	FALSE	FALSE	FALSE
3802	10.1002/anie.201804794	doi.org/10.1002/anie.201804794	Selective alpha-Monomethylation by an Amine-Borane/N,N-Dimethylformamide System as the Methyl Source		Angew. Chem.-Int. Edit.	66	Wang, YF	FALSE	FALSE	FALSE	FALSE
3803	10.1002/cjoc.201800166	doi.org/10.1002/cjoc.201800166	Direct CH Bond Activation of Benzoxazole and Benzothiazole with Aryl Bromides Catalyzed by Palladium(II)-N-heterocyclic Carbene Complexes		Chin. J. Chem.	66	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
3804	10.1016/j.ica.2017.06.039	doi.org/10.1016/j.ica.2017.06.039	Straightforward synthesis of ferrocenyl allylic thioethers		Inorg. Chim. Acta	66	Deydier, E; Manoury, E	FALSE	FALSE	FALSE	FALSE
3805	10.1002/chem.201703266	doi.org/10.1002/chem.201703266	Mechanistic Study on Nickel-Catalyzed Silylation of Aryl Methyl Ethers		Chem.-Eur. J.	66	Fu, Y	FALSE	FALSE	FALSE	FALSE
3806	10.1055/s-0036-1589101	doi.org/10.1055/s-0036-1589101	Nickel-Catalyzed Cross-Coupling of Functionalized Organomanganese Reagents with Aryl and Heteroaryl Halides Promoted by 4-Fluorostyrene		Synthesis	66	Knochel, P	FALSE	FALSE	FALSE	FALSE
3807	10.1039/c7cc06881f	doi.org/10.1039/c7cc06881f	A simple route to 1,4-addition reactions by Co-catalyzed reductive coupling of organic tosylates and triflates with activated alkenes		Chem. Commun.	66	Hsieh, JC; Cheng, CH	FALSE	FALSE	FALSE	FALSE
3808	10.1016/j.mcat.2017.06.033	doi.org/10.1016/j.mcat.2017.06.033	Synthesis, characterization and catalytic activity of nickel NHC complexes		Mol. Catal.	66	Wlodarska, A	FALSE	FALSE	FALSE	FALSE
3809	10.1002/chem.201406680	doi.org/10.1002/chem.201406680	Reaction Optimization, Scalability, and Mechanistic Insight on the Catalytic Enantioselective Desymmetrization of 1,1-Diborylalkanes via Suzuki-Miyaura Cross-Coupling		Chem.-Eur. J.	66	Hall, DG	FALSE	FALSE	FALSE	FALSE
3810	10.1002/chem.201504049	doi.org/10.1002/chem.201504049	Stereoselective Synthesis of Trisubstituted Alkenes through Sequential Iron-Catalyzed Reductive anti-Carbozincation of Terminal Alkynes and Base-Metal-Catalyzed Negishi CrossCoupling		Chem.-Eur. J.	66	Hu, XL	FALSE	FALSE	FALSE	FALSE
3811	10.1002/anie.201503528	doi.org/10.1002/anie.201503528	Organocatalyzed Asymmetric Conjugate Addition of Heteroaryl and Aryl Trifluoroborates: a Synthetic Strategy for Discoipyrrole D		Angew. Chem.-Int. Edit.	66	May, JA	FALSE	FALSE	FALSE	FALSE
3812	10.1021/acs.joc.5b01216	doi.org/10.1021/acs.joc.5b01216	Palladium-Catalyzed Oxidative Silylation of Simple Olefins To Give Allylsilanes Using Hexamethyldisilane and Molecular Oxygen as the Sole Oxidant		J. Org. Chem.	66	Obora, Y	FALSE	FALSE	FALSE	FALSE
3813	10.1021/acs.joc.5b00800	doi.org/10.1021/acs.joc.5b00800	Regioselective Cross-Couplings of Coumarins and Flavones with Ethers via C(sp(3))-H Functionalization		J. Org. Chem.	66	Zhou, AH	FALSE	FALSE	FALSE	FALSE
3814	10.1016/j.tetlet.2015.04.069	doi.org/10.1016/j.tetlet.2015.04.069	A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes		Tetrahedron Lett.	66	Ohta, H	FALSE	FALSE	FALSE	FALSE
3815	10.1002/anie.201412051	doi.org/10.1002/anie.201412051	Nickel-Catalyzed Enantioselective C-C Bond Formation through C-sp2-O Cleavage in Aryl Esters		Angew. Chem.-Int. Edit.	66	Martin, R	FALSE	FALSE	FALSE	FALSE
3816	10.1002/anie.201409065	doi.org/10.1002/anie.201409065	Phase-Transfer-Catalyzed Asymmetric SNAr Reaction of alpha-Amino Acid Derivatives with Arene Chromium Complexes		Angew. Chem.-Int. Edit.	66	Maruoka, K	FALSE	FALSE	FALSE	FALSE
3817	10.1071/CH15459	doi.org/10.1071/CH15459	Exploring the Catalytic Reactivity of Nickel Phosphine-Phosphite Complexes		Aust. J. Chem.	66	Stewart, SG	FALSE	FALSE	FALSE	FALSE
3818	10.1021/om500577w	doi.org/10.1021/om500577w	Fate of Aryl/Amido Complexes of Rhodium(III) Supported by a POCOP Pincer Ligand: C-N Reductive Elimination, beta-Hydrogen Elimination, and Relevance to Catalysis		Organometallics	66	Ozerov, OV	FALSE	FALSE	FALSE	FALSE
3819	10.1002/chem.201403446	doi.org/10.1002/chem.201403446	Highly Chemo-, Enantio-, and Regioselective Synthesis of alpha,alpha-Disubstituted Furanones by Cu-Catalyzed Conjugate Addition		Chem.-Eur. J.	66	Endo, K	FALSE	FALSE	FALSE	FALSE
3820	10.1002/anie.201309074	doi.org/10.1002/anie.201309074	Asymmetric Palladium-Catalyzed Allylic Alkylation Using Dialkylzinc Reagents: A Remarkable Ligand Effect		Angew. Chem.-Int. Edit.	66	Maulide, N	FALSE	FALSE	FALSE	FALSE
3821	10.1002/ejoc.201402202	doi.org/10.1002/ejoc.201402202	Asymmetric Synthesis of 2-Heteroaryl Cyclic Amines: Total Synthesis of (-)-Anabasine		Eur. J. Org. Chem.	66	Gillaizeau, I	FALSE	FALSE	FALSE	FALSE
3822	10.1016/j.tet.2014.03.076	doi.org/10.1016/j.tet.2014.03.076	A novel sustainable strategy for the synthesis of phenols by magnetic CuFe2O4-catalyzed oxidative hydroxylation of arylboronic acids under mild conditions in water		Tetrahedron	66	Wang, H	FALSE	FALSE	FALSE	FALSE
3823	10.1021/ol403631k	doi.org/10.1021/ol403631k	Direct, Catalytic, and Regioselective Synthesis of 2-Alkyl-, Aryl-, and Alkenyl-Substituted N-Heterocycles from N-Oxides		Org. Lett.	66	Larionov, OV	FALSE	FALSE	FALSE	FALSE
3824	10.1039/c4cc05307a	doi.org/10.1039/c4cc05307a	Room-temperature palladium-catalyzed direct 2-arylation of benzoxazoles with aryl and heteroaryl bromides		Chem. Commun.	66	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
3825	10.1039/c3ra45212c	doi.org/10.1039/c3ra45212c	Experimental and theoretical studies on nickel-zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)-H compounds		RSC Adv.	66	Tang, G	FALSE	FALSE	FALSE	FALSE
3826	10.1039/c4ob00642a	doi.org/10.1039/c4ob00642a	A neighboring group participation strategy: direct and highly diastereoselective synthesis of 2-substituted and 2,2-bisubstituted perhydrofuro[2,3-b] pyran derivatives		Org. Biomol. Chem.	66	Shao, HW	FALSE	FALSE	FALSE	FALSE
3827	10.1021/ar300318c	doi.org/10.1021/ar300318c	Unraveling the Mysteries of Microwave Chemistry Using Silicon Carbide Reactor Technology		Accounts Chem. Res.	66	Kappe, CO	FALSE	FALSE	FALSE	FALSE
3828	10.1016/j.tet.2013.04.073	doi.org/10.1016/j.tet.2013.04.073	Straightforward synthesis of substituted dibenzyl derivatives		Tetrahedron	66	Renaud, JL	FALSE	FALSE	FALSE	FALSE
3829	10.1002/ejoc.201300248	doi.org/10.1002/ejoc.201300248	A General Procedure for the Regioselective Synthesis of Aryl Thioethers and Aryl Selenides Through C-H Activation of Arenes		Eur. J. Org. Chem.	66	Lee, CF	FALSE	FALSE	FALSE	FALSE
3830	10.1021/ie3035338	doi.org/10.1021/ie3035338	Experimental and Theoretical Investigations of Consequence of Ionic Liquid Anion on Copper(I) Catalyzed Reaction of Aryl Iodide and Thiols		Ind. Eng. Chem. Res.	66	Gaikar, VG	FALSE	FALSE	FALSE	FALSE
3831	10.1016/j.tet.2012.12.086	doi.org/10.1016/j.tet.2012.12.086	Novel synthesis of 1,4,5-trisubstituted 1,2,3-triazoles via a one-pot three-component reaction of boronic acids, azide, and active methylene ketones		Tetrahedron	66	Cao, S	FALSE	FALSE	FALSE	FALSE
3832	10.3998/ark.5550190.0014.205	doi.org/10.3998/ark.5550190.0014.205	Design and synthesis of new bis-hydrazones and pyridine bis-hydrazones: application in the asymmetric Diels-Alder reaction		Arkivoc	66	Fernandez, R	FALSE	FALSE	FALSE	FALSE
3833	10.1002/anie.201200328	doi.org/10.1002/anie.201200328	C-H Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron sigma-Allyl Complexes		Angew. Chem.-Int. Edit.	66	Stephan, DW	FALSE	FALSE	FALSE	FALSE
3834	10.1002/ejoc.200901321	doi.org/10.1002/ejoc.200901321	A Concise, Metal-Free Approach to the Synthesis of Oxime Ethers from Cross-Dehydrogenative-Coupling of sp(3) C-H Bonds with Oximes		Eur. J. Org. Chem.	66	Qian, WX	FALSE	FALSE	FALSE	FALSE
3835	10.1021/ja904152r	doi.org/10.1021/ja904152r	Iridium Phosphite-Oxazoline Catalysts for the Highly Enantioselective Hydrogenation of Terminal Alkenes		J. Am. Chem. Soc.	66	Borner, A	FALSE	FALSE	FALSE	FALSE
3836	10.1021/ol802049t	doi.org/10.1021/ol802049t	Palladium-Catalyzed Hiyama Cross-Coupling Reactions of Aryl Mesylates		Org. Lett.	66	Yang, PY	FALSE	FALSE	FALSE	FALSE
3837	10.1021/jo048702k	doi.org/10.1021/jo048702k	Palladium-catalyzed [2+2+2] cocyclotrimerization of benzynes with bicyclic alkenes: An efficient route to anellated 9,10-dihydrophenanthrene derivatives and polyaromatic compounds		J. Org. Chem.	66	Cheng, CH	FALSE	FALSE	FALSE	FALSE
3838	10.1002/anie.200352633	doi.org/10.1002/anie.200352633	The tertiary sulfonamide as a latent directed-metalation group: Ni-0-catalyzed reductive cleavage and cross-coupling reactions of aryl sulfonamides with Grignard reagents		Angew. Chem.-Int. Edit.	66	Snieckus, V	FALSE	FALSE	FALSE	FALSE
3839	10.1246/bcsj.63.80	doi.org/10.1246/bcsj.63.80	HOMOCOUPLING OF ARYL HALIDES USING NICKEL(II) COMPLEX AND ZINC IN THE PRESENCE OF ET4NI - AN EFFICIENT METHOD FOR THE SYNTHESIS OF BIARYLS AND BIPYRIDINES		Bull. Chem. Soc. Jpn.	66	IYODA, M	FALSE	FALSE	FALSE	FALSE
3840	10.1021/ja00239a029	doi.org/10.1021/ja00239a029	CHEMOSELECTIVITY AND STEREOCONTROL IN MOLYBDENUM-CATALYZED ALLYLIC ALKYLATIONS		J. Am. Chem. Soc.	66	TROST, BM	FALSE	FALSE	FALSE	FALSE
3841	10.1021/jo00370a006	doi.org/10.1021/jo00370a006	OPTICALLY-ACTIVE ALLYLSILANES .10. ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE TRANSITION-METAL COMPLEXES .3. PREPARATION OF OPTICALLY-ACTIVE ALLYLSILANES BY PALLADIUM-CATALYZED ASYMMETRIC GRIGNARD CROSS-COUPLING		J. Org. Chem.	66	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
3842	10.1039/d1sc06701j	doi.org/10.1039/d1sc06701j	Palladium-catalyzed chemoselective direct alpha-arylation of carbonyl compounds with chloroaryl triflates at the C-Cl site		Chem. Sci.	66	So, CM	FALSE	FALSE	FALSE	FALSE
3843	10.1021/acscatal.1c04895	doi.org/10.1021/acscatal.1c04895	Acetate Facilitated Nickel Catalyzed Coupling of Aryl Chlorides and Alkyl Thiols		ACS Catal.	66	Wagner, JP; Fleischer, I	FALSE	FALSE	FALSE	FALSE
3844	10.1038/s41598-022-05747-1	doi.org/10.1038/s41598-022-05747-1	Synthesis and characterization of dendritic compounds containing nitrogen: monomer precursors in the construction of biomimetic membranes		Sci Rep	66	Montane, X	FALSE	FALSE	FALSE	FALSE
3845	10.1021/jacs.1c12622	doi.org/10.1021/jacs.1c12622	Catalytic Amination of Phenols with Amines		J. Am. Chem. Soc.	66	Shi, H	FALSE	FALSE	FALSE	FALSE
3846	10.1021/acs.joc.1c02659	doi.org/10.1021/acs.joc.1c02659	Access to gem-Difluoroalkenes via Organic Photoredox-Catalyzed gem-Difluoroallylation of Alkyl Iodides		J. Org. Chem.	66	Zhang, ZM; Wang, T	TRUE	FALSE	FALSE	FALSE
3847	10.1002/cctc.202101237	doi.org/10.1002/cctc.202101237	Mixed Alkyl/Aryl Diphos Ligands for Iron-Catalyzed Negishi and Kumada Cross Coupling Towards the Synthesis of Diarylmethane		ChemCatChem	66	Zhang, J	FALSE	FALSE	FALSE	FALSE
3848	10.1016/j.tet.2021.132472	doi.org/10.1016/j.tet.2021.132472	Manganese(I) catalyzed cross-coupling of secondary allylic alcohols and primary alcohols		Tetrahedron	66	Gunanathan, C	FALSE	FALSE	FALSE	FALSE
3849	10.3390/catal11091103	doi.org/10.3390/catal11091103	Evaluation of 3,3 '-Triazolyl Biisoquinoline N,N '-Dioxide Catalysts for Asymmetric Hydrosilylation of Hydrazones with Trichlorosilane		Catalysts	66	Peverati, R; Takenaka, N	FALSE	FALSE	FALSE	FALSE
3850	10.1021/jacs.1c06553	doi.org/10.1021/jacs.1c06553	Access to Highly Stereodefined 1,4-cis-Polydienes by a [Ni/Mg] Orthogonal Tandem Catalytic Polymerization		J. Am. Chem. Soc.	66	Mazet, C	FALSE	FALSE	FALSE	FALSE
3851	10.1021/acs.orglett.1c02093	doi.org/10.1021/acs.orglett.1c02093	Pd-Catalyzed Asymmetric Acyl-Carbamoylation of an Alkene to Construct an alpha-Quaternary Chiral Cycloketone		Org. Lett.	66	Xu, H; Dai, HX	FALSE	FALSE	FALSE	FALSE
3852	10.1007/s11164-021-04528-1	doi.org/10.1007/s11164-021-04528-1	Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling		Res. Chem. Intermed.	66	Pore, DM	FALSE	FALSE	FALSE	FALSE
3853	10.1021/jacs.1c03763	doi.org/10.1021/jacs.1c03763	One to Find Them All: A General Route to Ni(I)-Phenolate Species		J. Am. Chem. Soc.	66	Morandi, B	FALSE	FALSE	FALSE	FALSE
3854	10.1002/tcr.202100089	doi.org/10.1002/tcr.202100089	Recent Advances in the Pd-Catalyzed Coupling of Arylhydrazines and Ammonium Salts via C-N Bond Cleavage		Chem. Rec.	66	Zhao, JF	FALSE	FALSE	FALSE	FALSE
3855	10.1021/jacs.1c03126	doi.org/10.1021/jacs.1c03126	Site-Selective Defluorinative sp(3) C-H Alkylation of Secondary Amides		J. Am. Chem. Soc.	66	Martin, R	FALSE	FALSE	FALSE	FALSE
3856	10.1039/d1cc00769f	doi.org/10.1039/d1cc00769f	Palladium-catalyzed one-pot phosphorylation of phenols mediated by sulfuryl fluoride		Chem. Commun.	66	Ma, PX; Xu, HT	FALSE	FALSE	FALSE	FALSE
3857	10.1021/jacs.1c01086	doi.org/10.1021/jacs.1c01086	Nickel-Sulfonate Mode of Substrate Binding for Forward and Reverse Reactions of Methyl-SCoM Reductase Suggest a Radical Mechanism Involving Long-Range Electron Transfer		J. Am. Chem. Soc.	66	Ragsdale, SW	FALSE	TRUE	FALSE	FALSE
3858	10.1021/jacs.7b06469	doi.org/10.1021/jacs.7b06469	Nickel-Catalyzed Defluorinative Reductive Cross-Coupling of gem-Difluoroalkenes with Unactivated Secondary and Tertiary Alkyl Halides		J. Am. Chem. Soc.	66	Gong, TJ; Fu, Y	FALSE	FALSE	FALSE	FALSE
3859	10.1002/cjoc.201700071	doi.org/10.1002/cjoc.201700071	Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Bromides with Pyrimidin-2-yl Tosylates		Chin. J. Chem.	66	Wang, XC; Quan, ZJ	FALSE	TRUE	FALSE	FALSE
3860	10.1002/adsc.201700290	doi.org/10.1002/adsc.201700290	Nickel-Catalyzed Sulfonylation of C(sp(2))-H Bonds with Sodium Sulfinates		Adv. Synth. Catal.	66	Gong, JF; Song, MP	FALSE	FALSE	FALSE	FALSE
3861	10.1002/ejoc.201700660	doi.org/10.1002/ejoc.201700660	Nickel-Catalyzed Amination of Aryl Carbamates with Ammonia		Eur. J. Org. Chem.	66	Schranck, J	FALSE	FALSE	FALSE	FALSE
3862	10.1002/anie.201703486	doi.org/10.1002/anie.201703486	Nickel-Catalyzed alpha-Allylation of Aldehydes and Tandem Aldol Condensation/Allylation Reaction with Allylic Alcohols		Angew. Chem.-Int. Edit.	66	Sauthier, M	FALSE	FALSE	FALSE	FALSE
3863	10.1002/anie.201703400	doi.org/10.1002/anie.201703400	A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl-Aryl Cross-Coupling of Aryl Halides and Olefins		Angew. Chem.-Int. Edit.	66	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
3864	10.1055/s-0036-1588692	doi.org/10.1055/s-0036-1588692	Iridium-Catalyzed Anti-Stereoselective Ring-Opening Reactions of Azabicyclic Alkenes with Fluoroalkylamines		Synthesis	66	Yang, DQ	FALSE	FALSE	FALSE	FALSE
3865	10.1016/j.poly.2016.10.005	doi.org/10.1016/j.poly.2016.10.005	Synthesis, characterization, and cycloaddition reaction studies of zinc(II) acetate complexes containing 2,6-bis(pyrazol-1-yl)pyridine and 2,6-bis (3,5-dimethylpyrazol-1-yl)pyridine ligands		Polyhedron	66	Kim, Y	FALSE	FALSE	FALSE	FALSE
3866	10.1021/acs.joc.7b00002	doi.org/10.1021/acs.joc.7b00002	Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance		J. Org. Chem.	66	Baidya, M	FALSE	FALSE	FALSE	FALSE
3867	10.1021/acs.organomet.6b00885	doi.org/10.1021/acs.organomet.6b00885	Evaluating 1,1'-Bis(phosphino)ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C-N Cross-Coupling of (Hetero)aryl Chlorides		Organometallics	66	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
3868	10.1016/j.tet.2016.10.018	doi.org/10.1016/j.tet.2016.10.018	Pd-catalyzed Suzuki-Miyaura cross-coupling of [Ph2SR][OTf] with arylboronic acids		Tetrahedron	66	Zhang, CP	FALSE	FALSE	FALSE	FALSE
3869	10.1002/anie.201607270	doi.org/10.1002/anie.201607270	ortho-C-H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium		Angew. Chem.-Int. Edit.	66	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
3870	10.1016/j.ica.2016.07.048	doi.org/10.1016/j.ica.2016.07.048	Nickel(II) and nickel(0) complexes of bis(diisopropylphosphino)amine: Synthesis, structure, and electrochemical activity		Inorg. Chim. Acta	66	Lam, K; Kemp, RA	FALSE	FALSE	FALSE	FALSE
3871	10.1002/chem.201604504	doi.org/10.1002/chem.201604504	Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates		Chem.-Eur. J.	66	Rueping, M	FALSE	FALSE	FALSE	FALSE
3872	10.1016/j.tet.2016.07.063	doi.org/10.1016/j.tet.2016.07.063	A modified Cu(0)-Cu(I)-mediated C-aryl-C-aryl Ullmann coupling for the synthesis of biaryls		Tetrahedron	66	Ploypradith, P	FALSE	FALSE	FALSE	FALSE
3873	10.1002/anie.201604329	doi.org/10.1002/anie.201604329	Gold(I)-Catalyzed N-Desulfonylative Amination versus N-to-O 1,5-Sulfonyl Migration: A Versatile Approach to 1-Azabicycloalkanes		Angew. Chem.-Int. Edit.	66	Pale, P; Blanc, A	FALSE	FALSE	FALSE	FALSE
3874	10.1021/acsmacrolett.6b00279	doi.org/10.1021/acsmacrolett.6b00279	C-H Arylation in the Synthesis of pi-Conjugated Polymers		ACS Macro Lett.	66	Luscombe, CK	FALSE	FALSE	FALSE	FALSE
3875	10.1016/j.tet.2016.02.069	doi.org/10.1016/j.tet.2016.02.069	Palladium catalyzed Mizoroki-Heck reaction of pyrimidin-2-yl tosylates with aromatic and aliphatic olefins		Tetrahedron	66	Quan, ZJ; Wang, XC	FALSE	FALSE	FALSE	FALSE
3876	10.1021/acs.orglett.5b03455	doi.org/10.1021/acs.orglett.5b03455	Nickel-Catalyzed Borylation of Benzylic Ammonium Salts: Stereospecific Synthesis of Enantioenriched Benzylic Boronates		Org. Lett.	66	Watson, MP	FALSE	FALSE	FALSE	FALSE
3877	10.1039/c6cc01312k	doi.org/10.1039/c6cc01312k	Palladium-catalyzed C(sp(3))-C(sp(2)) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: efficient synthesis of functionalized benzyltrimethylsilanes		Chem. Commun.	66	Yao, B; Li, XF	FALSE	FALSE	FALSE	FALSE
3878	10.1039/d0dt04121a	doi.org/10.1039/d0dt04121a	Mechanism of nickel-catalyzed direct carbonyl-Heck coupling reaction: the crucial role of second-sphere interactions	The development of metal-catalysed cross-coupling reactions between one electrophilic and one organometallic nucleophilic partner has revolutionized the practice of chemical synthesis, with coupling reactions between sp(2) centres now commonplace in both academic and industrial research. Methods to allow coupling of sp(3) centres are rapidly being developed, with many recent advances even enabling control of the absolute configuration of newly formed stereogenic centres. The related cross-electrophile couplings have not been developed as thoroughly owing to the challenge of obtaining cross-selectivity between two substrates with similar reactivity. However, the discovery of improved methods to address this challenge has led to significant recent progress. The development of enantioselective cross-electrophile coupling reactions is an emerging area of research. Both stereoconvergent and stereospecific variants have been reported for the synthesis of a range of products containing tertiary stereogenic centres. Many of these transformations build on lessons learnt from traditional (electrophile-nucleophile) cross-couplings of alkyl electrophiles. For example, all enantioselective transformations described to date use a nickel catalyst. Continued progression is likely to provide strategic disconnections for asymmetric synthesis of natural products and medicinal agents.	Dalton Trans.	65	Wu, YB	FALSE	FALSE	FALSE	FALSE
3879	10.1039/d0dt04082g	doi.org/10.1039/d0dt04082g	alpha-Alkylation of arylacetonitriles with primary alcohols catalyzed by backbone modified N-heterocyclic carbene iridium(I) complexes	Sulfated tungstate catalyzed environmentally benign, simple, one pot, and solvent-free method has been developed for the synthesis of 1,3,5-triarylbenzenes via cyclic self-condensation of three molecules of aryl ketones. High yields, short reaction time, easy work-up procedure and recycling of the catalyst endorse advantage. (C) 2017 Elsevier Ltd. All rights reserved.	Dalton Trans.	65	Gulcemal, S	FALSE	FALSE	FALSE	FALSE
3880	10.21577/0103-5053.20200192	doi.org/10.21577/0103-5053.20200192	Theoretical Study of the Reactivity of Phenyl Radicals Toward Enol Acetates	A Ni-catalyzed oxidative C-H/C-H cross-dehydrogenative coupling (CDC) reaction was developed for constructing various highly functionalized alkyl (aryl)-substituted thiophenes. This method employs thiophenes and aliphatic (aromatic) amides that contain an 8-aminoquinoline as a removable directing group in the presence of a silver oxidant. The approach enables the facile one-step synthesis of substituted thiophenes with high functional group compatibility via double C-H bond cleavage without affecting C-Br and C-I bonds. DFT calculations verify the importance of KH2PO4 as an additive for promoting C-H bond cleavage and support the involvement of a Ni(III) species in the reaction.	J. Braz. Chem. Soc.	65	Buarque, CD	FALSE	FALSE	FALSE	FALSE
3881	10.1016/j.jfluchem.2020.109695	doi.org/10.1016/j.jfluchem.2020.109695	2-Position-selective C-H fluoromethylation of six-membered heteroaryl N-oxides with (fluoromethyl)triphenylphosphonium iodide	The cross-coupling of aryltrimethylammonium triflates with AIMe(3) and beta-H-containing trialkylaluminums was performed in dioxane at 110 C-omicron under catalysis of (dPPP)NiCl2 to afford alkylated arenes. The cross-coupling of 2-menaphthyltrimethylammonium triflate with trialkylaluminums and 1-naphthyltrimethylammonium triflate with triarylaluminums was also carried out respectively under the same conditions. (C) 2017 Elsevier Ltd. All rights reserved.	J. Fluor. Chem.	65	Qing, FL	FALSE	FALSE	FALSE	FALSE
3882	10.1039/d0cc07216h	doi.org/10.1039/d0cc07216h	Hydrogen-bonded nickel(i) complexes	A robust acenaphthoimidazolylidene gold complex is demonstrated as a highly efficient catalyst in the direct alkylsulfonylation of boronic acids. Remarkably, a wide range of highly reactive and unreactive C-electrophiles were well tolerated to produce various (hetero)aryl-alkyl, aryl-alkenyl, and alkenyl-alkyl sulfones in satisfactory yields with 5 mol % catalyst loading. Along with the steric properties of NHC ligands, the high catalytic activity of this gold complex suggests that the strong sigma-donation of acenaphthoimidazolylidene also played a role in promoting this challenging redox-neutral catalytic process.	Chem. Commun.	65	Szymczak, NK	FALSE	FALSE	FALSE	FALSE
3883	10.1021/acs.orglett.0c03786	doi.org/10.1021/acs.orglett.0c03786	C(sp(3))-H Monoarylation of Methanol Enabled by a Bidentate Auxiliary	An Fe/Cu-mediated one-pot ketone synthesis was reported; Unlike Ni- and Pd-mediated one-pot ketone syntheses, the reported Fe/Cu-mediated method allowed selective activation and coupling of alkyl iodides over vinyl iodides. The newly developed one-pot ketone synthesis was applied to a synthesis of vinyl iodide/ketone 13, the left half of halichondrin B, as well as vinyl iodide/ketone 8a, the C20-C26 building block of halichondrins.	Org. Lett.	65	Gou, Q; Yuan, BF	FALSE	FALSE	FALSE	FALSE
3884	10.1080/14756366.2021.1900165	doi.org/10.1080/14756366.2021.1900165	Transition metal-catalysed A-ring C-H activations and C(sp(2))-C(sp(2)) couplings in the 13 alpha-oestrone series and in vitro evaluation of antiproliferative properties	Bimetallic effects on stoichiometric beta-hydride elimination and migratory insertion reactions were examined. Bimetallic reaction conditions drove beta-hydride elimination at Cu, while bimetallic C-B elimination occurred in the absence of beta-hydrogens. The inherent migratory insertion chemistry of alkynes at Ni was diverted under bimetallic reaction conditions to favor C-H deprotonation.	J. Enzym. Inhib. Med. Chem.	65	Mernyak, E	FALSE	FALSE	FALSE	FALSE
3885	10.1021/jacs.0c09639	doi.org/10.1021/jacs.0c09639	Cleavage of C(sp(3))-F Bonds in Trifluoromethylarenes Using a Bis(NHC)nickel(0) Complex	Ni-II-catalyzed C-N cross-coupling reaction of secondary acyclic amides (2-picolinamides, which were derived from 2-picolinic acid and amines) and aryl halides for the construction of tertiary amides has been reported. Relatively inexpensive NiCl2 was used as the catalyst for the N-arylation of various 2-picolinamides (secondary acyclic amides), in which the 2-picolinamide unit plausibly served as an internal ligand.	J. Am. Chem. Soc.	65	Ogoshi, S	FALSE	FALSE	FALSE	FALSE
3886	10.1055/a-1282-9731	doi.org/10.1055/a-1282-9731	Nickel-Catalyzed alpha-1,3-Dienylation of 1,3-Dicarbonyl Compounds with Propargylic Carbonates	Organic synthesis efficiency can take considerable advantage from microwave heating. Compared to conventional heating, it allows to improve the reactions speed and yield through an energy-efficient, clean, and easy-to-use processing tool. Transition-metal catalyzed cross-coupling reactions and in particular the Suzuki-Miyaura cross-coupling is powerful and widely used tool for the formation of carbon-carbon bonds. Cross coupling reactions are of large interest for the bonding of a broad range of functional groups, in particular biaryl groups, allowing for a strong stereoselectivity. In this paper, recent research results concerning the application of microwave heating in Suzuki-Miyaura cross-coupling reactions are reviewed with particular emphasis on reactions involving supported Pd as a catalyst.	Synlett	65	Ishida, N; Murakami, M	FALSE	FALSE	FALSE	FALSE
3887	10.1021/acs.organomet.0c00485	doi.org/10.1021/acs.organomet.0c00485	Ni((4-tBu)stb)(3): A Robust 16-Electron Ni(0) Olefin Complex for Catalysis	A ligand-free, highly efficient Cu-catalytic N-arylation of iminodibenzyl and iminostilbene derivatives with a broad scope of unactivated aryl halides under mild conditions has been developed for the first time. Moreover, the first Ni-based catalytic system was also applied to the N-arylation of pre-existing derivatives. These novel protocols provide facile and convenient access to the construction of dibenzazepines and offer promising alternatives to the widely used palladium catalysts.	Organometallics	65	Cornella, J	FALSE	TRUE	FALSE	FALSE
3888	10.1002/chem.202002800	doi.org/10.1002/chem.202002800	Nickel-Catalyzed Amination of (Hetero)aryl Halides Facilitated by a Catalytic Pyridinium Additive	Several procedures were evaluated for the preparation of lithium 4,4'-di-tert-butylbiphenylide (LiDBB, Freeman's reagent) from lithium metal and 4,4'-di-tert-butylbiphenyl (DBB) in THF. Solutions with nominal concentration of 0.4 and 1.0 M were formed. The stability of LiDBB solutions was evaluated over time, and the gradual uptake of lithium metal was observed. At 0 degrees C the LiDBB solutions were stable for over a week in THF. At 20 degrees C the LiDBB solution underwent various decomposition pathways, which led to uptake of more lithium metal and the accumulation of side products. These decomposition pathways were studied, and the importance of ethene in the destruction of THF by LiDBB was observed. On a practical note, LiDBB solutions in THF were stable and effective for over a week at 0 degrees C or for more than 37 weeks when stored under argon at -25 degrees C. These observations will extend the utility of LiDBB as a reagent in organic synthesis.	Chem.-Eur. J.	65	Jin, J	FALSE	FALSE	FALSE	FALSE
3889	10.1021/acs.orglett.0c02016	doi.org/10.1021/acs.orglett.0c02016	Co(III)-Catalyzed Annulative Vinylene Transfer via C-H Activation: Three-Step Total Synthesis of 8-Oxopseudopalmatine and Oxopalmatine	An iridium photocatalyst and visible light facilitate a room temperature, nickel-catalyzed coupling of (hetero)aryl bromides with activated alpha-heterosubstituted or benzylic C(sp(3))-H bonds. Mechanistic investigations on this unprecedented transformation have uncovered the possibility of an unexpected mechanism hypothesized to involve a Ni-Br homolysis event from an excited-state nickel complex. The resultant bromine radical is thought to abstract weak C(sp(3))-H bonds to generate reactive alkyl radicals that can be engaged in Ni-catalyzed arylation. Evidence suggests that the iridium photocatalyst facilitates nickel excitation and bromine radical generation via triplet-triplet energy transfer.	Org. Lett.	65	Xiao, Q; Zhang, YF	FALSE	FALSE	FALSE	FALSE
3890	10.1002/chem.202001685	doi.org/10.1002/chem.202001685	Unexpected Vulnerability of DPEphos to C-O Activation in the Presence of Nucleophilic Metal Hydrides	Nickel can be used to promote oxidative C(sp(2))-H/C(sp(2))-H cross-coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional-group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.	Chem.-Eur. J.	65	Whittlesey, MK	FALSE	FALSE	FALSE	FALSE
3891	10.1021/acs.jpcb.0c03844	doi.org/10.1021/acs.jpcb.0c03844	Uracil-5-yl O-Sulfamate: An Illusive Radiosensitizer. Pitfalls in Modeling the Radiosensitizing Derivatives of Nucleobases	Cross-coupling is a fundamental reaction in the synthesis of functional molecules, and has been widely applied, for example, to phenols, anilines, alcohols, amines and their derivatives. Here we report the Ni-catalysed Stille cross-coupling reaction of quaternary ammonium salts via C-N bond cleavage. Aryl/alkyl-trimethylammonium salts [Ar/R-NMe3](+) react smoothly with arylstannanes in 1: 1 molar ratio in the presence of a catalytic amount of commercially available Ni(cod)(2) and imidazole ligand together with 3.0 equivalents of CsF, affording the corresponding biaryl with broad functional group compatibility. The reaction pathway, including C-N bond cleavage step, is proposed based on the experimental and computational findings, as well as isolation and single-crystal X-ray diffraction analysis of Ni-containing intermediates. This reaction should be widely applicable for transformation of amines/quaternary ammonium salts into multi-aromatics.	J. Phys. Chem. B	65	Rak, J	FALSE	FALSE	FALSE	FALSE
3892	10.6023/cjoc201912030	doi.org/10.6023/cjoc201912030	Palladium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Potassium Trifluoroborate Salts	A unique C-H allylation has been discovered with unbiased aliphatic olefins. An intimate M-L affiliation between a high-valent cobalt catalyst and amino-quinoline derived benzamides has been found to be crucial for this unprecedented selectivity. An exemplary set of aliphatic olefins, high yields coupled with excellent regio- and stereoselectivity, and wide functional group tolerances are noteworthy. In addition, a catalytically competent organometallic Co(III) species has been identified through X-ray crystallography. This study is expected to facilitate new synthetic designs toward unconventional allylic selectivity with aliphatic olefins.	Chin. J. Org. Chem.	65	Huang, GB; Li, XY	FALSE	FALSE	FALSE	FALSE
3893	10.1021/acs.joc.0c00899	doi.org/10.1021/acs.joc.0c00899	Transition-Metal-Free Stereospecific Oxidative Annulative Coupling of Indolines with Aziridines	Deprotonative directed ortho cupration of aromatic/heteroaromatic C-H bond and subsequent oxidation with t-BuOOH furnished functionalized phenols in high yields with high regio- and chemoselectivity. DFT calculations revealed that this hydroxylation reaction proceeds via a copper (I -> III -> I) redox mechanism. Application of this reaction to aromatic C-H amination using BnONH2 efficiently afforded the corresponding primary anilines. These reactions show broad scope and good functional group compatibility. Catalytic versions of these transformations are also demonstrated.	J. Org. Chem.	65	Punniyamurthy, T	FALSE	FALSE	FALSE	FALSE
3894	10.1021/jacs.0c03589	doi.org/10.1021/jacs.0c03589	Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction	A strategy for cross-electrophile coupling has been developed via the merger of photoredox and transition metal catalysis. In this report, we demonstrate the use of commercially available tris(trimethylsilyl)silane with metallaphotoredox catalysis to efficiently couple alkyl bromides with aryl or heteroaryl bromides in excellent yields. We hypothesize that a photocatalytically generated silyl radical species can perform halogen-atom abstraction to activate alkyl halides as nucleophilic cross-coupling partners. This protocol allows the use of mild yet robust conditions to construct C-sp(3)-C-sp(2) bonds generically via a unique cross-coupling pathway.	J. Am. Chem. Soc.	65	Sigman, MS	FALSE	FALSE	FALSE	FALSE
3895	10.1016/j.tet.2020.131201	doi.org/10.1016/j.tet.2020.131201	Ni(II)/tBu-SMI-PHOX catalyzed enantioselective addition of arylboronic acids to cyclic N-sulfonyl aldimines	A practical and highly stereoselective iron-catalyzed cross-coupling reaction of stereodefined enol carbamates and Grignard reagents to yield tri- and tetrasubstituted acrylates is reported. A facile method for the stereoselective generation of these enol carbamates has also been developed.	Tetrahedron	65	Cao, GR; Teng, DW	FALSE	FALSE	FALSE	FALSE
3896	10.1021/jacs.0c02839	doi.org/10.1021/jacs.0c02839	Catalytic Deoxygenative Coupling of Aromatic Esters with Organophosphorus Compounds	The development of practical, efficient, and atom-economical methods for the formation of carbon-carbon bonds remains a topic of considerable interest in current synthetic organic chemistry. In this review, we have summarized selected topics from the recent literature with particular emphasis on C-alkylation processes involving hydrogen transfer using alcohols as alkylation reagents. This review includes selected highlights concerning recent progress towards the modification of catalytic systems for the alpha-alkylation of ketones, nitriles, and esters. Furthermore, we have devoted a significant portion of this review to the methylation of ketones, alcohols, and indoles using methanol. Lastly, we have also documented recent advances in beta-alkylation methods involving the dimerization of alcohols (Guerbet reaction), as well as new developments in C-alkylation methods based on sp 3 C-H activation.	J. Am. Chem. Soc.	65	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
3897	10.1021/jacs.0c01724	doi.org/10.1021/jacs.0c01724	Synthesis of beta-Phenethylamines via Ni/Photoredox Cross-Electrophile Coupling of Aliphatic Aziridines and Aryl Iodides	Highly active aluminium hydroxide supported nanopalladium-catalyzed Suzuki-Miyaura coupling reactions of potassium aryl- and heteroaryltrifluoroborates with aryldiazonium salts or aromatic, heteroaromatic halides have been achieved, respectively. Most substrates were shown to cross-couple with ease to aryl compounds as well as to a variety of heteroaromatic bromides in good to excellent yields.	J. Am. Chem. Soc.	65	Doyle, AG	TRUE	TRUE	FALSE	FALSE
3898	10.1021/acs.orglett.0c00679	doi.org/10.1021/acs.orglett.0c00679	Iron-Catalyzed Borylation of Aryl Ethers via Cleavage of C-O Bonds	Recently, esters have received much attention as transmetalation partners for cross-coupling reactions. Herein, we report a systematic study of the reactivity of a series of esters and thioesters with [{(dtbpe)Ni}(2)(-(2):(2)-C6H6)] (dtbpe=1,2-bis(di-tert-butyl)phosphinoethane), which is a source of (dtbpe)nickel(0). Trifluoromethylthioesters were found to form (2)-carbonyl complexes. In contrast, acetylthioesters underwent rapid C-acyl-S bond cleavage followed by decarbonylation to generate methylnickel complexes. This decarbonylation could be pushed backwards by the addition of CO, allowing for regeneration of the thioester. Most of the thioester complexes were found to undergo stoichiometric cross-coupling with phenylboronic acid to yield sulfides. While ethyl trifluoroacetate was also found to form an (2)-carbonyl complex, phenyl esters were found to predominantly undergo C-aryl-O bond cleavage to yield arylnickel complexes. These could also undergo transmetalation to yield biaryls. Attempts to render the reactions catalytic were hindered by ligand scrambling to yield nickel bis(acetate) complexes, the formation of which was supported by independent syntheses. Finally, 2-naphthyl acetate was also found to undergo clean C-aryl-O bond cleavage, and although stoichiometric cross-coupling with phenylboronic acid proceeded with good yield, catalytic turnover has so far proven elusive.	Org. Lett.	65	Feng, Z	FALSE	FALSE	FALSE	FALSE
3899	10.1021/jacs.0c00123	doi.org/10.1021/jacs.0c00123	Catalytic Acceptorless Dehydrogenation of Aliphatic Alcohols	Herein, we describe a novel copper-catalyzed epoxide opening reaction with gem-diborylmethane. Aliphatic, aromatic epoxides as well as aziridines are converted to the corresponding gamma-pinacolboronate alcohols or amines in moderate to excellent yields. This new reaction provides beneficial applications for classic epoxide substrates as well as interesting gem-diborylalkane reagents.	J. Am. Chem. Soc.	65	Mitsunuma, H; Kanai, M	FALSE	FALSE	FALSE	FALSE
3900	10.1039/c9ob02667c	doi.org/10.1039/c9ob02667c	Chemical transformations of quaternary ammonium salts via C-N bond cleavage		Org. Biomol. Chem.	65	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3901	10.1002/anie.201915218	doi.org/10.1002/anie.201915218	Synergistic Relay Reactions To Achieve Redox-Neutral alpha-Alkylations of Olefinic Alcohols with Ruthenium(II) Catalysis		Angew. Chem.-Int. Edit.	65	Li, CJ	FALSE	FALSE	FALSE	FALSE
3902	10.1021/acs.orglett.9b04117	doi.org/10.1021/acs.orglett.9b04117	Continuous Flow Enables Metallaphotoredox Catalysis in a Medicinal Chemistry Setting: Accelerated Optimization and Library Execution of a Reductive Coupling between Benzylic Chlorides and Aryl Bromides		Org. Lett.	65	Brill, ZG	FALSE	FALSE	FALSE	FALSE
3903	10.1039/c9cc07072a	doi.org/10.1039/c9cc07072a	Formation of allylated quaternary carbon centers via C-O/C-O bond fragmentation of oxalates and allyl carbonates		Chem. Commun.	65	Gong, HG	FALSE	FALSE	FALSE	FALSE
3904	10.1002/anie.201913825	doi.org/10.1002/anie.201913825	Enantioselective Synthesis of 3-Substituted Cyclobutenes by Catalytic Conjugate Addition/Trapping Strategies		Angew. Chem.-Int. Edit.	65	Lu, P	FALSE	FALSE	FALSE	FALSE
3905	10.1021/acscatal.9b03894	doi.org/10.1021/acscatal.9b03894	Catalytic Dehydrative Peptide Synthesis with gem-Diboronic Acids		ACS Catal.	65	Takemoto, Y	FALSE	FALSE	FALSE	FALSE
3906	10.1039/c9ob02107h	doi.org/10.1039/c9ob02107h	Double C-N bond cleavages of N-alkyl 4-oxopiperidinium salts: access to unsymmetrical tertiary sulfonamides		Org. Biomol. Chem.	65	Fu, Y; Du, ZY; Huo, CD	FALSE	FALSE	FALSE	FALSE
3907	10.1021/acs.joc.9b02094	doi.org/10.1021/acs.joc.9b02094	Ni-Catalyzed C-H Arylation of Oxazoles and Benzoxazoles Using Pharmaceutically Relevant Aryl Chlorides and Bromides		J. Org. Chem.	65	Kalyani, D	FALSE	FALSE	FALSE	FALSE
3908	10.1021/acs.oprd.9b00232	doi.org/10.1021/acs.oprd.9b00232	Metal-Reductant-Free Electrochemical Nickel-Catalyzed Couplings of Aryl and Alkyl Bromides in Acetonitrile		Org. Process Res. Dev.	65	Hansen, EC	FALSE	TRUE	FALSE	FALSE
3909	10.1002/ejic.201900692	doi.org/10.1002/ejic.201900692	Nickel Carbodicarbene Catalyzes Kumada Cross-Coupling of Aryl Ethers with Grignard Reagents through C-O Bond Activation		Eur. J. Inorg. Chem.	65	Ong, TG	FALSE	FALSE	FALSE	FALSE
3910	10.1021/acs.orglett.9b01014	doi.org/10.1021/acs.orglett.9b01014	Deaminative Reductive Cross-Electrophile Couplings of Alkylpyridinium Salts and Aryl Bromides		Org. Lett.	65	Watson, MP	FALSE	TRUE	FALSE	FALSE
3911	10.1021/acscatal.8b05111	doi.org/10.1021/acscatal.8b05111	Ni-Mediated Generation of CN Unit from Formamide and Its Catalysis in the Cyanation Reactions		ACS Catal.	65	Yang, L	FALSE	FALSE	FALSE	FALSE
3912	10.1021/acs.inorgchem.8b03425	doi.org/10.1021/acs.inorgchem.8b03425	CO Displacement in an Oxidative Addition of Primary Silanes to Rhodium(I)		Inorg. Chem.	65	Sadow, AD	FALSE	FALSE	FALSE	FALSE
3913	10.1038/s41467-019-08631-1	doi.org/10.1038/s41467-019-08631-1	Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel		Nat. Commun.	65	Li, CJ	FALSE	FALSE	FALSE	FALSE
3914	10.1021/jacs.8b13499	doi.org/10.1021/jacs.8b13499	Mechanistic Characterization of (Xantphos)Ni(I)-Mediated Alkyl Bromide Activation: Oxidative Addition, Electron Transfer, or Halogen-Atom Abstraction		J. Am. Chem. Soc.	65	Diao, TN	FALSE	TRUE	FALSE	FALSE
3915	10.1039/c8sc04162h	doi.org/10.1039/c8sc04162h	Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes		Chem. Sci.	65	Feng, C	FALSE	FALSE	FALSE	FALSE
3916	10.1039/c8ob02864h	doi.org/10.1039/c8ob02864h	Nickel- catalyzed syn- stereocontrolled ring- opening of oxa- and azabicyclic alkenes with dialkylzinc reagents		Org. Biomol. Chem.	65	Yang, DQ	FALSE	FALSE	FALSE	FALSE
3917	10.1039/c8qo00820e	doi.org/10.1039/c8qo00820e	Nickel catalyzed synthesis of 4,4-bichromenes/4,4-bithiochromenes and their Atropisomerism		Org. Chem. Front.	65	Kabilan, S	FALSE	FALSE	FALSE	FALSE
3918	10.1016/j.molstruc.2018.08.043	doi.org/10.1016/j.molstruc.2018.08.043	Syntheses, structures, and properties of three mixed-ligand complexes based on 3,6-bis(imidazole-1-yl)pyridazine		J. Mol. Struct.	65	Wang, DZ	FALSE	FALSE	FALSE	FALSE
3919	10.1002/anie.201810652	doi.org/10.1002/anie.201810652	Nitromethane as a Carbanion Source for Domino Benzoannulation with Ynones: One-Pot Synthesis of Polyfunctional Naphthalenes and a Total Synthesis of Macarpine		Angew. Chem.-Int. Edit.	65	Pabbaraja, S	FALSE	FALSE	FALSE	FALSE
3920	10.1002/ajoc.201800560	doi.org/10.1002/ajoc.201800560	Reaction of Quinoline N-Oxides and Pyridine N-Oxides with Arylzinc Reagents: Synthesis of 2-Arylquinolines and 2-Arylpyridines		Asian J. Org. Chem.	65	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3921	10.1021/jacs.8b08746	doi.org/10.1021/jacs.8b08746	Enol Acetates: Versatile Substrates for the Enantioselective Intermolecular Tsuji Allylation		J. Am. Chem. Soc.	65	Aponick, A	FALSE	FALSE	FALSE	FALSE
3922	10.1021/acs.orglett.8b02972	doi.org/10.1021/acs.orglett.8b02972	Intramolecular Desulfitative Coupling: Nickel-Catalyzed Transformation of Diaryl Sulfones into Biaryls via Extrusion of SO2		Org. Lett.	65	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
3923	10.1002/asia.201800478	doi.org/10.1002/asia.201800478	Pd-Catalyzed Decarbonylative C-H Coupling of Azoles and Aromatic Esters		Chem.-Asian J.	65	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
3924	10.1002/anie.201805486	doi.org/10.1002/anie.201805486	Cobalt-Catalyzed Cross-Couplings between Alkenyl Acetates and Aryl or Alkenyl Zinc Pivalates		Angew. Chem.-Int. Edit.	65	Knochel, P	FALSE	FALSE	FALSE	FALSE
3925	10.1039/c8qo00517f	doi.org/10.1039/c8qo00517f	Unsymmetrical CNN-palladacycles with geometry-constrained iminopyridyl ligands: an efficient precatalyst in Suzuki coupling for accessing 1,1-diarylalkanes from secondary benzylic bromides		Org. Chem. Front.	65	Jin, LQ; Hu, XQ	FALSE	FALSE	FALSE	FALSE
3926	10.1039/c8dt01852a	doi.org/10.1039/c8dt01852a	NIXANTPHOS: a highly active ligand for palladium catalyzed Buchwald-Hartwig amination of unactivated aryl chlorides		Dalton Trans.	65	Mao, JY; Walsh, PJ	FALSE	FALSE	FALSE	FALSE
3927	10.1039/c8dt00441b	doi.org/10.1039/c8dt00441b	1,1 '-Binaphthyl-substituted diphosphene: synthesis, structures, and chiral optical properties		Dalton Trans.	65	Tsurusaki, A; Kamikawa, K	FALSE	FALSE	FALSE	FALSE
3928	10.1021/acs.organomet.8b00005	doi.org/10.1021/acs.organomet.8b00005	Unsymmetrical Pincer N-Heterocyclic Carbene-Nitrogen-Phosphine Chelated Palladium(II) Complexes: Synthesis, Structure, and Reactivity in Direct Csp(2)-H Arylation of Benzoxazoles		Organometallics	65	Li, RX	FALSE	FALSE	FALSE	FALSE
3929	10.1039/c8ob00392k	doi.org/10.1039/c8ob00392k	Site-specific hydroxyalkylation of chromones via alcohol mediated Minisci-type radical conjugate addition		Org. Biomol. Chem.	65	Yu, JT; Cheng, J	FALSE	FALSE	FALSE	FALSE
3930	10.1039/c8ob00238j	doi.org/10.1039/c8ob00238j	A visible-light photocatalytic thiolation of aryl, heteroaryl and vinyl iodides		Org. Biomol. Chem.	65	Polyzos, A	FALSE	FALSE	FALSE	FALSE
3931	10.1039/c7sc05059c	doi.org/10.1039/c7sc05059c	A combined experimental and computational study on the reaction of fluoroarenes with Mg-Mg, Mg-Zn, Mg-Al and Al-Zn bonds		Chem. Sci.	65	Crimmin, MR	FALSE	FALSE	FALSE	FALSE
3932	10.1002/asia.201701224	doi.org/10.1002/asia.201701224	HMPA-Promoted Siladifluoromethylation of Di-, and Triarylmethanes with the Ruppert-Prakash Reagent		Chem.-Asian J.	65	Cao, S	FALSE	FALSE	FALSE	FALSE
3933	10.1039/c6ra16627j	doi.org/10.1039/c6ra16627j	Efficient hydroarylation and hydroalkenylation of vinylarenes by Bronsted acid catalysis		RSC Adv.	65	Xia, CG; Jiang, GX	FALSE	FALSE	FALSE	FALSE
3934	10.1002/anie.201506432	doi.org/10.1002/anie.201506432	Acyl Radicals from Aromatic Carboxylic Acids by Means of Visible-Light Photoredox Catalysis		Angew. Chem.-Int. Edit.	65	Wallentin, CJ	TRUE	FALSE	FALSE	FALSE
3935	10.1002/adsc.201500209	doi.org/10.1002/adsc.201500209	3-Naphthylindole Construction by Rhodium(II)-Catalyzed Regioselective Direct Arylation of Indoles with 1-Diazonaphthalen-2-(1H)-ones		Adv. Synth. Catal.	65	Baral, ER	FALSE	FALSE	FALSE	FALSE
3936	10.1002/adsc.201500301	doi.org/10.1002/adsc.201500301	An Efficient Synthesis of N-(Hetero)arylcarbazoles: Palladium-Catalyzed Coupling Reaction between (Hetero) aryl Chlorides and N-Carbazolylmagnesium Chloride		Adv. Synth. Catal.	65	Nakayama, Y	FALSE	FALSE	FALSE	FALSE
3937	10.1021/acs.orglett.5b00780	doi.org/10.1021/acs.orglett.5b00780	Scalable Synthesis of Fmoc-Protected GalNAc-Threonine Amino Acid and T-N Antigen via Nickel Catalysis		Org. Lett.	65	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
3938	10.1021/acs.joc.5b00065	doi.org/10.1021/acs.joc.5b00065	Platinum-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Phenols		J. Org. Chem.	65	Long, YH	FALSE	FALSE	FALSE	FALSE
3939	10.1002/chem.201405558	doi.org/10.1002/chem.201405558	Biaryl Synthesis by Ring-Opening Friedel-Crafts Arylation of 1,4-Epoxy-1,4-dihydronaphthalenes Catalyzed by Iron Trichloride		Chem.-Eur. J.	65	Sawama, Y	FALSE	FALSE	FALSE	FALSE
3940	10.1021/jo502541t	doi.org/10.1021/jo502541t	Synthesis of ortho-Haloaminoarenes by Aryne Insertion of Nitrogen-Halide Bonds		J. Org. Chem.	65	Wang, Q	FALSE	FALSE	FALSE	FALSE
3941	10.1039/c5ob00545k	doi.org/10.1039/c5ob00545k	Divergent synthesis of 4,6-diarylated pyridin-2(1H)-ones from chalcones: novel access to 2,4,6-triaryl pyridines		Org. Biomol. Chem.	65	Kapoor, KK	FALSE	FALSE	FALSE	FALSE
3942	10.1002/ejoc.201403354	doi.org/10.1002/ejoc.201403354	Transition-Metal-Free Synthesis of Fluorinated Nitriles and Diaryl Ketones Through a Selective C-F Bond Functionalization Under Mild Conditions		Eur. J. Org. Chem.	65	Yu, CM	FALSE	FALSE	FALSE	FALSE
3943	10.1039/c5cy00802f	doi.org/10.1039/c5cy00802f	Wool-anchored Pd(OAc)(2) complex: a highly active and reusable catalyst for desulfurative coupling reactions		Catal. Sci. Technol.	65	Yang, QL	FALSE	FALSE	FALSE	FALSE
3944	10.1016/j.tetlet.2014.09.129	doi.org/10.1016/j.tetlet.2014.09.129	Base initiated aromatization/C-O bond formation: a new entry to O-pyrazole polyfluoroarylated ethers		Tetrahedron Lett.	65	Liu, CB	FALSE	FALSE	FALSE	FALSE
3945	10.1016/j.jorganchem.2014.01.025	doi.org/10.1016/j.jorganchem.2014.01.025	Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of rhodium and iridium based devices		J. Organomet. Chem.	65	Aydemir, M	FALSE	FALSE	FALSE	FALSE
3946	10.1002/ejoc.201400090	doi.org/10.1002/ejoc.201400090	Selective Suzuki- Miyaura Monocouplings with Symmetrical Dibromoarenes and Aryl Ditriflates for the One- Pot Synthesis of Unsymmetrical Triaryls		Eur. J. Org. Chem.	65	Dodd, RH	FALSE	FALSE	FALSE	FALSE
3947	10.1016/j.tetlet.2013.12.083	doi.org/10.1016/j.tetlet.2013.12.083	Efficient assembly of alpha-aryl and alpha-vinyl nitriles via iron-catalyzed ether bond activation		Tetrahedron Lett.	65	Fan, XH	FALSE	FALSE	FALSE	FALSE
3948	10.1002/aoc.3020	doi.org/10.1002/aoc.3020	BiCl3-catalyzed carboncarbon cross-coupling of organoboronic acids with aryl iodides		Appl. Organomet. Chem.	65	Chakraborty, D	FALSE	FALSE	FALSE	FALSE
3949	10.1016/j.jcat.2012.11.020	doi.org/10.1016/j.jcat.2012.11.020	Aerobic homocoupling of phenylboronic acid on Mg-Al mixed-oxides-supported Au nanoparticles		J. Catal.	65	Xiao, FS	FALSE	FALSE	FALSE	FALSE
3950	10.1007/s00706-012-0838-x	doi.org/10.1007/s00706-012-0838-x	Recent advances in Kumada-Tamao-Corriu cross-coupling reaction catalyzed by different ligands		Mon. Chem.	65	Heravi, MM	FALSE	FALSE	FALSE	FALSE
3951	10.1002/mrc.3864	doi.org/10.1002/mrc.3864	O-17 NMR studies of ortho-substituent effects in substituted phenyl tosylates		Magn. Reson. Chem.	65	Koppel, IA	FALSE	FALSE	FALSE	FALSE
3952	10.1021/jo3008397	doi.org/10.1021/jo3008397	Synthesis of Alkenyl Sulfides Through the Iron-Catalyzed Cross-Coupling Reaction of Vinyl Halides with Thiols		J. Org. Chem.	65	Lee, CF	FALSE	FALSE	FALSE	FALSE
3953	10.1016/j.tetlet.2012.03.036	doi.org/10.1016/j.tetlet.2012.03.036	A new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep and its application in asymmetric hydrogenation		Tetrahedron Lett.	65	Wang, MC	FALSE	FALSE	FALSE	FALSE
3954	10.1039/c2cc33641c	doi.org/10.1039/c2cc33641c	Triflimide-catalyzed allyl-allyl cross-coupling: a metal-free allylic alkylation		Chem. Commun.	65	Liu, XW	FALSE	FALSE	FALSE	FALSE
3955	10.1016/j.tetlet.2011.10.126	doi.org/10.1016/j.tetlet.2011.10.126	Improved Hiyama cross-coupling reactions using HOMSi (R) reagents: a novel application of a palladacycle		Tetrahedron Lett.	65	Hughes, AB	FALSE	FALSE	FALSE	FALSE
3956	10.1021/ol2020863	doi.org/10.1021/ol2020863	Efficient Copper-Catalyzed S-Vinylation of Thiols with Vinyl Halides		Org. Lett.	65	Lee, CF	FALSE	FALSE	FALSE	FALSE
3957	10.1021/ol201702a	doi.org/10.1021/ol201702a	Ni(II) Salts and 2-Propanol Effect Catalytic Reductive Coupling of Epoxides and Alkynes		Org. Lett.	65	Jamison, TF	FALSE	FALSE	FALSE	FALSE
3958	10.1021/jo100846t	doi.org/10.1021/jo100846t	A General Palladium Catalyst System for Suzuki-Miyaura Coupling of Potassium Aryltrifluoroborates and Aryl Mesylates		J. Org. Chem.	65	Kwong, FY	FALSE	FALSE	FALSE	FALSE
3959	10.1021/ja903091g	doi.org/10.1021/ja903091g	Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation		J. Am. Chem. Soc.	65	Nakamura, E	FALSE	FALSE	FALSE	FALSE
3960	10.1016/j.tetlet.2008.11.082	doi.org/10.1016/j.tetlet.2008.11.082	Simple, efficient and recyclable catalytic system for performing copper-catalyzed C-S coupling of thiols with aryl iodides in PEG and PEG-H2O		Tetrahedron Lett.	65	Wang, YG	FALSE	FALSE	FALSE	FALSE
3961	10.1021/om700522q	doi.org/10.1021/om700522q	Iron trichloride mediated allylation of lithium alkoxides through an unusual carbon-oxygen bond cleavage		Organometallics	65	Kabalka, GW	FALSE	FALSE	FALSE	FALSE
3962	10.1002/chem.200601582	doi.org/10.1002/chem.200601582	Self-assembly of hybrid dendrons with complex primary structure into functional helical pores		Chem.-Eur. J.	65	Percec, V	FALSE	FALSE	FALSE	FALSE
3963	10.1016/j.tetlet.2004.09.114	doi.org/10.1016/j.tetlet.2004.09.114	An efficient palladium-catalyzed coupling reaction of lithium alkynyltriisopropoxyborates with acid chlorides: a new access to synthesis of conjugated ynones		Tetrahedron Lett.	65	Oh, CH	FALSE	FALSE	FALSE	FALSE
3964	10.1021/ja011428g	doi.org/10.1021/ja011428g	Ruthenium-catalyzed two-component addition to form 1,3-dienes: Optimization, scope, applications, and mechanism		J. Am. Chem. Soc.	65	Trost, BM	FALSE	FALSE	FALSE	FALSE
3965	10.1039/a809488h	doi.org/10.1039/a809488h	New bis(phosphines) derived from N,N '-substituted ethylenediamine derivatives. Synthesis and transition metal chemistry of X2PN(R)CH2CH2(R)NPX2 (R = CH2Ph or Ph, X = Ph; R = CH2Ph, X-2 = O2C6H4). The crystal and molecular structure of Ph2PN(CH2Ph)CH2CH2(CH2Ph)NPPh2 and cis-[{PtCl2Ph2PN(CH2Ph)CH2CH2(CH2Ph)NPPh2}]		J. Chem. Soc.-Dalton Trans.	65	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
3966	10.1021/jo00309a008	doi.org/10.1021/jo00309a008	ALPHA-METALATED TERTIARY ENOL CARBAMATES - NEW ACYL ANION EQUIVALENTS		J. Org. Chem.	65		FALSE	FALSE	FALSE	FALSE
3967	10.1002/anie.202116775	doi.org/10.1002/anie.202116775	Reductant-Free Cross-Electrophile Synthesis of Di(hetero)arylmethanes by Palladium-Catalyzed Desulfinative C-C Coupling		Angew. Chem.-Int. Edit.	65	Willis, MC	FALSE	TRUE	FALSE	FALSE
3968	10.1039/d2ob00056c	doi.org/10.1039/d2ob00056c	Theoretical study for evaluating and discovering organic hydride compounds as novel trifluoromethylation reagents		Org. Biomol. Chem.	65	Yan, MC	FALSE	FALSE	FALSE	FALSE
3969	10.1002/ajoc.202100665	doi.org/10.1002/ajoc.202100665	Synthesis of C4-Acyl-tetrofuranosides and C5-Acyl-pentopyranosides Enabled by the Liebeskind-Srogl Cross-Coupling Reaction		Asian J. Org. Chem.	65	Li, M	FALSE	FALSE	FALSE	FALSE
3970	10.1002/ejoc.202101505	doi.org/10.1002/ejoc.202101505	Synthesis of 2-Substituted Indoles by Pd-Catalyzed Reductive Cyclization of 1-Halo-2-nitrobenzene with Alkynes		Eur. J. Org. Chem.	65	Bhanage, BM	FALSE	FALSE	FALSE	FALSE
3971	10.1002/cjoc.202100763	doi.org/10.1002/cjoc.202100763	Enantioselective NiH-Catalyzed Reductive Hydrofunctionalization of Alkenes		Chin. J. Chem.	65	Zhu, SL	FALSE	FALSE	FALSE	FALSE
3972	10.1021/acs.inorgchem.1c03313	doi.org/10.1021/acs.inorgchem.1c03313	Reductive Carbonylation of Nitroarenes Using a Heterogenized Phen-Pd Catalyst		Inorg. Chem.	65	Lee, Y	FALSE	FALSE	FALSE	FALSE
3973	10.1021/acs.orglett.1c03991	doi.org/10.1021/acs.orglett.1c03991	Nickel-Catalyzed Chemo- and Regioselective Benzylarylation of Unactivated Alkenes with o-Bromobenzyl Chlorides		Org. Lett.	65	Wu, SH; Wang, LH	FALSE	FALSE	FALSE	FALSE
3974	10.1002/ajoc.202100591	doi.org/10.1002/ajoc.202100591	Recent Developments in Hydrodecyanation and Decyanative Functionalization Reactions		Asian J. Org. Chem.	65	Patra, T; Maiti, D	FALSE	FALSE	FALSE	FALSE
3975	10.1002/ejoc.202100955	doi.org/10.1002/ejoc.202100955	N-Aroylsulfonamide-Photofragmentation (ASAP)-A Versatile Route to Biaryls		Eur. J. Org. Chem.	65	Wessig, P	TRUE	FALSE	FALSE	FALSE
3976	10.1021/acs.orglett.1c02938	doi.org/10.1021/acs.orglett.1c02938	Nickel/Photo-Cocatalyzed C(sp(2))-H Allylation of Aldehydes and Formamides		Org. Lett.	65	Wang, C	TRUE	FALSE	FALSE	FALSE
3977	10.1016/j.poly.2021.115412	doi.org/10.1016/j.poly.2021.115412	Direct arylation (hetero-coupling) of heteroarenes via unsymmetrical palladium-PEPPSI-NHC type complexes		Polyhedron	65	Zafar, MN	FALSE	FALSE	FALSE	FALSE
3978	10.1016/j.xcrp.2021.100476	doi.org/10.1016/j.xcrp.2021.100476	Manganese-catalyzed chlorosulfonylation of terminal alkene and alkyne via convergent paired electrolysis		Cell Rep. Phys. Sci.	65	Lei, AW	FALSE	FALSE	FALSE	FALSE
3979	10.1021/acs.orglett.1c01553	doi.org/10.1021/acs.orglett.1c01553	Switchable Cobalt-Catalyzed alpha-Olefination and alpha-Alkylation of Nitriles with Primary Alcohols		Org. Lett.	65	Ding, KY	FALSE	FALSE	FALSE	FALSE
3980	10.1039/d1sc02210e	doi.org/10.1039/d1sc02210e	Ni(0)-promoted activation of C-O bonds		Chem. Sci.	65	Lee, Y	FALSE	FALSE	FALSE	FALSE
3981	10.1021/acs.organomet.1c00280	doi.org/10.1021/acs.organomet.1c00280	The Effect of Added Ligands on the Reactions of [Ni(COD)(dppf)] with Alkyl Halides: Halide Abstraction May Be Reversible		Organometallics	65	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
3982	10.1038/s41467-021-23887-2	doi.org/10.1038/s41467-021-23887-2	Asymmetric benzylic C(sp(3))-H acylation via dual nickel and photoredox catalysis		Nat. Commun.	65	Huo, HH	FALSE	FALSE	FALSE	FALSE
3983	10.1021/acscatal.1c01201	doi.org/10.1021/acscatal.1c01201	The Emerging Applications of Sulfur(VI) Fluorides in Catalysis		ACS Catal.	65	Sammis, GM	FALSE	FALSE	FALSE	FALSE
3984	10.1039/d1qo00487e	doi.org/10.1039/d1qo00487e	Regioselective synthesis of indenones via nickel-catalyzed Larock annulations		Org. Chem. Front.	65	Rong, ZQ	FALSE	FALSE	FALSE	FALSE
3985	10.1002/ejoc.202100115	doi.org/10.1002/ejoc.202100115	Forging C-S(Se) Bonds by Nickel-catalyzed Decarbonylation of Carboxylic Acid and Cleavage of Aryl Dichalcogenides		Eur. J. Org. Chem.	65	Zhu, YM	FALSE	FALSE	FALSE	FALSE
3986	10.1039/d1nj01581h	doi.org/10.1039/d1nj01581h	Nickel-catalyzed C3-alkylation of indoles with alcohols via a borrowing hydrogen strategy		New J. Chem.	65	Jin, LQ	FALSE	FALSE	FALSE	FALSE
3987	10.1039/d0qo01462a	doi.org/10.1039/d0qo01462a	Intermolecular alkene arylcyanation using BnSCN as a cyanide source via a reductive strategy: access to 3,3-disubstituted oxindoles		Org. Chem. Front.	65	Sun, FG	FALSE	FALSE	FALSE	FALSE
3988	10.1021/acsomega.0c05936	doi.org/10.1021/acsomega.0c05936	Organosolv Fractionation of Walnut Shell Biomass to Isolate Lignocellulosic Components for Chemical Upgrading of Lignin to Aromatics		ACS Omega	65	Abu-Omar, MM	FALSE	FALSE	FALSE	FALSE
3989	10.1016/j.chempr.2021.02.013	doi.org/10.1016/j.chempr.2021.02.013	Ni-catalyzed enantioselective [2+2+2] cycloaddition of malononitriles with alkynes		Chem	65	Liu, WB	FALSE	FALSE	FALSE	FALSE
3990	10.1002/anie.201706719	doi.org/10.1002/anie.201706719	Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates		Angew. Chem.-Int. Edit.	65	Morken, JP	FALSE	FALSE	FALSE	FALSE
3991	10.1002/chem.201701211	doi.org/10.1002/chem.201701211	Cobalt-Catalyzed Alkylation of Secondary Alcohols with Primary Alcohols via Borrowing Hydrogen/Hydrogen Autotransfer		Chem.-Eur. J.	65	Kempe, R	FALSE	FALSE	FALSE	FALSE
3992	10.1039/c7sc01750b	doi.org/10.1039/c7sc01750b	Nickel-catalyzed C-H/N-H annulation of aromatic amides with alkynes in the absence of a specific chelation system		Chem. Sci.	65	Chatani, N	FALSE	FALSE	FALSE	FALSE
3993	10.1021/acscatal.7b02014	doi.org/10.1021/acscatal.7b02014	Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature		ACS Catal.	65	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
3994	10.1021/jacs.7b06340	doi.org/10.1021/jacs.7b06340	Ni-Catalyzed Regioselective 1,2-Dicarbofunctionalization of Olefins by Intercepting Heck Intermediates as Imine-Stabilized Transient Metallacycles		J. Am. Chem. Soc.	65	Giri, R	FALSE	FALSE	FALSE	FALSE
3995	10.1021/jacs.7b04937	doi.org/10.1021/jacs.7b04937	Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates		J. Am. Chem. Soc.	65	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
3996	10.1039/c7cc01932g	doi.org/10.1039/c7cc01932g	Highly nucleophilic vitamin B-12-assisted nickel-catalysed reductive coupling of aryl halides and non-activated alkyl tosylates		Chem. Commun.	65	Komeyama, K	FALSE	FALSE	FALSE	FALSE
3997	10.1002/ejoc.201700290	doi.org/10.1002/ejoc.201700290	Palladium-Catalyzed Chemo- and Regioselective Oxidative Cross-Dehydrogenative Coupling of Acetanilides with Benzothiazole		Eur. J. Org. Chem.	65	Kianmehr, E	FALSE	FALSE	FALSE	FALSE
3998	10.1021/acs.joc.6b02564	doi.org/10.1021/acs.joc.6b02564	Nickel-Catalyzed Cross-Coupling of Allyl Alcohols with Aryl- or Alkenylzinc Reagents		J. Org. Chem.	65	Wang, ZX	FALSE	FALSE	FALSE	FALSE
3999	10.1016/j.tetlet.2017.02.073	doi.org/10.1016/j.tetlet.2017.02.073	Nickel-catalyzed decarboxylative coupling of an alkynyl carboxylic acid with aryl iodides		Tetrahedron Lett.	65	Lee, S	FALSE	FALSE	FALSE	FALSE
4000	10.1021/acs.joc.6b02642	doi.org/10.1021/acs.joc.6b02642	A Ligand-Dissociation-Involved Mechanism in Amide Formation of Monofluoroacylboronates with Hydroxylamines		J. Org. Chem.	65	Jiang, YY; Bi, SW	FALSE	FALSE	FALSE	FALSE
4001	10.1002/slct.201601241	doi.org/10.1002/slct.201601241	Heck Reactions and Carbonylations of Alkenyl Nonaflates - Synthesis of Tetradehydroamino Acids and alpha,beta-Unsaturated Carboxylic Acids		ChemistrySelect	65	Reissig, HU	FALSE	FALSE	FALSE	FALSE
4002	10.1021/acs.organomet.6b00652	doi.org/10.1021/acs.organomet.6b00652	Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes		Organometallics	65	Schomaker, JM	FALSE	FALSE	FALSE	FALSE
4003	10.1021/acs.orglett.6b02619	doi.org/10.1021/acs.orglett.6b02619	Catalytic Direct C2-Alkenylation of Oxazoles at Parts per Million Levels of Palladium/PhMezole-Phos Complex		Org. Lett.	65	Kwong, FY	FALSE	FALSE	FALSE	FALSE
4004	10.1016/j.jorganchem.2016.05.014	doi.org/10.1016/j.jorganchem.2016.05.014	Reactivity of mixed organozinc and mixed organocopper reagents: 14. Phosphine-nickel catalyzed aryl-allyl coupling of (n-butyl)(aryl)zincs. Ligand and substrate control on the group selectivity and regioselectivity		J. Organomet. Chem.	65	Erdik, E	FALSE	FALSE	FALSE	FALSE
4005	10.1021/acssuschemeng.6b00729	doi.org/10.1021/acssuschemeng.6b00729	Amberlyst-15/[Bmim][PF6] Catalyzed Synthesis of C-3-Symmetric Triarylbenzenes via Cyclotrimerization of Alkynes		ACS Sustain. Chem. Eng.	65	Bhanage, BM	FALSE	FALSE	FALSE	FALSE
4006	10.1021/jacs.6b03897	doi.org/10.1021/jacs.6b03897	One-Pot Ketone Synthesis with Alkylzinc Halides Prepared from Alkyl Halides via a Single Electron Transfer (SET) Process: New Extension of Fukuyama Ketone Synthesis		J. Am. Chem. Soc.	65	Kishi, Y	FALSE	TRUE	FALSE	FALSE
4007	10.1002/adsc.201600080	doi.org/10.1002/adsc.201600080	An Approach to Five-Membered Lactams from Aliphatic Amides and Terminal Acetylenes by Nickel Catalysis		Adv. Synth. Catal.	65	Zhang, YH	FALSE	FALSE	FALSE	FALSE
4008	10.1016/j.tetlet.2016.04.027	doi.org/10.1016/j.tetlet.2016.04.027	Iron-catalyzed allylic substitution reactions of allylic ethers with Grignard reagents		Tetrahedron Lett.	65	Li, ZP	FALSE	FALSE	FALSE	FALSE
4009	10.1002/adsc.201501138	doi.org/10.1002/adsc.201501138	Stereoselective thia-Michael 1,4-Addition to Acyclic 2,4-Dienones and 2-En-4-ynones		Adv. Synth. Catal.	65	Kowalczyk, R	FALSE	FALSE	FALSE	FALSE
4010	10.1021/acs.orglett.6b00453	doi.org/10.1021/acs.orglett.6b00453	Cobalt-Catalyzed Asymmetric Hydrogenation of 1,1-Diarylethenes		Org. Lett.	65	Lu, Z	FALSE	FALSE	FALSE	FALSE
4011	10.1002/chem.201505106	doi.org/10.1002/chem.201505106	Nickel-Catalyzed Cross-Coupling of Organolithium Reagents with (Hetero)Aryl Electrophiles		Chem.-Eur. J.	65	Hornillos, V; Feringa, BL	FALSE	TRUE	FALSE	FALSE
4012	10.1021/acscatal.5b02058	doi.org/10.1021/acscatal.5b02058	Density Functional Study of Nickel N-Heterocyclic Carbene Catalyzed C-O Bond Hydrogenolysis of Methyl Phenyl Ether: The Concerted beta-H Transfer Mechanism		ACS Catal.	65	Surawatanawong, P	FALSE	FALSE	FALSE	FALSE
4013	10.1002/adsc.201500721	doi.org/10.1002/adsc.201500721	Synthesis of Short-Chain Alkenyl Ethers from Primary and Biosourced Alcohols via the Nickel-Catalyzed Hydroalkoxylation Reaction of Butadiene and Derivatives		Adv. Synth. Catal.	65	Suisse, I; Sauthier, M	FALSE	FALSE	FALSE	FALSE
4014	10.1002/ajoc.202100039	doi.org/10.1002/ajoc.202100039	Base-Promoted Direct Cascade Transformation of Chromones to Coumarins via Benzannulation and Transesterification	Whereas the metal-catalyzed C(sp(2))-N cross coupling of cyclopropylamine with aryl electrophiles represents an attractive route to pharmaceutically relevant N-arylcyclopro-pylamines, few catalysts that are capable of effecting such transformations have been identified. Herein, the nickel-catalyzed C(sp(2))-N cross-coupling of cyclopropylamine and related nucleophiles, including ammonium salts, with (hetero)aryl (pseudo)halides is reported for the first time, with the demonstrated scope of reactivity exceeding that displayed by all previously reported catalysts (Pd, Cu, or other). Our preliminary efforts to effect the N-arylation of cyclopropylamine with (hetero)aryl chlorides at room temperature by use of (L)NiCl(o-tolyl) precatalysts (L = PAd-DalPhos, Cl; L = JosiPhos CyPF-Cy, C2) were unsuccessful, despite the established efficacy of Cl and C2 in transformations of other primary alkylamines. However, systematic modification of the ancillary ligand (L) structure enabled success in such transformations, with crystallographically characterized (L)NiCl(o-tolyl) precatalysts incorporating o-phenylene-bridged bisphosphines featuring phosphatrioxaadamantane and PCy2 (L = L3, CyPAd-DalPhos; C3), P(o-tolyl)(2) and P(t-Bu)(2) (L = L4; C4), or PCy2 and P(t-Bu)(2) (L = L5; C5) donor pairings proving to be particularly effective. In employing the air-stable precatalyst C3 in cross-couplings of cyclopropylamine, substituted electrophiles encompassing an unprecedentedly broad range of heteroaryl (pyridine, isoquinoline, quinoline, quinoxaline, pyrimidine, purine, benzothiophene, and benzothiazole) and (pseudo)halide (chloride, bromide, mesylate, tosylate, triflate, sulfamate, and carbamate) structures were employed successfully, in the majority of cases under mild conditions (3 mol % of Ni, 25 degrees C). Preliminary studies also confirmed the ability of C3 to effect the N-arylation of cyclopropanemethylamine hydrochloride and cyclobutylamine hydrochloride under similar conditions. A notable exception in this chemistry was observed specifically in the case of electron-rich aryl chlorides, where the use of C4 in place of C3 proved more effective. In keeping with this observation, catalyst inhibition by 4-chloroanisole was observed in the otherwise efficient cross-coupling of cyclopropylamine and 3-chloropyridine when using C3. Competition studies involving C3 revealed a (pseudo)halide reactivity preference (Cl > Br, OTs).	Asian J. Org. Chem.	64	Lee, YR	FALSE	FALSE	FALSE	FALSE
4015	10.1016/j.tet.2020.131912	doi.org/10.1016/j.tet.2020.131912	Palladium-catalyzed C-P bond activation of aroyl phosphine oxides without the adjacent anchoring atom	Over the past few decades, an impressive array of C-H activation methodology has been developed for organic synthesis. However, due to the inherent inertness of the C-H bonds (e.g. similar to 110 kcal mol(-1) for the cleavage of C(aryl)-H bonds) harsh reaction conditions have been realized to overcome high energetic transition states resulting in a limited substrate scope and functional group tolerance. Therefore, the development of mild C-H functionalization protocols is in high demand to exploit the full potential of the C-H activation strategy in the synthesis of a complex molecular framework. Although, electron-rich substrates undergo electrophilic metalation under relatively mild conditions, electron-deficient substrates proceed through a rate-limiting C-H insertion under forcing conditions at high temperature. In addition, a stoichiometric amount of toxic silver salt is frequently used in palladium catalysis to facilitate the C-H activation process which is not acceptable from the environmental and industrial standpoint. We report herein, a Pd(II)-catalyzed decarboxylative C-H acylation of 2-arylpyridines with alpha-ketocarboxylic acids under mild conditions. The present protocol does not require stoichiometric silver(I) salts as additives and proceeds smoothly at ambient temperature. A novel decarbonylative C-H acylation reaction has also been accomplished using aryl glyoxals as acyl surrogates. Finally, a practical C-H acylation via a dehydrogenative pathway has been demonstrated using commercially available benzaldehydes and aqueous hydroperoxides. We also disclose that acetonitrile solvent is optimal for the acylation reaction at room temperature and has a prominent role in the reaction outcome. Control experiments suggest that the acylation reaction via decarboxylative, decarbonylative and dehydrogenative proceeds through a radical pathway. Thus we disclose a practical protocol for the sp(2) C-H acylation reaction.	Tetrahedron	64	Zhu, H; Wang, ZQ	FALSE	FALSE	FALSE	FALSE
4016	10.1021/acs.joc.0c02389	doi.org/10.1021/acs.joc.0c02389	Nickel-Catalyzed Cross-Coupling of Aryl 2-Pyridyl Ethers with Organozinc Reagents: Removal of the Directing Group via Cleavage of the Carbon-Oxygen Bonds	The nickel-catalyzed cyclization of in situ generated ortho-chlorobenzophenone hydrazone derivatives, to afford 3-(hetero) aryl-1H-indazoles, is documented for the first time. The product 1H-indazoles can be transformed subsequently in a one-pot procedure into 1,3-di(hetero) aryl-1H-indazoles via copper-catalyzed N-arylation with (hetero) aryl bromides.	J. Org. Chem.	64	Wang, ZX	FALSE	FALSE	FALSE	FALSE
4017	10.1021/acs.joc.0c02209	doi.org/10.1021/acs.joc.0c02209	Nickel-Catalyzed Arylation/Alkenylation of tert-Cyclobutanols with Aryl/Alkenyl Triflates via a C-C Bond Cleavage	Amide and olefins are important synthetic intermediates with complementary reactivity which play a key role in the construction of natural products, pharmaceuticals and manmade materials. Converting the normally highly stable aliphatic amides into olefins directly is a challenging task. Here we show that a Ni/NHC-catalytic system has been established for decarbonylative elimination of aliphatic amides to generate various olefins via C-N and C-C bond cleavage. This study not only overcomes the acyl C-N bond activation in aliphatic amides, but also encompasses distinct chemical advances on a new type of elimination reaction called retro-hydroamidocarbonylation. This transformation shows good functional group compatibility and can serve as a powerful synthetic tool for late-stage olefination of amide groups in complex compounds.	J. Org. Chem.	64	Zhou, BW	FALSE	FALSE	FALSE	FALSE
4018	10.1021/acs.joc.0c02252	doi.org/10.1021/acs.joc.0c02252	Transition Metal-Free Heteroarylation of Quinoxaline: Construction of Heteroaryl-Fused Phenazines by Oxidative Coupling	Ni-Pd binary nanoclusters are reported for the activation of the C-O bond for Suzuki-Miyaura cross coupling of bioactive heterocycle-tethered sterically hindered aryl carbonates with aryl boronic acids. The reaction does not take place in the presence of either the Pd or Ni salts/complexes or the individual Pd or Ni nanoparticles, indicating ensembling cooperativity between the Pd and Ni nanoparticles in activating the C-O bond.	J. Org. Chem.	64	Dastan, A	FALSE	FALSE	FALSE	FALSE
4019	10.1055/s-0040-1705987	doi.org/10.1055/s-0040-1705987	Harnessing C-O Bonds in Stereoselective Cross-Coupling and Cross-Electrophile Coupling Reactions	A new class of aromatic metamorphosis has been developed in which dibenzofurans were converted into triphenylenes. This transformation is composed of three successive operations: (1) nickel-catalyzed ring-opening C-O bond arylation with arylmagnesium bromides, (2) trifluoromethanesulfonylation (triflation) of the resulting hydroxy moiety with Tf2O, and (3) palladium-catalyzed or photoinduced ring closure. In the last ring-closing step, the photoinduced process has proven to be more productive than the palladium-catalyzed one. By employing pi-extended dinaphthofuran as the substrate, dorsally benzo-fused [5]helicene was obtained in a satisfactory yield.	Synlett	64	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
4020	10.1016/j.cej.2020.125788	doi.org/10.1016/j.cej.2020.125788	A novel path towards synthesis of nitrogen-rich porous carbon nanofibers for high performance supercapacitors	Pd-catalyzed decarboxylative asymmetric allylic alkylation has been developed for sterically hindered alpha-aryl, beta-oxo-allyl ester lactone substrates. Pb-mediated alpha-arylation of the beta-oxo-allyl ester was used as the key step to synthesize the substrates for catalysis in moderate to high yields. Optimization studies for decarboxylative asymmetric allylic alkylations (DAAA) were conducted using delta-valerolactone-derived alpha-aryl beta-oxo-allyl ester with 2,4,6-trimethoxyphenyl as the aryl substituent. Using (R,R)-ANDEN-phenyl Trost as the chiral ligand, enantioselectivities of up to >99% ee and 98% ee were achieved with the six-membered and five-membered lactone substrates, respectively. Bulky aryl groups containing di-ortho substitutions and naphthyl groups gave the highest enantioselectivities. This synthetic route allows for the simple modification of aryl groups, giving highly enantioselective access to important structural motifs.	Chem. Eng. J.	64	Naraghi, M	FALSE	FALSE	FALSE	FALSE
4021	10.1021/jacs.0c06995	doi.org/10.1021/jacs.0c06995	Small Phosphine Ligands Enable Selective Oxidative Addition of Ar-O over Ar-Cl Bonds at Nickel(0)	Ligands are essential for controlling the reactivity and selectivity of reactions catalysed by transition metals. Access to large phosphine ligand libraries has become an essential tool for the application of metal-catalysed reactions industrially, but these existing libraries are not well suited to new catalytic methods based on non-precious metals (for example, Ni, Cu and Fe). The development of the requisite nitrogen-and oxygen-based ligand libraries lags far behind that of the phosphines and the development of new libraries is anticipated to be time consuming. Here we show that this process can be dramatically accelerated by mining for new ligands in a typical pharmaceutical compound library that is rich in heterocycles. Using this approach, we were able to screen a structurally diverse set of compounds with minimal synthetic effort and identify several new ligand classes for nickel-catalysed cross-electrophile coupling. These new ligands gave improved yields for challenging cross-couplings of pharmaceutically relevant substrates compared with those of those of previously published ligands.	J. Am. Chem. Soc.	64	Neufeldt, SR	FALSE	FALSE	FALSE	FALSE
4022	10.1021/acs.orglett.0c02369	doi.org/10.1021/acs.orglett.0c02369	Direct Catalytic Symmetrical, Unsymmetrical N,N-Dialkylation and Cyclization of Acylhydrazides Using Alcohols	Palladium-catalyzed ring-opening reactions of cyclopropanated 7-oxabenzonorbornadiene derivatives using alcohol nucleophiles were investigated. The optimal conditions were found to be 10 mol % PdCl2(CH3CN)(2) in methanol, offering yields up to 92%. The reaction was successful using primary, secondary and tertiary alcohol nucleophiles and was compatible with a variety of substituents on cyclopropanated oxabenzonorbornadiene. With unsymmetrical C1-substituted cyclopropanated 7-oxabenzonorbornadienes, the regioselectivity of the reaction was excellent, forming only one regioisomer in all cases.	Org. Lett.	64	Gunanathan, C	FALSE	FALSE	FALSE	FALSE
4023	10.1039/d0nj01139h	doi.org/10.1039/d0nj01139h	Synthesis and characterization of new square planar heteroleptic cationic complexes [Ni(ii) beta-oxodithioester-dppe](+); their use as a catalyst for Chan-Lam coupling	A theoretical investigation has been performed on nickel- and palladium-N-heterocyclic carbene (NHC) complexes in the Mizoroki-Heck (MH) reaction. A density functional theory (DFT) comparison of reaction pathways in cationic and neutral catalytic cycles for both metals was made using the M06 functional. The oxidative addition barrier is much lower for NHC-Ni than that for NHC-Pd for both mono- and bis-ligand pathways; the bis-ligand pathway (i.e., where both NHCs remain coordinated) is energetically more favorable for both metals. The migratory insertion steps have lower free energy barriers for NHC-Ni than for NHC-Pd complexes for both neutral and cationic pathways. beta-Hydride elimination is computed as thermodynamically difficult for NHC-Ni complexes, indicating a possible reluctance in the elimination of the Ni-based hydride intermediate and formation of the Heck adduct at room temperature. The base-assisted reductive elimination is easier for NHC-Pd than for NHC-Ni complexes in the neutral and cationic pathways, in agreement with reported experimental observations.	New J. Chem.	64	Singh, N	FALSE	FALSE	FALSE	FALSE
4024	10.1002/adsc.202000622	doi.org/10.1002/adsc.202000622	Transition Metal-Free Aroylation of Diarylmethanes with N-Bn-N-Boc Arylamides and N-Acylpyrroles	The replacement of expensive noble metals by earth-abundant transition metals is a central topic in catalysis. Herein, we introduce a highly active and selective homogeneous manganese-based C=O bond hydrogenation catalyst. Our catalyst has a broad substrate scope, it is able to hydrogenate aryl-alkyl, diaryl, dialkyl, and cycloalkyl ketones as well as aldehydes. A very good functional group tolerance including the quantitative and selective hydrogenation of a ketone in the presence of a non-shielded olefin is observed. In Mn hydrogenation catalysis, the combination of the multidentate ligand, the oxidation state of the metal, and the choice of the right ancillary ligand is crucial for high activity. This observation emphasizes an advantage and the importance of homogeneous catalysts in 3d-metal catalysis. For coordination compounds, fine-tuning of a complex coordination environment is easily accomplished in comparison to enzyme and/or heterogeneous catalysts.	Adv. Synth. Catal.	64	Li, J	FALSE	FALSE	FALSE	FALSE
4025	10.1002/ejoc.202000575	doi.org/10.1002/ejoc.202000575	Palladium-Catalyzed Suzuki Coupling ofN-Acyloxazolidinones via Selective Cleavage of C-N Bonds	Regio- and stereoselective allylic substitution is an important tool for the synthesis of complex organic molecules. Due to the high branched-product selectivity, iridium gives a new opportunity in enantioselective synthesis. Iridium-catalyzed enantioselective allylic substitution is one of the most reliable methods for the synthesis of chiral building blocks. This review gives a comprehensive survey of iridium-catalyzed enantioselective allylic substitution. Iridium catalysts are divided into two types; iridacycle and bidentate (P, alkene) iridium complex. Iridacycle catalyst is suitable for the reaction of primary allylic electrophiles. On the other hand, bidentate (P, alkene) iridium catalyst is suitable for the reaction of racemic secondary allylic electrophiles.	Eur. J. Org. Chem.	64	Wang, ZJ; Zeng, Z	FALSE	FALSE	FALSE	FALSE
4026	10.1038/s41467-020-17085-9	doi.org/10.1038/s41467-020-17085-9	Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis	Copper-catalyzed directed decarboxylative amination of nonactivated aliphatic carboxylic acids is described. This intramolecular C-N bond formation reaction provides efficient access to the synthesis of pyrrolidine and piperidine derivatives as well as the modification of complex natural products. Moreover, this reaction presents excellent site selectivity in the C-N bond formation step through the use of directing group. Our work can be considered as a big step toward controllable radical decarboxylative carbon-heteroatom cross-coupling.	Nat. Commun.	64	Yu, DG	FALSE	FALSE	FALSE	FALSE
4027	10.1021/acs.orglett.0c01129	doi.org/10.1021/acs.orglett.0c01129	Enantioselective Construction of Spiro Quaternary Carbon Stereocenters via Pd-Catalyzed Intramolecular alpha-Arylation	A de novo synthesis of a benzene ring allows for the preparation of a diverse range of heterocycles including indoles, benzofurans, benzothiophenes, carbazoles, and dibenzofurans from simple heteroaryl propargylic esters using a unified carbonylative benzannulation strategy. Multiple substituents can be easily introduced to the C4-C7 positions of indoles and related heterocycles.	Org. Lett.	64	Tang, WJ	FALSE	FALSE	FALSE	FALSE
4028	10.1021/acscatal.0c01199	doi.org/10.1021/acscatal.0c01199	Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis	This note describes a dimethyl dicarbonate-assisted, Pd-(OAc)(2)/PPh3-catalyzed acylative Suzuki coupling of carboxylic acids with diarylborinic acids or tetraarylboronates for practical and efficient synthesis of sterically undemanding aryl ketones at room temperature. More than just cost-effective alternatives to aryl boronic acids, diarylborinic acids and tetraarylboronates displayed higher reactivity in the acylative Suzuki coupling. A variety of alkyl aryl ketones, including those bearing a hydroxy, bromo, or carbonyl group, could be readily obtained in modest to excellent yields.	ACS Catal.	64	Doyle, AG	TRUE	TRUE	FALSE	FALSE
4029	10.1021/acs.joc.0c00178	doi.org/10.1021/acs.joc.0c00178	Chemoselective Rhodium-Catalyzed Borylation of Bromoiodoarenes Under Mild Conditions	In the presence of trialkylaluminum reagents, diverse aryl methyl ethers can be transformed into valuable products by C-O bond-cleaving alkylation, for the first time without the limiting -hydride elimination. This new nickel-catalyzed dealkoxylative alkylation method enables powerful orthogonal synthetic strategies for the transformation of a variety of naturally occurring and easily accessible anisole derivatives. The directing and/or activating properties of aromatic methoxy groups are utilized first, before they are replaced by alkyl chains in a subsequent coupling process.	J. Org. Chem.	64	Noonan, KJT	FALSE	FALSE	FALSE	FALSE
4030	10.1038/s42004-020-0304-3	doi.org/10.1038/s42004-020-0304-3	Pd-catalyzed fluoro-carbonylation of aryl, vinyl, and heteroaryl iodides using 2-(difluoromethoxy)-5-nitropyridine	All elementary steps in the mechanism of Pd-catalyzed decarbonylation of hydrocinnamic acid through formation of a mixed anhydride species have been characterized through electronic structure calculations. Oxidative addition of the mixed anhydride to a singly or doubly ligated Pd is followed by decarbonylation, alkene formation, and catalyst regeneration. Metal-assisted deprotonation of the alkyl-Pd species by a coordinated carboxylate is predicted to be the rate-determining step; theory suggests that bulkier phosphine ligands (e.g., P(o-Tol)(3)) reduce the free energy of activation substantially, while variation of the auxiliary anhydride has little influence on efficiency.	Comm. Chem.	64	Shibata, N	FALSE	FALSE	FALSE	FALSE
4031	10.1177/1934578X20925340	doi.org/10.1177/1934578X20925340	Aspects in the Total Syntheses of Higher Terpenoids Starting From Wieland-Miescher Ketone and Its Derivative: A Review	The first general palladium catalyst for the catalytic mono-alpha-arylation of aryl- and heteroarylketones with aryl mesylates and tosylates is described. The newly developed indolyl-derived phosphine ligand L7 has been identified to promote this reaction efficiently. The key to success is attributed to the enhanced steric congestion of the catalyst and effective oxidative addition of the C((Ar))-OMs bond. In the presence of Pd(OAc)(2) (0.25-2.5 mol %) and L7, selective monoarylations are achieved with ample reaction scope and product yields up to 95%. Importantly, we demonstrated the applicability of this protocol with the modification of biological phenolic compounds, rendering it amenable for functionalization of phenolic (pro)drugs.	Nat. Prod. Commun.	64	Hagiwara, H	FALSE	FALSE	FALSE	FALSE
4032	10.1002/ejoc.202000117	doi.org/10.1002/ejoc.202000117	Palladium-Catalyzed Cyanation of Aryl Halides Using Formamide and Cyanuric Chloride as a New CN Source	A highly efficient synthetic approach to unnatural chiral beta-Ar,Ar'-alpha-amino acid esters bearing two contiguous stereogenic centers has been developed. The first enantioselective 1,6-conjugate addition of glycine Schiff bases to para-quinone methides was achieved using a Cu(CH3CN)(4)BF4/Ph-Foxap catalytic system (1 mol %). The reaction proceeded smoothly to generate corresponding products in high yields with excellent diastereoselectivities (up to 99:1) and enantioselectivities (up to >99% ee). Subsequent reduction delivered enantiopure unnatural amino alcohols, which were utilized for the synthesis of novel chiral ligands.	Eur. J. Org. Chem.	64	Panahi, F; Khalafi-Nezhad, A	FALSE	FALSE	FALSE	FALSE
4033	10.1021/acs.joc.9b02913	doi.org/10.1021/acs.joc.9b02913	Ligand-Free Ru-Catalyzed Direct sp(3) C-H Alkylation of Fluorene Using Alcohols		J. Org. Chem.	64	Gnanaprakasam, B	FALSE	FALSE	FALSE	FALSE
4034	10.1002/anie.201915624	doi.org/10.1002/anie.201915624	Rational Development of Remote C-H Functionalization of Biphenyl: Experimental and Computational Studies		Angew. Chem.-Int. Edit.	64	Yu, JQ	FALSE	FALSE	FALSE	FALSE
4035	10.1002/ejoc.201901835	doi.org/10.1002/ejoc.201901835	Nickel-Catalyzed Arylative Additions on 2-Alkynyl-N-Arylsulfonylanilides to Construct Functionalized Indoles		Eur. J. Org. Chem.	64	Dake, GR	FALSE	FALSE	FALSE	FALSE
4036	10.1055/s-0039-1690764	doi.org/10.1055/s-0039-1690764	Recent Advances in Chromium-Catalyzed Organic Transformations		Synlett	64	Zeng, XM	FALSE	FALSE	FALSE	FALSE
4037	10.1039/c9ob02408e	doi.org/10.1039/c9ob02408e	Tandem addition/cyclization for synthesis of 2-aroyl benzofurans and 2-aroyl indoles by carbopalladation of nitriles		Org. Biomol. Chem.	64	Hu, ML; Chen, JX	FALSE	FALSE	FALSE	FALSE
4038	10.1002/slct.201903749	doi.org/10.1002/slct.201903749	Preparation, Characterization and First Application of Graphene Oxide-Metformin-Nickel for the Suzuki Cross-Coupling Reaction		ChemistrySelect	64	Raoufi, F	FALSE	FALSE	FALSE	FALSE
4039	10.1002/jccs.201900450	doi.org/10.1002/jccs.201900450	Nickel-mediated cross-coupling via C-O activation assisted by organoaluminum		J. Chin. Chem. Soc.	64	Ong, TG	FALSE	FALSE	FALSE	FALSE
4040	10.6023/cjoc201903029	doi.org/10.6023/cjoc201903029	Advances on Directing-Group Assisted meta-C-H Functionalization Catalyzed by Transition Metal		Chin. J. Org. Chem.	64	Wu, M	FALSE	FALSE	FALSE	FALSE
4041	10.1039/c9ra06724h	doi.org/10.1039/c9ra06724h	Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from alpha-bromoketones and 2-aminopyridines		RSC Adv.	64	Xu, JY	FALSE	FALSE	FALSE	FALSE
4042	10.1016/j.tetlet.2019.151131	doi.org/10.1016/j.tetlet.2019.151131	N-Heterocyclic carbene as a Bronsted base catalyst for the amination of naphthol derivatives and alcoholysis of glutaric anhydrides		Tetrahedron Lett.	64	Kaliyamoorthy, A	FALSE	FALSE	FALSE	FALSE
4043	10.1021/acs.orglett.9b02306	doi.org/10.1021/acs.orglett.9b02306	(KOBu)-Bu-t-Promoted Transition-Metal-Free Transamidation of Primary and Tertiary Amides with Amines		Org. Lett.	64	Dash, J	FALSE	FALSE	FALSE	FALSE
4044	10.1021/acs.oprd.9b00208	doi.org/10.1021/acs.oprd.9b00208	Efficient and Practical Synthesis of 3 ',4 ',5 '-Trifluoro-[1,1 '-biphenyl]-2-amine: A Key Intermediate of Fluxapyroxad		Org. Process Res. Dev.	64	Li, ZH	FALSE	FALSE	FALSE	FALSE
4045	10.1016/j.tet.2019.03.010	doi.org/10.1016/j.tet.2019.03.010	Ring-expansion approaches for the total synthesis of salimabromide		Tetrahedron	64	Magauer, T	FALSE	FALSE	FALSE	FALSE
4046	10.1039/c9dt00455f	doi.org/10.1039/c9dt00455f	Aryl C-O oxidative addition of phenol derivatives to nickel supported by an N-heterocyclic carbene via a Ni-0 five-centered complex		Dalton Trans.	64	Surawatanawong, P	FALSE	FALSE	FALSE	FALSE
4047	10.1002/anie.201900659	doi.org/10.1002/anie.201900659	Forming Benzylic Iodides via a Nickel Catalyzed Diastereoselective Dearomative Carboiodination Reaction of Indoles		Angew. Chem.-Int. Edit.	64	Lautens, M	FALSE	FALSE	FALSE	FALSE
4048	10.1016/j.mcat.2018.12.029	doi.org/10.1016/j.mcat.2018.12.029	Bi-functional catalyst of porous N-doped carbon with bimetallic FeCu for solvent-free resultant imines and hydrogenation of nitroarenes		Mol. Catal.	64	Li, R	FALSE	FALSE	FALSE	FALSE
4049	10.1039/c8dt04728f	doi.org/10.1039/c8dt04728f	Acetate as a model for aspartate-based CXCR4 chemokine receptor binding of cobalt and nickel complexes of cross-bridged tetraazamacrocycles		Dalton Trans.	64	Hubin, TJ	FALSE	FALSE	FALSE	FALSE
4050	10.1002/anie.201812806	doi.org/10.1002/anie.201812806	Reductive Molybdenum-Catalyzed Direct Amination of Boronic Acids with Nitro Compounds		Angew. Chem.-Int. Edit.	64	Suarez-Pantiga, S; Sanz, R	FALSE	FALSE	FALSE	FALSE
4051	10.1021/acs.biomac.8b01608	doi.org/10.1021/acs.biomac.8b01608	Stimuli-Responsive Poly(N-Vinyllactams) with Glycidyl Side Groups: Synthesis, Characterization, and Conjugation with Enzymes		Biomacromolecules	64	Pich, A	FALSE	FALSE	FALSE	FALSE
4052	10.1002/slct.201803105	doi.org/10.1002/slct.201803105	A Straightforward Metal-Free and Mild Base Promoted Amidation and Transesterification via Acyl C-O bond Cleavage-An Expedite Synthesis of Aromatic Amides and Esters		ChemistrySelect	64	Gandhi, T	FALSE	FALSE	FALSE	FALSE
4053	10.1039/c8cc08010k	doi.org/10.1039/c8cc08010k	Mn(II)-catalysed alkylation of methylene ketones with alcohols: direct access to functionalised branched products		Chem. Commun.	64	Banerjee, D	FALSE	FALSE	FALSE	FALSE
4054	10.1021/acs.orglett.8b03698	doi.org/10.1021/acs.orglett.8b03698	Amination of Phosphorodiamidate-Substituted Pyridines and Related N-Heterocycles with Magnesium Amides		Org. Lett.	64	Knochel, P	FALSE	FALSE	FALSE	FALSE
4055	10.1002/ajoc.201800625	doi.org/10.1002/ajoc.201800625	Silver-Catalyzed Stereoselective trans Addition of 4-Hydroxycoumarins to Haloalkynes and Late-Stage Nitration		Asian J. Org. Chem.	64	Ma, F; Li, HJ	FALSE	FALSE	FALSE	FALSE
4056	10.1039/c8dt03188f	doi.org/10.1039/c8dt03188f	Reactivity of the diphosphinodithio ligated nickel(0) complex toward alkyl halides and resultant nickel( I) and nickel( II)- alkyl complexes		Dalton Trans.	64	Wang, WG	FALSE	FALSE	FALSE	FALSE
4057	10.1039/c8gc02280a	doi.org/10.1039/c8gc02280a	Copper catalysis: ligand-controlled selective N-methylation or N-formylation of amines with CO2 and phenylsilane		Green Chem.	64	Li, HR	FALSE	FALSE	FALSE	FALSE
4058	10.1021/acscatal.8b02334	doi.org/10.1021/acscatal.8b02334	Ir-Catalyzed Selective Hydroboration of 2-Substituted 1,3-Dienes: A General Method to Access Homoallylic Boronates		ACS Catal.	64	Mazet, C	FALSE	FALSE	FALSE	FALSE
4059	10.1038/s41467-018-06240-y	doi.org/10.1038/s41467-018-06240-y	Asymmetric remote C-H borylation of internal alkenes via alkene isomerization		Nat. Commun.	64	Lu, Z	FALSE	FALSE	FALSE	FALSE
4060	10.1002/anie.201805118	doi.org/10.1002/anie.201805118	Direct Cross-Coupling of Allylic C(sp(3))-H Bonds with Aryl- and Vinylbromides by Combined Nickel and Visible-Light Catalysis		Angew. Chem.-Int. Edit.	64	Rueping, M	FALSE	FALSE	FALSE	FALSE
4061	10.1021/acscatal.8b00440	doi.org/10.1021/acscatal.8b00440	Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C-H Bond Activation		ACS Catal.	64	Kanai, M	FALSE	FALSE	FALSE	FALSE
4062	10.1021/acs.orglett.8b00408	doi.org/10.1021/acs.orglett.8b00408	Divergent Asymmetric Syntheses of Podophyllotoxin and Related Family Members via Stereoselective Reductive Ni-Catalysis		Org. Lett.	64	Peng, Y	FALSE	FALSE	FALSE	FALSE
4063	10.1021/acscatal.7b04030	doi.org/10.1021/acscatal.7b04030	A General Nickel-Catalyzed Kumada Vinylation for the Preparation of 2-Substituted 1,3-Dienes		ACS Catal.	64	Mazet, C	FALSE	FALSE	FALSE	FALSE
4064	10.1039/c7gc02282d	doi.org/10.1039/c7gc02282d	Base-free nickel-catalyzed hydroboration of simple alkenes with bis(pinacolato)diboron in an alcoholic solvent		Green Chem.	64	Wang, YQ	FALSE	FALSE	FALSE	FALSE
4065	10.1021/acs.orglett.5b02572	doi.org/10.1021/acs.orglett.5b02572	Nickel-Catalyzed Direct C (sp(3))-H Arylation of Aliphatic Amides with Thiophenes		Org. Lett.	64	Xu, XH	FALSE	FALSE	FALSE	FALSE
4066	10.1002/anie.201504524	doi.org/10.1002/anie.201504524	Iron-Catalyzed Cross-Coupling of Alkenyl Acetates		Angew. Chem.-Int. Edit.	64	Jacobi von Wangelin, A	FALSE	FALSE	FALSE	FALSE
4067	10.1021/acs.orglett.5b01612	doi.org/10.1021/acs.orglett.5b01612	Copper-Catalyzed Cross-Coupling Reaction of Allyl Boron Ester with 1 degrees/2 degrees/3 degrees-Halogenated Alkanes		Org. Lett.	64	Fu, Y	FALSE	FALSE	FALSE	FALSE
4068	10.1039/c5cc01970b	doi.org/10.1039/c5cc01970b	Nickel-catalyzed directed sulfenylation of sp(2) and sp(3) C-H bonds		Chem. Commun.	64	Shi, XD	FALSE	FALSE	FALSE	FALSE
4069	10.1039/c5dt02298c	doi.org/10.1039/c5dt02298c	Selective amination of aryl chlorides catalysed by Ni(PMe3)(4)		Dalton Trans.	64	Sun, HJ	FALSE	FALSE	FALSE	FALSE
4070	10.1002/asia.201402746	doi.org/10.1002/asia.201402746	Mechanistic Origin of Chemoselectivity in Thiolate-Catalyzed Tishchenko Reactions		Chem.-Asian J.	64	Hu, GH	FALSE	FALSE	FALSE	FALSE
4071	10.1021/ol502499q	doi.org/10.1021/ol502499q	Nickel-Catalyzed alpha-Arylation of Zinc Enolates with Polyfluoroarenes via C-F Bond Activation under Neutral Conditions		Org. Lett.	64	Shen, QL	FALSE	FALSE	FALSE	FALSE
4072	10.1016/j.tetlet.2014.09.001	doi.org/10.1016/j.tetlet.2014.09.001	Operationally convenient method for preparation of sulfonamides containing alpha,alpha-difluoro-beta-amino carbonyl moiety		Tetrahedron Lett.	64	Han, JL	FALSE	FALSE	FALSE	FALSE
4073	10.1021/cs501045v	doi.org/10.1021/cs501045v	Nickel-Catalyzed Amination of Aryl Chlorides and Sulfamates in 2-Methyl-THF		ACS Catal.	64	Garg, NK	FALSE	FALSE	FALSE	FALSE
4074	10.1002/jhet.1898	doi.org/10.1002/jhet.1898	A Facile Synthesis of Novel Cyclic Esters of gamma-Keto Acid Derivatives by Heck Coupling Reaction		J. Heterocycl. Chem.	64	Krishnamurthy, G	FALSE	FALSE	FALSE	FALSE
4075	10.1021/ja5039616	doi.org/10.1021/ja5039616	Pd/NHC-Catalyzed Enantiospecific and Regioselective Suzuki-Miyaura Arylation of 2-Arylaziridines: Synthesis of Enantioenriched 2-Arylphenethylamine Derivatives		J. Am. Chem. Soc.	64	Takeda, Y	FALSE	FALSE	FALSE	FALSE
4076	10.1021/ol302112q	doi.org/10.1021/ol302112q	Kumada-Tamao-Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl		Org. Lett.	64	Prieto, A	FALSE	FALSE	FALSE	FALSE
4077	10.1021/ol301248d	doi.org/10.1021/ol301248d	Rhodium-Catalyzed Asymmetric Formal Cycloadditions of Racemic Butadiene Monoxide with Imines		Org. Lett.	64	Du, HF	FALSE	FALSE	FALSE	FALSE
4078	10.1021/ol300950r	doi.org/10.1021/ol300950r	Metal-Free Ortho C-H Borylation of 2-Phenoxypyridines under Mild Conditions		Org. Lett.	64	Fu, H	FALSE	FALSE	FALSE	FALSE
4079	10.1055/s-0031-1290751	doi.org/10.1055/s-0031-1290751	Photochemically Induced Synthesis of the Topoisomerase I Inhibitors Indeno[1,2-c]isoquinoline-5,11-diones		Synlett	64	Couture, A	TRUE	FALSE	FALSE	FALSE
4080	10.1002/adsc.201100285	doi.org/10.1002/adsc.201100285	Cross-Coupling of Grignard Reagents with Sulfonyl-Activated sp(3) Carbon-Nitrogen Bonds		Adv. Synth. Catal.	64	Tian, SK	FALSE	FALSE	FALSE	FALSE
4081	10.1002/anie.201100620	doi.org/10.1002/anie.201100620	Visual Chiral Recognition through Enantioselective Metallogel Collapsing: Synthesis, Characterization, and Application of Platinum-Steroid Low-Molecular-Mass Gelators		Angew. Chem.-Int. Edit.	64	Tu, T	FALSE	FALSE	FALSE	FALSE
4082	10.1021/ar100082d	doi.org/10.1021/ar100082d	Exploration of New C-O Electrophiles in Cross-Coupling Reactions		Accounts Chem. Res.	64	Shi, ZJ	FALSE	TRUE	FALSE	FALSE
4083	10.1016/j.tetlet.2009.05.079	doi.org/10.1016/j.tetlet.2009.05.079	Air-tolerant C-C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen		Tetrahedron Lett.	64	Teply, F	FALSE	FALSE	FALSE	FALSE
4084	10.1002/adsc.200900287	doi.org/10.1002/adsc.200900287	A New Approach to Pyrrolocoumarin Derivatives by Palladium-Catalyzed Reactions: Expedient Construction of Polycyclic Lamellarin Scaffold		Adv. Synth. Catal.	64	Xu, MH	FALSE	FALSE	FALSE	FALSE
4085	10.1134/S0965545X08030012	doi.org/10.1134/S0965545X08030012	Organometallic compounds as reversible spin scavengers and chain growth regulators in free-radical polymerization processes		Polym. Sci. Ser. A	64	Grishin, DF	FALSE	FALSE	FALSE	FALSE
4086	10.1016/j.tet.2004.09.010	doi.org/10.1016/j.tet.2004.09.010	Asymmetric Kumada-Corriu cross-coupling reaction with Pd-2(dba)(3) and an N-Ar axially chiral mimetic-type ligand catalyst		Tetrahedron	64	Kondo, K	FALSE	FALSE	FALSE	FALSE
4087	10.5059/yukigoseikyokaishi.57.608	doi.org/10.5059/yukigoseikyokaishi.57.608	Rhodium and iridium complex-catalyzed highly selective reactions		J. Synth. Org. Chem. Jpn.	64	Takeuchi, R	FALSE	FALSE	FALSE	FALSE
4088	10.1021/ja00413a014	doi.org/10.1021/ja00413a014	INTERACTION OF NICKEL(0) COMPLEXES WITH ALLYL CARboxYLATES, ALLYL ETHERS, ALLYLIC ALCOHOLS, AND VINYL-ACETATE - PI-COMPLEX FORMATION AND OXIDATIVE ADDITION TO NICKEL INVOLVING CLEAVAGE OF THE ALKENYL-OXYGEN BOND		J. Am. Chem. Soc.	64	YAMAMOTO, T	FALSE	FALSE	FALSE	FALSE
4089	10.1021/acs.orglett.2c00029	doi.org/10.1021/acs.orglett.2c00029	Rhodium(III)-Catalyzed Asymmetric 1,2-Carboamidation of Alkenes Enables Access to Chiral 2,3-Dihydro-3-benzofuranmethanamides		Org. Lett.	64	Yang, YX; Zhou, B	FALSE	FALSE	FALSE	FALSE
4090	10.1002/anie.202200003	doi.org/10.1002/anie.202200003	Covalent Organic Framework Based Functional Materials: Important Catalysts for Efficient CO2 Utilization		Angew. Chem.-Int. Edit.	64	Cai, YP; Li, SL; Lan, YQ	FALSE	FALSE	FALSE	FALSE
4091	10.1021/acs.orglett.1c03720	doi.org/10.1021/acs.orglett.1c03720	Palladium-Catalyzed Aminomethylative Oppolzer-Type Cyclization of Enynes: Access to Aminomethylated Benzofulvenes		Org. Lett.	64	Huang, HM	FALSE	FALSE	FALSE	FALSE
4092	10.1038/s41467-021-27437-8	doi.org/10.1038/s41467-021-27437-8	Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO2		Nat. Commun.	64	Yu, DG	FALSE	FALSE	FALSE	FALSE
4093	10.1039/d1ob01990b	doi.org/10.1039/d1ob01990b	Synthesis of alkynamides through reaction of alkyl- or aryl-substituted alkynylaluminums with isocyanates		Org. Biomol. Chem.	64	Lee, Y	FALSE	FALSE	FALSE	FALSE
4094	10.1021/acs.orglett.1c03324	doi.org/10.1021/acs.orglett.1c03324	A Dual CuH- and Pd-Catalyzed Stereoselective Synthesis of Highly Substituted 1,3-Dienes		Org. Lett.	64	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
4095	10.1002/anie.202112993	doi.org/10.1002/anie.202112993	Simultaneous Kinetic Resolution and Asymmetric Induction within a Borrowing Hydrogen Cascade Mediated by a Single Catalyst		Angew. Chem.-Int. Edit.	64	Yu, PY; Xing, XY	FALSE	FALSE	FALSE	FALSE
4096	10.1039/d1cc05347g	doi.org/10.1039/d1cc05347g	Selective synthesis of enol ethers via nickel-catalyzed cross coupling of alpha-oxy-vinylsulfones with alkylzinc reagents		Chem. Commun.	64	Zhang, X; Niu, DW	FALSE	FALSE	FALSE	FALSE
4097	10.1021/acs.jpca.1c05412	doi.org/10.1021/acs.jpca.1c05412	Insight into the Mechanism and Regioselectivity of Pd(OAc)(2)-Catalyzed C-O Bond Activation via a beta-O Elimination Approach: A Computational Study		J. Phys. Chem. A	64	Xue, Y	FALSE	FALSE	FALSE	FALSE
4098	10.1016/j.tetlet.2021.153326	doi.org/10.1016/j.tetlet.2021.153326	Nickel-catalyzed sustainable synthesis of N-heterocycles through dehydrogenative coupling of alcohols		Tetrahedron Lett.	64	Mukherjee, A	FALSE	FALSE	FALSE	FALSE
4099	10.1039/d1sc03596g	doi.org/10.1039/d1sc03596g	Synthesis of C-acyl furanosides via the cross-coupling of glycosyl esters with carboxylic acids		Chem. Sci.	64	Diao, TN	FALSE	FALSE	FALSE	FALSE
4100	10.1021/jacs.1c05281	doi.org/10.1021/jacs.1c05281	Design of an Electron-Withdrawing Benzonitrile Ligand for Ni-Catalyzed Cross-Coupling Involving Tertiary Nucleophiles		J. Am. Chem. Soc.	64	Rousseaux, SAL	FALSE	TRUE	FALSE	FALSE
4101	10.1021/acs.joc.1c00997	doi.org/10.1021/acs.joc.1c00997	Synthesis of Long-Chain Alkanoyl Benzenes by an Aluminum(III) Chloride-Catalyzed Destannylative Acylation Reaction		J. Org. Chem.	64	Roemer, M	FALSE	FALSE	FALSE	FALSE
4102	10.1021/acs.joc.1c00808	doi.org/10.1021/acs.joc.1c00808	Tris(pentafluorophenyl)borane-Catalyzed Formal Cyanoalkylation of Indoles with Cyanohydrins		J. Org. Chem.	64	Kiyokawa, K; Minakata, S	FALSE	FALSE	FALSE	FALSE
4103	10.1021/jacs.1c03038	doi.org/10.1021/jacs.1c03038	Selective C-O Bond Reduction and Borylation of Aryl Ethers Catalyzed by a Rhodium-Aluminum Heterobimetallic Complex		J. Am. Chem. Soc.	64	Nakao, Y	FALSE	FALSE	FALSE	FALSE
4104	10.1039/d0qo01607a	doi.org/10.1039/d0qo01607a	Copper-catalyzed four-component reaction of alkenes, Togni's reagent, amines and CO2: stereoselective synthesis of (Z)-enol carbamates		Org. Chem. Front.	64	Qi, CR; Jiang, HF	FALSE	FALSE	FALSE	FALSE
4105	10.1039/d1cc00202c	doi.org/10.1039/d1cc00202c	Palladium-catalyzed decarbonylative and decarboxylative cross-coupling of acyl chlorides with potassium perfluorobenzoates affording unsymmetrical biaryls		Chem. Commun.	64	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
4106	10.1021/acscatal.1c00225	doi.org/10.1021/acscatal.1c00225	Catalyst-Controlled Regiodivergent Synthesis of 1-and 3-Thiosugars with High Stereoselectivity and Chemoselectivity		ACS Catal.	64	Huang, NAY; Zou, K; Yao, H	FALSE	FALSE	FALSE	FALSE
4107	10.1016/j.jorganchem.2017.03.045	doi.org/10.1016/j.jorganchem.2017.03.045	Towards phosphine-free Pd(II) pincer complexes for catalyzing Suzuki-Miyaura cross-coupling reaction in aqueous medium		J. Organomet. Chem.	64	Karvembu, R	FALSE	FALSE	FALSE	FALSE
4108	10.1021/jacs.7b04279	doi.org/10.1021/jacs.7b04279	Combined Theoretical and Experimental Studies of Nickel-Catalyzed Cross-Coupling of Methoxyarenes with Arylboronic Esters via C-O Bond Cleavage		J. Am. Chem. Soc.	64	Mori, S	FALSE	FALSE	FALSE	FALSE
4109	10.1021/acs.orglett.7b01588	doi.org/10.1021/acs.orglett.7b01588	Direct Conversion of Carboxylic Acids to Alkyl Ketones		Org. Lett.	64	Molander, GA	FALSE	FALSE	FALSE	FALSE
4110	10.1021/jacs.7b02742	doi.org/10.1021/jacs.7b02742	Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions		J. Am. Chem. Soc.	64	Zhou, JS	FALSE	FALSE	FALSE	FALSE
4111	10.1039/c7cc01655g	doi.org/10.1039/c7cc01655g	Regioselective hydrosilylation of epoxides catalysed by nickel(II) hydrido complexes		Chem. Commun.	64	Gade, LH	FALSE	FALSE	FALSE	FALSE
4112	10.1039/c6gc03355e	doi.org/10.1039/c6gc03355e	Metal-free radical C-H methylation of pyrimidinones and pyridinones with dicumyl peroxide		Green Chem.	64	Zou, JP	FALSE	FALSE	FALSE	FALSE
4113	10.1002/chem.201603832	doi.org/10.1002/chem.201603832	Cobalt-Catalyzed Reductive Cross-Coupling Between Styryl and Benzyl Halides		Chem.-Eur. J.	64	Gosmini, C	FALSE	FALSE	FALSE	FALSE
4114	10.1039/c7ra10755b	doi.org/10.1039/c7ra10755b	Theoretical study on the reaction mechanism of ligandless Ni-catalyzed hydrodesulfurization of aryl sulfide		RSC Adv.	64	Wang, MY; Liu, JY	FALSE	FALSE	FALSE	FALSE
4115	10.1021/acscatal.6b02576	doi.org/10.1021/acscatal.6b02576	Direct and Practical Synthesis of Primary Anilines through Iron-Catalyzed C-H Bond Amination		ACS Catal.	64	Morandi, B	FALSE	FALSE	FALSE	FALSE
4116	10.1016/j.jorganchem.2016.08.017	doi.org/10.1016/j.jorganchem.2016.08.017	Polystyrene-resin supported N-heterocyclic carbene-Pd(II) complex based on plant-derived theophylline: A reusable and effective catalyst for the Suzuki-Miyaura cross-coupling reaction of arenediazonium tetrafluoroborate salts with arylboronic acids		J. Organomet. Chem.	64	Movassagh, B	FALSE	FALSE	FALSE	FALSE
4117	10.1139/cjc-2016-0006	doi.org/10.1139/cjc-2016-0006	Synthesis of building blocks for an iterative approach towards oligomers of the Streptococcus pneumoniae type 1 zwitterionic capsular polysaccharide repeating unit		Can. J. Chem.	64	Oscarson, S	FALSE	FALSE	FALSE	FALSE
4118	10.1021/jacs.6b07844	doi.org/10.1021/jacs.6b07844	Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes		J. Am. Chem. Soc.	64	Hayashi, T	FALSE	FALSE	FALSE	FALSE
4119	10.1021/acs.joc.5b02667	doi.org/10.1021/acs.joc.5b02667	One-Pot Synthesis of Arylketones from Aromatic Acids via Palladium-Catalyzed Suzuki Coupling		J. Org. Chem.	64	Zeng, Z	FALSE	FALSE	FALSE	FALSE
4120	10.3762/bjoc.12.49	doi.org/10.3762/bjoc.12.49	Copper-mediated arylation with arylboronic acids: Facile and modular synthesis of triarylmethanes		Beilstein J. Org. Chem.	64	Rao, HSP	FALSE	FALSE	FALSE	FALSE
4121	10.1039/c5cc10272c	doi.org/10.1039/c5cc10272c	A practical cobalt-catalyzed cross-coupling of benzylic zinc reagents with aryl and heteroaryl bromides or chlorides		Chem. Commun.	64	Knochel, P	FALSE	FALSE	FALSE	FALSE
4122	10.1007/3418_2015_117	doi.org/10.1007/3418_2015_117	Nickel-Catalyzed C-H Bond Functionalization Utilizing an N,N '-Bidentate Directing Group		Top. Organomet. Chem.	64	Chatani, N	FALSE	FALSE	FALSE	FALSE
4123	10.1021/acs.orglett.1c00100	doi.org/10.1021/acs.orglett.1c00100	Direct Arylation of Azoles Enabled by Pd/Cu Dual Catalysis	Reactions of PdCl2 with 2 equiv of N,N'disubstituted-imidazole-2-thiones (RRC3N2S)-R-1-C-2 (R-1 = R-2 = Me (1a), Pr-i (1b), Cy (1c), C6Me3H2 (1d); R-1 = Me, R-2 = Ph (1e)) under the different conditions afford five mononuclear complexes trans-[((RRC3N2S)-R-1-C-2)(2)PdCl2] (R-1 = R-2 = Me (2a), Pr-i (2b), Cy (2c), C6Me3H2 (2d); R-1= Me, R-2 = Ph (2e)) and five binuclear Pd(II) complexes [(PdCl2){mu-((RRC3N2S)-R-1-C-2)}](2) (R-1 = R-2 = Me (3a), Pr-i (3b), Cy (3c), C6Me3H2 (3d); R-1 = Me, R-2 = Ph (3e)), respectively. Complexes 2a-2e are easily converted into the corresponding 3a-3e by adding equimolar PdCl2 in refluxing MeOH, while the reverse reaction is achieved at room temperature by addition of 2 equiv of la le. In 2b, 2d, and 2e, each Pd(II) holds a distorted square planar geometry completed by two trans Cl atoms and two trans S atoms. Complexes 3a-3e have a dimeric [Pd2S2] structure in which two {PdCl2} units are interlinked by two N,N'-disubstituted-imidazole-2-thiones. Each Pd(II) adopts a distorted square planar geometry accomplished by two cis Cl atoms and two cis bridging S atoms. Among them, complex 3d has the two largest C6Me3H2 groups on the 2 and 5 positions of imidazole-2-thione, the longest Pd-mu-S bond, the largest S-Pd-S angle, and displays the highest catalytic activity toward Suzuki Miyaura and copper-free Sonogashira cross-coupling reactions, which are confirmed by density functional theory calculations. The results provide an interesting insight into the introduction of various substituent groups into the periphery ligands of coordination complex-based catalysts, which could tune their geometric structures to acquire the best catalytic activity toward organic reactions.	Org. Lett.	63	Slutskyy, Y	FALSE	FALSE	FALSE	FALSE
4124	10.1016/j.poly.2020.114979	doi.org/10.1016/j.poly.2020.114979	Dehydrogenative amide synthesis from alcohols and amines utilizing N-heterocyclic carbene-based ruthenium complexes as efficient catalysts: The influence of catalyst loadings, ancillary and added ligands	The mechanisms of Ni-catalyzed C-H arylation, alkylation, and sulfenylation with N,N-bidentate directing groups are investigated using density functional theory (DFT) calculations. While the C-H cleavage occurs via the concerted metalation-deprotonation (CMD) mechanism in all types of reactions, the subsequent C-C and C-X bond formation steps may occur via either oxidative addition to form a Ni(IV) intermediate or radical pathways involving Ni(III) complexes generated from homolytic dissociation of disulfides/peroxides or halide-atom transfer from alkyl halides. DFT calculations revealed that radical mechanisms are preferred in reactions with sterically hindered coupling partners with relatively low bond dissociation energies (BDE) such as dicumyl peroxide, heptafluoroisopropyl iodide and diphenyl disulfide. In contrast, these radical processes are highly disfavored when generating unstable phenyl and primary alkyl radicals. In such cases, the reaction proceeds via an oxidative addition/reductive elimination mechanism involving a Ni(IV) intermediate. These theoretical insights into the substrate-controlled mechanisms in the C-H functionalizations were employed to investigate a number of experimental phenomena including substituent effects on reactivity, chemo- and regioselectivity and the effects of oxidant in the intermolecular oxidative C-H/C-H coupling reactions.	Polyhedron	63	Cheng, H	FALSE	FALSE	FALSE	FALSE
4125	10.1039/d0sc04578k	doi.org/10.1039/d0sc04578k	Understanding the unique reactivity patterns of nickel/JoSPOphos manifold in the nickel-catalyzed enantioselective C-H cyclization of imidazoles	We developed a novel phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides (p-QMs). This reaction provided a promising method for the synthesis of triarylmethanes, which widely exist in natural products and in molecules which have been shown to have biological and pharmacological activity.	Chem. Sci.	63	Liu, JB; Chen, DZ	FALSE	FALSE	FALSE	FALSE
4126	10.1021/acs.orglett.0c03998	doi.org/10.1021/acs.orglett.0c03998	Convergent Evolution of Diastereomeric Mixtures of 5-Methoxy-pentylzirconocenes toward Trans-1,2-substituted Cyclopentanes	Direct nickel-catalyzed.alkylation of chiral N-acyl-ilisopropy1-1,3-thiazolidine-2-thiones using a commercially available nickel(II) complex, (Me3P)(2)NiCl2, has been developed for tropylium and trityl tetrafluoroborate salts. The reaction provides a single diastereomer of the corresponding adducts in good to high yields, which, in turn, can be easily converted into a wide array of enantiomerically pure compounds that are difficult to obtain by other asymmetric procedures.	Org. Lett.	63	Vasse, JL	FALSE	FALSE	FALSE	FALSE
4127	10.1002/cssc.202002830	doi.org/10.1002/cssc.202002830	Tungsten-Catalyzed Direct N-Alkylation of Anilines with Alcohols	An efficient Ni-catalyzed reductive carboxylation of allylic alcohols with CO2 has been successfully developed, providing linear beta,gamma-unsaturated carboxylic acids as the sole regioisomer with generally high E/Z stereoselectivity. In addition, the carboxylic acids can be generated from propargylic alcohols via hydrogenation to give allylic alcohol intermediates, followed by carboxylation. A preliminary mechanistic investigation suggests that the hydrogenation step is made possible by a Ni hydride intermediate produced by a hydrogen atom transfer from water.	ChemSusChem	63	Ke, ZF	FALSE	FALSE	FALSE	FALSE
4128	10.1039/d0cc04831c	doi.org/10.1039/d0cc04831c	Base-mediated cascade amidination/N-alkylation of amines by alcohols	A general method is reported for the stereo selective preparation of highly functionalized allylic thioethers. This protocol is based on a Pd-catalyzed thiolation of modular vinyl cyclic carbonate substrates and features high (Z) selectivity, good yields, minimal waste, ample product scope, and operational simplicity. A one-pot strategy was used for the stereoselective formation of pharma-relevant allylic sulfones derived from their in situ prepared thioether precursors.	Chem. Commun.	63	Zhang, CY; Zhang, GY	FALSE	FALSE	FALSE	FALSE
4129	10.1016/j.tetlet.2020.152254	doi.org/10.1016/j.tetlet.2020.152254	Efficient aerobic cross-dehydrogenative coupling of tertiary amines over NiGa layered double oxide	The present review offers an overview of nonclassical (e.g., with no pre-or in situ activation of a carboxylic acid partner) approaches for the construction of amide bonds. The review aims to comprehensively discuss relevant work, which was mainly done in the field in the last 20 years. Organization of the data follows a subdivision according to substrate classes: catalytic direct formation of amides from carboxylic and amines (section 2 ); the use of carboxylic acid surrogates (section 3); and the use of amine surrogates (section 4). The ligation strategies (NCL, Staudinger, KAHA, KATs, etc.) that could involve both carboxylic acid and amine surrogates are treated separately in section 5 .	Tetrahedron Lett.	63	Zhou, WY	FALSE	FALSE	FALSE	FALSE
4130	10.1002/aoc.5869	doi.org/10.1002/aoc.5869	Benzimidazole bearing Pd-PEPPSI complexes catalyzed direct C2-arylation/heteroarylation ofN-substituted benzimidazoles	Six new imidazolium salts of the form 3-R-1-picolylimidazolium bromide (la: R = 4-nitrophenyl, lb: R = 4-acetylphenyl, 1c: R = 4-cyanophenyl, ld: R = le: R = butenyl, if: R = pentenyl) were synthesised and isolated in high yields. The corresponding Ag NHC intermediate complexes 2a, 2d, and 2e were transmetalated to yield [M(NHC)(2)Cl-2 M = Co, Nil complexes in good to excellent yields. The Co-NHC (3a, 3d, 3e) and Ni NHC (3a', 3d', 3e') complexes were relatively stable in air, insoluble in chlorinated solvents but very soluble in methanol and DMSO. Poorly resolved NMR spectra and magnetic susceptibility values of 2.53 and 2.73 mu(B) for 3d and 3e respectively suggest both to be paramagnetic cobalt complexes. All the imidazolium salts, isolated Ag-NHC complexes and the corresponding Co and Ni NHC complexes were characterised by spectroscopic and analytical techniques. The complexes were found to be active at tow catalyst loading (1 mol%) for the C N coupling of aniline with phenyl bromide under mild reaction conditions. In addition, the in situ generated catalyst obtained from a mixture of NiCl2/1a (1:2 molar ratio) initiated the C-N coupling of several aryl amines with substituted aryl bromides bearing a wide variety of functional groups. Good to excellent yields of the desired diaryl amine products were obtained. The yields are comparable to data obtained with palladium catalysts or to data obtained under harsher temperature conditions of Cu mediated Ullman reactions.	Appl. Organomet. Chem.	63	Peddiahgari, VGR	FALSE	FALSE	FALSE	FALSE
4131	10.1021/acs.orglett.0c01284	doi.org/10.1021/acs.orglett.0c01284	Nickel-Catalyzed Formal Aminocarbonylation of Secondary Benzyl Chlorides with Isocyanides	Nickel-catalyzed enantioselective cross-couplings between symmetric cyclic sulfates and aromatic Grignard reagents are described. These reactions are effective with a broad range of substituted cyclic sulfates and deliver products with asymmetric tertiary carbon centers. Mechanistic experiments point to a stereoinvertive S(N)2-like oxidative addition of a nickel complex to the electrophilic substrate.	Org. Lett.	63	Qu, JP; Chen, YF	FALSE	FALSE	FALSE	FALSE
4132	10.1002/ajoc.202000188	doi.org/10.1002/ajoc.202000188	Direct Access to (+/-)-10-Desbromoarborescidine A from Tryptamine and Pentane-1,5-diol	Pyrimidin-2-y1 tosylates which are successfully applied as the electrophiles instead of halides coupled with olefins via Pd(PPh3)(2)Cl-2 catalyzed Mizoroki Heck reaction conditions to give the corresponding C2-alkenyl pyrimidine derivatives with high beta-regioselectivity. This protocol proves to be tolerant of various pyrimidin-2-y1 tosylates as well as various olefins including styrene deriptives, aliphatic olefins (vinyl cyanide, methyl acrylate, ethyl acrylate, n-butyl acrylate, butyl vinyl ether, 1-hexene and 1-octene). (C) 2016 Elsevier Ltd. All rights reserved.	Asian J. Org. Chem.	63	Achard, M	FALSE	FALSE	FALSE	FALSE
4133	10.1021/acs.orglett.0c01109	doi.org/10.1021/acs.orglett.0c01109	Ni-Catalyzed Allylic Dearomatization Reaction of beta-Naphthols with Allylic Alcohols	Allylic amination, directly from alcohols, has been demonstrated without any Lewis acid activators using an efficient and regiospecific molecular iron catalyst. Various amines and alcohols were employed and the reaction proceeded through the oxidation/reduction (redox) pathway. A direct one-step synthesis of common drugs, such as cinnarizine and nafetifine, was exhibited from cinnamyl alcohol that produced water as side product.	Org. Lett.	63	You, SL	FALSE	FALSE	FALSE	FALSE
4134	10.1021/acscatal.0c00980	doi.org/10.1021/acscatal.0c00980	Nickel-Catalyzed Intermolecular Carbobromination of Alkynes	There is significant interest in the development of C-C bond-forming methodologies that directly access challenging benzylic stereocenters. Predominantly, efforts have been focused on the development of enantiospecific or enantioselective cross-coupling methodologies. An alternate and conceptually ideal approach involves the development of branch-selective and enantioselective Murai-type alkene hydroarylations. Recent progress towards this broad, yet challenging goal is highlighted.	ACS Catal.	63	Kurahashi, T; Matsubara, S	FALSE	FALSE	FALSE	FALSE
4135	10.1021/acs.orglett.0c00624	doi.org/10.1021/acs.orglett.0c00624	Intermolecular Vicinal Diaminative Assembly of Tetrahydroquinoxalines via Metal-free Oxidative [4+2] Cycloaddition Strategy	The area of catalysis of radical reactions has recently flourished. Various reaction conditions have been discovered and explained in terms of catalytic cycles. These cycles rarely stand alone as unique paths from substrates to products. Instead, most radical reactions have innate chains which form products without any catalyst. How do we know if a species added in catalytic amounts is a catalyst, an initiator, or something else? Herein we critically address both catalystfree and catalytic radical reactions through the lens of radical chemistry. Basic principles of kinetics and thermodynamics are used to address problems of initiation, propagation, and inhibition of radical chains. The catalysis of radical reactions differs from other areas of catalysis. Whereas efficient innate chain reactions are difficult to catalyze because individual steps are fast, both inefficient chain processes and non-chain processes afford diverse opportunities for catalysis, as illustrated with selected examples.	Org. Lett.	63	Zhong, FR	FALSE	FALSE	FALSE	FALSE
4136	10.1021/acs.joc.9b03294	doi.org/10.1021/acs.joc.9b03294	Cu-Catalyzed Generation of Alkyl Radicals from Alkylsilyl Peroxides and Subsequent C(sp(3)) C(sp(2)) Cross-Coupling with Arylboronic Acids	The direct arylation of pyridine substrates using non-precious catalysts is underdeveloped but highly desirable due to its efficiency to access important motifs while being extremely cost-effective. The first nickel-catalyzed C-3 direct arylation of pyridine derivatives to provide a new approach to valuable 1-azafluorene pharmacophore frameworks was developed. This transformation is accomplished using air-stable nickel catalyst precursors combined with phenanthroline ligands and tolerates a variety of substituents. Computational studies suggest facile oxidative addition via the pyridinium form, deprotonation, and a subsequent carbo-nickelation cyclization. Nickel homolysis/recombination permits isomerization to the stereochemical array needed for the final elimination.	J. Org. Chem.	63	Maruoka, K	FALSE	FALSE	FALSE	FALSE
4137	10.1021/jacs.9b12519	doi.org/10.1021/jacs.9b12519	Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds		J. Am. Chem. Soc.	63	Larionov, OV	FALSE	FALSE	FALSE	FALSE
4138	10.1021/acs.orglett.9b04414	doi.org/10.1021/acs.orglett.9b04414	Palladium-Catalyzed Synthesis of 1,2-Diketones from Aryl Halides and Organoaluminum Reagents Using tert-Butyl Isocyanide as the CO Source		Org. Lett.	63		FALSE	FALSE	FALSE	FALSE
4139	10.1038/s41428-019-0259-3	doi.org/10.1038/s41428-019-0259-3	A robust nickel catalyst with an unsymmetrical propyl-bridged diphosphine ligand for catalyst-transfer polymerization		Polym. J.	63	Noonan, KJT	FALSE	FALSE	FALSE	FALSE
4140	10.1002/anie.201912055	doi.org/10.1002/anie.201912055	Manganese-Catalyzed beta-Methylation of Alcohols by Methanol		Angew. Chem.-Int. Edit.	63	Kempe, R	FALSE	FALSE	FALSE	FALSE
4141	10.1016/j.jpowsour.2019.227233	doi.org/10.1016/j.jpowsour.2019.227233	Improved proton conductive membranes from poly (phenylenebenzophenone)s with pendant sulfonyl imide acid groups for fuel cells		J. Power Sources	63	Kim, W	FALSE	FALSE	FALSE	FALSE
4142	10.1039/c9ob01547g	doi.org/10.1039/c9ob01547g	A cascade process for directly converting nitriles (RCN) to cyanamides (RNHCN) via SO2F2-activated Tiemann rearrangement		Org. Biomol. Chem.	63	Ding, CR	FALSE	FALSE	FALSE	FALSE
4143	10.1021/acs.oprd.9b00207	doi.org/10.1021/acs.oprd.9b00207	Pd-Catalyzed Dehydrogenative Oxidation of Alcohols to Functionalized Molecules		Org. Process Res. Dev.	63	Mori, T	FALSE	FALSE	FALSE	FALSE
4144	10.1039/c9cc02603g	doi.org/10.1039/c9cc02603g	Nickel(ii)-catalyzed direct olefination of benzyl alcohols with sulfones with the liberation of H-2		Chem. Commun.	63	Balaraman, E	FALSE	FALSE	FALSE	FALSE
4145	10.1002/anie.201812702	doi.org/10.1002/anie.201812702	Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes under Visible-Light Photoredox Catalysis		Angew. Chem.-Int. Edit.	63	Casitas, A; Lloret-Fillol, J	TRUE	FALSE	FALSE	FALSE
4146	10.1002/ejoc.201800341	doi.org/10.1002/ejoc.201800341	Highly Regioselective Isoquinoline Synthesis via Nickel-Catalyzed Iminoannulation of Alkynes at Room Temperature		Eur. J. Org. Chem.	63	Zhang, B	FALSE	FALSE	FALSE	FALSE
4147	10.1002/adsc.201800504	doi.org/10.1002/adsc.201800504	Synthesis of Arylamines via Non-Aerobic Dehydrogenation Using a Palladium/Carbon-Ethylene System		Adv. Synth. Catal.	63	Hayashi, M	FALSE	FALSE	FALSE	FALSE
4148	10.1021/acs.joc.8b01176	doi.org/10.1021/acs.joc.8b01176	Palladium-Catalyzed Direct Arylation of Polyfluoroarenes for Accessing Tetra-ortho-Substituted Biaryls: Buchwald-type Ligand Having Complementary -PPh2 Moiety Exhibits Better Efficiency		J. Org. Chem.	63	Kwong, FY	FALSE	FALSE	FALSE	FALSE
4149	10.1246/cl.180385	doi.org/10.1246/cl.180385	Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar-Br Bond		Chem. Lett.	63	Yoshida, H	FALSE	FALSE	FALSE	FALSE
4150	10.1039/c8sc01256c	doi.org/10.1039/c8sc01256c	Copper mediated C-H amination with oximes: en route to primary anilines		Chem. Sci.	63	Dai, HX	FALSE	FALSE	FALSE	FALSE
4151	10.3390/molecules23061449	doi.org/10.3390/molecules23061449	Cobalt-Catalyzed (Hetero)arylation of Saturated Cyclic Amines with Grignard Reagents		Molecules	63	Guerinot, A; Cossy, J	FALSE	FALSE	FALSE	FALSE
4152	10.1021/acs.orglett.8b00755	doi.org/10.1021/acs.orglett.8b00755	Amide-Directed Ru-Catalyzed Hydrodemethoxylation of ortho-Methoxy-Benzamides and -Naphthamides: A DoM Reaction Counterpart		Org. Lett.	63	Snieckus, V	FALSE	FALSE	FALSE	FALSE
4153	10.1016/j.tet.2018.03.039	doi.org/10.1016/j.tet.2018.03.039	Nickel(II)-catalyzed addition reaction of arylboronic acids to isatins		Tetrahedron	63	Qiu, LQ	FALSE	FALSE	FALSE	FALSE
4154	10.1002/cptc.201700232	doi.org/10.1002/cptc.201700232	Aryl Sulfonates as Initiators for Extreme Ultraviolet Lithography: Applications in Epoxy-Based Hybrid Materials		ChemPhotoChem	63	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
4155	10.1039/c8cc00001h	doi.org/10.1039/c8cc00001h	Stereoselective synthesis of a Podophyllum lignan core by intramolecular reductive nickel-catalysis		Chem. Commun.	63	Peng, Y	FALSE	FALSE	FALSE	FALSE
4156	10.1039/c7nj03989a	doi.org/10.1039/c7nj03989a	Copper-catalyzed alpha-C-H acyloxylation of carbonyl compounds with terminal alkynes		New J. Chem.	63	Yang, T; Zhou, CS	FALSE	FALSE	FALSE	FALSE
4157	10.1016/j.poly.2017.08.021	doi.org/10.1016/j.poly.2017.08.021	Seven copper (I) complexes of diphosphine ligands and N boolean AND N ligands: Syntheses, structural characterizations and spectroscopic properties		Polyhedron	63	Jin, QH	FALSE	FALSE	FALSE	FALSE
4158	10.1016/j.tet.2017.09.052	doi.org/10.1016/j.tet.2017.09.052	Synthesis of naphthyl-substituted terminal olefins via Pd-Catalyzed one-pot coupling of acetylnaphthalene, N-Tosylhydrazide with aryl halide		Tetrahedron	63	Liu, P; Liu, Y	FALSE	FALSE	FALSE	FALSE
4159	10.1039/c6ob00013d	doi.org/10.1039/c6ob00013d	Synthesis of N-heterocyclic carbene-PdCl2-(iso)quinoline complexes and their application in arylamination at low catalyst loadings		Org. Biomol. Chem.	63	Lu, JM	FALSE	FALSE	FALSE	FALSE
4160	10.1002/cctc.201500575	doi.org/10.1002/cctc.201500575	Palladium-Catalyzed sp(2) C-H Arylation of Azoarenes with Arylhydrazines		ChemCatChem	63	Ye, Y	FALSE	FALSE	FALSE	FALSE
4161	10.1002/anie.201507902	doi.org/10.1002/anie.201507902	Salt- Free Reduction of Nonprecious Transition- Metal Compounds: Generation of Amorphous Ni Nanoparticles for Catalytic C-C Bond Formation		Angew. Chem.-Int. Edit.	63	Sato, K	FALSE	FALSE	FALSE	FALSE
4162	10.1021/jacs.5b08477	doi.org/10.1021/jacs.5b08477	Asymmetric Allylic C-H Oxidation for the Synthesis of Chromans		J. Am. Chem. Soc.	63	Gong, LZ	FALSE	FALSE	FALSE	FALSE
4163	10.1002/anie.201505789	doi.org/10.1002/anie.201505789	Dehydrogenative Carbon-Carbon Bond Formation Using Alkynyloxy Moieties as Hydrogen-Accepting Directing Groups		Angew. Chem.-Int. Edit.	63	Minami, Y	FALSE	FALSE	FALSE	FALSE
4164	10.1021/acs.orglett.5b02200	doi.org/10.1021/acs.orglett.5b02200	Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C-O Bond Cleavage		Org. Lett.	63	Tobisu, M	FALSE	FALSE	FALSE	FALSE
4165	10.1016/j.jorganchem.2015.04.019	doi.org/10.1016/j.jorganchem.2015.04.019	Synthesis and catalytic activity of nickel(II) complexes of CNC pincer-type N-heterocyclic carbene ligands		J. Organomet. Chem.	63	Luo, MM	FALSE	FALSE	FALSE	FALSE
4166	10.1002/adsc.201500304	doi.org/10.1002/adsc.201500304	Nickel- or Cobalt-Catalyzed Cross-Coupling of Arylsulfonic Acid Salts with Grignard Reagents		Adv. Synth. Catal.	63	Reeves, JT	FALSE	FALSE	FALSE	FALSE
4167	10.1002/adsc.201400761	doi.org/10.1002/adsc.201400761	Ligand-Free Nickel-Catalysed 1,4-Addition of Arylboronic Acids to alpha,beta-Unsaturated Carbonyl Compounds		Adv. Synth. Catal.	63	Song, GH	FALSE	FALSE	FALSE	FALSE
4168	10.1021/jacs.5b01671	doi.org/10.1021/jacs.5b01671	Direct Aerobic Carbonylation of C(sp(2))-H and C(sp(3))-H Bonds through Ni/Cu Synergistic Catalysis with DMF as the Carbonyl Source		J. Am. Chem. Soc.	63	Ge, HB	FALSE	FALSE	FALSE	FALSE
4169	10.1021/acs.orglett.5b00146	doi.org/10.1021/acs.orglett.5b00146	Pd-Catalyzed Enantioselective Hydroalkoxylation of Alkoxyallenes with Phenol for Construction of Acyclic O,O-Acetals		Org. Lett.	63	Cao, P	FALSE	FALSE	FALSE	FALSE
4170	10.1039/c5cc00905g	doi.org/10.1039/c5cc00905g	Introducing a new radical trifluoromethylation reagent		Chem. Commun.	63	Soloshonok, VA	FALSE	FALSE	FALSE	FALSE
4171	10.1002/cplu.201402169	doi.org/10.1002/cplu.201402169	Poly(vinylpyridine)-Grafted Silica Containing Palladium or Nickel Nanoparticles as Heterogeneous Catalysts for the Sonogashira Coupling Reaction		ChemPlusChem	63	Farjadian, F	FALSE	FALSE	FALSE	FALSE
4172	10.1039/c4dt01808g	doi.org/10.1039/c4dt01808g	Tetraphenylethylene-based phosphine: tuneable emission and carbon dioxide fixation		Dalton Trans.	63	Zhang, JY	FALSE	FALSE	FALSE	FALSE
4173	10.1021/jo500068p	doi.org/10.1021/jo500068p	Synthesis of Quaternary Carbon Stereocenters by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Arylboronates		J. Org. Chem.	63	Shintani, R	FALSE	FALSE	FALSE	FALSE
4174	10.1039/c3sc53047g	doi.org/10.1039/c3sc53047g	Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents		Chem. Sci.	63	Fananas-Mastral, M	FALSE	FALSE	FALSE	FALSE
4175	10.1021/ol401341s	doi.org/10.1021/ol401341s	Reversal of Polarity in Masked o-Benzoquinones: Rapid Access to Unsymmetrical Oxygenated Biaryls		Org. Lett.	63	Peddinti, RK	FALSE	FALSE	FALSE	FALSE
4176	10.1002/asia.201201062	doi.org/10.1002/asia.201201062	Copper-Catalyzed Synthesis of alpha-Hydroxy Phosphonates from H-Phosphonates and Alcohols or Ethers		Chem.-Asian J.	63	Tang, G	FALSE	FALSE	FALSE	FALSE
4177	10.1039/c3ra42955e	doi.org/10.1039/c3ra42955e	Transition metal-free domino sequential synthesis of (E)-stilbenes, biaryl methanes and biaryl ethers using Et2AlCl as a Lewis acid		RSC Adv.	63	Tadigoppul, N	FALSE	FALSE	FALSE	FALSE
4178	10.3390/molecules171012121	doi.org/10.3390/molecules171012121	Suzuki-Miyaura Reactions Catalyzed by C-2-Symmetric Pd-Multi-Dentate N-Heterocyclic Carbene Complexes		Molecules	63	Li, ZN	FALSE	FALSE	FALSE	FALSE
4179	10.1016/j.jorganchem.2011.09.008	doi.org/10.1016/j.jorganchem.2011.09.008	Trinuclear copper(I) complex of 1,3-bis(2-pyridinylmethyl)imidazolylidene as a carbene-transfer reagent for the preparation of catalytically active nickel(II) and palladium(II) complexes		J. Organomet. Chem.	63	Qiu, HY	FALSE	FALSE	FALSE	FALSE
4180	10.1039/c2ra21632a	doi.org/10.1039/c2ra21632a	Sustainable H2O/ethyl lactate system for ligand-free Suzuki-Miyaura reaction		RSC Adv.	63	Wan, JP	FALSE	FALSE	FALSE	FALSE
4181	10.1021/om2008309	doi.org/10.1021/om2008309	Chiral Imidazoline-Phosphine Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions		Organometallics	63	Shi, M	FALSE	FALSE	FALSE	FALSE
4182	10.1021/om200945q	doi.org/10.1021/om200945q	Pd/Josiphos-Catalyzed Enantioselective alpha-Arylation of Silyi Ketene Acetals and Mechanistic Studies on Transmetalation and Enantioselection		Organometallics	63	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
4183	10.1002/chem.201100909	doi.org/10.1002/chem.201100909	Nickel-Catalyzed Cross-Coupling of Aryl Bromides with Tertiary Grignard Reagents Utilizing Donor-Functionalized N-Heterocyclic Carbenes (NHCs)		Chem.-Eur. J.	63	Glorius, F	FALSE	FALSE	FALSE	FALSE
4184	10.1021/ol102784c	doi.org/10.1021/ol102784c	An Efficient Copper-Catalyzed Carbon-Sulfur Bond Formation Protocol in Water		Org. Lett.	63	Zhou, XG	FALSE	FALSE	FALSE	FALSE
4185	10.1002/anie.201101461	doi.org/10.1002/anie.201101461	Mutual Activation: Suzuki-Miyaura Coupling through Direct Cleavage of the sp(2) C-O Bond of Naphtholate		Angew. Chem.-Int. Edit.	63	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
4186	10.1021/ol100838m	doi.org/10.1021/ol100838m	Iron-Mediated Direct Suzuki-Miyaura Reaction: A New Method for the ortho-Arylation of Pyrrole and Pyridine		Org. Lett.	63	Hu, CW	FALSE	FALSE	FALSE	FALSE
4187	10.5012/bkcs.2010.31.03.582	doi.org/10.5012/bkcs.2010.31.03.582	Rhodium-Catalyzed Reductive Decyanation of Nitrites Using Hydrosilane as a Reducing Agent: Scope, Mechanism and Synthetic Application		Bull. Korean Chem. Soc.	63	Tobisu, M	FALSE	FALSE	FALSE	FALSE
4188	10.3184/030823410X12680525004303	doi.org/10.3184/030823410X12680525004303	An efficient palladium-catalysed amination of aryl chlorides in presence of 1,3-bis-(2,6-diisopropylphenyl)imidazolinium chloride		J. Chem. Res	63	Li, JH	FALSE	FALSE	FALSE	FALSE
4189	10.1021/ja907700e	doi.org/10.1021/ja907700e	N,N-Diethyl O-Carbamate: Directed Metalation Group and Orthogonal Suzuki-Miyaura Cross-Coupling Partner		J. Am. Chem. Soc.	63	Snieckus, V	FALSE	FALSE	FALSE	FALSE
4190	10.1021/om8010596	doi.org/10.1021/om8010596	Synthesis of Novel Chelating Benzimidazole-Based Carbenes and Their Nickel(II) Complexes: Activity in the Kumada Coupling Reaction		Organometallics	63	Bouwman, E	FALSE	FALSE	FALSE	FALSE
4191	10.1021/jo7027097	doi.org/10.1021/jo7027097	Direct vinylation and difluorovinylation of arylboronic acids using vinyl- and 2,2-difluorovinyl tosylates via the Suzuki-Miyaura cross coupling		J. Org. Chem.	63	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
4192	10.1002/anie.200701282	doi.org/10.1002/anie.200701282	Efficient CuO-nanoparticle-catalyzed C-S cross-coupling of thiols with iodobenzene		Angew. Chem.-Int. Edit.	63	Punniyamurthy, T	FALSE	FALSE	FALSE	FALSE
4193	10.1016/j.tetlet.2004.05.033	doi.org/10.1016/j.tetlet.2004.05.033	Mild and efficient palladium-catalyzed homocoupling of lithium alkynyltriisopropoxyborates: a new route to synthesis of 1,3-diynes		Tetrahedron Lett.	63	Oh, CH	FALSE	FALSE	FALSE	FALSE
4194	10.1021/om0302948	doi.org/10.1021/om0302948	A palladium-ferrocenyl tetraphosphine system as catalyst for Suzuki cross-coupling and Heck vinylation of aryl halides: Dynamic behavior of the palladium/phosphine species		Organometallics	63	Hierso, JC	FALSE	FALSE	FALSE	FALSE
4195	10.1021/jo020640f	doi.org/10.1021/jo020640f	Palladium-catalyzed cross-coupling reactions of 4-tosyl-2(5H)-furanone with boronic acids: A facile and efficient route to generate 4-substituted 2(5H)-furanones		J. Org. Chem.	63	Wu, J	FALSE	FALSE	FALSE	FALSE
4196	10.1021/ar010112a	doi.org/10.1021/ar010112a	Transition metal-catalyzed enantioselective ring-opening reactions of oxabicyclic alkenes		Accounts Chem. Res.	63	Lautens, M	FALSE	FALSE	FALSE	FALSE
4197	10.1021/ja011122+	doi.org/10.1021/ja011122+	An improved catalyst for the asymmetric arylation of ketone enolates		J. Am. Chem. Soc.	63	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
4198	10.1016/S0040-4020(99)00788-7	doi.org/10.1016/S0040-4020(99)00788-7	Nickel-catalysed couplings of aryl chlorides with secondary amines and piperazines		Tetrahedron	63	Fort, Y	FALSE	FALSE	FALSE	FALSE
4199	10.1002/asia.202101370	doi.org/10.1002/asia.202101370	Cs2CO3-Promoted C-O Coupling Protocol Enables Solventless (Hetero)aryl Ether Synthesis under Air Atmosphere		Chem.-Asian J.	63	Chen, C; Verpoort, F	FALSE	FALSE	FALSE	FALSE
4200	10.1021/acs.orglett.1c03739	doi.org/10.1021/acs.orglett.1c03739	Palladium-Catalyzed Asymmetric Cross-Coupling Reactions of Cyclobutanols and Unactivated Olefins		Org. Lett.	63	Zhang, JL; Chen, F	FALSE	FALSE	FALSE	FALSE
4201	10.1002/hlca.202100177	doi.org/10.1002/hlca.202100177	The Journey of Ni(I) Chemistry		Helv. Chim. Acta	63	Morandi, B	FALSE	FALSE	FALSE	FALSE
4202	10.1021/acscatal.1c03449	doi.org/10.1021/acscatal.1c03449	Nickel/Enamine Cooperative Catalysis Enables Highly Enantioselective Allylic Alkylation of alpha-Branched Aldehydes		ACS Catal.	63	Shen, HC	FALSE	FALSE	FALSE	FALSE
4203	10.1002/anie.202105631	doi.org/10.1002/anie.202105631	Photoredox-Catalyst-Enabled para-Selective Trifluoromethylation of tert-Butyl Arylcarbamates		Angew. Chem.-Int. Edit.	63	Shi, DQ; Zhao, YS	TRUE	FALSE	FALSE	FALSE
4204	10.1021/acs.orglett.1c01457	doi.org/10.1021/acs.orglett.1c01457	Synthesis of Plakortolides E and I Enabled by Base Metal Catalysis		Org. Lett.	63	Christmann, M	FALSE	FALSE	FALSE	FALSE
4205	10.1002/asia.201700877	doi.org/10.1002/asia.201700877	Robust Acenaphthoimidazolylidene Palladacycles: Highly Efficient Catalysts for the Amination of N-Heteroaryl Chlorides		Chem.-Asian J.	63	Tu, T	FALSE	FALSE	FALSE	FALSE
4206	10.1016/j.tetlet.2017.06.055	doi.org/10.1016/j.tetlet.2017.06.055	Sulfated tungstate catalyzed synthesis of C-3-symmetric 1,3,5-triaryl benzenes under solvent-free condition		Tetrahedron Lett.	63	Akamanchi, KG	FALSE	FALSE	FALSE	FALSE
4207	10.1039/c7cc04252c	doi.org/10.1039/c7cc04252c	Nickel-catalysed direct alkylation of thiophenes via double C(sp(3))-H/C(sp(2))-H bond cleavage: the importance of KH2PO4		Chem. Commun.	63	Qiu, RH; Yin, SF	FALSE	FALSE	FALSE	FALSE
4208	10.1039/c7qo00174f	doi.org/10.1039/c7qo00174f	Palladium-catalyzed coupling of azoles with 1-aryltriazenes via C-H/C-N cleavage		Org. Chem. Front.	63	Wang, ZX	FALSE	FALSE	FALSE	FALSE
4209	10.1021/acs.orglett.7b01336	doi.org/10.1021/acs.orglett.7b01336	Catalytic Asymmetric Construction of the Tryptanthrin Skeleton via an Enantioselective Decarboxylative [4+2] Cyclization		Org. Lett.	63	Mei, GJ; Shi, F	FALSE	FALSE	FALSE	FALSE
4210	10.1021/jacs.7b01705	doi.org/10.1021/jacs.7b01705	Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes		J. Am. Chem. Soc.	63	Reisman, SE	FALSE	FALSE	FALSE	FALSE
4211	10.1021/acs.joc.7b00081	doi.org/10.1021/acs.joc.7b00081	Copper-Catalyzed Regioselective C-H Sulfonyloxylation of Electron-Rich Arenes with p-Toluenesulfonic Acid and Sulfonyloxylation of Aryl(mesityl)iodonium Sulfonates		J. Org. Chem.	63	Xiang, SK	FALSE	TRUE	FALSE	FALSE
4212	10.1021/acs.joc.6b02693	doi.org/10.1021/acs.joc.6b02693	Rhodium(III)-Catalyzed ortho-Alkylation of Phenoxy Substrates with Diazo Compounds via C-H Activation: A Case of Decarboxylative Pyrimidine/Pyridine Migratory Cyclization Rather than Removal of Pyrimidine/Pyridine Directing Group		J. Org. Chem.	63	Swamy, KCK	FALSE	FALSE	FALSE	FALSE
4213	10.1016/j.jorganchem.2016.09.026	doi.org/10.1016/j.jorganchem.2016.09.026	Palladium complexes catalyzed regioselective arylation of 2-oxindole via in situ C(sp(2))-OH activation mediated by PyBroP		J. Organomet. Chem.	63	Dharmaraj, N	FALSE	FALSE	FALSE	FALSE
4214	10.1016/j.tet.2016.08.062	doi.org/10.1016/j.tet.2016.08.062	DMAP-promoted in situ activation of bromoacetic acid as a 2-carbon synthon for facile synthesis of pyridines and fused pyridin-2-ones		Tetrahedron	63	Lu, T; Du, D	FALSE	FALSE	FALSE	FALSE
4215	10.1021/acs.joc.6b01627	doi.org/10.1021/acs.joc.6b01627	Nickel/N-Heterocyclic Carbene-Catalyzed Suzuki-Miyaura Type Cross-Coupling of Aryl Carbamates		J. Org. Chem.	63	Tobisu, M; Chatani, N	FALSE	FALSE	FALSE	FALSE
4216	10.1021/acs.macromol.6b01006	doi.org/10.1021/acs.macromol.6b01006	Nickel-Catalyzed Suzuki Polycondensation for Controlled Synthesis of Ester-Functionalized Conjugated Polymers		Macromolecules	63	Noonan, KJT	FALSE	FALSE	FALSE	FALSE
4217	10.1021/acs.orglett.6b01134	doi.org/10.1021/acs.orglett.6b01134	Nickel-Catalyzed Reductive Cross-Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides: A One-Pot Synthesis of Diarylmethanes		Org. Lett.	63	Sun, HM	FALSE	FALSE	FALSE	FALSE
4218	10.1002/ejoc.201600385	doi.org/10.1002/ejoc.201600385	1,6-Addition Arylation of para-Quinone Methides: An Approach to Unsymmetrical Triarylmethanes		Eur. J. Org. Chem.	63	Yao, HQ; Lin, AJ	FALSE	FALSE	FALSE	FALSE
4219	10.1002/anie.201511975	doi.org/10.1002/anie.201511975	Reductive Cross-Coupling of Conjugated Arylalkenes and Aryl Bromides with Hydrosilanes by Cooperative Palladium/Copper Catalysis		Angew. Chem.-Int. Edit.	63	Semba, K; Nakao, Y	FALSE	FALSE	FALSE	FALSE
4220	10.1002/anie.201511663	doi.org/10.1002/anie.201511663	Enantioselective Rhodium-Catalyzed Dearomative Arylation or Alkenylation of Quinolinium Salts		Angew. Chem.-Int. Edit.	63	Wang, FJ	FALSE	FALSE	FALSE	FALSE
4221	10.1002/ejoc.201501607	doi.org/10.1002/ejoc.201501607	Palladium-Catalyzed Aminocarbonylation of Aryl Halides with 2,4,6-Trichloro-1,3,5-triazine/Formamide Mixed Reagent		Eur. J. Org. Chem.	63	Iranpoor, N; Panahi, F	FALSE	FALSE	FALSE	FALSE
4222	10.1055/s-0035-1560380	doi.org/10.1055/s-0035-1560380	Regioselective Allylation of Carbon Electrophiles with Alkenylsilanes under Dual Catalysis by Cationic Platinum(II) Species		Synthesis	63	Miura, K	FALSE	TRUE	FALSE	FALSE
4223	10.1002/anie.201509133	doi.org/10.1002/anie.201509133	Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments		Angew. Chem.-Int. Edit.	63	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
4224	10.1039/c6gc00163g	doi.org/10.1039/c6gc00163g	Palladium catalyzed direct benzylation/allylation of malonates with alcohols - in situ C-O bond activation		Green Chem.	63	Zhang, YG	FALSE	FALSE	FALSE	FALSE
4225	10.1039/c6ra14678c	doi.org/10.1039/c6ra14678c	Carbonylative coupling of aryl tosylates/triflates with arylboronic acids under CO atmosphere		RSC Adv.	63	Chang, S	FALSE	FALSE	FALSE	FALSE
4226	10.1021/acs.orglett.1c00296	doi.org/10.1021/acs.orglett.1c00296	Mizoroki-Heck Reaction of Unstrained Aryl Ketones via Ligand-Promoted C-C Bond Olefination	A new class of aryl-heteroarylphosphines, 3-arylbenzofuran-2-ylphosphines, was synthesized by [Cp*Rh(111)1-catalyzed redox-neutral cyclization of N-phenoxyacetamides with 1-alkynylphosphine sulfides and oxides followed by reduction. This step-economic reaction proceeds in excellent regioselectivity with a broad substrate scope. The application of the resulting air-stable trivalent-phosphine containing dicyclo-hexylphosphino moiety in palladium-catalyzed Suzuki Miyaura coupling and Buchwald Hartwig amination of aryl chlorides is also described.	Org. Lett.	62	Dai, HX	FALSE	FALSE	FALSE	FALSE
4227	10.1002/chem.202004477	doi.org/10.1002/chem.202004477	Multi-Step Continuous-Flow Organic Synthesis: Opportunities and Challenges	Pd-catalyzed arylation or benzylation of nitroazoles using aryl sulfonates or benzyl acetates is described. Electronically varied aryl tosylates and mesylates, as well as benzyl acetates, afford the arylated and benzylated products. Arylation of nitrobenzene is also reported. The relative rate for the arylation of halides is greater than that of tosylates using the reported reaction parameters. These studies enhance the scope of electrophiles for nitroarene arylations and benzylations, which was hitherto limited to the use of halide electrophiles.	Chem.-Eur. J.	62	Jiao, J	FALSE	FALSE	FALSE	FALSE
4228	10.1016/j.tetlet.2020.152605	doi.org/10.1016/j.tetlet.2020.152605	Nickel-catalyzed aminocarbonylation of Aryl/Alkenyl/Allyl (pseudo) halides with isocyanides and H2O	A highly efficient protocol of Ni(II) metal complex, [Ni(quin)(2)], catalyzing N-formylation and N-acylation of amines with moderate to excellent yields, using N,N-dimethylformamide and N,N-dimethylacetamide in the presence of imidazole, is described here. The protocol shows broad substrate scope for aliphatic, aromatic, and heterocyclic amines.	Tetrahedron Lett.	62	Liu, YK; Zhou, BW	FALSE	FALSE	FALSE	FALSE
4229	10.1002/jcc.26471	doi.org/10.1002/jcc.26471	Computational prediction on the catalytic activity of heterobimetallic complex featuring M-M triple bond in acetylene cyclotrimerization: Mechanistic study	A new and general nickel-catalyzed cyanation of hetero(aryl) Chlorides using less toxic Zn(CN)(2) as the cyanide source has been developed. The reaction relies on the use of inexpensive NiCl2.6H(2)O/dppf/Zn, as the catalytic system, and DMAP as the additive, allowing the cyanation to occur :under mild reaction conditions (50-80 degrees C) with wide functional group tolerance. DMAP was found to be crucial for successful transformation, and the reaction likely proceeds via a Ni(0)/Ni(II) catalysis based on mechanistic studies. The method was also successfully extended to aryl bromides and aryl iodides.	J. Comput. Chem.	62	Li, XY	FALSE	FALSE	FALSE	FALSE
4230	10.1002/chem.202002795	doi.org/10.1002/chem.202002795	Carbodicarbene: geminal-Bimetallic Coordination in Selective Manner	Synthetically versatile 3,3-disubstituted fluorooxindoles exhibiting vicinal chirality centers were obtained in high yields and with excellent enantio-, diastereo-, and regioselectivity through catalytic asymmetric fluoroenolate alkylation with allylic acetates. The reaction proceeds under mild conditions and can be scaled up without compromising the asymmetric induction. The unique synthetic usefulness of the products is highlighted by the incorporation of additional functionalities and the formation of 3-fluorinated oxindoles exhibiting an array of four adjacent centers of chirality. A new C-F bond functionalization path that provides unprecedented possibilities for the stereoselective generation of a chiral quaternary carbon center in the alkaloid scaffold is introduced.	Chem.-Eur. J.	62	Zhao, LL	FALSE	FALSE	FALSE	FALSE
4231	10.1055/s-0040-1707266	doi.org/10.1055/s-0040-1707266	Identification of a Surprising Boronic Acid Homocoupling Process in Suzuki-Miyaura Cross-Coupling Reactions Utilizing a Hindered Fluorinated Arene	Zwitterionic capsular polysaccharide extracts, similar to 8 kDa in mass, from Streptococcus pneumoniae type 1 (Spt1) have shown unique T-cell activating properties. Oligomers of the trisaccharide repeating unit of the Spt1 capsular polysaccharide [-> 3)-4-NH2-alpha-D-QuipNAc-(1 -> 4)-alpha-D-GalpA-(1 -> 3)-alpha-D-GalpA-(1-](n) of defined length are needed to further investigate this response. An approach towards iteratively extendable trisaccharide building blocks of the zwitterionic capsular polysaccharides of Spt1 is described. Key elements include the comparison of pre-glycosylation oxidation and post-glycosylation oxidation approaches using thioglycoside donors to the target trisaccharide, the optimisation of the post-glycosylation oxidation approach, and the conversion of the trisaccharide to building blocks tailored for iterative glycosylation. The construction and evaluation of stereotunable 2-N-3-O-oxazolidinone donors for the common bacterial 2-acetamido-4-amino-2,4,6-trideoxy-alpha-D-galactopyranoside motif is also described, as is a key intermediate for their efficient synthesis.	Synlett	62	Sieber, JD	FALSE	FALSE	FALSE	FALSE
4232	10.1039/d0ra05251e	doi.org/10.1039/d0ra05251e	Direct access to multi-functionalized benzenesvia[4+2] annulation of alpha-cyano-beta-methylenones and alpha,beta-unsaturated aldehydes	An efficient ligand-free copper-manganese (Cu-Mn) spinel oxide-catalyzed direct tandem C-H oxygenation and N-arylation of benzylamines has been developed. The method has been utilized for the synthesis of medicinally important 2-arylqui-nazolin-4(3H)-ones. Salient features of this method include recyclable catalyst, no ligand, excellent product yields, shorter reaction times and a broad substrate scope.	RSC Adv.	62	Lin, YH	FALSE	FALSE	FALSE	FALSE
4233	10.1021/acs.joc.0c01381	doi.org/10.1021/acs.joc.0c01381	Cu(I)-Catalyzed Three-Component Cyclization for the Construction of Functionalized Thiazoles	A novel method for the synthesis of anthranilate esters is described. The esterification reaction of nitro-substituted anthranilic acids was carried out under microwave irradiation. A range of solvents and other reaction parameters were investigated to provide the most environmentally friendly reaction conditions. The feasibility of scale-up was demonstrated, allowing a simple and inexpensive production of anthranilate esters.	J. Org. Chem.	62	He, QX; Cao, H	FALSE	FALSE	FALSE	FALSE
4234	10.1002/ejoc.202000270	doi.org/10.1002/ejoc.202000270	A Star-Shaped Triazine-Based Vitamin B(5)Copper(II) Nanocatalyst for Tandem Aerobic Synthesis of Bis(indolyl)methanes	Reductive cross-coupling has emerged, as a direct method for the construction of carbon carbon bonds. Most cobalt-, nickel-, and palladium-catalyzed reductive cross-coupling reactions to date are limited to stoichiometric Mn(0) or Zn(0) as the reductant. One nickel-catalyzed cross-coupling paradigm using Et3N as the terminal reductant is reported. By using this photoredox catalysis and nickel catalysis approach, a direct Csp(2)-Csp(3) reductive cross coupling of aryl bromides with alkyl bromides is achieved under mild conditions without stoichiometric metal reductants.	Eur. J. Org. Chem.	62	Jafarpour, M; Rezaeifard, A	FALSE	FALSE	FALSE	FALSE
4235	10.1021/jacs.0c02075	doi.org/10.1021/jacs.0c02075	Enantioselective Assembly of Cycloenones with a Nitrile-Containing All-Carbon Quaternary Center from Malononitriles Enabled by Ni Catalysis	A method for synthesizing substituted 2H-chromenes using TMSOTf-catalyzed polystyrene-supported succinimidyl selenide-induced intramolecular seleno-arylation of tethered alkenes as a key step has been developed. The catalytic process provides an efficient method for the stereoselective and regioselective synthesis of 3,4-dihydro-2H-chromenes possessing a seleno-functionality, followed by syn-elimination of selenoxides to provide 2H-chromenes in good yields and with high purities.	J. Am. Chem. Soc.	62	Liu, WB	FALSE	FALSE	FALSE	FALSE
4236	10.1002/ajoc.202000110	doi.org/10.1002/ajoc.202000110	Computational Insights into the Divergent Regioselectivities for Nickel-Catalyzed Dicarbofunctionalization of Allyl Moiety of N-Allyl-2-aminopyrimidine	A new reductive preparation of unsymmetrical sulfides from esters and thiols in the presence of InI3 and either 1,1,3,3-tetramethyldisiloxane (TMDS) or PhSiH3 as the reductant was developed. This protocol was applied to not only benzoic acid esters that have a methoxy, methyl, chloro, bromo, iodo, or trifluoromethyl group on the aromatic ring but also aliphatic acid esters with either aromatic or aliphatic thiols. A reaction mechanism is proposed by using Hammett plot results and several control experiments.	Asian J. Org. Chem.	62	Bao, XG; Wang, Y	FALSE	FALSE	FALSE	FALSE
4237	10.1021/acscatal.0c00246	doi.org/10.1021/acscatal.0c00246	Nickel-Catalyzed Direct Acylation of Aryl and Alkyl Bromides with Acylimidazoles	Owing to the synthetic importance of branched olefinated products, we report palladium catalyzed formation of branched olefins facilitated by a C-H activation based protocol. This involves selective insertion of olefins and subsequent decarboxylation using a completely unbiased benzene ring as the starting precursor. The significance of the protocol has been further highlighted by exhibition of functionality tolerance along with a late-stage modification of the branched olefinated products leading to the formation of other functionalized molecules.	ACS Catal.	62	Li, C	FALSE	FALSE	FALSE	FALSE
4238	10.1021/acs.orglett.0c00047	doi.org/10.1021/acs.orglett.0c00047	Origins of Unconventional gamma Site Selectivity in Palladium-Catalyzed C(sp(3))-H Activation and Arylation of Aliphatic Alcohols		Org. Lett.	62	Dang, YF	FALSE	FALSE	FALSE	FALSE
4239	10.1039/c9cc08448g	doi.org/10.1039/c9cc08448g	Cobalt-catalyzed alkylation of methyl-substituted N-heteroarenes with primary alcohols: direct access to functionalized N-heteroaromatics		Chem. Commun.	62	Kundu, S	FALSE	FALSE	FALSE	FALSE
4240	10.1016/j.ultsonch.2019.104746	doi.org/10.1016/j.ultsonch.2019.104746	Ultrasonic-assisted reduction for facile synthesis of ultrafine supported Pd nanocatalysts by hydroxyl groups on the surfaces of layered double hydroxides and their catalytic properties		Ultrason. Sonochem.	62	Bai, XF	FALSE	FALSE	FALSE	FALSE
4241	10.2174/1871530319666191202141209	doi.org/10.2174/1871530319666191202141209	Neurotransmitters and Behavrioral Alterations Induced by Nickel Exposure		Endocr. Metab. Immune Disord.-Drug Targets	62	Cauli, O	FALSE	FALSE	FALSE	FALSE
4242	10.1021/acs.organomet.9b00629	doi.org/10.1021/acs.organomet.9b00629	Scope and Mechanism of the Ruthenium-Catalyzed Dehydrative C-H Coupling of Phenols with alpha,beta-Unsaturated Carbonyl Compounds: Expedient Synthesis of Chromene and Benzoxacyclic Derivatives		Organometallics	62	Yi, CS	FALSE	FALSE	FALSE	FALSE
4243	10.1021/jacs.9b09245	doi.org/10.1021/jacs.9b09245	Nickel-Catalyzed Difunctionalization of Unactivated Alkenes Initiated by Unstabilized Enolates		J. Am. Chem. Soc.	62	Newhouse, TR	FALSE	FALSE	FALSE	FALSE
4244	10.1155/2019/2381208	doi.org/10.1155/2019/2381208	2-Oxiranyl-pyridines: Synthesis and Regioselective Epoxide Ring Openings with Chiral Amines as a Route to Chiral Ligands		Heteroatom Chem.	62	Skarzewski, J	FALSE	FALSE	FALSE	FALSE
4245	10.1021/acs.joc.9b01387	doi.org/10.1021/acs.joc.9b01387	Nickel-Catalyzed Defluorinative Reductive Cross-Coupling Reaction of gem-Difluoroalkenes with Thiosulfonate or Selenium Sulfonate		J. Org. Chem.	62	Wang, SY; Ji, SJ	FALSE	FALSE	FALSE	FALSE
4246	10.1021/acs.orglett.9b02621	doi.org/10.1021/acs.orglett.9b02621	Photochemically-Mediated, Nickel-Catalyzed Synthesis of N-(Hetero)aryl Sulfamate Esters		Org. Lett.	62	Roizen, JL	TRUE	FALSE	FALSE	FALSE
4247	10.1039/c9nj02191d	doi.org/10.1039/c9nj02191d	Nickel-catalyzed regioselective C-H acylation of chelating arenes: a new catalytic system for C-C bond formation via a radical process and its mechanistic explorations		New J. Chem.	62	Cai, C	FALSE	FALSE	FALSE	FALSE
4248	10.1021/acs.oprd.9b00199	doi.org/10.1021/acs.oprd.9b00199	Concise Synthesis of a Potential 5-Lipoxygenase Activating Protein (FLAP) Inhibitor and Its Analogs through Late-Stage Alkene Dicarbofunctionalization		Org. Process Res. Dev.	62	Giri, R	FALSE	FALSE	FALSE	FALSE
4249	10.1002/chem.201902147	doi.org/10.1002/chem.201902147	Streamlined Synthesis of Diaminopyridines by Pd-Catalyzed Ammonia Coupling with Deactivated Amino-Chloropyridines		Chem.-Eur. J.	62	Fantasia, S	FALSE	FALSE	FALSE	FALSE
4250	10.6023/cjoc201902011	doi.org/10.6023/cjoc201902011	One-Pot, Two-Step Reductive Amination of Boronate Ester Containing Aromatic Amines and Aldehydes Using B(2)pin(2) as Reductant		Chin. J. Org. Chem.	62	Zou, DP; Wu, YJ	FALSE	FALSE	FALSE	FALSE
4251	10.1039/c9ob00995g	doi.org/10.1039/c9ob00995g	Sterically controlled C-H/C-H homocoupling of arenes via C-H borylation		Org. Biomol. Chem.	62	Srinivasan, R	FALSE	FALSE	FALSE	FALSE
4252	10.1016/j.tetlet.2019.05.003	doi.org/10.1016/j.tetlet.2019.05.003	Chiral Bronsted acid-catalyzed Friedel-Crafts reaction of 3-indolylsulfamidates with indoles: Synthesis of enantioenriched bisindolylmethane sulfamates		Tetrahedron Lett.	62	Kim, SG	FALSE	FALSE	FALSE	FALSE
4253	10.1021/acs.joc.9b00708	doi.org/10.1021/acs.joc.9b00708	Direct C-H Multifluoroarylation of Ethers through Hydrogen Atom Transfer Using Photoredox Catalysis		J. Org. Chem.	62	Yang, C; Xia, WJ	TRUE	FALSE	FALSE	FALSE
4254	10.1021/acs.organomet.9b00083	doi.org/10.1021/acs.organomet.9b00083	Revisiting Claims of the Iron-, Cobalt-, Nickel-, and Copper-Catalyzed Suzuki Biaryl Cross-Coupling of Aryl Halides with Aryl Boronic Acids		Organometallics	62	Bedford, RB	FALSE	FALSE	FALSE	FALSE
4255	10.1039/c8sc04505d	doi.org/10.1039/c8sc04505d	Enantioselective and site-specific copper-catalyzed reductive allyl-allyl cross-coupling of allenes		Chem. Sci.	62	Xiong, T	FALSE	FALSE	FALSE	FALSE
4256	10.1021/jacs.8b13884	doi.org/10.1021/jacs.8b13884	Synthesis and Characterization of Oxygen-Embedded Quinoidal Pentacene and Nonacene		J. Am. Chem. Soc.	62	Zeng, ZB	FALSE	FALSE	FALSE	FALSE
4257	10.1021/acscatal.8b04481	doi.org/10.1021/acscatal.8b04481	Cobalt-Catalyzed Regio- and Enantioselective Markovnikov 1,2-Hydrosilylation of Conjugated Dienes		ACS Catal.	62	Huang, Z	FALSE	FALSE	FALSE	FALSE
4258	10.1002/anie.201813182	doi.org/10.1002/anie.201813182	P-III-Chelation-Assisted Indole C7-Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis		Angew. Chem.-Int. Edit.	62	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
4259	10.1002/anie.201808509	doi.org/10.1002/anie.201808509	Rhodium-Catalyzed Enantioselective Defluorinative alpha-Arylation of Secondary Amides		Angew. Chem.-Int. Edit.	62	Lautens, M	FALSE	FALSE	FALSE	FALSE
4260	10.6023/A18060224	doi.org/10.6023/A18060224	Synthesis of Non-Natural Amino Acid Derivatives Bearing Triphenylamine Core Skeleton via Pd-Catalyzed Direct Asymmetric Allylic Alkylation		Acta Chim. Sin.	62	Jiang, GX	FALSE	FALSE	FALSE	FALSE
4261	10.1039/c8nj03955k	doi.org/10.1039/c8nj03955k	Gold-catalyzed tandem reaction of 2-alkynylanilines followed by 1,6-conjugate addition to p-quinone methides: efficient access to unsymmetrical diarylindolylmethanes		New J. Chem.	62	Oh, CH	FALSE	FALSE	FALSE	FALSE
4262	10.1021/acs.orglett.8b02256	doi.org/10.1021/acs.orglett.8b02256	Nickel-Catalyzed Hydrogen-Borrowing Strategy for alpha-Alkylation of Ketones with Alcohols: A New Route to Branched gem-Bis(alkyl) Ketones		Org. Lett.	62	Banerjee, D	FALSE	FALSE	FALSE	FALSE
4263	10.1021/jacs.8b06069	doi.org/10.1021/jacs.8b06069	Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation		J. Am. Chem. Soc.	62	Dong, VM	FALSE	FALSE	FALSE	FALSE
4264	10.1021/acs.macromol.8b01333	doi.org/10.1021/acs.macromol.8b01333	Elucidating the Role of Diphosphine Ligand in Nickel-Mediated Suzuki-Miyaura Polycondensation		Macromolecules	62	Noonan, KJT	FALSE	FALSE	FALSE	FALSE
4265	10.1039/c8ob00488a	doi.org/10.1039/c8ob00488a	Palladium-catalyzed carbonylation of benzylic ammonium salts to amides and esters via C-N bond activation		Org. Biomol. Chem.	62	Wang, T	FALSE	FALSE	FALSE	FALSE
4266	10.1021/acs.joc.8b00515	doi.org/10.1021/acs.joc.8b00515	Improved Substrate Scope in the Potassium Hexacyanoferrate(II)-Based Cyanation for the Synthesis of Benzonitriles and Their Heterocyclic Analogues		J. Org. Chem.	62	Richardson, J	FALSE	FALSE	FALSE	FALSE
4267	10.1021/acsomega.8b00159	doi.org/10.1021/acsomega.8b00159	A Simple and Versatile Method for the Formation of Acetals/Ketals Using Trace Conventional Acids		ACS Omega	62	Xie, JW	FALSE	FALSE	FALSE	FALSE
4268	10.1016/j.jorganchem.2018.01.044	doi.org/10.1016/j.jorganchem.2018.01.044	2,6-Lutidine-linked bis-saturated NHC pincer ligands, silver complexes and transmetallation		J. Organomet. Chem.	62	Asay, M	FALSE	FALSE	FALSE	FALSE
4269	10.1039/c7qi00694b	doi.org/10.1039/c7qi00694b	Efficient procedure with new fused pyrimidinone derivatives, Schiff base ligand and its La and Gd complexes by green chemistry		Inorg. Chem. Front.	62	Taha, RH	FALSE	FALSE	FALSE	FALSE
4270	10.2174/1385272822666180704143509	doi.org/10.2174/1385272822666180704143509	Research Progress on Cross-coupling Reactions of Alkenylaluminum with Electrophilic Reagents		Curr. Org. Chem.	62	Li, QH	FALSE	TRUE	FALSE	FALSE
4271	10.1039/c7ob02159c	doi.org/10.1039/c7ob02159c	Iron(III)-catalyzed chelation assisted remote C-H bond oxygenation of 8-amidoquinolines		Org. Biomol. Chem.	62	Chandrasekharam, M	FALSE	FALSE	FALSE	FALSE
4272	10.1002/ejoc.201701197	doi.org/10.1002/ejoc.201701197	Synthesis of trans-Configured Enol Ethers by a Sequence of syn-Selective Glycolate Aldol Addition, Hydrolysis, and Grob Fragmentation		Eur. J. Org. Chem.	62	Bruckner, R	FALSE	FALSE	FALSE	FALSE
4273	10.1021/acs.joc.5b02448	doi.org/10.1021/acs.joc.5b02448	Amination-Oxidation Strategy for the Copper-Catalyzed Synthesis of Monoarylamines		J. Org. Chem.	62	Billingsley, KL	FALSE	FALSE	FALSE	FALSE
4274	10.1039/c6dt02185a	doi.org/10.1039/c6dt02185a	Ligand effects on the properties of Ni(III) complexes: aerobically-induced aromatic cyanation at room temperature		Dalton Trans.	62	Mirica, LM	FALSE	FALSE	FALSE	FALSE
4275	10.1021/acs.orglett.5b03142	doi.org/10.1021/acs.orglett.5b03142	Cobalt Catalyzed C-H and N-H Bond Annulation of Sulfonamide with Terminal and Internal Alkynes		Org. Lett.	62	Sundararaju, B	FALSE	FALSE	FALSE	FALSE
4276	10.1016/j.tetlet.2015.10.009	doi.org/10.1016/j.tetlet.2015.10.009	Ni-catalyzed Suzuki-Miyaura coupling reactions of pyrimidin-2-yl phosphates, tosylates and pivalates with arylboronic acids		Tetrahedron Lett.	62	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
4277	10.1055/s-0035-1560712	doi.org/10.1055/s-0035-1560712	Dimerization of Aryl Sulfonates by in situ Generated Nickel(0)		Synlett	62	Durandetti, M	FALSE	FALSE	FALSE	FALSE
4278	10.1055/s-0034-1380424	doi.org/10.1055/s-0034-1380424	Oxidative Homocoupling of Diheteroaryl- or Diarylmanganese Reagents Generated via Directed Manganation Using TMP2Mn		Synlett	62	Knochel, P	FALSE	FALSE	FALSE	FALSE
4279	10.1055/s-0034-1379899	doi.org/10.1055/s-0034-1379899	Palladium/N-Heterocyclic Carbene Catalyzed Mono- and Double-Cyanation of Aryl Halides Using Potassium Ferrocyanide Trihydrate under Aerobic Conditions		Synthesis	62	Cao, CS	FALSE	FALSE	FALSE	FALSE
4280	10.1016/j.tetlet.2015.03.106	doi.org/10.1016/j.tetlet.2015.03.106	Reductive homocoupling of benzylic halides in aqueous medium using recyclable alumina-supported nickel nanoparticles		Tetrahedron Lett.	62	Bhar, S	FALSE	FALSE	FALSE	FALSE
4281	10.1021/acs.orglett.5b00905	doi.org/10.1021/acs.orglett.5b00905	Palladium-Catalyzed C(sp(3)) C(sp(2)) Cross-Coupling of (Trimethylsilyl)methyllithium with (Hetero)Aryl Halides		Org. Lett.	62	Feringa, BL	FALSE	FALSE	FALSE	FALSE
4282	10.1021/acs.orglett.5b00844	doi.org/10.1021/acs.orglett.5b00844	Pd(II)-Catalyzed P(O)(RR2)-R-1-Directed Asymmetric C-H Activation and Dynamic Kinetic Resolution for the Synthesis of Chiral Biaryl Phosphates		Org. Lett.	62	Yang, SD	FALSE	FALSE	FALSE	FALSE
4283	10.1021/om5004682	doi.org/10.1021/om5004682	Stoichiometric Reactions of Acylnickel(II) Complexes with Electrophiles and the Catalytic Synthesis of Ketones		Organometallics	62	Weix, DJ	FALSE	TRUE	FALSE	FALSE
4284	10.1002/anie.201406077	doi.org/10.1002/anie.201406077	Iridium-Catalyzed Enantioselective Allyl-Allylsilane Cross-Coupling		Angew. Chem.-Int. Edit.	62	Carreira, EM	FALSE	FALSE	FALSE	FALSE
4285	10.1016/j.tet.2013.11.102	doi.org/10.1016/j.tet.2013.11.102	A route to the 9,10-secosteroid astrogorgiadiol featuring a key sp(2)-sp(3) Suzuki type cross-coupling		Tetrahedron	62	Medard, G	FALSE	FALSE	FALSE	FALSE
4286	10.1039/c4ra11520a	doi.org/10.1039/c4ra11520a	Nickel-catalyzed cross-coupling of carboxylic anhydrides with arylboronic acids		RSC Adv.	62	Yang, LM	FALSE	FALSE	FALSE	FALSE
4287	10.1039/c3ob41382a	doi.org/10.1039/c3ob41382a	Palladium-catalyzed Suzuki-Miyaura coupling of aryl sulfamates with arylboronic acids		Org. Biomol. Chem.	62	Shao, LX	FALSE	FALSE	FALSE	FALSE
4288	10.1055/s-0032-1316921	doi.org/10.1055/s-0032-1316921	Rhodium-Catalyzed Asymmetric Amination of Allylic Trichloroacetimidates		Synthesis	62	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
4289	10.1055/s-0032-1316898	doi.org/10.1055/s-0032-1316898	Synthesis of Phenanthridin-6(5H)-ones via Copper-Catalyzed Cyclization of 2-Phenylbenzamides		Synlett	62	Tan, Z	FALSE	FALSE	FALSE	FALSE
4290	10.1002/ejoc.201300197	doi.org/10.1002/ejoc.201300197	Stereoselective Organocatalytic Approach to alpha,beta-Disubstituted-beta-amino Acids: A Short Enantioselective Synthesis of Cispentacin		Eur. J. Org. Chem.	62	Moyano, A	FALSE	FALSE	FALSE	FALSE
4291	10.1021/am301394u	doi.org/10.1021/am301394u	Highly Ordered Mesoporous TiO2-Fe2O3 Mixed Oxide Synthesized by Sol-Gel Pathway: An Efficient and Reusable Heterogeneous Catalyst for Dehalogenation Reaction		ACS Appl. Mater. Interfaces	62	Bhaumik, A	FALSE	FALSE	FALSE	FALSE
4292	10.1002/chem.201202251	doi.org/10.1002/chem.201202251	Asymmetric Allylic Alkylation of Acyclic Allylic Ethers with Organolithium Reagents		Chem.-Eur. J.	62	Harutyunyan, SR	FALSE	FALSE	FALSE	FALSE
4293	10.1002/chem.201201607	doi.org/10.1002/chem.201201607	Highly Stereoselective Synthesis of Tertiary Propargylic Centers and Their Isomerization to Enantiomerically Enriched Allenes		Chem.-Eur. J.	62	Ruano, JLG	FALSE	FALSE	FALSE	FALSE
4294	10.1002/adsc.201200369	doi.org/10.1002/adsc.201200369	Nickel-Catalyzed Cross-Coupling of Arene- or Heteroarenecarbonitriles with Aryl- or Heteroarylmanganese Reagents through C-CN Bond Activation		Adv. Synth. Catal.	62	Wang, ZX	FALSE	FALSE	FALSE	FALSE
4295	10.1021/ja300743t	doi.org/10.1021/ja300743t	Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents		J. Am. Chem. Soc.	62	Feringa, BL	FALSE	FALSE	FALSE	FALSE
4296	10.1021/ol200881v	doi.org/10.1021/ol200881v	Reductive Conjugate Addition of Haloalkanes to Enones To Form Silyl Enol Ethers		Org. Lett.	62	Weix, DJ	FALSE	FALSE	FALSE	FALSE
4297	10.1021/ol1020527	doi.org/10.1021/ol1020527	Ruthenium-Catalyzed Tertiary Amine Formation from Nitroarenes and Alcohols		Org. Lett.	62	Deng, GJ	FALSE	FALSE	FALSE	FALSE
4298	10.1021/jo1011202	doi.org/10.1021/jo1011202	Enantioselective Synthesis of Cyclic, Quaternary Oxonitriles		J. Org. Chem.	62	Altundas, R	FALSE	FALSE	FALSE	FALSE
4299	10.1515/znb-2009-11-1226	doi.org/10.1515/znb-2009-11-1226	Synthetic Access to a Novel Binaphthyl Ligand Bearing a Phosphine and a Triazole Donor Site		Z.Naturforsch.(B)	62	Thiel, WR	FALSE	FALSE	FALSE	FALSE
4300	10.1039/b819510b	doi.org/10.1039/b819510b	Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane		Org. Biomol. Chem.	62	Cheng, J	FALSE	FALSE	FALSE	FALSE
4301	10.1021/ol802239n	doi.org/10.1021/ol802239n	Synthesis of 4-Arylcoumarins via Cu-Catalyzed Hydroarylation with Arylboronic Acids		Org. Lett.	62	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
4302	10.1002/adsc.200800446	doi.org/10.1002/adsc.200800446	Enantioselective Platinum-Catalyzed Tandem Hydroarylation-Cycloisomerization of 1,6-Enynes		Adv. Synth. Catal.	62	Toullec, PY	FALSE	FALSE	FALSE	FALSE
4303	10.1016/j.tet.2008.02.068	doi.org/10.1016/j.tet.2008.02.068	Highly efficient copper(0)-catalyzed Suzuki-Miyaura cross-coupling reactions in reusable PEG-400		Tetrahedron	62	Mao, JC	FALSE	FALSE	FALSE	FALSE
4304	10.1002/anie.200703382	doi.org/10.1002/anie.200703382	A general method for meta and para functionalization of arenes using TMP2Mg center dot 2LiCl		Angew. Chem.-Int. Edit.	62	Knochel, P	FALSE	FALSE	FALSE	FALSE
4305	10.1002/anie.200453859	doi.org/10.1002/anie.200453859	Design and synthesis of endoperoxide antimalarial prodrug models		Angew. Chem.-Int. Edit.	62	O'Neill, PM	FALSE	FALSE	FALSE	FALSE
4306	10.1016/S0022-328X(02)01174-9	doi.org/10.1016/S0022-328X(02)01174-9	Scope and limitation of the nickel-catalyzed coupling reaction between lithium borates and mesylates		J. Organomet. Chem.	62	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
4307	10.1246/bcsj.68.713	doi.org/10.1246/bcsj.68.713	ASYMMETRIC HYDROSILYLATION OF 1-ALKENES CATALYZED BY PALLADIUM-MOP		Bull. Chem. Soc. Jpn.	62		FALSE	FALSE	FALSE	FALSE
4308	10.5059/yukigoseikyokaishi.52.800	doi.org/10.5059/yukigoseikyokaishi.52.800	RHODIUM-CATALYZED CARBON-CARBON BOND FORMATION		J. Synth. Org. Chem. Jpn.	62	MATSUDA, I	FALSE	FALSE	FALSE	FALSE
4309	10.1002/adsc.202200003	doi.org/10.1002/adsc.202200003	Nickel-Catalyzed Reductive Acylation of Carboxylic Acids with Alkyl Halides and N-Hydroxyphthalimide Esters Enabled by Electrochemical Process		Adv. Synth. Catal.	62	Yang, C; Xia, WJ	FALSE	TRUE	FALSE	FALSE
4310	10.1002/anie.202200352	doi.org/10.1002/anie.202200352	Mapping Dual-Base-Enabled Nickel-Catalyzed Aryl Amidations: Application in the Synthesis of 4-Quinolones		Angew. Chem.-Int. Edit.	62	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
4311	10.1055/s-0040-1719881	doi.org/10.1055/s-0040-1719881	Nickel-Catalyzed Reductive Cross-Coupling of Oxalates Derived from alpha-Hydroxy Carbonyls with Vinyl Bromides		Synthesis	62	Wu, F	FALSE	FALSE	FALSE	FALSE
4312	10.1021/jacs.1c09718	doi.org/10.1021/jacs.1c09718	A Comprehensive Discovery Platform for Organophosphorus Ligands for Catalysis		J. Am. Chem. Soc.	62	Aspuru-Guzik, A	FALSE	FALSE	FALSE	FALSE
4313	10.1021/acs.joc.1c02806	doi.org/10.1021/acs.joc.1c02806	DMF-Assisted Radical Cyclization of o-Isocyanodiaryl Ethers via 1,5-Aryl Migration: Construction of 2-Arylbenzoxazoles		J. Org. Chem.	62	Ding, QP	FALSE	FALSE	FALSE	FALSE
4314	10.1021/acs.jpca.1c07707	doi.org/10.1021/acs.jpca.1c07707	Theoretical Studies on Bimetallic Salen Complexes Catalyzed Epoxide Hydration: Effects of Metal Centers, Substrates, and Ligands		J. Phys. Chem. A	62	Chen, ZX	FALSE	FALSE	FALSE	FALSE
4315	10.1021/acs.orglett.1c03484	doi.org/10.1021/acs.orglett.1c03484	Construction of 2-Amino-2 '-ketonyl Biaryls via Acid-Mediated Ring Opening of 9H-Fluoren-9-ols with Organic Azides		Org. Lett.	62	Gu, ZH	FALSE	FALSE	FALSE	FALSE
4316	10.1021/acscatal.1c03729	doi.org/10.1021/acscatal.1c03729	Nickel-Catalyzed Regiodivergent Cyanation of Allylic Alcohols: Scope, Mechanism, and Application to the Synthesis of 1,n-Dinitriles		ACS Catal.	62	Fang, XJ	FALSE	FALSE	FALSE	FALSE
4317	10.1002/cssc.202101963	doi.org/10.1002/cssc.202101963	Cobalt-Catalyzed Highly Regioselective Three-Component Arylcarboxylation of Acrylate with Aryl Bromides and Carbon Dioxide		ChemSusChem	62	Xi, CJ	FALSE	FALSE	FALSE	FALSE
4318	10.1016/j.tet.2021.132431	doi.org/10.1016/j.tet.2021.132431	C(sp(2))-C(sp2) Suzuki cross-coupling of arylammonium salts catalyzed by a stable Pd-NHC complex		Tetrahedron	62	Shi, YH; Cao, CS	FALSE	FALSE	FALSE	FALSE
4319	10.1021/acs.orglett.1c02458	doi.org/10.1021/acs.orglett.1c02458	Deaminative Reductive Methylation of Alkylpyridinium Salts		Org. Lett.	62	Watson, MP	FALSE	FALSE	FALSE	FALSE
4320	10.1016/j.jorganchem.2021.122042	doi.org/10.1016/j.jorganchem.2021.122042	DFT studies on the mechanisms of enantioselective Ni-catalyzed reductive coupling reactions to form 1,1-diarylalkanes		J. Organomet. Chem.	62	Ren, QH	FALSE	FALSE	FALSE	FALSE
4321	10.1002/anie.202108587	doi.org/10.1002/anie.202108587	Chiral Arylated Amines via C-N Coupling of Chiral Amines with Aryl Bromides Promoted by Light		Angew. Chem.-Int. Edit.	62	Xue, D	FALSE	FALSE	FALSE	FALSE
4322	10.1021/acs.joc.1c01073	doi.org/10.1021/acs.joc.1c01073	A Process Chemistry Benchmark for sp(2)-sp(3) Cross Couplings		J. Org. Chem.	62	Beutner, GL; Simmons, EM	FALSE	FALSE	FALSE	FALSE
4323	10.1002/ejoc.202100420	doi.org/10.1002/ejoc.202100420	Metal-Free Synthesis of Alkenylazaarenes and 2-Aminoquinolines through Base-Mediated Aerobic Oxidative Dehydrogenation of Benzyl Alcohols		Eur. J. Org. Chem.	62	Batra, S	FALSE	FALSE	FALSE	FALSE
4324	10.1021/acs.inorgchem.1c00145	doi.org/10.1021/acs.inorgchem.1c00145	Sulfide Oxidation by 2,6-Bis[hydroxyl(methyl)amino]-4-morpholino-1,3,5-triazinatodioxomolybdenum(VI): Mechanistic Implications with DFT Calculations for a New Class of Molybdenum(VI) Complex		Inorg. Chem.	62	Kuo, LY	FALSE	FALSE	FALSE	FALSE
4325	10.1055/a-1507-6419	doi.org/10.1055/a-1507-6419	Chromium-Catalyzed Reductive Cleavage of Unactivated Aromatic and Benzylic C-O Bonds		Synthesis	62	Zeng, XM	FALSE	FALSE	FALSE	FALSE
4326	10.1021/acs.joc.1c00473	doi.org/10.1021/acs.joc.1c00473	Substrate-Controlled Regiodivergent Synthesis of Fluoroacylated Carbazoles via Friedel-Crafts Acylation		J. Org. Chem.	62	Chen, P; Jiang, YJ	FALSE	FALSE	FALSE	FALSE
4327	10.1021/acscatal.1c00536	doi.org/10.1021/acscatal.1c00536	Synergistic Effects of Boron and Oxygen Interaction Enabling Nickel-Catalyzed Exogenous Base-Free Stereoselective Arylvinylation of Alkynes through Vinyl Transposition		ACS Catal.	62	Cho, EJ	FALSE	FALSE	FALSE	FALSE
4328	10.1021/jacs.7b06723	doi.org/10.1021/jacs.7b06723	Radical Redox-Relay Catalysis: Formal [3+2] Cycloaddition of N-Acylaziridines and Alkenes		J. Am. Chem. Soc.	62	Lin, S	FALSE	FALSE	FALSE	FALSE
4329	10.1002/asia.201700891	doi.org/10.1002/asia.201700891	SO2F2-Mediated One-Pot Synthesis of Aryl Carboxylic Acids and Esters from Phenols through a Pd-Catalyzed Insertion of Carbon Monoxide		Chem.-Asian J.	62	Qin, HL	FALSE	FALSE	FALSE	FALSE
4330	10.1055/s-0036-1589045	doi.org/10.1055/s-0036-1589045	Base-Mediated Ring Opening of meso-Epoxides with 4-Aryl-N H-1,2,3-triazoles: Synthesis of trans-2-(Aryltriazolyl)cycloalkanols		Synthesis	62	Peddinti, RK	FALSE	FALSE	FALSE	FALSE
4331	10.1016/j.tet.2017.06.004	doi.org/10.1016/j.tet.2017.06.004	Nickel-catalyzed cross-coupling of aryl or 2-menaphthyl quaternary ammonium triflates with organoaluminum reagents		Tetrahedron	62	Wang, ZX	FALSE	FALSE	FALSE	FALSE
4332	10.1021/acs.joc.7b00657	doi.org/10.1021/acs.joc.7b00657	Diastereoselective and Catalytic alpha-Alkylation of Chiral N-Acyl Thiazolidinethiones with Stable Carbocationic Salts		J. Org. Chem.	62	Romea, P; Urpi, F	FALSE	FALSE	FALSE	FALSE
4333	10.1126/sciadv.1700832	doi.org/10.1126/sciadv.1700832	Templated deprotonative metalation of polyaryl systems: Facile access to simple, previously inaccessible multi-iodoarenes		Sci. Adv.	62	O'Hara, CT	FALSE	FALSE	FALSE	FALSE
4334	10.1021/acs.orglett.7b00473	doi.org/10.1021/acs.orglett.7b00473	Palladium-Catalyzed Electrochemical Allylic Alkylation between Alkyl and Allylic Halides in Aqueous Solution		Org. Lett.	62	Huang, JM	FALSE	TRUE	FALSE	FALSE
4335	10.1021/jacs.6b13299	doi.org/10.1021/jacs.6b13299	Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals		J. Am. Chem. Soc.	62	Liu, GS	FALSE	FALSE	FALSE	FALSE
4336	10.1002/adsc.201600946	doi.org/10.1002/adsc.201600946	Non-Covalent Carbonyl-Directed Heck-Matsuda Desymmetrizations: Synthesis of Cyclopentene-Fused Spirooxindoles, Spirolactones, and Spirolactams		Adv. Synth. Catal.	62	Correia, CRD	FALSE	FALSE	FALSE	FALSE
4337	10.1039/c7ra02549a	doi.org/10.1039/c7ra02549a	Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C-N bond cleavage		RSC Adv.	62	Zhao, JF	FALSE	FALSE	FALSE	FALSE
4338	10.1002/anie.201607646	doi.org/10.1002/anie.201607646	Nickel-Catalyzed Alkoxy-Alkyl Interconversion with Alkylborane Reagents through C-O Bond Activation of Aryl and Enol Ethers		Angew. Chem.-Int. Edit.	62	Rueping, M	FALSE	FALSE	FALSE	FALSE
4339	10.1021/acs.orglett.6b02981	doi.org/10.1021/acs.orglett.6b02981	Palladium-Catalyzed Stereoselective Formation of Substituted Allylic Thioethers and Sulfones		Org. Lett.	62	Guo, WS; Kleij, W	FALSE	FALSE	FALSE	FALSE
4340	10.1002/ajoc.201600411	doi.org/10.1002/ajoc.201600411	Nickel-Catalyzed C(Aryl)-O Bond Activation/Cross-Coupling Reaction of Carbazoles with Methyl Grignard: Synthesis of Ellipticine		Asian J. Org. Chem.	62	Das, P	FALSE	FALSE	FALSE	FALSE
4341	10.1021/acs.organomet.6b00484	doi.org/10.1021/acs.organomet.6b00484	Computational Study on the Mechanism of the Palladium-Catalyzed Arylation of alpha,beta-Unsaturated Aldehydes		Organometallics	62	Poblador-Bahamonde, AI	FALSE	FALSE	FALSE	FALSE
4342	10.1021/acs.orglett.6b01806	doi.org/10.1021/acs.orglett.6b01806	Cobalt(III)-Catalyzed C-C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C-H Activation		Org. Lett.	62	Li, XW	FALSE	FALSE	FALSE	FALSE
4343	10.1002/adsc.201600349	doi.org/10.1002/adsc.201600349	Cobalt-Catalyzed Twofold Direct C(sp(2))-C(sp(3)) Bond Coupling: Regioselective C-3 Alkylation of Coumarins with (Cyclo)alkyl Ethers		Adv. Synth. Catal.	62	Du, YF	FALSE	FALSE	FALSE	FALSE
4344	10.1002/adsc.201600336	doi.org/10.1002/adsc.201600336	Nickel-Catalyzed Borylation of Aryl and Benzyl 2-Pyridyl Ethers: A Method for Converting a Robust ortho-Directing Group		Adv. Synth. Catal.	62	Tobisu, M	FALSE	FALSE	FALSE	FALSE
4345	10.1055/s-0035-1561859	doi.org/10.1055/s-0035-1561859	Novel Methodology for the Efficient Synthesis of 3-Aryloxindoles: [1,2]-Phospha-Brook Rearrangement-Palladium-Catalyzed Cross-Coupling Sequence		Synlett	62	Terada, M	FALSE	FALSE	FALSE	FALSE
4346	10.1055/s-0035-1560960	doi.org/10.1055/s-0035-1560960	Memory of Chirality (MOC) in Intramolecular sp(3) C-H Amination		Synlett	62	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
4347	10.1039/c5nj01833a	doi.org/10.1039/c5nj01833a	Nickel-glycerol: an efficient, recyclable catalysis system for Suzuki cross coupling reactions using aryl diazonium salts		New J. Chem.	62	Nagarkar, JM	FALSE	FALSE	FALSE	FALSE
4348	10.1002/chem.202100075	doi.org/10.1002/chem.202100075	Merging Pd-0/Pd-II Redox and Pd-II/Pd-II Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes	A zirconium/nickel-mediated one-pot synthesis of ketones is reported. In the presence of Zn or Mn, Cp2ZrCl2 was found to dramatically accelerate the coupling and suppress side product formation via an I -> SPy displacement at the same time. Unlike Zn/Pd- and Fe/Cu-mediated one-pot ketone syntheses, the new method is effective for nucleophiles bearing OR or equivalent functional groups at the alpha-position. A mechanism comprising a nickel catalytic cycle, a zirconium catalytic cycle, and Zr -> Ni transmetalation is proposed, and Cp2ZrCl2 and/or low-valent Zr species are suggested to play crucial dual roles.	Chem.-Eur. J.	61	Semba, K; Nakao, Y	FALSE	TRUE	FALSE	FALSE
4349	10.1002/chem.202004413	doi.org/10.1002/chem.202004413	alpha- and gamma-Regiocontrol and Enantiospecificity in the Copper-Catalyzed Substitution Reaction of Propargylic Phosphates with Grignard Reagents	Methyl group is the smallest carbon substituent that plays important roles in many compounds. Conversion of a carboxylic acid into a ketone is a fundamental transformation in organic chemistry. This functional group change is usually performed indirectly by activating the carboxylic acid into an acyl chloride or into a Weinreb amide, and then by nucleophilic attack with an organometallic reagent. However, direct conversion of a carboxylic acid into a ketone can be achieved in one-step reaction using at least 2 equiv. of an organolithium reagent at low temperature and producing much tertiary alcohol. Herein, methylation of alkyl acid under Ni-catalyzed reductive coupling conditions using methyl p-methyl tosylate as the methylation reagent was reported to yield methylated ketones. Moderate yields as well as good functional group tolerance were observed under the present mild and easy-to-operate reaction conditions.	Chem.-Eur. J.	61	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
4350	10.1039/d0cc04986g	doi.org/10.1039/d0cc04986g	Photoredox/palladium co-catalyzed propargylic benzylation with internal propargylic carbonates	The (POBOP)NiCl pincer complex (POBOP = 1,7-OP(i-Pr)(2)-m-carboranyl) was synthesized by the selective B-H activation of the chelating carboranyl ligand and structurally and spectroscopically characterized. The reaction of (POBOP)NiCl and 1 equiv. of I-2 at room temperature led to the selective iodination of the vicinal B-H bond in the complex. The reaction of (POBOP)NiCl and 7 equiv. of I-2 at room temperature led to further iodination of the ligand and dissociation of the metal from the complex. (C) 2016 Elsevier B.V. All rights reserved.	Chem. Commun.	61	Chen, XM	TRUE	FALSE	FALSE	FALSE
4351	10.1002/ajoc.202000242	doi.org/10.1002/ajoc.202000242	Ligand-Free Iron-Catalyzed Homo-Coupling of Aryllithium Reagents	The organic synthesis reactions of diboron(4) compounds in which B-B cleavage is involved can introduce a new set of boron-containing organic reagents that were proven to be very useful in many organic synthetic routes and can be regarded as ideal candidates for green chemistry. So it is very valuable and significant to understand one of the thermodynamic properties of the B-B bond, the strength of the B-B bond, which can be measured by using the homolytic bond dissociation enthalpies (BDEs). To this end, the 34 B-B BDEs of diboron(4) compounds were calculated by theoretical methods including composite high-level ab initio and density functional theory (DFT) methods. The results show that it is reasonable and reliable to regard the 34 B-B BDE averages of the five high-level methods including G3, G3B3, CBS-Q, CBS-QB3 and ROCBS-QB3 as the standard reference values and the SOGGA11-X method provides the best accuracy with the smallest root mean square error (RMSE) of 4.4 kJ mol(-1). Subsequently, the B-B BDEs of three types of diboron(4) compounds according to their different molecular symmetry were investigated in detail by using this method. The results indicate that the different substituents have different effects on B-B BDE values. Natural bond orbital (NBO) analysis and investigations of the ground-state effect (GE) and the radical-state effect (RE) as well as frontier orbital energy analysis were performed in order to further disclose the essence of corresponding BDE change patterns. In addition, in order to better understand the catalytic process involving B-B cleavages by transitional-metal catalysts, the Pt-B and Cu-B BDE predictions after B-B cleavage were also conducted at this level. The results demonstrate that the participation of transition metals such as Pt and Cu can make the B-B cleavage much easier and the different substituents have different effects on the stability of transition metal boryl complexes.	Asian J. Org. Chem.	61	Peng, XS; Wong, HNC	FALSE	FALSE	FALSE	FALSE
4352	10.1021/acs.joc.0c01392	doi.org/10.1021/acs.joc.0c01392	Palladium-Catalyzed ortho-C-H Glycosylation/ipso-Alkenylation of Aryl Iodides	A set of nickel(II) Cp complexes with triazolylidenes containing various different wingtip groups (aryl, alkyl, pyridyl, CH2OH) have been synthesized by direct metalation of the corresponding triazolium salt with nickelocene. Distinct effects of the substituents on electronic and steric properties of the formed complexes are demonstrated by NMR spectroscopy and single crystal structural analysis, as well as by the catalytic activity of the complexes in the hydrosilylation of aldehydes. While all complexes display appreciable catalytic performance, the cyclometalated pyridyl-functionalized triazolylidene nickel complex 2e is highly active and reaches turnover frequencies of >20 000 h(-1) with good catalyst stability (full conversion at 0.05 mol % catalyst, maximum turnovers of similar to 6000). A variety of functional groups on the benzaldehyde are tolerated. Ketones are not converted, which identifies complex 2e as a highly selective precatalyst for the hydrosilylation of aldehydes in the presence of ketones.	J. Org. Chem.	61	Liang, YM	FALSE	FALSE	FALSE	FALSE
4353	10.1021/acs.orglett.0c02053	doi.org/10.1021/acs.orglett.0c02053	Visible-Light-Induced Pd-Catalyzed Radical Strategy for Constructing C-Vinyl Glycosides	General direct C2-alkenylation of oxazoles is reported using alkenyl tosylates at parts per million levels of palladium catalyst. From a series of ligands screened, PhMezole-Phos emerged as the promising ligand candidate to facilitate this reaction. Significantly, the method is scalable and exhibits excellent substrate tolerance. Highly sterically hindered substrates and small vinyl tosylate can be coupled successfully. Moreover, our method enables a rapid diversification of oxazole-based (CN)-N-boolean AND ligands which can be readily derived into new group 9 organometallic compounds.	Org. Lett.	61	Liang, YM	FALSE	FALSE	FALSE	FALSE
4354	10.1038/s41467-020-17939-2	doi.org/10.1038/s41467-020-17939-2	Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos-Ni(I) species	An anionic Ni complex was isolated and its structure determined by X-ray crystallography. With such an anionic complex as a key intermediate, a regio- and stereoselective multicomponent coupling reaction of perfluoroarenes, aryl Grignard reagents, and 1,3-butadiene in a 1:1:2 ratio was achieved, resulting in the formation of 1,6-octadiene derivatives containing two aryl groups, one from the perfluoroarene and the other from the aryl Grignard reagent, at the 3- and 8-positions, respectively.	Nat. Commun.	61	Li, YH	FALSE	FALSE	FALSE	FALSE
4355	10.1021/acscatal.0c02683	doi.org/10.1021/acscatal.0c02683	Direct Carbon-Carbon sigma Bond Amination of Unstrained Arylalkylketones	A combination of cobalt and nickel catalytic cycles enables a highly branch-selective (Markovnikov) olefin hydroarylation. Radical cyclization and ring scission experiments are consistent with hydrogen atom transfer (HAT) generation of a carbon-centered radical that leads to engagement of a nickel cycle.	ACS Catal.	61	Xie, HS; Zeng, W	FALSE	FALSE	FALSE	FALSE
4356	10.1021/acs.orglett.0c01612	doi.org/10.1021/acs.orglett.0c01612	Nickel-Catalyzed Asymmetric Addition of Aromatic Halides to Ketones: Highly Enantioselective Synthesis of Chiral 2,3-Dihydrobenzofurans Containing a Tertiary Alcohol	We have obtained a suite of two-dimensional layered isostructural coordination polymers [M(pypa)(2)(H2O)(2)](n) (M = Mn (1), Co (2), Ni (3), Cu (4), respectively), Hpypa = 1H-[3-(4-pyridy)pyrazole]-propionic acid), and used them in catalyzing the homocoupling of aromatic halides. 3 and 4 exhibit preeminent catalytic performance on the homocoupling of aryl bromide or aryl iodide without byproducts, while 2 only promoted the homocoupling of aryl iodide. But 1 showed no catalytic activities for all tested aromatic halides. Subsequently, density functional theory was performed for the balanced geometry frameworks, net charges of atoms, and energy of frontier molecule orbits. By using this method we determined that the catalytic performance was influenced by central metal ions. For further improving the catalytic performance, polyvinylpyrrolidone or polyethylene glycol 20000 (PEG 20000) was used as surfactants to synthesize the microscales of 3's (3a and 3b). 3a and 3b showed more preeminent catalytic activity than 3.	Org. Lett.	61	Huang, GZ	FALSE	FALSE	FALSE	FALSE
4357	10.1016/j.jorganchem.2020.121311	doi.org/10.1016/j.jorganchem.2020.121311	Nickel(II) allyl complexes with anionic N -heterocyclic carbene-borate ligands	Transition metal hydride complexes are usually amphoteric, not only acting as hydride donors, but also as Bronsted-Lowry acids. A simple additive ligand acidity constant equation (LAC for short) allows the estimation of the acid dissociation constant K-a(LAC) of diamagnetic transition metal hydride and dihydrogen complexes. It is remarkably successful in systematizing diverse reports of over 450 reactions of acids with metal complexes and bases with metal hydrides and dihydrogen complexes, including catalytic cycles where these reactions are proposed or observed. There are links between pK(a)(LAC) and pK(a)(THF), pK(a)(DCM), pK(a)(MecN) for neutral and cationic acids. For the groups from chromium to nickel, tables are provided that order the acidity of metal hydride and dihydrogen complexes from most acidic (pK(a)(LAc) -18) to least acidic (pK(a)(LAC) 50). Figures are constructed showing metal acids above the solvent pK(a) scales and organic acids below to summarize a large amount of information. Acid-base features are analyzed for catalysts from chromium to gold for ionic hydrogenations, bifunctional catalysts for hydrogen oxidation and evolution electrocatalysis, H/D exchange, olefin hydrogenation and isomerization, hydrogenation of ketones, aldehydes, imines, and carbon dioxide, hydrogenases and their model complexes, and palladium catalysts with hydride intermediates.	J. Organomet. Chem.	61	Tamm, M	FALSE	FALSE	FALSE	FALSE
4358	10.1002/chem.201905048	doi.org/10.1002/chem.201905048	A Practical Method for Continuous Production of sp3-Rich Compounds from (Hetero)Aryl Halides and Redox-Active Esters		Chem.-Eur. J.	61	Ley, SV	FALSE	FALSE	FALSE	FALSE
4359	10.7536/PC190809	doi.org/10.7536/PC190809	The Total Synthesis of ent-Kaurane Diterpenoids		Prog. Chem.	61	Ma, DW	FALSE	FALSE	FALSE	FALSE
4360	10.1021/acs.orglett.9b02910	doi.org/10.1021/acs.orglett.9b02910	Sequential ortho-C-H and ipso-C-O Functionalization Using a Bifunctional Directing Group		Org. Lett.	61	Xu, XH; Jin, Z	FALSE	FALSE	FALSE	FALSE
4361	10.1038/s41557-019-0319-5	doi.org/10.1038/s41557-019-0319-5	Towards the online computer-aided design of catalytic pockets		Nat. Chem.	61	Cavallo, L	FALSE	FALSE	FALSE	FALSE
4362	10.1021/acscatal.9b03715	doi.org/10.1021/acscatal.9b03715	Nickel-Catalyzed C-N Cross-Coupling of Ammonia, (Hetero)anilines, and Indoles with Activated (Hetero)aryl Chlorides Enabled by Ligand Design		ACS Catal.	61	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
4363	10.1038/s42004-019-0182-8	doi.org/10.1038/s42004-019-0182-8	Chemoenzymatic conversion of amides to enantioenriched alcohols in aqueous medium		Comm. Chem.	61	Garg, NK	FALSE	FALSE	FALSE	FALSE
4364	10.1021/jacs.9b02411	doi.org/10.1021/jacs.9b02411	Connecting Organometallic Ni(III) and Ni(IV): Reactions of Carbon-Centered Radicals with High-Valent Organonickel Complexes		J. Am. Chem. Soc.	61	Sanford, MS	FALSE	FALSE	FALSE	FALSE
4365	10.1055/s-0037-1610699	doi.org/10.1055/s-0037-1610699	Potassium Alkoxide/Disilane-Mediated Dehalogenative Deuteration		Synlett	61	Liu, WB	FALSE	FALSE	FALSE	FALSE
4366	10.1021/acs.accounts.8b00638	doi.org/10.1021/acs.accounts.8b00638	Salt-Free Reduction of Transition Metal Complexes by Bis(trimethylsilyl)cyclohexadiene, -dihydropyrazine, and-4,4 '-bipyridinylidene Derivatives		Accounts Chem. Res.	61	Tsurugi, H; Mashima, K	FALSE	FALSE	FALSE	FALSE
4367	10.1039/c9ob00144a	doi.org/10.1039/c9ob00144a	Programmed synthesis of triarylnitroimidazoles via sequential cross-coupling reactions		Org. Biomol. Chem.	61	Ahmed, QN	FALSE	FALSE	FALSE	FALSE
4368	10.1021/acs.joc.8b02766	doi.org/10.1021/acs.joc.8b02766	Synthesis of Aryl Trimethylstannane via BF3 center dot OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature		J. Org. Chem.	61	Zhang, SQ	FALSE	FALSE	FALSE	FALSE
4369	10.1039/c9ra00749k	doi.org/10.1039/c9ra00749k	Ni(ii)-catalyzed mono-selective ortho-arylation of unactivated aryl C-H bonds utilizing amino acids as a directing group		RSC Adv.	61	Liu, H	FALSE	FALSE	FALSE	FALSE
4370	10.1016/j.apsusc.2018.08.241	doi.org/10.1016/j.apsusc.2018.08.241	Gradient structure based dual-robust superhydrophobic surfaces with high-adhesive force		Appl. Surf. Sci.	61	Wang, Z	FALSE	FALSE	FALSE	FALSE
4371	10.1021/jacs.8b12025	doi.org/10.1021/jacs.8b12025	Metallaphotoredox-Catalyzed Cross-Electrophile C-sp(3)-C-sp(3) Coupling of Aliphatic Bromides		J. Am. Chem. Soc.	61	MacMillan, DWC	FALSE	TRUE	FALSE	FALSE
4372	10.1016/j.tet.2018.09.036	doi.org/10.1016/j.tet.2018.09.036	Cascade radical cyclization/cross-coupling of halobenzamides by synergistic Cu/Fe catalysis: An access to 7-tert-alkylated isoquinolinediones		Tetrahedron	61	Tang, S	FALSE	FALSE	FALSE	FALSE
4373	10.1021/acssuschemeng.8b02614	doi.org/10.1021/acssuschemeng.8b02614	1,3-Bis(carboxymethyl)imidazolium Chloride as a Metal-Free and Recyclable Catalyst for the Synthesis of N-Allylanilines by Allylic Substitution of Alcohols		ACS Sustain. Chem. Eng.	61	Pastor, IM	FALSE	FALSE	FALSE	FALSE
4374	10.1002/anie.201807393	doi.org/10.1002/anie.201807393	A Practical and General Amidation Method from Isocyanates Enabled by Flow Technology		Angew. Chem.-Int. Edit.	61	Kerr, WJ	FALSE	FALSE	FALSE	FALSE
4375	10.1021/acs.joc.8b01474	doi.org/10.1021/acs.joc.8b01474	C-N Bond Formation from Allylic Alcohols via Cooperative Nickel and Titanium Catalysis		J. Org. Chem.	61	Michaelis, DJ	FALSE	FALSE	FALSE	FALSE
4376	10.1039/c8qo00444g	doi.org/10.1039/c8qo00444g	Oxidation of active sp(3) C-H bonds initiated consecutive intermolecular/intramolecular cyclization between glycine derivatives and o-vinylphenols: construction of a polycyclic benzofuroquinoline skeleton		Org. Chem. Front.	61	Jia, XD	FALSE	FALSE	FALSE	FALSE
4377	10.1039/c8cc03954b	doi.org/10.1039/c8cc03954b	Palladium-catalyzed C(carbonyl)-C bond cleavage of amides: a facile access to phenylcarbamate derivatives with alcohols		Chem. Commun.	61	Zhou, XG	FALSE	FALSE	FALSE	FALSE
4378	10.1039/c8nj02413h	doi.org/10.1039/c8nj02413h	Pd/C-catalyzed reductive carbonylation of nitroaromatics for the synthesis of unsymmetrical ureas: one-step synthesis of neburon		New J. Chem.	61	Wu, XF	FALSE	FALSE	FALSE	FALSE
4379	10.1246/cl.180361	doi.org/10.1246/cl.180361	Catalytic Cleavage and Reformation of Ethereal sigma-Bonds		Chem. Lett.	61	Murai, M	FALSE	FALSE	FALSE	FALSE
4380	10.1021/jacs.8b04637	doi.org/10.1021/jacs.8b04637	Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling		J. Am. Chem. Soc.	61	Montgomery, J	FALSE	TRUE	FALSE	FALSE
4381	10.6023/cjoc201803001	doi.org/10.6023/cjoc201803001	Trityl Ion-Mediated Oxidative C-H Alkynylation of 1,2-Dihydroquinolines		Chin. J. Org. Chem.	61	Li, W	FALSE	FALSE	FALSE	FALSE
4382	10.6023/cjoc201711045	doi.org/10.6023/cjoc201711045	Catalytic Asymmetric Dehydrative Arylation of 3-Indolylmethanols with Tryptophols: Enantioselective Synthesis of Bisindolyl-Substituted Triarylmethanes		Chin. J. Org. Chem.	61	Mei, GJ	FALSE	FALSE	FALSE	FALSE
4383	10.1002/cjoc.201700808	doi.org/10.1002/cjoc.201700808	Silver-Catalyzed Three-Component Coupling of Carbon Dioxide, Amines and alpha-Diazoesters		Chin. J. Chem.	61	Qi, CR; Jiang, HF	FALSE	FALSE	FALSE	FALSE
4384	10.1039/c8cc00271a	doi.org/10.1039/c8cc00271a	Decarbonylative thioetherification by nickel catalysis using air- and moisture-stable nickel precatalysts		Chem. Commun.	61	Szostak, M	FALSE	FALSE	FALSE	FALSE
4385	10.1021/acs.orglett.7b03514	doi.org/10.1021/acs.orglett.7b03514	Palladium/Norbornene-Catalyzed ortho Aliphatic Acylation with Mixed Anhydride: Selectivity and Reactivity		Org. Lett.	61	Fu, Y; Gu, ZH	FALSE	FALSE	FALSE	FALSE
4386	10.1039/c7ob02895d	doi.org/10.1039/c7ob02895d	Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols		Org. Biomol. Chem.	61	Xu, SM	FALSE	FALSE	FALSE	FALSE
4387	10.1002/ejoc.201701463	doi.org/10.1002/ejoc.201701463	Stannylation of Aryl Halides, Stille Cross-Coupling, and One-Pot, Two-Step Stannylation/Stille Cross-Coupling Reactions under Solvent-Free Conditions		Eur. J. Org. Chem.	61	Nechaev, MS	FALSE	FALSE	FALSE	FALSE
4388	10.1055/s-0036-1590908	doi.org/10.1055/s-0036-1590908	Transition-Metal-Catalyzed Carboxylation of Organic Halides and Their Surrogates with Carbon Dioxide		Synthesis	61	Mei, TS	FALSE	FALSE	FALSE	FALSE
4389	10.1039/c7qo00716g	doi.org/10.1039/c7qo00716g	Cu-Catalyzed tertiary alkylation of alpha-(trifluoromethyl) styrenes with tertiary alkylmagnesium reagents		Org. Chem. Front.	61	Cao, S	FALSE	FALSE	FALSE	FALSE
4390	10.1055/s-0036-1589102	doi.org/10.1055/s-0036-1589102	Electrophilic Ring Opening of Small Heterocycles		Synthesis	61	Wang, C	FALSE	TRUE	FALSE	FALSE
4391	10.1039/c7qo00327g	doi.org/10.1039/c7qo00327g	Palladium-catalyzed direct ortho-alkynylation of arylalkylacid derivatives at gamma and delta positions via an N,O-bidentate directing group		Org. Chem. Front.	61	Shi, DQ; Zhao, YS	FALSE	FALSE	FALSE	FALSE
4392	10.1080/00397911.2015.1127384	doi.org/10.1080/00397911.2015.1127384	Highly efficient TfOH-catalyzed head-to-tail dimerization of vinylarenes		Synth. Commun.	61	Zhao, XH	FALSE	FALSE	FALSE	FALSE
4393	10.1021/acs.jmedchem.5b00612	doi.org/10.1021/acs.jmedchem.5b00612	Phenylalanine and Phenylglycine Analogues as Arginine Mimetics in Dengue Protease Inhibitors		J. Med. Chem.	61	Klein, CD	FALSE	FALSE	FALSE	FALSE
4394	10.1016/j.tet.2015.04.066	doi.org/10.1016/j.tet.2015.04.066	Rhodium-catalyzed benzylic fluorination of trichloroacetimidates		Tetrahedron	61	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
4395	10.1055/s-0034-1380813	doi.org/10.1055/s-0034-1380813	Synthesis of an Intermediate of Nafoxidine via Nickel-Catalyzed Ketone Arylation		Synthesis	61	Nolan, SP	FALSE	FALSE	FALSE	FALSE
4396	10.1021/acs.accounts.5b00051	doi.org/10.1021/acs.accounts.5b00051	Cross-Couplings Using Aryl Ethers via C-O Bond Activation Enabled by Nickel Catalysts		Accounts Chem. Res.	61	Tobisu, M	FALSE	FALSE	FALSE	FALSE
4397	10.1021/acs.accounts.5b00057	doi.org/10.1021/acs.accounts.5b00057	Methods and Mechanisms for Cross-Electrophile Coupling of Csp(2) Halides with Alkyl Electrophiles		Accounts Chem. Res.	61	Weix, DJ	FALSE	TRUE	FALSE	FALSE
4398	10.1039/c4cc08363f	doi.org/10.1039/c4cc08363f	Cu-catalyzed intramolecular aryl-etherification reactions of alkoxyl alkynes with diaryliodonium salts via cleavage of a stable C-O bond		Chem. Commun.	61	Chen, C	FALSE	FALSE	FALSE	FALSE
4399	10.1039/c5qo00224a	doi.org/10.1039/c5qo00224a	Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations		Org. Chem. Front.	61	Gu, J	FALSE	FALSE	FALSE	FALSE
4400	10.1039/c5qo00241a	doi.org/10.1039/c5qo00241a	Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: a new approach to diarylethanone		Org. Chem. Front.	61	Hu, FD	FALSE	FALSE	FALSE	FALSE
4401	10.1039/c5nj00655d	doi.org/10.1039/c5nj00655d	A novel nickel-catalyzed synthesis of thioesters, esters and amides from aryl iodides in the presence of chromium hexacarbonyl		New J. Chem.	61	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
4402	10.1039/c5cc05506g	doi.org/10.1039/c5cc05506g	Triply cyclometalated trinuclear iridium(III) and trinuclear palladium(II) complexes with a tri-mesoionic carbene ligand		Chem. Commun.	61	Sarkar, B	FALSE	FALSE	FALSE	FALSE
4403	10.1016/j.tet.2014.10.008	doi.org/10.1016/j.tet.2014.10.008	Organocatalytic desymmetrization of cyclic meso-anhydrides through enantioselective alcoholysis with functionalized primary nitroallylic alcohols		Tetrahedron	61	Chen, KM	FALSE	FALSE	FALSE	FALSE
4404	10.1021/ol502207z	doi.org/10.1021/ol502207z	Nickel-Catalyzed Reductive Cyclization of Alkyl Dihalides		Org. Lett.	61	Qian, Q	FALSE	FALSE	FALSE	FALSE
4405	10.1016/j.jorganchem.2013.12.047	doi.org/10.1016/j.jorganchem.2013.12.047	Theoretical investigation of the mechanisms of the biphenyl formation in Ni-catalyzed reductive cross-coupling system		J. Organomet. Chem.	61	Ren, QH	FALSE	FALSE	FALSE	FALSE
4406	10.1021/jo402799t	doi.org/10.1021/jo402799t	Melamine and Melamine-Formaldehyde Polymers as Ligands for Palladium and Application to Suzuki-Miyaura Cross-Coupling Reactions in Sustainable Solvents		J. Org. Chem.	61	Chalker, JM	FALSE	FALSE	FALSE	FALSE
4407	10.1039/c4ob00403e	doi.org/10.1039/c4ob00403e	Efficient C(sp(alkyl)(3))-SCF3 bond formations via copper-mediated trifluoromethylthiolation of alkyl halides		Org. Biomol. Chem.	61	Weng, ZQ	FALSE	FALSE	FALSE	FALSE
4408	10.1021/jo401850q	doi.org/10.1021/jo401850q	Cross-Coupling Reactions Involving Metal Carbene: From C=C/C-C Bond Formation to C-H Bond Functionalization		J. Org. Chem.	61	Wang, JB	FALSE	FALSE	FALSE	FALSE
4409	10.1002/chem.201300241	doi.org/10.1002/chem.201300241	Highly Efficient Catalytic Enantioselective Mannich Reaction of Malonates with N-tert-Butoxycarbonyl Imines by Using Yb(OTf)(3)/Pybox Catalysts at Room Temperature		Chem.-Eur. J.	61	Karimi, B	FALSE	FALSE	FALSE	FALSE
4410	10.1021/ic302590g	doi.org/10.1021/ic302590g	Direct Synthesis of Ligand-Based Radicals by the Addition of Bipyridine to Chromium(II) Compounds		Inorg. Chem.	61	Smith, KM	FALSE	FALSE	FALSE	FALSE
4411	10.1016/j.poly.2012.09.030	doi.org/10.1016/j.poly.2012.09.030	Synthesis, crystal structures, magnetic properties and Suzuki and Heck coupling catalytic activities of new coordination polymers containing tetracyanopalladate(II) anions		Polyhedron	61	Karadag, A	FALSE	FALSE	FALSE	FALSE
4412	10.1002/anie.201207958	doi.org/10.1002/anie.201207958	Aldimine-Directed Branched-Selective Hydroarylation of Styrenes		Angew. Chem.-Int. Edit.	61	Yoshikai, N	FALSE	FALSE	FALSE	FALSE
4413	10.1016/j.jorganchem.2012.10.013	doi.org/10.1016/j.jorganchem.2012.10.013	Nickel-catalyzed C-F bond activation and alkylation of polyfluoroaryl imines		J. Organomet. Chem.	61	Li, XY	FALSE	FALSE	FALSE	FALSE
4414	10.1016/j.tetasy.2012.09.012	doi.org/10.1016/j.tetasy.2012.09.012	Asymmetric oxidation of enol phosphates to alpha-hydroxy ketones using Sharpless reagents and a fructose derived dioxirane		Tetrahedron-Asymmetry	61	Krawczyk, E	FALSE	FALSE	FALSE	FALSE
4415	10.1002/aoc.2852	doi.org/10.1002/aoc.2852	A comparative Suzuki reaction of aryl halides using a new dimeric orthopalladated complex under conventional and microwave irradiation conditions		Appl. Organomet. Chem.	61	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
4416	10.1039/c2cc17283f	doi.org/10.1039/c2cc17283f	A highly active and magnetically retrievable nanoferrite-DOPA-copper catalyst for the coupling of thiophenols with aryl halides		Chem. Commun.	61	Varma, RS	FALSE	FALSE	FALSE	FALSE
4417	10.1039/c2dt31753b	doi.org/10.1039/c2dt31753b	Neutral Ni-II, Pd-II and Pt-II ONS-pincer complexes of 5-acetylbarbituric-4N-dimethylthiosemicarbazone: synthesis, characterization and properties		Dalton Trans.	61	Garcia-Santos, I	FALSE	FALSE	FALSE	FALSE
4418	10.1002/anie.201202466	doi.org/10.1002/anie.201202466	Cobalt-Catalyzed Direct Arylation and Benzylation by C-H/C-O Cleavage with Sulfamates, Carbamates, and Phosphates		Angew. Chem.-Int. Edit.	61	Ackermann, L	FALSE	FALSE	FALSE	FALSE
4419	10.1055/s-0030-1260169	doi.org/10.1055/s-0030-1260169	N-Heterocyclic Carbene/Pd(II)/1-Methylimidazole Complex Catalyzed Suzuki-Miyaura Coupling Reaction of Aryl Chlorides in Water		Synthesis	61	Shao, LX	FALSE	FALSE	FALSE	FALSE
4420	10.1055/s-0030-1259079	doi.org/10.1055/s-0030-1259079	Ligand-Free Copper-Catalyzed Synthesis of Diaryl Thioethers from Aryl Halides and Thioacetamide		Synlett	61	Tao, CZ	FALSE	FALSE	FALSE	FALSE
4421	10.1021/ja103973a	doi.org/10.1021/ja103973a	Iron-Catalyzed Suzuki-Miyaura Coupling of Alkyl Halides		J. Am. Chem. Soc.	61	Nakamura, M	FALSE	FALSE	FALSE	FALSE
4422	10.1055/s-0029-1218013	doi.org/10.1055/s-0029-1218013	Thieme Journal Awardees - Where Are They Now? On Cobalt-Catalyzed Biaryl Coupling Reactions		Synlett	61	Jacobi von Wangelin, A	FALSE	FALSE	FALSE	FALSE
4423	10.1016/j.jorganchem.2005.09.010	doi.org/10.1016/j.jorganchem.2005.09.010	Nickel(II) complexes with bifunctional phosphine-imidazolium ligands and their catalytic activity in the Kumada-Corriu coupling reaction		J. Organomet. Chem.	61	Labande, A	FALSE	FALSE	FALSE	FALSE
4424	10.1021/om0501879	doi.org/10.1021/om0501879	Simple synthesis of CpNi(NHC)Cl complexes (Cp = cyclopentadienyl; NHC=N-heterocyclic carbene)		Organometallics	61	Nolan, SP	FALSE	FALSE	FALSE	FALSE
4425	10.1021/jo026702j	doi.org/10.1021/jo026702j	Formal synthesis of (+/-)-guanacastepene A		J. Org. Chem.	61	Snider, BB	FALSE	FALSE	FALSE	FALSE
4426	10.1021/jo00392a020	doi.org/10.1021/jo00392a020	MECHANISM OF INTRAMOLECULAR PHOTOCYCLOADDITIONS OF CYCLOOCTENONES		J. Org. Chem.	61	PIRRUNG, MC	FALSE	FALSE	FALSE	FALSE
4427	10.1039/d1qo01927a	doi.org/10.1039/d1qo01927a	Construction of quaternary carbon centers by KOtBu-catalyzed alpha-homoallylic alkylation of lactams with 1,3-dienes		Org. Chem. Front.	61	Xing, D	FALSE	FALSE	FALSE	FALSE
4428	10.1016/j.matpr.2021.09.464	doi.org/10.1016/j.matpr.2021.09.464	Palladium complex of sulphated schiff base with ortho-vanillin as catalyst for O-arylation of phenol		Mater. Today-Proc.	61	Kumar, A	FALSE	FALSE	FALSE	FALSE
4429	10.1021/acs.joc.1c02132	doi.org/10.1021/acs.joc.1c02132	Manganese(I) Catalyzed Alkenylation of Phosphine Oxides Using Alcohols with Liberation of Hydrogen and Water		J. Org. Chem.	61	Gunanathan, C	FALSE	FALSE	FALSE	FALSE
4430	10.1021/acs.orglett.1c02738	doi.org/10.1021/acs.orglett.1c02738	Electrochemical Deoxygenative Thiolation of Preactivated Alcohols and Ketones		Org. Lett.	61	Wang, Y; Wang, Y	FALSE	TRUE	FALSE	FALSE
4431	10.1039/d1ob01503f	doi.org/10.1039/d1ob01503f	Palladium-catalyzed synthesis of alpha-aryl acetophenones from styryl ethers and aryl diazonium salts via regioselective Heck arylation at room temperature		Org. Biomol. Chem.	61	Kandasamy, J	FALSE	FALSE	FALSE	FALSE
4432	10.1007/s11244-021-01493-2	doi.org/10.1007/s11244-021-01493-2	Computational Study of Homogeneous Multimetallic Cooperative Catalysis		Top. Catal.	61	Maseras, F	FALSE	FALSE	FALSE	FALSE
4433	10.1073/pnas.2103513118	doi.org/10.1073/pnas.2103513118	Identification of simple arylfluorosulfates as potent agents against resistant bacteria		Proc. Natl. Acad. Sci. U. S. A.	61	Dong, JJ	FALSE	FALSE	FALSE	FALSE
4434	10.1039/d1qo00811k	doi.org/10.1039/d1qo00811k	Advances in regioselective functionalization of 9-phenanthrenols		Org. Chem. Front.	61	Wang, QF	FALSE	FALSE	FALSE	FALSE
4435	10.1021/acs.orglett.1c01213	doi.org/10.1021/acs.orglett.1c01213	Ni-Catalyzed Reductive Allylation of alpha-Chloroboronates to Access Homoallylic Boronates		Org. Lett.	61	Song, QL	FALSE	FALSE	FALSE	FALSE
4436	10.1039/d1sc01028j	doi.org/10.1039/d1sc01028j	Ceramic boron carbonitrides for unlocking organic halides with visible light		Chem. Sci.	61	Zheng, MF; Wang, XC	FALSE	FALSE	FALSE	FALSE
4437	10.1021/jacs.1c00142	doi.org/10.1021/jacs.1c00142	Regiocontrolled Reductive Vinylation of Aliphatic 1,3-Dienes with Vinyl Triflates by Nickel Catalysis		J. Am. Chem. Soc.	61	Shu, XZ	FALSE	FALSE	FALSE	FALSE
4438	10.1021/acscatal.0c04287	doi.org/10.1021/acscatal.0c04287	Phosphine-Borane Ligands Induce Chemoselective Activation and Catalytic Coupling of Acyl Chlorides at Palladium		ACS Catal.	61	Bourissou, D	FALSE	FALSE	FALSE	FALSE
4439	10.1002/anie.202017190	doi.org/10.1002/anie.202017190	Asymmetric Hydroacylation Involving Alkene Isomerization for the Construction of C-3-Chirogenic Center		Angew. Chem.-Int. Edit.	61	Zhang, ZF	FALSE	FALSE	FALSE	FALSE
4440	10.1021/acs.orglett.7b02287	doi.org/10.1021/acs.orglett.7b02287	Asymmetric Benzylic Functionalizations of 3-Vinyl Benzofurans via Cascade Formal Trienamine-Vinylogous Iminium Ion Activation		Org. Lett.	61	Chen, YC	FALSE	FALSE	FALSE	FALSE
4441	10.1002/cctc.201700218	doi.org/10.1002/cctc.201700218	Selective Reduction of Nitroarenes with Silanes Catalyzed by Nickel N- Heterocyclic Carbene Complexes		ChemCatChem	61	Royo, B	FALSE	FALSE	FALSE	FALSE
4442	10.1016/j.tet.2017.05.088	doi.org/10.1016/j.tet.2017.05.088	Metal-free, regio- and stereoselective S-methylation/phenylation of allyl halides using sulfoxides as sulfenylating agent		Tetrahedron	61	Badsara, SS	FALSE	FALSE	FALSE	FALSE
4443	10.1021/jacs.7b03781	doi.org/10.1021/jacs.7b03781	Copper-Catalyzed Arylation of Benzylic C-H bonds with Alkylarenes as the Limiting Reagents		J. Am. Chem. Soc.	61	Liu, GS	FALSE	FALSE	FALSE	FALSE
4444	10.1021/acs.orglett.7b00793	doi.org/10.1021/acs.orglett.7b00793	Nickel-Catalyzed Enantioselective Cross-Coupling of N-Hydroxyphthalimide Esters with Vinyl Bromides		Org. Lett.	61	Reisman, SE	FALSE	FALSE	FALSE	FALSE
4445	10.1039/c6qo00451b	doi.org/10.1039/c6qo00451b	Nickel-catalyzed direct formation of the C-S bonds of aryl sulfides from arylsulfonyl chlorides and aryl iodides using Mn as a reducing agent		Org. Chem. Front.	61	Huang, DG	FALSE	FALSE	FALSE	FALSE
4446	10.1002/anie.201606955	doi.org/10.1002/anie.201606955	Construction of Quaternary Stereocenters by Nickel-Catalyzed Heck Cyclization Reactions		Angew. Chem.-Int. Edit.	61	Desrosiers, JN	FALSE	FALSE	FALSE	FALSE
4447	10.1055/s-0035-1560439	doi.org/10.1055/s-0035-1560439	Nickel-Catalyzed Reductive Carboxylation of Cyclopropyl Motifs with Carbon Dioxide		Synthesis	61	Martin, R	FALSE	FALSE	FALSE	FALSE
4448	10.1016/j.jorganchem.2016.04.034	doi.org/10.1016/j.jorganchem.2016.04.034	Substrate-assisted rhodium-catalyzed C-H bond cyanation of 2-arylbenzothiazoles		J. Organomet. Chem.	61	Ding, QP; Peng, YY	FALSE	FALSE	FALSE	FALSE
4449	10.1002/cctc.201600234	doi.org/10.1002/cctc.201600234	Copper(I)-Phosphinite Complexes in Click Cycloadditions: Three-Component Reactions and Preparation of 5-Iodotriazoles		ChemCatChem	61	Diez-Gonzalez, S	FALSE	FALSE	FALSE	FALSE
4450	10.1002/chem.201601112	doi.org/10.1002/chem.201601112	Aniline-Promoted Cyclization-Replacement Cascade Reactions of 2-Hydroxycinnamaldehydes with Various Carbonic Nucleophiles through In Situ Formed N,O-Acetals		Chem.-Eur. J.	61	Wang, W	FALSE	FALSE	FALSE	FALSE
4451	10.1002/slct.201600532	doi.org/10.1002/slct.201600532	Functionalization of Quinolines through Copper-Catalyzed Regioselective Halogenation Reaction		ChemistrySelect	61	Baidya, M	FALSE	FALSE	FALSE	FALSE
4452	10.1021/jacs.6b01214	doi.org/10.1021/jacs.6b01214	Palladium/L-Proline-Catalyzed Enantioselective alpha-Arylative Desymmetrization of Cyclohexanones		J. Am. Chem. Soc.	61	Jia, YX	FALSE	FALSE	FALSE	FALSE
4453	10.1038/ncomms11073	doi.org/10.1038/ncomms11073	Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design		Nat. Commun.	61	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
4454	10.1039/c6ra23004k	doi.org/10.1039/c6ra23004k	Nickel stabilized by triazole-functionalized carbon nanotubes as a novel reusable and efficient heterogeneous nanocatalyst for the Suzuki-Miyaura coupling reaction		RSC Adv.	61	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
4455	10.1038/s41929-020-00560-3	doi.org/10.1038/s41929-020-00560-3	Deciphering the dichotomy exerted by Zn(ii) in the catalytic sp(2) C-O bond functionalization of aryl esters at the molecular level	An efficient method for the synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids has been developed. The desired products were obtained in good to excellent yields under mild reaction conditions. The reactions were shown to proceed very fast, in most cases, within 10 min.	Nat. Catal.	60	Martin, R	FALSE	FALSE	FALSE	FALSE
4456	10.1002/anie.202014660	doi.org/10.1002/anie.202014660	A Concise Total Synthesis of (-)-Berkelic Acid	Unactivated acyclic internal aliphatic olefins are often found to be unreactive in conventional alkenylation reactions. To address this problem, a cobalt catalyzed allylic selective dehydrogenative Heck reaction with internal aliphatic olefins has been developed. The method is highly regio- and stereoselective, the conditions are mild and a wide variety of functional groups can be tolerated. Remarkably, both internal and terminal aliphatic olefins can be employed, thereby significantly expanding the scope of alkenylation chemistry with aliphatic olefins.	Angew. Chem.-Int. Edit.	60	Zhou, QH	FALSE	FALSE	FALSE	FALSE
4457	10.1016/j.tet.2020.131785	doi.org/10.1016/j.tet.2020.131785	Oxidative Pictet-Spengler cyclisations through acceptorless iridium-catalysed dehydrogenation of tertiary amines	A new approach has been developed for the synthesis of 8-substituted 2H-chromenes, featuring a novel cascade aromatic Claisen rearrangement/o-quinone methide formation/6 pi-electrocyclization. This new method was demonstrated with 28 examples tolerating different substitutions at alkenes, allylic and aromatic ring and with total syntheses of three 2H-chromene natural products.	Tetrahedron	60	Marsden, SP	FALSE	FALSE	FALSE	FALSE
4458	10.1021/acscatal.0c04956	doi.org/10.1021/acscatal.0c04956	Synthesis of Carbocyclic Compounds via a Nickel-Catalyzed Carboiodination Reaction	In this experiment, students perform an air-free synthesis of three dichlorophosphinenickel(II) compounds, NiCl2(PPh3)(2), NiCl2(PCy3)(2), and NiCl2(DPPE), using NiCl2. 6H(2)O and the appropriate phosphine as the precursors. These colorful nickel compounds are air-sensitive in solution, but are stable toward air once isolated in the solid form. The synthesized nickel products will be utilized in a catalytic Suzuki cross-coupling reaction between phenylboronic acid and 1-bromo-4-(trifluoromethyl)benzene. The formation of the desired product, 4-(trifluoromethyl)biphenyl, is observed and determined quantitatively by F-19{H-1} NMR spectroscopy. The effect of the phosphine ligands on the formation of the nickel products and their catalytic activity will also be determined. KEYWORDS: Second-Year Undergraduate, Inorganic Chemistry, Hands-On Learning/Manipulatives, Laboratory Instruction,	ACS Catal.	60	Lautens, M	FALSE	FALSE	FALSE	FALSE
4459	10.1021/acs.joc.0c02033	doi.org/10.1021/acs.joc.0c02033	Tandem Olefin Isomerization/Cyclization Catalyzed by Complex Nickel Hydride and Bronsted Acid	The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl-and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated a-alkenyl bromides resulted in the a-products in good results.	J. Org. Chem.	60	Berkefeld, A; Fleischer, I	FALSE	FALSE	FALSE	FALSE
4460	10.1021/acs.joc.0c00793	doi.org/10.1021/acs.joc.0c00793	Highly Selective Room-Temperature Suzuki-Miyaura Coupling of Bromo-2-sulfonyloxypyridines for Unsymmetrical Diarylpyridines	C-H alkynylations of electron-rich anilines were accomplished by means of user-friendly nickel catalysis. The C-H functionalization occurred with high positional selectivity and ample scope by kinetically relevant C-H activation. The robust nickel catalyst tolerated synthetically useful functional groups, which set the stage for the facile synthesis of substituted indoles. The chemoselectivity of the cost-effective nickel catalyst was reflected by enabling transformative nickel-catalyzed C-H functionalization with purine nucleobases through monodentate chelation assistance.	J. Org. Chem.	60	Kim, WS	FALSE	FALSE	FALSE	FALSE
4461	10.1039/d0cc01210f	doi.org/10.1039/d0cc01210f	2,3-Dimethoxyindolines: a latent electrophile for SNAr reactions triggered by indium catalysts	Magnesium-promoted reductive silylation of 2- and 4-vinylpyridines with chiorotrialkylsilanes in N-methylpyrrolidinone at room temperature led to the selective formation of a variety of the corresponding beta-mono-silylated compounds at the terminal carbon atom in good to excellent yields, whereas silylation of 3-vinylpyridine under the same reduction conditions failed to give a complex mixture of silylated compounds. The difference of the results between 2- or 4-vinylpyridines and 3-vinylpyridine is attributed to that of the stabilizing effect to reaction intermediates by the resonance with the nitrogen atom of pyridine. (C) 2016 Elsevier Ltd. All rights reserved.	Chem. Commun.	60	Abe, T	FALSE	FALSE	FALSE	FALSE
4462	10.1016/j.cclet.2019.09.057	doi.org/10.1016/j.cclet.2019.09.057	Palladium-catalyzed meta-C-H bond iodination of arenes with I-2	A convenient and regioselective cross-coupling of heteroaryl boronic acids with allylic alcohols under catalyst-free reaction conditions is described. The developed procedure is simple, works under external oxidant- and metal-free conditions, and proves to be very general with an unprecedented ortho-selectivity. This approach represents one of the very few examples of ortho-functionalization of boronic acids. (C) 2016 Elsevier Ltd. All rights reserved.	Chin. Chem. Lett.	60	Xu, H; Dai, HX	FALSE	FALSE	FALSE	FALSE
4463	10.1021/jacs.0c00283	doi.org/10.1021/jacs.0c00283	Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)-O Bonds Enabled by Chromium Catalysis	Highly enantioselective cobalt-catalyzed hydrogenation of 1,1-diarylethenes was developed by using bench stable chiral oxazoline iminopyridine-cobalt complexes as precatalysts. A unique o-chloride effect was observed to achieve high enantioselectivity. Easy removal as well as further transformations of the chloro group make this protocol a potentially useful alternative to synthesize various chiral 1,1-diarylethanes. This process can be successfully performed under 1 atm of hydrogen at room temperature on gram scale.	J. Am. Chem. Soc.	60	Zeng, XM	FALSE	FALSE	FALSE	FALSE
4464	10.1021/acs.joc.9b03512	doi.org/10.1021/acs.joc.9b03512	Synthesis of Amide Enol Carbamates and Carbonates through Cu(OTf)(2)-Catalyzed Reactions of Ynamides with t-Butyl Carbamates/Carbonates	In this work, the mixture of formamide and 2,4,6-trichloro-1,3,5-triazine (cyanuric chloride or TCT) is introduced as a new amidating agent in Pd-catalyzed aminocarbonylation of aryl halides. In the presence of a catalytic amount of palladium and TCT/formamide reagent, a range of aryl halides (X = Cl, Br, I) were converted into amides efficiently in N, N-dimethylformamide at 120 degrees C.	J. Org. Chem.	60	Si, CM; Wei, BG	FALSE	FALSE	FALSE	FALSE
4465	10.1039/c9gc03351c	doi.org/10.1039/c9gc03351c	In water alkylation of amines with alcohols through a borrowing hydrogen process catalysed by ruthenium nanoparticles		Green Chem.	60	Taddei, M	FALSE	FALSE	FALSE	FALSE
4466	10.1002/adsc.201901142	doi.org/10.1002/adsc.201901142	Palladium-Catalyzed Decarboxylative Synthesis of 5H-Benzo[4,5][1,3]oxazino[2,3-a]isoindole-5,11(6aH)-Diones using 2-Phenyl-4H-Benzo[d][1,3]oxazin-4-Ones and alpha-Oxo Carboxylic Acids		Adv. Synth. Catal.	60	Singh, BK	FALSE	FALSE	FALSE	FALSE
4467	10.1039/c9nj05114g	doi.org/10.1039/c9nj05114g	An umpolung reaction of alpha-iminonitriles and its application to the synthesis of aminomalononitriles		New J. Chem.	60	Shimizu, M	FALSE	FALSE	FALSE	FALSE
4468	10.1007/s10562-019-02929-x	doi.org/10.1007/s10562-019-02929-x	A Highly Active, Recyclable and Cost-Effective Magnetic Nanoparticles Supported Copper Catalyst for N-arylation Reaction		Catal. Lett.	60	Asadi, Z	FALSE	FALSE	FALSE	FALSE
4469	10.1021/acs.orglett.9b02858	doi.org/10.1021/acs.orglett.9b02858	Transition-Metal-Catalyzed Transformation of Sulfonates via S-O Bond Cleavage: Synthesis of Alkyl Aryl Ether and Diaryl Ether		Org. Lett.	60	Lian, Z	FALSE	FALSE	FALSE	FALSE
4470	10.1002/cjoc.201800554	doi.org/10.1002/cjoc.201800554	Conversion of Carbonyl Compounds to Olefins via Enolate Intermediate		Chin. J. Chem.	60	Fang, HY; Shi, ZJ	FALSE	FALSE	FALSE	FALSE
4471	10.1055/s-0037-1611840	doi.org/10.1055/s-0037-1611840	SO (2) F (2) -Promoted Dehydration of Aldoximes: A Rapid and Simple Access to Nitriles		Synlett	60	Zhang, GF; Ding, CR	FALSE	FALSE	FALSE	FALSE
4472	10.1002/ajoc.201900254	doi.org/10.1002/ajoc.201900254	Copper-Catalyzed Homocoupling of Alkyl Halides in the Presence of Samarium		Asian J. Org. Chem.	60	Liu, YJ; Liu, SF	FALSE	FALSE	FALSE	FALSE
4473	10.1007/s10593-019-02475-9	doi.org/10.1007/s10593-019-02475-9	Expanding the chemical space of sp(3)-enriched 4,5-disubstituted oxazoles via synthesis of novel building blocks		Chem. Heterocycl. Compds.	60	Grygorenko, OO	FALSE	FALSE	FALSE	FALSE
4474	10.1021/jacs.9b03113	doi.org/10.1021/jacs.9b03113	Conversion of Aldehydes to Branched or Linear Ketones via Regiodivergent Rhodium-Catalyzed Vinyl Bromide Reductive Coupling-Redox Isomerization Mediated by Formate		J. Am. Chem. Soc.	60	Krische, MJ	FALSE	FALSE	FALSE	FALSE
4475	10.20964/2019.04.38	doi.org/10.20964/2019.04.38	Potentiometeric Study of New Schiff Base Complexes Bearing Morpholine in Ethanol-water Medium with some Metal Ions		Int. J. Electrochem. Sci.	60	Al-Farhan, BS	FALSE	FALSE	FALSE	FALSE
4476	10.1021/acscatal.9b00218	doi.org/10.1021/acscatal.9b00218	Sonogashira Cross-Coupling of Aryltrimethylammonium Salts		ACS Catal.	60	Shi, YH; Cao, CS	FALSE	FALSE	FALSE	FALSE
4477	10.1021/acs.orglett.9b00191	doi.org/10.1021/acs.orglett.9b00191	Intramolecular Reductive Cyclization of o-Nitroarenes via Biradical Recombination		Org. Lett.	60	Zheng, K	FALSE	FALSE	FALSE	FALSE
4478	10.1021/acs.joc.8b03137	doi.org/10.1021/acs.joc.8b03137	Iridium-Catalyzed Alkylation of Amine and Nitrobenzene with Alcohol to Tertiary Amine under Base- and Solvent-Free Conditions		J. Org. Chem.	60	Zheng, XL; Chen, H	FALSE	FALSE	FALSE	FALSE
4479	10.1002/anie.201812533	doi.org/10.1002/anie.201812533	Catalyst-Controlled 1,2-and 1,1-Arylboration of -Alkyl Alkenyl Arenes		Angew. Chem.-Int. Edit.	60	Brown, MK	FALSE	FALSE	FALSE	FALSE
4480	10.1021/acs.joc.8b02478	doi.org/10.1021/acs.joc.8b02478	Development of and Recent Advances in Pd-Catalyzed Decarboxylative Asymmetric Protonation		J. Org. Chem.	60	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
4481	10.1021/jacs.8b08826	doi.org/10.1021/jacs.8b08826	Copper-Mediated Amination of Aryl C-H Bonds with the Direct Use of Aqueous Ammonia via a Disproportionation Pathway		J. Am. Chem. Soc.	60	Baik, MH; Chang, S	FALSE	FALSE	FALSE	FALSE
4482	10.1002/anie.201805372	doi.org/10.1002/anie.201805372	Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis		Angew. Chem.-Int. Edit.	60	Gessner, VH	FALSE	FALSE	FALSE	FALSE
4483	10.1021/acs.orglett.8b02325	doi.org/10.1021/acs.orglett.8b02325	Nickel-Catalyzed Asymmetric Propargylic Amination of Propargylic Carbonates Bearing an Internal Alkyne Group		Org. Lett.	60	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
4484	10.1021/jacs.8b07436	doi.org/10.1021/jacs.8b07436	Enantioselective Trifluoromethylalkynylation of Alkenes via Copper-Catalyzed Radical Relay		J. Am. Chem. Soc.	60	Liu, GS	FALSE	FALSE	FALSE	FALSE
4485	10.1039/c8ob00949j	doi.org/10.1039/c8ob00949j	Copper-catalyzed oxidative cross-dehydrogenative coupling of 2H-chromenes and terminal alkynes		Org. Biomol. Chem.	60	Li, XY; Liu, L	FALSE	FALSE	FALSE	FALSE
4486	10.1002/cjoc.201800135	doi.org/10.1002/cjoc.201800135	Organocatalytic Enantioselective Synthesis of Chiral Diarylmethylamines from Racemic Alcohols		Chin. J. Chem.	60	Sun, JW	FALSE	FALSE	FALSE	FALSE
4487	10.1002/anie.201804318	doi.org/10.1002/anie.201804318	Palladium-Catalyzed Enantioselective Arylation of Racemic Ketones to Form Bridged Bicycles via Dynamic Kinetic Resolution		Angew. Chem.-Int. Edit.	60	Zhou, JS	FALSE	FALSE	FALSE	FALSE
4488	10.1039/c8sc00434j	doi.org/10.1039/c8sc00434j	Copper-catalyzed asymmetric hydrogenation of 2-substituted ketones via dynamic kinetic resolution		Chem. Sci.	60	Rodriguez, S; Zhang, YD	FALSE	FALSE	FALSE	FALSE
4489	10.1021/acs.orglett.8b00974	doi.org/10.1021/acs.orglett.8b00974	Nickel-Catalyzed Deoxycyanation of Activated Phenols via Cyanurate Intermediates with Zn(CN)(2): A Route to Aryl Nitriles		Org. Lett.	60	Heravi, MM; Panahi, F	FALSE	FALSE	FALSE	FALSE
4490	10.1002/aoc.4284	doi.org/10.1002/aoc.4284	Highly efficient AgNO3-catalyzed approach to 2-(benzo[d]azol-2-yl)phenols from salicylaldehydes with 2-aminothiophenol, 2-aminophenol and benzene-1,2-diamine		Appl. Organomet. Chem.	60	He, XW	FALSE	FALSE	FALSE	FALSE
4491	10.1016/j.jelechem.2018.02.043	doi.org/10.1016/j.jelechem.2018.02.043	Electrochemistry of a series of symmetric and asymmetric CpNiBr(NHC) complexes: Probing the electrochemical environment due to push-pull effects		J. Electroanal. Chem.	60	Landman, M	FALSE	TRUE	FALSE	FALSE
4492	10.1021/jacs.7b13710	doi.org/10.1021/jacs.7b13710	Diastereo- and Enantioselective Formal [3+2] Cycloaddition of Cyclopropyl Ketones and Alkenes via Ti-Catalyzed Radical Redox Relay		J. Am. Chem. Soc.	60	Lin, S	FALSE	FALSE	FALSE	FALSE
4493	10.1055/s-0036-1589143	doi.org/10.1055/s-0036-1589143	Cyrene as a Bio-Based Solvent for the Suzuki-Miyaura Cross-Coupling		Synlett	60	Watson, AJB	FALSE	FALSE	FALSE	FALSE
4494	10.1021/acs.macromol.7b02042	doi.org/10.1021/acs.macromol.7b02042	Making Various Degradable Polymers from Epoxides Using a Versatile Dinuclear Chromium Catalyst		Macromolecules	60	Liu, Y; Lu, XB	FALSE	FALSE	FALSE	FALSE
4495	10.1039/c7cy01205e	doi.org/10.1039/c7cy01205e	Less hindered ligands give improved catalysts for the nickel catalysed Grignard cross-coupling of aromatic ethers		Catal. Sci. Technol.	60	Clarke, ML	FALSE	FALSE	FALSE	FALSE
4496	10.1246/cl.170798	doi.org/10.1246/cl.170798	Copper-catalyzed Cyanation of Aryl Iodides Using Nitromethane		Chem. Lett.	60	Sakai, N	FALSE	FALSE	FALSE	FALSE
4497	10.1021/acs.orglett.7b03152	doi.org/10.1021/acs.orglett.7b03152	Synthesis of 4H-1,3-Benzoxazines via Metal- and Oxidizing Reagent Free Aromatic C-H Oxygenation		Org. Lett.	60	Xu, HC	FALSE	FALSE	FALSE	FALSE
4498	10.1021/acsomega.7b01159	doi.org/10.1021/acsomega.7b01159	Tuning Cross-Coupling Approaches to C3 Modification of 3-Deazapurines		ACS Omega	60	Tanasova, M	FALSE	FALSE	FALSE	FALSE
4499	10.6023/A15040284	doi.org/10.6023/A15040284	Visible-Light Photoredox Catalysis: Direct Arylation of Electron-Deficient Heterocycles and Arenes with Aryl Diazonium Salts		Acta Chim. Sin.	60	Wu, WL	TRUE	TRUE	FALSE	FALSE
4500	10.1016/j.tetlet.2015.10.014	doi.org/10.1016/j.tetlet.2015.10.014	A general and inexpensive protocol for the Cu-catalyzed C-S cross-coupling reaction between aryl halides and thiols		Tetrahedron Lett.	60	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
4501	10.1021/acs.orglett.5b02115	doi.org/10.1021/acs.orglett.5b02115	Weak Coordination Promoted Regioselective Oxidative Coupling Reaction for 2,2 '-Difunctional Biaryl Synthesis in Hexafluoro-2-propanol		Org. Lett.	60	Rao, Y	FALSE	FALSE	FALSE	FALSE
4502	10.1021/jacs.5b05086	doi.org/10.1021/jacs.5b05086	Catalytic Asymmetric Arylation of alpha-Aryl-alpha-diazoacetates with Aniline Derivatives		J. Am. Chem. Soc.	60	Zhu, SF	FALSE	FALSE	FALSE	FALSE
4503	10.1055/s-0034-1379927	doi.org/10.1055/s-0034-1379927	Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage		Synlett	60	Ackermann, L	FALSE	FALSE	FALSE	FALSE
4504	10.1016/j.tet.2015.02.067	doi.org/10.1016/j.tet.2015.02.067	Nickel-catalyzed reductive Heck type coupling of saturated alkyl halides with acrylates and oxabenzonorbornadiene		Tetrahedron	60	Shukla, P	FALSE	FALSE	FALSE	FALSE
4505	10.1016/j.jorganchem.2015.01.009	doi.org/10.1016/j.jorganchem.2015.01.009	Nickel-catalyzed one-pot synthesis of biaryls from phenols and arylboronic acids via C-O activation using TCT reagent		J. Organomet. Chem.	60	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
4506	10.1039/c5ob00431d	doi.org/10.1039/c5ob00431d	Rhodium-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimines towards the synthesis of alpha,alpha-diaryl-alpha-amino acid derivatives		Org. Biomol. Chem.	60	Nishimura, T	FALSE	FALSE	FALSE	FALSE
4507	10.1002/anie.201407944	doi.org/10.1002/anie.201407944	Chemical Dynamic Kinetic Resolution and S/R Interconversion of Unprotected alpha-Amino Acids		Angew. Chem.-Int. Edit.	60	Moriwaki, H	FALSE	FALSE	FALSE	FALSE
4508	10.1021/ja5066015	doi.org/10.1021/ja5066015	Iron-Catalyzed Directed Alkylation of Aromatic and Olefinic Carboxamides with Primary and Secondary Alkyl Tosylates, Mesylates, and Halides		J. Am. Chem. Soc.	60	Ilies, L	FALSE	FALSE	FALSE	FALSE
4509	10.1021/ja505823s	doi.org/10.1021/ja505823s	Highly Regioselective Nickel-Catalyzed Cross-Coupling of N-Tosylaziridines and Alkylzinc Reagents		J. Am. Chem. Soc.	60	Jamison, TF	FALSE	FALSE	FALSE	FALSE
4510	10.1021/ol500838h	doi.org/10.1021/ol500838h	Alkene-Assisted Nickel-Catalyzed Regioselective 1,4-Addition of Organoboronic Acid to Dienones: A Direct Route to All-Carbon Quaternary Centers		Org. Lett.	60	Cheng, CH	FALSE	FALSE	FALSE	FALSE
4511	10.1016/j.tet.2014.02.014	doi.org/10.1016/j.tet.2014.02.014	Commutative reduction of aromatic ketones to arylmethylenes/alcohols by hypophosphites catalyzed by Pd/C under biphasic conditions		Tetrahedron	60	Popowycz, F	FALSE	FALSE	FALSE	FALSE
4512	10.1039/c4gc01572j	doi.org/10.1039/c4gc01572j	Transition-metal free 2-arylbenzoxazole formation from aryl amides and cyclohexanones		Green Chem.	60	Deng, GJ	FALSE	FALSE	FALSE	FALSE
4513	10.3987/COM-13-S(S)60	doi.org/10.3987/COM-13-S(S)60	ENANTIOSELECTIVE SYNTHESIS OF SPIROOXINDOLES VIA DIRECT CATALYTIC ASYMMETRIC ALDOL-TYPE REACTION OF ISOTHIOCYANATO OXINDOLES		Heterocycles	60	Kato, S	FALSE	FALSE	FALSE	FALSE
4514	10.1021/ja4095236	doi.org/10.1021/ja4095236	Synthesis and Reactivity of Two-Coordinate Ni(I) Alkyl and Aryl Complexes		J. Am. Chem. Soc.	60	Hillhouse, GL	FALSE	FALSE	FALSE	FALSE
4515	10.1016/j.carres.2013.09.006	doi.org/10.1016/j.carres.2013.09.006	Stereoselective alpha-glycosylation of C(6)-hydroxyl myo-inositols via nickel catalysis-application to the synthesis of GPI anchor pseudo-oligosaccharides		Carbohydr. Res.	60	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
4516	10.1016/j.jorganchem.2013.06.033	doi.org/10.1016/j.jorganchem.2013.06.033	Synthesis and characterization of novel organonickel and organocobalt complexes via carbon-chlorine bond activation		J. Organomet. Chem.	60	Sun, HJ	FALSE	FALSE	FALSE	FALSE
4517	10.1016/j.tetlet.2013.06.061	doi.org/10.1016/j.tetlet.2013.06.061	A mild and catalyst-free aromatization using dihydroxylcyclohexanone derivatives as phenyl sources: a new approach to anilines		Tetrahedron Lett.	60	Luo, J	FALSE	FALSE	FALSE	FALSE
4518	10.1021/ja311783k	doi.org/10.1021/ja311783k	Retention or Inversion in Stereospecific Nickel-Catalyzed Cross-Coupling of Benzylic Carbamates with Arylboronic Esters: Control of Absolute Stereochemistry with an Achiral Catalyst		J. Am. Chem. Soc.	60	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
4519	10.1002/adsc.201200996	doi.org/10.1002/adsc.201200996	Aldehyde-Catalyzed Transition Metal-Free Dehydrative -Alkylation of Methyl Carbinols with Alcohols		Adv. Synth. Catal.	60	Xu, Q	FALSE	FALSE	FALSE	FALSE
4520	10.1002/anie.201301625	doi.org/10.1002/anie.201301625	Zinc-Catalyzed Synthesis of Functionalized Furans and Triarylmethanes from Enynones and Alcohols or Azoles: Dual X-H Bond Activation by Zinc		Angew. Chem.-Int. Edit.	60	Lopez, LA	FALSE	FALSE	FALSE	FALSE
4521	10.1002/anie.201302349	doi.org/10.1002/anie.201302349	Rhodium(I)-Catalyzed Enantioselective Hydrogenation of Substituted Acrylic Acids with Sterically Similar beta,beta-Diaryls		Angew. Chem.-Int. Edit.	60	Ding, KL	FALSE	FALSE	FALSE	FALSE
4522	10.1039/c3dt00086a	doi.org/10.1039/c3dt00086a	Ionic Ni(II) complexes containing a triphenylphosphine ligand and an imidazolium cation: synthesis, structures and catalysis for aryl Grignard cross-coupling of aryl halides		Dalton Trans.	60	Sun, HM	FALSE	FALSE	FALSE	FALSE
4523	10.1021/om300950c	doi.org/10.1021/om300950c	Ambient-Temperature Carbon-Oxygen Bond Cleavage of an alpha-Aryloxy Ketone with Cp2Ti(BTMSA) and Selective Protonolysis of the Resulting Ti-OR Bonds		Organometallics	60	Smith, KM	FALSE	FALSE	FALSE	FALSE
4524	10.1016/j.tet.2012.08.095	doi.org/10.1016/j.tet.2012.08.095	Rhodium catalyzed synthesis of isoindolinones via C-H activation of N-benzoylsulfonamides		Tetrahedron	60	Zhu, C	FALSE	FALSE	FALSE	FALSE
4525	10.1002/adsc.201200389	doi.org/10.1002/adsc.201200389	N-Heterocyclic Carbene Complexes of Nickel as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives		Adv. Synth. Catal.	60	Royo, B	FALSE	FALSE	FALSE	FALSE
4526	10.1016/j.tet.2012.05.091	doi.org/10.1016/j.tet.2012.05.091	Pd- and Cu-catalyzed C-H arylation of indazoles		Tetrahedron	60	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
4527	10.1021/om300369f	doi.org/10.1021/om300369f	C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride		Organometallics	60	Chen, YF	FALSE	FALSE	FALSE	FALSE
4528	10.1021/ol3002442	doi.org/10.1021/ol3002442	Palladium-Catalyzed One-Pot Diarylamine Formation from Nitroarenes and Cyclohexanones		Org. Lett.	60	Deng, GJ	FALSE	FALSE	FALSE	FALSE
4529	10.1039/c2cc34238c	doi.org/10.1039/c2cc34238c	Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes		Chem. Commun.	60	Su, WP	FALSE	FALSE	FALSE	FALSE
4530	10.1246/cl.2011.1001	doi.org/10.1246/cl.2011.1001	Cross-coupling of Aryl/Alkenyl Silyl Ethers with Grignard Reagents through Nickel-catalyzed C-O Bond Activation		Chem. Lett.	60	Xi, ZF	FALSE	FALSE	FALSE	FALSE
4531	10.5012/bkcs.2011.32.8.2584	doi.org/10.5012/bkcs.2011.32.8.2584	Suzuki-Miyaura Cross-coupling Reaction Catalyzed by Nickel Nanoparticles Supported on Poly(N-vinyl-2-pyrrolidone)/TiO2-ZrO2 Composite		Bull. Korean Chem. Soc.	60	Kalbasi, RJ	FALSE	FALSE	FALSE	FALSE
4532	10.1021/ol201620g	doi.org/10.1021/ol201620g	Regio- and Stereoselective Synthesis of Multisubstituted Olefins and Conjugate Dienes by Using alpha-Oxo Ketene Dithioacetals as the Building Blocks		Org. Lett.	60	Yu, ZK	FALSE	FALSE	FALSE	FALSE
4533	10.1055/s-0030-1260799	doi.org/10.1055/s-0030-1260799	NHC-NiH Reactions with Simple Olefins: Advances in Hydroalkenylation, Polymerization, and Ionic-Liquid Synthesis		Synlett	60	Ho, CY	FALSE	FALSE	FALSE	FALSE
4534	10.1021/ol200495a	doi.org/10.1021/ol200495a	(R)-3,5-diCF(3)-SYNPHOS and (R)-p-CF3-SYNPHOS, Electron-Poor Diphosphines for Efficient Room Temperature Rh-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids		Org. Lett.	60	Ratovelomanana-Vidal, V	FALSE	TRUE	FALSE	FALSE
4535	10.1039/c0ob00639d	doi.org/10.1039/c0ob00639d	Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols		Org. Biomol. Chem.	60	Ding, QP	FALSE	FALSE	FALSE	FALSE
4536	10.1002/anie.201104017	doi.org/10.1002/anie.201104017	Catalytic Asymmetric Alkynylation of C1-Substituted C,N-Cyclic Azomethine Imines by Cu-I/Chiral Bronsted Acid Co-Catalyst		Angew. Chem.-Int. Edit.	60	Maruoka, K	FALSE	FALSE	FALSE	FALSE
4537	10.1021/ja1033167	doi.org/10.1021/ja1033167	PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C-H Acyloxylation of Arenes		J. Am. Chem. Soc.	60	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
4538	10.1002/adsc.200900671	doi.org/10.1002/adsc.200900671	One-Pot Thioetherification of Aryl Halides Using Thiourea and Alkyl Bromides Catalyzed by Copper(I) Iodide Free from Foul-Smelling Thiols in Wet Polyethylene Glycol (PEG 200)		Adv. Synth. Catal.	60	Firouzabadi, H	FALSE	FALSE	FALSE	FALSE
4539	10.1055/s-0028-1087418	doi.org/10.1055/s-0028-1087418	Preparation and Catalytic Performance of Novel Dimeric Tetranuclear Zinc Complexes in Hydroamination of Alkenes at Room Temperature		Synlett	60	Roesky, PW	FALSE	FALSE	FALSE	FALSE
4540	10.1021/ja804804p	doi.org/10.1021/ja804804p	Pd-catalyzed direct arylation of tautomerizable heterocycles with aryl boronic acids via C-OH bond activation using phosphonium salts		J. Am. Chem. Soc.	60	Kang, FA	FALSE	FALSE	FALSE	FALSE
4541	10.1055/s-2008-1078446	doi.org/10.1055/s-2008-1078446	Rhodium-catalyzed allylic alkylations as key steps in the synthesis of cyclic alpha-alkylated amino acids		Synthesis	60	Stolz, D	FALSE	FALSE	FALSE	FALSE
4542	10.1002/chem.200802018	doi.org/10.1002/chem.200802018	Synthesis of Diarylamines Catalyzed by Iron Salts		Chem.-Eur. J.	60	Bolm, C	FALSE	FALSE	FALSE	FALSE
4543	10.1021/jo7019064	doi.org/10.1021/jo7019064	Palladium-catalyzed suzuki-miyaura cross-couplings of aryl tosylates with potassium aryltrifluoroborates		J. Org. Chem.	60	Wu, J	FALSE	FALSE	FALSE	FALSE
4544	10.1021/om700607m	doi.org/10.1021/om700607m	Unexpected solvent-induced Cis/Trans isomerization and catalytic application of a bis-bidentate Nickel(II) complex with n-heterocyclic carbene and amido functionalities		Organometallics	60	Lee, HM	FALSE	FALSE	FALSE	FALSE
4545	10.1021/ol071248x	doi.org/10.1021/ol071248x	The first n-heterocyclic carbene-based nickel catalyst for C-S coupling		Org. Lett.	60	Zhang, YG	FALSE	FALSE	FALSE	FALSE
4546	10.1016/j.tet.2006.11.060	doi.org/10.1016/j.tet.2006.11.060	Palladium on carbon-diethylamine-mediated hydrodeoxygenation of phenol derivatives under mild conditions		Tetrahedron	60	Sajiki, H	FALSE	FALSE	FALSE	FALSE
4547	10.1055/s-2006-926424	doi.org/10.1055/s-2006-926424	Nickel(0)/tetra-n-butylammonium bromide (TBAB) catalyzed Suzuki-Miyaura reaction		Synthesis	60	Wang, L	FALSE	FALSE	FALSE	FALSE
4548	10.1021/ol0529142	doi.org/10.1021/ol0529142	Cobalt(II)-Catalyzed cross-coupling between polyfunctional arylcopper reagents and aryl fluorides or tosylates		Org. Lett.	60	Korn, TJ	FALSE	FALSE	FALSE	FALSE
4549	10.1016/j.tet.2003.12.070	doi.org/10.1016/j.tet.2003.12.070	The 'lactone method': enantioselective preparation of novel P,N-biaryl ligands and their use in the synthesis of the biarylic alkaloids, ancistrotanzanine B and ancistroealaine A		Tetrahedron	60	Bringmann, G	FALSE	FALSE	FALSE	FALSE
4550	10.1021/om991013s	doi.org/10.1021/om991013s	Diastereoselective ortho-metalation of stereogenic ferrocenylphosphine oxides. Asymmetric synthesis of the first enantiopure phosphorus-chiral 2,2 '-bis(diarylphosphino)-1,1 '-biferrocenyls		Organometallics	60	Widhalm, M	FALSE	FALSE	FALSE	FALSE
4551	10.1021/jo990072c	doi.org/10.1021/jo990072c	Synthesis of unsymmetrical biaryls by palladium-catalyzed cross coupling reactions of arenes with tetrabutylammonium triphenyldifluorosilicate, a hypervalent silicon reagent		J. Org. Chem.	60	DeShong, P	FALSE	FALSE	FALSE	FALSE
4552	10.1248/yakushi1947.118.6_193	doi.org/10.1248/yakushi1947.118.6_193	MOP: Design, preparation, and use for palladium-catalyzed asymmetric reactions		Yakugaku Zasshi-J. Pharm. Soc. Jpn.	60	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
4553	10.1007/BF00817258	doi.org/10.1007/BF00817258	Synthesis of aminophosphines containing a chiral dinaphthoazepine entity and their use in asymmetric catalysis		Mon. Chem.	60		FALSE	FALSE	FALSE	FALSE
4554	10.1016/0022-328X(87)80052-9	doi.org/10.1016/0022-328X(87)80052-9	A NEW FURAN ANNELATION REACTION BY THE PALLADIUM-CATALYZED REACTION OF 2-ALKYNYL CARBONATES OR 2-(1-ALKYNYL)OXIRANES WITH BETA-KETO-ESTERS		J. Organomet. Chem.	60		FALSE	FALSE	FALSE	FALSE
4555	10.1021/jo00376a022	doi.org/10.1021/jo00376a022	CHIRAL (MACROCYCLIC) SULFIDE-CONTAINING AND SULFIDE/ALKYLAMINO-CONTAINING LIGANDS FOR NICKEL-CATALYZED GRIGNARD CROSS-COUPLING REACTIONS		J. Org. Chem.	60		FALSE	FALSE	FALSE	FALSE
4556	10.1016/j.tet.2022.132657	doi.org/10.1016/j.tet.2022.132657	Synthesis of aryl sulfonyl fluorides from aryl sulfonyl chlorides using sulfuryl fluoride (SO2F2) as fluoride provider		Tetrahedron	60	Qin, HL; Tang, HL	FALSE	FALSE	FALSE	FALSE
4557	10.1021/acs.inorgchem.1c03108	doi.org/10.1021/acs.inorgchem.1c03108	Attenuation of Ni(0) Decomposition: Mechanistic Insights into AgF-Assisted Nickel-Mediated Silylation		Inorg. Chem.	60	Rasappan, R	FALSE	FALSE	FALSE	FALSE
4558	10.1016/j.tetlet.2021.153572	doi.org/10.1016/j.tetlet.2021.153572	Palladium-catalyzed borylation of aryl bromides and chlorides using phosphatrioxa-adamantane ligands		Tetrahedron Lett.	60	Maumela, MC	FALSE	FALSE	FALSE	FALSE
4559	10.1055/a-1672-2260	doi.org/10.1055/a-1672-2260	Acid-Catalyzed Intramolecular Ring-Opening Reactions of Cyclopropanated Oxabenzonorbornadienes with Carboxylic Acid Nucleophiles		Synthesis	60	Tam, W	FALSE	FALSE	FALSE	FALSE
4560	10.1039/d1ra06330h	doi.org/10.1039/d1ra06330h	A simple and efficient copper-catalyzed three-component reaction to synthesize (Z)-1,2-dihydro-2-iminoquinolines		RSC Adv.	60	Luo, H; Yang, WG	FALSE	FALSE	FALSE	FALSE
4561	10.1021/acscatal.1c03265	doi.org/10.1021/acscatal.1c03265	A Pivotal Role of Chloride Ion on Nickel-Catalyzed Enantioselective Reductive Cross-Coupling to Perfluoroalkylated Boronate Esters		ACS Catal.	60	Xu, T	FALSE	FALSE	FALSE	FALSE
4562	10.1021/acs.orglett.1c02460	doi.org/10.1021/acs.orglett.1c02460	Palladium-Catalyzed Distal m-C-H Functionalization of Arylacetic Acid Derivatives		Org. Lett.	60	Satyanarayana, G	FALSE	FALSE	FALSE	FALSE
4563	10.1039/d1dt02551a	doi.org/10.1039/d1dt02551a	Computational determination of the mechanism of the Pd-catalyzed formation of isatoic anhydrides from o-haloanilines, CO, and CO2		Dalton Trans.	60	Lu, QQ; Liu, F	FALSE	FALSE	FALSE	FALSE
4564	10.1002/cjoc.202100101	doi.org/10.1002/cjoc.202100101	Asymmetric Synthesis of Chiral 1,3-Disubstituted Allylsilanes via Copper(I)-Catalyzed 1,4-Conjugate Silylation of alpha,beta-Unsaturated Sulfones and Subsequent Julia-Kocienski Olefination		Chin. J. Chem.	60	Yin, L	FALSE	FALSE	FALSE	FALSE
4565	10.1002/jccs.202100046	doi.org/10.1002/jccs.202100046	Copper porphyrin-catalyzed C(sp(2))-O bond construction via coupling phenols with formamides		J. Chin. Chem. Soc.	60	Liu, HY	FALSE	FALSE	FALSE	FALSE
4566	10.1021/acs.orglett.1c00551	doi.org/10.1021/acs.orglett.1c00551	1,2-trans-Stereoselective Synthesis of C-Glycosides of 2-Deoxy-2-amino-sugars Involving Glycosyl Radicals		Org. Lett.	60	Hu, XG	FALSE	FALSE	FALSE	FALSE
4567	10.1002/app.50711	doi.org/10.1002/app.50711	Dienes and diamondoids: poly(2-[1-adamantyl]-1,3-butadiene) and random copolymers with isoprene via redox-emulsion polymerization and their hydrogenation		J. Appl. Polym. Sci.	60	Roll, MF	FALSE	FALSE	FALSE	FALSE
4568	10.1055/s-0036-1588806	doi.org/10.1055/s-0036-1588806	Thieme Chemistry Journals Awardees - Where Are They Now? Efficient Cross-Coupling of Secondary Amines/Azoles and Activated (Hetero)Aryl Chlorides Using an Air-Stable DPEPhos/Nickel Pre-Catalyst		Synlett	60	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
4569	10.1016/j.mcat.2016.12.023	doi.org/10.1016/j.mcat.2016.12.023	CpNiBr(NHC) complexes as pre-catalysts in the chemoselective anaerobic oxidation of secondary aryl alcohols: Experimental and DFT studies		Mol. Catal.	60	Landman, M	FALSE	FALSE	FALSE	FALSE
4570	10.1039/c7sc00243b	doi.org/10.1039/c7sc00243b	A mild catalytic system for radical conjugate addition of nitrogen heterocycles		Chem. Sci.	60	Jui, NT	FALSE	FALSE	FALSE	FALSE
4571	10.1016/j.tet.2017.01.002	doi.org/10.1016/j.tet.2017.01.002	Transition-metal-free dehalogenation of aryl halides promoted by phenanthroline/potassium tert-butoxide		Tetrahedron	60	Liu, W	FALSE	FALSE	FALSE	FALSE
4572	10.1016/j.poly.2016.10.033	doi.org/10.1016/j.poly.2016.10.033	Syntheses, structural characterizations and terahertz spectra of Ag(I)/Cu(I) complexes with bis[2-(diphenylphosphino)phenyl]ether and N boolean AND N ligands		Polyhedron	60	Jin, QH	FALSE	FALSE	FALSE	FALSE
4573	10.1021/acscatal.6b02208	doi.org/10.1021/acscatal.6b02208	Copper-Catalyzed Asymmetric Borylative Ring Opening of Diazabicycles		ACS Catal.	60	Yun, J	FALSE	FALSE	FALSE	FALSE
4574	10.1016/j.tetlet.2016.06.092	doi.org/10.1016/j.tetlet.2016.06.092	An unprecedented oxidative intermolecular homo coupling reaction between two sp(3)C-sp(3)C centers under metal-free condition		Tetrahedron Lett.	60	Sahoo, SK	FALSE	FALSE	FALSE	FALSE
4575	10.1016/j.crci.2015.11.016	doi.org/10.1016/j.crci.2015.11.016	An efficient and economical synthesis of 5-substituted 1H-tetrazoles via Pb(II) salt catalyzed [3+2] cycloaddition of nitriles and sodium azide		C. R. Chim.	60	Agarwal, A	FALSE	FALSE	FALSE	FALSE
4576	10.1021/jacs.6b00250	doi.org/10.1021/jacs.6b00250	Practical Ni-Catalyzed Aryl-Alkyl Cross-Coupling of Secondary Redox-Active Esters		J. Am. Chem. Soc.	60	Baran, PS	FALSE	FALSE	FALSE	FALSE
4577	10.1021/acs.orglett.5b03591	doi.org/10.1021/acs.orglett.5b03591	Lewis Acid Induced Anomerization of Se-Glycosides. Application to Synthesis of alpha-Se-GalCer		Org. Lett.	60	Murphy, PV	FALSE	FALSE	FALSE	FALSE
4578	10.1039/c6ob01807f	doi.org/10.1039/c6ob01807f	(Biphenyl-2-alkyne) derivatives as common precursors for the synthesis of 9-iodo-10-organochalcogen-phenanthrenes and 9-organochalcogen-phenanthrenes		Org. Biomol. Chem.	60	Zeni, G	FALSE	FALSE	FALSE	FALSE
4579	10.1021/jacs.1c00529	doi.org/10.1021/jacs.1c00529	Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers	Herein, we described a nickel-catalyzed monofluoroalkenylation through defluorinative reductive cross-coupling of gem-difluoroalkenes with alkyl halides. Key to the success of this strategy is the combination of C- F cleavage with alkyl halides activation. This reaction enables the convenient synthesis of a large variety of functionalized monofluoroalkenes under mild reaction conditions with broad functional group compatibility and excellent Z-selectivity. The combination of Ni catalysis with (Bpin)(2)/K3PO4 as terminal reductant promoted the efficient C(sp(2))-C(sp(3)) formation especially the generation of all-carbon quatemary centers with high chemoselectivity.	J. Am. Chem. Soc.	59	Morandi, B	FALSE	FALSE	FALSE	FALSE
4580	10.1021/acs.orglett.0c04316	doi.org/10.1021/acs.orglett.0c04316	Nickel-Mediated Enantiospecific Silylation via Benzylic C-OMe Bond Cleavage	The field of Ni-catalysed cross-coupling has seen rapid recent growth because of the low cost of Ni, its earth abundance, and its ability to promote unique cross-coupling reactions. Whereas advances in the related field of Pd-catalysed cross-coupling have been driven by ligand design, the development of ligands specifically for Ni has received minimal attention. Here, we disclose a class of phosphines that enable the Ni-catalysed Csp(3) Suzuki coupling of acetals with boronic acids to generate benzylic ethers, a reaction that failed with known ligands for Ni and designer phosphines for Pd. Using parameters to quantify phosphine steric and electronic properties together with regression statistical analysis, we identify a model for ligand success. The study suggests that effective phosphines feature remote steric hindrance, a concept that could guide future ligand design tailored to Ni. Our analysis also reveals that two classic descriptors for ligand steric environment-cone angle and % buried volume-are not equivalent, despite their treatment in the literature.	Org. Lett.	59	Rasappan, R	FALSE	FALSE	FALSE	FALSE
4581	10.1039/d0cy01881c	doi.org/10.1039/d0cy01881c	Efficient photocatalytic chemoselective and stereoselective C-C bond formation over AuPd@N-rich carbon nitride	A useful strategy for the synthesis of enol phosphates from beta-keto esters via Atherton-Atodd reaction was developed. A variety of enol phosphates can be quickly and readily prepared with broad substrate scope and moderate yields under mild conditions. This method provides a low cost and practical way to synthesize enol phosphates from beta-keto esters.	Catal. Sci. Technol.	59	Jiang, HY; Bian, FX	FALSE	FALSE	FALSE	FALSE
4582	10.1007/s10562-020-03496-2	doi.org/10.1007/s10562-020-03496-2	Microwave-Assisted Nickel-Catalyzed Rapid Reductive Coupling of Ethyl 3-iodopropionate to Adipic Acid	N-Alkylation of amines is a class of important organic reaction. The products of this reaction are related to the important technological fields including chemical, medical, pharmaceutical and defense. In recent years, the development and need of green catalytic synthesis technology make such C-N bond formation reaction via N-alkylation become one of the current research focuses of organic chemistry. Because water is the only by-product, the N-alkylation of amines with alcohols as alkylating agents is green, environmental, simple and reliable. However, the most of such reactions require a late transition metal catalyst. In this paper the progress in late transition metal-catalyzed N-alkylation reaction with alcohols as alkylating agents starting from various aliphatic, aromatic and heterocyclic aromatic amines in recent years is reviewed. Various homogeneous and heterogeneous catalytic systems as well as the substrate application scope of each method involved in this reaction are mainly introduced. The expectation and development direction about this N-alkylation in future are suggested.	Catal. Lett.	59	Yang, WR	FALSE	FALSE	FALSE	FALSE
4583	10.1016/j.tet.2020.131861	doi.org/10.1016/j.tet.2020.131861	Cu(I)-N-heterocyclic carbene-catalyzed base free C-N bond formation of arylboronic acids with amines and azoles	A straightforward strategy for the syntheses of curcumene and ar-himachalene is reported. Synthetic highlights include a catalytic and asymmetric vinylogous Mukaiyama reaction and a stereospecific hydrogenolysis of a tertiary benzylic center using Pd/C or Ni/Raney catalysts. Notably, using Ni/Raney, the stereoselectivity outcome (inversion vs retention) of the hydrogenolysis depends on the tertiary benzylic alcohol substitution.	Tetrahedron	59	Shi, DB	FALSE	FALSE	FALSE	FALSE
4584	10.1002/adsc.202001262	doi.org/10.1002/adsc.202001262	Effective C5-Arylation of Peptide-Integrated Oxazoles: Almazole D		Adv. Synth. Catal.	59	Arndt, HD	FALSE	FALSE	FALSE	FALSE
4585	10.1039/d0gc03411h	doi.org/10.1039/d0gc03411h	Nitromethane as a surrogate cyanating agent: 7-N,N-dimethylamino-4-hydroxycoumarin-catalyzed, metal-free synthesis of alpha-iminonitriles	A new route to phosphines was developed by a Method that features a pre-join and transform process that proceeds via acylphosphine intermediates that May be :readily prepared from carboxylic acids and disubstituted phosphines. The efficient decarbonylations of these acylphosphines, using a nickel catalyst delivered the corresponding phosphines. This method shows that the carboxyl group can play a role similar to halides or triflates for introducing a substituted phosphorus atom on an aromatic ring.	Green Chem.	59	Yang, DY	FALSE	FALSE	FALSE	FALSE
4586	10.1002/anie.202008071	doi.org/10.1002/anie.202008071	Regio- and Diastereoselective Rhodium-Catalyzed Allylic Substitution with Unstabilized Benzyl Nucleophiles	The complexes [PY(Pz)(2)]Zn(OC(=O)Me)(2) (1) and [Py(Me(2)Pz)(2)]Zn(OC(=O)Me)(2) (2), where ligands Py(Pz)(2) and Py(Me(2)Pz)(2) are tridentate 2,6-bis(pyrazol-1-yl)pyridine and 2,6-bis(3,5-dimethylpyrato1-1-yl)pyridine, respectively, have been synthesized and characterized. The single crystal X-ray diffraCtion analysis confirmed compound 2 to be monomeric with six -Coordinate zinc center. In addition to tridentate ligand Py(Me(2)Pz)(2), both kappa(1) -acetate and kappa(2) -acetate ligands are ligated to zinc Metal atom in 2. The synthesized complexes 1 and 2 were used as effective catalysts for the cycloaddition between CO2 and epoxides in the presence of various kinds of cocatalysts such as n-Bu4PBr, n-Bu4NI, n-Bu4NBr, n-Bu4NCl, PPNCI, and DMAP under the condition of 75 degrees C, 10 bar CO2 pressure, 0.1 mol% catalyst loading, and 24 h. The reaction temperature, CO2 pressure, and catalyst loading ratio applied in this study are somewhat milder condition than those for other reported zinc -based catalysts. In addition, 1/n-Bu4PBr system showed the best catalytic activity for the cycloaddition of CO2 to propylene oxide, which showed the highest reactivity among seven other kinds of epoxides. (C) 2016 Elsevier Ltd. All rights reserved.	Angew. Chem.-Int. Edit.	59	Evans, PA	FALSE	FALSE	FALSE	FALSE
4587	10.1002/adsc.202000820	doi.org/10.1002/adsc.202000820	Emerging Nickel Catalysis in Heck Reactions: Recent Developments	We report the syntheses of combretastatins D-2 and D-4 as well as a formal synthesis of combretastatin D-1 by a conceptually new route harnessing a ring-contracting flash vacuum pyrolytic extrusion of sulfur dioxide from the respective 16-membered sulfone precursors. Via flash vacuum pyrolysis, even metaparacyclophanes as small and strained as the hitherto unknown oxa[1.5]metaparacyclophane could be prepared as a side product en route to combretastatin D-2 by synchronous extrusion of SO2 and CO2.	Adv. Synth. Catal.	59	Ghosh, T	FALSE	FALSE	FALSE	FALSE
4588	10.1002/ijch.202000069	doi.org/10.1002/ijch.202000069	Formate-Mediated Cross-Electrophile Reductive Coupling of Aryl Iodides and Bromopyridines	The discovery of a new series of potent hepatitis C virus (HCV) NS5A inhibitors containing biaryl sulfone or sulfate cores is reported. Structure-activity relationship (SAR) studies on inhibitors containing various substitution patterns of the sulfate or sulfone core structure established that m-,m'- substituted biaryl sulfate core-based inhibitors containing an amide moiety (compound 20) or an imidazole moiety (compound 24) showed extremely high potency. Compound 20 demonstrated double-digit pM potencies against both genotype 1b (GT-1b) and 2a (GT-2a). Compound 24 also exhibited double-digit pM potencies against GT-1b and sub nM potencies against GT-2a. Furthermore, compounds 20 and 24 exhibited no cardiotoxicity in an hERG ligand binding assay and showed acceptable plasma stability and no mutagenic potential in the Ames test. In addition, these compounds showed distinctive additive effects in combination treatment with the NS5B targeting drug sofosbuvir (Sovaldi (R)). The results of this study showed that the compounds 20 and 24 could be effective HCV inhibitors. (C) 2016 Elsevier Masson SAS. All rights reserved.	Isr. J. Chem.	59	Krische, MJ	FALSE	TRUE	FALSE	FALSE
4589	10.1039/d0cc04512h	doi.org/10.1039/d0cc04512h	Synthesis of diarylalkanes through an intramolecular/intermolecular addition sequence by auto-tandem catalysis with strong Bronsted base	A computational study of the C(methyl)-O bond activation of fluorinated aryl methyl ethers by a platinum(0) complex Pt(PCyp(3))(2) (Cyp = cyclopentyl) (N. A. Jasim, R. N. Perutz, B. Procacci and A. C. Whitwood, Chem. Commun., 2014, 50, 3914) demonstrates that the reaction proceeds via an S(N)2 mechanism. Nucleophilic attack of Pt(0) generates an ion pair consisting of a T-shaped platinum cation with an agostic interaction with a cyclopentyl group and a fluoroaryloxy anion. This ion-pair is converted to a 4-coordinate Pt(II) product trans-(PtMe(OArF)(PCyp(3))(2)]. Structure-reactivity correlations are fully consistent with this mechanism. The Gibbs energy of activation is calculated to be substantially higher for aryl methyl ethers without fluorine substituents and higher still for alkyl methyl ethers. These conclusions are in accord with the experimental results. Further support was obtained in an experimental study of the reaction of Pt(PCy3)(2) with 2,3,5,6-tetrafluoro-4-allyloxypyridine yielding the salt of the Pt(eta(3)-allyl) cation and the tetrafluoropyridinolate anion [Pt(PCy3)(2)(eta(3)-allyl)][OC5NF4]. The calculated activation energy for this reaction is significantly lower than that for fluorinated aryl methyl ethers.	Chem. Commun.	59	Kondoh, A	FALSE	FALSE	FALSE	FALSE
4590	10.1039/d0ob01163k	doi.org/10.1039/d0ob01163k	Direct electrochemical reductive amination between aldehydes and amines with a H/D-donor solvent	Arylation, vinylation, and alkynylation of electron-deficient arenes and heteroarenes have been achieved by chemoselective C-H zincation followed by copper catalyzed coupling reactions using iodonium salts. approach offers a direct and general access to a wide scope of (hetero)biaryls as well as alkenylated and alkynylated heteroarenes under mild conditions. It is particularly useful and valuable for the rapid and modular synthesis of diverse (hetero)aryl compounds, as demonstrated in the synthesis of transient receptor potential vanilloid 1 (TRPV1) antagonists and angiotensin II receptor type 1 (AT1 receptor) antagonists.	Org. Biomol. Chem.	59	Li, YB; Huang, YB	FALSE	FALSE	FALSE	FALSE
4591	10.1039/d0gc00383b	doi.org/10.1039/d0gc00383b	Light and oxygen-enabled sodium trifluoromethanesulfinate-mediated selective oxidation of C-H bonds	Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B-C bonds and other processes.	Green Chem.	59	Fu, H	FALSE	FALSE	FALSE	FALSE
4592	10.1021/jacs.0c04695	doi.org/10.1021/jacs.0c04695	Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers	A mild and efficient substrate-assisted C-H bond cyanation of 2-arylbenzothiazoles has been developed using CuCN as cyano-group source. The reaction exhibits broad functional groups tolerance giving the desired products in moderate to excellent yields. Regioselective cyanation was in favor of the less sterically hindered position to those meta-substituted substrate. (C) 2016 Elsevier B.V. All rights reserved.	J. Am. Chem. Soc.	59	Martin, R	FALSE	FALSE	FALSE	FALSE
4593	10.1039/d0gc01183e	doi.org/10.1039/d0gc01183e	Metal-free C-H methylation and acetylation of heteroarenes with PEG-400	In recent years, metal and their complexes-catalyzed organic reactions have received much attention in organic chemistry due to their rapidity and efficiency. Iron complexes have attracted much attention from chemical society due to the advantages of high catalytic activity and selectivity. The advances of iron complexes-catalyzed organic reactions are reviewed, such as polymerisation reactions, hydrosilylation/hydroboration, cycloaddition, redox reactions, cross-coupling reactions and 1,4-additions, and the prospects of its development are forecasted.	Green Chem.	59	Wang, JJ	FALSE	FALSE	FALSE	FALSE
4594	10.1021/jacs.0c00078	doi.org/10.1021/jacs.0c00078	Pd-Catalyzed Decarboxylative Olefination: Stereoselective Synthesis of Polysubstituted Butadienes and Macrocyclic P-glycoprotein Inhibitors	The use of sp(3) C-H bonds-which are ubiquitous in organic molecules-as latent nucleophile equivalents for transition metal-catalyzed cross-coupling reactions has the potential to substantially streamline synthetic efforts in organic chemistry while bypassing substrate activation steps. Through the combination of photoredox-mediated hydrogen atom transfer (HAT) and nickel catalysis, we have developed a highly selective and general C-H arylation protocol that activates a wide array of C-H bonds as native functional handles for cross-coupling. This mild approach takes advantage of a tunable HAT catalyst that exhibits predictable reactivity patterns based on enthalpic and bond polarity considerations to selectively functionalize a-amino and a-oxy sp(3) C-H bonds in both cyclic and acyclic systems.	J. Am. Chem. Soc.	59	Xia, YZ	FALSE	FALSE	FALSE	FALSE
4595	10.1021/acs.orglett.0c00542	doi.org/10.1021/acs.orglett.0c00542	Palladium-Catalyzed Decarbonylative Alkylation of Acyl Fluorides	An efficient and concise asymmetric synthesis of (R)-(+)-ar-curcumene, (R)-4,7-dimethyl-1-tetralone, and their enantiomers was accomplished. The key step to construct the stereogenic benzylmethyl centers of these natural products is the cobalt-catalyzed asymmetric Kumada cross-coupling reaction of a racemic alpha-bromo ester. (C) 2015 Elsevier Ltd. All rights reserved.	Org. Lett.	59	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
4596	10.1002/cmdc.201900641	doi.org/10.1002/cmdc.201900641	New Efficient Eco-Friendly Supported Catalysts for the Synthesis of Amides with Antioxidant and Anti-Inflammatory Properties		ChemMedChem	59	Ghinet, A	FALSE	FALSE	FALSE	FALSE
4597	10.1002/ijch.201900139	doi.org/10.1002/ijch.201900139	Stabilization of Ni(I)(1,4,8,11-tetraazacyclotetradecane)(+) in a Sol-Gel Matrix: It's Plausible use in Catalytic Processes		Isr. J. Chem.	59	Burg, A	FALSE	FALSE	FALSE	FALSE
4598	10.1002/anie.201910436	doi.org/10.1002/anie.201910436	Nickel-Catalyzed Inter- and Intramolecular Aryl Thioether Metathesis by Reversible Arylation		Angew. Chem.-Int. Edit.	59	Morandi, B	FALSE	FALSE	FALSE	FALSE
4599	10.1021/acs.joc.9b02394	doi.org/10.1021/acs.joc.9b02394	Synthesis of N-Acyl Sulfamates from Fluorosulfonates and Potassium Trimethylsilyloxyl Imidates		J. Org. Chem.	59	Ma, PX; Xu, HT; Yang, G	FALSE	FALSE	FALSE	FALSE
4600	10.1021/acs.organomet.9b00276	doi.org/10.1021/acs.organomet.9b00276	A Modified Cationic Mechanism for PdCl2-Catalyzed Transformation of a Homoallylic Alcohol to an Allyl Ether		Organometallics	59	Ariafard, A	FALSE	FALSE	FALSE	FALSE
4601	10.1021/acs.orglett.9b00875	doi.org/10.1021/acs.orglett.9b00875	Synthesis of Alkynyl Sulfides by Copper-Catalyzed Thiolation of Terminal Alkynes Using Thiosulfonates		Org. Lett.	59	Yoshida, S; Hosoya, T	FALSE	FALSE	FALSE	FALSE
4602	10.6023/cjoc201811035	doi.org/10.6023/cjoc201811035	Research Progress in the Cycloaddition Reactions of Oxiranes		Chin. J. Org. Chem.	59	Li, X; Wei, WL	FALSE	FALSE	FALSE	FALSE
4603	10.1039/c8qo01403e	doi.org/10.1039/c8qo01403e	Ir-Catalyzed ring-opening of oxa(aza)benzonorbornadienes with water or alcohols		Org. Chem. Front.	59	Yang, DQ	FALSE	FALSE	FALSE	FALSE
4604	10.1002/slct.201804066	doi.org/10.1002/slct.201804066	Choline Chloride/Urea as an Eco-Friendly Deep Eutectic Solvent for TCT-Mediated Amide Coupling at Room Temperature		ChemistrySelect	59	Saberi, D	FALSE	FALSE	FALSE	FALSE
4605	10.1039/c8tc06517a	doi.org/10.1039/c8tc06517a	Enhancing charge mobilities in selectively fluorinated oligophenyl organic semiconductors: a design approach based on experimental and computational perspectives		J. Mater. Chem. C	59	Bunge, SD; Twieg, RJ; Dunietz, BD	FALSE	FALSE	FALSE	FALSE
4606	10.1002/ejoc.201801385	doi.org/10.1002/ejoc.201801385	Regioselective Hydrodehalogenation of Aromatic alpha- and beta-Halo carbonyl Compounds by CuI in Isopropanol		Eur. J. Org. Chem.	59	Ahmed, N	FALSE	FALSE	FALSE	FALSE
4607	10.1021/acs.organomet.8b00747	doi.org/10.1021/acs.organomet.8b00747	Mechanism Insight into the Csp(3)-H Amination Catalyzed by the Metal Phthalocyanine		Organometallics	59	Cao, ZX	FALSE	FALSE	FALSE	FALSE
4608	10.1039/c8qo00794b	doi.org/10.1039/c8qo00794b	Oxidative C(sp(3))-H amidation of tertiary arylamines with nitriles		Org. Chem. Front.	59	Tang, G	FALSE	FALSE	FALSE	FALSE
4609	10.1002/anie.201806742	doi.org/10.1002/anie.201806742	Enantioselective alpha-Benzylation of Acyclic Esters Using pi-Extended Electrophiles		Angew. Chem.-Int. Edit.	59	Snaddon, TN	FALSE	TRUE	FALSE	FALSE
4610	10.1002/anie.201803603	doi.org/10.1002/anie.201803603	Bottom-up Construction of -Extended Arenes by a Palladium-Catalyzed Annulative Dimerization of o-Iodobiaryl Compounds		Angew. Chem.-Int. Edit.	59	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
4611	10.1039/c8cc01226a	doi.org/10.1039/c8cc01226a	Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates via direct dehydrogenative C(sp(2))-O cross-coupling		Chem. Commun.	59	Cai, GX	FALSE	FALSE	FALSE	FALSE
4612	10.1016/j.poly.2017.11.021	doi.org/10.1016/j.poly.2017.11.021	Synthesis, characterization and electrochemical properties of O-alkyldithiophosphate nickel complexes with dppf ligand		Polyhedron	59	Xie, B	FALSE	FALSE	FALSE	FALSE
4613	10.1021/acs.orglett.7b03482	doi.org/10.1021/acs.orglett.7b03482	Synthesis of the Tetracyclic Structure of Batrachotoxin Enabled by Bridgehead Radical Coupling and Pd/Ni-Promoted Ullmann Reaction		Org. Lett.	59	Inoue, M	FALSE	FALSE	FALSE	FALSE
4614	10.1039/c8ra04984j	doi.org/10.1039/c8ra04984j	Transesterification of (hetero)aryl esters with phenols by an Earth-abundant metal catalyst		RSC Adv.	59	Bao, YS	FALSE	FALSE	FALSE	FALSE
4615	10.1055/s-0036-1590962	doi.org/10.1055/s-0036-1590962	Stereospecific Nickel-Catalyzed Borylation of Secondary Benzyl Pivalates		Synlett	59	Martin, R	FALSE	FALSE	FALSE	FALSE
4616	10.1021/acs.joc.7b01653	doi.org/10.1021/acs.joc.7b01653	Aqueous Reaction of Alcohols, Organohalides, and Odorless Sodium Thiosulfate under Transition-Metal-Free Conditions: Synthesis of Unsymmetrical Aryl Sulfides via Dual C-S Bond Formation		J. Org. Chem.	59	Wang, SY; Ji, SJ	FALSE	FALSE	FALSE	FALSE
4617	10.1039/c6ra04100k	doi.org/10.1039/c6ra04100k	Experimental and theoretical studies of molecular complexes of theophylline with some phenylboronic acids		RSC Adv.	59	TalwelkarShimpi, M	FALSE	FALSE	FALSE	FALSE
4618	10.1002/anie.201505699	doi.org/10.1002/anie.201505699	Comparison of dppf-Supported Nickel Precatalysts for the Suzuki-Miyaura Reaction: The Observation and Activity of Nickel(I)		Angew. Chem.-Int. Edit.	59	Hazari, N	FALSE	FALSE	FALSE	FALSE
4619	10.1021/acs.orglett.5b02482	doi.org/10.1021/acs.orglett.5b02482	Synthesis of E-Alkyl Alkenes from Terminal Alkynes via Ni-Catalyzed Cross-Coupling of Alkyl Halides with B-Alkenyl-9-borabicyclo[3.3.1]nonanes		Org. Lett.	59	Hu, XL	FALSE	FALSE	FALSE	FALSE
4620	10.1021/jacs.5b07677	doi.org/10.1021/jacs.5b07677	C-H Functionalization at Sterically Congested Positions by the Platinum-Catalyzed Borylation of Arenes		J. Am. Chem. Soc.	59	Tobisu, M	FALSE	FALSE	FALSE	FALSE
4621	10.1021/acs.orglett.5b01955	doi.org/10.1021/acs.orglett.5b01955	Ortho-C-H Benzylation of Aryl Imines with Benzyl Phosphates under Cobalt-Pyphos Catalysis		Org. Lett.	59	Yoshikai, N	FALSE	FALSE	FALSE	FALSE
4622	10.1016/j.ica.2015.07.030	doi.org/10.1016/j.ica.2015.07.030	The trans-cis isomerization of Ni(eta(2)-TEMPO)(2): Interconnections and conformational complexity		Inorg. Chim. Acta	59	DeYonker, NJ	FALSE	FALSE	FALSE	FALSE
4623	10.1002/adsc.201500346	doi.org/10.1002/adsc.201500346	Alkylations of Arylboronic Acids including Difluoroethylation/Trifluoroethylation via Nickel-Catalyzed Suzuki Cross-Coupling Reaction		Adv. Synth. Catal.	59	Yang, CH	FALSE	FALSE	FALSE	FALSE
4624	10.1002/chem.201500627	doi.org/10.1002/chem.201500627	Preparation and Regioselective Magnesiation or Lithiation of Bis(trimethylsilyl)methyl-Substituted Heteroaryls for the Generation of Highly Functionalized Heterocycles		Chem.-Eur. J.	59	Knochel, P	FALSE	FALSE	FALSE	FALSE
4625	10.1021/ol503607h	doi.org/10.1021/ol503607h	Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes		Org. Lett.	59	Chen, TQ	FALSE	FALSE	FALSE	FALSE
4626	10.1021/ja512527s	doi.org/10.1021/ja512527s	Constructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products		J. Am. Chem. Soc.	59	Overman, LE	FALSE	FALSE	FALSE	FALSE
4627	10.1002/chem.201405223	doi.org/10.1002/chem.201405223	Copper-Catalyzed Reductive Cross-Coupling of Nonactivated Alkyl Tosylates and Mesylates with Alkyl and Aryl Bromides		Chem.-Eur. J.	59	Fu, Y	FALSE	FALSE	FALSE	FALSE
4628	10.1007/s11426-014-5138-3	doi.org/10.1007/s11426-014-5138-3	Highly efficient nickel/phosphine catalyzed cross-couplings of diarylborinic acids with aryl tosylates and sulfamates		Sci. China-Chem.	59	Zou, G	FALSE	FALSE	FALSE	FALSE
4629	10.1055/s-0033-1339126	doi.org/10.1055/s-0033-1339126	Unified Synthesis of (-)-Folicanthine and (-)- Ditryptophenaline Enabled by a Room Temperature Nickel-Mediated Reductive Dimerization		Synthesis	59	Peng, Y	FALSE	FALSE	FALSE	FALSE
4630	10.1002/adsc.201301081	doi.org/10.1002/adsc.201301081	Synthesis of Dibenzophosphole Oxides via Palladium-Catalyzed Intramolecular Direct Arylation Reactions of ortho-Halodiaryl-phosphine Oxides		Adv. Synth. Catal.	59	Cui, YM	FALSE	FALSE	FALSE	FALSE
4631	10.1039/c4cc06397j	doi.org/10.1039/c4cc06397j	Metal-free Mizoroki-Heck type reaction: a radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins		Chem. Commun.	59	Tang, SC	FALSE	FALSE	FALSE	FALSE
4632	10.1021/op300364p	doi.org/10.1021/op300364p	A Robust First-Pass Protocol for the Heck-Mizoroki Reaction		Org. Process Res. Dev.	59	Murray, PM	FALSE	FALSE	FALSE	FALSE
4633	10.1039/c3ob27128e	doi.org/10.1039/c3ob27128e	Iron-catalyzed N-alkylation using pi-activated ethers as electrophiles		Org. Biomol. Chem.	59	Fan, XH	FALSE	FALSE	FALSE	FALSE
4634	10.1002/chem.201203969	doi.org/10.1002/chem.201203969	Bidentate Hydroxyalkyl NHC Ligands for the Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents		Chem.-Eur. J.	59	Crevisy, C	FALSE	FALSE	FALSE	FALSE
4635	10.1002/asia.201200723	doi.org/10.1002/asia.201200723	Functionalization of Hexa-peri-hexabenzocoronenes: Investigation of the Substituent Effects on a Superbenzene		Chem.-Asian J.	59	Kim, D	FALSE	FALSE	FALSE	FALSE
4636	10.1016/j.tet.2012.05.101	doi.org/10.1016/j.tet.2012.05.101	Twisted bimesitylene-based oxadiazoles as novel host materials for phosphorescent OLEDs		Tetrahedron	59	Moorthy, JN	FALSE	FALSE	FALSE	FALSE
4637	10.1021/ol3021836	doi.org/10.1021/ol3021836	Nickel-Mediated N-Arylation with Arylboronic Acids: An Avenue to Chan-Lam Coupling		Org. Lett.	59	Singh, KN	FALSE	FALSE	FALSE	FALSE
4638	10.1055/s-0031-1290656	doi.org/10.1055/s-0031-1290656	A Transition-Metal-Free Cross-Coupling Reaction of Allylic Bromides with Aryl- and Vinylboronic Acids		Synlett	59	Ueda, M	FALSE	FALSE	FALSE	FALSE
4639	10.1039/c2dt31271a	doi.org/10.1039/c2dt31271a	1,1 '-Bis(diphenylphosphino)ferrocene in functional molecular materials		Dalton Trans.	59	Young, DJ	FALSE	FALSE	FALSE	FALSE
4640	10.1021/jo2015906	doi.org/10.1021/jo2015906	Manganese(III) Acetate-Mediated Cyclization of Diarylmethylenecyclopropa[b]naphthalenes: A Method for the Synthesis of 1,2-Benzanthracene Derivatives		J. Org. Chem.	59	Wu, LL	FALSE	FALSE	FALSE	FALSE
4641	10.3762/bjoc.7.147	doi.org/10.3762/bjoc.7.147	Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents		Beilstein J. Org. Chem.	59	Knochel, P	FALSE	FALSE	FALSE	FALSE
4642	10.1021/ol1020477	doi.org/10.1021/ol1020477	One-Pot Syntheses of Chromeno[3,4-c]pyrrole-3,4-diones via Ugi-4CR and Intramolecular Michael Addition		Org. Lett.	59	Che, C	FALSE	FALSE	FALSE	FALSE
4643	10.1016/j.tet.2010.04.099	doi.org/10.1016/j.tet.2010.04.099	2,2 '-Diamino-6,6 '-dimethylbiphenyl as an efficient ligand in the palladium-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions		Tetrahedron	59	Shao, LX	FALSE	FALSE	FALSE	FALSE
4644	10.1039/c004233a	doi.org/10.1039/c004233a	One-pot synthesis of furocoumarins via sequential Pd/Cu-catalyzed alkynylation and intramolecular hydroalkoxylation		Org. Biomol. Chem.	59	Xu, MH	FALSE	FALSE	FALSE	FALSE
4645	10.1002/anie.201002116	doi.org/10.1002/anie.201002116	Zinc Chloride Enhanced Arylations of Secondary Benzyl Trifluoroacetates in the Presence of beta-Hydrogen Atoms		Angew. Chem.-Int. Edit.	59	Lei, AW	FALSE	FALSE	FALSE	FALSE
4646	10.1002/ejoc.200900581	doi.org/10.1002/ejoc.200900581	An Economical Access to 3,4-Diaryl-2(5H)-furanones and 4-Aryl-6-methyl-2(2H)-pyranones by Pd-Catalyzed Suzuki-Type Arylation of 3-Aryl-4-tosyloxy-2(5H)-furanones and 6-Methyl-4-tosyloxy-2(2H)-pyranones, Respectively		Eur. J. Org. Chem.	59	Bellina, F	FALSE	FALSE	FALSE	FALSE
4647	10.1002/ejoc.200700978	doi.org/10.1002/ejoc.200700978	Efficient copper(I)-catalyzed C-S cross coupling of thiols with aryl halides in water		Eur. J. Org. Chem.	59	Rout, L	FALSE	FALSE	FALSE	FALSE
4648	10.1016/j.tet.2007.04.016	doi.org/10.1016/j.tet.2007.04.016	Copper(I)-catalysed homo-coupling of aryldiazonium salts: synthesis of symmetrical biaryls		Tetrahedron	59	Cepanec, I	FALSE	FALSE	FALSE	FALSE
4649	10.1021/jo0623890	doi.org/10.1021/jo0623890	Nickel-catalyzed coupling producing (2Z)-2,4-alkadien-1-ols, conversion to (E)-3-alkene-1,2,5-triol derivatives, and synthesis of decarestrictine D		J. Org. Chem.	59	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
4650	10.1002/ejoe.200600600	doi.org/10.1002/ejoe.200600600	Recoverable homogeneous palladium(0) catalyst for cross-coupling reactions of arenediazonium salts with potassium organotrifluoroborates: Detection of catalytic intermediates by electrospray ionization mass spectrometry		Eur. J. Org. Chem.	59	Masllorens, J	FALSE	FALSE	FALSE	FALSE
4651	10.1021/om050781i	doi.org/10.1021/om050781i	Synthesis and structural characterization of the first bis(benzimidazolin-2-ylidene) complexes of nickel(II)		Organometallics	59	Huynh, HV	FALSE	FALSE	FALSE	FALSE
4652	10.1002/1521-3765(20020816)8:16<3620::AID-CHEM3620>3.0.CO;2-P	doi.org/10.1002/1521-3765(20020816)8:16<3620::AID-CHEM3620>3.0.CO;2-P	Intramolecular coupling of allyl carboxylates with allyl stannanes and allyl silanes: A new type of reductive elimination reaction?		Chem.-Eur. J.	59	Echavarren, AM	FALSE	FALSE	FALSE	FALSE
4653	10.1021/jo960617s	doi.org/10.1021/jo960617s	Stereoselective synthesis of heterocyclic zinc reagents via a nickel-catalyzed radical cyclization		J. Org. Chem.	59		FALSE	FALSE	FALSE	FALSE
4654	10.1021/jo00057a055	doi.org/10.1021/jo00057a055	SYNTHESIS OF TRANS-OLEFINS BY A NICKEL-CATALYZED REDUCTION OF ENOL ETHERS - A FORMAL, TOTAL SYNTHESIS OF (+/-)-RECIFEIOLIDE		J. Org. Chem.	59		FALSE	FALSE	FALSE	FALSE
4655	10.1021/jo00196a002	doi.org/10.1021/jo00196a002	REGIOSELECTIVE SYNTHESIS OF ALLYLTRIMETHYLSILANES FROM ALLYLIC HALIDES AND ALLYLIC SULFONATES - APPLICATION TO THE SYNTHESIS OF 2,3-BIS(TRIMETHYLSILYL)ALK-1-ENES		J. Org. Chem.	59	SMITH, JG	FALSE	FALSE	FALSE	FALSE
4656	10.1021/acs.orglett.2c00334	doi.org/10.1021/acs.orglett.2c00334	Synthesis of alpha-Aryl Primary Amides from alpha-Silyl Nitriles and Aryl Sulfoxides through [3,3]-Sigmatropic Rearrangement		Org. Lett.	59	Chen, XB	FALSE	FALSE	FALSE	FALSE
4657	10.1002/cjoc.202100819	doi.org/10.1002/cjoc.202100819	Enantioselective Reductive Cross-Coupling of Aryl/Alkenyl Bromides with Benzylic Chlorides via Photoredox/Biimidazoline Nickel Dual Catalysis		Chin. J. Chem.	59	Fang, Q; Lu, Z	TRUE	FALSE	FALSE	FALSE
4658	10.1039/d1gc04001d	doi.org/10.1039/d1gc04001d	Cu/N-Oxyl-catalyzed aerobic oxidative esterification to oxalic acid diesters from ethylene glycol via highly selective intermolecular alcohol oxidation		Green Chem.	59	Yatabe, T; Yamaguchi, K	FALSE	FALSE	FALSE	FALSE
4659	10.1002/ejic.202101006	doi.org/10.1002/ejic.202101006	Evaluating a Dispersion of Sodium in Sodium Chloride for the Synthesis of Low-Valent Nickel Complexes		Eur. J. Inorg. Chem.	59	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
4660	10.1021/acs.joc.1c02311	doi.org/10.1021/acs.joc.1c02311	Iron-Catalyzed Oxidative Amination of Benzylic C(sp(3))-H Bonds with Anilines		J. Org. Chem.	59	Sun, HM	FALSE	FALSE	FALSE	FALSE
4661	10.1021/jacs.1c11503	doi.org/10.1021/jacs.1c11503	Homologation of Electron-Rich Benzyl Bromide Derivatives via Diazo C-C Bond Insertion		J. Am. Chem. Soc.	59	Race, NJ	FALSE	TRUE	FALSE	FALSE
4662	10.1021/acssuschemeng.1c04903	doi.org/10.1021/acssuschemeng.1c04903	Coordinatively Unsaturated Hf-MOF-808 Prepared via Hydrothermal Synthesis as a Bifunctional Catalyst for the Tandem N-Alkylation of Amines with Benzyl Alcohol		ACS Sustain. Chem. Eng.	59	Moliner, M; Corma, A	FALSE	FALSE	FALSE	FALSE
4663	10.1039/d1qo01474a	doi.org/10.1039/d1qo01474a	Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides		Org. Chem. Front.	59	Shen, ZL	FALSE	FALSE	FALSE	FALSE
4664	10.1021/jacs.1c08105	doi.org/10.1021/jacs.1c08105	Ni/Photoredox-Catalyzed Enantioselective Cross-Electrophile Coupling of Styrene Oxides with Aryl Iodides		J. Am. Chem. Soc.	59	Doyle, AG	TRUE	TRUE	FALSE	FALSE
4665	10.1021/acs.orglett.1c02406	doi.org/10.1021/acs.orglett.1c02406	Effects of Silver Carbonate and p-Nitrobenzoic Acid for Accelerating Palladium-Catalyzed Allylic C-H Acyloxylation		Org. Lett.	59	Tsurugi, H; Mashima, K	FALSE	FALSE	FALSE	FALSE
4666	10.1021/acscatal.1c03010	doi.org/10.1021/acscatal.1c03010	CgPhen-DalPhos Enables the Nickel-Catalyzed O-Arylation of Tertiary Alcohols with (Hetero)Aryl Electrophiles		ACS Catal.	59	Stradiotto, M	FALSE	TRUE	FALSE	FALSE
4667	10.1055/a-1528-1711	doi.org/10.1055/a-1528-1711	Recent Advances in Transition-Metal-Catalyzed C-H Functionalization Reactions Involving Aza/Oxabicyclic Alkenes		Synthesis	59	Jeganmohan, M	FALSE	FALSE	FALSE	FALSE
4668	10.1039/d1ob00595b	doi.org/10.1039/d1ob00595b	Domino Heck/Hiyama cross-coupling: trapping of the sigma-alkylpalladium intermediate with arylsilanes		Org. Biomol. Chem.	59	Wu, XX; Jiang, GM; Hu, LP	FALSE	FALSE	FALSE	FALSE
4669	10.1021/acs.orglett.1c00940	doi.org/10.1021/acs.orglett.1c00940	Palladium-Catalyzed Intermolecular Alkene Carboacylation via Ester C-O Bond Activation		Org. Lett.	59	Stanley, LM	FALSE	FALSE	FALSE	FALSE
4670	10.1039/d1sc01115d	doi.org/10.1039/d1sc01115d	Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes		Chem. Sci.	59	Wang, CA	FALSE	FALSE	FALSE	FALSE
4671	10.1039/d1sc00133g	doi.org/10.1039/d1sc00133g	Synthesis of quaternary centres by single electron reduction and alkylation of alkylsulfones		Chem. Sci.	59	Nambo, M; Crudden, CM	FALSE	FALSE	FALSE	FALSE
4672	10.1055/a-1416-4924	doi.org/10.1055/a-1416-4924	A Simple and Efficient Synthesis of Fused Benzo[b]thiophene Derivatives		Synthesis	59	Fisyuk, AS	FALSE	FALSE	FALSE	FALSE
4673	10.1039/c7cc05000c	doi.org/10.1039/c7cc05000c	Naphthol synthesis: annulation of nitrones with alkynes via rhodium(III)-catalyzed C-H activation		Chem. Commun.	59	Li, XW	FALSE	FALSE	FALSE	FALSE
4674	10.1021/acs.joc.7b00550	doi.org/10.1021/acs.joc.7b00550	Palladium Catalyzed Arylation and Benzylation of Nitroarenes Using Aryl Sulfonates and Benzyl Acetates		J. Org. Chem.	59	Kalyani, D	FALSE	FALSE	FALSE	FALSE
4675	10.1021/jacs.7b03387	doi.org/10.1021/jacs.7b03387	Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes		J. Am. Chem. Soc.	59	Stahl, SS	FALSE	FALSE	FALSE	FALSE
4676	10.1002/ejoc.201700239	doi.org/10.1002/ejoc.201700239	Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis		Eur. J. Org. Chem.	59	Oestreich, M	FALSE	FALSE	FALSE	FALSE
4677	10.1002/anie.201611819	doi.org/10.1002/anie.201611819	Catalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C-O and C-C Bond Activation		Angew. Chem.-Int. Edit.	59	Rueping, M	FALSE	FALSE	FALSE	FALSE
4678	10.1002/asia.201601537	doi.org/10.1002/asia.201601537	Efficient Hydrogenation of Biomass Oxoacids to Lactones by Using NHC-Iridium Coordination Polymers as Solid Molecular Catalysts		Chem.-Asian J.	59	Tu, T	FALSE	FALSE	FALSE	FALSE
4679	10.1016/j.tetlet.2016.12.013	doi.org/10.1016/j.tetlet.2016.12.013	Copper-catalyzed cross-coupling reactions of non-activated primary, secondary or tertiary alkyl chlorides with phenylmagnesium bromide		Tetrahedron Lett.	59	Tao, CZ	FALSE	FALSE	FALSE	FALSE
4680	10.1039/c6cc08401j	doi.org/10.1039/c6cc08401j	An efficient parts-per-million alpha-Fe2O3 nanocluster/graphene oxide catalyst for Suzuki-Miyaura coupling reactions and 4-nitrophenol reduction in aqueous solution		Chem. Commun.	59	Astruc, D	FALSE	FALSE	FALSE	FALSE
4681	10.1021/acscatal.6b03040	doi.org/10.1021/acscatal.6b03040	Nickel-Catalyzed Deamidative Step-Down Reduction of Amides to Aromatic Hydrocarbons		ACS Catal.	59	Lahiri, GK; Maiti, D	FALSE	FALSE	FALSE	FALSE
4682	10.1039/c6qo00529b	doi.org/10.1039/c6qo00529b	A practical protocol for the synthesis of bibenzyls via C(sp(3))-H activation of methyl arenes under metal-free conditions		Org. Chem. Front.	59	Singh, KN	FALSE	FALSE	FALSE	FALSE
4683	10.1039/c7ra07437a	doi.org/10.1039/c7ra07437a	A general and mild Cu-catalytic N-arylation of iminodibenzyls and iminostilbenes using unactivated aryl halides		RSC Adv.	59	Yao, WB; Jiang, HJ	FALSE	FALSE	FALSE	FALSE
4684	10.1016/j.tetlet.2016.11.027	doi.org/10.1016/j.tetlet.2016.11.027	Calcium(II) catalyzed regioselective dehydrative cross-coupling reactions: Practical synthesis of internal alkenes and benzopyrans		Tetrahedron Lett.	59	Yaragorla, S	FALSE	FALSE	FALSE	FALSE
4685	10.1002/anie.201607959	doi.org/10.1002/anie.201607959	Preparation of Vinyl Arenes by Nickel-Catalyzed Reductive Coupling of Aryl Halides with Vinyl Bromides		Angew. Chem.-Int. Edit.	59	Ren, QH; Gong, HG	FALSE	FALSE	FALSE	FALSE
4686	10.1021/acs.orglett.6b02784	doi.org/10.1021/acs.orglett.6b02784	Site-Selective Silylation of Aliphatic C-H Bonds Mediated by [1,5]-Hydrogen Transfer: Synthesis of alpha-Sila Benzamides		Org. Lett.	59	Zeng, XM	FALSE	FALSE	FALSE	FALSE
4687	10.1021/acs.joc.6b01648	doi.org/10.1021/acs.joc.6b01648	Transition-Metal-Free Cross-Coupling of Aryl Halides with Arylstannanes		J. Org. Chem.	59	Zhang, ZT	FALSE	FALSE	FALSE	FALSE
4688	10.1021/acs.orglett.6b02665	doi.org/10.1021/acs.orglett.6b02665	Stereospecific Synthesis of Tetrahydronaphtho[2,3-b]furans Enabled by a Nickel-Promoted Tandem Reductive Cyclization		Org. Lett.	59	Peng, Y	FALSE	FALSE	FALSE	FALSE
4689	10.1021/acs.orglett.6b02516	doi.org/10.1021/acs.orglett.6b02516	Iron-Catalyzed alpha-Arylation of Deoxybenzoins with Arenes through an Oxidative Dehydrogenative Approach		Org. Lett.	59	Zhang, FM	FALSE	FALSE	FALSE	FALSE
4690	10.1021/acs.inorgchem.6b01218	doi.org/10.1021/acs.inorgchem.6b01218	Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic-Inorganic Ligand		Inorg. Chem.	59	Crabtree, RH	FALSE	FALSE	FALSE	FALSE
4691	10.1038/ncomms11676	doi.org/10.1038/ncomms11676	Multimetallic catalysed radical oxidative C(sp(3))-H/C(sp)-H cross-coupling between unactivated alkanes and terminal alkynes		Nat. Commun.	59	Lei, AW	FALSE	FALSE	FALSE	FALSE
4692	10.1021/acs.orglett.6b00643	doi.org/10.1021/acs.orglett.6b00643	Exploiting Aryl Mesylates and Tosylates in Catalytic Mono-alpha-arylation of Aryl- and Heteroarylketones		Org. Lett.	59	Kwong, FY	FALSE	FALSE	FALSE	FALSE
4693	10.1039/c5ob02364e	doi.org/10.1039/c5ob02364e	Synthesis of 8-heteroaryl nitroxoline analogues via one-pot sequential Pd-catalyzed coupling reactions		Org. Biomol. Chem.	59	Stefane, B	FALSE	FALSE	FALSE	FALSE
4694	10.1039/c6ob01765g	doi.org/10.1039/c6ob01765g	Pd-Catalyzed C(sp(3))-C(sp(2)) cross-coupling of Y(CH2SiMe3)(3)(THF)(2) with vinyl bromides and triflates		Org. Biomol. Chem.	59	Yao, B; Li, XF	FALSE	FALSE	FALSE	FALSE
4695	10.1039/c6sc01457g	doi.org/10.1039/c6sc01457g	Nickel-catalyzed C-3 direct arylation of pyridinium ions for the synthesis of 1-azafluorenes		Chem. Sci.	59	Desrosiers, JN; Wei, XD	FALSE	FALSE	FALSE	FALSE
4696	10.1021/acs.joc.0c02644	doi.org/10.1021/acs.joc.0c02644	Cyanoquinolines and Furo[3,4-b]quinolinones Formation via On-The-Spot 2,3-Functionalization of Quinolines with Cyanopropargylic Alcohols	A chiral CpRu(II)/p-TsOH combined catalyst is described for asymmetric allylation that reverses the pi-allyl donicity of AllX (All: allyl, X: leaving group) from AllOAc > AllOPh > AllOH > AllOMe to AllOH > AllOMe > AllOPh > AllOAc. This represents a novel deviation from conventional Tsuji-Trost-Pd-based methods that operate under basic conditions. This is the first successful demonstration of endowing reactivity in chemically stable AllOMe, which should significantly expand the scope of synthetic possibilities.	J. Org. Chem.	58	Trofimov, BA	FALSE	FALSE	FALSE	FALSE
4697	10.1002/ejoc.202001602	doi.org/10.1002/ejoc.202001602	Two-Step Protocol for Iodotrimethylsilane-Mediated Deoxy-Functionalization of Alcohols		Eur. J. Org. Chem.	58	Liu, YX; Wang, QM	FALSE	FALSE	FALSE	FALSE
4698	10.1021/acs.joc.0c01819	doi.org/10.1021/acs.joc.0c01819	Homogeneous Nickel-Catalyzed Sustainable Synthesis of Quinoline and Quinoxaline under Aerobic Conditions	Fluorobenzenes, in particular fluorobenzene (FB) and 1,2-difluorobenzene (1,2-DiFB), are increasingly becoming recognised as versatile solvents for conducting organometallic chemistry and transition-metal-based catalysis. The presence of fluorine substituents reduces the ability to donate p-electron density from the arene and consequently fluorobenzenes generally bind weakly to metal centres, allowing them to be used as essentially non-coordinating solvents or as readily displaced ligands. In this context, examples of well-defined complexes of fluorobenzenes are discussed, including trends in binding strength with increasing fluorination and different substitution patterns. Compared to more highly fluorinated benzenes, FB and 1,2-DiFB typically demonstrate greater chemical inertness, however, C-H and C-F bond activation reactions can be induced using appropriately reactive transition metal complexes. Such reactions are surveyed, including catalytic examples, not only to provide perspective for the use of FB and 1,2-DiFB as innocent solvent media, but also to highlight opportunities for their exploitation in contemporary organic synthesis.	J. Org. Chem.	58	Adhikari, D	FALSE	FALSE	FALSE	FALSE
4699	10.1021/jacs.0c08708	doi.org/10.1021/jacs.0c08708	Nickel-Catalyzed Four-Component Carbocarbonylation of Alkenes under 1 atm of CO	Nickel precatalysts are potentially a more sustainable alternative to traditional palladium precatalysts for the Suzuki-Miyaura coupling reaction. Currently, there is significant interest in Suzuki-Miyaura coupling reactions involving readily accessible phenolic derivatives such as aryl sulfamates, as the sulfamate moiety can act as a directing group for the prefunctionalization of the aromatic backbone of the electrophile prior to cross-coupling. By evaluating complexes in the Ni(0), (I), and (II) oxidation states we report a precatalyst, (dppf)Ni(o-tolyl) ( Cl) (dppf = 1,1'-bis(diphenylphosphino)-ferrocene), for Suzuki-Miyatra coupling reactions involving aryl sulfamates and boronic acids, which operates at a significantly lower catalyst loading and at milder reaction conditions than other reported systems. In some cases it can even function at room temperature. Mechanistic studies on precatalyst activation and the speciation of nickel during catalysis reveal that Ni(I) species,are formed in the catalytic reaction via two different pathways: (i) the precatalyst (dppf)Ni(o-tolyl)(Cl) undergoes, comproportionation with the active Ni(0). species; and (ii) the catalytic intermediate (dppf)Ni(Ar)(sulfamate) (Ar = aryl) undergoes comproportionation with the active Ni(0) species. In both cases the formation of Ni(I) is detrimental to Catalysis, which is proposed to proceed via a Ni(0)/Ni(II) cycle. DFT calculations are used to support experimental observations and provide insight about the elementary steps involved in reactions directly on the catalytic cycle, as well as off-cycle processes,. Our mechanistic investigation provides guidelines for designing even more active nickel catalysts.	J. Am. Chem. Soc.	58	Zhang, XG	FALSE	FALSE	FALSE	FALSE
4700	10.1039/d0gc01649g	doi.org/10.1039/d0gc01649g	Photoinduced catalyst-free deborytation-deuteration of arylboronic acids with D2O	Chiral Lewis acids play an important role in the precise construction of various types of chiral molecules. Here, a cage-shaped borate 2 was designed and synthesized as a chiral Lewis acid that possesses a unique C(3-)symmetric structure composed of three homochiral binaphthyl moieties. The highly symmetrical structure of 2 with homochirality was clearly elucidated by X-ray crystallographic analysis. The peculiar chiral environment of 2.THF exhibited chiral recognition of some simple amines and a sulfoxide. Moreover, the application of 2.THF to hetero-Diels-Alder reactions as a chiral Lewis-acid catalyst afforded the enantioselective products, which were obtained through an entropy-controlled pathway according to the analysis of the relationship between optical yield and reaction temperature. In particular, the robust chiral reaction field of 2.THF allowed the first example of an asymmetric hetero-Diels-Alder reaction with a simple diene despite the requirement of high temperature.	Green Chem.	58	Zeng, HY	TRUE	FALSE	FALSE	FALSE
4701	10.1021/acs.orglett.0c02913	doi.org/10.1021/acs.orglett.0c02913	Thianthrenation-Enabled alpha-Arylation of Carbonyl Compounds with Arenes	A general and efficient synthesis of -substituted phosphinoacetic acids using simple esters and diphenylchlorophosphine-borane as readily available starting materials is here described. The formation and structure of the corresponding palladium complex derived from 2-ethyl diphenylphosphinoacetic acid is also reported.	Org. Lett.	58	Wang, P	FALSE	FALSE	FALSE	FALSE
4702	10.1021/acs.orglett.0c02236	doi.org/10.1021/acs.orglett.0c02236	Nickel(II)-Catalyzed Borylation of Alkenyl Methyl Ethers via C-O Bond Cleavage	Ruthenium ligated to tricyclohexylphosphine or di-tert-butylbipyridine catalyzes the arylation of carboxylic acids with diverse aryl halides (iodide, bromide, and triflate; aryl and heteroaryl). In addition, arylation with 2-iodophenol formed benzochromenones, carboxylate was shown to be a stronger donor than an amide, and the arylation of a pyridine carboxylate was demonstrated. Stoichiometric studies demonstrated that the added ligand is required for reaction with the electrophile but not the C-H bond.	Org. Lett.	58	Qiu, XD; Ling, Y	FALSE	FALSE	FALSE	FALSE
4703	10.1002/cplu.202000451	doi.org/10.1002/cplu.202000451	Mechanochemical Synthesis of N-Aryl Amides from O-Protected Hydroxamic Acids	The nickel-catalyzed direct borylation and silylation of phenolic esters has been established. The key to this highly efficient acyl C-O bond borylative and silylative cleavage depends on the appropriate choice of different ligands and additives in the presence of nickel catalyst. Both transformations exhibit good functional group compatibility and can serve as powerful synthetic tools for late-stage functionalization of complex compounds. The elucidation of key mechanistic features of this newly developed acyl C-O bond activation in esters was confirmed by two well-characterized organonickel(II) intermediates.	ChemPlusChem	58	Vilela, F	FALSE	FALSE	FALSE	FALSE
4704	10.3390/catal10080861	doi.org/10.3390/catal10080861	Transition Metal-Catalyzed alpha-Position Carbon-Carbon Bond Formations of Carbonyl Derivatives	Suzuki-Miyaura reactions, involving the activation of carbon-halogen bonds, especially C-Cl bonds, have drawn widespread attention because of their huge industrial potential. However, these reactions are dependent on the development of highly active and stable catalysts. Herein, we developed a convenient one-pot wet route to synthesize Pd (x) Cu (y) bimetallic nanocrystals for the Suzuki-Miyaura reaction. By introducing Cu, an earth-abundant element, the catalytic activity was greatly enhanced while the amount of Pd required was reduced. Pd (x) Cu (y) nanocrystals of different compositions, including Pd3Cu, Pd2Cu, PdCu, PdCu2, and PdCu3, were successfully synthesized by tuning the Pd:Cu ratio. Their catalytic performance in Suzuki-Miyaura reactions between phenylboronic acid and halobenzenes (iodo-, bromo-, or chlorobenzene) showed that PdCu3 nanocatalyst demonstrated the best efficacy.	Catalysts	58	Kim, M; Kim, C	FALSE	FALSE	FALSE	FALSE
4705	10.1021/acscatal.0c01301	doi.org/10.1021/acscatal.0c01301	Aryl Fluoride Activation through Palladium-Magnesium Bimetallic Cooperation: A Mechanistic and Computational Study	Isoindolinones comprise an important class of medicinally active compounds. Herein we report a straightforward functionalization of isoindolinones with aryl bromides (22 examples) using a palladium(II) acetate/NIXANTPHOS-based catalyst system. Additionally 3-aryl-3-hydroxyisoindolinone derivatives, which exhibit anti-tumor activity, can be accessed via a tandem reaction. Thus, when the arylation product is exposed to air under basic conditions, in situ oxidation takes place to install the 3-hydroxy group. Furthermore, a tandem arylation/allylic substitution reaction is advanced in which both the arylation and allylic substitution are catalyzed by the same palladium catalyst. Finally, a tandem arylation/alkylation procedure is presented. These tandem reactions enable the synthesis of a variety of structurally diverse isoindolinone derivatives from common starting materials.	ACS Catal.	58	Walsh, PJ; Tomson, NC	FALSE	FALSE	FALSE	FALSE
4706	10.1038/s41467-020-17224-2	doi.org/10.1038/s41467-020-17224-2	Upgrading ketone synthesis direct from carboxylic acids and organohalides	An electron-deficient Cp-E rhodium(III) complex bearing a cyclopentadienyl ligand with two ethyl ester substituents catalyzes the tandem [2+2+2] annulation-lactamization of acetanilides with two alkynoates via cleavage of adjacent two C-H bonds to give densely substituted benzo[cd]indolones. The reactions of meta-methoxy-substituted acetanilides with two alkynoates also provided benzo[cd] indolones via cleavage of adjacent C-H/C-O bonds. Furthermore, 3,5-dimethoxyacetanilides reacted with two alkynoates to give dearomatized spiro compounds.	Nat. Commun.	58	Xie, J	FALSE	FALSE	FALSE	FALSE
4707	10.1021/acs.orglett.0c01857	doi.org/10.1021/acs.orglett.0c01857	Catalytic Asymmetric Addition Reactions of Formaldehyde N,N-Dialkylhydrazone to Synthesize Chiral Nitrile Derivatives	A pentamethylcyclopentadienyl iridium complex containing a tricyclic, dianionic, tridentate, scorpionate (facial binding), mixed organic inorganic ligand was synthesized and characterized by single-crystal X-ray crystallography, as well as polynuclear NMR, UV-vis, and IR spectroscopies. The central cycle of the tridentate ligand consists of a modified boroxine in which two of the boron centers are tetrahedral, anionic borates. The complex is stable to hydrolysis in aqueous solution for >9 weeks at 25 degrees C but reacts with a 50 mM solution of sodium periodate within 12 s to form a periodate-driven oxygen evolution catalyst that has a turnover frquency of >15 s(-1). However, the catalyst is almost completely deactivated within 5 min, achieving an average turnover number of ca. 2500 molecules of oxygen per atom of iridium. Nanoparticles were not observed on this time scale but did form within 4 h of catalyst activation under these experimental conditions. The parent complex was modeled using density functional theory, which accurately reflected the geometry of the complex and indicated significant interaction of iridium- and boracycle-centered orbitals.	Org. Lett.	58	Liu, XH; Feng, XM	FALSE	FALSE	FALSE	FALSE
4708	10.1016/S1872-2067(20)63561-6	doi.org/10.1016/S1872-2067(20)63561-6	Intermediate formation enabled regioselective access to amide in the Pd-catalyzed reductive aminocarbonylation of olefin with nitroarene	The effect of ZnCl2 additives on a series of (salicylaldiminato)Ni ethylene polymerization catalysts is reported. While ZnCl2 acts solely as a pyridine scavenger for simple imine catalyst frameworks such as the biphenylimine 4, in the case of complexes containing a 2,2'-bipyridine pendent group such as 5, ZnCl2 can coordinate to generate a bimetallic Ni/Zn active species that produces a polymer with significantly higher M-n value. 5 is not catalytically active in the absence of ZnCl2, and control experiments indicate that Zn coordination of the bpy pocket to generate a heterobimetallic Ni/Zn complex is critical for productive catalysis to occur. A heterobimetallic Ni/ZnCl2 precatalyst 7 has also been synthesized and structurally characterized and shows activity similar to that of the in situ bimetallic generated from 5 + ZnCl2.	Chin. J. Catal.	58	Xia, CG; Li, FW	FALSE	FALSE	FALSE	FALSE
4709	10.1021/acs.orglett.0c01580	doi.org/10.1021/acs.orglett.0c01580	Ruthenium-Catalyzed Hydrogen Evolution o-Aminoalkylation of Phenols with Cyclic Amines	A new strategy for catalytic enantioselective C-acylation to generate alpha-quaternary-substituted lactams is reported. Ni-catalyzed three-component coupling of lactam enolates, benzonitriles, and aryl halides produces beta-imino lactams that then afford beta-keto lactams by acid hydrolysis. Use of a readily available Mandyphos-type ligand and addition of LiBr enable the construction of quaternary stereocenters on alpha-substituted lactams to form beta-keto lactams in up to 94% ee.	Org. Lett.	58	Zhang, M	FALSE	FALSE	FALSE	FALSE
4710	10.1021/acs.organomet.0c00338	doi.org/10.1021/acs.organomet.0c00338	Palladium-Catalyzed Cyclobutanation of Aryl Sulfonates through both C-O and C-H Cleavage	A new and efficient nickel-catalyzed alkylation of C-Ar-O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various C-sp2-C-sp3 bonds through C-sp2-O substitution, without the restriction of beta-hydride elimination. Moreover, the advantage of the newly developed method was demonstrated in a selective and sequential C-O bond activation process.	Organometallics	58	Dong, QZ; Chen, T	FALSE	FALSE	FALSE	FALSE
4711	10.1021/acs.joc.0c00597	doi.org/10.1021/acs.joc.0c00597	Mechanism and Origins of Enantio- and Regioselectivities in Catalytic Asymmetric Minisci-Type Addition to Heteroarenes	An efficient copper-catalyzed/-mediated and 8-aminoquinoline-assisted arylselenylation of inert C-H bonds of (hetero)arenes with readily available diselenides has been reported. The reaction is scalable and tolerates a wide spectrum of functional groups to deliver diarylselenides in very high yields (up to 98%). Application of this methodology to the facile synthesis of thiophene-fused selenochromone was demonstrated.	J. Org. Chem.	58	Zhu, RX	FALSE	FALSE	FALSE	FALSE
4712	10.1007/s41981-020-00094-6	doi.org/10.1007/s41981-020-00094-6	Development of large-scale oxidative Bromination with HBr-DMSO by using a continuous-flow microwave system for the subsequent synthesis of 4-Methoxy-2-methyldiphenylamine	Nickel-catalyzed cross-electrophile coupling reactions of benzylic esters and aryl halides have been developed. Both inter-and intramolecular variants proceed under mild reaction conditions. A range of heterocycles and functional groups are tolerated under the reaction conditions. Additionally, the first example of a stereospecific cross-electrophile coupling of a secondary benzylic ester is described.	J. Flow Chem.	58	Lv, YW; Yu, JG	FALSE	FALSE	FALSE	FALSE
4713	10.1021/acs.orglett.0c01121	doi.org/10.1021/acs.orglett.0c01121	Acylation of Aryl Halides and alpha-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis	We report the first Co-catalyzed borylation of aryl halides and pseudohalides with bis(pinacolato)diboron (B(2)pin(2)). The synthesis of two new Co(II) complexes of oxazolinylferrocenylphosphine ligands is described. Upon activation with LiMe, the Co complex catalyzes the borylation reactions of aryl bromides, iodides, sulfonates, 0arenediazonium salts, and even aryl chlorides under mild conditions, providing the borylated products in excellent to moderate yields and with high functional group tolerance.	Org. Lett.	58	Wang, C	FALSE	FALSE	FALSE	FALSE
4714	10.1246/cl.200083	doi.org/10.1246/cl.200083	Synthesis and Crystal Packing Structures of 2,7-Diazapyrenes with Various Alkyl Groups at 1,3,6,8-Positions	A selection of heteroaryl fluorosulfates were readily synthesized using commercial SO2F2 gas. These substrates are highly efficient coupling partners in the Suzuki reaction. Through judicious selection of Pd catalysts the fluorosulfate functionality is differentiated from bromide and chloride; the order of reactivity being: -Br> -OSO2F> -Cl. Exploiting this trend allowed the stepwise chemoselective synthesis of a number of polysubstituted pyridines, including the drug Etoricoxib.	Chem. Lett.	58	Miyake, Y	FALSE	FALSE	FALSE	FALSE
4715	10.1002/anie.201915454	doi.org/10.1002/anie.201915454	Integrating Allyl Electrophiles into Nickel-Catalyzed Conjunctive Cross-Coupling	Simple strategies for decarboxylative functionalizations of electron-deficient benzoic acids via using Cu(I) as promoter and electron-rich ones by employing Pd(II) as catalyst under aerobic conditions have been established, which lead to smooth synthesis of aryl halides (-I, Br, and Cl) through the decarboxylative functionalization of benzoic acids with readily available halogen sources CuX (X = I, Br, Cl), and easy preparation of benzonitriles from decarboxylative cyanation of aryl carboxylic acids with nontoxic and low-cost K4Fe(CN)(6) under an oxygen atmosphere for the first time.	Angew. Chem.-Int. Edit.	58	Engle, KM	FALSE	TRUE	FALSE	FALSE
4716	10.1021/acs.orglett.0c00094	doi.org/10.1021/acs.orglett.0c00094	The Tetraethylphosphorodiamidate (OP(O)(NEt2)(2)) Directed Metalation Group (DMG). Directed ortho and Lateral Metalation and the Phospha Anionic Fries Rearrangement	Palladium-catalyzed allylic substitution reactions are among the most efficient methods to construct C-C bonds between sp(3)-hybridized carbon atoms. In contrast, much less work has been done with nickel catalysts, perhaps because of the different mechanisms of the allylic substitution reactions. Palladium catalysts generally undergo substitution by a soft-nucleophile pathway, wherein the nucleophile attacks the allyl group externally. Nickel catalysts are usually paired with hard nucleophiles, which attack the metal before C-C bond formation. Introduced herein is a rare nickel-based catalyst which promotes substitution with diarylmethane pronucleophiles by the soft-nucleophile pathway. Preliminary studies on the asymmetric allylic alkylation are promising.	Org. Lett.	58	Snieckus, V	FALSE	FALSE	FALSE	FALSE
4717	10.1039/c9cc09899b	doi.org/10.1039/c9cc09899b	Ruthenium-catalyzed benzylic substitution of benzyl esters with stabilized carbon nucleophiles	The general synthesis of [Ni(Cp)(X)(NHC)] complexes from a nickel halide, CpLi, and a carbene solution is reported. This procedure yields unprecedented complexes with ring-expanded NHC ligands (RE-NHC) of six- (1a, 1b), seven- (1c), and eight-membered (1d) heterocycles. The NMR spectra of 1a-1d are consistent with the hindered rotation of Ni-C-carbene and N-C-Mes bonds, while X-ray analyses of 1b, 1c, and 1d reveal a pronounced trans influence of the RE-NHC ligands. Complexes 1a-1e are efficient pre-catalysts in Kumada-Tamao-Corriu coupling with the maximum efficiency observed for complexes bearing the six-membered NHC.	Chem. Commun.	58	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
4718	10.1038/s41929-020-0439-8	doi.org/10.1038/s41929-020-0439-8	Catalytic enantioselective desymmetrizing functionalization of alkyl radicals via Cu(i)/CPA cooperative catalysis	Novel, facile C-S and S-S bond coupling reactions were achieved by using an aryl diazonium salt as an arylating agent and thioacetamide as a sulphur surrogate. The reaction proceeds smoothly at room temperature without using any transition metal catalyst, ligand or base. Aryl diazonium salts undergo rapid reactions with thioacetamide at room temperature to give the desired products in a much shorter period than the previously reported metal catalysed protocols.	Nat. Catal.	58	Liu, XY	FALSE	FALSE	FALSE	FALSE
4719	10.1016/j.jpcs.2019.109256	doi.org/10.1016/j.jpcs.2019.109256	Green tea extract-modified silica gel decorated with palladium nanoparticles as a heterogeneous and recyclable nanocatalyst for Buchwald-Hartwig C-N cross-coupling reactions	A highly mono-selective ortho-trifluoromethylation of benzamides was achieved via Cu-promoted C-H activations. The reaction employs an 8-aminoquinoline group as the bidentate directing group and Togni reagent II as the CF3 source. The reaction tolerated a wide variety of functional groups and various ortho-trifluoromethylated benzamides were efficiently synthesized in 36-82% yield.	J. Phys. Chem. Solids	58	Veisi, H	FALSE	FALSE	FALSE	FALSE
4720	10.1021/acs.orglett.9b04634	doi.org/10.1021/acs.orglett.9b04634	Nickel-Catalyzed Hydroarylation of in Situ Generated 1,3-Dienes with Arylboronic Acids Using a Secondary Homoallyl Carbonate as a Surrogate for the 1,3-Diene and Hydride Source		Org. Lett.	58	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
4721	10.1002/adsc.201901302	doi.org/10.1002/adsc.201901302	Palladium Catalyzed C-O Coupling of Amino Alcohols for the Synthesis of Aryl Ethers		Adv. Synth. Catal.	58	Larrow, JF	FALSE	FALSE	FALSE	FALSE
4722	10.1002/adsc.201901398	doi.org/10.1002/adsc.201901398	Palladium-Catalyzed Intramolecular Mizoroki-Heck-Type Reaction of Diarylmethyl Carbonates		Adv. Synth. Catal.	58	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
4723	10.1039/c9fd00051h	doi.org/10.1039/c9fd00051h	Suzuki-Miyaura coupling revisited: an integrated computational study		Faraday Discuss.	58	Harvey, JN	FALSE	FALSE	FALSE	FALSE
4724	10.1021/acs.orglett.9b02940	doi.org/10.1021/acs.orglett.9b02940	Enantioselective Conjugate Addition of Aryl Halides and Triflates to Electron-Deficient Olefins via Nickel- and Rhodium-Catalyzed Sequential Relay Reactions		Org. Lett.	58	Luo, YF; He, JB	FALSE	TRUE	FALSE	FALSE
4725	10.1021/acs.joc.9b02154	doi.org/10.1021/acs.joc.9b02154	Density Functional Theory Mechanistic Insight into the Base-Free Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Acid Fluoride: Concerted versus Stepwise Transmetalation		J. Org. Chem.	58	Wang, ZX	FALSE	FALSE	FALSE	FALSE
4726	10.1039/c9dt03201k	doi.org/10.1039/c9dt03201k	Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines		Dalton Trans.	58	Nicasio, MC	FALSE	FALSE	FALSE	FALSE
4727	10.1021/acs.orglett.9b02793	doi.org/10.1021/acs.orglett.9b02793	Iron-Catalyzed Coupling of Methyl N-Heteroarenes with Primary Alcohols: Direct Access to E-Selective Olefins		Org. Lett.	58	Banerjee, D	FALSE	FALSE	FALSE	FALSE
4728	10.1039/c9sc01083a	doi.org/10.1039/c9sc01083a	Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes		Chem. Sci.	58	Montgomery, J	FALSE	FALSE	FALSE	FALSE
4729	10.1021/acs.orglett.9b01164	doi.org/10.1021/acs.orglett.9b01164	Enones from Acid Fluorides and Vinyl Triflates by Reductive Nickel Catalysis		Org. Lett.	58	Shu, XZ	FALSE	FALSE	FALSE	FALSE
4730	10.1021/acs.joc.8b03267	doi.org/10.1021/acs.joc.8b03267	Ru(II)-Catalyzed C-H Activation/Alkylation of 3-Formylbenzofurans with Conjugated Olefins: Product Divergence		J. Org. Chem.	58	Ramana, CV	FALSE	FALSE	FALSE	FALSE
4731	10.1055/s-0037-1610356	doi.org/10.1055/s-0037-1610356	Practical Synthesis of Precursors of Cyclohexyne and 1,2-Cyclohexadiene		Synthesis	58	Okano, K	FALSE	FALSE	FALSE	FALSE
4732	10.1021/acs.joc.8b03170	doi.org/10.1021/acs.joc.8b03170	Organocatalytic C(sp(3))-H Functionalization of 5-Methyl-2,3-dihydrofuran Derivatives with Trifluoropyruvates via a Sequential exo-Tautomerization/Carbonyl-Ene Process		J. Org. Chem.	58	Hao, ZH; Xiao, J	FALSE	FALSE	FALSE	FALSE
4733	10.1021/acscatal.8b04348	doi.org/10.1021/acscatal.8b04348	Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Reductive C-F and C-O Bond Cleavage		ACS Catal.	58	Wang, C	FALSE	FALSE	FALSE	FALSE
4734	10.7536/PC180446	doi.org/10.7536/PC180446	Application of the Tianium, Nickel and Iron Complexes in the Hydrosilylation		Prog. Chem.	58	Bai, Y; Peng, JJ	FALSE	FALSE	FALSE	FALSE
4735	10.1016/j.tetlet.2018.08.015	doi.org/10.1016/j.tetlet.2018.08.015	Selective ruthenium-catalyzed double reductive aminations using hydrosilane to access tertiary amines and piperidine derivatives		Tetrahedron Lett.	58	Li, B; Jiang, SH	FALSE	FALSE	FALSE	FALSE
4736	10.1021/acs.orglett.8b02084	doi.org/10.1021/acs.orglett.8b02084	Asymmetric Synthesis of Remote Quaternary Centers by Copper-Catalyzed Desymmetrization: An Enantioselective Total Synthesis of (+)-Mesembrine		Org. Lett.	58	Jeon, J	FALSE	FALSE	FALSE	FALSE
4737	10.1021/acs.joc.8b01288	doi.org/10.1021/acs.joc.8b01288	Selective Long-Distance Isomerization of Terminal Alkenes via Nondissociative Chain Walking		J. Org. Chem.	58	Kochi, T	FALSE	FALSE	FALSE	FALSE
4738	10.1002/celc.201800407	doi.org/10.1002/celc.201800407	2-Electron Reduction of CO2 by Graphene Supported Ru Complexes - on the Role of Electron Donation		ChemElectroChem	58	Szyja, BM	FALSE	TRUE	FALSE	FALSE
4739	10.1021/acs.joc.7b03213	doi.org/10.1021/acs.joc.7b03213	Theoretical Insight into the Mechansim and Origin of Ligand-Controlled Regioselectivity in Homogenous Gold-Catalyzed Intramolecular Hydroarylation of Alkynes		J. Org. Chem.	58	Zhu, RX; Zhang, DJ	FALSE	FALSE	FALSE	FALSE
4740	10.1039/c7cc06717h	doi.org/10.1039/c7cc06717h	Efficient Ni-catalyzed conversion of phenols protected with 2,4,6-trichloro-1,3,5-triazine (TCT) to olefins		Chem. Commun.	58	Etemadi-Davan, E; Iranpoor, N	FALSE	FALSE	FALSE	FALSE
4741	10.1039/c6dt03235d	doi.org/10.1039/c6dt03235d	The selective activation of a C-F bond with an auxiliary strong Lewis acid: a method to change the activation preference of C-F and C-H bonds		Dalton Trans.	58	Li, XY	FALSE	FALSE	FALSE	FALSE
4742	10.1039/c6ra18997k	doi.org/10.1039/c6ra18997k	Direct C-H heteroarylation of azoles with 1,-2di(pyrimidin-2-yl)disulfides through C-S cleavage of disulfides		RSC Adv.	58	Quan, ZJ; Wang, XC	FALSE	FALSE	FALSE	FALSE
4743	10.1002/anie.201507373	doi.org/10.1002/anie.201507373	Enantioselective Copper(I)-Catalyzed Alkynylation of Oxocarbenium Ions to Set Diaryl Tetrasubstituted Stereocenters		Angew. Chem.-Int. Edit.	58	Watson, MP	FALSE	FALSE	FALSE	FALSE
4744	10.1021/acs.joc.5b01559	doi.org/10.1021/acs.joc.5b01559	Scholl Cyclizations of Aryl Naphthalenes: Rearrangement Precedes Cyclization		J. Org. Chem.	58	Johnson, RP	FALSE	FALSE	FALSE	FALSE
4745	10.1016/j.tetlet.2015.01.016	doi.org/10.1016/j.tetlet.2015.01.016	Synthesis of a polymerizable, bivalent glycan mimetic of the HIV envelope spike gp120		Tetrahedron Lett.	58	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
4746	10.1021/acs.orglett.5b00510	doi.org/10.1021/acs.orglett.5b00510	Palladium-Catalyzed Coupling of Azoles or Thiazoles with Aryl Thioethers via C-H/C-S Activation		Org. Lett.	58	Wang, ZX	FALSE	FALSE	FALSE	FALSE
4747	10.1055/s-0034-1378914	doi.org/10.1055/s-0034-1378914	Nickel-NHC-Catalyzed Cross-Coupling of 2-Methylsulfanylbenzofurans with Alkyl Grignard Reagents		Synlett	58	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
4748	10.1039/c5cc03314d	doi.org/10.1039/c5cc03314d	Copper(II)/amine synergistically catalyzed enantioselective alkylation of cyclic N-acyl hemiaminals with aldehydes		Chem. Commun.	58	Liu, L	FALSE	FALSE	FALSE	FALSE
4749	10.1039/c5ob00594a	doi.org/10.1039/c5ob00594a	Copper-free arylation of 3,3-disubstituted allylic halides with triazene-softened aryl Grignard reagents		Org. Biomol. Chem.	58	Ren, HJ	FALSE	FALSE	FALSE	FALSE
4750	10.1039/c5ra13708j	doi.org/10.1039/c5ra13708j	Metal-free C-N cross-coupling of electrophilic compounds and N-haloimides		RSC Adv.	58	Liang, FS	FALSE	FALSE	FALSE	FALSE
4751	10.1055/s-0034-1379025	doi.org/10.1055/s-0034-1379025	Synthesis of Aryl(di)azinylmethanes and Bis(di)azinylmethanes via Transition-Metal-Catalyzed Cross-Coupling Reactions		Synthesis	58	Maes, BUW	FALSE	FALSE	FALSE	FALSE
4752	10.1016/j.tetlet.2014.07.041	doi.org/10.1016/j.tetlet.2014.07.041	Highly selective synthesis of 1-polyfluoroaryl-1,2,3-triazoles via a one-pot three-component reaction		Tetrahedron Lett.	58	Zhang, B	FALSE	FALSE	FALSE	FALSE
4753	10.1039/c4ob01088d	doi.org/10.1039/c4ob01088d	Synthetic and mechanistic aspects of the regioselective base-mediated reaction of perfluoroalkyl- and perfluoroarylsilanes with heterocyclic N-oxides		Org. Biomol. Chem.	58	Larionov, OV	FALSE	FALSE	FALSE	FALSE
4754	10.1039/c4cc04111a	doi.org/10.1039/c4cc04111a	Synthesis of N-aryl substituted, five- and six-membered azacycles using aluminum-amide cornplexes		Chem. Commun.	58	Lee, SH	FALSE	FALSE	FALSE	FALSE
4755	10.1021/ja505776m	doi.org/10.1021/ja505776m	Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy		J. Am. Chem. Soc.	58	Bower, JF	FALSE	FALSE	FALSE	FALSE
4756	10.1021/ja503489b	doi.org/10.1021/ja503489b	Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp(2)) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics		J. Am. Chem. Soc.	58	Xie, ZW	FALSE	FALSE	FALSE	FALSE
4757	10.1055/s-0033-1340151	doi.org/10.1055/s-0033-1340151	Nickel-Catalyzed Cross-Electrophile Coupling of 2-Chloropyridines with Alkyl Bromides		Synlett	58	Weix, DJ	FALSE	TRUE	FALSE	FALSE
4758	10.1021/ja410704d	doi.org/10.1021/ja410704d	Nickel-Catalyzed Regiodivergent Opening of Epoxides with Aryl Halides: Co-Catalysis Controls Regioselectivity		J. Am. Chem. Soc.	58	Weix, DJ	FALSE	FALSE	FALSE	FALSE
4759	10.1021/jo402386k	doi.org/10.1021/jo402386k	Platinum(II)-Catalyzed Asymmetric Ring-Opening Addition of Arylboronic Acids to Oxabenzonorbornadienes		J. Org. Chem.	58	Yang, DQ	FALSE	FALSE	FALSE	FALSE
4760	10.1039/c4dt00461b	doi.org/10.1039/c4dt00461b	[CNN]-pincer nickel(II) complexes of N-heterocyclic carbene (NHC): synthesis and catalysis of the Kumada reaction of unactivated C-Cl bonds		Dalton Trans.	58	Sun, HJ	FALSE	FALSE	FALSE	FALSE
4761	10.1021/ja403340r	doi.org/10.1021/ja403340r	Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-Transfer Conditions		J. Am. Chem. Soc.	58	Maruoka, K	FALSE	FALSE	FALSE	FALSE
4762	10.1007/s11426-012-4795-3	doi.org/10.1007/s11426-012-4795-3	Mechanistic study of copper-catalyzed intramolecular ortho-C-H activation/carbon-nitrogen and carbon-oxygen cyclizations		Sci. China-Chem.	58	Fu, Y	FALSE	FALSE	FALSE	FALSE
4763	10.1002/chem.201203694	doi.org/10.1002/chem.201203694	Visible-Light Photocatalytic Radical Alkenylation of -Carbonyl Alkyl Bromides and Benzyl Bromides		Chem.-Eur. J.	58	Lei, AW	TRUE	FALSE	FALSE	FALSE
4764	10.1002/ejoc.201201061	doi.org/10.1002/ejoc.201201061	A Microwave-Assisted Domino Benzannulation Reaction towards Functionalized Naphthalenes, Quinolines, and Isoquinolines		Eur. J. Org. Chem.	58	Yang, CH	FALSE	FALSE	FALSE	FALSE
4765	10.1021/ol3011198	doi.org/10.1021/ol3011198	Ketone Formation via Mild Nickel-Catalyzed Reductive Coupling of Alkyl Halides with Aryl Acid Chlorides		Org. Lett.	58	Ren, QH	FALSE	FALSE	FALSE	FALSE
4766	10.2174/138527212800672646	doi.org/10.2174/138527212800672646	Iron Nanoparticles-Catalyzed Electrophilic Amination of Functionalized Organocopper and Organozinc Reagents		Curr. Org. Chem.	58	Ranu, BC	FALSE	TRUE	FALSE	FALSE
4767	10.1021/ol301275u	doi.org/10.1021/ol301275u	Cine Substitution of Arenes Using the Aryl Carbamate as a Removable Directing Group		Org. Lett.	58	Garg, NK	FALSE	FALSE	FALSE	FALSE
4768	10.1021/jo300290v	doi.org/10.1021/jo300290v	Probing for a Leaving Group Effect on the Generation and Reactivity of Phenyl Cations		J. Org. Chem.	58	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
4769	10.1002/cctc.201100083	doi.org/10.1002/cctc.201100083	Nickel-Catalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride (Lithium Triethylborohydride)		ChemCatChem	58	Cao, S	FALSE	FALSE	FALSE	FALSE
4770	10.1016/j.tet.2011.05.020	doi.org/10.1016/j.tet.2011.05.020	Studies for the enantiocontrolled preparation of substituted tetrahydropyrans: applications for the synthesis of leucascandrolide A macrolactone		Tetrahedron	58	Williams, DR	FALSE	FALSE	FALSE	FALSE
4771	10.1039/c1dt00013f	doi.org/10.1039/c1dt00013f	Relationship between electrochemical potentials and substitution reaction rates of ferrocene-containing beta-diketonato rhodium(I) complexes; Cytotoxicity of [Rh(FcCOCHCOPh)(cod)]		Dalton Trans.	58	Swarts, JC	FALSE	FALSE	FALSE	FALSE
4772	10.1002/anie.201103581	doi.org/10.1002/anie.201103581	Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates		Angew. Chem.-Int. Edit.	58	Shintani, R	FALSE	FALSE	FALSE	FALSE
4773	10.1002/ejoc.201001242	doi.org/10.1002/ejoc.201001242	Conversion of Dibenzoxaphosphinines into 2-Hydroxybiphenyl-2 '-ylphosphane Ligands and Their BH3 Adducts: The O-H delta+center dot center dot center dot H delta--B Hydrogen-Hydrogen Bond		Eur. J. Org. Chem.	58	Heinicke, JW	FALSE	FALSE	FALSE	FALSE
4774	10.1055/s-0030-1259038	doi.org/10.1055/s-0030-1259038	Gold-Catalyzed Stereoselective Synthesis of Di- or Trisubstituted Olefins Possessing a 1,4-Diene Framework via Intramolecular Allylation of Alkynes		Synlett	58	Horino, Y	FALSE	FALSE	FALSE	FALSE
4775	10.1002/aoc.1667	doi.org/10.1002/aoc.1667	Ni(OAc)(2): a highly efficient catalyst for the synthesis of enaminone and enamino ester derivatives under solvent-free conditions		Appl. Organomet. Chem.	58	Liu, JY	FALSE	FALSE	FALSE	FALSE
4776	10.1002/anie.200901879	doi.org/10.1002/anie.200901879	A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents		Angew. Chem.-Int. Edit.	58	Lin, ZY	FALSE	FALSE	FALSE	FALSE
4777	10.1021/ja803783c	doi.org/10.1021/ja803783c	Control of vertex geometry, structure dimensionality, functionality, and pore metrics in the reticular synthesis of crystalline metal-organic frameworks and polyhedra		J. Am. Chem. Soc.	58	Furukawa, H	FALSE	FALSE	FALSE	FALSE
4778	10.1071/CH08095	doi.org/10.1071/CH08095	Palladium-catalyzed cyanation of aryl perfluorooctylsulfonates		Aust. J. Chem.	58	Cai, C	FALSE	FALSE	FALSE	FALSE
4779	10.1039/b618617c	doi.org/10.1039/b618617c	Iron-catalyzed aryl-aryl cross-coupling reaction tolerating amides and unprotected quinolinones		Chem. Commun.	58	Knochel, P	FALSE	FALSE	FALSE	FALSE
4780	10.1002/adsc.200404187	doi.org/10.1002/adsc.200404187	Palladium-catalyzed cross-coupling reaction by means of organogermanium trichlorides		Adv. Synth. Catal.	58	Enokido, T	FALSE	FALSE	FALSE	FALSE
4781	10.1016/j.molcata.2003.11.030	doi.org/10.1016/j.molcata.2003.11.030	N-donor complexes of palladium as catalysts for Suzuki cross-coupling reactions in ionic liquids		J. Mol. Catal. A-Chem.	58	Welton, T	FALSE	FALSE	FALSE	FALSE
4782	10.1002/chem.200204506	doi.org/10.1002/chem.200204506	Regio- and stereoselective reductive coupling of bicyclic alkenes with propiolates catalyzed by nickel complexes: A novel route to functionalized 1,2-dihydroarenes and gamma-lactones		Chem.-Eur. J.	58	Cheng, CH	FALSE	FALSE	FALSE	FALSE
4783	10.1021/jo0207473	doi.org/10.1021/jo0207473	Palladium-catalyzed tetrakis(dimethylamino)ethylene-promoted reductive coupling of aryl halides		J. Org. Chem.	58	Tanaka, H	FALSE	FALSE	FALSE	FALSE
4784	10.3891/acta.chem.scand.47-0196	doi.org/10.3891/acta.chem.scand.47-0196	SYNTHESIS OF OPTICALLY-ACTIVE A-RING FRAGMENTS OF TAXOL VIA ELECTROPHILIC RING-CLOSURE OF AN EPOXY-ALLYLSILANE		Acta Chem. Scand.	58		FALSE	FALSE	FALSE	FALSE
4785	10.1021/ar00136a003	doi.org/10.1021/ar00136a003	NEW SYNTHETIC REACTIONS OF ALLYL ALKYL CARBONATES, ALLYL BETA-KETO CARboxYLATES, AND ALLYL VINYLIC CARBONATES CATALYZED BY PALLADIUM COMPLEXES		Accounts Chem. Res.	58	TSUJI, J	FALSE	FALSE	FALSE	FALSE
4786	10.1021/acscatal.1c00247	doi.org/10.1021/acscatal.1c00247	Unraveling the Mechanism of Palladium-Catalyzed Base-Free Cross-Coupling of Vinyl Carboxylates: Dual Role of Arylboronic Acids as a Reducing Agent and a Coupling Partner		ACS Catal.	58	Wang, XT	FALSE	FALSE	FALSE	FALSE
4787	10.1039/d1ob02360h	doi.org/10.1039/d1ob02360h	Pd-Catalyzed desulfitative arylation of olefins by N-methoxysulfonamide		Org. Biomol. Chem.	58	Panda, N	FALSE	FALSE	FALSE	FALSE
4788	10.1021/acs.orglett.1c03172	doi.org/10.1021/acs.orglett.1c03172	Copper-Catalyzed Methoxylation of Aryl Bromides with 9-BBN-OMe		Org. Lett.	58	Li, C	FALSE	FALSE	FALSE	FALSE
4789	10.1021/acs.joc.1c01467	doi.org/10.1021/acs.joc.1c01467	Metal-Free Synthesis of Heteroaryl Amines or Their Hydrochlorides via an External-Base-Free and Solvent-Free C-N Coupling Protocol		J. Org. Chem.	58	Chen, C; Verpoort, F	FALSE	FALSE	FALSE	FALSE
4790	10.1021/acs.inorgchem.1c02017	doi.org/10.1021/acs.inorgchem.1c02017	Heterogenizing a Homogeneous Nickel Catalyst Using Nanoconfined Strategy for Selective Synthesis of Mono- and 1,2-Disubstituted Benzimidazoles		Inorg. Chem.	58	Aijaz, A	FALSE	FALSE	FALSE	FALSE
4791	10.1055/a-1637-9308	doi.org/10.1055/a-1637-9308	Nickel Hydride Catalyzed Remote Hydroarylation of Olefins		Synlett	58	Zhu, SL	FALSE	FALSE	FALSE	FALSE
4792	10.1055/a-1608-5693	doi.org/10.1055/a-1608-5693	Bathocuproine-Enabled Nickel-Catalyzed Selective Ullmann Cross-Coupling of Two sp(2)-Hybridized Organohalides		Synlett	58	Li, YQ	FALSE	FALSE	FALSE	FALSE
4793	10.1039/d1cc03261e	doi.org/10.1039/d1cc03261e	Carbolong chemistry: nucleophilic aromatic substitution of a triflate functionalized iridapentalene		Chem. Commun.	58	Chen, DF; Xia, HP	FALSE	FALSE	FALSE	FALSE
4794	10.1038/s41467-021-24908-w	doi.org/10.1038/s41467-021-24908-w	Site-specific Umpolung amidation of carboxylic acids via triplet synergistic catalysis		Nat. Commun.	58	Xie, J	FALSE	FALSE	FALSE	FALSE
4795	10.1016/j.tet.2021.132152	doi.org/10.1016/j.tet.2021.132152	A general copper-catalyzed radical C(sp(3))-C(sp(2)) cross-coupling to access 1,1-diarylalkanes under ambient conditions		Tetrahedron	58	Liu, XY	FALSE	FALSE	FALSE	FALSE
4796	10.1080/00397911.2021.1919711	doi.org/10.1080/00397911.2021.1919711	N-Heterocyclic carbene palladium (II)-pyridine (NHC-Pd (II)-Py) complex catalyzed heck reactions		Synth. Commun.	58	Yuan, JY	FALSE	FALSE	FALSE	FALSE
4797	10.1039/d1sc00283j	doi.org/10.1039/d1sc00283j	Nickel-catalyzed asymmetric reductive arylation of alpha-chlorosulfones with aryl halides		Chem. Sci.	58	Lei, CH; Gong, HG	FALSE	FALSE	FALSE	FALSE
4798	10.1039/d1qo00148e	doi.org/10.1039/d1qo00148e	K2S2O8 promoted dehydrative cross-coupling between alpha,alpha-disubstituted allylic alcohols and thiophenols/thiols		Org. Chem. Front.	58	Yuan, Y; Huo, CD	FALSE	FALSE	FALSE	FALSE
4799	10.1021/acs.accounts.0c00770	doi.org/10.1021/acs.accounts.0c00770	Predicting Reaction Yields via Supervised Learning		Accounts Chem. Res.	58	Doyle, AG	FALSE	FALSE	FALSE	FALSE
4800	10.1039/d1cc00181g	doi.org/10.1039/d1cc00181g	Manganese catalyzed C-alkylation of methyl N-heteroarenes with primary alcohols		Chem. Commun.	58	Maji, B	FALSE	FALSE	FALSE	FALSE
4801	10.1021/acs.joc.7b01334	doi.org/10.1021/acs.joc.7b01334	Coupling of Challenging Heteroaryl Halides with Alkyl Halides via Nickel-Catalyzed Cross-Electrophile Coupling		J. Org. Chem.	58	Hansen, EC	FALSE	TRUE	FALSE	FALSE
4802	10.6023/cjoc201610034	doi.org/10.6023/cjoc201610034	Progress in Late Transition Metal-Catalyzed N-Alkylation of Amines with Alcohols		Chin. J. Org. Chem.	58	Du, ZY	FALSE	FALSE	FALSE	FALSE
4803	10.1021/acs.orglett.7b00820	doi.org/10.1021/acs.orglett.7b00820	Synthesis of Dihydropyridinone-Fused Indoles and alpha-Carbolines via N-Heterocyclic Carbene-Catalyzed [3+3] Annulation of Indolin-2-imines and Bromoenals		Org. Lett.	58	Ye, S	FALSE	FALSE	FALSE	FALSE
4804	10.1021/acs.joc.7b00209	doi.org/10.1021/acs.joc.7b00209	[4+2] Annulation of Donor-Acceptor Cyclopropanes with Acetylenes Using 1,2-Zwitterionic Reactivity		J. Org. Chem.	58	Tomilov, YV	FALSE	FALSE	FALSE	FALSE
4805	10.1021/acs.joc.6b02830	doi.org/10.1021/acs.joc.6b02830	Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl-Alkyl Cross-Couplings		J. Org. Chem.	58	Vannucci, AK	TRUE	FALSE	FALSE	FALSE
4806	10.1002/anie.201609635	doi.org/10.1002/anie.201609635	Rapid Room-Temperature, Chemoselective C-sp2-C-sp2 Coupling of Poly(pseudo)halogenated Arenes Enabled by Palladium(I) Catalysis in Air		Angew. Chem.-Int. Edit.	58	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
4807	10.1002/slct.201601747	doi.org/10.1002/slct.201601747	Supramolecular Ensemble of Aggregates of Pentacenequinone Derivative and Cadmium NPs: A Potential Catalytic/Photocatalytic System for Direct C-H Activation of Quinones and Azoles		ChemistrySelect	58	Bhalla, V	TRUE	FALSE	FALSE	FALSE
4808	10.1021/jacs.6b11205	doi.org/10.1021/jacs.6b11205	F- Nucleophilic-Addition-Induced Allylic Alkylation		J. Am. Chem. Soc.	58	Feng, C	FALSE	FALSE	FALSE	FALSE
4809	10.1002/aoc.3527	doi.org/10.1002/aoc.3527	Nickel-catalyzed Buchwald-Hartwig amination of pyrimidin-2-yl tosylates with indole, benzimidazole and 1,2,4-triazole		Appl. Organomet. Chem.	58	Quan, ZJ; Wang, XC	FALSE	FALSE	FALSE	FALSE
4810	10.1021/acs.orglett.6b02631	doi.org/10.1021/acs.orglett.6b02631	Inherent vs Apparent Chemoselectivity in the Kumada-Corriu Cross-Coupling Reaction		Org. Lett.	58	Newman, SG	FALSE	FALSE	FALSE	FALSE
4811	10.1055/s-0035-1562777	doi.org/10.1055/s-0035-1562777	Catalytic Metal-Free Intramolecular Acylcyanation: Synthesis of Functionalized Pyridine Derivatives Bearing Pendent Stereocenters		Synthesis	58	Wang, HJ; Liao, WW	FALSE	FALSE	FALSE	FALSE
4812	10.1021/jacs.6b07396	doi.org/10.1021/jacs.6b07396	Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates		J. Am. Chem. Soc.	58	Watson, MP	FALSE	FALSE	FALSE	FALSE
4813	10.1021/acs.orglett.6b01675	doi.org/10.1021/acs.orglett.6b01675	Arylboration of 1-Arylalkenes by Cooperative Nickel/Copper Catalysis		Org. Lett.	58	Semba, K; Nakao, Y	FALSE	FALSE	FALSE	FALSE
4814	10.1021/acs.organomet.6b00154	doi.org/10.1021/acs.organomet.6b00154	Preparation of a Highly Congested Carbazoyl-Derived P,N-Type Phosphine Ligand for Acetone Monoarylations		Organometallics	58	Kwong, FY	FALSE	FALSE	FALSE	FALSE
4815	10.1021/acs.joc.6b00421	doi.org/10.1021/acs.joc.6b00421	Palladium-Catalyzed Room-Temperature Acylative Suzuki Coupling of High-Order Aryl Borons with Carboxylic Acids		J. Org. Chem.	58	Zou, G	FALSE	FALSE	FALSE	FALSE
4816	10.1016/j.jorganchem.2016.02.018	doi.org/10.1016/j.jorganchem.2016.02.018	Synthesis of inexpensive chiral half-sandwich nickel N-heterocyclic carbene complexes: X-ray diffraction study of the D-menthyl-functionalized complex [Ni(iPr(2)Ph-NHC-CH(2)OMent)ClCp]		J. Organomet. Chem.	58	Ritleng, V; Chetcuti, MJ	FALSE	FALSE	FALSE	FALSE
4817	10.3987/COM-15-13402	doi.org/10.3987/COM-15-13402	A NOVEL SOLID-PHASE SYNTHESIS OF 2H-CHROMENES		Heterocycles	58	Tang, E	FALSE	FALSE	FALSE	FALSE
4818	10.1055/s-0040-1706013	doi.org/10.1055/s-0040-1706013	Nickel-Catalyzed Cross-Electrophile Coupling of the Difluoromethyl Group for Fluorinated Cyclopropane Synthesis	Reaction of aryl 2-pyridyl ethers with amines was carried out via Ni-catalyzed C-O-Py bond cleavage, giving aniline derivatives in reasonable to excellent yields. Both electron-rich and electron-poor aryl 2-pyridyl ethers and a wide range of amines can be used in the transformation. The method provides a conversion way for the 2-pyridyloxy directing group in the C-H bond functionalization reactions.	Synlett	57	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
4819	10.1021/jacs.0c12843	doi.org/10.1021/jacs.0c12843	Synthesis of Axially Chiral 2,2 '-Bisphosphobiarenes via a Nickel-Catalyzed Asymmetric Ullmann Coupling: General Access to Privileged Chiral Ligands without Optical Resolution	A highly efficient, one-pot, and catalyst-free approach for fast synthesis of an array of alpha-ketoamides starting from easily obtainable alpha-oxocarboxylic acids and primary-/secondary-amines has been developed via insitu activation of acids using stoichiometric 2,4,6-trichloro-1,3,5-trizaine at room temperature, reactions could proceed smoothly to provide the corresponding alpha-ketoamides in good to excellent yields of up to 99%.	J. Am. Chem. Soc.	57	Watson, DA	FALSE	FALSE	FALSE	FALSE
4820	10.1039/d0qo01171a	doi.org/10.1039/d0qo01171a	Ruthenium catalyzed alpha-methylation of sulfones with methanol as a sustainable C1 source	The development of new methodologies to affect non-ortho-functionalization of arenes has emerged as a globally important arena for research, which is key to both fundamental studies and applied technologies. A range of simple arene feedstocks (namely, biphenyl, meta-terphenyl, para-terphenyl, 1,3,5-triphenylbenzene, and biphenylene) is transformed to hitherto unobtainable multi-iodoarenes via an s-block metal sodium magnesiate templated deprotonative approach. These iodoarenes have the potential to be used in a whole host of high-impact transformations, as precursors to key materials in the pharmaceutical, molecular electronic, and nanomaterials industries. To prove the concept, we transformed biphenyl to 3,5-bis(N-carbazolyl)-1,1'-biphenyl, a novel isomer of 4,4'-bis(N-carbazolyl)-1,1'- biphenyl (CPB), a compound which is currently widely used as a host material for organic light-emitting diodes.	Org. Chem. Front.	57	Ling, F; Zhong, WH	FALSE	FALSE	FALSE	FALSE
4821	10.1016/j.tetlet.2020.152532	doi.org/10.1016/j.tetlet.2020.152532	Selective transition metal-free aroylation of diarylmethanes with 2-acyl-imidazolium salts via acyl C-C bond cleavage	Esters are one of the most common functional groups in natural and synthetic products, and the one-step conversion of the ester group into other functional groups is an attractive strategy in organic synthesis. Direct amidation of esters is particularly appealing due to the omnipresence of the amide moiety in biomolecules, fine chemicals, and drug candidates. However, efficient methods for direct amidation of unactivated esters are still lacking. Here we report nickel-catalysed reductive coupling of unactivated esters with nitroarenes to furnish in one step a wide range of amides bearing functional groups relevant to the development of drugs and agrochemicals. The method has been used to expedite the syntheses of bio-active molecules and natural products, as well as their post-synthetic modifications. Preliminary mechanistic study indicates a reaction pathway distinct from conventional amidation methods using anilines as nitrogen sources. The work provides a novel and efficient method for amide synthesis.	Tetrahedron Lett.	57	Li, J	FALSE	FALSE	FALSE	FALSE
4822	10.1021/acs.joc.0c01254	doi.org/10.1021/acs.joc.0c01254	Room-Temperature Negishi Reaction of Trisubstituted Vinyl Phosphates for the Synthesis of Tetrasubstituted Alkenes	The stereospecific reductive cross-electrophile coupling reaction of 2-vinyl-4-halotetrahydropyrans for vinylcyclopropane synthesis is reported. The nickel-catalyzed reaction occurs with both alkyl fluorides and alkyl chlorides. To the best of our knowledge, this is the first reported cross-electrophile coupling reaction of an alkyl fluoride. Ring contraction proceeds with high stereospecificity, providing selective synthesis of either diastereomer of di- and trisubstituted cyclopropanes. The utility of this methodology is demonstrated by several synthetic applications including the synthesis of the natural product dictyopterene A. 2-Vinyl-4-fluorotetrahydrofurans also undergo stereospecific ring contractions, providing access to synthetically useful hydroxymethyl cyclopropanes.	J. Org. Chem.	57	Tobrman, T	FALSE	FALSE	FALSE	FALSE
4823	10.1021/acs.orglett.0c01905	doi.org/10.1021/acs.orglett.0c01905	Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine	Palladium-catalysed coupling reactions based on a novel and easy-to-synthesise difluorinated organotrifluoroborate were used to assemble precursors to 6p-electrocyclisations of three different types. Electrocyclisations took place at temperatures between 90 and 240 degrees C, depending on the central component of the pi-system; nonaromatic trienes were most reactive, but even systems that required the temporary dearomatisation of two arenyl subunits underwent electrocyclisation, albeit at elevated temperatures. Photochemical conditions were effective for these more demanding reactions. The package of methods delivered a structurally diverse set of fluorinated arenes, spanning a 20 kcalmol(-1) range of reactivity, by a flexible route.	Org. Lett.	57	Iwai, T; Sawamura, M	FALSE	FALSE	TRUE	TRUE
4824	10.1126/science.aba3823	doi.org/10.1126/science.aba3823	Microfluidic electrochemistry for single-electron transfer redox-neutral reactions	Pillar[5]arene-based 1-benzylimidazole and 1-(9-anthracenylmethyl)imidazole salts were prepared for the first time as novel class supramolecular NHC ligands. These ligands, together with PdCl2(CH3CN)(2), were used as catalysts in the Heck coupling reactions of styrene and aryl halide derivatives. The 1-(9-anthracenylmethyl)imidazole salt exhibited better catalytic activity than the 1-benzylimidazole salt, owing to the steric bulk of the ligand. The novel pillar[5]arene-based imidazolium salt is a promising supramolecular skeleton for the construction of highly active catalysts. (C) 2016 Elsevier Ltd. All rights reserved.	Science	57	Jensen, KF	FALSE	FALSE	FALSE	FALSE
4825	10.1021/acscatal.0c01470	doi.org/10.1021/acscatal.0c01470	Diastereoselective sp(3) C-O Bond Formation via Visible Light-Induced, Copper-Catalyzed Cross-Couplings of Glycosyl Bromides with Aliphatic Alcohols	A practical and scalable nickel-catalyzed allylic stannylation of allyl acetates with Bu3SnOMe is described. A variety of acyclic and cyclic allyl acetates, even with base-sensitive moieties, undergoes the stannylation by using NiBr2/4,4'-di-tert-butylbipyridine (dtbpy)/Mn catalyst system to afford highly functionalized allyl stannanes with excellent regioselectivity and yields. Furthermore, the scope of protocol is also extended by the reaction of propargyl acetates, giving rise to propargyl or allenyl stannanes. Additionally, a unique diastereoselectivity using the nickel catalyst different from the palladium was demonstrated for the stannylation of cyclic allyl acetates. In the reaction, inexpensive and stable nickel complexes, abundant reductant (Mn), and atom-economical stannyl source were used.	ACS Catal.	57	Luo, L; Nguyen, E	FALSE	FALSE	FALSE	FALSE
4826	10.1016/j.jorganchem.2020.121199	doi.org/10.1016/j.jorganchem.2020.121199	Diastereomeric P*,N,S-tridentate diamidophosphites with a ferrocene moiety in asymmetric palladium catalysis	We describe here an efficient route for the synthesis of (Z)-vinylic sulfides 3 via the highly regio- and stereoselective coupling of (Z)-1,2-bis(aryl(alkyl)thio)alkenes and Grignard reagents over a Ni catalyst under mild conditions. (Z)-Vinylic sulfides 3 are important intermediates in the synthesis of tri- and tetrasubstituted alkenes that are important construction blocks for drugs and natural products. The directing organosulfur groups (SR) can be converted to diaryl(alkyl) disulfides (RSSR) using H2O2 as oxidant, hence avoiding the waste of sulfur resources. The protocol provides a general method that is highly regio- and stereoselective for the synthesis of a diversity of tri- and tetrasubstituted alkenes.	J. Organomet. Chem.	57	Gavrilov, KN	FALSE	FALSE	FALSE	FALSE
4827	10.1021/acs.joc.0c00009	doi.org/10.1021/acs.joc.0c00009	Nickel-Catalyzed Intramolecular Desulfitative C-N Coupling: A Synthesis of Aromatic Amines	The hydroxyl groups of naphthol and tauto-merizable phenol derivatives have been substituted by O-, S-, N-, and C-centered nucleophiles under solvent-free reaction conditions. The products are generated in good to excellent yields. para-Toluenesulfonic acid exhibits the best catalytic activity compared to other Bronsted acids. Experimental observations suggest that the reaction proceeds through the intermediacy of the keto tautomer of naphthol. Nucleophilic addition to the carbonyl group followed by elimination of water generates the desired product. The present methodology provides access to substituted naphtho[2,1-b]furan derivatives. The products generated using N-centered nucleophiles can be further transformed to important classes of organic molecules such as benzocarbazole and imidazole derivatives.	J. Org. Chem.	57	Lian, Z	FALSE	FALSE	FALSE	FALSE
4828	10.1002/ejic.202000150	doi.org/10.1002/ejic.202000150	Perfluoropyridine as an Efficient, Tunable Scaffold for Bis(pyrazol-1-yl)pyridine Copper Complexes	Efficient Ni-catalyzed direct cross-couplings of benzylic alcohol derivatives with arylacetonitriles via C-O activation are described. Various alpha-benzylated arylacetonitriles including those with functional groups can be prepared under mild reaction conditions.	Eur. J. Inorg. Chem.	57	Pennington, WT	FALSE	FALSE	FALSE	FALSE
4829	10.1002/anie.202002392	doi.org/10.1002/anie.202002392	Nickel-Catalyzed Cross-Coupling of Sulfonamides With (Hetero)aryl Chlorides	The preparation of functionalized 1,1-dibromoalkenyl phosphates is described. The protocol developed for their preparation is based on the generation of enolates from alpha,alpha-dibromoketones followed by a reaction with dialkyl chlorophosphates. The procedure tolerates various functional groups including ester, ketone, and nitrile, and the yields are generally high. [GRAPHICS] .	Angew. Chem.-Int. Edit.	57	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
4830	10.1039/d0ob00110d	doi.org/10.1039/d0ob00110d	Synthesis and antiproliferative activity of 6-naphthylpterocarpans	Herein, we report the synthesis of polyfunctional BODIPY building blocks suitable to be subjected to several reaction sequences with complete chemoselectivity, thereby allowing the preparation of complex BODIPY derivatives in a versatile and programmable manner. The reactions included the Liebeskind-Srogl cross-coupling reaction (LSCC), nucleophilic aromatic substitution (SNAr), Suzuki, Sonogashira, and Stille couplings, and a desulfitative reduction of the MeS group. This novel synthetic protocol is a powerful route to design a library of compounds with tailored photophysical properties for advanced applications. In this context, it is noteworthy that it offers a straightforward and cost-effective strategy to shift the BODIPY emission deep into the near-infrared spectral region while retaining high fluorescence quantum yields as well as highly efficient and stable laser action. These new dyes outperform the lasing behaviour of dyes considered as benchmarks over the red spectral region, overcoming the important drawbacks associated with these commercial laser dyes, namely low absorption at the standard pump wavelengths (355 and 532 nm) and/or poor photostability.	Org. Biomol. Chem.	57	Mandi, A; Kurtan, T	FALSE	FALSE	FALSE	FALSE
4831	10.1021/acs.orglett.0c00465	doi.org/10.1021/acs.orglett.0c00465	Nickel-Catalyzed Asymmetric Friedel-Crafts Propargylation of 3-Substituted Indoles with Propargylic Carbonates Bearing an Internal Alkyne Group	Background: Substituted-silyl thiophene carboxylates are important intermediates for the synthesis of substituted-silyl thiophene carboxamides which have been found to show high biological activities. Methods: Using alpha-mercapto ketones and 3-(substituted-silyl) propiolates as raw materials, 2-(substituted-silyl) thiophene-3-carboxylates could be synthesized smoothly via cycloaddition reaction catalyzed by potassium tert-butoxide. Results: A small library of target compounds was prepared under optimized reaction conditions in moderate to good yields. The reaction mechanism has been proposed. Conclusion: Potassium tert-butoxide is an environmentally friendly and efficient catalyst for the cycloaddition reaction of alpha-mercapto ketones and 3-(substituted-silyl) propiolates. This methodology provides ready access to 2-(substituted-silyl) thiophene-3-carboxylic acids which can be serve as the raw materials of 2-(substituted-silyl) thiophene-3-carboxamide and other pharmaceutically intriguing compounds.	Org. Lett.	57	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
4832	10.1039/c9qo01095e	doi.org/10.1039/c9qo01095e	C-F bond arylation of fluoroarenes catalyzed by Pd-0 phosphine complexes: theoretical insight into regioselectivity, reactivity, and prediction of ligands		Org. Chem. Front.	57	Zhong, RL	FALSE	FALSE	FALSE	FALSE
4833	10.1021/acs.joc.9b02282	doi.org/10.1021/acs.joc.9b02282	Chiral alpha-Amino Acid/Palladium-Catalyzed Asymmetric Allylation of alpha-Branched beta-Ketoesters with Allylic Amines: Highly Enantioselective Construction of All-Carbon Quaternary Stereocenters		J. Org. Chem.	57	Tian, SK	FALSE	FALSE	FALSE	FALSE
4834	10.1002/jcc.26099	doi.org/10.1002/jcc.26099	Mechanistic Study of Unprecedented Highly Regioselective Hydrocyanation of Terminal Alkynes: Insight into the Origins of the Regioselectivity and Ligand Effects		J. Comput. Chem.	57	Yang, YH; Zhao, LL	FALSE	FALSE	FALSE	FALSE
4835	10.1021/jacs.9b07489	doi.org/10.1021/jacs.9b07489	Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins		J. Am. Chem. Soc.	57	Martin, R	FALSE	FALSE	FALSE	FALSE
4836	10.1002/advs.201901551	doi.org/10.1002/advs.201901551	DNA-Encoded Libraries: Aryl Fluorosulfonates as Versatile Electrophiles Enabling Facile On-DNA Suzuki, Sonogashira, and Buchwald Reactions		Adv. Sci.	57	Yang, G	FALSE	TRUE	FALSE	FALSE
4837	10.1039/c9cc04795f	doi.org/10.1039/c9cc04795f	Pd-Catalyzed decarboxylative cross-coupling reactions of epoxides with alpha,beta-unsaturated carboxylic acids		Chem. Commun.	57	Lu, XY	FALSE	FALSE	FALSE	FALSE
4838	10.1002/ejoc.201900566	doi.org/10.1002/ejoc.201900566	Nucleophile Screening in Anion-Binding Reissert-Type Reactions of Quinolines with Chiral Tetrakis(triazole) Catalysts		Eur. J. Org. Chem.	57	Mancheno, OG	FALSE	FALSE	FALSE	FALSE
4839	10.1002/aoc.5192	doi.org/10.1002/aoc.5192	Nickel-Catalyzed Decarboxylative C-Si Bond Formation: A Regioselective Cross-Coupling Between Trialkyl Silanes and alpha,beta-Unsaturated Carboxylic Acids		Appl. Organomet. Chem.	57	Kandasamy, J	FALSE	FALSE	FALSE	FALSE
4840	10.1002/anie.201906000	doi.org/10.1002/anie.201906000	Ketones from Nickel-Catalyzed Decarboxylative, Non-Symmetric Cross-Electrophile Coupling of Carboxylic Acid Esters		Angew. Chem.-Int. Edit.	57	Weix, DJ	FALSE	TRUE	FALSE	FALSE
4841	10.1021/jacs.9b04551	doi.org/10.1021/jacs.9b04551	Catalytic Enantioselective Pinacol and Meinwald Rearrangements for the Construction of Quaternary Stereocenters		J. Am. Chem. Soc.	57	Zhu, JP	FALSE	FALSE	FALSE	FALSE
4842	10.1002/ejoc.201900844	doi.org/10.1002/ejoc.201900844	SO2F2-Activated Efficient Beckmann Rearrangement of Ketoximes for Accessing Amides and Lactams		Eur. J. Org. Chem.	57	Ding, CR	FALSE	FALSE	FALSE	FALSE
4843	10.1039/c9cc03737c	doi.org/10.1039/c9cc03737c	Nickel-catalyzed monofluoromethylation of (hetero)aryl bromides via reductive cross-coupling		Chem. Commun.	57	Wang, XS	FALSE	FALSE	FALSE	FALSE
4844	10.1021/acs.orglett.9b01120	doi.org/10.1021/acs.orglett.9b01120	Nickel-Catalyzed 1,2-Arylboration of Vinylarenes		Org. Lett.	57	Yin, GY	FALSE	FALSE	FALSE	FALSE
4845	10.1039/c9cc02989c	doi.org/10.1039/c9cc02989c	Room temperature N-heterocyclic carbene manganese catalyzed selective N-alkylation of anilines with alcohols		Chem. Commun.	57	Ke, ZF	FALSE	FALSE	FALSE	FALSE
4846	10.1002/aoc.4914	doi.org/10.1002/aoc.4914	Palladium-catalyzed decarboxylative coupling of ,-unsaturated carboxylic acids with aryl tosylates		Appl. Organomet. Chem.	57	Zhang, W	FALSE	FALSE	FALSE	FALSE
4847	10.1039/c9dt00450e	doi.org/10.1039/c9dt00450e	DFT studies on mechanistic origins of ligand-controlled selectivity in Pd-catalyzed non-decarbonylative and decarbonylative reductive conversion of acyl fluoride		Dalton Trans.	57	Xie, HJ	FALSE	FALSE	FALSE	FALSE
4848	10.1039/c8ob02977f	doi.org/10.1039/c8ob02977f	An atom efficient synthesis of tamoxifen		Org. Biomol. Chem.	57	Feringa, BL	FALSE	FALSE	FALSE	FALSE
4849	10.1016/j.tetlet.2018.12.022	doi.org/10.1016/j.tetlet.2018.12.022	Acid-promoted cyclization of 2-propynolphenols leading to 4-tosyloxy-2H-chromenes		Tetrahedron Lett.	57	Xiao, Q	FALSE	FALSE	FALSE	FALSE
4850	10.1039/c8nj04157a	doi.org/10.1039/c8nj04157a	Synthesis, characterization and first application of covalently immobilized nickel-porphyrin on graphene oxide for Suzuki cross-coupling reaction		New J. Chem.	57	Shiri, A	FALSE	FALSE	FALSE	FALSE
4851	10.1002/chem.201803402	doi.org/10.1002/chem.201803402	An Iron-Based Long-Lived Catalyst for Direct C-H Arylation of Arenes and Heteroarenes		Chem.-Eur. J.	57	Mandal, SK	FALSE	FALSE	FALSE	FALSE
4852	10.1021/acscatal.8b03396	doi.org/10.1021/acscatal.8b03396	Nickel-Catalyzed Decarboxylative Alkylation of Aryl Iodides with Anhydrides		ACS Catal.	57	Liao, XB	FALSE	FALSE	FALSE	FALSE
4853	10.1021/acscatal.8b02591	doi.org/10.1021/acscatal.8b02591	Boronic Acid Catalyzed Regioselective Aminolysis of 3,4-Epoxy Alcohols		ACS Catal.	57	Wang, C	FALSE	FALSE	FALSE	FALSE
4854	10.1021/acs.orglett.8b02526	doi.org/10.1021/acs.orglett.8b02526	Cobalt-Catalyzed Aerobic Oxidative C-H/C-H Cross-Coupling of Unactivated Arenes for the Synthesis of Biaryls		Org. Lett.	57	Zhang, YH	FALSE	FALSE	FALSE	FALSE
4855	10.1002/chem.201801492	doi.org/10.1002/chem.201801492	Direct Amination of Alcohols Catalyzed by Aluminum Triflate: AnExperimental and Computational Study		Chem.-Eur. J.	57	Wischert, R; Pera-Titus, M	FALSE	FALSE	FALSE	FALSE
4856	10.1002/chem.201803574	doi.org/10.1002/chem.201803574	Remote Nucleophilic Allylation by Allylrhodium Chain Walking		Chem.-Eur. J.	57	Lam, HW	FALSE	FALSE	FALSE	FALSE
4857	10.1038/s41467-018-05638-y	doi.org/10.1038/s41467-018-05638-y	One-pot aminobenzylation of aldehydes with toluenes		Nat. Commun.	57	Mao, JY; Walsh, PJ	FALSE	FALSE	FALSE	FALSE
4858	10.1021/acscatal.8b01960	doi.org/10.1021/acscatal.8b01960	Manganese-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions		ACS Catal.	57	Yu, ZK	FALSE	FALSE	FALSE	FALSE
4859	10.1039/c8ob01034j	doi.org/10.1039/c8ob01034j	Nickel-catalyzed cyanation of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine		Org. Biomol. Chem.	57	Wang, L; He, MY	FALSE	FALSE	FALSE	FALSE
4860	10.1039/c7cy02362f	doi.org/10.1039/c7cy02362f	Homodimerization of 2H-chromenes catalyzed by BrOnsted-acid derived UiO-66 MOFs		Catal. Sci. Technol.	57	Du, X; Luan, Y	FALSE	FALSE	FALSE	FALSE
4861	10.1002/adsc.201800437	doi.org/10.1002/adsc.201800437	Chlorotrimethylsilane and Sodium Iodide: A Remarkable Metal-Free Association for the Desulfurization of Benzylic Dithioketals under Mild Conditions		Adv. Synth. Catal.	57	Alami, M; Provot, O	FALSE	FALSE	FALSE	FALSE
4862	10.1038/s41467-018-04646-2	doi.org/10.1038/s41467-018-04646-2	Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides		Nat. Commun.	57	Wang, SY; Ji, SJ	FALSE	FALSE	FALSE	FALSE
4863	10.1038/s41929-018-0081-x	doi.org/10.1038/s41929-018-0081-x	Iron-catalysed substrate-directed Suzuki biaryl cross-coupling		Nat. Catal.	57	Bedford, RB	FALSE	FALSE	FALSE	FALSE
4864	10.1039/c8qo00156a	doi.org/10.1039/c8qo00156a	Palladium-catalysed coupling of alpha-halo vinylphosphonate and alpha-phosphonovinyl sulfonate with alkylzincs: straightforward and versatile synthesis of alpha-alkyl vinylphosphonates		Org. Chem. Front.	57	Li, RF	FALSE	FALSE	FALSE	FALSE
4865	10.1021/jacs.7b13220	doi.org/10.1021/jacs.7b13220	Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2		J. Am. Chem. Soc.	57	Martin, R	FALSE	FALSE	FALSE	FALSE
4866	10.1021/acs.organomet.7b00812	doi.org/10.1021/acs.organomet.7b00812	Baldwin-Type Rules for Metal-Controlled Intramolecular Migratory Insertions. A Computational Study of Ni, Pd, and Pt Case		Organometallics	57	Gomez-Bengoa, E	FALSE	FALSE	FALSE	FALSE
4867	10.1021/jacs.7b06185	doi.org/10.1021/jacs.7b06185	Total Syntheses of Scaparvins B, C, and D Enabled by a Key C-H Functionalization		J. Am. Chem. Soc.	57	Snyder, SA	FALSE	FALSE	FALSE	FALSE
4868	10.1039/c7gc02804k	doi.org/10.1039/c7gc02804k	K-10 montmorillonite-catalyzed solid phase diazotizations: environmentally benign coupling of diazonium salts with aromatic hydrocarbons to biaryls		Green Chem.	57	Torok, B	FALSE	FALSE	FALSE	FALSE
4869	10.1002/anie.201706534	doi.org/10.1002/anie.201706534	Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4-Dioxane		Angew. Chem.-Int. Edit.	57	Studer, A	FALSE	FALSE	FALSE	FALSE
4870	10.1002/anie.201705521	doi.org/10.1002/anie.201705521	Nickel-Catalyzed Reductive Allylation of Tertiary Alkyl Halides with Allylic Carbonates		Angew. Chem.-Int. Edit.	57	Gong, HG	FALSE	FALSE	FALSE	FALSE
4871	10.1021/acs.orglett.5b03230	doi.org/10.1021/acs.orglett.5b03230	Assembly of Primary (Hetero)Arylamines via Cul/Oxalic Diamide-Catalyzed Coupling of Aryl Chlorides and Ammonia		Org. Lett.	57	Ma, DW	FALSE	FALSE	FALSE	FALSE
4872	10.1055/s-0035-1560175	doi.org/10.1055/s-0035-1560175	Nucleophilic Substitution Reaction of Pyrimidin-2-yl Phosphates Using Amines and Thiols as Nucleophiles Mediated by PEG-400 as an Environmentally Friendly Solvent		Synthesis	57	Wang, XC	FALSE	FALSE	FALSE	FALSE
4873	10.1021/acs.orglett.5b02716	doi.org/10.1021/acs.orglett.5b02716	Nickel-Catalyzed Reductive Cross-Coupling of (Hetero)Aryl Iodides with Fluorinated Secondary Alkyl Bromides		Org. Lett.	57	Jiang, ZX	FALSE	FALSE	FALSE	FALSE
4874	10.1002/asia.201500599	doi.org/10.1002/asia.201500599	Mechanism of Nickel(II)-Catalyzed Oxidative C(sp(2))-H/C(sp(3))-H Coupling of Benzamides and Toluene Derivatives		Chem.-Asian J.	57	Yu, HZ	FALSE	FALSE	FALSE	FALSE
4875	10.1016/j.poly.2014.03.028	doi.org/10.1016/j.poly.2014.03.028	A series of silver(I) complexes with bis[2-(diphenylphosphino)phenyl]ether (DPEphos) and bis(diphenylphosphino)ethane (dppe): Synthesis, structural characterization and photophysical properties		Polyhedron	57	Jin, QH	FALSE	FALSE	FALSE	FALSE
4876	10.1016/j.tet.2014.08.035	doi.org/10.1016/j.tet.2014.08.035	Negishi cross-coupling of arenediazonium o-benzenedisulfonimides		Tetrahedron	57	Dughera, S	FALSE	FALSE	FALSE	FALSE
4877	10.1021/ja508067c	doi.org/10.1021/ja508067c	Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles		J. Am. Chem. Soc.	57	Reisman, SE	FALSE	TRUE	FALSE	FALSE
4878	10.1021/ol501180q	doi.org/10.1021/ol501180q	Beyond Directed Ortho Metalation: Ruthenium-Catalyzed Amide-Directed C-Ar-N Activation/C-C Coupling Reaction of Anthranilamides with Organoboronates		Org. Lett.	57	Snieckus, V	FALSE	FALSE	FALSE	FALSE
4879	10.1021/ja406730t	doi.org/10.1021/ja406730t	Diaminophosphine Oxide Ligand Enabled Asymmetric Nickel-Catalyzed Hydrocarbamoylations of Alkenes		J. Am. Chem. Soc.	57	Cramer, N	FALSE	FALSE	FALSE	FALSE
4880	10.1016/j.jorganchem.2013.03.021	doi.org/10.1016/j.jorganchem.2013.03.021	(IPr)Pd(pydc) (pydc = pyridine-2,6-dicarboxylate) - A highly active precatalyst for the sterically hindered C-N coupling reactions		J. Organomet. Chem.	57	Xu, XH	FALSE	FALSE	FALSE	FALSE
4881	10.1002/ajoc.201300077	doi.org/10.1002/ajoc.201300077	Iridium/NMDPP Catalyzed Asymmetric Ring-Opening Reaction of Oxabenzonorbornadienes with Phenolic or Naphtholic Nucleophiles		Asian J. Org. Chem.	57	Wang, J	FALSE	FALSE	FALSE	FALSE
4882	10.1021/ja3089422	doi.org/10.1021/ja3089422	Nickel-Catalyzed Cross Couplings of Benzylic Ammonium Salts and Boronic Acids: Stereospecific Formation of Diarylethanes via C-N Bond Activation		J. Am. Chem. Soc.	57	Watson, MP	FALSE	FALSE	FALSE	FALSE
4883	10.1002/adsc.201200334	doi.org/10.1002/adsc.201200334	Microwave-Assisted One-Step Synthesis of Acetophenones via Palladium-Catalyzed Regioselective Arylation of Vinyloxytrimethylsilane		Adv. Synth. Catal.	57	Liu, H	FALSE	FALSE	FALSE	FALSE
4884	10.1021/ja306062c	doi.org/10.1021/ja306062c	Decarbonylative C-H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A		J. Am. Chem. Soc.	57	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
4885	10.1021/ol300450j	doi.org/10.1021/ol300450j	Synthesis of a Wide Range of Thioethers by Indium Triiodide Catalyzed Direct Coupling between Alkyl Acetates and Thiosilanes		Org. Lett.	57	Baba, A	FALSE	FALSE	FALSE	FALSE
4886	10.1002/adsc.201100669	doi.org/10.1002/adsc.201100669	Enantioselective alpha-Arylation of Cyclic Ketones Catalyzed by a Combination of an Unmodified Cinchona Alkaloid and a Palladium Complex		Adv. Synth. Catal.	57	Glorius, F	FALSE	FALSE	FALSE	FALSE
4887	10.1002/anie.201204275	doi.org/10.1002/anie.201204275	Copper-Catalyzed Cross-Coupling of Functionalized Alkyl Halides and Tosylates with Secondary and Tertiary Alkyl Grignard Reagents		Angew. Chem.-Int. Edit.	57	Hu, XL	FALSE	FALSE	FALSE	FALSE
4888	10.1002/adsc.201100101	doi.org/10.1002/adsc.201100101	A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides		Adv. Synth. Catal.	57	Han, FS	FALSE	FALSE	FALSE	FALSE
4889	10.1021/ja200270k	doi.org/10.1021/ja200270k	A Structure-Activity Study of Ni-Catalyzed Alkyl-Alkyl Kumada Coupling. Improved Catalysts for Coupling of Secondary Alkyl Halides		J. Am. Chem. Soc.	57	Hu, XL	FALSE	FALSE	FALSE	FALSE
4890	10.1002/ejoc.201001667	doi.org/10.1002/ejoc.201001667	An Efficient Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides		Eur. J. Org. Chem.	57	Lee, CF	FALSE	FALSE	FALSE	FALSE
4891	10.1016/j.molcata.2011.01.011	doi.org/10.1016/j.molcata.2011.01.011	Palladium(0) nanoclusters stabilized by poly(4-styrenesulfonic acid-co-maleic acid) as an effective catalyst for Suzuki-Miyaura cross-coupling reactions in water		J. Mol. Catal. A-Chem.	57	Metin, O	FALSE	FALSE	FALSE	FALSE
4892	10.1039/c0nj01019g	doi.org/10.1039/c0nj01019g	An easy access to styrenes: trans aryl 1,3-, 1,4-and 1,5-dienes, and 1,3,5-trienes by Hiyama cross-coupling catalyzed by palladium nanoparticles		New J. Chem.	57	Ranu, BC	FALSE	FALSE	FALSE	FALSE
4893	10.1039/c1ob06356a	doi.org/10.1039/c1ob06356a	An organocatalytic approach to enantiomerically enriched alpha-arylcyclohexenones and cyclohexanones		Org. Biomol. Chem.	57	Cid, MB	FALSE	FALSE	FALSE	FALSE
4894	10.1002/anie.201103022	doi.org/10.1002/anie.201103022	Practical One-Pot Preparation of Magnesium Di(hetero)aryl- and Magnesium Dialkenylboronates for Suzuki-Miyaura Cross-Coupling Reactions		Angew. Chem.-Int. Edit.	57	Knochel, P	FALSE	FALSE	FALSE	FALSE
4895	10.1002/anie.201006763	doi.org/10.1002/anie.201006763	Synthesis of alpha-Aryl Nitriles through Palladium-Catalyzed Decarboxylative Coupling of Cyanoacetate Salts with Aryl Halides and Triflates		Angew. Chem.-Int. Edit.	57	Liu, L	FALSE	FALSE	FALSE	FALSE
4896	10.1021/jo101470r	doi.org/10.1021/jo101470r	Iridium-Catalyzed Asymmetric Ring Opening of Azabicyclic Alkenes by Amines		J. Org. Chem.	57	Yang, DQ	FALSE	FALSE	FALSE	FALSE
4897	10.1016/j.tet.2010.03.062	doi.org/10.1016/j.tet.2010.03.062	Novel cyclization cascades to functionalized indanes and tetrahydronaphthalenes		Tetrahedron	57	Wirth, T	FALSE	FALSE	FALSE	FALSE
4898	10.1055/s-2008-1078254	doi.org/10.1055/s-2008-1078254	Iodine-catalyzed allylic alkylation of thiols with allylic alcohols		Synlett	57	Chan, PWH	FALSE	FALSE	FALSE	FALSE
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4900	10.1135/cccc20080705	doi.org/10.1135/cccc20080705	Preparation of Boc-protected cinnamyl-type alcohols: A comparison of the Suzuki-Miyaura coupling, cross-metathesis, and Horner-Wadsworth-Emmons approaches and their merit in parallel synthesis		Collect. Czech. Chem. Commun.	57	Stambasky, J	FALSE	FALSE	FALSE	FALSE
4901	10.1016/j.tet.2007.05.064	doi.org/10.1016/j.tet.2007.05.064	Polyaniline supported palladium catalyzed Suzuki-Miyaura cross-coupling of bromo- and chloroarenes in water		Tetrahedron	57	Kantam, ML	FALSE	FALSE	FALSE	FALSE
4902	10.1002/chem.200601184	doi.org/10.1002/chem.200601184	Mechanistic study of a Pd/C-catalyzed reduction of aryl sulfonates using the Mg-MeOH-NH4OAc system		Chem.-Eur. J.	57	Sajiki, H	FALSE	FALSE	FALSE	FALSE
4903	10.1055/s-2005-871936	doi.org/10.1055/s-2005-871936	A simple copper salt-catalyzed synthesis of unsymmetrical diaryl selenides and tellurides from arylboronic acids with diphenyl diselenide and ditelluride		Synlett	57	Wang, L	FALSE	FALSE	FALSE	FALSE
4904	10.1021/ja0469030	doi.org/10.1021/ja0469030	Nickel-catalyzed addition of dimethylzinc to aldehydes across alkynes and 1,3-butadiene: An efficient four-component connection reaction		J. Am. Chem. Soc.	57	Tamaru, Y	FALSE	FALSE	FALSE	FALSE
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4906	10.1021/jo971268k	doi.org/10.1021/jo971268k	Palladium-catalyzed oxidation of primary and secondary allylic and benzylic alcohols		J. Org. Chem.	57	Larock, RC	FALSE	FALSE	FALSE	FALSE
4907	10.1039/p19940002273	doi.org/10.1039/p19940002273	ASYMMETRIC-SYNTHESIS OF AXIALLY CHIRAL 1,1'-BIPHENYL-2-CARboxYLATES VIA NUCLEOPHILIC AROMATIC-SUBSTITUTION ON 2-MENTHOXYBENZOATES BY ARYL GRIGNARD-REAGENTS		J. Chem. Soc.-Perkin Trans. 1	57		FALSE	FALSE	FALSE	FALSE
4908	10.1021/jo00002a039	doi.org/10.1021/jo00002a039	MECHANICAL ACTIVATION OF MAGNESIUM TURNINGS FOR THE PREPARATION OF REACTIVE GRIGNARD-REAGENTS		J. Org. Chem.	57		FALSE	FALSE	FALSE	FALSE
4909	10.1002/anie.202116870	doi.org/10.1002/anie.202116870	Palladium-Catalyzed Tail-to-Tail Reductive Dimerization of Terminal Alkynes to 2,3-Dibranched Butadienes		Angew. Chem.-Int. Edit.	57	Li, Y; Bao, M	FALSE	FALSE	FALSE	FALSE
4910	10.1039/d1cc06688a	doi.org/10.1039/d1cc06688a	Photoredox catalyzed C-H trifluoroethylamination of heteroarenes		Chem. Commun.	57	Xu, XH; Qing, FL	TRUE	FALSE	FALSE	FALSE
4911	10.1021/acs.orglett.1c04086	doi.org/10.1021/acs.orglett.1c04086	Ni-Catalyzed Decarboxylative Silylation of Alkynyl Carbonates: Access to Chiral Allenes via Enantiospecific Conversions		Org. Lett.	57	Kleij, AW	FALSE	FALSE	FALSE	FALSE
4912	10.1039/d1qo01614h	doi.org/10.1039/d1qo01614h	A Ni(ii)-catalyzed reductive cross-coupling reaction of oxalates and thiosulfonates/selenosulfonates		Org. Chem. Front.	57	Wang, SY	FALSE	FALSE	FALSE	FALSE
4913	10.1021/acscatal.1c04732	doi.org/10.1021/acscatal.1c04732	Scope and Mechanism of the Redox-Active 1,2-Benzoquinone Enabled Ruthenium-Catalyzed Deaminative alpha-Alkylation of Ketones with Amines		ACS Catal.	57	Yi, CS	FALSE	FALSE	FALSE	FALSE
4914	10.1021/acs.joc.1c02290	doi.org/10.1021/acs.joc.1c02290	Synthesis of Enantioenriched 3,4-Disubstituted Chromans through Lewis Base Catalyzed Carbosulfenylation		J. Org. Chem.	57	Denmark, SE	FALSE	FALSE	FALSE	FALSE
4915	10.1021/acs.orglett.1c03232	doi.org/10.1021/acs.orglett.1c03232	Pd-Catalyzed Double-Decarbonylative Aryl Sulfide Synthesis through Aryl Exchange between Amides and Thioesters		Org. Lett.	57	Szostak, M	FALSE	FALSE	FALSE	FALSE
4916	10.1039/d1ob01619a	doi.org/10.1039/d1ob01619a	MeOTf/KI-catalyzed efficient synthesis of 2-arylnaphthalenes via cyclodimerization of styrene oxides		Org. Biomol. Chem.	57	Chen, C; Xi, CJ	FALSE	FALSE	FALSE	FALSE
4917	10.1021/jacs.1c06614	doi.org/10.1021/jacs.1c06614	Enantioconvergent Arylation of Racemic Secondary Alcohols to Chiral Tertiary Alcohols Enabled by Nickel/N-Heterocyclic Carbene Catalysis		J. Am. Chem. Soc.	57	Shi, SL	FALSE	FALSE	FALSE	FALSE
4918	10.1039/d1dt01716k	doi.org/10.1039/d1dt01716k	Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands		Dalton Trans.	57	Nolan, SP	FALSE	FALSE	FALSE	FALSE
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4920	10.1021/acs.joc.1c00510	doi.org/10.1021/acs.joc.1c00510	[(PPh3)(2)NiCl2]-Catalyzed C-N Bond Formation Reaction via Borrowing Hydrogen Strategy: Access to Diverse Secondary Amines and Quinolines		J. Org. Chem.	57	Rit, A	FALSE	FALSE	FALSE	FALSE
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4923	10.1021/acs.orglett.1c00812	doi.org/10.1021/acs.orglett.1c00812	Cu-Catalyzed Oxidative Allylic C-H Arylation of Inexpensive Alkenes with (Hetero)Aryl Boronic Acids		Org. Lett.	57	Hoarau, C; Schneider, C	FALSE	FALSE	FALSE	FALSE
4924	10.1039/c7dt01912b	doi.org/10.1039/c7dt01912b	Heteroleptic nickel(II)-diNHC complexes and an unusual 'reverse' carbene-transfer reaction to silver(I)		Dalton Trans.	57	Huynh, HV	FALSE	FALSE	FALSE	FALSE
4925	10.1002/hc.21397	doi.org/10.1002/hc.21397	C-O and C-S coupling reaction of 1,2-di(pyrimidin-2-yl) disulfides with phenols/thiophenols promoted by copper(I) chloride		Heteroatom Chem.	57	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
4926	10.1021/acs.joc.7b00481	doi.org/10.1021/acs.joc.7b00481	Multiple Approaches to the In Situ Generation of Anhydrous Tetraalkylammonium Fluoride Salts for SNAr Fluorination Reactions		J. Org. Chem.	57	Sanford, MS	FALSE	FALSE	FALSE	FALSE
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4928	10.1039/c6gc03465a	doi.org/10.1039/c6gc03465a	A copper-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide using molecular oxygen as the oxidant		Green Chem.	57	Qi, CR; Jiang, HF	FALSE	FALSE	FALSE	FALSE
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4932	10.1021/jacs.6b10351	doi.org/10.1021/jacs.6b10351	Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates		J. Am. Chem. Soc.	57	Martin, R	FALSE	FALSE	FALSE	FALSE
4933	10.1021/acs.orglett.6b02550	doi.org/10.1021/acs.orglett.6b02550	Arylation, Vinylation, and Alkynylation of Electron-Deficient (Hetero)arenes Using Iodonium Salts		Org. Lett.	57	Wang, Q	FALSE	TRUE	FALSE	FALSE
4934	10.1002/cctc.201600589	doi.org/10.1002/cctc.201600589	Catalyst-Triggered Highly Selective C-S and C-Se Bond Formation by C-H Activation		ChemCatChem	57	Li, WM	FALSE	FALSE	FALSE	FALSE
4935	10.1021/acs.orglett.6b00819	doi.org/10.1021/acs.orglett.6b00819	C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis		Org. Lett.	57	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
4936	10.1002/anie.201601930	doi.org/10.1002/anie.201601930	Radical Hydrodeiodination of Aryl, Alkenyl, Alkynyl, and Alkyl Iodides with an Alcoholate as Organic Chain Reductant through Electron Catalysis		Angew. Chem.-Int. Edit.	57	Studer, A	FALSE	TRUE	FALSE	FALSE
4937	10.1002/ejoc.201501556	doi.org/10.1002/ejoc.201501556	Nickel-Catalysed Bis-Allylation of Activated Nucleophiles with Allyl Alcohol		Eur. J. Org. Chem.	57	Sauthier, M; Bonin, H	FALSE	FALSE	FALSE	FALSE
4938	10.1039/c6gc01113f	doi.org/10.1039/c6gc01113f	Sustainable, inexpensive and easy-to-use access to the super-reductant e(aq)(center dot-) through 355 nm photoionization of the ascorbate dianion-an alternative to radiolysis or UV-C photochemistry		Green Chem.	57	Goez, M	FALSE	FALSE	FALSE	FALSE
4939	10.1039/c5nj03450g	doi.org/10.1039/c5nj03450g	A 2-((4-Arylpiperazin-1-yl)methyl)phenol ligated Pd(II) complex: an efficient, versatile catalyst for Suzuki-Miyaura cross-coupling reactions		New J. Chem.	57	Keesara, S	FALSE	FALSE	FALSE	FALSE
4940	10.1002/ejoc.202100005	doi.org/10.1002/ejoc.202100005	BH3 . Me2S: An Alternative Hydride Source for NiH-Catalyzed Reductive Migratory Hydroarylation and Hydroalkenylation of Alkenes	N-Heterocyclic carbenes (NHCs) are widely used as ligands in catalysis by transition metal complexes. The catalytic activity of transition metal NHC complexes is much higher than that of the transition metal complexes bearing the phosphine and nitrogen-containing ligands. They show excellent catalytic performance in different transformations of the organic compounds, especially in the carbon-carbon and carbon-element bond forming reactions. Palladium NHC complexes are very efficient catalysts for the cross-coupling reactions. On the other hand, nickel is less expensive and regarded as a promising alternative to palladium and, therefore, it attracts increasing attention from the researches. The present review is focused on the recent advances in the synthesis of N-heterocyclic carbene complexes of nickel and palladium and their application in catalysis of cross-coupling reactions of organic, organoelement and organometallic compounds with organic halides.	Eur. J. Org. Chem.	56	Gong, HG	FALSE	FALSE	FALSE	FALSE
4941	10.1021/acs.orglett.1c00190	doi.org/10.1021/acs.orglett.1c00190	Deoxyfluorination of Carboxylic Acids with CpFluor: Access to Acyl Fluorides and Amides	The present work demonstrates the C-S cross-coupling reaction between aryl halides and thiols using nickel nanoparticles (Ni NPs) supported on reduced graphene oxide (Ni/RGO) as a heterogeneous catalyst. It is observed that the uniformly dispersed Ni NPs supported on RGO could exhibit excellent catalytic activity in C-S cross-coupling reactions and the catalytic application is generalized with diverse coupling partners. Although the electron-rich planar RGO surface helps in stabilizing the agglomeration-free Ni NPs, the catalytic process is found to occur involving Ni(II) species and the recovered catalyst containing both Ni(0)/Ni(II) species is equally efficient in recycle runs. A correlation of loading of Ni species, size of NPs and the intermediate Ni-related heterostructures formed during the catalytic process has been established for the first time, and found to be best in the C-S cross-coupling reaction for Ni(0) and Ni(II) NPs of the average sizes 11-12 nm and 4 nm, respectively.	Org. Lett.	56	Hu, JB	FALSE	FALSE	FALSE	FALSE
4942	10.1039/d0sc06056a	doi.org/10.1039/d0sc06056a	Nickel-catalyzed C-O/N-H, C-S/N-H, and C-CN/N-H annulation of aromatic amides with alkynes: C-O, C-S, and C-CN activation	We report Ni-catalyzed formal carboacylation of o-allylbenzamides with arylboronic acid pinacol esters. The reaction is triggered by oxidative addition of an activated amide C-N bond to a Ni(0) catalyst and proceeds via alkene insertion into a Ni(II)-acyl bond. The exo-selective carboacylation reaction generates 2-benzy-12,3-dihydro-1H-inden-1-ones in moderate to high yields (46-99%) from a variety of arylboronic acid pinacol esters and substituted o-allylbenzamides. These results show that amides are practical substrates for alkene carboacylation via amide C-N bond activation) and this approach bypasses challenges associated with alkene carboacylation triggered by C-C bond activation.	Chem. Sci.	56	Chatani, N	FALSE	FALSE	FALSE	FALSE
4943	10.1002/anie.202012877	doi.org/10.1002/anie.202012877	Light-Promoted C-N Coupling of Aryl Halides with Nitroarenes	A bimetallic system consisting of Cu-carbene and Mn-carbonyl co-catalysts was employed for carbonylative C-C coupling of arylboronic esters with alkyl halides, allowing for the convergent synthesis of ketones. The system operates under mild conditions and exhibits complementary reactivity to Pd catalysis. The method is compatible with a wide range of arylboronic ester nucleophiles and proceeds smoothly for both primary and secondary alkyl iodide electrophiles. Preliminary mechanistic experiments corroborate a hypothetical catalytic mechanism consisting of co-dependent cycles wherein the Cu-carbene co-catalyst engages in transmetallation to generate an organocopper nucleophile, while the Mn-carbonyl co-catalyst activates the alkyl halide electrophile by single-electron transfer and then undergoes reversible carbonylation to generate an acylmanganese electrophile. The two cycles then intersect with a heterobimetallic, product-releasing C-C coupling step.	Angew. Chem.-Int. Edit.	56	Xue, D	FALSE	FALSE	FALSE	FALSE
4944	10.1021/acs.orglett.0c02614	doi.org/10.1021/acs.orglett.0c02614	Asymmetric Synthesis of gamma-Secondary Amino Alcohols via a Borrowing-Hydrogen Cascade	While phenyl vinyl ether does not react with [Ru(eta(4)-1,5-COD)(eta(6)-1,3,5-COT)] (1)/PMe3, the C-O bond cleavage of phenyl vinyl ether occurs by 1/PMe3 in the presence of water to give a tris(mu-hydroxo) diruthenium(II) complex [(Me3P)(3)Ru(mu-OH)(3)Ru(PMe3)(3)](+)[OPh](-)center dot HOPh (3 center dot HOPh) with evolution of ethylene. The molecular structure of 3 center dot HOPh is unequivocally determined by X-ray analysis. The most likely mechanism for the formation of 3 center dot HOPh is protonation of [Ru(eta(4)-1,5-COD)(PMe3)(3)] (2c) by water and subsequent insertion of phenyl vinyl ether into the resulting Ru-H bond followed by the beta-phenoxide elimination and hydrolysis and dimerization of the phenoxoruthenium(II) species. Complex 3 acts as a catalyst for nitrile hydration. As a typical example, the hydration of benzonitrile was achieved by 3 (1.0 mol%) in 1,4-dioxane at 120 degrees C for 6 h to give benzamide quantitatively. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Lett.	56	Jin, MY; Xing, XY	FALSE	FALSE	FALSE	FALSE
4945	10.1021/acs.orglett.0c01937	doi.org/10.1021/acs.orglett.0c01937	Development and Mechanistic Studies of Iron-Catalyzed Construction of Csp(2)-B Bonds via C-O Bond Activation	Owing to the utmost importance of anthracene based phosphonates in multiple branches of science, we offer a direct, metal-free and operationally-simple protocol to access a new family of anthracenylphosphonates, i.e., diethyl ((10-arylanthracen- 9-yl) methyl) phosphonates by Friedel-Crafts (FC) type arylation reactions of easily accessible corresponding alpha-hydroxyphosphonate with arenes (1.2 equiv only) in the presence of inexpensive acid. The scope has been extended with both activated and unactivated arenes including haloanisoles, hetero-arenes and biphenyl at room temperature. Unexpectedly, under identical reaction conditions, pyrene afforded the a-pyrene substituted anthracenylphosphonates. Furthermore, these anthracenyl along with recently reported naphthyl phosphonates were screened for their activities against murine melanoma cell lines (skin cancer). Initial studies exhibited promising results with the IC50 values in the range of 9.46-96 mm for anthracenylphosphonates and 15-38 mm for naphthylphosphonates.	Org. Lett.	56	Feng, Z	FALSE	FALSE	FALSE	FALSE
4946	10.1021/acs.joc.0c00845	doi.org/10.1021/acs.joc.0c00845	Pyridine-Enabled C-N Bond Activation for the Rapid Construction of Amides and 4-Pyridylglyoxamides by Cooperative Palladium/Copper Catalysis	A nickel/N-heterocyclic carbene catalytic system has been established for decarbonylative borylation of amides with B(2)nep(2) by C-N bond activation. This transformation shows good functional-group compatibility and can serve as a powerful synthetic tool for late-stage borylation of amide groups in complex compounds. More importantly, as a key intermediate, the structure of an acyl nickel complex was first confirmed by X-ray analysis. Furthermore, the decarbonylative process was also observed. These findings confirm the key mechanistic features of the acyl C-N bond activation process.	J. Org. Chem.	56	Van der Eycken, EV	FALSE	FALSE	FALSE	FALSE
4947	10.1039/d0ob00535e	doi.org/10.1039/d0ob00535e	Synthesis of gem-difluoroalkenes via nickel-catalyzed allylic defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides	The direct addition of Csp(2)-H bonds onto polar C=C, C=O, and C=N bonds is both synthetically and mechanistically important, because using aromatic C-H substrates in place of organometallic reagents provides a more direct and atom-economical alternative to many important compounds without the pre-generation of organometallic compounds from stoichiometric halides and the unavoidable generation of stoichiometric metal halide waste. In this account, we summarize our contributions to the transition-metal-catalyzed addition of aromatic C-H bonds to polar C=C, C=O, and C=N bonds via directing-group-assisted regiospecific reactions. These synthetic methods provide efficient access to benzylic alcohols, alkylbenzenes, 3-substituted phthalides, N-substituted phthalimides, N-aryl benzamides, and indene derivatives from commercially available reagents. It is worth noting that valuable heterocycles such as 3-substituted phthalides and N-substituted phthalimides can be obtained in one step by this approach.	Org. Biomol. Chem.	56	Lu, XY	FALSE	FALSE	FALSE	FALSE
4948	10.1021/acs.joc.9b03077	doi.org/10.1021/acs.joc.9b03077	Toward an Air-Stable Triradical with Strong Spin Coupling: Synthesis of Substituted Truxene-5,10,15-triyl	We report on combined structural, kinetic, and computational studies unraveling the mechanism of a unique, highly selective intramolecular C(sp(2))-OMe cleavage/C(sp(2))-C(sp(2)) coupling tandem reaction in group 3 metal (Y and Sc) complexes of amidine-amidopyridinate ligands. The latter process represents a rare stoichiometric model of the nonredox cleavage of inert C(sp(2))-O bonds relevant to cross-coupling reactions of aromatic ethers catalyzed by late transition metals.	J. Org. Chem.	56	Zhao, DH	FALSE	FALSE	FALSE	FALSE
4949	10.1016/j.jcat.2020.02.021	doi.org/10.1016/j.jcat.2020.02.021	Exploring the coordination confinement effect of divalent palladium/zero palladium doped polyaniline-networking: As an excellent-performance nanocomposite catalyst for C-C coupling reactions	A cost-effective, operationally simple and eco-compatible protocol for the one-pot synthesis of photochromic pyrans by the reaction of propargyl alcohols as well as propargyl ethers with differently substituted phenols under ambient atmosphere in aqueous medium has been developed using beta-cyclo-dextrin hydrate as an efficient, recyclable and stable catalyst. This is the first report where beta-cyclodextrin hydrate acted as a catalyst for an organic transformation but beta-cyclodextrin alone failed.	J. Catal.	56	Liu, WY	FALSE	FALSE	FALSE	FALSE
4950	10.1021/jacs.9b13684	doi.org/10.1021/jacs.9b13684	Ru(II)-Catalyzed Amination of Aryl Fluorides via eta(6)-Coordination	Four types of ruthenium-catalyzed stereoselective allylic substitutions of monosubstituted allylic esters have been discussed. (1) Highly linear selective allylic alkylation of both branch and linear type allylic acetates with malonate anion by 2-DPPBA ligated Ru-3(CO)(12) catalyst, and the structure and reactivity of pi-allylruthenium intermediate. (2) Highly linear selective allylic amination of both branch and linear type allylic acetates by 2-DPPBA ligated Ru-3(CO)(12) catalyst. (3) Selecitve substitution at the position originally substituted with leaving group in the allylic alkylation of mono- and disubstituted allylic esters with malonate anion by [RuCl2(P-cymene)](2) with PPh3 or 2-DPPBA catalyst, and the chirality transfer of the optically active allylic esters to the allylic alkylated products. (4) Regio- and enantioselective allylic amination of racemic monosubstituted allylic esters with aliphatic secondary amines by RuCl3 with (S,S)-ip-pybox catalyst	J. Am. Chem. Soc.	56	Shi, H	FALSE	FALSE	FALSE	FALSE
4951	10.1002/anie.202000224	doi.org/10.1002/anie.202000224	Amide Synthesis by Nickel/Photoredox-Catalyzed Direct Carbamoylation of (Hetero)Aryl Bromides	2-Phenylquinolines, 2-phenyl-3-methyl-quinolines, and 2-phenyl-3-ethylquinolines were synthesized in high yields (78-90%) by the reaction of aniline, benzylamine, aliphatic alcohols (ethanol, n-propanol, n-butanol), and CCl4 catalyzed by FeCl(3)6H(2)O in tetrachloromethane.	Angew. Chem.-Int. Edit.	56	Melchiorre, P	TRUE	FALSE	FALSE	FALSE
4952	10.1039/c9cc08663c	doi.org/10.1039/c9cc08663c	Palladium-catalyzed denitrative Sonogashira-type cross-coupling of nitrobenzenes with terminal alkynes		Chem. Commun.	56	Yang, YD; You, JS	FALSE	FALSE	FALSE	FALSE
4953	10.1016/j.poly.2019.114269	doi.org/10.1016/j.poly.2019.114269	Exploration of the mechanism and scope of the Cul/DABCO catalysed C-S coupling reaction		Polyhedron	56	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
4954	10.1016/j.mencom.2020.01.010	doi.org/10.1016/j.mencom.2020.01.010	First P-star,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions		Mendeleev Commun.	56	Gavrilov, KN; Goulioukina, NS	FALSE	FALSE	FALSE	FALSE
4955	10.1080/16583655.2020.1843872	doi.org/10.1080/16583655.2020.1843872	DFT evaluation of the effects of OH, NH2 and Br substituents on the properties of 2,2 '-bipyridine derivatives		J. Taibah Univ. Sci.	56	Popoola, SA	FALSE	FALSE	FALSE	FALSE
4956	10.1021/acs.orglett.9b03170	doi.org/10.1021/acs.orglett.9b03170	Ni-Catalyzed Cycloisomerization between 3-Phenoxy Acrylic Acid Derivatives and Alkynes via Intramolecular Cleavage and Formation of the C-O Bond To Give 2,3-Disubstituted Benzofurans		Org. Lett.	56	Arisawa, M	FALSE	FALSE	FALSE	FALSE
4957	10.1039/c9cy01239g	doi.org/10.1039/c9cy01239g	Theoretical study of the ligand effect on NHC-cobalt-catalyzed hydrogenation of ketones Electronic supplementary information (ESI) available		Catal. Sci. Technol.	56	Wu, KB	FALSE	TRUE	FALSE	FALSE
4958	10.1021/acs.orglett.9b03030	doi.org/10.1021/acs.orglett.9b03030	Nonbifunctional Outer-Sphere Strategy Achieved Highly Active alpha-Alkylation of Ketones with Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)		Org. Lett.	56	Ke, ZF	FALSE	FALSE	FALSE	FALSE
4959	10.1039/c9ra05346h	doi.org/10.1039/c9ra05346h	SO2F2 mediated cascade dehydrogenative Morita-Baylis-Hillman reaction of the C(sp(3))-H of primary alcohols with the C(sp(2))-H of electron-deficient olefins for the assembly of allylic alcohols		RSC Adv.	56	Sun, B; Qin, HL	FALSE	FALSE	FALSE	FALSE
4960	10.1021/acs.orglett.9b02273	doi.org/10.1021/acs.orglett.9b02273	Photocatalytic Reductive Formation of alpha-Tertiary Ethers from Ketals		Org. Lett.	56	Dixon, DJ	TRUE	FALSE	FALSE	FALSE
4961	10.1002/cctc.201900047	doi.org/10.1002/cctc.201900047	Nickel-Catalyzed Selective Cross-Coupling of Chlorosilanes with Organoaluminum Reagents		ChemCatChem	56	Naganawa, Y; Nakajima, Y	FALSE	FALSE	FALSE	FALSE
4962	10.1021/acs.joc.9b01517	doi.org/10.1021/acs.joc.9b01517	Nickel-Catalyzed Direct Alkenylation of Methyl Heteroarenes with Primary Alcohols		J. Org. Chem.	56	Baidya, M	FALSE	FALSE	FALSE	FALSE
4963	10.1021/acs.organomet.9b00082	doi.org/10.1021/acs.organomet.9b00082	A Molecular/Heterogeneous Nickel Catalyst for Suzuki-Miyaura Coupling		Organometallics	56	Vannucci, AK	FALSE	FALSE	FALSE	FALSE
4964	10.1039/c8dt05100c	doi.org/10.1039/c8dt05100c	Synthesis, structure and palladium coordination of ambiphilic, pyridine- and phosphine-tethered N-boryl imine ligands		Dalton Trans.	56	Arndtsen, BA	FALSE	FALSE	FALSE	FALSE
4965	10.1021/acs.orglett.9b01097	doi.org/10.1021/acs.orglett.9b01097	Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis		Org. Lett.	56	Molander, GA	TRUE	FALSE	FALSE	FALSE
4966	10.1002/anie.201814572	doi.org/10.1002/anie.201814572	Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis		Angew. Chem.-Int. Edit.	56	Yin, GY	FALSE	FALSE	FALSE	FALSE
4967	10.1055/s-0037-1611663	doi.org/10.1055/s-0037-1611663	Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C-O Activation		Synlett	56	Ackermann, L	FALSE	FALSE	FALSE	FALSE
4968	10.1021/acs.orglett.9b00034	doi.org/10.1021/acs.orglett.9b00034	Rhenium-Catalyzed Dehydrogenative Coupling of Alcohols and Amines to Afford Nitrogen-Containing Aromatics and More		Org. Lett.	56	Kirchner, K	FALSE	FALSE	FALSE	FALSE
4969	10.1002/chem.201805175	doi.org/10.1002/chem.201805175	Sulfuryl Fluoride Mediated Conversion of Aldehydes to Nitriles		Chem.-Eur. J.	56	Fokin, VV	FALSE	FALSE	FALSE	FALSE
4970	10.1016/j.cclet.2018.09.009	doi.org/10.1016/j.cclet.2018.09.009	Nickel-catalysed C-O bond reduction of 2,4,6-triaryloxy-1,3,5-triazines in 2-methyltetrahydrofuran		Chin. Chem. Lett.	56	Wang, L; He, MY	FALSE	FALSE	FALSE	FALSE
4971	10.1055/s-0037-1610251	doi.org/10.1055/s-0037-1610251	Copper-Catalyzed NaBAr (4) -Based N-Arylation of Amines		Synthesis	56	Peng, YY	FALSE	FALSE	FALSE	FALSE
4972	10.1021/acs.orglett.8b03062	doi.org/10.1021/acs.orglett.8b03062	Interruption of Formal Schmidt Rearrangement/Hosomi-Sakurai Reaction of Vinyl Azides with Allyl/Propargylsilanes		Org. Lett.	56	Zhang, JP; Pan, L	FALSE	FALSE	FALSE	FALSE
4973	10.1002/chem.201803451	doi.org/10.1002/chem.201803451	Dismantling of Vinyl Ethers by Pentanuclear [(iPr(3)P)Ni](5)H-6: Facile Cooperative C-O, C-C and C-H Activation Pathways		Chem.-Eur. J.	56	Johnson, SA	FALSE	FALSE	FALSE	FALSE
4974	10.1002/zaac.201800151	doi.org/10.1002/zaac.201800151	Phosphine Functionalized NHC Ligands and Their Cyclopentadienide Nickel(II) Complexes		Z. Anorg. Allg. Chem.	56	Thiel, WR	FALSE	FALSE	FALSE	FALSE
4975	10.1021/acs.orglett.8b02196	doi.org/10.1021/acs.orglett.8b02196	Visible-Light-Triggered C-C and C-N Bond Formation by C-S Bond Cleavage of Benzylic Thioethers		Org. Lett.	56	Masson, G	FALSE	FALSE	FALSE	FALSE
4976	10.1021/acs.orglett.8b02073	doi.org/10.1021/acs.orglett.8b02073	Tf2O-Promoted Activating Strategy of Phosphate Analogues: Synthesis of Mixed Phosphates and Phosphinate		Org. Lett.	56	Kang, JY	FALSE	FALSE	FALSE	FALSE
4977	10.1021/jacs.8b04627	doi.org/10.1021/jacs.8b04627	Branch-Selective and Enantioselective Iridium-Catalyzed Alkene Hydroarylation via Anilide-Directed C-H Oxidative Addition		J. Am. Chem. Soc.	56	Bower, JF	FALSE	FALSE	FALSE	FALSE
4978	10.1016/j.tetlet.2018.06.037	doi.org/10.1016/j.tetlet.2018.06.037	Synthesis of electron-deficient (S-a,R,R)-(CF3)(2)-C-3-TunePhos and its applications in asymmetric hydrogenation of alpha-iminophosphonates		Tetrahedron Lett.	56	Zhou, YG	FALSE	FALSE	FALSE	FALSE
4979	10.1002/ejoc.201800503	doi.org/10.1002/ejoc.201800503	Palladium/Lewis Acid Cocatalyzed Reductive Asymmetric Ring-Opening Reaction of Azabenzonorbornadienes with Tertiary Amines as the Hydrogen Source		Eur. J. Org. Chem.	56	Khan, R; Fan, BM	FALSE	FALSE	FALSE	FALSE
4980	10.1016/j.jorganchem.2018.03.015	doi.org/10.1016/j.jorganchem.2018.03.015	Mechanisms of the synthesis of trialkylsubstituted alkenylboronates from unactivated internal alkynes catalyzed by copper: A theoretical study		J. Organomet. Chem.	56	Han, LL; Liu, T	FALSE	FALSE	FALSE	FALSE
4981	10.1021/acscatal.8b00244	doi.org/10.1021/acscatal.8b00244	Ni/Ti Dual Catalytic Cross-Coupling of Nitriles and Organobromides To Access Ketones		ACS Catal.	56	Rahaim, RJ	FALSE	FALSE	FALSE	FALSE
4982	10.1021/acs.orglett.8b00108	doi.org/10.1021/acs.orglett.8b00108	Fe(III)-Catalyzed Hydroallylation of Unactivated Alkenes with Morita-Baylis-Hillman Adducts		Org. Lett.	56	Cui, SL	FALSE	FALSE	FALSE	FALSE
4983	10.1021/acs.orglett.8b00105	doi.org/10.1021/acs.orglett.8b00105	alpha-Alkylation of Chiral Sulfinimines for Constructing Quaternary Chiral Carbons by Introducing Removable Directing Groups		Org. Lett.	56	Yang, G; Yang, C	FALSE	FALSE	FALSE	FALSE
4984	10.1021/acs.accounts.7b00432	doi.org/10.1021/acs.accounts.7b00432	Keeping Track of the Electrons		Accounts Chem. Res.	56	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
4985	10.1039/c8ra09048c	doi.org/10.1039/c8ra09048c	Cu-catalyzed cross-coupling reactions of vinyl epoxide with organoboron compounds: access to homoallylic alcohols		RSC Adv.	56	Lu, XY	FALSE	FALSE	FALSE	FALSE
4986	10.1055/s-0036-1590869	doi.org/10.1055/s-0036-1590869	Enantioselective Palladium-Catalyzed Decarboxylative Allylation of -Keto Esters Assisted by a Thiourea		Synlett	56	Chung, LW; Zhang, XM	FALSE	FALSE	FALSE	FALSE
4987	10.1055/s-0036-1588568	doi.org/10.1055/s-0036-1588568	Chromium-Catalyzed, Regioselective Cross-Coupling of C-O Bonds by Using Organic Bromides as Reactants		Synlett	56	Luo, MM; Zeng, XM	FALSE	FALSE	FALSE	FALSE
4988	10.1002/anie.201710241	doi.org/10.1002/anie.201710241	A Nickel-Catalyzed Carbonyl-Heck Reaction		Angew. Chem.-Int. Edit.	56	Newman, SG	FALSE	FALSE	FALSE	FALSE
4989	10.1016/j.tetlet.2017.09.036	doi.org/10.1016/j.tetlet.2017.09.036	n-Butyllithium-promoted regioselective elimination of vicinal bis-triflate having an adjacent ether oxygen		Tetrahedron Lett.	56	Kutsumura, N	FALSE	FALSE	FALSE	FALSE
4990	10.1039/c5cc10518h	doi.org/10.1039/c5cc10518h	Chemo- and regioselective reductive deoxygenation of 1-en-4-yn-ols into 1,4-enynes through FeF3 and TfOH co-catalysis		Chem. Commun.	56	Bi, XH	FALSE	FALSE	FALSE	FALSE
4991	10.1016/j.tetlet.2015.11.025	doi.org/10.1016/j.tetlet.2015.11.025	Radical N-cyanation of sulfoximine through acetonitrile C-CN cleavage		Tetrahedron Lett.	56	Shao, Y	FALSE	FALSE	FALSE	FALSE
4992	10.1002/chem.201503414	doi.org/10.1002/chem.201503414	Indium Tribromide Catalyzed Coupling Reaction of Enol Ethers with Silyl Ketene Imines toward the Synthesis of beta,gamma-Unsaturated Nitriles		Chem.-Eur. J.	56	Nishimoto, Y	FALSE	FALSE	FALSE	FALSE
4993	10.1007/s11244-015-0417-6	doi.org/10.1007/s11244-015-0417-6	The Role of Low Valent Transition Metal Complexes in Homogeneous Catalysis: An EPR Investigation		Top. Catal.	56	Carter, E	FALSE	FALSE	FALSE	FALSE
4994	10.1021/acs.orglett.5b01418	doi.org/10.1021/acs.orglett.5b01418	Activation-Enabled Syntheses of Functionalized Pillar[5]arene Derivatives		Org. Lett.	56	Stoddart, JF	FALSE	FALSE	FALSE	FALSE
4995	10.1021/acscatal.5b00306	doi.org/10.1021/acscatal.5b00306	Selective C-H Bond Fluorination of Phenols with a Removable Directing Group: Late-Stage Fluorination of 2-Phenoxyl Nicotinate Derivatives		ACS Catal.	56	Xu, DQ	FALSE	FALSE	FALSE	FALSE
4996	10.1002/anie.201500396	doi.org/10.1002/anie.201500396	Copper/Palladium Synergistic Catalysis for the syn- and anti-Selective Carboboration of Alkenes		Angew. Chem.-Int. Edit.	56	Brown, MK	FALSE	FALSE	FALSE	FALSE
4997	10.1002/cctc.201500079	doi.org/10.1002/cctc.201500079	Palladium-Catalyzed Oxidative Heck Coupling of Cyclic Enones with Simple Arenes by C-H Activation		ChemCatChem	56	Seayad, J	FALSE	FALSE	FALSE	FALSE
4998	10.1039/c5qo00040h	doi.org/10.1039/c5qo00040h	Nickel-catalyzed decarboxylative arylation of azoles with perfluoro- and nitrobenzoates		Org. Chem. Front.	56	Crawford, JM	FALSE	FALSE	FALSE	FALSE
4999	10.1039/c5cc03113c	doi.org/10.1039/c5cc03113c	Alkyl-aryl ketone synthesis via nickel-catalyzed reductive coupling of alkyl halides with aryl acids and anhydrides		Chem. Commun.	56	Zhang, XH	FALSE	FALSE	FALSE	FALSE
5000	10.1039/c5dt01358e	doi.org/10.1039/c5dt01358e	A green and sustainable phosphine-free NHC-ruthenium catalyst for selective oxidation of alcohols to carboxylic acids in water		Dalton Trans.	56	Keul, H	FALSE	FALSE	FALSE	FALSE
5001	10.1039/c4cc08559k	doi.org/10.1039/c4cc08559k	Chiral Bronsted acid-catalyzed Friedel-Crafts alkylation of electron-rich arenes with in situ-generated ortho-quinone methides: highly enantioselective synthesis of diarylindolylmethanes and triarylmethanes		Chem. Commun.	56	Schneider, C	FALSE	FALSE	FALSE	FALSE
5002	10.1039/c4cc09594d	doi.org/10.1039/c4cc09594d	Stable bis(trifluoromethyl)nickel(III) complexes		Chem. Commun.	56	Mirica, LM	FALSE	FALSE	FALSE	FALSE
5003	10.1021/ol502583h	doi.org/10.1021/ol502583h	1,3-Dicyclohexylimidazol-2-ylidene as a Superior Ligand for the Nickel-Catalyzed Cross-Couplings of Aryl and Benzyl Methyl Ethers with Organoboron Reagents		Org. Lett.	56	Tobisu, M	FALSE	FALSE	FALSE	FALSE
5004	10.1039/c4cc04377d	doi.org/10.1039/c4cc04377d	Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions		Chem. Commun.	56	Liu, JM	FALSE	FALSE	FALSE	FALSE
5005	10.1055/s-0033-1339032	doi.org/10.1055/s-0033-1339032	Advances in the Ring Opening of Small-Ring Heterocycles with Organoboron Derivatives		Synlett	56	Pineschi, M	FALSE	FALSE	FALSE	FALSE
5006	10.1016/j.apcata.2014.05.020	doi.org/10.1016/j.apcata.2014.05.020	Suzuki-Miyaura cross-coupling of aryl iodides and phenylboronic acid over palladium-free CeO2 catalysts		Appl. Catal. A-Gen.	56	Volpe, MA	FALSE	FALSE	FALSE	FALSE
5007	10.1021/jo500409r	doi.org/10.1021/jo500409r	A General Suzuki Cross-Coupling Reaction of Heteroaromatics Catalyzed by Nanopalladium on Amino-Functionalized Siliceous Mesocellular Foam		J. Org. Chem.	56	Backvall, JE	FALSE	FALSE	FALSE	FALSE
5008	10.1021/om500088p	doi.org/10.1021/om500088p	One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(eta(6)-arene)Ni(N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni-0-NHC Unit		Organometallics	56	Ogoshi, S	FALSE	FALSE	FALSE	FALSE
5009	10.1021/ol500310u	doi.org/10.1021/ol500310u	Copper-Catalyzed Suzuki-Miyaura Coupling of Arylboronate Esters: Transmetalation with (PN)CuF and Identification of Intermediates		Org. Lett.	56	Giri, R	FALSE	FALSE	FALSE	FALSE
5010	10.1021/ja4109616	doi.org/10.1021/ja4109616	Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols		J. Am. Chem. Soc.	56	Norrby, PO	FALSE	FALSE	FALSE	FALSE
5011	10.1021/om4010737	doi.org/10.1021/om4010737	Nickel(II)-Catalyzed Cross-Coupling Polycondensation of Thiophenes via C-S Bond Cleavage		Organometallics	56	Mori, A	FALSE	FALSE	FALSE	FALSE
5012	10.1039/c4ra06055e	doi.org/10.1039/c4ra06055e	Pd-catalyzed oxidative C-H arylation of heterocycle embedded thiophene/furan with aryl boronic acid/ester		RSC Adv.	56	Nagarajan, NS	FALSE	FALSE	FALSE	FALSE
5013	10.1016/j.tetlet.2013.08.018	doi.org/10.1016/j.tetlet.2013.08.018	Nickel(II) thiosemicarbazone complex catalyzed Mizoroki-Heck reaction		Tetrahedron Lett.	56	Sridevi, VS	FALSE	FALSE	FALSE	FALSE
5014	10.1080/07328303.2013.816851	doi.org/10.1080/07328303.2013.816851	Copper-Catalyzed Synthesis of N-aryl-D-Glucosamines from Arylboronic Acids		J. Carbohydr. Chem.	56	Tao, CZ	FALSE	FALSE	FALSE	FALSE
5015	10.1021/ol401416r	doi.org/10.1021/ol401416r	Interrupted Fischer-Indole Intermediates via Oxyarylation of Alkenyl Boronic Acids		Org. Lett.	56	Anderson, LL	FALSE	FALSE	FALSE	FALSE
5016	10.1021/jo400378g	doi.org/10.1021/jo400378g	Intermolecular Enantioselective Heck-Matsuda Arylations of Acyclic Olefins: Application to the Synthesis of beta-Aryl-gamma-lactones and beta-Aryl Aldehydes		J. Org. Chem.	56	Correia, CRD	FALSE	FALSE	FALSE	FALSE
5017	10.2174/1389557511313060003	doi.org/10.2174/1389557511313060003	Nickel and Cobalt-Catalyzed Coupling of Alkyl Halides with Alkenes via Heck Reactions and Radical Conjugate Addition		Mini-Rev. Med. Chem.	56	Gong, HG	FALSE	FALSE	FALSE	FALSE
5018	10.1016/j.poly.2013.01.010	doi.org/10.1016/j.poly.2013.01.010	Synthesis, characterization, structure, redox property, antibacterial and catalytic activity of tridentate Schiff base cobalt(III), nickel(II) and palladium(II) complexes		Polyhedron	56	Pattanayak, P	FALSE	FALSE	FALSE	FALSE
5019	10.1002/ajoc.201200185	doi.org/10.1002/ajoc.201200185	Nickel-catalyzed Hydrodecyanation of Carbon-Cyano Bonds		Asian J. Org. Chem.	56	Enthaler, S	FALSE	FALSE	FALSE	FALSE
5020	10.1039/c3sc00090g	doi.org/10.1039/c3sc00090g	Evidence for a preferential intramolecular oxidative addition in Ni-catalyzed cross-coupling reactions and their impact on chain-growth polymerizations		Chem. Sci.	56	McNeil, AJ	FALSE	FALSE	FALSE	FALSE
5021	10.1002/adsc.201200624	doi.org/10.1002/adsc.201200624	Batch Stille Coupling with Insoluble and Recyclable Stannylated Polynorbornenes		Adv. Synth. Catal.	56	Albeniz, AC	FALSE	FALSE	FALSE	FALSE
5022	10.1021/jo300547v	doi.org/10.1021/jo300547v	Comparison of Arylboron-Based Nucleophiles in Ni-Catalyzed Suzuki-Miyaura Cross-Coupling with Aryl Mesylates and Sulfamates		J. Org. Chem.	56	Percec, V	FALSE	FALSE	FALSE	FALSE
5023	10.1021/jo3001194	doi.org/10.1021/jo3001194	trans-Chloro(1-Naphthyl)bis(triphenylphosphine)nickel(II)/PCy3 Catalyzed Cross-Coupling of Aryl and Heteroaryl Neopentylglycolboronates with Aryl and Heteroaryl Mesylates and Sulfamates at Room Temperature		J. Org. Chem.	56	Percec, V	FALSE	FALSE	FALSE	FALSE
5024	10.1021/ol3000519	doi.org/10.1021/ol3000519	Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles		Org. Lett.	56	Stahl, SS	FALSE	FALSE	FALSE	FALSE
5025	10.1039/c1ob06739g	doi.org/10.1039/c1ob06739g	Copper-catalyzed C-alkylation of secondary alcohols and methyl ketones with alcohols employing the aerobic relay race methodology		Org. Biomol. Chem.	56	Xu, Q	FALSE	FALSE	FALSE	FALSE
5026	10.1021/jo1025157	doi.org/10.1021/jo1025157	Study of the Stereoselectivity of 2-Azido-2-deoxygalactosyl Donors: Remote Protecting Group Effects and Temperature Dependency		J. Org. Chem.	56	Li, ZT	FALSE	FALSE	FALSE	FALSE
5027	10.1002/adsc.201100134	doi.org/10.1002/adsc.201100134	A Highly Active and Recyclable Catalyst: Phosphine Dendrimer-Stabilized Nickel Nanoparticles for the Suzuki Coupling Reaction		Adv. Synth. Catal.	56	Wu, L	FALSE	FALSE	FALSE	FALSE
5028	10.1055/s-0030-1258545	doi.org/10.1055/s-0030-1258545	Recyclable NHC-Ni Complex Immobilized on Magnetite/Silica Nanoparticles for C-S Cross-Coupling of Aryl Halides with Thiols		Synlett	56	Jun, BH	FALSE	FALSE	FALSE	FALSE
5029	10.1021/jo1006152	doi.org/10.1021/jo1006152	Iridium-Catalyzed Enantioselective Allylic Substitution of O-Allyl Carbamothioates		J. Org. Chem.	56	You, SL	FALSE	FALSE	FALSE	FALSE
5030	10.1016/j.tetlet.2010.03.110	doi.org/10.1016/j.tetlet.2010.03.110	Copper-free palladium-catalyzed Sonogashira and Hiyama cross-couplings using aryl imidazol-1-ylsulfonates		Tetrahedron Lett.	56	Williams, SJ	FALSE	FALSE	FALSE	FALSE
5031	10.1002/chem.201000032	doi.org/10.1002/chem.201000032	Kumada-Corriu Cross-Couplings with 2-Pyridyl Grignard Reagents		Chem.-Eur. J.	56	Ackermann, L	FALSE	FALSE	FALSE	FALSE
5032	10.1016/j.cbpa.2009.09.013	doi.org/10.1016/j.cbpa.2009.09.013	Recent progress in chemical and chemoenzymatic synthesis of carbohydrates		Curr. Opin. Chem. Biol.	56	Chen, X	FALSE	FALSE	FALSE	FALSE
5033	10.1016/j.tet.2008.01.050	doi.org/10.1016/j.tet.2008.01.050	[RuCl3(H2O)(n)]-catalyzed direct arylations		Tetrahedron	56	Ackermann, L	FALSE	FALSE	FALSE	FALSE
5034	10.1002/anie.200803193	doi.org/10.1002/anie.200803193	A General Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Mesylates		Angew. Chem.-Int. Edit.	56	Kwong, FY	FALSE	FALSE	FALSE	FALSE
5035	10.1021/jo0709448	doi.org/10.1021/jo0709448	Ni(II)-(sigma-Aryl) complex: A facile, efficient catalyst for nickel-catalyzed carbon-nitrogen coupling reactions		J. Org. Chem.	56	Yang, LM	FALSE	FALSE	FALSE	FALSE
5036	10.1016/j.jorganchem.2004.12.022	doi.org/10.1016/j.jorganchem.2004.12.022	Di-t-butyl(ferrocenylmethyl)phosphine: air-stability, structural characterization, coordination chemistry, and application to palladium-catalyzed cross-coupling reactions		J. Organomet. Chem.	56	Shaughnessy, KH	FALSE	FALSE	FALSE	FALSE
5037	10.1002/adsc.200404297	doi.org/10.1002/adsc.200404297	Synthesis of coumarins in a molten n-Bu4NOAc/n-Bu4NBr mixture through a domino Heck reaction/cyclization process		Adv. Synth. Catal.	56	Cacchi, S	FALSE	FALSE	FALSE	FALSE
5038	10.1002/chem.200305340	doi.org/10.1002/chem.200305340	Ruthenium-catalyzed one-pot double allylation/cycloisomerization of 1,3-dicarbonyl compounds leading to exo-methylenecyclopentanes		Chem.-Eur. J.	56	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
5039	10.1021/ma0347114	doi.org/10.1021/ma0347114	Highly branched polyphenylenes with 1,3,5-triphenylbenzene fragments via cyclocondensation of acetylaromatic compounds and Ni-0-catalyzed dehalogenation: Synthesis and light emission		Macromolecules	56	Khotina, IA	FALSE	FALSE	FALSE	FALSE
5040	10.1021/jo026746s	doi.org/10.1021/jo026746s	Functionalized arylzinc compounds in ethereal solvent: Direct synthesis from aryl iodides and zinc powder and application to Pd-catalyzed reaction with allylic halides		J. Org. Chem.	56	Takagi, K	FALSE	FALSE	FALSE	FALSE
5041	10.1021/jo010452+	doi.org/10.1021/jo010452+	Nickel-catalyzed cross-couplings of 4-diethylphosphonooxycoumarins with organozinc reagents: An efficient new methodology for the synthesis of 4-substituted coumarins		J. Org. Chem.	56	Yang, Z	FALSE	FALSE	FALSE	FALSE
5042	10.1021/jo00018a016	doi.org/10.1021/jo00018a016	TRANSITION-METAL PROMOTED REACTIONS .38. NICL2(DPPE)-CATALYZED GEMINAL DIALKYLATION OF DITHIOACETALS AND TRIMETHYLATION OF ORTHO THIOESTERS		J. Org. Chem.	56		FALSE	FALSE	FALSE	FALSE
5043	10.1021/ja00255a017	doi.org/10.1021/ja00255a017	SPONTANEOUS AND OLEFIN-PROMOTED REDUCTIVE ELIMINATION OF ETA-3-ALLYL(ORGANO)PALLADIUM(II) COMPLEXES - MECHANISTIC AND MOLECULAR-ORBITAL ANALYSIS		J. Am. Chem. Soc.	56	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
5044	10.1039/d2ob00065b	doi.org/10.1039/d2ob00065b	Palladium-catalyzed cyclizative cross coupling of ynone oximes with 2-haloaryl N-acrylamides for isoxazolyl indoline bis-heterocycles		Org. Biomol. Chem.	56	Reddy, MS	FALSE	FALSE	FALSE	FALSE
5045	10.1039/d2cc00127f	doi.org/10.1039/d2cc00127f	Hydride transfer-initiated synthesis of 3-functionalized quinolines by deconstruction of isoquinoline derivatives		Chem. Commun.	56	Zhang, M	FALSE	FALSE	FALSE	FALSE
5046	10.1039/d2cp00105e	doi.org/10.1039/d2cp00105e	Theoretical study of Ni-I-Ni-III cycle mediated by heterogeneous zinc in C-N cross-coupling reaction		Phys. Chem. Chem. Phys.	56	Guan, W	FALSE	FALSE	FALSE	FALSE
5047	10.1002/slct.202104114	doi.org/10.1002/slct.202104114	SO2F2-Promoted Dehydroxylative Fluorination of Alcohols		ChemistrySelect	56	Ding, CR	FALSE	FALSE	FALSE	FALSE
5048	10.1021/acs.joc.1c02435	doi.org/10.1021/acs.joc.1c02435	Iron-Catalyzed Oxidative Cross-Coupling of Phenols and Tyrosine Derivatives with 3-Alkyloxindoles		J. Org. Chem.	56	Pappo, D	FALSE	FALSE	FALSE	FALSE
5049	10.1039/d1sc05913k	doi.org/10.1039/d1sc05913k	Reusable Co-nanoparticles for general and selective N-alkylation of amines and ammonia with alcohols		Chem. Sci.	56	Beller, M; Jagadeesh, RV	FALSE	FALSE	FALSE	FALSE
5050	10.1038/s41467-021-26843-2	doi.org/10.1038/s41467-021-26843-2	Asymmetric radical carboesterification of dienes		Nat. Commun.	56	Bao, HL	FALSE	FALSE	FALSE	FALSE
5051	10.1021/acs.joc.1c01866	doi.org/10.1021/acs.joc.1c01866	Visible-Light-Induced Multicomponent Cascade Cycloaddition of N-Propargyl Aromatic Amines, Cyclobutanone Oxime Esters, and K2S2O5: Access to Cyanoalkylsulfonylated Quinolines		J. Org. Chem.	56	Zhou, NN	FALSE	FALSE	FALSE	FALSE
5052	10.1002/adsc.202101077	doi.org/10.1002/adsc.202101077	Nickel-Catalyzed Selective Synthesis of alpha-Alkylated Ketones via Dehydrogenative Cross-Coupling of Primary and Secondary Alcohols		Adv. Synth. Catal.	56	Adhikari, D	FALSE	FALSE	FALSE	FALSE
5053	10.1021/acs.orglett.1c02054	doi.org/10.1021/acs.orglett.1c02054	Iridium(III) Catalyzed Z-Selective Allylic Arylation of alpha-Fluoro But-1-enoic Acid Amides via beta-F-Elimination in Water		Org. Lett.	56	Bouzbouz, S	FALSE	FALSE	FALSE	FALSE
5054	10.1021/acs.orglett.1c02874	doi.org/10.1021/acs.orglett.1c02874	Nickel-Catalyzed Cross-Electrophile C(sp(3))-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes		Org. Lett.	56	Shu, XZ	FALSE	TRUE	FALSE	FALSE
5055	10.1039/d1ob01409a	doi.org/10.1039/d1ob01409a	NaOTs-promoted transition metal-free C-N bond cleavage to form C-X (X = N, O, S) bonds		Org. Biomol. Chem.	56	Zeng, Z	FALSE	FALSE	FALSE	FALSE
5056	10.1007/s12274-021-3694-3	doi.org/10.1007/s12274-021-3694-3	Well-defined coordination environment breaks the bottleneck of organic synthesis: Single-atom palladium catalyzed hydrosilylation of internal alkynes		Nano Res.	56	Tang, HT	FALSE	FALSE	FALSE	FALSE
5057	10.1038/s41929-021-00658-2	doi.org/10.1038/s41929-021-00658-2	Olefin functionalization/isomerization enables stereoselective alkene synthesis		Nat. Catal.	56	Koh, MJ	FALSE	FALSE	FALSE	FALSE
5058	10.1055/s-0040-1720350	doi.org/10.1055/s-0040-1720350	Direct Access to S-Heterocycles by Scandium(III) Triflate Catalyzed Cyclization of Aromatic Thiols and Diols		Synlett	56	Minakawa, M	FALSE	FALSE	FALSE	FALSE
5059	10.1002/anie.202105800	doi.org/10.1002/anie.202105800	Enantio- and Diastereodivergent Sequential Catalysis Featuring Two Transition-Metal-Catalyzed Asymmetric Reactions		Angew. Chem.-Int. Edit.	56	Lautens, M	FALSE	FALSE	FALSE	FALSE
5060	10.1021/acs.orglett.1c01734	doi.org/10.1021/acs.orglett.1c01734	SuFExable Isocyanides for Ugi Reaction: Synthesis of Sulfonyl Fluoro Peptides		Org. Lett.	56	Cui, SL	FALSE	FALSE	FALSE	FALSE
5061	10.1002/adsc.202100219	doi.org/10.1002/adsc.202100219	Ir(NHC)-Catalyzed Synthesis of beta-Alkylated Alcohols via Borrowing Hydrogen Strategy: Influence of Bimetallic Structure		Adv. Synth. Catal.	56	Jang, HY	FALSE	FALSE	FALSE	FALSE
5062	10.1021/acs.orglett.1c00782	doi.org/10.1021/acs.orglett.1c00782	Nickel-Catalyzed Guerbet Type Reaction: C-Alkylation of Secondary Alcohols via Double (de)Hydrogenation		Org. Lett.	56	Balaraman, E	FALSE	FALSE	FALSE	FALSE
5063	10.1021/jacs.1c02117	doi.org/10.1021/jacs.1c02117	Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis		J. Am. Chem. Soc.	56	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
5064	10.1021/acscatal.0c05557	doi.org/10.1021/acscatal.0c05557	Cobalt-Catalyzed Coupling of Aryl Chlorides with Aryl Boron Esters Activated by Alkoxides		ACS Catal.	56	Bedford, RB	FALSE	FALSE	FALSE	FALSE
5065	10.1021/acs.orglett.7b02326	doi.org/10.1021/acs.orglett.7b02326	Copper-Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amides		Org. Lett.	56	Ma, DW	FALSE	FALSE	FALSE	FALSE
5066	10.1002/aoc.3705	doi.org/10.1002/aoc.3705	Palladium-catalyzed reductive homocoupling of aryl sulfonates via cleavage of CO bond at room temperature		Appl. Organomet. Chem.	56	Zhong, SL; Liu, WC	FALSE	FALSE	FALSE	FALSE
5067	10.1021/acs.orglett.7b01938	doi.org/10.1021/acs.orglett.7b01938	Nickel-Catalyzed Coupling of Azoles with Aromatic Nitriles		Org. Lett.	56	Kalyani, D	FALSE	FALSE	FALSE	FALSE
5068	10.1021/acs.orglett.7b01070	doi.org/10.1021/acs.orglett.7b01070	Enantioselective Synthesis of gem-Diaryl Benzofuran-3(2H)-ones via One-Pot Asymmetric Rhodium/Palladium Relay Catalysis		Org. Lett.	56	Xu, B	FALSE	FALSE	FALSE	FALSE
5069	10.1002/adsc.201601271	doi.org/10.1002/adsc.201601271	Nickel Catalysis Enables Hetero [2+2+1] Cycloaddition between Yne-Isothiocyanates and Isonitriles with Low Catalyst Loading		Adv. Synth. Catal.	56	Wen, LR; Li, M	FALSE	FALSE	FALSE	FALSE
5070	10.1021/jacs.7b00643	doi.org/10.1021/jacs.7b00643	Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction		J. Am. Chem. Soc.	56	Ding, YJ; Zhan, ZP	FALSE	FALSE	FALSE	FALSE
5071	10.1021/acscatal.6b03543	doi.org/10.1021/acscatal.6b03543	Mechanism and Origin of Et2Al(OEt)-Induced Chemoselectivity of Nickel-Catalyzed Three-Component Coupling of One Diketene and Two Alkynes		ACS Catal.	56	Bi, SW	FALSE	FALSE	FALSE	FALSE
5072	10.1002/anie.201609844	doi.org/10.1002/anie.201609844	Catalytic Enantioselective Arylboration of Alkenylarenes		Angew. Chem.-Int. Edit.	56	Brown, MK	FALSE	FALSE	FALSE	FALSE
5073	10.1016/j.tetasy.2016.10.007	doi.org/10.1016/j.tetasy.2016.10.007	Enantioselective nitromethane addition to brominated and fluorinated benzaldehydes (Henry reaction) catalyzed by chiral bisoxazoline-copper(II) complexes		Tetrahedron-Asymmetry	56	Aguirre, G	FALSE	FALSE	FALSE	FALSE
5074	10.1021/acs.orglett.6b03306	doi.org/10.1021/acs.orglett.6b03306	N-Heterocyclic Carbene-Catalyzed Construction of 1,3,5-Trisubstituted Benzenes from Bromoenals and alpha-Cyano-beta-methylenones		Org. Lett.	56	Ye, S	FALSE	FALSE	FALSE	FALSE
5075	10.1002/adsc.201600549	doi.org/10.1002/adsc.201600549	Ligand-Free Copper-Manganese Spinel Oxide-Catalyzed Tandem One-Pot C-H Amidation and N-Arylation of Benzylamines: A Facile Access to 2-Arylquinazolin-4(3H)-ones		Adv. Synth. Catal.	56	Bharate, SB	FALSE	FALSE	FALSE	FALSE
5076	10.1021/jacs.6b08075	doi.org/10.1021/jacs.6b08075	Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity		J. Am. Chem. Soc.	56	Watson, MP	FALSE	FALSE	FALSE	FALSE
5077	10.1002/aoc.3507	doi.org/10.1002/aoc.3507	Nicotine functionalized-silica palladium (II) complex: a highly efficient, environmentally benign and recyclable nanocatalyst for C-C bond forming reactions under mild conditions		Appl. Organomet. Chem.	56	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
5078	10.1248/cpb.c16-00282	doi.org/10.1248/cpb.c16-00282	Synthesis of Dendrimers with a Bidentate Phosphine Core Ligand Having Carboxy Groups at the Peripheral Layer and Their Application to Aqueous Media Cross-Coupling Reactions		Chem. Pharm. Bull.	56	Fujita, K	FALSE	FALSE	FALSE	FALSE
5079	10.1055/s-0035-1561602	doi.org/10.1055/s-0035-1561602	Indium(III) Chloride Promoted Highly Efficient Tandem Rearrangement-alpha-Addition Strategy towards the Synthesis of alpha-Hydroxyamides		Synlett	56	Prapurna, YL	FALSE	FALSE	FALSE	FALSE
5080	10.1021/acs.accounts.0c00745	doi.org/10.1021/acs.accounts.0c00745	Importance of Engineered and Learned Molecular Representations in Predicting Organic Reactivity, Selectivity, and Chemical Properties	Synthesis and characterization of the new air-stable pre-catalyst (DPEPhos)Ni(2-mesityl)Br (C1) is reported, along with the application of this pre-catalyst in the cross-coupling of secondary amines/azoles with activated (hetero) aryl chlorides to afford tertiary (hetero) anilines. The performance of C1 in these cross-couplings is competitive with some of the best and/or most widely employed nickel catalysts for such transformations.	Accounts Chem. Res.	55	Paton, RS	FALSE	FALSE	FALSE	FALSE
5081	10.1038/s41929-020-00564-z	doi.org/10.1038/s41929-020-00564-z	The amine-catalysed Suzuki-Miyaura-type coupling of aryl halides and arylboronic acids	Aryl carbamates were employed in the nickel-catalyzed monoarylation of ammonia. The applied, well-defined single-component nickel(II) precatalyst contains a Josiphos ligand, is air-stable, and operates without any ancillary reductant. This catalyst system also promotes the amination of aryl carbamates with ammonium sulfate as well as with hydrochloride salts of primary alkylamines. Their easy preparation, robustness, and directing group ability makes aryl carbamates particularly attractive synthetic intermediates.	Nat. Catal.	55	Xu, HJ	FALSE	FALSE	FALSE	FALSE
5082	10.1021/acscatal.0c04280	doi.org/10.1021/acscatal.0c04280	Pd-Catalyzed Cross-Coupling of Hindered, Electron-Deficient Anilines with Bulky (Hetero)aryl Halides Using Biaryl Phosphorinane Ligands	Detailed kinetic studies of the reaction of a model Ni-0 complex with a range of aryl electrophiles have been conducted. The reactions proceed via a fast ligand exchange pre-equilibrium, followed by oxidative addition to produce either [(NiX)-X-I(dppf)] (and biaryl) or [Ni-II(Ar)X(dppf)]; the ortho substituent of the aryl halide determines selectivity between these possibilities. A reactivity scale is presented in which a range of substrates is quantitatively ranked in order of the rate at which they undergo oxidative addition. The rate of oxidative addition is loosely correlated to conversion in prototypical cross-coupling reactions. Substrates that lead to Ni-I products in kinetic experiments conditions. produce more homocoupling products under catalytic	ACS Catal.	55	Shekhar, S	FALSE	TRUE	FALSE	FALSE
5083	10.1039/d0cy01008a	doi.org/10.1039/d0cy01008a	Mechanistic insight into the azo radical-promoted dehydrogenation of heteroarene towards N-heterocycles	A novel cobalt-promoted arylation of aryl C-H bonds with aryl-boronic acids has been realized by using 8-aminoquinoline as the directing group. The reaction tolerated a wide variety of functional groups and diversely substituted ortho-arylated benzamides were efficiently synthesized in good to excellent yields. Even though a catalytic amount of a Co-salt was enough to effect the transformation, better yields were obtained with a stoichiometric amount of the Co-salt. A notable feature of this newly developed protocol is that acrylamides, which cannot be arylated using copper salts as the promoter, can also be efficiently arylated. In addition, the stereochemistry of these arylation products can be largely retained under the standard conditions.	Catal. Sci. Technol.	55	Adhikari, D	FALSE	FALSE	FALSE	FALSE
5084	10.1021/acs.joc.0c01632	doi.org/10.1021/acs.joc.0c01632	Tungsten-Catalyzed Allylic Substitution with a Heteroatom Nucleophile: Reaction Development and Synthetic Applications	Study of the kinetics of intramolecular aryl ether C-O bond cleavage by Ni was facilitated by access to a family of metal complexes supported by diphosphines with pendant aryl-methyl ethers. The nature of the aryl substituents was found to have little effect on the rate of cleavage. In contrast, soluble Lewis acidic additives accelerate the aryl ether cleavage dramatically. The effect of AlMe3 was studied in detail, and showed an increase in rate by several orders of magnitude. Low temperature NMR spectroscopy studies demonstrate quantitative coordination of ether to Al. From the Lewis acid-bound precursor, the activation parameters for ether cleavage are significantly lower. These findings provide a mechanistic basis for milder catalyst design for the activation of strong bonds.	J. Org. Chem.	55	Khan, A	FALSE	FALSE	FALSE	FALSE
5085	10.1039/d0cc03309j	doi.org/10.1039/d0cc03309j	Palladium/copper-cocatalyzed decarbonylative alkynylation of acyl fluorides with alkynylsilanes: synthesis of unsymmetrical diarylethynes	A family of CoCl2(PNpy) complexes were prepared, where PNpy = 2-iminopyridyl-phosphine ligands derived from amino-alkyl and aminoaryl phosphines and 2-keto- and 2-formylpyridines. Reduction of CoCl2(PNpy) complexes in the presence of PPh3 gave CoH(PNpy)(PPh3) and CoMe(PNpy)(PPh3), which were active for hydrofunctionalization of alkenes. According to DFT calculations, the CoMe(PNpy)(PPh3) complexes are best described as Co (II) derivatives of the anion [PNpy](-), with a labile PPh3 coligand. Metalation of Na[(Ph2)PC(2)N(H)py] gave the dimers [CoCl2(P(C2)N(H)py)](2). Monomeric complexes catalyze hydrosilylation of 1-octene with Ph2SiH2, with the CoCl2 ((iPr2)P(C3)N(H)py)/2NaBEt(3)H system exhibiting the highest rate and selectivity for anti-Markovnikov product. In situ NMR studies established the following: (i) silanes protonolyze catalyst precursors to give the. Co-silylcomplexes Co (SiR3) ((Ph2)P(C6H4)N(Ph)py)(pph(3)), (ii) alkenes compete with PPh3 to give Co(SiHPh2)((Ph2)P(C6H4)N(Ph)py) (eta(2)-alkene), (iii) ethylene inserts into the Co-Si bond to give Co(CH2CH3SiR3)((Ph2)P(C6H4)N(Ph)py)(pph(3)).	Chem. Commun.	55	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
5086	10.1021/acs.orglett.0c01683	doi.org/10.1021/acs.orglett.0c01683	Allylboronates from Vinyl Triflates and alpha-Chloroboronates by Reductive Nickel Catalysis	Despite the number of methods available for dehalogenation and carbon-carbon bond formation using aryl halides, strategies that provide ohemoselectivity for systems bearing multiple carbon-halogen bonds are still needed. Herein, we report the ability to tune the reduction potential of metal-free phenothiazine-based photoredox catalysts and demonstrate the application of these catalysts for chemoselective carbon-halogen bond activation to achieve C-C cross-coupling reactions as well as reductive dehalogenations. This procedure works both for conjugated polyhalides as well as unconjugated substrates. We further illustrate the usefulness of this protocol by intrarnolectilar cyclization of a pyrrole substrate, an advanced building block for a family of natural products known to exhibit biological activity.	Org. Lett.	55	Shu, XZ	FALSE	FALSE	FALSE	FALSE
5087	10.1016/j.apcata.2020.117536	doi.org/10.1016/j.apcata.2020.117536	Highly efficient one-pot multi-directional selective hydrogenation and N-alkylation catalyzed by Ru/LDH under mild conditions	BACKGROUNDEvaluation of 4-phenylphenalenones and structural analogues against the fungal pathogen Mycosphaerella fijiensis (causal agent of black sigatoka disease in bananas) under light-controlled conditions uncovered some key structural features for the design of photodynamic compounds. RESULTSStructure-activity relationship analysis revealed the importance of a chromophoric aryl-ketone and a steroidomimetic structural motif in the activity of the assayed compounds. The results pointed to 1,2-dihydro-3H-naphtho[2,1:3,4]cyclohepta[1,2-b]furan-3-one, which displayed an activity in the range of propiconazole but with photodynamic behaviour. CONCLUSIONThe present work demonstrates that 1,2-dihydro-3H-naphtho[2,1:3,4]cyclohepta[1,2-b]heterocyclic-3-one derivatives can be used as potential lead compounds for the development of fungicides, relying on a dual mode of action. (c) 2015 Society of Chemical Industry	Appl. Catal. A-Gen.	55	Jiang, HY; Bian, FX	FALSE	FALSE	FALSE	FALSE
5088	10.1021/acs.jpcb.0c01123	doi.org/10.1021/acs.jpcb.0c01123	Design and Photo-Induced Dynamics of Radical-Chromophore Adducts with One- or Two-Atom Separation: Toward Potential Probes for High Field Optical DNP Experiments	Nickel-catalyzed selective cross-coupling of aromatic electrophiles (bromides, chlorides, fluorides and methyl ethers) with organolithium reagents is presented. The use of a commercially available nickel N-heterocyclic carbene (NHC) complex allows the reaction with a variety of (hetero)aryllithium compounds, including those prepared via metal-halogen exchange or direct metallation, whereas a commercially available electron-rich nickel-bisphosphine complex smoothly converts alkyllithium species into the corresponding coupled product. These reactions proceed rapidly (1h) under mild conditions (room temperature) while avoiding the undesired formation of reduced or homocoupled products.	J. Phys. Chem. B	55	Rane, V	TRUE	FALSE	FALSE	FALSE
5089	10.1002/anie.201914315	doi.org/10.1002/anie.201914315	Rational Design of an Iron-Based Catalyst for Suzuki-Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles	A complementary set of Ni- and Cu-based catalyst systems for the selective N-arylation of 2-aminobenzimidazoles have been developed. Selective N-arylation of the primary amine (C-NH2) group was achieved by Ni-catalyzed, boronic acid promoted cross-coupling reactions in air, whereas, selective N-arylation of the azole nitrogen was achieved with Cu-catalysis and aryl halides. These protocols are general and give rapid access to an array of both the N-arylated isomers of 2-aminobenzimidazoles.	Angew. Chem.-Int. Edit.	55	Byers, JA	FALSE	TRUE	FALSE	FALSE
5090	10.1039/c9cc07558e	doi.org/10.1039/c9cc07558e	Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction		Chem. Commun.	55	Rueping, M	FALSE	FALSE	FALSE	FALSE
5091	10.1021/acs.orglett.9b04092	doi.org/10.1021/acs.orglett.9b04092	Synergistic Copper-Catalyzed Reductive.Aminocarbonylation of Alkyl Iodides with Nitroarenes		Org. Lett.	55	Mankad, NP	FALSE	FALSE	FALSE	FALSE
5092	10.1002/chem.201904053	doi.org/10.1002/chem.201904053	The Nargenicin Family of Oxa-Bridged Macrolide Antibiotics		Chem.-Eur. J.	55	Pidot, SJ	FALSE	FALSE	FALSE	FALSE
5093	10.1002/anie.201913062	doi.org/10.1002/anie.201913062	Nickel-Catalyzed 1,2-Diarylation of Alkenyl Carboxylates: A Gateway to 1,2,3-Trifunctionalized Building Blocks		Angew. Chem.-Int. Edit.	55	Engle, KM	FALSE	FALSE	FALSE	FALSE
5094	10.1002/adsc.201901203	doi.org/10.1002/adsc.201901203	Regioselective Iron-Catalysed Cross-Coupling Reaction of Aryl Propargylic Bromides and Aryl Grignard Reagents		Adv. Synth. Catal.	55	Quiros, MT; Cardenas, DJ	FALSE	FALSE	FALSE	FALSE
5095	10.1016/j.jorganchem.2019.120937	doi.org/10.1016/j.jorganchem.2019.120937	Synthesis and structural characterization of nickel(II) complexes of 20-membered macrocyclic rings bearing chelating bis(N-heterocyclic carbene) ligands		J. Organomet. Chem.	55	Kilyanek, SM	FALSE	FALSE	FALSE	FALSE
5096	10.1039/c9sc03429c	doi.org/10.1039/c9sc03429c	Expedient access to saturated nitrogen heterocycles by photoredox cyclization of imino-tethered dihydropyridines		Chem. Sci.	55	Romanov-Michailidis, F	FALSE	FALSE	FALSE	FALSE
5097	10.1002/cssc.201801660	doi.org/10.1002/cssc.201801660	C-Alkylation of Secondary Alcohols by Primary Alcohols through Manganese-Catalyzed Double Hydrogen Autotransfer		ChemSusChem	55	El-Sepelgy, O; Rueping, M	FALSE	FALSE	FALSE	FALSE
5098	10.1016/j.ijhydene.2019.03.114	doi.org/10.1016/j.ijhydene.2019.03.114	Enhancing hydrogen storage properties of the Mg/MgH2 system by the addition of bis(tricyclohexylphosphine)nickel(II) dichloride		Int. J. Hydrog. Energy	55	Postole, G	FALSE	FALSE	FALSE	FALSE
5099	10.1002/anie.201814524	doi.org/10.1002/anie.201814524	Quaternary Centers by Nickel-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and (Hetero)Aryl Zinc Reagents		Angew. Chem.-Int. Edit.	55	Baran, PS	FALSE	FALSE	FALSE	FALSE
5100	10.1002/ejoc.201801690	doi.org/10.1002/ejoc.201801690	Rh-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to 3-Arylpropenoates: Enantioselective Synthesis of (R)-Tolterodine		Eur. J. Org. Chem.	55	Iuliano, A	FALSE	FALSE	FALSE	FALSE
5101	10.1038/s42004-018-0107-y	doi.org/10.1038/s42004-018-0107-y	Nickel-catalyzed remote and proximal Wacker-type oxidation		Comm. Chem.	55	Han, W	FALSE	FALSE	FALSE	FALSE
5102	10.1021/acscatal.8b03979	doi.org/10.1021/acscatal.8b03979	Access to Enantioenriched Benzylic 1,1-Silylboronate Esters by Palladium-Catalyzed Enantiotopic-Group Selective Suzuki-Miyaura Coupling of (Diborylmethyl)silanes with Aryl Iodides		ACS Catal.	55	Cho, SH	FALSE	FALSE	FALSE	FALSE
5103	10.1002/celc.201800422	doi.org/10.1002/celc.201800422	Direct Anodic Dehydrogenative Cross- and Homo-Coupling of Formanilides		ChemElectroChem	55	Waldvogel, SR	FALSE	FALSE	FALSE	FALSE
5104	10.1039/c8nj00530c	doi.org/10.1039/c8nj00530c	Revisiting 1-chloro-1,2-benziodoxol-3-one: efficient ortho-chlorination of aryls under aqueous conditions		New J. Chem.	55	Chandrasekharam, M	FALSE	FALSE	FALSE	FALSE
5105	10.1021/acscatal.8b01005	doi.org/10.1021/acscatal.8b01005	Application of Diazaphospholidine/Diazaphospholene-Based Bisphosphines in Room-Temperature Nickel-Catalyzed C(sp(2))-N Cross-Couplings of Primary Alkylamines with (Hetero)aryl Chlorides and Bromides		ACS Catal.	55	Speed, AWH; Stradiotto, M	FALSE	FALSE	FALSE	FALSE
5106	10.1007/s10570-018-1815-2	doi.org/10.1007/s10570-018-1815-2	Design and preparation of a cellulose-based adsorbent modified by imidazolium ionic liquid functional groups and their studies on anionic dye adsorption		Cellulose	55	Zhang, SF; Qian, LW	FALSE	FALSE	FALSE	FALSE
5107	10.1021/acscatal.8b01224	doi.org/10.1021/acscatal.8b01224	Cross-Coupling of Phenol Derivatives with Umpolung Aldehydes Catalyzed by Nickel		ACS Catal.	55	Li, CJ	FALSE	FALSE	FALSE	FALSE
5108	10.1021/acs.orglett.8b00360	doi.org/10.1021/acs.orglett.8b00360	Transition-Metal-Free Formylation of Allylzinc Reagents Leading to alpha-Quaternary Aldehydes		Org. Lett.	55	Haraguchi, R; Fukuzawa, S	FALSE	FALSE	FALSE	FALSE
5109	10.1021/acs.orglett.7b03560	doi.org/10.1021/acs.orglett.7b03560	Nickel Phosphite/Phosphine-Catalyzed C-S Cross-Coupling of Aryl Chlorides and Thiols		Org. Lett.	55	Stewart, SG	FALSE	FALSE	FALSE	FALSE
5110	10.2533/chimia.2018.212	doi.org/10.2533/chimia.2018.212	Transforming Olefins into Dinucleophiles		Chimia	55	Nevado, C	FALSE	FALSE	FALSE	FALSE
5111	10.1039/c7ra12716b	doi.org/10.1039/c7ra12716b	Catalyst- and solvent-free approach to 2-arylated quinolines via [5+1] annulation of 2-methylquinolines with diynones		RSC Adv.	55	Liang, Y	FALSE	FALSE	FALSE	FALSE
5112	10.1055/s-0036-1588563	doi.org/10.1055/s-0036-1588563	Synthesis of Tetraarylmethanes by the Triflic Acid-Promoted Formal Cross-Dehydrogenative Coupling of Triarylmethanes with Arenes		Synlett	55	Nambo, M; Crudden, CM	FALSE	FALSE	FALSE	FALSE
5113	10.1002/aoc.3757	doi.org/10.1002/aoc.3757	Green synthesis of palladium nanoparticles using Hibiscus sabdariffa L. flower extract: Heterogeneous and reusable nanocatalyst in Suzuki coupling reactions		Appl. Organomet. Chem.	55	Hekmati, M	FALSE	FALSE	FALSE	FALSE
5114	10.1002/ajoc.201700342	doi.org/10.1002/ajoc.201700342	Metal-Catalyzed Synthesis of 1,1-Diarylethylene Scaffolds		Asian J. Org. Chem.	55	Hamze, A	FALSE	FALSE	FALSE	FALSE
5115	10.1021/acs.orglett.7b02166	doi.org/10.1021/acs.orglett.7b02166	Nickel-Catalyzed Synthesis of Stereochemically Defined Enamides via Bi- and Tricomponent Coupling Reaction		Org. Lett.	55	Bandini, M	FALSE	FALSE	FALSE	FALSE
5116	10.1039/c7sc02578e	doi.org/10.1039/c7sc02578e	Formal aromaticity transfer for palladiumcatalyzed coupling between phenols and pyrrolidines/indolines		Chem. Sci.	55	Li, CJ	FALSE	FALSE	FALSE	FALSE
5117	10.1039/c6ra07450b	doi.org/10.1039/c6ra07450b	Palladium-catalyzed ortho C-H bond alkylation of benzylamides with alpha-bromo ketones		RSC Adv.	55	Liang, G; Huang, LH	FALSE	FALSE	FALSE	FALSE
5118	10.1016/j.tet.2015.10.011	doi.org/10.1016/j.tet.2015.10.011	Palladium-catalyzed borylation of m-dibromobenzene derivative and its applications in one-pot tandem Suzuki-Miyaura arenes synthesis		Tetrahedron	55	Zhang, DQ	FALSE	FALSE	FALSE	FALSE
5119	10.1021/acscatal.5b01463	doi.org/10.1021/acscatal.5b01463	Nickel-Catalyzed Allylic C(sp(3))-F Bond Activation of Trifluoromethyl Groups via beta-Fluorine Elimination: Synthesis of Difluoro-1,4-dienes		ACS Catal.	55	Ichikawa, J	FALSE	FALSE	FALSE	FALSE
5120	10.1007/s10562-015-1558-8	doi.org/10.1007/s10562-015-1558-8	Palladium-Catalyzed Decarboxylative Csp(2)-Csp(2) Cross-Coupling Reactions: An Efficient Route for Synthesis of Azaisoflavone Derivatives		Catal. Lett.	55	Zhang, PF	FALSE	FALSE	FALSE	FALSE
5121	10.1002/ajoc.201500148	doi.org/10.1002/ajoc.201500148	Manganese-Catalyzed Alkyl-Heck-Type Reaction via Oxidative Decarbonylation of Aldehydes		Asian J. Org. Chem.	55	Li, ZP	FALSE	FALSE	FALSE	FALSE
5122	10.1021/acs.orglett.5b00990	doi.org/10.1021/acs.orglett.5b00990	Nickel-Catalyzed Direct Amination of Arenes with Alkylamines		Org. Lett.	55	Liu, ZX	FALSE	FALSE	FALSE	FALSE
5123	10.1016/j.tetlet.2015.01.131	doi.org/10.1016/j.tetlet.2015.01.131	Palladium-catalyzed decarboxylative cross-coupling of 3-pyridyl and 4-pyridyl carboxylates with aryl bromides		Tetrahedron Lett.	55	Chennamaneni, LR	FALSE	FALSE	FALSE	FALSE
5124	10.1016/j.carres.2014.07.004	doi.org/10.1016/j.carres.2014.07.004	Additive-controlled stereoselective glycosylations of 2,3-oxazolidinone protected glucosamine or galactosamine thioglycoside donors with phenols based on preactivation protocol		Carbohydr. Res.	55	Ye, XS	FALSE	FALSE	FALSE	FALSE
5125	10.1039/c4sc03106g	doi.org/10.1039/c4sc03106g	Cobalt co-catalysis for cross-electrophile coupling: diarylmethanes from benzyl mesylates and aryl halides		Chem. Sci.	55	Weix, DJ	FALSE	FALSE	FALSE	FALSE
5126	10.1039/c4cc08703h	doi.org/10.1039/c4cc08703h	Diboron as a reductant for nickel-catalyzed reductive coupling: rational design and mechanistic studies		Chem. Commun.	55	Huang, HM	FALSE	FALSE	FALSE	FALSE
5127	10.1002/adsc.201400624	doi.org/10.1002/adsc.201400624	Synthesis of Allylarenes via Catalytic Decarboxylation of Allyl Benzoates		Adv. Synth. Catal.	55	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
5128	10.1007/s10562-014-1345-y	doi.org/10.1007/s10562-014-1345-y	Metal Acetylacetonates Covalently Anchored onto Amine Functionalized Silica/Starch Composite for the One-Pot Thioetherification and Synthesis of 2H-Indazoles		Catal. Lett.	55	Paul, S	FALSE	FALSE	FALSE	FALSE
5129	10.1002/hc.21189	doi.org/10.1002/hc.21189	Selective Synthesis of Quinolines and Indoles: Sulfur-Assisted or Selenium-Catalyzed Reaction of beta-(2-Nitrophenyl)-alpha, beta-unsaturated Ketones with Carbon Monoxide		Heteroatom Chem.	55	Nishiyama, Y	FALSE	FALSE	FALSE	FALSE
5130	10.1039/c3dt53391c	doi.org/10.1039/c3dt53391c	DFT studies on the mechanism of palladium-catalyzed carbon-silicon cleavage for the synthesis of benzosilole derivatives		Dalton Trans.	55	Lin, ZY	FALSE	FALSE	FALSE	FALSE
5131	10.1002/ejoc.201402475	doi.org/10.1002/ejoc.201402475	Nickel-Catalyzed One-Pot Suzuki-Miyaura Cross-Coupling of Phenols and Arylboronic Acids Mediated by N,N-Ditosylaniline		Eur. J. Org. Chem.	55	Yu, JJ	FALSE	FALSE	FALSE	FALSE
5132	10.1021/cs500587b	doi.org/10.1021/cs500587b	Palladium-Catalyzed Intra- and Intermolecular C-H Arylation Using Mesylates: Synthetic Scope and Mechanistic Studies		ACS Catal.	55	Kalyani, D	FALSE	FALSE	FALSE	FALSE
5133	10.1002/jhet.1784	doi.org/10.1002/jhet.1784	L-Proline-Catalyzed Knoevenagel Condensation: A Tandem Synthesis of 3-Acetylcoumarinoindoles and Their N-Alkyl Derivatives by Using PEG-600 as the Reaction Medium		J. Heterocycl. Chem.	55	Venkatanarayana, M	FALSE	FALSE	FALSE	FALSE
5134	10.1021/ol500707w	doi.org/10.1021/ol500707w	Directed ortho Metalation Strategies. Effective Regioselective Routes to 1,2-, 2,3-, and 1,2,3-Substituted Naphthalenes		Org. Lett.	55	Snieckus, V	FALSE	FALSE	FALSE	FALSE
5135	10.1039/c3cy01053h	doi.org/10.1039/c3cy01053h	Nickel-catalyzed oxidative coupling of alkynes and arylboronic acids using the metal-organic framework Ni-2(BDC)(2)(DABCO) as an efficient heterogeneous catalyst		Catal. Sci. Technol.	55	Truong, T	FALSE	FALSE	FALSE	FALSE
5136	10.1055/s-0033-1338418	doi.org/10.1055/s-0033-1338418	Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates		Synthesis	55	Xu, MH	FALSE	FALSE	FALSE	FALSE
5137	10.1021/ja404006w	doi.org/10.1021/ja404006w	Copolymer-Incarcerated Nickel Nanoparticles with N-Heterocyclic Carbene Precursors as Active Cross-Linking Agents for Corriu-Kumada-Tamao Reaction		J. Am. Chem. Soc.	55	Kobayashi, S	FALSE	FALSE	FALSE	FALSE
5138	10.1021/ja4030462	doi.org/10.1021/ja4030462	A Five-Coordinate Nickel(II) Fluoroalkyl Complex as a Precursor to a Spectroscopically Detectable Ni(III) Species		J. Am. Chem. Soc.	55	Vicic, DA	FALSE	FALSE	FALSE	FALSE
5139	10.1016/j.tetasy.2012.06.024	doi.org/10.1016/j.tetasy.2012.06.024	Alternative strategies for the stereoselective synthesis of enantioenriched 6-arylated piperidin-2-ones		Tetrahedron-Asymmetry	55	Michon, C	FALSE	FALSE	FALSE	FALSE
5140	10.1021/ol301195x	doi.org/10.1021/ol301195x	Nickel-Catalyzed Monosubstitution of Polyfluoroarenes with Organozinc Reagents Using Alkoxydiphosphine Ligand		Org. Lett.	55	Nakamura, E	FALSE	FALSE	FALSE	FALSE
5141	10.1021/ol3010112	doi.org/10.1021/ol3010112	Synthesis of 1,1-Diarylethylenes via Efficient Iron/Copper Co-Catalyzed Coupling of 1-Arylvinyl Halides with Grignard Reagents		Org. Lett.	55	Hamze, A	FALSE	FALSE	FALSE	FALSE
5142	10.1016/j.tet.2012.01.008	doi.org/10.1016/j.tet.2012.01.008	Well-defined NHC-Pd(II)-Im(NHC=N-heterocyclic carbene; Im=1-methylimidazole) complex catalyzed C-N coupling of primary amines with aryl chlorides		Tetrahedron	55	Shao, LX	FALSE	FALSE	FALSE	FALSE
5143	10.1021/ja2059999	doi.org/10.1021/ja2059999	Nickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of alpha,beta-Unsaturated Phenyl Esters with Alkynes		J. Am. Chem. Soc.	55	Ohashi, M	FALSE	FALSE	FALSE	FALSE
5144	10.1246/cl.2011.375	doi.org/10.1246/cl.2011.375	Nickel-catalyzed Cycloadditions of Benzoxazinones with Alkynes: Synthesis of Quinolines and Quinolones		Chem. Lett.	55	Kurahashi, T	FALSE	FALSE	FALSE	FALSE
5145	10.1016/j.tetlet.2011.01.113	doi.org/10.1016/j.tetlet.2011.01.113	Suzuki-Miyaura cross-coupling and ring-closing metathesis: a strategic combination to the synthesis of indeno[1,2-c]isoquinolin-5,11-diones		Tetrahedron Lett.	55	Couture, A	FALSE	FALSE	FALSE	FALSE
5146	10.1002/chem.201003403	doi.org/10.1002/chem.201003403	Nickel-Catalyzed Cross-Coupling of Phenols and Arylboronic Acids Through an In Situ Phenol Activation Mediated by PyBroP		Chem.-Eur. J.	55	Han, FS	FALSE	FALSE	FALSE	FALSE
5147	10.1002/anie.201004703	doi.org/10.1002/anie.201004703	A Highly Para-Selective Copper(II)-Catalyzed Direct Arylation of Aniline and Phenol Derivatives		Angew. Chem.-Int. Edit.	55	Gaunt, MJ	FALSE	FALSE	FALSE	FALSE
5148	10.1002/anie.201102092	doi.org/10.1002/anie.201102092	Controlled Alcohol-Carbonyl Interconversion by Nickel Catalysis		Angew. Chem.-Int. Edit.	55	Itami, K	FALSE	FALSE	FALSE	FALSE
5149	10.1039/c0nj00898b	doi.org/10.1039/c0nj00898b	Scalable synthesis of catalysts for the Mizoroki-Heck cross coupling reaction: palladium nanoparticles assembled in a polymeric nanosphere		New J. Chem.	55	Iyer, KS	FALSE	FALSE	FALSE	FALSE
5150	10.1021/om100722f	doi.org/10.1021/om100722f	Iridium-Catalyzed Anti-Stereocontrolled Asymmetric Ring Opening of Azabicyclic Alkenes with Primary Aromatic Amines		Organometallics	55	Yang, DQ	FALSE	FALSE	FALSE	FALSE
5151	10.1002/adsc.201000350	doi.org/10.1002/adsc.201000350	A Direct Synthesis of Symmetrical (E,E)-1,4-Diaryl-1,3-butadienes by Wenkert Arylation of Thiophene		Adv. Synth. Catal.	55	Hintermann, L	FALSE	FALSE	FALSE	FALSE
5152	10.1021/jo100643j	doi.org/10.1021/jo100643j	A Novel, Air-Stable Phosphine Ligand for the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction of Chloro Arenes		J. Org. Chem.	55	Sarkar, A	FALSE	FALSE	FALSE	FALSE
5153	10.1071/CH09625	doi.org/10.1071/CH09625	The Discovery of Catalytic Enantioselective Polyvalent Iodine Mediated Reactions		Aust. J. Chem.	55	Lupton, DW	FALSE	FALSE	FALSE	FALSE
5154	10.1002/chem.200901913	doi.org/10.1002/chem.200901913	Nickel-Catalyzed Cross-Coupling of Alkyl Zinc Halides for the Formation of C(sp(2))-C(sp(3)) Bonds: Scope and Mechanism		Chem.-Eur. J.	55	Cardenas, DJ	FALSE	FALSE	FALSE	FALSE
5155	10.1039/b820790a	doi.org/10.1039/b820790a	A reusable FeCl3 center dot 6H(2)O/cationic 2,2 '-bipyridyl catalytic system for the coupling of aryl iodides with thiols in water under aerobic conditions		Green Chem.	55	Wu, WY	FALSE	FALSE	FALSE	FALSE
5156	10.1002/anie.200903146	doi.org/10.1002/anie.200903146	Rhodium-Catalyzed Cross-Coupling of Organoboron Compounds with Vinyl Acetate		Angew. Chem.-Int. Edit.	55	Kuwano, R	FALSE	FALSE	FALSE	FALSE
5157	10.1021/jm070678q	doi.org/10.1021/jm070678q	New N-arachidonoylserotonin analogues with potential dual mechanism of action against pain		J. Med. Chem.	55	Di Marzo, V	FALSE	FALSE	FALSE	FALSE
5158	10.1080/00397910701490212	doi.org/10.1080/00397910701490212	Pd/C: A recyclable catalyst for cyanation of aryl halides with K-4[Fe(CN)(6)]		Synth. Commun.	55	Cai, C	FALSE	FALSE	FALSE	FALSE
5159	10.1016/j.tetlet.2004.07.032	doi.org/10.1016/j.tetlet.2004.07.032	Ru-3(CO)(12)-catalyzed intramolecular allylic transfer reaction of tethered carbonyl group and allylic acetate moiety		Tetrahedron Lett.	55	Yu, CM	FALSE	FALSE	FALSE	FALSE
5160	10.1016/j.tetlet.2004.05.101	doi.org/10.1016/j.tetlet.2004.05.101	A new chiral 2-sulfonylamino-2 '-phosphino-1,1 '-binaphthyI ligand for highly enantioselective copper-catalyzed conjugate addition of diethylzinc to benzylideneacetones		Tetrahedron Lett.	55	Morimoto, T	FALSE	FALSE	FALSE	FALSE
5161	10.1021/jo049940i	doi.org/10.1021/jo049940i	NiCl2(dppe)-catalyzed cross-coupling of aryl mesylates, arenesulfonates, and halides with arylboronic acids		J. Org. Chem.	55	Percec, V	FALSE	FALSE	FALSE	FALSE
5162	10.1021/ja991703n	doi.org/10.1021/ja991703n	Efficient cross-coupling of aryl chlorides with aryl grignard reagents (Kumada reaction) mediated by a palladium/imidazolium chloride system		J. Am. Chem. Soc.	55	Nolan, SP	FALSE	FALSE	FALSE	FALSE
5163	10.1021/jo00236a023	doi.org/10.1021/jo00236a023	ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION-METAL COMPLEXES .5. PALLADIUM-CATALYZED ASYMMETRIC ALLYLATION OF ACTIVE METHINE COMPOUNDS		J. Org. Chem.	55	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
5164	10.1039/d1qo01765a	doi.org/10.1039/d1qo01765a	Electrochemical synthesis for alpha-arylation of ketones using enol acetates and aryl diazonium salts		Org. Chem. Front.	55	Zhou, PC; Wang, D	FALSE	TRUE	FALSE	FALSE
5165	10.1038/s42004-022-00633-3	doi.org/10.1038/s42004-022-00633-3	Synthesis of alpha,beta-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes		Comm. Chem.	55	Hong, SY	FALSE	FALSE	FALSE	FALSE
5166	10.1039/d1qo01693h	doi.org/10.1039/d1qo01693h	Synthesis of acridinones via palladium-catalyzed reductive annulation of 2-nitrobenzaldehydes and resorcinols		Org. Chem. Front.	55	Zhao, H; Zhang, M	FALSE	FALSE	FALSE	FALSE
5167	10.1002/ajoc.202100641	doi.org/10.1002/ajoc.202100641	Transformation of tert-Butyl Amide Directing Groups to Nitriles in Iridium-Catalyzed C-H Bond Functionalizations		Asian J. Org. Chem.	55	Kim, M	FALSE	FALSE	FALSE	FALSE
5168	10.1021/acs.orglett.1c03329	doi.org/10.1021/acs.orglett.1c03329	Photoredox-Catalyzed Difunctionalization of Unactivated Olefins for Synthesizing Lactam-Substituted gem-Difluoroalkenes		Org. Lett.	55	Pan, F	TRUE	FALSE	FALSE	FALSE
5169	10.1002/ajoc.202100616	doi.org/10.1002/ajoc.202100616	Dehalogenation and Desulfonation from Aryl and Alkyl Compounds with a Cobalt Catalyst in the Presence of Alcohol		Asian J. Org. Chem.	55	Auffrant, A; Gosmini, C	FALSE	FALSE	FALSE	FALSE
5170	10.1039/d1gc03230e	doi.org/10.1039/d1gc03230e	Metal-free, visible-light driven C-H ketoalkylation of glycine derivatives and peptides		Green Chem.	55	Guo, LN	FALSE	FALSE	FALSE	FALSE
5171	10.1021/acs.orglett.1c02893	doi.org/10.1021/acs.orglett.1c02893	Nickel-Catalyzed Reductive Csp(2)-Csp(3) Cross Coupling Using Phosphonium Salts		Org. Lett.	55	Wang, HF; Liang, HZ	FALSE	FALSE	FALSE	FALSE
5172	10.1002/cctc.202100925	doi.org/10.1002/cctc.202100925	Highly Active Ni Nanoparticles on N-doped Mesoporous Carbon with Tunable Selectivity for the One-Pot Transfer Hydroalkylation of Nitroarenes with EtOH in the Absence of H-2		ChemCatChem	55	Xu, CC	FALSE	FALSE	FALSE	FALSE
5173	10.1039/d1sc03712a	doi.org/10.1039/d1sc03712a	Nickel-catalyzed reductive coupling of unactivated alkyl bromides and aliphatic aldehydes		Chem. Sci.	55	Montgomery, J	FALSE	FALSE	FALSE	FALSE
5174	10.1038/s42004-021-00550-x	doi.org/10.1038/s42004-021-00550-x	Data-science driven autonomous process optimization		Comm. Chem.	55	Hein, JE	FALSE	FALSE	FALSE	FALSE
5175	10.1021/acscatal.1c02913	doi.org/10.1021/acscatal.1c02913	Ligand-Controlled Regiodivergent Catalytic Amidation of Unactivated Secondary Alkyl Bromides		ACS Catal.	55	Martin, R	FALSE	FALSE	FALSE	FALSE
5176	10.1002/cssc.202101203	doi.org/10.1002/cssc.202101203	Reductive C-N Coupling of Nitroarenes: Heterogenization of MoO3 Catalyst by Confinement in Silica		ChemSusChem	55	Song, H	FALSE	FALSE	FALSE	FALSE
5177	10.1016/j.chempr.2021.06.007	doi.org/10.1016/j.chempr.2021.06.007	Zirconium-redox-shuttled cross-electrophile coupling of aromatic and heteroaromatic halides		Chem	55	Ye, BH	FALSE	FALSE	FALSE	FALSE
5178	10.1039/d1cc02983e	doi.org/10.1039/d1cc02983e	Ni-Catalyzed C(sp(2))-H alkylation of N-quinolylbenzamides using alkylsilyl peroxides as structurally diverse alkyl sources		Chem. Commun.	55	Maruoka, K	FALSE	FALSE	FALSE	FALSE
5179	10.1021/acs.joc.1c00592	doi.org/10.1021/acs.joc.1c00592	Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis		J. Org. Chem.	55	Balaraman, E	FALSE	FALSE	FALSE	FALSE
5180	10.1126/science.abh2623	doi.org/10.1126/science.abh2623	C(sp(3))-H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling		Science	55	Stahl, SS	FALSE	FALSE	FALSE	FALSE
5181	10.1016/j.jorganchem.2021.121806	doi.org/10.1016/j.jorganchem.2021.121806	Phosphine ligands in the ruthenium-catalyzed reductive amination without an external hydrogen source		J. Organomet. Chem.	55	Chusov, D	FALSE	FALSE	FALSE	FALSE
5182	10.1021/jacs.1c01923	doi.org/10.1021/jacs.1c01923	Direct Carbon Isotope Exchange of Pharmaceuticals via Reversible Decyanation		J. Am. Chem. Soc.	55	Audisio, D	FALSE	FALSE	FALSE	FALSE
5183	10.1002/ajoc.201700064	doi.org/10.1002/ajoc.201700064	Pd(PPh3)(4)-Catalyzed Buchwald-Hartwig Amination ofAryl Fluorosulfonates with Aryl Amines		Asian J. Org. Chem.	55	Kim, BM	FALSE	FALSE	FALSE	FALSE
5184	10.1002/adsc.201700438	doi.org/10.1002/adsc.201700438	Arylation of Azaarylmethylamines with Aryl Chlorides and a NiBr2/NIXANTPHOS-based Catalyst		Adv. Synth. Catal.	55	Zheng, B	FALSE	FALSE	FALSE	FALSE
5185	10.1246/cl.170466	doi.org/10.1246/cl.170466	A Facile Route to 4-Polyfluoroarylquinolin-2(1H)-ones and 4-Polyfluoroarylcoumarins via C-H Bond Activation		Chem. Lett.	55	Wang, ZY	FALSE	FALSE	FALSE	FALSE
5186	10.1002/anie.201700417	doi.org/10.1002/anie.201700417	Oxygen Activated, Palladium Nanoparticle Catalyzed, Ultrafast CrossCoupling of Organolithium Reagents		Angew. Chem.-Int. Edit.	55	Feringa, B	FALSE	FALSE	FALSE	FALSE
5187	10.1021/acs.organomet.7b00030	doi.org/10.1021/acs.organomet.7b00030	Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C=N and C=O Hydrosilylations Catalyzed by Ru-S Complexes with One Monodentate Chiral Phosphine Ligand		Organometallics	55	Oestreich, M	FALSE	FALSE	FALSE	FALSE
5188	10.1021/acs.orglett.6b03856	doi.org/10.1021/acs.orglett.6b03856	Nickel-Catalyzed Stereoselective Alkenylation of C(sp(3))-H Bonds with Terminal Alkynes		Org. Lett.	55	Zhang, YH	FALSE	FALSE	FALSE	FALSE
5189	10.1080/00397911.2017.1339803	doi.org/10.1080/00397911.2017.1339803	Transition metal-free tandem pyridinyl-allyl-allyl cross-coupling reaction		Synth. Commun.	55	Chen, ZK	FALSE	FALSE	FALSE	FALSE
5190	10.1021/jacs.6b10350	doi.org/10.1021/jacs.6b10350	Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes		J. Am. Chem. Soc.	55	Sanford, MS	FALSE	FALSE	FALSE	FALSE
5191	10.1039/c6nj03265f	doi.org/10.1039/c6nj03265f	A well-defined low-valent cobalt catalyst Co(PMe3)(4) with dimethylzinc: a simple catalytic approach for the reductive dimerization of benzyl halides		New J. Chem.	55	Petit, M	FALSE	FALSE	FALSE	FALSE
5192	10.1139/cjc-2016-0287	doi.org/10.1139/cjc-2016-0287	Theoretical study on the mechanism of iridium-catalyzed gamma-functionalization of primary alkyl C-H bonds		Can. J. Chem.	55	Li, Z	FALSE	FALSE	FALSE	FALSE
5193	10.1021/jacs.6604088	doi.org/10.1021/jacs.6604088	Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2		J. Am. Chem. Soc.	55	Martin, R	FALSE	FALSE	FALSE	FALSE
5194	10.1515/znb-2016-0011	doi.org/10.1515/znb-2016-0011	Synthesis and investigation of new cyclic haloamidinium salts		Z.Naturforsch.(B)	55	Wilhelm, R	FALSE	FALSE	FALSE	FALSE
5195	10.1021/jacs.6b02405	doi.org/10.1021/jacs.6b02405	Aromatic Cyanoalkylation through Double C-H Activation Mediated by Ni(III)		J. Am. Chem. Soc.	55	Mirica, LM	FALSE	FALSE	FALSE	FALSE
5196	10.1038/ncomms11129	doi.org/10.1038/ncomms11129	Practical carbon-carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation		Nat. Commun.	55	Fu, Y	FALSE	FALSE	FALSE	FALSE
5197	10.1021/acssuschemeng.5b01282	doi.org/10.1021/acssuschemeng.5b01282	Direct alpha-Alkylation of Acetophenones with Benzhydrols as Well as 1-Phenylethanols Using Amberlyst-15/Ionic Liquid as an Efficient Catalytic System		ACS Sustain. Chem. Eng.	55	Bhanage, BM	FALSE	FALSE	FALSE	FALSE
5198	10.1007/s40242-016-5261-0	doi.org/10.1007/s40242-016-5261-0	Ni-Catalyzed Cross Coupling of Aryl Grignard Reagents with Aryl Halides in a Nonpolar Solvent and an Efficient Synthesis of Biaryls Under Neat Conditions		Chem. Res. Chin. Univ.	55	Kang, CQ; Gao, LX	FALSE	FALSE	FALSE	FALSE
5199	10.1038/srep19723	doi.org/10.1038/srep19723	Perovskite LaFeO3/montmorillonite nanocomposites: synthesis, interface characteristics and enhanced photocatalytic activity		Sci Rep	55	Yang, HM	FALSE	FALSE	FALSE	FALSE
5200	10.1002/cctc.202001949	doi.org/10.1002/cctc.202001949	Nickel-Catalyzed Acyl Group Transfer of o-Alkynylphenol Esters Accompanied by C-O Bond Fission for Synthesis of Benzo[b]furan	Decarboxylative coupling reactions of alkynyl carboxylic acids with aryl tosylates were developed in the presence of a palladium catalyst. Among the commercially available phosphine ligands, only 1-dicyclohexylphosphino-2-(di-tert-butylphosphino-ethyl) ferrocene (CyPF-tBu) showed good reactivity. The reaction took place smoothly and gave the decarboxylative coupled products in moderate to good yields. This demonstrates the excellent functional group tolerance toward alkyl, alkoxy, fluoro, thiophenyl, ester, and ketone groups. In addition, alkyl-substituted propiolic acids, such as octynoic and hexynoic acids, were coupled with phenyl tosylate to provide the desired products. We found that the electronic properties of the substituents on the phenyl ring in arylpropiolic acids are an important factor. The order of reactivity was found to be aryl iodide > aryl bromide > aryl tosylate > aryl chloride. However, aryl chloride-bearing electron-withdrawing groups showed higher reactivity than those bearing aryl tosylates.	ChemCatChem	54	Doi, R; Sato, Y	FALSE	FALSE	FALSE	FALSE
5201	10.1021/acs.orglett.0c03939	doi.org/10.1021/acs.orglett.0c03939	Nickel-Catalyzed Reductive 2-Pyridination of Aryl Iodides with Difluoromethyl 2-Pyridyl Sulfone	A Pd(OAc)(2)-catalyzed desulfinative cross-coupling of (Z)-beta-halostyrenes with sodium sulfinates in the presence of PPh3 and Na2CO3 at reflux in good yields is reported. The stereocontrolled cross-coupling process provides a series of sulfonylmethyl (Z)-stilbenes. A synthesis of tamoxifen was studied.	Org. Lett.	54	Hu, JB	FALSE	FALSE	FALSE	FALSE
5202	10.1055/s-0040-1705989	doi.org/10.1055/s-0040-1705989	Anchored Pd(0) Nanoparticles on Synthetic Talc for the Synthesis of Biaryls and a Precursor of Angiotensin II Inhibitors	Electronic, steric and leaving group effects for Ni-catalyzed direct arylations using C-O electrophiles were benchmarked. The scope of arylations with pivalates was general with respect to both the electronics on the electrophile and the azoles. Furthermore, the arylation of azoles with tosylates, mesylates and carbamates with varying electronics was explored, and showed electronic trends similar to those of the pivalate reactions. Finally, the relative rate of arylation of 5-methyl benzoxazole with two electronically-similar electrophiles bearing different leaving groups was established. The results from these studies implicate the following order of relative reactivity: mesylates > pivalates > carbamates. (C) 2017 Elsevier Ltd. All rights reserved.	Synthesis	54	Domingues, NLC	FALSE	FALSE	FALSE	FALSE
5203	10.1021/acs.joc.0c00999	doi.org/10.1021/acs.joc.0c00999	Ir(III)-Catalyzed C-H Functionalization of Triphenylphosphine Oxide toward 3-Aryl Oxindoles	A new process for the [4 + 2] annulation of donor-acceptor cyclopropanes with acetylenes under the effect of anhydrous GaCl3 using 1,2-zwitterion reactivity was elaborated. The reaction opens access to substituted dihydronaphthalenes, naphthalenes, and other fused carbocycles. The direction of the reaction can be efficiently controlled by temperature.	J. Org. Chem.	54	Yang, SD	FALSE	FALSE	FALSE	FALSE
5204	10.1021/acs.joc.0c01771	doi.org/10.1021/acs.joc.0c01771	Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos)	An efficient Rh(III)-catalyzed ortho-alkylation of phenoxy substrates with diazo compounds has been achieved for the first time using pyrimidine or pyridine as the directing group. Furthermore, bis-alkylation has also been achieved using parasubstituted phenoxypyrimidine and 3 mol equiv of the diazo ester. The ortho-alkylated derivatives of phenoxy products possessing the ester functionality undergo decarboxylative pyrimidine/pyridine migratory cyclization (rather than deprotection of pyrimidine/pyridine group) using 20% NaOEt in EtOH affording a novel class of 3-(pyrimidin-2(1H)-ylidene)benzofuran-2(3H)-ones and 6-methyl-3-(pyridin-2(1H)-ylidene)benzofuran-2(3H)-one. The ortho-alkylated phenoxypyridine possessing ester functionality also undergoes decarboxylative pyridine migratory cyclization using MeOTf/NaOMe in toluene providing 6 methyl-3-(1-methylpyridin-2(IH)-ylidene)benzofuran-2 (3H)-one.	J. Org. Chem.	54	Gessner, VH	FALSE	FALSE	FALSE	FALSE
5205	10.1002/cctc.202001462	doi.org/10.1002/cctc.202001462	Experimental and Computational Studies towards Chemoselective C-F over C-Cl Functionalisation: Reversible Oxidative Addition is the Key	This study introduces an efficient method for the selective formylation of indoles and pyrroles at the positions of C(3) and C(2), respectively. The mixture of three equivalents of N,N-dimethylformamide and one equivalent of 2,4,6-trichloro-1,3,5-triazine (cyanuric chloride) generates an easy handling formylating agent for the efficient formylation of these classes of compounds to give the corresponding aldehydes under mild reaction conditions. This procedure was highly efficient, and a range of formylated indoles and pyrroles were obtained in good to excellent yields.	ChemCatChem	54	Keaveney, ST	FALSE	FALSE	FALSE	FALSE
5206	10.1021/acs.accounts.0c00291	doi.org/10.1021/acs.accounts.0c00291	Cross-Electrophile Couplings of Activated and Sterically Hindered Halides and Alcohol Derivatives	In textbooks, the low reactivity of amides is attributed to the strong resonance stability. However, Garg and co-workers recently reported the Ni-catalyzed activation of robust amide C-N bonds, leading to conversions of amides into esters, ketones, and other amides with high selectivity. Among them, the Ni-catalyzed Suzuki-Miyaura coupling (SMC) of N-benzyl-N-tert-butoxycarbonyl (N-Bn-N-Boc) amides with pinacolatoboronate (PhBpin) was performed in the presence of K3PO4 and water. Water significantly enhanced the reaction. With the aid of density functional theory (DFT) calculations, the present study explored the mechanism of the aforementioned SMC reaction as well as analyzed the weakening of amide C-N bond by N-functionalization. The most favorable pathway includes four basic steps: oxidative addition, protonation, transmetalation, and reductive elimination. Comparing the base- and water-free process, the transmetalation step with the help of K3PO4 and water is significantly more facile. Water efficiently protonates the basic N(Boc) (Bn) group to form a neutral HN(Boc) (Bn), which is easily removed. The transmetalation step is the rate-determining step with an energy barrier of 25.6 kcal/mol. Further, a DFT prediction was carried out to investigate the full catalytic cycle of a cyclic (amino) (aryl)carbene in the Ni-catalyzed SMC of amides, which provided clues for further design of catalysts.	Accounts Chem. Res.	54	Gong, HG	FALSE	TRUE	FALSE	FALSE
5207	10.1039/d0cs00262c	doi.org/10.1039/d0cs00262c	Transition metal-catalysed allylic functionalization reactions involving radicals	In the field of asymmetric synthesis, the development of new chiral ligands has been regarded as an attractive challenge for decades. Novel chiral ligands can often have a great impact on synthetic protocols. In this context, we are currently interested in the application of 1,10-phenanthroline (phen) as an entirely new class of chiral ligand. To handle this issue, we designed a chiral phen ligand that provides the N,N,O-tridentate coordination of the phen moiety and an additional phenolic hydroxyl group. As phen possesses greater coordination ability with various ions, our chiral phen ligand would be valuable as one of the privileged chiral ligands applied to a broad range of metal catalysts and new reactions. This account summarizes the results of the application of the chiral phen ligand to various kinds of metal catalysis.	Chem. Soc. Rev.	54	Glorius, F	FALSE	FALSE	FALSE	FALSE
5208	10.1021/acs.joc.0c00929	doi.org/10.1021/acs.joc.0c00929	Pd- and Ni-Based Systems for the Catalytic Borylation of Aryl (Pseudo)halides with B-2(OH)(4)	The Kumada-Corriu reaction is a,powerful tool for C-C bond formation, but is seldom utilized due to perceived chemoselectivity issues. Herein, we demonstrate that high-yielding couplings can occur in the presence of many electrophilic and heterocyclic functional groups. Our strategy is mechanically based, matching oxidative addition rates with the rate of syringe pump addition of the Grignard reagent. The mechanistic reason for the effectiveness of this strategy is uncovered by continuous-infusion ESI-MS studies.	J. Org. Chem.	54	Frantz, DE	FALSE	FALSE	FALSE	FALSE
5209	10.1021/acs.orglett.0c02340	doi.org/10.1021/acs.orglett.0c02340	Direct Synthesis of Mono-alpha-arylated Ketones from Alcohols and Olefins via Ni-Catalyzed Oxidative Cross-Coupling	Iron-catalyzed cross-coupling reaction of vinylic ethers with aryl Grignard reagents is described. The reaction proceeded at room temperature with catalytic amounts of an iron salt without the aid of costly ligands and additives. In this catalytic system, vinylic C-O bonds were preferentially cleaved over aromatic C-O bonds of aryl ethers or aryl sulfonates.	Org. Lett.	54	Shu, W	FALSE	FALSE	FALSE	FALSE
5210	10.1021/acs.orglett.0c01869	doi.org/10.1021/acs.orglett.0c01869	Palladium-Catalyzed N-Acylation of Tertiary Amines by Carboxylic Acids: A Method for the Synthesis of Amides	An environmentally friendly silica-grafted nicotine-based palladium(II) complex was successfully prepared and evaluated for the first time as novel and efficient nanocatalyst in C-C bond forming reactions. Grafted-nicotine in this catalytic system plays an important role, and as an effective ligand and a quaternary ammonium salt demonstrates an efficient stabilizing effect on the Pd(II) species by a synergistic effect of coordination and electrostatic interactions. The catalyst was well characterized by FT-IR, CHN, XRD, TEM, SEM-EDX, ICP and TG analysis, and demonstrated a highly efficient catalytic activity in the reaction system under phosphine-free and low Pd loading conditions, and the coupled products were produced in good to excellent yields. Furthermore, the catalyst can be easily recovered and reused without a significant loss of activity. Copyright (c) 2016 John Wiley & Sons, Ltd.	Org. Lett.	54	Chen, TQ	FALSE	FALSE	FALSE	FALSE
5211	10.1021/acscatal.0c02105	doi.org/10.1021/acscatal.0c02105	Direct C-H Arylation of Aldehydes by Merging Photocatalyzed Hydrogen Atom Transfer with Palladium Catalysis	N,O-aminals, molecules bearing a geminally N,O -substituted (stereogenic) carbon center, have been recently recognized as an important class of building blocks in organic synthesis. As direct precursors of imines and iminium ions, N,O-aminals were converted through asymmetric organocatalysis or metal catalysis to diverse enantiomerically enriched compounds including N-heterocycles. Furthermore, cyclic N,O-hemiaminals acted as acyclic amino aldehyde surrogates, which were transformed to enantioenriched products otherwise challenging to access. Finally, cyclic N,O-aminals were formed in situ as key intermediates in asymmetric catalysis. In this review, we introduce a wide array of catalytic asymmetric protocols involving the use of four distinct types of N,O-aminals as starting materials or key intermediates.	ACS Catal.	54	Zheng, C	TRUE	FALSE	FALSE	FALSE
5212	10.1002/ejoc.202000477	doi.org/10.1002/ejoc.202000477	Mechanism, Chemoselectivity, and Stereoselectivity of NHC-Catalyzed Asymmetric Desymmetrization of Enal-Tethered Cyclohexadienones	The synthesis and regioselective functionalization of rare 2,4-disubstituted-pyrido[1,2:1,5]pyrazolo[3,4-d]pyrimidine derivatives is reported. C-4 aminations were performed by chlorine nucleophilic substitution SNAr reactions, and their efficiencies were compared with those for direct one-pot amide C-O activation with bromotripyrrolidinophosphonium hexafluorophosphate (PyBroP) as a reagent. The latter method was used to perform palladium-catalyzed C-4 (het)arylation. Finally, two C-4 amino and aryl derivatives were prepared on a large scale and engaged in desulfurative Liebeskind-Srogl-type reactions under microwave irradiation to afford the envisioned compound library. Each step was optimized, and the results are discussed.	Eur. J. Org. Chem.	54	Li, X; Qiao, Y	FALSE	FALSE	FALSE	FALSE
5213	10.1039/d0qo00173b	doi.org/10.1039/d0qo00173b	Transition-metal-free aerobic C-O bond formation via C-N bond cleavage	A highly enantioselective palladium/L-proline-catalyzed alpha-arylative desymmetrization of cyclohexanones was developed. The new strategy for alpha-arylation reaction led to a series of optically active morphan derivatives bearing a-carbonyl tertiary stereo centers in good yields with excellent enantioselectivities (up to 99% ee).	Org. Chem. Front.	54	Lu, HF; Gao, HY	FALSE	FALSE	FALSE	FALSE
5214	10.1021/acs.joc.9b03433	doi.org/10.1021/acs.joc.9b03433	Synthesis of Triarylmethanes by Decarbonylation of 3,3-Diaryl Benzofuranones	The ligand-assisted palladium (Pd)-catalyzed Suzuki-Miyaura cross-coupling reaction is one of the most attractive protocols in organic chemistry and phosphines have been established as the best ligand system for this transformation. However, these phosphines have significant limitations, such as high toxicity, sensitivity to air and moisture, handling problems, and high costs. Recently, Schiff bases have been recognized as excellent alternatives to phosphines in Suzuki-Miyaura reactions. Similar to phosphines, the steric and electronic characteristics of Schiff bases can be manipulated by selecting suitable condensing aldehydes and amines. Many Schiff base-derived homogeneous and heterogeneous Pd catalysts have been reported for Suzuki-Miyaura reactions and this review provides insights into the state-of-the-art in applications of these Schiff base-derived Pd catalysts in the Suzuki-Miyaura reaction. (C) 2015 Elsevier B.V. All rights reserved.	J. Org. Chem.	54	Qiu, RH; Kambe, N	FALSE	FALSE	FALSE	FALSE
5215	10.1021/acs.orglett.0c00101	doi.org/10.1021/acs.orglett.0c00101	Efficient Strategy for alpha-Selective Glycosidation of D-Glucosamine and Its Application to the Synthesis of a Bacterial Capsular Polysaccharide Repeating Unit Containing Multiple alpha-Linked GlcNAc Residues		Org. Lett.	54	Gao, J	FALSE	FALSE	FALSE	FALSE
5216	10.1002/cssc.201903397	doi.org/10.1002/cssc.201903397	Anodically Triggered Aldehyde Cation Autocatalysis for Alkylation of Heteroarenes		ChemSusChem	54	Yuan, KD	FALSE	FALSE	FALSE	FALSE
5217	10.1007/s13204-019-01133-y	doi.org/10.1007/s13204-019-01133-y	Convenient but powerful method to dope single-walled carbon nanotube films with iodonium salts		Appl. Nanosci.	54	Kumanek, B; Janas, D	FALSE	FALSE	FALSE	FALSE
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5222	10.1002/aoc.5181	doi.org/10.1002/aoc.5181	Efficient construction of C-C bonds from aryl halides/aryl esters with arylboronic acids catalysed by palladium(II) thiourea complexes		Appl. Organomet. Chem.	54	Rengan, R	FALSE	FALSE	FALSE	FALSE
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5229	10.1021/acs.orglett.9b00294	doi.org/10.1021/acs.orglett.9b00294	Ni(NIXANTPHOS)-Catalyzed Mono-Arylation of Toluenes with Aryl Chlorides and Bromides		Org. Lett.	54	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
5230	10.6023/cjoc201812051	doi.org/10.6023/cjoc201812051	Palladium-Catalyzed Dehydrative Cross Couplings of Stabilized Phosphorus Ylides with Allylic Alcohols		Chin. J. Org. Chem.	54	Ma, XT; Zhang, ZL	FALSE	FALSE	FALSE	FALSE
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5232	10.1021/acs.orglett.8b03040	doi.org/10.1021/acs.orglett.8b03040	Silver-Catalyzed Olefination of Acetals and Ketals with Diazoesters to beta-Alkoxyacrylates		Org. Lett.	54	Qian, B; Huang, HM	FALSE	FALSE	FALSE	FALSE
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5306	10.1002/chem.201605611	doi.org/10.1002/chem.201605611	Cationic [(Iminophosphine) Nickel( Allyl)](+) Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes		Chem.-Eur. J.	54	Schmidt, JAR	FALSE	FALSE	FALSE	FALSE
5307	10.1021/acs.orglett.6b02933	doi.org/10.1021/acs.orglett.6b02933	Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents		Org. Lett.	54	Zhou, SL	FALSE	FALSE	FALSE	FALSE
5308	10.1021/acscatal.6b02392	doi.org/10.1021/acscatal.6b02392	Rh(I)/NHC*-Catalyzed Site- and Enantioselective Functionalization of C(sp(3))-H Bonds Toward Chiral Triarylmethanes		ACS Catal.	54	Glorius, F	FALSE	FALSE	FALSE	FALSE
5309	10.1021/acs.orglett.6b02343	doi.org/10.1021/acs.orglett.6b02343	Multicomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex		Org. Lett.	54	Iwasaki, T; Kambe, N	FALSE	FALSE	FALSE	FALSE
5310	10.1021/acs.orglett.5b03712	doi.org/10.1021/acs.orglett.5b03712	Pd(II)-Catalyzed C3-Selective Arylation of Pyridine with (Hetero)arenes		Org. Lett.	54	Yu, JQ	FALSE	FALSE	FALSE	FALSE
5311	10.1021/acs.orglett.5b03396	doi.org/10.1021/acs.orglett.5b03396	Chiral Diarylmethanes via Copper-Catalyzed Asymmetric Allylic Arylation with Organolithium Compounds		Org. Lett.	54	Hornillos, V; Feringa, BL	FALSE	FALSE	FALSE	FALSE
5312	10.1002/chem.202005426	doi.org/10.1002/chem.202005426	Photohomolysis and Photoheterolysis in Aryl Sulfonates and Aryl Phosphates	This work describes the cross-electrophile methylation of aryl bromides and aryl tosylates with methyl tosylate. The mild reaction conditions allow effective methylation of a wide set of heteroaryl electrophiles and dimethylation of dibromoarenes.	Chem.-Eur. J.	53	Fagnoni, M	TRUE	FALSE	FALSE	FALSE
5313	10.1021/acscatal.0c05484	doi.org/10.1021/acscatal.0c05484	Nickel-Catalyzed, Stereospecific C-C and C-B Cross-Couplings via C-N and C-O Bond Activation	Two efficient protocols for the nickel-catalyzed aryl alkyl cross-coupling reactions using esters as coupling components have been established. The methods enable the selective oxidative addition of nickel to acyl C-O and aryl C-O bonds and allow the aryl alkyl cross-coupling via decarbonylative bond cleavage or through cleavage of a C-O bond with high efficiency and good functional group compatibility. The protocols allow the streamlined, unconventional utilization of widespread ester groups and their precursors, carboxylic acids and phenols, in synthetic organic chemistry.	ACS Catal.	53	Watson, MP	FALSE	FALSE	FALSE	FALSE
5314	10.1038/s41467-020-20725-9	doi.org/10.1038/s41467-020-20725-9	2,2-difluorovinyl benzoates for diverse synthesis of gem-difluoroenol ethers by Ni-catalyzed cross-coupling reactions	Exploitation of the low binding affinity of NHC-palladium complex for the carbonyl oxygen of ester to form three-centered transition state led to the discovery of Suzuki-Miyaura coupling via unprecedented C(acyl)-O bond cleavage. The use of bulky NHC ligand resulted in direct coupling as it prevented decarbonylation of ester. This access to alternative chemoselectivity by careful selection has extended the synthetic portfolio of esters for the diversification of interesting molecular scaffolds.	Nat. Commun.	53	Yu, WY	FALSE	FALSE	FALSE	FALSE
5315	10.1021/acscatal.0c04620	doi.org/10.1021/acscatal.0c04620	Mechanistic Studies of Copper(I)-Catalyzed Stereoselective [2,3]-Sigmatropic Rearrangements of Diazoesters with Allylic Iodides/Sulfides	Current efforts in this laboratory continue to focus on the preparation of novel complexant motifs for potential use in chemoselective minor-actinide liquid-liquid separations of relevant cations from used nuclear fuel. The present work describes an efficient Pd-catalyzed amination reaction of diversely functionalized 6-bromo-1,2,4-triazinyl-pyridine scaffolds with various amines to afford the opportunity for convergent modulation of complexant electronic and steric properties directly from one substrate towards potentially enhanced solubility in process-relevant solvents. The 21 novel examples presented highlight a unified approach to extensive molecular diversity and provide the ability to further study chelate effects, solubility properties, and complexation efficacy on nonsymmetric, moderately soft-Lewis-basic complexant scaffolds without the incorporation of additional heteroaromatic moieties. Synthetic-method optimization, amine and scaffold scope, as well as a scale-up experiment are presented.	ACS Catal.	53	Dang, YF	FALSE	FALSE	FALSE	FALSE
5316	10.1055/a-1328-0352	doi.org/10.1055/a-1328-0352	Zn-Mediated Hydrodeoxygenation of Tertiary Alkyl Oxalates	A revisit of organoaluminum reagents for cross coupling reactions has opened up several types of C-C bond formation protocols through cleavage of phenolic/alcoholic C-O and C-F and ammonium C-N bonds. Catalyzed by the commercially available NiCl2(PCy3)(2) catalyst, these reactions proceed smoothly with a wide range of substrates and broad functional group compatibility, providing a versatile methodology for organoaluminum-mediated cross-coupling processes.	Synlett	53	Gong, HG	FALSE	FALSE	FALSE	FALSE
5317	10.1021/acs.joc.0c00703	doi.org/10.1021/acs.joc.0c00703	Reagent Controlled Glycosylations for the Assembly of Well-Defined Pel Oligosaccharides	A Ni-catalyzed reductive cross-coupling of styrenyl aziridines with aryl iodides is reported. This reaction proceeds by a stereoconvergent mechanism and is thus amenable to asymmetric catalysis using a chiral BiOxazoline ligand for Ni. The process allows facile access to highly enantioenriched 2-arylphenethylamines from racemic aziridines. Multivariate analysis revealed that ligand polarizability, among other features, influences the observed enantioselectivity, shedding light on the success of this emerging ligand class for enantioselective Ni catalysis.	J. Org. Chem.	53	Codee, JDC	FALSE	FALSE	FALSE	FALSE
5318	10.1039/d0qo00923g	doi.org/10.1039/d0qo00923g	Selective direct C-H polyfluoroarylation of electron-deficient N-heterocyclic compounds	A Cu-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide is described for the first time in this paper. The reaction tolerates a wide range of functional groups, providing a convenient protocol for the synthesis of various O-aryl carbamates. The successful development of the transformation was enabled by the use of BF3 center dot OEt2 as the promoter and molecular oxygen as the oxidant. Mechanistic studies suggested that the Cu-II carbamato complex is involved in the catalytic transformation.	Org. Chem. Front.	53	Fu, HY	FALSE	FALSE	FALSE	FALSE
5319	10.6023/cjoc202006075	doi.org/10.6023/cjoc202006075	Palladium-Catalyzed Reductive Coupling of Aromatic Bromides and Trimethylsilyldiazomethane: Its Application to Methylation of Aromatic Compounds	A simple and facile method for the synthesis of aromatic tertiary amines by amination of fluoroarenes with secondary amines in the presence of n-butyllithium at room temperature was reported. (C) 2017 Elsevier Ltd. All rights reserved.	Chin. J. Org. Chem.	53	Wang, JB	FALSE	FALSE	FALSE	FALSE
5320	10.1021/jacs.0c09008	doi.org/10.1021/jacs.0c09008	Cu-Catalyzed Enantioselective Alkylarylation of Vinylarenes Enabled by Chiral Binaphthyl-box Hybrid Ligands	N-Heterocyclic carbene based pincer ligands bearing a central silyl donor, [CSiC](-) , have been envisioned as a class of strongly sigma-donating ligands that can be used for synthesizing electron-rich transition-metal complexes for the activation of inert bonds. However, this type of pincer ligand and complexes thereof have remained elusive owing to their challenging synthesis. We herein describe the first synthesis of a CSiC pincer ligand scaffold through the coupling of a silylNHC chelate with a benzyl-NHC chelate induced by oneelectron oxidation in the coordination sphere of a cobalt complex. The monoanionic CSiC ligand stabilizes the Co-I dinitrogen complex [(CSiC) Co(N-2)] with an unusual coordination geometry and enables the challenging oxidative addition of E-H bonds (E= C, N, O) to Co-I to form Co-III complexes. The structure and reactivity of the cobalt(I) complex are ascribed to the unique electronic properties of the CSiC pincer ligand, which provides a strong trans effect and pronounced sigma-donation.	J. Am. Chem. Soc.	53	Maruoka, K	FALSE	FALSE	FALSE	FALSE
5321	10.1021/jacs.0c07492	doi.org/10.1021/jacs.0c07492	Radical Dehydroxylative Alkylation of Tertiary Alcohols by Ti Catalysis	A concise, protecting-group-free synthesis of the antipsychotic agent (+)-nemonapride has been achieved featuring a europium(III) trifluoromethanesulfonate (Eu(OTf)(3))-catalyzed C4 selective aminolysis of a 3,4-epoxy alcohol by benzylamine and an expedient use of the resulting 4-benzylamino-1,3-diol product for constructing the pyrrolidine skeleton.	J. Am. Chem. Soc.	53	Shu, XZ	FALSE	FALSE	FALSE	FALSE
5322	10.1016/j.intermet.2020.106839	doi.org/10.1016/j.intermet.2020.106839	Al and Ni nanoparticles as precursors for Ni aluminides	Copper-catalyzed functionalization of terminal or 1,1-disubstituted alkenes with bis(pinacolato)diboron and exceptional regiocontrol favoring the branched isomer. Pairing methanol provides formal hydroboration products with this procedure with photocatalytic cross-couplings using iridium and nickel cocatalysis provides an effective, highly regioselective procedure for the hydroarylation of terminal alkenes.	Intermetallics	53	Kickelbick, G	FALSE	FALSE	FALSE	FALSE
5323	10.1039/d0cc01460e	doi.org/10.1039/d0cc01460e	Manganese complex-catalysed alpha-alkylation of ketones with secondary alcohols enables the synthesis of beta-branched carbonyl compounds	Development of efficient, mild, and easily operable stereoselective glycosylations is of critical importance to access sufficient amounts of pure and structurally well-defined carbohydrates for studies of their biological functions. Such studies will facilitate our understanding of the role of complex oligosaccharides and glycoconjugates in biological processes as well as the development of carbohydrate-based effective therapeutic agents. This review highlights recent advances in the transition metal catalyzed stereoselective glycosylations for the synthesis of a variety of structurally complex and biologically significant O-, N-, C-, and S-glycosides.	Chem. Commun.	53	Maji, B	FALSE	FALSE	FALSE	FALSE
5324	10.1126/sciadv.aba7614	doi.org/10.1126/sciadv.aba7614	Ester dance reaction on the aromatic ring	A nickel-catalyzed methylation of aryl halides with cheap and readily available CH3I or CD (3) I is described. The reaction is applicable to a wide range of substrates and allows installation of a CD3 group under mild reaction conditions without deuterium scrambling to other carbon atoms. Initial mechanistic studies on the stoichiometric and catalytic reactions of the isolated [(dppp)Ni(C6H4-4-CO2Et)Br] [dppp= 1,3-bis(diphenylphosphanyl)propane] suggest that a Ni-0/ Ni-II catalytic cycle is favored.	Sci. Adv.	53	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5325	10.1016/j.tetlet.2020.151940	doi.org/10.1016/j.tetlet.2020.151940	Cobalt- or copper-catalyzed synthesis of gem-difluoroallyl MIDA boronates from alpha-trifluoromethyl alkenes	In this study, we report the harnessing of new reactivity of N,O-acetals in an aminocatalytic fashion for organic synthesis. Unlike widely used strategies requiring the use of acids and/or elevated temperatures, direct replacement of the amine component of the N,O-acetals by carbon-centered nucleophiles for C-C bond formation is realized under mild reaction conditions. Furthermore, without necessary preformation of the N,O-acetals, an amine-catalyzed in situ formation of N,O-acetals is developed. Coupling both reactions into a one-pot operation enables the achievement of a catalytic process. We demonstrate the employment of simple anilines as promoters for the cyclization-substitution cascade reactions of trans-2-hydroxycinnamaldehydes with various carbonic nucleophiles including indoles, pyrroles, naphthols, phenols, and silyl enol ethers. The process offers an alternative approach to structurally diverse, privileged 2-substituted 2H-chromenes. The synthetic power of the new process is furthermore shown by its application in a 2-step synthesis of the natural product candenatenin E and for the facile installation of 2-substituted 2H-chromene moieties into biologically active indoles.	Tetrahedron Lett.	53	Cao, S	FALSE	FALSE	FALSE	FALSE
5326	10.1007/s11172-020-2818-3	doi.org/10.1007/s11172-020-2818-3	Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki-Miyaura reaction	Three novel porous heterobimetallic coordination polymers, [Ln(2)Pd(3)(BPDC)(2)(HBPDC)(2)(mu 2-O)Cl-4(H2O)(6)center dot nH(2)O](m) (Ln = Pr, n=5 (1), Ln=Gd, n=4 (2), and Ln=Tb, n=4 (3)), were readily prepared by combining Pd(II) and Ln(III) with 2,2'-bipyridine-4,4'-dicarboxylic acid (H2BPDC) as a heteroleptic ligand, under hydrothermal conditions, and structurally characterized by means of single-crystal X-ray diffraction, Fr-IR, powder X-ray diffraction, elemental analysis and thermogravimetric (TG) techniques. Single-crystal X-ray diffraction examination showed that 1-3 have similar 3D frameworks, connected via hydrogen bonding interactions, and consisting of three distinct types of building blocks: Pd(BPDC)Cl-2, Pd(HBPDC)2 and a Ln dimer (Ln(2)O(15)). The new isostructural, air and water stable coordination polymers, resulting from association of lanthanides with palladium, exhibited superior but distinct capabilities as eco-friendly heterogeneous catalysts in Suzuki-Miyaura, Heck and Sonogashira cross-couplings, under green reaction conditions. Supramolecular, solid catalysts 1-3 have been recovered quantitatively from the reaction mixtures by simple filtration. Also importantly, their sustainability, utility and cost-effectiveness have been demonstrated by recycling experiments with catalyst 1 in Suzuki-Miyaura, proceeding practically without loss of activity after four runs. (C) 2015 Elsevier B.V. All rights reserved.	Russ. Chem. Bull.	53	Chernyshev, VM	FALSE	FALSE	FALSE	FALSE
5327	10.1021/acs.orglett.0c00500	doi.org/10.1021/acs.orglett.0c00500	Iridium/Acid Cocatalyzed Direct Access to Fused Indoles via Transfer Hydrogenative Annulation of Quinolines and 1,2-Diketones	Hydroalkoxylation of butadiene has been performed in the presence of nickel precatalysts associated with chelating diphosphine ligands. High butadiene conversions and selectivities forming alkyl butenyl ethers were obtained with low catalyst loading. Reactions were performed with a wide scope of primary alcohols including benzylic alcohol derivatives and bio-sourced alcohols. In the same way, the scope of dienes that can be reacted according to this reaction has been also studied. Substituted butadiene derivatives have shown a lower reactivity compared to butadiene. Isoprene formed OC5 alkenyl ethers with a high regioselectivity for one branched isomeric form.	Org. Lett.	53	Zhang, M	FALSE	FALSE	FALSE	FALSE
5328	10.1039/c9dt04111g	doi.org/10.1039/c9dt04111g	Hydrogenation and N-alkylation of anilines and imines via transfer hydrogenation with homogeneous nickel compounds		Dalton Trans.	53	Garcia, JJ	FALSE	FALSE	FALSE	FALSE
5329	10.1021/acs.orglett.9b03557	doi.org/10.1021/acs.orglett.9b03557	Regioselectivity Influences in Platinum-Catalyzed Intramolecular Alkyne O-H and N-H Additions		Org. Lett.	53	Ferreira, EM	FALSE	FALSE	FALSE	FALSE
5330	10.1002/ejoc.201901364	doi.org/10.1002/ejoc.201901364	Decyanative Cross-Coupling of Cyanopyrimidines with O-, S-, and N-Nucleophiles: A Route to Alkoxylpyrimidines, Aminopyrimidines and Alkylthiopyrimidines		Eur. J. Org. Chem.	53	Yin, GD	FALSE	FALSE	FALSE	FALSE
5331	10.1021/acscatal.9b02636	doi.org/10.1021/acscatal.9b02636	How Solvents Control the Stereospecificity of Ni-Catalyzed Miyaura Borylation of Allylic Pivalates		ACS Catal.	53	Lu, Z; Hong, X	FALSE	FALSE	FALSE	FALSE
5332	10.1021/acscatal.9b02483	doi.org/10.1021/acscatal.9b02483	Nickel-Catalyzed Regioselective Hydrobenzylation of 1,3-Dienes with Hydrazones		ACS Catal.	53	Li, CJ	FALSE	FALSE	FALSE	FALSE
5333	10.1039/c9cc05385a	doi.org/10.1039/c9cc05385a	Ni-Catalyzed deaminative hydroalkylation of internal alkynes		Chem. Commun.	53	Liu, F	FALSE	FALSE	FALSE	FALSE
5334	10.1002/asia.201900904	doi.org/10.1002/asia.201900904	Construction of C(sp(2))-C(sp(3)) Bond between Quinoxalin-2(1H)-ones and N-Hydroxyphthalimide Esters via Photocatalytic Decarboxylative Coupling		Chem.-Asian J.	53	Jin, C	TRUE	FALSE	FALSE	FALSE
5335	10.1002/anie.201903215	doi.org/10.1002/anie.201903215	Synthesis of Nitrile-Bearing Quaternary Centers by an Equilibrium-Driven Transnitrilation and Anion-Relay Strategy		Angew. Chem.-Int. Edit.	53	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
5336	10.1039/c9nj01635j	doi.org/10.1039/c9nj01635j	The asymmetric vinylogous Mannich reaction of noncyclic dicyanoolefins catalyzed by a bifunctional thiourea-ammonium salt phase transfer catalyst		New J. Chem.	53	Lin, YJ; Duan, HF	FALSE	FALSE	FALSE	FALSE
5337	10.1021/acs.orglett.9b01941	doi.org/10.1021/acs.orglett.9b01941	HCN on Tap: On-Demand Continuous Production of Anhydrous HCN for Organic Synthesis		Org. Lett.	53	Hone, CA; Kappe, CO	FALSE	FALSE	FALSE	FALSE
5338	10.1021/acs.joc.9b00717	doi.org/10.1021/acs.joc.9b00717	A Microwave-Assisted SmI2-Catalyzed Direct N-Alkylation of Anilines with Alcohols		J. Org. Chem.	53	Nanduri, S	FALSE	FALSE	FALSE	FALSE
5339	10.1039/c9cc02659b	doi.org/10.1039/c9cc02659b	Regioselective installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp(2))-H bonds for the construction of para-amino-arylfluorosulfates		Chem. Commun.	53	Qin, HL	FALSE	FALSE	FALSE	FALSE
5340	10.1002/cctc.201900318	doi.org/10.1002/cctc.201900318	Ti-Pd Alloys as Heterogeneous Catalysts for the Hydrogen Autotransfer Reaction and Catalytic Improvement nby Hydrogenation Effects		ChemCatChem	53	Kondo, R; Obora, Y	FALSE	FALSE	FALSE	FALSE
5341	10.1039/c8qo01405a	doi.org/10.1039/c8qo01405a	Manganese-mediated reductive amidation of esters with nitroarenes		Org. Chem. Front.	53	Cheung, CW; Ma, JA	FALSE	FALSE	FALSE	FALSE
5342	10.1021/acs.orglett.9b00059	doi.org/10.1021/acs.orglett.9b00059	Asymmetric Transfer Hydrogenation of Heterobicyclic Alkenes with Water as Hydrogen Source		Org. Lett.	53	Chen, JC; Fan, BM	FALSE	FALSE	FALSE	FALSE
5343	10.1002/adsc.201801035	doi.org/10.1002/adsc.201801035	Palladium-Catalyzed Allylic Alkylation of 2-Aryl-1,3-Dithianes, an Umpolung Synthesis of beta,gamma-Unsaturated Ketones		Adv. Synth. Catal.	53	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
5344	10.1021/acs.joc.8b02904	doi.org/10.1021/acs.joc.8b02904	Radical Anions of Aromatic Carbonitriles as Reagents for Arylation of Fluorinated Benzonitriles		J. Org. Chem.	53	Peshkov, RY	FALSE	FALSE	FALSE	FALSE
5345	10.3390/catal9010076	doi.org/10.3390/catal9010076	Benzothiazole Nickelation: An Obstacle to the Catalytic Arylation of Azoles by Cyclopentadienyl Nickel N-Heterocyclic Carbene Complexes		Catalysts	53	Chetcuti, MJ; Ritleng, V	FALSE	FALSE	FALSE	FALSE
5346	10.1038/s41467-018-07069-1	doi.org/10.1038/s41467-018-07069-1	Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives		Nat. Commun.	53	Zeng, XM	FALSE	FALSE	FALSE	FALSE
5347	10.1021/jacs.8b09473	doi.org/10.1021/jacs.8b09473	Ni-Catalyzed Reductive Coupling of Electron-Rich Aryl Iodides with Tertiary Alkyl Halides		J. Am. Chem. Soc.	53	Gong, HG	FALSE	TRUE	FALSE	FALSE
5348	10.1039/c8cc06202a	doi.org/10.1039/c8cc06202a	C-H functionalisation of aldehydes using light generated, non-stabilised diazo compounds in flow		Chem. Commun.	53	Ley, SV	FALSE	FALSE	FALSE	FALSE
5349	10.1021/acs.organomet.8b00438	doi.org/10.1021/acs.organomet.8b00438	Comprehensive Study of the Reactions Between Chelating Phosphines and Ni(cod)(2)		Organometallics	53	Louie, J	FALSE	FALSE	FALSE	FALSE
5350	10.1039/c8ob01389f	doi.org/10.1039/c8ob01389f	Nickel-catalysed radical tandem cyclisation/arylation: practical synthesis of 4-benzyl-3,3-difluoro-gamma-lactams		Org. Biomol. Chem.	53	Mai, WP; Lu, K	FALSE	FALSE	FALSE	FALSE
5351	10.1021/acs.orglett.8b01582	doi.org/10.1021/acs.orglett.8b01582	Palladium-Catalyzed Reductive Conversion of Acyl Fluorides via Ligand-Controlled Decarbonylation		Org. Lett.	53	Ogiwara, Y; Sakai, N	FALSE	FALSE	FALSE	FALSE
5352	10.1021/acs.orglett.8b01327	doi.org/10.1021/acs.orglett.8b01327	Diels-Alder and Stille Coupling Approach for the Short Protecting-Group-Free Synthesis of Mycophenolic Acid, Its Phenylsulfenyl and Phenylselenyl Analogues, and Reactive Oxygen Species (ROS) Probing Capacity in Water		Org. Lett.	53	Churchill, DG	FALSE	FALSE	FALSE	FALSE
5353	10.1002/ajoc.201800070	doi.org/10.1002/ajoc.201800070	Heterobimetallic Lanthanide-Sodium Alkoxides Catalyze the Amidation of Esters		Asian J. Org. Chem.	53	Yuan, D; Yao, YM	FALSE	FALSE	FALSE	FALSE
5354	10.1039/c8cc00358k	doi.org/10.1039/c8cc00358k	Ni-catalyzed two-component reductive dicarbofunctionalization of alkenes via radical cyclization		Chem. Commun.	53	Diao, TN	FALSE	FALSE	FALSE	FALSE
5355	10.1002/anie.201712429	doi.org/10.1002/anie.201712429	A New Portal to SuFEx Click Chemistry: A Stable Fluorosulfuryl Imidazolium Salt Emerging as an F-SO2+ Donor of Unprecedented Reactivity, Selectivity, and Scope		Angew. Chem.-Int. Edit.	53	Sharpless, KB; Dong, JJ	FALSE	FALSE	FALSE	FALSE
5356	10.1002/adsc.201701115	doi.org/10.1002/adsc.201701115	Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands		Adv. Synth. Catal.	53	Sortais, JB	FALSE	FALSE	FALSE	FALSE
5357	10.1039/c8ra01377b	doi.org/10.1039/c8ra01377b	Cobalt-catalyzed C(sp(3))-H/C(sp(2))-H oxidative coupling between alkanes and benzamides		RSC Adv.	53	Liu, H	FALSE	FALSE	FALSE	FALSE
5358	10.1021/jacs.7b10009	doi.org/10.1021/jacs.7b10009	Irradiation-Induced Heck Reaction of Unactivated Alkyl Halides at Room Temperature		J. Am. Chem. Soc.	53	Shang, R; Fe, Y	FALSE	FALSE	FALSE	FALSE
5359	10.1039/c7cc07777g	doi.org/10.1039/c7cc07777g	Ruthenium-catalyzed olefinic C-H alkenylation of enol-carbamates: highly stereo-selective synthesis of (Z,Z) and (Z,E)-butadienes		Chem. Commun.	53	Zhang, J; Zhong, GF	FALSE	FALSE	FALSE	FALSE
5360	10.1021/jacs.7b07373	doi.org/10.1021/jacs.7b07373	Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins		J. Am. Chem. Soc.	53	Lambrecht, DS; Liu, P	FALSE	FALSE	FALSE	FALSE
5361	10.1021/acscatal.7b02919	doi.org/10.1021/acscatal.7b02919	Entrances, Traps, and Rate-Controlling Factors for Nickel-Catalyzed C-H Functionalization		ACS Catal.	53	Montgomery, J; Zimmerman, PM	FALSE	FALSE	FALSE	FALSE
5362	10.1039/c6gc00367b	doi.org/10.1039/c6gc00367b	Water - the best solvent for DMAP-mediated dual cyclization towards metal-free first synthesis of fully substituted phthalimides		Green Chem.	53	Maiti, DK	FALSE	FALSE	FALSE	FALSE
5363	10.1039/c6ob01281g	doi.org/10.1039/c6ob01281g	Palladium-catalysed direct C-2 methylation of indoles		Org. Biomol. Chem.	53	Ding, YS	FALSE	FALSE	FALSE	FALSE
5364	10.1021/acs.joc.5b01292	doi.org/10.1021/acs.joc.5b01292	Chemical Dynamic Thermodynamic Resolution and S/R Interconversion of Unprotected Unnatural Tailor-made alpha-Amino Acids		J. Org. Chem.	53	Sooshonok, VA	FALSE	FALSE	FALSE	FALSE
5365	10.1021/acs.joc.5b01272	doi.org/10.1021/acs.joc.5b01272	Buchwald-Hartwig Amination of (Hetero)Aryl Tosylates Using a Well-Defined N-Heterocyclic Carbene/Palladium(II) Precatalyst		J. Org. Chem.	53	Cesar, V	FALSE	FALSE	FALSE	FALSE
5366	10.1021/acs.joc.5b00771	doi.org/10.1021/acs.joc.5b00771	Synthesis of 2-Arylpyridopyrimidinones, 6-Aryluracils, and Tri- and Tetrasubstituted Conjugated Alkenes via Pd-Catalyzed Enolic C-O Bond Activation-Arylation		J. Org. Chem.	53	Guchhait, SK	FALSE	FALSE	FALSE	FALSE
5367	10.1021/ic502792q	doi.org/10.1021/ic502792q	Synthesis and Structural Studies of Nickel(0) Tetracarbene Complexes with the Introduction of a New Four-Coordinate Geometric Index, tau(delta)		Inorg. Chem.	53	Kubiak, CP	FALSE	FALSE	FALSE	FALSE
5368	10.1002/chem.201405275	doi.org/10.1002/chem.201405275	Chemoselective Chromium(II)-Catalyzed Cross-Coupling Reactions of Dichlorinated Heteroaromatics with Functionalized Aryl Grignard Reagents		Chem.-Eur. J.	53	Malhotra, S	FALSE	FALSE	FALSE	FALSE
5369	10.1039/c5cc05312a	doi.org/10.1039/c5cc05312a	Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to alpha-alkyl vinylarenes		Chem. Commun.	53	Stahl, SS	FALSE	FALSE	FALSE	FALSE
5370	10.1021/ol503229c	doi.org/10.1021/ol503229c	Mild Rhodium(III)-Catalyzed C-H Allylation with 4-Vinyl-1,3-dioxolan-2-ones: Direct and Stereoselective Synthesis of (E)-Allylic Alcohols		Org. Lett.	53	Wang, HG	FALSE	FALSE	FALSE	FALSE
5371	10.1055/s-0034-1379366	doi.org/10.1055/s-0034-1379366	Synthesis of Diarylmethanes through Palladium-Catalyzed Coupling of Benzylic Phosphates with Arylsilanes		Synlett	53	Zhang, PB	FALSE	FALSE	FALSE	FALSE
5372	10.1021/ol500675q	doi.org/10.1021/ol500675q	Application of Cooperative Iron/Copper Catalysis to a Palladium-Free Borylation of Aryl Bromides with Pinacolborane		Org. Lett.	53	Chavant, PY	FALSE	FALSE	FALSE	FALSE
5373	10.1515/pac-2014-5041	doi.org/10.1515/pac-2014-5041	The strategic generation and interception of palladium-hydrides for use in alkene functionalization reactions		Pure Appl. Chem.	53	Sigman, MS	FALSE	FALSE	FALSE	FALSE
5374	10.1021/ol500112y	doi.org/10.1021/ol500112y	Direct Cross-Coupling Access to Diverse Aromatic Sulfide: Palladium-Catalyzed Double C-S Bond Construction Using Na2S2O3 as a Sulfurating Reagent		Org. Lett.	53	Jiang, XF	FALSE	FALSE	FALSE	FALSE
5375	10.1246/bcsj.20130166	doi.org/10.1246/bcsj.20130166	Scope and Limitation for FeSO4-Mediated Direct Arylation of Heteroarenes with Arylboronic Acids and Its Synthetic Applications		Bull. Chem. Soc. Jpn.	53	Komeyama, K	FALSE	FALSE	FALSE	FALSE
5376	10.1039/c4ra07105k	doi.org/10.1039/c4ra07105k	Upgrading malic acid to bio-based benzoates via a Diels-Alder-initiated sequence with the methyl coumalate platform		RSC Adv.	53	Kraus, GA	FALSE	FALSE	FALSE	FALSE
5377	10.1039/c4qo00253a	doi.org/10.1039/c4qo00253a	Efficient and scalable Pd-catalyzed double aminocarbonylations under atmospheric pressure at low catalyst loadings		Org. Chem. Front.	53	Liu, SL	FALSE	FALSE	FALSE	FALSE
5378	10.1039/c4dt02374a	doi.org/10.1039/c4dt02374a	Mechanism of Ni N-heterocyclic carbene catalyst for C-O bond hydrogenolysis of diphenyl ether: a density functional study		Dalton Trans.	53	Surawatanawong, P	FALSE	FALSE	FALSE	FALSE
5379	10.1080/00304948.2013.834772	doi.org/10.1080/00304948.2013.834772	Microwave-assisted Suzuki Cross-Coupling Reactions using Dimeric ortho-palladated Complex of Tribenzylamine		Org. Prep. Proced. Int.	53	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
5380	10.1002/chem.201302677	doi.org/10.1002/chem.201302677	Synthesis of Catechol-, Pinacol-, and Neopentylglycolborane through the Heterogeneous Catalytic B-B Hydrogenolysis of Diboranes(4)		Chem.-Eur. J.	53	Braunschweig, H	FALSE	FALSE	FALSE	FALSE
5381	10.1002/anie.201305098	doi.org/10.1002/anie.201305098	Alkoxide Activation of Aminoboranes towards Selective Amination		Angew. Chem.-Int. Edit.	53	Fernandez, E	FALSE	FALSE	FALSE	FALSE
5382	10.1021/ja407749w	doi.org/10.1021/ja407749w	Regioselective Allene Hydrosilylation Catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium		J. Am. Chem. Soc.	53	Montgomery, J	FALSE	FALSE	FALSE	FALSE
5383	10.1016/j.tet.2013.07.019	doi.org/10.1016/j.tet.2013.07.019	Ligand-free indium(III)-catalyzed Heck reaction		Tetrahedron	53	Pan, YM	FALSE	FALSE	FALSE	FALSE
5384	10.1002/pola.26750	doi.org/10.1002/pola.26750	Synthesis of high performance polyacrylonitrile by RASA SET-LRP in the presence of Mg powder		J. Polym. Sci. Pol. Chem.	53	Chen, H	FALSE	FALSE	FALSE	FALSE
5385	10.1016/j.tet.2013.05.063	doi.org/10.1016/j.tet.2013.05.063	A novel allylic substitution strategy to four-component synthesis of pyrazole-substituted fused pyrroles		Tetrahedron	53	Jiang, B	FALSE	FALSE	FALSE	FALSE
5386	10.1021/ja404285b	doi.org/10.1021/ja404285b	Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive		J. Am. Chem. Soc.	53	Kambe, N	FALSE	FALSE	FALSE	FALSE
5387	10.1002/chem.201300127	doi.org/10.1002/chem.201300127	Vinyl Nosylates: An Ideal Partner for Palladium-Catalyzed Cross-Coupling Reactions		Chem.-Eur. J.	53	Weibel, JM	FALSE	FALSE	FALSE	FALSE
5388	10.1021/ja402740q	doi.org/10.1021/ja402740q	Pd-Catalyzed Asymmetric Allylic Alkylation of Pyrazol-5-ones with Allylic Alcohols: The Role of the Chiral Phosphoric Acid in C-O Bond Cleavage and Stereocontrol		J. Am. Chem. Soc.	53	Gong, LZ	FALSE	FALSE	FALSE	FALSE
5389	10.1002/chem.201300229	doi.org/10.1002/chem.201300229	Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines		Chem.-Eur. J.	53	Gosmini, C	FALSE	TRUE	FALSE	FALSE
5390	10.1021/ol3019665	doi.org/10.1021/ol3019665	Robust Acenaphthoimidazolylidene Palladium Complexes: Highly Efficient Catalysts for Suzuki-Miyaura Couplings with Sterically Hindered Substrates		Org. Lett.	53	Tu, T	FALSE	FALSE	FALSE	FALSE
5391	10.1016/j.tetlet.2012.06.054	doi.org/10.1016/j.tetlet.2012.06.054	A general rhodium-catalyzed cross-coupling reaction of thiols with aryl iodides		Tetrahedron Lett.	53	Lee, CF	FALSE	FALSE	FALSE	FALSE
5392	10.1021/ja3013825	doi.org/10.1021/ja3013825	Nickel-Catalyzed Negishi Alkylations of Styrenyl Aziridines		J. Am. Chem. Soc.	53	Doyle, AG	FALSE	FALSE	FALSE	FALSE
5393	10.1016/j.ica.2012.01.057	doi.org/10.1016/j.ica.2012.01.057	Synthesis and reactivity of bis(diphenylphosphino)amine ligands and their application in Suzuki cross-coupling reactions		Inorg. Chim. Acta	53	Kayan, C	FALSE	FALSE	FALSE	FALSE
5394	10.1002/adsc.201100927	doi.org/10.1002/adsc.201100927	Platinum on Carbon-Catalyzed Hydrodefluorination of Fluoroarenes using Isopropyl Alcohol-Water-Sodium Carbonate Combination		Adv. Synth. Catal.	53	Sajiki, H	FALSE	FALSE	FALSE	FALSE
5395	10.1039/c2ra20231j	doi.org/10.1039/c2ra20231j	The first organocatalytic asymmetric synthesis of 3-substituted isoindolinones		RSC Adv.	53	More, V	FALSE	FALSE	FALSE	FALSE
5396	10.1002/anie.201203778	doi.org/10.1002/anie.201203778	Gallium Tribromide Catalyzed Coupling Reaction of Alkenyl Ethers with Ketene Silyl Acetals		Angew. Chem.-Int. Edit.	53	Baba, A	FALSE	FALSE	FALSE	FALSE
5397	10.1002/adsc.201100262	doi.org/10.1002/adsc.201100262	sp(3)-sp(2) C-C Bond Formation via Bronsted Acid Trifluoromethanesulfonic Acid-Catalyzed Direct Coupling Reaction of Alcohols and Alkenes		Adv. Synth. Catal.	53	Ji, JX	FALSE	FALSE	FALSE	FALSE
5398	10.1021/ja206850s	doi.org/10.1021/ja206850s	Nickel-Catalyzed Chelation-Assisted Transformations Involving Ortho C-H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes		J. Am. Chem. Soc.	53	Chatani, N	FALSE	FALSE	FALSE	FALSE
5399	10.1002/asia.201100147	doi.org/10.1002/asia.201100147	Gold(I)-Catalyzed Cyclization of Alkynyl Hydrogen Phosphates		Chem.-Asian J.	53	Kim, S	FALSE	FALSE	FALSE	FALSE
5400	10.1021/ol200964m	doi.org/10.1021/ol200964m	Concise, Convergent Syntheses of (+/-)-Trichostatin A Utilizing a Pd-Catalyzed Ketone Enolate alpha-Alkenylation Reaction		Org. Lett.	53	Helquist, P	FALSE	FALSE	FALSE	FALSE
5401	10.1021/ol2012132	doi.org/10.1021/ol2012132	Trifluoromethanesulfonic Acid Catalyzed Isomerization of Kinetic Enol Derivatives to the Thermodynamically Favored Isomers		Org. Lett.	53	Lee, PH	FALSE	FALSE	FALSE	FALSE
5402	10.1021/om200004a	doi.org/10.1021/om200004a	Solvent Dependence of the Structure of Ethylzinc Acetate and Its Application in CO2/Epoxide Copolymerization		Organometallics	53	Shaffer, MSP	FALSE	FALSE	FALSE	FALSE
5403	10.1021/om200060x	doi.org/10.1021/om200060x	Nickel-Catalyzed Cross-Coupling of Organogold Reagents		Organometallics	53	Blum, SA	FALSE	FALSE	FALSE	FALSE
5404	10.1021/ol9028034	doi.org/10.1021/ol9028034	Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C-H Bond Cleavages with Sulfamates or Phosphates as Electrophiles		Org. Lett.	53	Ackermann, L	FALSE	TRUE	FALSE	FALSE
5405	10.1021/jo901728b	doi.org/10.1021/jo901728b	Formation of Chiral C(sp(3))-C(sp) Bond by Allylic Substitution of Secondary Allylic Picolinates and Alkynyl Copper Reagents		J. Org. Chem.	53	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
5406	10.1021/ol901745x	doi.org/10.1021/ol901745x	Tandem C-C Bond-Forming Processes: Interception of the Pd-Catalyzed Decarboxylative Allylation of Allyl Diphenylglycinate Imines with Activated Olefins		Org. Lett.	53	Chruma, JJ	FALSE	FALSE	FALSE	FALSE
5407	10.1055/s-0029-1217368	doi.org/10.1055/s-0029-1217368	Ni-Catalyzed Carbocyclization of 1,6-Enynes Mediated by Dialkylzinc Reagents: Me2Zn or Et2Zn Makes a Difference		Synlett	53	Zhao, G	FALSE	FALSE	FALSE	FALSE
5408	10.1021/jo900098a	doi.org/10.1021/jo900098a	A Ligand Free and Room Temperature Protocol for Pd-Catalyzed Kumada-Corriu Couplings of Unactivated Alkenyl Phosphates		J. Org. Chem.	53	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
5409	10.1016/j.tetlet.2008.08.002	doi.org/10.1016/j.tetlet.2008.08.002	Selective aromatic carbon-oxygen bond cleavage of trifluoromethoxyarenes: a trifluoromethoxy group as a convertible directing group		Tetrahedron Lett.	53	Amii, H	FALSE	FALSE	FALSE	FALSE
5410	10.1039/b809626k	doi.org/10.1039/b809626k	Synthesis of functionalised diarylmethanes via a cobalt-catalysed cross-coupling of arylzinc species with benzyl chlorides		Chem. Commun.	53	Amatore, M	FALSE	FALSE	FALSE	FALSE
5411	10.1002/asia.200800161	doi.org/10.1002/asia.200800161	A general preparation of polyfunctional benzylic zinc organometallic compounds		Chem.-Asian J.	53	Knochel, P	FALSE	FALSE	FALSE	FALSE
5412	10.1002/anie.200802157	doi.org/10.1002/anie.200802157	Palladium-catalyzed amination of aryl mesylates		Angew. Chem.-Int. Edit.	53	Kwong, FY	FALSE	FALSE	FALSE	FALSE
5413	10.1080/00397910701831498	doi.org/10.1080/00397910701831498	Palladium-catalyzed cyanation of aryl triflates		Synth. Commun.	53	Cai, C	FALSE	FALSE	FALSE	FALSE
5414	10.1016/j.tetlet.2006.11.156	doi.org/10.1016/j.tetlet.2006.11.156	Short synthesis of 4-aryl-3-pyrrolin-2-ones		Tetrahedron Lett.	53	Pelkey, ET	FALSE	FALSE	FALSE	FALSE
5415	10.1021/jo982135h	doi.org/10.1021/jo982135h	Microwave-assisted aqueous Suzuki cross-coupling reactions		J. Org. Chem.	53	Schotten, T	FALSE	FALSE	FALSE	FALSE
5416	10.1021/jo982312e	doi.org/10.1021/jo982312e	Nickel-catalyzed highly stereoselective ring opening of 7-oxa- and azanorbornenes with organic halides		J. Org. Chem.	53	Cheng, CH	FALSE	FALSE	FALSE	FALSE
5417	10.1021/ma951840e	doi.org/10.1021/ma951840e	Regioregular and regioirregular poly(p-phenylene)s via Ni(O)-catalyzed homocoupling of arylene bismesylates		Macromolecules	53	Percec, V	FALSE	FALSE	FALSE	FALSE
5418	10.1021/jacs.1c11044	doi.org/10.1021/jacs.1c11044	Ni/Chiral Sodium Carboxylate Dual Catalyzed Asymmetric O-Propargylation		J. Am. Chem. Soc.	53	Guo, C	FALSE	FALSE	FALSE	FALSE
5419	10.1021/acscatal.1c04239	doi.org/10.1021/acscatal.1c04239	Ni-Catalyzed Formal Cross-Electrophile Coupling of Alcohols with Aryl Halides		ACS Catal.	53	Ma, GB; Gong, H	FALSE	TRUE	FALSE	FALSE
5420	10.1039/d1cc05221g	doi.org/10.1039/d1cc05221g	Synthesis of 1,4-enynes via nickel-catalyzed cross-coupling of allylic alcohols with alkynylzinc reagents		Chem. Commun.	53	Wang, ZX	FALSE	FALSE	FALSE	FALSE
5421	10.1039/d1ob01806j	doi.org/10.1039/d1ob01806j	Visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones		Org. Biomol. Chem.	53	Wang, QM	FALSE	FALSE	FALSE	FALSE
5422	10.1039/d1dt02849a	doi.org/10.1039/d1dt02849a	One pot tandem dual C=C and C=O bond reductions in the beta-alkylation of secondary alcohols with primary alcohols by ruthenium complexes of amido and picolyl functionalized N-heterocyclic carbenes		Dalton Trans.	53	Ghosh, P	FALSE	FALSE	FALSE	FALSE
5423	10.1126/sciadv.abh4088	doi.org/10.1126/sciadv.abh4088	Synthesis of medicinally relevant oxalylamines via copper/Lewis acid synergistic catalysis		Sci. Adv.	53	Wu, WQ; Jiang, HF	FALSE	FALSE	FALSE	FALSE
5424	10.1021/jacs.1c05346	doi.org/10.1021/jacs.1c05346	Direct Observation of Diastereomeric alpha-C-Bound Enolates during Enantioselective alpha-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes		J. Am. Chem. Soc.	53	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
5425	10.1039/d1ob01054a	doi.org/10.1039/d1ob01054a	Copper-promoted direct amidation of isoindolinone scaffolds by sodium persulfate		Org. Biomol. Chem.	53	Zha, DJ	FALSE	FALSE	FALSE	FALSE
5426	10.1021/jacs.1c03228	doi.org/10.1021/jacs.1c03228	Catalytic Regioselective Olefin Hydroarylation(alkenylation) by Sequential Carbonickelation-Hydride Transfer		J. Am. Chem. Soc.	53	Wang, HY; Koh, MJ	FALSE	FALSE	FALSE	FALSE
5427	10.1039/d1ob00521a	doi.org/10.1039/d1ob00521a	Sterically hindering the trajectory of nucleophilic attack towards p-benzynes by a properly oriented hydrogen atom: an approach to achieve regioselectivity		Org. Biomol. Chem.	53	Singha, M; Basak, A	FALSE	FALSE	FALSE	FALSE
5428	10.1021/acs.orglett.1c00465	doi.org/10.1021/acs.orglett.1c00465	Access to alpha-Cyano Carbonyls Bearing a Quaternary Carbon Center by Reductive Cyanation		Org. Lett.	53	Dong, KW	FALSE	FALSE	FALSE	FALSE
5429	10.1021/acs.orglett.1c00671	doi.org/10.1021/acs.orglett.1c00671	Late-Stage F-18/F-19 Isotopic Exchange for the Synthesis of F-18-Labeled Sulfamoyl Fluorides		Org. Lett.	53	Chun, JH	FALSE	FALSE	FALSE	FALSE
5430	10.1039/c7ob00841d	doi.org/10.1039/c7ob00841d	Ni and Cu-catalyzed one pot synthesis of unsymmetrical 1,3-di(hetero) aryl-1H-indazoles from hydrazine, o-chloro (hetero) benzophenones, and (hetero) aryl bromides		Org. Biomol. Chem.	53	Bonacorso, HG	FALSE	FALSE	FALSE	FALSE
5431	10.1021/jacs.7b02326	doi.org/10.1021/jacs.7b02326	Deoxygenation of Ethers To Form Carbon-Carbon Bonds via Nickel Catalysis		J. Am. Chem. Soc.	53	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
5432	10.1039/c7ob00593h	doi.org/10.1039/c7ob00593h	Amidation of unactivated ester derivatives mediated by trifluoroethanol		Org. Biomol. Chem.	53	Jamieson, C	FALSE	FALSE	FALSE	FALSE
5433	10.1021/acs.orglett.7b00579	doi.org/10.1021/acs.orglett.7b00579	Differentially Substituted Phosphines via Decarbonylation of Acylphosphines		Org. Lett.	53	Wang, ZQ	FALSE	FALSE	FALSE	FALSE
5434	10.1002/jhet.2513	doi.org/10.1002/jhet.2513	Nickel-catalyzed Kumada Cross-coupling Reaction for the Synthesis of 2,4-Diarylquinazolines		J. Heterocycl. Chem.	53	Peng, YY	FALSE	FALSE	FALSE	FALSE
5435	10.1016/j.tetlet.2016.06.022	doi.org/10.1016/j.tetlet.2016.06.022	Cross-coupling of vinylethylene carbonates with arylboronic acids catalyzed by in situ generated palladium nanoparticles in water		Tetrahedron Lett.	53	Zhang, YJ	FALSE	FALSE	FALSE	FALSE
5436	10.1002/adsc.201600205	doi.org/10.1002/adsc.201600205	Electron-Poor, Fluoro-Containing Arylboronic Acids as Efficient Coupling Partners for Bis(1,5-cyclooctadiene)nickel(0)/Tricyclohexylphosphine-Catalyzed Cross-Coupling Reactions of Aryl Arenesulfonates		Adv. Synth. Catal.	53	Hu, QS	FALSE	TRUE	FALSE	FALSE
5437	10.1002/chem.201601515	doi.org/10.1002/chem.201601515	Practical Stannylation of Allyl Acetates Catalyzed by Nickel with Bu3SnOMe		Chem.-Eur. J.	53	Komeyama, K	FALSE	FALSE	FALSE	FALSE
5438	10.1021/acs.joc.6b00883	doi.org/10.1021/acs.joc.6b00883	Nickel-Catalyzed Hiyama-type Decarboxylative Coupling of Propiolic Acids and Organosilanes		J. Org. Chem.	53	Kim, J; Lee, S	FALSE	FALSE	FALSE	FALSE
5439	10.1021/acs.joc.6b00466	doi.org/10.1021/acs.joc.6b00466	Chan-Evans-Lam Amination of Boronic Acid Pinacol (BPin) Esters: Overcoming the Aryl Amine Problem		J. Org. Chem.	53	Watson, AJB	FALSE	FALSE	FALSE	FALSE
5440	10.1002/adsc.201500928	doi.org/10.1002/adsc.201500928	Catalytic Enantioselective Total Synthesis of Riccardiphenol B		Adv. Synth. Catal.	53	Alexakis, A	FALSE	FALSE	FALSE	FALSE
5441	10.1021/acs.orglett.0c04056	doi.org/10.1021/acs.orglett.0c04056	Synthesis of Substituted Anilines from Cyclohexanones Using Pd/C-Ethylene System and Its Application to Indole Synthesis		Org. Lett.	52	Hayashi, M	FALSE	FALSE	FALSE	FALSE
5442	10.1021/acs.orglett.1c00058	doi.org/10.1021/acs.orglett.1c00058	Using Chlorotrifluoroethane for Trifluoroethylation of (Hetero)aryl Bromides and Chlorides via Nickel Catalysis	BACKGROUNDQuinoxyfen is a fungicide developed by Dow AgroSciences for the control of powdery mildew. Re-registration studies required gram quantities of 2-chloro-10-fluorochromeno[2,3,4-de]quinoline, a photometabolite of quinoxyfen. The only previous method of preparation of this photometabolite was by photolysis of quinoxyfen in less than 1% yield. Therefore, a new method allowing for the preparation of this photometabolite in gram quantities was required. RESULTSSeveral different metal catalyzed intramolecular cyclization approaches were investigated for the synthesis of 2-chloro-10-fluorochromeno[2,3,4-de]quinoline. While most methods failed to provide the desired product from a 2-bromophenyl derivative of quinoxyfen, a novel one-pot two-step synthesis led to the desired material in good yield from quinoxyfen. CONCLUSIONA short and efficient synthetic route was developed to access 2-chloro-10-fluorochromeno[2,3,4-de]quinoline from readily available (4-fluoro-2-hydroxyphenyl)boronic acid and quinoxyfen and was found to be scalable, which enabled the preparation of the desired photometabolite in gram quantities thus meeting material requirements to complete regulatory studies for the re-registration of quinoxyfen. (c) 2017 Society of Chemical Industry	Org. Lett.	52	Zhang, XG	FALSE	FALSE	FALSE	FALSE
5443	10.1039/d0ra08737h	doi.org/10.1039/d0ra08737h	LiCl-promoted-dehydration of fructose-based carbohydrates into 5-hydroxymethylfurfural in isopropanol	A novel copper-catalyzed arylation of benzylic C-H bonds with nucleophilic arylboronic acids has been developed that provides an efficient way to synthesize various 1,1-diarylalkanes with a broad substrate scope and excellent functional group compatibility. The reactions occur at room temperature using alkylarenes as the limiting reagents, which allows access to the arylation of the more valuable and complex bioactive compounds.	RSC Adv.	52	Ma, H	FALSE	FALSE	FALSE	FALSE
5444	10.1002/ejoc.202001335	doi.org/10.1002/ejoc.202001335	Metal-Free Hydrophosphoryloxylation of Ynamides: Rapid Access to Enol Phosphates	Although Ni(PEt3)(4) does not react with di- or trifluoroarenes at room temperature, upon the addition of aluminum hydrocarbons such as AlMe3 an immediate reaction occurs, to give AlMe2F and Ni(II) complexes from C-F bond activation and transmetalation. The influence of additional Lewis basic compounds, such as pyridine, on selectivity in these systems provides insight into how selectivity in a cross-coupling reaction is controlled by the transmetalating agent and how the oxidative addition and transmetalation steps are not necessarily distinct.	Eur. J. Org. Chem.	52	Zhao, YY	FALSE	FALSE	FALSE	FALSE
5445	10.1016/j.molstruc.2020.128635	doi.org/10.1016/j.molstruc.2020.128635	Regio-isomeric isoxazole sulfonates: Synthesis, characterization, electrochemical studies and DNA binding activity	An efficient synthesis of beta-amino alcohols from a variety of epoxides and primary unbranched amines in the absence of any catalyst in high yields and regioselectivities is reported. A variety of polar mixed solvent systems allow for the selective formation of secondary amino alcohols over tertiary amino alcohols. The reaction scope extends to a wide variety of aromatic and aliphatic substituted epoxides and primary amines bearing complex functionality.	J. Mol. Struct.	52	Hameed, S	FALSE	FALSE	FALSE	FALSE
5446	10.1021/acs.joc.0c01887	doi.org/10.1021/acs.joc.0c01887	Examination of the Dynamic Covalent Chemistry of [2+3]-Imine Cages	Despite recent progress in the catalytic transformation of inert phenol derivatives as alternatives to aryl halides and triflates, attempts at the cross-coupling of inert phenol derivatives with the C-H bonds of arenes have met with limited success. Herein, we report the rhodium-catalyzed cross-coupling of aryl carbamates with arenes bearing a convertible directing group. The key to success is the use of an in situ generated rhodium bis(N-heterocyclic carbene) species as the catalyst, which can promote activation of the inert C(sp(2))-O bond in aryl carbamates.	J. Org. Chem.	52	Mastalerz, M	FALSE	FALSE	FALSE	FALSE
5447	10.1021/acs.joc.0c01909	doi.org/10.1021/acs.joc.0c01909	Ruthenium-Catalyzed Meta-Selective C-H Difluoromethylation of Phenol Derivatives	A regioselective and concomitant transfer of thiocyanate (-SCN) and aroyl/acyl (-COR) groups from aroyl/acyl isothiocyanates onto oxiranes was achieved, giving thiocyanato benzoates in 100% atom economy. In this biomimetic organocatalytic process, one part (-SCN) of aroyl/acyl isothiocyanates acts as the nucleophile whereas the other half (-COR) serves as an electrophilic partner.	J. Org. Chem.	52	Zhao, YS	FALSE	FALSE	FALSE	FALSE
5448	10.1039/d0qo00775g	doi.org/10.1039/d0qo00775g	Palladium-catalyzed cyanation of aryl halides with in situ generated CN(-)from ClCF2H and NaNH2	A variety of bibenzyl derivatives have been synthesized with excellent atom economy via C(sp(3))-H-C(sp(3))-H coupling of readily available methyl arenes using K2S2O8 under metal-free and environmentally benign conditions.	Org. Chem. Front.	52	Song, QL	FALSE	FALSE	FALSE	FALSE
5449	10.1039/d0qo00615g	doi.org/10.1039/d0qo00615g	Palladium-catalyzed domino Heck cyclization/ring opening of sulfolenes/desulfitative coupling: regio- and stereoselective synthesis of alkylated conjugated dienes	2-Arylbenzazoles are promising molecules for potential applications in medicine and material areas. Efficient protocols for direct regioselective functionalization of 2-arylbenzoxazoles are in high demand. Herein, we disclose a general method for selective ortho-olefination of 2-arylbenzo [d] oxazoles with alkenes enabled by versatile Cp*Rh(III) in high yields. This protocol features broad functional group tolerance and high regioselectivity. Intermolecular competition studies and kinetic isotope effect experiments imply that the oxidative olefination process occurs via an electrophilic C-H activation pathway. The molecular structure of the m-fluoro-substituted olefination product confirms regioselective C-H activation/olefination at the more hindered site in cases where the meta F atom or heteroatom substituent existed. Apparent torsion angles were observed in the structures of mono-and bis-olefination products, which resulted in distinct different chemical shifts of olefinic protons. Additionally, two gram-scale reactions and further transformation experiments demonstrate that this method is practical for synthesis of ortho-alkenylated 2-arylbenzoxazole derivatives.	Org. Chem. Front.	52	Wu, XX; Hu, LP	FALSE	FALSE	FALSE	FALSE
5450	10.1021/acs.orglett.0c01851	doi.org/10.1021/acs.orglett.0c01851	NaCl as Catalyst and Water as Solvent: Highly E-Selective Olefination of Methyl Substituted N-Heteroarenes with Benzyl Amines and Alcohols	The synthesis of four new sulfur-containing palladacycles 3a-d [FcC(S)OEtPdClZR(3), where: 3a, ZR(3): PPh3; 3b, ZR(3): P(o-Tol)(3); 3c, ZR(3): PMe3; 3d, ZR(3): SbPh3] from ferrocenyl thionoester 1 [FcC(S)OEt] in good yields is reported. The catalytic applications of these cyclopalladated complexes in Heck and Suzuki cross-coupling reactions were also evaluated, in combination with infrared or microwave as energy sources. The coupled products of these reactions were obtained in good to excellent yields, short reaction times and low catalyst loading. (C) 2016 Elsevier B.V. All rights reserved.	Org. Lett.	52	Elias, AJ	FALSE	FALSE	FALSE	FALSE
5451	10.1021/acs.orglett.0c01127	doi.org/10.1021/acs.orglett.0c01127	Pd-Catalyzed Cross-Coupling of Highly Sterically Congested Enol Carbamates with Grignard Reagents via C-O Bond Activation	An improved method for the reductive coupling of aryl and vinyl bromides with alkyl halides that gave high yields for a variety of substrates at room temperature with a low (2.5 to 0.5 mol%) catalyst loading is presented. Under the optimized conditions, difficult substrates, such as unhindered alkenyl bromides, can be coupled to give the desired olefins with minimal diene formation and good stereoretention. These improved conditions also worked well for aryl bromides. For example, a gram-scale reaction was demonstrated with 0.5 mol% catalyst loading, whereas reactions at 10 mol% catalyst loading completed in as little as 20 minutes. Finally, a low-cost single-component pre-catalyst, (bpy)NiI2 (bpy=2,2'-bipyridine) that is both air-and moisture-stable over a period of months was introduced.	Org. Lett.	52	So, CM	FALSE	FALSE	FALSE	FALSE
5452	10.1002/ejoc.201901137	doi.org/10.1002/ejoc.201901137	Vitamin B-12 Enables Consecutive Generation of Acyl and Alkyl Radicals from One Reagent	We have investigated and exploited a new photochemical route to hydrated electrons, which are among the strongest reductants known and can even be used for direct carbon dioxide and nitrogen fixation. Our electron precursor is the ascorbate dianion, which we photoionize with a 355 nm laser. The method is instrumentally much simpler and far less accompanied by health and safety issues than is pulse radiolysis. Advantages over other photoionizable substrates or systems comprise the favourably long operating wavelength, at which many additives do not absorb anymore; the low price and nonexisting biohazards of this naturally occurring electron precursor; and the lack of visible absorption as well as the nonreactivity of the ionization by-product, the ascorbate radical, which greatly simplifies the mechanistic and kinetic studies of subsequent reactions. To illustrate the usefulness of this electron source, we have prepared a number of radical anions (through scavenging the electrons) including several that are inaccessible by the usual photochemical route for mechanistic or thermodynamic reasons, obtained their calibrated absorption spectra, and in one case investigated their green-light photochemistry. As proof of its applicability to environmental remediation, we have successfully utilized this electron generator to detoxify a model compound for halogenated organic waste.	Eur. J. Org. Chem.	52	Gryko, D	FALSE	FALSE	FALSE	FALSE
5453	10.3390/molecules25030602	doi.org/10.3390/molecules25030602	Nickel-Catalyzed Removal of Alkene Protecting Group of Phenols, Alcohols via Chain Walking Process		Molecules	52	Yi, J	FALSE	FALSE	FALSE	FALSE
5454	10.1002/aoc.5517	doi.org/10.1002/aoc.5517	Facile amidation of esters with aromatic amines promoted by lanthanide tris (amide) complexes		Appl. Organomet. Chem.	52	Luo, YJ	FALSE	FALSE	FALSE	FALSE
5455	10.1002/adsc.201901096	doi.org/10.1002/adsc.201901096	Amino Acids: Nontoxic and Cheap Alternatives for Amines for the Synthesis of Benzoxazoles through the Oxidative Functionalization of Catechols		Adv. Synth. Catal.	52	Sharghi, H	FALSE	FALSE	FALSE	FALSE
5456	10.1038/s41929-019-0392-6	doi.org/10.1038/s41929-019-0392-6	An air-stable binary Ni(0)-olefin catalyst		Nat. Catal.	52	Cornella, J	FALSE	FALSE	FALSE	FALSE
5457	10.1016/j.matpr.2019.08.151	doi.org/10.1016/j.matpr.2019.08.151	Ag/GO nanocatalysts for N-alkylation		Mater. Today-Proc.	52	Sarno, M	FALSE	FALSE	FALSE	FALSE
5458	10.1002/anie.201913518	doi.org/10.1002/anie.201913518	Construction of Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 3-Arylpiperidin-2-ones Under Phase-Transfer Conditions		Angew. Chem.-Int. Edit.	52	Kano, T; Maruoka, K	FALSE	FALSE	FALSE	FALSE
5459	10.1039/c9qo01073d	doi.org/10.1039/c9qo01073d	The decarboxylative C-H heteroarylation of azoles catalysed by nickel catalysts to access unsymmetrical biheteroaryls		Org. Chem. Front.	52	Yang, K; Li, ZY; Sun, XQ	FALSE	FALSE	FALSE	FALSE
5460	10.1021/acs.orglett.9b03475	doi.org/10.1021/acs.orglett.9b03475	Nickel-Catalyzed Benzylic Substitution of Benzyl Esters with Malonates as a Soft Carbon Nucleophile		Org. Lett.	52	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
5461	10.1016/j.chempr.2019.07.023	doi.org/10.1016/j.chempr.2019.07.023	Gold-Catalyzed Oxidative Biaryl Cross-Coupling of Organometallics		Chem	52	Xie, J	FALSE	FALSE	FALSE	FALSE
5462	10.1039/c9na00368a	doi.org/10.1039/c9na00368a	Atomic layer deposition of palladium nanoparticles on a functional electrospun poly-cyclodextrin nanoweb as a flexible and reusable heterogeneous nanocatalyst for the reduction of nitroaromatic compounds		Nanoscale Adv.	52	Topuz, F; Uyar, T	FALSE	FALSE	FALSE	FALSE
5463	10.1039/c9qo00744j	doi.org/10.1039/c9qo00744j	Ni-Catalyzed enantioselective reductive aryl-alkenylation of alkenes: application to the synthesis of (+)-physovenine and (+)-physostigmine		Org. Chem. Front.	52	Lei, AW; Kong, WQ	FALSE	FALSE	FALSE	FALSE
5464	10.1002/ajoc.201900438	doi.org/10.1002/ajoc.201900438	Ligand-Free FeCl2-Catalyzed alpha-Alkylation of Ketones with Alcohols		Asian J. Org. Chem.	52	Yang, Y	FALSE	FALSE	FALSE	FALSE
5465	10.1021/acs.orglett.9b01989	doi.org/10.1021/acs.orglett.9b01989	Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor		Org. Lett.	52	Iwai, T; Sawamura, M	FALSE	FALSE	FALSE	FALSE
5466	10.1021/jacs.9b04136	doi.org/10.1021/jacs.9b04136	Highly Chemoselective, Transition-Metal-Free Transamidation of Unactivated Amides and Direct Amidation of Alkyl Esters by N-C/O-C Cleavage		J. Am. Chem. Soc.	52	Szostak, M	FALSE	FALSE	FALSE	FALSE
5467	10.1002/adsc.201801713	doi.org/10.1002/adsc.201801713	Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand		Adv. Synth. Catal.	52	Sawamura, M	FALSE	FALSE	FALSE	FALSE
5468	10.1002/chem.201901150	doi.org/10.1002/chem.201901150	One-Pot Sequential Kumada-Tamao-Corriu Couplings of (Hetero) Aryl Polyhalides in the Presence of Grignard-Sensitive Functional Groups Using Pd-PEPPSI-IPent(Cl)		Chem.-Eur. J.	52	Organ, MG	FALSE	FALSE	FALSE	FALSE
5469	10.1021/acscatal.8b05072	doi.org/10.1021/acscatal.8b05072	Cobalamin-Dependent Apparent Intramolecular Methyl Transfer for Biocatalytic Constitutional Isomerization of Catechol Monomethyl Ethers		ACS Catal.	52	Kroutil, W	FALSE	FALSE	FALSE	FALSE
5470	10.1021/acs.orglett.9b00698	doi.org/10.1021/acs.orglett.9b00698	N-Arylation of NH-Sulfoximines via Dual Nickel Photocatalysis		Org. Lett.	52	Konig, B	TRUE	FALSE	FALSE	FALSE
5471	10.1021/jacs.9b02338	doi.org/10.1021/jacs.9b02338	Asymmetric Propargylic Radical Cyanation Enabled by Dual Organophotoredox and Copper Catalysis		J. Am. Chem. Soc.	52	Lu, LQ; Xiao, WJ	FALSE	FALSE	FALSE	FALSE
5472	10.1002/anie.201900721	doi.org/10.1002/anie.201900721	Kinetic Resolution and Dynamic Kinetic Resolution of Chromene by Rhodium-Catalyzed Asymmetric Hydroarylation		Angew. Chem.-Int. Edit.	52	Wang, J	FALSE	FALSE	FALSE	FALSE
5473	10.1002/anie.201814475	doi.org/10.1002/anie.201814475	Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of -Lactams with Aryl Chlorides and Bromides		Angew. Chem.-Int. Edit.	52	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
5474	10.1021/acs.orglett.8b03918	doi.org/10.1021/acs.orglett.8b03918	Transition-Metal-Free Desulfinative Cross-Coupling of Heteroaryl Sulfinates with Grignard Reagents		Org. Lett.	52	Sheng, R	FALSE	FALSE	FALSE	FALSE
5475	10.1021/acs.joc.8b02760	doi.org/10.1021/acs.joc.8b02760	Transition Metal-Free Intermolecular C(sp(2))-H Direct Amination of Furanones via a Redox Pathway		J. Org. Chem.	52	Wang, X; Li, RT	FALSE	FALSE	FALSE	FALSE
5476	10.1007/s11426-018-9359-4	doi.org/10.1007/s11426-018-9359-4	Synthesis of 4H-chromenes by silver (I)-catalyzed cycloaddition of ortho-quinone methides with N-allenamides		Sci. China-Chem.	52	Jia, J; Xu, ZH	FALSE	FALSE	FALSE	FALSE
5477	10.1002/slct.201803376	doi.org/10.1002/slct.201803376	Tunable P-Stereogenic P,N-Phosphine Ligands Design: Synthesis and Coordination Chemistry to Palladium		ChemistrySelect	52	Herault, D; Buono, G	FALSE	FALSE	FALSE	FALSE
5478	10.1021/acs.orglett.8b02932	doi.org/10.1021/acs.orglett.8b02932	Metal-Free Catalytic Reductive Cleavage of Enol Ethers		Org. Lett.	52	Dobrovetsky, R	FALSE	FALSE	FALSE	FALSE
5479	10.1039/c8cc06768f	doi.org/10.1039/c8cc06768f	Palladium(0)-catalyzed C(sp(3))-Si bond formation via formal carbene insertion into a Si-H bond		Chem. Commun.	52	Wang, JB	FALSE	FALSE	FALSE	FALSE
5480	10.1021/acs.orglett.8b02481	doi.org/10.1021/acs.orglett.8b02481	Controllable Pd-Catalyzed Allylation of Indoles with Skipped Enynes: Divergent Synthesis of Indolenines and N-Allylindoles		Org. Lett.	52	Yao, HQ; Lin, AJ	FALSE	FALSE	FALSE	FALSE
5481	10.1002/chem.201803297	doi.org/10.1002/chem.201803297	Structural and Synthetic Insights into Pyridine Homocouplings Mediated by a -Diketiminato Magnesium Amide Complex		Chem.-Eur. J.	52	McLellan, R; Hevia, E	FALSE	FALSE	FALSE	FALSE
5482	10.1021/acs.joc.8b01498	doi.org/10.1021/acs.joc.8b01498	Synthesis of 3-Substituted 3-Bromo-1-phenylallenes from Alkynylcycloheptatrienes		J. Org. Chem.	52	Bour, C; Gandon, V	FALSE	FALSE	FALSE	FALSE
5483	10.1021/acs.joc.8b01428	doi.org/10.1021/acs.joc.8b01428	Transition-Metal-Free Arylation and Alkylation of Diarylmethyl p-Tolyl Sulfones with Zinc Reagents		J. Org. Chem.	52	Miao, MZ; Ren, HJ	FALSE	FALSE	FALSE	FALSE
5484	10.1021/acs.orglett.8b01807	doi.org/10.1021/acs.orglett.8b01807	Pd-Catalyzed Dearomative Allylation of Benzyl Phosphates		Org. Lett.	52	Muto, K; Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5485	10.1021/acs.orglett.8b01863	doi.org/10.1021/acs.orglett.8b01863	Nickel and Nucleophilic Cobalt-Catalyzed Trideuteriomethylation of Aryl Halides Using Trideuteriomethyl p-Toluenesulfonate		Org. Lett.	52	Komeyama, K	FALSE	FALSE	FALSE	FALSE
5486	10.1002/adsc.201800336	doi.org/10.1002/adsc.201800336	Rhodium(I)-Catalyzed Azide-Alkyne Cycloaddition (RhAAC) of Internal Alkynylphosphonates with High Regioselectivities under Mild Conditions		Adv. Synth. Catal.	52	Song, WZ	FALSE	FALSE	FALSE	FALSE
5487	10.1246/cl.180226	doi.org/10.1246/cl.180226	Decarbonylative Aryl Thioether Synthesis by Ni Catalysis		Chem. Lett.	52	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5488	10.1002/ajoc.201800083	doi.org/10.1002/ajoc.201800083	Iron-Catalyzed Synthesis of Amines and Thioethers Directly from Allylic Alcohols		Asian J. Org. Chem.	52	Zhang, PK	FALSE	FALSE	FALSE	FALSE
5489	10.1021/acs.orglett.8b00775	doi.org/10.1021/acs.orglett.8b00775	Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides		Org. Lett.	52	Itami, K	FALSE	FALSE	FALSE	FALSE
5490	10.1021/acs.joc.7b03210	doi.org/10.1021/acs.joc.7b03210	Directed ortho-Metalation and Anionic ortho-Fries Rearrangement of Polycyclic Aromatic O-Carbamates: Regioselective Synthesis of Substituted Chrysenes		J. Org. Chem.	52	Jorgensen, KB	FALSE	FALSE	FALSE	FALSE
5491	10.1002/slct.201702614	doi.org/10.1002/slct.201702614	I-2-Catalyzed Synthesis of Disulfides by NaBH4 Mediated Reductive Coupling of Phenylsulfonyl Imidazoles		ChemistrySelect	52	Chen, BH	FALSE	FALSE	FALSE	FALSE
5492	10.1021/jacs.7b09802	doi.org/10.1021/jacs.7b09802	Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis		J. Am. Chem. Soc.	52	Liu, GS	TRUE	FALSE	FALSE	FALSE
5493	10.1021/acscatal.7b00616	doi.org/10.1021/acscatal.7b00616	Deciphering the Mechanism of the Nickel-Catalyzed Hydroalkoxylation Reaction: A Combined Experimental and Computational Study		ACS Catal.	52	Capet, F; Sauthier, M	FALSE	FALSE	FALSE	FALSE
5494	10.1016/j.tet.2017.08.021	doi.org/10.1016/j.tet.2017.08.021	Highly regio- and stereoselective palladium-catalyzed allene bifunctionalization cascade via pi-allyl intermediate		Tetrahedron	52	Bai, T	FALSE	FALSE	FALSE	FALSE
5495	10.1039/c7py00987a	doi.org/10.1039/c7py00987a	Alkyl-substituted spiropyrans: electronic effects, model compounds and synthesis of aliphatic main-chain copolymers		Polym. Chem.	52	Sommer, M	FALSE	FALSE	FALSE	FALSE
5496	10.1039/c5ob02535d	doi.org/10.1039/c5ob02535d	Copper(I) chloride promoted Csp(2)-N cross-coupling of 1,2-di(pyrimidin-2-yl) disulfides with amines: an efficient approach to obtain C2-amino functionalized pyrimidines		Org. Biomol. Chem.	52	Quan, ZJ	FALSE	FALSE	FALSE	FALSE
5497	10.1021/acscatal.5b01782	doi.org/10.1021/acscatal.5b01782	Robust Iridium Coordination Polymers: Highly Selective, Efficient, and Recyclable Catalysts for Oxidative Conversion of Glycerol to Potassium Lactate with Dihydrogen Liberation		ACS Catal.	52	Tu, T	FALSE	FALSE	FALSE	FALSE
5498	10.1002/chem.201502338	doi.org/10.1002/chem.201502338	Mild and Soft Catalyzed Trifluoromethylthiolation of Boronic Acids: The Crucial Role of Water		Chem.-Eur. J.	52	Billard, T	FALSE	FALSE	FALSE	FALSE
5499	10.1016/j.tetlet.2015.06.087	doi.org/10.1016/j.tetlet.2015.06.087	An efficient iron-catalyzed S-arylation of aryl and alkylthiols with aryl halides in the presence of water under aerobic conditions		Tetrahedron Lett.	52	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
5500	10.1021/acs.joc.5b00991	doi.org/10.1021/acs.joc.5b00991	Optimization of Reaction and Substrate Activation in the Stereoselective Cross-Coupling of Chiral 3,3-Diboronyl Amides		J. Org. Chem.	52	Hall, DG	FALSE	FALSE	FALSE	FALSE
5501	10.1021/acs.orglett.5b00654	doi.org/10.1021/acs.orglett.5b00654	Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates		Org. Lett.	52	Sharpless, KB	FALSE	FALSE	FALSE	FALSE
5502	10.1055/s-0034-1380141	doi.org/10.1055/s-0034-1380141	A Novel Nickel-Catalyzed Domino Method for the Direct Synthesis of Symmetrical Disulfides Using Potassium 5-Methyl-1,3,4-oxadiazole-2-thiolate as a Sulfurating Reagent		Synlett	52	Soleiman-Beigi, M	FALSE	FALSE	FALSE	FALSE
5503	10.1021/acs.orglett.5b00241	doi.org/10.1021/acs.orglett.5b00241	Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates		Org. Lett.	52	Kalyani, D	FALSE	FALSE	FALSE	FALSE
5504	10.1002/marc.201400699	doi.org/10.1002/marc.201400699	An Efficient N-Heterocyclic Carbene-Ruthenium Complex: Application Towards the Synthesis of Polyesters and Polyamides		Macromol. Rapid Commun.	52	Keul, H	FALSE	FALSE	FALSE	FALSE
5505	10.3987/COM-14-S(K)18	doi.org/10.3987/COM-14-S(K)18	COPPER MEDIATED FORMATION OF CARBON-HETEROATOM BONDS USING ORGANOBORON REAGENTS AND ULTRASOUND		Heterocycles	52	Kabalka, GW	FALSE	FALSE	FALSE	FALSE
5506	10.1039/c5py00610d	doi.org/10.1039/c5py00610d	Kumada catalyst transfer polycondensation for controlled synthesis of polyfluorenes using 1,3-bis(diarylphosphino)propanes as ligands		Polym. Chem.	52	Geng, YH	FALSE	FALSE	FALSE	FALSE
5507	10.1039/c5ra03869c	doi.org/10.1039/c5ra03869c	A novel and efficient zinc-catalyzed thioetherification of aryl halides		RSC Adv.	52	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
5508	10.1039/c5ob01203a	doi.org/10.1039/c5ob01203a	N-heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed alpha-arylation reactions of tetralones with aryl chlorides and further transformation of the products		Org. Biomol. Chem.	52	Shao, LX	FALSE	FALSE	FALSE	FALSE
5509	10.1021/om500767p	doi.org/10.1021/om500767p	Synthesis of Low-Valent Nickel Complexes in Aqueous Media, Mechanistic Insights, and Selected Applications		Organometallics	52	Garcia, JJ	FALSE	FALSE	FALSE	FALSE
5510	10.1021/ol503043r	doi.org/10.1021/ol503043r	Iron- and Cobalt-Catalyzed Arylation of Azetidines, Pyrrolidines, and Piperidines with Grignard Reagents		Org. Lett.	52	Cossy, J	FALSE	FALSE	FALSE	FALSE
5511	10.1055/s-0034-1379483	doi.org/10.1055/s-0034-1379483	Cyanation of Unactivated Aryl Chlorides and Aryl Mesylates Catalyzed by Palladium and Hemilabile MOP-Type Ligands		Synlett	52	Xie, XM	FALSE	FALSE	FALSE	FALSE
5512	10.1002/adsc.201400560	doi.org/10.1002/adsc.201400560	Generation of Ethynyl-Grignard Reagent in a Falling Film Microreactor: An Expeditious Flow Synthesis of Propargylic Alcohols and Analogues		Adv. Synth. Catal.	52	Shen, RW	FALSE	FALSE	FALSE	FALSE
5513	10.1021/ja508815w	doi.org/10.1021/ja508815w	Stereospecific Pd-Catalyzed Cross-Coupling Reactions of Secondary Alkylboron Nucleophiles and Aryl Chlorides		J. Am. Chem. Soc.	52	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
5514	10.1002/jccs.201400027	doi.org/10.1002/jccs.201400027	Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides under Ligand-Free Conditions		J. Chin. Chem. Soc.	52	Lee, CF	FALSE	FALSE	FALSE	FALSE
5515	10.1055/s-0033-1339111	doi.org/10.1055/s-0033-1339111	Nickel-Catalyzed Reductive Allylation of Ketones with Allylic Carbonates		Synthesis	52	Deng, W	FALSE	FALSE	FALSE	FALSE
5516	10.1021/om500156q	doi.org/10.1021/om500156q	A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes		Organometallics	52	Jamison, TF	FALSE	FALSE	FALSE	FALSE
5517	10.1021/ja501815p	doi.org/10.1021/ja501815p	Catalytic Asymmetric Synthesis of Tertiary Alkyl Fluorides: Negishi Cross-Couplings of Racemic alpha,alpha-Dihaloketones		J. Am. Chem. Soc.	52	Fu, GC	FALSE	FALSE	FALSE	FALSE
5518	10.1002/anie.201308666	doi.org/10.1002/anie.201308666	Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents and Identification of Selective Anti-Breast-Cancer Agents		Angew. Chem.-Int. Edit.	52	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
5519	10.1021/jo401867e	doi.org/10.1021/jo401867e	Silver(I)-Catalyzed Reaction between Pyrazole and Propargyl Acetates: Stereoselective Synthesis of the Scorpionate Ligands (E)-Allyl-gem-dipyrazoles (ADPs)		J. Org. Chem.	52	Sahoo, AK	FALSE	FALSE	FALSE	FALSE
5520	10.1002/ajoc.201300172	doi.org/10.1002/ajoc.201300172	Palladium-Catalyzed C-H and C-N Arylation of Aminothiazoles with Arylboronic Acids		Asian J. Org. Chem.	52	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5521	10.1021/ol402644y	doi.org/10.1021/ol402644y	Tandem Isomerization and C-H Activation: Regioselective Hydroheteroarylation of Allylarenes		Org. Lett.	52	Ong, TG	FALSE	FALSE	FALSE	FALSE
5522	10.1166/sam.2013.1477	doi.org/10.1166/sam.2013.1477	Sol-Gel Catalysts as an Efficient Tool for the Kumada-Corriu Reaction in Continuous Flow		Sci. Adv. Mater.	52	Marra, L	FALSE	FALSE	FALSE	FALSE
5523	10.1021/ja312487r	doi.org/10.1021/ja312487r	Copper-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling		J. Am. Chem. Soc.	52	Feringa, BL	FALSE	FALSE	FALSE	FALSE
5524	10.1039/c3cs60228a	doi.org/10.1039/c3cs60228a	C-N bond forming cross-coupling reactions: an overview		Chem. Soc. Rev.	52	Van der Eycken, E	FALSE	FALSE	FALSE	FALSE
5525	10.1039/c3gc41469h	doi.org/10.1039/c3gc41469h	An efficient palladium catalyst on bentonite for Suzuki-Miyaura reaction at room temperature		Green Chem.	52	Ding, GD	FALSE	FALSE	FALSE	FALSE
5526	10.1021/ja308891e	doi.org/10.1021/ja308891e	Titanocene-Catalyzed Multicomponent Coupling Approach to Diarylethynyl Methanes		J. Am. Chem. Soc.	52	Ashfeld, BL	FALSE	FALSE	FALSE	FALSE
5527	10.1021/ol300401c	doi.org/10.1021/ol300401c	Regioselectivity Switch Achieved in the Palladium Catalyzed alpha-Arylation of Enones by Employing the Modified Kuwajima-Urabe Conditions		Org. Lett.	52	Kapur, M	FALSE	FALSE	FALSE	FALSE
5528	10.1002/anie.201202527	doi.org/10.1002/anie.201202527	Synthesis of Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions		Angew. Chem.-Int. Edit.	52	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
5529	10.1039/c2cc33232a	doi.org/10.1039/c2cc33232a	Mild ketone formation via Ni-catalyzed reductive coupling of unactivated alkyl halides with acid anhydrides		Chem. Commun.	52	Lin, KH	FALSE	FALSE	FALSE	FALSE
5530	10.1080/00397911.2011.585731	doi.org/10.1080/00397911.2011.585731	EFFICIENT ONE-STEP SYNTHESIS OF C-3-SYMMETRICAL BENZENOID COMPOUNDS MEDIATED BY SOCl2/EtOH		Synth. Commun.	52	Zhao, SH	FALSE	FALSE	FALSE	FALSE
5531	10.1021/ol202267t	doi.org/10.1021/ol202267t	NiCl2(PMe3)(2)-Catalyzed Borylation of Aryl Chlorides		Org. Lett.	52	Yamakawa, T	FALSE	FALSE	FALSE	FALSE
5532	10.1039/c1ce05516j	doi.org/10.1039/c1ce05516j	Zinc(II) and cadmium(II) coordination polymers mediated by rationally designed symmetrical/asymmetrical V-shaped heterocyclic aromatic ligands exhibiting different supramolecular architectures		Crystengcomm	52	Huang, W	FALSE	FALSE	FALSE	FALSE
5533	10.1039/c1sc00026h	doi.org/10.1039/c1sc00026h	Transition metal-catalyzed cross coupling with N-acyliminium ions derived from quinolines and isoquinolines		Chem. Sci.	52	Doyle, AG	FALSE	FALSE	FALSE	FALSE
5534	10.1021/jo1007898	doi.org/10.1021/jo1007898	Copper-Catalyzed Coupling Reaction of C-OMe Bonds Adjacent to a Nitrogen Atom with Terminal Alkynes		J. Org. Chem.	52	Zhang, YH	FALSE	FALSE	FALSE	FALSE
5535	10.1002/anie.201004426	doi.org/10.1002/anie.201004426	A General Strategy Toward Aromatic 1,2-Ambiphilic Synthons: Palladium-Catalyzed ortho-Halogenation of PyDipSi-Arenes		Angew. Chem.-Int. Edit.	52	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
5536	10.1055/s-0029-1218283	doi.org/10.1055/s-0029-1218283	Rhodium-Catalyzed Cross-Coupling of Arylboronic Acids Using Vinyl Acetate as the Electrophilic Partner		Synlett	52	Kwong, FY	FALSE	TRUE	FALSE	FALSE
5537	10.1021/ja905082c	doi.org/10.1021/ja905082c	Allylic Ethers as Educts for Suzuki-Miyaura Couplings in Water at Room Temperature		J. Am. Chem. Soc.	52	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
5538	10.1002/anie.200904033	doi.org/10.1002/anie.200904033	Palladium-Catalyzed Cross-Coupling of Aryl Halides Using Organotitanium Nucleophiles		Angew. Chem.-Int. Edit.	52	Kwong, FY	FALSE	FALSE	FALSE	FALSE
5539	10.1021/ma802100c	doi.org/10.1021/ma802100c	Aza-Wittig Polymerization: A Simple Method for the Synthesis of Regioregular Poly(azomethine)s		Macromolecules	52	Chujo, Y	FALSE	FALSE	FALSE	FALSE
5540	10.1016/j.jorganchem.2007.07.007	doi.org/10.1016/j.jorganchem.2007.07.007	Palladium-nanoparticles catalyzed hydrodehalogenation of aryl chlorides in ionic liquids		J. Organomet. Chem.	52	Nacci, A	FALSE	FALSE	FALSE	FALSE
5541	10.1021/jo062148s	doi.org/10.1021/jo062148s	Palladium-catalyzed aryl-aryl cross-coupling reaction using ortho-substituted arylindium reagents		J. Org. Chem.	52	Sestelo, JP	FALSE	FALSE	FALSE	FALSE
5542	10.1002/adsc.200606146	doi.org/10.1002/adsc.200606146	Combinatorial approach to heterogeneous asymmetric aquacatalysis with amphiphilic polymer-supported chiral phosphine-palladium complexes		Adv. Synth. Catal.	52	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
5543	10.1016/j.tet.2005.02.085	doi.org/10.1016/j.tet.2005.02.085	Organometallic alkylation of 2-chloro-4,6-dimethoxy-1,3,5-triazine: a study		Tetrahedron	52	Menicagli, R	FALSE	FALSE	FALSE	FALSE
5544	10.1016/S0040-4020(03)01234-1	doi.org/10.1016/S0040-4020(03)01234-1	Triethylborane as an efficient promoter for palladium-catalyzed allylation of active methylene compounds with allyl alcohols		Tetrahedron	52	Tamaru, Y	FALSE	FALSE	FALSE	FALSE
5545	10.1016/S0022-328X(02)01264-0	doi.org/10.1016/S0022-328X(02)01264-0	Cross-coupling reaction of organoboron compounds via base-assisted transmetalation to palladium(II) complexes		J. Organomet. Chem.	52	Miyaura, N	FALSE	FALSE	FALSE	FALSE
5546	10.1039/b203465d	doi.org/10.1039/b203465d	Palladium(II) complex-catalysed enantioselective benzoylation of alcohols using carbon monoxide and an organobismuth(V) compound		J. Chem. Soc.-Perkin Trans. 1	52	Uemura, S	FALSE	FALSE	FALSE	FALSE
5547	10.1021/jm00073a021	doi.org/10.1021/jm00073a021	SUBSTITUTED 3-PHENYLPIPERIDINES - NEW CENTRALLY ACTING DOPAMINE AUTORECEPTOR ANTAGONISTS		J. Med. Chem.	52	SONESSON, C	FALSE	FALSE	FALSE	FALSE
5548	10.1021/ja00033a033	doi.org/10.1021/ja00033a033	APPLICATIONS OF AN ASYMMETRIC [2 + 2]-PHOTOCYCLOADDITION - TOTAL SYNTHESIS OF (-)-ECHINOSPORIN - CONSTRUCTION OF AN ADVANCED 11-DEOXYPROSTAGLANDIN INTERMEDIATE		J. Am. Chem. Soc.	52	SMITH, AB	FALSE	FALSE	FALSE	FALSE
5549	10.1021/ja00225a037	doi.org/10.1021/ja00225a037	SEQUENTIAL ANNULATION APPROACH TO STERPURIC ACID AND STERPURENE-3,12,14-TRIOL, METABOLITES OF THE SILVER LEAF FUNGUS STEREUM-PURPUREUM		J. Am. Chem. Soc.	52	PAQUETTE, LA	FALSE	FALSE	FALSE	FALSE
5550	10.1021/jo00199a036	doi.org/10.1021/jo00199a036	STUDIES IN STEREOCHEMISTRY .47. ASYMMETRIC INDUCTION BY LEAVING GROUP IN NUCLEOPHILIC AROMATIC-SUBSTITUTION		J. Org. Chem.	52		FALSE	FALSE	FALSE	FALSE
5551	10.1021/acs.orglett.2c00207	doi.org/10.1021/acs.orglett.2c00207	Nickel-Catalyzed Reductive Csp(3)-Ge Coupling of Alkyl Bromides with Chlorogermanes		Org. Lett.	52	Shu, XZ	FALSE	FALSE	FALSE	FALSE
5552	10.1039/d2cc00717g	doi.org/10.1039/d2cc00717g	Visible light-assisted Ni-/Ir-catalysed atom-economic synthesis of spiro[furan-3,1 '-indene] derivatives		Chem. Commun.	52	Wang, JJ	FALSE	FALSE	FALSE	FALSE
5553	10.1021/acs.orglett.2c00267	doi.org/10.1021/acs.orglett.2c00267	Decarbonylative Pd-Catalyzed Suzuki Cross-Coupling for the Synthesis of Structurally Diverse Heterobiaryls		Org. Lett.	52	Szostak, M	FALSE	FALSE	FALSE	FALSE
5554	10.1039/d1cy02085d	doi.org/10.1039/d1cy02085d	Gold-catalyzed thioetherification of allyl, benzyl, and propargyl phosphates		Catal. Sci. Technol.	52	Miura, H; Shishido, T	FALSE	FALSE	FALSE	FALSE
5555	10.1002/hlca.202100184	doi.org/10.1002/hlca.202100184	Nickel-Catalyzed Ring Expansion of Cyclobutanones towards Indanones		Helv. Chim. Acta	52	Zhao, JB; Liu, Y	FALSE	FALSE	FALSE	FALSE
5556	10.1039/d1sc06968c	doi.org/10.1039/d1sc06968c	A C-to-O atom-swapping reaction sequence enabled by Ni-catalyzed decarbonylation of lactones		Chem. Sci.	52	Li, JQ	FALSE	FALSE	FALSE	FALSE
5557	10.1021/acs.orglett.1c03933	doi.org/10.1021/acs.orglett.1c03933	Ligand- and Substrate-Controlled Chemodivergent Pd-Catalyzed Annulations of Cyclic beta-Keto Esters with 3-Aryl-2H-azirines		Org. Lett.	52	Xie, F	FALSE	FALSE	FALSE	FALSE
5558	10.1038/s41467-021-26794-8	doi.org/10.1038/s41467-021-26794-8	Catalytic enantioselective reductive domino alkyl arylation of acrylates via nickel/photoredox catalysis		Nat. Commun.	52	Mao, JY	FALSE	FALSE	FALSE	FALSE
5559	10.1021/acscatal.1c03732	doi.org/10.1021/acscatal.1c03732	Dynamic Kinetic Resolution of Flavonoids via Asymmetric Allylic Alkylation: Construction of Two Contiguous Stereogenic Centers on Nucleophiles		ACS Catal.	52	Yu, CB; Zhou, YG	FALSE	FALSE	FALSE	FALSE
5560	10.1039/d1sc04261k	doi.org/10.1039/d1sc04261k	Ligand-redox assisted nickel catalysis toward stereoselective synthesis of (n+1)-membered cycloalkanes from 1,n-diols with methyl ketones		Chem. Sci.	52	Adhikari, D	FALSE	FALSE	FALSE	FALSE
5561	10.1021/acs.orglett.1c02143	doi.org/10.1021/acs.orglett.1c02143	Nickel-Catalyzed Isomerization/Allylic Cyanation of Alkenyl Alcohols		Org. Lett.	52	Fang, XJ	FALSE	FALSE	FALSE	FALSE
5562	10.1039/d1cc02762j	doi.org/10.1039/d1cc02762j	Pd-catalyzed sp-sp(3) cross-coupling of benzyl bromides using lithium acetylides		Chem. Commun.	52	Buter, J; Feringa, BL	FALSE	FALSE	FALSE	FALSE
5563	10.1021/acs.orglett.1c01280	doi.org/10.1021/acs.orglett.1c01280	Nickel-Catalyzed Ipso-Borylation of Silyloxyarenes via C-O Bond Activation		Org. Lett.	52	Montgomery, J	FALSE	FALSE	FALSE	FALSE
5564	10.1021/acs.orglett.1c01369	doi.org/10.1021/acs.orglett.1c01369	Palladium-Catalyzed Allenamide Carbopalladation/Allylation with Active Methine Compounds		Org. Lett.	52	Yao, HQ; Lin, AJ	FALSE	FALSE	FALSE	FALSE
5565	10.1039/d1sc00900a	doi.org/10.1039/d1sc00900a	Construction of congested Csp(3)-Csp(3) bonds by a formal Ni-catalyzed alkylboration		Chem. Sci.	52	Brown, MK	FALSE	FALSE	FALSE	FALSE
5566	10.1055/a-1467-2432	doi.org/10.1055/a-1467-2432	Synthesis of Dibenzyls by Nickel-Catalyzed Homocoupling of Benzyl Alcohols		Synthesis	52	Shu, XZ	FALSE	FALSE	FALSE	FALSE
5567	10.1021/jacs.7b07488	doi.org/10.1021/jacs.7b07488	Insights into the Mechanism of Anodic N-N Bond Formation by Dehydrogenative Coupling		J. Am. Chem. Soc.	52	Waldvogel, SR	FALSE	FALSE	FALSE	FALSE
5568	10.1016/j.polymer.2017.03.036	doi.org/10.1016/j.polymer.2017.03.036	Poly(phenylene-carborane) for boron-carbide/carbon ceramic precursor synthesized via nickel catalysis		Polymer	52	Wang, JY	FALSE	FALSE	FALSE	FALSE
5569	10.1021/acs.orglett.6b03861	doi.org/10.1021/acs.orglett.6b03861	Aromatic Metamorphosis of Dibenzofurans into Triphenylenes Starting with Nickel-Catalyzed Ring-Opening C-O Arylation		Org. Lett.	52	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
5570	10.1002/anie.201611495	doi.org/10.1002/anie.201611495	Hydrodehalogenation of Haloarenes by a Sodium Hydride-Iodide Composite		Angew. Chem.-Int. Edit.	52	Hirao, H; Chiba, S	FALSE	FALSE	FALSE	FALSE
5571	10.1002/anie.201610409	doi.org/10.1002/anie.201610409	C-O Activation by a Rhodium Bis(N-Heterocyclic Carbene) Catalyst: Aryl Carbamates as Arylating Reagents in Directed C-H Arylation		Angew. Chem.-Int. Edit.	52	Chatani, N	FALSE	FALSE	FALSE	FALSE
5572	10.1002/ejoc.201601098	doi.org/10.1002/ejoc.201601098	(E)-Selective Wittig Reactions between a Nonstabilized Phosphonium Ylide Bearing a Phosphastibatriptycene Skeleton and Benzaldehydes		Eur. J. Org. Chem.	52	Uchiyama, Y	FALSE	FALSE	FALSE	FALSE
5573	10.1071/CH17176	doi.org/10.1071/CH17176	High Catalytic Activity of Peptide Nanofibres Decorated with Ni and Cu Nanoparticles for the Synthesis of 5-Substituted 1H-Tetrazoles and N-Arylation of Amines		Aust. J. Chem.	52	Ghorbani-Choghamarani, A	FALSE	FALSE	FALSE	FALSE
5574	10.1007/s10562-016-1880-9	doi.org/10.1007/s10562-016-1880-9	Silica-Supported Ni(II)-DABCO Complex: An Efficient and Reusable Catalyst for the Heck Reaction		Catal. Lett.	52	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
5575	10.1007/s11172-016-1619-1	doi.org/10.1007/s11172-016-1619-1	Pyridinyl trifluoromethanesulfonates: preparation methods and use in organic synthesis		Russ. Chem. Bull.	52	Krasnokutskaya, EA	FALSE	FALSE	FALSE	FALSE
5576	10.1246/cl.160712	doi.org/10.1246/cl.160712	Nickel-catalyzed Ring-opening Cross-coupling of Cyclic Alkenyl Ethers with Arylboronic Esters via Carbon-Oxygen Bond Cleavage		Chem. Lett.	52	Tobisu, M	FALSE	FALSE	FALSE	FALSE
5577	10.1002/anie.201604429	doi.org/10.1002/anie.201604429	Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides		Angew. Chem.-Int. Edit.	52	Oderinde, MS; Johannes, JW	TRUE	FALSE	FALSE	FALSE
5578	10.1021/acs.orglett.6b02459	doi.org/10.1021/acs.orglett.6b02459	Tandem O-H Insertion/[1,3]-Alkyl Shift of Rhodium Azavinyl Carbenoids with Benzylic Alcohols: A Route To Convert C-OH Bonds into C-C Bonds		Org. Lett.	52	Bi, XH	FALSE	FALSE	FALSE	FALSE
5579	10.1055/s-0035-1562614	doi.org/10.1055/s-0035-1562614	A Catalyst-Free One-Pot Protocol for the Construction of Substituted Isoindolinones under Sustainable Conditions		Synlett	52	Sashidhara, KV	FALSE	FALSE	FALSE	FALSE
5580	10.1246/bcsj.20160100	doi.org/10.1246/bcsj.20160100	Mesolysis Processes with Benzylic Carbon-Oxygen. Bond Cleavage in Radical Anions of Aryl Benzyl Ethers Studied by Electron Pulse Radiolysis in DMF		Bull. Chem. Soc. Jpn.	52	Yamaji, M	FALSE	TRUE	FALSE	FALSE
5581	10.1002/bkcs.10819	doi.org/10.1002/bkcs.10819	Zinc Enolate/Sulfinate Prepared from a Single-Run Reaction Using Zinc Dust with O-Tosylated 4-Hydroxy Coumarin and Pyrone		Bull. Korean Chem. Soc.	52	Kim, SH	FALSE	FALSE	FALSE	FALSE
5582	10.1002/anie.201601899	doi.org/10.1002/anie.201601899	Iron-Catalyzed Stereoselective Cross-Coupling Reactions of Stereodefined Enol Carbamates with Grignard Reagents		Angew. Chem.-Int. Edit.	52	Frantz, DE	FALSE	FALSE	FALSE	FALSE
5583	10.1002/chem.201504753	doi.org/10.1002/chem.201504753	Alkoxyallene-ynes: Selective Preparation of Bicyclo[5.3.0] Ring Systems Including a -Alkoxy Cyclopentadienone		Chem.-Eur. J.	52	Lannou, MI; Sorin, G	FALSE	FALSE	FALSE	FALSE
5584	10.1002/anie.201511438	doi.org/10.1002/anie.201511438	Direct Acylation of C(sp(3))-H Bonds Enabled by Nickel and Photoredox Catalysis		Angew. Chem.-Int. Edit.	52	Doyle, AG	TRUE	FALSE	FALSE	FALSE
5585	10.1002/anie.201508757	doi.org/10.1002/anie.201508757	Asymmetric Allylic Alkylation of -Ketoesters with Allylic Alcohols by a Nickel/Diphosphine Catalyst		Angew. Chem.-Int. Edit.	52	Mashima, K	FALSE	FALSE	FALSE	FALSE
5586	10.1039/c5dt04663g	doi.org/10.1039/c5dt04663g	Half-sandwich nickel complexes with ring-expanded NHC ligands - synthesis, structure and catalytic activity in Kumada-Tamao-Corriu coupling		Dalton Trans.	52	Buchowicz, W	FALSE	FALSE	FALSE	FALSE
5587	10.1039/c5cc09817c	doi.org/10.1039/c5cc09817c	Copper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to gamma-hydroxyl boronic esters		Chem. Commun.	52	Xiao, B; Fu, Y	FALSE	FALSE	FALSE	FALSE
5588	10.1039/d0dt03941a	doi.org/10.1039/d0dt03941a	Mechanistic study of the cooperative palladium/Lewis acid-catalyzed transfer hydrocyanation reaction: the origin of the regioselectivity	Facet 111 oriented Au nanoplatelets (20-40 nm wide, 3-4 nm height) grafted on graphene ((Au) over bar /fl-G) are about three orders of magnitude more efficient than Pd nanoparticles supported on graphene to promote Suzuki-Miyaura coupling. In contrast to Pd catalysis, it is shown here that the product yields in Suzuki-Miyaura coupling catalyzed by Au nanoparticles follow the order chlorobenzene > bromobenzene > iodobenzene. Kinetic studies show that this reactivity order is the result of the poisoning effect of halides for Au that is much higher for I- than Br- and much higher than for Cl-, due to adsorption. This strong iodide adsorption leading to Au catalyst deactivation was predicted by DFT calculations of Au clusters. (Au) over bar /fl-G are about one order of magnitude more efficient than small Au nanoparticles (4-6 nm) obtained by the polyol method supported on graphene. Our results can have impact in organic synthesis, showing the advantage of (Au) over bar /fl-G as catalyst for Suzuki-Miyaura couplings. (C) 2017 Elsevier Inc. All rights reserved.	Dalton Trans.	51	Zhao, LL	FALSE	FALSE	FALSE	FALSE
5589	10.1021/acs.joc.0c02407	doi.org/10.1021/acs.joc.0c02407	N-Alkylation of Amines with Alcohols Catalyzed by Manganese(II) Chloride or Bromopentacarbonylmanganese(I)	A practical approach has been developed for efficient synthesis of unsymmetrical aryl s-triazines via highly selective sequential Suzuki coupling of cyanuric chloride (2,4,6-trichlorotriazine) with aryl or vinyl boronic or diarylborinic acids catalysed by 0.1-0.5 mol% Pd(PPh3)(2)Cl-2 under mild conditions. The second and third Suzuki couplings for unsymmetrically trisubstituted aryl s-triazines could be more practically conducted in one-pot procedure. An electron-withdrawing conjugate group at phenyl ring of arylboronic acids was unexpectedly found to completely block the coupling while steric hindrance from an ortho electron-donating substituent could be overcome.	J. Org. Chem.	51	Peng, ZH	FALSE	FALSE	FALSE	FALSE
5590	10.1002/bkcs.12211	doi.org/10.1002/bkcs.12211	Dual Rh(II)/Pd(0) Relay Catalysis for One-Pot Synthesis of alpha-Quaternary Allylated Indolin-2-ones and Benzofuran-2-ones	A novel iron catalyzed hydroarylation, methylarylation, and diarylation of styrenes to form unsymmetrical 1,1-diarylalkanes with electron rich anisole and 1,3,5-trimethoxybenzene under mild conditions have been developed. Benzoyl peroxide is used as an oxidant for hydroarylation, whereas in the case of methylarylation and diarylation the oxidant tert-butyl peracetate is used.	Bull. Korean Chem. Soc.	51	Xuan, Z	FALSE	FALSE	FALSE	FALSE
5591	10.1002/anie.202014340	doi.org/10.1002/anie.202014340	Nickel-Catalyzed N-Arylation of Fluoroalkylamines	Diphenylphosphine-oxide-fused Ni-II porphyrin 8 was synthesized from 3,5,7-trichloroporphyrin 5 via a reaction sequence of nucleophilic aromatic substitution with lithium diphenylphosphide, oxidation with H2O2, and palladium-catalyzed intramolecular cyclization. Reduction of 8 with HSiCl3 gave diphenylphosphine-fused Ni-II porphyrin 9. The embedded P=O and P moieties serve as a strong electron-accepting and electron-donating group to perturb the optical and electrochemical properties of the Ni-II porphyrin. Ni-II porphyrin 9 is diamagnetic with a low-spin Ni-II center in solution but becomes paramagnetic with a five-coordinated Ni-II center with high-spin (S=1) state in the solid state. Diphenylphosphine-oxide-fused Zn-II porphyrin 10 was also synthesized and shown to form a face-to-face dimer with mutual O-Zn bonds in the crystal and in nonpolar and moderately polar solvents. The dimerization of 10 in CDCl3 has been revealed to be an entropy-driven process with a large entropy gain (S-D=207JK(-1)mol(-1)).	Angew. Chem.-Int. Edit.	51	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
5592	10.1021/acs.orglett.0c02765	doi.org/10.1021/acs.orglett.0c02765	Gold(I)-Catalyzed Reactions between 2-(1-Alkynyl)-2-alken-1-ones and Vinyldiazo Ketones for Divergent Synthesis of Nonsymmetric Heteroaryl-Substituted Triarylmethanes: N- versus C-Attack Paths	In this study, a one-pot two-step reductive coupling between acetyl naphthalene derivatives, tosylhy-drazide, and arylboronic acids, affording substituted 1(or 2)-(1-phenylethyl)naphthalenes in moderate-to-excellent yields, was reported. Notably, solvent played a crucial role in the coupling of 1-acetyl naphthalene derivatives (toluene) or 2-acetyl naphthalene derivatives (1,4-dioxane) as starting materials. Meanwhile, the scope of this one-pot coupling reaction was extended to 1(or 2)-naphthaldehyde substrates. Particularly, the system was also suitable to synthesize 1(or 2)-(1-phenylethyl)naphthalenes on a multi-gram scale, and was applied in the synthesis of naphthylmethyl substituted carbazolyl compounds. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Lett.	51	Liu, RS	FALSE	FALSE	FALSE	FALSE
5593	10.1016/j.molstruc.2020.128572	doi.org/10.1016/j.molstruc.2020.128572	A new mononuclear nickel complex with 5,5 '-dimethyl-2,2 '-bipyridine: Synthesis, structural investigation and catalytic properties		J. Mol. Struct.	51	Maalej, W	FALSE	FALSE	FALSE	FALSE
5594	10.1021/acs.joc.0c01861	doi.org/10.1021/acs.joc.0c01861	Divergent Synthesis of Isonitriles and Nitriles by Palladium-Catalyzed Benzylic Substitution with TMSCN	Palladium substituted CeO2, SnO2 and their mixed oxides have been synthesized in quantitative yields out of non-toxic and inexpensive precursors using a simple and rapid single step solution combustion method. The resulting oxides, especially the mixed oxides Ce0.79Sn0.20Pd0.01O2-delta, Sn0.79Ce0.20Pd0.01O2-delta and Sn0.99Pd0.01O2-delta proved to be highly active (TOF >12,000 h(-1)) for Suzuki-Miyaura cross-couplings of phenylboronic acid with various bromoarenes. The reactions were carried out in ambient air at moderate temperatures using environmentally friendly aqueous ethanol solutions as reaction solvents. Minimal amounts of palladium in the product solution (<0.14 mg/L), the reaction kinetics as well as catalyst poisoning tests support the thesis that the reaction proceeds via dissolved palladium species in a homogeneous reaction mechanism. Nevertheless, the synthesized catalysts could be reused for at least five times with only minor changes in activity and no changes in the crystal structure, indicating the high potential of the investigated catalysts as quasi-heterogeneous C-C coupling catalysts. (C) 2016 Elsevier B.V. All rights reserved.	J. Org. Chem.	51	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
5595	10.1055/s-0040-1707127	doi.org/10.1055/s-0040-1707127	Evolution of a Cycloaddition-Rearrangement Approach to the Squalestatins: A Quarter-Century Odyssey	A new synthetic approach has been developed for efficient access to triarylmethanes by palladium catalyzed decarboxylative cross coupling reactions. The reaction features sp(2)-sp(3) coupling where benzoic acids upon decarboxylation reacted with diaryl methyl iodides having both electron donating and withdrawing functionalities, leading to the synthesis of diverse triarylmethanes.	Synlett	51	Hodgson, DM	FALSE	FALSE	FALSE	FALSE
5596	10.1021/acs.orglett.0c02091	doi.org/10.1021/acs.orglett.0c02091	Nickel-Catalyzed Reductive Aryl Thiocarbonylation of Alkene via Thioester Group Transfer Strategy	An efficient catalyst free, three-component, cascade approach has been designed and developed for the rapid assembly of unsymmetrical triarylmethane framework. The strategy employed aromatic aldehydes, Grignard reagents, and neutral aromatics as reaction partners, under simple thermal conditions. This process affords very broad scope for all three partners as it is performed in the absence of any external additives. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Lett.	51	Sun, FG	FALSE	FALSE	FALSE	FALSE
5597	10.1021/acs.joc.0c01768	doi.org/10.1021/acs.joc.0c01768	Computational Analysis of Enantioselective Pd-Catalyzed alpha-Arylation of Ketones	With the goal of achieving highly efficient palladium catalyzed cross-coupling reactions under mild reaction conditions, the Pd-PEPPSI complexes Cl and C2 bearing 1,2-di(tert-butyl)acenaphthyl (DtBu-An) backbones were synthesized and characterized, and their use in Suzuki Miyaura cross-coupling was investigated. The effects of catalyst structure and reaction conditions on the cross-coupling efficiency were evaluated in detail. The significant differences in catalytic activity compared with classical PEPPSI-IPr and PEPPSI-IPrAn precatalysts are discussed, where the axial sterics on the backbone play an important role. At low palladium loadings of 0.05-0.1 mol % and upon the addition of the relatively weak base K3PO4, the palladium complex Cl was found to be highly efficient for the coupling of (hetero)aryl chlorides with arylboronic acids under aerobic conditions, affording the corresponding biaryls in excellent yields.	J. Org. Chem.	51	Orlandi, M	FALSE	FALSE	FALSE	FALSE
5598	10.1021/acs.orglett.0c02165	doi.org/10.1021/acs.orglett.0c02165	Dual Nickel-/Palladium-Catalyzed Reductive Cross-Coupling Reactions between Two Phenol Derivatives	We found that N-acyl phthalimides and several N-acylated azoles are capable of reacting with aldehydes to form O-acyl-N,O-acetals in an apparent amide C-N bond insertion. In the context of N-acyl phthalimides, the reaction is mediated by substoichiometric amounts of sodium iodide and potassium phthalimide. DFT computations supported a proposed mechanism and provided insights into the effect of the alkali metal additive. This strategy could be used to prepare a myriad of N,O-acetals from a range of aldehydes. A one-pot procedure was also developed in which N-acyl phthalimide was generated in situ prior to forming the N,O-acetal product. The one -pot strategy was used to demonstrate that activated amides derived from imidazole, pyrazole, (benzo)triazole, and tetrazole are also amenable substrates. Collectively, these studies provide an approach to the synthesis of a variety of N,O-acetals under mild conditions from inexpensive starting materials. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Lett.	51	Lian, Z	FALSE	FALSE	FALSE	FALSE
5599	10.1021/acs.joc.0c00269	doi.org/10.1021/acs.joc.0c00269	Zn-Catalyzed Cyanation of Aryl Iodides	Cp*Co-III-catalyzed C-H allylation of various aromatic C-H bonds using allyl alcohols as allylating reagents is described. Improved reaction conditions using fluorinated alcohol solvents afforded efficient directed C-H allylation of 6-arylpurines, benzamides, and a synthetically useful Weinreb amide with good functional group compatibility.	J. Org. Chem.	51	Li, YH	FALSE	FALSE	FALSE	FALSE
5600	10.1021/acs.orglett.0c00936	doi.org/10.1021/acs.orglett.0c00936	Catalytic Asymmetric Allylic Amination with Isatins, Sulfonamides, Imides, Amines, and N-Heterocycles	Open-shell phenalenyl chemistry has widely been explored in the last five decades demonstrating its potential in various applications including molecular switch, spin memory device, molecular battery, cathode material, etc. In this article, we have explored another new direction of open-shell phenalenyl chemistry toward transition metal-free catalytic C-H functionalization process. A phenalenyl ligand, namely, 9-methylamino-phenalen-1-one (4a), promoted chelation-assisted single electron transfer (SET) process, which facilitates the C-H functionalization of unactivated arenes to form the biaryl products. The present methodology offers a diverse substrate scope, which can be operated without employing any dry or inert conditions and under truly transition metal based catalyst like loading yet avoiding any expensive or toxic transition metal. This not only is the first report on the application of phenalenyl chemistry in C-H functionalization process but also provides a low-catalyst loading organocatalytic system (up to 0.5 mol % catalyst loading) as compared to the existing ones (mostly 20-40 mol %), which has taken advantage of long known phenalenyl based radical stability through the presence of its low-lying nonbonding molecular orbital.	Org. Lett.	51	Wolf, C	FALSE	FALSE	FALSE	FALSE
5601	10.1016/j.tetlet.2019.151491	doi.org/10.1016/j.tetlet.2019.151491	Highly efficient palladium-catalyzed cross-coupling of diarylborinic acids with arenediazoniums for practical diaryl synthesis		Tetrahedron Lett.	51	Zou, G	FALSE	FALSE	FALSE	FALSE
5602	10.1016/j.molstruc.2019.07.054	doi.org/10.1016/j.molstruc.2019.07.054	N-donor 2-(Sulfonamido)benzamide ligands, their palladium(II) coordination species and C-C coupling catalysis efficiencies		J. Mol. Struct.	51	Plass, W; Eseola, AO	FALSE	FALSE	FALSE	FALSE
5603	10.1039/c9cc06638a	doi.org/10.1039/c9cc06638a	Direct amide synthesis via Ni-mediated aminocarbonylation of arylboronic acids with CO and nitroarenes		Chem. Commun.	51	Cheung, CW; Ma, JA	FALSE	FALSE	FALSE	FALSE
5604	10.1038/s41467-019-13098-1	doi.org/10.1038/s41467-019-13098-1	Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles		Nat. Commun.	51	Zhang, J; Zhong, GF	FALSE	FALSE	FALSE	FALSE
5605	10.1021/acs.orglett.9b03274	doi.org/10.1021/acs.orglett.9b03274	Making Carbonyls of Amides Nucleophilic and Hydroxyls of Alcohols Electrophilic Mediated by SO2F2 for Synthesis of Esters from Amides		Org. Lett.	51	Qin, HL	FALSE	TRUE	FALSE	FALSE
5606	10.1021/acs.orglett.9b02613	doi.org/10.1021/acs.orglett.9b02613	Construction of Spirocyclic Tetrahydro-beta-carbolines via Cross-Annulation of Phenols with Tryptamines in Water		Org. Lett.	51	Zeng, HY	FALSE	FALSE	FALSE	FALSE
5607	10.1002/cssc.201801877	doi.org/10.1002/cssc.201801877	Alcohol Amination Catalyzed by Copper Powder as a Self-Supported Catalyst		ChemSusChem	51	Shi, F	FALSE	FALSE	FALSE	FALSE
5608	10.1021/acs.orglett.9b01669	doi.org/10.1021/acs.orglett.9b01669	Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction of Naphthyl and Quinolyl Alcohols with Boronic Acids		Org. Lett.	51	Samec, JSM	FALSE	FALSE	FALSE	FALSE
5609	10.1016/j.tetlet.2019.04.004	doi.org/10.1016/j.tetlet.2019.04.004	Nickel-catalyzed N-arylation of amines with arylboronic acids under open air		Tetrahedron Lett.	51	Ando, S; Ishizuka, T	FALSE	FALSE	FALSE	FALSE
5610	10.1002/aoc.4831	doi.org/10.1002/aoc.4831	Synthesis of heterobiaryls via Suzuki-Miyaura coupling reaction of potassium aryltrifluoroborates with heteroaryl halides in aqueous systems		Appl. Organomet. Chem.	51	Liu, LF; Dong, Y	FALSE	FALSE	FALSE	FALSE
5611	10.1021/jacs.8b13524	doi.org/10.1021/jacs.8b13524	Nickel-catalyzed Enantioselective Hydroarylation and Hydroalkenylation of Styrenes		J. Am. Chem. Soc.	51	Mei, TS	FALSE	FALSE	FALSE	FALSE
5612	10.1021/acscatal.8b04677	doi.org/10.1021/acscatal.8b04677	Cp*Rh-III-Catalyzed Allyl Aryl Coupling of Olefins and Arylboron Reagents Enabled by C(sp(3))-H Activation		ACS Catal.	51	Glorius, F	FALSE	FALSE	FALSE	FALSE
5613	10.1038/s41929-018-0215-1	doi.org/10.1038/s41929-018-0215-1	Challenges and outlook for catalytic direct amidation reactions		Nat. Catal.	51	Wang, X	FALSE	FALSE	FALSE	FALSE
5614	10.1038/s41467-018-08063-3	doi.org/10.1038/s41467-018-08063-3	Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters		Nat. Commun.	51	Abellan, G	FALSE	FALSE	FALSE	FALSE
5615	10.1021/acs.orglett.8b03417	doi.org/10.1021/acs.orglett.8b03417	Practical Ni-Catalyzed Cross-Coupling of Unsaturated Zinc Pivalates with Unsaturated Nonaflates and Triflates		Org. Lett.	51	Knochel, P	FALSE	FALSE	FALSE	FALSE
5616	10.1016/j.jcou.2018.12.007	doi.org/10.1016/j.jcou.2018.12.007	Nickel-catalyzed carboxylation of aryl zinc reagent with CO2: A theoretical and experimental study		J. CO2 Util.	51	Jia, R; Zhang, HX	FALSE	FALSE	FALSE	FALSE
5617	10.1186/s13065-018-0510-6	doi.org/10.1186/s13065-018-0510-6	Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis		Chem. Cent. J.	51	Ji, H	FALSE	FALSE	FALSE	FALSE
5618	10.1021/acs.orglett.8b03539	doi.org/10.1021/acs.orglett.8b03539	Nickel-Catalyzed Cyanation of Unactivated Alkyl Chlorides or Bromides with Zn(CN)(2)		Org. Lett.	51	Liu, YH	FALSE	FALSE	FALSE	FALSE
5619	10.1002/ejoc.201800533	doi.org/10.1002/ejoc.201800533	Synthesis of C9,C10-Diheteroarylated Phenanthrenes via Palladium-Catalyzed C-H Bond Activation		Eur. J. Org. Chem.	51	Soule, JF; Doucet, H	FALSE	FALSE	FALSE	FALSE
5620	10.1055/s-0037-1610256	doi.org/10.1055/s-0037-1610256	Asymmetric Construction of Halogenated Cyclic Quaternary Carbon Center through Enolate Activation of Aldehydes		Synlett	51	Li, JL	FALSE	FALSE	FALSE	FALSE
5621	10.1002/adsc.201800879	doi.org/10.1002/adsc.201800879	Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Alkyl Bromides: Efficient Synthesis of Alkyl Aryl Ketones		Adv. Synth. Catal.	51	Wu, XF	FALSE	FALSE	FALSE	FALSE
5622	10.1038/s41467-018-06019-1	doi.org/10.1038/s41467-018-06019-1	A general deoxygenation approach for synthesis of ketones from aromatic carboxylic acids and alkenes		Nat. Commun.	51	Xie, J; Zhu, CJ	FALSE	FALSE	FALSE	FALSE
5623	10.1021/acscatal.8b01380	doi.org/10.1021/acscatal.8b01380	Kumada Arylation of Secondary Amides Enabled by Chromium Catalysis for Unsymmetric Ketone Synthesis under Mild Conditions		ACS Catal.	51	Zeng, XM	FALSE	FALSE	FALSE	FALSE
5624	10.1002/ajoc.201800207	doi.org/10.1002/ajoc.201800207	Dibenzofuran Synthesis: Decarbonylative Intramolecular C-H Arylation of Aromatic Esters		Asian J. Org. Chem.	51	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5625	10.1021/jacs.8b03744	doi.org/10.1021/jacs.8b03744	C-N Cross-Coupling via Photoexcitation of Nickel-Amine Complexes		J. Am. Chem. Soc.	51	Miyake, GM	TRUE	FALSE	FALSE	FALSE
5626	10.1038/s41467-018-04480-6	doi.org/10.1038/s41467-018-04480-6	Total synthesis of cyrneines A-B and glaucopine C		Nat. Commun.	51	Han, FS	FALSE	FALSE	FALSE	FALSE
5627	10.1002/adsc.201800187	doi.org/10.1002/adsc.201800187	Direct Allylation of Active Methylene Compounds with Allylic Alcohols by Use of Palladium/Phosphine-Borane Catalyst System		Adv. Synth. Catal.	51	Onodera, G; Kimura, M	FALSE	FALSE	FALSE	FALSE
5628	10.1002/aoc.4138	doi.org/10.1002/aoc.4138	Suzuki-Miyaura coupling catalyzed by palladium nanoparticles biosynthesized using Glycyrrhiza glabra as reducing and stabilyzing agent		Appl. Organomet. Chem.	51	Veisi, H	FALSE	FALSE	FALSE	FALSE
5629	10.1021/acs.orglett.8b00060	doi.org/10.1021/acs.orglett.8b00060	Palladium-Catalyzed Amination of Aryl Sulfoxides		Org. Lett.	51	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
5630	10.1080/00397911.2017.1420801	doi.org/10.1080/00397911.2017.1420801	Stereoselective synthesis of functionalized vinyl ethers from allyl bromides activated by triethylamine		Synth. Commun.	51	Arfaoui, A	FALSE	FALSE	FALSE	FALSE
5631	10.1039/c7cc08416a	doi.org/10.1039/c7cc08416a	Versatile (eta(6)-arene) Ni(PCy3) nickel monophosphine precursors		Chem. Commun.	51	Johnson, SA	FALSE	FALSE	FALSE	FALSE
5632	10.1002/chem.201702331	doi.org/10.1002/chem.201702331	Halide Abstraction Competes with Oxidative Addition in the Reactions of Aryl Halides with [Ni(PMenPh(3-n))(4)]		Chem.-Eur. J.	51	Maseras, F	FALSE	FALSE	FALSE	FALSE
5633	10.1021/acs.chemmater.7b02964	doi.org/10.1021/acs.chemmater.7b02964	Sulfone-Based Deep Blue Thermally Activated Delayed Fluorescence Emitters: Solution-Processed Organic Light-Emitting Diodes with High Efficiency and Brightness		Chem. Mat.	51	Hernandez-Sosa, G	FALSE	FALSE	FALSE	FALSE
5634	10.1021/acs.organomet.7b00692	doi.org/10.1021/acs.organomet.7b00692	Invisible Chelating Effect Exhibited between Carbodicarbene and Phosphine through pi-pi Interaction and Implication in the Cross-Coupling Reaction		Organometallics	51	Zhao, LL	FALSE	FALSE	FALSE	FALSE
5635	10.1002/anie.201706423	doi.org/10.1002/anie.201706423	Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation		Angew. Chem.-Int. Edit.	51	Schoenebeck, F	FALSE	FALSE	FALSE	FALSE
5636	10.1002/ajoc.201700324	doi.org/10.1002/ajoc.201700324	C(sp(2))-O Bond Formation through a Nickel-Catalyzed Cross-Coupling Reaction in Water Enabled by Micellar Catalysis		Asian J. Org. Chem.	51	Laitonjam, WS	FALSE	FALSE	FALSE	FALSE
5637	10.1248/yakushi.15-00201	doi.org/10.1248/yakushi.15-00201	Stereoselective Synthesis of Multi-substituted Fluoro-beta-lactams and Their Conversion to Fluorinated beta-Amino Acid Core		Yakugaku Zasshi-J. Pharm. Soc. Jpn.	51	Tarui, A	FALSE	FALSE	FALSE	FALSE
5638	10.1021/acs.organomet.5b00733	doi.org/10.1021/acs.organomet.5b00733	Macrocyclic Aryl Nickel(II) Complexes: Synthesis, Structure, and Reactivity Studies		Organometallics	51	Zhao, L	FALSE	FALSE	FALSE	FALSE
5639	10.1021/acs.orglett.5b02344	doi.org/10.1021/acs.orglett.5b02344	Design of an Indolylphosphine Ligand for Reductive Elimination-Demanding Monoarylation of Acetone Using Aryl Chlorides		Org. Lett.	51	So, CM	FALSE	FALSE	FALSE	FALSE
5640	10.1016/j.tetlet.2015.07.033	doi.org/10.1016/j.tetlet.2015.07.033	Aryl/heteroaryl pentafluorobenzenesulfonates (ArOPFBs): new electrophilic coupling partners for room temperature Suzuki-Miyaura cross-coupling reactions		Tetrahedron Lett.	51	Shashikanth, S	FALSE	FALSE	FALSE	FALSE
5641	10.1021/acs.accounts.5b00064	doi.org/10.1021/acs.accounts.5b00064	Nickel Catalysis: Synergy between Method Development and Total Synthesis		Accounts Chem. Res.	51	Jamison, TF	FALSE	FALSE	FALSE	FALSE
5642	10.1039/c5ra04279h	doi.org/10.1039/c5ra04279h	Base-promoted direct and highly selective alkynylation of electron-deficient octafluorotoluene		RSC Adv.	51	Zhao, HT	FALSE	FALSE	FALSE	FALSE
5643	10.1039/c5ra18890c	doi.org/10.1039/c5ra18890c	First direct access to 2-hydroxybenzophenones via nickel-catalyzed cross-coupling of 2-hydroxybenzaldehydes with aryl iodides		RSC Adv.	51	Nowrouzi, N	FALSE	FALSE	FALSE	FALSE
5644	10.1039/c5ra03522h	doi.org/10.1039/c5ra03522h	Aryl tosylates as non-ionic photoacid generators (PAGs): photochemistry and applications in cationic photopolymerizations		RSC Adv.	51	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
5645	10.1021/ja506885s	doi.org/10.1021/ja506885s	Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones		J. Am. Chem. Soc.	51	Fu, GC	FALSE	TRUE	FALSE	FALSE
5646	10.1021/ja5043534	doi.org/10.1021/ja5043534	Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents		J. Am. Chem. Soc.	51	Kambe, N	FALSE	FALSE	FALSE	FALSE
5647	10.1021/ja4127455	doi.org/10.1021/ja4127455	Mechanistic Study of Chemoselectivity in Ni-Catalyzed Coupling Reactions between Azoles and Aryl Carboxylates		J. Am. Chem. Soc.	51	Fu, Y	FALSE	FALSE	FALSE	FALSE
5648	10.1016/j.tet.2013.11.104	doi.org/10.1016/j.tet.2013.11.104	Pd-catalyzed Fukuyama cross-coupling of secondary organozinc reagents for the direct synthesis of unsymmetrical ketones		Tetrahedron	51	Reisman, SE	FALSE	FALSE	FALSE	FALSE
5649	10.1021/ol403083e	doi.org/10.1021/ol403083e	AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes		Org. Lett.	51	Hu, JB	FALSE	FALSE	FALSE	FALSE
5650	10.1039/c4ob01027b	doi.org/10.1039/c4ob01027b	Synthesis and characterization of bisoxazolines-and pybox-copper(II) complexes and their application in the coupling of alpha-carbonyls with functionalized amines		Org. Biomol. Chem.	51	Jia, WG	FALSE	FALSE	FALSE	FALSE
5651	10.1039/c3gc42182a	doi.org/10.1039/c3gc42182a	A highly efficient and recyclable ligand-free protocol for the Suzuki coupling reaction of potassium aryltrifluoroborates in water		Green Chem.	51	Liu, LF	FALSE	FALSE	FALSE	FALSE
5652	10.1080/00268976.2014.886738	doi.org/10.1080/00268976.2014.886738	Theoretical investigation on the mechanism of FeCl3-catalysed cross-coupling reaction of alcohols with alkenes		Mol. Phys.	51	Sun, K	FALSE	FALSE	FALSE	FALSE
5653	10.1021/ja409803x	doi.org/10.1021/ja409803x	Isolation, Structure, and Reactivity of an Arylnickel(II) Pivalate Complex in Catalytic C-H/C-O Biaryl Coupling		J. Am. Chem. Soc.	51	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5654	10.1021/ol400690t	doi.org/10.1021/ol400690t	Palladium-Catalyzed Diarylmethyl C(sp(3))-C(sp(2)) Bond Formation: A New Coupling Approach toward Triarylmethanes		Org. Lett.	51	Zhang, Y	FALSE	FALSE	FALSE	FALSE
5655	10.1039/c3ra41690a	doi.org/10.1039/c3ra41690a	Highly efficient and practical synthesis of functionalized 1,5-dienes via Pd(II)-catalyzed halohomoallylation of alkynes		RSC Adv.	51	Li, JX	FALSE	FALSE	FALSE	FALSE
5656	10.1002/ejic.201200988	doi.org/10.1002/ejic.201200988	C,N-Palladacycles Containing N-Heterocyclic Carbene and Azido Ligands - Effective Catalysts for Suzuki-Miyaura Cross-Coupling Reactions		Eur. J. Inorg. Chem.	51	Kim, YJ	FALSE	FALSE	FALSE	FALSE
5657	10.1039/c2gc16111g	doi.org/10.1039/c2gc16111g	Palladium nanoparticle catalysis: borylation of aryl and benzyl halides and one-pot biaryl synthesis via sequential borylation-Suzuki-Miyaura coupling		Green Chem.	51	Bej, A	FALSE	FALSE	FALSE	FALSE
5658	10.1039/c2ob07107j	doi.org/10.1039/c2ob07107j	Aminohydroxyacetone synthons: versatile intermediates for the organocatalytic asymmetric aldol reaction		Org. Biomol. Chem.	51	Kotsuki, H	FALSE	FALSE	FALSE	FALSE
5659	10.1039/c2cc34551j	doi.org/10.1039/c2cc34551j	Regioselective palladium-catalyzed direct cross-coupling of coumarins with simple arenes		Chem. Commun.	51	Hong, S	FALSE	FALSE	FALSE	FALSE
5660	10.1246/cl.2011.1254	doi.org/10.1246/cl.2011.1254	FeCl3-mediated Direct Chalcogenation of Phenols		Chem. Lett.	51	Komeyama, K	FALSE	FALSE	FALSE	FALSE
5661	10.1021/jo201516v	doi.org/10.1021/jo201516v	Palladium-Catalyzed Direct Arylation of Heteroaromatic Compounds: Improved Conditions Utilizing Controlled Microwave Heating		J. Org. Chem.	51	Kappe, CO	FALSE	FALSE	FALSE	FALSE
5662	10.1002/ejoc.201100350	doi.org/10.1002/ejoc.201100350	Chemoselective Rh-Catalyzed Allylic Alkylations of Chelated Enolates using Dienylcarbonates		Eur. J. Org. Chem.	51	Kazmaier, U	FALSE	FALSE	FALSE	FALSE
5663	10.1021/ja201321v	doi.org/10.1021/ja201321v	Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for Highly Enantioselective Syntheses of Pseudopterosins		J. Am. Chem. Soc.	51	RajanBabu, TV	FALSE	FALSE	FALSE	FALSE
5664	10.1021/ol200267b	doi.org/10.1021/ol200267b	Palladium- and Nickel-Catalyzed Aminations of Aryl Imidazolylsulfonates and Sulfamates		Org. Lett.	51	Ackermann, L	FALSE	FALSE	FALSE	FALSE
5665	10.1021/jo102417x	doi.org/10.1021/jo102417x	Cobalt-Xantphos-Catalyzed, LiCl-Mediated Preparation of Arylzinc Reagents from Aryl Iodides, Bromides, and Chlorides		J. Org. Chem.	51	Yoshikai, N	FALSE	FALSE	FALSE	FALSE
5666	10.1002/anie.201006751	doi.org/10.1002/anie.201006751	Palladium-Catalyzed Carbocyclization of Alkynyl Ketones Proceeding through a Carbopalladation Pathway		Angew. Chem.-Int. Edit.	51	Gorelsky, SI	FALSE	FALSE	FALSE	FALSE
5667	10.1002/anie.201100683	doi.org/10.1002/anie.201100683	Nickel-Catalyzed Cross-Coupling of Aryltrimethylammonium Iodides with Organozinc Reagents		Angew. Chem.-Int. Edit.	51	Wang, ZX	FALSE	FALSE	FALSE	FALSE
5668	10.1021/ol1008334	doi.org/10.1021/ol1008334	Intramolecular alpha-Glucosaminidation: Synthesis of Mycothiol		Org. Lett.	51	Knapp, S	FALSE	FALSE	FALSE	FALSE
5669	10.1002/adsc.200900480	doi.org/10.1002/adsc.200900480	Synthesis of 2,3-Diarylbenzo[b]thiophenes via Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling and Palladium-Catalyzed Decarboxylative Arylation		Adv. Synth. Catal.	51	Miura, M	FALSE	FALSE	FALSE	FALSE
5670	10.1246/bcsj.82.870	doi.org/10.1246/bcsj.82.870	Substituent Effect of Imino-O-arenesulfonates, a Coupling Partner in Suzuki-Miyaura Reaction for Substitution of the Pyrazine Ring: A Study for the Synthesis of Coelenterazine Analogs		Bull. Chem. Soc. Jpn.	51	Isobe, M	FALSE	FALSE	FALSE	FALSE
5671	10.1021/om800850c	doi.org/10.1021/om800850c	Synthesis, Characterization, and Electrochemistry of Compounds Containing 1-Diphenylphosphino-1 '-(di-tert-butylphosphino)ferrocene (dppdtbpf)		Organometallics	51	Nataro, C	FALSE	TRUE	FALSE	FALSE
5672	10.1002/ejoc.200700772	doi.org/10.1002/ejoc.200700772	Palladium-catalyzed 1,2-addition of organic halides and terminal alkynes to 7-oxabenzonorbornadiene: An efficient route to polyaromatic hydrocarbons		Eur. J. Org. Chem.	51	Liu, CH	FALSE	FALSE	FALSE	FALSE
5673	10.1021/ar600021z	doi.org/10.1021/ar600021z	New catalytic reactions of Oxa- and azabicyclic Alkenes		Accounts Chem. Res.	51	Cheng, CH	FALSE	FALSE	FALSE	FALSE
5674	10.1021/jo049385k	doi.org/10.1021/jo049385k	Palladium-catalyzed transformation of cyclobutanone O-benzoyloximes to nitriles via C-C bond cleavage		J. Org. Chem.	51	Nishimura, T	FALSE	FALSE	FALSE	FALSE
5675	10.1021/jo0345087	doi.org/10.1021/jo0345087	Oxidative kinetic resolution of racemic alcohols catalyzed by chiral ferrocenyloxazolinylphosphine-ruthenium complexes		J. Org. Chem.	51	Uemura, S	FALSE	FALSE	FALSE	FALSE
5676	10.1021/ol020159b	doi.org/10.1021/ol020159b	Phenyliodonium zwitterion as an efficient electrophile in the palladium-catalyzed Suzuki-type reaction: A novel method for the synthesis of 3-aryl-4-hydroxycoumarins		Org. Lett.	51	Zhu, Q	FALSE	FALSE	FALSE	FALSE
5677	10.1021/jo020281o	doi.org/10.1021/jo020281o	(P(C6H5)(3))CpRu+-catalyzed deprotection of allyl carboxylic esters		J. Org. Chem.	51	Kitamura, M	FALSE	FALSE	FALSE	FALSE
5678	10.1021/jo010668b	doi.org/10.1021/jo010668b	Palladium(0)-catalyzed enantioselective O,S-rearrangement of racemic O-allylic thiocarbamates: A new entry to enantioenriched allylic sulfur compounds		J. Org. Chem.	51	Gais, HJ	FALSE	FALSE	FALSE	FALSE
5679	10.1016/S0040-4039(00)01448-9	doi.org/10.1016/S0040-4039(00)01448-9	Rhodium-catalyzed substitution of allylic carbonates with enoxysilanes		Tetrahedron Lett.	51	Matsuda, I	FALSE	FALSE	FALSE	FALSE
5680	10.1021/ja983441f	doi.org/10.1021/ja983441f	Building with cubane-1,4-diyl. Synthesis of aryl-substituted cubanes, p-[n]cubyls, and cubane-separated bis(arenes)		J. Am. Chem. Soc.	51	Eaton, PE	FALSE	FALSE	FALSE	FALSE
5681	10.1021/ja00336a033	doi.org/10.1021/ja00336a033	PALLADIUM-CATALYZED CARBONYLATIVE COUPLING OF VINYL TRIFLATES WITH ORGANOSTANNANES - A TOTAL SYNTHESIS OF (+/-)DELTA-9(12)-CAPNELLENE		J. Am. Chem. Soc.	51		FALSE	FALSE	FALSE	FALSE
5682	10.1039/d1ra07252h	doi.org/10.1039/d1ra07252h	Cu(ii)-vitamin C-complex catalyzed photo-induced homocoupling reaction of aryl boronic acid in base-free and visible light conditions		RSC Adv.	51	Jafarpour, M; Rezaeifard, A	FALSE	FALSE	FALSE	FALSE
5683	10.1021/acscatal.1c05386	doi.org/10.1021/acscatal.1c05386	Identification of a Nitrenoid Reductive Elimination Pathway in Nickel-Catalyzed C-N Cross-Coupling		ACS Catal.	51	Johnson, ER; Stradiotto, M	FALSE	FALSE	FALSE	FALSE
5684	10.1039/d1qo01756j	doi.org/10.1039/d1qo01756j	Palladium-catalyzed decarbonylative methylation of aryl carboxylic acids		Org. Chem. Front.	51	Feng, BY; Chen, Y	FALSE	FALSE	FALSE	FALSE
5685	10.1016/j.jcat.2021.12.007	doi.org/10.1016/j.jcat.2021.12.007	Microenvironment modulation of cuprous cluster enables inert aryl chlorides activation in single-molecule metallaphotoredox amination		J. Catal.	51	Jing, S	FALSE	FALSE	FALSE	FALSE
5686	10.1039/d1nj04081b	doi.org/10.1039/d1nj04081b	Cinchona alkaloid derivative modified Fe3O4 nanoparticles for enantioselective ring opening of meso-cyclic anhydrides		New J. Chem.	51	Soni, HP	FALSE	FALSE	FALSE	FALSE
5687	10.1021/acscatal.1c05208	doi.org/10.1021/acscatal.1c05208	In-Situ Bromination Enables Formal Cross-Electrophile Coupling of Alcohols with Aryl and Alkenyl Halides		ACS Catal.	51	Weix, DJ	FALSE	TRUE	FALSE	FALSE
5688	10.1021/acs.joc.1c02098	doi.org/10.1021/acs.joc.1c02098	Tf2O-Mediated Cyclization of 7-Enamides: Bioinspired Construction of Fused Eight-Membered Carbocyclic Enimines and Enones		J. Org. Chem.	51	Huang, PQ	FALSE	FALSE	FALSE	FALSE
5689	10.3390/molecules26237346	doi.org/10.3390/molecules26237346	Preparation of Metal-Immobilized Methacrylate-Based Monolithic Columns for Flow-Through Cross-Coupling Reactions		Molecules	51	Sabarudin, A	FALSE	FALSE	FALSE	FALSE
5690	10.1021/jacs.1c10150	doi.org/10.1021/jacs.1c10150	Dual Nickel/Photoredox-Catalyzed Deaminative Cross-Coupling of Sterically Hindered Primary Amines		J. Am. Chem. Soc.	51	Rovis, T	TRUE	FALSE	FALSE	FALSE
5691	10.1021/acs.organomet.1c00505	doi.org/10.1021/acs.organomet.1c00505	Direct C-H Arylation and Alkylation of Electron-Deficient Heteroaromatic Compounds with Organozinc Reagents		Organometallics	51	Peng, ZH	FALSE	TRUE	FALSE	FALSE
5692	10.1055/a-1675-0018	doi.org/10.1055/a-1675-0018	Cyanide-Free Cyanation of Aryl Iodides with Nitromethane by Using an Amphiphilic Polymer-Supported Palladium Catalyst		Synlett	51	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
5693	10.1039/d1qo01078f	doi.org/10.1039/d1qo01078f	Hydroxyl group-directed, tartaric acid-catalyzed synthesis of meta-functionalized aryl ethers and phenols through domino conjugate addition/aromatization of para-quinols		Org. Chem. Front.	51	Chen, SJ; Liu, YL	FALSE	FALSE	FALSE	FALSE
5694	10.1002/slct.202102062	doi.org/10.1002/slct.202102062	Nano Ni/g-C3N4 Photocatalyzed Aerobic Oxidative Coupling Reaction toward Alkyl Aryl Ketones Derivatives under Visible Light Irradiation		ChemistrySelect	51	Hosseini-Sarvari, M	TRUE	FALSE	FALSE	FALSE
5695	10.6023/cjoc202104030	doi.org/10.6023/cjoc202104030	Palladium-Catalyzed Intramolecular Decarboxylative Allylic Amination of Aroyloxycarbamates		Chin. J. Org. Chem.	51	Dai, QP	FALSE	FALSE	FALSE	FALSE
5696	10.1038/s41467-021-25268-1	doi.org/10.1038/s41467-021-25268-1	Redox-enabled direct stereoconvergent heteroarylation of simple alcohols		Nat. Commun.	51	Yang, GQ; Zhao, Y	FALSE	FALSE	FALSE	FALSE
5697	10.1039/d1nj02677a	doi.org/10.1039/d1nj02677a	Nickel-catalyzed cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides with spiro-bidentate-pyox ligands		New J. Chem.	51	Teng, DW	FALSE	FALSE	FALSE	FALSE
5698	10.1039/d1ra04651a	doi.org/10.1039/d1ra04651a	6-Halo-2-pyridone as an efficient organocatalyst for ester aminolysis		RSC Adv.	51	Yamada, T; Okamoto, S	FALSE	FALSE	FALSE	FALSE
5699	10.1021/acs.joc.1c00945	doi.org/10.1021/acs.joc.1c00945	Copper-Catalyzed Regioselective Sila-Acylation and Silaformylation of 1,3-Dienes Using Esters		J. Org. Chem.	51	Fujihara, T	FALSE	FALSE	FALSE	FALSE
5700	10.1055/a-1503-7339	doi.org/10.1055/a-1503-7339	Cu(I)-Bis(phosphine) Dioxides as Catalysts for the Enantioselective alpha-Arylation of Carbonyl Compounds		Synlett	51	Orlandi, M	FALSE	FALSE	FALSE	FALSE
5701	10.1039/d1ob00187f	doi.org/10.1039/d1ob00187f	Conversion of esters to thioesters under mild conditions		Org. Biomol. Chem.	51	Liu, XJ	FALSE	FALSE	FALSE	FALSE
5702	10.1016/j.tetlet.2017.07.087	doi.org/10.1016/j.tetlet.2017.07.087	Carbon-carbon bond forming reactions via Pd-catalyzed detellurative homocoupling of diorganyl tellurides		Tetrahedron Lett.	51	Jin, J	FALSE	FALSE	FALSE	FALSE
5703	10.1021/acs.orglett.7b02063	doi.org/10.1021/acs.orglett.7b02063	Stereospecific, Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Allylic Pivalates To Deliver Quaternary Stereocenters		Org. Lett.	51	Watson, MP	FALSE	FALSE	FALSE	FALSE
5704	10.1021/acs.organomet.7b00314	doi.org/10.1021/acs.organomet.7b00314	Catalytic Regioselective C-H Acetoxylation of Arenes Using 4,6-Dimethoxy-1,3,5-triazin-2-yloxy as a Removable/Modifiable Directing Group		Organometallics	51	Peng, ZH	FALSE	FALSE	FALSE	FALSE
5705	10.1002/slct.201700923	doi.org/10.1002/slct.201700923	Catalyst-Free and One-Pot Procedure for Fast Formation of alpha-Ketoamides Using alpha-Oxocarboxylic Acids and Amines at Room Temperature		ChemistrySelect	51	Sun, ZL; Wang, B	FALSE	FALSE	FALSE	FALSE
5706	10.1002/chem.201700909	doi.org/10.1002/chem.201700909	Diphenylphosphine-Oxide-Fused and Diphenylphosphine-Fused Porphyrins: Synthesis, Tunable Electronic Properties, and Formation of Cofacial Dimers		Chem.-Eur. J.	51	Osuka, A	FALSE	TRUE	FALSE	FALSE
5707	10.1039/c6sc03699f	doi.org/10.1039/c6sc03699f	Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis		Chem. Sci.	51	Ribas, X	FALSE	FALSE	FALSE	FALSE
5708	10.1039/c6ra27325d	doi.org/10.1039/c6ra27325d	Titanium tetrachloride-mediated synthesis of N-aryl-substituted azacycles from cyclic ethers		RSC Adv.	51	Wang, ZH	FALSE	FALSE	FALSE	FALSE
5709	10.1016/j.poly.2016.04.006	doi.org/10.1016/j.poly.2016.04.006	Synthesis of and catalytic nitrile hydration by a cationic tris(mu-hydroxo)diruthenium(II) complex having PMe3 ligands		Polyhedron	51	Hirano, M	FALSE	FALSE	FALSE	FALSE
5710	10.1021/jacs.6b07567	doi.org/10.1021/jacs.6b07567	Nickel-Catalyzed Cross-Electrophile Coupling of Alkyl Fluorides: Stereospecific Synthesis of Vinylcyclopropanes		J. Am. Chem. Soc.	51	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
5711	10.1016/j.tetlet.2016.07.103	doi.org/10.1016/j.tetlet.2016.07.103	Highly efficient access to 4-chloro-2H-chromenes and 1,2-dihydroquinolines under mild conditions: TMSCl-mediated cyclization of 2-propynolphenols/anilines		Tetrahedron Lett.	51	Xiao, Q	FALSE	FALSE	FALSE	FALSE
5712	10.1038/srep33131	doi.org/10.1038/srep33131	Palladium-catalyzed direct arylation and cyclization of o-iodobiaryls to a library of tetraphenylenes		Sci Rep	51	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
5713	10.1002/anie.201603399	doi.org/10.1002/anie.201603399	Sterically Demanding Oxidative Amidation of alpha-Substituted Malononitriles with Amines Using O-2		Angew. Chem.-Int. Edit.	51	Hayashi, Y	FALSE	FALSE	FALSE	FALSE
5714	10.1021/jacs.6b04566	doi.org/10.1021/jacs.6b04566	Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis		J. Am. Chem. Soc.	51	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
5715	10.1002/anie.201603627	doi.org/10.1002/anie.201603627	C-C Coupling of Benzyl Fluorides Catalyzed by an Electrophilic Phosphonium Cation		Angew. Chem.-Int. Edit.	51	Stephan, DW	FALSE	TRUE	FALSE	FALSE
5716	10.1021/acs.orglett.6b01398	doi.org/10.1021/acs.orglett.6b01398	Air-Stable Triazine-Based Ni(II) PNP Pincer Complexes As Catalysts for the Suzuki-Miyaura Cross-Coupling		Org. Lett.	51	Kirchner, K	FALSE	FALSE	FALSE	FALSE
5717	10.1021/acs.joc.6b00289	doi.org/10.1021/acs.joc.6b00289	Nickel-Catalyzed Phosphorylation of Phenol Derivatives via C-O/P-H Cross-Coupling		J. Org. Chem.	51	Chen, TQ	FALSE	FALSE	FALSE	FALSE
5718	10.1016/j.tet.2016.03.042	doi.org/10.1016/j.tet.2016.03.042	Facile and highly selective silylation of vinylpyridines at the beta-olefinic carbon by magnesium-promoted reduction		Tetrahedron	51	Maekawa, H	FALSE	FALSE	FALSE	FALSE
5719	10.1039/d0cc07743g	doi.org/10.1039/d0cc07743g	Ni-catalyzed reductive decyanation of nitriles with ethanol as the reductant	A series of rare [NiX2((CCprop)-C-Me)] complexes bearing the cis-chelating benzimidazole-derived dicarbene ligand (CCprop)-C-Me and varying anionic coligands (2, X = N-3; 3, X = NCS; 4, X = I; 5, X = O2CCF3) have been prepared and coligand dependent structural and spectroscopic features have been evaluated. This study also revealed an unusual 'reverse' carbene transfer reaction from nickel to silver giving the disilver species [Ag2X2(mu-kappa(2)-(CCprop)-C-Me)] (6, X = OAc; 7, X = O2CCF3). A preliminary catalytic study of two representative NiII diNHC complexes in the aqueous and phosphine-free Suzuki-Miyaura coupling reaction of aryl halides is reported as well. These reactions provide good yields of coupling products, but do not require inert conditions.	Chem. Commun.	50	Jin, LQ; Hu, XQ	FALSE	FALSE	FALSE	FALSE
5720	10.1021/jacs.0c13236	doi.org/10.1021/jacs.0c13236	Enantioselective alpha-Arylation of Ketones via a Novel Cu(I)-Bis(phosphine) Dioxide Catalytic System	Mediated by a catalytic amount of FeCl3, the C-H alkylation of S, S-functionalized internal ole-fins, i.e., alpha-oxo ketene dithioacetals and their analogues, was efficiently achieved using simple ethers and toluene derivatives as the coupling partners, ditert-butyl peroxide (DTBP) as the oxidant, and DABCO center dot 6H(2)O as the additive. The alkylthio functionality is essential for the internal olefinic C-H bond to undergo such an alkylation with the O-adjacent C(sp(3))-H bonds of the ethers and the benzylic C-H bonds of the toluene derivatives, respectively. Tetrasubstituted olefins were thus synthesized and further transformed to highly substituted pyrazoles and isoxazoles. The strategy to activate an internal olefinic C-H bond by polarizing its parent olefinic C=C bond with both the dialkylthio group and an electron-withdrawing functionality was investigated. The mechanistic studies suggest a radical pathway for the C(sp(2))-H/C(sp(3))-H cross-coupling reactions. The present protocol provides a convenient route to tetrasubstituted olefins.	J. Am. Chem. Soc.	50	Orlandi, M	FALSE	FALSE	FALSE	FALSE
5721	10.3390/molecules26041165	doi.org/10.3390/molecules26041165	New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2 '-Bis(aminomethyl)-1,1 '-binaphthyl	The first cobalt-catalyzed amide activation of N-Boc-amides, and their conversion into esters, is reported here. This new methodology presents a very practical process that does not require an inert atmosphere, uses an inexpensive cobalt catalyst, and proceeds under mild reaction conditions. This catalytic system has a broad substrate scope and has been shown to be highly efficient, with catalyst loadings as low as 1 mol%.	Molecules	50	Kayaki, Y	FALSE	FALSE	FALSE	FALSE
5722	10.17344/acsi.2021.6920	doi.org/10.17344/acsi.2021.6920	Dehydrogenation of 1-Phenylethanol Catalyzed by Nickel(II)diphosphine Complexes	This article focuses on the development of practical approaches to the in situ generation of anhydrous fluoride salts for applications in nucleophilic aromatic substitution (SNAr) reactions. We report herein that a variety of combinations of inexpensive nucleophiles (e.g., tetraalkylammonium cyanide and phenoxide salts) and fluorine-containing electrophiles (e.g., acid fluoride, fluoroformate, benzenesulfonyl fluoride, and aryl fluorosulfonate derivatives) are effective for this transformation. Ultimately, we demonstrate that the combination of tetramethylammonium 2,6-dimethylphenoxide and sulfuryl fluoride (SO2F2) serves as a particularly practical route to anhydrous tetramethylammonium fluoride. This procedure is applied to the SNAr fluorination of a range of electron-deficient aryl and heteroaryl chlorides as well as nitroarenes.	Acta Chim. Slov.	50	Kulkarni, NV	FALSE	FALSE	FALSE	FALSE
5723	10.1002/aoc.6012	doi.org/10.1002/aoc.6012	Biogenic synthesis of palladium nanoparticles using Boswellia sarrata and their applications in cross-coupling reactions	A palladium catalyzed Suzuki cross-coupling for construction of Csp(3)-Csp(2) bond via Csp(3)-N bond activation of benzyltrimethyl-ammonium salt is described. This reaction not only offered a highly efficient approach to diarylmethanes but also paved the way for the application of benzyltrimethylammonium salts in the palladium catalyzed cross coupling reactions.	Appl. Organomet. Chem.	50	Salunkhe, RS	FALSE	FALSE	FALSE	FALSE
5724	10.1055/s-0040-1707300	doi.org/10.1055/s-0040-1707300	Iron-Promoted Decarboxylation of Arylacetic Acids for the Synthesis of Aromatic Nitriles with Sodium Nitrite as the Nitrogen Source	Cp*Co(III)-catalyzed direct allylation of enamides has been accomplished with the exclusive formation of allylated Z-enamides with high efficiency. In addition, the employment of maleimides as the reaction partner under the same catalytic conditions provides a series of succinimide-substituted Z-enamides.	Synlett	50	Tian, XZ; Ren, YL	FALSE	FALSE	FALSE	FALSE
5725	10.1021/acscatal.0c02514	doi.org/10.1021/acscatal.0c02514	Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0)	A copper-based metal-organic framework Cu-CPO-27 was synthesized, and used as a recyclable catalyst for the amidation of unactivated alkanes by benzamides via direct oxidative C(sp(3))-H/N-H coupling under ligand-free conditions. Using a catalytic amount of the Cu-CPO-27 for the transformation, high yields of N-cyclohexyl benzamides were achieved. The Cu-CPO-27 was more catalytically active than other Cu-MOFs such as Cu-3(BTC)(2), Cu(BDC), Cu(EDB), Cu-2(BPDC)(2)(BPY), Cu-2(BDC)(2)(DABCO), and Cu-2(EDB)(2)(BPY). The Cu-CPO-27 also exhibited advantages as compared to several copper-based salts, including Cu(OAc)(2), CuCl2, CuBr, Cul, CuCI, Cu(NO3)(2), and CuSO4. The Cu-CPO-27 catalyst could be reused several times for the amidation transformation while its catalytic activity was not decreased significantly. To the best of our knowledge, the amidation of unactivated alkanes by benzamides via direct oxidative C(sp(3))-H/N-H coupling was not previously performed under heterogeneous catalysis conditions. (C) 2016 Elsevier Ltd. All rights reserved.	ACS Catal.	50	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
5726	10.1002/cssc.202000978	doi.org/10.1002/cssc.202000978	Highly Efficient Cleavage of Ether Bonds in Lignin Models by Transfer Hydrogenolysis over Dual-Functional Ruthenium/Montmorillonite	Coumarin sulfonates 4-43 were synthesized by reacting 3-hydroxy coumarin 1, 4-hydroxy coumarin 2 and 6-hydroxy coumarin 3 with different substituted sulfonyl chlorides and subjected to evaluate for their in vitro immunomodulatory potential. The compounds were investigated for their effect on oxidative burst activity of zymosan stimulated whole blood phagocytes using a luminol enhanced chemiluminescence technique. Ibuprofen was used as standard drug (IC50 = 54.2 +/- 9.2 mu M). Eleven compounds 6 (IC50 = 46.60 +/- 14.6 mu M), 8 (IC50 = 11.50 +/- 6.5 mu M), 15 (IC50 = 21.40 +/- 12.2 mu M), 19 (IC50 = 5.75 +/- 0.86 mu M), 22 (IC50 = 10.27 +/- 1.06 mu M), 23 (IC50 = 33.09 +/- 5.61 mu M), 24 (IC50 = 4.93 +/- 0.58 mu M), 25 (IC50 = 21.96 +/- 14.74 mu M), 29 (IC50 = 12.47 +/- 9.2 mu M), 35 (IC50 = 20.20 +/- 13.4 mu M) and 37 (IC50 = 14.47 +/- 5.02 mu M) out of forty demonstrated their potential suppressive effect on production of reactive oxygen species (ROS) as compared to ibuprofen. All the synthetic derivatives 4-43 were characterized by different available spectroscopic techniques such as H-1 NMR, C-13 NMR, EIMS and HRMS. CHN analysis was also performed. (C) 2016 Elsevier Inc. All rights reserved.	ChemSusChem	50	Xue, ZM	FALSE	FALSE	FALSE	FALSE
5727	10.1021/acs.joc.0c01099	doi.org/10.1021/acs.joc.0c01099	Iridium-Catalyzed Alkylation of Secondary Alcohols with Primary Alcohols: A Route to Access Branched Ketones and Alcohols	Generation of useful arylnitrile structures from simple aromatic feedstock chemicals represents a fundamentally important reaction in chemical synthesis. The first nickel-catalyzed cyanation of phenol derivatives with metal-free cyanating agents, aminoacetonitriles, is described. A nickel-based catalytic system consisting of a unique diphosphine ligand such as dcype or dcypt enables the cyanation of versatile phenol derivatives such as aryl carbamates and aryl pivalates. The use of aminoacetonitriles as a cyanating agent leads to an environmentally and easy-to-use method for arylnitrile synthesis.	J. Org. Chem.	50	Gulcemal, S; Gulcemal, D	FALSE	FALSE	FALSE	FALSE
5728	10.1039/d0sc01641a	doi.org/10.1039/d0sc01641a	A methylation platform of unconventional inert aryl electrophiles: trimethylboroxine as a universal methylating reagent	An efficient and easy method for C-sp3-C-sp3 homocoupling was developed using cobalt bromide as catalyst. A series of functionalized alkyl bromides and alkyl chlorides were coupled in high yields under mild conditions. This reaction seems to involve a radical intermediate.	Chem. Sci.	50	Yang, YD; You, JS	FALSE	FALSE	FALSE	FALSE
5729	10.1039/d0cy00471e	doi.org/10.1039/d0cy00471e	Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes	This review highlights a number of additives that can be used to make asymmetric reactions perfect. Without changing other reaction conditions, simply adding additives can lead to improved asymmetric catalysis, such as reduced reaction time, improved yield, or/and increased selectivity.	Catal. Sci. Technol.	50	Satishkumar, G	FALSE	FALSE	FALSE	FALSE
5730	10.1021/acs.orglett.0c00945	doi.org/10.1021/acs.orglett.0c00945	Highly Stereoselective Synthesis of 1,2-Disubstituted Indanes by Pd-Catalyzed Heck/Suzuki Sequence of Diarylmethyl Carbonates	The rhodium(III)-catalyzed mild and site selective C-H allylation of enol carbamates with 4-vinyl-1,3-dioxolan-2-one and allylic carbonates affords allylic alcohols and terminal allylated products, respectively. The assistance of the carbamoyl directing group provides a straightforward preparation of biologically and synthetically important allylated enol carbamates.	Org. Lett.	50	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
5731	10.1016/j.tetlet.2020.151721	doi.org/10.1016/j.tetlet.2020.151721	A photocatalyst-free photo-induced denitroalkylation of beta-nitrostyrenes with 4-alkyl substituted Hantzsch esters at room temperature	The C-H alkylation of aniline derivatives with both primary and secondary alkyl halides was achieved with a versatile nickel catalyst of a vicinal diamine ligand. Step-economic access to functionalized 2-pyrimidyl anilines, key structural motifs in anticancer drugs, is thus provided. The C-H functionalization proceeded through facile C-H activation and SET-type C-X bond cleavage with the assistance of a monodentate directing group, which could be removed in a traceless fashion.	Tetrahedron Lett.	50	Li, YM	FALSE	FALSE	FALSE	FALSE
5732	10.1039/c9ob02691f	doi.org/10.1039/c9ob02691f	Cascade and multicomponent synthesis of structurally diverse 2-(pyrazol-3-yl)pyridines and polysubstituted pyrazoles	C-glycosides are important compounds as they are used as bioactive molecules and building blocks. We have developed methods to concisely synthesize C-glycosides from unprotected 2-N-acyl-aldohexoses and unactivated ketones; we designed aldol-condensation-oxa-Michael addition reactions catalyzed by amine-based catalysts using additives. Depending on the conditions used, C-glycosides were stereoselectively obtained. Our methods allowed the C-C bond formations at the anomeric centers of unprotected carbohydrates under mild conditions to lead the C-glycosides in atom-and step-economical ways.	Org. Biomol. Chem.	50	Jimenez, A; Valdes, C	FALSE	FALSE	FALSE	FALSE
5733	10.1039/c9cc09497k	doi.org/10.1039/c9cc09497k	Access to the most sterically crowded anilines via non-catalysed C-C coupling reactions	The majority reactions of alkynes in the literature are reported to proceed via either structural sigma-activation or catalytic pi-activation of C C bonds. We skillfully designed novel methods for the catalytic sigma-activation of C C bonds of alkynyl compounds. For terminal alkynyl compounds, sigma-activation was achieved by silver(I)-catalyzed C-H functionalization. Whereas sigma-activation of internal alkynes was accomplished by the generation of propargylic cations from propargylic alcohols under Lewis-acid catalysis. These sigma-activated species have been successfully used for new C-C and C-hetero-atom bond formation reactions. Plausible reaction pathways were proposed based on typical control experiments to help the readers to gain insights into reactions and for further discovery of new reactions based on this concept of catalytic sigma-activation of C C bonds.	Chem. Commun.	50	Vrana, J	FALSE	FALSE	FALSE	FALSE
5734	10.1021/acs.joc.9b02880	doi.org/10.1021/acs.joc.9b02880	Synthesis of CBD and Its Derivatives Bearing Various C4 '-Side Chains with a Late-Stage Diversification Method		J. Org. Chem.	50	Shen, JS	FALSE	FALSE	FALSE	FALSE
5735	10.1021/acscatal.9b03620	doi.org/10.1021/acscatal.9b03620	Chemodivergent Nickel(0)-Catalyzed Arene C-F Activation with Alkynes: Uriprecedented C-F/C-H Double Insertion		ACS Catal.	50	Ribas, X	FALSE	FALSE	FALSE	FALSE
5736	10.1007/s40242-019-9248-5	doi.org/10.1007/s40242-019-9248-5	Selective N-Alkylation of 2-Amino-4H-chromene-3-carbonitrile Derivatives with Alcohols Catalyzed by AlCl3 Under the Assistance of CH3COOH		Chem. Res. Chin. Univ.	50	Zhao, B; Kan, W	FALSE	FALSE	FALSE	FALSE
5737	10.1016/j.tetlet.2019.151283	doi.org/10.1016/j.tetlet.2019.151283	First Cp*Co(III)-catalyzed Mizoroki-Heck coupling reactions of alkenes and aryl bromide/iodide		Tetrahedron Lett.	50	Joshi, RK	FALSE	FALSE	FALSE	FALSE
5738	10.1002/anie.201906815	doi.org/10.1002/anie.201906815	Nickel-Catalyzed Conversion of Enol Triflates into Alkenyl Halides		Angew. Chem.-Int. Edit.	50	Reisman, SE	FALSE	FALSE	FALSE	FALSE
5739	10.1021/acs.orglett.9b02504	doi.org/10.1021/acs.orglett.9b02504	Modular Arene Difunctionalization of Unactivated C-O and C-H Bonds by Sequential Chromium-Catalyzed Transformations		Org. Lett.	50	Luo, MM; Zeng, XM	FALSE	FALSE	FALSE	FALSE
5740	10.1021/acs.joc.9b01432	doi.org/10.1021/acs.joc.9b01432	Synthetic Access to 3-Substituted Pyroglutamic Acids from Tetramate Derivatives of Serine, Threonine, allo-Threonine, and Cysteine		J. Org. Chem.	50	Moloney, MG	FALSE	FALSE	FALSE	FALSE
5741	10.1021/acs.inorgchem.9b01392	doi.org/10.1021/acs.inorgchem.9b01392	Ligands and Bases Mediate Switching between Aminocarbonylations and Alkoxycarbonylations in Coupling of Aminophenols with Iodoarenes		Inorg. Chem.	50	Chen, DZ	FALSE	FALSE	FALSE	FALSE
5742	10.1021/acs.orglett.9b01987	doi.org/10.1021/acs.orglett.9b01987	Desulfonylative Arylation of Redox-Active Alkyl Sulfones with Aryl Bromides		Org. Lett.	50	Hughes, JME; Fier, PS	FALSE	FALSE	FALSE	FALSE
5743	10.1002/anie.201904028	doi.org/10.1002/anie.201904028	Deoxygenative Borylation of Secondary and Tertiary Alcohols		Angew. Chem.-Int. Edit.	50	Studer, A	FALSE	FALSE	FALSE	FALSE
5744	10.1002/anie.201814340	doi.org/10.1002/anie.201814340	Enantioselective Construction of alpha-Chiral Silanes by Nickel-Catalyzed C(sp(3))-C(sp(3)) Cross-Coupling		Angew. Chem.-Int. Edit.	50	Oestreich, M	FALSE	FALSE	FALSE	FALSE
5745	10.1039/c8ob01895b	doi.org/10.1039/c8ob01895b	Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals		Org. Biomol. Chem.	50	Morrill, LC	FALSE	FALSE	FALSE	FALSE
5746	10.1002/anie.201814493	doi.org/10.1002/anie.201814493	Constructing Mononuclear Palladium Catalysts by Precoordination/Solvothermal Polymerization: Recyclable Catalyst for Regioselective Oxidative Heck Reactions		Angew. Chem.-Int. Edit.	50	Tang, HT; Pan, YM	FALSE	FALSE	FALSE	FALSE
5747	10.1039/c8qo01052h	doi.org/10.1039/c8qo01052h	Reductive cleavage of the N-O bond: elemental sulfur-mediated conversion of N-alkoxyamides to amides		Org. Chem. Front.	50	Du, YF	FALSE	FALSE	FALSE	FALSE
5748	10.1002/chem.201805682	doi.org/10.1002/chem.201805682	Divergent Total Syntheses of C3 a-C7 ' Linked Diketopiperazine Alkaloids (+)-Asperazine and (+)-Pestalazine A Enabled by a Ni-Catalyzed Reductive Coupling of Tertiary Alkyl Chloride		Chem.-Eur. J.	50	Peng, Y	FALSE	FALSE	FALSE	FALSE
5749	10.1021/acs.orglett.8b03560	doi.org/10.1021/acs.orglett.8b03560	Palladium-Catalyzed Cross-Coupling of gem-Bis(boronates) with Aryl Halides: An Alternative To Access Quaternary alpha-Aryl Aldehydes		Org. Lett.	50	Zhao, XM; Xu, T	FALSE	FALSE	FALSE	FALSE
5750	10.1016/j.tetlet.2018.11.026	doi.org/10.1016/j.tetlet.2018.11.026	Silver-promoted cross-coupling of substituted allyl(trimethyl)silanes with aryl iodides by palladium catalysis		Tetrahedron Lett.	50	Yao, B	FALSE	FALSE	FALSE	FALSE
5751	10.1021/acs.orglett.8b02155	doi.org/10.1021/acs.orglett.8b02155	Copper-Catalyzed Reagent-Controlled Regioselective Cyanoborylation of Vinylarenes		Org. Lett.	50	Xiao, B; Fu, Y	FALSE	FALSE	FALSE	FALSE
5752	10.1016/j.jcat.2018.07.007	doi.org/10.1016/j.jcat.2018.07.007	Design and fabrication of PdO/CexOy composite catalysts with coaxial nanotuber and studies of their synergistic performance in Suzuki-Miyaura reactions		J. Catal.	50	Jie, B	FALSE	FALSE	FALSE	FALSE
5753	10.1039/c8cc05437a	doi.org/10.1039/c8cc05437a	Ruthenium nanoparticle catalyzed selective reductive amination of imine with aldehyde to access tertiary amines		Chem. Commun.	50	Li, B; Shao, Y	FALSE	FALSE	FALSE	FALSE
5754	10.1021/acs.joc.8b00552	doi.org/10.1021/acs.joc.8b00552	Synthesis of 2-Substituted Quinolines from 2-Aminostyryl Ketones Using Iodide as a Catalyst		J. Org. Chem.	50	Cheon, CH	FALSE	FALSE	FALSE	FALSE
5755	10.1016/j.tet.2018.03.029	doi.org/10.1016/j.tet.2018.03.029	Asymmetric ring-opening reaction of azabenzonorbornadienes with phenols promoted by palladium/(R,R)-DIOP complex		Tetrahedron	50	Zhou, YY; Fan, BM	FALSE	FALSE	FALSE	FALSE
5756	10.1021/jacs.8b02462	doi.org/10.1021/jacs.8b02462	Suzuki-Miyaura Coupling of Simple Ketones via Activation of Unstrained Carbon-Carbon Bonds		J. Am. Chem. Soc.	50	Dong, GB	FALSE	FALSE	FALSE	FALSE
5757	10.1021/acs.joc.7b02780	doi.org/10.1021/acs.joc.7b02780	Stereospecific Stille Cross-Couplings Using Mn(II)Cl-2		J. Org. Chem.	50	Falck, JR	FALSE	FALSE	FALSE	FALSE
5758	10.2174/1385272822666181010125902	doi.org/10.2174/1385272822666181010125902	Titanium Tetrachloride-mediated Synthesis of Diarylmethanes through the Reaction of Benzyl Alcohol Derivatives with Aromatic Substrates		Curr. Org. Chem.	50	Leggio, A; Liguori, A	FALSE	FALSE	FALSE	FALSE
5759	10.1038/s41929-017-0007-z	doi.org/10.1038/s41929-017-0007-z	Complete lignocellulose conversion with integrated catalyst recycling yielding valuable aromatics and fuels		Nat. Catal.	50	Barta, K	FALSE	FALSE	FALSE	FALSE
5760	10.1039/c7dt03403b	doi.org/10.1039/c7dt03403b	C-H nickellation of phenol-derived phosphinites: regioselectivity and structures of cyclonickellated complexes		Dalton Trans.	50	Zargarian, D	FALSE	FALSE	FALSE	FALSE
5761	10.1002/adsc.201700722	doi.org/10.1002/adsc.201700722	Tandem Cross Coupling Reaction of Alcohols for Sustainable Synthesis of beta-Alkylated Secondary Alcohols and Flavan Derivatives		Adv. Synth. Catal.	50	Kundu, S	FALSE	FALSE	FALSE	FALSE
5762	10.1021/acs.joc.7b02033	doi.org/10.1021/acs.joc.7b02033	Metal-Free, Bronsted Acid-Catalyzed Formal [3+2] Annulation of Quinone Monoacetals with 2-Naphthols		J. Org. Chem.	50	Kaicharla, T; Biju, AT	FALSE	FALSE	FALSE	FALSE
5763	10.1021/acs.orglett.7b02522	doi.org/10.1021/acs.orglett.7b02522	Ex Situ Generation of Sulfuryl Fluoride for the Synthesis of Aryl Fluorosulfates		Org. Lett.	50	De Borggraeve, WM	FALSE	FALSE	FALSE	FALSE
5764	10.1021/acs.joc.5b02151	doi.org/10.1021/acs.joc.5b02151	Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides		J. Org. Chem.	50	Wang, ZX	FALSE	FALSE	FALSE	FALSE
5765	10.1021/acs.orglett.5b01630	doi.org/10.1021/acs.orglett.5b01630	Pd-Catalyzed Regiodivergent Hydroesterification of Aryl Olefins with Phenyl Formate		Org. Lett.	50	Shi, Y	FALSE	FALSE	FALSE	FALSE
5766	10.1021/jacs.5b03937	doi.org/10.1021/jacs.5b03937	Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts		J. Am. Chem. Soc.	50	Gaunt, MJ	FALSE	TRUE	FALSE	FALSE
5767	10.1055/s-0034-1379994	doi.org/10.1055/s-0034-1379994	Palladium-Catalyzed Oxidative Heck Coupling of Vinyl Pyridines with Aryl Boronic Acids		Synlett	50	Chen, SS	FALSE	FALSE	FALSE	FALSE
5768	10.1002/anie.201410350	doi.org/10.1002/anie.201410350	Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes		Angew. Chem.-Int. Edit.	50	Mascarenas, JL	FALSE	FALSE	FALSE	FALSE
5769	10.1039/c5cc05209b	doi.org/10.1039/c5cc05209b	Dual metal and Lewis base catalysis approach for asymmetric synthesis of dihydroquinolines and the alpha-arylation of aldehydes via N-acyliminium ions		Chem. Commun.	50	Rueping, M	FALSE	FALSE	FALSE	FALSE
5770	10.1039/c4ob02586e	doi.org/10.1039/c4ob02586e	NiSO4-catalyzed C-H activation/C-S cross-coupling of 1,2,3-triazole N-oxides with thiols		Org. Biomol. Chem.	50	Chen, ZW	FALSE	FALSE	FALSE	FALSE
5771	10.1021/ja509077a	doi.org/10.1021/ja509077a	Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2		J. Am. Chem. Soc.	50	Martin, R	FALSE	FALSE	FALSE	FALSE
5772	10.1016/j.tetlet.2014.07.118	doi.org/10.1016/j.tetlet.2014.07.118	Cu(I) metal organic framework catalyzed C-C and C-N coupling reactions		Tetrahedron Lett.	50	Srivastava, R	FALSE	FALSE	FALSE	FALSE
5773	10.1021/ja05064586	doi.org/10.1021/ja05064586	Ni-Catalyzed Carboxylation of Unactivated Primary Alkyl Bromides and Sulfonates with CO2		J. Am. Chem. Soc.	50	Martin, R	FALSE	FALSE	FALSE	FALSE
5774	10.1016/j.tet.2014.03.039	doi.org/10.1016/j.tet.2014.03.039	A general, simple catalyst for enantiospecific cross couplings of benzylic ammonium triflates and boronic acids: no phosphine ligand required		Tetrahedron	50	Watson, MP	FALSE	FALSE	FALSE	FALSE
5775	10.1021/ol403209k	doi.org/10.1021/ol403209k	Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates		Org. Lett.	50	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
5776	10.1039/c3dt53352b	doi.org/10.1039/c3dt53352b	Anion exchange in [Ni(eta(5)-C5H4R)(Cl)(NHC)]. Counterion effect on the structure and catalytic activity		Dalton Trans.	50	Buchowicz, W	FALSE	FALSE	FALSE	FALSE
5777	10.1039/c4qo00233d	doi.org/10.1039/c4qo00233d	Acenaphthoimidazolium chloride-enabled nickel-catalyzed amination of bulky aryl tosylates		Org. Chem. Front.	50	Jiang, J	FALSE	FALSE	FALSE	FALSE
5778	10.1039/c3ob42053a	doi.org/10.1039/c3ob42053a	Nickel-catalyzed triarylamine synthesis: synthetic and mechanistic aspects		Org. Biomol. Chem.	50	Fan, XH	FALSE	FALSE	FALSE	FALSE
5779	10.1016/j.comptc.2013.10.019	doi.org/10.1016/j.comptc.2013.10.019	Theoretical study on mechanism of reactions of triarylphosphines with S-nitrosated proteins		Comput. Theor. Chem.	50	Qi, CZ	FALSE	FALSE	FALSE	FALSE
5780	10.1039/c4ra05203j	doi.org/10.1039/c4ra05203j	A highly efficient, ligand-free and recyclable SBA-15 supported Cu2O catalyzed cyanation of aryl iodides with potassium hexacyanoferrate(II)		RSC Adv.	50	Zhu, HJ	FALSE	FALSE	FALSE	FALSE
5781	10.1002/ejoc.201300967	doi.org/10.1002/ejoc.201300967	One-Step Synthesis of Biaryls under Mild Conditions		Eur. J. Org. Chem.	50	Bhat, BR	FALSE	FALSE	FALSE	FALSE
5782	10.1021/ol401550h	doi.org/10.1021/ol401550h	Highly Efficient Aminocarbonylation of Iodoarenes at Atmospheric Pressure Catalyzed by a Robust Acenaphthoimidazolyidene Allylic Palladium Complex		Org. Lett.	50	Tu, T	FALSE	FALSE	FALSE	FALSE
5783	10.1021/om400424a	doi.org/10.1021/om400424a	Intramolecular Arene C-H to C-P Functionalization Mediated by Nickel(II) and Palladium(II)		Organometallics	50	Agapie, T	FALSE	FALSE	FALSE	FALSE
5784	10.1002/hlca.201200454	doi.org/10.1002/hlca.201200454	Formation of cine-Substitution Products in the SuzukiMiyaura Cross-Coupling Reaction Catalyzed by Dinuclear Palladium Complexes		Helv. Chim. Acta	50	Tsukada, N	FALSE	FALSE	FALSE	FALSE
5785	10.1016/j.apcata.2013.03.027	doi.org/10.1016/j.apcata.2013.03.027	Synthesis of a class of new phosphine-oxazoline ligands and their applications in palladium-catalyzed asymmetric addition of arylboronic acids to isatins		Appl. Catal. A-Gen.	50	Qiu, LQ	FALSE	FALSE	FALSE	FALSE
5786	10.1021/ol400537b	doi.org/10.1021/ol400537b	Rhodium(III)-Catalyzed Direct Selective C(5)-H Oxidative Annulations of 2-Substituted Imidazoles and Alkynes by Double C-H Activation		Org. Lett.	50	Dong, L	FALSE	FALSE	FALSE	FALSE
5787	10.1055/s-0032-1318482	doi.org/10.1055/s-0032-1318482	Silver Ion Mediated In Situ Synthesis of Mixed Diaryl Sulfides from Diaryl Disulfides		Synlett	50	Barman, P	FALSE	FALSE	FALSE	FALSE
5788	10.1021/ja311045f	doi.org/10.1021/ja311045f	Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2		J. Am. Chem. Soc.	50	Martin, R	FALSE	FALSE	FALSE	FALSE
5789	10.1039/c3dt51562a	doi.org/10.1039/c3dt51562a	Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions		Dalton Trans.	50	Garcia-Vivo, D	FALSE	FALSE	FALSE	FALSE
5790	10.1007/s10562-012-0913-2	doi.org/10.1007/s10562-012-0913-2	A Novel Iron Complex for Cross-Coupling Reactions of Multiple C-Cl Bonds in Polychlorinated Solvents with Grignard Reagents		Catal. Lett.	50	Ghosh, A	FALSE	FALSE	FALSE	FALSE
5791	10.1021/ma301797w	doi.org/10.1021/ma301797w	Mechanistic Insight into Catalyst-Transfer Polymerization of Unusual Anion-Radical Naphthalene Diimide Monomers: An Observation of Ni(0) Intermediates		Macromolecules	50	Senkovskyy, V	FALSE	FALSE	FALSE	FALSE
5792	10.1021/es302188f	doi.org/10.1021/es302188f	Hydrodefluorination and Hydrogenation of Fluorobenzene under Mild Aqueous Conditions		Environ. Sci. Technol.	50	McNeill, K	FALSE	FALSE	FALSE	FALSE
5793	10.1002/ejoc.201200678	doi.org/10.1002/ejoc.201200678	Synthesis and Reactivity of the 3-Substituted Isoindolinone Framework to Assemble Highly Functionalized Related Structures		Eur. J. Org. Chem.	50	Massa, A	FALSE	FALSE	FALSE	FALSE
5794	10.1021/ol301847m	doi.org/10.1021/ol301847m	Nickel-Catalyzed Amination of Aryl Sulfamates and Carbamates Using an Air-Stable Precatalyst		Org. Lett.	50	Garg, NK	FALSE	FALSE	FALSE	FALSE
5795	10.1021/ol3009842	doi.org/10.1021/ol3009842	Selective Catalytic sp(3) C-O Bond Cleavage with C-N Bond Formation in 3-Alkoxy-1-propanols		Org. Lett.	50	Hong, SH	FALSE	FALSE	FALSE	FALSE
5796	10.1021/jo202577m	doi.org/10.1021/jo202577m	Palladium-Catalyzed Oxidative Heck Coupling Reaction for Direct Synthesis of 4-Arylcoumarins Using Coumarins and Arylboronic Acids		J. Org. Chem.	50	Li, YM	FALSE	FALSE	FALSE	FALSE
5797	10.1021/ol203154j	doi.org/10.1021/ol203154j	Pd-Catalyzed Regioselective and Stereospecific Suzuki-Miyaura Coupling of Allylic Carbonates with Arylboronic Acids		Org. Lett.	50	Zhang, YJ	FALSE	FALSE	FALSE	FALSE
5798	10.1039/c2dt12243j	doi.org/10.1039/c2dt12243j	Palladium(II) thiocarboxamide complexes: synthesis, characterisation and application to catalytic Suzuki coupling reactions		Dalton Trans.	50	Ramesh, R	FALSE	FALSE	FALSE	FALSE
5799	10.1021/ja210025q	doi.org/10.1021/ja210025q	Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki-Miyaura Coupling of alpha-(Acetylamino)benzylboronic Esters		J. Am. Chem. Soc.	50	Ohmura, T	FALSE	FALSE	FALSE	FALSE
5800	10.1021/om200787s	doi.org/10.1021/om200787s	Remarkable Effect of Valence Electrons in Thiolato-Bridged Diruthenium Complexes toward Catalytic Dimerization of alpha-Methylstyrenes		Organometallics	50	Nishibayashi, Y	FALSE	TRUE	FALSE	FALSE
5801	10.1021/jo201840n	doi.org/10.1021/jo201840n	Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides		J. Org. Chem.	50	Molander, GA	FALSE	FALSE	FALSE	FALSE
5802	10.1246/cl.2011.702	doi.org/10.1246/cl.2011.702	Direct Conversion of Pinacol Arylboronic Esters to Aryl Triolborates		Chem. Lett.	50	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
5803	10.1038/nn.2800	doi.org/10.1038/nn.2800	Hierarchical chemosensory regulation of male-male social interactions in Drosophila		Nat. Neurosci.	50	Wang, LM	FALSE	FALSE	FALSE	FALSE
5804	10.1021/ol200764g	doi.org/10.1021/ol200764g	Anthranilamide: A Simple, Removable ortho-Directing Modifier for Arylboronic Acids Serving also as a Protecting Group in Cross-Coupling Reactions		Org. Lett.	50	Suginome, M	FALSE	FALSE	FALSE	FALSE
5805	10.1021/jo2000034	doi.org/10.1021/jo2000034	Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids		J. Org. Chem.	50	Zhao, YF	FALSE	FALSE	FALSE	FALSE
5806	10.1021/ja108547u	doi.org/10.1021/ja108547u	Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Ethers: Enantioselective Synthesis of Diarylethanes		J. Am. Chem. Soc.	50	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
5807	10.1002/adsc.201000223	doi.org/10.1002/adsc.201000223	Well-Defined Allylnickel Chloride/N-Heterocyclic Carbene [(NHC)Ni(allyl)Cl] Complexes as Highly Active Precatalysts for C-N and C-S Cross-Coupling Reactions		Adv. Synth. Catal.	50	Nicasio, MC	FALSE	FALSE	FALSE	FALSE
5808	10.1021/ja101939r	doi.org/10.1021/ja101939r	A New Entry of Amination Reagents for Heteroaromatic C-H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature		J. Am. Chem. Soc.	50	Miura, M	FALSE	FALSE	FALSE	FALSE
5809	10.1021/jo100407s	doi.org/10.1021/jo100407s	Amine-Promoted Synthesis of Vinyl Aziridines		J. Org. Chem.	50	Armstrong, A	FALSE	FALSE	FALSE	FALSE
5810	10.1021/ol9029534	doi.org/10.1021/ol9029534	Nickel-Catalyzed Efficient and Practical Suzuki-Miyaura Coupling of Alkenyl and Aryl Carbamates with Aryl Boroxines		Org. Lett.	50	Li, BJ	FALSE	FALSE	FALSE	FALSE
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5812	10.1002/jhet.96	doi.org/10.1002/jhet.96	Suzuki-Miyaura Arylations of Tetramic Acid Sulfonates: Evaluation of Lactam Protection, Sulfonate Esters, and Sterics		J. Heterocycl. Chem.	50	Pelkey, ET	FALSE	FALSE	FALSE	FALSE
5813	10.1016/j.tetlet.2007.12.118	doi.org/10.1016/j.tetlet.2007.12.118	Efficient ligand-free nickel-catalyzed C-S cross-coupling of thiols with aryl iodides		Tetrahedron Lett.	50	Punnlyamurthy, T	FALSE	FALSE	FALSE	FALSE
5814	10.1055/s-2007-985567	doi.org/10.1055/s-2007-985567	Monooxychlorophosphine as a novel and efficient ligand for palladium-catalyzed suzuki-miyaura cross-coupling of aryl chlorides		Synlett	50	Gao, LX	FALSE	FALSE	FALSE	FALSE
5815	10.2174/138527206775192979	doi.org/10.2174/138527206775192979	pi(3)-Allylruthenium complexes and ruthenium-catalysed nucleophilic substitution of allylic substrates		Curr. Org. Chem.	50	Bruneau, C	FALSE	FALSE	FALSE	FALSE
5816	10.1016/j.jorganchem.2005.08.035	doi.org/10.1016/j.jorganchem.2005.08.035	Nickel(0)/N-heterocyclic carbene complexes catalysed arylation of aromatic diamines		J. Organomet. Chem.	50	Schneider, R	FALSE	FALSE	FALSE	FALSE
5817	10.1021/jo051660v	doi.org/10.1021/jo051660v	A highly regio- and stereoselective nickel-catalyzed ring-opening reaction of alkyl- and allylzirconium reagents to 7-oxabenzonorbornadienes		J. Org. Chem.	50	Cheng, CH	FALSE	FALSE	FALSE	FALSE
5818	10.1002/anie.200500918	doi.org/10.1002/anie.200500918	Couplings with mouoorganotin compounds: A radical twist from the original Stille reaction		Angew. Chem.-Int. Edit.	50	Echavarren, AM	FALSE	FALSE	FALSE	FALSE
5819	10.1016/j.molcata.2004.03.029	doi.org/10.1016/j.molcata.2004.03.029	In situ generated palladium catalysts bearing 1,3-dialkylperimidin-2-yline ligands for Suzuki reactions of aryl chlorides		J. Mol. Catal. A-Chem.	50	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
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5821	10.1021/jo00109a044	doi.org/10.1021/jo00109a044	ARYL MESYLATES IN METAL-CATALYZED HOMOCOUPLING AND CROSS-COUPLING REACTIONS .2. SUZUKI-TYPE NICKEL-CATALYZED CROSS-COUPLING OF ARYL ARENESULFONATES AND ARYL MESYLATES WITH ARYLBORONIC ACIDS		J. Org. Chem.	50	PERCEC, V	FALSE	FALSE	FALSE	FALSE
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5823	10.1021/jo00248a016	doi.org/10.1021/jo00248a016	ENANTIOSELECTIVE RING CONSTRUCTION WITH CONTROL OF SIDE-CHAIN STEREOCHEMISTRY - SYNTHESIS OF (+)-ISONEONEPETALACTONE		J. Org. Chem.	50	TABER, DF	FALSE	FALSE	FALSE	FALSE
5824	10.1016/S0040-4020(01)85098-5	doi.org/10.1016/S0040-4020(01)85098-5	SYNTHESES WITH SULFONES .48. STEREOSELECTIVE SYNTHESIS OF 2-ISOPROPYL- 1,4-DIENES THROUGH THE IRON-CATALYZED CROSS-COUPLING REACTION OF 2-BENZENESULFONYL- 1,4-DIENES AND ISOPROPYLMAGNESIUM CHLORIDE		Tetrahedron	50		FALSE	FALSE	FALSE	FALSE
5825	10.2533/chimia.2021.943	doi.org/10.2533/chimia.2021.943	From Academia to the Market - Air-stable Ni(II)/Josiphos Catalysts		Chimia	50	Link, A	FALSE	FALSE	FALSE	FALSE
5826	10.1021/acs.inorgchem.1c02397	doi.org/10.1021/acs.inorgchem.1c02397	Designing Catalytic Systems Using Binary Solvent Mixtures: Impact of Mole Fraction of Water on Hydride Transfer		Inorg. Chem.	50	Appel, AM	FALSE	FALSE	FALSE	FALSE
5827	10.1021/acs.organomet.1c00370	doi.org/10.1021/acs.organomet.1c00370	Computational Study on the Mechanisms and Origins of Selectivity in Hydroarylation of 1,3-Diyne Alcohol Catalyzed by Di- and Mononuclear Manganese Complexes		Organometallics	50	Yuan, XA; Bi, SW	FALSE	FALSE	FALSE	FALSE
5828	10.1055/a-1509-5954	doi.org/10.1055/a-1509-5954	Nickel-Catalyzed Homocoupling of Aryl Ethers with Magnesium Anthracene Reductant		Synthesis	50	Higashida, K; Sawamura, M	FALSE	FALSE	FALSE	FALSE
5829	10.1039/c7ob01791j	doi.org/10.1039/c7ob01791j	Nickel-catalyzed N-vinylation of heteroaromatic amines via C-H bond activation		Org. Biomol. Chem.	50	Balaraman, E	FALSE	FALSE	FALSE	FALSE
5830	10.1021/jacs.7b06191	doi.org/10.1021/jacs.7b06191	Ni-Catalyzed Alkene Carboacylation via Amide C-N Bond Activation		J. Am. Chem. Soc.	50	Stanley, LM	FALSE	FALSE	FALSE	FALSE
5831	10.1055/s-0036-1588464	doi.org/10.1055/s-0036-1588464	Nickel-Catalyzed Reductive Cross-Coupling of Aryl Triflates and Nonaflates with Alkyl Iodides		Synthesis	50	Sumida, Y; Hosoya, T	FALSE	FALSE	FALSE	FALSE
5832	10.1038/ncomms14993	doi.org/10.1038/ncomms14993	Nickel-catalysed retro-hydroamidocarbonylation of aliphatic amides to olefins		Nat. Commun.	50	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
5833	10.1021/jacs.7b01254	doi.org/10.1021/jacs.7b01254	Copper(I)-Catalyzed Enantioselective Addition of Enynes to Ketones		J. Am. Chem. Soc.	50	Shimizu, Y; Kanai, M	FALSE	FALSE	FALSE	FALSE
5834	10.1021/jacs.6b13346	doi.org/10.1021/jacs.6b13346	C(sp(2))-H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities		J. Am. Chem. Soc.	50	Chirik, PJ	FALSE	TRUE	FALSE	FALSE
5835	10.1021/acs.orglett.6b03703	doi.org/10.1021/acs.orglett.6b03703	Transition-Metal-Free Amination of Pyridine-2-sulfonyl Chloride and Related N-Heterocycles Using Magnesium Amides		Org. Lett.	50	Knochel, P	FALSE	FALSE	FALSE	FALSE
5836	10.1039/c6sc02895k	doi.org/10.1039/c6sc02895k	Versatile synthesis and enlargement of functionalized distorted heptagon-containing nanographenes		Chem. Sci.	50	Campana, AG	FALSE	FALSE	FALSE	FALSE
5837	10.1021/acs.orglett.6b02330	doi.org/10.1021/acs.orglett.6b02330	Pd-Catalyzed Suzuki-Miyaura and Hiyama-Denmark Couplings of Aryl Sulfamates		Org. Lett.	50	Hazari, N	FALSE	FALSE	FALSE	FALSE
5838	10.1002/adsc.201600024	doi.org/10.1002/adsc.201600024	Self-Assembled Multilayer-Stabilized Nickel Nanoparticle Catalyst for Ligand-Free Cross-Coupling Reactions: in situ Metal Nanoparticle and Nanospace Simultaneous Organization		Adv. Synth. Catal.	50	Sato, Y; Arisawa, M	FALSE	FALSE	FALSE	FALSE
5839	10.1002/adsc.201600284	doi.org/10.1002/adsc.201600284	Enantioselective Copper-Catalyzed Propargylic Etherification of Propargylic Esters with Phenols Promoted by Inorganic Base Additives		Adv. Synth. Catal.	50	Hu, XP	FALSE	FALSE	FALSE	FALSE
5840	10.1002/chem.201602088	doi.org/10.1002/chem.201602088	Rhodium(I)-Catalyzed Benzannulation of Heteroaryl Propargylic Esters: Synthesis of Indoles and Related Heterocycles		Chem.-Eur. J.	50	Tang, WP	FALSE	FALSE	FALSE	FALSE
5841	10.3762/bjoc.12.108	doi.org/10.3762/bjoc.12.108	Synthesis of beta-arylated alkylamides via Pd-catalyzed one-pot installation of a directing group and C(sp(3))-H arylation		Beilstein J. Org. Chem.	50	Liu, YY	FALSE	FALSE	FALSE	FALSE
5842	10.1055/s-0035-1561584	doi.org/10.1055/s-0035-1561584	Synthesis and Catalytic Asymmetric Applications of Quinazolinol Ligands		Synthesis	50	Ulukanli, S	FALSE	FALSE	FALSE	FALSE
5843	10.1002/ejic.201600090	doi.org/10.1002/ejic.201600090	Multiple-Metal (De-)Hydrogenation-Catalysed Processes		Eur. J. Inorg. Chem.	50	Mata, JA	FALSE	FALSE	FALSE	FALSE
5844	10.1002/adsc.201500822	doi.org/10.1002/adsc.201500822	Nickel-Catalyzed alpha-Benzylation of Arylacetonitriles via C-O Activation		Adv. Synth. Catal.	50	Chen, TQ; Han, LB	FALSE	FALSE	FALSE	FALSE
5845	10.1039/c5gc02985f	doi.org/10.1039/c5gc02985f	Heterogeneous recyclable nano-palladium catalyzed amidation of esters using formamides as amine sources		Green Chem.	50	Bao, YS	FALSE	FALSE	FALSE	FALSE
5846	10.1021/acs.orglett.0c02934	doi.org/10.1021/acs.orglett.0c02934	Cobalt-Catalyzed C(sp(2))-C(sp(3)) Suzuki-Miyaura Cross Coupling	A series of ionic iron(III) complexes of general formula [HLn][FeX4] (HL1 = 1,3-dibenzylbenzimidazolium cation, X = Cl, 1; HL1, X = Br, 2; HL2 = 1,3-dibutylbenzimidazolium cation, X = Br, 3; HL3 = 1,3-bis(diphenylmethyl) benzimidazolium cation, X = Br, 4) were easily prepared in high yields by the direct reaction of FeX3 with 1 equiv. of [HLn] X under mild conditions. All of them were characterized using elemental analysis, Raman spectroscopy and electrospray ionization mass spectrometry, and X-ray crystallography for 1 and 4. In the presence of magnesium turnings and LiCl, these air- and moisture-insensitive complexes showed high catalytic activities in direct cross-couplings of aryl phosphates with primary and secondary alkyl bromides with broad substrate scope, wherein complex 4 was the most effective.	Org. Lett.	49	Chirik, PJ	FALSE	FALSE	FALSE	FALSE
5847	10.1002/adsc.202001346	doi.org/10.1002/adsc.202001346	Cross-Coupling Reactions of Aryl Halides with Primary and Secondary Aliphatic Alcohols Catalyzed by an O,N,N-Coordinated Nickel Complex	A palladium-catalyzed asymmetric allylallyl cross-coupling reaction to construct the chiral quaternary carbon center of crinane alkaloids has been developed. On the basis of an efficient approach, the enantioselective synthesis of (-)-crinane (1) is presented, and the first asymmetric total synthesis of (+)-4a-dehydroxycrinamabine (2) was achieved by subsequent oxidation, 1,4-conjugate addition, RCM reaction, reductive amination, and Pictet-Spengler reaction. The method provided an alternative strategy for the syntheses of crinane alkaloids and other Amaryllidaceae natural products.	Adv. Synth. Catal.	49	Hashimoto, T; Yamaguchi, Y	FALSE	FALSE	FALSE	FALSE
5848	10.1039/d0ob02011g	doi.org/10.1039/d0ob02011g	Microwave-assisted periselective annulation of triarylphosphenes with aldehydes and ketones	Alkylsilicates were engaged under photoredox/nickel dual catalysis conditions with alkyl halides for the first time. The C(sp(3))-C(sp(3)) cross-coupling products were obtained in moderate yields and were accompanied by the homocoupling products of the alkyl halide derivatives. These promising findings are strongly suggestive of the high synthetic potential of the dual catalytic approach for the forging of alkyl carbon-carbon bonds.	Org. Biomol. Chem.	49	Xu, JX	FALSE	FALSE	FALSE	FALSE
5849	10.1002/adsc.202000945	doi.org/10.1002/adsc.202000945	One-Shot Radical Cross Coupling Between Benzyl Alcohols and Alkenyl Halides Using Ni/Ti/Mn System	Herein is reported the mild and general coupling of amine/ether C(sp(3))-H bonds with various kinds of C(sp(2))-O electrophiles with high selectivity and efficiency. Valuable allylic/benzylic amines are generated in moderate to excellent yields. The utility of this transformation is demonstrated by a broad substrate scope (> 50 examples), good functional group tolerance and facile product modification.	Adv. Synth. Catal.	49	Suga, T; Ukaji, Y	FALSE	FALSE	FALSE	FALSE
5850	10.1021/acs.orglett.0c02722	doi.org/10.1021/acs.orglett.0c02722	Nickel-Catalyzed Cyanation of Unactivated Alkyl Sulfonates with Zn(CN)(2)	A Ni(II)-catalyzed asymmetric addition of arylboronic acids to cyclic aldimines and ketimines is reported. Our tropos phosphine-oxazoline biphenyl ligand is crucial for the high catalytic activity, which coordinates to Ni(II) to form a complex with a single axial configuration. The desired chiral amine products could be prepared with excellent yields (up to 99%) and enantioselectivities (up to 99.8%) under mild reaction conditions.	Org. Lett.	49	Liu, YH	FALSE	FALSE	FALSE	FALSE
5851	10.1016/j.chempr.2020.06.020	doi.org/10.1016/j.chempr.2020.06.020	Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes	Herein, we report the first catalytic version of a cobalt-catalysed reductive homocoupling of benzyl halides which proceeds with low catalyst loadings (0.5 to 5 mol%). By synthetizing each cobalt intermediate we demonstrate that reaction proceeds through two single electron transfers (SET) and that dimethylzinc is only involved in the regeneration of the catalytic species.	Chem	49	Tang, HT; Pan, YM	FALSE	FALSE	FALSE	FALSE
5852	10.1002/anie.202006826	doi.org/10.1002/anie.202006826	Nickel-Catalyzed Mono-Selective alpha-Arylation of Acetone with Aryl Chlorides and Phenol Derivatives	In a brief exploratory study we investigated Heck reactions of several alkenyl nonaflates with a protected dehydroalanine derivative. Whereas simple alkenyl nonaflates provided the expected 1,3-dienes in good to excellent yields, more complex oxa-bridged bicyclic substrates gave poorer results. Nevertheless, this approach is of interest for the synthesis of tetradehydroamino acids. Palladium-catalyzed carbonylations of alkenyl nonaflates employing molybdenum hexacarbonyl as convenient carbon monoxide source leading to esters or to carboxylic acids were also studied. Microwave conditions seem to be superior to purely thermal conditions. With an oxygen-bridged bicyclic alkenyl nonaflate the expected carboxylic acid was isolated, however, the formation of a tropone derivative as a result of an acid-promoted fragmentation was also observed.	Angew. Chem.-Int. Edit.	49	Tlili, A; Amgoune, A	FALSE	FALSE	FALSE	FALSE
5853	10.6023/cjoc202003037	doi.org/10.6023/cjoc202003037	Synthesis and Cytotoxic Activity of C-Vinyl-rhamnopyranoside Derivatives	Asymmetric preparation of all-carbon quaternary stereocenters is an important goal. Despite advances in formation of highly enantioenriched products with quaternary stereocenters proximal to a functional group, methods to install quaternary stereocenters isolated from functional groups are limited. Transition metal catalysis offers a potential solution, but prior cross couplings are limited to allylic substrates or deliver little to no enantiomeric enrichment. We report a stereospecific, nickel-catalyzed Suzuki-Miyaura arylation of tertiary benzylic acetates to deliver products with diaryl and triaryl quaternary stereocenters in high-yield's and ee's. This reaction employs an inexpensive, air-stable Ni(II) salt and commercially available phosphine ligand to transform tertiary alcohol derivatives, which are easily available in exceptional ee, into valuable products with stereoretention.	Chin. J. Org. Chem.	49	Huang, NY; Liu, MG	FALSE	FALSE	FALSE	FALSE
5854	10.1016/j.ica.2020.119457	doi.org/10.1016/j.ica.2020.119457	Suzuki-Miyaura coupling catalyzed by a Ni(II) PNP pincer complex: Scope and mechanistic insights	Translation of new F-18-fluorination reactions to produce radiotracers for human positron emission tomography (PET) imaging is rare because the chemistry must have useful scope and the process for F-18-labeled tracer production must be robust and simple to execute. The application of transition metal mediators has enabled impactful F-18-fluorination methods, but to date none of these reactions have been applied to produce a human-injectable PET tracer. In this article we present chemistry and process innovations that culminate in the first production from [F-18]fluoride of human doses of [F-18]5-fluorouracil, a PET tracer for cancer imaging in humans. The first preparation of nickel 6-aryl complexes by transmetalation from arylboronic acids or esters was developed and enabled the synthesis of the [F-18]5-fluorouracil precursor. Routine production of >10 mCi doses of [F-18]5-fluorouracil was accomplished with a new instrument for azeotrope-free [F-18]fluoride concentration in a process that leverages the tolerance of water in nickel-mediated F-18-fluorination.	Inorg. Chim. Acta	49	Tonzetich, ZJ	FALSE	FALSE	FALSE	FALSE
5855	10.1039/c9sc05444h	doi.org/10.1039/c9sc05444h	Aldehydes and ketones influence reactivity and selectivity in nickel-catalysed Suzuki-Miyaura reactions		Chem. Sci.	49	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
5856	10.1021/jacs.9b11208	doi.org/10.1021/jacs.9b11208	Ni-Catalyzed Reductive Cyanation of Aryl Halides and Phenol Derivatives via Transnitrilation		J. Am. Chem. Soc.	49	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
5857	10.1021/acs.orglett.9b03511	doi.org/10.1021/acs.orglett.9b03511	Ni-Catalyzed Regioselective Hydroalkoxylation of Branched 1,3-Dienes		Org. Lett.	49	Mazet, C	FALSE	FALSE	FALSE	FALSE
5858	10.1016/j.mcat.2019.110565	doi.org/10.1016/j.mcat.2019.110565	Synthesis of quinolines via acceptorless dehydrogenative tandem cyclization of 2-amionbenzyl alcohol with alcohols using magnetic CuNiFeO nanocatalyst		Mol. Catal.	49	Bhanage, BM	FALSE	FALSE	FALSE	FALSE
5859	10.1021/acs.orglett.9b02830	doi.org/10.1021/acs.orglett.9b02830	Ylide-Functionalized Phosphine (YPhos)-Palladium Catalysts: Selective Monoarylation of Alkyl Ketones with Aryl Chlorides		Org. Lett.	49	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
5860	10.1002/adsc.201900813	doi.org/10.1002/adsc.201900813	Lewis Acid-Mediated Cyanation of Phenols Using N-Cyano-N-phenyl-p-toluenesulfonamide		Adv. Synth. Catal.	49	Wang, QL; Zhao, WX	FALSE	FALSE	FALSE	FALSE
5861	10.1016/j.jcat.2019.07.058	doi.org/10.1016/j.jcat.2019.07.058	Hydrogen transfer-mediated selective dual C-H alkylations of 2-alkylquinolines by doped TiO2-supported nanocobalt oxides		J. Catal.	49	Zhang, M	FALSE	FALSE	FALSE	FALSE
5862	10.1021/acs.orglett.9b02221	doi.org/10.1021/acs.orglett.9b02221	Total Synthesis of (+/-)-Brussonol and (+/-)-Komaroviquinone via a Regioselective Cross-Electrophile Coupling of Aryl Bromides and Epoxides		Org. Lett.	49	Burtoloso, ACB	FALSE	TRUE	FALSE	FALSE
5863	10.1021/acs.oprd.9b00194	doi.org/10.1021/acs.oprd.9b00194	Palladium-Catalyzed C-N Cross-Coupling of NH-Heteroarenes and Quaternary Ammonium Salts via C-N Bond Cleavage		Org. Process Res. Dev.	49	Zeng, QL	FALSE	FALSE	FALSE	FALSE
5864	10.3390/molecules24081458	doi.org/10.3390/molecules24081458	Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates		Molecules	49	Komeyama, K	FALSE	FALSE	FALSE	FALSE
5865	10.1021/acs.orglett.9b00554	doi.org/10.1021/acs.orglett.9b00554	Chromium-Catalyzed Activation of Acyl C-O Bonds with Magnesium for Amidation of Esters with Nitroarenes		Org. Lett.	49	Luo, MM; Zeng, XM	FALSE	FALSE	FALSE	FALSE
5866	10.1021/acs.inorgchem.8b02915	doi.org/10.1021/acs.inorgchem.8b02915	Competitive Ligand Exchange and Dissociation in Ru Indenyl Complexes		Inorg. Chem.	49	McIndoe, JS; Rosenberg, L	FALSE	FALSE	FALSE	FALSE
5867	10.1039/c8ob02462f	doi.org/10.1039/c8ob02462f	Iron- catalyzed cascade addition/cyclization of 2-biphenyl isocyanides with toluenes: a highly efficient approach to 6-benzylated phenanthridines		Org. Biomol. Chem.	49	Ding, QP	FALSE	FALSE	FALSE	FALSE
5868	10.1038/s42004-018-0092-1	doi.org/10.1038/s42004-018-0092-1	Pyrrolidines and piperidines bearing chiral tertiary alcohols by nickel-catalyzed enantioselective reductive cyclization of N-alkynones		Comm. Chem.	49	Tang, WJ	FALSE	FALSE	FALSE	FALSE
5869	10.1021/acs.orglett.8b02434	doi.org/10.1021/acs.orglett.8b02434	Synthesis of 5H-Dibenzo[c,g]chromen-5-ones via FeCl3 -Mediated Tandem C-O Bond Cleavage/6 pi Electrocyclization/Oxidative Aromatization		Org. Lett.	49	Miao, MZ; Ren, HJ	FALSE	TRUE	FALSE	FALSE
5870	10.1016/j.bmcl.2018.06.038	doi.org/10.1016/j.bmcl.2018.06.038	Design and synthesis of bridged piperidine and piperazine isosteres		Bioorg. Med. Chem. Lett.	49	Hanessian, S	FALSE	FALSE	FALSE	FALSE
5871	10.1021/acs.joc.8b00965	doi.org/10.1021/acs.joc.8b00965	Synthesis of Triarylmethanes via Palladium-Catalyzed Suzuki Coupling of Trimethylammonium Salts and Arylboronic Acids		J. Org. Chem.	49	Zhao, JF	FALSE	FALSE	FALSE	FALSE
5872	10.1002/cctc.201800454	doi.org/10.1002/cctc.201800454	Bench-Stable N-Heterocyclic Carbene Nickel Precatalysts for C-C and C-N Bond-Forming Reactions		ChemCatChem	49	Jamison, TF	FALSE	FALSE	FALSE	FALSE
5873	10.1002/adsc.201800179	doi.org/10.1002/adsc.201800179	Formal Carbene Insertion into C-O or C-N Bond: An Efficient Strategy for the Synthesis of 2-Substituted 2H-Chromene Derivatives from Chromene Acetals or Hemiaminal Ethers		Adv. Synth. Catal.	49	Hu, WH	FALSE	FALSE	FALSE	FALSE
5874	10.1021/acs.orglett.8b01233	doi.org/10.1021/acs.orglett.8b01233	Decarbonylative Methylation of Aromatic Esters by a Nickel Catalyst		Org. Lett.	49	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
5875	10.1021/jacs.8b03560	doi.org/10.1021/jacs.8b03560	Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization		J. Am. Chem. Soc.	49	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
5876	10.1021/acs.orglett.8b00930	doi.org/10.1021/acs.orglett.8b00930	Reductive Cleavage of Aromatic and Heteroaromatic Ester Functions via Copper-Catalyzed Proto-Decarbomethoxylation		Org. Lett.	49	Busca, P	FALSE	FALSE	FALSE	FALSE
5877	10.1039/c8qo00091c	doi.org/10.1039/c8qo00091c	Base-promoted [3+3] cyclization of cyclopropenones and cyclopropenethiones with amides for the synthesis of 6H-1,3-oxazin-6-ones and 6H-1,3-thiazin-6-ones		Org. Chem. Front.	49	Shi, M	FALSE	FALSE	FALSE	FALSE
5878	10.1002/anie.201712618	doi.org/10.1002/anie.201712618	From Anilines to Aryl Ethers: A Facile, Efficient, and Versatile Synthetic Method Employing Mild Conditions		Angew. Chem.-Int. Edit.	49	Zhang, A	FALSE	FALSE	FALSE	FALSE
5879	10.1021/jacs.7b11707	doi.org/10.1021/jacs.7b11707	Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling		J. Am. Chem. Soc.	49	Reisman, SE	FALSE	FALSE	FALSE	FALSE
5880	10.1021/jacs.7b10365	doi.org/10.1021/jacs.7b10365	Enantioselective Palladium-Catalyzed Intramolecular alpha-Arylative Desymmetrization of 1,3-Diketones		J. Am. Chem. Soc.	49	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
5881	10.1039/c6ob01299j	doi.org/10.1039/c6ob01299j	Nickel catalyzed alpha-arylation of ketones with aryltrimethylammonium triflates		Org. Biomol. Chem.	49	Wang, ZX	FALSE	FALSE	FALSE	FALSE
5882	10.1039/c6cc07199f	doi.org/10.1039/c6cc07199f	Aluminium-mediated aromatic C-F bond activation: regioswitchable construction of benzene-fused triphenylene frameworks		Chem. Commun.	49	Ichikawa, J	FALSE	FALSE	FALSE	FALSE
5883	10.1021/acs.orglett.5b02370	doi.org/10.1021/acs.orglett.5b02370	Catalytic Asymmetric Formal Insertion of Aryldiazoalkanes into the C-H Bond of Aldehydes: Synthesis of Enantioenriched Acyclic alpha-Tertiary Aryl Ketones		Org. Lett.	49	Hwang, GS	FALSE	FALSE	FALSE	FALSE
5884	10.1021/acscatal.5b01021	doi.org/10.1021/acscatal.5b01021	Nickel- and Palladium-Catalyzed Coupling of Aryl Fluorosulfonates with Aryl Boronic Acids Enabled by Sulfuryl Fluoride		ACS Catal.	49	Hanley, PS	FALSE	FALSE	FALSE	FALSE
5885	10.1021/acs.organomet.5b00351	doi.org/10.1021/acs.organomet.5b00351	Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels-Alder Reactions		Organometallics	49	Oestreich, M	FALSE	FALSE	FALSE	FALSE
5886	10.1021/jacs.5b03587	doi.org/10.1021/jacs.5b03587	Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes		J. Am. Chem. Soc.	49	Ohashi, M	FALSE	FALSE	FALSE	FALSE
5887	10.1021/jacs.5b03428	doi.org/10.1021/jacs.5b03428	Bond-Weakening Catalysis: Conjugate Aminations Enabled by the Soft Homolysis of Strong N-H Bonds		J. Am. Chem. Soc.	49	Knowles, RR	FALSE	FALSE	FALSE	FALSE
5888	10.1055/s-0034-1378940	doi.org/10.1055/s-0034-1378940	Base-Mediated Addition of 1-(2-Hydroxyalkyl)pyrroles to Acetylene: Atom-Economic Route to 1-[2-(Vinyloxy)alkyl]pyrroles		Synthesis	49	Sadykov, EK	FALSE	FALSE	FALSE	FALSE
5889	10.1039/c5sc01460c	doi.org/10.1039/c5sc01460c	Access to enantioenriched 2,3-and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction		Chem. Sci.	49	Mazet, C	FALSE	FALSE	FALSE	FALSE
5890	10.1039/c5ob01901j	doi.org/10.1039/c5ob01901j	Ni-catalyzed reductive addition of alkyl halides to isocyanides		Org. Biomol. Chem.	49	Dai, YJ	FALSE	FALSE	FALSE	FALSE
5891	10.1039/c5ra13137e	doi.org/10.1039/c5ra13137e	Practical access to 1,3,5-triarylbenzenes from chalcones and DMSO		RSC Adv.	49	Cui, XL	FALSE	FALSE	FALSE	FALSE
5892	10.1021/jo502172c	doi.org/10.1021/jo502172c	Aryl Imidazylates and Aryl Sulfates As Electrophiles in Metal-Free ArS(N)1 Reactions		J. Org. Chem.	49	Fagnoni, M	FALSE	TRUE	FALSE	FALSE
5893	10.1248/yakushi.14-00192	doi.org/10.1248/yakushi.14-00192	Efficient Synthesis of Multisubstituted Aromatic Compounds from Phenol Derivatives		Yakugaku Zasshi-J. Pharm. Soc. Jpn.	49	Ikawa, T	FALSE	FALSE	FALSE	FALSE
5894	10.1016/j.tet.2014.03.063	doi.org/10.1016/j.tet.2014.03.063	A novel atom-economic synthesis of functionalized imidazolidines through copper(I)-catalyzed domino three-component coupling and cyclization reactions		Tetrahedron	49	Li, YF	FALSE	FALSE	FALSE	FALSE
5895	10.1021/ol500456s	doi.org/10.1021/ol500456s	Catalytic Stereospecific Allyl-Allyl Cross-Coupling of Internal Allyl Electrophiles with AllylB(pin)		Org. Lett.	49	Morken, JP	FALSE	TRUE	FALSE	FALSE
5896	10.1021/ja412962w	doi.org/10.1021/ja412962w	Iridium-Catalyzed Enantioselective Allyl-Alkene Coupling		J. Am. Chem. Soc.	49	Carreira, EM	FALSE	FALSE	FALSE	FALSE
5897	10.1021/ol403680c	doi.org/10.1021/ol403680c	Enantioselective Synthesis of Triarylmethanes by Chiral Imidodiphosphoric Acids Catalyzed Friedel-Crafts Reactions		Org. Lett.	49	Jiang, YJ	FALSE	FALSE	FALSE	FALSE
5898	10.1021/ja411911s	doi.org/10.1021/ja411911s	Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex		J. Am. Chem. Soc.	49	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
5899	10.1039/c4cc01312c	doi.org/10.1039/c4cc01312c	Rhodium-catalyzed regio- and stereoselective oxyamination of dienes via tandem aziridination/ring-opening of dienyl carbamates		Chem. Commun.	49	Matheu, MI	FALSE	FALSE	FALSE	FALSE
5900	10.1002/pola.26954	doi.org/10.1002/pola.26954	Precise Synthesis of pH-Responsive Copolymers with Naphthoic Acid Side Groups via Living Cationic Polymerization		J. Polym. Sci. Pol. Chem.	49	Aoshima, S	FALSE	FALSE	FALSE	FALSE
5901	10.1021/ja406025p	doi.org/10.1021/ja406025p	A Pd(0)-Catalyzed Direct Dehydrative Coupling of Terminal Alkynes with Allylic Alcohols To Access 1,4-Enynes		J. Am. Chem. Soc.	49	Liu, L	FALSE	FALSE	FALSE	FALSE
5902	10.1016/j.apcata.2013.04.040	doi.org/10.1016/j.apcata.2013.04.040	Self-coupling of secondary alcohols by Ni/CeO2 catalyst		Appl. Catal. A-Gen.	49	Shimizu, K	FALSE	FALSE	FALSE	FALSE
5903	10.1002/aoc.2997	doi.org/10.1002/aoc.2997	Synthesis of substituted biaryls via Suzuki, Stille and Hiyama cross-coupling and homo-coupling reactions by CN-dimeric and monomeric ortho-palladated catalysts		Appl. Organomet. Chem.	49	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
5904	10.1021/jp312690e	doi.org/10.1021/jp312690e	C-O Bond Cleavage of Dimethyl Ether by Transition Metal Ions: A Systematic Study on Catalytic Properties of Metals and Performance of DFT Functionals		J. Phys. Chem. A	49	Wilson, AK	FALSE	FALSE	FALSE	FALSE
5905	10.1021/jo400424d	doi.org/10.1021/jo400424d	Noncatalytic Pyridyl-Directed Alkylation and Arylation Carbon-Fluorine Bond of Polyfluoroarenes with Grignard Reagents		J. Org. Chem.	49	Cao, S	FALSE	FALSE	FALSE	FALSE
5906	10.1016/j.tet.2013.01.053	doi.org/10.1016/j.tet.2013.01.053	Reaction of organozinc halides with aryl isocyanates		Tetrahedron	49	Hu, YL	FALSE	FALSE	FALSE	FALSE
5907	10.1038/NCHEM.1504	doi.org/10.1038/NCHEM.1504	Regioselective reactions of 3,4-pyridynes enabled by the aryne distortion model		Nat. Chem.	49	Garg, NK	FALSE	FALSE	FALSE	FALSE
5908	10.1002/anie.201300621	doi.org/10.1002/anie.201300621	Arene CH-O Hydrogen Bonding: A Stereocontrolling Tool in Palladium-Catalyzed Arylation and Vinylation of Ketones		Angew. Chem.-Int. Edit.	49	Zhou, JR	FALSE	FALSE	FALSE	FALSE
5909	10.1039/c3cc43955k	doi.org/10.1039/c3cc43955k	Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine		Chem. Commun.	49	Kano, N	FALSE	FALSE	FALSE	FALSE
5910	10.1039/c3dt32111h	doi.org/10.1039/c3dt32111h	Cross-coupling of alkyl halides with aryl or alkyl Grignards catalyzed by dinuclear Ni(II) complexes containing functionalized tripodal amine-pyrazolyl ligands		Dalton Trans.	49	Zhao, J	FALSE	FALSE	FALSE	FALSE
5911	10.1021/jo301156e	doi.org/10.1021/jo301156e	Palladium-Catalyzed Borylation of Primary Alkyl Bromides		J. Org. Chem.	49	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
5912	10.1016/j.tetlet.2012.03.059	doi.org/10.1016/j.tetlet.2012.03.059	Palladium-catalyzed cross-couplings of functionalized 2-bromobenzofurans for atom-economic synthesis of 2-arylbenzofurans using triarylbismuth reagents		Tetrahedron Lett.	49	Rao, MLN	FALSE	FALSE	FALSE	FALSE
5913	10.1016/j.tetlet.2012.02.081	doi.org/10.1016/j.tetlet.2012.02.081	NiCl2 center dot 6H(2)O as recyclable heterogeneous catalyst for N-arylation of amines and NH-heterocycles under microwave exposure		Tetrahedron Lett.	49	Singh, KN	FALSE	FALSE	FALSE	FALSE
5914	10.1021/jo300209d	doi.org/10.1021/jo300209d	Cross-Coupling of Aryltrimethylammonium Iodides with Arylzinc Reagents Catalyzed by Amido Pincer Nickel Complexes		J. Org. Chem.	49	Wang, ZX	FALSE	FALSE	FALSE	FALSE
5915	10.1021/ja300164d	doi.org/10.1021/ja300164d	Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines		J. Am. Chem. Soc.	49	Bao, M	FALSE	FALSE	FALSE	FALSE
5916	10.1039/c2cc36403d	doi.org/10.1039/c2cc36403d	Copper-catalyzed synthesis of benzocarbazoles via alpha-C-arylation of ketones		Chem. Commun.	49	Fu, H	FALSE	FALSE	FALSE	FALSE
5917	10.1021/ja2077813	doi.org/10.1021/ja2077813	Ate Complexes of Secondary Boronic Esters as Chiral Organometallic-Type Nucleophiles for Asymmetric Synthesis		J. Am. Chem. Soc.	49	Aggarwal, VK	FALSE	FALSE	FALSE	FALSE
5918	10.1021/om1003732	doi.org/10.1021/om1003732	Ni(acac)(2)/Phosphine as an Excellent Precursor of Nickel(0) for Catalytic Systems		Organometallics	49	Ananikov, VP	FALSE	FALSE	FALSE	FALSE
5919	10.1021/ol1003252	doi.org/10.1021/ol1003252	Direct Synthesis of Arylketones by Nickel-Catalyzed Addition of Arylboronic Acids to Nitriles		Org. Lett.	49	Cheng, CH	FALSE	FALSE	FALSE	FALSE
5920	10.1002/anie.200905993	doi.org/10.1002/anie.200905993	Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes		Angew. Chem.-Int. Edit.	49	Ito, H	FALSE	FALSE	FALSE	FALSE
5921	10.1007/s11144-009-0053-x	doi.org/10.1007/s11144-009-0053-x	Leaving group effect in the sulfonyl transfer reactions of aryl benzenesulfonates with Grignard reagents		React. Kinet. Catal. Lett.	49	Erdik, E	FALSE	FALSE	FALSE	FALSE
5922	10.1021/ol9017613	doi.org/10.1021/ol9017613	A Nickel Catalyst for the Addition of Organoboronate Esters to Ketones and Aldehydes		Org. Lett.	49	Itami, K	FALSE	FALSE	FALSE	FALSE
5923	10.1002/anie.200902084	doi.org/10.1002/anie.200902084	Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis		Angew. Chem.-Int. Edit.	49	Mikami, K	FALSE	FALSE	FALSE	FALSE
5924	10.1021/jo8014819	doi.org/10.1021/jo8014819	Suzuki-Miyaura coupling of aryl tosylates catalyzed by an array of indolyl phosphine-palladium catalysts		J. Org. Chem.	49	Kwong, FY	FALSE	FALSE	FALSE	FALSE
5925	10.1021/ol7028096	doi.org/10.1021/ol7028096	Phosphinamide-directed benzylic lithiation. Application to the synthesis of peptide building blocks		Org. Lett.	49	Ortiz, FL	FALSE	FALSE	FALSE	FALSE
5926	10.1055/s-2007-991067	doi.org/10.1055/s-2007-991067	DMF-Catalysed thermal dehydration of aldoximes: A convenient access to functionalized aliphatic and aromatic Nitriles		Synlett	49	Varvounis, G	FALSE	FALSE	FALSE	FALSE
5927	10.1021/ol050393c	doi.org/10.1021/ol050393c	Directed ortho metalation methodology. The N,N-dialkyl aryl O-sulfamate as a new directed metalation as a group and cross-coupling partner for Grignard reagents		Org. Lett.	49	Macklin, TK	FALSE	FALSE	FALSE	FALSE
5928	10.1021/jo048721u	doi.org/10.1021/jo048721u	Nickel-catalyzed addition of alkenylzirconium reagents to bicyclic olefins: A highly regio- and stereoselective ring-opening reaction		J. Org. Chem.	49	Cheng, CH	FALSE	FALSE	FALSE	FALSE
5929	10.1021/ol048816i	doi.org/10.1021/ol048816i	Palladium-catalyzed enantioselective ring opening of oxabicyclic alkenes with organozinc halides		Org. Lett.	49	Li, M	FALSE	FALSE	FALSE	FALSE
5930	10.1021/om034115y	doi.org/10.1021/om034115y	General and selective olefination of aldehydes and ketones catalyzed by a cobalt(II) porphyrin complex		Organometallics	49	Zhang, XP	FALSE	FALSE	FALSE	FALSE
5931	10.1021/ol034251z	doi.org/10.1021/ol034251z	Asymmetric reductive ring-opening of bicyclic olefins catalyzed by palladium and nickel complexes		Org. Lett.	49	Cheng, CH	FALSE	FALSE	FALSE	FALSE
5932	10.1021/la010473z	doi.org/10.1021/la010473z	Novel pyridinium surfactants with unsaturated alkyl chains: Aggregation behavior and interactions with methyl orange in aqueous solution		Langmuir	49	Engberts, JBFN	FALSE	FALSE	FALSE	FALSE
5933	10.1002/jccs.199700033	doi.org/10.1002/jccs.199700033	Synthesis and characterization of oligo(2,7-biphenylenylene-(E)-vinylene)s: Conjugated oligomers containing antiaromatic 12-pi electron units		J. Chin. Chem. Soc.	49	Kwong, CY	FALSE	FALSE	FALSE	FALSE
5934	10.1021/om960799g	doi.org/10.1021/om960799g	Symmetrization of phenylmercuric hydroxides by the action of nickel(II) and cobalt(II) acetylacetonates. Isolation and structural characterization of an intermediate in this reaction		Organometallics	49	Doring, M	FALSE	FALSE	FALSE	FALSE
5935	10.1016/S0040-4020(01)89366-2	doi.org/10.1016/S0040-4020(01)89366-2	PREPARATION OF OPTICALLY-ACTIVE BINAPHTHYLMONOPHOSPHINES (MOPS) CONTAINING VARIOUS FUNCTIONAL-GROUPS		Tetrahedron	49		FALSE	FALSE	FALSE	FALSE
5936	10.1021/om00028a069	doi.org/10.1021/om00028a069	PALLADIUM-CATALYZED GENERATION OF O-ALLYLIC URETHANES AND CARBONATES FROM AMINES/ALCOHOLS, CARBON-DIOXIDE, AND ALLYLIC CHLORIDES		Organometallics	49	MCGHEE, WD	FALSE	FALSE	FALSE	FALSE
5937	10.1021/ar00146a001	doi.org/10.1021/ar00146a001	OLEFIN SYNTHESIS VIA ORGANOMETALLIC COUPLING REACTIONS OF ENOL TRIFLATES		Accounts Chem. Res.	49	SCOTT, WJ	FALSE	FALSE	FALSE	FALSE
5938	10.1021/jo00199a030	doi.org/10.1021/jo00199a030	TRANSFORMATION OF CARBON OXYGEN INTO CARBON CARBON BONDS MEDIATED BY LOW-VALENT NICKEL SPECIES		J. Org. Chem.	49	WENKERT, E	FALSE	FALSE	FALSE	FALSE
5939	10.1039/d1gc04556c	doi.org/10.1039/d1gc04556c	NHC-palladium-catalyzed ionic liquid-accelerated regioselective oxyarylation of alkynes with diaryl ethers		Green Chem.	49	Li, JX	FALSE	FALSE	FALSE	FALSE
5940	10.1039/d1cy02229f	doi.org/10.1039/d1cy02229f	Aromatization as the driving force for single electron transfer towards C-C cross-coupling reactions		Catal. Sci. Technol.	49	Adhikari, D	FALSE	FALSE	FALSE	FALSE
5941	10.1007/s11426-021-1172-x	doi.org/10.1007/s11426-021-1172-x	Catalyst-controlled regiodivergent 1,2-difunctionalization of alkenes with two carbon-based electrophiles		Sci. China-Chem.	49	Yin, GY	FALSE	FALSE	FALSE	FALSE
5942	10.1039/d1cc04656j	doi.org/10.1039/d1cc04656j	Synthesis of 1H-indazoles by an electrochemical radical C-sp2-H/N-H cyclization of arylhydrazones		Chem. Commun.	49	Lei, AW	FALSE	FALSE	FALSE	FALSE
5943	10.1021/acs.orglett.1c03305	doi.org/10.1021/acs.orglett.1c03305	Access to gem-Dibromoenones Enabled by Carbon-Centered Radical Addition to Terminal Alkynes in Water Solution		Org. Lett.	49	Zeng, XH	FALSE	FALSE	FALSE	FALSE
5944	10.1016/j.jorganchem.2021.122145	doi.org/10.1016/j.jorganchem.2021.122145	Synthesis, coordination and catalytic use of phosphinoferrocene ligands bearing 6-phospha-2,4,6-trioxaadamantane P-donor moieties		J. Organomet. Chem.	49	Stepnicka, P	FALSE	FALSE	FALSE	FALSE
5945	10.1021/acs.orglett.1c03073	doi.org/10.1021/acs.orglett.1c03073	Palladium-Catalyzed Cascade Allylative Dicarbofunctionalization of Aryl Phenol-Tethered Alkynes with Allyl Iodides: Synthesis of Skipped Dienes		Org. Lett.	49	Chen, SF	FALSE	FALSE	FALSE	FALSE
5946	10.1021/acs.orglett.1c03210	doi.org/10.1021/acs.orglett.1c03210	Directed Nickel-Catalyzed Diastereoselective Reductive Difunctionalization of Alkenyl Amines		Org. Lett.	49	Wang, C	FALSE	FALSE	FALSE	FALSE
5947	10.1007/s11426-021-1077-4	doi.org/10.1007/s11426-021-1077-4	Catalyst-free, radical-mediated intermolecular 1,2-arylheteroarylation of alkenes by cleaving inert C-C bond		Sci. China-Chem.	49	Zhu, C	FALSE	FALSE	FALSE	FALSE
5948	10.1039/d1cc04038c	doi.org/10.1039/d1cc04038c	Photocatalytic intermolecular carboarylation of alkenes by selective C-O bond cleavage of diarylethers		Chem. Commun.	49	Zhu, C	TRUE	FALSE	FALSE	FALSE
5949	10.1007/s11426-021-1017-0	doi.org/10.1007/s11426-021-1017-0	Highly efficient NHC-iridium-catalyzed beta-methylation of alcohols with methanol at low catalyst loadings		Sci. China-Chem.	49	Tu, T	FALSE	FALSE	FALSE	FALSE
5950	10.1016/j.tetlet.2021.153208	doi.org/10.1016/j.tetlet.2021.153208	Versatile and base-free copper-catalyzed alpha-arylations of aromatic ketones using diaryliodonium salts		Tetrahedron Lett.	49	Taillefer, M	FALSE	FALSE	FALSE	FALSE
5951	10.1002/cjoc.202100034	doi.org/10.1002/cjoc.202100034	Reductive Coupling of Aryl Halides via C-H Activation of Indene		Chin. J. Chem.	49	Zhang, BS; Wang, XC; Quan, ZJ	FALSE	FALSE	FALSE	FALSE
5952	10.1021/acs.orglett.1c00974	doi.org/10.1021/acs.orglett.1c00974	Pd-Catalyzed Enantioselective Dicarbofunctionalization of Alkene to Access Disubstituted Dihydroisoquinolinone		Org. Lett.	49	Guo, H	FALSE	FALSE	FALSE	FALSE
5953	10.1039/d1gc01157j	doi.org/10.1039/d1gc01157j	Visible light-mediated synthesis of amides from carboxylic acids and amine-boranes		Green Chem.	49	Ma, YN; Chen, XN	FALSE	FALSE	FALSE	FALSE
5954	10.1021/jacs.7b06338	doi.org/10.1021/jacs.7b06338	Nickel-Catalyzed Azide-Alkyne Cycloaddition To Access 1,5-Disubstituted 1,2,3-Triazoles in Air and Water		J. Am. Chem. Soc.	49	Hong, SY	FALSE	FALSE	FALSE	FALSE
5955	10.1016/j.jcat.2017.04.034	doi.org/10.1016/j.jcat.2017.04.034	Oriented Au nanoplatelets on graphene promote Suzuki-Miyaura coupling with higher efficiency and different reactivity pattern than supported palladium		J. Catal.	49	Garcia, H	FALSE	FALSE	FALSE	FALSE
5956	10.1016/j.jorganchem.2017.05.013	doi.org/10.1016/j.jorganchem.2017.05.013	Palladium-catalyzed cross-coupling of aryl chlorides with O, N-chelate stabilized diarylborinates		J. Organomet. Chem.	49	Zou, G	FALSE	FALSE	FALSE	FALSE
5957	10.1021/jacs.7b03195	doi.org/10.1021/jacs.7b03195	Nickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes		J. Am. Chem. Soc.	49	Nevado, C	FALSE	FALSE	FALSE	FALSE
5958	10.1021/jacs.7b03448	doi.org/10.1021/jacs.7b03448	Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines		J. Am. Chem. Soc.	49	Doylet, AG	FALSE	FALSE	FALSE	FALSE
5959	10.1021/acs.orglett.6b03430	doi.org/10.1021/acs.orglett.6b03430	Organocatalytic Regioselective Concomitant Thiocyanation and Acylation of Oxiranes Using Aroyl Isothiocyanates		Org. Lett.	49	Patel, BK	FALSE	FALSE	FALSE	FALSE
5960	10.1021/acscatal.6b02927	doi.org/10.1021/acscatal.6b02927	Iron/Zinc-Co-catalyzed Directed Arylation and Alkenylation of C(sp(3))-H Bonds with Organoborates		ACS Catal.	49	Ilies, L; Nakamura, E	FALSE	FALSE	FALSE	FALSE
5961	10.1002/slct.201600978	doi.org/10.1002/slct.201600978	Metal-Free Arylation to Access Distinct Anthracenylphosphonates and Anticancer Activities for These and Allied Phosphonates		ChemistrySelect	49	Chakravarty, M	FALSE	FALSE	FALSE	FALSE
5962	10.1002/chem.201602250	doi.org/10.1002/chem.201602250	Highly Enantioselective Formation of alpha-Allyl-alpha-Arylcyclopentanones via Pd-Catalysed Decarboxylative Asymmetric Allylic Alkylation		Chem.-Eur. J.	49	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
5963	10.1021/acs.joc.5b02849	doi.org/10.1021/acs.joc.5b02849	Bronsted Acid Catalyzed Functionalization of Aromatic Alcohols through Nucleophilic Substitution of Hydroxyl Group		J. Org. Chem.	49	Biswas, S	FALSE	FALSE	FALSE	FALSE
5964	10.1002/adsc.201500358	doi.org/10.1002/adsc.201500358	Catalysis by beta-Cyclodextrin Hydrate - Synthesis of 2,2-Disubstituted 2H-Chromenes in Aqueous Medium		Adv. Synth. Catal.	49	Bhar, S	FALSE	FALSE	FALSE	FALSE
5965	10.1039/c5ra23417d	doi.org/10.1039/c5ra23417d	A one-pot process for the microwave-assisted synthesis of 7-substituted pyrazolo[1,5-a] pyrimidine		RSC Adv.	49	Berteina-Raboin, S	FALSE	FALSE	FALSE	FALSE
5966	10.6023/cjoc202006077	doi.org/10.6023/cjoc202006077	Nucleophilic Etherification of Heteroaryl Alkyl Ethers, Heteroaryl Halides with (Deuterated) Alcohols	Density functional theory calculations were performed to explore the mechanism of Ni-catalyzed cross coupling reactions involving organo-lithium and-zinc reagents through ethereal C-O bond cleavage. Based on this work, together with our previous mechanistic study on etheric Kumada-Tamao reaction, we identify and characterize a novel catalytic cycle for cross-coupling mediated by Ni(0)-ate complex.	Chin. J. Org. Chem.	48	Wang, XQ	FALSE	FALSE	FALSE	FALSE
5967	10.1007/s10562-020-03487-3	doi.org/10.1007/s10562-020-03487-3	Pd/Cu-Free Cobalt-Catalyzed Suzuki and Heck Using Green Bio-Magnetic Hybrid and DFT-Based Theoretical Study	We present an approach to multidimensional high-throughput discovery of catalytic coupling reactions that integrates molecular design with automated analysis and interpretation of mass spectral data. We simultaneously assessed the reactivity of three pools of compounds that shared the same functional groups (halides, boronic acids, alkenes, and alkynes, among other groups) but carried inactive substituents having specifically designed differences in masses. The substituents were chosen such that the products from any class of reaction in multiple reaction sets would have unique differences in masses, thus allowing simultaneous identification of the products of all transformations in a set of reactants. In this way, we easily distinguished the products of new reactions from noise and known couplings. Using this method, we discovered an alkyne hydroallylation and a nickel-catalyzed variant of alkyne diarylation.	Catal. Lett.	48	Hajipour, AR; Khorsandi, Z; Farrokhpour, H	FALSE	FALSE	FALSE	FALSE
5968	10.1021/acs.orglett.0c04084	doi.org/10.1021/acs.orglett.0c04084	Base-Mediated Anti-Markovnikov Hydroamidation of Vinyl Arenes with Arylamides	Alkyl xanthate esters are perhaps best known for their use in deoxygenation chemistry. However, their use in cross-coupling chemistry has not been productive, which is due, in part, to inadequate xanthate activation strategies. Herein, we report the use of O-benzyl xanthate esters, readily derived from alcohols, as radical pronucleophiles in Csp(3)-Csp(2) cross couplings under Ni/photoredox dual catalysis. Xanthate (C-O) cleavage is found to be reliant on photogenerated (sec-butyl) radical for nickel-catalyzed cross-couplings. Mechanistic experiments support independently, and relative rates are carefully orchestrated, such that no activators to form new carbon-centered radicals primed the fact that the key radical components are formed cross reactivity is observed.	Org. Lett.	48	Verma, AK	FALSE	FALSE	FALSE	FALSE
5969	10.1021/acs.orglett.1c04074	doi.org/10.1021/acs.orglett.1c04074	Ni-Catalyzed Synthesis of Thiocarboxylic Acid Derivatives	Chan-Evans-Lam reaction has been served as a powerful cross-coupling reaction in organic synthesis since its discovery in the 1990s owing to the feature of mild reaction conditions, functional group tolerance and open-flask chemistry. Up to now, it has been not only extensively utilized in carbon-heteroatom or carbon-carbon bonds formation, but also successfully applied to synthesize natural products and alkaloids. The new strategies of Chan-Evans-Lam reaction in organic synthesis as well as applications in total synthesis in recent five years are discussesed.	Org. Lett.	48	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
5970	10.1002/ejoc.202001057	doi.org/10.1002/ejoc.202001057	Microfluidic Visible-Light Paterno-Buchi Reaction of Oxindole Enol Ethers	The importance of cyclometalated Ni(II) complex species assumed in catalytic processes related to C-X or C-H activation and functionalisation e.g. in C-C cross coupling reactions stands in stark contrast to the small number of investigations on the synthesis, reactivity, electrochemical and spectroscopic properties of cyclometalated complexes to model catalytically relevant species. This review reveals that the methods to synthesise cyclometalated Ni(II) complexes are rather weakly developed compared with corresponding Pd or Pt derivatives. Furthermore, cyclometalated ligands with their strongly sigma-donating carbanionic functions, their chelate effect and often good pi-accepting properties are also interesting from the general viewpoint of organometallic coordination chemistry and applications beyond catalysis. The recently reported cyclometalated complexes [Ni(Phbpy)(R)] with the carbanionic Phbpy(-) = 6-(phenyl-2-ide)-2,2'-bipyridine ligand (R = Br, CH3, CF3) were described in detail to demonstrate some of the specific properties of such cyclometalated complexes. Further ligand design might allow to synthesise cyclometalated Ni(II) complexes with very interesting properties such as efficient triplet luminescence. What has been achieved in this field with Pt(II) and Pd(II) might be transferred to Ni(II) in the future and some ideas are presented.	Eur. J. Org. Chem.	48	Vega-Penaloza, A; Dell'Amico, L	FALSE	FALSE	FALSE	FALSE
5971	10.2533/chimia.2020.724	doi.org/10.2533/chimia.2020.724	New Catalysis Concepts for Molecular Design and Feedstocks Valorization	Cu-I-ZSM5 and Cu-II-ZSM5 as reusable and heterogeneous nanocatalysts were synthesized and characterized using various techniques. The catalysts have been applied for the practical synthesis of various phenyl aryl/benzyl sulfides via one-pot and odorless processes from the reaction of triphenyltin chloride or phenylboronic acid as phenyl source with different aryl/benzyl halides in the presence of S-8 as sulfur source and KF or KOH as S-8 activator in DMF at 80 degrees C. (C) 2016 Elsevier B.V. All rights reserved.	Chimia	48	Morandi, B	FALSE	FALSE	FALSE	FALSE
5972	10.1016/j.jorganchem.2020.121359	doi.org/10.1016/j.jorganchem.2020.121359	A novel gold(I)-mediated intramolecular transamidation of benzoyl thiourea derivatives to form benzamides via dethiocyanation	We report a palladium-catalyzed C-2 allylation of indoles and subsequent cyclization of the allylated indoles. The electronic effects of chloro and ester groups that can be readily installed at the C-3 position of indoles facilitated a highly efficient C-H allylation at the C-2 position. The resulting 2-allyl-3-chloroindoles were found to be suitable substrates for benzannulation reactions with alkynes and norbornadiene as an acetylene synthon. This approach, utilizing readily available indoles, allyl acetates, and norbornadiene, allows a rapid access to complex carbazoles.	J. Organomet. Chem.	48	Odame, F	FALSE	FALSE	FALSE	FALSE
5973	10.1039/d0sc01229g	doi.org/10.1039/d0sc01229g	Synthesis of thioethers, arenes and arylated benzoxazoles by transformation of the C(aryl)-C bond of aryl alcohols	Nickel-catalyzed cross-coupling reactions are experiencing a dramatic resurgence in recent years given their ability to employ a wider range of electrophiles as well as promote stereospecific or stereoselective transformations. In contrast to the extensively studied Pd catalysts that generally employ diamagnetic intermediates, Ni systems can more easily access various oxidation states including odd-electron configurations. For example, organometallic Ni-III intermediates with aryl and/or alkyl ligands are commonly proposed as the active intermediates in cross-coupling reactions. Herein, we report the first isolated Ni-III-dialkyl complex and show that this species is involved in stoichiometric and catalytic C-C bond formation reactions. Interestingly, the rate of C-C bond formation from a Ni-III center is enhanced in the presence of an oxidant, suggesting the involvement of transient Ni-IV species. Indeed, such a Ni-IV species was observed and characterized spectroscopically for a nickelacycle system. Overall, these studies suggest that both Ni-III and Ni-IV species could play an important role in a range of Ni-catalyzed cross-coupling reactions, especially those involving alkyl substrates.	Chem. Sci.	48	Zhang, ZR; Han, BX	FALSE	FALSE	FALSE	FALSE
5974	10.1039/d0dt01694b	doi.org/10.1039/d0dt01694b	Mapping the properties of bidentate ligands with calculated descriptors (LKB-bid)	An unprecedented formation of benzylic sp(3)C-sp(3)C coupled dibenzylic products has been illustrated. The reactions have been carried out in the presence of three oxidizing reagents, i.e., diacetoxy-iodobenzene (IBDA), N-fluorobenzenesulfonimide (NFSI), and pyridine (Py) using toluene derivatives. (C) 2016 Elsevier Ltd. All rights reserved.	Dalton Trans.	48	Fey, N	FALSE	FALSE	FALSE	FALSE
5975	10.1016/j.tetlet.2020.151885	doi.org/10.1016/j.tetlet.2020.151885	Iron/TEMPO-catalyzed direct aerobic oxidative coupling of methyl-mubstituted N-heteroazaarenes with alcohols		Tetrahedron Lett.	48	Zhang, Y	FALSE	FALSE	FALSE	FALSE
5976	10.1021/jacs.0c02237	doi.org/10.1021/jacs.0c02237	Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons	The Chan-Evans-Lam reaction is a valuable C-N bond forming process. However, aryl boronic acid pinacol (BPin) ester reagents can be difficult coupling partners that often deliver low yields, in particular in reactions with aryl amines. Herein, we report effective reaction conditions for the Chan-Evans-Lam amination of aryl BPin with alkyl and aryl amines. A mixed MeCN/EtOH solvent system was found to enable effective C-N bond formation using aryl amines while EtOH is not required for the coupling of alkyl amines.	J. Am. Chem. Soc.	48	Doyle, AG	FALSE	TRUE	FALSE	FALSE
5977	10.1021/acs.orglett.0c00900	doi.org/10.1021/acs.orglett.0c00900	Intramolecular Palladium-Catalyzed Ring Opening of Oxabenzonorbornadienes with C-1-Tethered Aryl Halides	The imidazolium salts [(N-alkyl-imidazolyl) methyl] benzotriazole hexafluorophosphate (L1H: alkyl = n-C4H9, L2H: alkyl = picoly, L3H: alkyl = 9-anthrylmethyl, L4H: alkyl = 1-naphthylmethyl) have been prepared. Mononuclear N-Heterocyclic carbene silver complexes: L1AgPF6 (1), L2AgPF6 (2), L3AgPF6 (3) were synthesized in DMSO. Transmetalation reactions afford the synthesis of the nickel(II) complex L2Ni(PF6)2 (4). Furthermore, L2H, L3H and L4H were treated with silver oxide in CH3CN to afford other complexes (5, 6 and 7). The complexes 5 and 6 formed 1D and 2D supramolecular chains by Ag-N bond and intermolecular p-p interactions, respectively, which were found that the carbene carbon atoms of NHCs are not coordinated to silver atom. However, in Complex 7, silver atoms selectly bind to nitrogen atoms of benzotriazoles and carbon atoms of imidazoles, which afford the dinuclear Ag metallamacrocycles. Complexes 1-7 were characterized by single crystal X-ray diffraction, NMR spectroscopy, elemental analysis and powder X-ray diffraction. The catalytic activity of NHC-Ni complex 4 for Suzuki-Miyaura cross-coupling was studied. (C) 2016 Elsevier B.V. All rights reserved.	Org. Lett.	48	Tam, W	FALSE	FALSE	FALSE	FALSE
5978	10.1002/ejoc.201901883	doi.org/10.1002/ejoc.201901883	Ruthenium-Catalyzed meta-C-Ar-H Bond Difluoroalkylation of 2-Phenoxypyridines	This Perspective describes general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions. Recent advances including new ligands and palladium catalysts are described. Related Negishi cross-coupling reactions involving Ni-, Cu-, Co-, and Fe-catalyzed cross-couplings are covered. The availability of a range of zinc organometallics combined with new efficient catalysts allows for efficient cross coupling reactions with various organic electrophiles under usually mild conditions.	Eur. J. Org. Chem.	48	Cui, XL	FALSE	FALSE	FALSE	FALSE
5979	10.1021/acs.orglett.0c00442	doi.org/10.1021/acs.orglett.0c00442	Silyl Radical Mediated Cross-Electrophile Coupling of N-Acyl-imides with Alkyl Bromides under Photoredox/Nickel Dual Catalysis	We developed simple and practical N-alkylation reactions of amines and sulfinamides with primary and secondary alcohols by using only catalytic amounts of air as the initiator without adding any external catalysts. This method has advantages of simple conditions, easy operation, and comparatively wider scope of substrates, providing an efficient and green catalyst-free-like alcohol-based dehydrative N-alkylation method. Mechanistic studies revealed that air initiated the reactions by aerobic oxidation of the alcohols to the key initiating aldehydes or ketones in the presence of bases. (C) 2015 Elsevier Ltd. All rights reserved.	Org. Lett.	48	Amgoune, A	TRUE	TRUE	FALSE	FALSE
5980	10.1002/ajoc.202000004	doi.org/10.1002/ajoc.202000004	Nickel-Catalyzed 1,1-Difluoroethylation of (Hetero)aryl Halides with 1,1-Difluoroethyl Chloride (CH3CF2Cl)		Asian J. Org. Chem.	48	Li, XJ	FALSE	FALSE	FALSE	FALSE
5981	10.1039/c9cc08079a	doi.org/10.1039/c9cc08079a	Base-free Ni-catalyzed Suzuki-type cross-coupling reactions of epoxides with boronic acids		Chem. Commun.	48	Lu, XY	FALSE	FALSE	FALSE	FALSE
5982	10.1002/aoc.5379	doi.org/10.1002/aoc.5379	NHC-assisted Ni(II)-catalyzed acceptorless dehydronation of amines and secondary alcohols		Appl. Organomet. Chem.	48	Habibi, A	FALSE	FALSE	FALSE	FALSE
5983	10.1021/jacs.9b11049	doi.org/10.1021/jacs.9b11049	Energy Transfer to Ni-Amine Complexes in Dual Catalytic, Light-Driven C-N Cross-Coupling Reactions		J. Am. Chem. Soc.	48	Miyake, GM	FALSE	FALSE	FALSE	FALSE
5984	10.1016/j.tetlet.2019.151148	doi.org/10.1016/j.tetlet.2019.151148	One-pot reactions of bicyclic zinc enolate generated from Ni-catalyzed reductive cyclization to furnish octahydro-4,7-ethanobenzofuran-9-one derivatives		Tetrahedron Lett.	48	Tsujihara, T; Kawano, T	FALSE	FALSE	FALSE	FALSE
5985	10.1055/s-0037-1611895	doi.org/10.1055/s-0037-1611895	Aryl Ketone Mediated Photoinduced Radical Coupling for the Alkylation- of Benzazoles Employing Saturated Heterocyclic Compounds		Synthesis	48	Kamijo, S	TRUE	FALSE	FALSE	FALSE
5986	10.1016/j.mcat.2019.110462	doi.org/10.1016/j.mcat.2019.110462	A green and recyclable ligand-free copper (I) catalysis system for amination of halonitrobenzenes in aqueous ammonia solution		Mol. Catal.	48	Cheng, HY; Arai, M	FALSE	FALSE	FALSE	FALSE
5987	10.1021/acs.orglett.9b02236	doi.org/10.1021/acs.orglett.9b02236	Transition-Metal-Free ipso-Trifluoromethyithiolation of Lithium Aryl Boronates		Org. Lett.	48	Shen, QL	FALSE	FALSE	FALSE	FALSE
5988	10.3762/bjoc.15.186	doi.org/10.3762/bjoc.15.186	Installation of -SO2F groups onto primary amides		Beilstein J. Org. Chem.	48	Qin, HL	FALSE	FALSE	FALSE	FALSE
5989	10.1021/acs.orglett.9b01782	doi.org/10.1021/acs.orglett.9b01782	Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis		Org. Lett.	48	Zhou, JRS	FALSE	FALSE	FALSE	FALSE
5990	10.1021/acs.oprd.9b00235	doi.org/10.1021/acs.oprd.9b00235	Rapid Amination of Methoxy Pyridines with Aliphatic Amines		Org. Process Res. Dev.	48	Wang, XQ	FALSE	FALSE	FALSE	FALSE
5991	10.1039/c9cc04090k	doi.org/10.1039/c9cc04090k	Controllable chemoselectivity in the coupling of bromoalkynes with alcohols under visible-light irradiation without additives: synthesis of propargyl alcohols and alpha-ketoesters		Chem. Commun.	48	Meng, LG; Wang, L	FALSE	FALSE	FALSE	FALSE
5992	10.1021/acscatal.9b00981	doi.org/10.1021/acscatal.9b00981	Pd-Catalyzed C-N Coupling Reactions Facilitated by Organic Bases: Mechanistic Investigation Leads to Enhanced Reactivity in the Arylation of Weakly Binding Amines		ACS Catal.	48	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
5993	10.1021/jacs.8b11752	doi.org/10.1021/jacs.8b11752	Base-Promoted, Remote C-H Activation at a Cationic (eta(5)-C5Me5)Ir(III) Center Involving Reversible C-C Bond Formation of Bound C5Me5		J. Am. Chem. Soc.	48	Macgregor, SA; Carmona, E	FALSE	FALSE	FALSE	FALSE
5994	10.1021/jacs.8b13403	doi.org/10.1021/jacs.8b13403	Sequential Functionalization of meta-C-H and ipso-C-O Bonds of Phenols		J. Am. Chem. Soc.	48	Xu, XH; Jin, Z	FALSE	FALSE	FALSE	FALSE
5995	10.3866/PKU.WHXB201807071	doi.org/10.3866/PKU.WHXB201807071	Homodinuclear Ferrous Group Metal Complexes and Their Application in Homogeneous Catalysis		Acta Phys.-Chim. Sin.	48	Liu, C	FALSE	FALSE	FALSE	FALSE
5996	10.1002/slct.201802386	doi.org/10.1002/slct.201802386	6H(2)O-Catalyzed One-Pot Synthesis of Amides via Ritter Reaction with Alcohols, Acetic Anhydride and Nitriles		ChemistrySelect	48	Feng, CL	FALSE	FALSE	FALSE	FALSE
5997	10.3390/molecules23102412	doi.org/10.3390/molecules23102412	Palladium-Catalyzed Room Temperature Acylative Cross-Coupling of Activated Amides with Trialkylboranes		Molecules	48	Zou, G	FALSE	FALSE	FALSE	FALSE
5998	10.1021/acs.inorgchem.8b01657	doi.org/10.1021/acs.inorgchem.8b01657	Asymmetric Cationic Phosphines: Synthesis, Coordination Chemistry, and Reactivity		Inorg. Chem.	48	Newman, PD	FALSE	FALSE	FALSE	FALSE
5999	10.1021/acs.joc.7b03193	doi.org/10.1021/acs.joc.7b03193	Radical On Water Addition to the C=N Bond of Hydrazones: A Synthesis of Isoindolinone Derivatives		J. Org. Chem.	48	Jang, DO	FALSE	FALSE	FALSE	FALSE
6000	10.1039/c8ob00911b	doi.org/10.1039/c8ob00911b	Chelation-assisted de-aryloxylative amination of 2-aryloxy quinolines: a new synthetic route to a key fragment of a bioactive PRMT5 inhibitor		Org. Biomol. Chem.	48	Bhadra, S	FALSE	FALSE	FALSE	FALSE
6001	10.1016/j.tetlet.2018.02.008	doi.org/10.1016/j.tetlet.2018.02.008	Direct arylation for the synthesis of 2-arylquinolines from N-methoxyquinoline-1-ium tetrafluoroborate salts and arylboronic acids		Tetrahedron Lett.	48	Zou, DP; Wu, YJ; Wu, YS	FALSE	FALSE	FALSE	FALSE
6002	10.1016/j.tet.2017.10.043	doi.org/10.1016/j.tet.2017.10.043	Base-assisted, copper-catalyzed N-arylation of (benz)imidazoles and amines with diarylborinic acids		Tetrahedron	48	Zou, G	FALSE	FALSE	FALSE	FALSE
6003	10.1002/anie.201708231	doi.org/10.1002/anie.201708231	CsB4O6F: ACongruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units		Angew. Chem.-Int. Edit.	48	Wang, Y; Zhang, FF; Pan, SL	FALSE	FALSE	FALSE	FALSE
6004	10.1002/aoc.3350	doi.org/10.1002/aoc.3350	Sulfonated palladium(II) N-heterocyclic carbene complex immobilized on nano-micro size poly(4-vinylpyridinium chloride) for Suzuki-Miyaura cross-coupling reaction		Appl. Organomet. Chem.	48	Moghadam, M	FALSE	FALSE	FALSE	FALSE
6005	10.1055/s-0034-1380418	doi.org/10.1055/s-0034-1380418	Palladium-Catalyzed Allylic Amination of Homoallylic Alcohols with Amines via Carbon-Carbon Bond Cleavage		Synthesis	48	Kang, Q	FALSE	FALSE	FALSE	FALSE
6006	10.1055/s-0034-1378691	doi.org/10.1055/s-0034-1378691	Rhodium-Catalyzed Addition-Spirocyclization of Arylboronic Esters Containing -Aryl ,-Unsaturated Ester Moiety		Synlett	48	Matsuda, T	FALSE	FALSE	FALSE	FALSE
6007	10.1002/chem.201406457	doi.org/10.1002/chem.201406457	General and Mild Ni-0-Catalyzed alpha-Arylation of Ketones Using Aryl Chlorides		Chem.-Eur. J.	48	Nolan, SP	FALSE	FALSE	FALSE	FALSE
6008	10.1016/j.tetasy.2014.12.010	doi.org/10.1016/j.tetasy.2014.12.010	A new asymmetric synthesis of 2,6-cis-diarylated piperidines		Tetrahedron-Asymmetry	48	Deniau, E	FALSE	FALSE	FALSE	FALSE
6009	10.1039/c5ra17668a	doi.org/10.1039/c5ra17668a	Direct metal-free synthesis of diarylamines from 2-nitropropane via the twofold C-H functionalization of arenes		RSC Adv.	48	Aksenov, AV	FALSE	FALSE	FALSE	FALSE
6010	10.1002/ejoc.201402881	doi.org/10.1002/ejoc.201402881	Suzuki-Miyaura Coupling of Aryl Chlorides with Arylboronic Acids Using the Morpholine-NiCl2 Catalyst System		Eur. J. Org. Chem.	48	Abe, T	FALSE	FALSE	FALSE	FALSE
6011	10.1002/ejoc.201403043	doi.org/10.1002/ejoc.201403043	Bronsted Acid/Lewis Acid Cooperatively Catalyzed Addition of Diazoesters to 2H-Chromene Acetals		Eur. J. Org. Chem.	48	Luan, Y	FALSE	FALSE	FALSE	FALSE
6012	10.1055/s-0034-1378555	doi.org/10.1055/s-0034-1378555	Nickel-Mediated Synthesis of Isoindolinones at Room Temperature		Synthesis	48	Wertjes, WC	FALSE	FALSE	FALSE	FALSE
6013	10.1021/ol501744g	doi.org/10.1021/ol501744g	Bismuth(III)-Catalyzed Dehydrative Etherification and Thioetherification of Phenolic Hydroxy Groups		Org. Lett.	48	Murai, M	FALSE	FALSE	FALSE	FALSE
6014	10.3866/PKU.WHXB201403241	doi.org/10.3866/PKU.WHXB201403241	Reaction Mechanism for the Ni-Catalyzed Reductive Cross-Coupling of Aryl Halides		Acta Phys.-Chim. Sin.	48	Ren, QH	FALSE	FALSE	FALSE	FALSE
6015	10.1021/jo4025573	doi.org/10.1021/jo4025573	BF3 center dot Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds		J. Org. Chem.	48	Yang, HT	FALSE	FALSE	FALSE	FALSE
6016	10.1039/c3cc49859j	doi.org/10.1039/c3cc49859j	Ni-catalyzed asymmetric reductive allylation of aldehydes with allylic carbonates		Chem. Commun.	48	Qian, Q	FALSE	FALSE	FALSE	FALSE
6017	10.1055/s-0033-1338520	doi.org/10.1055/s-0033-1338520	Substituted 2,2 '-Bipyridines by Nickel Catalysis: 4,4 '-Di-tert-butyl-2,2 '-bipyridine		Synthesis	48	Weix, DJ	FALSE	FALSE	FALSE	FALSE
6018	10.1016/j.tetlet.2013.07.071	doi.org/10.1016/j.tetlet.2013.07.071	Palladium-catalyzed hydrodehalogenation of aryl halides using paraformaldehyde as the hydride source: high-throughput screening by paper-based colorimetric iodide sensor		Tetrahedron Lett.	48	Han, MS	FALSE	FALSE	FALSE	FALSE
6019	10.1016/j.tetlet.2013.05.128	doi.org/10.1016/j.tetlet.2013.05.128	Mizoroki-Heck reactions of methyl acrylate in presence of a palladated rasta resin		Tetrahedron Lett.	48	Becht, JM	FALSE	FALSE	FALSE	FALSE
6020	10.1016/j.apcata.2013.04.009	doi.org/10.1016/j.apcata.2013.04.009	Mizoroki-Heck coupling reactions of arenediazonium tetrafluoroborate salts catalyzed by aluminium hydroxide-supported palladium nanoparticles		Appl. Catal. A-Gen.	48	Li, X	FALSE	FALSE	FALSE	FALSE
6021	10.1002/aoc.3000	doi.org/10.1002/aoc.3000	Suzuki-Miyaura coupling reactions of aryl chlorides catalyzed by a new nickel(II) sigma-aryl complex		Appl. Organomet. Chem.	48	Lei, XY	FALSE	FALSE	FALSE	FALSE
6022	10.1021/jo400349r	doi.org/10.1021/jo400349r	Access to 2 '-Substituted Binaphthyl Monoalcohols via Complementary Nickel-Catalyzed Kumada Coupling Reactions under Mild Conditions: Key Role of a P,O Ligand		J. Org. Chem.	48	Slaughter, LM	FALSE	FALSE	FALSE	FALSE
6023	10.1021/ol401105x	doi.org/10.1021/ol401105x	Relay Catalysis by a Multifunctional Cu Catalyst in a Tandem Dehydro-/Dehalogenation Sequence along with N-Arylation		Org. Lett.	48	Xu, P	FALSE	FALSE	FALSE	FALSE
6024	10.1021/op300301u	doi.org/10.1021/op300301u	Development of a Multigram Synthesis of URB937, a Peripherally Restricted FAAH Inhibitor		Org. Process Res. Dev.	48	Fiorelli, C	FALSE	FALSE	FALSE	FALSE
6025	10.1039/c3cc43616k	doi.org/10.1039/c3cc43616k	Fe-promoted cross coupling of homobenzylic methyl ethers with Grignard reagents via sp(3) C-O bond cleavage		Chem. Commun.	48	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
6026	10.1021/jo3008258	doi.org/10.1021/jo3008258	Chemoselective Schmidt Reaction Mediated by Triflic Acid: Selective Synthesis of Nitriles from Aldehydes		J. Org. Chem.	48	Prabhu, KR	FALSE	FALSE	FALSE	FALSE
6027	10.1021/jo300162c	doi.org/10.1021/jo300162c	Friedel-Crafts Amidoalkylation via Thermolysis and Oxidative Photocatalysis		J. Org. Chem.	48	Stephenson, CRJ	TRUE	FALSE	FALSE	FALSE
6028	10.1021/jo202472k	doi.org/10.1021/jo202472k	Carbon-Boron Bond Cross-Coupling Reaction Catalyzed by -PPh2 Containing Palladium-Indolylphosphine Complexes		J. Org. Chem.	48	Kwong, FY	FALSE	FALSE	FALSE	FALSE
6029	10.1021/ol300455e	doi.org/10.1021/ol300455e	Direct Heteroarylation of Tautomerizable Heterocycles into Unsymmetrical and Symmetrical Biheterocycles via Pd/Cu-Catalyzed Phosphonium Coupling		Org. Lett.	48	Van der Eycken, E	FALSE	FALSE	FALSE	FALSE
6030	10.6023/cjoc1106222	doi.org/10.6023/cjoc1106222	Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Azabicyclic Alkenes		Chin. J. Org. Chem.	48	Yang, DQ	FALSE	FALSE	FALSE	FALSE
6031	10.1021/jo2022982	doi.org/10.1021/jo2022982	Nickel Catalyzed Cross-Coupling of Aryl C-O Based Electrophiles with Aryl Neopentylglycolboronates		J. Org. Chem.	48	Percec, V	FALSE	TRUE	FALSE	FALSE
6032	10.1021/ol201248c	doi.org/10.1021/ol201248c	Nickel(0)-Catalyzed Cyclization of N-Benzoylaminals for Isoindolinone Synthesis		Org. Lett.	48	Watson, MP	FALSE	FALSE	FALSE	FALSE
6033	10.1021/ol200402m	doi.org/10.1021/ol200402m	An Enantioselective Synthesis of 2-Aryl Cycloalkanones by Sc-Catalyzed Carbon Insertion		Org. Lett.	48	Kingsbury, JS	FALSE	FALSE	FALSE	FALSE
6034	10.1002/ejoc.201001519	doi.org/10.1002/ejoc.201001519	Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids		Eur. J. Org. Chem.	48	Yang, LM	FALSE	FALSE	FALSE	FALSE
6035	10.1002/anie.201100293	doi.org/10.1002/anie.201100293	Combining Gold(I)/Gold(III) Catalysis and C-H Functionalization: A Formal Intramolecular [3+2] Annulation towards Tricyclic Indolines and Mechanistic Studies		Angew. Chem.-Int. Edit.	48	Zhang, LM	FALSE	FALSE	FALSE	FALSE
6036	10.1055/s-0029-1219166	doi.org/10.1055/s-0029-1219166	Air-Stable Diaminophosphine Sulfides as Preligands for Nickel-Catalyzed Cross-Couplings of Unactivated Fluoro(hetero)arenes		Synlett	48	Ackermann, L	FALSE	FALSE	FALSE	FALSE
6037	10.1039/c0cc03107k	doi.org/10.1039/c0cc03107k	A pyridine-bridged bis-benzimidazolylidene pincer nickel(II) complex: synthesis and practical catalytic application towards Suzuki-Miyaura coupling with less-activated electrophiles		Chem. Commun.	48	Tu, T	FALSE	FALSE	FALSE	FALSE
6038	10.1002/chem.201001022	doi.org/10.1002/chem.201001022	Nickel-Catalyzed Cross-Coupling of Non-Activated or Functionalized Aryl Halides with Aryl Grignard Reagents		Chem.-Eur. J.	48	Wang, ZX	FALSE	FALSE	FALSE	FALSE
6039	10.1002/adsc.200900375	doi.org/10.1002/adsc.200900375	Ruthenium-Catalyzed Oxidative Homo-Coupling of 2-Arylpyridines		Adv. Synth. Catal.	48	Deng, GJ	FALSE	FALSE	FALSE	FALSE
6040	10.1055/s-0029-1216790	doi.org/10.1055/s-0029-1216790	A Novel Synthesis of Aryl Mesylates via One-Pot Demethylation-Mesylation of Aryl Methyl Ethers Using a Mixture of Phosphorus Pentoxide in Methanesulfonic Acid		Synthesis	48	Kaboudin, B	FALSE	FALSE	FALSE	FALSE
6041	10.1021/ol900719z	doi.org/10.1021/ol900719z	Electron-Poor Chiral Diphosphine Ligands: High Performance for Rh-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids at Room Temperature		Org. Lett.	48	Korenaga, T	FALSE	TRUE	FALSE	FALSE
6042	10.1016/j.tetlet.2009.02.064	doi.org/10.1016/j.tetlet.2009.02.064	1-Bromo-2-(diphenylphosphinoyl)ethyne and 1-bromo-2-(p-tolylsulfinyl)ethyne: versatile reagents eventually leading to benzocyclotrimers		Tetrahedron Lett.	48	Fabris, F	FALSE	FALSE	FALSE	FALSE
6043	10.1021/jo070313d	doi.org/10.1021/jo070313d	Nickel-NHC-catalyzed alpha-arylation of acyclic ketones and amination of haloarenes and unexpected preferential N-arylation of 4-aminopropiophenone		J. Org. Chem.	48	Matsubara, K	FALSE	FALSE	FALSE	FALSE
6044	10.1002/ejoc.200700098	doi.org/10.1002/ejoc.200700098	Pd/C: A recyclable catalyst for cyanation of aryl bromides		Eur. J. Org. Chem.	48	Zhu, YZ	FALSE	FALSE	FALSE	FALSE
6045	10.1016/j.molcata.2006.09.039	doi.org/10.1016/j.molcata.2006.09.039	Pyridin- and quinolinylidene nickel carbene complexes as effective catalysts for the Grignard cross-coupling reaction		J. Mol. Catal. A-Chem.	48	Raubenheimer, HG	FALSE	FALSE	FALSE	FALSE
6046	10.1055/s-2006-939682	doi.org/10.1055/s-2006-939682	Synthesis of 4-nitrophenyl sulfones and application in the modified Julia olefination		Synlett	48	Zhu, JP	FALSE	FALSE	FALSE	FALSE
6047	10.1021/jo051394l	doi.org/10.1021/jo051394l	Kumada coupling of aryl and vinyl tosylates under mild conditions		J. Org. Chem.	48	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6048	10.1021/jo0502549	doi.org/10.1021/jo0502549	Microwave-assisted multistep synthesis of functionalized 4-arylquinolin-2(1H)-ones using palladium-catalyzed cross-coupling chemistry		J. Org. Chem.	48	Kappe, CO	FALSE	FALSE	FALSE	FALSE
6049	10.1016/j.tet.2004.12.033	doi.org/10.1016/j.tet.2004.12.033	Synthesis and biological evaluation of (+/-)-cryptotanshinone and its simplified analogues as potent CDC25 inhibitors		Tetrahedron	48	Li, J	FALSE	FALSE	FALSE	FALSE
6050	10.1055/s-2004-834878	doi.org/10.1055/s-2004-834878	Palladium-catalysed coupling reactions: (Z)-vinyl (N,N-diisopropyl)carbamate group as an efficient precursor of a (Z)-vinyl triflate function		Synthesis	48	Betzer, JF	FALSE	FALSE	FALSE	FALSE
6051	10.1016/j.tet.2004.05.018	doi.org/10.1016/j.tet.2004.05.018	Bis(triphenylphosphine)palladium(II)succinimide as a precatalyst for Suzuki cross-coupling-subtle effects exerted by the succinimide ligand		Tetrahedron	48	Fairlamb, IJS	FALSE	FALSE	FALSE	FALSE
6052	10.1055/s-2002-22719	doi.org/10.1055/s-2002-22719	Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homocoupling of aryl halides		Synlett	48	Tanaka, H	FALSE	FALSE	FALSE	FALSE
6053	10.1002/(SICI)1521-3765(20000117)6:2<353::AID-CHEM353>3.0.CO;2-U	doi.org/10.1002/(SICI)1521-3765(20000117)6:2<353::AID-CHEM353>3.0.CO;2-U	Platinum-catalysed allylic alkylation: Reactivity, enantioselectivity, and regioselectivity		Chem.-Eur. J.	48	Williams, JMJ	FALSE	FALSE	FALSE	FALSE
6054	10.1002/jhet.5570360608	doi.org/10.1002/jhet.5570360608	The Directed ortho Metalation - Cross-coupling symbiosis in heteroaromatic synthesis		J. Heterocycl. Chem.	48	Snieckus, V	FALSE	FALSE	FALSE	FALSE
6055	10.1021/om980920e	doi.org/10.1021/om980920e	Palladium(0) olefin complexes and enantioselective allylic amination/alkylation with a P,N-auxiliary		Organometallics	48	Pregosin, PS	FALSE	FALSE	FALSE	FALSE
6056	10.1016/S0032-3861(98)00113-X	doi.org/10.1016/S0032-3861(98)00113-X	Chain conformation and flexibility of thorny rod polymers		Polymer	48	Vaia, RA	FALSE	FALSE	FALSE	FALSE
6057	10.1016/S0040-4020(97)10212-5	doi.org/10.1016/S0040-4020(97)10212-5	Phosphine-directed stereo- & regioselective Ni-catalyzed reactions of Grignard reagents with allylic ethers		Tetrahedron	48	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
6058	10.1016/0022-328X(88)80540-0	doi.org/10.1016/0022-328X(88)80540-0	NICKEL-CATALYZED ALLYLATION OF STABLE ENOLATES BY ALLYLIC ETHERS AND ALLYLIC ALCOHOLS		J. Organomet. Chem.	48	ALVAREZ, E	FALSE	FALSE	FALSE	FALSE
6059	10.1002/asia.202200041	doi.org/10.1002/asia.202200041	SmI2-mediated C-alkylation of Ketones with Alcohols under Microwave Conditions: A Novel Route to Alkylated Ketones		Chem.-Asian J.	48	Nanduri, S	FALSE	FALSE	FALSE	FALSE
6060	10.1021/acs.iecr.1c04508	doi.org/10.1021/acs.iecr.1c04508	Electrocatalytic Reductive Amination and Simultaneous Oxidation of Biomass-Derived 5-Hydroxymethylfurfural		Ind. Eng. Chem. Res.	48	Yan, K	FALSE	TRUE	FALSE	FALSE
6061	10.1039/d1ta07422a	doi.org/10.1039/d1ta07422a	Triazine derivatives as organic phase change materials with inherently low flammability		J. Mater. Chem. A	48	Xu, JW; Zhu, Q	FALSE	FALSE	FALSE	FALSE
6062	10.1021/acs.orglett.1c03387	doi.org/10.1021/acs.orglett.1c03387	Cooperative Lewis Acid Catalysis for the Enantioselective C(sp(3))-H Bond Functionalizations of 2-Alkyl Azaarenes		Org. Lett.	48	Rai, P	FALSE	FALSE	FALSE	FALSE
6063	10.1039/d1ob01944a	doi.org/10.1039/d1ob01944a	Synthesis of a TNF inhibitor, flurbiprofen and an i-Pr analogue in enantioenriched forms by copper-catalyzed propargylic substitution with Grignard reagents		Org. Biomol. Chem.	48	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
6064	10.1021/acs.orglett.1c03298	doi.org/10.1021/acs.orglett.1c03298	Copper-Catalyzed Intermolecular Alkynylation and Allylation of Unactivated C(sp(3))-H Bonds via Hydrogen Atom Transfer		Org. Lett.	48	Liang, L; Niu, HY	FALSE	FALSE	FALSE	FALSE
6065	10.1021/acscatal.1c03113	doi.org/10.1021/acscatal.1c03113	Cu-Catalyzed Cross-Coupling of Nitroarenes with Aryl Boronic Acids to Construct Diarylamines		ACS Catal.	48	Driver, TG	FALSE	FALSE	FALSE	FALSE
6066	10.1039/d1cy01254a	doi.org/10.1039/d1cy01254a	Nickel-catalysed fluoromethylation reactions		Catal. Sci. Technol.	48	Anilkumar, G	FALSE	FALSE	FALSE	FALSE
6067	10.1021/acs.orglett.1c01832	doi.org/10.1021/acs.orglett.1c01832	Access to Branched Allylarenes via Rhodium(III)-Catalyzed C-H Allylation of (Hetero)arenes with 2-Methylidenetrimethylene Carbonate		Org. Lett.	48	Zhang, SS; Zhang, LY	FALSE	FALSE	FALSE	FALSE
6068	10.1021/acs.inorgchem.1c01311	doi.org/10.1021/acs.inorgchem.1c01311	Visible-Light-Driven C-N Bond Formation by a Hexanickel Cluster Substituted Polyoxometalate-Based Photocatalyst		Inorg. Chem.	48	Li, MX; Han, QX	TRUE	FALSE	FALSE	FALSE
6069	10.1021/acs.joc.1c00654	doi.org/10.1021/acs.joc.1c00654	Phosphine-Free Ruthenium Complex-Catalyzed Synthesis of Mono- or Dialkylated Acyl Hydrazides via the Borrowing Hydrogen Strategy		J. Org. Chem.	48	Renaud, JL	FALSE	FALSE	FALSE	FALSE
6070	10.1055/s-0036-1589025	doi.org/10.1055/s-0036-1589025	Regioselective and Transition-Metal-Free Addition of tert-Butyl Magnesium Reagents to Pyridine Derivatives: A Convenient Method for the Synthesis of 3-Substituted 4-tert-Butylpyridine Derivatives		Synthesis	48	Wanner, KT	FALSE	FALSE	FALSE	FALSE
6071	10.1021/jacs.7b06567	doi.org/10.1021/jacs.7b06567	Nickel-Catalyzed beta,gamma-Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Conjunctive Cross-Coupling		J. Am. Chem. Soc.	48	Engle, KM	FALSE	FALSE	FALSE	FALSE
6072	10.1039/c7ob01237c	doi.org/10.1039/c7ob01237c	A Pd-catalyzed, boron ester-mediated, reductive cross-coupling of two aryl halides to synthesize tricyclic biaryls		Org. Biomol. Chem.	48	Wang, XD	FALSE	FALSE	FALSE	FALSE
6073	10.1002/anie.201701552	doi.org/10.1002/anie.201701552	Carbon-Fluorine Reductive Elimination from Nickel(III) Complexes		Angew. Chem.-Int. Edit.	48	Ritter, T	FALSE	FALSE	FALSE	FALSE
6074	10.6023/cjoc201611018	doi.org/10.6023/cjoc201611018	Rapid, Practical and Efficient Synthesis of Enol Phosphates from beta-Keto Esters and Phosphites		Chin. J. Org. Chem.	48	Guo, SM; Cai, H	FALSE	FALSE	FALSE	FALSE
6075	10.1021/acs.orglett.7b00885	doi.org/10.1021/acs.orglett.7b00885	Synthesis of m-Alkylphenols via a Ruthenium-Catalyzed C-H Bond Functionalization of Phenol Derivatives		Org. Lett.	48	Li, G	FALSE	FALSE	FALSE	FALSE
6076	10.1039/c6cc08392g	doi.org/10.1039/c6cc08392g	Palladium-catalysed mono-alpha-alkenylation of ketones with alkenyl tosylates		Chem. Commun.	48	Kwong, FY	FALSE	FALSE	FALSE	FALSE
6077	10.1055/s-0035-1562442	doi.org/10.1055/s-0035-1562442	Nickel-Catalyzed Reductive Cross-Coupling of Benzyl Halides with Aryl Halides		Synthesis	48	Qian, Q; Gong, HG	FALSE	FALSE	FALSE	FALSE
6078	10.1021/jacs.6b02120	doi.org/10.1021/jacs.6b02120	Ni-Catalyzed Enantioselective C-Acylation of alpha-Substituted Lactams		J. Am. Chem. Soc.	48	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
6079	10.1021/acs.orglett.6b01420	doi.org/10.1021/acs.orglett.6b01420	Copper-Catalyzed 8-Aminoquinoline-Directed Selenylation of Arene and Heteroarene C-H Bonds		Org. Lett.	48	Baidya, M	FALSE	FALSE	FALSE	FALSE
6080	10.1007/s12039-016-1111-3	doi.org/10.1007/s12039-016-1111-3	Synthesis, crystal structure, thermal and theoretical studies of bis(N-ethyl-N-phenyldithiocarbamato) Ni(II) and (N-ethyl-N-phenyldithiocarbamato) (isothiocyanato) (triphenylphosphine) Ni(II)		J. Chem. Sci.	48	Onwudiwe, DC	FALSE	FALSE	FALSE	FALSE
6081	10.1021/acscatal.6b00865	doi.org/10.1021/acscatal.6b00865	Palladium- and Nickel-Catalyzed Amination of Aryl Fluorosulfonates		ACS Catal.	48	Hanley, PS	FALSE	FALSE	FALSE	FALSE
6082	10.1038/ncomms11065	doi.org/10.1038/ncomms11065	Iterative protecting group-free cross-coupling leading to chiral multiply arylated structures		Nat. Commun.	48	Crudden, CM	FALSE	FALSE	FALSE	FALSE
6083	10.1021/acs.accounts.5b00428	doi.org/10.1021/acs.accounts.5b00428	Metal-Catalyzed Directed Regio- and Enantioselective Ring-Opening of Epoxides		Accounts Chem. Res.	48	Wang, C; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
6084	10.1039/c6ob00628k	doi.org/10.1039/c6ob00628k	Synthetic transformation of 1,3-diarylisobenzofuran-DMAD adducts: a facile preparation of tri-substituted alpha-naphthols		Org. Biomol. Chem.	48	Mohanakrishnan, AK	FALSE	FALSE	FALSE	FALSE
6085	10.1246/bcsj.20200277	doi.org/10.1246/bcsj.20200277	Chromium-Catalyzed Ligand-Free Amidation of Esters with Anilines	Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as well as in chemical applications such as the catalytic transformation of organic substrates. Despite nickel's importance, the investigation of its compounds in various oxidation states remains uneven and those in the + 1 oxidation are less common than those in the neighboring 0 and + 2 oxidation states. Nonetheless, in recent years, the volume of work on Ni(I) complexes has increased to the extent that they can be no longer regarded as rare. This review focuses on the syntheses and structures of Ni(I) complexes and shows that they display a range of structures, reactivity and magnetic behavior that places them in the forefront of current nickel chemistry research.	Bull. Chem. Soc. Jpn.	47	Zeng, XM	FALSE	FALSE	FALSE	FALSE
6086	10.1021/acs.orglett.1c00245	doi.org/10.1021/acs.orglett.1c00245	Water Mediated Rearrangement of Alkynyl Cyclohexadienones: Access to meta-Alkenylated Phenols	Silyloxyarenes are demonstrated to be a versatile substrate class in a variety of nickel-catalyzed coupling processes. The C(sp(2))-O bond of aryl silyl ethers is directly transformed into C-H or C-Si bonds using Ti(O-i-Pr)(4) or trialkylsilanes as reagents using nickel catalysts with N-heterocyclic carbene (NHC) ligands. Paired with the useful characteristics of silyl protecting groups, these methods enable protected hydroxyls to directly participate in high-value bond-forming steps rather than requiring deprotection-activation strategies that conventional approaches require. These processes of silyloxyarenes provide reactivity complementary to widely used phenol derivatives such as aryl pivalates, carbamates, and methyl ethers, thus enabling a powerful strategy for sequential chemoselective derivatization of complex substrates without protecting group and activating group manipulations.	Org. Lett.	47	Volla, CMR	FALSE	FALSE	FALSE	FALSE
6087	10.1021/acs.joc.0c01720	doi.org/10.1021/acs.joc.0c01720	Visible-Spectrum Solar-Light-Mediated Benzylic C-H Oxygenation Using 9,10-Dibromoanthracene As an Initiator	Although the addition of acid halides across olefins is well-studied, limitations remain with a number of substrate classes that possess leaving groups, polyunsaturation, and acid-sensitive moieties, particularly polyenes prone to cyclization. The process is also challenging when conducted on a small scale, and moreover, methods for the addition of their deuterated counterparts typically require special techniques, especially when control of stoichiometry is required. Herein is described a readily synthesized and handled reagent class which can accomplish the controlled and selective Markovnikov addition of both HCl and HBr across several alkene classes under mild reaction conditions tolerant of diverse functionality. The process is particularly valuable on a laboratory scale, and direct comparisons to other methods are provided. As a result of in-depth mechanistic studies seeking to understand how these novel tools work and the active species behind their efficacy, the means to easily add DCl and DBr using a controlled amount of D2O was discovered along with the critical role of hydrolysis in leading to active hydrohalogenation species.	J. Org. Chem.	47	Szpilman, AM	FALSE	FALSE	FALSE	FALSE
6088	10.1039/d0qo00825g	doi.org/10.1039/d0qo00825g	1,4-Addition of o-naphthoquinone methides induced by silver-catalyzed cyclization of enynones: an approach to unsymmetrical triarylmethanes and benzo[f]chromenes	Cobalt catalysts with electronically enhanced site selectivity have been developed, as evidenced by the high ortho-to-fluorine selectivity observed in the C(sp(2))-H borylation of fluorinated arenes. Both the air-sensitive cobalt(III) dihydride boryl 4-Me-((PNP)-P-iPr)Co(H)(2)BPin (1) and the air-stable cobalt(II) bis(pivalate) 4-Me-((PNP)-P-iPr)Co((O2CBu)-Bu-t)(2) (2) compounds were effective and exhibited broad functional group tolerance across a wide range of fluoroarenes containing electronically diverse functional groups, regardless of the substitution pattern on the arene. The electronically enhanced ortho-to-fluorine selectivity observed with the cobalt catalysts was maintained in the presence of a benzylic dimethylamine and hydrosilanes, overriding the established directing-group effects observed with precious-metal catalysts. The synthetically useful selectivity observed with cobalt was applied to an efficient synthesis of the anti-inflammatory drug flurbiprofen.	Org. Chem. Front.	47	Zhu, SF	FALSE	FALSE	FALSE	FALSE
6089	10.1016/j.polymer.2020.122611	doi.org/10.1016/j.polymer.2020.122611	Simultaneous improvement of mechanical properties and curing temperature of cyanate ester resin by in situ generated modifier polymer having phenolic OH group	The utility of N-heterocyclic carbene ligands in nickel catalyzed Suzuki-Miyaura cross-coupling of aryl esters and carbamates is investigated. Imidazol-2-ylidene bearing 2-adarnarityl groups at its nitrogen atoms generates the most active nickel species among the ligands examined, allowing cross-coupling of a range of aryl carbamates and pivalates. Unlike the previously reported system using tricydohexylphosphine, this protocol is suitable for the cross-coupling using arylboronic esters in addition to arylboronic acids.	Polymer	47	Oyama, T	FALSE	FALSE	FALSE	FALSE
6090	10.1039/d0cc00457j	doi.org/10.1039/d0cc00457j	Nickel-catalyzed intramolecular desymmetrization addition of aryl halides to 1,3-diketones	Hypervalent iodine (111)-intermediated direct oxidative rearrangement of 3-hydroxybut-2-enimidates affording oxazoles under mild conditions has been developed. This protocol provides a new methodology to the synthesis of compounds containing oxazole structure. (C) 2016 Elsevier Ltd. All rights reserved.	Chem. Commun.	47	Xu, T	FALSE	FALSE	FALSE	FALSE
6091	10.1016/j.apcata.2020.117519	doi.org/10.1016/j.apcata.2020.117519	One-pot synthesis of aniline N-alkylation from benzyl alcohol over Cu-Fe catalyst	Benzylic alcohols and ethers are common subunits in bioactive molecules, as well as useful intermediates in organic chemistry. In this Communication, We describe a new approach to the enantioselective synthesis of benzylic ethers through the chiral phosphine-catalyzed coupling of two readily available partners, gamma-aryl substituted alkynoates and alcohols, under mild conditions. In this process, the alkynoate partner undergoes an internal redox reaction. Specifically, the benzylic position is oxidized with good enantioselectivity, and the alkyne is reduced to the alkene.	Appl. Catal. A-Gen.	47	Shimazu, S	FALSE	FALSE	FALSE	FALSE
6092	10.1002/adsc.202000531	doi.org/10.1002/adsc.202000531	Nickel(II)/N-Heterocyclic Carbene Catalyzed Desulfinylative Arylation by C-S Cleavage of Aryl Sulfoxides with Phenylboronic Acids	A novel alpha-arylation of deoxybenzoins with non-prefunctionalized arenes is developed through an iron-catalyzed oxidative dehydrogenative approach. The reaction shows broad substrate scope and functional group tolerance and thus provides efficient access to synthetically useful 1,2,2-triarylethanones. A reasonable mechanism is also proposed.	Adv. Synth. Catal.	47	Chen, WZ	FALSE	FALSE	FALSE	FALSE
6093	10.1055/s-0040-1708007	doi.org/10.1055/s-0040-1708007	Acetic Anhydride-Acetic Acid as a New Dehydrating Agent of Aldoximes for the Preparation of Nitriles: Preparation of 2-Cyanoglycals	Based on transient absorption measurements obtained upon electron-pulse radiolysis of aromatic ethers in N,N-dimethylformamide (DMF), mesolysis processes of the radical anions were investigated. We observed transient absorption spectral change due to the formation of the radical anions in the temperature range (220-295 K). The transient absorption of the radical anions decreased with first-order kinetics along with the growth of the absorption spectrum of the corresponding benzylic radical. Arrhenius analysis of the decay rates of the radical anions provided the activation energies and the frequency factors for the mesolysis. These observations indicated that the mesolysis of the radical anions occurs via a stepwise mechanism, resulting in the formation of benzylic radical and phenolate anion due to the C-O bond cleavage.	Synlett	47	Kinfe, HH	FALSE	FALSE	FALSE	FALSE
6094	10.1039/c9ob02734c	doi.org/10.1039/c9ob02734c	Experimental and theoretical study on the cyclic(alkyl)(amino)carbene-copper catalyzed Friedel-Crafts reaction ofN,N-dialkylanilines with styrenes	The treatment of alpha-chiral secondary alkyl iodides with tBuLi at -100 degrees C leads to the corresponding secondary alkyllithiums with high retention of configuration. Subsequent quenching with various electrophiles such as Bu2S2, DMF, MeOB(OR)(2), or Et2CO provides the desired products with retention of configuration. Furthermore, a transmetalation with CuBr center dot P(OEt)(3) also allows retentive trapping with acid chlorides and ethylene oxide. The quenching of the resulting alkyllithiums with ClCO2Et furnishes stereoselectively syn- and anti-ethyl-2,3-dimethyl ester carboxylates (d.r.>94%). Related esters bearing three adjacent stereo-controlled centers (stereotriads) have also been prepared. This method has been applied to the synthesis of the ant pheromone (+/-)-lasiol in 26% overall yield (four steps) with d.r.=97:3 starting from commercially available cis-2,3-epoxybutane.	Org. Biomol. Chem.	47	Hu, XB; Wu, YT	FALSE	FALSE	FALSE	FALSE
6095	10.1039/d0cc01380c	doi.org/10.1039/d0cc01380c	Metal-free dehydrosulfurization of thioamides to nitriles under visible light	A simple and concise construction of a series of new quinoline-based isoindolin-l-ones, namely N-substituted-2,3-dihydro-1H-pyrrolo[3,4-b]quinolin-1-ones, wherein the benzene moiety of isoindolin-l-one is replaced by a quinoline ring has been achieved via a two-step procedure, involving the one-step synthesis of ethyl 2-chloromethyl-quinoline-3-carboxylate followed by its one-pot reaction with various amines in a refluxing EtOH-AcOH (v/v, 10:1) solvent system. These newly synthesized compounds could be good candidates for the development of lead compounds for use in medicinal chemistry.	Chem. Commun.	47	Liao, SH	FALSE	FALSE	FALSE	FALSE
6096	10.1021/acs.joc.0c00424	doi.org/10.1021/acs.joc.0c00424	Computational Study on Why and How of Nonconventional meta-C-H Arylation of Electron-Rich Arenes via Pd/Quinoxaline-Based Ligand/Norbornene Cooperative Catalysis	Ni-catalyzed cross-coupling reactions have found important applications in organic synthesis. The fundamental characterization of the key steps in cross-coupling reactions, including C-C bond-forming reductive elimination, represents a significant challenge. Bimolecular pathways were invoked in early proposals, but the experimental evidence was limited. We present the preparation of well-defined (pyridine-pyrrolyl)Ni monomethyl and monophenyl complexes that allow the direct observation of bimolecular reductive elimination to generate ethane and biphenyl, respectively. The sp(3)-sp(3) and sp(2)-sp(2) couplings proceed via two distinct pathways. Oxidants promote the fast formation of Ni(III) from (pyridine-pyrrolyl)Ni-methyl, which dimerizes to afford a bimetallic Ni(III) intermediate. Our data are most consistent with the subsequent methyl coupling from the bimetallic Ni(III) to generate ethane as the rate-determining step. In contrast, the formation of biphenyl is facilitated by the coordination of a bidentate donor ligand.	J. Org. Chem.	47	Zhang, DJ	FALSE	TRUE	FALSE	FALSE
6097	10.1016/j.ica.2020.119446	doi.org/10.1016/j.ica.2020.119446	Reactivity of nickel metal precursors towards amido linked N-heterocyclic carbenes and their catalytic studies for cross coupling reactions	A copper-catalyzed asymmetric [3+2] cycloaddition of 3-trimethylsilylpropargylic esters with either -naphthols or electron-rich phenols has been realized and proceeds by a desilylation-activated process. Under the catalysis of Cu(OAc)(2)H2O in combination with a structurally optimized ketimine P,N,N-ligand, a wide range of optically active 1,2-dihydronaphtho[2,1-b]furans or 2,3-dihydrobenzofurans were obtained in good yields and with high enantioselectivities (up to 96% ee). This represents the first desilylation-activated catalytic asymmetric propargylic transformation.	Inorg. Chim. Acta	47	Chauhan, RS	FALSE	FALSE	FALSE	FALSE
6098	10.1055/s-0039-1690807	doi.org/10.1055/s-0039-1690807	Ni-Catalyzed Reductive Difunctionalization of Alkenes	The TiCl4 induced anomerization of selenium glycosides of galacturonic acid derivatives is reported. The reaction was successful for galacturonic acid when various alkyl, alkenyl, alkynyl, saccharide, steroid, and lipid groups were attached to the anomeric Se atom. An increased amount of TiCl4 and/or higher temperature were needed to ensure completion of the reaction in some cases. Yields were higher for reactions carried out at higher dilution. The reaction was applied to the synthesis of Se-based mimics of the potent immunostimulant alpha-GalCer (KRN7000).	Synthesis	47	Kong, WQ	FALSE	FALSE	FALSE	FALSE
6099	10.1021/acs.orglett.0c00532	doi.org/10.1021/acs.orglett.0c00532	Visible-Light-Driven Copper-Catalyzed C(sp(3))-O Cross-Coupling of Benzylic Radicals with Phenols	The secondary phosphine oxides are known to exist in equilibrium between the pentavalent phosphine oxides (SPO) and the trivalent phosphinous acids (PA). This equilibrium can be displaced in favour of the trivalent tautomeric form upon coordination to late transition metals. This tutorial review provides the state of the art of the use of secondary phosphine oxides as pre-ligands in transition metal-catalysed reactions. Using a combination of SPOs and several metals such as Pd, Pt, Ru, Rh and Au, a series of effective and original transformations have been obtained and will be discussed here.	Org. Lett.	47	Chen, JR	FALSE	FALSE	FALSE	FALSE
6100	10.1021/jacs.9b13920	doi.org/10.1021/jacs.9b13920	Dehydrogenative Coupling of Benzylic and Aldehydic C-H Bonds		J. Am. Chem. Soc.	47	Ishida, N; Murakami, M	FALSE	FALSE	FALSE	FALSE
6101	10.1039/c9gc03619a	doi.org/10.1039/c9gc03619a	The salt-free nickel-catalysed alpha-allylation reaction of ketones with allyl alcohol and diallylether		Green Chem.	47	Sauthier, M	FALSE	FALSE	FALSE	FALSE
6102	10.1021/acs.orglett.9b04355	doi.org/10.1021/acs.orglett.9b04355	Asymmetric Total Synthesis and Biological Evaluation of the Natural PDE4 Inhibitor Toddacoumalone		Org. Lett.	47	Xiong, XF	FALSE	FALSE	FALSE	FALSE
6103	10.1021/acs.joc.9b02064	doi.org/10.1021/acs.joc.9b02064	Direct alpha-Benzylation of Methyl Enol Ethers with Activated Benzyl Alcohols: Its Rearrangement and Access to (+/-)-Tetrahydronyasol, Propterol A, and 1,3-Diarylpropane		J. Org. Chem.	47	Khan, FA	FALSE	FALSE	FALSE	FALSE
6104	10.1039/c9dt02819f	doi.org/10.1039/c9dt02819f	Controlling the selectivity and efficiency of the hydrogen borrowing reaction by switching between rhodium and iridium catalysts		Dalton Trans.	47	Pernik, I; Messerle, BA	FALSE	FALSE	FALSE	FALSE
6105	10.1021/acsomega.9b02722	doi.org/10.1021/acsomega.9b02722	Mechanistic Study on Allylic Arylation in Water with Linear Polystyrene-Stabilized Pd and PdO Nanoparticles		ACS Omega	47	Ohtaka, A	FALSE	FALSE	FALSE	FALSE
6106	10.1039/c9ra02394a	doi.org/10.1039/c9ra02394a	Heterogeneous Suzuki-Miyaura coupling of heteroaryl ester via chemoselective C(acyl)-O bond activation		RSC Adv.	47	Bao, YS	FALSE	FALSE	FALSE	FALSE
6107	10.1039/c8ob02448k	doi.org/10.1039/c8ob02448k	Ln(OTf)(3)-catalysed highly regioselective alcoholysis of 2,3-epoxy alcohols		Org. Biomol. Chem.	47	Iwabuchi, Y	FALSE	FALSE	FALSE	FALSE
6108	10.1039/c8qo01258j	doi.org/10.1039/c8qo01258j	Diastereoselective Rh-catalyzed decarboxylative allylation to form quaternary stereocenters using sulfinimine as the directing group		Org. Chem. Front.	47	Yang, G	FALSE	FALSE	FALSE	FALSE
6109	10.1021/acs.joc.8b02150	doi.org/10.1021/acs.joc.8b02150	Copper-Catalyzed Tandem Reactions of 2-Amine-[1,3,5]triazines with Nitriles		J. Org. Chem.	47	Zhang, C	FALSE	FALSE	FALSE	FALSE
6110	10.1021/acs.organomet.8b00451	doi.org/10.1021/acs.organomet.8b00451	Examining the Impact of Heteroaryl Variants of PAd-DalPhos on Nickel-Catalyzed C(sp(2))-N Cross-Couplings		Organometallics	47	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
6111	10.1039/c8gc02073f	doi.org/10.1039/c8gc02073f	Transition metal- and photoredox-catalyzed valorisation of lignin subunits		Green Chem.	47	Konig, B	FALSE	FALSE	FALSE	FALSE
6112	10.1039/c8qo00827b	doi.org/10.1039/c8qo00827b	Enantioselective and regiodivergent allylation of pyrimidines with terminal allenes: an approach to pyrimidine acyclic nucleosides		Org. Chem. Front.	47	Guo, HM	FALSE	FALSE	FALSE	FALSE
6113	10.1038/s41557-018-0110-z	doi.org/10.1038/s41557-018-0110-z	Activation of diverse carbon-heteroatom and carbon-carbon bonds via palladium(II)-catalysed beta-X elimination		Nat. Chem.	47	Engle, KM	FALSE	FALSE	FALSE	FALSE
6114	10.1021/jacs.8b08779	doi.org/10.1021/jacs.8b08779	Ni-Catalyzed Cross-Coupling of Dimethyl Aryl Amines with Arylboronic Esters under Reductive Conditions		J. Am. Chem. Soc.	47	Fang, HY; Shi, ZJ	FALSE	FALSE	FALSE	FALSE
6115	10.1055/s-0037-1609963	doi.org/10.1055/s-0037-1609963	Nickel-Catalyzed Transformation of Aryl 2-Pyridyl Ethers via Cleavage of the Carbon-Oxygen Bond: Synthesis of Mono--arylated Ketones		Synthesis	47	Wang, ZX	FALSE	FALSE	FALSE	FALSE
6116	10.1055/s-0037-1609575	doi.org/10.1055/s-0037-1609575	Palladium-Catalyzed Decarboxylative Benzylation of Acetylides and Enolates		Synthesis	47	Tunge, JA	FALSE	FALSE	FALSE	FALSE
6117	10.1039/c8cc02380h	doi.org/10.1039/c8cc02380h	Expanding the limit of Pd-catalyzed decarboxylative benzylations		Chem. Commun.	47	Lundgren, RJ	FALSE	FALSE	FALSE	FALSE
6118	10.1039/c8cc01937a	doi.org/10.1039/c8cc01937a	The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes		Chem. Commun.	47	Miyake, Y	FALSE	FALSE	FALSE	FALSE
6119	10.1002/anie.201713304	doi.org/10.1002/anie.201713304	Design, Synthesis, and Application of Chiral C-2-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis		Angew. Chem.-Int. Edit.	47	Nagorny, P	FALSE	FALSE	FALSE	FALSE
6120	10.1002/cjoc.201700773	doi.org/10.1002/cjoc.201700773	Construction of Multi-Substituted Benzenes via NHC-Catalyzed Reactions of Carboxylic Esters		Chin. J. Chem.	47	Chi, YR	FALSE	FALSE	FALSE	FALSE
6121	10.1055/s-0036-1591860	doi.org/10.1055/s-0036-1591860	Asymmetric Organocatalytic Friedel-Crafts Hydroxyalkylation of Indoles Using Electrophilic Pyrazole-4,5-diones		Synthesis	47	Enders, D	FALSE	TRUE	FALSE	FALSE
6122	10.1039/c7cc08611c	doi.org/10.1039/c7cc08611c	Synthesis of 2,5-disubstituted oxazoles via cobalt(III)-catalyzed cross-coupling of N-pivaloyloxyamides and alkynes		Chem. Commun.	47	Zhu, J	FALSE	FALSE	FALSE	FALSE
6123	10.1002/aoc.4054	doi.org/10.1002/aoc.4054	Catalytic activity of Fe(II) and Cu(II) PNP pincer complexes for Suzuki coupling reaction		Appl. Organomet. Chem.	47	Bhat, BR	FALSE	FALSE	FALSE	FALSE
6124	10.1246/cl.170907	doi.org/10.1246/cl.170907	Modified Conditions for Copper-catalyzed ipso-Thiolation of Arylboronic Acid Esters with Thiosulfonates		Chem. Lett.	47	Yoshida, S; Hosoya, T	FALSE	FALSE	FALSE	FALSE
6125	10.1021/jacs.7b10537	doi.org/10.1021/jacs.7b10537	Mechanistic Investigations of the Hydrogenolysis of Diary! Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands		J. Am. Chem. Soc.	47	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6126	10.21577/0103-5053.20170051	doi.org/10.21577/0103-5053.20170051	Cellulose Oxidation and the Use of Carboxyl Cellulose Metal Complexes in Heterogeneous Catalytic Systems to Promote Suzuki-Miyaura Coupling and C-O Bond Formation Reaction		J. Braz. Chem. Soc.	47	Suarez, PAZ	FALSE	FALSE	FALSE	FALSE
6127	10.1002/ejoc.201701081	doi.org/10.1002/ejoc.201701081	Nickel-Catalyzed C-S Coupling: Synthesis of Diaryl Sulfides Starting from Phenyldithiocarbamates and Iodobenzenes		Eur. J. Org. Chem.	47	Dong, ZB	FALSE	FALSE	FALSE	FALSE
6128	10.1021/acs.organomet.7b00565	doi.org/10.1021/acs.organomet.7b00565	Pd-PEPPSI: A General Pd-NHC Precatalyst for Suzuki-Miyaura Cross-Coupling of Esters by C-O Cleavage		Organometallics	47	Szostak, M	FALSE	FALSE	FALSE	FALSE
6129	10.1039/c6ob02269c	doi.org/10.1039/c6ob02269c	Ni-catalyzed reductive coupling of alpha-halocarbonyl derivatives with vinyl bromides		Org. Biomol. Chem.	47	Yao, K	FALSE	FALSE	FALSE	FALSE
6130	10.1039/c5ra25752b	doi.org/10.1039/c5ra25752b	Microwave directed metal-free regiodivergent synthesis of 1,2-teraryls and study of supramolecular interactions		RSC Adv.	47	Pratap, R	FALSE	FALSE	FALSE	FALSE
6131	10.1021/acs.orglett.5b03061	doi.org/10.1021/acs.orglett.5b03061	Direct Amidation of N-Boc- and N-Cbz-Protected Amines via Rhodium-Catalyzed Coupling of Arylboroxines and Carbamates		Org. Lett.	47	Zhang, YG	FALSE	FALSE	FALSE	FALSE
6132	10.1002/chem.201502418	doi.org/10.1002/chem.201502418	Solvent-Controlled C2/C5-Regiodivergent Alkenylation of Pyrroles		Chem.-Eur. J.	47	Lin, AJ	FALSE	FALSE	FALSE	FALSE
6133	10.1016/j.tet.2015.08.023	doi.org/10.1016/j.tet.2015.08.023	NiCl2 center dot 6H(2)O: an efficient catalyst precursor for phosphine-free Heck and Sonogashira cross-coupling reactions		Tetrahedron	47	Nowrouzi, N	FALSE	FALSE	FALSE	FALSE
6134	10.1021/jacs.5b03870	doi.org/10.1021/jacs.5b03870	Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis		J. Am. Chem. Soc.	47	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
6135	10.1021/acs.joc.5b00728	doi.org/10.1021/acs.joc.5b00728	Palladium-Catalyzed Alkynylation of Morita-Baylis-Hillman Carbonates with (Triisopropylsilyl)acetylene on Water		J. Org. Chem.	47	Liu, L	FALSE	FALSE	FALSE	FALSE
6136	10.1002/chem.201500560	doi.org/10.1002/chem.201500560	Nickel N-Heterocyclic Carbene Catalyzed CC Bond Formation: A New Route to Aryl Ketones		Chem.-Eur. J.	47	Gu, LJ	FALSE	FALSE	FALSE	FALSE
6137	10.1016/j.tetlet.2015.04.014	doi.org/10.1016/j.tetlet.2015.04.014	Cobalt porphyrin catalyzed hydrodehalogenation of aryl bromides with KOH		Tetrahedron Lett.	47	Chan, KS	FALSE	FALSE	FALSE	FALSE
6138	10.1021/ed500158p	doi.org/10.1021/ed500158p	Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling in a Green Alcohol Solvent for an Undergraduate Organic Chemistry Laboratory		J. Chem. Educ.	47	Garg, NK	FALSE	FALSE	FALSE	FALSE
6139	10.1039/c4gc02522a	doi.org/10.1039/c4gc02522a	A novel green protocol for ligand free Suzuki-Miyaura cross-coupling reactions in WEB at room temperature		Green Chem.	47	Boruah, PR	FALSE	FALSE	FALSE	FALSE
6140	10.1039/c5cc01378j	doi.org/10.1039/c5cc01378j	Nickel-catalyzed borylation of arenes and indoles via C-H bond cleavage		Chem. Commun.	47	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6141	10.1021/ol502682q	doi.org/10.1021/ol502682q	Nickel-Catalyzed Reductive Methylation of Alkyl Halides and Acid Chlorides with Methyl p-Tosylate		Org. Lett.	47	Lin, KH	FALSE	FALSE	FALSE	FALSE
6142	10.1016/j.jorganchem.2014.08.015	doi.org/10.1016/j.jorganchem.2014.08.015	DFT study of the single electron transfer mechanisms in Ni-Catalyzed reductive cross-coupling of aryl bromide and alkyl bromide		J. Organomet. Chem.	47	Ren, QH	FALSE	FALSE	FALSE	FALSE
6143	10.1021/ja5070763	doi.org/10.1021/ja5070763	Iron-Catalyzed C(sp(2))-H Bond Functionalization with Organoboron Compounds		J. Am. Chem. Soc.	47	Ilies, L	FALSE	FALSE	FALSE	FALSE
6144	10.1021/jo501882q	doi.org/10.1021/jo501882q	Organocatalytic Kinetic Resolution of Racemic Secondary Nitroallylic Alcohols Combined with Simultaneous Desymmetrization of Prochiral Cyclic Anhydrides		J. Org. Chem.	47	Chen, KM	FALSE	FALSE	FALSE	FALSE
6145	10.1021/ja503819x	doi.org/10.1021/ja503819x	Beyond Directed ortho Metalation: Ru-Catalyzed C-Ar-O Activation/Cross-Coupling Reaction by Amide Chelation		J. Am. Chem. Soc.	47	Snieckus, V	FALSE	FALSE	FALSE	FALSE
6146	10.1002/anie.201403823	doi.org/10.1002/anie.201403823	Nickel-Catalyzed alpha-Arylation of Ketones with Phenol Derivatives		Angew. Chem.-Int. Edit.	47	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
6147	10.1021/ol500696p	doi.org/10.1021/ol500696p	Copper-Promoted Reductive Coupling of Aryl Iodides with 1,1,1-Trifluoro-2-iodoethane		Org. Lett.	47	Xu, HJ	FALSE	FALSE	FALSE	FALSE
6148	10.1016/j.jfluchem.2014.02.008	doi.org/10.1016/j.jfluchem.2014.02.008	Direct C-H perfluoroalkylation of (di)benzo(hetero)arenes in aqueous media		J. Fluor. Chem.	47	Postigo, P	FALSE	FALSE	FALSE	FALSE
6149	10.1002/ejoc.201402022	doi.org/10.1002/ejoc.201402022	Efficient C-N and C-S Bond Formation Using the Highly Active [Ni(allyl)Cl(IPr*(OMe))] Precatalyst		Eur. J. Org. Chem.	47	Nolan, SP	FALSE	FALSE	FALSE	FALSE
6150	10.1021/jo402259z	doi.org/10.1021/jo402259z	pi-Complexation in Nickel-Catalyzed Cross-Coupling Reactions		J. Org. Chem.	47	Allen, WD	FALSE	FALSE	FALSE	FALSE
6151	10.1021/ol402047d	doi.org/10.1021/ol402047d	Polymer-Supported Siloxane Transfer Agents for Pd-Catalyzed Cross-Coupling Reactions		Org. Lett.	47	Smith, AB	FALSE	FALSE	FALSE	FALSE
6152	10.1002/adsc.201300055	doi.org/10.1002/adsc.201300055	Highly Regioselective Synthesis of Substituted Isoindolinones via Ruthenium-Catalyzed Alkyne Cyclotrimerizations		Adv. Synth. Catal.	47	Sheppard, TD	FALSE	FALSE	FALSE	FALSE
6153	10.1080/00397911.2012.688160	doi.org/10.1080/00397911.2012.688160	RuCl3-Catalyzed Regioselective Diarylation with Aryl Tosylates via C-H Activation		Synth. Commun.	47	Zhao, BL	FALSE	FALSE	FALSE	FALSE
6154	10.1021/ol401483j	doi.org/10.1021/ol401483j	Copper Catalyzed beta-Difluoroacetylation of Dihydropyrans and Glycals by Means of Direct C-H Functionalization		Org. Lett.	47	Poisson, T	FALSE	FALSE	FALSE	FALSE
6155	10.1038/NCHEM.1652	doi.org/10.1038/NCHEM.1652	Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides		Nat. Chem.	47	Li, L	FALSE	FALSE	FALSE	FALSE
6156	10.3390/catal3020486	doi.org/10.3390/catal3020486	Mechanistic Studies for Synthesis of Bis(indolyl)methanes: Pd-Catalyzed C-H Activation of Indole-Carboxylic Acids with Benzyl Alcohols in Water		Catalysts	47	Hikawa, H	FALSE	FALSE	FALSE	FALSE
6157	10.3184/174751913X13662179283121	doi.org/10.3184/174751913X13662179283121	PdCl2(1-methylimidazole)(2)-catalysed Suzuki-Miyaura and Mizoroki-Heck reactions performed in neat water		J. Chem. Res	47	Lu, JM	FALSE	FALSE	FALSE	FALSE
6158	10.1016/j.bmc.2013.01.067	doi.org/10.1016/j.bmc.2013.01.067	Synthesis and evaluation of quinazoline derivatives as phosphodiesterase 7 inhibitors		Bioorg. Med. Chem.	47	Sanchez, AI	FALSE	FALSE	FALSE	FALSE
6159	10.1021/ol400625f	doi.org/10.1021/ol400625f	Highly Enantiospecific Platinum-Catalyzed Cycloisomerizations: Synthesis of Enantioenriched Oxabicycloheptene Derivatives		Org. Lett.	47	Ferreira, EM	FALSE	FALSE	FALSE	FALSE
6160	10.1002/aoc.2970	doi.org/10.1002/aoc.2970	Pd-catalyzed ligand-free desulfitative Heck reaction with arenesulfinic acid salts under air		Appl. Organomet. Chem.	47	Qi, CZ	FALSE	FALSE	FALSE	FALSE
6161	10.1021/ol303567t	doi.org/10.1021/ol303567t	Palladium-Catalyzed Coupling of Polyfluorinated Arenes with Heteroarenes via C-F/C-H Activation		Org. Lett.	47	Lu, L	FALSE	FALSE	FALSE	FALSE
6162	10.1021/ol303130j	doi.org/10.1021/ol303130j	Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Sulfamates and Tosylates		Org. Lett.	47	Cook, SP	FALSE	FALSE	FALSE	FALSE
6163	10.1021/jo302207b	doi.org/10.1021/jo302207b	Synthesis of Diarylmethanes via Metal-Free Reductive Cross-Coupling of Diarylborinic Acids with Tosyl Hydrazones		J. Org. Chem.	47	Zou, G	FALSE	FALSE	FALSE	FALSE
6164	10.1021/jo301050q	doi.org/10.1021/jo301050q	Studies on the Selectivity Between Nickel-Catalyzed 1,2-cis-2-Amino Glycosylation of Hydroxyl Groups of Thioglycoside Acceptors with C(2)-Substituted Benzylidene N-Phenyl Trifluoroacetimidates and Intermolecular Aglycon Transfer of the Sulfide Group		J. Org. Chem.	47	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
6165	10.1002/chem.201103723	doi.org/10.1002/chem.201103723	[NiCl2(dppp)]-Catalyzed Cross-Coupling of Aryl Halides with Dialkyl Phosphite, Diphenylphosphine Oxide, and Diphenylphosphine		Chem.-Eur. J.	47	Han, FS	FALSE	FALSE	FALSE	FALSE
6166	10.1021/ja300326t	doi.org/10.1021/ja300326t	Nickel-Mediated Hydrogenolysis of C-O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?		J. Am. Chem. Soc.	47	Agapie, T	FALSE	FALSE	FALSE	FALSE
6167	10.1039/c2cc36452b	doi.org/10.1039/c2cc36452b	Enantioselective construction of sterically hindered tertiary alpha-aryl ketones: a catalytic asymmetric synthesis of isoflavanones		Chem. Commun.	47	Carroll, MP	FALSE	FALSE	FALSE	FALSE
6168	10.1039/c2ob25425e	doi.org/10.1039/c2ob25425e	Nickel-catalyzed C-H direct amination of benzoxazoles with secondary amines		Org. Biomol. Chem.	47	Li, YM	FALSE	FALSE	FALSE	FALSE
6169	10.1039/c1cc15845g	doi.org/10.1039/c1cc15845g	C-H and C-O oxidative addition in reactions of aryl carboxylates with a PNP pincer-ligated Rh(I) fragment		Chem. Commun.	47	Ozerov, OV	FALSE	FALSE	FALSE	FALSE
6170	10.1055/s-0030-1258528	doi.org/10.1055/s-0030-1258528	Regioselective Gold-Catalyzed Allylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalenes		Synlett	47	Sawama, Y	FALSE	FALSE	FALSE	FALSE
6171	10.1021/om100384q	doi.org/10.1021/om100384q	Iridium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadienes with Amine Nucleophiles		Organometallics	47	Yang, DQ	FALSE	FALSE	FALSE	FALSE
6172	10.1021/ol9022529	doi.org/10.1021/ol9022529	Regioselective Allene Synthesis and Propargylations with Propargyl Diethanolamine Boronates		Org. Lett.	47	Fandrick, DR	FALSE	FALSE	FALSE	FALSE
6173	10.1016/j.tet.2009.06.101	doi.org/10.1016/j.tet.2009.06.101	Aminocarbonylations of alkenyl phosphates, chlorides, bromides, and triflates with Mo(CO)(6) as a solid CO source		Tetrahedron	47	Larhed, M	FALSE	FALSE	FALSE	FALSE
6174	10.1021/ol901217m	doi.org/10.1021/ol901217m	Carbon-Carbon Formation via Ni-Catalyzed Suzuki-Miyaura Coupling through C-CN Bond Cleavage of Aryl Nitrile		Org. Lett.	47	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
6175	10.1002/anie.200900329	doi.org/10.1002/anie.200900329	C(aryl)-O Activation of Aryl Carboxylates in Nickel-Catalyzed Biaryl Syntheses		Angew. Chem.-Int. Edit.	47	Goossen, LJ	FALSE	FALSE	FALSE	FALSE
6176	10.1039/b907362k	doi.org/10.1039/b907362k	Iron-catalyzed thioetherification of thiols with aryl iodides		Chem. Commun.	47	Lee, CF	FALSE	FALSE	FALSE	FALSE
6177	10.1021/ol800977n	doi.org/10.1021/ol800977n	Total synthesis of crisamicin A		Org. Lett.	47	Wang, ZG	FALSE	FALSE	FALSE	FALSE
6178	10.2478/s11532-008-0017-4	doi.org/10.2478/s11532-008-0017-4	Kinetics and mechanism of the C-S coupling reactions of aryl Grignard reagents with aryl arenesulfonates		Cent. Eur. J. Chem	47	Erdik, E	FALSE	FALSE	FALSE	FALSE
6179	10.1016/j.tet.2007.10.007	doi.org/10.1016/j.tet.2007.10.007	Palladium on carbon as a precatalyst for the Suzuki-Miyuara cross-coupling of aryl chlorides		Tetrahedron	47	Simeone, JP	FALSE	FALSE	FALSE	FALSE
6180	10.1055/s-2007-967976	doi.org/10.1055/s-2007-967976	Phosphinamide-directed ortho metalations: Application to the desymmetrization of the diphenylphosphoryl group		Synlett	47	Ortiz, FL	FALSE	FALSE	FALSE	FALSE
6181	10.1016/S1381-1169(03)00447-3	doi.org/10.1016/S1381-1169(03)00447-3	Novel palladium imidazole catalysts for Suzuki cross-coupling reactions		J. Mol. Catal. A-Chem.	47	Welton, T	FALSE	FALSE	FALSE	FALSE
6182	10.1016/S0040-4020(02)00576-8	doi.org/10.1016/S0040-4020(02)00576-8	Palladium-catalyzed biaryl-coupling reaction of arylboronic acids in water using hydrophilic phosphine ligands		Tetrahedron	47	Miyaura, N	FALSE	FALSE	FALSE	FALSE
6183	10.1016/0022-328X(96)06251-1	doi.org/10.1016/0022-328X(96)06251-1	Macrocyclic diphosphine ligands in asymmetric carbon-carbon bond-forming reactions		J. Organomet. Chem.	47	Widhalm, M	FALSE	FALSE	FALSE	FALSE
6184	10.1016/0022-328X(93)83025-Q	doi.org/10.1016/0022-328X(93)83025-Q	AZACARBONYLATIONS AND OXACARBONYLATIONS OF ALLYL PHOSPHATES CATALYZED BY RHODIUM CARBONYL CLUSTER - SELECTIVE SYNTHESIS OF BETA,GAMMA-UNSATURATED AMIDES, ESTERS, AND ACIDS		J. Organomet. Chem.	47		FALSE	FALSE	FALSE	FALSE
6185	10.1021/om00127a020	doi.org/10.1021/om00127a020	FERROCENYL SULFIDES - PREPARATION AND REACTIVITY AS BIDENTATE CHELATING LIGANDS		Organometallics	47		FALSE	FALSE	FALSE	FALSE
6186	10.1039/d2ob00330a	doi.org/10.1039/d2ob00330a	Facile tin(ii)-catalyzed synthesis of N-heterocycles from dicarboxylic acids and arylamines		Org. Biomol. Chem.	47	Kim, HK	FALSE	FALSE	FALSE	FALSE
6187	10.1039/d2cc00461e	doi.org/10.1039/d2cc00461e	Merging strain-release and copper catalysis: the selective ring-opening cross-coupling of 1,2-oxazetidines with boronic acids		Chem. Commun.	47	Hu, XQ	FALSE	FALSE	FALSE	FALSE
6188	10.1021/acs.orglett.1c04359	doi.org/10.1021/acs.orglett.1c04359	Photoredox-Catalyzed Allylic Defluorinative Alkoxycarbonylation of Trifluoromethyl Alkenes through Intermolecular Alkoxycarbonyl Radical Addition		Org. Lett.	47	Fu, MC; Fu, Y	TRUE	FALSE	FALSE	FALSE
6189	10.1039/d1ra08568a	doi.org/10.1039/d1ra08568a	Copper-assisted preparation of pyridinyl sulfonate esters from hydroxypyridines and sodium sulfinates		RSC Adv.	47	Zhu, HB; Fan, QW; Xie, ZB	FALSE	FALSE	FALSE	FALSE
6190	10.1039/d2ob00008c	doi.org/10.1039/d2ob00008c	Copper-catalyzed thiocarbonylation and thiolation of alkyl iodides		Org. Biomol. Chem.	47	Li, YH	FALSE	FALSE	FALSE	FALSE
6191	10.1039/d1cc05417a	doi.org/10.1039/d1cc05417a	Atom-economic amide synthesis by using an iron-substituted polyoxometalate catalyst		Chem. Commun.	47	Yu, H	FALSE	FALSE	FALSE	FALSE
6192	10.1021/acs.orglett.1c03535	doi.org/10.1021/acs.orglett.1c03535	Nickel-Catalyzed Reductive Cross-Coupling of N-Acyl and N-Sulfonyl Benzotriazoles with Diverse Nitro Compounds: Rapid Access to Amides and Sulfonamides		Org. Lett.	47	Li, WF	FALSE	FALSE	FALSE	FALSE
6193	10.1039/d1ra08596d	doi.org/10.1039/d1ra08596d	Reductive C(sp(3))-C(sp(3)) homo-coupling of benzyl or allyl halides with H-2 using a water-soluble electron storage catalyst		RSC Adv.	47	Ogo, S	FALSE	FALSE	FALSE	FALSE
6194	10.1021/jacs.1c07139	doi.org/10.1021/jacs.1c07139	Reactivity of (bi-Oxazoline)organonickel Complexes and Revision of a Catalytic Mechanism		J. Am. Chem. Soc.	47	Diao, TN	FALSE	FALSE	FALSE	FALSE
6195	10.6023/cjoc202103015	doi.org/10.6023/cjoc202103015	Phosphine Oxide-Directed Palladium-Catalyzed Heck-Type Functionalization of o-Carboranes		Chin. J. Org. Chem.	47	Lin, CX; Yuan, YF	FALSE	FALSE	FALSE	FALSE
6196	10.1021/jacs.1c05567	doi.org/10.1021/jacs.1c05567	Synthesis of C-Mannosylated Glycopeptides Enabled by Ni-Catalyzed Photoreductive Cross-Coupling Reactions		J. Am. Chem. Soc.	47	Goddard-Borger, ED	TRUE	FALSE	FALSE	FALSE
6197	10.1021/acs.orglett.1c02114	doi.org/10.1021/acs.orglett.1c02114	Reductive Radical Conjugate Addition of Alkyl Electrophiles Catalyzed by a Cobalt/Iridium Photoredox System		Org. Lett.	47	Escobar, RA; Johannes, JW	TRUE	TRUE	FALSE	FALSE
6198	10.1021/acs.orglett.1c01713	doi.org/10.1021/acs.orglett.1c01713	Switching between X-Pyrano-, X-Furano-, and Anhydro-X-pyranoside Synthesis (X = C, N) under Lewis acid Catalyzed Conditions		Org. Lett.	47	Gagne, MR	FALSE	FALSE	FALSE	FALSE
6199	10.1039/d1cc02617h	doi.org/10.1039/d1cc02617h	Deoxyfluorination of alcohols with aryl fluorosulfonates		Chem. Commun.	47	Hu, JB	FALSE	FALSE	FALSE	FALSE
6200	10.1021/acs.joc.1c00681	doi.org/10.1021/acs.joc.1c00681	Direct para-Selective C-H Amination of Iodobenzenes: Highly Efficient Approach for the Synthesis of Diarylamines		J. Org. Chem.	47	Huang, ZB; Shi, DQ; Zhao, YS	FALSE	FALSE	FALSE	FALSE
6201	10.1039/d1nj01732b	doi.org/10.1039/d1nj01732b	Mechanical metal activation for Ni-catalyzed, Mn-mediated cross-electrophile coupling between aryl and alkyl bromides		New J. Chem.	47	Shi, WJ; Zou, G	FALSE	FALSE	FALSE	FALSE
6202	10.1021/jacs.1c00440	doi.org/10.1021/jacs.1c00440	Redox Activity of Pyridine-Oxazoline Ligands in the Stabilization of Low-Valent Organonickel Radical Complexes		J. Am. Chem. Soc.	47	Diao, TN	FALSE	FALSE	FALSE	FALSE
6203	10.1021/acs.orglett.7b01370	doi.org/10.1021/acs.orglett.7b01370	Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents		Org. Lett.	47	Iwasaki, T; Kambe, N	FALSE	FALSE	FALSE	FALSE
6204	10.1021/acs.orglett.7b00660	doi.org/10.1021/acs.orglett.7b00660	Nickel-(II)-Catalyzed N-Formylation and N-Acylation of Amines		Org. Lett.	47	Jagtap, SV	FALSE	FALSE	FALSE	FALSE
6205	10.1021/acs.orglett.7b00351	doi.org/10.1021/acs.orglett.7b00351	Enantioselective Direct alpha-Arylation of Pyrazol-5-ones with 2-Indolylmethanols via Organo-Metal Cooperative Catalysis		Org. Lett.	47	Shi, F	FALSE	FALSE	FALSE	FALSE
6206	10.1055/s-0035-1560565	doi.org/10.1055/s-0035-1560565	Type 2 Ring-Opening Reactions of Cyclopropanated 7-Oxabenzonorbornadienes with Carboxylic Acid Nucleophiles		Synthesis	47	Tam, W	FALSE	FALSE	FALSE	FALSE
6207	10.1021/acscatal.6b01687	doi.org/10.1021/acscatal.6b01687	Palladium-Catalyzed Synthesis of Alkylated Amines from Aryl Ethers or Phenols		ACS Catal.	47	Beller, M	FALSE	FALSE	FALSE	FALSE
6208	10.1002/adsc.201600378	doi.org/10.1002/adsc.201600378	Cobalt-Catalyzed Reductive Cross-Coupling Between Benzyl Chlorides and Aryl Halides		Adv. Synth. Catal.	47	Auffrant, A; Gosmini, C	FALSE	FALSE	FALSE	FALSE
6209	10.1007/s11164-015-2273-1	doi.org/10.1007/s11164-015-2273-1	A facile synthesis of novel pyrrolo[3,4-b]quinolin-1-one derivatives		Res. Chem. Intermed.	47	Li, Y	FALSE	FALSE	FALSE	FALSE
6210	10.1002/bkcs.10706	doi.org/10.1002/bkcs.10706	Copper-catalyzed Decarboxylative Hydroboration: Synthesis of Vinyl Boronic Esters		Bull. Korean Chem. Soc.	47	Na, K; Lee, S	FALSE	FALSE	FALSE	FALSE
6211	10.1055/a-1406-0484	doi.org/10.1055/a-1406-0484	Titanium: A Unique Metal for Radical Dehydroxylative Functionalization of Alcohols	Cu2O/N,N'-bis(thiophen-2-ylmethyl)-oxalamide is established to be an effective catalyst system for Goldberg amidation with inferior reactive (hetero)aryl chlorides, which have not been efficiently documented by Cu-catalysis to date. The reaction is well liberalized toward a variety of functionalized (hetero)aryl chlorides and a wide range of aromatic and aliphatic primary amides in good to excellent yields. Furthermore, the arylation of lactams and oxazolidinones is achieved. The present catalytic system also accomplished an intramolecular cross-coupling product.	Synlett	46	Shu, XZ	FALSE	FALSE	FALSE	FALSE
6212	10.1016/j.tet.2021.131955	doi.org/10.1016/j.tet.2021.131955	A general approach to C-Acyl glycosides via palladium/copper Co-catalyzed coupling reaction of glycosyl carbothioates and arylboronic acids	An efficient approach to construct chiral 1,1-disubstituted ethane derivatives is presented. This strategy relies on the formation of the key dearomatizative vinylogous iminium ion species through protonation of the formal trienamine intermediates between 2-(3-vinylbenzofuran-2-yl)ethan-1-ones and a chiral primary amine. An array of nucleophiles, including 4-hydroxycoumarins, indoles, etc., have been effectively assembled at the benzylic site, delivering the expected 1,1-disubstituted ethane products in moderate to excellent enantioselectivity.	Tetrahedron	46	Li, Q; Ye, XS	FALSE	FALSE	FALSE	FALSE
6213	10.1039/d0ra10739e	doi.org/10.1039/d0ra10739e	Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt	Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO2) bond by palladium, which represents an unprecedented elemental reaction.	RSC Adv.	46	Komeyama, K	FALSE	FALSE	FALSE	FALSE
6214	10.1038/s41467-020-20644-9	doi.org/10.1038/s41467-020-20644-9	Collective synthesis of acetylenic pharmaceuticals via enantioselective Nickel/Lewis acid-catalyzed propargylic alkylation	Metal ions can have beneficial effects on photoinduced electron transfer. Merging such metal-ion-coupled electron transfer (MCET) with consecutive photoinduced electron transfer (conPET) enables the one-electron reduction of chlorobenzene with blue light in the presence of diisopropylethylamine as an electron donor. The presence of the metal ions extends the substrate scope of the photoredox catalysis to extreme reduction potentials (beyond - 3 V vs. SCE).	Nat. Commun.	46	Guo, C	FALSE	FALSE	FALSE	FALSE
6215	10.1016/j.jorganchem.2020.121373	doi.org/10.1016/j.jorganchem.2020.121373	Terpenylammonium salts in Pd(dba)(2) catalyzed allylic alkylation and in stoichiometric reactions with dibenzylideneacetone-palladium (0) complexes	We describe herein a new strategy for the chemoselective synthesis of amides by using a metal catalyzed hydroxy-directed reaction. A hydroxy group located at the beta-position of an ester group promoted the activation of a carbonyl group with a tantalum alkoxide catalyst followed by amidation reactions, leading to a wide variety of beta-hydroxyamides with excellent chemeselectivity. The chemoselective amidation strategy can be extended to the catalytic synthesis of dipeptide derivatives, which remains challenging research subjects in modern organic synthesis.	J. Organomet. Chem.	46	Petrushkina, EA	FALSE	FALSE	FALSE	FALSE
6216	10.1039/d0sc01462a	doi.org/10.1039/d0sc01462a	Palladium-catalyzed synthesis of beta-hydroxy compounds via a strained 6,4-palladacycle from directed C-H activation of anilines and C-O insertion of epoxides	A user-friendly, nickel-catalyzed reductive amidation of unactivated primary, secondary, and tertiary alkyl bromides with isocyanates is described. This catalytic strategy offers an efficient synthesis of a wide range of aliphatic amides under mild conditions and with an excellent chemoselectivity profile while avoiding the use of stoichiometric and sensitive organometallic reagents.	Chem. Sci.	46	Lee, YR	FALSE	FALSE	FALSE	FALSE
6217	10.1038/s41929-020-0462-9	doi.org/10.1038/s41929-020-0462-9	Asymmetric O-propargylation of secondary aliphatic alcohols	The aggregates of the PBI derivative 1 in combination with Benedict's reagent have been used for the first time as reactors for facile preparation of Cu2O NPs at room temperature. During this process the aldehyde groups of the aggregates of derivative 1 are oxidized to carboxylate groups which act as stabilizers for Cu2O NPs to generate the supramolecular ensemble 2:Cu2O. Interestingly, the in situ generated supra molecular ensemble (2:Cu2O) of Cu2O NPs and aggregates of oxidized species 2 exhibited excellent photocatalytic efficiency in the Suzuki-Miyaura and Suzuki type cross-coupling reactions under mild and eco-friendly conditions.	Nat. Catal.	46	Niu, DW	FALSE	FALSE	FALSE	FALSE
6218	10.1021/jacs.0c02355	doi.org/10.1021/jacs.0c02355	On the Nature of C(sp(3))-C(sp(2)) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides	Facile synthetic procedures to synthesize a series of difficult-to-obtain mercaptoalkylferrocenes, namely, Fc(CH2)(n)SH, where n = 1 (1), 2 (2), 3 (3), or 4 (4) and Fc = Fe(eta(5)-C5H5)(eta(5)-C5H4), are reported. Dimerization of 1-4 to the corresponding disulfides 19-22 was observed in air. Dimer 20 (Z = 2) crystallized in the triclinic space group P (1) over bar. Dimers 20-22 could be reduced back to the original Fc(CH2)(n)SH derivatives with LiAlH4 in refluxing tetrahydrofuran. Density functional theory (DFT) calculations showed that the highest occupied molecular orbital of 1-4 lies exclusively on the ferrocenyl group implying that the electrochemical oxidation observed at ca. -15 < E-pa < 76 mV versus FcH/FcH(+) involves exclusively an Fe(II) to Fe(III) process. Further DFT calculations showed this one-electron oxidation is followed by proton loss on the thiol group to generate a radical, Fc(CH2)(n)S-center dot, with spin density mainly located on the sulfur. Rapid exothermic dimerization leads to the observed dimers, Fc(CH2)-S-S-(CH2)(n)Fc. Reduction of the ferrocenium groups on the dimer occurs at potentials that still showed the ferrocenyl group Delta E = E-pa,E-monomer - E-pc,E-dimer <= 78 mV, indicating that the redox properties of the ferrocenyl group on the mercaptans are very similar to those of the dimer. H-1 NMR measurements showed that, like ferrocenyl oxidation, the resonance position of the sulfhydryl proton, SE, and others, are dependent on -(CH2)(n)- chain length. Self-assembled monolayers (SAMs) on gold were generated to investigate the electrochemical behavior of 1-4 in the absence of diffusion. Under these conditions, Delta E approached 0 mV for the longer chain derivatives at slow scan rates. The surface-bound ferrocenyl group of the metal-thioether, Fc(CH2)(n) -S-Au, is oxidized at approximately equal potentials as the equivalent CH2Cl2-dissolved ferrocenyl species 1-4. Surface coverage by the SAMs is dependent on alkyl chain length with the largest coverage obtained for 4, while the rate of heterogeneous electron transfer between SAM substrate and electrode was the fastest for the shortest chain derivative, Fc-CH2-S-Au.	J. Am. Chem. Soc.	46	Gutierrez, O	TRUE	FALSE	FALSE	FALSE
6219	10.1039/d0cc00767f	doi.org/10.1039/d0cc00767f	Enantioconvergent alkylation of ketones with racemic secondary alcohols via hydrogen borrowing catalysis	Cyclic sulfamidates undergo borylation under copper-catalyzed conditions using B(2)pin(2) to give enantiomerically (and diasteromerically) defined (aminoalkyl) boronic esters. External iodide is essential, but the intermediacy of simple alkyl iodides has been excluded; N-sulfated intermediates are key in the borylation sequence. Based on stereochemical studies and trapping experiments, the involvement of carbon-centered radicals under these copper-catalyzed conditions appears likely.	Chem. Commun.	46	Donohoe, TJ	FALSE	FALSE	FALSE	FALSE
6220	10.1021/jacs.0c00245	doi.org/10.1021/jacs.0c00245	Polarity-Reversal Strategy for the Functionalization of Electrophilic Strained Molecules via Light-Driven Cobalt Catalysis	A rhodium complex catalyzed the conversion of the C-O bond of heteroaryl aryl ethers to the C-F bond. The reaction of (4-chloro-phenylthio)pentafluorobenzene with heteroaryl aryl ethers provided heteroaryl fluorides and heteroaryl (4-chlorophenylthio)tetrafluorophenyl ethers; this involved the cleavage of a single heteroaryl C-O bond under equilibrium conditions. The reaction of heteroaryl aryl ethers with 2-fluorobenzothiazole in which two heteroaryl and aryl C-O bonds were cleaved provided heteroaryl fluorides and aryl fluorides. The reactions were applicable to five-membered and six-membered heteroaryl aryl ethers and also to diaryl ethers possessing one or two electron-withdrawing groups.	J. Am. Chem. Soc.	46	Gryko, D	FALSE	TRUE	FALSE	FALSE
6221	10.1016/j.chempr.2019.12.026	doi.org/10.1016/j.chempr.2019.12.026	Broadly Applicable Directed Catalytic Reductive Difunctionalization of Alkenyl Carbonyl Compounds	High step- and atom-economy are the endlessly pursued in organic and pharmaceutical syntheses. Herein, a new method for directly coupling benzyl/allyl alcohols with malonates via a palladium catalyzed Tsuji-Trost type reaction was developed. The reaction was carried out in an organic carbonate solvent which would activate alcohols in situ, replacing the traditional pre-synthesized carbonates. The new process demonstrated high efficiency, high selectivity and high generality. A wide variety of mono-substituted and bis-substituted malonates were selectively produced under different conditions, and this method represents a more step-and atom-economical and environmentally benign synthetic protocol.	Chem	46	Koh, MJ	FALSE	FALSE	FALSE	FALSE
6222	10.1039/c9cc07840a	doi.org/10.1039/c9cc07840a	Nickel-catalyzed electrochemical reductive decarboxylative coupling of N-hydroxyphthalimide esters with quinoxalinones		Chem. Commun.	46	Xu, K; Zeng, CC	FALSE	FALSE	FALSE	FALSE
6223	10.1039/c9sc03570b	doi.org/10.1039/c9sc03570b	New sulfuryl fluoride-derived alkylating reagents for the 1,1-dihydrofluoroalkylation of thiols		Chem. Sci.	46	Sammis, GM	FALSE	FALSE	FALSE	FALSE
6224	10.1002/chem.201903625	doi.org/10.1002/chem.201903625	Development of N-Phosphinomethyl-Substituted NHC-Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO2		Chem.-Eur. J.	46	Iwasawa, N	FALSE	FALSE	FALSE	FALSE
6225	10.1039/c9gc01993f	doi.org/10.1039/c9gc01993f	An N-heterocyclic carbene-functionalised covalent organic framework with atomically dispersed palladium for coupling reactions under mild conditions		Green Chem.	46	Wang, JW	FALSE	FALSE	FALSE	FALSE
6226	10.3390/catal9100840	doi.org/10.3390/catal9100840	Eucalyptol as a Bio-Based Solvent for Buchwald-Hartwig Reaction on O,S,N-Heterocycles		Catalysts	46	Berteina-Raboin, S	FALSE	FALSE	FALSE	FALSE
6227	10.1002/anie.201908336	doi.org/10.1002/anie.201908336	Suzuki-Miyaura Coupling of (Hetero)Aryl Sulfones: Complementary Reactivity Enables Iterative Polyaryl Synthesis		Angew. Chem.-Int. Edit.	46	Moran, J	FALSE	FALSE	FALSE	FALSE
6228	10.1021/jacs.9b07514	doi.org/10.1021/jacs.9b07514	Catalytic Enantioselective-House Meinwald Rearrangement: Efficient Construction of All-Carbon Quaternary Stereocenters		J. Am. Chem. Soc.	46	Sun, JW	FALSE	FALSE	FALSE	FALSE
6229	10.1039/c9cc04634h	doi.org/10.1039/c9cc04634h	Sterically hindered N-heterocyclic carbene/palladium(ii) catalyzed Suzuki-Miyaura coupling of nitrobenzenes		Chem. Commun.	46	Chen, WZ	FALSE	FALSE	FALSE	FALSE
6230	10.1007/s11051-019-4533-2	doi.org/10.1007/s11051-019-4533-2	Ni nanoparticles on polyaromatic hyperbranched polymer support as a mild, tunable, and sustainable catalyst for catalytic transfer hydrogenation		J. Nanopart. Res.	46	Pal, M; Rajadurai, M	FALSE	FALSE	FALSE	FALSE
6231	10.1039/c9dt00819e	doi.org/10.1039/c9dt00819e	Cyclotrimerization of alkynes catalyzed by a self-supported cyclic tri-nuclear nickel(0) complex with alpha-diimine ligands		Dalton Trans.	46	Yang, XJ	FALSE	FALSE	FALSE	FALSE
6232	10.1021/acs.orglett.9b00174	doi.org/10.1021/acs.orglett.9b00174	Ni-Catalyzed Reductive C-O Bond Arylation of Oxalates Derived from alpha-Hydroxy Esters with Aryl Halides		Org. Lett.	46	Gong, HG	FALSE	FALSE	FALSE	FALSE
6233	10.1016/j.molstruc.2018.09.034	doi.org/10.1016/j.molstruc.2018.09.034	Structure, spectroscopic properties and catalytic activity for epoxide ring-opening of nickel methylxanthate		J. Mol. Struct.	46	Kumar, G	FALSE	FALSE	FALSE	FALSE
6234	10.1016/j.jcat.2018.12.011	doi.org/10.1016/j.jcat.2018.12.011	Visible-light-initiated one-pot clean synthesis of nitrone from nitrobenzene and benzyl alcohol over CdS photocatalyst		J. Catal.	46	Zhao, ZK	FALSE	FALSE	FALSE	FALSE
6235	10.1016/j.tet.2018.10.033	doi.org/10.1016/j.tet.2018.10.033	Development of a reductive Hosomi-Sakurai reaction		Tetrahedron	46	Maulide, N	FALSE	FALSE	FALSE	FALSE
6236	10.1038/s41467-018-07198-7	doi.org/10.1038/s41467-018-07198-7	N2H4 as traceless mediator for homo- and cross-aryl coupling		Nat. Commun.	46	Li, CJ	FALSE	FALSE	FALSE	FALSE
6237	10.1039/c8cy01200h	doi.org/10.1039/c8cy01200h	Efficient nickel-catalysed N-alkylation of amines with alcohols		Catal. Sci. Technol.	46	Barta, K	FALSE	FALSE	FALSE	FALSE
6238	10.1021/acs.orglett.8b02980	doi.org/10.1021/acs.orglett.8b02980	Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of lodoalkanes		Org. Lett.	46	Chen, JC; Fan, BM	FALSE	FALSE	FALSE	FALSE
6239	10.6023/cjoc201804012	doi.org/10.6023/cjoc201804012	Synthesis of Quinoline Derivatives Containing Lactone Structure Promoted by Radical Cation Salt		Chin. J. Org. Chem.	46	Yuan, Y; Jia, XD	FALSE	FALSE	FALSE	FALSE
6240	10.1021/acs.orglett.8b02264	doi.org/10.1021/acs.orglett.8b02264	Nickel-Catalyzed Aromatic Cross-Coupling Difluoromethylation of Grignard Reagents with Difluoroiodomethane		Org. Lett.	46	Mikami, K	FALSE	FALSE	FALSE	FALSE
6241	10.1021/acs.joc.8b01109	doi.org/10.1021/acs.joc.8b01109	Cobalt-Rhodium Heterobimetallic Nanoparticle-Catalyzed N-Alkylation of Amines with Alcohols to Secondary and Tertiary Amines		J. Org. Chem.	46	Chung, YK	FALSE	FALSE	FALSE	FALSE
6242	10.1021/acscatal.8b02187	doi.org/10.1021/acscatal.8b02187	Stable, Well-Defined Nickel(0) Catalysts for Catalytic C-C and C-N Bond Formation		ACS Catal.	46	Montgomery, J	FALSE	FALSE	FALSE	FALSE
6243	10.1021/acs.orglett.8b01117	doi.org/10.1021/acs.orglett.8b01117	Stereocontrolled Synthesis of 2-Deoxy-C-glycopyranosyl Arenes Using Glycals and Aromatic Amines		Org. Lett.	46	Xiong, DC; Ye, XS	FALSE	FALSE	FALSE	FALSE
6244	10.1021/acs.orglett.8b00496	doi.org/10.1021/acs.orglett.8b00496	Catalyst-Free and Solvent-Controlled Reductive Coupling of Activated Vinyl Triflates with Chlorotrimethylsilane by Magnesium Metal and Its Synthetic Application		Org. Lett.	46	Maekawa, H	FALSE	FALSE	FALSE	FALSE
6245	10.1039/c7cc08181b	doi.org/10.1039/c7cc08181b	Nickel-catalyzed amination of aryl fluorides with primary amines		Chem. Commun.	46	Iwai, T; Sawamura, M	FALSE	FALSE	FALSE	FALSE
6246	10.1002/ajoc.201700503	doi.org/10.1002/ajoc.201700503	Copper-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Alkenes: Method Development, Applications and Mechanistic Studies		Asian J. Org. Chem.	46	Meng, FK	FALSE	FALSE	FALSE	FALSE
6247	10.1055/s-0036-1590838	doi.org/10.1055/s-0036-1590838	Ether Synthesis through Reductive Cross-Coupling of Ketones with Alcohols Using Me2SiHCl as both Reductant and Lewis Acid		Synlett	46	Morandi, B	FALSE	FALSE	FALSE	FALSE
6248	10.1002/anie.201707309	doi.org/10.1002/anie.201707309	Transition-Metal-Free Ring-Opening Silylation of Indoles and Benzofurans with (Diphenyl-tert-butylsilyl) lithium		Angew. Chem.-Int. Edit.	46	Studer, A	FALSE	FALSE	FALSE	FALSE
6249	10.1021/acs.orglett.7b02821	doi.org/10.1021/acs.orglett.7b02821	Dichotomy of Atom-Economical Hydrogen-Free Reductive Amidation vs Exhaustive Reductive Amination		Org. Lett.	46	Chusov, D	FALSE	FALSE	FALSE	FALSE
6250	10.1039/c5cc10464e	doi.org/10.1039/c5cc10464e	Aerobic oxidative cyclization of benzamides via meta-selective C-H tert-alkylation: rapid entry to 7-alkylated isoquinolinediones		Chem. Commun.	46	Tang, S	FALSE	FALSE	FALSE	FALSE
6251	10.1039/c5cc10005d	doi.org/10.1039/c5cc10005d	Nickel-catalyzed synthesis of (E)-olefins from benzylic alcohol derivatives and arylacetonitriles via C-O activation		Chem. Commun.	46	Chen, TQ	FALSE	FALSE	FALSE	FALSE
6252	10.1021/acs.orglett.5b02458	doi.org/10.1021/acs.orglett.5b02458	Palladium-Catalyzed C-H Arylation of (Benzo)oxazoles or (Benzo)thiazoles with Aryltrimethylammonium Triflates		Org. Lett.	46	Wang, ZX	FALSE	FALSE	FALSE	FALSE
6253	10.1021/acs.organomet.5b00561	doi.org/10.1021/acs.organomet.5b00561	Intermolecular Hydroalkoxylation of Terminal Alkynes Catalyzed by a Dipyrrinato Rhodium(I) Complex with Unusual Selectivity		Organometallics	46	Messerle, BA	FALSE	FALSE	FALSE	FALSE
6254	10.1055/s-0034-1378867	doi.org/10.1055/s-0034-1378867	Chromatography-Free and Eco-Friendly Synthesis of Aryl Tosylates and Mesylates		Synthesis	46	Lei, XY	FALSE	FALSE	FALSE	FALSE
6255	10.1246/cl.150359	doi.org/10.1246/cl.150359	Straightforward Synthesis of HOMSi Reagents via sp(2) C-H Silylation		Chem. Lett.	46	Minami, Y	FALSE	FALSE	FALSE	FALSE
6256	10.1007/s11426-015-5360-7	doi.org/10.1007/s11426-015-5360-7	Mechanism of Pd-catalyzed selective C-H activation of aliphatic amines via four-membered-ring cyclometallation pathway		Sci. China-Chem.	46	Fu, Y	FALSE	FALSE	FALSE	FALSE
6257	10.1021/acs.accounts.5b00242	doi.org/10.1021/acs.accounts.5b00242	Preparation and Synthetic Value of pi-Bond-Rich Branched Hydrocarbons		Accounts Chem. Res.	46	Sherburn, MS	FALSE	FALSE	FALSE	FALSE
6258	10.1021/jacs.5b04548	doi.org/10.1021/jacs.5b04548	Highly Active Nickel Catalysts for C-H Functionalization Identified through Analysis of Off-Cycle Intermediates		J. Am. Chem. Soc.	46	Zimmerman, PM	FALSE	FALSE	FALSE	FALSE
6259	10.1002/aoc.3297	doi.org/10.1002/aoc.3297	Immobilization of palladium(II)-containing bis(imidazolium) ligand on ion-exchange resins: efficient and reusable catalysts for CC coupling reactions		Appl. Organomet. Chem.	46	Moghadam, M	FALSE	FALSE	FALSE	FALSE
6260	10.1021/jacs.5b00004	doi.org/10.1021/jacs.5b00004	Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols		J. Am. Chem. Soc.	46	Nishibayashi, Y	FALSE	FALSE	FALSE	FALSE
6261	10.1021/ol503748t	doi.org/10.1021/ol503748t	Palladium-Catalyzed Regio- and Stereoselective gamma-Arylation of Tertiary Allylic Amines: Identification of Potent Adenylyl Cyclase Inhibitors		Org. Lett.	46	Watts, VJ	FALSE	FALSE	FALSE	FALSE
6262	10.1016/j.tetlet.2014.12.016	doi.org/10.1016/j.tetlet.2014.12.016	A facile one-pot synthesis of 2-(2-pyridyl)quinolines via Povarov reaction		Tetrahedron Lett.	46	Barbosa, LCA	FALSE	FALSE	FALSE	FALSE
6263	10.1002/anie.201408739	doi.org/10.1002/anie.201408739	Reversing the Stereoselectivity of a Palladium-Catalyzed O-Glycosylation through an Inner-Sphere or Outer-Sphere Pathway		Angew. Chem.-Int. Edit.	46	Liu, XW	FALSE	FALSE	FALSE	FALSE
6264	10.1039/C5CC00196J	doi.org/10.1039/C5CC00196J	The electronic effects of ligands on metal-coordination geometry: a key role in the visual discrimination of dimethylaminopyridine and its application towards chemo-switch		Chem. Commun.	46	Li, ZM	FALSE	FALSE	FALSE	FALSE
6265	10.1039/c5sc00305a	doi.org/10.1039/c5sc00305a	Nickel-catalyzed reductive cleavage of aryl alkyl ethers to arenes in absence of external reductant		Chem. Sci.	46	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6266	10.1016/j.tet.2014.07.059	doi.org/10.1016/j.tet.2014.07.059	Pd-catalyzed chemo-selective mono-arylations and bis-arylations of functionalized 4-chlorocoumarins with triarylbismuths as threefold arylating reagents		Tetrahedron	46	Rao, MLN	FALSE	FALSE	FALSE	FALSE
6267	10.1021/cs400641k	doi.org/10.1021/cs400641k	Mechanistic Studies of Gold and Palladium Cooperative Dual-Catalytic Cross-Coupling Systems		ACS Catal.	46	Blum, SA	FALSE	FALSE	FALSE	FALSE
6268	10.6023/cjoc201307035	doi.org/10.6023/cjoc201307035	Progress of Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions of Phenol Derivatives		Chin. J. Org. Chem.	46	Chen, GJ	FALSE	FALSE	FALSE	FALSE
6269	10.1002/ejoc.201301372	doi.org/10.1002/ejoc.201301372	Iron-Catalyzed pi-Activated C-O Ether Bond Cleavage with C-C and C-H Bond Formation		Eur. J. Org. Chem.	46	Fan, XH	FALSE	FALSE	FALSE	FALSE
6270	10.1039/c4sc00423j	doi.org/10.1039/c4sc00423j	Catalytic enantioselective synthesis of 2-aryl-chromenes		Chem. Sci.	46	Scheidt, KA	FALSE	FALSE	FALSE	FALSE
6271	10.1007/s11243-013-9759-8	doi.org/10.1007/s11243-013-9759-8	Synthesis, catalytic activity and phytotoxicity of a supported nickel(II) Schiff base complex		Transit. Met. Chem.	46	Islam, SM	FALSE	FALSE	FALSE	FALSE
6272	10.1002/cctc.201300177	doi.org/10.1002/cctc.201300177	The Ru-Catalyzed Alkylative Dearyloxylation of L-type 2-Aryloxyethanols		ChemCatChem	46	Plietker, B	FALSE	FALSE	FALSE	FALSE
6273	10.1016/j.tet.2013.05.030	doi.org/10.1016/j.tet.2013.05.030	Controlled mono- and double-Heck reaction catalyzed by a dicarbene dipalladium complex		Tetrahedron	46	Cao, CS	FALSE	FALSE	FALSE	FALSE
6274	10.1016/j.jfluchem.2013.02.025	doi.org/10.1016/j.jfluchem.2013.02.025	Synthesis of polyfluorinated aryl ethers via ligand-free palladium-catalyzed C-F activation of pentafluorobenzene		J. Fluor. Chem.	46	Weng, ZG	FALSE	FALSE	FALSE	FALSE
6275	10.1039/c3ra42972e	doi.org/10.1039/c3ra42972e	Palladium-catalyzed carbonylative coupling of (chloromethyl)arenes with terminal arylalkynes to produce 1,4-diaryl-3-butyn-2-ones		RSC Adv.	46	Feng, XJ	FALSE	FALSE	FALSE	FALSE
6276	10.1021/ol301615z	doi.org/10.1021/ol301615z	Synthesis of Aryl Ethers via a Sulfonyl Transfer Reaction		Org. Lett.	46	Sutton, SC	FALSE	FALSE	FALSE	FALSE
6277	10.1016/j.tet.2012.04.005	doi.org/10.1016/j.tet.2012.04.005	Ni(0)/NHC-catalyzed amination of N-heteroaryl methyl ethers through the cleavage of carbon-oxygen bonds		Tetrahedron	46	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6278	10.1021/ol300570f	doi.org/10.1021/ol300570f	The Regioselective Switch for Amino-NHC Mediated C-H Activation of Benzimidazole via Ni-Al Synergistic Catalysis		Org. Lett.	46	Ong, TG	FALSE	FALSE	FALSE	FALSE
6279	10.1021/jo202339v	doi.org/10.1021/jo202339v	Copper-Catalyzed Petasis-Type Reaction: A General Route to alpha-Substituted Amides From Imines, Acid Chlorides, and Organoboron Reagents		J. Org. Chem.	46	Arndtsen, BA	FALSE	FALSE	FALSE	FALSE
6280	10.1021/ja211389g	doi.org/10.1021/ja211389g	Copper-Mediated Sequential Cyanation of Aryl C-B and Arene C-H Bonds Using Ammonium Iodide and DMF		J. Am. Chem. Soc.	46	Chang, S	FALSE	FALSE	FALSE	FALSE
6281	10.1002/anie.201108350	doi.org/10.1002/anie.201108350	Nickel-Catalyzed Heck-Type Alkenylation of Secondary and Tertiary a-Carbonyl Alkyl Bromides		Angew. Chem.-Int. Edit.	46	Lei, AW	FALSE	FALSE	FALSE	FALSE
6282	10.1021/jo2015246	doi.org/10.1021/jo2015246	Cross-Coupling of Mesylated Phenol Derivatives with Potassium Cyclopropyltrifluoroborate		J. Org. Chem.	46	Molander, GA	FALSE	FALSE	FALSE	FALSE
6283	10.1016/j.tet.2011.05.057	doi.org/10.1016/j.tet.2011.05.057	Well-defined NHC-Pd(II)-Im (NHC=N-heterocyclic carbene; Im=1-methylimidazole) complexes catalyzed amination of aryl chlorides		Tetrahedron	46	Shao, LX	FALSE	FALSE	FALSE	FALSE
6284	10.1021/jo2007169	doi.org/10.1021/jo2007169	Retention of Regiochemistry and Chirality in the Ruthenium Catalyzed Allylic Alkylation of Disubstituted Allylic Esters		J. Org. Chem.	46	Kawatsura, M	FALSE	FALSE	FALSE	FALSE
6285	10.1016/j.tetlet.2011.04.078	doi.org/10.1016/j.tetlet.2011.04.078	S-arylation of mercaptobenzimidazoles using Cu(I) catalysts-experimental and theoretical observations		Tetrahedron Lett.	46	Sambandam, A	FALSE	FALSE	FALSE	FALSE
6286	10.1021/ol200128y	doi.org/10.1021/ol200128y	Cross-Coupling of Mesylated Phenol Derivatives with Potassium Ammonio- and Amidomethyltrifluoroborates		Org. Lett.	46	Molander, GA	FALSE	FALSE	FALSE	FALSE
6287	10.1021/ja110215b	doi.org/10.1021/ja110215b	Enantioselective Total Syntheses of (-)-Taiwaniaquinone H and (-)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric alpha-Arylation		J. Am. Chem. Soc.	46	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6288	10.1016/j.bmcl.2010.12.020	doi.org/10.1016/j.bmcl.2010.12.020	Synthesis and preliminary evaluation of curcumin analogues as cytotoxic agents		Bioorg. Med. Chem. Lett.	46	Zhang, ZR	FALSE	FALSE	FALSE	FALSE
6289	10.1002/anie.201104390	doi.org/10.1002/anie.201104390	Cobalt-Catalyzed Reductive Allylation of Alkyl Halides with Allylic Acetates or Carbonates		Angew. Chem.-Int. Edit.	46	Gosmini, C	FALSE	FALSE	FALSE	FALSE
6290	10.1021/ol102106v	doi.org/10.1021/ol102106v	Highly Regioselective Ruthenium-Catalyzed Allylic Alkylations of Chelated Enolates		Org. Lett.	46	Kazmaier, U	FALSE	FALSE	FALSE	FALSE
6291	10.1055/s-0029-1218837	doi.org/10.1055/s-0029-1218837	Synthesis of New Dicationic Azolium Salts and Their Application as NHC Precursors in Suzuki-Miyaura Coupling		Synthesis	46	Liebscher, J	FALSE	FALSE	FALSE	FALSE
6292	10.1016/j.tetlet.2009.12.036	doi.org/10.1016/j.tetlet.2009.12.036	Regio- and stereoselective microwave-assisted synthesis of 5-alkyl-4-alkenyl-4-phenyl-1,3-oxazolidin-2-ones		Tetrahedron Lett.	46	Ariza, X	FALSE	FALSE	FALSE	FALSE
6293	10.1039/b922280d	doi.org/10.1039/b922280d	Cross-couplings between benzylic and aryl halides on water: synthesis of diarylmethanes		Chem. Commun.	46	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
6294	10.1002/anie.201003585	doi.org/10.1002/anie.201003585	Enantioselective and Z/E-Selective Conjugate Addition of alpha-Substituted Cyanoacetates to Acetylenic Esters Catalyzed by Bifunctional Ruthenium and Iridium Complexes		Angew. Chem.-Int. Edit.	46	Ikariya, T	FALSE	FALSE	FALSE	FALSE
6295	10.1002/anie.200905332	doi.org/10.1002/anie.200905332	Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes		Angew. Chem.-Int. Edit.	46	List, B	FALSE	FALSE	FALSE	FALSE
6296	10.1055/s-0029-1218012	doi.org/10.1055/s-0029-1218012	Direct Cobalt-Catalyzed Cross-Coupling Between Aryl and Alkyl Halides		Synlett	46	Jacobi von Wangelin, A	FALSE	FALSE	FALSE	FALSE
6297	10.1021/ol802608r	doi.org/10.1021/ol802608r	Palladium-Catalyzed Sequential Arylation and Allylic Alkylation of Highly Functionalized Ketones: A Concise Synthesis of Mesembrine		Org. Lett.	46	Zhang, HB	FALSE	FALSE	FALSE	FALSE
6298	10.1021/ol0713842	doi.org/10.1021/ol0713842	Iridium-catalyzed asymmetric allylic substitution with aryl zinc reagents		Org. Lett.	46	Alexakis, A	FALSE	FALSE	FALSE	FALSE
6299	10.1002/adsc.200700038	doi.org/10.1002/adsc.200700038	Palladium-catalyzed regioselective cross-coupling reactions of 3-Bromo-4-tosyloxyquinolin-2(1H)-one with arylboronic acids. A facile and convenient route to 3,4-disubstituted Quinolin-2(1H)-ones		Adv. Synth. Catal.	46	Wu, J	FALSE	FALSE	FALSE	FALSE
6300	10.1002/chem.200600993	doi.org/10.1002/chem.200600993	Highly enantioselective epoxidation of 2-methylnaphthoquinone (vitamin K-3) mediated by new Cinchona alkaloid phase-transfer catalysts		Chem.-Eur. J.	46	Berkessel, A	FALSE	FALSE	FALSE	FALSE
6301	10.1055/s-2006-948173	doi.org/10.1055/s-2006-948173	Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst		Synlett	46	Moreno-Manas, M	FALSE	FALSE	FALSE	FALSE
6302	10.1016/j.jcat.2006.06.020	doi.org/10.1016/j.jcat.2006.06.020	Ni ion-containing ionic liquid salt and Ni ion-containing immobilized ionic liquid on silica: Application to Suzuki cross-coupling reactions between chloroarenes and arylboronic acids		J. Catal.	46	Sasaki, T	FALSE	FALSE	FALSE	FALSE
6303	10.1021/jo060299p	doi.org/10.1021/jo060299p	Pd-catalyzed ring opening of oxa- and azabicyclic alkenes with aryl and vinyl halides: Efficient entry to 2-substituted 1,2-dihydro-1-naphthols and 2-substituted 1-naphthols		J. Org. Chem.	46	Martin, SF	FALSE	FALSE	FALSE	FALSE
6304	10.1055/s-2005-917111	doi.org/10.1055/s-2005-917111	An expeditious approach to quinolines via Friedlander synthesis catalyzed by FeCl3 or Mg(ClO4)(2)		Synlett	46	Wu, J	FALSE	FALSE	FALSE	FALSE
6305	10.1016/j.tet.2005.02.019	doi.org/10.1016/j.tet.2005.02.019	A convenient palladium catalyzed synthesis of symmetric biaryls, biheterocycles and biaryl chiral diamides		Tetrahedron	46	Goswami, S	FALSE	FALSE	FALSE	FALSE
6306	10.1002/ejoc.200400258	doi.org/10.1002/ejoc.200400258	Pd/C-catalyzed transfer reduction of aryl chlorides with sodium formate in water		Eur. J. Org. Chem.	46	Arcadi, A	FALSE	FALSE	FALSE	FALSE
6307	10.1021/op034104g	doi.org/10.1021/op034104g	Development of a scalable process for CI-1034, an endothelin antagonist		Org. Process Res. Dev.	46	Jacks, TE	FALSE	FALSE	FALSE	FALSE
6308	10.1021/ol036027f	doi.org/10.1021/ol036027f	Cyclization of oxa-bicyclic alkenes with beta-iodo-(Z)-propenoates and o-iodobenzoate catalyzed by nickel complexes: A simple efficient route to annulated coumarins		Org. Lett.	46	Cheng, CH	FALSE	FALSE	FALSE	FALSE
6309	10.1016/S0022-328X(03)00458-3	doi.org/10.1016/S0022-328X(03)00458-3	The synthesis and X-ray structure of trans-NiCl2(1,3-bis (2,6-diisopropylphenyl)imidazol-2-ylidene)(2); attempts to polymerize olefins utilizing a nickel(II) complex of a sterically demanding N-heterocyclic carbene		J. Organomet. Chem.	46	Baird, MC	FALSE	FALSE	FALSE	FALSE
6310	10.1002/aoc.398	doi.org/10.1002/aoc.398	Alumina-supported nickel catalyst for liquid-phase reactions: an expedient and efficient heterogeneous catalyst for hydrogenation reactions		Appl. Organomet. Chem.	46	Fort, Y	FALSE	FALSE	FALSE	FALSE
6311	10.1021/ol025731d	doi.org/10.1021/ol025731d	Highly stereoselective ring-opening addition of terminal acetylenes to bicyclic olefins catalyzed by nickel complexes		Org. Lett.	46	Cheng, CH	FALSE	FALSE	FALSE	FALSE
6312	10.1021/ol025673w	doi.org/10.1021/ol025673w	Facile Pd-catalyzed cross-coupling of 2 '-deoxyguanosine O-6-arylsulfonates with arylboronic acids		Org. Lett.	46	Lakshman, MK	FALSE	FALSE	FALSE	FALSE
6313	10.1021/ol0069204	doi.org/10.1021/ol0069204	Synthesis of biaryls via unusual deoxygenative dimerization of 1,4-epoxy-1,4-dihydroarenes catalyzed by palladium complexes		Org. Lett.	46	Cheng, CH	FALSE	FALSE	FALSE	FALSE
6314	10.1021/ol990885n	doi.org/10.1021/ol990885n	A general method for convergent synthesis of polycyclic ethers based on Suzuki cross-coupling: Concise synthesis of the ABCD ring system of ciguatoxin		Org. Lett.	46	Sasaki, M	FALSE	FALSE	FALSE	FALSE
6315	10.1002/(SICI)1521-3773(19991102)38:21<3163::AID-ANIE3163>3.0.CO;2-#	doi.org/10.1002/(SICI)1521-3773(19991102)38:21<3163::AID-ANIE3163>3.0.CO;2-#	Discovery of novel catalysts for allylic alkylation with a visual colorimetric assay		Angew. Chem.-Int. Edit.	46	Lavastre, O	FALSE	FALSE	FALSE	FALSE
6316	10.1016/S0040-4020(97)10217-4	doi.org/10.1016/S0040-4020(97)10217-4	Ni-catalyzed nucleophilic conjugate additions of Grignard and organozincate reagents to substituted 4-vinylpyridines. General synthesis of phosphodiesterase IV inhibitors.		Tetrahedron	46	Houpis, IN	FALSE	FALSE	FALSE	FALSE
6317	10.1021/jo960058p	doi.org/10.1021/jo960058p	Palladium-catalyzed cross-coupling of arenediazonium salts with arylboronic acids		J. Org. Chem.	46	Sengupta, S	FALSE	FALSE	FALSE	FALSE
6318	10.1039/p19920003419	doi.org/10.1039/p19920003419	A STEREOSELECTIVE SYNTHESIS OF TRISUBSTITUTED ALKENES .1. NICKEL-CATALYZED COUPLING OF GRIGNARD-REAGENTS WITH 5-ALKYL-2,3-DIHYDROFURANS		J. Chem. Soc.-Perkin Trans. 1	46	KOCIENSKI, PJ	FALSE	FALSE	FALSE	FALSE
6319	10.1246/nikkashi.1987.197	doi.org/10.1246/nikkashi.1987.197	ULTRASOUNDS IN SYNTHETIC REACTIONS .4. ULLMANN-TYPE COUPLING REACTION OF ARYL TRIFLUOROMETHANESULFONATES CATALYZED BY LOW VALENT NICKEL-COMPLEXES		Nippon Kagaku Kaishi	46	INOUE, Y	FALSE	FALSE	FALSE	FALSE
6320	10.1246/bcsj.57.108	doi.org/10.1246/bcsj.57.108	CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANO-ALUMINUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(O) CATALYST		Bull. Chem. Soc. Jpn.	46		FALSE	FALSE	FALSE	FALSE
6321	10.1038/s41467-022-28005-4	doi.org/10.1038/s41467-022-28005-4	Merging enzymes with chemocatalysis for amide bond synthesis		Nat. Commun.	46	Micklefield, J	FALSE	FALSE	FALSE	FALSE
6322	10.1021/acscatal.1c05144	doi.org/10.1021/acscatal.1c05144	Synergistic Catalyst-Mediator Pairings for Electroreductive Cross-Electrophile Coupling Reactions		ACS Catal.	46	Sevov, CS	FALSE	TRUE	FALSE	FALSE
6323	10.1016/j.mcat.2021.111953	doi.org/10.1016/j.mcat.2021.111953	Efficient base-free hydrodehalogenation of organic halides catalyzed by a well-defined diphosphine-ruthenium(II) complex		Mol. Catal.	46	Wang, Z; Liu, QB	FALSE	FALSE	FALSE	FALSE
6324	10.1039/d1ob01874d	doi.org/10.1039/d1ob01874d	Nickel-catalyzed cross-electrophile coupling of aryl chlorides with allylic alcohols		Org. Biomol. Chem.	46	Wang, ZX	FALSE	FALSE	FALSE	FALSE
6325	10.1021/acs.orglett.1c03187	doi.org/10.1021/acs.orglett.1c03187	Total Syntheses of Vicinal Dichloride Monoterpenes Enabled by Aza-Bellus-Claisen Rearrangement		Org. Lett.	46	Huang, J; Yang, Z	FALSE	FALSE	FALSE	FALSE
6326	10.1021/acs.orglett.1c03343	doi.org/10.1021/acs.orglett.1c03343	Visible-Light- and PPh3-Mediated Direct C-N Coupling of Nitroarenes and Boronic Acids at Ambient Temperature		Org. Lett.	46	Jana, R	FALSE	FALSE	FALSE	FALSE
6327	10.1021/acs.orglett.1c03060	doi.org/10.1021/acs.orglett.1c03060	Synthesis of 2-(2-Pyridyl)-2H-azirines via Metal-Free C-C Cross-Coupling of Bromoazirines with 2-Stannylpyridines		Org. Lett.	46	Novikov, MS	FALSE	FALSE	FALSE	FALSE
6328	10.1021/acs.orglett.1c02412	doi.org/10.1021/acs.orglett.1c02412	Diarylborinic Acid-Catalyzed Regioselective Ring Openings of Epoxy Alcohols with Pyrazoles, Imidazoles, Triazoles, and Other Nitrogen Heterocycles		Org. Lett.	46	Taylor, MS	FALSE	FALSE	FALSE	FALSE
6329	10.1039/d1nj02243a	doi.org/10.1039/d1nj02243a	Base-controlled chemoselectivity: direct coupling of alcohols and acetonitriles to synthesise alpha-alkylated arylacetonitriles or acetamides		New J. Chem.	46	Xia, AB; Xu, DQ	FALSE	FALSE	FALSE	FALSE
6330	10.1039/d1gc01902c	doi.org/10.1039/d1gc01902c	A highly stable all-in-one photocatalyst for aryl etherification: the Ni-II embedded covalent organic framework		Green Chem.	46	Xiang, YG; Chen, H	FALSE	FALSE	FALSE	FALSE
6331	10.1002/anie.202107492	doi.org/10.1002/anie.202107492	Nickel-Catalyzed, Reductive C(sp(3))-Si Cross-Coupling of alpha-Cyano Alkyl Electrophiles and Chlorosilanes		Angew. Chem.-Int. Edit.	46	Oestreich, M	FALSE	TRUE	FALSE	FALSE
6332	10.1021/acs.orglett.1c01189	doi.org/10.1021/acs.orglett.1c01189	Aldehyde to Ketone Homologation Enabled by Improved Access to Thioalkyl Phosphonium Salts		Org. Lett.	46	Magolan, J	FALSE	FALSE	FALSE	FALSE
6333	10.1021/acscatal.1c01102	doi.org/10.1021/acscatal.1c01102	Nickel-Catalyzed Cross-Electrophile Coupling between C(sp(2))-F and C(sp(2))-Cl Bonds by the Reaction of ortho-Fluoro-Aromatic Amides with Aryl Chlorides		ACS Catal.	46	Chatani, N	FALSE	TRUE	FALSE	FALSE
6334	10.1016/j.tetlet.2021.153001	doi.org/10.1016/j.tetlet.2021.153001	Copper-catalyzed regioselective 2-amination of o-haloanilides with aqueous ammonia		Tetrahedron Lett.	46	Sun, Y; Mao, ZW	FALSE	FALSE	FALSE	FALSE
6335	10.1002/ejoc.201700837	doi.org/10.1002/ejoc.201700837	Regioselective Chlorination and Suzuki-Miyaura Cross-Coupling of 4-Alkoxycoumarins, 4-Alkoxy-2-pyrones, and Related Heterocycles		Eur. J. Org. Chem.	46	McGlacken, GP	FALSE	FALSE	FALSE	FALSE
6336	10.1021/acs.organomet.7b00280	doi.org/10.1021/acs.organomet.7b00280	Carbon-Sulfur Bond Cleavage Reactions of Quinolyl-Substituted Thiophenes with Iron Carbonyls		Organometallics	46	Hirotsu, M	FALSE	FALSE	FALSE	FALSE
6337	10.1021/jacs.7b02455	doi.org/10.1021/jacs.7b02455	Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines		J. Am. Chem. Soc.	46	Liu, GS	FALSE	FALSE	FALSE	FALSE
6338	10.1021/acs.joc.6b03038	doi.org/10.1021/acs.joc.6b03038	Asymmetric Ring-Opening Reactions of Aza- and Oxa-bicyclic Alkenes with Boronic Acids Using a Palladium/Zinc Co-catalytic System		J. Org. Chem.	46	Chen, JC; Fan, BM	FALSE	FALSE	FALSE	FALSE
6339	10.1002/ejic.201601351	doi.org/10.1002/ejic.201601351	Catalytic Behaviour of Calixarenylphosphanes in Nickel-Catalysed Suzuki-Miyaura Cross-Coupling		Eur. J. Inorg. Chem.	46	Semeril, D; Matt, D	FALSE	FALSE	FALSE	FALSE
6340	10.1002/chem.201604160	doi.org/10.1002/chem.201604160	Lewis Acid Accelerated Aryl Ether Bond Cleavage with Nickel: Orders of Magnitude Rate Enhancement Using AlMe3		Chem.-Eur. J.	46	Agapie, T	FALSE	FALSE	FALSE	FALSE
6341	10.1021/acs.organomet.6b00256	doi.org/10.1021/acs.organomet.6b00256	beta-Oxo-delta-diimine Nickel Complexes: A Comparison of Tautomeric Active Species in Ethylene Polymerization Catalysis		Organometallics	46	Tonks, IA	FALSE	FALSE	FALSE	FALSE
6342	10.1002/ejoc.201501492	doi.org/10.1002/ejoc.201501492	Copper-Catalyzed Borylation of Cyclic Sulfamidates: Access to Enantiomerically Pure (beta-and gamma-Aminoalkyl) boronic Esters		Eur. J. Org. Chem.	46	Gallagher, T	FALSE	FALSE	FALSE	FALSE
6343	10.1002/adsc.202001589	doi.org/10.1002/adsc.202001589	A 1,4-Palladium Migration/Heck Sequence with Unactivated Alkenes: Stereoselective Synthesis of Trisubstituted 1,3-Dienes	A simple and highly efficient method for the constructions of Csp-Csp, Csp(2)-Csp(2) and Csp(3)-Csp(3) bonds is reported. The symmetrical diaryl tellurides undergo detellurative homocouplings to afford symmetrical biaryl products. The reactions are carried out at ambient temperature using PdCl2 as a catalyst in the presence of Ag2O and Na2CO3. Similarly, the detellurative homocouplings of dibenzyl telluride and bis (phenylethynyl)telluride give bibenzyl and the conjugated diyne, respectively. (C) 2017 Elsevier Ltd. All rights reserved.	Adv. Synth. Catal.	45	He, ZT; Feng, CG; Lin, GQ	FALSE	FALSE	FALSE	FALSE
6344	10.1021/jacs.0c13034	doi.org/10.1021/jacs.0c13034	The Asymmetric Synthesis of Amines via Nickel-Catalyzed Enantioconvergent Substitution Reactions	One of the major current challenges in the field of C-H functionalization is the development of new removable/modifiable directing groups (DGs). We report here the 4,6-dimethoxy-1,3,5-triazin-2-yloxy group as a new readily removable/modifiable DG for the regioselective acetoxylation of 2-(aryloxy)-4,6-dimethoxy-1,3,5-triazine. This developed phenol-derived DG can be easily removed to offer synthetically versatile pyrocatechols or converted into a useful biphenyl skeleton. In addition, the acetoxylation of 2-(aryloxy)-4,6-dimethoxy-1,3,5-triazine offers a new avenue to synthesize polysubstituted s-triazine derivatives.	J. Am. Chem. Soc.	45	Fu, GC	FALSE	FALSE	FALSE	FALSE
6345	10.1002/adsc.202001338	doi.org/10.1002/adsc.202001338	Efficient and Clean Nickel Catalyzed alpha-Allylation Reaction of Nitriles	A useful transformation of nitriles to N-phenyl amides has been achieved through a novel intermolecular phenyl transfer reaction from phenyl hydrazides and N-addition to nitriles in the presence of PIFA under mild and solvent-free conditions. This cross coupling reaction includes the oxidative cleavage of sp(2) C-N bonds of phenyl hydrazides to form a phenyl radical and the subsequent N-addition to cyanos to form new sp(2) C-N bonds and provides efficient access to various N-phenyl amides in moderate to good yields under mild reaction conditions.	Adv. Synth. Catal.	45	Sauthier, M	FALSE	FALSE	FALSE	FALSE
6346	10.1021/acs.orglett.0c03505	doi.org/10.1021/acs.orglett.0c03505	Primary Sulfonamide Synthesis Using the Sulfinylamine Reagent N-Sulfinyl-O-(tert-butyl)hydroxylamine, t-BuONSO	A catalytic amidation protocol mediated by 2,2,2-trifluoroethanol has been developed, facilitating the condensation of unactivated esters and amines, furnishing both secondary and tertiary amides. The complete scope and limitations of the method are described, along with modified conditions for challenging substrates such as acyclic secondary amines and chiral esters with retention of chiral integrity.	Org. Lett.	45	Willis, MC	FALSE	FALSE	FALSE	FALSE
6347	10.1021/acs.orglett.0c03666	doi.org/10.1021/acs.orglett.0c03666	Decarboxylative/Oxidative Amidation of Aryl alpha-Ketocarboxylic Acids with Nitroarenes and Nitroso Compounds in Aqueous Medium	An efficient nickel-catalyzed decarbonylative amination reaction of aryl and heteroaryl esters has been achieved for the first time. The new amination protocol allows the direct interconversion of esters and amides into the corresponding amines and represents a good alternative to classical rearrangements as well as cross coupling reactions.	Org. Lett.	45	Batra, S	FALSE	FALSE	FALSE	FALSE
6348	10.1016/j.cej.2020.125942	doi.org/10.1016/j.cej.2020.125942	Hierarchically tailored hybrids via interfacial-engineering of self-assembled UiO-66 and prussian blue analogue: Novel strategy to impart epoxy high-efficient fire retardancy and smoke suppression	Density functional theory (DFT) calculations have been performed to unravel the mechanism of Lewis-acid-induced Ni(cod)(2)-catalyzed selective coupling reactions of one diketene and two alkynes. Complex mixtures (unsymmetrical phenylacetic acid P1, symmetrical phenylacetic acid P2 and (3E)-4-ethyl-5-methylene-3-heptenoic acid P3) were obtained in the absence of Et2Al(OEt). P1 formation involves C(sp(2))-O oxidative addition of diketene, twice alkyne insertion, intramolecular C=C insertion, acidolysis, and beta-H elimination. For P2/P3 formation, the common key issue related to the C=C double bond cleavage of the substrate diketene was explored and found that it was accomplished via a four-membered-ring-closure/four-membered-ring-opening process. And then, P2 was produced via the second alkyne insertion while P3 was accessed by a stoichiometric reaction with HCI. The Et2Al(OEt)-induced chemoselectivity was also probed. It is found that the Ni-O (from Al reagent) bonding facilitates the second alkyne insertion, and the Al-O (from carboxylate) bonding weakens the four-membered ring-closure step, which consequently leads to the formation of P1 exclusively. Additionally, HCI plays a promoting role as a cocatalyst in producing P1 and P2. The theoretical results not only well rationalize the experimental observations but provide insights into the mechanism of the Ni-catalyzed multicomponent coupling reactions.	Chem. Eng. J.	45	Wang, DY	FALSE	FALSE	FALSE	FALSE
6349	10.1039/d0cc03966g	doi.org/10.1039/d0cc03966g	Base-free oxidation of alcohols enabled by nickel(ii)-catalyzed transfer dehydrogenation	An interesting nickel-based catalyst supported on DABCO-functionalized silica was successfully prepared and evaluated as heterogeneous nanocatalyst in Heck cross coupling reaction of various aryl halides and methyl acrylate. The as-prepared nanocatalyst was well characterized by FT-IR, FE-SEM, TEM, XRD, SEM-EDX, ICP and TGA techniques and found to be highly efficient in the reaction system in terms of activity and recyclability. This work provides an economical and heterogeneous catalytic system based nickel nanoparticle supported on DABCO functionalized silica for the Heck cross-coupling reaction of various aryl halides with methyl acrylate. [GRAPHICS]	Chem. Commun.	45	Sessler, JL; Lei, CH	FALSE	FALSE	FALSE	FALSE
6350	10.1021/acs.orglett.0c02478	doi.org/10.1021/acs.orglett.0c02478	Palladium-Catalyzed Tandem C-C Activation/Cyclization Induced by Carbopalladation of Functionalized Nitriles: Synthesis of Benzo Dipyrromethenes	The palladium-catalyzed direct cross-coupling of aryl bromides and (1Z,5Z)-cycloocta-1,5-dien-1-yllithium is described as an important method to synthesize 1-arylcyclooctadienes. The use of a well-established Pd(2)dba(3)/XPhos catalytic system affords the desired new compounds in good to excellent yields; the reaction proceeds at room temperature with both high efficiency and selectivity. Finally we found the best conditions to combine a suitable lithium-halogen exchange with a cross-coupling reaction.	Org. Lett.	45	Shao, YL; Chen, JX	FALSE	FALSE	FALSE	FALSE
6351	10.1039/d0cc02142c	doi.org/10.1039/d0cc02142c	Facile synthesis of a nickel(0) phosphine complex at ambient temperature	Cross-couplings of alkyl halides and organometallic species based on single electron transfer using Ni and Fe catalyst systems have been studied extensively, and separately, for decades. Here we demonstrate the first couplings of redox-active esters (both isolated and derived in situ from carboxylic acids) with organozinc and organo-magnesium species using an Fe-based catalyst system originally developed for alkyl halides. This work is placed in context by showing a direct comparison with a Ni catalyst for >40 examples spanning a range of primary, secondary, and tertiary substrates. This new C-C coupling is scalable and sustainable, and it exhibits a number of clear advantages in several cases over its Ni-based counterpart.	Chem. Commun.	45	Wright, DS	FALSE	FALSE	FALSE	FALSE
6352	10.1021/acs.orglett.0c01668	doi.org/10.1021/acs.orglett.0c01668	Improved Process for the Palladium-Catalyzed C-O Cross-Coupling of Secondary Alcohols	The group selectivity and regioselectivity in the allylation of mixed (n-butyl)(aryl) zinc reagents in THF depends on the nickel catalyst type and also on nature of the allylic substrate. Allylation of (n-butyl)(phenyl) zinc reagent with alkyl substituted primary allylic chlorides and acetates in the presence of NiCl2(dppf) catalysis affords the phenyl coupling product with gamma-selectivity. However, allylation with aryl substituted primary allylic substrates results in both phenyl-and alkyl-coupling products with medium alpha-selectivity in the presence of NiCl2(dppf) catalysis whereas phenyl coupling product is formed with alpha-selectivity in the presence of NiCl2(Ph3P)(2) catalysis. This new NiCl2(dppf) catalyzed protocol for gamma-selective aryl allylation of (n-butyl)(aryl) zinc reagents with alkyl substituted primary allylic chlorides in THF at room temperature provides an atom economic alternative to allylation of (aryl)(2)Zn reagents. A mechanism for the dependence of group selectivity and regioselectivity of Ni catalyzed allylation of (n-butyl)(aryl)zinc reagents on the catalyst ligand and the substrate was proposed. (C) 2016 Elsevier B.V. All rights reserved.	Org. Lett.	45	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
6353	10.1016/j.tet.2020.131245	doi.org/10.1016/j.tet.2020.131245	Polyoxometalate catalyzed imine synthesis: Investigation of mechanistic pathways	The nickel-catalyzed borylation of aryl 2-pyridyl ethers via the loss of a 2-pyridyloxy group is described. This method allows a 2-pyridyloxy group to be used as a convertible directing group in C-H bond functionalization reactions. The nickel catalyst can also borylate arylmethyl 2-pyridyl ethers, in which the stereochemistry at the benzylic position is retained in the case of chiral secondary benzylic substrates.	Tetrahedron	45	Mandal, D	FALSE	FALSE	FALSE	FALSE
6354	10.1002/anie.202003948	doi.org/10.1002/anie.202003948	Cycloisomerization of Olefins in Water	Cross-coupling of polyfluoroarenes with aryl carbamates through the cleavage of both sp(2) C-O and C-H bonds is reported, The reaction conditions are simple, and only transition-metal catalysts and ligands are essential. Mechanistic studies indicated that Ni catalyst played an important role in activating C-O bond, while the Cu one in activating C-H Bond. The developed system proved to be effective for cross-coupling of terminal alkynes with aryl carbamates.	Angew. Chem.-Int. Edit.	45	Shenvi, RA	FALSE	FALSE	FALSE	FALSE
6355	10.1248/cpb.c20-00075	doi.org/10.1248/cpb.c20-00075	One-Pot Formal Dehydrogenative Ketone Synthesis from Aldehydes and Non-activated Hydrocarbons	Various 1-methyl-, 1-triisopropylsilyl-, and 1-benzylindoles are carboxylated under CO2 pressure (3.0 MPa) with the aid of 1.0 molar equiv of Me2AlCl to give 1-substituted indole-3-carboxylic acids in good to excellent yields. Mechanistic studies suggest that the intermediate, an indol-3-ylaluminum ate complex, was reversibly formed by electrophilic addition of Me2AlCl to the substrate followed by de-protonation of the resulting adduct. This method is successfully extended to alkoxycarbonylation with ethyl chloroformate and carbamoylation with naphthalen-1-yl isocyanate, which afford ethyl indole-3-carboxylates and N-naphthalen-1-ylindole-3-carboxamides, respectively. (C) 2015 Elsevier Ltd. All rights reserved.	Chem. Pharm. Bull.	45	Yahata, K	FALSE	FALSE	FALSE	FALSE
6356	10.1039/c9nj06438a	doi.org/10.1039/c9nj06438a	Metal-free annulative hydrosulfonation of propiolate esters: synthesis of 4-sulfonates of coumarins and butenolides	A series of 8-heteroaryl substituted quinolines were prepared, either by direct C-H arylation of five-membered heteroarenes, or Pd-catalyzed coupling of organoboron reagents with bromoquinolines. The use of (benzo) thiophenyl or (benzo) furanyl boron coupling partners allowed further C-H functionalization on the five-membered heteroaryl ring with aryl bromides in one flask to access a variety of polyconjugated molecular architectures. The developed methodology represents a simple approach towards 8-arylated analogues of the biologically interesting nitroxoline core.	New J. Chem.	45	Fernandes, RA	FALSE	FALSE	FALSE	FALSE
6357	10.1021/acs.orglett.0c00061	doi.org/10.1021/acs.orglett.0c00061	Covalent Organic Framework as a Heterogeneous Ligand for the Regioselective Oxidative Heck Reaction		Org. Lett.	45	Wei, YQ	FALSE	FALSE	FALSE	FALSE
6358	10.1021/acscatal.9b04353	doi.org/10.1021/acscatal.9b04353	Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters		ACS Catal.	45	Denmark, SE	FALSE	FALSE	FALSE	FALSE
6359	10.1002/anie.201912618	doi.org/10.1002/anie.201912618	Copper-Catalyzed Enantioselective Allylic Alkylation with a gamma-Butyrolactone-Derived Silyl Ketene Acetal		Angew. Chem.-Int. Edit.	45	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
6360	10.1002/aoc.5291	doi.org/10.1002/aoc.5291	E-Selective Hydrothiolation of Terminal Arylallenes with Arylthiols Catalyzed by Ni (PMe3)(4)		Appl. Organomet. Chem.	45	Li, XY	FALSE	FALSE	FALSE	FALSE
6361	10.1038/s42004-019-0229-x	doi.org/10.1038/s42004-019-0229-x	Amination of beta-hydroxyl acid esters via cooperative catalysis enables access to bio-based beta-amino acid esters		Comm. Chem.	45	Barta, K	FALSE	FALSE	FALSE	FALSE
6362	10.1021/acs.organomet.9b00453	doi.org/10.1021/acs.organomet.9b00453	Ancillary Ligand Modification via Reductive Elimination at Nickel(II)		Organometallics	45	Fryzuk, M	FALSE	FALSE	FALSE	FALSE
6363	10.1021/acscatal.9b03019	doi.org/10.1021/acscatal.9b03019	Orthogonal Selectivity in C-H Olefination: Synthesis of Branched Vinylarene with Unactivated Aliphatic Substitution		ACS Catal.	45	Maiti, D	FALSE	FALSE	FALSE	FALSE
6364	10.1039/c9ob01417a	doi.org/10.1039/c9ob01417a	Iridium-catalyzed diastereoselective amination of alcohols with chiral tert-butanesulfinamide by the use of a borrowing hydrogen methodology		Org. Biomol. Chem.	45	Zhang, Y; Xia, LX	FALSE	FALSE	FALSE	FALSE
6365	10.1039/c9cc04120f	doi.org/10.1039/c9cc04120f	A nanoscale iron catalyst for heterogeneous direct N- and C-alkylations of anilines and ketones using alcohols under hydrogen autotransfer conditions		Chem. Commun.	45	Namitharan, K	FALSE	FALSE	FALSE	FALSE
6366	10.1039/c9cc03344k	doi.org/10.1039/c9cc03344k	Allylation of aldehydes by dual photoredox and nickel catalysis		Chem. Commun.	45	Gualandi, A; Ceroni, P; Cozzi, PG	FALSE	FALSE	FALSE	FALSE
6367	10.1021/acs.joc.9b00616	doi.org/10.1021/acs.joc.9b00616	Substrate Self-Assisted Secondary Bond Activation of Allylic Alcohol in a Tsuji-Trost Reaction Revealed by NMR Methods		J. Org. Chem.	45	Ma, XT	FALSE	FALSE	FALSE	FALSE
6368	10.1055/s-0037-1612214	doi.org/10.1055/s-0037-1612214	Enantioselective Reductive Diarylation of Alkenes by Ni-Catalyzed Domino Heck Cyclization/Cross Coupling		Synlett	45	Kong, WQ	FALSE	FALSE	FALSE	FALSE
6369	10.1002/anie.201901724	doi.org/10.1002/anie.201901724	Regioselective Functionalization of 7-Azaindole by Controlled Annular Isomerism: The Directed Metalation-Group Dance		Angew. Chem.-Int. Edit.	45	Snieckus, V	FALSE	FALSE	FALSE	FALSE
6370	10.1002/anie.201903330	doi.org/10.1002/anie.201903330	From Alkyl Halides to Ketones: Nickel-Catalyzed Reductive Carbonylation Utilizing Ethyl Chloroformate as the Carbonyl Source		Angew. Chem.-Int. Edit.	45	Hu, XL	FALSE	FALSE	FALSE	FALSE
6371	10.1055/s-0037-1610682	doi.org/10.1055/s-0037-1610682	Regioselective Addition of Quinoline Derivatives to Carbonyl Compounds via Palladium-Catalyzed Umpolung with Diethylzinc		Synthesis	45	Onomura, O	FALSE	FALSE	FALSE	FALSE
6372	10.1002/anie.201812862	doi.org/10.1002/anie.201812862	PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines		Angew. Chem.-Int. Edit.	45	Stradiotto, M	FALSE	TRUE	FALSE	FALSE
6373	10.1039/c8cc09099h	doi.org/10.1039/c8cc09099h	Rhodium(iii)-catalyzed regioselective oxidative annulation of anilines and allylbenzenes via C(sp(3))-H/C(sp(2))-H bond cleavage		Chem. Commun.	45	You, JS	FALSE	FALSE	FALSE	FALSE
6374	10.1021/jacs.8b11159	doi.org/10.1021/jacs.8b11159	Synthesis of 2-Aryloxy-1,3-dienes from Phenols and Propargyl Carbonates		J. Am. Chem. Soc.	45	Murakami, M	FALSE	FALSE	FALSE	FALSE
6375	10.1021/jacs.8b02469	doi.org/10.1021/jacs.8b02469	Ring-Walking in Catalyst-Transfer Polymerization		J. Am. Chem. Soc.	45	McNeil, AJ	FALSE	FALSE	FALSE	FALSE
6376	10.1002/anie.201800829	doi.org/10.1002/anie.201800829	Decarboxylative Benzylation of Aryl and Alkenyl Boronic Esters		Angew. Chem.-Int. Edit.	45	Lundgren, RJ	FALSE	FALSE	FALSE	FALSE
6377	10.1038/s41467-018-03532-1	doi.org/10.1038/s41467-018-03532-1	Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel		Nat. Commun.	45	Zhang, XG	FALSE	FALSE	FALSE	FALSE
6378	10.1002/anie.201711990	doi.org/10.1002/anie.201711990	Barbier-Negishi Coupling of Secondary Alkyl Bromides with Aryl and Alkenyl Triflates and Nonaflates		Angew. Chem.-Int. Edit.	45	Baudoin, O	FALSE	FALSE	FALSE	FALSE
6379	10.1039/c7ob02599h	doi.org/10.1039/c7ob02599h	A Bronsted acid-promoted asymmetric intramolecular allylic amination of alcohols		Org. Biomol. Chem.	45	Xie, HX	FALSE	FALSE	FALSE	FALSE
6380	10.1055/s-0036-1590903	doi.org/10.1055/s-0036-1590903	Design and Synthesis of Enantiopure Tetrakis(pentafluorophenyl) Borate Analogues for Asymmetric Counteranion Directed Catalysis		Synlett	45	List, B	FALSE	FALSE	FALSE	FALSE
6381	10.1039/c6ob01355d	doi.org/10.1039/c6ob01355d	Bi(OTf)(3)-catalyzed addition of isocyanides to 2H-chromene acetals: an efficient pathway for accessing 2-carboxamide-2H-chromenes		Org. Biomol. Chem.	45	Wang, J	FALSE	FALSE	FALSE	FALSE
6382	10.1111/cas.12813	doi.org/10.1111/cas.12813	Prognostic role of PIK3CA mutations of cell-free DNA in early-stage triple negative breast cancer		Cancer Sci.	45	Iwase, H	FALSE	FALSE	FALSE	FALSE
6383	10.1016/j.inoche.2015.02.018	doi.org/10.1016/j.inoche.2015.02.018	(Ferrocenylthienyl)phosphines for the Suzuki-Miyaura C,C coupling		Inorg. Chem. Commun.	45	Lang, H	FALSE	FALSE	FALSE	FALSE
6384	10.1016/j.ica.2015.01.005	doi.org/10.1016/j.ica.2015.01.005	Two cadmium(II) complexes with oxazoline-based ligands as effective catalysts for C-N cross-coupling reactions		Inorg. Chim. Acta	45	Jia, WG	FALSE	FALSE	FALSE	FALSE
6385	10.1016/j.jssc.2014.10.002	doi.org/10.1016/j.jssc.2014.10.002	A key route to designing huge eight-fold interpenetrated coordination networks with ths-type topology: Synthesis, structures, and topological characteristics		J. Solid State Chem.	45	Tseng, TW	FALSE	FALSE	FALSE	FALSE
6386	10.1021/jo501814n	doi.org/10.1021/jo501814n	Intramolecular Oxyacylation of Alkenes Using a Hydroxyl Directing Group		J. Org. Chem.	45	Douglas, CJ	FALSE	FALSE	FALSE	FALSE
6387	10.1021/ol501397b	doi.org/10.1021/ol501397b	Catalytic Asymmetric Total Synthesis of (+)-Caprazol		Org. Lett.	45	Watanabe, T	FALSE	FALSE	FALSE	FALSE
6388	10.1021/jo500561z	doi.org/10.1021/jo500561z	Synthesis of Substituted Styrenes and 3-Vinylphenols Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis		J. Org. Chem.	45	Yoshida, K	FALSE	FALSE	FALSE	FALSE
6389	10.1016/j.molcata.2014.01.001	doi.org/10.1016/j.molcata.2014.01.001	SPIONs-bis(NHC)-palladium(II): A novel, powerful and efficient catalyst for Mizoroki-Heck and Suzuki-Miyaura C-C coupling reactions		J. Mol. Catal. A-Chem.	45	Khosropour, AR	FALSE	FALSE	FALSE	FALSE
6390	10.1039/c4cc00931b	doi.org/10.1039/c4cc00931b	sp(3)C-H bond alkylation of ketones with alkenes via ruthenium(II) catalysed dehydrogenation of alcohols		Chem. Commun.	45	Li, B	FALSE	FALSE	FALSE	FALSE
6391	10.1021/ol402262c	doi.org/10.1021/ol402262c	Palladium-Catalyzed C-2 Selective Arylation of Quinolines		Org. Lett.	45	Huang, GS	FALSE	FALSE	FALSE	FALSE
6392	10.1002/ejoc.201300750	doi.org/10.1002/ejoc.201300750	An Approach to the Synthesis of Functionalized Polycyclic Aromatic Hydrocarbons		Eur. J. Org. Chem.	45	Quayle, P	FALSE	FALSE	FALSE	FALSE
6393	10.1007/s11426-013-4880-2	doi.org/10.1007/s11426-013-4880-2	Stereoselective C(sp(3))-C(sp(2)) Negishi coupling of (2-amido-1-phenylpropyl)zinc compounds through the steric control of beta-amido group		Sci. China-Chem.	45	Tang, S	FALSE	FALSE	FALSE	FALSE
6394	10.1016/j.molstruc.2013.01.008	doi.org/10.1016/j.molstruc.2013.01.008	Theoretical and experimental studies on the structure and spectroscopic properties of Ni(II) complexes of the type [Ni(L)(PPh3)] [H2L=5-methyl-N-(2-mercaptophenyl)salicylideneimine and 5-chloro-N-(2-mercaptophenyl)salicylideneimine]		J. Mol. Struct.	45	Karvembu, R	FALSE	FALSE	FALSE	FALSE
6395	10.1016/j.tetlet.2012.10.005	doi.org/10.1016/j.tetlet.2012.10.005	Nickel-catalyzed decarboxylative coupling reaction of alkynyl carboxylic acids and allyl acetates		Tetrahedron Lett.	45	Lee, S	FALSE	FALSE	FALSE	FALSE
6396	10.1016/j.tetlet.2012.09.072	doi.org/10.1016/j.tetlet.2012.09.072	Palladium-catalyzed cross-coupling reaction of aryl(trialkyl)silanes with aryl nitriles		Tetrahedron Lett.	45	Tang, S	FALSE	FALSE	FALSE	FALSE
6397	10.1021/ol302688u	doi.org/10.1021/ol302688u	Nickel-Catalyzed Synthesis of Diarylamines via Oxidatively Induced C-N Bond Formation at Room Temperature		Org. Lett.	45	Nakamura, E	FALSE	FALSE	FALSE	FALSE
6398	10.1016/j.inoche.2012.08.016	doi.org/10.1016/j.inoche.2012.08.016	Synthesis of triethylphosphite complexes of nickel(II) and palladium(II) with tridentate Schiff base ligand for catalytic application in carbon-carbon coupling reactions		Inorg. Chem. Commun.	45	Karvembu, R	FALSE	FALSE	FALSE	FALSE
6399	10.1021/ja3079362	doi.org/10.1021/ja3079362	Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation Pathway		J. Am. Chem. Soc.	45	Doyle, AG	FALSE	FALSE	FALSE	FALSE
6400	10.1002/adsc.201100836	doi.org/10.1002/adsc.201100836	Copper-Catalyzed Cyanation of Aryl Iodides with Malononitrile: An Unusual Cyano Group Transfer Process from C(sp3) to C(sp2)		Adv. Synth. Catal.	45	Zhou, XG	FALSE	FALSE	FALSE	FALSE
6401	10.1002/chem.201103418	doi.org/10.1002/chem.201103418	Pd-Catalyzed Reaction of Allyl Carbonate with Polyols: The Role of CO2 in Transesterification versus Etherification of Glycerol		Chem.-Eur. J.	45	Lloyd-Jones, GC	FALSE	FALSE	FALSE	FALSE
6402	10.1039/c1cc14593b	doi.org/10.1039/c1cc14593b	Shuffle off the classic beta-Si elimination by Ni-NHC cooperation: implication for C-C forming reactions involving Ni-alkyl-beta-silanes		Chem. Commun.	45	Ho, CY	FALSE	FALSE	FALSE	FALSE
6403	10.1039/c1ob06752d	doi.org/10.1039/c1ob06752d	Suzuki-Miyaura cross-couplings of arenediazonium tetrafluoroborate salts with arylboronic acids catalyzed by aluminium hydroxide-supported palladium nanoparticles		Org. Biomol. Chem.	45	Li, X	FALSE	FALSE	FALSE	FALSE
6404	10.1021/ja2062715	doi.org/10.1021/ja2062715	Regioselective Activation of Glycosyl Acceptors by a Diarylborinic Acid-Derived Catalyst		J. Am. Chem. Soc.	45	Taylor, MS	FALSE	FALSE	FALSE	FALSE
6405	10.1021/jo200904g	doi.org/10.1021/jo200904g	Synthesis of 8-Arylquinolines via One-Pot Pd-Catalyzed Borylation of Quinoline-8-yl Halides and Subsequent Suzuki-Miyaura Coupling		J. Org. Chem.	45	Zhang, YD	FALSE	FALSE	FALSE	FALSE
6406	10.1021/ja2008906	doi.org/10.1021/ja2008906	Enantioselective alpha-Arylation of Aldehydes via the Productive Merger of lodonium Salts and Organocatalysis		J. Am. Chem. Soc.	45	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
6407	10.1021/ja1097385	doi.org/10.1021/ja1097385	Rhodium-Catalyzed Anti-Markovnikov Intermolecular Hydroalkoxylation of Terminal Acetylenes		J. Am. Chem. Soc.	45	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
6408	10.1039/c1cc13348a	doi.org/10.1039/c1cc13348a	Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates		Chem. Commun.	45	Kobayashi, S	FALSE	FALSE	FALSE	FALSE
6409	10.1002/anie.201004374	doi.org/10.1002/anie.201004374	Nucleophilic alpha-Arylation and alpha-Alkylation of Ketones by Polarity Inversion of N-Alkoxyenamines: Entry to the Umpolung Reaction at the alpha-Carbon Position of Carbonyl Compounds		Angew. Chem.-Int. Edit.	45	Miyata, O	FALSE	FALSE	FALSE	FALSE
6410	10.1080/10426507.2010.544271	doi.org/10.1080/10426507.2010.544271	Cs2CO3 CATALYZED RAPID AND EFFICIENT CONVERSION OF AMINES INTO SULFONAMIDES; ALCOHOLS AND PHENOLS INTO SULFONIC ESTERS		Phosphorus Sulfur Silicon Relat. Elem.	45	Pasha, MA	FALSE	FALSE	FALSE	FALSE
6411	10.1021/ol100610v	doi.org/10.1021/ol100610v	Rhodium-Catalyzed Domino Conjugate Addition-Cyclization Reactions for the Synthesis of a Variety of N- and O-Heterocycles: Arylboroxines as Effective Carbon Nucleophiles		Org. Lett.	45	Youn, SW	FALSE	FALSE	FALSE	FALSE
6412	10.1055/s-0029-1219580	doi.org/10.1055/s-0029-1219580	Synthesis of N-Arylisoindolin-1-ones via Pd-Catalyzed Intramolecular Decarbonylative Coupling of N-(2-Bromobenzyl)oxanilic Acid Phenyl Esters		Synlett	45	Dai, WM	FALSE	FALSE	FALSE	FALSE
6413	10.1039/b918117b	doi.org/10.1039/b918117b	Synthesis of CuO on mesoporous silica and its applications for coupling reactions of thiols with aryl iodides		Chem. Commun.	45	Lin, HP	FALSE	FALSE	FALSE	FALSE
6414	10.1002/anie.201001752	doi.org/10.1002/anie.201001752	Palladium-Catalyzed Arylative Ring-Opening Reactions of Norbornenols: Entry to Highly Substituted Cyclohexenes, Quinolines, and Tetrahydroquinolines		Angew. Chem.-Int. Edit.	45	Cramer, N	FALSE	FALSE	FALSE	FALSE
6415	10.1002/anie.200907359	doi.org/10.1002/anie.200907359	Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard Reagents		Angew. Chem.-Int. Edit.	45	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
6416	10.3987/COM-08-S(D)3	doi.org/10.3987/COM-08-S(D)3	PALLADIUM-CATALYZED ARYLATION AT C-H AND C-C BONDS OF MASKED THIAZOLE DERIVATIVES		Heterocycles	45	Furukawa, H	FALSE	FALSE	FALSE	FALSE
6417	10.1055/s-0028-1083381	doi.org/10.1055/s-0028-1083381	Room-Temperature Palladium-Catalyzed Allyl Cross-Coupling Reaction with Boronic Acids Using Phosphine-Free Hydrazone Ligands		Synlett	45	Mino, T	FALSE	FALSE	FALSE	FALSE
6418	10.1002/anie.200802292	doi.org/10.1002/anie.200802292	Preparation of aryl and heteroaryl indium(III) reagents by the direct insertion of indium in the presence of LiCl		Angew. Chem.-Int. Edit.	45	Knochel, P	FALSE	FALSE	FALSE	FALSE
6419	10.1039/b809140d	doi.org/10.1039/b809140d	Copper-catalyzed asymmetric allylic substitution with aryl and ethyl Grignard reagents		Chem. Commun.	45	Tomioka, K	FALSE	FALSE	FALSE	FALSE
6420	10.1021/ol702167t	doi.org/10.1021/ol702167t	Nickel-catalyzed carboannulation reaction of o-bromobenzyl zinc bromide with unsaturated compounds		Org. Lett.	45	Sun, L	FALSE	FALSE	FALSE	FALSE
6421	10.1016/j.molcata.2007.03.060	doi.org/10.1016/j.molcata.2007.03.060	Layered double hydroxides supported rhodium(0): An efficient and reusable catalyst for Heck, Suzuki, and Stille reactions of haloarenes		J. Mol. Catal. A-Chem.	45	Kantam, ML	FALSE	FALSE	FALSE	FALSE
6422	10.1016/j.tetlet.2006.01.020	doi.org/10.1016/j.tetlet.2006.01.020	Palladium-catalyzed Suzuki-Miyaura couplings of potassium aryl trifluoroborates with 4-tosyloxycoumarins or 4-tosyloxyquinolin-2(1H)-one		Tetrahedron Lett.	45	Wu, J	FALSE	FALSE	FALSE	FALSE
6423	10.1002/ejic.200500685	doi.org/10.1002/ejic.200500685	Synthesis and properties of cryptands with a thioether bridge and pi-donors - Silver(I) and copper(I)-complexes		Eur. J. Inorg. Chem.	45	Gleiter, R	FALSE	FALSE	FALSE	FALSE
6424	10.1039/b502026c	doi.org/10.1039/b502026c	Alkenylation of allylic alcohols using alkenylboron dihalides: a formal transition-metal free Suzuki reaction		Chem. Commun.	45	Kabalka, GW	FALSE	FALSE	FALSE	FALSE
6425	10.1021/om034187p	doi.org/10.1021/om034187p	Oxidative addition of aryl Sulfonates to Palladium(0) complexes of mono- and bidentate phosphines. Mild addition of aryl tosylates and the effects of anions on rate and mechanism		Organometallics	45	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6426	10.1002/adsc.200303045	doi.org/10.1002/adsc.200303045	Combinatorial design of copper-based mixed nanoclusters: New catalysts for Suzuki cross-coupling		Adv. Synth. Catal.	45	Rothenberg, G	FALSE	FALSE	FALSE	FALSE
6427	10.1021/cc020045r	doi.org/10.1021/cc020045r	Synthesis of 4-(5-iodo-3-methylpyrazolyl) phenylsulfonamide and its elaboration to a COX II inhibitor library by solution-phase Suzuki coupling using Pd/C as a solid-supported catalyst		J. Comb. Chem.	45	Organ, MG	FALSE	FALSE	FALSE	FALSE
6428	10.1016/S0040-4020(01)00351-9	doi.org/10.1016/S0040-4020(01)00351-9	Rhodium-catalysed asymmetric ring opening reactions with carboxylate nucleophiles		Tetrahedron	45	Lautens, M	FALSE	FALSE	FALSE	FALSE
6429	10.1016/S0040-4020(00)01018-8	doi.org/10.1016/S0040-4020(00)01018-8	An efficient route to biaryls from aryl halides catalysed by subnanometrical 2,2 '-bipyridine liganded Ni-Al clusters		Tetrahedron	45	Fort, Y	FALSE	FALSE	FALSE	FALSE
6430	10.1006/jcat.2000.2865	doi.org/10.1006/jcat.2000.2865	The oxidative coupling of methyl benzoate		J. Catal.	45	White, MG	FALSE	FALSE	FALSE	FALSE
6431	10.1021/ma990301x	doi.org/10.1021/ma990301x	Synthesis and characterization of poly[[1,1 '-biphenyl]-4,4 '-diyl[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]]		Macromolecules	45	Sheares, VV	FALSE	FALSE	FALSE	FALSE
6432	10.1016/0040-4039(96)01718-2	doi.org/10.1016/0040-4039(96)01718-2	New monodentate chiral phosphine 2,6-dimethyl-9-phenyl-9-phosphabicyclo[3.3.1]nonane(9-PBN): Application to asymmetric allylic substitution reaction		Tetrahedron Lett.	45	Hamada, Y	FALSE	FALSE	FALSE	FALSE
6433	10.1016/S0040-4020(01)81896-2	doi.org/10.1016/S0040-4020(01)81896-2	DIPEPTIDE ISOSTERES .2. SYNTHESIS OF HYDROXYETHYLENE DIPEPTIDE ISOSTERE DIASTEREOMERS FROM A COMMON GAMMA-LACTONE INTERMEDIATE - PREPARATION OF RENIN AND HIV-1 PROTEASE INHIBITOR TRANSITION-STATE MIMICS		Tetrahedron	45	BAKER, WR	FALSE	FALSE	FALSE	FALSE
6434	10.1002/aoc.6574	doi.org/10.1002/aoc.6574	Bimetallic CoMoO4@C nanorod catalyzes one-pot synthesis of benzimidazoles from benzyl alcohol and o-phenylendiamine without alkali		Appl. Organomet. Chem.	45	Li, R	FALSE	FALSE	FALSE	FALSE
6435	10.1002/ejoc.202200152	doi.org/10.1002/ejoc.202200152	N-Alkylation of alpha-Amino Esters and Amides through Hydrogen Borrowing		Eur. J. Org. Chem.	45	Coomber, CE	FALSE	FALSE	FALSE	FALSE
6436	10.1002/anie.202115702	doi.org/10.1002/anie.202115702	Nickel-Catalyzed Desymmetric Reductive Cyclization/Coupling of 1,6-Dienes: An Enantioselective Approach to Chiral Tertiary Alcohol		Angew. Chem.-Int. Edit.	45	Zhou, QL	FALSE	FALSE	FALSE	FALSE
6437	10.1021/acscatal.1c04074	doi.org/10.1021/acscatal.1c04074	Substituent-Enhanced Intermolecular Catalytic Ene-yne Metathesis for Efficient 1,3-Diene Synthesis		ACS Catal.	45	Sadow, AD	FALSE	FALSE	FALSE	FALSE
6438	10.1021/acs.orglett.1c03500	doi.org/10.1021/acs.orglett.1c03500	Aminomethylation of Aryl Bromides by Nickel-Catalyzed Electrochemical Redox Neutral Cross Coupling		Org. Lett.	45	Ye, JX	FALSE	TRUE	FALSE	FALSE
6439	10.1021/acs.inorgchem.1c02127	doi.org/10.1021/acs.inorgchem.1c02127	The Role of AQ in the Regioselectivity of Strong Alkyl C-O Bond Activation Catalyzed by Pd(OAc)(2): A Density Functional Theory Mechanistic Study		Inorg. Chem.	45	Pu, M; Lei, M	FALSE	FALSE	FALSE	FALSE
6440	10.1021/acs.orglett.1c03384	doi.org/10.1021/acs.orglett.1c03384	Asymmetric Hydrogenation of Racemic alpha-Aryl-beta-ethoxycarbonyl Cyclopentanones via Dynamic Kinetic Resolution and Its Application to the Synthesis of (+)-Burmaniol A		Org. Lett.	45	Xie, JH	FALSE	FALSE	FALSE	FALSE
6441	10.1021/acscatal.1c02952	doi.org/10.1021/acscatal.1c02952	Stereoselective gem-Difluorovinylation of gem-Difluorinated Cyclopropanes Enabled by Ni/Pd Cooperative Catalysis		ACS Catal.	45	Zhang, XM; Lian, Z	FALSE	FALSE	FALSE	FALSE
6442	10.1021/acs.orglett.1c02225	doi.org/10.1021/acs.orglett.1c02225	Sequential Ring-Opening and Ring-Closing Reactions for Converting para-Substituted Pyridines into meta-Substituted Anilines		Org. Lett.	45	Morofuji, T; Kano, N	FALSE	FALSE	FALSE	FALSE
6443	10.1021/acscatal.1c01739	doi.org/10.1021/acscatal.1c01739	In-Situ-Generated Active Hf-hydride in Zeolites for the Tandem N-Alkylation of Amines with Benzyl Alcohol		ACS Catal.	45	Moliner, M; Boronat, M	FALSE	FALSE	FALSE	FALSE
6444	10.1021/acs.joc.1c00983	doi.org/10.1021/acs.joc.1c00983	Enantioselective alpha-Arylation of Primary Alcohols under Sequential One-Pot Catalysis		J. Org. Chem.	45	Lichosyt, D; Dydio, P	FALSE	FALSE	FALSE	FALSE
6445	10.1016/j.tetlet.2021.152947	doi.org/10.1016/j.tetlet.2021.152947	Ruthenium-catalyzed stereospecific benzylic alkylation of optically active benzyl esters with malonate nucleophiles		Tetrahedron Lett.	45	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
6446	10.1039/d1ob00195g	doi.org/10.1039/d1ob00195g	Dicarbofunctionalization of unactivated alkenes by palladium-catalyzed domino Heck/intermolecular direct hetero arylation with heteroarenes		Org. Biomol. Chem.	45	Kuram, MR	FALSE	FALSE	FALSE	FALSE
6447	10.1021/acscatal.7b00772	doi.org/10.1021/acscatal.7b00772	O-Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp(3)-Csp(2) Cross-Coupling		ACS Catal.	45	Molander, GA	TRUE	FALSE	FALSE	FALSE
6448	10.1021/jacs.7b03371	doi.org/10.1021/jacs.7b03371	Nickel-Catalyzed Cross-Coupling of Vinyl Dioxanones to Form Enantiomerically Enriched Cyclopropanes		J. Am. Chem. Soc.	45	Krische, MJ	FALSE	FALSE	FALSE	FALSE
6449	10.1016/j.tet.2017.03.058	doi.org/10.1016/j.tet.2017.03.058	Copper-catalyzed methylation of 1,3-diketones with tert-butyl peroxybenzoate		Tetrahedron	45	Zou, JP	FALSE	FALSE	FALSE	FALSE
6450	10.1002/ejoc.201601571	doi.org/10.1002/ejoc.201601571	Photoredox/Nickel Dual Catalysis for the C(sp(3))-C(sp(3)) Cross-Coupling of Alkylsilicates with Alkyl Halides		Eur. J. Org. Chem.	45	Ollivier, C; Fensterbank, L	TRUE	FALSE	FALSE	FALSE
6451	10.1021/acs.joc.6b02666	doi.org/10.1021/acs.joc.6b02666	An N-Heterocyclic Carbene-Nickel Half-Sandwich Complex as a Precatalyst for Suzuki Miyaura Coupling of Aryl/Heteroaryl Halides with Aryl/Heteroarylboronic Acids		J. Org. Chem.	45	Ando, S; Ishizuka, T	FALSE	FALSE	FALSE	FALSE
6452	10.1021/acs.joc.6b02586	doi.org/10.1021/acs.joc.6b02586	Syntheses of Combretastatins D-1, D-2, and D-4 via Ring Contraction by Flash Vacuum Pyrolysis		J. Org. Chem.	45	Schobert, R	FALSE	FALSE	FALSE	FALSE
6453	10.1016/j.molcata.2016.07.012	doi.org/10.1016/j.molcata.2016.07.012	Catalytic etherification of alcohols in Shilov system: C-O versus C-H bond activation		J. Mol. Catal. A-Chem.	45	Mitchenko, SA	FALSE	FALSE	FALSE	FALSE
6454	10.1021/acs.orglett.6b03158	doi.org/10.1021/acs.orglett.6b03158	Ester Formation via Nickel-Catalyzed Reductive Coupling of Alkyl Halides with Chloroformates		Org. Lett.	45	Gong, HG	FALSE	FALSE	FALSE	FALSE
6455	10.1016/j.jaap.2016.09.009	doi.org/10.1016/j.jaap.2016.09.009	Mechanism of transmethylation in anisole decomposition over HZSM-5: Experimental study		J. Anal. Appl. Pyrolysis	45	Shen, DK	FALSE	FALSE	FALSE	FALSE
6456	10.1021/acs.cgd.6b00494	doi.org/10.1021/acs.cgd.6b00494	Homocoupling Reaction of Aryl Halides Catalyzed by Metal Cations in Isostructural Coordination Polymers		Cryst. Growth Des.	45	Hou, HW	FALSE	FALSE	FALSE	FALSE
6457	10.1002/asia.201600943	doi.org/10.1002/asia.201600943	Rhodium(III)-Catalyzed Tandem [2+2+2] Annulation-Lactamization of Anilides with Two Alkynoates via Cleavage of Two Adjacent C-H or C-H/C-O bonds		Chem.-Asian J.	45	Shibata, Y; Tanaka, K	FALSE	FALSE	FALSE	FALSE
6458	10.1002/chem.201602668	doi.org/10.1002/chem.201602668	Nickel-Catalyzed Cross-Electrophile Coupling with Organic Reductants in Non-Amide Solvents		Chem.-Eur. J.	45	Weix, DJ	FALSE	TRUE	FALSE	FALSE
6459	10.1021/acs.oprd.6b00229	doi.org/10.1021/acs.oprd.6b00229	A Homogeneous Method for the Conveniently Scalable Palladium- and Nickel-Catalyzed Cyanation of Aryl Halides		Org. Process Res. Dev.	45	Guimond, N	FALSE	FALSE	FALSE	FALSE
6460	10.1002/slct.201600650	doi.org/10.1002/slct.201600650	Controlled, Sequential approach to Synthesize Stereogenic Methanes via in situ Generated Reactive Intermediates		ChemistrySelect	45	Ramanathan, CR	FALSE	FALSE	FALSE	FALSE
6461	10.1021/acs.orglett.6b01566	doi.org/10.1021/acs.orglett.6b01566	Solvent-Controlled, Tunable beta-OAc and beta-H Elimination in Rh(III)-Catalyzed Allyl Acetate and Aryl Amide Coupling via C-H Activation		Org. Lett.	45	Yan, H; Lu, CS	FALSE	FALSE	FALSE	FALSE
6462	10.1021/acscatal.6b00793	doi.org/10.1021/acscatal.6b00793	Nickel-Catalyzed Alkylation of Amide Derivatives		ACS Catal.	45	Garg, NK	FALSE	FALSE	FALSE	FALSE
6463	10.1016/j.tetasy.2015.11.009	doi.org/10.1016/j.tetasy.2015.11.009	Asymmetric synthesis of (R)-ar-curcumene, (R)-4,7-dimethyl-1-tetralone, and their enantiomers via cobalt-catalyzed asymmetric Kumada cross-coupling		Tetrahedron-Asymmetry	45	Bian, QH	FALSE	FALSE	FALSE	FALSE
6464	10.1039/d0dt03942j	doi.org/10.1039/d0dt03942j	From carbones to carbenes and ylides in the coordination sphere of iridium	In the presence of CuCl and (BuOLi)-O-t, PdCl2/dppe catalyzes the reaction of (benzo) oxazoles or (benzo) thiazoles with 1-aryltriazenes to yield arylated products of (benzo) oxazoles or (benzo) thiazoles. Functional groups including F, Cl, CF3, COOEt, CN, OMe, NMe2, Py, and thienyl groups can be tolerated.	Dalton Trans.	44	Ke, ZF	FALSE	FALSE	FALSE	FALSE
6465	10.24820/ark.5550190.p011.533	doi.org/10.24820/ark.5550190.p011.533	Direct arylation of heteroaromatic compounds by Pd(OAc)(2)/tetrakis(N-benzimidazoliummethyl)benzene salt system	The crystal structure of 5,10,15,20-tetra(ethoxycarbonyl)porphyrin copper(II) showed that its central copper has a six-coordinate structure. An efficient copper porphyrin-catalyzed cross-dehydrogenative coupling (CDC) esterification reaction between C(sp(3))-H and carboxylic acids using di-tert-butyl peroxide (DTBP) as an oxidant was established. The kinetic isotope effect (KIE) indicated that C(sp(3))-H bond cleavage was the rate-determining step of this CDC reaction.	Arkivoc	44	Ozdemir, I	FALSE	FALSE	FALSE	FALSE
6466	10.1021/acs.joc.0c01822	doi.org/10.1021/acs.joc.0c01822	alpha-Alkylation of Nitriles with Primary Alcohols by a Well-Defined Molecular Cobalt Catalyst	The linear or branched ally! moieties on aromatic rings are well-known as ubiquitous structural motifs found in a range of natural products and medicinally relevant molecules. They also represent an important class of organic intermediates for the transformation of an olefin group into many useful functional groups. Established methods for the installation of allylic groups rely primarily on nucleophilic substitution or transmetalation of aryl metal complexes to allyl electrophiles, Lewis acid-mediated Friedel-Crafts allylation of electron-rich arenes, and Tsuji-Trost allylation reactions with pi-allyl species. Complementing previous protocols, the transition metal-catalyzed allylation reactions via C-H activation strategy using various allylic surrogates like allylic acetates, allylic carbonates, allylic phosphonates, allylic halides, allylic alcohols, vinyl oxiranes, allenes, 1,3-dienes, and others have recently emerged as a powerful tool for creating the corresponding allyl, crotyl and prenyl moieties. This review, which includes all reported methods in the literature until the beginning of 2017, focuses on recent progress on direct allylation reactions of aromatic and vinylic C(sp(2))-H bonds with allylic sources and various transition metal catalysts.	J. Org. Chem.	44	Ding, KY	FALSE	FALSE	FALSE	FALSE
6467	10.1021/acs.orglett.0c03248	doi.org/10.1021/acs.orglett.0c03248	Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling of Aryl Halides with Dichloromethane via a Radical Process	A new transition-metal-free amination of pyridine-2-sulfonyl chloride and related N-heterocycles using magnesium amides of type R2NMgCl center dot LiCl is reported. Additionally, the directed ortho-magnesiation of pyridine-2-sulfonamides using TMPMgCl center dot LiCl was investigated. Reaction of the magnesium intermediates with various electrophiles and subsequent amination using magnesium amides led to a range of 2,3-functionalized pyridines. Also, cyclization reactions providing an aza-indole and an aza-carbazole were carried out.	Org. Lett.	44	Xu, T	TRUE	FALSE	FALSE	FALSE
6468	10.1021/acs.jafc.0c01909	doi.org/10.1021/acs.jafc.0c01909	Turpentine Derived Secondary Amines for Sustainable Crop Protection: Synthesis, Activity Evaluation and QSAR Study	A nickel half-sandwich complex supported by our original NHC ligand was developed as a robust precatalyst for Suzuki-Miyaura cross-coupling. The addition of PPh3 was a crucial element in the suppression of side reactions and in accelerating the cross-coupling reaction. By employing the optimal conditions, aryl-aryl, heteroaryl-aryl, and heteroaryl-heteroaryl couplings were achieved.	J. Agric. Food Chem.	44	Zhao, ZD	FALSE	FALSE	FALSE	FALSE
6469	10.1021/jacs.0c08512	doi.org/10.1021/jacs.0c08512	Nickel-Catalyzed C-F/N-H Annulation of Aromatic Amides with Alkynes: Activation of C-F Bonds under Mild Reaction Conditions	An efficient synthetic pathway to enyne derivatives from readily-available allenols has been accomplished using trimethyl phosphate as an inexpensive and stable activator of the hydroxy groups of the allenols in the presence of sodium hydride. The present method could be applied to various allenol derivatives to produce a variety of functionalized-enyne products.	J. Am. Chem. Soc.	44	Chatani, N	FALSE	FALSE	FALSE	FALSE
6470	10.1021/acs.orglett.0c02635	doi.org/10.1021/acs.orglett.0c02635	Iridium-Catalyzed C-Alkylation of Methyl Group on N-Heteroaromatic Compounds using Alcohols	The transition-metal-catalyzed alpha-arylation of carbonyl compounds is a widely practiced method for C-C bond formation. Several enantioselective versions of this process have been reported, but intermolecular, enantioselective coupling reactions of aryl electrophiles with alpha-fluoro carbonyl compounds have yet to be disclosed. We report enantioselective coupling of aryl and heteroaryl bromides and triflates with alpha-fluoroindanones catalyzed by palladium complexes of a BINOL-derived monophosphine and Segphos, respectively. The enolates were generated directly from alpha-fluoroindanones in the presence of potassium phosphate base during the reactions. We also report that reactions of alpha-fluorotetralones occur in high yields and enantioselectivities when conducted with enolates generated by elimination of trifluoroacetate from trifluoromethyl beta-diketone hydrates. These reactions were catalyzed by palladium complexes of the commercially available bisphosphine Difluorphos. Thus, the formation of enantioenriched alpha-aryl-alpha-fluoroketones can be readily achieved by C-C bond formation when the appropriate palladium catalyst and alpha-fluoro enolate precursor were used.	Org. Lett.	44	Fujita, K	FALSE	FALSE	FALSE	FALSE
6471	10.1002/anie.202007211	doi.org/10.1002/anie.202007211	A General Approach toO-Sulfation by a Sulfur(VI) Fluoride Exchange Reaction	A general and simple synthesis of 2,4,6-trisubstituted pyridines and fused pyridine-2-ones from bromoacetic acid is developed via a DMAP-promoted in situ activation strategy. In this protocol, readily accessible bromoacetic acid has been effectively employed as a 2C synthon to undergo formal [2+4] cycloadditions with diverse acyclic and cyclic 1-azadienes. Low costs of the reagents and materials, mild reaction conditions and broad functional-group tolerance make this protocol applicable for practical and scalable synthesis. (C) 2016 Elsevier Ltd. All rights reserved.	Angew. Chem.-Int. Edit.	44	Niu, J	FALSE	FALSE	FALSE	FALSE
6472	10.1021/acscatal.0c01462	doi.org/10.1021/acscatal.0c01462	Suzuki-Miyaura Cross-Coupling of Sulfoxides	The rhodium-catalyzed asymmetric allenylation of sulfonylimines is disclosed providing silyl homoallenylamide products in up to 99:1 er. Through subsequent activation of the C-N bond of the silyl homoallenyl sulfonamide, palladium-catalyzed stereospecific allylic allenylation could be achieved giving C-C bond formation with high chirality transfer. The synthetic utility of both the silyl homoallenyl sulfonamides and the silyl homoallenyl malonates as bis(nucleophiles) is demonstrated.	ACS Catal.	44	Shi, YH; Cao, CS	FALSE	FALSE	FALSE	FALSE
6473	10.1021/acs.macromol.0c00810	doi.org/10.1021/acs.macromol.0c00810	Rigidification of Poly(p-phenylene)s through ortho-Phenyl Substitution	A novel protocol for the synthesis of functionalized pyridines containing quaternary carbon centers through a metal-free catalytic intramolecular acylcyanation approach has been developed. Broad scope, versatility, and efficiency of the process was demonstrated.	Macromolecules	44	Mullen, K	FALSE	FALSE	FALSE	FALSE
6474	10.1021/acs.orglett.0c01600	doi.org/10.1021/acs.orglett.0c01600	Activator-Promoted Aryl Halide-Dependent Chemoselective Buchwald-Hartwig and Suzuki-Miyaura Type Cross-Coupling Reactions	A practical and greener method of the cross-coupling of vinylethylene carbonates (VECs) with arylboronic acids has been described. The coupling reaction was catalyzed by in situ generated palladium nanopartides (PdNPs) without any ligands and additional stabilizers in water under ambient conditions to provide useful 4-hydroxylprenylarenes and their derivatives in good to high yields. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Lett.	44	Uozumi, Y; Yamada, YMA	FALSE	FALSE	FALSE	FALSE
6475	10.1021/acs.orglett.0c01424	doi.org/10.1021/acs.orglett.0c01424	Nickel-Catalyzed Homo- and Cross-Coupling of Allyl Alcohols via Allyl Boronates	Air-stable, thermally robust, and well-defined cationic Ni(II) PNP pincer complexes based on the 2,4-diaminotriazine scaffold are described. These complexes are active catalysts for the Suzuki-Miyaura cross-coupling of a wide range of aryl, heteroaryl (including benzoxazole, thiazole, pyridine, pyrimidine, thiazole), primary and secondary alkyl halides, and pseudohalides with different organoboronate reagents giving excellent to good isolated yields. Neutral deprotonated complexes seem to play a key role in the catalytic process.	Org. Lett.	44	Liu, ZH	FALSE	FALSE	FALSE	FALSE
6476	10.1039/d0ob00789g	doi.org/10.1039/d0ob00789g	Acylation of oxindoles using methyl/phenyl esters via the mixed Claisen condensation - an access to 3-alkylideneoxindoles	A facile route toward 1,1-diarylethylenes 6 has been developed in good yields via mCPBA-promoted oxidation of beta-hydroxysulfides 2, BF3 center dot OEt2-mediated Friedel-Crafts reaction of the resulting beta-hydroxysulfoxides 3 with oxygenated benzenes 4, followed by Pd/C-mediated [2,3]-sigmatropic rearrangement of sulfoxides 5. The protocol provides a short-term, easy-operational, inexpensive reagent, mild condition and rapidly obtainable transformation. (C) 2016 Elsevier Ltd. All rights reserved.	Org. Biomol. Chem.	44	Gandhi, T	FALSE	FALSE	FALSE	FALSE
6477	10.1002/cctc.202000467	doi.org/10.1002/cctc.202000467	Turning on Catalysis: Construction of Triphenylphosphine Moieties into Porous Frameworks	Uncatalyzed nucleophilic reaction of 3-formylchromones with tertiary push pull enamines in refluxing acetonitrile gave polyfunctionalized benzophenone derivatives as a result of a [3-1-3] annulation in moderate to good yields. (C) 2016 Elsevier Ltd. All rights reserved.	ChemCatChem	44	Xiao, FS	FALSE	FALSE	FALSE	FALSE
6478	10.1002/ejoc.201901661	doi.org/10.1002/ejoc.201901661	Direct Amination of Isohexides via Borrowing Hydrogen Methodology: Regio- and Stereoselective Issues		Eur. J. Org. Chem.	44	Jacolot, M; Popowycz, F	FALSE	FALSE	FALSE	FALSE
6479	10.1002/adsc.201901268	doi.org/10.1002/adsc.201901268	Borinic Acid-Catalyzed Regioselective Ring-Opening of 3,4-and 2,3-Epoxy Alcohols with Halides		Adv. Synth. Catal.	44	Taylor, MS	FALSE	FALSE	FALSE	FALSE
6480	10.1039/c9sc04079j	doi.org/10.1039/c9sc04079j	Facile triflic acid-catalyzed alpha-1,2-cis-thio glycosylations: scope and application to the synthesis of S-linked oligosaccharides, glycolipids, sublancin glycopeptides, and T-N/T-F antigens		Chem. Sci.	44	Stockdill, JL; Nguyen, HM	FALSE	FALSE	FALSE	FALSE
6481	10.1021/acs.joc.9b02323	doi.org/10.1021/acs.joc.9b02323	Mn-Enabled Radical-Based Alkyl-Alkyl Cross-Coupling Reaction from 4-Alkyl-1,4-dihydropyridines		J. Org. Chem.	44	Zeng, RS; Zhao, YS	FALSE	FALSE	FALSE	FALSE
6482	10.1002/adsc.201900962	doi.org/10.1002/adsc.201900962	Tandem Transformation of Aldoximes to N-Methylated Amides Using Methanol		Adv. Synth. Catal.	44	Kundu, S	FALSE	FALSE	FALSE	FALSE
6483	10.14102/j.cnki.0254-5861.2011-2331	doi.org/10.14102/j.cnki.0254-5861.2011-2331	A New Palladium Complex Containing the Mixture of Carbene and Phosphine Ligands: Synthesis, Crystal Structure and Spectral FT-IR, NMR and UV-Vis Researches		Chin. J. Struct. Chem.	44	Aktas, A	FALSE	FALSE	FALSE	FALSE
6484	10.1055/s-0039-1689973	doi.org/10.1055/s-0039-1689973	Copper(II) Acetate Mediated Synthesis of 3-Sulfonyl-2-aryl-2H-chromenes		Synthesis	44	Chang, MY	FALSE	FALSE	FALSE	FALSE
6485	10.1021/acs.orglett.9b02473	doi.org/10.1021/acs.orglett.9b02473	Regioselective Single-Electron Tsuji-Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach		Org. Lett.	44	Molander, GA	TRUE	TRUE	FALSE	FALSE
6486	10.1021/acs.orglett.9b01593	doi.org/10.1021/acs.orglett.9b01593	Pd-Catalyzed Denitrative Intramolecular C-H Arylation		Org. Lett.	44	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
6487	10.1021/acs.orglett.9b00946	doi.org/10.1021/acs.orglett.9b00946	Highly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Ethers		Org. Lett.	44	Marek, I	FALSE	FALSE	FALSE	FALSE
6488	10.1038/s41467-019-09249-z	doi.org/10.1038/s41467-019-09249-z	Axial shielding of Pd(II) complexes enables perfect stereoretention in Suzuki-Miyaura cross-coupling of Csp(3) boronic acids		Nat. Commun.	44	Burke, MD	FALSE	FALSE	FALSE	FALSE
6489	10.1039/c8sc05170d	doi.org/10.1039/c8sc05170d	Transition-metal-free alpha-arylation of oxindoles via visible-light-promoted electron transfer		Chem. Sci.	44	Xia, CF	FALSE	FALSE	FALSE	FALSE
6490	10.1039/c9ob00111e	doi.org/10.1039/c9ob00111e	Total synthesis of levetiracetam		Org. Biomol. Chem.	44	Stecko, S	FALSE	FALSE	FALSE	FALSE
6491	10.1039/c8ob02708k	doi.org/10.1039/c8ob02708k	Copper-catalyzed arene amination in pure aqueous ammonia		Org. Biomol. Chem.	44	Takita, R	FALSE	FALSE	FALSE	FALSE
6492	10.3390/molecules23112810	doi.org/10.3390/molecules23112810	Ultrasound-Assisted Metal-Mediated Method for the Formation of Tetrahydro-3,3 '-Disubstituted Biscoumarins		Molecules	44	Nikolova, RD	FALSE	FALSE	FALSE	FALSE
6493	10.1039/c8ob01533c	doi.org/10.1039/c8ob01533c	Regioselective addition of phosphites to acyl cyclopropanes and following rearrangements: a facile access to enol phosphates		Org. Biomol. Chem.	44	Lu, DF; Gong, YF	FALSE	FALSE	FALSE	FALSE
6494	10.1002/anie.201806237	doi.org/10.1002/anie.201806237	Copper-Catalyzed Ring-Opening Silylation of Benzofurans with Disilane		Angew. Chem.-Int. Edit.	44	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
6495	10.1021/acs.joc.8b00819	doi.org/10.1021/acs.joc.8b00819	Direct Amidation of Carboxylic Acids through an Active alpha-Acyl Enol Ester Intermediate		J. Org. Chem.	44	Feng, HD; Liu, XH	FALSE	FALSE	FALSE	FALSE
6496	10.1039/c8cc03823f	doi.org/10.1039/c8cc03823f	Dual-catalytic decarbonylation of fatty acid methyl esters to form olefins		Chem. Commun.	44	Tolman, WB	FALSE	FALSE	FALSE	FALSE
6497	10.1039/c8cy00129d	doi.org/10.1039/c8cy00129d	Direct cross-coupling between atkenes and tetrahydrofuran with a platinum-loaded titanium oxide photocatalyst		Catal. Sci. Technol.	44	Yoshida, H	FALSE	FALSE	FALSE	FALSE
6498	10.1002/chem.201800744	doi.org/10.1002/chem.201800744	Asymmetric Synthesis of Diarylmethyl Sulfones by Palladium-Catalyzed Enantioselective Benzylic Substitution: A Remarkable Effect of Water		Chem.-Eur. J.	44	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
6499	10.1016/j.jechem.2017.06.003	doi.org/10.1016/j.jechem.2017.06.003	One-step synthesis of carbon-supported copper nanoparticles from biomass for N-arylation of pyrazole		J. Energy Chem.	44	Ma, D	FALSE	FALSE	FALSE	FALSE
6500	10.1002/ajoc.201700681	doi.org/10.1002/ajoc.201700681	Nickel and Copper-Catalyzed Carbonylation Reaction of Organoboranes		Asian J. Org. Chem.	44	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
6501	10.1016/j.cclet.2017.08.004	doi.org/10.1016/j.cclet.2017.08.004	Monodentate phosphorus-coordinated palladium(II) complexes as new catalyst for Mizoroki-Heck reaction of aryl halides with electron-deficient olefins		Chin. Chem. Lett.	44	Jia, XF	FALSE	FALSE	FALSE	FALSE
6502	10.1007/s11814-017-0281-0	doi.org/10.1007/s11814-017-0281-0	Enhancement in photocatalytic degradation of methylene blue by LaFeO3-GO integrated photocatalyst-adsorbents under visible light irradiation		Korean J. Chem. Eng.	44	Aziz, F	FALSE	FALSE	FALSE	FALSE
6503	10.1055/s-0036-1588548	doi.org/10.1055/s-0036-1588548	Palladium-Catalysed Cross-Coupling of Benzylammonium Salts with Boronic Acids under Mild Conditions		Synthesis	44	Phipps, RJ	FALSE	FALSE	FALSE	FALSE
6504	10.1039/c7nj02488f	doi.org/10.1039/c7nj02488f	Nickel-catalyzed reductive defunctionalization of esters and amides to aromatic hydrocarbons		New J. Chem.	44	Mondal, M	FALSE	FALSE	FALSE	FALSE
6505	10.1002/anie.201708800	doi.org/10.1002/anie.201708800	Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol		Angew. Chem.-Int. Edit.	44	Grubbs, RH	FALSE	FALSE	FALSE	FALSE
6506	10.1039/c6sc00702c	doi.org/10.1039/c6sc00702c	Nickel-catalyzed enantioselective arylation of pyridine		Chem. Sci.	44	Doyle, AG	FALSE	FALSE	FALSE	FALSE
6507	10.1039/c6ra07130a	doi.org/10.1039/c6ra07130a	Nickel-catalyzed alpha-benzylation of sulfones with esters via C-O activation		RSC Adv.	44	Chen, TQ; Han, LB	FALSE	FALSE	FALSE	FALSE
6508	10.1016/j.tet.2015.07.046	doi.org/10.1016/j.tet.2015.07.046	Selective introduction of a trifluoroacetyl group onto 4-vinylpyridines through magnesium-promoted reduction		Tetrahedron	44	Maekawa, H	FALSE	FALSE	FALSE	FALSE
6509	10.1021/acs.orglett.5b02194	doi.org/10.1021/acs.orglett.5b02194	Cyclohexenylboration of Aldehydes and Ketones with the Borabicyclo[3.3.2]decanes (BBDs)		Org. Lett.	44	Soderquist, JA	FALSE	FALSE	FALSE	FALSE
6510	10.1007/s11426-015-5466-y	doi.org/10.1007/s11426-015-5466-y	Carbon-hydrogen activation in China		Sci. China-Chem.	44	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
6511	10.1002/ejoc.201500522	doi.org/10.1002/ejoc.201500522	Pd-Catalyzed Allylic Alkynylation of Allylic Acetates with Terminal Alkynes		Eur. J. Org. Chem.	44	Fan, BM	FALSE	FALSE	FALSE	FALSE
6512	10.1016/j.jcat.2014.10.013	doi.org/10.1016/j.jcat.2014.10.013	Palladium nanocrystals stabilized by cucurbit[6]uril as efficient heterogeneous catalyst for direct C-H functionalization of polyfluoroarenes		J. Catal.	44	Cao, R	FALSE	FALSE	FALSE	FALSE
6513	10.1039/c5cc04085j	doi.org/10.1039/c5cc04085j	Iridium-catalyzed allyl-allyl cross-coupling of allylic carbonates with (E)-1,3-diarylpropenes		Chem. Commun.	44	Zhang, WB	FALSE	FALSE	FALSE	FALSE
6514	10.1021/ol5017367	doi.org/10.1021/ol5017367	Efficient Synthesis of Polysubstituted Olefins Using Stable Palladium Nanocatalyst: Applications in Synthesis of Tamoxifen and Isocombretastatin A4		Org. Lett.	44	Sekar, G	FALSE	FALSE	FALSE	FALSE
6515	10.1248/cpb.c14-00086	doi.org/10.1248/cpb.c14-00086	Design, Synthesis and Photochemical Reactivation of Caged Prodrugs of 8-Hydroxyquinoline-Based Enzyme Inhibitors		Chem. Pharm. Bull.	44	Aoki, S	TRUE	FALSE	FALSE	FALSE
6516	10.1039/c4ra00120f	doi.org/10.1039/c4ra00120f	An expedient route to heterocycles through alpha-arylation of ketones and arylamides by microwave induced thermal S(RN)1 reactions		RSC Adv.	44	Penenory, AB	FALSE	FALSE	FALSE	FALSE
6517	10.1039/c4cc05376a	doi.org/10.1039/c4cc05376a	Cu-Catalyzed Suzuki-Miyaura reactions of primary and secondary benzyl halides with arylboronates		Chem. Commun.	44	Fu, Y	FALSE	FALSE	FALSE	FALSE
6518	10.1016/j.comptc.2013.11.012	doi.org/10.1016/j.comptc.2013.11.012	The theoretical assessment and prediction of C-Br bond dissociation enthalpies		Comput. Theor. Chem.	44	Zheng, WR	FALSE	FALSE	FALSE	FALSE
6519	10.1021/ol402685g	doi.org/10.1021/ol402685g	Alternate Mode of Palladium-Catalyzed Alkynyliminium Ion Cyclizations Affording Stereodefined N-Alkyl-3-alkylidenepyrrolidines		Org. Lett.	44	Tsukamoto, H	FALSE	FALSE	FALSE	FALSE
6520	10.1002/pola.26573	doi.org/10.1002/pola.26573	Microwave-assisted suzuki coupling reaction for rapid synthesis of conjugated polymerpoly(9,9-dihexylfluorene)s as an example		J. Polym. Sci. Pol. Chem.	44	Ma, YG	FALSE	FALSE	FALSE	FALSE
6521	10.1021/ja312087x	doi.org/10.1021/ja312087x	Nickel-Catalyzed Cross-Couplings of Benzylic Pivalates with Arylboroxines: Stereospecific Formation of Diarylalkanes and Triarylmethanes		J. Am. Chem. Soc.	44	Watson, MP	FALSE	FALSE	FALSE	FALSE
6522	10.1021/ol303546p	doi.org/10.1021/ol303546p	Synthesis of Quinolones by Nickel-Catalyzed Cycloaddition via Elimination of Nitrile		Org. Lett.	44	Kurahashi, T	FALSE	FALSE	FALSE	FALSE
6523	10.1039/c3ra42434k	doi.org/10.1039/c3ra42434k	Carbon nanofibers supported molybdenum carbide catalysts for hydrodeoxygenation of vegetable oils		RSC Adv.	44	Lou, H	FALSE	FALSE	FALSE	FALSE
6524	10.1021/jo301642v	doi.org/10.1021/jo301642v	Scope of the Two-Step, One-Pot Palladium-Catalyzed Borylation/Suzuki Cross-Coupling Reaction Utilizing Bis-Boronic Acid		J. Org. Chem.	44	Molander, GA	FALSE	FALSE	FALSE	FALSE
6525	10.1021/ol301713j	doi.org/10.1021/ol301713j	Palladium-Catalyzed Nitromethylation of Aryl Halides: An Orthogonal Formylation Equivalent		Org. Lett.	44	Kozlowski, MC	FALSE	FALSE	FALSE	FALSE
6526	10.1016/j.tet.2012.05.021	doi.org/10.1016/j.tet.2012.05.021	An efficient synthesis of enol phosphates via organic base-promoted addition of phosphites to 4-oxo-enoates		Tetrahedron	44	Lu, LQ	FALSE	FALSE	FALSE	FALSE
6527	10.1055/s-0031-1291127	doi.org/10.1055/s-0031-1291127	Bidentate Lewis Acid Catalyzed Inverse-Electron-Demand Diels-Alder Reaction for the Selective Functionalization of Aldehydes		Synthesis	44	Wegner, HA	FALSE	TRUE	FALSE	FALSE
6528	10.1055/s-0031-1290504	doi.org/10.1055/s-0031-1290504	A Concise Synthesis of 3-Arylated Di- and Tetrahydro-2H-2-benzazepin-1-ones; A New Synthetic Approach to the Homoprotoberberine Framework		Synthesis	44	Couture, A	FALSE	FALSE	FALSE	FALSE
6529	10.1021/ol3001552	doi.org/10.1021/ol3001552	Ni- and Pd-Catalyzed Synthesis of Substituted and Functionalized Allylic Boronates		Org. Lett.	44	Morken, JP	FALSE	FALSE	FALSE	FALSE
6530	10.1021/jo2009164	doi.org/10.1021/jo2009164	Stereoselective Palladium-Catalyzed alpha-Arylation of 3-Aryl-1-Indanones: An Asymmetric Synthesis of (+)-Pauciflorol F		J. Org. Chem.	44	Heo, JN	FALSE	FALSE	FALSE	FALSE
6531	10.1002/adsc.201000710	doi.org/10.1002/adsc.201000710	Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-Effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride [Ni(dppp)Cl-2] with only 1 mol% Loading		Adv. Synth. Catal.	44	Han, FS	FALSE	FALSE	FALSE	FALSE
6532	10.1002/anie.201103599	doi.org/10.1002/anie.201103599	Rearrangement of 2-Aryloxybenzaldehydes to 2-Hydroxybenzophenones by Rhodium-Catalyzed Cleavage of Aryloxy C-O Bonds		Angew. Chem.-Int. Edit.	44	Li, CJ	FALSE	FALSE	FALSE	FALSE
6533	10.1021/ol100493v	doi.org/10.1021/ol100493v	Combined Directed ortho Metalation-Halogen Dance (HD) Synthetic Strategies. HD-Anionic ortho Fries Rearrangement and Double HD Sequences		Org. Lett.	44	Snieckus, V	FALSE	FALSE	FALSE	FALSE
6534	10.1016/j.jorganchem.2010.02.007	doi.org/10.1016/j.jorganchem.2010.02.007	Carbon-nitrogen bond activation of amines by rhodium(III) porphyrin complexes		J. Organomet. Chem.	44	Chan, KS	FALSE	FALSE	FALSE	FALSE
6535	10.1055/s-0029-1219365	doi.org/10.1055/s-0029-1219365	New Regiospecific Catalytic Approaches to 4,5-Dihydroisoxazoles and 2,5-Dihydroisoxazoles from O-Propargylic Hydroxylamines		Synlett	44	Knight, DW	FALSE	FALSE	FALSE	FALSE
6536	10.1016/j.jorganchem.2009.09.044	doi.org/10.1016/j.jorganchem.2009.09.044	Sulfonyl transfer mechanism in C-S coupling of phenylmagnesium bromide with phenyl arenesulfonates		J. Organomet. Chem.	44	Erdik, E	FALSE	FALSE	FALSE	FALSE
6537	10.1055/s-0029-1219165	doi.org/10.1055/s-0029-1219165	Directed ortho- and meta-Magnesiation or Zincation of Polyfunctional Aryl Nonaflates		Synlett	44	Knochel, P	FALSE	FALSE	FALSE	FALSE
6538	10.1021/jo902235h	doi.org/10.1021/jo902235h	N-Heterocyclic Carbene-Catalyzed Monoacylation of 1,4-Naphthoquinones with Aldehydes		J. Org. Chem.	44	Csaky, AG	FALSE	FALSE	FALSE	FALSE
6539	10.1016/j.tetlet.2009.05.064	doi.org/10.1016/j.tetlet.2009.05.064	Pd-CNT-catalyzed ligandless and additive-free heterogeneous Suzuki-Miyaura cross-coupling of arylbromides		Tetrahedron Lett.	44	Wang, B	FALSE	FALSE	FALSE	FALSE
6540	10.1021/jo070528n	doi.org/10.1021/jo070528n	Easy access to new heterocyclic systems: 1,4-oxazine and substituted 1,4-oxazines		J. Org. Chem.	44	Gillaizeau, I	FALSE	FALSE	FALSE	FALSE
6541	10.1021/jo062385v	doi.org/10.1021/jo062385v	Directed Ortho metalation-cross coupling strategies. N-cumyl arylsulfonamides. Facile deprotection and expedient route to 7- and 4,7-substituted saccharins		J. Org. Chem.	44	Snieckus, V	FALSE	FALSE	FALSE	FALSE
6542	10.1055/s-2007-965958	doi.org/10.1055/s-2007-965958	TBAB-promoted ligand-free copper-catalyzed cross-coupling reactions of aryl halides with arylboronic acids		Synthesis	44	Li, JH	FALSE	FALSE	FALSE	FALSE
6543	10.1016/j.tetlet.2007.01.175	doi.org/10.1016/j.tetlet.2007.01.175	Nickel(II)-aryl complexes as catalysts for the Suzuki cross-coupling reaction of chloroarenes and arylboronic acids		Tetrahedron Lett.	44	Yang, LM	FALSE	FALSE	FALSE	FALSE
6544	10.1002/anie.200603631	doi.org/10.1002/anie.200603631	Direct ortho iodination of beta- and gamma-aryl alkylamine derivatives		Angew. Chem.-Int. Edit.	44	Barluenga, J	FALSE	FALSE	FALSE	FALSE
6545	10.1021/ol062344l	doi.org/10.1021/ol062344l	Cobalt-catalyzed aryl-sulfur bond formation		Org. Lett.	44	Wong, YC	FALSE	FALSE	FALSE	FALSE
6546	10.1021/jo0607360	doi.org/10.1021/jo0607360	Synthesis and reactivity of imide-derived bisvinyl phosphates. Reactivity of 2,6-disubstituted 1,4-dihydropyridines		J. Org. Chem.	44	Gillaizeau, I	FALSE	FALSE	FALSE	FALSE
6547	10.1021/jo048300c	doi.org/10.1021/jo048300c	Nickel-catalyzed cross-coupling of neopentyl arenesulfonates with methyl and primary alkylmagnesium bromides		J. Org. Chem.	44	Park, K	FALSE	FALSE	FALSE	FALSE
6548	10.1021/jo001614p	doi.org/10.1021/jo001614p	Asymmetric hydrosilylation of styrenes catalyzed by palladium-MOP complexes: Ligand modification and mechanistic studies		J. Org. Chem.	44	Hayashi, T	FALSE	FALSE	FALSE	FALSE
6549	10.1016/S0920-5861(00)00404-1	doi.org/10.1016/S0920-5861(00)00404-1	Axially chiral monophosphine ligands (MOPs) and their use for palladium-catalyzed asymmetric hydrosilylation of olefins		Catal. Today	44	Hayashi, T	FALSE	FALSE	FALSE	FALSE
6550	10.1021/ja993071a	doi.org/10.1021/ja993071a	Synthesis, crystal structure, magnetic, and electron paramagnetic resonance properties of a spiroconjugated biradical. Evidence for spiroconjugation exchange pathway		J. Am. Chem. Soc.	44	Kahn, O	FALSE	FALSE	FALSE	FALSE
6551	10.1002/(SICI)1099-0488(19980930)36:13<2449::AID-POLB19>3.0.CO;2-3	doi.org/10.1002/(SICI)1099-0488(19980930)36:13<2449::AID-POLB19>3.0.CO;2-3	Chain conformation of rod-like polymers in the melt: Small-angle neutron scattering of poly(benzoyl paraphenylene)		J. Polym. Sci. Pt. B-Polym. Phys.	44	Vaia, RA	FALSE	FALSE	FALSE	FALSE
6552	10.1038/32623	doi.org/10.1038/32623	Total synthesis of brevetoxin A		Nature	44	Nicolaou, KC	FALSE	FALSE	FALSE	FALSE
6553	10.1021/om970842f	doi.org/10.1021/om970842f	Nitrile-group transfer from solvents to aryl halides. Novel carbon-carbon bond formation and cleavage mediated by palladium and zinc species		Organometallics	44	Cheng, CH	FALSE	FALSE	FALSE	FALSE
6554	10.1039/a607663g	doi.org/10.1039/a607663g	Chelation-assisted nucleophilic aromatic substitution of 2-sulfonyl-substituted 1-methoxynaphthalenes by Grignard-reagents: Factors determining the activating ability of the 2-sulfonyl substituents		J. Chem. Soc.-Perkin Trans. 1	44		FALSE	FALSE	FALSE	FALSE
6555	10.1016/0040-4039(96)01291-9	doi.org/10.1016/0040-4039(96)01291-9	A new approach to (+)-brefeldin A via a nickel-catalyzed coupling reaction of cyclopentenyl acetate and lithium 2-furylborate		Tetrahedron Lett.	44	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
6556	10.1021/jo00119a022	doi.org/10.1021/jo00119a022	HIGHLY SELECTIVE AND PRACTICAL ALKYNE-ALKYNE CROSS-COUPLING USING CP(2)ZRBU(2) AND ETHYLENE		J. Org. Chem.	44		FALSE	FALSE	FALSE	FALSE
6557	10.1021/jo00258a047	doi.org/10.1021/jo00258a047	TRANSITION-METAL PROMOTED REACTIONS .25. REGIOSELECTIVE SILYLOLEFINATION OF ALLYLIC DITHIOACETALS - STEREOSELECTIVE SYNTHESIS OF 1-(TRIMETHYLSILYL)BUTADIENES		J. Org. Chem.	44		FALSE	FALSE	FALSE	FALSE
6558	10.1246/bcsj.57.480	doi.org/10.1246/bcsj.57.480	REGIOSELECTIVE HOMOMERIZATION AND CODIMERIZATION OF 1-ALKYNES LEADING TO 2,4-DISUBSTITUTED 1-BUTEN-3-YNES BY CATALYSIS OF A (ETA-5-C5ME5)2TICL2/RMGX SYSTEM		Bull. Chem. Soc. Jpn.	44		FALSE	FALSE	FALSE	FALSE
6559	10.1021/acs.orglett.1c04000	doi.org/10.1021/acs.orglett.1c04000	Ligand-Enabled C-H Olefination and Lactonization of Benzoic Acids and Phenylacetic Acids via Palladium Catalyst		Org. Lett.	44	Ji, YF	FALSE	FALSE	FALSE	FALSE
6560	10.1002/anie.202110391	doi.org/10.1002/anie.202110391	Chemoselective and Diastereoselective Synthesis of C-Aryl Nucleoside Analogues by Nickel-Catalyzed Cross-Coupling of Furanosyl Acetates with Aryl Iodides		Angew. Chem.-Int. Edit.	44	Li, C	FALSE	FALSE	FALSE	FALSE
6561	10.3390/molecules26216703	doi.org/10.3390/molecules26216703	Non-C-2-Symmetric Bis-Benzimidazolium Salt Applied in the Synthesis of Sterically Hindered Biaryls		Molecules	44	Lee, DS	FALSE	FALSE	FALSE	FALSE
6562	10.1055/a-1677-4881	doi.org/10.1055/a-1677-4881	An Oxidant- and Catalyst-Free Synthesis of Dibenzo[a,c]carbazoles via UV Light Irradiation of 2,3-Diphenyl-1H-indoles		Synthesis	44	Zhang, ZT	FALSE	FALSE	FALSE	FALSE
6563	10.1080/00958972.2021.1955251	doi.org/10.1080/00958972.2021.1955251	Synthesis and characterization of Mo(0) and W(0) complexes of bis(azol-1-yl)methane based bisphosphines		J. Coord. Chem.	44	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
6564	10.1039/d1qo00930c	doi.org/10.1039/d1qo00930c	An alternative mode to activate alcohols: application to the synthesis of N-heteroarene derivatives		Org. Chem. Front.	44	Taillefer, M	FALSE	FALSE	FALSE	FALSE
6565	10.1021/acs.orglett.1c01649	doi.org/10.1021/acs.orglett.1c01649	Nickel-Catalyzed Diastereoselective Reductive Cross-Coupling of Disubstituted Cycloalkyl Iodides with Aryl Iodides		Org. Lett.	44	Shen, ZL	FALSE	FALSE	FALSE	FALSE
6566	10.1021/acs.joc.1c00532	doi.org/10.1021/acs.joc.1c00532	Iodide-Mediated [3+2]-Cycloaddition Reaction with N-Tosylaziridines and alpha,beta-Unsaturated Ketones		J. Org. Chem.	44	Hosokawa, S	FALSE	FALSE	FALSE	FALSE
6567	10.1021/acs.orglett.1c00855	doi.org/10.1021/acs.orglett.1c00855	Hexafluoroisopropyl Sulfamate: A Useful Reagent for the Synthesis of Sulfamates and Sulfamides		Org. Lett.	44	Johnson, JW; Magolan, J	FALSE	FALSE	FALSE	FALSE
6568	10.1016/j.tetlet.2021.152916	doi.org/10.1016/j.tetlet.2021.152916	Nickel-catalyzed hydroalkylation of 1,3-dienes with malonates using a homoallyl carbonate as the 1,3-diene and hydride source		Tetrahedron Lett.	44	Tsuji, H; Kawatsura, M	FALSE	FALSE	FALSE	FALSE
6569	10.1002/adsc.201700672	doi.org/10.1002/adsc.201700672	Bisphosphine-Ligated Nickel Pre-catalysts in C(sp(2))-N Cross-Couplings of Aryl Chlorides: A Comparison of Nickel(I) and Nickel(II)		Adv. Synth. Catal.	44	Johnson, ER; Stradiotto, M	FALSE	FALSE	FALSE	FALSE
6570	10.1246/cl.170533	doi.org/10.1246/cl.170533	pi-Allyl Donicity Switch in Catalytic Asymmetric Allylation: Usability of a Robust and Feasible Allyl Methyl Ether		Chem. Lett.	44	Kitamura, M	FALSE	FALSE	FALSE	FALSE
6571	10.1021/jacs.7b06288	doi.org/10.1021/jacs.7b06288	Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer		J. Am. Chem. Soc.	44	Molander, GA	FALSE	FALSE	FALSE	FALSE
6572	10.1021/acs.orglett.7b01513	doi.org/10.1021/acs.orglett.7b01513	Synthesis of (-)-6,7-Dideoxysqualestatin H5 by Carbonyl Ylide Cycloaddition-Rearrangement and Cross-electrophile Coupling		Org. Lett.	44	Hodgson, DM	FALSE	FALSE	FALSE	FALSE
6573	10.1038/ncomms14878	doi.org/10.1038/ncomms14878	Direct amidation of esters with nitroarenes		Nat. Commun.	44	Hu, XL	FALSE	FALSE	FALSE	FALSE
6574	10.1016/j.jorganchem.2017.01.009	doi.org/10.1016/j.jorganchem.2017.01.009	Cp2TiCl2-catalyzed cycloboration of alpha-olefins with PhBCl2 in the synthesis of 2-alkyl(aryl,benzyl)-1-phenylboriranes		J. Organomet. Chem.	44	Khafizova, LO	FALSE	FALSE	FALSE	FALSE
6575	10.1002/slct.201601809	doi.org/10.1002/slct.201601809	Cu(II)-Et-S@MCM-41: A Green and Cost-Effective Catalytic System for S-arylation of Aryl Halides Using Thiourea and Benzyl Bromide		ChemistrySelect	44	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
6576	10.1016/j.bioorg.2016.09.006	doi.org/10.1016/j.bioorg.2016.09.006	Coumarin sulfonates: As potential leads for ROS inhibition		Bioorganic Chem.	44	Khan, KM	FALSE	FALSE	FALSE	FALSE
6577	10.1016/j.poly.2016.05.037	doi.org/10.1016/j.poly.2016.05.037	Nickel(II) Schiff base complexes: Synthesis, characterization and catalytic activity in Kumada-Corriu cross-coupling reactions		Polyhedron	44	Kuchtanin, V	FALSE	FALSE	FALSE	FALSE
6578	10.1021/acs.orglett.6b02235	doi.org/10.1021/acs.orglett.6b02235	Phosphine-Triggered Selectivity Switch in Silver-Catalyzed o-Alkynylbenzohydroxamic Acid Cycloisomerizations		Org. Lett.	44	Belmont, P	FALSE	FALSE	FALSE	FALSE
6579	10.1002/anie.201602075	doi.org/10.1002/anie.201602075	Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with alpha-Naphthylbenzyl Carbonates and Pivalates		Angew. Chem.-Int. Edit.	44	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
6580	10.1021/acs.orglett.6b00757	doi.org/10.1021/acs.orglett.6b00757	Type 1 Ring-Opening Reactions of Cyclopropanated 7-Azabenzonorbornadienes with Organocuprates		Org. Lett.	44	Tam, W	FALSE	FALSE	FALSE	FALSE
6581	10.1039/d0sc06586b	doi.org/10.1039/d0sc06586b	Ruthenium catalyzed beta-selective alkylation of vinylpyridines with aldehydes/ketones via N2H4 mediated deoxygenative couplings	The influence of ancillary ligand and nickel oxidation state in the nickel-catalyzed C(sp(2))-N cross-coupling of aryl chlorides is examined by use of experimental and DFT methods for the first time, focusing on (L) NiCl and (L) Ni(o-tolyl) Cl pre-catalysts (PAd-DalPhos, L1; dppf, L2). Whereas Ni(II) pre-catalysts generally out-performed Ni(I) species in our study, the viability and in some cases superiority of Ni(I) pre-catalysts in challenging aminations is established. Computational analyses support the viability of Ni(0)/Ni(II) cycles featuring rate-limiting CN reductive elimination, as well as parallel Ni(I)/Ni(III) mechanisms involving rate-limiting C-Cl oxidative addition.	Chem. Sci.	43	Lv, LY	FALSE	FALSE	FALSE	FALSE
6582	10.1055/a-1374-9384	doi.org/10.1055/a-1374-9384	Visible-Light-Mediated Z-Stereoselective Monoalkylation of beta,beta-Dichlorostyrenes by Photoredox/Nickel Dual Catalysis	A highly enantioselective arylation of unactivated racemic secondary allylic alcohols with aniline derivatives has been develdped. The transformation was enabled by an iridium-chiral cyclic phosphoramidite complex in the presence of boron trifluotide djeihyl etherate the promoter, and the reactivity and enantioselectiyity of the substrates were tuned by the variation of our newly-developed chiral cyclic phosphoramidite ligands together with temperature and solvents. The method shows advantages including use of the readily available starting materials, an operationally convenient protocol, full regioselectivity and excellent enaritioseleativity, and tolerance of many functional groups with water as the only byproduct.	Synlett	43	Ollivier, C; Fensterbank, L	TRUE	FALSE	FALSE	FALSE
6583	10.1021/acs.joc.0c02663	doi.org/10.1021/acs.joc.0c02663	Photocatalytic Reductive C-O Bond Cleavage of Alkyl Aryl Ethers by Using Carbazole Catalysts with Cesium Carbonate	We report herein the highly enantioselective synthesis of 2-substituted tetrahydroquinolines through borrowing hydrogen, a process recognized for its environmentally benign and atom-economical nature. The use of an achiral iridacycle complex in combination with a chiral phosphoric acid as catalysts was the key to the development of this highly efficient and enantioselective transformation.	J. Org. Chem.	43	Matsubara, R	TRUE	FALSE	FALSE	FALSE
6584	10.1021/acs.joc.0c02350	doi.org/10.1021/acs.joc.0c02350	Coupling of Alternating Current to Transition-Metal Catalysis: Examples of Nickel-Catalyzed Cross-Coupling	Under the conditions of nickel(0) catalysis, enantiomerically enriched vinyl dioxanones engage boroxines or B-2(pin)(2) in stereospecific cross-coupling to form diverse tetrasubstituted cyclopropanes bearing all-carbon quaternary stereocenters. The collective data corroborate a mechanism involving nickel(0)-mediated benzylic oxidative addition with inversion of stereochemistry followed by reversible olefin insertion to form a (cyclopropylcarbinyl)nickel complex, which upon reductive elimination releases the cyclopropane.	J. Org. Chem.	43	Semenov, SN	FALSE	FALSE	FALSE	FALSE
6585	10.3390/molecules26010188	doi.org/10.3390/molecules26010188	Transamidation of Amides and Amidation of Esters by Selective N-C(O)/O-C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)-NHC Complexes	We have developed a copper-catalyzed enantioselective intermolecular aminoarylation of alkenes using a novel N-fluoro-N-alkylsulfonamide as the amine reagent, which could react with the Cu(I) catalyst to release a related amino radical. After addition to styrene, the generated benzylic radical could couple with a chiral L*(CuAr)-Ar-II complex to achieve enantioselective arylation. Various optical 2,2-diarylethylamines were efficiently synthesized from simple styrenes with high enantioselectivity, and these products can serve as valuable synthons toward bioactive molecules' synthesis.	Molecules	43	Szostak, M	FALSE	FALSE	FALSE	FALSE
6586	10.1039/d0cc05306f	doi.org/10.1039/d0cc05306f	Photoinduced umpolung addition of carbonyl compounds with alpha,beta-unsaturated esters enables the polysubstituted gamma-lactone formation	Bimetallic catalysis represents an alternative paradigm for coupling chemistry that complements the more traditional single-site catalysis approach. In this perspective, recent advances in bimetallic systems for catalytic C-C and C-X coupling reactions are reviewed. Behavior which complements that of established single-site catalysts is highlighted. Two major reaction classes are covered. First, generation of catalytic amounts of organometallic species of e.g. Cu,Au,or Ni capable of transmetallation to a Pd co- catalyst (or other traditional cross-coupling catalyst) has allowed important new C-C coupling technologies to emerge. Second, catalytic transformations involving binuclear bond-breaking and/epresent a frontier area for C-C and C-X coupling processes.	Chem. Commun.	43	He, YH; Guan, Z	TRUE	FALSE	FALSE	FALSE
6587	10.1002/aoc.6032	doi.org/10.1002/aoc.6032	Nickel-Copper bimetallic mesoporous nanoparticles: As an efficient heterogeneous catalyst for N-alkylation of amines with alcohols	A convergent three-step method for the synthesis of 2-substituted chromans is described. These results have been accomplished via the Heck coupling of readily accessible allylic alcohols and 2-iodophenols, followed by reduction and Mitsunobu cyclization. The utility and generality of this method is demonstrated through the synthesis of a series of 2-aryl-, 2-heteroaryl-and 2-alkylchromans, as well as an azachroman derivative. The asymmetric version of this approach via a Noyori-catalyzed ketone reduction and subsequent cyclization is likewise highlighted.	Appl. Organomet. Chem.	43	Kassaee, MZ	FALSE	FALSE	FALSE	FALSE
6588	10.1021/acs.organomet.0c00573	doi.org/10.1021/acs.organomet.0c00573	Palladium-Catalyzed Solvent-Free Preparation of Arylphosphonates ArP(O)(OAr)(2) from (ArO)(3)P via the Michaelis-Arbuzov Rearrangement	Five novel silver(I) complexes and two copper(I) phosphine complexes containing the bis[2-(diphenylphosphino)phenyllether ligand were synthesized and structurally characterized. Treatment of AgX/CuX and the bis[2-(diphenylphosphino)phenyl]ether with N boolean AND N ligands afforded the silver(I) or copper(I) complexes {[Ag-2(P)(2)(dpa)(H2O)(2)](dpa)(ClO4)(2)}(n) (1), {[Ag(POP)(dpp)](ClO4)}(n) (2), [Ag-2(POP)(2)(4,4'bipy)(CH3CN)(2)](CF3SO3)(2)center dot CH3CN (3), {[Ag(POP)(dpe)](CF3SO3)center dot CH3CN}(n) (4), {[Ag-2(POP)(2)(dpe)(H2O)(2)](dpe) (BF4)(2)}(n) (5), [Cu(POP)(bpy)](BF4) (6) and [Cu-2(POP)(2)(4,4'-bipy)](CF3SO3)(2)center dot 4CH(3)CN (7) {POP = bis[2-(diphenylphosphino)phenyllether; dpp = 1,3-bis(4-pyridyl)propane; dpa = 1,2-bis(4-pyridyl)ethane; dpe = 1,2-bis(4-pyridyl)ethene; 4,4'-bipy = 4,4'-bipyridine; bpy = 2,2'-bipyridine}. These complexes are all characterized by IR, elemental analysis, X-ray diffraction, luminescence, P-31 NMR and H-1 NMR spectroscopy. Complex 5 has an irregular (6,3) network structure connected through hydrogen bonds between the C-H groups of aromatic rings and anions; complexes 1 and 2 are of 2D topological architectures which are linked by hydrogen bonds; complex 4 is of a 1D infinite zigzag chain structure formed by the bridging ligand dpe; complexes 3 and 7 are of dinuclear structures and complex 6 is of mononuclear structure. The choice of solvent and the type and coordination modes of the bipyridine derivatives are of importance in defining the structural and topological features of the resulting networks. In addition, the complexes 1-7 exhibit interesting luminescence in the solid state at room temperature. At the same time, we also studied the terahertz spectrum which provided some new informations of these complexes. (C) 2016 Elsevier Ltd. All rights reserved.	Organometallics	43	Han, LB	FALSE	FALSE	FALSE	FALSE
6589	10.1039/d0sc03217d	doi.org/10.1039/d0sc03217d	Nickel-catalyzed migratory alkyl-alkyl cross-coupling reaction	Wittig reactions between benzaldehyde derivatives and a nonstabilized phosphonium ylide bearing a phosphastibatriptycene skeleton, regarded as a tridentate aryl ligand, gave (E)-alkenes with high selectivity in the presence of both lithium and sodium salts. As previously reported, reactions between a triphenylphosphonium ylide and benzaldehyde derivatives under the same conditions afforded mainly (Z)-alkenes. Variable-temperature (VT) P-31{H-1} NMR spectra showed two signals, assigned to cis-and trans-1,2-oxaphosphetanes, which were observed at different temperatures (-80 degrees C and -40 degrees C, respectively) in the Wittig reaction between benzaldehyde and the nonstabilized phosphonium ylide bearing the phosphastibatriptycene skeleton, in the presence of both lithium and sodium salts, and showed the existence of equilibrium between these products at -40 degrees C. On the other hand, this equilibrium was not clearly observed in the reaction between the triphenylphosphonium ylide and benzaldehyde, for which only one signal was detected. The observed intermediates were confirmed to be 1,2-oxaphosphetanes by deprotonation of the isolated beta-hydroxyalkylphosphonium salts bearing a phosphastibatriptycene skeleton and a triphenylphosphine moiety, respectively. Crossover reactions were conducted in the deprotonations of beta-hydroxyalkylphosphonium salts with TMS2NNa in the presence of p-chlorobenzaldehyde, resulting in the observation of signals corresponding to 1,2-oxaphosphetanes containing phenyl and p-chlorophenyl groups at the 4-positions, indicating the exchange process between benzaldehyde and p-chlorobenzaldehyde at -40 degrees C for the phosphastibatriptycene system and at 0 degrees C for triphenyl derivatives. These results clearly indicated that stereochemical drift occurred at those temperatures, even in reactions using nonstabilized phosphonium ylides. The stereochemical drift in the phosphastibatriptycene system occurred at a lower temperature than in the case of the triphenyl derivative, thus explaining the (E)-selective Wittig reactions between the benzaldehyde derivatives and the nonstabilized phosphastibatriptycene-based phosphonium ylide in the presence of lithium and sodium salts.	Chem. Sci.	43	Yin, GY	FALSE	FALSE	FALSE	FALSE
6590	10.1021/jacs.0c05901	doi.org/10.1021/jacs.0c05901	Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity	Cross-coupling of various O-based electrophiles with aryl bromides was developed through Ni-catalyzed C-O activation in the presence of magnesium. Beside carboxylates, carbamates, and ethers, phenols exhibited excellent reactivity under modified conditions. This chemistry was featured as a simple and environmentally benign process with low catalyst loading and easy manipulations. The method exhibited broad substrate scopes.	J. Am. Chem. Soc.	43	MacMillan, DWC	TRUE	FALSE	FALSE	FALSE
6591	10.1016/j.inoche.2020.107993	doi.org/10.1016/j.inoche.2020.107993	Synthesis and characterization of Pd based on [2,2 '-bipyridin]-4-amine functionalized nano cellulose as a novel and recyclable nano catalyst for Suzuki reaction	An efficient one-pot method for the synthesis of organic disulfides from aryl and alkyl halides and potassium sulfide has been described. K2S acts as an inexpensive and readily available sulfur source. A variety of symmetric diaryl and dialkyl disulfides was prepared in good to excellent yields using NiCl2 center dot 6H(2)O and acetylacetone as the catalytic system.	Inorg. Chem. Commun.	43	Sun, YQ	FALSE	FALSE	FALSE	FALSE
6592	10.1038/s41586-020-2399-1	doi.org/10.1038/s41586-020-2399-1	Desymmetrization of difluoromethylene groups by C-F bond activation	A Ru-catalyzed direct olefination of electron deficient alkenes with allyl acetate via C-H bond activation is disclosed. By using N,N-disubstituted aminocarbonyl as the directing group, this external oxidant-free protocol resulted in high reaction efficiency and good stereo- and regioselectivities, which opens a novel synthetic passway for access to (Z,E)-butadiene skeletons.	Nature	43	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6593	10.1039/d0gc00763c	doi.org/10.1039/d0gc00763c	A practical and concise homogeneous nickel catalyst for efficient solvent-free synthesis of gamma-valerolactone	Several new amino-type secondary phosphine oxide (SPO) pre-ligands (3a-3h) that contain P-N bonds were synthesized and characterized. SPOs 3a-3h can tautomerize to phosphinous acids (PA, 3a-3h) as genuine ligands. The formation of SPOs 3a-3h occurred first through nucleophilic attack on the imine carbon atom, then by the addition of RPCl2 (R = Ph, Cy, tBu, or iPr), and work-up under acidic conditions. The P-N bond in the newly prepared SPOs is evident from the crystal structures of SPOs 3d and 3h. Reactions of SPOs 3f, 3g, or 3h with Pd(COD)Cl-2 (COD = cyclooctadiene) yielded palladium complexes 6f, 6g, or 6h. In these crystal structures, PAs 3f, 3g, and 3h act as didentate ligands through P and N donors. Intriguingly, the reaction of SPO 3f with Pd(COD)Cl-2 also gave rise to palladium complexes 7fa, 7fb, and 8f. The crystal structures of 7fa and 7fb show that the palladium atom is chelated by PA 3f and coordinated by a phosphine-like ligand fragmented from SPO 3f through C-N bond dissociation. Finally, the syntheses of carbazole derivatives were pursued in Catellani reactions with SPOs 3g and 3h as pre-ligands. A mechanism is proposed to account for the catalytic reaction (see the Supporting Information). The optimized conditions for Suzuki reactions using selected SPO ligands are also reported.	Green Chem.	43	Deng, J; Fu, Y	FALSE	FALSE	FALSE	FALSE
6594	10.3390/catal10040372	doi.org/10.3390/catal10040372	Suzuki-Miyaura Cross-Coupling of Amides Using Well-Defined, Air- and Moisture-Stable Nickel/NHC (NHC = N-Heterocyclic Carbene) Complexes	Copper(I)/ligand-catalyzed one pot synthesis of highly substituted 2,3-difunctionalized-4-chlorofurans has been reported. The reaction proceeds via a Cu(I)-catalyzed regioselective 5-endo-trig radical cyclization of 2,2,2-trichlorethyl vinyl ethers followed by the base-promoted dehydrochlorination. The success of the kinetically disfavored 5-endo cyclization was attributed to the formation of captodatively stabilized radical intermediate in the cyclization step and relatively high reaction temperature. Synthetic application of this protocol was also demonstrated in the preparation of alkyl and aryl substituted 4-chlorofuranonapthoquinones.	Catalysts	43	Szostak, M	FALSE	FALSE	FALSE	FALSE
6595	10.1016/j.jcat.2020.01.021	doi.org/10.1016/j.jcat.2020.01.021	Replacement of Pd nanoparticles: Hydrogenation promoted by frustrated Lewis acid-base pairs in carbon quantum dots	Organic catalysts have found wide applications in organic synthesis. Many organic reactions, which originally do not occur under normal conditions or are difficult to operate normally, have been successfully conducted under mild conditions in the presence of catalysts. In recent years, 2,4,6-trichloro-1,3,5-triazine (TCT, cyanuric chloride) has been used as organic catalyst in many organic synthesis, because it is stable, nonvolatile, inexpensive, commercially available, and easy to handle. On account of these properties it has been used as a green catalyst and sometimes is a catalyst of choice in organic reactions. [GRAPHICS]	J. Catal.	43	Lin, W; Li, ZH	FALSE	FALSE	FALSE	FALSE
6596	10.1021/acscatal.9b05049	doi.org/10.1021/acscatal.9b05049	Reductive Cleavage of Azoarene as a Key Step in Nickel-Catalyzed Amidation of Esters with Nitroarenes		ACS Catal.	43	Harvey, JN	FALSE	FALSE	FALSE	FALSE
6597	10.1039/c9sc03737c	doi.org/10.1039/c9sc03737c	Light-enabled metal-free pinacol coupling by hydrazine		Chem. Sci.	43	Khaliullin, RZ; Li, CJ	FALSE	FALSE	FALSE	FALSE
6598	10.1021/acs.jpca.9b07043	doi.org/10.1021/acs.jpca.9b07043	Computational Insight into the Mechanism of Ruthenium(II)Catalyzed alpha-Alkylation of Arylmethyl Nitriles Using Alcohols		J. Phys. Chem. A	43	Zhang, X	FALSE	FALSE	FALSE	FALSE
6599	10.1021/acscatal.9b02779	doi.org/10.1021/acscatal.9b02779	Direct Synthesis of Nitriles from Carboxylic Acids Using Indium-Catalyzed Transnitrilation: Mechanistic and Kinetic Study		ACS Catal.	43	Vanoye, L; Favre-Reguillon, A	FALSE	FALSE	FALSE	FALSE
6600	10.1002/ejoc.201901291	doi.org/10.1002/ejoc.201901291	Solvent-Free N-Alkylation of Amides with Alcohols Catalyzed by Nickel on Silica-Alumina		Eur. J. Org. Chem.	43	Duguet, N; Metay, E	FALSE	FALSE	FALSE	FALSE
6601	10.1016/j.tetlet.2019.151105	doi.org/10.1016/j.tetlet.2019.151105	Synthesis of isoindolinones: Intramolecular [4+2] cycloaddition/retro [4+2] of pyridone propiolamides		Tetrahedron Lett.	43	Wilson, JE	FALSE	FALSE	FALSE	FALSE
6602	10.1021/acs.joc.9b02105	doi.org/10.1021/acs.joc.9b02105	Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium Arylborates		J. Org. Chem.	43	Duong, HA	FALSE	FALSE	FALSE	FALSE
6603	10.1021/jacs.9b08504	doi.org/10.1021/jacs.9b08504	Nonsymmetrical Bis-Azine Biaryls from Chloroazines: A Strategy Using Phosphorus Ligand-Coupling		J. Am. Chem. Soc.	43	McNally, A	FALSE	FALSE	FALSE	FALSE
6604	10.1039/c9cc04726c	doi.org/10.1039/c9cc04726c	Photo-nickel dual catalytic benzoylation of aryl bromides		Chem. Commun.	43	Konig, B	TRUE	FALSE	FALSE	FALSE
6605	10.1021/acs.organomet.9b00543	doi.org/10.1021/acs.organomet.9b00543	Bis(dialkylphosphino)ferrocene-Ligated Nickel(II) Precatalysts for Suzuki-Miyaura Reactions of Aryl Carbonates		Organometallics	43	Hazari, N	FALSE	FALSE	FALSE	FALSE
6606	10.1002/ejoc.201900057	doi.org/10.1002/ejoc.201900057	Amination of 2-Pyridinesulfonic and 8-Quinolinesulfonic Acids with Magnesium Amides		Eur. J. Org. Chem.	43	Knochel, P	FALSE	FALSE	FALSE	FALSE
6607	10.1007/s11696-019-00734-9	doi.org/10.1007/s11696-019-00734-9	Synthesis of 1,2-propanediamine via reductive amination of isopropanolamine over Raney Ni under the promotion of K2CO3		Chem. Pap.	43	Yang, JM; Lu, J	FALSE	FALSE	FALSE	FALSE
6608	10.1016/j.poly.2019.01.021	doi.org/10.1016/j.poly.2019.01.021	Ni(II), Pd(II) and Pt(II) complexes with SacNac tridentate ligand		Polyhedron	43	Lopez, JA	FALSE	FALSE	FALSE	FALSE
6609	10.1002/cctc.201801841	doi.org/10.1002/cctc.201801841	Oxovanadium(V)-Catalyzed Direct Amination of Allyl Alcohols		ChemCatChem	43	Moriuchi, T	FALSE	FALSE	FALSE	FALSE
6610	10.1002/slct.201804039	doi.org/10.1002/slct.201804039	Magnetically Recyclable Nano Nickel Ferrite Catalyzed One-pot Chalcogenation of Bioactive Heterocycles Under Aerobic Condition		ChemistrySelect	43	Das, AR	FALSE	FALSE	FALSE	FALSE
6611	10.1016/j.poly.2018.11.044	doi.org/10.1016/j.poly.2018.11.044	Flexible, N-sulfonyl-substituted aliphatic amine ligands in palladium-catalyzed Suzuki-Miyaura C-C coupling: Influence of substituents bulkiness and co-ligand size		Polyhedron	43	Plass, W; Eseola, AO	FALSE	FALSE	FALSE	FALSE
6612	10.1016/j.chemphys.2018.09.018	doi.org/10.1016/j.chemphys.2018.09.018	Copper (II) Schiff base-graphene oxide composite as an efficient catalyst for Suzuki-Miyaura reaction		Chem. Phys.	43	Bhat, BR	FALSE	FALSE	FALSE	FALSE
6613	10.1039/c8sc04698k	doi.org/10.1039/c8sc04698k	Visual kinetic analysis		Chem. Sci.	43	Bures, J	FALSE	FALSE	FALSE	FALSE
6614	10.3390/molecules24020294	doi.org/10.3390/molecules24020294	Direct Synthesis of Phosphonates and -Amino-phosphonates from 1,3-Benzoxazines		Molecules	43	Linzaga-Elizalde, I	FALSE	FALSE	FALSE	FALSE
6615	10.1039/c7qo01163f	doi.org/10.1039/c7qo01163f	Asymmetric ring-opening reactions of azabenzonorbornadienes through transfer hydrogenation using secondary amines as hydrogen sources: tuning of absolute configuration by acids		Org. Chem. Front.	43	Zhou, YY; Fan, BM	FALSE	FALSE	FALSE	FALSE
6616	10.1039/c8cc03541e	doi.org/10.1039/c8cc03541e	Stille cross- coupling of secondary and tertiary a-( trifluoromethyl)- benzyl chlorides with allylstannanes		Chem. Commun.	43	Shibata, N	FALSE	FALSE	FALSE	FALSE
6617	10.1016/j.tetlet.2018.01.077	doi.org/10.1016/j.tetlet.2018.01.077	Base metal-catalyzed alcohol C-C couplings under hydrogen transfer conditions		Tetrahedron Lett.	43	Liu, FH	FALSE	FALSE	FALSE	FALSE
6618	10.1246/cl.171130	doi.org/10.1246/cl.171130	Machine Learning Approach for Prediction of Reaction Yield with Simulated Catalyst Parameters		Chem. Lett.	43	Yada, A; Sato, K	FALSE	FALSE	FALSE	FALSE
6619	10.1021/acs.joc.7b02740	doi.org/10.1021/acs.joc.7b02740	Transition-Metal-Free Oxidative Aminooxyarylation of Alkenes: Annulations toward Aminooxylated Oxindoles		J. Org. Chem.	43	Zhang, MZ	FALSE	FALSE	FALSE	FALSE
6620	10.1002/aoc.4076	doi.org/10.1002/aoc.4076	A new air and moisture stable robust bio-polymer based palladium catalyst for highly efficient synthesis of biaryl compounds		Appl. Organomet. Chem.	43	Baran, N	FALSE	FALSE	FALSE	FALSE
6621	10.1021/jacs.7b10855	doi.org/10.1021/jacs.7b10855	Preparation of Quaternary Centers via Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Tertiary Sulfones		J. Am. Chem. Soc.	43	Crudden, CM	FALSE	FALSE	FALSE	FALSE
6622	10.1039/c8ra07841f	doi.org/10.1039/c8ra07841f	Substrate switchable Suzuki-Miyaura coupling for benzyl ester vs. benzyl halide		RSC Adv.	43	Nishiwaki, N	FALSE	FALSE	FALSE	FALSE
6623	10.3762/bjoc.13.228	doi.org/10.3762/bjoc.13.228	Homologated amino acids with three vicinal fluorines positioned along the backbone: development of a stereoselective synthesis		Beilstein J. Org. Chem.	43	Hunter, L	FALSE	FALSE	FALSE	FALSE
6624	10.1021/acscatal.7b02795	doi.org/10.1021/acscatal.7b02795	Nickel/Photoredox-Catalyzed Amidation via Alkylsilicates and Isocyanates		ACS Catal.	43	Molander, GA	TRUE	FALSE	FALSE	FALSE
6625	10.1039/c6ob00073h	doi.org/10.1039/c6ob00073h	Direct synthesis of anilines and nitrosobenzenes from phenols		Org. Biomol. Chem.	43	de Alaniz, JR	FALSE	FALSE	FALSE	FALSE
6626	10.1021/jacs.5b07895	doi.org/10.1021/jacs.5b07895	An Alternative Reaction Course in O-Glycosidation with O-Glycosyl Trichloroacetimidates as Glycosyl Donors and Lewis Acidic Metal Salts as Catalyst: Acid-Base Catalysis with Gold Chloride-Glycosyl Acceptor Adducts		J. Am. Chem. Soc.	43	Schmidt, RR	FALSE	FALSE	FALSE	FALSE
6627	10.1021/jacs.5b04892	doi.org/10.1021/jacs.5b04892	Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl-CF3 Coupling		J. Am. Chem. Soc.	43	Sanford, MS	FALSE	TRUE	FALSE	FALSE
6628	10.1038/ncomms8508	doi.org/10.1038/ncomms8508	Decarbonylative organoboron cross-coupling of esters by nickel catalysis		Nat. Commun.	43	Musaev, DG	FALSE	FALSE	FALSE	FALSE
6629	10.1002/anie.201500404	doi.org/10.1002/anie.201500404	Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts		Angew. Chem.-Int. Edit.	43	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6630	10.1039/c5ra09631f	doi.org/10.1039/c5ra09631f	Site and stereoselectivity in sulfa-Michael addition to equivocally activated conjugated dienes		RSC Adv.	43	Kowalczyk, R	FALSE	FALSE	FALSE	FALSE
6631	10.1039/c4cc09337b	doi.org/10.1039/c4cc09337b	Iron catalysed cross-couplings of azetidines - application to the formal synthesis of a pharmacologically active molecule		Chem. Commun.	43	Rueping, M	FALSE	FALSE	FALSE	FALSE
6632	10.1021/jo501925s	doi.org/10.1021/jo501925s	4,4 ',4 ''-Trimethy1-2,2 ':6 ',2 ''-terpyridine by Oxidative Coupling of 4-Pico line		J. Org. Chem.	43	Weix, DJ	FALSE	FALSE	FALSE	FALSE
6633	10.1021/ol501707z	doi.org/10.1021/ol501707z	Nickel-Catalyzed C-H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes		Org. Lett.	43	Zeng, XM	FALSE	FALSE	FALSE	FALSE
6634	10.1021/ja5026485	doi.org/10.1021/ja5026485	Enantiospecific Intramolecular Heck Reactions of Secondary Benzylic Ethers		J. Am. Chem. Soc.	43	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
6635	10.1016/j.tetlet.2014.02.046	doi.org/10.1016/j.tetlet.2014.02.046	Catalyzation of 1,4-additions of arylboronic acids to alpha,beta-unsaturated substrates using nickel(I) complexes		Tetrahedron Lett.	43	Wei, YP	FALSE	FALSE	FALSE	FALSE
6636	10.1515/pac-2014-5033	doi.org/10.1515/pac-2014-5033	Pd- and Ni-catalyzed C-H arylations using C-O electrophiles		Pure Appl. Chem.	43	Kalyani, D	FALSE	FALSE	FALSE	FALSE
6637	10.1039/c3cc47360k	doi.org/10.1039/c3cc47360k	Metal-free ring-opening of epoxides with potassium trifluoroborates		Chem. Commun.	43	Csaky, AG	FALSE	FALSE	FALSE	FALSE
6638	10.1021/ja409748m	doi.org/10.1021/ja409748m	Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne		J. Am. Chem. Soc.	43	Takita, R	FALSE	FALSE	FALSE	FALSE
6639	10.1246/cl.130508	doi.org/10.1246/cl.130508	Cobalt-catalyzed Branched-selective Addition of Aromatic Ketimines to Styrenes under Room-temperature Conditions		Chem. Lett.	43	Yoshikai, N	FALSE	FALSE	FALSE	FALSE
6640	10.1021/ja4076716	doi.org/10.1021/ja4076716	Directed Nickel-Catalyzed Negishi Cross Coupling of Alkyl Aziridines		J. Am. Chem. Soc.	43	Doyle, AG	FALSE	FALSE	FALSE	FALSE
6641	10.1021/jo400432q	doi.org/10.1021/jo400432q	Determination of Absolute Configuration of Secondary Alcohols Using Thin-Layer Chromatography		J. Org. Chem.	43	Rychnovsky, SD	FALSE	FALSE	FALSE	FALSE
6642	10.1002/adsc.201300026	doi.org/10.1002/adsc.201300026	A Copper-Catalyzed Aerobic Cascade Dehydrogenative Dehalogenative Reaction		Adv. Synth. Catal.	43	Xu, P	FALSE	FALSE	FALSE	FALSE
6643	10.1016/j.tetlet.2012.11.106	doi.org/10.1016/j.tetlet.2012.11.106	S(N)2 substitution reaction of 2-C-acetoxymethyl glycals catalyzed by iodine: a novel synthesis of 2-C-N-arylamidomethyl glycals		Tetrahedron Lett.	43	Reddy, BVS	FALSE	FALSE	FALSE	FALSE
6644	10.1002/anie.201208606	doi.org/10.1002/anie.201208606	Carboxy-Directed Asymmetric Hydrogenation of 1,1-Diarylethenes and 1,1-Dialkylethenes		Angew. Chem.-Int. Edit.	43	Zhou, QL	FALSE	FALSE	FALSE	FALSE
6645	10.1007/s11426-012-4711-x	doi.org/10.1007/s11426-012-4711-x	Theoretical study on formation of thioesters via O-to-S acyl transfer		Sci. China-Chem.	43	Guo, QX	FALSE	FALSE	FALSE	FALSE
6646	10.1039/c2cc17744g	doi.org/10.1039/c2cc17744g	Triply ferrocene-bridged boroxine cyclophane		Chem. Commun.	43	Miljanic, OS	FALSE	FALSE	FALSE	FALSE
6647	10.1039/c2cc15972d	doi.org/10.1039/c2cc15972d	An efficient palladium-benzimidazolyl phosphine complex for the Suzuki-Miyaura coupling of aryl mesylates: facile ligand synthesis and metal complex characterization		Chem. Commun.	43	So, CM	FALSE	FALSE	FALSE	FALSE
6648	10.1016/j.tetlet.2011.10.050	doi.org/10.1016/j.tetlet.2011.10.050	Synthesis of isotopomers of N-(tert-butoxycarbonyl)-4-cyano-L-phenylalanine methyl ester: choice of cyanation solvent		Tetrahedron Lett.	43	Brewer, SH	FALSE	FALSE	FALSE	FALSE
6649	10.1039/c1cc11087j	doi.org/10.1039/c1cc11087j	On water sp(3)-sp(2) cross-couplings between benzylic and alkenyl halides		Chem. Commun.	43	Krasovskaya, V	FALSE	FALSE	FALSE	FALSE
6650	10.1021/jo100877j	doi.org/10.1021/jo100877j	Palladium-Catalyzed C-F Activation of Polyfluoronitrobenzene Derivatives in Suzuki-Miyaura Coupling Reactions		J. Org. Chem.	43	Sandford, G	FALSE	FALSE	FALSE	FALSE
6651	10.1055/s-0030-1258080	doi.org/10.1055/s-0030-1258080	Synthesis of 2-Substituted Pyrimidines via Cross-Coupling Reaction of Pyrimidin-2-yl Sulfonates with Nucleophiles in Polyethylene Glycol 400		Synlett	43	Wang, XC	FALSE	FALSE	FALSE	FALSE
6652	10.1002/anie.201004543	doi.org/10.1002/anie.201004543	Nickel-Catalyzed Cyclization of Difluoro-Substituted 1,6-Enynes with Organozinc Reagents through the Stereoselective Activation of C-F Bonds: Synthesis of Bicyclo[3.2.0]heptene Derivatives		Angew. Chem.-Int. Edit.	43	Chatani, N	FALSE	FALSE	FALSE	FALSE
6653	10.3390/molecules14062032	doi.org/10.3390/molecules14062032	The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions		Molecules	43	Yigit, M	FALSE	FALSE	FALSE	FALSE
6654	10.1021/om800004j	doi.org/10.1021/om800004j	Anagostic interactions and catalytic activities of sterically bulky benzannulated N-heterocyclic carbene complexes of nickel(II)		Organometallics	43	Huynh, HV	FALSE	FALSE	FALSE	FALSE
6655	10.1021/jo800155a	doi.org/10.1021/jo800155a	New insight into Ni(II)-catalyzed cyclization reactions of propargylic compounds with soft nucleophiles: Novel indenes formation		J. Org. Chem.	43	Liang, YM	FALSE	FALSE	FALSE	FALSE
6656	10.1021/jo7022558	doi.org/10.1021/jo7022558	Nickel-catalyzed amination of aryl tosylates		J. Org. Chem.	43	Yang, LM	FALSE	FALSE	FALSE	FALSE
6657	10.1055/s-2007-983845	doi.org/10.1055/s-2007-983845	Catalytic activities of a bis(carbene)-derived nickel(II)-pincer complex in Kumada-Tamao-Corriu and Suzuki-Miyaura coupling reactions for the synthesis of biaryl compounds		Synthesis	43	Inamoto, K	FALSE	FALSE	FALSE	FALSE
6658	10.1016/j.tetlet.2007.04.017	doi.org/10.1016/j.tetlet.2007.04.017	A simple and efficient FeCl3-catalyzed direct alkylation of active methylene compounds with benzylic and allylic alcohols under mild conditions		Tetrahedron Lett.	43	Jana, U	FALSE	FALSE	FALSE	FALSE
6659	10.1021/jo0623742	doi.org/10.1021/jo0623742	CuI-catalyzed Suzuki-Miyaura and Sonogashira cross-coupling reactions using DABCO as ligand		J. Org. Chem.	43	Li, JH	FALSE	FALSE	FALSE	FALSE
6660	10.1016/j.tetlet.2006.10.156	doi.org/10.1016/j.tetlet.2006.10.156	Facile access to 4-(1-alkynyl)-2(5H)-furanones by Sonogashira coupling of terminal acetylenes with beta-tetronic acid bromide: efficient synthesis of cleviolide		Tetrahedron Lett.	43	Boukouvalas, J	FALSE	FALSE	FALSE	FALSE
6661	10.1039/b614015g	doi.org/10.1039/b614015g	Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates		Chem. Commun.	43	Kawatsura, M	FALSE	FALSE	FALSE	FALSE
6662	10.1055/s-2006-926305	doi.org/10.1055/s-2006-926305	Palladium on activated carbon - A recyclable catalyst for Suzuki-Miyaura cross-coupling of aryl chlorides in water		Synthesis	43	Lysen, M	FALSE	FALSE	FALSE	FALSE
6663	10.1002/anie.200600100	doi.org/10.1002/anie.200600100	Regio- and stereoselective rhodium-catalyzed allylic alkylations of chelated enolates		Angew. Chem.-Int. Edit.	43	Kazmaier, U	FALSE	FALSE	FALSE	FALSE
6664	10.1021/ol0522485	doi.org/10.1021/ol0522485	Rhodium-catalyzed reaction of aryl and alkenylboronic acids with 2,4-dienoate esters: Conjugate addition and Heck reaction products		Org. Lett.	43	Csaky, AG	FALSE	FALSE	FALSE	FALSE
6665	10.1055/s-2004-837298	doi.org/10.1055/s-2004-837298	Efficient protocol for the phosphine-free Suzuki-Miyaura reaction catalyzed by palladium on carbon at room temperature		Synthesis	43	Zhang, GL	FALSE	FALSE	FALSE	FALSE
6666	10.1016/j.polymer.2004.05.051	doi.org/10.1016/j.polymer.2004.05.051	Palladium-catalyzed selective dehalogenative homocoupling polymerization of AB(2)-type dihaloaryl sulfonate monomers		Polymer	43	Bae, JY	FALSE	FALSE	FALSE	FALSE
6667	10.1016/S0040-4020(03)00761-0	doi.org/10.1016/S0040-4020(03)00761-0	Synthesis and metallation of 2-(pyridyl)benzoic acids and ethyl 2-(pyridyl)benzoates: a new route to azafluorenones		Tetrahedron	43	Mongin, F	FALSE	FALSE	FALSE	FALSE
6668	10.1021/ol005956t	doi.org/10.1021/ol005956t	Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system		Org. Lett.	43	Nolan, SP	FALSE	FALSE	FALSE	FALSE
6669	10.1006/jcat.1999.2616	doi.org/10.1006/jcat.1999.2616	Direct synthesis of dimethylbiphenyls by toluene coupling in the presence of palladium triflate and triflic acid		J. Catal.	43	White, MG	FALSE	FALSE	FALSE	FALSE
6670	10.1021/ma9900129	doi.org/10.1021/ma9900129	Poly(p-phenylene)s with mesogenic side groups: A potential class of N-II side chain liquid crystalline polymers?		Macromolecules	43	Percec, V	FALSE	FALSE	FALSE	FALSE
6671	10.1016/S0022-328X(98)01058-4	doi.org/10.1016/S0022-328X(98)01058-4	Catalytic asymmetric reactions via pi-allylpalladium complexes coordinated with chiral monophosphine ligands		J. Organomet. Chem.	43	Hayashi, T	FALSE	FALSE	FALSE	FALSE
6672	10.1021/jo980704f	doi.org/10.1021/jo980704f	Oxidative biaryl coupling reaction of phenol ether derivatives using a hypervalent iodine(III) reagent		J. Org. Chem.	43	Kita, Y	FALSE	FALSE	FALSE	FALSE
6673	10.1016/S0020-1693(97)05770-8	doi.org/10.1016/S0020-1693(97)05770-8	Enantioselective catalysis XVI: regio- and enantioselectivity in nickel-catalysed cross-coupling reactions of allylic substrates with Grignard reagents		Inorg. Chim. Acta	43	Nagel, U	FALSE	FALSE	FALSE	FALSE
6674	10.1021/jo962307f	doi.org/10.1021/jo962307f	Formation of scalemic aziridines via the nucleophilic opening of aziridines		J. Org. Chem.	43	Bergmeier, SC	FALSE	FALSE	FALSE	FALSE
6675	10.5059/yukigoseikyokaishi.49.919	doi.org/10.5059/yukigoseikyokaishi.49.919	PALLADIUM AND RHODIUM CATALYZED CARBONYLATION - CARBONYLATION OF ALLYLIC COMPOUNDS AND CROSS DOUBLE CARBONYLATION OF AMINES AND ALCOHOLS		J. Synth. Org. Chem. Jpn.	43	MURAHASHI, S	FALSE	FALSE	FALSE	FALSE
6676	10.1021/om00162a014	doi.org/10.1021/om00162a014	PREPARATION AND REDUCTIVE ELIMINATION OF (ETA-3-ALLYL)(ARYL)NICKEL(II) COMPLEXES - UNUSUALLY FACILE ETA-3-ALLYL-ARYL COUPLING ON NICKEL HAVING AN 18-ELECTRON CONFIGURATION		Organometallics	43	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
6677	10.1016/j.chempr.2022.01.005	doi.org/10.1016/j.chempr.2022.01.005	Palladium-catalyzed stereospecific C-P toward diverse		Chem	43	Shi, ZZ	FALSE	FALSE	FALSE	FALSE
6678	10.1021/acs.orglett.1c03541	doi.org/10.1021/acs.orglett.1c03541	Unlocking Amides through Selective C-N Bond Cleavage: Allyl Bromide-Mediated Divergent Synthesis of Nitrogen-Containing Functional Groups		Org. Lett.	43	Lin, WY	FALSE	FALSE	FALSE	FALSE
6679	10.1002/anie.202113836	doi.org/10.1002/anie.202113836	Synthesis and Optical Resolution of Configurationally Stable Zwitterionic Pentacoordinate Silicon Derivatives		Angew. Chem.-Int. Edit.	43	Fensterbank, L; Lemiere, G	FALSE	FALSE	FALSE	FALSE
6680	10.1055/s-0040-1719856	doi.org/10.1055/s-0040-1719856	Hydrohalogenation of Unactivated Alkenes Using a Methanesulfonic Acid/Halide Salt Combination		Synthesis	43	Paquin, JF	FALSE	FALSE	FALSE	FALSE
6681	10.1039/d1py01141c	doi.org/10.1039/d1py01141c	Poly(para-phenylene) ionomer membranes: effect of methyl and trifluoromethyl substituents		Polym. Chem.	43	Miyatake, K	FALSE	FALSE	FALSE	FALSE
6682	10.1039/d1cc05006k	doi.org/10.1039/d1cc05006k	Haloarene-guided cascade arylation of cyclic vinylogous esters under palladium catalysis		Chem. Commun.	43	Wu, YK	FALSE	FALSE	FALSE	FALSE
6683	10.1002/asia.202100776	doi.org/10.1002/asia.202100776	Cu2O-Catalyzed Conversion of Benzyl Alcohols Into Aromatic Nitriles via the Complete Cleavage of the C equivalent to N Triple Bond in the Cyanide Anion		Chem.-Asian J.	43	Ren, YL; Tian, XZ; Zheng, XF	FALSE	FALSE	FALSE	FALSE
6684	10.1021/jacs.1c05274	doi.org/10.1021/jacs.1c05274	Enantiomerically Enriched alpha-Borylzinc Reagents by Nickel-Catalyzed Carbozincation of Vinylboronic Esters		J. Am. Chem. Soc.	43	Morken, JP	FALSE	FALSE	FALSE	FALSE
6685	10.1002/eem2.12205	doi.org/10.1002/eem2.12205	Electronic Coupling of Single Atom and FePS3 Boosts Water Electrolysis		Energy Environ. Mater.	43	Xiao, XH	FALSE	TRUE	FALSE	FALSE
6686	10.1038/s41598-021-90478-y	doi.org/10.1038/s41598-021-90478-y	An advancement in the synthesis of nano Pd@magnetic amine-Functionalized UiO-66-NH2 catalyst for cyanation and O-arylation reactions		Sci Rep	43	Moghaddam, FM	FALSE	FALSE	FALSE	FALSE
6687	10.1021/acsomega.0c06358	doi.org/10.1021/acsomega.0c06358	Exploring the Effect of Cyclization of Histamine H-1 Receptor Antagonists on Ligand Binding Kinetics		ACS Omega	43	de Esch, IJP	FALSE	FALSE	FALSE	FALSE
6688	10.1039/d1qo00264c	doi.org/10.1039/d1qo00264c	Nickel-catalyzed reductive benzylation of tertiary alkyl halides with benzyl chlorides and chloroformates		Org. Chem. Front.	43	Sun, DL; Gong, HG	FALSE	FALSE	FALSE	FALSE
6689	10.1002/ajoc.202100031	doi.org/10.1002/ajoc.202100031	Palladium-Phenylpyrazolylphosphine-Catalyzed Cross-Coupling of Alkenyl Pivalates		Asian J. Org. Chem.	43	So, CM	FALSE	FALSE	FALSE	FALSE
6690	10.1021/acs.orglett.7b02076	doi.org/10.1021/acs.orglett.7b02076	Nickel Catalyzed Regio-, Diastereo-, and Enantioselective Cross Coupling of 3,4-Epoxyalcohol with Aryl Iodides		Org. Lett.	43	Banerjee, A; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
6691	10.1039/c7qo00068e	doi.org/10.1039/c7qo00068e	Chemoselective acyl C-O bond activation in esters for Suzuki-Miyaura coupling		Org. Chem. Front.	43	Mondal, M	FALSE	FALSE	FALSE	FALSE
6692	10.1002/slct.201601789	doi.org/10.1002/slct.201601789	Phosphate-Mediated Enyne Synthesis from Allenols		ChemistrySelect	43	Sajiki, H; Sawama, Y	FALSE	FALSE	FALSE	FALSE
6693	10.1021/jacs.6b01533	doi.org/10.1021/jacs.6b01533	Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides		J. Am. Chem. Soc.	43	Weix, DJ	FALSE	TRUE	FALSE	FALSE
6694	10.1021/acs.joc.5b02853	doi.org/10.1021/acs.joc.5b02853	Reaction of Glyconitriles with Organometallic Reagents: Access to Acyl beta-C-Glycosides		J. Org. Chem.	43	Guillarme, S	FALSE	FALSE	FALSE	FALSE
6695	10.1002/anie.201507494	doi.org/10.1002/anie.201507494	Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights		Angew. Chem.-Int. Edit.	43	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
6696	10.1039/d0sc05452f	doi.org/10.1039/d0sc05452f	Preparation of alpha-amino acids via Ni-catalyzed reductive vinylation and arylation of alpha-pivaloyloxy glycine	We report non-decarbonylative Mizoroki-Heck reactions of amide derivatives. The transformation relies on the use of nickel catalysis and proceeds using sterically hindered tri- and tetrasubstituted olefins to give products containing quaternary centers. The resulting polycyclic or spirocyclic products can be obtained in good yields. Moreover, a diastereoselective variant of this method gives access to an adduct bearing vicinal, highly substituted sp3 stereocenters. These results demonstrate that amide derivatives can be used as building blocks for the assembly of complex scaffolds.	Chem. Sci.	42	Gong, HG	FALSE	FALSE	FALSE	FALSE
6697	10.1021/acscatal.0c03857	doi.org/10.1021/acscatal.0c03857	Sulfonamide Directivity Enables Ni-Catalyzed 1,2-Diarylation of Diverse Alkenyl Amines	A copper(I)-catalyzed enantioselective addition of enynes to ketones was developed. The method allows facile construction of enantiomerically enriched tertiary alcohols using skipped enynes as stable hydrocarbon pronucleophiles. The combination of a soft copper(I)-conjugated Bronsted base catalyst with a chiral diphosphine ligand, (S,S)-Ph-BPE, enabled chemoselective deprotonation of the skipped enynes in the presence of ketones bearing intrinsically more acidic a-protons. The catalytically generated chiral allylcopper species enantio-, diastereo-, regio-, and chemoselectively reacted with ketones, thereby demonstrating excellent substrate generality with functional group tolerance. The skipped enyne moieties of the pronucleophiles were exclusively converted to cis-conjugated enynes, which will eventually allow for further versatile transformations.	ACS Catal.	42	Engle, KM	FALSE	FALSE	FALSE	FALSE
6698	10.1016/j.ceramint.2020.05.133	doi.org/10.1016/j.ceramint.2020.05.133	Fabrication of porous Cu supported Ni-P/CeO2 composite coatings for enhanced hydrogen evolution reaction in alkaline solution	A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally diverse aryl as well as alkenyl and alkyl boronate esters with high reactivity, broad substrate scope, and excellent functional-group tolerance. Further experiments show that this protocol can be carried out on a gram scale and applied to orthogonal synthetic strategies.	Ceram. Int.	42	Liu, SL	FALSE	FALSE	FALSE	FALSE
6699	10.1002/chem.202000721	doi.org/10.1002/chem.202000721	One-Pot Substitution of Aliphatic Alcohols Mediated by Sulfuryl Fluoride	Using nickel and photoredox catalysis, the direct functionalization of C(sp(3))-H bonds of N-aryl amines by acyl electrophiles is described. The method affords a diverse range of -amino ketones at room temperature and is amenable to late-stage coupling of complex and biologically relevant groups. C(sp(3))-H activation occurs by photoredox-mediated oxidation to generate -amino radicals which are intercepted by nickel in catalytic C(sp(3))-C coupling. The merger of these two modes of catalysis leverages nickel's unique properties in alkyl cross-coupling while avoiding limitations commonly associated with transition-metal-mediated C(sp(3))-H activation, including requirements for chelating directing groups and high reaction temperatures.	Chem.-Eur. J.	42	Sammis, PGM	FALSE	FALSE	FALSE	FALSE
6700	10.1002/anie.202000124	doi.org/10.1002/anie.202000124	Ni(COD)(DQ): An Air-Stable 18-Electron Nickel(0)-Olefin Precatalyst	Catalyzed by supported palladium nanoparticles, a decarbonylative amidation reaction between various aryl esters and formamides by C-O bond activation has been developed for the synthesis of amides. The catalyst can be reused and shows high activity after five cycles. The XPS analysis of the catalyst before and after the reaction suggested that the reaction might be performed via a Pd-0/Pd-II/Pd-IV catalytic cycle that began with Pd-0. The hot filtration test strongly suggests that the present reaction would proceed in a heterogeneous manner.	Angew. Chem.-Int. Edit.	42	Engle, KM	FALSE	TRUE	FALSE	FALSE
6701	10.1002/adsc.201901139	doi.org/10.1002/adsc.201901139	Harnessing the Intrinsic Reactivity of 2-Cyano-Substituted Heteroarenes to Achieve Programmable Double Alkylation	The first example of a resorcin[6]arene cavitand in which sulfate bridges are introduced between the OH groups is here reported. In addition to their structural role, sulfate bridges behave as functional supramolecular interacting groups thus favoring the complexation of suitable organic ammonium guests.	Adv. Synth. Catal.	42	Zhu, HY	FALSE	FALSE	FALSE	FALSE
6702	10.1002/adma.201906015	doi.org/10.1002/adma.201906015	Organic Small Molecule Activates Transition Metal Foam for Efficient Oxygen Evolution Reaction		Adv. Mater.	42	Huang, WQ	FALSE	FALSE	FALSE	FALSE
6703	10.1039/c9ra10758d	doi.org/10.1039/c9ra10758d	A one pot protocol to convert nitro-arenes into N-aryl amides		RSC Adv.	42	Benaglia, M	FALSE	FALSE	FALSE	FALSE
6704	10.1016/j.tet.2019.130759	doi.org/10.1016/j.tet.2019.130759	Increasing the antioxidant capability via the synergistic effect of coupling diphenylamine with sterically hindered phenol		Tetrahedron	42	Hayes, W	FALSE	FALSE	FALSE	FALSE
6705	10.1021/acs.orglett.9b01355	doi.org/10.1021/acs.orglett.9b01355	Cyclization of Bisphosphines to Phosphacycles via the Cleavage of Two Carbon-Phosphorus Bonds by Nickel Catalysis		Org. Lett.	42	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6706	10.1021/acs.inorgchem.8b03489	doi.org/10.1021/acs.inorgchem.8b03489	C-O and C-N Functionalization of Cationic, NCN-Type Pincer Complexes of Trivalent Nickel: Mechanism, Selectivity, and Kinetic Isotope Effect		Inorg. Chem.	42	Zargarian, D	FALSE	FALSE	FALSE	FALSE
6707	10.1039/c8ob03048k	doi.org/10.1039/c8ob03048k	Enantioselective synthesis of chiral heterocyclic biaryls via asymmetric Suzuki-Miyaura cross-coupling of 3-bromopyridine derivatives		Org. Biomol. Chem.	42	Qiu, LQ	FALSE	FALSE	FALSE	FALSE
6708	10.1039/c8cc09701a	doi.org/10.1039/c8cc09701a	Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles		Chem. Commun.	42	Crimmin, MR	FALSE	FALSE	FALSE	FALSE
6709	10.1002/cctc.201800898	doi.org/10.1002/cctc.201800898	Pd-Ni BMNPs Encapsulated in UiO-66 as an Efficient Catalyst for the Activation of Inert C-O Bonds		ChemCatChem	42	Cai, C	FALSE	FALSE	FALSE	FALSE
6710	10.1021/acs.joc.8b01547	doi.org/10.1021/acs.joc.8b01547	Tuning Regioselectivity of Wacker Oxidation in One Catalytic System: Small Change Makes Big Step		J. Org. Chem.	42	Kang, YB	FALSE	FALSE	FALSE	FALSE
6711	10.1021/acscatal.8b01572	doi.org/10.1021/acscatal.8b01572	Radical-Organometallic Hybrid Reaction System Enabling Couplings between Tertiary-Alkyl Groups and 1-Alkenyl Groups		ACS Catal.	42	Nishikata, T	FALSE	FALSE	FALSE	FALSE
6712	10.1002/anie.201707760	doi.org/10.1002/anie.201707760	Fast, Efficient and Low E-Factor One-Pot Palladium-Catalyzed Cross-Coupling of (Hetero)Arenes		Angew. Chem.-Int. Edit.	42	Feringa, BL	FALSE	FALSE	FALSE	FALSE
6713	10.1134/S1070428018070047	doi.org/10.1134/S1070428018070047	Synthesis and Transformations of Aryl-Substituted Alkenes of the Adamantane Series		Russ. J. Organ. Chem.	42	Savel'eva, SA	FALSE	FALSE	FALSE	FALSE
6714	10.1021/acsomega.7b01540	doi.org/10.1021/acsomega.7b01540	Direct/Reversible Amidation of Troponyl Alkylglycinates via Cationic Troponyl Lactones and Mechanistic Insights		ACS Omega	42	Sharma, NK	FALSE	FALSE	FALSE	FALSE
6715	10.1021/acscatal.7b03079	doi.org/10.1021/acscatal.7b03079	Nickel-Catalyzed Suzuki Cross Couplings with Unprotected Allylic Alcohols Enabled by Bidentate N-Heterocyclic Carbene (NHC)/Phosphine Ligands		ACS Catal.	42	Michaelis, DJ	FALSE	FALSE	FALSE	FALSE
6716	10.1021/acscatal.7b03388	doi.org/10.1021/acscatal.7b03388	Ligand-Controlled Nickel-Catalyzed Reductive Relay Cross-Coupling of Alkyl Bromides and Aryl Bromides		ACS Catal.	42	Yin, GY	FALSE	FALSE	FALSE	FALSE
6717	10.1002/aoc.3855	doi.org/10.1002/aoc.3855	Nickel-catalyzed oxidative esterification of formamides with 1,3-dicarbonyl compounds under mild reaction conditions		Appl. Organomet. Chem.	42	Saberi, D	FALSE	FALSE	FALSE	FALSE
6718	10.1246/cl.150936	doi.org/10.1246/cl.150936	Nickel-catalyzed Cross-coupling of Anisole Derivatives with Trimethylaluminum through the Cleavage of Carbon Oxygen Bonds		Chem. Lett.	42	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6719	10.1016/j.tet.2015.03.066	doi.org/10.1016/j.tet.2015.03.066	Nickel promoted switchable hydroheteroarylation of cyclodienes via C-H bond activation of heteroarenes		Tetrahedron	42	Ong, TG	FALSE	FALSE	FALSE	FALSE
6720	10.1002/anie.201501908	doi.org/10.1002/anie.201501908	Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of -Oxo Acids		Angew. Chem.-Int. Edit.	42	MacMillan, DWC	TRUE	FALSE	FALSE	FALSE
6721	10.1021/jacs.5b02945	doi.org/10.1021/jacs.5b02945	Ni-Catalyzed Alkenylation of Ketone Enolates under Mild Conditions: Catalyst Identification and Optimization		J. Am. Chem. Soc.	42	Helquist, P	FALSE	FALSE	FALSE	FALSE
6722	10.1002/adsc.201500058	doi.org/10.1002/adsc.201500058	2H-Chromenes Generated by an Iron(III) Complex-Catalyzed Allylic Cyclization		Adv. Synth. Catal.	42	Corbu, A	FALSE	FALSE	FALSE	FALSE
6723	10.1039/c5qo00039d	doi.org/10.1039/c5qo00039d	A divergent synthesis of 3,10-dialkylpicenes		Org. Chem. Front.	42	Chen, XC	FALSE	FALSE	FALSE	FALSE
6724	10.1039/c5cy00851d	doi.org/10.1039/c5cy00851d	Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions		Catal. Sci. Technol.	42	Clifton, J	FALSE	FALSE	FALSE	FALSE
6725	10.1039/c4cc08426h	doi.org/10.1039/c4cc08426h	Ni-Catalyzed alpha-arylation of esters and amides with phenol derivatives		Chem. Commun.	42	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
6726	10.1002/anie.201402576	doi.org/10.1002/anie.201402576	Catalytic Cleavage of Ether C-O Bonds by Pincer Iridium Complexes		Angew. Chem.-Int. Edit.	42	Goldman, AS	FALSE	FALSE	FALSE	FALSE
6727	10.1021/jo500905m	doi.org/10.1021/jo500905m	Reductive Cross-Coupling of Nonaromatic, Heterocyclic Bromides with Aryl and Heteroaryl Bromides		J. Org. Chem.	42	Molander, GA	FALSE	FALSE	FALSE	FALSE
6728	10.1021/ol5007086	doi.org/10.1021/ol5007086	Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions		Org. Lett.	42	Smith, AB	FALSE	FALSE	FALSE	FALSE
6729	10.1039/c3qo00045a	doi.org/10.1039/c3qo00045a	Access to pyridines via DMAP-catalyzed activation of alpha-chloro acetic ester to react with unsaturated imines		Org. Chem. Front.	42	Hao, L	FALSE	FALSE	FALSE	FALSE
6730	10.1071/CH14171	doi.org/10.1071/CH14171	Probing Mechanisms of Aryl-Aryl Bond Cleavages under Flash Vacuum Pyrolysis Conditions		Aust. J. Chem.	42	Scott, LT	FALSE	FALSE	FALSE	FALSE
6731	10.1080/00397911.2013.862835	doi.org/10.1080/00397911.2013.862835	SIMPLE PREPARATION PROCESS OF SYN PHENYLPROPANOLAMINES FROM RACEMIC O-TBDPS CYANOHYDRINS		Synth. Commun.	42	Tang, S	FALSE	FALSE	FALSE	FALSE
6732	10.1039/c3qo00066d	doi.org/10.1039/c3qo00066d	Highly selective 4-alkynoic acids synthesis via iron-mediated complete inversion of stereogenic carbon centers		Org. Chem. Front.	42	Zhang, XB	FALSE	FALSE	FALSE	FALSE
6733	10.1039/c3ob41328d	doi.org/10.1039/c3ob41328d	Metal-free borylative ring-opening of vinyl epoxides and aziridines		Org. Biomol. Chem.	42	Pubill-Ulldemolins, C	FALSE	FALSE	FALSE	FALSE
6734	10.1021/cs400572q	doi.org/10.1021/cs400572q	Rhenium-Catalyzed Acceptorless Dehydrogenative Coupling via Dual Activation of Alcohols and Carbonyl Compounds		ACS Catal.	42	Zhu, CJ	FALSE	FALSE	FALSE	FALSE
6735	10.1021/es401183v	doi.org/10.1021/es401183v	Complete Hydrodehalogenation of Polyfluorinated and Other Polyhalogenated Benzenes under Mild Catalytic Conditions		Environ. Sci. Technol.	42	McNeill, K	FALSE	FALSE	FALSE	FALSE
6736	10.1021/ol400289v	doi.org/10.1021/ol400289v	Asymmetric Synthesis of 1-Heteroaryl-1-arylalkyl Tertiary Alcohols and 1-Pyridyl-1-arylethanes by Lithiation-Borylation Methodology		Org. Lett.	42	Aggarwal, VK	FALSE	FALSE	FALSE	FALSE
6737	10.1016/j.tet.2012.12.062	doi.org/10.1016/j.tet.2012.12.062	The study of catalyst free and copper catalyzed reactions of cyanochromenes and sodium azide		Tetrahedron	42	Yao, CF	FALSE	FALSE	FALSE	FALSE
6738	10.1021/ol303366u	doi.org/10.1021/ol303366u	Nickel-Mediated Inter- and Intramolecular C-S Coupling of Thiols and Thioacetates with Aryl Iodides at Room Temperature		Org. Lett.	42	Peng, Y	FALSE	FALSE	FALSE	FALSE
6739	10.1039/c3ra44195d	doi.org/10.1039/c3ra44195d	A quick and flexible synthetic approach to enureas (alkenyl ureas) via the Pd-catalyzed C-N coupling reaction of alkenyl tosylates and mesylates		RSC Adv.	42	Chikhalia, KH	FALSE	FALSE	FALSE	FALSE
6740	10.1002/ejoc.201200444	doi.org/10.1002/ejoc.201200444	An Efficient Suzuki-Miyaura Coupling of Aryl Sulfamates and Boronic Acids Catalyzed by NiCl2(dppp)		Eur. J. Org. Chem.	42	Han, FS	FALSE	FALSE	FALSE	FALSE
6741	10.1002/ejoc.201101842	doi.org/10.1002/ejoc.201101842	Ti/Ni-Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds		Eur. J. Org. Chem.	42	Miguel, D	FALSE	FALSE	FALSE	FALSE
6742	10.1021/ol2033306	doi.org/10.1021/ol2033306	Ligand-Free Ni-Catalyzed Reductive Cleavage of Inert Carbon-Sulfur Bonds		Org. Lett.	42	Martin, R	FALSE	FALSE	FALSE	FALSE
6743	10.1039/c1sc00697e	doi.org/10.1039/c1sc00697e	Catalytic enantioselective electrocyclic cascades		Chem. Sci.	42	Smith, MD	FALSE	FALSE	FALSE	FALSE
6744	10.1039/c2cc32676k	doi.org/10.1039/c2cc32676k	One-pot thioetherification of aryl halides with thiourea and benzyl bromide in water catalyzed by Cu-grafted furfural imine-functionalized mesoporous SBA-15		Chem. Commun.	42	Bhaumik, A	FALSE	FALSE	FALSE	FALSE
6745	10.1021/ol2024357	doi.org/10.1021/ol2024357	Iron-Catalyzed Oxidative Monoarylation of Primary Amines with Organozinc Reagents		Org. Lett.	42	Nakamura, E	FALSE	FALSE	FALSE	FALSE
6746	10.1246/bcsj.20110139	doi.org/10.1246/bcsj.20110139	Stabilization of Excited State Using Through-Space Interaction between Independent pi-Systems Mediated by a peri-Substituted Hydroxy Group in 1-Arylnaphthalenes: Unexpected Blue Emission of 1,3,5-Tris(peri-hydroxynaphthyl)benzene		Bull. Chem. Soc. Jpn.	42	Yasuda, M	FALSE	FALSE	FALSE	FALSE
6747	10.1002/adsc.201100141	doi.org/10.1002/adsc.201100141	A Mild Palladium-Catalyzed Suzuki Coupling Reaction of Quinoline Carboxylates with Boronic Acids		Adv. Synth. Catal.	42	Li, WJ	FALSE	FALSE	FALSE	FALSE
6748	10.1016/j.molcata.2011.04.001	doi.org/10.1016/j.molcata.2011.04.001	Reductive dehalogenation of aryl halides over palladium catalysts deposited on SBA-15 type molecular sieve modified with amine donor groups		J. Mol. Catal. A-Chem.	42	Stepnicka, P	FALSE	FALSE	FALSE	FALSE
6749	10.1021/jo1024464	doi.org/10.1021/jo1024464	Rapid Nickel-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Carbamates and Sulfamates Utilizing Microwave Heating		J. Org. Chem.	42	Kappe, CO	FALSE	FALSE	FALSE	FALSE
6750	10.3762/bjoc.6.70	doi.org/10.3762/bjoc.6.70	Suzuki-Miyaura cross-coupling reaction of 1-aryltriazenes with arylboronic acids catalyzed by a recyclable polymer-supported N-heterocyclic carbene-palladium complex catalyst		Beilstein J. Org. Chem.	42	Luo, MM	FALSE	FALSE	FALSE	FALSE
6751	10.1021/ol100599c	doi.org/10.1021/ol100599c	Nickel-Catalyzed Arylative Ring-Opening of 3-Methylenecycloalkane-1,1-dicarboxylates		Org. Lett.	42	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
6752	10.1002/anie.200907287	doi.org/10.1002/anie.200907287	Nickel-Catalyzed Amination of Aryl Pivalates by the Cleavage of Aryl C-O Bonds		Angew. Chem.-Int. Edit.	42	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6753	10.1002/chem.201000420	doi.org/10.1002/chem.201000420	Aryl Phosphoramides: Useful Electrophiles for Suzuki-Miyaura Coupling Catalyzed by a NiCl2/dppp System (dppp=1,3-Bis(diphenylphosphino)propane)		Chem.-Eur. J.	42	Han, FS	FALSE	TRUE	FALSE	FALSE
6754	10.1021/ja907281f	doi.org/10.1021/ja907281f	Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C-O Bond Activation		J. Am. Chem. Soc.	42	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
6755	10.1021/ol900009a	doi.org/10.1021/ol900009a	Nano Indium Oxide as a Recyclable Catalyst for C-S Cross-Coupling of Thiols with Aryl Halides under Ligand Free conditions		Org. Lett.	42	Rao, KR	FALSE	FALSE	FALSE	FALSE
6756	10.1021/ja804672m	doi.org/10.1021/ja804672m	Palladium-catalyzed Hiyama cross-couplings of aryl arenesulfonates with arylsilanes		J. Am. Chem. Soc.	42	Wu, J	FALSE	FALSE	FALSE	FALSE
6757	10.1055/s-2008-1067193	doi.org/10.1055/s-2008-1067193	Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents using (Z)-3,3-dimethyl-1,2-bis(diphenylphosphino)but-1-ene as ligand		Synthesis	42	Kanemura, S	FALSE	FALSE	FALSE	FALSE
6758	10.1002/anie.200704162	doi.org/10.1002/anie.200704162	Cyclic triolborates: Air- and water-stable ate complexes of organoboronic acids		Angew. Chem.-Int. Edit.	42	Miyaura, N	FALSE	FALSE	FALSE	FALSE
6759	10.1021/ja0713375	doi.org/10.1021/ja0713375	Design of axially chiral dicarboxylic acid for asymmetric Mannich reaction of arylaldehyde N-Boc imines and diazo compounds		J. Am. Chem. Soc.	42	Maruoka, K	FALSE	FALSE	FALSE	FALSE
6760	10.1002/jccs.200600130	doi.org/10.1002/jccs.200600130	In situ generated palladium nanoparticles for catalytic dehalogenation of aryl halides and deboronation of arylboronic acids		J. Chin. Chem. Soc.	42	Liu, ST	FALSE	FALSE	FALSE	FALSE
6761	10.1002/anie.200600442	doi.org/10.1002/anie.200600442	Heck coupling with nonactivated alkenyl tosylates and phosphates: Examples of effective 1,2-migrations of the alkenyl palladium(II) intermediates		Angew. Chem.-Int. Edit.	42	Norrby, PO	FALSE	FALSE	FALSE	FALSE
6762	10.1016/j.tetlet.2005.10.018	doi.org/10.1016/j.tetlet.2005.10.018	A vicarious synthesis of unsymmetrical meta- and para-terphenyls from 2H-pyran-2-ones		Tetrahedron Lett.	42	Goel, A	FALSE	FALSE	FALSE	FALSE
6763	10.1055/s-2004-832818	doi.org/10.1055/s-2004-832818	Nickel-catalyzed cross-coupling reactions of 4-mesylcoumarins with aryl halides: Facile synthesis of 4-substituted coumarins		Synlett	42	Lin, GQ	FALSE	FALSE	FALSE	FALSE
6764	10.1021/ol048563t	doi.org/10.1021/ol048563t	A new halopropargylation of alkynes promoted by boron trihalides. Highly stereo- and regioselective syntheses of substituted (Z)-1-halo-1,4-enyne derivatives		Org. Lett.	42	Kabalka, GW	FALSE	FALSE	FALSE	FALSE
6765	10.1081/SCC-200026232	doi.org/10.1081/SCC-200026232	Microwave irradiated solventless Sonogashira reaction on nickel(0) powder doped KF/Al2O3		Synth. Commun.	42	Wang, L	FALSE	FALSE	FALSE	FALSE
6766	10.1021/ma021615e	doi.org/10.1021/ma021615e	Synthesis of fluorinated and hydrocarbon ester functionalized poly(p-phenylenes) and their solubility in supercritical fluids		Macromolecules	42	Wright, ME	FALSE	FALSE	FALSE	FALSE
6767	10.1016/S0040-4020(98)00849-7	doi.org/10.1016/S0040-4020(98)00849-7	Catalytic alternative of the Ullmann reaction		Tetrahedron	42	Lemaire, M	FALSE	FALSE	FALSE	FALSE
6768	10.1021/ja00140a015	doi.org/10.1021/ja00140a015	PRACTICAL CATALYST FOR CYCLIC METATHESIS - SYNTHESIS OF FUNCTIONAL AND/OR ENANTIOPURE CYCLOALKENES		J. Am. Chem. Soc.	42	NUGENT, WA	FALSE	FALSE	FALSE	FALSE
6769	10.1016/0022-328X(89)87299-7	doi.org/10.1016/0022-328X(89)87299-7	TRANSITION-METAL CATALYZED ASYMMETRIC CROSS COUPLING REACTIONS - NEW LIGANDS AND THE EFFECTS OF ADDED SALTS - CRYSTAL-STRUCTURES OF [PH2PCH2CH((CH2)3SME)NME2].PDCL2 AND [PH2PCH2CH((CH2)2SME)NME2].PDCL2		J. Organomet. Chem.	42		FALSE	FALSE	FALSE	FALSE
6770	10.1039/d1cc04996h	doi.org/10.1039/d1cc04996h	Ni-Catalyzed enantioselective reductive arylcyanation/cyclization of N-(2-iodo-aryl) acrylamide		Chem. Commun.	42	Dong, KW	FALSE	FALSE	FALSE	FALSE
6771	10.1039/d1qo01530c	doi.org/10.1039/d1qo01530c	Diastereoselective construction of structurally diverse 2,3-dihydroquinolin-4-one scaffolds via redox neutral cascade [1,7]-hydride transfer/cyclization		Org. Chem. Front.	42	Li, SS; Wang, L; Dong, FY	FALSE	FALSE	FALSE	FALSE
6772	10.1021/acs.cgd.1c00885	doi.org/10.1021/acs.cgd.1c00885	Mechanochromic Luminescence of Four Zn(II)/Cd(II) Complexes Based on Same Schiff-base Ligand with Different Coordination Modes		Cryst. Growth Des.	42	Zheng, XJ	FALSE	FALSE	FALSE	FALSE
6773	10.1021/acs.joc.1c00931	doi.org/10.1021/acs.joc.1c00931	Hydrosilane-Mediated Electrochemical Reduction of Amides		J. Org. Chem.	42	Chiba, K	FALSE	TRUE	FALSE	FALSE
6774	10.1021/acs.orglett.1c02601	doi.org/10.1021/acs.orglett.1c02601	Alkenylation and Arylation of Peptides via Ni-Catalyzed Reductive Coupling of alpha-C-Tosyl Peptides with Csp(2) Triflates/Halides		Org. Lett.	42	Qian, Q; Sun, DL	FALSE	FALSE	FALSE	FALSE
6775	10.1021/acs.orglett.1c02532	doi.org/10.1021/acs.orglett.1c02532	Regioselective Silylations of Propargyl and Allyl Pivalates through Ca-Promoted Reductive C(sp(3))-O Bond Cleavage		Org. Lett.	42	Maekawa, H	FALSE	FALSE	FALSE	FALSE
6776	10.1021/acs.orglett.1c02270	doi.org/10.1021/acs.orglett.1c02270	Ni-Catalyzed Reductive Arylcyanation of Alkenes		Org. Lett.	42	Kong, WQ	FALSE	FALSE	FALSE	FALSE
6777	10.1002/chem.202101273	doi.org/10.1002/chem.202101273	Nickel-Catalyzed Thiolation of Aryl Nitriles		Chem.-Eur. J.	42	Morandi, B	FALSE	FALSE	FALSE	FALSE
6778	10.6023/cjoc202101049	doi.org/10.6023/cjoc202101049	Synthesis and Antifungal Activity of 3-Aryl-7-methyl-7-hydroxy-2-octen-6-olide		Chin. J. Org. Chem.	42	Wang, MA	FALSE	FALSE	FALSE	FALSE
6779	10.1016/j.tetlet.2021.153099	doi.org/10.1016/j.tetlet.2021.153099	Copper-mediated ortho C-H primary amination of anilines		Tetrahedron Lett.	42	Xu, H; Dai, HX	FALSE	FALSE	FALSE	FALSE
6780	10.1038/s41586-021-03448-9	doi.org/10.1038/s41586-021-03448-9	Skeletal editing through direct nitrogen deletion of secondary amines		Nature	42	Levin, MD	FALSE	FALSE	FALSE	FALSE
6781	10.1021/acsmedchemlett.0c00673	doi.org/10.1021/acsmedchemlett.0c00673	Synthesis of C6-Substituted Purine Nucleoside Analogues via Late-Stage Photoredox/Nickel Dual Catalytic Cross-Coupling		ACS Med. Chem. Lett.	42	El Marrouni, A	TRUE	FALSE	FALSE	FALSE
6782	10.1039/c7sc01170a	doi.org/10.1039/c7sc01170a	Cu/Mn bimetallic catalysis enables carbonylative Suzuki-Miyaura coupling with unactivated alkyl electrophiles		Chem. Sci.	42	Mankad, NP	FALSE	FALSE	FALSE	FALSE
6783	10.1021/jacs.7b04312	doi.org/10.1021/jacs.7b04312	Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides		J. Am. Chem. Soc.	42	Watson, DA	FALSE	FALSE	FALSE	FALSE
6784	10.1021/acs.orglett.7b01022	doi.org/10.1021/acs.orglett.7b01022	Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary Benzyl Carbonates with Nitrogen and Oxygen Nucleophiles		Org. Lett.	42	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
6785	10.1002/chem.201602926	doi.org/10.1002/chem.201602926	SuFEx Click: New Materials from SOxF and Silyl Ethers		Chem.-Eur. J.	42	Locklin, J	FALSE	FALSE	FALSE	FALSE
6786	10.1021/acs.orglett.6b02300	doi.org/10.1021/acs.orglett.6b02300	Palladium/Lewis Acid Co-catalyzed Divergent Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Alcohols		Org. Lett.	42	Fan, BM	FALSE	FALSE	FALSE	FALSE
6787	10.1055/s-0035-1562488	doi.org/10.1055/s-0035-1562488	Cobalt-Catalyzed Oxidative Homocoupling of Arylzinc Species		Synthesis	42	Gosmini, C	FALSE	FALSE	FALSE	FALSE
6788	10.1002/anie.201606218	doi.org/10.1002/anie.201606218	Highly Active and Selective Manganese C=O Bond Hydrogenation Catalysts: The Importance of the Multidentate Ligand, the Ancillary Ligands, and the Oxidation State		Angew. Chem.-Int. Edit.	42	Kempe, R	FALSE	FALSE	FALSE	FALSE
6789	10.1016/j.tetlet.2016.07.093	doi.org/10.1016/j.tetlet.2016.07.093	Desymmetrization of acid anhydride with asymmetric esterification catalyzed by chiral phosphoric acid		Tetrahedron Lett.	42	Yamada, K; Takasu, K	FALSE	FALSE	FALSE	FALSE
6790	10.1021/jacs.6b03253	doi.org/10.1021/jacs.6b03253	Nickel-Catalyzed Alkylative Cross-Coupling of Anisoles with Grignard Reagents via C-O Bond Activation		J. Am. Chem. Soc.	42	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6791	10.1021/acs.joc.6b00050	doi.org/10.1021/acs.joc.6b00050	A One-Pot/Single-Analysis Approach to Substrate Scope Investigations Using Comprehensive Two-Dimensional Gas Chromatography (GCxGC)		J. Org. Chem.	42	O'Neil, GW	FALSE	FALSE	FALSE	FALSE
6792	10.1002/anie.201600305	doi.org/10.1002/anie.201600305	Hydride Reduction by a Sodium Hydride-Iodide Composite		Angew. Chem.-Int. Edit.	42	Hirao, H; Chiba, S	FALSE	FALSE	FALSE	FALSE
6793	10.1055/s-0035-1560397	doi.org/10.1055/s-0035-1560397	Copper-Catalyzed Negishi Coupling of Diarylzinc Reagents with Aryl Iodides		Synthesis	42	Giri, R	FALSE	FALSE	FALSE	FALSE
6794	10.1002/anie.201509341	doi.org/10.1002/anie.201509341	An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles		Angew. Chem.-Int. Edit.	42	Buchwald, SL	FALSE	TRUE	FALSE	FALSE
6795	10.1039/c6cc00024j	doi.org/10.1039/c6cc00024j	Metal catalyst-free substitution of allylic and propargylic phosphates with diarylmethyl anions		Chem. Commun.	42	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
6796	10.1021/acs.orglett.0c04310	doi.org/10.1021/acs.orglett.0c04310	Modular and Divergent Syntheses of Protoberberine and Protonitidine Alkaloids	Heterobiaryls are important pharmacophores that are challenging to prepare by traditional cross-coupling methods. An alternative approach is presented where pyridines and diazines are converted into heteroaryl phosphonium salts and coupled with aryl boronic acids. Nickel catalysts are unique for selective heteroaryl transfer, and the reaction has a broad substrate scope that includes complex pharmaceuticals. Phosphonium ions also display orthogonal reactivity in cross-couplings compared to halides, enabling chemoselective palladium-and nickel-catalyzed coupling sequences.	Org. Lett.	41	Jiang, XF	FALSE	FALSE	FALSE	FALSE
6797	10.1055/s-0040-1706662	doi.org/10.1055/s-0040-1706662	Nickel-Catalyzed Intramolecular Nucleophilic Addition of Aryl Halides to Aryl Ketones for the Synthesis of Benzofuran Derivatives	The development of new methods for the direct functionalization of unactivated C-H bonds is ushering in a paradigm shift in the field of retrosynthetic analysis. In particular, the catalytic enantioselective functionalization of C-H bonds represents a highly atom- and step-economic approach toward the generation of structural complexity. However, as a result of their ubiquity and low reactivity, controlling both the chemo- and stereoselectivity of such processes constitutes a significant challenge. Herein we comprehensively review all asymmetric transition-metal-catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emphasis on the nature of stereochemistry generation. Our analysis serves to document the considerable and rapid progress within in the field, while also highlighting limitations of current methods.	Synthesis	41	Deng, CL	FALSE	FALSE	FALSE	FALSE
6798	10.1021/acs.joc.0c02690	doi.org/10.1021/acs.joc.0c02690	Overcoming Kinetic and Thermodynamic Challenges of Classic Cope Rearrangements	Carboxylate groups are ubiquitous in bioactive molecules. The syntheses of carboxylates from petroleum feedstock require a series of oxidation reactions. CO2 represents a cheap and sustainable, preoxidized C1 source. Herein, we describe a simple, selective, and mild procedure for the construction of (hetero)cyclic alpha,beta-unsaturated carboxylic acids from 1,6- and 1,7-enyes and CO2. Terminal 1,7-enynes and sterically hindered alkenes experience a change in regioselectivity and form unconjugated carboxylic acids. Mechanistic studies of the reductive cyclization suggest a hydride insertion pathway, explaining the change in regioselectivity caused by steric effects and distinguishing this work from previous reactions involving CO2.	J. Org. Chem.	41	Grenning, AJ	FALSE	FALSE	FALSE	FALSE
6799	10.1021/acscatal.0c04713	doi.org/10.1021/acscatal.0c04713	Nickel-Catalyzed Vinylidene Insertions into O-H Bonds	A Ni-catalyzed reductive cross-coupling reaction between two electrophiles, amides and aryl iodides, has been developed. This work is the first example using amide as an electrophile to couple with another electrophile, instead of using highly basic and pyrophoric nucleophiles. Furthermore, the Ni catalyst chemoselectively inserting the C-N bond of amide triggered the reductive cross-coupling reaction, which solves the problem that the Ni catalyst preferentially inserts the more reactive C-I bond to form a self-coupling product.	ACS Catal.	41	Uyeda, C	FALSE	FALSE	FALSE	FALSE
6800	10.1039/d0cc05003b	doi.org/10.1039/d0cc05003b	Iron-catalysed enantioconvergent Suzuki-Miyaura cross-coupling to afford enantioenriched 1,1-diarylalkanes	Herein, we report a mild and simple method for the highly selective C(sp(2))-H amination reaction of arenes through visible-light-mediated photoredox catalysis with various amines, including imidazole, triazole, and tetrazole. This procedure has broad application for a range of aromatic compounds and heterocycles.	Chem. Commun.	41	Tyrol, CC	FALSE	FALSE	FALSE	FALSE
6801	10.1039/d0ra09110c	doi.org/10.1039/d0ra09110c	A bifunctional amino acid to study protein-protein interactions	The combination of a transition-metal catalyst and organocatalyst was designed to achieve a highly enantioselective system for the allylic dearomatization reaction of naphthols with racemic secondary allylic alcohols. The desired beta-naphthalenones, bearing an all-carbon quaternary center, were obtained in good yields with high chemo- and enantioselectivities. The cooperative catalytic system, involving a chiral iridium complex and phosphoric acid, provided measurable improvements in yields, and chemo-and enantioselectivities relative to single-catalyst systems. Control experiments indicated that the chiral iridium complex functions as a key species in the control of the absolute configuration, thus enabling the formation of both beta-naphthalenone enantiomers by simply employing opposite enantiomeric ligands.	RSC Adv.	41	Li, XD	FALSE	FALSE	FALSE	FALSE
6802	10.1021/acs.orglett.0c03138	doi.org/10.1021/acs.orglett.0c03138	Combined Cyanoborylation, C-H Activation Strategy for Styrene Functionalization	Transformation of aromatic thioesters into aryl-boronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.	Org. Lett.	41	Montgomery, J	FALSE	FALSE	FALSE	FALSE
6803	10.1002/slct.202002787	doi.org/10.1002/slct.202002787	Nickel-Catalyzed Carbon-Sulfur Bond Formation through Couplings of Aryl Iodides and Aryl Ethanethioates	Direct homologation of aromatic amides with internal alkynes has been accomplished via a nickel-catalyzed sequential C-H activation reaction. The use of a rigid chelating group and a strong aprotic polar solvent successfully divert the classical [4 + 2] annulation to the [2 + 2 + 2] homologation pathway. This transformation is promoted by a simple nickel catalyst without the need of stoichiometric metal oxidants. Mechanistic studies support an unusual substrate-assisted ligand exchange process. NMR and X-ray data suggest a [5,5] Ni-bridged metallacycle as the catalyst resting state. Substrate assisted directing group swap plays an important role for the subsequent meta-C-H insertion. In contrast, [4 + 2] annulation can be accomplished using a bulky, electron-rich phosphine ligand, which favors rapid reductive C-N elimination.	ChemistrySelect	41	Mao, P; Mai, WP	FALSE	FALSE	FALSE	FALSE
6804	10.1039/d0ob01226b	doi.org/10.1039/d0ob01226b	Palladium-catalysed regio- and stereoselective arylative substitution of gamma,delta-epoxy-alpha,beta-unsaturated esters and amides by sodium tetraaryl borates	Palladium-catalyzed Suzuki-Miyaura cross-coupling of primary benzamides enabled by a merger of site selective N,N-di-Boc-activation and cooperative catalysis via N-C bond cleavage for the synthesis of biaryl ketones is reported. We present the synergistic combination of Lewis base and palladium catalysis as a concept to activate inert amide N-C bonds. The mild reaction conditions provide a direct route to structurally diverse ketones. The reaction tolerates a wide range of electrophilic functional groups. Considering the fundamental importance of primary amides as pharmaceutical and synthetic intermediates, the strategy has a potential for developing a diverse array of valuable amide N-C bond functionalization reactions by the synergistic merger of Lewis base and organometallic catalysis.	Org. Biomol. Chem.	41	Artok, L	FALSE	FALSE	FALSE	FALSE
6805	10.1039/d0cc02881a	doi.org/10.1039/d0cc02881a	Conversion of racemic alcohols to optically pure amine precursors enabled by catalyst dynamic kinetic resolution: experiment and computation	An unprecedented rhodium-catalyzed selective cleavage of double alkyl-oxygen bonds of bis/tris(o-alkyloxyphenyl)phosphine has been realized, in which P atom functions as a. directing group and simple aryl acids are the methyl group acceptor to provide methyl esters and a quaternary phosphonium salt. The preliminary mechanism was investigated via an O-18 labeling experiment and stoichiometric reaction between a Rh-A crystal and an aromatic acid.	Chem. Commun.	41	Azofra, LM	FALSE	FALSE	FALSE	FALSE
6806	10.1016/j.jorganchem.2020.121354	doi.org/10.1016/j.jorganchem.2020.121354	Novel and efficient polymer supported copper catalyst for heck reaction	A silver-catalyzed cycloisomerization reaction of a series of o-alkynylbenzohydroxamic acids is reported. Several 5-exo-dig and 6-endo-dig modes of cydization were observed with the nitrogen or oxygen atoms of the amide group acting as nucleophiles. The selectivity was strongly dependent on the silver salt used and on the presence of triphenylphosphine as an additive. Indeed, while the use of Ag2O at room temperature allowed the isolation of isobenzofuran-1-one oximes (7 compounds, 48-92% yield), [Ag(Im)](n) with the concomitant addition of 2 equiv of PPh3 led to a switch in selectivity and to a family of isoindolin-1-ones (10 compounds, 59-87%).	J. Organomet. Chem.	41	Anas, S	FALSE	FALSE	FALSE	FALSE
6807	10.1039/d0ob00811g	doi.org/10.1039/d0ob00811g	Sulfur-mediated synthesis of unsymmetrically substituted N-aryl oxalamides by the cascade thioamidation/cyclocondensation and hydrolysis reaction	A nickel-catalyzed reductive carboxylation technique for the synthesis of cyclopropanecarboxylic acids has been developed. This user-friendly and mild transformation operates at atmospheric pressure of carbon dioxide and utilizes either organic halides or alkene precursors, thus representing the first example of catalytic reductive carboxylation of secondary counterparts lacking adjacent pi-components.	Org. Biomol. Chem.	41	Volkova, YA	FALSE	FALSE	FALSE	FALSE
6808	10.1002/ajoc.202000145	doi.org/10.1002/ajoc.202000145	Magnetically recoverable Ni@CuI hybrid nanocatalysts affording spiropyrroline heterocycles from ketoximes and alkenes	Homoleptic and heteroleptic Ni(II) complexes represented as NiL21 and (NiLLL3)-L-1-L-2 (where, L-1 = N-ethyl-N-phenyldithiocarbamato anion, L-2 = isothiocyanato anion, and L-3 = triphenylphosphine) were synthesized. The complexes have been characterized by elemental, IR, NMR, and single-crystal X-ray analysis. The thermal decomposition behaviour of the complexes were studied using thermogravimetric analysis (TGA). The optimized geometry and the electronic analysis of the type of bonding within the complex structures were performed using methods based on the density functional theory and atom in molecule (AIM) analysis method. X-ray structural analysis of both complexes confirms distorted square planar geometry about the Ni atom. The TGA indicates that the complexes belong to the class of volatile dithiocarbamates which yield the corresponding metal sulphide without any intermediate products. Structural parameters from crystallographic and DFT studies have been compared and found to correlate with each other. The small discrepancies in geometric parameters are attributable to H-bonding and packing interactions within the lattice which are not modelled during computational study. AIM analysis suggests that in (NiLLL3)-L-1-L-2, the Ni center dot center dot center dot L interactions are more covalent in nature whereas in NiL21 complex, they are more ionic in character.	Asian J. Org. Chem.	41	Rawat, DS	FALSE	FALSE	FALSE	FALSE
6809	10.1021/jacs.0c02805	doi.org/10.1021/jacs.0c02805	Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source	This review describes new methods for the synthesis of chiral monophosphine ligands with menthyl phenylphosphinate as a chiral auxiliary through asymmetric Suzuki-Miyaura cross-coupling reactions and asymmetric C-H functionalization. The chiral menthyl phenylphosphinate as a chiral auxiliary is easy to prepare and the menthyl group can easily be transformed into other functional groups, with the chiral center synchronously remaining. These methodologies provide highly efficient and practical strategies for the synthesis of novel axially chiral biaryl monophosphine oxides and their corresponding phosphines. Meanwhile, these reactions are easy to handle and exhibit wide scope for substrates with excellent diastereomeric ratios.	J. Am. Chem. Soc.	41	Doyle, AG	TRUE	FALSE	FALSE	FALSE
6810	10.1038/s42004-020-0292-3	doi.org/10.1038/s42004-020-0292-3	Nickel-catalyzed enantioselective reductive carbo-acylation of alkenes	Palladium-catalysed C(sp(2))-N cross-coupling (that is, Buchwald-Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical industry, for the synthesis of (hetero) aniline derivatives. However, the cost and relative scarcity of palladium provides motivation for the development of alternative, more Earth-abundant catalysts for such transformations. Here we disclose an operationally simple and air-stable ligand/nickel(II) pre-catalyst that accommodates the broadest combination of C(sp(2))-N coupling partners reported to date for any single nickel catalyst, without the need for a precious-metal co-catalyst. Key to the unprecedented performance of this pre-catalyst is the application of the new, sterically demanding yet electron-poor bisphosphine PAd-DalPhos. Featured are the first reports of nickel-catalysed room temperature reactions involving challenging primary alkylamine and ammonia reaction partners employing an unprecedented scope of electrophiles, including transformations involving sought-after (hetero) aryl mesylates for which no capable catalyst system is known.	Comm. Chem.	41	Wang, C	FALSE	FALSE	FALSE	FALSE
6811	10.1021/acs.joc.0c00094	doi.org/10.1021/acs.joc.0c00094	Insights into Substrate Self-Assisted Activation of Allylic Alcohols Guiding to Mild Allylic Substitution of Tautomerizable Heteroarenes	The catalytic C-O bond activation of aryl ethers attracts substantial interest as it is significant for the lignin degradation process. A nickel complex with N-heterocyclic carbene (Ni-SIPr) has been shown to selectively catalyze C-O bond hydrogenolysis of aryl methyl ether to obtain arene and alcohol as the only products. Here, the reaction mechanism of Ni-SIPr catalyzed C-O bond hydrogenolysis of methyl phenyl ether (PhOMe) was studied using density functional theory. In the presence of H-2, the catalytic cycle involves the following: (i) aromatic C-O bond oxidative addition of Ni(SIPr)(eta(2)-PhOMe) to form Ni(SIPr)-(OMe)(Ph), (ii) beta-H transfer from the methoxy to phenyl group in Ni(SIPr)(OMe)(Ph) via sigma-complex-assisted metathesis (sigma-CAM), which eliminates benzene and forms Ni(SIPr)(eta(2)-CH2O), (iii) H-2 binding to form Ni(SIPr)(H-2)(eta(2)-CH2O) prior to H-transfer from H-2 to the formaldehyde carbon via sigma-CAM to generate Ni(SIPr)(H)(OMe), and (iv) reductive elimination to form methanol and the binding of methyl phenyl ether to regenerate Ni(SIPr)(eta(2)-PhOMe). The tert-butoxide base could play a role to assist with the formation of Ni(SIPr)(eta(2)-PhOMe), the catalytically active species, and could bind to Ni(SIPr)(H)(OMe) before reductive elimination. A similar mechanism was found for the C-O bond hydrogenolysis of 2-methoxynaphthalene. Our study showed that the C-O bond oxidative addition is the rate-determining step and that the aromatic C-O bond cleavage to form Ni(SIPr)(OMe)(Ph) is more favorable than the aliphatic C-O bond cleavage to form Ni(SIPr)(OPh)(Me), consistent with the arene and alcohol products obtained from the experiment. Notably, the beta-H transfer from the methoxy to phenyl group on Ni-SIPr is not a stepwise beta-H elimination as generally perceived, but rather a concerted process that occurs via sigma-CAM. This leads to benzene elimination before H-2 binding, in accordance with the results of the isotope labeling experiment of C-O bond hydrogenolysis of 2-methoxynaphthalene. In the absence of H-2, Ni(SIPr)(eta(2)-CH2O) tends to undergo C-H bond activation and alpha-H elimination to release H-2 and generate a nickel carbonyl complex, the catalytically inactive species. This was reflected by experimental results which demonstrated low conversion of 2-methoxynaphthalene in the absence of H-2. Thus, H-2 is crucial to the catalytic reaction through its role in suppressing the formation of the inactive nickel carbonyl species. Insights into the mechanisms of Ni-SIPr catalyzed conversion of methyl phenyl ether should benefit the development of catalysts for C-O bond activation.	J. Org. Chem.	41	Ma, XT	FALSE	FALSE	FALSE	FALSE
6812	10.1021/jacs.9b13531	doi.org/10.1021/jacs.9b13531	Nickel-Catalyzed Decarbonylative Amination of Carboxylic Acid Esters	The direct coupling of sp(3) C-OH bond of N -heterocyclic aminols with sp(2) C-H bond of electron rich arenes have been achieved via iron catalyzed dehydrative cross coupling strategy. This novel protocol provides an efficient and straight forward route to access biologically important C4-aryl-3,4dihydroquinazoline derivatives through the reaction of C4-hydroxy-3,4-dihydroquinazolineiaminol with phenol and aniline derivatives under mild reaction conditions. (C) 2015 Elsevier Ltd. All rights reserved.	J. Am. Chem. Soc.	41	Sanford, MS	FALSE	FALSE	FALSE	FALSE
6813	10.1016/j.mcat.2020.110845	doi.org/10.1016/j.mcat.2020.110845	A theoretical study of the influence of gold nanoplatelets sites in C-C coupling reaction	A chiral thiourea catalyzed asymmetric 1,6-conjugate addition of para-quinone methides with dicyanoolefins has been developed. The reaction provided an efficient approach to the synthesis of chiral diarylmethine skeletons in good yields (up to 99% yield) with high diastereo- and enantioselectivity (>20:1 dr and up to 99.5:0.5 er), also on a gram scale. The preliminary mechanistic study showed that the remote stereocontrol was achieved through intermolecular hydrogen-bond interaction between the chiral thiourea catalyst and the para-quinone methides directly for the first time.	Mol. Catal.	41	Man, IC	FALSE	FALSE	FALSE	FALSE
6814	10.1016/j.poly.2020.114380	doi.org/10.1016/j.poly.2020.114380	A bis(arylphosphinito)amide pincer ligand that binds nickel forming six-membered metallacycles	Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation-borylation of enantiopure secondary benzylic carbamates at -20 degrees C with full chirality transfer.	Polyhedron	41	Miller, AJM	FALSE	FALSE	FALSE	FALSE
6815	10.1039/c9ra08930f	doi.org/10.1039/c9ra08930f	Synthesis of Ag nanoparticles/ordered mesoporous carbon as a highly efficient catalyst for the electroreduction of benzyl bromide		RSC Adv.	41	Wang, H; Lu, JX	FALSE	FALSE	FALSE	FALSE
6816	10.1021/acs.orglett.9b02946	doi.org/10.1021/acs.orglett.9b02946	Synthesis of Allylsilanes via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Allyl Alcohols		Org. Lett.	41	Wang, ZX	FALSE	FALSE	FALSE	FALSE
6817	10.1055/s-0039-1690158	doi.org/10.1055/s-0039-1690158	beta-Selective One-Pot Synthesis of Acyl-C-Glycosides via Corey-Seebach Umpolung Reaction		Synlett	41	Schutzenmeister, N	FALSE	FALSE	FALSE	FALSE
6818	10.6023/A19060201	doi.org/10.6023/A19060201	Application of Propargylic Radicals in Organic Synthesis		Acta Chim. Sin.	41	Lu, LQ; Xiao, WJ	FALSE	FALSE	FALSE	FALSE
6819	10.1021/acs.joc.9b01293	doi.org/10.1021/acs.joc.9b01293	Nickel-Catalyzed Decarboxylative Generation and Asymmetric Allylation of 2-Azaallyl Anions		J. Org. Chem.	41	Chruma, JJ	FALSE	FALSE	FALSE	FALSE
6820	10.1021/acs.jpca.9b04284	doi.org/10.1021/acs.jpca.9b04284	Mechanism and Origin of Enantioselectivity in Nickel-Catalyzed Alkyl-Alkyl Suzuki Coupling Reaction		J. Phys. Chem. A	41	Sunoj, RB	FALSE	FALSE	FALSE	FALSE
6821	10.1021/acs.orglett.9b01925	doi.org/10.1021/acs.orglett.9b01925	Ruthenium-Catalyzed Synthesis of N-Methylated Amides using Methanol		Org. Lett.	41	Kundu, S	FALSE	FALSE	FALSE	FALSE
6822	10.1039/c9ob01173k	doi.org/10.1039/c9ob01173k	Controllable synthesis of 3-chloro- and 3,3-dichloro-2-oxindoles via hypervalent iodine-mediated chlorooxidation		Org. Biomol. Chem.	41	Yu, CM	FALSE	FALSE	FALSE	FALSE
6823	10.1002/app.48200	doi.org/10.1002/app.48200	RhCl(TPPTS)(3) supported on iota-carrageenan as recyclable catalysts for Suzuki cross-coupling		J. Appl. Polym. Sci.	41	Levy-Ontman, O	FALSE	FALSE	FALSE	FALSE
6824	10.1039/c9sc00783k	doi.org/10.1039/c9sc00783k	Nickel-catalyzed C-N bond activation: activated primary amines as alkylating reagents in reductive cross-coupling		Chem. Sci.	41	Rueping, M	FALSE	FALSE	FALSE	FALSE
6825	10.1021/acs.orglett.8b03476	doi.org/10.1021/acs.orglett.8b03476	Cross-Coupling of Chloro(hetero)arenes with Thiolates Employing a Ni(0)-Precatalyst		Org. Lett.	41	Fleischer, I	FALSE	FALSE	FALSE	FALSE
6826	10.1021/acs.orglett.8b02450	doi.org/10.1021/acs.orglett.8b02450	Iridium-Catalyzed Isomerization of N-Sulfonyl Aziridines to Allyl Amines		Org. Lett.	41	Verdaguer, X; Riera, A	FALSE	FALSE	FALSE	FALSE
6827	10.2533/chimia.2018.601	doi.org/10.2533/chimia.2018.601	A Perspective in Catalysis: Development of Efficient Methods in the Age of Sustainability		Chimia	41	Cornella, J	FALSE	FALSE	FALSE	FALSE
6828	10.1055/s-0037-1610023	doi.org/10.1055/s-0037-1610023	Regio- and Stereoselective Nickel-Catalyzed Coupling of Boronic Acids with Allenoates		Synthesis	41	Bandini, M	FALSE	FALSE	FALSE	FALSE
6829	10.1021/acs.orglett.8b01646	doi.org/10.1021/acs.orglett.8b01646	Switchable Selectivity in the Pd-Catalyzed Alkylative Cross-Coupling of Esters		Org. Lett.	41	Newman, SG	FALSE	FALSE	FALSE	FALSE
6830	10.1021/acs.energyfuels.8b01032	doi.org/10.1021/acs.energyfuels.8b01032	Lignin Valorization: A Novel in Situ Catalytic Hydrogenolysis Method in Alkaline Aqueous Solution		Energy Fuels	41	Li, XB	FALSE	FALSE	FALSE	FALSE
6831	10.1002/chem.201801887	doi.org/10.1002/chem.201801887	Nickel-Catalyzed Coupling of Arylzinc Halides with Thioesters		Chem.-Eur. J.	41	Fleischer, I	FALSE	FALSE	FALSE	FALSE
6832	10.1021/acs.joc.8b00604	doi.org/10.1021/acs.joc.8b00604	Ruthenium-Catalyzed Ring-Opening Addition of Anilides to 7-Azabenzonorbornadienes: A Diastereoselective Route to Hydronaphthylamines		J. Org. Chem.	41	Zhang, YH	FALSE	FALSE	FALSE	FALSE
6833	10.1002/chem.201801099	doi.org/10.1002/chem.201801099	Facile Synthesis of Single alpha-tert-Alkylated Acetaldehydes by Hydroxyalkylation of Enamides in Aqueous Solution		Chem.-Eur. J.	41	Nishikata, T	FALSE	FALSE	FALSE	FALSE
6834	10.1039/c7qo01064h	doi.org/10.1039/c7qo01064h	Cobalt-catalyzed asymmetric reactions of heterobicyclic alkenes with in situ generated organozinc halides		Org. Chem. Front.	41	Chen, JC; Fan, BM	FALSE	FALSE	FALSE	FALSE
6835	10.1055/s-0036-1591523	doi.org/10.1055/s-0036-1591523	(DPEPhos)Ni(mesityl)Br: An Air-Stable Pre-Catalyst for Challenging Suzuki-Miyaura Cross-Couplings Leading to Unsymmetrical Biheteroaryls		Synlett	41	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
6836	10.1021/acscatal.7b04105	doi.org/10.1021/acscatal.7b04105	Mechanistic Study of the Nickel-Catalyzed alpha,beta-Coupling of Saturated Ketones		ACS Catal.	41	Wiest, O	FALSE	FALSE	FALSE	FALSE
6837	10.1039/c8ra03754j	doi.org/10.1039/c8ra03754j	Highly efficient and recyclable water-soluble fullerene-supported PdCl2 nanocatalyst in Suzuki-Miyaura cross-coupling reaction		RSC Adv.	41	Huo, P; Liu, WY	FALSE	FALSE	FALSE	FALSE
6838	10.1039/c7ta08389k	doi.org/10.1039/c7ta08389k	Gram-scale synthesis of aligned C3N4-polypyrrole heterojunction aerogels with tunable band structures as efficient visible and near infrared light-driven metal-free photocatalysts		J. Mater. Chem. A	41	Wang, BD	FALSE	FALSE	FALSE	FALSE
6839	10.1021/acs.orglett.7b02399	doi.org/10.1021/acs.orglett.7b02399	Transition-Metal-Free Hydrogenation of Aryl Halides: From Alcohol to Aldehyde		Org. Lett.	41	Kang, YB	FALSE	FALSE	FALSE	FALSE
6840	10.1039/c6sc01086e	doi.org/10.1039/c6sc01086e	Re-orienting coupling of organocuprates with propargyl electrophiles from S(N)2 ' to S(N)2 with stereocontrol		Chem. Sci.	41	Trost, BM	FALSE	FALSE	FALSE	FALSE
6841	10.1021/jacs.5b10270	doi.org/10.1021/jacs.5b10270	Stereospecific Rhodium-Catalyzed Allylic Substitution with Alkenyl Cyanohydrin Pronucleophiles: Construction of Acyclic Quaternary Substituted alpha,beta-Unsaturated Ketones		J. Am. Chem. Soc.	41	Evans, PA	FALSE	FALSE	FALSE	FALSE
6842	10.1055/s-0035-1560531	doi.org/10.1055/s-0035-1560531	Nickel-Catalyzed Regioselective Reductive Cross-Coupling of Aryl Halides with Polysubstituted Allyl Halides in the Presence of Imidazolium Salts		Synlett	41	Ren, HJ	FALSE	FALSE	FALSE	FALSE
6843	10.1021/acs.orglett.5b01466	doi.org/10.1021/acs.orglett.5b01466	Privilege Ynone Synthesis via Palladium-Catalyzed Alkynylation of Super-Active Esters		Org. Lett.	41	Zhang, WQ	FALSE	FALSE	FALSE	FALSE
6844	10.1039/c5dt01040c	doi.org/10.1039/c5dt01040c	Investigations on the catalytic carboxylation of olefins with CO2 towards alpha,beta-unsaturated carboxylic acid salts: characterization of intermediates and ligands as well as substrate effects		Dalton Trans.	41	Schaub, T	FALSE	FALSE	FALSE	FALSE
6845	10.1039/c5ob01849h	doi.org/10.1039/c5ob01849h	Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases		Org. Biomol. Chem.	41	Kerr, WJ	FALSE	FALSE	FALSE	FALSE
6846	10.1039/c5ob01016k	doi.org/10.1039/c5ob01016k	Nickel-catalyzed Suzuki-Miyaura type cross-coupling reactions of (2,2-difluorovinyl)benzene derivatives with arylboronic acids		Org. Biomol. Chem.	41	Wu, JJ	FALSE	FALSE	FALSE	FALSE
6847	10.1016/j.tet.2014.06.037	doi.org/10.1016/j.tet.2014.06.037	Sonogashira cross-coupling of 3-bromo-1,2-diones: an access to 3-alkynyl-1,2-diones		Tetrahedron	41	Lopp, M	FALSE	FALSE	FALSE	FALSE
6848	10.1002/ejoc.201402129	doi.org/10.1002/ejoc.201402129	2,4-and 2,5-Disubstituted Arylthiazoles: Rapid Synthesis by C-H Coupling and Biological Evaluation		Eur. J. Org. Chem.	41	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
6849	10.1021/om5001327	doi.org/10.1021/om5001327	Nickel Hydroxo Complexes as Intermediates in Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling		Organometallics	41	Monfette, S	FALSE	FALSE	FALSE	FALSE
6850	10.1039/c4qo00012a	doi.org/10.1039/c4qo00012a	Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates		Org. Chem. Front.	41	Millan, IRMA	FALSE	FALSE	FALSE	FALSE
6851	10.1039/c4cc00297k	doi.org/10.1039/c4cc00297k	Palladium-catalyzed intermolecular Heck reaction of alkyl halides		Chem. Commun.	41	Zhou, JR	FALSE	FALSE	FALSE	FALSE
6852	10.1002/ejoc.201300934	doi.org/10.1002/ejoc.201300934	p-Nitrophenyl Ethylthioester in Enantioselective Organocatalytic Michael Additions: Different Behaviour of beta-Aryl and beta-Alkyl Enals		Eur. J. Org. Chem.	41	Cid, MB	FALSE	FALSE	FALSE	FALSE
6853	10.1016/j.tetlet.2013.08.032	doi.org/10.1016/j.tetlet.2013.08.032	Substituent effects on the amination of racemic allyl carbonates using commercially available chiral rhodium catalysts		Tetrahedron Lett.	41	Blankespoor, RL	FALSE	FALSE	FALSE	FALSE
6854	10.1055/s-0033-1339334	doi.org/10.1055/s-0033-1339334	Negishi Cross-Coupling Reaction as a Route to Isocombretastatins		Synlett	41	Fedorov, AY	FALSE	FALSE	FALSE	FALSE
6855	10.1016/j.comptc.2013.04.015	doi.org/10.1016/j.comptc.2013.04.015	A DFT study on Pd-catalyzed Suzuki cross-coupling polycondensation of aryl bromide monomers		Comput. Theor. Chem.	41	Li, Z	FALSE	FALSE	FALSE	FALSE
6856	10.1021/jo302307y	doi.org/10.1021/jo302307y	Cyanide Anion as a Leaving Group in Nucleophilic Aromatic Substitution: Synthesis of Quaternary Centers at Azine Heterocycles		J. Org. Chem.	41	Huestis, MP	FALSE	FALSE	FALSE	FALSE
6857	10.1016/j.tet.2012.10.080	doi.org/10.1016/j.tet.2012.10.080	Facile synthesis of 3-arylpyridine derivatives by palladacycle-catalyzed Stille cross-coupling reaction		Tetrahedron	41	Leng, YT	FALSE	FALSE	FALSE	FALSE
6858	10.1039/c3sc00052d	doi.org/10.1039/c3sc00052d	Carbon-carbon bond construction using boronic acids and aryl methyl sulfides: orthogonal reactivity in Suzuki-type couplings		Chem. Sci.	41	Weller, AS	FALSE	FALSE	FALSE	FALSE
6859	10.1055/s-0031-1289698	doi.org/10.1055/s-0031-1289698	N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex Catalyzed alpha-Arylation of Ketones with Aryl Chlorides		Synthesis	41	Shao, LX	FALSE	FALSE	FALSE	FALSE
6860	10.1021/ol2028702	doi.org/10.1021/ol2028702	Enantioselective Boronate Additions to N-Acyl Quinoliniums Catalyzed by Tartaric Acid		Org. Lett.	41	Schaus, SE	FALSE	FALSE	FALSE	FALSE
6861	10.1021/ja209235d	doi.org/10.1021/ja209235d	Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins		J. Am. Chem. Soc.	41	Jamison, TF	FALSE	FALSE	FALSE	FALSE
6862	10.1016/j.carres.2011.08.015	doi.org/10.1016/j.carres.2011.08.015	Study of the stereoselectivity of 2-azido-2-deoxygalactosyl donors: relationship to the steric factors of glycosyl acceptors		Carbohydr. Res.	41	Li, ZT	FALSE	FALSE	FALSE	FALSE
6863	10.1021/ja206047h	doi.org/10.1021/ja206047h	Enantioselective alpha-Arylation of N-Acyloxazolidinones with Copper(II)-bisoxazoline Catalysts and Diaryliodonium Salts		J. Am. Chem. Soc.	41	Gaunt, MJ	FALSE	FALSE	FALSE	FALSE
6864	10.1021/ic2007342	doi.org/10.1021/ic2007342	Synthesis and Reactivity of a Transition Metal Complex Containing Exclusively TEMPO Ligands: Ni(eta(2)-TEMPO)(2)		Inorg. Chem.	41	Captain, B	FALSE	FALSE	FALSE	FALSE
6865	10.1002/chem.201100205	doi.org/10.1002/chem.201100205	Towards the Limit of Atropochiral Stability: H-MIOP, an N-Heterocyclic Carbene Precursor and Cationic Analogue of the H-MOP Ligand		Chem.-Eur. J.	41	Canac, Y	FALSE	FALSE	FALSE	FALSE
6866	10.1055/s-0030-1259723	doi.org/10.1055/s-0030-1259723	Efficient Aqueous-Phase Heck Reaction Catalyzed by a Robust Hydrophilic Pyridine-Bridged Bisbenzimidazolylidene-Palladium Pincer Complex		Synlett	41	Tu, T	FALSE	FALSE	FALSE	FALSE
6867	10.1021/ol102825t	doi.org/10.1021/ol102825t	Tin Mediated Allylation Reactions of Enol Ethers in Water		Org. Lett.	41	Lin, MH	FALSE	FALSE	FALSE	FALSE
6868	10.1002/anie.201101147	doi.org/10.1002/anie.201101147	Synthesis of Atropisomerically Defined, Highly Substituted Biaryl Scaffolds through Catalytic Enantioselective Bromination and Regioselective Cross-Coupling		Angew. Chem.-Int. Edit.	41	Miller, SJ	FALSE	FALSE	FALSE	FALSE
6869	10.1088/1674-0068/23/06/669-674	doi.org/10.1088/1674-0068/23/06/669-674	Predicting Rate Constants for Nucleophilic Reactions of Amines with Diarylcarbenium Ions Using an ONIOM Method		Chin. J. Chem. Phys.	41	Fu, Y	FALSE	FALSE	FALSE	FALSE
6870	10.1021/ol101136a	doi.org/10.1021/ol101136a	Catalytic and Regioselective Ring Expansion of Arylcyclobutanones with Trimethylsilyldiazomethane. Ligand-Dependent Entry to beta-Ketosilane or Enolsilane Adducts		Org. Lett.	41	Kingsbury, JS	FALSE	FALSE	FALSE	FALSE
6871	10.1002/ejoc.201000147	doi.org/10.1002/ejoc.201000147	Ni-II-(sigma-Aryl) Complex Catalyzed Suzuki Reaction of Aryl Tosylates with Arylboronic Acids		Eur. J. Org. Chem.	41	Yang, LM	FALSE	FALSE	FALSE	FALSE
6872	10.1002/chem.200902132	doi.org/10.1002/chem.200902132	Structure-Reactivity Relationships in Negishi Cross-Coupling Reactions		Chem.-Eur. J.	41	Mayr, H	FALSE	FALSE	FALSE	FALSE
6873	10.1016/j.poly.2009.05.080	doi.org/10.1016/j.poly.2009.05.080	Synthesis and structure of indenylnickel(II) chlorides bearing free N-heterocyclic carbene ligands and their catalysis for styrene polymerization		Polyhedron	41	Sun, HM	FALSE	FALSE	FALSE	FALSE
6874	10.1021/jo802460z	doi.org/10.1021/jo802460z	Palladium-Catalyzed Markovnikov Terminal Arylalkynes Hydrostannation: Application to the Synthesis of 1,1-Diarylethylenes		J. Org. Chem.	41	Alami, M	FALSE	FALSE	FALSE	FALSE
6875	10.1016/j.jorganchem.2008.11.003	doi.org/10.1016/j.jorganchem.2008.11.003	Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity		J. Organomet. Chem.	41	Doi, T	FALSE	FALSE	FALSE	FALSE
6876	10.1055/s-2008-1067095	doi.org/10.1055/s-2008-1067095	Sterically demanding, zwitterionic trialkylphosphonium sulfonates as air-stable ligand precursors for efficient palladium-catalyzed cross-couplings of aryl bromides and chlorides		Synthesis	41	Shaughnessy, KH	FALSE	FALSE	FALSE	FALSE
6877	10.1002/anie.200705558	doi.org/10.1002/anie.200705558	Palladium-catalyzed intermolecular ene-yne coupling: Development of an atom-efficient Mizoroki-Heck-type reaction		Angew. Chem.-Int. Edit.	41	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
6878	10.1002/anie.200801447	doi.org/10.1002/anie.200801447	Nickel-catalyzed cross-coupling of aryl methyl ethers with aryl boronic esters		Angew. Chem.-Int. Edit.	41	Tobisu, M	FALSE	FALSE	FALSE	FALSE
6879	10.1021/ol701927g	doi.org/10.1021/ol701927g	Efficient cross-coupling of aryl chlorides with arylzinc reagents catalyzed by amido pincer complexes of nickel		Org. Lett.	41	Wang, ZX	FALSE	FALSE	FALSE	FALSE
6880	10.1016/j.tetlet.2006.01.145	doi.org/10.1016/j.tetlet.2006.01.145	Ferrocenylmethylphosphines as ligands for room temperature Ni(0)-catalyzed Suzuki-Miyaura cross-coupling reactions of aryl arenesulfonates and aryl chlorides		Tetrahedron Lett.	41	Hu, QS	FALSE	FALSE	FALSE	FALSE
6881	10.1080/00397910600773692	doi.org/10.1080/00397910600773692	Expeditious approach to coumarins via Pechmann reaction catalyzed by molecular iodine or AgOTf		Synth. Commun.	41	Wu, J	FALSE	FALSE	FALSE	FALSE
6882	10.1021/jo051283m	doi.org/10.1021/jo051283m	Nickel-catalyzed enantioselective three-component coupling of bis-1,3-dienes, aldehydes, and dimethylzinc		J. Org. Chem.	41	Mori, M	FALSE	FALSE	FALSE	FALSE
6883	10.1021/jo049454v	doi.org/10.1021/jo049454v	Synthesis and deprotonation of 2-(halophenyl)pyridines and 1-(halophenyl)isoquinolines		J. Org. Chem.	41	Mongin, F	FALSE	FALSE	FALSE	FALSE
6884	10.1016/j.tetlet.2004.05.144	doi.org/10.1016/j.tetlet.2004.05.144	Iminophosphine-palladium(O) complexes as highly active catalysts in the Suzuki reaction. Synthesis of undecaaryl substituted corroles		Tetrahedron Lett.	41	Scrivanti, A	FALSE	FALSE	FALSE	FALSE
6885	10.1016/S0957-4166(03)00088-0	doi.org/10.1016/S0957-4166(03)00088-0	Diphosphine mono-sulfides: readily available chiral monophosphines		Tetrahedron-Asymmetry	41	Willis, MC	FALSE	FALSE	FALSE	FALSE
6886	10.1021/jo0257952	doi.org/10.1021/jo0257952	The Baylis-Hillman reaction: One-pot facile synthesis of 2,4-functionalized 1,4-pentadienes		J. Org. Chem.	41	Basavaiah, D	FALSE	FALSE	FALSE	FALSE
6887	10.1021/jm000290u	doi.org/10.1021/jm000290u	Correlation of anti-HIV activity with anion spacing in a series of cosalane analogues with extended polycarboxylate pharmacophores		J. Med. Chem.	41	Cushman, M	FALSE	FALSE	FALSE	FALSE
6888	10.1021/ar990080f	doi.org/10.1021/ar990080f	Chiral monodentate phosphine ligand MOP for transition metal-catalyzed asymmetric reactions		Accounts Chem. Res.	41	Hayashi, T	FALSE	FALSE	FALSE	FALSE
6889	10.1016/S0040-4020(99)00456-1	doi.org/10.1016/S0040-4020(99)00456-1	Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline.		Tetrahedron	41	Lautens, M	FALSE	FALSE	FALSE	FALSE
6890	10.1246/bcsj.70.1943	doi.org/10.1246/bcsj.70.1943	The palladium-catalyzed cross-coupling reaction of organosilicon compounds with allylic carbonates or diene monoxides		Bull. Chem. Soc. Jpn.	41		FALSE	FALSE	FALSE	FALSE
6891	10.1021/jo00070a022	doi.org/10.1021/jo00070a022	NICKEL-MEDIATED CROSS-COUPLING OF UNACTIVATED NEOPENTYL IODIDES WITH ORGANOZINCS		J. Org. Chem.	41		FALSE	FALSE	FALSE	FALSE
6892	10.1021/om00128a003	doi.org/10.1021/om00128a003	SELECTIVE CLEAVAGE OF C-O AND OR SI-O BONDS IN TRIMETHYLSILYL ETHERS PROMOTED BY COBALT(I), RHODIUM(I), AND RUTHENIUM(II) HYDRIDE COMPLEXES		Organometallics	41	KOMIYA, S	FALSE	FALSE	FALSE	FALSE
6893	10.1039/d1ra09052f	doi.org/10.1039/d1ra09052f	Iridium/graphene nanostructured catalyst for the N-alkylation of amines to synthesize nitrogen-containing derivatives and heterocyclic compounds in a green process		RSC Adv.	41	Chen, TR	FALSE	FALSE	FALSE	FALSE
6894	10.1021/acs.orglett.1c03776	doi.org/10.1021/acs.orglett.1c03776	Palladium-Catalyzed Three-Component Regioselective Dehydrogenative Coupling of Indoles, 2-Methylbut-2-ene, and Carboxylic Acids		Org. Lett.	41	Wang, YQ	FALSE	FALSE	FALSE	FALSE
6895	10.1039/d1qo01406d	doi.org/10.1039/d1qo01406d	gem-Difluorovinylation of alkynyl bromoarenes via dual nickel-/palladium-catalyzed cross-electrophile coupling		Org. Chem. Front.	41	Zhang, XM; Lian, Z	FALSE	FALSE	FALSE	FALSE
6896	10.1039/d1cc05408b	doi.org/10.1039/d1cc05408b	Alumination of aryl methyl ethers: switching between sp(2) and sp(3) C-O bond functionalisation with Pd-catalysis		Chem. Commun.	41	Crimmin, MR	FALSE	FALSE	FALSE	FALSE
6897	10.1039/d1qo01284c	doi.org/10.1039/d1qo01284c	Nickel-catalyzed cascade carbonylative synthesis of N-benzoyl indoles from 2-nitroalkynes and aryl iodides		Org. Chem. Front.	41	Ying, J	FALSE	FALSE	FALSE	FALSE
6898	10.1021/acs.orglett.1c02096	doi.org/10.1021/acs.orglett.1c02096	A Ball-Milling-Enabled Cross-Electrophile Coupling		Org. Lett.	41	Browne, DL	FALSE	TRUE	FALSE	FALSE
6899	10.1021/acscatal.1c02146	doi.org/10.1021/acscatal.1c02146	General Chemoselective Suzuki-Miyaura Coupling of Polyhalogenated Aryl Triflates Enabled by an Alkyl-Heteroaryl-Based Phosphine Ligand		ACS Catal.	41	So, CM	FALSE	FALSE	FALSE	FALSE
6900	10.1246/cl.210015	doi.org/10.1246/cl.210015	Alkylation of Heteroaryl Chlorides through Homolytic Aromatic Substitution by Alkyl Radicals Derived from Alkyl Formates		Chem. Lett.	41	Shirakawa, E	FALSE	FALSE	FALSE	FALSE
6901	10.1039/d1sc01349a	doi.org/10.1039/d1sc01349a	Strain-release 2-azaallyl anion addition/borylation of [1.1.1]propellane: synthesis and functionalization of benzylamine bicyclo[1.1.1]pentyl boronates		Chem. Sci.	41	Walsh, PJ	FALSE	FALSE	FALSE	FALSE
6902	10.1039/d1qo00358e	doi.org/10.1039/d1qo00358e	Facile synthesis of 4-acetoxyindoles via PhI(OAc)(2)-mediated dearomatization of 2-alkynylanilines		Org. Chem. Front.	41	He, QQ; Fan, RH	FALSE	FALSE	FALSE	FALSE
6903	10.1021/acs.orglett.7b01858	doi.org/10.1021/acs.orglett.7b01858	Thiophene-Alkyne-Based CMPs as Highly Selective Regulators for Oxidative Heck Reaction		Org. Lett.	41	Zhan, ZP	FALSE	FALSE	FALSE	FALSE
6904	10.1038/s41570-017-0065	doi.org/10.1038/s41570-017-0065	Stereospecific and stereoconvergent cross-couplings between alkyl electrophiles		Nat. Rev. Chem.	41	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
6905	10.1021/acs.orglett.7b01054	doi.org/10.1021/acs.orglett.7b01054	Enantioselective Nickel-Catalyzed Mizoroki Heck Cyclizations To Generate Quaternary Stereocenters		Org. Lett.	41	Desrosiers, JN	FALSE	FALSE	FALSE	FALSE
6906	10.6023/cjoc201703042	doi.org/10.6023/cjoc201703042	Nickel-Catalyzed Reductive Methylation of Alkyl Acid with Methyl p-Tosylate		Chin. J. Org. Chem.	41	Wang, HY	FALSE	FALSE	FALSE	FALSE
6907	10.1039/c6nj03876j	doi.org/10.1039/c6nj03876j	Copper porphyrin catalyzed esterification of C(sp(3))-H via a cross-dehydrogenative coupling reaction		New J. Chem.	41	Liu, HY	FALSE	FALSE	FALSE	FALSE
6908	10.1246/cl.161001	doi.org/10.1246/cl.161001	Palladium-catalyzed Decarbonylative Alkynylation of Aromatic Esters		Chem. Lett.	41	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
6909	10.1021/acs.organomet.6b00830	doi.org/10.1021/acs.organomet.6b00830	Selective Cross-Coupling of (Hetero)aryl Halides with Ammonia To Produce Primary Arylamines using Pd-NHC Complexes		Organometallics	41	Organ, MG	FALSE	FALSE	FALSE	FALSE
6910	10.1021/jacs.6b04789	doi.org/10.1021/jacs.6b04789	Photochemical Nickel-Catalyzed C-H Arylation: Synthetic Scope and Mechanistic Investigations		J. Am. Chem. Soc.	41	Molander, GA	TRUE	FALSE	FALSE	FALSE
6911	10.1021/acs.orglett.6b02026	doi.org/10.1021/acs.orglett.6b02026	Sterically Controlled Cu-Catalyzed or Transition-Metal-Free Cross-Coupling of gem-Difluoroalkenes with Tertiary, Secondary, and Primary Alkyl Grignard Reagents		Org. Lett.	41	Cao, S	FALSE	FALSE	FALSE	FALSE
6912	10.1021/acs.orglett.6b01642	doi.org/10.1021/acs.orglett.6b01642	Copper-Catalyzed Direct Propargylation of Polyfluoroarenes with Secondary Propargyl Phosphates		Org. Lett.	41	Zhang, XG	FALSE	FALSE	FALSE	FALSE
6913	10.2174/1570178613666160812102130	doi.org/10.2174/1570178613666160812102130	Synthesis of 2-(Substituted-silyl)thiophene-3-carboxylates via a Facile [3+2] Cycloaddition Reaction Catalyzed by Potassium tert-Butoxide		Lett. Org. Chem.	41	Cheng, YN; Li, HL	FALSE	FALSE	FALSE	FALSE
6914	10.7536/PC150906	doi.org/10.7536/PC150906	Ring Openings of tert-Cyclobutanols: New Strategy towards the Synthesis of gamma-Substituted Ketones via C-C Bond Cleavage		Prog. Chem.	41	Chen, Z	FALSE	FALSE	FALSE	FALSE
6915	10.1021/acs.joc.0c02388	doi.org/10.1021/acs.joc.0c02388	Selective Synthesis of beta-Ketonitriles via Catalytic Carbopalladation of Dinitriles	A Pd/(R)-BINAP-catalyzed asymmetric benzylic substitution of secondary benzyl carbonates with amides and amines proceeds to form the corresponding optically active benzylamines in good yields with a high enantiomeric ratio. The reaction occurs in a dynamic kinetic asymmetric transformation (DYKAT) manner. Additionally, the asymmetric Pd catalysis can also be applicable to phenol nucleophiles, thus delivering chiral ethers with acceptable yields and enantioselectivity.	J. Org. Chem.	40	Li, RH	FALSE	FALSE	FALSE	FALSE
6916	10.1021/acs.inorgchem.0c02831	doi.org/10.1021/acs.inorgchem.0c02831	Ranking Ligands by Their Ability to Ease (C6F5)(2)(NiL)-L-II -> (NiL)-L-0 + (C6F5)(2) Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands	We demonstrated a convenient new procedure of the Ullmann homocoupling reaction for the synthesis of symmetrical biaryls via homocoupling of aryl iodides over a recyclable gold catalyst comprising Au nanoparticles supported on functional magnetic mesoporous silica (alpha-Fe2O3)-MCM-41-HS-Au. The catalyst was easily separated by an external magnet, and the recovered catalyst was reused in six successive reaction cycles without any significant loss of activity. So, using this catalyst is affordable. Also, the reaction time is much shorter than a few previously reported work. [GRAPHICS] .	Inorg. Chem.	40	Espinet, P	FALSE	FALSE	FALSE	FALSE
6917	10.1039/d0cc06787c	doi.org/10.1039/d0cc06787c	Continuous flow synthesis of arylhydrazines via nickel/photoredox coupling of tert-butyl carbazate with aryl halides	Eco-compatible activation methods in Suzuki-Miyaura cross-coupling reactions offer challenging opportunities for the design of clean and efficient synthetic processes. The main enabling technologies described in the literature are microwaves, ultrasound, grinding (mechanochemistry) and light. These methods can be performed in water or other green solvents with phase-transfer catalysis or even in solventless conditions. In this review, the authors will summarize the progress in this field mainly from 2010 up to the present day.	Chem. Commun.	40	Williams, JD; Kappe, CO	FALSE	FALSE	FALSE	FALSE
6918	10.1055/s-0040-1706602	doi.org/10.1055/s-0040-1706602	Vitamin B-12-Catalyzed Dicarbofunctionalization of Bromoalkenes Under Visible Light Irradiation	Using reaction of 2-chloroethyl phenyl sulfide with 3-aminopropyl functionalized mesoporous MCM-41, applicable substrate was prepared for fixing Cu2+ NPs. The Cu(II)-Et-S@MCM-41 was characterized by FT-IR, CHNS, XRD, FE-SEM, TEM, EDX, ICP-AES, BET and TG analysis. This novel heterogeneous nanocatalyst showed high catalytic performance and reusability for S-arylation of aryl bromides and chlorides using thiourea, benzyl bromide and K2CO3 at 100 degrees C in aqueous medium.	Synthesis	40	Gryko, D	FALSE	FALSE	FALSE	FALSE
6919	10.1021/acs.organomet.0c00584	doi.org/10.1021/acs.organomet.0c00584	Ligand Effects on Decarbonylation of Palladium-Acyl Complexes	The discovery of an ultrafast cross-coupling of alkyland aryllithium reagents with a range of aryl bromides is presented. The essential role of molecular oxygen to form the active palladium catalyst was established; palladium nanoparticles that are highly active in cross-coupling reactions with reaction times ranging from 5 s to 5 min are thus generated in situ. High selectivities were observed for a range of heterocycles and functional groups as well as for an expanded scope of organolithium reagents. The applicability of this method was showcased by the synthesis of the [C-11]-labeled PET tracer celecoxib.	Organometallics	40	Tolman, WB	FALSE	FALSE	FALSE	FALSE
6920	10.1039/d0cc06468h	doi.org/10.1039/d0cc06468h	Nickel-catalyzed C-alkylation of thioamide, amides and esters by primary alcohols through a hydrogen autotransfer strategy	Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.	Chem. Commun.	40	Yang, P; Tang, B	FALSE	FALSE	FALSE	FALSE
6921	10.1016/j.tet.2020.131571	doi.org/10.1016/j.tet.2020.131571	Transition metal free alpha-C-alkylation of ketones using secondary alcohols	The decomposition of ethyl acetate catalyzed by Ni(I) has been investigated in the gas phase both experimentally and computationally. This approach allows us to determine what is the bare effect of the metal center in the catalytic process, without the intervention of environmental factors such as solvent, ligands, counterions, etc. This reaction is found to exhibit three competitive channels affording different products: ketene or ethanol, two units of acetaldehyde, and acetic acid or ethylene. Interestingly, each of these channels involves a characteristic hydrogen shift as the key step on the catalytic process: an inner-sphere H shift, an outer-sphere shift, and a peculiar orbital-like motion that merits careful characterization.	Tetrahedron	40	Morrill, LC	FALSE	FALSE	FALSE	FALSE
6922	10.1021/acs.joc.0c02266	doi.org/10.1021/acs.joc.0c02266	Synthesis of Biaryls via Decarbonylative Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Aryl Anhydrides	A highly general and selective Co-catalyzed biaryl coupling through C-F cleavage under phosphine or NHC-free conditions was described. A broad range of aryl fluorides including unactivated fluorides as well as those with sensitive functionalities could couple with various Ti(OEt)(4)-mediated aryl Grignard reagents with high selectivity under the catalysis of CoCl2/DMPU. Importantly, selective C-F bond activation couplings between two types of fluorines (difluorinated aromatics and on two different coupling partners) and in the presence of C-Cl or C-Br bonds could also be achieved.	J. Org. Chem.	40	Zhu, YM	FALSE	FALSE	FALSE	FALSE
6923	10.1039/d0dt02063j	doi.org/10.1039/d0dt02063j	Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands	A novel Cu(0)-Cu(I)-mediated C-aryl-C-aryl Ullmann coupling has been successfully developed. The use of Cu(I) salts allowed the reactions to proceed under relatively mild conditions (65 degrees C in DMSO for 15-72 h). The developed method was compatible with a relatively wide range of functional groups simultaneously present on the aromatic ring of different electronic nature. The aryl halides with an electron-withdrawing group ortho to the halide or an electron-donating group meta or para to the halide furnished the corresponding products in good to excellent yields (up to 98%). (C) 2016 Elsevier Ltd. All rights reserved.	Dalton Trans.	40	Johnson, MW	FALSE	FALSE	FALSE	FALSE
6924	10.1002/slct.202000814	doi.org/10.1002/slct.202000814	Scandium(III) Trifluoromethanesulfonate Catalyzed Reactions of 9-Aryl-9-fluorenols with 1,1-Diarylethylenes	Rhodium-catalyzed transformation of alkyl aryl sulfides into arylboronic acid pinacol esters via C-S bond cleavage is reported. In combination with transition-metal-catalyzed sitlfanyli group-guided regioselective C-H borylation reactions of alkylthioarenes, this method allows the synthesis of a diverse range of multisubstituted atenes.	ChemistrySelect	40	Wang, LM	FALSE	FALSE	FALSE	FALSE
6925	10.1039/d0nj00032a	doi.org/10.1039/d0nj00032a	Metal-free iodine-promoted direct synthesis of unsymmetrical triarylmethanes	A novel Ni-0-catalyzed carboxylation of aryl tosylates with carbon dioxide has been achieved under moderate temperatures and atmospheric pressure. In this procedure, the active Ni-0 species is generated in situ by simply mixing the Ni-0 precatalyst [NiBr2(bipy)] with an excess of manganese metal. This approach requires neither a glove-box nor the tedious preparation of sophisticated intermediate organometallic derivatives. This mild, convenient, and user-friendly process is successfully applied to the valorization of carbon dioxide and the synthesis of versatile reactants with broad tolerance of substituents.	New J. Chem.	40	Xu, DZ	FALSE	FALSE	FALSE	FALSE
6926	10.1021/acscatal.0c00291	doi.org/10.1021/acscatal.0c00291	Ester Transfer Reaction of Aromatic Esters with Haloarenes and Arenols by a Nickel Catalyst	A method for Pd-catalyzed, aminoquinoline-directed arylation of vinylic C-H bonds with aryl iodides has been developed. This reaction represents a rare example of Pd-catalyzed vinylic C-H functionalization of unsubstituted acrylamide, allowing for the highly regio-and stereoselective preparation of Z-olefins. High tolerance to functional groups is observed with good yields and excellent selectivity. It offers a complementary synthetic method to traditional pathways for Z-olefins.	ACS Catal.	40	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
6927	10.3390/molecules25051040	doi.org/10.3390/molecules25051040	Solvent-Free Iron(III) Chloride-Catalyzed Direct Amidation of Esters	The carbonylative Suzuki-Miyaura reaction between aryl tosylates/triflates with arylboronic acid is herein reported, using base-free conditions and a balloon pressure of carbon monoxide. Under these conditions, unsymmetrical biaryl ketones were obtained in modest to excellent yields. This method was adapted to the synthesis of oxybenzone and ketoprofen in good yields under mild conditions.	Molecules	40	Moshapo, PT	FALSE	FALSE	FALSE	FALSE
6928	10.1126/science.aaz3855	doi.org/10.1126/science.aaz3855	Catalyst-controlled doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles		Science	40	Fu, GC	FALSE	FALSE	FALSE	FALSE
6929	10.1021/jacs.9b12706	doi.org/10.1021/jacs.9b12706	Aryl-Nickel-Catalyzed Benzylic Dehydrogenation of Electron-Deficient Heteroarenes		J. Am. Chem. Soc.	40	Newhouse, TR	FALSE	TRUE	FALSE	FALSE
6930	10.1021/acs.orglett.9b04320	doi.org/10.1021/acs.orglett.9b04320	Reductive sp(3)-sp(2) Coupling Reactions Enable Late-Stage Modification of Pharmaceuticals		Org. Lett.	40	Mennie, KM; Levi, SM	FALSE	FALSE	FALSE	FALSE
6931	10.1021/acs.orglett.9b03871	doi.org/10.1021/acs.orglett.9b03871	Direct Use of Carboxylic Acids in the Photocatalytic Hydroacylation of Styrenes To Generate Dialkyl Ketones		Org. Lett.	40	Doyle, AG	TRUE	FALSE	FALSE	FALSE
6932	10.1021/acs.joc.9b02352	doi.org/10.1021/acs.joc.9b02352	Introduction of Aryl Fluorosulfates into the Realm of Catellani Reaction Substrates		J. Org. Chem.	40	De Borggraeve, WM	FALSE	FALSE	FALSE	FALSE
6933	10.1002/asia.201900908	doi.org/10.1002/asia.201900908	Nickel-Catalyzed Chemoselective Acetalization of Aldehydes With Alcohols under Neutral Conditions		Chem.-Asian J.	40	Balaraman, E	FALSE	FALSE	FALSE	FALSE
6934	10.21577/0103-5053.20190067	doi.org/10.21577/0103-5053.20190067	Palladium Nanoparticles Supported on beta-Cyclodextrin Functionalized Poly(amidoamine)s and Their Application in Suzuki-Miyaura Cross-Coupling Reactions		J. Braz. Chem. Soc.	40	Deng, W	FALSE	FALSE	FALSE	FALSE
6935	10.1002/anie.201901814	doi.org/10.1002/anie.201901814	Seven-Step Continuous Flow Synthesis of Linezolid Without Intermediate Purification		Angew. Chem.-Int. Edit.	40	Jamison, TF	FALSE	FALSE	FALSE	FALSE
6936	10.1002/anie.201900995	doi.org/10.1002/anie.201900995	beta-Selective C-Glycosylation and its Application in the Synthesis of ScleropentasideA		Angew. Chem.-Int. Edit.	40	Schutzenmeister, N	FALSE	FALSE	FALSE	FALSE
6937	10.1007/s10562-019-02652-7	doi.org/10.1007/s10562-019-02652-7	Fe-PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki-Miyaura Coupling Reactions		Catal. Lett.	40	Bhat, BR	FALSE	FALSE	FALSE	FALSE
6938	10.1002/slct.201900153	doi.org/10.1002/slct.201900153	First Example of the Use of Biosourced Alkyl Levulinates as Solvents for Synthetic Chemistry: Application to the Heterogeneously Catalyzed Heck Coupling		ChemistrySelect	40	Fache, F	FALSE	FALSE	FALSE	FALSE
6939	10.1039/c8cc09913h	doi.org/10.1039/c8cc09913h	A solid-supported arylboronic acid catalyst for direct amidation		Chem. Commun.	40	Baxendale, IR; Whiting, A	FALSE	FALSE	FALSE	FALSE
6940	10.1021/acsomega.9b00163	doi.org/10.1021/acsomega.9b00163	FeCl2-Mediated Rearrangement of Allylic Alcohols		ACS Omega	40	DeBoef, B	FALSE	FALSE	FALSE	FALSE
6941	10.1016/j.molstruc.2018.09.064	doi.org/10.1016/j.molstruc.2018.09.064	PEPPSI-type 2-methyl-2-propenyl-functionalized N-heterocyclic carbene-palladium complexes: Synthesis, structural characterization and catalytic activity on Suzuki-Miyaura reaction		J. Mol. Struct.	40	Sahin, N	FALSE	FALSE	FALSE	FALSE
6942	10.2174/1385272823666190423125226	doi.org/10.2174/1385272823666190423125226	Recent Developments in the de Novo Synthesis of Heterocycles by First-Row Transition-Metal-Catalyzed Acceptorless Dehydrogenation		Curr. Org. Chem.	40	Arun, V; De Sarkar, S	FALSE	FALSE	FALSE	FALSE
6943	10.1039/c8cc06370b	doi.org/10.1039/c8cc06370b	Nickel- catalysed alkylation of C( sp3)- H bonds with alcohols: direct access to functionalised N- heteroaromatics		Chem. Commun.	40	Banerjee, D	FALSE	FALSE	FALSE	FALSE
6944	10.1021/acs.orglett.8b02188	doi.org/10.1021/acs.orglett.8b02188	Direct Substitution of Secondary and Tertiary Alcohols To Generate Sulfones under Catalyst- and Additive-Free Conditions		Org. Lett.	40	Xie, PZ; Loh, TP	FALSE	FALSE	FALSE	FALSE
6945	10.1055/s-0036-1591997	doi.org/10.1055/s-0036-1591997	From Propargylic Fluorinations to [1,3]-Rearrangements: Anion and Ligand Effects in Cu-Acetylide Chemistry		Synlett	40	Cordier, CJ	FALSE	FALSE	FALSE	FALSE
6946	10.1021/acscatal.8b02026	doi.org/10.1021/acscatal.8b02026	Expanding the Color Space in the Two-Color Heterogeneous Photocatalysis of Ullmann C-C Coupling Reactions		ACS Catal.	40	Lanterna, AE; Scaiano, JC	TRUE	FALSE	FALSE	FALSE
6947	10.1016/j.jallcom.2018.03.356	doi.org/10.1016/j.jallcom.2018.03.356	In-situ hydrodeoxygenation of a mixture of oxygenated compounds with hydrogen donor over ZrNi/Ir-ZSM-5+Pd/C		J. Alloy. Compd.	40	Wang, L; Li, SZ; Wang, HW	FALSE	FALSE	FALSE	FALSE
6948	10.1039/c7sc05216b	doi.org/10.1039/c7sc05216b	Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols		Chem. Sci.	40	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
6949	10.1021/acs.orglett.7b03049	doi.org/10.1021/acs.orglett.7b03049	Nickel-Catalyzed Hydrogenolysis and Conjugate Addition of 2-(Hydroxymethyl)pyridines via Organozinc Intermediates		Org. Lett.	40	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
6950	10.1055/s-0036-1590863	doi.org/10.1055/s-0036-1590863	DFT Studies Provide Mechanistic Insight into Nickel-Catalyzed Cross-Coupling Involving Organoaluminum-Mediated C-O Bond Cleavage		Synlett	40	Wang, C; Uchiyama, M	FALSE	FALSE	FALSE	FALSE
6951	10.1002/anie.201709180	doi.org/10.1002/anie.201709180	Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst		Angew. Chem.-Int. Edit.	40	Milstein, D	FALSE	FALSE	FALSE	FALSE
6952	10.1007/s11426-017-9025-1	doi.org/10.1007/s11426-017-9025-1	Ni-mediated C-N activation of amides and derived catalytic transformations		Sci. China-Chem.	40	Hong, X	FALSE	FALSE	FALSE	FALSE
6953	10.1002/ejoc.201701005	doi.org/10.1002/ejoc.201701005	The Manganese-Catalyzed Cross-Coupling Reaction and the Influence of Trace Metals		Eur. J. Org. Chem.	40	Madsen, R	FALSE	FALSE	FALSE	FALSE
6954	10.1002/ejoc.201501170	doi.org/10.1002/ejoc.201501170	Practical Synthesis of Phenanthridinones by Palladium-Catalyzed One-Pot C-C and C-N Coupling Reaction: Extending the Substrate Scope to o-Chlorobenzamides		Eur. J. Org. Chem.	40	Fu, HY; Chen, H	FALSE	FALSE	FALSE	FALSE
6955	10.1055/s-0035-1560640	doi.org/10.1055/s-0035-1560640	Synthesis, Properties, and Enantiomerization Behavior of Axially Chiral Phenolic Derivatives of 8-(Naphth-1-yl)quinoline and Comparison to 7,7-Dihydroxy-8,8-biquinolyl and 1,1-Bi-2-naphthol		Synthesis	40	Blakemore, PR	FALSE	FALSE	FALSE	FALSE
6956	10.1055/s-0034-1380450	doi.org/10.1055/s-0034-1380450	A New Benzannulation Reaction of Azoaromatics		Synlett	40	Quayle, P	FALSE	FALSE	FALSE	FALSE
6957	10.6023/cjoc201506029	doi.org/10.6023/cjoc201506029	Acenaphthoimidazole N-Heterocyclic Carbene Palladium Complexes Catalyzed Cyanation Reactions in Aqueous Accelerated by Microwave Irradiation		Chin. J. Org. Chem.	40	Jiang, XJ	FALSE	FALSE	FALSE	FALSE
6958	10.1002/anie.201503936	doi.org/10.1002/anie.201503936	Dialkyl Ether Formation by Nickel-Catalyzed Cross-Coupling of Acetals and Aryl Iodides		Angew. Chem.-Int. Edit.	40	Doyle, AG	FALSE	FALSE	FALSE	FALSE
6959	10.1002/ps.3894	doi.org/10.1002/ps.3894	Design, synthesis and herbicidal activity of novel quinazoline-2,4-diones as 4-hydroxyphenylpyruvate dioxygenase inhibitors		Pest Manag. Sci.	40	Yang, WC	FALSE	FALSE	FALSE	FALSE
6960	10.1002/qua.24922	doi.org/10.1002/qua.24922	Quantum topological resolution of catalyst proficiency		Int. J. Quantum Chem.	40	Jenkins, S	FALSE	FALSE	FALSE	FALSE
6961	10.1002/aoc.3312	doi.org/10.1002/aoc.3312	Oxidative homocoupling of arylboronic acids catalyzed by a 4-aminoantipyrine-Pd(II)complex		Appl. Organomet. Chem.	40	Contreras-Celedon, CA	FALSE	FALSE	FALSE	FALSE
6962	10.1021/acs.oprd.5b00123	doi.org/10.1021/acs.oprd.5b00123	Effective Laboratory-Scale Preparation of Axitinib by Two Cul-Catalyzed Coupling Reactions		Org. Process Res. Dev.	40	Sun, BW	FALSE	FALSE	FALSE	FALSE
6963	10.1016/j.tetlet.2015.02.121	doi.org/10.1016/j.tetlet.2015.02.121	Selective synthesis of either enantiomer of an anti-breast cancer agent via a common enantioenriched intermediate		Tetrahedron Lett.	40	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
6964	10.1002/asia.201500308	doi.org/10.1002/asia.201500308	Highly Chemoselective and Versatile Method for Direct Conversion of Carboxylic Acids to Ketones Utilizing Zinc Ate Complexes		Chem.-Asian J.	40	Hirano, K	FALSE	FALSE	FALSE	FALSE
6965	10.1002/ajoc.201500048	doi.org/10.1002/ajoc.201500048	Addition-Elimination of Aryldimethylaluminum Reagents to Vinylarenes Promoted by the Addition of a Ketone		Asian J. Org. Chem.	40	Mori, A	FALSE	FALSE	FALSE	FALSE
6966	10.1002/ejic.201500148	doi.org/10.1002/ejic.201500148	Modulating Sonogashira Cross-Coupling Reactivity in Four-Coordinate Nickel Complexes by Using Geometric Control		Eur. J. Inorg. Chem.	40	Merten, C	FALSE	FALSE	FALSE	FALSE
6967	10.1016/j.tetlet.2014.11.120	doi.org/10.1016/j.tetlet.2014.11.120	An efficient and recyclable chitosan supported copper(II) heterogeneous catalyst for C-N cross coupling between aryl halides and aliphatic diamines		Tetrahedron Lett.	40	Pramanik, A	FALSE	FALSE	FALSE	FALSE
6968	10.1039/c5cc00430f	doi.org/10.1039/c5cc00430f	Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groups		Chem. Commun.	40	Zou, G	FALSE	FALSE	FALSE	FALSE
6969	10.1016/j.jorganchem.2014.09.032	doi.org/10.1016/j.jorganchem.2014.09.032	The reactivity of N,C,N-intramolecularly coordinated antimony(III) and bismuth(III) oxides with the sterically encumbered organoboronic acid 2,6-i-Pr2C6H3B(OH)(2)		J. Organomet. Chem.	40	Dostal, L	FALSE	FALSE	FALSE	FALSE
6970	10.1002/chem.201402487	doi.org/10.1002/chem.201402487	An Easy Route to (Hetero) arylboronic Acids		Chem.-Eur. J.	40	Blanchet, J	FALSE	FALSE	FALSE	FALSE
6971	10.1021/cs401164z	doi.org/10.1021/cs401164z	Palladium-Catalyzed Stine-Type Coupling of N-Acyl Iminium Ions with Distannanes: A Multicomponent Synthesis of alpha-Amidostannanes		ACS Catal.	40	Arndtsen, BA	FALSE	FALSE	FALSE	FALSE
6972	10.1002/anie.201303994	doi.org/10.1002/anie.201303994	Nickel-Catalyzed Enantioselective Arylation of Pyridinium Ions: Harnessing an Iminium Ion Activation Mode		Angew. Chem.-Int. Edit.	40	Doyle, AG	FALSE	FALSE	FALSE	FALSE
6973	10.1002/ejoc.201300347	doi.org/10.1002/ejoc.201300347	Subtle Steric Effects in Nickel-Catalysed Kumada-Tamao-Corriu Cross-Coupling Using Resorcinarenyl-Imidazolium Salts		Eur. J. Org. Chem.	40	Semeril, D	FALSE	FALSE	FALSE	FALSE
6974	10.3390/molecules18021602	doi.org/10.3390/molecules18021602	An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media		Molecules	40	Shen, LQ	FALSE	FALSE	FALSE	FALSE
6975	10.1016/j.tet.2012.10.044	doi.org/10.1016/j.tet.2012.10.044	Active-alkali metal promoted reductive desulfurization of dibenzothiophene and its hindered analogues		Tetrahedron	40	Pittalis, M	FALSE	FALSE	FALSE	FALSE
6976	10.1021/op3002992	doi.org/10.1021/op3002992	A Practical Synthesis of a PI3K Inhibitor under Noncryogenic Conditions via Functionalization of a Lithium Triarylmagnesiate Intermediate		Org. Process Res. Dev.	40	Tian, QP	FALSE	FALSE	FALSE	FALSE
6977	10.1021/ol301221p	doi.org/10.1021/ol301221p	Suzuki-Miyaura Cross-Coupling Reactions of Potassium Boc-Protected Aminomethyltrifluoroborate with Aryl and Hetaryl Mesylates		Org. Lett.	40	Molander, GA	FALSE	FALSE	FALSE	FALSE
6978	10.1039/c2cc32176a	doi.org/10.1039/c2cc32176a	Application of the lithiation-borylation reaction to the rapid and enantioselective synthesis of the bisabolane family of sesquiterpenes		Chem. Commun.	40	Aggarwal, VK	FALSE	FALSE	FALSE	FALSE
6979	10.1039/c2ob25581b	doi.org/10.1039/c2ob25581b	Theoretical study on the mechanism of Ag-catalyzed synthesis of 3-alkylideneoxindoles from N-aryl-alpha-diazoamides: a Lewis acid or Ag-carbene pathway?		Org. Biomol. Chem.	40	Li, Z	FALSE	FALSE	FALSE	FALSE
6980	10.1055/s-0031-1289871	doi.org/10.1055/s-0031-1289871	Construction of Enantioenriched Tertiary Stereogenic Centers by Nickel- and Palladium-Catalyzed Cross-Coupling Reactions of Alkyl Electrophiles		Synlett	40	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
6981	10.1021/jo201263r	doi.org/10.1021/jo201263r	Stereochemistry of Transmetalation of Alkylboranes in Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions		J. Org. Chem.	40	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
6982	10.1021/ol201457y	doi.org/10.1021/ol201457y	Palladium-/Copper-Catalyzed Regioselective Amination and Chloroamination of Indoles		Org. Lett.	40	Liu, XY	FALSE	FALSE	FALSE	FALSE
6983	10.1021/ol2012007	doi.org/10.1021/ol2012007	Ruthenium-Catalyzed Conversion of sp(3) C-O Bonds in Ethers to C-C Bonds Using Triarylboroxines		Org. Lett.	40	Kochi, T	FALSE	FALSE	FALSE	FALSE
6984	10.1021/ol200617f	doi.org/10.1021/ol200617f	Nickel-Catalyzed Reductive Cross-Coupling of Unactivated Alkyl Halides		Org. Lett.	40	Gong, HG	FALSE	FALSE	FALSE	FALSE
6985	10.1016/j.poly.2011.01.020	doi.org/10.1016/j.poly.2011.01.020	Ru(III) complexes containing 3,5-pyrazole dicarboxylic acid and triphenylphosphine/triphenylarsine: Synthesis, characterization and catalytic activity		Polyhedron	40	Natarajan, K	FALSE	FALSE	FALSE	FALSE
6986	10.1021/ol100666v	doi.org/10.1021/ol100666v	alpha-Arylation of 3-Aryloxindoles		Org. Lett.	40	Sammakia, T	FALSE	FALSE	FALSE	FALSE
6987	10.1039/c0cc01980a	doi.org/10.1039/c0cc01980a	Practical iron-catalyzed dehalogenation of aryl halides		Chem. Commun.	40	Jacobi von Wangelin, A	FALSE	FALSE	FALSE	FALSE
6988	10.1016/j.tetlet.2008.04.116	doi.org/10.1016/j.tetlet.2008.04.116	Suzuki-Miyaura cross-coupling of alpha-phosphoryloxy enol ethers with arylboronic acids		Tetrahedron Lett.	40	Pongdee, R	FALSE	FALSE	FALSE	FALSE
6989	10.1021/ja0730718	doi.org/10.1021/ja0730718	Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids		J. Am. Chem. Soc.	40	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
6990	10.1002/anie.200701365	doi.org/10.1002/anie.200701365	A concise synthesis of enantioenriched fluorinated carbocycles		Angew. Chem.-Int. Edit.	40	Gouverneur, V	FALSE	FALSE	FALSE	FALSE
6991	10.1021/jo060945k	doi.org/10.1021/jo060945k	Synthesis of bulky and electron-rich MOP-type ligands and their applications in palladium-catalyzed C-N bond formation		J. Org. Chem.	40	Zhang, ZG	FALSE	FALSE	FALSE	FALSE
6992	10.1002/anie.200602143	doi.org/10.1002/anie.200602143	Taming a functional group: Creating air-stable, chiral primary phosphanes		Angew. Chem.-Int. Edit.	40	Higham, LJ	FALSE	FALSE	FALSE	FALSE
6993	10.1246/cl.2005.796	doi.org/10.1246/cl.2005.796	Efficient route to 4-substituted-2(5H)-furanones, 2(1H)-quinolones, and pyrones by nickel-catalyzed cross-coupling of arenesulfonates with organozinc reagents		Chem. Lett.	40	Wu, J	FALSE	FALSE	FALSE	FALSE
6994	10.1021/ar030239v	doi.org/10.1021/ar030239v	Molybdenum-catalyzed asymmetric allylic alkylations		Accounts Chem. Res.	40	Belda, O	FALSE	FALSE	FALSE	FALSE
6995	10.1016/j.tetasy.2003.08.044	doi.org/10.1016/j.tetasy.2003.08.044	Halide ion effects in the rhodium-catalyzed allylic substitution reaction using copper(I) alkoxides and enolates		Tetrahedron: Asymmetry	40	Evans, PA	FALSE	FALSE	FALSE	FALSE
6996	10.1002/adsc.200303036	doi.org/10.1002/adsc.200303036	Suzuki-Miyaura cross-coupling with quasi-heterogeneous palladium		Adv. Synth. Catal.	40	Conlon, DA	FALSE	FALSE	FALSE	FALSE
6997	10.1351/pac200375040421	doi.org/10.1351/pac200375040421	Synthesis of coumarins by ring-closing metathesis		Pure Appl. Chem.	40	Grubbs, RH	FALSE	FALSE	FALSE	FALSE
6998	10.1021/jo020438c	doi.org/10.1021/jo020438c	Asymmetric cyclization of omega-formyl-1,3-dienes catalyzed by a zerovalent nickel complex in the presence of silanes		J. Org. Chem.	40	Mori, M	FALSE	FALSE	FALSE	FALSE
6999	10.1021/jo0102157	doi.org/10.1021/jo0102157	Synthesis of 4-substituted coumarins via the palladium-catalyzed cross-couplings of 4-tosylcoumarins with terminal acetylenes and organozinc reagents		J. Org. Chem.	40	Yang, Z	FALSE	FALSE	FALSE	FALSE
7000	10.1016/S0040-4020(99)01107-2	doi.org/10.1016/S0040-4020(99)01107-2	Palladium-catalyzed asymmetric reduction of racemic allylic esters with formic acid: Effects of phosphine ligands on isomerization of pi-allylpalladium intermediates and enantioselectivity		Tetrahedron	40	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7001	10.1039/a908076g	doi.org/10.1039/a908076g	Nickel(0)-catalyzed asymmetric cross-coupling reactions of allylic compounds with arylboronic acids		J. Chem. Soc.-Perkin Trans. 1	40	Uemura, S	FALSE	FALSE	FALSE	FALSE
7002	10.1016/S0040-4020(99)00756-5	doi.org/10.1016/S0040-4020(99)00756-5	Synthetic approaches to condensed aromatic analogues from etoposide, synthesis of A-ring pyridazine picroetoposide		Tetrahedron	40	Monneret, C	FALSE	FALSE	FALSE	FALSE
7003	10.1016/S0040-4020(01)81672-0	doi.org/10.1016/S0040-4020(01)81672-0	DEHYDROGENATION OF ALCOHOLS WITH ALLYL CARBONATES CATALYZED BY PALLADIUM OR RUTHENIUM COMPLEXES		Tetrahedron	40		FALSE	FALSE	FALSE	FALSE
7004	10.1021/om00126a012	doi.org/10.1021/om00126a012	STEREOCHEMISTRY OF SOME LIGAND SUBSTITUTION AND INSERTION REACTIONS IN PSEUDOTETRAHEDRAL RUTHENIUM(II) COMPLEXES		Organometallics	40		FALSE	FALSE	FALSE	FALSE
7005	10.1016/0022-328X(83)80215-0	doi.org/10.1016/0022-328X(83)80215-0	PHOSPHINE-NICKEL(II), PHOSPHINE-COBALT(II), PHOSPHINE-PALLADIUM(0) AND PHOSPHINE-PALLADIUM(II) COMPLEXES AS CATALYSTS IN CROSS-COUPLING REACTIONS OF ARYL-GRIGNARD AND ALKYL-GRIGNARD REAGENTS WITH ORGANIC TELLURIDES		J. Organomet. Chem.	40	UEMURA, S	FALSE	FALSE	FALSE	FALSE
7006	10.1021/acs.orglett.2c00217	doi.org/10.1021/acs.orglett.2c00217	Ni-Catalyzed Asymmetric Reductive Alkenylation of alpha-Chlorosulfones with Vinyl Bromides		Org. Lett.	40	Sun, DL	FALSE	FALSE	FALSE	FALSE
7007	10.1021/acs.orglett.1c03963	doi.org/10.1021/acs.orglett.1c03963	Dynamic Kinetic Resolution in Gold-Catalyzed (4+2)-Annulations between Alkynyl Benzaldehydes and Allenamides to Yield Enantioenriched All-Carbon Diarylalkylmethane Derivatives		Org. Lett.	40	Liu, RS	FALSE	FALSE	FALSE	FALSE
7008	10.1039/d1nj04796e	doi.org/10.1039/d1nj04796e	Dibenzo[d,d']benzo[2,1-b:3,4-b']difurans with extended pi-conjugated chains: synthetic approaches and properties		New J. Chem.	40	Hirano, M	FALSE	FALSE	FALSE	FALSE
7009	10.1080/10426507.2021.2012178	doi.org/10.1080/10426507.2021.2012178	Designing biaryl phosphacyclic ligands: their characterization and evaluation in palladium-catalyzed Suzuki-Miyaura reactions of aryl bromides and chlorides		Phosphorus Sulfur Silicon Relat. Elem.	40	Lamola, JL	FALSE	FALSE	FALSE	FALSE
7010	10.1021/acs.joc.1c00204	doi.org/10.1021/acs.joc.1c00204	Esterification of Carboxylic Acids with Aryl Halides via the Merger of Paired Electrolysis and Nickel Catalysisy		J. Org. Chem.	40	Mei, TS	FALSE	TRUE	FALSE	FALSE
7011	10.1021/acs.orglett.1c02852	doi.org/10.1021/acs.orglett.1c02852	Organocatalytic Asymmetric Arylation of p-Quinone Phosphonates: A Green Access to Biaryl Monophosphorus Ligands		Org. Lett.	40	Zhang, JC	FALSE	FALSE	FALSE	FALSE
7012	10.1055/a-1626-5749	doi.org/10.1055/a-1626-5749	Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks		Synthesis	40	Stevens, CV	FALSE	FALSE	FALSE	FALSE
7013	10.1021/acs.orglett.1c02616	doi.org/10.1021/acs.orglett.1c02616	Stereospecific Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Tosylate and Allyl Alcohol Electrophiles		Org. Lett.	40	Alexanian, EJ	FALSE	TRUE	FALSE	FALSE
7014	10.1021/acs.orglett.1c01879	doi.org/10.1021/acs.orglett.1c01879	Nickel-Catalyzed Arylation of C(sp(3))-O Bonds in Allylic Alkyl Ethers with Organoboron Compounds		Org. Lett.	40	Shi, DY	FALSE	FALSE	FALSE	FALSE
7015	10.1039/d1nj02508b	doi.org/10.1039/d1nj02508b	Facile one-pot synthesis of ketones from primary alcohols under mild conditions		New J. Chem.	40	Kim, HK	FALSE	FALSE	FALSE	FALSE
7016	10.1016/j.poly.2021.115289	doi.org/10.1016/j.poly.2021.115289	Effect of the ancillary ligand in N-heterocyclic carbene iridium(III) catalyzed N-alkylation of amines with alcohols		Polyhedron	40	Huang, M	FALSE	FALSE	FALSE	FALSE
7017	10.1055/a-1467-2494	doi.org/10.1055/a-1467-2494	Late-Stage Derivatization of Buflavine by Nickel-Catalyzed Direct Substitution of a Methoxy Group via C-O Bond Activation		Synthesis	40	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7018	10.1021/acs.orglett.7b00494	doi.org/10.1021/acs.orglett.7b00494	Pd-Catalyzed Acyl C-O Bond Activation for Selective Ring-Opening of alpha-Methylene-beta-lactones with Amines		Org. Lett.	40	Howell, AR	FALSE	FALSE	FALSE	FALSE
7019	10.1055/s-0035-1562788	doi.org/10.1055/s-0035-1562788	Ultrasound-Promoted Synthesis of 4-Pyrimidinols and Their Tosyl Derivatives		Synthesis	40	Dominguez, M	FALSE	FALSE	FALSE	FALSE
7020	10.1002/ejoc.201600356	doi.org/10.1002/ejoc.201600356	Regioselective Synthesis of 2,4-Substituted Pyrido[1,2:1,5]pyrazolo[3,4-d]pyrimidines through Sequential Pd-Catalyzed Arylation and SNAr Reactions		Eur. J. Org. Chem.	40	Routier, S	FALSE	FALSE	FALSE	FALSE
7021	10.1016/j.tet.2016.03.074	doi.org/10.1016/j.tet.2016.03.074	The Diels-Alder reactivity of 2-vinylindenes: synthesis of functionalized tetrahydrofluorenes		Tetrahedron	40	Sarpong, R	FALSE	FALSE	FALSE	FALSE
7022	10.1002/bkcs.10777	doi.org/10.1002/bkcs.10777	Unprecedented Oxidative Addition of Highly Active Manganese into the Oxygen-Sulfur Bond of Coumarin and Pyrone 4-Tosylates		Bull. Korean Chem. Soc.	40	Kim, SH	FALSE	FALSE	FALSE	FALSE
7023	10.1007/s10853-016-9800-3	doi.org/10.1007/s10853-016-9800-3	Functionalization of boron nitride nanosheets (BNNSs) by organic polymers: formation of substituted polythiophene-BNNS structures		J. Mater. Sci.	40	Spencer, JT	FALSE	FALSE	FALSE	FALSE
7024	10.1055/s-0035-1561563	doi.org/10.1055/s-0035-1561563	Selective Preparation of Xanthones from 2-Bromofluorobenzenes and Salicylaldehydes via Palladium-Catalyzed Acylation-SNAr Approach		Synlett	40	Wu, XF	FALSE	FALSE	FALSE	FALSE
7025	10.1021/jacs.6b01877	doi.org/10.1021/jacs.6b01877	Tandem C(sp(2))-OMe Activation/C(sp(2))-C(sp(2)) Coupling in Early Transition-Metal Complexes: Aromatic C-O Activation beyond Late Transition Metals		J. Am. Chem. Soc.	40	Carpentier, JF; Kirillov, E	FALSE	FALSE	FALSE	FALSE
7026	10.1021/acs.orglett.5b03471	doi.org/10.1021/acs.orglett.5b03471	Organocatalyzed Asymmetric 1,6-Conjugate Addition of para-Quinone Methides with Dicyanoolefins		Org. Lett.	40	Lin, AJ; Yao, HQ	FALSE	FALSE	FALSE	FALSE
7027	10.1039/c6cc00536e	doi.org/10.1039/c6cc00536e	Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation-borylation conditions		Chem. Commun.	40	Aggarwal, VK	FALSE	FALSE	FALSE	FALSE
7028	10.1039/d0ob01964j	doi.org/10.1039/d0ob01964j	Acceptorless dehydrogenative condensation: synthesis of indoles and quinolines from diols and anilines	An efficient and mild method for acyl-C-sp3 bond formation based on the direct conversion of carboxylic acids has been established. This protocol is enabled by the synergistic, Ir-photoredox/nickel catalytic cross-coupling of in situ activated carboxylic acids and alkyltrifluoroborates. This versatile method is amenable to the cross-coupling of structurally diverse carbokylic acids with various potassium alkyltrifluoroborates, affording the corresponding ketones with high yields. In this operationally simple cross-coupling protocol, aliphatic ketones are obtained in one step from bench stable, readily available carboxylic acids.	Org. Biomol. Chem.	39	Ballesteros-Garrido, R	FALSE	FALSE	FALSE	FALSE
7029	10.1002/bkcs.12212	doi.org/10.1002/bkcs.12212	Pd-Catalyzed Negishi Cross-Coupling of Vinyl Bromides with Diborylmethylzinc Chloride	A practical, versatile, and efficient method for the palladium-catalyzed direct heteroarylation of acetanilides was developed. In this method, a wide range of acetanilides bearing electron-donating and electron-withdrawing groups are well tolerated, and the desired 2-arylbenzothiazoles are generated in good to high yields through a cross-dehydrogenative coupling process.	Bull. Korean Chem. Soc.	39	Cho, SH	FALSE	FALSE	FALSE	FALSE
7030	10.2174/1570193X17999200723160453	doi.org/10.2174/1570193X17999200723160453	Recent Advances in the Cross-Coupling of Arylaluminums with Electro-phile Reagents	An asymmetric dual-metal relay catalysis strategy that combines Rh/chiral sulfur-olefin-catalyzed enantioselective 1,2-addition with a Pd-catalyzed intramolecular C-O coupling has been developed. The method allows rapid and efficient synthesis of quaternary carbon-containing gem-diaryl benzofuran-3(2H)-ones in good yields in a highly enantioselective manner (up to 99% ee) through a simple one-pot cascade reaction.	Mini-Rev. Org. Chem.	39	Li, QH	FALSE	TRUE	FALSE	FALSE
7031	10.1246/cl.200750	doi.org/10.1246/cl.200750	Palladium-catalyzed Decarbonylative Cyanation of Acyl Fluorides and Chlorides	Trifluoromethanesulfonic acid catalyzed C-O bond cleavage leading to the preparation of functional esters in the presence of N-methylpyrrolidin-2-one (NMP) was accomplished. Various substrates were well tolerated, and a gram-scale experiment was successfully realized. DFT calculations indicated that NMP plays a decisive role in accelerating nucleophilic attack of the functional acid to generate the functional esters in chlorobenzene.	Chem. Lett.	39	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7032	10.1002/cjoc.202000319	doi.org/10.1002/cjoc.202000319	Nickel-Catalyzed Cross-Coupling of Aryl Pivalates with Cyclobutanols Involving C-O and C-C Bond Cleavage	We present herein an unprecedented, efficient and enantioselective synthesis of triarylmethanes and 1,1-diarylalkanes through N-heterocyclic carbene-catalyzed acylative desymmetrization of bisphenols. This method utilizes readily available substrates, reagents and a simple procedure to deliver the valuable products in excellent enantiopurity. DFT calculations reveal that the selectivity is governed by the C-C bond cleavage step of the tetrahedral intermediate leading to the ester product. A transition state model featuring a combination of intramolecular hydrogen bond and steric effect is developed to explain the enantioselectivity.	Chin. J. Chem.	39	Liu, YH	FALSE	FALSE	FALSE	FALSE
7033	10.1002/anie.202006489	doi.org/10.1002/anie.202006489	Unilaterally Fluorinated Acenes: Synthesis and Solid-State Properties	The synthesis of alkyl esters from readily available alkyl halides and chloroformates was achieved for the first time using a mild Ni-catalyzed reductive coupling protocol. Unactivated primary and secondary alkyl iodides as well as glycosyl, benzyl, and aminomethyl halides were successfully employed to yield products in moderate to excellent yields with high functional group tolerance.	Angew. Chem.-Int. Edit.	39	Koert, U	FALSE	FALSE	FALSE	FALSE
7034	10.1039/d0qo00544d	doi.org/10.1039/d0qo00544d	Optimizing chemical reaction conditions using deep learning: a case study for the Suzuki-Miyaura cross-coupling reaction	First-row transition metal catalysis offers a cheaper, more environmentally sustainable alternative to second- and third-row transition metal catalysts. Nickel has shown great promise as a tool for the borylation of unsaturated compounds to yield boronic esters, but Markovnikov-selective hydroborations of simple styrenes have not been well-explored. Herein, we report the synthesis of benzyl boronic esters via nickel-catalyzed hydroboration of styrenes using a heteroleptic N-heterocyclic carbene (NHC)-phosphine nickel complex, IMes(Cy3P)NiCl2. The IMes(Cy3P)NiCl2 complex displays a broad substrate scope and maintains the integrity of yield and regioselectivity when challenged with substrates bearing increased steric hindrance. The heteroleptic complexes also tolerate both electron-withdrawing and-donating groups, in contrast to traditional bis-phosphine and Ni(0) complexes.	Org. Chem. Front.	39	Jiang, HL; Zheng, MY	FALSE	FALSE	FALSE	FALSE
7035	10.1039/d0qo00402b	doi.org/10.1039/d0qo00402b	The protecting group enabled para-selective C-H benzylation of anilides via iron(ii) catalysis: a convenient approach for the synthesis of triarylmethanes	The origin of the regio- and stereocontrol in the Rd-catalyzed gamma-arylation of alpha,beta-unsaturated aldehydes was theoretically investigated. The reaction proceeds via isomerization of different Pd intermediates followed by reductive elimination. Up to 10 Pd isomers were identified and are in equilibrium controlled by an unprecedented swinging palladium mechanism. The subsequent reductive elimination step showed that the formation of the favored gamma-arylated product Was achieved by-a bending of the aryl moiety.. Computational studies also shed light on the mechanism of the arylation reaction and are in good agreement with the experimental observations where only the gamma-arylated product was detected. All geometries were optimized by density functional theory using the B3LYP-functional with standard double-zeta basis set (LANL2DZ). and effective-core potential's for the palladium center and the 6-311G(d,p) basis sets for other atoms. The addition of dispersion forces and solvent corrections were found to play an important role in the description of the system.	Org. Chem. Front.	39	Shi, DQ; Zhao, YS	FALSE	FALSE	FALSE	FALSE
7036	10.1039/d0ra04629a	doi.org/10.1039/d0ra04629a	Continuous flow synthesis of aryl aldehydes by Pd-catalyzed formylation of phenol-derived aryl fluorosulfonates using syngas	Developing more efficient catalysts remains one of the primary targets of organometallic chemists. To accelerate reaching this goal, effective molecular descriptors and visualization tools can represent a remarkable aid. Here, we present a Web application for analyzing the catalytic pocket of metal complexes using topographic steric maps as a general and unbiased descriptor that is suitable for every class of catalysts. To show the broad applicability of our approach, we first compared the steric map of a series of transition metal complexes presenting popular mono-, di-, and tetracoordinated ligands and three classic zirconocenes. This comparative analysis highlighted similarities and differences between totally unrelated ligands. Then, we focused on a recently developed Fe(II) catalyst that is active in the asymmetric transfer hydrogenation of ketones and imines. Finally, we expand the scope of these tools to rationalize the inversion of enantioselectivity in enzymatic catalysis, achieved by point mutation of three amino acids of mononuclear p-hydroxymandelate synthase.	RSC Adv.	39	Hone, CA; Kappe, CO	FALSE	FALSE	FALSE	FALSE
7037	10.1002/cjoc.202000084	doi.org/10.1002/cjoc.202000084	Poly(o-xylylene)s via Cobalt-Catalyzed Reductive Polymerization	The synthesis of beta-arylated alkylamides via alkyl C-H bond arylation has been realized by means of direct one-pot reactions of acyl chlorides, aryl iodides and 8-aminoquinoline. Depending on the structure of the starting materials, both single and double beta-arylated alkylamides could be accessed.	Chin. J. Chem.	39	Zhao, YC	FALSE	FALSE	FALSE	FALSE
7038	10.1039/d0cc01593h	doi.org/10.1039/d0cc01593h	Iron-catalysed alkylation of 2-methyl and 4-methyl azaarenes with alcohols via C-H bond activation	Mechanistic insight into the construction of quaternary silicon chiral centers by rhodium-catalyzed synthesis of spiro-9-silabifluorenes through dehydrogenative silylation is reported. The C-2-symmetric bisphosphine ligand, BINAP, was effective in controlling enantioselectivity, and axially chiral spiro-9-silabifluorenes were obtained in excellent yields with high enantiomeric excess. Monitoring of the reaction revealed the presence of a monohydrosilane intermediate as a mixture of two constitutional isomers. The reaction proceeded through two consecutive dehydrogenative silylations, and the absolute configuration was determined in the first silylative cyclization. Competitive reactions with electron-rich and electron-deficient dihydrosilanes indicated that the rate of silylative cyclization increased with decreasing electron density on the silicon atom of the starting dihydrosilane. Further investigation disclosed a rare interconversion between the two constitutional isomers of the monohydrosilane intermediate with retention of the absolute configuration.	Chem. Commun.	39	Banerjee, D	FALSE	FALSE	FALSE	FALSE
7039	10.1021/acs.biomac.0c00507	doi.org/10.1021/acs.biomac.0c00507	Renewable Molecules & Materials: Anselme Payen Award Symposium in Honor of Ann-Christine Albertsson		Biomacromolecules	39		FALSE	FALSE	FALSE	FALSE
7040	10.1021/acs.orglett.0c00333	doi.org/10.1021/acs.orglett.0c00333	Enantioselective Synthesis of Tertiary alpha,alpha-Diaryl Carbonyl Compounds Using Chiral N,N '-Dioxides under Umpolung Conditions	The reactions of 2-pyridinecarboxaldehyde-phenylhydrazonatolithium C(5)H(4)Npy-CHvN(i)-NaLi(Ph) (abbreviated as LiL) with a 1/2 equivalent of anhydrous metal (Zn, Sn, Fe and Co) chlorides or NiCl2(DME) (DME = 1, 2-dimethoxyethane) produced the corresponding mononuclear metal(II) complexes (1-4 and 7), in which each ligand acts as a bidentate ligand and the coordination geometries around the metals are shown to be tetrahedral within the complexes 1, 3, 4 and 7, respectively, and a tetragonal pyramid in the complex 2. The reaction of LiL successively with sodium tert-butoxide and anhydrous ZrCl4 afforded the unanticipated bizirconium complex 5, in which each monoanionic ligand behaves as a tridentate bridge. Whereas treatment of LiL with NiCl2 and then CH2Cl2 led to an interesting methylene-bridged bis(2-pyridyl-phenylhydrazone) compound 6 in moderate yield; a comparative experiment showed that when the LiL reacted with CH2Cl2, the coupling compound 6 was also obtained but in very low yield. A plausible mechanism of compound 6 formation was also proposed and supported by the density functional theory (DFT) calculations. All the synthesized compounds 1-7 were characterized by single-crystal X-ray diffraction.	Org. Lett.	39	Shin, S	FALSE	FALSE	FALSE	FALSE
7041	10.1039/c9gc03608c	doi.org/10.1039/c9gc03608c	Visible light-promoted copper catalyzed regioselective acetamidation of terminal alkynes by arylamines		Green Chem.	39	Hwang, KC	FALSE	FALSE	FALSE	FALSE
7042	10.1055/s-0039-1690045	doi.org/10.1055/s-0039-1690045	Nickel versus Palladium in Cross-Coupling Catalysis: On the Role of Substrate Coordination to Zerovalent Metal Complexes		Synthesis	39	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
7043	10.1021/acs.orglett.9b03760	doi.org/10.1021/acs.orglett.9b03760	Boron-Templated Dimerization of Allylic Alcohols To Form Protected 1,3-Diols via Acid Catalysis		Org. Lett.	39	Michaelis, DJ	FALSE	FALSE	FALSE	FALSE
7044	10.1021/acs.orglett.9b03503	doi.org/10.1021/acs.orglett.9b03503	Palladium-Catalyzed Hydrocarbonylative Cyclization Enabled by Formal Insertion of Aromatic C=N Bonds into Pd-Acyl Bonds		Org. Lett.	39	Huang, HM	FALSE	FALSE	FALSE	FALSE
7045	10.1002/ejoc.201901037	doi.org/10.1002/ejoc.201901037	Acyl and Benzyl-C-beta-D-Glucosides: Synthesis and Biostudies for Glucose-Uptake-Promoting Activity in C2C12 Mytotubes		Eur. J. Org. Chem.	39	Aidhen, IS	FALSE	FALSE	FALSE	FALSE
7046	10.1080/00397911.2019.1647438	doi.org/10.1080/00397911.2019.1647438	Nickel-catalyzed synthesis of 9-monoalkylated fluorenes from 9-fluorenone hydrazone and alcohols		Synth. Commun.	39	Fan, XH; Yang, LM	FALSE	FALSE	FALSE	FALSE
7047	10.1007/s12039-019-1638-1	doi.org/10.1007/s12039-019-1638-1	Ni(II)/Al(0) mediated benzylic Csp3-Csp3 coupling in aqueous media		J. Chem. Sci.	39	Roy, S	FALSE	FALSE	FALSE	FALSE
7048	10.1002/ejoc.201900602	doi.org/10.1002/ejoc.201900602	alpha-Methylation of Ketones with Methanol Catalyzed by Ni/SiO2-Al2O3		Eur. J. Org. Chem.	39	Duguet, N; Metay, E	FALSE	FALSE	FALSE	FALSE
7049	10.1002/hlca.201900059	doi.org/10.1002/hlca.201900059	Nickel-Catalyzed Cascade Annulation for the Rapid Synthesis of Carbocyclic Nitriles		Helv. Chim. Acta	39	Morandi, B	FALSE	FALSE	FALSE	FALSE
7050	10.1021/jacs.8b13709	doi.org/10.1021/jacs.8b13709	Nickel-Catalyzed Addition of Aryl Bromides to Aldehydes To Form Hindered Secondary Alcohols		J. Am. Chem. Soc.	39	Weix, DJ	FALSE	FALSE	FALSE	FALSE
7051	10.1002/chir.23036	doi.org/10.1002/chir.23036	Organocatalytic alkylation of carbohydrate-containing aldehydes with dihydroquinoline N,O-acetals: Absolute configuration of 1,2-dihydroquinolines		Chirality	39	Pineschi, M	FALSE	FALSE	FALSE	FALSE
7052	10.1080/02678292.2018.1468504	doi.org/10.1080/02678292.2018.1468504	New synthetic strategies and disconnections in the synthesis of liquid crystals enabled by photoredox cross-coupling reactions		Liq. Cryst.	39	Mandle, RJ	FALSE	FALSE	FALSE	FALSE
7053	10.1021/acs.organomet.8b00605	doi.org/10.1021/acs.organomet.8b00605	Probing the Influence of PAd-DalPhos Ancillary Ligand Structure on Nickel-Catalyzed Ammonia Cross-Coupling		Organometallics	39	Johnson, ER; Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7054	10.1055/s-0037-1610158	doi.org/10.1055/s-0037-1610158	Modular Dihydrobenzoazaphosphole Ligands for Suzuki-Miyaura Cross-Coupling		Synthesis	39	Zhang, YD; Senanayake, CH	FALSE	FALSE	FALSE	FALSE
7055	10.1038/s41467-018-06830-w	doi.org/10.1038/s41467-018-06830-w	Defluorosilylation of fluoroarenes and fluoroalkanes		Nat. Commun.	39	Shibata, N	FALSE	FALSE	FALSE	FALSE
7056	10.1021/acs.orglett.8b01886	doi.org/10.1021/acs.orglett.8b01886	Palladium/N-Heterocyclic Carbene (NHC)-Catalyzed Asymmetric [3+2] Cycloaddition Reaction of Vinyl Epoxides with Allenic Amides		Org. Lett.	39	Ding, CH; Hou, XL	FALSE	FALSE	FALSE	FALSE
7057	10.3390/molecules23071715	doi.org/10.3390/molecules23071715	Convenient Method of Synthesizing Aryloxyalkyl Esters from Phenolic Esters Using Halogenated Alcohols		Molecules	39	Feng, F; Qu, W	FALSE	FALSE	FALSE	FALSE
7058	10.1021/acs.orglett.8b01323	doi.org/10.1021/acs.orglett.8b01323	Palladium-Catalyzed Benzylic Phosphorylation of Diarylmethyl Carbonates		Org. Lett.	39	Hirano, K; Miura, M	FALSE	FALSE	FALSE	FALSE
7059	10.1002/macp.201700564	doi.org/10.1002/macp.201700564	Poly[3,4-dihydroxybenzhydrazide]: A Polydopamine Analogue?		Macromol. Chem. Phys.	39	Liebscher, J	FALSE	FALSE	FALSE	FALSE
7060	10.1016/j.tet.2018.02.053	doi.org/10.1016/j.tet.2018.02.053	Synthetic studies on a series of functionalized pyrylium salts, 4-chloro- and 4-bromophosphinines		Tetrahedron	39	Nagahora, N	FALSE	FALSE	FALSE	FALSE
7061	10.1016/j.tetlet.2017.12.073	doi.org/10.1016/j.tetlet.2017.12.073	An efficient stereoselective synthesis of aminocyclohexenes from 7-azanorbornenes via LiAlH4 mediated tandem double bond migration-ring opening sequence		Tetrahedron Lett.	39	Wu, WT; Zhang, Y	FALSE	FALSE	FALSE	FALSE
7062	10.1515/hc-2015-0137	doi.org/10.1515/hc-2015-0137	A stereolibrary of conformationally restricted amino acids based on pyrrolidinyl/piperidinyloxazole motifs		Heterocycl. Commun.	39	Grygorenko, OO	FALSE	FALSE	FALSE	FALSE
7063	10.1021/acs.orglett.5b02410	doi.org/10.1021/acs.orglett.5b02410	Palladium-Catalyzed Stereospecific Decarboxylative Benzylation of Alkynes		Org. Lett.	39	Tunge, JA	FALSE	FALSE	FALSE	FALSE
7064	10.1021/acs.joc.5b00135	doi.org/10.1021/acs.joc.5b00135	Engaging Nonaromatic, Heterocyclic Tosylates in Reductive Cross-Coupling with Aryl and Heteroaryl Bromides		J. Org. Chem.	39	Molander, GA	FALSE	FALSE	FALSE	FALSE
7065	10.1016/j.ejmech.2014.12.020	doi.org/10.1016/j.ejmech.2014.12.020	Synthesis of functionalized 3-, 5-, 6-and 8-aminoquinolines via intermediate (3-pyrrolin-1-yl)- and (2-oxopyrrolidin-1-yl)quinolines and evaluation of their antiplasmodial and antifungal activity		Eur. J. Med. Chem.	39	D'hooghe, M	FALSE	FALSE	FALSE	FALSE
7066	10.1039/c5ob01096a	doi.org/10.1039/c5ob01096a	A Sn atom-economical approach toward arylstannanes: Ni-catalysed stannylation of aryl halides using Bu3SnOMe		Org. Biomol. Chem.	39	Komeyama, K	FALSE	FALSE	FALSE	FALSE
7067	10.1039/c4cc08012b	doi.org/10.1039/c4cc08012b	Controlled synthesis of high molecular weight poly(3-hexylthiophene)s via Kumada catalyst transfer polycondensation with Ni(IPr)(acac)(2) as the catalyst		Chem. Commun.	39	Geng, YH	FALSE	FALSE	FALSE	FALSE
7068	10.1080/00397911.2014.945187	doi.org/10.1080/00397911.2014.945187	Direct Synthesis of Allylic Thioethers Under Greener Conditions: A Solvent- and Catalyst-Free Approach		Synth. Commun.	39	Braga, AL	FALSE	FALSE	FALSE	FALSE
7069	10.1021/ol502953w	doi.org/10.1021/ol502953w	General and Facile Method for exo-Methlyene Synthesis via Regioselective C-C Double-Bond Formation Using a Copper-Amine Catalyst System		Org. Lett.	39	Nishikata, T	FALSE	FALSE	FALSE	FALSE
7070	10.3762/bjoc.10.189	doi.org/10.3762/bjoc.10.189	One-pot stereoselective synthesis of alpha,beta-differentiated diamino esters via the sequence of aminochlorination, aziridination and intermolecular S(N)2 reaction		Beilstein J. Org. Chem.	39	Han, JL	FALSE	FALSE	FALSE	FALSE
7071	10.1002/cjoc.201400174	doi.org/10.1002/cjoc.201400174	Platinum-Catalyzed Asymmetric Ring-opening Reaction of Oxabenzonorbornadiene with Terminal Alkynes		Chin. J. Chem.	39	Long, YH	FALSE	FALSE	FALSE	FALSE
7072	10.1016/j.tet.2013.10.017	doi.org/10.1016/j.tet.2013.10.017	Copper-catalyzed coupling of aryl iodides and tert-butyl beta-keto esters: efficient access to alpha-aryl ketones and alpha-arylacetic acid tert-butyl esters		Tetrahedron	39	Jiang, YW	FALSE	FALSE	FALSE	FALSE
7073	10.1002/chem.201304715	doi.org/10.1002/chem.201304715	Mixed-Ligand Catalysts: A Powerful Tool in Transition-Metal-Catalyzed Cross-Coupling Reactions		Chem.-Eur. J.	39	Peng, L	FALSE	FALSE	FALSE	FALSE
7074	10.1021/ol403104s	doi.org/10.1021/ol403104s	Asymmetric Conjugate Addition to alpha-Substituted Enones/Enolate Trapping		Org. Lett.	39	Alexakis, A	FALSE	FALSE	FALSE	FALSE
7075	10.1039/c4ra04834b	doi.org/10.1039/c4ra04834b	Reduced graphene oxide supported Ni nanoparticles: a high performance reusable heterogeneous catalyst for Kumada-Corriu cross-coupling reactions		RSC Adv.	39	Basu, B	FALSE	FALSE	FALSE	FALSE
7076	10.1080/00397911.2014.924141	doi.org/10.1080/00397911.2014.924141	NICKEL-CATALYZED REDUCTIVE ALKYLATION OF HALOGENATED PYRIDINES WITH SECONDARY ALKYL BROMIDES		Synth. Commun.	39	Liu, HY	FALSE	FALSE	FALSE	FALSE
7077	10.1016/j.tet.2013.08.067	doi.org/10.1016/j.tet.2013.08.067	Practical synthesis of C1-8 fragment of autolytimycin via a chelation-controlled diastereoselective addition of diisopropenylzinc to alpha-methoxy aldehyde		Tetrahedron	39	Shen, YH	FALSE	FALSE	FALSE	FALSE
7078	10.1021/ol402666p	doi.org/10.1021/ol402666p	Enantioselective Synthesis of Axially Chiral Multifunctionalized Biaryls via Asymmetric Suzuki-Miyaura Coupling		Org. Lett.	39	Qiu, LQ	FALSE	FALSE	FALSE	FALSE
7079	10.1002/adsc.201300452	doi.org/10.1002/adsc.201300452	Enantioselective Palladium-Catalyzed Ring-Opening Reaction of Azabenzonorbornadienes with Methyl 2-Iodobenzoate: An Efficient Access to cis-Dihydrobenzo[c]phenanthridinones		Adv. Synth. Catal.	39	Xu, XH	FALSE	FALSE	FALSE	FALSE
7080	10.1007/s40242-013-3057-z	doi.org/10.1007/s40242-013-3057-z	Stereoselective palladium-catalyzed cross-coupling of (2-amido-1-phenylpropyl)zinc compounds with aryl bromides		Chem. Res. Chin. Univ.	39	Tang, S	FALSE	FALSE	FALSE	FALSE
7081	10.1021/jm301516q	doi.org/10.1021/jm301516q	Discovery of 5-Benzyl-3-phenyl-4,5-dihydroisoxazoles and 5-Benzyl-3-phenyl-1,4,2-dioxazoles as Potent Firefly Luciferase Inhibitors		J. Med. Chem.	39	Pulkkinen, JT	FALSE	FALSE	FALSE	FALSE
7082	10.1039/c3cc42292e	doi.org/10.1039/c3cc42292e	Straightforward and highly diastereoselective synthesis of 2,2-di-substituted perhydrofuro[2,3-b]pyran (and furan) derivatives promoted by BiCl3		Chem. Commun.	39	Li, YX	FALSE	FALSE	FALSE	FALSE
7083	10.1039/c3ra40413g	doi.org/10.1039/c3ra40413g	Pd-catalyzed chemoselective threefold cross-coupling of triarylbismuths with benzylic bromides		RSC Adv.	39	Rao, MLN	FALSE	FALSE	FALSE	FALSE
7084	10.1039/c3cc43915a	doi.org/10.1039/c3cc43915a	Nickel-catalyzed alkyne annulation by anilines: versatile indole synthesis by C-H/N-H functionalization		Chem. Commun.	39	Ackermann, L	FALSE	FALSE	FALSE	FALSE
7085	10.1002/cjoc.201200711	doi.org/10.1002/cjoc.201200711	Cu2O-Mediated Room Temperature Cyanation of Aryl Boronic Acids/Esters and TMSCN		Chin. J. Chem.	39	Han, FS	FALSE	FALSE	FALSE	FALSE
7086	10.1002/pola.26340	doi.org/10.1002/pola.26340	Porphyrin-diindenothieno[2,3-b]thiophene alternating copolymerua blue-light harvester in ternary-blend polymer solar cells		J. Polym. Sci. Pol. Chem.	39	Hsu, CS	FALSE	FALSE	FALSE	FALSE
7087	10.1021/ja306602g	doi.org/10.1021/ja306602g	Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent: Stereospecific Construction of Acyclic Quaternary Carbon Stereogenic Centers		J. Am. Chem. Soc.	39	Evans, PA	FALSE	FALSE	FALSE	FALSE
7088	10.1021/ol302166n	doi.org/10.1021/ol302166n	Palladium-Catalyzed Intramolecular C-H Arylation of Arenes Using Tosylates and Mesylates as Electrophiles		Org. Lett.	39	Kalyani, D	FALSE	TRUE	FALSE	FALSE
7089	10.1055/s-0031-1290455	doi.org/10.1055/s-0031-1290455	Ni(cod)(2)/PCy3-Catalyzed Cross-Coupling Reactions of Dihaloarenes with Arylboronic Acids		Synlett	39	Hu, QS	FALSE	FALSE	FALSE	FALSE
7090	10.1055/s-0031-1290972	doi.org/10.1055/s-0031-1290972	Regioselective Synthesis of Trialkylpyrazines via Nickel-Catalyzed Negishi Cross-Coupling of Pyrazine Triflate		Synthesis	39	Lee, KI	FALSE	FALSE	FALSE	FALSE
7091	10.1055/s-0031-1290765	doi.org/10.1055/s-0031-1290765	The Use of Tertiary Alkylmagnesium Nucleophiles in Ni-Catalyzed Cross-Coupling Reactions		Synlett	39	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
7092	10.1016/j.comptc.2012.02.014	doi.org/10.1016/j.comptc.2012.02.014	Origin of regioselectivity of Ni-catalyzed N-butenyl-substituted imidazolium salt annulation reaction: A theoretical study		Comput. Theor. Chem.	39	Qi, CZ	FALSE	FALSE	FALSE	FALSE
7093	10.1021/ol300217x	doi.org/10.1021/ol300217x	Synthesis of Functionalized Dialkyl Ketones from Carboxylic Acid Derivatives and Alkyl Halides		Org. Lett.	39	Weix, DJ	FALSE	FALSE	FALSE	FALSE
7094	10.1055/s-0031-1289650	doi.org/10.1055/s-0031-1289650	Highly Efficient and Enantioselective alpha-Arylation of Cycloalkanones by Scandium-Catalyzed Diazoalkane-Carbonyl Homologation		Synthesis	39	Kingsbury, JS	FALSE	FALSE	FALSE	FALSE
7095	10.1016/j.tet.2011.09.013	doi.org/10.1016/j.tet.2011.09.013	Hydroxylated terphenylphosphine ligands for palladium-catalyzed ortho-selective cross-coupling of dibromophenols, dibromoanilines, and their congeners with Grignard reagents		Tetrahedron	39	Manabe, K	FALSE	FALSE	FALSE	FALSE
7096	10.1039/c0cc02173c	doi.org/10.1039/c0cc02173c	Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates		Chem. Commun.	39	Nakao, Y	FALSE	FALSE	FALSE	FALSE
7097	10.1016/j.tetasy.2010.05.025	doi.org/10.1016/j.tetasy.2010.05.025	Axially chiral phosphine-oxazoline ligands in the silver(I)-catalyzed asymmetric Mannich reaction of fluorinated aldimines with trimethylsiloxyfuran		Tetrahedron-Asymmetry	39	Shi, M	FALSE	FALSE	FALSE	FALSE
7098	10.1021/jm9010803	doi.org/10.1021/jm9010803	Phosphinic Tripeptides as Dual Angiotensin-Converting Enzyme C-Domain and Endothelin-Converting Enzyme-1 Inhibitors		J. Med. Chem.	39	Dive, V	FALSE	FALSE	FALSE	FALSE
7099	10.1021/jp908260j	doi.org/10.1021/jp908260j	Functionalized Mesostructured Silicas As Supports for Palladium Catalysts: Effect of Pore Structure and Collapse on Catalytic Activity in the Suzuki-Miyaura Reaction		J. Phys. Chem. C	39	Crudden, CM	FALSE	FALSE	FALSE	FALSE
7100	10.1039/c0cc01335h	doi.org/10.1039/c0cc01335h	Ni(I) and Ni(II) ring-expanded N-heterocyclic carbene complexes: C-H activation, indole elimination and catalytic hydrodehalogenation		Chem. Commun.	39	Whittlesey, MK	FALSE	FALSE	FALSE	FALSE
7101	10.1021/ol901975u	doi.org/10.1021/ol901975u	Heteroaromatic Sulfonates and Phosphates as Electrophiles in Iron-Catalyzed Cross-Couplings		Org. Lett.	39	Skrydstrup, T	FALSE	TRUE	FALSE	FALSE
7102	10.1002/ejic.200801149	doi.org/10.1002/ejic.200801149	Formation of Homoleptic Tetracarbene versus cis-Chelating Dicarbene Complexes of Nickel(II) and Applications in Kumada-Corriu Couplings		Eur. J. Inorg. Chem.	39	Huynh, HV	FALSE	FALSE	FALSE	FALSE
7103	10.1016/j.synthmet.2008.07.015	doi.org/10.1016/j.synthmet.2008.07.015	A new pi-conjugated star-shaped polymer comprising of full fluorene units: An efficient blue emitter without reduction of color purity undergoing an annealing		Synth. Met.	39	Fang, Q	FALSE	FALSE	FALSE	FALSE
7104	10.1021/ma801243x	doi.org/10.1021/ma801243x	Organolithium-Activated Nickel (OLAN) Catalysis: A New Synthetic Route for Polyarylates		Macromolecules	39	Carter, KR	FALSE	FALSE	FALSE	FALSE
7105	10.1002/adsc.200800414	doi.org/10.1002/adsc.200800414	Rhodiuni/N-Heterocyclic Carbene-Catalyzed Cross-Couplings of Aryl Arenesulfonates with Arylboronic Acids		Adv. Synth. Catal.	39	Zhang, L	FALSE	FALSE	FALSE	FALSE
7106	10.1055/s-2008-1067182	doi.org/10.1055/s-2008-1067182	Ortho-selective cross-coupling of fluorobenzenes with Grignard reagents: Acceleration by electron-donating ortho-directing groups		Synthesis	39	Manabe, K	FALSE	FALSE	FALSE	FALSE
7107	10.1039/b813605j	doi.org/10.1039/b813605j	Enantioselective synthesis of the dimeric pyranonaphthoquinone core of the cardinalins using a late-stage homocoupling strategy		Org. Biomol. Chem.	39	Brimble, MA	FALSE	FALSE	FALSE	FALSE
7108	10.1021/cc070030z	doi.org/10.1021/cc070030z	AgOTf-catalyzed three-component reactions of 2-alkynylbenzaldehydes, amines, and diethylphosphite. An efficient route to 2,3-disubstituted-1,2-dihydroisoquinolin-1-ylphosphonates		J. Comb. Chem.	39	Wu, J	FALSE	FALSE	FALSE	FALSE
7109	10.1021/ol051615+	doi.org/10.1021/ol051615+	Efficient cross-coupling of functionalized arylzinc halides catalyzed by a nickel chloride-diethyl phosphite system		Org. Lett.	39	Gavryushin, A	FALSE	FALSE	FALSE	FALSE
7110	10.1021/ma049572k	doi.org/10.1021/ma049572k	Design and synthesis of new polymeric materials for organic nonvolatile electrical bistable storage devices: Poly(biphenylmethylene)s		Macromolecules	39	Carter, KR	FALSE	FALSE	FALSE	FALSE
7111	10.1002/anie.200461444	doi.org/10.1002/anie.200461444	Metal-free cross-coupling reactions of aryl sulfonates and phosphates through photoheterolysis of aryl-oxygen bonds		Angew. Chem.-Int. Edit.	39	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
7112	10.1039/b411111g	doi.org/10.1039/b411111g	A simple solid phase diversity linker strategy using enol phosphonates		Org. Biomol. Chem.	39	Steel, PG	FALSE	FALSE	FALSE	FALSE
7113	10.1021/ol027256p	doi.org/10.1021/ol027256p	Microwave promoted Pd-catalyzed cyanation of aryl triflates: A fast and versatile access to 3-cyano-3-desoxy-10-ketomorphinans		Org. Lett.	39	Neumeyer, JL	FALSE	FALSE	FALSE	FALSE
7114	10.1135/cccc20030917	doi.org/10.1135/cccc20030917	Synthesis of helicene scaffolds via [2+2+2] cycloisomerization of aromatic triynes		Collect. Czech. Chem. Commun.	39	Stara, IG	FALSE	FALSE	FALSE	FALSE
7115	10.1021/jo010786z	doi.org/10.1021/jo010786z	Regioselective palladium-catalyzed alkylation of allylic halides with benzylic Grignard reagents. Two-step synthesis of abietane terpenes and tetracyclic polyprenoid compounds		J. Org. Chem.	39	Demuth, M	FALSE	FALSE	FALSE	FALSE
7116	10.1021/jo980200h	doi.org/10.1021/jo980200h	Palladium-catalyzed reaction of N-allylbenzotriazoles with amines: A novel method for the preparation of allylamines		J. Org. Chem.	39	Katritzky, AR	FALSE	FALSE	FALSE	FALSE
7117	10.1016/S0020-1693(97)06085-4	doi.org/10.1016/S0020-1693(97)06085-4	Palladium(II) and platinum(II) complexes containing new phosphinoxy chiral P,N-ligands		Inorg. Chim. Acta	39	Faraone, F	FALSE	FALSE	FALSE	FALSE
7118	10.1039/a608384f	doi.org/10.1039/a608384f	Copper(I)-catalysed homocoupling of organosilicon compounds: Synthesis of biaryls, dienes and diynes		J. Chem. Soc.-Perkin Trans. 1	39	Kang, SK	FALSE	FALSE	FALSE	FALSE
7119	10.1016/S0022-328X(96)06712-5	doi.org/10.1016/S0022-328X(96)06712-5	Synthesis of (R)-2-diphenylphosphino-2'-diphenylphosphinomethyl,-1,1'-binaphthyl and its use for asymmetric hydrogenation of alpha-alkylstyrenes		J. Organomet. Chem.	39		FALSE	FALSE	FALSE	FALSE
7120	10.1021/ja00016a037	doi.org/10.1021/ja00016a037	A PRACTICAL REVERSED-POLARITY ALTERNATIVE TO ORGANOCUPRATE CONJUGATE ADDITION CHEMISTRY - HALOCARBON COUPLING REACTIONS OF ENAL-DERIVED AND ENONE-DERIVED ALLYLNICKEL REAGENTS		J. Am. Chem. Soc.	39		FALSE	FALSE	FALSE	FALSE
7121	10.1021/jo00244a060	doi.org/10.1021/jo00244a060	NICKEL-CATALYZED SILYLOLEFINATION OF DITHIOACETALS - A STEREOSELECTIVE WAY TO VINYLSILANES		J. Org. Chem.	39		FALSE	FALSE	FALSE	FALSE
7122	10.1021/om00146a015	doi.org/10.1021/om00146a015	PREPARATION OF NOVEL PLATINUM AND PALLADIUM COMPLEXES BY REACTION OF 1,1'-METALLOCENEDICHALCOGENOLS WITH TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) OR TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0) - THE IMPORTANT ROLE OF THE COORDINATING ABILITY OF THE METAL ATOM OF THE METALLOCENE IN PRODUCT FORMATIONH		Organometallics	39	AKABORI, S	FALSE	FALSE	FALSE	FALSE
7123	10.1016/S0040-4020(01)90587-3	doi.org/10.1016/S0040-4020(01)90587-3	NEW SYNTHETIC METHODS FOR ALPHA, BETA-UNSATURATED KETONES, ALDEHYDES, ESTERS AND LACTONES BY THE PALLADIUM-CATALYZED REACTIONS OF SILYL ENOL ETHERS, KETENE SILYL ACETALS, AND ENOL ACETATES WITH ALLYL CARBONATES		Tetrahedron	39		FALSE	FALSE	FALSE	FALSE
7124	10.1039/d2ob00041e	doi.org/10.1039/d2ob00041e	A concise synthesis of herbertenolide		Org. Biomol. Chem.	39	Xie, WQ	FALSE	FALSE	FALSE	FALSE
7125	10.1021/acs.orglett.1c04268	doi.org/10.1021/acs.orglett.1c04268	Photoredox/Nickel Dual Catalysis Enables the Synthesis of Alkyl Cyclopropanes via C(sp(3))-C(sp(3)) Cross Electrophile Coupling of Unactivated Alkyl Electrophiles		Org. Lett.	39	Maji, B	TRUE	TRUE	FALSE	FALSE
7126	10.1021/acs.orglett.1c04321	doi.org/10.1021/acs.orglett.1c04321	Ir-Catalyzed Remote Functionalization by the Combination of Deconjugative Chain-Walking and C-H Activation Using a Transient Directing Group		Org. Lett.	39	Shibata, T	FALSE	FALSE	FALSE	FALSE
7127	10.1021/acs.jpcc.1c09050	doi.org/10.1021/acs.jpcc.1c09050	Ester-Carbene and Its Dimerization with Exclusive Cis-Selectivity on a Silver Surface		J. Phys. Chem. C	39	Ong, CW; Chiang, CM	FALSE	FALSE	FALSE	FALSE
7128	10.1007/s11244-021-01554-6	doi.org/10.1007/s11244-021-01554-6	A Palladium Complex Dispersed in Ionic Liquid as an Efficient Catalytic Combination for the Synthesis of Benzazoles		Top. Catal.	39	Ramakrishna, D	FALSE	FALSE	FALSE	FALSE
7129	10.1021/acs.orglett.1c04123	doi.org/10.1021/acs.orglett.1c04123	Regio- and Stereoselective Synthesis of Enol Carboxylate, Phosphate, and Sulfonate Esters via Iodo(III)functionalization of Alkynes		Org. Lett.	39	Yoshikai, N	FALSE	FALSE	FALSE	FALSE
7130	10.1002/aoc.6493	doi.org/10.1002/aoc.6493	Nickel-catalyzed alpha-alkylation of ketones with benzyl alcohols		Appl. Organomet. Chem.	39	Liu, N	FALSE	FALSE	FALSE	FALSE
7131	10.1021/acs.orglett.1c02285	doi.org/10.1021/acs.orglett.1c02285	Nickel-Catalyzed Cyanation of Aryl Thioethers		Org. Lett.	39	Morandi, B	FALSE	FALSE	FALSE	FALSE
7132	10.1021/acs.orglett.1c01447	doi.org/10.1021/acs.orglett.1c01447	Ni-Catalyzed 1,2-Diarylation of Alkenyl Ketones: A Comparative Study of Carbonyl-Directed Reaction Systems		Org. Lett.	39	Engle, KM	FALSE	FALSE	FALSE	FALSE
7133	10.1039/d1nj01762d	doi.org/10.1039/d1nj01762d	A magnetic palladium nickel carbon nanocomposite as a heterogeneous catalyst for the synthesis of distyrylbenzene and biphenyl derivatives		New J. Chem.	39	Niknam, K	FALSE	FALSE	FALSE	FALSE
7134	10.1021/acscatal.1c00531	doi.org/10.1021/acscatal.1c00531	Linear Regression Model Development for Analysis of Asymmetric Copper-Bisoxazoline Catalysis		ACS Catal.	39	Sigman, MS	FALSE	FALSE	FALSE	FALSE
7135	10.1021/acs.orglett.1c00280	doi.org/10.1021/acs.orglett.1c00280	Synthesis of 4-Alkylindoles from 2-Alkynylanilines via Dearomatization- and Aromatization-Triggered Alkyl Migration		Org. Lett.	39	He, QQ; Fan, RH	FALSE	FALSE	FALSE	FALSE
7136	10.1021/acs.organomet.7b00463	doi.org/10.1021/acs.organomet.7b00463	Synthesis and Characterization of Bidentate NHC-C-Aryl Nickel(II) Complexes: Isocyanide Insertion To Form NHC-eta(2)-iminoacyl Complexes		Organometallics	39	Fout, AR	FALSE	FALSE	FALSE	FALSE
7137	10.1055/s-0036-1590819	doi.org/10.1055/s-0036-1590819	Nickel-Catalyzed Cross-Coupling of Ammonia or Primary Alkylamines with (Hetero)aryl Sulfamates, Carbamates, or Pivalates		Synlett	39	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7138	10.1016/j.tet.2017.05.090	doi.org/10.1016/j.tet.2017.05.090	Stereoselective formal synthesis of (-)-fumagillol		Tetrahedron	39	Raghavan, S	FALSE	FALSE	FALSE	FALSE
7139	10.1021/acs.orglett.7b00732	doi.org/10.1021/acs.orglett.7b00732	General and Mild Nickel-Catalyzed Cyanation of Aryl/Heteroaryl Chlorides with Zn(CN)(2): Key Roles of DMAP		Org. Lett.	39	Liu, YH	FALSE	FALSE	FALSE	FALSE
7140	10.1248/cpb.c16-00568	doi.org/10.1248/cpb.c16-00568	Concise, Protecting-Group-Free Synthesis of (+)-Nemonapride via Eu(OTf)(3)-Catalyzed Aminolysis of 3,4-Epoxy Alcohol		Chem. Pharm. Bull.	39	Iwabuchi, Y	FALSE	FALSE	FALSE	FALSE
7141	10.1246/cl.160783	doi.org/10.1246/cl.160783	Dibenzofuran-based C-2-Symmetric Chiral Diamines: Their Synthesis and Chiral Recognition Properties		Chem. Lett.	39	Ito, S; Asami, M	FALSE	FALSE	FALSE	FALSE
7142	10.1021/acs.joc.6b00800	doi.org/10.1021/acs.joc.6b00800	Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis		J. Org. Chem.	39	Molander, GA	TRUE	FALSE	FALSE	FALSE
7143	10.1021/acs.organomet.6b00485	doi.org/10.1021/acs.organomet.6b00485	ZnCl2 Capture Promotes Ethylene Polymerization by a Salicylaldiminato Ni Complex Bearing a Pendent 2,2 '-Bipyridine Group		Organometallics	39	Tonks, IA	FALSE	FALSE	FALSE	FALSE
7144	10.1016/j.tetlet.2016.06.042	doi.org/10.1016/j.tetlet.2016.06.042	An N-heterocyclic carbene-based nickel catalyst for the Kumada-Tamao-Corriu coupling of aryl bromides and tertiary alkyl Grignard reagents		Tetrahedron Lett.	39	Ando, S; Ishizuka, T	FALSE	FALSE	FALSE	FALSE
7145	10.1021/acs.orglett.6b00744	doi.org/10.1021/acs.orglett.6b00744	Arylative Desulfonation of Diarylmethyl Phenyl Sulfone with Arenes Catalyzed by Scandium Triflate		Org. Lett.	39	Nambo, M; Crudden, CM	FALSE	FALSE	FALSE	FALSE
7146	10.1021/acs.joc.6b00616	doi.org/10.1021/acs.joc.6b00616	Stereoselective Formal Synthesis of (+)- and (-)-Cyclophellitol and (-)-Conduritol-B and Synthesis of (-)-Conduramine-B Derivative Using a Sulfinyl Moiety for C-O Bond Formation and alpha-Chloro Sulfide for C-C Bond Formation		J. Org. Chem.	39	Raghavan, S	FALSE	FALSE	FALSE	FALSE
7147	10.1002/pi.5086	doi.org/10.1002/pi.5086	Nickel-catalysed Kumada polycondensation of di-functionalized Grignard reagent with aryl fluoride		Polym. Int.	39	Wang, JY	FALSE	FALSE	FALSE	FALSE
7148	10.1021/acs.joc.6b00317	doi.org/10.1021/acs.joc.6b00317	Synthesis of beta-Substituted Cyclic Enones via Phosphonium Salt-Activated, Palladium-Catalyzed Cross-Coupling of Cyclic 1,3-Diones		J. Org. Chem.	39	Yang, SM	FALSE	FALSE	FALSE	FALSE
7149	10.1002/anie.201511486	doi.org/10.1002/anie.201511486	Nickel-Catalyzed Activation of Acyl C-O Bonds of Methyl Esters		Angew. Chem.-Int. Edit.	39	Houk, KN; Garg, NK	FALSE	FALSE	FALSE	FALSE
7150	10.1039/c6nj01434h	doi.org/10.1039/c6nj01434h	CuFe2O4 magnetic nanoparticle catalyzed odorless synthesis of sulfides using phenylboronic acid and aryl halides in the presence of S-8		New J. Chem.	39	Rostami, A	FALSE	FALSE	FALSE	FALSE
7151	10.6023/cjoc202008012	doi.org/10.6023/cjoc202008012	Study on the Copper-Catalyzed Selective Allylation of Aryl (or Alkyl) Halides	An iodine promoted phosphonation of benzoxazoles and benzothiazoles with trialkyl phosphites was described. This reaction undergoes three steps: an addition procedure, followed by a radical oxidation, and an elimination reaction, provides an efficient method to access 2-phosphated products with a broad scope of substrates.	Chin. J. Org. Chem.	38	He, HH; Zhang, XH	FALSE	FALSE	FALSE	FALSE
7152	10.1080/10406638.2021.1881130	doi.org/10.1080/10406638.2021.1881130	A Facile Synthesis and Antitumor Activity of Novel 2-Aryl-2,3-dihydro-1H-pyrrolo[3,4-b]quinoxalin-1-ones	Silver nitrate-catalyzed cascade decarboxylation and oxidative cyclization of alpha-oxocarboxylic acids, alkenes, and aldehydes is demonstrated for the first time. With ammonium persulfate as the oxidant, the cascade reactions afford dihydroflavonoid derivatives as products in moderate to good yields, exhibiting a broad substrate tolerance. Control experiments indicated that the mechanism includes a radical pathway with aldehydes as the carbon radical acceptors.	Polycycl. Aromat. Compd.	38	Li, Y	FALSE	FALSE	FALSE	FALSE
7153	10.1002/chem.202004455	doi.org/10.1002/chem.202004455	Highly Regioselective 5-endo-tet Cyclization of 3,4-Epoxy Amines into 3-Hydroxypyrrolidines Catalyzed by La(OTf)(3)	Nickel-catalyzed cross-coupling of allyl alcohols with aryl- and alkenylzinc chlorides through C-O bond cleavage was performed. Reaction of (E)-3-phenylprop-2-en-1-ol and 1-aryl-prop-2-en-1-ols with aryl- or alkenylzinc chlorides gave linear cross-coupling products. Reaction of 1-phenyl- or 1-methyl-substituted (E)-3-phenylprop-2-en-1-ol with aryl- or alkenylzinc chlorides resulted in 3-aryl/alkenyl-substituted (E)-(prop-1-ene-1,3-diyl)dibenzenes or 3-aryl/alkenyl-substituted (E)-(but-1-enyl)benzene. Reaction of allyl alcohol with p-Me2NC6H4ZnCl resulted in a mixture of normal coupling product 4-allyl-N,N-dimethylaniline and its isomerized product N,N-dimethyl-4-(prop-1-en-1-yl)aniline.	Chem.-Eur. J.	38	Iwabuchi, Y	FALSE	FALSE	FALSE	FALSE
7154	10.1055/s-0040-1707216	doi.org/10.1055/s-0040-1707216	Nickel-Catalyzed Asymmetric Cross-Electrophile Coupling Reactions	A series of pyridine-type ligands containing C C bonds were designed and synthesized for selective oxidative Heck reaction. These ligands were utilized as functional units and integrated into the skeleton of conjugated microporous polymers. 6,6'-diiodo-2,2'-bipyridine and 1,3,5-triethynylbenzene were polycondensed via Sonogashira cross-coupling strategy to afford CMP-1 material. The resultant CMP-1 was used as a heterogeneous catalytic ligand for the Pd-II-catalyzed oxidative Heck reaction with high linear selectivity. The linear selectivity of CMP-1 is about 30 times higher than that of bipyridine-based monomer ligand. This work opens a new front of using CMP as an intriguing platform for developing highly efficient catalysts in controlling the regioselectivity in organic reactions.	Synlett	38	Wang, C	FALSE	TRUE	FALSE	FALSE
7155	10.1039/d0cc05912a	doi.org/10.1039/d0cc05912a	Pyridine mediated transition-metal-free direct alkylation of anilines using alcohols via borrowing hydrogen conditions	The palladium-catalysed aqueous -arylation of ketones was developed and tested for a large variety of reaction partners. These mild conditions enabled the coupling of aryl/alkyl-ketones with N-protected halotryptophans, heterocyclic haloarenes, and challenging base-sensitive compounds. The synthetic potential of this new methodology for the diversification of complex bioactive molecules was exemplified by derivatising prochlorperazine. The methodology is mild, aqueous and flexible, representing a means of functionalizing a wide range of halo-aromatics and therefore has the potential to be extended to complex molecule diversification.	Chem. Commun.	38	Bhat, VT; Namitharan, K	FALSE	FALSE	FALSE	FALSE
7156	10.1021/acs.organomet.0c00060	doi.org/10.1021/acs.organomet.0c00060	Oxidative Addition of Aryl Halides to a Triphosphine Ni(0) Center to Form Pentacoordinate Ni(II) Aryl Species	This review describes methods for the direct catalytic dehydrative substitution of alcohols in the absence of stoichiometric activating agents, excluding methods that involve transfer hydrogenation. Although some earlier literature is discussed, this review mainly covers literature published from 2010 through August 2015.	Organometallics	38	Harvey, JN	FALSE	FALSE	FALSE	FALSE
7157	10.1055/s-0039-1691525	doi.org/10.1055/s-0039-1691525	Construction of C-C Bond via C-N and C-O Cleavage	A palladium-catalyzed one-pot procedure for the synthesis of aryl ketones has, been developed. Triazine esters when coupled with aryl boronic acids provided aryl ketones in moderate to excellent yields (up to 95%) in the presence of 1 mol % Pd(PPh3)(2)Cl-2 for 30 min.	Synlett	38	Shu, XZ	FALSE	FALSE	FALSE	FALSE
7158	10.1021/acs.orglett.0c00983	doi.org/10.1021/acs.orglett.0c00983	Palladium-Catalyzed Mizoroki-Heck Reaction of Nitroarenes and Styrene Derivatives	A novel, highly versatile and efficient method has been developed for the Barbier-Grignard-type arylation of ketones and an unexpected cross-coupling of phenolic ketones was observed using unactivated bromides and magnesium in tetra-hydrofuran/toluene at 96 degrees C promoted by multicatalysts of cupric bromide (15 mol%), bismuth chloride (5 mol%) and silver bromide (10 mol%). The substituent and electronic effects on the reaction have been discussed. High yields of arylation and cross-coupling have been attained under mild conditions. A novel reasonable mechanism involving a quinone intermediate is proposed. The high chemical selectivity in the cross-coupling to the hydroxy group of phenolic ketones should help ketones find new applications.	Org. Lett.	38	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
7159	10.1016/j.tetlet.2020.151660	doi.org/10.1016/j.tetlet.2020.151660	NFSI/KF mediated mild and chemoselective interconversion of aryl TBDMS ethers to their benzene sulfonate	The chemistry of nickel N-heterocyclic carbene species has blossomed at the beginning of this century with a particularly rapid acceleration in the last 5 years, as indicated by the fact that more than 65% of the discussed research articles in this comprehensive review date from the period 2010-2015. The rapid evolution of this chemistry has led to an increasing number of applications in the field of catalytic C-heteroatom bond formation, reduction, and oxidation where the heteroatom is nitrogen, sulfur, oxygen, or boron. Thus, in addition to the development of aryl aminations, aryl thiolations, alkyne hydrothiolations, and transfer hydrogenations, which are the most ancient reactions of this type known for these systems, the last five years have seen the appearance of a number of novel interesting Ni(NHC)-catalyzed transformations such as the dehydrogenative cross coupling of aldehydes and amines or alcohols, the hydroamination of alkenes, the hydroimination of alkynes, a one-step indoline synthesis, (cross-) Tishchenko reactions, the borylation of unsaturated C-C bonds and arenes, the borylative cleavage of C-N bonds, the hydrosilylation of C-O and C-N multiple bonds, the reductive cleavage of aromatic C-O bonds, and the anaerobic oxidation of alcohols. This rapid expansion calls for a review of the state of the art at this time with a special emphasis on mechanistic data to allow new insights into catalyst improvement.	Tetrahedron Lett.	38	Thore, SN	FALSE	FALSE	FALSE	FALSE
7160	10.1002/anie.202001211	doi.org/10.1002/anie.202001211	Synthesis of Polybenzoacenes: Annulative Dimerization of Phenylene Triflate by Twofold C-H Activation	We have developed a stereospecific, nickel-catalyzed cross-coupling of secondary benzylic ammonium salts and diboronate esters to deliver highly enantioenriched benzylic boronates. This reaction utilizes amine-derived electrophiles, which are readily available in high enantiopurity, and simple, inexpensive nickel catalysts. This reaction has broad scope, enabling synthesis of a variety of secondary benzylic boronates in good yields and excellent ee's.	Angew. Chem.-Int. Edit.	38	Murakami, K; Itami, K	FALSE	FALSE	FALSE	FALSE
7161	10.1007/s10904-019-01288-9	doi.org/10.1007/s10904-019-01288-9	Synthesis of Unsymmetrical Bis(phosphine) Oxides and Their Phosphines via Secondary Phosphine Oxide Precursors		J. Inorg. Organomet. Polym. Mater.	38	Tyler, DR	FALSE	FALSE	FALSE	FALSE
7162	10.1007/s11030-019-10001-4	doi.org/10.1007/s11030-019-10001-4	Pd(NHC)(cinnamyl)Cl-catalyzed Suzuki cross-coupling reaction of aryl sulfonates with arylboronic acids		Mol. Divers.	38	Wang, QW	FALSE	FALSE	FALSE	FALSE
7163	10.1021/acs.orglett.9b02797	doi.org/10.1021/acs.orglett.9b02797	Diastereoselective Nickel-Catalyzed Carboiodination Generating Six-Membered Nitrogen-Based Heterocycles		Org. Lett.	38	Lautens, M	FALSE	FALSE	FALSE	FALSE
7164	10.1002/anie.201905174	doi.org/10.1002/anie.201905174	Enantioselective Palladium-Catalyzed Cross-Coupling of alpha-Bromo Carboxamides and Aryl Boronic Acids		Angew. Chem.-Int. Edit.	38	Tang, WJ	FALSE	FALSE	FALSE	FALSE
7165	10.1002/chem.201901406	doi.org/10.1002/chem.201901406	Selective C-C Coupling of Vinyl Epoxides with Diborylmethide Lithium Salts		Chem.-Eur. J.	38	Fernandez, E	FALSE	FALSE	FALSE	FALSE
7166	10.1039/c9ob00561g	doi.org/10.1039/c9ob00561g	Ni vs. Pd in Suzuki-Miyaura sp(2)-sp(2) cross-coupling: a head-to-head study in a comparable precatalyst/ligand system		Org. Biomol. Chem.	38	Watson, AJB	FALSE	FALSE	FALSE	FALSE
7167	10.1021/acs.orglett.9b00394	doi.org/10.1021/acs.orglett.9b00394	Stereospecific Iron-Catalyzed Carbon(sp(2))-Carbon(sp(3)) Cross-Coupling with Alkyllithium and Alkenyl Iodides		Org. Lett.	38	Peng, XS; Wong, HNC	FALSE	FALSE	FALSE	FALSE
7168	10.1002/ejoc.201900267	doi.org/10.1002/ejoc.201900267	Pd-Catalyzed Decarboxylative Asymmetric Protonation (DAP) Using Chiral PHOX Ligands vs. Chiral Ligand-Free Conditions Employing (1R,2S)(-)-Ephedrine - A Comparison Study		Eur. J. Org. Chem.	38	Guiry, PJ	FALSE	FALSE	FALSE	FALSE
7169	10.1038/s41929-019-0250-6	doi.org/10.1038/s41929-019-0250-6	Organosodium compounds for catalytic cross-coupling		Nat. Catal.	38	Asako, S; Takai, K	FALSE	FALSE	FALSE	FALSE
7170	10.1055/s-0037-1611720	doi.org/10.1055/s-0037-1611720	Site-Selective Synthesis of 3,17-Diaryl-1,3,5,16-estratetraenes		Synlett	38	Langer, P	FALSE	FALSE	FALSE	FALSE
7171	10.1016/j.bmcl.2018.12.011	doi.org/10.1016/j.bmcl.2018.12.011	Ganocapenoids A-D: Four new aromatic meroterpenoids from Ganoderma capense		Bioorg. Med. Chem. Lett.	38	Cheng, YX	FALSE	FALSE	FALSE	FALSE
7172	10.1016/j.jorganchem.2018.09.026	doi.org/10.1016/j.jorganchem.2018.09.026	N-heterocyclic carbene palladium(II)-catalyzed Suzuki-Miyaura cross coupling of N-acylsuccinimides by C-N cleavage		J. Organomet. Chem.	38	Wang, T; Liu, LT	FALSE	FALSE	FALSE	FALSE
7173	10.1039/c8cc07200k	doi.org/10.1039/c8cc07200k	Nucleophilic ring opening of trans-2,3-disubstituted epoxides to -amino alcohols with catalyst-controlled regioselectivity		Chem. Commun.	38	Coates, GW	FALSE	FALSE	FALSE	FALSE
7174	10.1016/j.comptc.2018.09.011	doi.org/10.1016/j.comptc.2018.09.011	Iron-catalyzed olefin synthesis by direct coupling of alkenes with alcohols: A DFT investigation		Comput. Theor. Chem.	38	Liu, HL	FALSE	FALSE	FALSE	FALSE
7175	10.1002/anie.201805961	doi.org/10.1002/anie.201805961	Metal-Free Synthesis of Pharmaceutically Important Biaryls by Photosplicing		Angew. Chem.-Int. Edit.	38	Hertweck, C	TRUE	FALSE	FALSE	FALSE
7176	10.1002/adsc.201800468	doi.org/10.1002/adsc.201800468	Cobalt-Catalyzed Formation of Functionalized Diarylmethanes from Benzylmesylates and Aryl Halides		Adv. Synth. Catal.	38	Auffrant, A; Gosmini, C	FALSE	FALSE	FALSE	FALSE
7177	10.1021/jacs.8b06605	doi.org/10.1021/jacs.8b06605	Functional Group Transposition: A Palladium-Catalyzed Metathesis of Ar-X sigma-Bonds and Acid Chloride Synthesis		J. Am. Chem. Soc.	38	Arndtsen, BA	FALSE	FALSE	FALSE	FALSE
7178	10.1021/acscatal.8b02029	doi.org/10.1021/acscatal.8b02029	Palladium-Catalyzed Intermolecular Heck-Type Reaction of Epoxides		ACS Catal.	38	Zhou, JS	FALSE	FALSE	FALSE	FALSE
7179	10.1039/c8cc04127j	doi.org/10.1039/c8cc04127j	Orthogonal reactivity of Ni(i)/Pd(0) dual catalysts for Ullmann C-C cross-coupling: theoretical insight		Chem. Commun.	38	Guan, W; Su, ZM	FALSE	FALSE	FALSE	FALSE
7180	10.1016/j.tetlet.2018.05.032	doi.org/10.1016/j.tetlet.2018.05.032	Palladium catalyzed Heck-arylation/cyclization cascade: An environmentally benign and efficient synthesis of 4-arylcoumarins in water		Tetrahedron Lett.	38	Chen, JM	FALSE	FALSE	FALSE	FALSE
7181	10.1002/anie.201800701	doi.org/10.1002/anie.201800701	Synthesis of Reversed C-Acyl Glycosides through Ni/Photoredox Dual Catalysis		Angew. Chem.-Int. Edit.	38	Molander, GA	TRUE	FALSE	FALSE	FALSE
7182	10.1021/acs.orglett.8b00847	doi.org/10.1021/acs.orglett.8b00847	Direct Silyl-Heck Reaction of Chlorosilanes		Org. Lett.	38	Shimada, S; Nakajima, Y	FALSE	FALSE	FALSE	FALSE
7183	10.1002/ajoc.201800037	doi.org/10.1002/ajoc.201800037	Pd-Catalyzed One-Pot Dehydroxylative Coupling of Phenols and Amines under a Carbon Monoxide Atmosphere: A Chemical-Specific Discrimination for Arylcarboxylic Amide Synthesis		Asian J. Org. Chem.	38	Qin, HL	FALSE	FALSE	FALSE	FALSE
7184	10.1039/c7sc03950f	doi.org/10.1039/c7sc03950f	Amide synthesis via nickel-catalysed reductive aminocarbonylation of aryl halides with nitroarenes		Chem. Sci.	38	Hu, XL	FALSE	FALSE	FALSE	FALSE
7185	10.1016/j.molstruc.2017.07.066	doi.org/10.1016/j.molstruc.2017.07.066	Supramolecular structures of V(III) complexes supported by PNP pincer ligands		J. Mol. Struct.	38	Alves, LG; Martins, AM	FALSE	FALSE	FALSE	FALSE
7186	10.1055/s-0034-1381034	doi.org/10.1055/s-0034-1381034	An Efficient Method for the Synthesis of 2-Methylallyl Alkenes by Cross-Coupling Reactions		Synthesis	38	Tabele, C	FALSE	FALSE	FALSE	FALSE
7187	10.1016/j.tet.2015.08.022	doi.org/10.1016/j.tet.2015.08.022	Nickel-catalyzed cross-coupling of sterically hindered 1-bromomethyl-o-carborane with alkyl and aryl Grignard reagents		Tetrahedron	38	Lu, J	FALSE	FALSE	FALSE	FALSE
7188	10.1016/j.tet.2015.02.011	doi.org/10.1016/j.tet.2015.02.011	Dual reactivity of secondary phosphines and their chalcogenides towards 1-(vinyloxy)alkylferrocenes: the switch between alpha- and beta-addition		Tetrahedron	38	Trofimov, BA	FALSE	FALSE	FALSE	FALSE
7189	10.1021/ol503061c	doi.org/10.1021/ol503061c	Air-Stable Nickel Precatalysts for Fast and Quantitative Cross-Coupling of Aryl Sulfamates with Aryl Neopentylglycolboronates at Room Temperature		Org. Lett.	38	Percec, V	FALSE	FALSE	FALSE	FALSE
7190	10.1021/ie501081q	doi.org/10.1021/ie501081q	Magnetic Silica-Supported Palladium Catalyst: Synthesis of Allyl Aryl Ethers in Water		Ind. Eng. Chem. Res.	38	Varma, RS	FALSE	FALSE	FALSE	FALSE
7191	10.1016/j.jscs.2014.02.002	doi.org/10.1016/j.jscs.2014.02.002	An efficient synthesis of new thiazolidin-4-one fused s-triazines as potential antimicrobial and anticancer agents		J. Saudi Chem. Soc.	38	Kumari, P	FALSE	FALSE	FALSE	FALSE
7192	10.1016/j.cclet.2014.04.019	doi.org/10.1016/j.cclet.2014.04.019	Nickel-catalyzed cross-coupling reaction of alkynyl bromides with Grignard reagents		Chin. Chem. Lett.	38	Li, QH	FALSE	FALSE	FALSE	FALSE
7193	10.1021/ol5019135	doi.org/10.1021/ol5019135	Branch-Selective Allylic C-H Carboxylation of Terminal Alkenes by Pd/sox Catalyst		Org. Lett.	38	Liu, GS	FALSE	FALSE	FALSE	FALSE
7194	10.1002/adsc.201400076	doi.org/10.1002/adsc.201400076	Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates		Adv. Synth. Catal.	38	Yu, ZK	FALSE	FALSE	FALSE	FALSE
7195	10.1021/ja5031744	doi.org/10.1021/ja5031744	Palau'chlor: A Practical and Reactive Chlorinating Reagent		J. Am. Chem. Soc.	38	Baran, PS	FALSE	FALSE	FALSE	FALSE
7196	10.1246/cl.131205	doi.org/10.1246/cl.131205	Theoretical Study on Alkoxydiphosphine Ligand for Bimetallic Cooperation in Nickel-catalyzed Monosubstitution of C-F Bond		Chem. Lett.	38	Ilies, L	FALSE	FALSE	FALSE	FALSE
7197	10.1021/cs500208n	doi.org/10.1021/cs500208n	Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity		ACS Catal.	38	Ke, ZF	FALSE	FALSE	FALSE	FALSE
7198	10.1002/ajoc.201300031	doi.org/10.1002/ajoc.201300031	Aryl[2-(hydroxypro-2-yl)cyclohyxyl]dimethylsilane: A Robust Aryl(trialkyl)silane Reagent for Nickel-catalyzed Cross-coupling Reactions with Aryl Tosylates		Asian J. Org. Chem.	38	Nakao, Y	FALSE	FALSE	FALSE	FALSE
7199	10.1016/j.tet.2012.11.003	doi.org/10.1016/j.tet.2012.11.003	Novel robust benzimidazolylidene palladium complexes: synthesis, structure, and catalytic applications in amination of chloroarenes		Tetrahedron	38	Tu, T	FALSE	FALSE	FALSE	FALSE
7200	10.1021/ol3029059	doi.org/10.1021/ol3029059	Palladium Catalyzed One-Pot Sequential Suzuki Cross-Coupling-Direct C-H Functionalization of Imidazo[1,2-a]pyrazines		Org. Lett.	38	Gembus, V	FALSE	FALSE	FALSE	FALSE
7201	10.1021/ol3028913	doi.org/10.1021/ol3028913	Water Control over the Chemoselectivity of a Ti/Ni Multimetallic System: Heck- or Reductive-Type Cyclization Reactions of Alkyl Iodides		Org. Lett.	38	de Cienfuegos, LA	FALSE	FALSE	FALSE	FALSE
7202	10.1002/ejoc.201200951	doi.org/10.1002/ejoc.201200951	Palladium-Catalyzed Mono-alpha-arylation of Carbonyl-Containing Compounds with Aryl Halides using DalPhos Ligands		Eur. J. Org. Chem.	38	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7203	10.1002/ajoc.201200013	doi.org/10.1002/ajoc.201200013	Indium(III)-Promoted Organocatalytic Enantioselective alpha-Alkylation of Aldehydes with Benzylic and Benzhydrylic Alcohols		Asian J. Org. Chem.	38	Cozzi, PG	FALSE	FALSE	FALSE	FALSE
7204	10.1021/ja304068t	doi.org/10.1021/ja304068t	Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon-Boron Bonds		J. Am. Chem. Soc.	38	Fu, GC	FALSE	TRUE	FALSE	FALSE
7205	10.1021/ja301588z	doi.org/10.1021/ja301588z	Palladium-Catalyzed Cycloaddition of Alkynyl Aryl Ethers with Internal Alkynes via Selective Ortho C-H Activation		J. Am. Chem. Soc.	38	Minami, Y	FALSE	FALSE	FALSE	FALSE
7206	10.1021/ol300364s	doi.org/10.1021/ol300364s	Nickel-Catalyzed Cross-Coupling of Chromene Acetals and Boronic Acids		Org. Lett.	38	Doyle, AG	FALSE	FALSE	FALSE	FALSE
7207	10.1002/anie.201207428	doi.org/10.1002/anie.201207428	Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki-Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides		Angew. Chem.-Int. Edit.	38	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
7208	10.1039/c1cc16582h	doi.org/10.1039/c1cc16582h	Regioselective C-H bond functionalizations of acridines using organozinc reagents		Chem. Commun.	38	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7209	10.1039/c2cc17468e	doi.org/10.1039/c2cc17468e	An expedient Pd/DBU mediated cyanation of aryl/heteroaryl bromides with K-4[Fe(CN)(6)]		Chem. Commun.	38	Liu, H	FALSE	FALSE	FALSE	FALSE
7210	10.1007/s11172-011-0239-z	doi.org/10.1007/s11172-011-0239-z	Electrochemical investigation of complexation of polymer ligands containing 2,2'-biquinolyl fragments with Ni-II ions in solution		Russ. Chem. Bull.	38	Magdesieva, TV	FALSE	TRUE	FALSE	FALSE
7211	10.3762/bjoc.7.95	doi.org/10.3762/bjoc.7.95	Synthesis of novel 5-alkyl/aryl/heteroaryl substituted diethyl 3,4-dihydro-2H-pyrrole-4,4-dicarboxylates by aziridine ring expansion of 2-[(aziridin-1-yl)-1-alkyl/aryl/heteroaryl-methylene]malonic acid diethyl esters		Beilstein J. Org. Chem.	38	More, SS	FALSE	FALSE	FALSE	FALSE
7212	10.1002/chem.201100361	doi.org/10.1002/chem.201100361	Palladium-Catalyzed Borylation of Aryl Mesylates and Tosylates and Their Applications in One-Pot Sequential Suzuki-Miyaura Biaryl Synthesis		Chem.-Eur. J.	38	Kwong, FY	FALSE	FALSE	FALSE	FALSE
7213	10.1055/s-0030-1259728	doi.org/10.1055/s-0030-1259728	Palladium-Catalyzed Monoarylation of Aryl Amine with Aryl Tosylates		Synlett	38	Xie, XM	FALSE	FALSE	FALSE	FALSE
7214	10.1039/c1dt10928f	doi.org/10.1039/c1dt10928f	Nickel complexes of a bis(benzimidazolin-2-ylidene)pyridine pincer ligand with four- and five-coordinate geometries		Dalton Trans.	38	Brown, DH	FALSE	FALSE	FALSE	FALSE
7215	10.1002/anie.201100705	doi.org/10.1002/anie.201100705	Differentiating C-Br and C-Cl Bond Activation by Using Solvent Polarity: Applications to Orthogonal Alkyl-Alkyl Negishi Reactions		Angew. Chem.-Int. Edit.	38	Organ, MG	FALSE	FALSE	FALSE	FALSE
7216	10.1021/jo101027h	doi.org/10.1021/jo101027h	Direct B-Alkyl Suzuki-Miyaura Cross-Coupling of 2-Halopurines. Practical Synthesis of ST1535, a Potent Adenosine A(2A) Receptor Antagonist		J. Org. Chem.	38	Piersanti, G	FALSE	FALSE	FALSE	FALSE
7217	10.1021/ol100001b	doi.org/10.1021/ol100001b	Rh(I)-Catalyzed Decarboxylative Transformations of Arenecarboxylic Acids: Ligand- and Reagent-Controlled Selectivity toward Hydrodecarboxylation or Heck-Mizoroki Products		Org. Lett.	38	Zhao, PJ	FALSE	FALSE	FALSE	FALSE
7218	10.1016/j.tetlet.2009.11.025	doi.org/10.1016/j.tetlet.2009.11.025	Gold-catalyzed C-S bond formation from thiols		Tetrahedron Lett.	38	van de Weghe, P	FALSE	FALSE	FALSE	FALSE
7219	10.1002/chem.200903390	doi.org/10.1002/chem.200903390	Cavity-Shaped Ligands: Calix[4]arene-Based Monophosphanes for Fast Suzuki-Miyaura Cross-Coupling		Chem.-Eur. J.	38	Semeril, D	FALSE	FALSE	FALSE	FALSE
7220	10.1002/chem.200902785	doi.org/10.1002/chem.200902785	Construction of Polysubstituted Olefins through Ni-Catalyzed Direct Activation of Alkenyl C-O of Substituted Alkenyl Acetates		Chem.-Eur. J.	38	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
7221	10.1055/s-0029-1216832	doi.org/10.1055/s-0029-1216832	Kumada Cross-Coupling of Aryl Grignard Reagents with Aryl Halides Catalyzed by an Immobilized Nickel Catalyst		Synthesis	38	Wang, L	FALSE	FALSE	FALSE	FALSE
7222	10.1039/b805648j	doi.org/10.1039/b805648j	Nickel-catalysed Negishi cross-coupling reactions: scope and mechanisms		Chem. Soc. Rev.	38	Phapale, VB	FALSE	FALSE	FALSE	FALSE
7223	10.1021/jo8015852	doi.org/10.1021/jo8015852	Palladium- and Nickel-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Protons with Organozinc Reagents		J. Org. Chem.	38	Knochel, P	FALSE	FALSE	FALSE	FALSE
7224	10.1016/j.molcata.2008.01.001	doi.org/10.1016/j.molcata.2008.01.001	Microwave accelerated Suzuki coupling of chloro-aryl phosphine-oxides: A method for introducing diversity into phosphine ligands		J. Mol. Catal. A-Chem.	38	Clarke, ML	FALSE	FALSE	FALSE	FALSE
7225	10.1002/adsc.200700155	doi.org/10.1002/adsc.200700155	Chiral thiourea-phosphine organocatalysts in the asymmetric Aza-Morita-Baylis-Hillman reaction		Adv. Synth. Catal.	38	Shi, M	FALSE	FALSE	FALSE	FALSE
7226	10.1016/j.tet.2007.03.028	doi.org/10.1016/j.tet.2007.03.028	(p-sulfomethyl)phenylalanine as a mimic of O-sulfatyl-tyrosine in synthetic partial sequences of P-selectin glycoprotein ligand 1 (PSGL-1)		Tetrahedron	38	Kunz, H	FALSE	FALSE	FALSE	FALSE
7227	10.1107/S1600536806003643	doi.org/10.1107/S1600536806003643	Di-mu-bromo-2 kappa Br-2 : 2 'kappa Br-2-bis[bis(mu-acetyl-acetonato-1 kappa O : 2 kappa O ')bromo-2 kappa Br-bis(tetra-hydrofuran-1 kappa O) cadmium(II) nickel(II)]		Acta Crystallogr. Sect. E.-Crystallogr. Commun.	38	Imhof, W	FALSE	FALSE	FALSE	FALSE
7228	10.1055/s-2005-921920	doi.org/10.1055/s-2005-921920	Diethyl chlorophosphate		Synlett	38	Dorn, VB	FALSE	FALSE	FALSE	FALSE
7229	10.1039/b401077a	doi.org/10.1039/b401077a	A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0)		New J. Chem.	38	Beeby, A	FALSE	FALSE	FALSE	FALSE
7230	10.1021/om034046n	doi.org/10.1021/om034046n	Transfer hydrogenation of imines catalyzed by a nickel(0)/NHC complex		Organometallics	38	Schneider, R	FALSE	FALSE	FALSE	FALSE
7231	10.1039/b207002m	doi.org/10.1039/b207002m	Exhaustive hydrodechlorination of chlorinated aromatic environmental pollutants to alicyclic compounds		Green Chem.	38	Avnir, D	FALSE	FALSE	FALSE	FALSE
7232	10.1016/S0040-4039(02)02212-8	doi.org/10.1016/S0040-4039(02)02212-8	Room temperature dehalogenation of chloroarenes by polymethylhydrosiloxane (PMHS) under palladium catalysis		Tetrahedron Lett.	38	Rahaim, RJ	FALSE	FALSE	FALSE	FALSE
7233	10.1016/S0040-4039(02)00718-9	doi.org/10.1016/S0040-4039(02)00718-9	Palladium-catalyzed cross-coupling reactions of 4-tosylcoumarin and arylboronic acids: synthesis of 4-arylcoumarin compounds		Tetrahedron Lett.	38	Fathi, R	FALSE	FALSE	FALSE	FALSE
7234	10.1135/cccc20021223	doi.org/10.1135/cccc20021223	Covalent analogues of DNA base-pairs and triplets IV. Synthesis of trisubstituted benzenes bearing purine and/or pyrimidine rings by cyclotrimerization of 6-ethynylpurines and/or 5-ethynyl-1,3-dimethyluracil		Collect. Czech. Chem. Commun.	38	Hocek, M	FALSE	FALSE	FALSE	FALSE
7235	10.1039/b104340b	doi.org/10.1039/b104340b	Optimisation of the allylsilane approach to C-10 deoxo carba analogues of dihydroartemisinin: synthesis and in vitro antimalarial activity of new, metabolically stable C-10 analogues		J. Chem. Soc.-Perkin Trans. 1	38	O'Neill, PM	FALSE	FALSE	FALSE	FALSE
7236	10.1021/ja003168t	doi.org/10.1021/ja003168t	A ruthenium-catalyzed pyrrolidine and piperidine synthesis		J. Am. Chem. Soc.	38	Trost, BM	FALSE	FALSE	FALSE	FALSE
7237	10.1021/ol000038g	doi.org/10.1021/ol000038g	Modular construction of dendritic carbosilanes. Organization of dendrimer connectivity around bifunctional precursors that are adapted for sequential convergent and divergent propagative steps		Org. Lett.	38	Stobart, SR	FALSE	FALSE	FALSE	FALSE
7238	10.1039/b001333l	doi.org/10.1039/b001333l	Heteroaromatic ethers of phenols in nickel-catalysed ipso-replacement reactions with magnesium, zinc and tin organometallic compounds		J. Chem. Soc.-Perkin Trans. 1	38	Brigas, AF	FALSE	FALSE	FALSE	FALSE
7239	10.1016/S0040-4020(99)00425-1	doi.org/10.1016/S0040-4020(99)00425-1	Synthesis of bicyclic proline analogs using a formal [3+2] intramolecular aziridine-allylsilane cycloaddition reaction		Tetrahedron	38	Bergmeier, SC	FALSE	FALSE	FALSE	FALSE
7240	10.1016/S0040-4039(98)02670-7	doi.org/10.1016/S0040-4039(98)02670-7	Synthesis of carbohelicenes and derivatives by carbenoid couplings		Tetrahedron Lett.	38	Gingras, M	FALSE	FALSE	FALSE	FALSE
7241	10.1016/S0957-4166(98)00136-0	doi.org/10.1016/S0957-4166(98)00136-0	Synthesis and application of novel chiral phosphino-oxazoline ligands with 1,1 '-binaphthyl skeleton		Tetrahedron: Asymmetry	38	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7242	10.1021/jo971636k	doi.org/10.1021/jo971636k	Palladium-catalyzed cross-coupling reactions with aryl nonaflates: A practical alternative to aryl triflates		J. Org. Chem.	38	Knochel, P	FALSE	FALSE	FALSE	FALSE
7243	10.1016/0040-4039(95)00286-3	doi.org/10.1016/0040-4039(95)00286-3	PALLADIUM(II)-MEDIATED OXIDATION OF ALCOHOLS USING 1,2-DICHLOROETHANE AS PD(0) REOXIDANT		Tetrahedron Lett.	38		FALSE	FALSE	FALSE	FALSE
7244	10.1139/v95-057	doi.org/10.1139/v95-057	MULTISUBSTITUTED PHTHALONITRILES, NAPHTHALENEDICARBONITRILES, AND PHENANTHRENETETRACARBONITRILES AS PRECURSORS FOR PHTHALOCYANINE SYNTHESES		Can. J. Chem.-Rev. Can. Chim.	38	LEZNOFF, CC	FALSE	FALSE	FALSE	FALSE
7245	10.1021/jo00002a028	doi.org/10.1021/jo00002a028	TRIPLY CONVERGENT, STEREOSPECIFIC ALKENE FORMATION VIA PETERSON OLEFINATION		J. Org. Chem.	38	BARRETT, AGM	FALSE	FALSE	FALSE	FALSE
7246	10.1246/bcsj.64.1118	doi.org/10.1246/bcsj.64.1118	NUCLEOPHILIC DISPLACEMENT CATALYZED BY TRANSITION-METAL .9. [PD2(DBA)3].CHCL3-DPPF CATALYZED CYANATION OF ARYL HALIDES AND ARYL TRIFLATES		Bull. Chem. Soc. Jpn.	38	TAKAGI, K	FALSE	FALSE	FALSE	FALSE
7247	10.1039/dt9900002407	doi.org/10.1039/dt9900002407	SELECTIVE C-O BOND-CLEAVAGE OF ALLYLIC ESTERS USING [MOH4(PH2PCH2CH2PPH2)2] UNDER LIGHT IRRADIATION TO GIVE HYDRIDOCARboxYLATOMOLYBDENUM(II) COMPLEXES		J. Chem. Soc.-Dalton Trans.	38	ITO, T	FALSE	FALSE	FALSE	FALSE
7248	10.1016/S0040-4039(00)97053-9	doi.org/10.1016/S0040-4039(00)97053-9	STEREOSPECIFIC FUNCTIONALIZATION OF (R)-(-)-1,1'-BI-2-NAPHTHOL TRIFLATE		Tetrahedron Lett.	38		FALSE	FALSE	FALSE	FALSE
7249	10.1021/ja00203a066	doi.org/10.1021/ja00203a066	CHEMOSELECTIVE SYNTHESIS OF ALLYLTRIMETHYLSILANES BY CROSS-COUPLING OF VINYL TRIFLATES WITH TRIS((TRIMETHYLSILY)METHYL)ALUMINUM CATALYZED BY PALLADIUM(0)		J. Am. Chem. Soc.	38	SAULNIER, MG	FALSE	FALSE	FALSE	FALSE
7250	10.1021/jo00378a033	doi.org/10.1021/jo00378a033	NEW ORGANOCUPRATE-INDUCED REDUCTION OF THE ENOL PHOSPHATE MOIETY IN 1-[(DIETHOXYPHOSPHINYL)OXY]-F-1-ALKENE-1-PHOSPHONATES - AN EFFICIENT SYNTHESIS OF (Z)-1-HYDRYL-F-1-ALKENE-1-PHOSPHONATES		J. Org. Chem.	38	ISHIHARA, T	FALSE	FALSE	FALSE	FALSE
7251	10.1039/d2qo00043a	doi.org/10.1039/d2qo00043a	Molecular editing in natural product synthesis		Org. Chem. Front.	38	Xu, CF	FALSE	FALSE	FALSE	FALSE
7252	10.1080/07328303.2021.2015366	doi.org/10.1080/07328303.2021.2015366	Additive-controlled synthesis of 1-and 2-dexoysugars from thioglycosides		J. Carbohydr. Chem.	38	Xiong, DC	FALSE	FALSE	FALSE	FALSE
7253	10.1039/d1ob01765a	doi.org/10.1039/d1ob01765a	Copper-catalyzed synthesis of 1-(2-benzofuryl)-N-heteroarenes from o-hydroxy-gem-(dibromovinyl)benzenes and N-heteroarenes		Org. Biomol. Chem.	38	Rao, MLN	FALSE	FALSE	FALSE	FALSE
7254	10.1002/chem.202102130	doi.org/10.1002/chem.202102130	Facile Conversion of Molecularly Complex (Hetero)aryl Carboxylic Acids into Alkynes for Accelerated SAR Exploration		Chem.-Eur. J.	38	Lutter, FH; Jouffroy, M	FALSE	FALSE	FALSE	FALSE
7255	10.6023/cjoc202104056	doi.org/10.6023/cjoc202104056	Direct Assembly of Polysubstituted Benzenes via Base-Catalyzed Benzannulation Reaction of alpha-Cyano-beta-methylalkenyl-(hetero)aryl Ketones		Chin. J. Org. Chem.	38	Du, GF	FALSE	FALSE	FALSE	FALSE
7256	10.1021/acs.orglett.1c02223	doi.org/10.1021/acs.orglett.1c02223	Nickel-Catalyzed Asymmetric Reductive Dicarbamoylation of Alkenes		Org. Lett.	38	Wang, C	FALSE	FALSE	FALSE	FALSE
7257	10.1021/acs.organomet.1c00369	doi.org/10.1021/acs.organomet.1c00369	Structural and Reactivity Comparisons of JosiPhos CyPF-Cy and a Simplified Variant (CyPBn-Cy) in Nickel-Catalyzed C(sp(2))-N Cross-Couplings		Organometallics	38	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7258	10.1007/s11172-021-3213-4	doi.org/10.1007/s11172-021-3213-4	The influence of the phosphine ligand nature on palladium catalysts in the norbornadiene allylation with allyl formate		Russ. Chem. Bull.	38	Flid, VR	FALSE	FALSE	FALSE	FALSE
7259	10.1039/d1ob00791b	doi.org/10.1039/d1ob00791b	Nickel-catalyzed reductive 1,3-diene formation from the cross-coupling of vinyl bromides		Org. Biomol. Chem.	38	Wu, D	FALSE	FALSE	FALSE	FALSE
7260	10.1021/acs.joc.1c00452	doi.org/10.1021/acs.joc.1c00452	Copper-Catalyzed Lactamization of (E)-2-(2-Bromophenyl)-3-arylacrylamides for the Synthesis of (E)-3-Arylideneindolin-2-ones		J. Org. Chem.	38	Zou, Y	FALSE	FALSE	FALSE	FALSE
7261	10.1039/d0sc06868c	doi.org/10.1039/d0sc06868c	Lewis acid mediated, mild C-H aminoalkylation of azoles via three component coupling		Chem. Sci.	38	Emmert, MH	FALSE	FALSE	FALSE	FALSE
7262	10.1055/s-0036-1588437	doi.org/10.1055/s-0036-1588437	Pd/C-Catalyzed Homocoupling Reaction for the Synthesis of Symmetrical Biaryl Diamides		Synlett	38	Shen, GD; Yang, BC	FALSE	FALSE	FALSE	FALSE
7263	10.1002/anie.201704948	doi.org/10.1002/anie.201704948	Phosphonium Salts as Pseudohalides: Regioselective Nickel-Catalyzed Cross-Coupling of Complex Pyridines and Diazines		Angew. Chem.-Int. Edit.	38	McNally, A	FALSE	FALSE	FALSE	FALSE
7264	10.1016/j.crci.2017.01.006	doi.org/10.1016/j.crci.2017.01.006	Intramolecular vinylation of carbanions using N-acyl benzomorpholines as masked vinylureas and vinylcarbamates		C. R. Chim.	38	Clayden, J	FALSE	FALSE	FALSE	FALSE
7265	10.1055/s-0036-1588328	doi.org/10.1055/s-0036-1588328	Synthesis of -Substituted Diphenylphosphinocarboxylic Acids and Their Palladium Complexes		Synlett	38	Fernandez-Ibanez, A	FALSE	FALSE	FALSE	FALSE
7266	10.1002/anie.201608535	doi.org/10.1002/anie.201608535	Terminal-Selective Functionalization of Alkyl Chains by Regioconvergent Cross-Coupling		Angew. Chem.-Int. Edit.	38	Baudoin, O	FALSE	FALSE	FALSE	FALSE
7267	10.1016/j.tet.2016.08.041	doi.org/10.1016/j.tet.2016.08.041	Synthesis of N,O-acetals by net amide C-N bond insertion of aldehydes into N-acyl phthalimides and N-acyl azoles		Tetrahedron	38	Willoughby, PH	FALSE	FALSE	FALSE	FALSE
7268	10.1007/s00706-016-1673-2	doi.org/10.1007/s00706-016-1673-2	Symmetrical disulfide synthesis via nickel-catalysis using potassium sulfide as sulfur source		Mon. Chem.	38	Soleiman-Beigi, M	FALSE	FALSE	FALSE	FALSE
7269	10.1016/j.tet.2016.07.082	doi.org/10.1016/j.tet.2016.07.082	Oxidative rearrangement strategy for synthesis of 2,4,5-trisubstituted oxazoles utilizing hypervalent iodine reagent		Tetrahedron	38	Zhang, XH; Xiong, Y	FALSE	FALSE	FALSE	FALSE
7270	10.1016/j.tet.2016.03.005	doi.org/10.1016/j.tet.2016.03.005	Synthesis of polyfunctionalized benzophenones via the reaction of 3-formylchromones with tertiary push-pull enamines		Tetrahedron	38	Sosnovskikh, VY	FALSE	FALSE	FALSE	FALSE
7271	10.3987/COM-21-14540	doi.org/10.3987/COM-21-14540	EFFICIENT SYNTHESIS OF CYCLOTRIPHOSPHAZENE TRIPODAL TRIDENTATE LIGAND VIA THE COPPER(I)-TEMPLATE METHOD	The first example of the synthesis of m-alkylphenols via a ruthenium-catalyzed C-Ar-H bond functionalization of phenol derivatives with sec/tert-alkyl bromides is reported. Mechanistic studies indicated that the m-C-Ar-H bond alkylation may involve a radical process and that a six-membered ruthenacycle complex was the active catalyst. Moreover, this approach can provide an expedited strategy for the atom-/step-economical synthesis of many noteworthy pharmaceuticals and other functional molecules.	Heterocycles	37	Kajiyama, K	FALSE	FALSE	FALSE	FALSE
7272	10.1021/acs.organomet.0c00515	doi.org/10.1021/acs.organomet.0c00515	Heteroleptic Ni(II) Complexes Bearing a Bulky Yet Flexible IBiOx-6 Ligand: Improved Selectivity in Cross-Electrophile Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides	A rapid development of a new methodology for decarboxylative N-arylation of carboxylic acids and the preparation of 5-substituted 1H-tetrazoles catalysed by peptide nanofibres decorated with Cu and Ni nanoparticles is presented. Compared with conventional aryl halides, benzoic acids are extremely interesting and environmentally friendly options for the synthesis of secondary aryl amines.	Organometallics	37	Sun, HM	FALSE	TRUE	FALSE	FALSE
7273	10.1021/acs.jafc.0c04131	doi.org/10.1021/acs.jafc.0c04131	Synthesis and Biological Testing of Ester Pheromone Analogues for Two Fruitworm Moths (Carposinidae)	Hydrocarbons are still the most important precursors of functionalized organic molecules, which has stirred interest in the discovery of new C-H bond functionalization methods. We describe herein a new step-economical approach that enables C-C bonds to be constructed at the terminal position of linear alkanes. First, we show that secondary alkyl bromides can undergo in situ conversion into alkyl zinc bromides and regioconvergent Negishi coupling with aryl or alkenyl triflates. The use of a suitable phosphine ligand favoring Pd migration enabled the selective formation of the linear cross-coupling product. Subsequently, mixtures of secondary alkyl bromides were prepared from linear alkanes by standard bromination, and regioconvergent cross-coupling then provided access to the corresponding linear arylation product in only two steps.	J. Agric. Food Chem.	37	Twidle, AM	FALSE	FALSE	FALSE	FALSE
7274	10.1021/acs.orglett.0c02320	doi.org/10.1021/acs.orglett.0c02320	Cu-Catalyzed Direct Amination of Cyclic Amides via C-OH Bond Activation Using DMF	This work investigated the decomposition of anisole (methoxyl-based lignin model compound) in a fluidized bed reactor over no catalysts and a series of HZSM-5 zeolite catalysts with different Si/Al atomic ratios. Transmethylation reaction was identified as the initial step of the thermal decomposition of anisole, leading to the prominent production of phenolic compounds. Methyl phenols were identified as the main products, with the yield of o-cresol being higher than that of p-cresol at the temperatures below 600 degrees C. The transmethylation reaction over HZSM-5 zeolite catalyst was found to occur at temperatures 150 degrees C lower than those for non-catalytic reaction, with the yield of the phenolic compounds being promoted by 2.5 times. Production of the main phenolic compounds during the catalytic decomposition of anisole was enhanced to different extents depending on the Si/Al ratio. The highest selectivity of 79 wt.% was achieved over the zeolite catalyst with a Si/Al ratio of 80. The Bronsted acid sites of the catalyst played a significant role in both the preferential formation of phenolic compounds and preservation of the methyl group. (C) 2016 Elsevier B.V. All rights reserved.	Org. Lett.	37	Lin, J; Jin, Y	FALSE	FALSE	FALSE	FALSE
7275	10.1021/acs.orglett.0c01676	doi.org/10.1021/acs.orglett.0c01676	Fast Amide Couplings in Water: Extraction, Column Chromatography, and Crystallization Not Required	Bulky amido ligands are precious in s-block chemistry, since they can implant complementary strong basic and weak nucleophilic properties within compounds. Recent work has shown the pivotal importance of the base structure with enhancement of basicity and extraordinary regioselectivities possible for cyclic alkali metal magnesiates containing mixed n-butyl/amido ligand sets. This work advances alkali metal and alkali metal magnesiate chemistry of the bulky arylsilyl amido ligand [N(SiMe3)(Dipp)](-) (Dipp= 2,6-iPr(2)-C6H3). Infinite chain structures of the parent sodium and potassium amides are disclosed, adding to the few known crystallographically characterised unsolvated s-block metal amides. Solvation by N, N, N', N '', N ''-pentamethyldiethylenetriamine (PMDETA) or N, N, N', N'-tetramethylethylenediamine (TMEDA) gives molecular variants of the lithium and sodium amides; whereas for potassium, PMDETA gives a molecular structure, TMEDA affords a novel, hemi-solvated infinite chain. Crystal structures of the first magnesiate examples of this amide in [MMg{N(SiMe3)(Dipp)}(2)(mu-nBu)](infinity) (M= Na or K) are also revealed, though these breakdown to their homometallic components in donor solvents as revealed through NMR and DOSY studies.	Org. Lett.	37	Handa, S	FALSE	FALSE	FALSE	FALSE
7276	10.1039/d0ob00880j	doi.org/10.1039/d0ob00880j	Practical direct synthesis of N-aryl-substituted azacycles from N-alkyl protected arylamines using TiCl4 and DBU	The C-H thiolation of aniline derivatives was accomplished with a versatile nickel(II) catalyst under ligand-free conditions. The robust nature of the nickel catalysis system was reflected by the C-H thiolation with a good functional group tolerance and an ample scope, employing anilines possessing removable directing groups. The widely applicable nickel catalyst also allowed for aniline C-H selenylations, while mechanistic studies provided strong support that the rate-determining step is the C-H activation.	Org. Biomol. Chem.	37	Kim, HK	FALSE	FALSE	FALSE	FALSE
7277	10.1002/anie.202006293	doi.org/10.1002/anie.202006293	CuPd Nanoparticles as a Robust Catalyst for Electrochemical Allylic Alkylation	This contribution describes a copper-catalyzed, C(sp(3))-C(sp(3)) cross-coupling reaction of cyclic sulfate esters, a distinct class of electrophilic derivatives of polyols, with alkyl Grignard reagents to afford functionalized alcohol products in good yields. The method is operationally simple and highlights the potential of cyclic sulfate esters as highly reactive substrates in catalytic, chemoselective polyol transformations.	Angew. Chem.-Int. Edit.	37	Yu, C; Williard, P; Sun, SH	FALSE	TRUE	FALSE	FALSE
7278	10.1007/s11172-020-2858-8	doi.org/10.1007/s11172-020-2858-8	Alkyl perchlorates in the Ritter-type reaction. Synthesis ofN-alkylamides	A novel 9,10-dihydro-9,10-ethanoanthracene-11,12-diimine/Pd(OAc)(2) system has been demonstrated to form a highly efficient catalyst for the Suzuki-Miyaura cross-coupling of various aryl bromides and activated aryl chlorides with arylboronic acids in high yields at room temperature in ethanol/aqueous media under ambient atmosphere.	Russ. Chem. Bull.	37	Averina, EB	FALSE	FALSE	FALSE	FALSE
7279	10.1002/chem.202000215	doi.org/10.1002/chem.202000215	Identification of the Active Catalyst for Nickel-Catalyzed Stereospecific Kumada Coupling Reactions of Ethers		Chem.-Eur. J.	37	Borovik, AS; Jarvo, ER	FALSE	FALSE	FALSE	FALSE
7280	10.1039/c9cc08727c	doi.org/10.1039/c9cc08727c	Nickel-catalyzed reductive amidation of aryl-triazine ethers		Chem. Commun.	37	Heravi, MM; Panahi, F	FALSE	FALSE	FALSE	FALSE
7281	10.3390/catal10020230	doi.org/10.3390/catal10020230	Facile Fabrication of Glycosylpyridyl-Triazole@Nickel Nanoparticles as Recyclable Nanocatalyst for Acylation of Amines in Water		Catalysts	37	Jin, JZ; Shen, C	FALSE	FALSE	FALSE	FALSE
7282	10.1021/acs.orglett.9b03899	doi.org/10.1021/acs.orglett.9b03899	Engaging Alkenes and Alkynes in Deaminative Alkyl-Alkyl and Alkyl-Vinyl Cross-Couplings of Alkylpyridinium Salts		Org. Lett.	37	Watson, MP	FALSE	FALSE	FALSE	FALSE
7283	10.1002/ejic.201900972	doi.org/10.1002/ejic.201900972	Bulky 1,1 '-Ferrocenyl Ligands Featuring Diazaphospholene or Dioxaphosphepine Donor Fragments: Catalytic Screening in Nickel-Catalyzed C-N Cross-Coupling		Eur. J. Inorg. Chem.	37	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7284	10.3762/bjoc.15.176	doi.org/10.3762/bjoc.15.176	Vicinal difunctionalization of alkenes by four-component radical cascade reaction of xanthogenates, alkenes, CO, and sulfonyl oxime ethers		Beilstein J. Org. Chem.	37	Ryu, I	FALSE	FALSE	FALSE	FALSE
7285	10.1021/acs.organomet.9b00027	doi.org/10.1021/acs.organomet.9b00027	Mechanistic Studies on the Nickel-Catalyzed Cyclopropanation with Lithiomethyltrimethylammonium Triflate		Organometallics	37	Chen, P	FALSE	FALSE	FALSE	FALSE
7286	10.1016/j.jcat.2019.04.001	doi.org/10.1016/j.jcat.2019.04.001	High-index facets of Pt-Fe nanowires induce steric effect on selective hydrogenation of acetophenone		J. Catal.	37	Zeng, J	FALSE	FALSE	FALSE	FALSE
7287	10.1021/jacs.9b00788	doi.org/10.1021/jacs.9b00788	Enantioselective Divergent Synthesis of C19-Oxo Eburnane Alkaloids via Palladium-Catalyzed Asymmetric Allylic Alkylation of an N-Alkyl-alpha,beta-unsaturated Lactam		J. Am. Chem. Soc.	37	Trost, BM	FALSE	FALSE	FALSE	FALSE
7288	10.1002/chem.201806239	doi.org/10.1002/chem.201806239	Co-I-Catalyzed Barbier Reactions of Aromatic Halides with Aromatic Aldehydes and Imines		Chem.-Eur. J.	37	Presset, M; Le Gall, E	FALSE	FALSE	FALSE	FALSE
7289	10.1002/slct.201803530	doi.org/10.1002/slct.201803530	Lewis-Acid-Catalyzed Direct Nucleophilic Substitution Reaction of Alcohols for the Functionalization of Aromatic Amines		ChemistrySelect	37	Maurya, SK	FALSE	FALSE	FALSE	FALSE
7290	10.1055/s-0037-1611342	doi.org/10.1055/s-0037-1611342	Synthesis of Naphthoic Acids as Potential Anticancer Agents		Synlett	37	Deck, LM	FALSE	FALSE	FALSE	FALSE
7291	10.1021/jacs.8b09909	doi.org/10.1021/jacs.8b09909	Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design		J. Am. Chem. Soc.	37	Morken, JP	FALSE	FALSE	FALSE	FALSE
7292	10.1002/anie.201808024	doi.org/10.1002/anie.201808024	Decarboxylative C(sp(3))-O Cross-Coupling		Angew. Chem.-Int. Edit.	37	Hu, XL	FALSE	FALSE	FALSE	FALSE
7293	10.1038/s41557-018-0078-8	doi.org/10.1038/s41557-018-0078-8	Metathesis-active ligands enable a catalytic functional group metathesis between aroyl chlorides and aryl iodides		Nat. Chem.	37	Morandi, B	FALSE	FALSE	FALSE	FALSE
7294	10.1016/j.tet.2018.04.067	doi.org/10.1016/j.tet.2018.04.067	Bronsted acid-mediated annulations of pyrroles featuring N-tethered alpha,beta-unsaturated ketones and esters: Total syntheses of (+/-)-tashiromine and (+/-)-indolizidine 209I		Tetrahedron	37	Bissember, AC; Smith, JA	FALSE	FALSE	FALSE	FALSE
7295	10.1016/j.tetlet.2018.05.003	doi.org/10.1016/j.tetlet.2018.05.003	Highly efficient synthesis of aryl ketones by PEPPSI-palladium catalyzed acylative Suzuki coupling of amides with diarylborinic acids		Tetrahedron Lett.	37	Zou, G	FALSE	FALSE	FALSE	FALSE
7296	10.1016/j.ica.2017.12.032	doi.org/10.1016/j.ica.2017.12.032	First row metal complexes of the hindered tridentate ligand 2,6-bis-(3 ',5 '-diphenylpyrazolyl)pyridine		Inorg. Chim. Acta	37	Garner, CM	FALSE	FALSE	FALSE	FALSE
7297	10.1002/ejoc.201701478	doi.org/10.1002/ejoc.201701478	Nickel-Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates		Eur. J. Org. Chem.	37	Manolikakes, G	FALSE	FALSE	FALSE	FALSE
7298	10.1007/s11705-017-1669-4	doi.org/10.1007/s11705-017-1669-4	Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions		Front. Chem. Sci. Eng.	37	Zhang, ZG; Ren, QL	FALSE	FALSE	FALSE	FALSE
7299	10.1021/acsomega.7b01450	doi.org/10.1021/acsomega.7b01450	Selective Synthesis of (Benzyl) biphenyls by Successive Suzuki-Miyaura Coupling of Phenylboronic Acids with 4-Bromobenzyl Acetate under Air Atmosphere		ACS Omega	37	Ohsumi, M	FALSE	FALSE	FALSE	FALSE
7300	10.1021/acs.oprd.7b00241	doi.org/10.1021/acs.oprd.7b00241	Optimization of Manganese Coupling Reaction for Kilogram-Scale Preparation of Two Aryl-1,3-dione Building Blocks		Org. Process Res. Dev.	37	Smejkal, T	FALSE	FALSE	FALSE	FALSE
7301	10.1021/acs.orglett.5b03151	doi.org/10.1021/acs.orglett.5b03151	Nickel-Catalyzed Formal Homocoupling of Methoxyarenes for the Synthesis of Symmetrical Biaryls via C-O Bond Cleavage		Org. Lett.	37	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7302	10.1039/c4gc02047b	doi.org/10.1039/c4gc02047b	The copper-nicotinamide complex: sustainable applications in coupling and cycloaddition reactions		Green Chem.	37	Baig, RBN	FALSE	FALSE	FALSE	FALSE
7303	10.1039/c5qo00001g	doi.org/10.1039/c5qo00001g	Metal catalyzed cross-coupling of aryl and benzyl methyl sulfides: nickel catalyzed C-aryl-C-sp3 and C-sp3-C-sp3 bond formations		Org. Chem. Front.	37	Leiendecker, M	FALSE	FALSE	FALSE	FALSE
7304	10.1039/c4cc09321f	doi.org/10.1039/c4cc09321f	Cu-Catalyzed cross-coupling reactions of epoxides with organoboron compounds		Chem. Commun.	37	Fu, Y	FALSE	FALSE	FALSE	FALSE
7305	10.1016/j.tetlet.2014.11.020	doi.org/10.1016/j.tetlet.2014.11.020	Diaminophosphine oxides as preligands for Ni-catalyzed Suzuki cross-coupling reactions of aryl chlorides with arylboronic acids		Tetrahedron Lett.	37	Lei, XY	FALSE	FALSE	FALSE	FALSE
7306	10.1016/j.tetlet.2014.06.114	doi.org/10.1016/j.tetlet.2014.06.114	A green bromination method for the synthesis of benzylic dibromides		Tetrahedron Lett.	37	Levine, M	FALSE	FALSE	FALSE	FALSE
7307	10.1016/j.tetlet.2014.01.148	doi.org/10.1016/j.tetlet.2014.01.148	Regioselective Suzuki-Miyaura cross-coupling reactions of the bis(triflate) of 4,7-dihydroxycoumarin		Tetrahedron Lett.	37	Langer, P	FALSE	FALSE	FALSE	FALSE
7308	10.1055/s-0033-1339114	doi.org/10.1055/s-0033-1339114	Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki-Miyaura Coupling		Synlett	37	Li, PF	FALSE	FALSE	FALSE	FALSE
7309	10.1021/ja504625m	doi.org/10.1021/ja504625m	Redox-Triggered C-C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation		J. Am. Chem. Soc.	37	Krische, MJ	FALSE	FALSE	FALSE	FALSE
7310	10.1021/ja412159g	doi.org/10.1021/ja412159g	Synthesis of Enantiomerically Enriched Triarylmethanes by Enantiospecific Suzuki-Miyaura Cross-Coupling Reactions		J. Am. Chem. Soc.	37	Crudden, CM	FALSE	FALSE	FALSE	FALSE
7311	10.1021/ol5004737	doi.org/10.1021/ol5004737	Type 1 Ring-Opening Reactions of Cyclopropanated 7-Oxabenzonorbornadienes with Organocuprates		Org. Lett.	37	Tam, W	FALSE	FALSE	FALSE	FALSE
7312	10.1055/s-0033-1340665	doi.org/10.1055/s-0033-1340665	Iron-Catalyzed Oxidative Arylmethylation of Activated Alkenes Using a Peroxide as the Methyl Source		Synlett	37	Song, RJ	FALSE	FALSE	FALSE	FALSE
7313	10.1016/j.tet.2013.11.056	doi.org/10.1016/j.tet.2013.11.056	A silver(I)-catalyzed reaction of 2-alkynylbenzaldoxime with arylsulfonyl chloride		Tetrahedron	37	Wu, J	FALSE	FALSE	FALSE	FALSE
7314	10.1039/c3ra46288a	doi.org/10.1039/c3ra46288a	Nickel-catalyzed N-arylation of benzophenone hydrazone with bromoarenes		RSC Adv.	37	Yang, LM	FALSE	FALSE	FALSE	FALSE
7315	10.1039/c4qo00027g	doi.org/10.1039/c4qo00027g	A general method for asymmetric arylation and vinylation of silyl ketene acetals		Org. Chem. Front.	37	Yang, JF	FALSE	FALSE	FALSE	FALSE
7316	10.1002/jhet.1090	doi.org/10.1002/jhet.1090	Suzuki-Miyaura Cross-Coupling Reaction of Naphthyl Triflate with Indole Boronic Acids Catalyzed by a Recyclable Polymer-Supported N-Heterocyclic Carbene-Palladium Complex Catalyst: Synthesis of Naphthalene-Linked Bis-Heterocycles		J. Heterocycl. Chem.	37	Reddy, PA	FALSE	FALSE	FALSE	FALSE
7317	10.1021/jo4005537	doi.org/10.1021/jo4005537	Nickel-Catalyzed Suzuki-Miyaura Coupling of Heteroaryl Ethers with Arylboronic Acids		J. Org. Chem.	37	Jin, Z	FALSE	FALSE	FALSE	FALSE
7318	10.1021/ol400922j	doi.org/10.1021/ol400922j	The Design, Synthesis and Validation of Recoverable and Readily Reusable Siloxane Transfer Agents for Pd-Catalyzed Cross-Coupling Reactions		Org. Lett.	37	Smith, AB	FALSE	FALSE	FALSE	FALSE
7319	10.1016/j.molcata.2012.07.007	doi.org/10.1016/j.molcata.2012.07.007	Cross coupling reactions of multiple C-Cl bonds of polychlorinated solvents with Grignard reagent using a pincer nickel complex		J. Mol. Catal. A-Chem.	37	Ghosh, A	FALSE	FALSE	FALSE	FALSE
7320	10.6023/cjoc201206029	doi.org/10.6023/cjoc201206029	Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction		Chin. J. Org. Chem.	37	Chu, WY	FALSE	FALSE	FALSE	FALSE
7321	10.1016/j.tetlet.2012.01.051	doi.org/10.1016/j.tetlet.2012.01.051	Catalytic C-H arylation of unactivated heteroaromatics with aryl halides by cobalt porphyrin		Tetrahedron Lett.	37	Chan, KS	FALSE	FALSE	FALSE	FALSE
7322	10.1039/c2cc18150a	doi.org/10.1039/c2cc18150a	A facile route to flavone and neoflavone backbones via a regioselective palladium catalyzed oxidative Heck reaction		Chem. Commun.	37	Jafarpour, F	FALSE	FALSE	FALSE	FALSE
7323	10.1039/c2gc35714c	doi.org/10.1039/c2gc35714c	KOH-mediated transition metal-free synthesis of imines from alcohols and amines		Green Chem.	37	Xu, J	FALSE	FALSE	FALSE	FALSE
7324	10.1246/cl.2011.907	doi.org/10.1246/cl.2011.907	Phosphane-free Suzuki-Miyaura Coupling of Aryl Imidazolesulfonates with Arylboronic Acids and Potassium Aryltrifluoroborates under Aqueous Conditions		Chem. Lett.	37	Alonso, DA	FALSE	FALSE	FALSE	FALSE
7325	10.1002/anie.201006411	doi.org/10.1002/anie.201006411	Tetrasubstituted Olefins through the Stereoselective Catalytic Intermolecular Conjugate Addition of Simple Alkenes to alpha,beta-Unsaturated Carbonyl Compounds		Angew. Chem.-Int. Edit.	37	Yi, CS	FALSE	FALSE	FALSE	FALSE
7326	10.1021/ja107703n	doi.org/10.1021/ja107703n	Reductions of Challenging Organic Substrates by a Nickel Complex of a Noninnocent Crown Carbene Ligand		J. Am. Chem. Soc.	37	Spicer, MD	FALSE	FALSE	FALSE	FALSE
7327	10.1016/j.tetlet.2010.02.015	doi.org/10.1016/j.tetlet.2010.02.015	Transition metal-free activation of allylic acetates toward regioselective S-allylation of thiols		Tetrahedron Lett.	37	Ranu, BC	FALSE	FALSE	FALSE	FALSE
7328	10.1002/ejoc.200901080	doi.org/10.1002/ejoc.200901080	Use of the Diels-Alder Cycloaddition of Tetracyclone and Internal Aryl Acetylenes for the Synthesis of Functionalized Atropisomeric Biaryls		Eur. J. Org. Chem.	37	Hapke, M	FALSE	FALSE	FALSE	FALSE
7329	10.1016/j.tetlet.2009.09.046	doi.org/10.1016/j.tetlet.2009.09.046	Expeditious synthesis of 1,1-diarylethylenes related to isocombretastatin A-4 (isoCA-4) via palladium-catalyzed arylation of N-tosylhydrazones with aryl triflates		Tetrahedron Lett.	37	Alami, M	FALSE	FALSE	FALSE	FALSE
7330	10.1016/j.tet.2009.02.040	doi.org/10.1016/j.tet.2009.02.040	Synthesis of 6,7-dihydro-5H-dibenzo[c,e]azepines and biaryls by palladium-catalyzed Ullmann reaction		Tetrahedron	37	Li, JH	FALSE	FALSE	FALSE	FALSE
7331	10.1021/ol062314i	doi.org/10.1021/ol062314i	First synthesis of biquinolizinium salts: Novel example of a chiral azonia dication		Org. Lett.	37	Cuadro, AM	FALSE	FALSE	FALSE	FALSE
7332	10.1016/j.poly.2006.05.035	doi.org/10.1016/j.poly.2006.05.035	Synthesis, characterization, crystal and molecular structure of diphenyloxophosphinoethylenediamines		Polyhedron	37	Akba, O	FALSE	FALSE	FALSE	FALSE
7333	10.1021/jo052283p	doi.org/10.1021/jo052283p	Symmetrical bisquinolones via metal-catalyzed cross-coupling and homocoupling reactions		J. Org. Chem.	37	Kappe, CO	FALSE	FALSE	FALSE	FALSE
7334	10.1016/S0957-4166(02)00094-0	doi.org/10.1016/S0957-4166(02)00094-0	Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst		Tetrahedron: Asymmetry	37	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7335	10.1021/om010608w	doi.org/10.1021/om010608w	Solid state structures and phosphine exchange reactions of (1-Me-indenyl)(PR3)Ni-Cl		Organometallics	37	Zargarian, D	FALSE	FALSE	FALSE	FALSE
7336	10.1021/ja993427i	doi.org/10.1021/ja993427i	Palladium-catalyzed enantioselective alkylative ring opening		J. Am. Chem. Soc.	37	Lautens, M	FALSE	FALSE	FALSE	FALSE
7337	10.1039/b002547j	doi.org/10.1039/b002547j	Nickel(0)-catalysed asymmetric cross-coupling reactions of allylic compounds with Grignard reagents using optically active oxazolinylferrocenylphosphines as ligands		J. Chem. Soc.-Perkin Trans. 1	37	Uemura, S	FALSE	FALSE	FALSE	FALSE
7338	10.1021/ja991704f	doi.org/10.1021/ja991704f	First ruthenium-catalyzed allylation of thiols enables the general synthesis of allylic sulfides		J. Am. Chem. Soc.	37	Mitsudo, T	FALSE	FALSE	FALSE	FALSE
7339	10.1021/jo970439i	doi.org/10.1021/jo970439i	Highly efficient palladium-catalyzed boronic acid coupling reactions in water: Scope and limitations		J. Org. Chem.	37	Badone, D	FALSE	FALSE	FALSE	FALSE
7340	10.1016/S0040-4020(01)88230-2	doi.org/10.1016/S0040-4020(01)88230-2	AN EFFICIENT AND STEREOSELECTIVE SYNTHESIS OF INSECT PHEROMONES BY WAY OF NICKEL-CATALYZED GRIGNARD REACTIONS - SYNTHESES OF GOSSYPLURE AND PHEROMONES OF EUDIA-PAVONIA AND DROSOPHILA-MELANOGASTER		Tetrahedron	37		FALSE	FALSE	FALSE	FALSE
7341	10.1021/ma00032a031	doi.org/10.1021/ma00032a031	SYNTHESIS OF FUNCTIONAL POLY(PARA-PHENYLENE)S FROM SUBSTITUTED HYDROQUINONES VIA NICKEL-CATALYZED COUPLING OF THEIR BISTRIFLATES		Macromolecules	37	PERCEC, V	FALSE	FALSE	FALSE	FALSE
7342	10.1016/0022-328X(91)80189-Q	doi.org/10.1016/0022-328X(91)80189-Q	ENANTIOSELECTIVE CROSS-COUPLING OF VINYL-ELECTROPHILES, ARYL-ELECTROPHILES AND ALLYL-ELECTROPHILES CATALYZED BY NICKEL-COMPLEXES CONTAINING (R,R)-1,2-CYCLOPENTANEDIYLBIS(DIPHENYLPHOSPHINE) AND RELATED LIGANDS		J. Organomet. Chem.	37	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
7343	10.1039/dt9900001645	doi.org/10.1039/dt9900001645	PHOTOREACTION OF [MOH4(PH2PCH2CH2PPH2)2] WITH ALLYL CARBONATES TO GIVE HYDRIDOCARBONATOMOLYBDENUM(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF A 7-CO-ORDINATE MOLYBDENUM(II) COMPLEX [MOH(O2COET)(PH2PCH2CH2-PPH2)2]		J. Chem. Soc.-Dalton Trans.	37	ITO, T	FALSE	FALSE	FALSE	FALSE
7344	10.1021/ja00202a068	doi.org/10.1021/ja00202a068	TOTAL SYNTHESIS OF NATURAL (-)-ECHINOSPORIN - DETERMINATION OF THE ABSOLUTE-CONFIGURATION		J. Am. Chem. Soc.	37	SMITH, AB	FALSE	FALSE	FALSE	FALSE
7345	10.1021/acs.joc.1c02897	doi.org/10.1021/acs.joc.1c02897	Desulfurative Ni-Catalyzed Reductive Cross-Coupling of Benzyl Mercaptans/Mercaptoacetates with Aryl Halides		J. Org. Chem.	37	Liao, HH	FALSE	FALSE	FALSE	FALSE
7346	10.1021/acs.orglett.1c04018	doi.org/10.1021/acs.orglett.1c04018	Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent		Org. Lett.	37	Lei, CH	FALSE	FALSE	FALSE	FALSE
7347	10.1021/acs.orglett.1c03674	doi.org/10.1021/acs.orglett.1c03674	Ni-Catalyzed C(sp(3))-O Arylation of alpha-Hydroxy Esters		Org. Lett.	37	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
7348	10.1039/d1sc04582b	doi.org/10.1039/d1sc04582b	Inhibition of (dppf)nickel-catalysed Suzuki-Miyaura cross-coupling reactions by alpha-halo-N-heterocycles		Chem. Sci.	37	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
7349	10.1039/d1cc02930d	doi.org/10.1039/d1cc02930d	Tertiary cyclopropyl carbagermatranes: synthesis and cross-coupling		Chem. Commun.	37	Xiao, B	FALSE	FALSE	FALSE	FALSE
7350	10.1039/d1cc03332h	doi.org/10.1039/d1cc03332h	Selective construction of fused heterocycles by an iridium-catalyzed reductive three-component annulation reaction		Chem. Commun.	37	Zhang, M	FALSE	FALSE	FALSE	FALSE
7351	10.1021/acs.joc.1c00560	doi.org/10.1021/acs.joc.1c00560	Deconjugative alpha-Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids		J. Org. Chem.	37	Chahboun, R	FALSE	FALSE	FALSE	FALSE
7352	10.1021/acs.orglett.1c00431	doi.org/10.1021/acs.orglett.1c00431	Nickel-Catalyzed Reductive Vinylation of Chloro-hexahydropyrroloindoline Derivatives with Vinyl Triflates		Org. Lett.	37	Ma, GB; Gong, HG	FALSE	FALSE	FALSE	FALSE
7353	10.1002/anie.201705520	doi.org/10.1002/anie.201705520	Zirconium/Nickel-Mediated One-Pot Ketone Synthesis		Angew. Chem.-Int. Edit.	37	Kishi, Y	FALSE	FALSE	FALSE	FALSE
7354	10.3762/bjoc.13.146	doi.org/10.3762/bjoc.13.146	Development of a method for the synthesis of 2,4,5-trisubstituted oxazoles composed of carboxylic acid, amino acid, and boronic acid		Beilstein J. Org. Chem.	37	Kunishima, M	FALSE	FALSE	FALSE	FALSE
7355	10.1038/s41598-017-05895-9	doi.org/10.1038/s41598-017-05895-9	Concise and Stereodivergent Synthesis of Carbasugars Reveals Unexpected Structure-Activity Relationship (SAR) of SGLT2 Inhibition		Sci Rep	37	Shing, TKM	FALSE	FALSE	FALSE	FALSE
7356	10.1126/science.aan1568	doi.org/10.1126/science.aan1568	Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions		Science	37	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
7357	10.1021/acs.joc.6b02701	doi.org/10.1021/acs.joc.6b02701	Nucleophilic ipso-Substitution of Aryl Methyl Ethers through Aryl C-OMe Bond Cleavage; Access to Functionalized Bisthiophenes		J. Org. Chem.	37	Biswas, S	FALSE	FALSE	FALSE	FALSE
7358	10.1016/j.tet.2017.01.030	doi.org/10.1016/j.tet.2017.01.030	Palladium-mediated synthesis of 1,1,2-triarylethanes. Application to the synthesis of CDP-840		Tetrahedron	37	Kuei, CH	FALSE	FALSE	FALSE	FALSE
7359	10.1016/j.tetlet.2016.12.056	doi.org/10.1016/j.tetlet.2016.12.056	Direct allylation of benzyl alcohols, diarylmethanols, and triarylmethanols mediated by XtalFluor-E		Tetrahedron Lett.	37	Paquin, JF	FALSE	FALSE	FALSE	FALSE
7360	10.1039/c6ra25429b	doi.org/10.1039/c6ra25429b	Efficient access to triarylmethanes through decarboxylation		RSC Adv.	37	Panda, G	FALSE	FALSE	FALSE	FALSE
7361	10.1007/s12274-016-1176-9	doi.org/10.1007/s12274-016-1176-9	Highly efficient PdCu3 nanocatalysts for Suzuki-Miyaura reaction		Nano Res.	37	Wang, LY	FALSE	FALSE	FALSE	FALSE
7362	10.1016/j.jorganchem.2016.07.026	doi.org/10.1016/j.jorganchem.2016.07.026	Nickel-catalyzed phosphorylation of aryl triflates with P(O)-H compounds		J. Organomet. Chem.	37	Chen, TQ	FALSE	FALSE	FALSE	FALSE
7363	10.1016/j.tetlet.2016.07.089	doi.org/10.1016/j.tetlet.2016.07.089	Transition-metal-free cross-coupling reaction of benzylic halides with arylboronic acids leading to diarylmethanes		Tetrahedron Lett.	37	Ueda, M	FALSE	FALSE	FALSE	FALSE
7364	10.1021/jacs.6b07172	doi.org/10.1021/jacs.6b07172	Redox-Active Esters in Fe-Catalyzed C-C Coupling		J. Am. Chem. Soc.	37	Baran, PS	FALSE	FALSE	FALSE	FALSE
7365	10.1039/c5gc03012a	doi.org/10.1039/c5gc03012a	A supramolecular ensemble of a PBI derivative and Cu2O NPs: potential photocatalysts for the Suzuki and Suzuki type coupling reactions		Green Chem.	37	Bhalla, V	FALSE	FALSE	FALSE	FALSE
7366	10.1002/chem.201505002	doi.org/10.1002/chem.201505002	Selectivity Effects in Bimetallic Catalysis		Chem.-Eur. J.	37	Mankad, NP	FALSE	FALSE	FALSE	FALSE
7367	10.1246/cl.160057	doi.org/10.1246/cl.160057	Highly Efficient Palladium-catalyzed Suzuki-Miyaura Cross-coupling with 9,10-Dihydro-9,10-ethanoanthracene-11,12-diimine Ligands under Mild Aerobic Conditions		Chem. Lett.	37	Liu, WY; Mei, GQ	FALSE	FALSE	FALSE	FALSE
7368	10.1039/d1cc00047k	doi.org/10.1039/d1cc00047k	A novel construction of acetamides from rhodium-catalyzed aminocarbonylation of DMC with nitro compounds	Novel Buchwald-Hartwig aminations of aryl fluorosulfonates using a catalytic amount of Pd(PPh3)(4) in the presence of Cs2CO3 are described. From these reactions, a variety of biaryl amines were obtained in moderate to good yields. This system allows for the efficient amination of aromatic groups containing electron-rich as well as electron-poor functional groups. Aryl fluorosulfonates could be applied as alternative cross-coupling partners to aryl halides in palladium-catalyzed aminations.	Chem. Commun.	36	Qi, XX	FALSE	FALSE	FALSE	FALSE
7369	10.1039/d0ob01815e	doi.org/10.1039/d0ob01815e	Dealkoxylation ofN-alkoxyamides without an external reductant driven by Pd/Al cooperative catalysis	Chiral Si-, P-, and S-containing organic compounds with central, planar, and axial chiralities have found a plethora of applications in various fields of chemistry. Despite significant efforts to explore new catalytic methodologies and synthetic applications to access such compounds, there are still only a few examples which are low in number and limited in diversity. The catalytic construction of Si-, P-, and S-stereogenic organoheteroatom compounds is undoubtedly one of the most exciting and challenging aspects in asymmetric catalysis and the application of catalytic asymmetric C-H activation reaction for the construction of chiral organoheteroatom compounds is still in its infancy. In this Review, we highlighted the main progress on the corresponding catalytic asymmetric reactions that apply to the construction of Si-, P-, and S-stereogenic centers and related chiral organoheteroatom compounds in a catalytic C-H activation fashion. (C) 2016 Elsevier B.V. All rights reserved.	Org. Biomol. Chem.	36	Matsuda, T	FALSE	FALSE	FALSE	FALSE
7370	10.1021/acs.oprd.0c00134	doi.org/10.1021/acs.oprd.0c00134	Development and Execution of an Ni(II)-Catalyzed Reductive Cross-Coupling of Substituted 2-Chloropyridine and Ethyl 3-Chloropropanoate	Combining high-throughput experimentation with conventional experiments expedited discovery of new first-row nickel catalysts for the dehydrative decarbonylation of the bioderived substrates hydrocinnamic acid and fatty acids to their corresponding alkenes. Conventional experiments using a continuous distillation process (180 degrees C) revealed that catalysts composed of Ni-II or Ni-0 precursors (NiI2, Ni(PPh3)(4)) and simple aryl phosphine ligands were the most active. In the reactions with fatty acids, the nature of the added phosphine influenced the selectivity for a-alkene, which reached a maximum value of 94%. Mechanistic studies of the hydro-cinnamic reaction using Ni(PPh3)(4) as catalyst implicate a facile first turnover to produce styrene at room temperature, but deactivation of the Ni(0) catalyst by CO poisoning occurs subsequently, as evidenced by the formation of Ni(CO)(PPh3)(3), which was isolated and structurally characterized. Styrene dimerization is a major side reaction. Analysis of the reaction mechanism using density functional theory supported catalyst regeneration along with alkene formation as the most energetically demanding reaction steps.	Org. Process Res. Dev.	36	Vaidyanathan, R	FALSE	FALSE	FALSE	FALSE
7371	10.1002/aoc.5741	doi.org/10.1002/aoc.5741	Ligand-Facilitated Reductive Coupling of Benzyl Chlorides with Aryl Chlorides Catalyzed by Well-Defined Heteroleptic Ni (II)-NHC Complexes	A nickel-catalyzed facile synthesis of structurally diverse five-membered lactams from aliphatic amides and terminal acetylenes with the assistance of an 8-aminoquinolyl auxiliary has been achieved. A broad range of terminal acetylenes and aliphatic amides proved to be the efficient coupling partners, furnishing the corresponding lactams in moderate to good yields. The transformation is proven to undergo an oxidative alkynylation followed by the intramolecular annulation process. The methodology can be extended to aromatic amides and acrylamides, which provides an efficient and straightforward protocol for the construction of a variety of isoindolinone and pyrrolidinone derivatives.	Appl. Organomet. Chem.	36	Sun, HM	FALSE	FALSE	FALSE	FALSE
7372	10.1002/aoc.5383	doi.org/10.1002/aoc.5383	Dichloroimidazolidinedione-activated one-pot Suzuki-Miyaura cross-coupling of phenols	A new heterogeneous palladium(II) catalyst has been developed through a convenient and economic way. The catalyst was synthesized by confining palladium metal with a polystyrenal beta-alanine-imine network and characterized by FT-IR spectroscopy, thermogravimetric analysis, field emission scanning electron microscopy, energy dispersive X-ray, and elemental analysis. Polymeric imine can be prepared easily from chloromethylated polystyrene and beta-alanine. Using this polymer incarcerated palladium(II) catalyst a useful and efficient procedure for stereospecific synthesis of allyl-aryl ethers has been developed. The benzylic, aromatic, and heteroaromatic phenols react with various substituted allyl acetates by this procedure to furnish a library of allyl-aryl and allyl-hetero-aryl ethers in high yields. The catalyst could be recovered easily and reused five times without any considerable loss of its catalytic activity.	Appl. Organomet. Chem.	36	Mokhtari, J	FALSE	FALSE	FALSE	FALSE
7373	10.1039/c9cc09377j	doi.org/10.1039/c9cc09377j	Reductive amidation of alkyl tosylates with isocyanates by a Ni/Co-dual catalytic system		Chem. Commun.	36	Komeyama, K	FALSE	FALSE	FALSE	FALSE
7374	10.1002/aoc.5543	doi.org/10.1002/aoc.5543	Synthesis of bioactive magnetic nanoparticles spiro[indoline-3,4 '-[1,3]dithiine]@Ni (NO3)(2) supported on Fe3O4@SiO2@CPS as reusable nanocatalyst for the synthesis of functionalized 3,4-dihydro-2H-pyran		Appl. Organomet. Chem.	36	Ghazanfari, D	FALSE	FALSE	FALSE	FALSE
7375	10.1021/acs.organomet.9b00197	doi.org/10.1021/acs.organomet.9b00197	Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides		Organometallics	36	Fletcher, SP	FALSE	FALSE	FALSE	FALSE
7376	10.1021/jacs.9b07887	doi.org/10.1021/jacs.9b07887	meta C-H Arylation of Electron-Rich Arenes: Reversing the Conventional Site Selectivity		J. Am. Chem. Soc.	36	Yu, JQ	FALSE	TRUE	FALSE	FALSE
7377	10.1021/acs.jchemed.8b00945	doi.org/10.1021/acs.jchemed.8b00945	Syntheses of Four-Coordinate Nickel(II)-Phosphine Compounds and a Rapid Suzuki-Miyaura Cross-Coupling Reaction for Short Laboratory Sessions		J. Chem. Educ.	36	Cooke, J	FALSE	FALSE	FALSE	FALSE
7378	10.1002/adsc.201900221	doi.org/10.1002/adsc.201900221	Four Pathways in Radical Alkylation of Isocyanide with Simple Alcohol		Adv. Synth. Catal.	36	Liu, ZQ	FALSE	FALSE	FALSE	FALSE
7379	10.1016/j.ejmech.2019.02.002	doi.org/10.1016/j.ejmech.2019.02.002	Chemical synthesis, crystal structure, versatile evaluation of their biological activities and molecular simulations of novel pyrithiobac derivatives		Eur. J. Med. Chem.	36	Wang, JG	FALSE	FALSE	FALSE	FALSE
7380	10.1055/s-0037-1612010	doi.org/10.1055/s-0037-1612010	Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst		Synlett	36	Kon, Y	FALSE	FALSE	FALSE	FALSE
7381	10.1039/c8cc08930b	doi.org/10.1039/c8cc08930b	Rhodium(III)-catalyzed aromatic C-H cyanation with dimethylmalononitrile as a cyanating agent		Chem. Commun.	36	Bao, M	FALSE	FALSE	FALSE	FALSE
7382	10.1021/acs.orglett.8b03367	doi.org/10.1021/acs.orglett.8b03367	Nickel-Catalyzed Cross-Electrophile Coupling between Benzyl Alcohols and Aryl Halides Assisted by Titanium Co-reductant		Org. Lett.	36	Suga, T; Ukaji, Y	FALSE	TRUE	FALSE	FALSE
7383	10.3390/molecules23112740	doi.org/10.3390/molecules23112740	Regioselective Synthesis of New 2,4-(Het)aryl-3H-pyrido[1 ',2 ':1,5]pyrazolo[4,3-d]pyrimidines Involving Palladium-Catalyzed Cross-Coupling Reactions		Molecules	36	Routier, S	FALSE	FALSE	FALSE	FALSE
7384	10.1055/s-0037-1611012	doi.org/10.1055/s-0037-1611012	Synthesis of 1,3-Azol-2-yl O-Heterocycles by Microwave-Irradiation-Assisted Direct C-H Functionalization		Synlett	36	Konya, K	FALSE	FALSE	FALSE	FALSE
7385	10.1021/acs.orglett.8b02295	doi.org/10.1021/acs.orglett.8b02295	Borinic Acid-Catalyzed, Regioselective Ring Opening of 3,4-Epoxy Alcohols		Org. Lett.	36	Taylor, MS	FALSE	FALSE	FALSE	FALSE
7386	10.1002/anie.201803760	doi.org/10.1002/anie.201803760	Photochemical Generation of Chiral N,B,X-Heterocycles by Heteroaromatic C-X Bond Scission (X=S, O) and Boron Insertion		Angew. Chem.-Int. Edit.	36	Wang, SN	TRUE	FALSE	FALSE	FALSE
7387	10.1039/c8cc04456b	doi.org/10.1039/c8cc04456b	The influence of NHCs on C-Si and C-C reductive elimination: a computational study of the selectivity of Ni-catalyzed C-H activation of arenes with vinylsilanes		Chem. Commun.	36	Liu, XJ	FALSE	FALSE	FALSE	FALSE
7388	10.1002/anie.201802821	doi.org/10.1002/anie.201802821	Palladium-Catalyzed Asymmetric C(sp(3))-H Allylation of 2-Alkylpyridines		Angew. Chem.-Int. Edit.	36	Sawamura, M	FALSE	FALSE	FALSE	FALSE
7389	10.1021/jacs.8b03669	doi.org/10.1021/jacs.8b03669	Copper-Catalyzed Domino [1,3]/[1,2] Rearrangement for the Efficient Synthesis of Multisubstituted ortho-Anisidines		J. Am. Chem. Soc.	36	Nakamura, I	FALSE	FALSE	FALSE	FALSE
7390	10.1021/jacs.8b01800	doi.org/10.1021/jacs.8b01800	Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C-O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols		J. Am. Chem. Soc.	36	Stradiotto, M	FALSE	TRUE	FALSE	FALSE
7391	10.1002/kin.20966	doi.org/10.1002/kin.20966	Investigation on the Mechanism for C-N Coupling of 3-Iodopyridine and Pyrazole Catalyzed by Cu(I)		Int. J. Chem. Kinet.	36	Li, LC	FALSE	FALSE	FALSE	FALSE
7392	10.1134/S1070428015110019	doi.org/10.1134/S1070428015110019	First example of borirane synthesis by alpha-olefins reaction with BCl3 center dot SMe2 Catalyzed with (eta(5)-C5H5)(2)TiCl2		Russ. J. Organ. Chem.	36	Khusainova, LI	FALSE	FALSE	FALSE	FALSE
7393	10.1002/anie.201504066	doi.org/10.1002/anie.201504066	A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores		Angew. Chem.-Int. Edit.	36	Oestreich, M	FALSE	FALSE	FALSE	FALSE
7394	10.1021/ol502042r	doi.org/10.1021/ol502042r	Efficient Synthesis of ABAB Functionalized Phthalocyanines		Org. Lett.	36	de la Torre, G	FALSE	FALSE	FALSE	FALSE
7395	10.1016/j.ica.2014.02.030	doi.org/10.1016/j.ica.2014.02.030	Arylation of non-activated C-Cl bond with Grignard reagents catalyzed by pincer [PCP]-nickel complexes		Inorg. Chim. Acta	36	Sun, HJ	FALSE	FALSE	FALSE	FALSE
7396	10.1002/ejoc.201301505	doi.org/10.1002/ejoc.201301505	Synthesis of 5-Carbapterocarpens by alpha-Arylation of Tetralones Followed by One-Pot Demethylation/Cyclization with BBr3		Eur. J. Org. Chem.	36	Domingos, JLO	FALSE	FALSE	FALSE	FALSE
7397	10.1039/c4ra08421g	doi.org/10.1039/c4ra08421g	Synthesis of isochromene derivatives using an intramolecular benzylic C(sp(3))-C(sp(2)) bond forming Heck reaction on vinylogous carbonates		RSC Adv.	36	Gharpure, SJ	FALSE	FALSE	FALSE	FALSE
7398	10.1039/c4ra02941k	doi.org/10.1039/c4ra02941k	A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions		RSC Adv.	36	Park, J	FALSE	FALSE	FALSE	FALSE
7399	10.1021/ol4023358	doi.org/10.1021/ol4023358	Pd(0)-Catalyzed 1,1-Diarylation of Ethylene and Allylic Carbonates		Org. Lett.	36	Sigman, MS	FALSE	FALSE	FALSE	FALSE
7400	10.1055/s-0033-1339653	doi.org/10.1055/s-0033-1339653	Amido Pincer Nickel Catalyzed Kumada Cross-Coupling of Aryl, Heteroaryl, and Vinyl Chlorides		Synlett	36	Wang, ZX	FALSE	FALSE	FALSE	FALSE
7401	10.1016/j.tet.2013.07.076	doi.org/10.1016/j.tet.2013.07.076	Lewis acid-promoted cascade reaction of primary amine, 2-butynedioate, and propargylic alcohol: a convenient approach to 1,2-dihydropyridines and 1H-pyrrolo[3,4-b]pyridine-5,7(2H,6H)-diones		Tetrahedron	36	Lu, P	FALSE	FALSE	FALSE	FALSE
7402	10.1002/ejoc.201300610	doi.org/10.1002/ejoc.201300610	Diarylated Ethanones from Mo(CO)(6)-Mediated and Microwave-Assisted Palladium-Catalysed Carbonylative Negishi Cross-Couplings		Eur. J. Org. Chem.	36	Larhed, M	FALSE	FALSE	FALSE	FALSE
7403	10.1055/s-0032-1316904	doi.org/10.1055/s-0032-1316904	Synthesis and Suzuki-Miyaura Reactions of 3,6,8-Tribromoquinoline: A Structural Revision		Synlett	36	Langer, P	FALSE	FALSE	FALSE	FALSE
7404	10.1039/c3cy20826e	doi.org/10.1039/c3cy20826e	Ullmann coupling of aryl iodides catalyzed by gold nanoparticles stabilized on nanocrystalline magnesium oxide		Catal. Sci. Technol.	36	Layek, K	FALSE	FALSE	FALSE	FALSE
7405	10.1039/c3ob26994a	doi.org/10.1039/c3ob26994a	Study of the stereoselectivity of 2-azido-2-deoxyglucosyl donors: protecting group effects		Org. Biomol. Chem.	36	Li, ZT	FALSE	FALSE	FALSE	FALSE
7406	10.1039/c3cc46663a	doi.org/10.1039/c3cc46663a	Suzuki-Miyaura cross-coupling of bulky anthracenyl carboxylates by using pincer nickel N-heterocyclic carbene complexes: an efficient protocol to access fluorescent anthracene derivatives		Chem. Commun.	36	Tu, T	FALSE	FALSE	FALSE	FALSE
7407	10.1021/ja308460z	doi.org/10.1021/ja308460z	Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents		J. Am. Chem. Soc.	36	Fu, GC	FALSE	TRUE	FALSE	FALSE
7408	10.1021/ol301442z	doi.org/10.1021/ol301442z	Carbon-Based Leaving Group in Substitution Reactions: Functionalization of sp(3)-Hybridized Quaternary and Tertiary Benzylic Carbon Centers		Org. Lett.	36	Fillion, E	FALSE	FALSE	FALSE	FALSE
7409	10.1016/j.tetlet.2012.03.108	doi.org/10.1016/j.tetlet.2012.03.108	Chemoselective Suzuki-Miyaura reactions of 4-trifluoromethylsulfonyloxy-6-bromocoumarin		Tetrahedron Lett.	36	Langer, P	FALSE	FALSE	FALSE	FALSE
7410	10.1021/ja303442q	doi.org/10.1021/ja303442q	Catalytic Asymmetric Synthesis of Secondary Nitriles via Stereoconvergent Negishi Arylations and Alkenylations of Racemic alpha-Bromonitriles		J. Am. Chem. Soc.	36	Fu, GC	FALSE	FALSE	FALSE	FALSE
7411	10.1002/adsc.201100217	doi.org/10.1002/adsc.201100217	Molybdenum Carbide-Catalyzed Conversion of Renewable Oils into Diesel-like Hydrocarbons		Adv. Synth. Catal.	36	Lou, H	FALSE	FALSE	FALSE	FALSE
7412	10.1016/j.poly.2011.05.009	doi.org/10.1016/j.poly.2011.05.009	Synthesis and use of trans-dichlorido-tetrakis-(N-R-imidazole)nickel(II) complexes in Kumada-Tamao-Corriu cross-coupling reactions		Polyhedron	36	Semeril, D	FALSE	FALSE	FALSE	FALSE
7413	10.1002/asia.201100153	doi.org/10.1002/asia.201100153	Synthesis of Unsymmetrical Arylheteroarylmethanes by Direct On Water Cross-Coupling between Benzylic and Heteroaromatic Halides		Chem.-Asian J.	36	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
7414	10.1039/c1cc11193k	doi.org/10.1039/c1cc11193k	Arylation of alpha-pivaloxyl ketones with arylboronic reagents via Ni-catalyzed sp(3) C-O activation		Chem. Commun.	36	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
7415	10.1002/anie.201007325	doi.org/10.1002/anie.201007325	Nickel-Catalyzed Amination of Aryl Sulfamates		Angew. Chem.-Int. Edit.	36	Garg, NK	FALSE	FALSE	FALSE	FALSE
7416	10.1039/c0cc05169a	doi.org/10.1039/c0cc05169a	Nickel-catalyzed reductive cleavage of aryl-oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent		Chem. Commun.	36	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7417	10.3906/kim-0906-69	doi.org/10.3906/kim-0906-69	Picolyl substituted N-heterocyclic carbene/palladium catalyzed Heck reactions		Turk. J. Chem.	36	Yigit, M	FALSE	FALSE	FALSE	FALSE
7418	10.1021/ol900362d	doi.org/10.1021/ol900362d	Arylation and Vinylation of alpha-Diazocarbonyl Compounds with Boroxines		Org. Lett.	36	Wang, JB	FALSE	FALSE	FALSE	FALSE
7419	10.1021/ol802865c	doi.org/10.1021/ol802865c	Preparation of Unsymmetrical Biaryls by Pd(II)-Catalyzed Cross-Coupling of Aryl Iodides		Org. Lett.	36	Lu, WJ	FALSE	FALSE	FALSE	FALSE
7420	10.1039/b907722g	doi.org/10.1039/b907722g	Dynamic kinetic asymmetric transformation in copper catalyzed allylic alkylation		Chem. Commun.	36	Alexakis, A	FALSE	FALSE	FALSE	FALSE
7421	10.1351/pac200880050861	doi.org/10.1351/pac200880050861	Ruthenium catalysts for selective nucleophilic allylic substitution		Pure Appl. Chem.	36	Bruneau, C	FALSE	FALSE	FALSE	FALSE
7422	10.1016/j.tetlet.2008.01.101	doi.org/10.1016/j.tetlet.2008.01.101	Synthesis of hindered biphenyls by sequential non-transition metal-catalyzed reaction/palladium-catalyzed cross-couplings		Tetrahedron Lett.	36	Hu, QS	FALSE	FALSE	FALSE	FALSE
7423	10.1021/ol0527936	doi.org/10.1021/ol0527936	Pallladium-catalyzed multistep reactions involving ring closure of 2-iodophenoxyallenes and ring opening of bicyclic alkenes		Org. Lett.	36	Parthasarathy, K	FALSE	FALSE	FALSE	FALSE
7424	10.1039/b513887f	doi.org/10.1039/b513887f	Highly enantioselective Cu-catalysed allylic substitutions with Grignard reagents		Chem. Commun.	36	Feringa, BL	FALSE	FALSE	FALSE	FALSE
7425	10.1021/om0492395	doi.org/10.1021/om0492395	Catalytic Suzuki coupling reactions by amido phosphine complexes of palladium		Organometallics	36	Liang, LC	FALSE	FALSE	FALSE	FALSE
7426	10.1021/ol047670k	doi.org/10.1021/ol047670k	Hydrogenation and dehalogenation under aqueous conditions with an amphiphilic-polymer-supported nanopalladium catalyst		Org. Lett.	36	Nakao, R	FALSE	FALSE	FALSE	FALSE
7427	10.1055/s-2004-831317	doi.org/10.1055/s-2004-831317	Synthesis of 3-methoxyolivacine and olivacine by Friedel-Crafts reaction of indole-2,3-dicarboxylic anhydride with 2,4,6-trimethoxypyridine		Synlett	36	Miki, Y	FALSE	FALSE	FALSE	FALSE
7428	10.1016/S0040-4039(03)00873-6	doi.org/10.1016/S0040-4039(03)00873-6	A convenient approach to cyclic enol phosphates via ring-closing metathesis		Tetrahedron Lett.	36	Hanson, PR	FALSE	FALSE	FALSE	FALSE
7429	10.1021/ol0343562	doi.org/10.1021/ol0343562	High enantioselectivity in rhodium-catalyzed allylic alkylation of 1-substituted 2-propenyl acetates		Org. Lett.	36	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7430	10.1021/ol034141s	doi.org/10.1021/ol034141s	Facile asymmetric synthesis of the core nuclei of xanthanolides, guaianolides, and eudesmanolides		Org. Lett.	36	Reiser, O	FALSE	FALSE	FALSE	FALSE
7431	10.1021/ja0295568	doi.org/10.1021/ja0295568	A new cine-substitution of alkenyl Sulfones with aryltitanium reagents catalyzed by rhodium: Mechanistic studies and catalytic asymmetric synthesis of allylarenes		J. Am. Chem. Soc.	36	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7432	10.1021/ol005694v	doi.org/10.1021/ol005694v	First chelated chiral N-Heterocyclic bis-carbene complexes		Org. Lett.	36	RajanBabu, TV	FALSE	FALSE	FALSE	FALSE
7433	10.1021/jo982438b	doi.org/10.1021/jo982438b	Cross-coupling of aryl halides and allyl acetates with arylboron reagents in water using an amphiphilic resin-supported palladium catalyst		J. Org. Chem.	36	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
7434	10.1023/A:1019075719151	doi.org/10.1023/A:1019075719151	Catalytic asymmetric hydrosilylation of olefins - catalytic asymmetric synthesis of alcohols with high enantiomeric purity		Catal. Surv. Jpn.	36	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7435	10.1021/jo960677y	doi.org/10.1021/jo960677y	Nitrogen assistance in intramolecular nickel-promoted tandem cyclization-quenching processes		J. Org. Chem.	36		FALSE	FALSE	FALSE	FALSE
7436	10.1016/0022-328X(89)87301-2	doi.org/10.1016/0022-328X(89)87301-2	REACTIVE INTERMEDIATES IN ASYMMETRIC CROSS-COUPLING CATALYZED BY PALLADIUM P-N CHELATES		J. Organomet. Chem.	36	BAKER, KV	FALSE	FALSE	FALSE	FALSE
7437	10.1080/07328308908048004	doi.org/10.1080/07328308908048004	GLYCOSYL IMIDATES .36. SYNTHESIS OF A (4E, 8Z)-SPHINGADIENINE MOIETY CONTAINING CEREBROSIDE FROM TETRAGONIA-TETRAGONOIDES WITH ANTIULCEROGENIC ACTIVITY		J. Carbohydr. Chem.	36		FALSE	FALSE	FALSE	FALSE
7438	10.1021/jo00241a017	doi.org/10.1021/jo00241a017	ULTRASOUND IN ORGANIC-SYNTHESIS .13. SOME FUNDAMENTAL-ASPECTS OF THE SONOCHEMICAL BARBIER REACTION		J. Org. Chem.	36		FALSE	FALSE	FALSE	FALSE
7439	10.1021/om00153a013	doi.org/10.1021/om00153a013	PREPARATION AND CRYSTAL-STRUCTURES OF (1,1'-RUTHENOCENEDITHIOLATO-S,S',RU)(TRIPHENYLPHOSPHINE)-NICKEL(II) AND (1,1'-METALLOCENEDIOXALATO-O,O',FE(OR RU))(TRIPHENYLPHOSPHINE)PALLADIUM(II) - THE METAL (FE OR RU)-METAL (PD OR NI) DATIVE BOND		Organometallics	36	AKABORI, S	FALSE	FALSE	FALSE	FALSE
7440	10.1021/jo00207a043	doi.org/10.1021/jo00207a043	SYNTHESIS OF ALLENES BY NICKEL-CATALYZED GRIGNARD REACTIONS WITH SILYLPROPARGYL ALCOHOLS		J. Org. Chem.	36	WENKERT, E	FALSE	FALSE	FALSE	FALSE
7441	10.1021/jo00347a049	doi.org/10.1021/jo00347a049	REGIOSPECIFIC SYNTHESIS OF ARYLFURANS EMPLOYING A NICKEL(II)-PHOSPHINE COMPLEX AS A CATALYST IN THE HOMOLYTIC CROSS-COUPLING OF GRIGNARD-REAGENTS TO HALOFURANS		J. Org. Chem.	36	PRIDGEN, LN	FALSE	FALSE	FALSE	FALSE
7442	10.1039/d2dt00511e	doi.org/10.1039/d2dt00511e	Synthesis, structure, and electrochemical properties of [LNi(R-f)(C4F8)](-) and [LNi(R-f)(3)](-) complexes		Dalton Trans.	36	Vicic, DA	FALSE	FALSE	FALSE	FALSE
7443	10.1016/j.tetlet.2021.153570	doi.org/10.1016/j.tetlet.2021.153570	Visible light-mediated, high-efficiency oxidation of benzyl to acetophenone catalyzed by fluorescein		Tetrahedron Lett.	36	Zhu, Q	FALSE	FALSE	FALSE	FALSE
7444	10.1039/d1cc05691c	doi.org/10.1039/d1cc05691c	Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts		Chem. Commun.	36	Wolf, R	TRUE	FALSE	FALSE	FALSE
7445	10.1021/acs.orglett.1c03455	doi.org/10.1021/acs.orglett.1c03455	Chiral Iridium Complexes of Anionic NCP Pincer Ligand for Asymmetric Transfer Hydrogenation of 1,1-Diarylethenes with Ethanol		Org. Lett.	36	Liu, GX; Huang, Z	FALSE	FALSE	FALSE	FALSE
7446	10.1016/j.tetlet.2021.153388	doi.org/10.1016/j.tetlet.2021.153388	An efficient one-pot synthesis of 2-aminobenzothiazoles from substituted anilines using benzyltrimethylammonium dichloroiodate and ammonium thiocyanate in DMSO:H2O		Tetrahedron Lett.	36	Peterson, MA	FALSE	FALSE	FALSE	FALSE
7447	10.1038/s41586-021-03920-6	doi.org/10.1038/s41586-021-03920-6	Metallaphotoredox-enabled deoxygenative arylation of alcohols		Nature	36	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
7448	10.1021/acs.inorgchem.1c01038	doi.org/10.1021/acs.inorgchem.1c01038	Alkyl Radical-Free Cu(I) Photocatalytic Cross-Coupling: A Theoretical Study of Anomerically Specific Photocatalyzed Glycosylation of Pyranosyl Bromide		Inorg. Chem.	36	Nguyen, HM; Schlegel, HB	TRUE	FALSE	FALSE	FALSE
7449	10.1039/d1qo00925g	doi.org/10.1039/d1qo00925g	The conversion of ether bonds to hydroxyl via a base-promoted rearrangement of cyclic phosphine oxides		Org. Chem. Front.	36	Zheng, HX; Zhao, CQ	FALSE	FALSE	FALSE	FALSE
7450	10.1002/zaac.202100151	doi.org/10.1002/zaac.202100151	Facial vs. Meridional Coordination Modes in Re-I Tricarbonyl Complexes with a Carbodiphosphorane-based Tridentate Ligand		Z. Anorg. Allg. Chem.	36	Vogt, M; Langer, R	FALSE	FALSE	FALSE	FALSE
7451	10.1055/a-1524-4912	doi.org/10.1055/a-1524-4912	NiCl2 as a Cheap and Efficient Precatalyst for the Coupling of Aryl Fluorosulfonate and Phosphite/Phosphine Oxide		Synlett	36	Gu, SM; Cai, H	FALSE	FALSE	FALSE	FALSE
7452	10.1021/acs.orglett.1c01309	doi.org/10.1021/acs.orglett.1c01309	Dehydrative Allylation of Alkenyl sp(2) C-H Bonds		Org. Lett.	36	Xie, PZ	FALSE	FALSE	FALSE	FALSE
7453	10.1039/d1qo00656h	doi.org/10.1039/d1qo00656h	Nickel-catalyzed Suzuki-Miyaura cross-coupling of C-F bonds		Org. Chem. Front.	36	Chatani, N	FALSE	FALSE	FALSE	FALSE
7454	10.3390/catal11050526	doi.org/10.3390/catal11050526	Mechanochemical Synthesis of Nickel-Modified Metal-Organic Frameworks for Reduction Reactions		Catalysts	36	Luque, R; Rodriguez-Padron, D	FALSE	FALSE	FALSE	FALSE
7455	10.1021/acs.organomet.1c00033	doi.org/10.1021/acs.organomet.1c00033	Suzuki-Miyaura Csp(2)-Csp(2) Cross-Couplings Employing Nickel(II) Pincer Precatalysts: Mechanistic Investigations		Organometallics	36	Bissember, AC	FALSE	FALSE	FALSE	FALSE
7456	10.1039/c7cc06106d	doi.org/10.1039/c7cc06106d	Nickel-catalyzed methylation of aryl halides/tosylates with methyl tosylate		Chem. Commun.	36	Gong, HG	FALSE	FALSE	FALSE	FALSE
7457	10.1021/jacs.7b03159	doi.org/10.1021/jacs.7b03159	The Suzuki-Miyaura Coupling of Nitroarenes		J. Am. Chem. Soc.	36	Nakao, Y	FALSE	FALSE	FALSE	FALSE
7458	10.1021/acs.organomet.7b00373	doi.org/10.1021/acs.organomet.7b00373	Exploring the Influence of Phosphine Ligation on the Gold-Catalyzed Hydrohydrazination of Terminal Alkynes at Room Temperature		Organometallics	36	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7459	10.1016/j.cclet.2016.11.002	doi.org/10.1016/j.cclet.2016.11.002	Nickel-catalyzed C-N crossing coupling reaction: The synthetic method for N-aryl substituted indenoindole		Chin. Chem. Lett.	36	Li, XL; Xin, SX	FALSE	FALSE	FALSE	FALSE
7460	10.1002/chem.201605712	doi.org/10.1002/chem.201605712	C-3-Symmetric Boron Lewis Acid with a Cage-Shape for Chiral Molecular Recognition and Asymmetric Catalysis		Chem.-Eur. J.	36	Yasuda, M	FALSE	FALSE	FALSE	FALSE
7461	10.1021/jacs.6b09482	doi.org/10.1021/jacs.6b09482	Hydroxy-Directed Amidation of Carboxylic Acid Esters Using a Tantalum Alkoxide Catalyst		J. Am. Chem. Soc.	36	Tsuji, H; Yamamoto, H	FALSE	FALSE	FALSE	FALSE
7462	10.1055/s-0035-1562484	doi.org/10.1055/s-0035-1562484	Efficient Microwave-Assisted Synthesis of Methyl 4-or 5-Nitro-anthranilate		Synthesis	36	Besson, T	FALSE	FALSE	FALSE	FALSE
7463	10.1021/acscatal.6b00841	doi.org/10.1021/acscatal.6b00841	Remote Functionalization: Palladium-Catalyzed C5(sp(3))-H Arylation of 1-Boc-3-aminopiperidine through the Use of a Bidentate Directing Group		ACS Catal.	36	Maes, BUW	FALSE	FALSE	FALSE	FALSE
7464	10.1002/anie.201601206	doi.org/10.1002/anie.201601206	Intra- and Intermolecular Nickel-Catalyzed Reductive Cross-Electrophile Coupling Reactions of Benzylic Esters with Aryl Halides		Angew. Chem.-Int. Edit.	36	Jarvo, ER	FALSE	TRUE	FALSE	FALSE
7465	10.1002/slct.201600207	doi.org/10.1002/slct.201600207	Highly Efficient and Monodisperse Graphene Oxide Furnished Ru/Pd Nanoparticles for the Dehalogenation of Aryl Halides via Ammonia Borane		ChemistrySelect	36	Sen, F	FALSE	FALSE	FALSE	FALSE
7466	10.3762/bjoc.12.65	doi.org/10.3762/bjoc.12.65	Iridium/N-heterocyclic carbene-catalyzed C-H borylation of arenes by diisopropylaminoborane		Beilstein J. Org. Chem.	36	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7467	10.1039/c6qo00336b	doi.org/10.1039/c6qo00336b	A tetrasulfate-resorcin[6]arene cavitand as the host for organic ammonium guests		Org. Chem. Front.	36	Gaeta, C	FALSE	FALSE	FALSE	FALSE
7468	10.1055/s-0040-1707900	doi.org/10.1055/s-0040-1707900	Asymmetric Reductive Dicarbofunctionalization of Alkenes via Nickel Catalysis	A catalytic hydroamidation of alkynes with isocyanates using alkyl bromides as hydride sources has been developed. The method turns parasitic beta-hydride elimination into a strategic advantage, rapidly affording acrylamides with excellent chemo- and regioselectivity.	Synlett	35	Diao, TN	FALSE	FALSE	FALSE	FALSE
7469	10.1002/bkcs.12044	doi.org/10.1002/bkcs.12044	Transient Directing Group-Assisted C-H Bond Functionalization of Aliphatic Amines: Strategies for Efficiency and Site-Selectivity	Controlled synthesis of conjugated polymers with functional side chains is of great importance, affording well-defined optoelectronic materials possessing enhanced stability and tunability as compared to their alkyl-substituted counterparts. Herein, a chain-growth Suzuki polycondensation of an ester-functionalized thiophene is described using commercially available nickel precatalysts. Model compound studies were used to identify suitable catalysts, and these experiments provided guidance for the polymerization of the ester-substituted monomer. This is the first report of nickel-catalyzed Suzuki cross-coupling for catalyst-transfer polycondensation, and to further illustrate the versatility of this method, block and alternating copolymers with 3-hexylthiophene were synthesized. The presented protocol should serve as an entry point into the synthesis of other electron-deficient polymers and donor-acceptor copolymers with controlled molecular weights and low dispersity.	Bull. Korean Chem. Soc.	35	Kim, M	FALSE	FALSE	FALSE	FALSE
7470	10.1002/ejoc.202000413	doi.org/10.1002/ejoc.202000413	Rational Optimization of Lewis-Acid Catalysts for Direct Alcohol Amination, Part 2-Titanium Triflimide as New Active Catalyst	Being an active class of electrophiles, the desulfitative cross-couplings of sulfonyl chlorides has emerged as a hot issue nowadays. Under suitable temperature and transitional metal catalysis, sulfonyl chlorides efficiently cross-coupled with a wide range of nucleophiles which were potential in several important organic synthesis. The transitional metal catalyzed desulfitative coupling reactions of sulfonyl chlorides are briefly reviewed and are compared with their corresponding sulfonylation reaction in order to find the key factors that determine desulfonation and further providing reliable proposal for future researches.	Eur. J. Org. Chem.	35	Payard, PA; Pera-Titus, M	FALSE	FALSE	FALSE	FALSE
7471	10.1055/s-0039-1690717	doi.org/10.1055/s-0039-1690717	A Simplified Protocol for the Stereospecific Nickel-Catalyzed C-S Vinylation Using NiX2 Salts and Alkyl Phosphites		Synthesis	35	Lautens, M	FALSE	FALSE	FALSE	FALSE
7472	10.1039/c9fd00041k	doi.org/10.1039/c9fd00041k	Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes		Faraday Discuss.	35	Kennepohl, P	FALSE	FALSE	FALSE	FALSE
7473	10.1246/cl.190488	doi.org/10.1246/cl.190488	Alkylation of the Methyl Group of 2-Methylquinolines and Similar Methyl-N-Heteroaromatics with a Ru/In Dual Catalyst		Chem. Lett.	35	Oe, Y	FALSE	FALSE	FALSE	FALSE
7474	10.1002/cctc.201901319	doi.org/10.1002/cctc.201901319	Bidentate Ru(II)-NC Complexes as Catalysts for alpha-Alkylation of Unactivated Amides and Esters		ChemCatChem	35	Chen, DF	FALSE	FALSE	FALSE	FALSE
7475	10.1039/c9qo00562e	doi.org/10.1039/c9qo00562e	Synthesis of rigidified shikimic acid derivatives by ring-closing metathesis to imprint inhibitor efficacy against shikimate kinase enzyme		Org. Chem. Front.	35	Gonzalez-Bello, C	FALSE	FALSE	FALSE	FALSE
7476	10.1002/anie.201903791	doi.org/10.1002/anie.201903791	Unprecedented Regioregular Poly(1,4-arylene)s Prepared by Nickel(II)-Catalyzed Cross-Coupling Polymerization of 2,5-Disubstituted Bromo(chloro)arylene		Angew. Chem.-Int. Edit.	35	Mori, A	FALSE	FALSE	FALSE	FALSE
7477	10.1016/j.tetlet.2019.04.042	doi.org/10.1016/j.tetlet.2019.04.042	Ag2CO3-mediated direct functionalization of alkyl nitriles: Facile synthesis of gamma-ketonitriles through nitrile alkylation of enol acetates		Tetrahedron Lett.	35	Cheng, P	FALSE	FALSE	FALSE	FALSE
7478	10.1016/j.catcom.2018.08.023	doi.org/10.1016/j.catcom.2018.08.023	Oxygen-promoted Suzuki-Miyaura reaction of aryl fluorosulfates and potassium aryltrifluoroborates: Mild and efficient access to biaryls and terphenyls		Catal. Commun.	35	Li, XM; Yuan, ZL	FALSE	FALSE	FALSE	FALSE
7479	10.1021/acs.organomet.8b00350	doi.org/10.1021/acs.organomet.8b00350	Synthesis and Reactivity of Reduced alpha-Diimine Nickel Complexes Relevant to Acrylic Acid Synthesis		Organometallics	35	Chirik, PJ	FALSE	FALSE	FALSE	FALSE
7480	10.1021/acs.organomet.8b00199	doi.org/10.1021/acs.organomet.8b00199	How To Perform Suzuki-Miyaura Reactions of Nitroarene or Nitrations of Bromoarene Using a Pd-0 Phosphine Complex: Theoretical Insight and Prediction		Organometallics	35	Sakaki, S	FALSE	FALSE	FALSE	FALSE
7481	10.1002/adsc.201800100	doi.org/10.1002/adsc.201800100	Palladium-Catalyzed Decarboxylative Cross-Couplings of 1-Boc-3-iodoazetidine: Regioselective Access to 2-Alkynylazetidines, 3-Alkynylazetidines and 3-Vinylazetidines		Adv. Synth. Catal.	35	Zou, DP; Wu, YJ; Wu, YS	FALSE	FALSE	FALSE	FALSE
7482	10.1021/acs.organomet.8b00074	doi.org/10.1021/acs.organomet.8b00074	Disproportionation Reactions of an Organometallic Ni(I) Amidate Complex: Scope and Mechanistic Investigations		Organometallics	35	Love, JA; Schafer, LL	FALSE	FALSE	FALSE	FALSE
7483	10.7503/cjcu20170652	doi.org/10.7503/cjcu20170652	Theoretical Study on the Formation Mechanism of Catalytic Active Components in Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by Transition Metal Cobalt Complex		Chem. J. Chin. Univ.-Chin.	35	Lei, M	FALSE	FALSE	FALSE	FALSE
7484	10.1021/acs.orglett.7b03950	doi.org/10.1021/acs.orglett.7b03950	Introduction of a Crystalline, Shelf-Stable Reagent for the Synthesis of Sulfur(VI) Fluorides		Org. Lett.	35	Ende, CWA	FALSE	FALSE	FALSE	FALSE
7485	10.1055/s-0036-1591888	doi.org/10.1055/s-0036-1591888	Development of a Ratiometric Fluorescent Probe with Two Reactive Sulfoxides for Monitoring the Activity of Methionine Sulfoxide Reductase A		Synthesis	35	Misek, J	FALSE	FALSE	FALSE	FALSE
7486	10.1002/anie.201708748	doi.org/10.1002/anie.201708748	MoB/g-C3N4 Interface Materials as a Schottky Catalyst to Boost Hydrogen Evolution		Angew. Chem.-Int. Edit.	35	Mai, LQ	FALSE	FALSE	FALSE	FALSE
7487	10.1021/acscatal.7b02859	doi.org/10.1021/acscatal.7b02859	Nickel-Catalyzed Reductive Transamidation of Secondary Amides with Nitroarenes		ACS Catal.	35	Hu, XL	FALSE	FALSE	FALSE	FALSE
7488	10.1055/s-0034-1381035	doi.org/10.1055/s-0034-1381035	Catalyst-Free One-Pot Access to 3-Pyrazolylisoindolinone Derivatives		Synthesis	35	Song, QB	FALSE	FALSE	FALSE	FALSE
7489	10.1007/s13738-015-0682-0	doi.org/10.1007/s13738-015-0682-0	Buchwald-Hartwig amination reaction using supported palladium on phosphine-functionalized magnetic nanoparticles		J. Iran Chem. Soc.	35	Khalafi-Nezhad, A	FALSE	FALSE	FALSE	FALSE
7490	10.1002/ejoc.201500856	doi.org/10.1002/ejoc.201500856	Lewis-Acid-Catalysed Friedel-Crafts Alkylation of Donor-Acceptor Cyclopropanes with Electron-Rich Benzenes to Generate 1,1-Diarylalkanes		Eur. J. Org. Chem.	35	Kim, SG	FALSE	TRUE	FALSE	FALSE
7491	10.1021/jacs.5b05597	doi.org/10.1021/jacs.5b05597	Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual Catalysis		J. Am. Chem. Soc.	35	Jamison, TF	TRUE	FALSE	FALSE	FALSE
7492	10.1007/s11144-015-0839-y	doi.org/10.1007/s11144-015-0839-y	Hydrodeoxygenation of methyl stearate as a model compound over Mo2C supported on mesoporous carbon		React. Kinet. Mech. Catal.	35	Li, MS	FALSE	FALSE	FALSE	FALSE
7493	10.1021/acs.organomet.5b00215	doi.org/10.1021/acs.organomet.5b00215	A Nickel-Based, Tandem Catalytic Approach to Isoindolinones from Imines, Aryl Iodides, and CO		Organometallics	35	Bengali, AA	FALSE	FALSE	FALSE	FALSE
7494	10.1186/s11671-015-0795-5	doi.org/10.1186/s11671-015-0795-5	Templated fabrication of hollow nanospheres with 'windows' of accurate size and tunable number		Nanoscale Res. Lett.	35	Hou, YD	FALSE	FALSE	FALSE	FALSE
7495	10.1016/j.catcom.2014.08.037	doi.org/10.1016/j.catcom.2014.08.037	Nickel-catalysed Suzuki-Miyaura cross-coupling reactions of aryl halides with arylboronic acids in ionic liquids		Catal. Commun.	35	Wang, M	FALSE	FALSE	FALSE	FALSE
7496	10.1080/07328303.2014.996290	doi.org/10.1080/07328303.2014.996290	Stereoselective Synthesis of Quercetin 3-O-Glycosides of 2-Amino-2-Deoxy-d-Glucose Under Phase Transfer Catalytic Conditions		J. Carbohydr. Chem.	35	Cao, ZL	FALSE	FALSE	FALSE	FALSE
7497	10.3762/bjoc.10.215	doi.org/10.3762/bjoc.10.215	P(O)R-2-directed Pd-catalyzed C-H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands		Beilstein J. Org. Chem.	35	Yang, SD	FALSE	FALSE	FALSE	FALSE
7498	10.1002/asia.201301265	doi.org/10.1002/asia.201301265	Enantiomerization Pathway and Atropochiral Stability of the BINAP Ligand: A Density Functional Theory Study		Chem.-Asian J.	35	Boggio-Pasqua, M	FALSE	FALSE	FALSE	FALSE
7499	10.1039/c3cc49402k	doi.org/10.1039/c3cc49402k	Photoresponsive metallo-hydrogels based on visual discrimination of the positional isomers through selective thixotropic gel collapse		Chem. Commun.	35	Tu, T	TRUE	FALSE	FALSE	FALSE
7500	10.3184/174751914X13857348538466	doi.org/10.3184/174751914X13857348538466	Highly efficient synthesis of arylnaphthalenes by modified fibre-palladium(II) complex catalysed Suzuki reaction in air		J. Chem. Res	35	Wu, ZC	FALSE	FALSE	FALSE	FALSE
7501	10.1016/j.tetlet.2013.10.111	doi.org/10.1016/j.tetlet.2013.10.111	Imidazolium supported palladium-chloroglycine complex: recyclable catalyst for Suzuki-Miyaura coupling reactions		Tetrahedron Lett.	35	Karthikeyan, P	FALSE	FALSE	FALSE	FALSE
7502	10.1002/chem.201303668	doi.org/10.1002/chem.201303668	Generation of Stoichiometric Ethylene and Isotopic Derivatives and Application in Transition-Metal-Catalyzed Vinylation and Enyne Metathesis		Chem.-Eur. J.	35	Gogsig, TM	FALSE	FALSE	FALSE	FALSE
7503	10.1002/chem.201302999	doi.org/10.1002/chem.201302999	Nickel-Catalyzed Arylation, Alkenylation, and Alkynylation of Unprotected Thioglycosides at Room Temperature		Chem.-Eur. J.	35	Alami, M	FALSE	FALSE	FALSE	FALSE
7504	10.1002/adsc.201300091	doi.org/10.1002/adsc.201300091	Calixarene-Derived Mono-Iminophosphoranes: Highly Efficient Ligands for Palladium- and Nickel-Catalysed Cross-Coupling		Adv. Synth. Catal.	35	Semeril, D	FALSE	FALSE	FALSE	FALSE
7505	10.5560/ZNB.2013-2342	doi.org/10.5560/ZNB.2013-2342	N-Heterocyclic Carbene-facilated Condensation of 3-Methylphenylboronic Acid to the Boroxine		Z.Naturforsch.(B)	35	Yang, Z	FALSE	FALSE	FALSE	FALSE
7506	10.3390/molecules18032788	doi.org/10.3390/molecules18032788	Synthesis of New BINAP-Based Aminophosphines and Their P-31-NMR Spectroscopy		Molecules	35	Liu, F	FALSE	FALSE	FALSE	FALSE
7507	10.1055/s-0032-1318237	doi.org/10.1055/s-0032-1318237	Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides		Synlett	35	Qian, Q	FALSE	FALSE	FALSE	FALSE
7508	10.1038/pj.2012.89	doi.org/10.1038/pj.2012.89	Synthesis of pi-conjugated poly(thienylenearylene)s with nickel-catalyzed C-H functionalization polycondensation		Polym. J.	35	Mori, A	FALSE	FALSE	FALSE	FALSE
7509	10.1021/ja306992k	doi.org/10.1021/ja306992k	Palladium-Catalyzed C-H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation		J. Am. Chem. Soc.	35	Itami, K	FALSE	FALSE	FALSE	FALSE
7510	10.1021/ol300891k	doi.org/10.1021/ol300891k	Traceless Directing Group for Stereospecific Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions		Org. Lett.	35	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
7511	10.1016/j.tetlet.2012.05.155	doi.org/10.1016/j.tetlet.2012.05.155	Pd(OAc)(2) catalyzed synthesis of 2-aryl- and 2-heteroaryl-benzoxazoles and benzothiazoles in imidazolium ionic liquids (ILs) without additives and with recycling/reuse of the IL		Tetrahedron Lett.	35	Laali, KK	FALSE	FALSE	FALSE	FALSE
7512	10.1021/ja208461k	doi.org/10.1021/ja208461k	Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides		J. Am. Chem. Soc.	35	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
7513	10.1590/S0103-50532011000900018	doi.org/10.1590/S0103-50532011000900018	Organonickel(II) Complexes with Anionic Tridentate 1,3-Bis(azolylmethyl)phenyl Ligands. Synthesis, Structural Characterization and Catalytic Behavior		J. Braz. Chem. Soc.	35	Valderrama, M	FALSE	FALSE	FALSE	FALSE
7514	10.1016/j.tetlet.2011.05.079	doi.org/10.1016/j.tetlet.2011.05.079	Ionically tagged benzimidazole palladium(II) complex: preparation and catalytic application in cross-coupling reactions		Tetrahedron Lett.	35	Li, FW	FALSE	FALSE	FALSE	FALSE
7515	10.1039/c1cc15753a	doi.org/10.1039/c1cc15753a	PdCl2(dppf)-catalyzed in situ coupling of 2-hydroxypyridines with aryl boronic acids mediated by PyBroP and the one-pot chemo- and regioselective construction of two distinct aryl-aryl bonds		Chem. Commun.	35	Han, FS	FALSE	FALSE	FALSE	FALSE
7516	10.1039/c1cc15503b	doi.org/10.1039/c1cc15503b	A highly efficient precatalyst for amination of aryl chlorides: synthesis, structure and application of a robust acenaphthoimidazolylidene palladium complex		Chem. Commun.	35	Tu, T	FALSE	FALSE	FALSE	FALSE
7517	10.1021/ja909689t	doi.org/10.1021/ja909689t	Nickel/Bis(oxazoline)-Catalyzed Asymmetric Kumada Reactions of Alkyl Electrophiles: Cross-Couplings of Racemic alpha-Bromoketones		J. Am. Chem. Soc.	35	Fu, GC	FALSE	TRUE	FALSE	FALSE
7518	10.1002/anie.201003191	doi.org/10.1002/anie.201003191	Expanding the Limits of Organoboron Chemistry: Synthesis of Functionalized Arylboronates		Angew. Chem.-Int. Edit.	35	Merino, P	FALSE	FALSE	FALSE	FALSE
7519	10.1021/ol901825u	doi.org/10.1021/ol901825u	Homogeneous, Anaerobic (N-Heterocyclic Carbene)-Pd or -Ni Catalyzed Oxidation of Secondary Alcohols at Mild Temperatures		Org. Lett.	35	Navarro, O	FALSE	FALSE	FALSE	FALSE
7520	10.1039/b909341a	doi.org/10.1039/b909341a	Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the beta-position		Org. Biomol. Chem.	35	Fernandez, E	FALSE	FALSE	FALSE	FALSE
7521	10.1002/chem.200801008	doi.org/10.1002/chem.200801008	Nickel-catalyzed coupling of aryl bromides in the presence of alkyllithium reagents		Chem.-Eur. J.	35	Carter, KR	FALSE	FALSE	FALSE	FALSE
7522	10.3184/030823408X283711	doi.org/10.3184/030823408X283711	Iodine/aqueous NH4OAc: an improved reaction system for direct oxidative conversion of aldehydes and alcohols into nitriles		J. Chem. Res	35	Cai, C	FALSE	FALSE	FALSE	FALSE
7523	10.1021/ma061319s	doi.org/10.1021/ma061319s	Isomeric hexafluoroisopropylidene-linked benzophenone polymers via nickel catalysis		Macromolecules	35	Sheares, VV	FALSE	FALSE	FALSE	FALSE
7524	10.1021/ol063048b	doi.org/10.1021/ol063048b	Efficient metal-catalyzed direct benzylation and allylic alkylation of 2,4-pentanediones		Org. Lett.	35	Rueping, M	FALSE	FALSE	FALSE	FALSE
7525	10.1246/cl.2006.1368	doi.org/10.1246/cl.2006.1368	Asymmetric cross-coupling of potassium 2-butenyltrifluoroborates with aryl and 1-alkenyl bromides catalyzed by a Pd(OAc)(2)/Josiphos complex		Chem. Lett.	35	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
7526	10.1055/s-2006-926232	doi.org/10.1055/s-2006-926232	The preparation of 2-isoxazolines from O-propargylic hydroxylamines via a tandem rearrangement-cyclisation reaction		Synlett	35	Lindell, S	FALSE	FALSE	FALSE	FALSE
7527	10.1039/b609064h	doi.org/10.1039/b609064h	Direct synthesis of 1,1-diarylalkenes from alkenyl phosphates via nickel(0)-catalysed Suzuki-Miyaura coupling		Chem. Commun.	35	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
7528	10.1055/s-2005-871571	doi.org/10.1055/s-2005-871571	Nickel- and palladium-catalyzed cross-coupling reaction of polyfluorinated arenes and alkenes with Grignard reagents		Synlett	35	Saeki, T	FALSE	FALSE	FALSE	FALSE
7529	10.1055/s-2004-831247	doi.org/10.1055/s-2004-831247	Enantioselective copper-mediated allylic substitution with Grignard reagents employing a chiral reagent-directing leaving group		Synthesis	35	Breit, B	FALSE	FALSE	FALSE	FALSE
7530	10.1016/j.ccr.2004.03.025	doi.org/10.1016/j.ccr.2004.03.025	Photo-sensitizing ruthenium complexes for solid state dye solar cells in combination with conducting polymers as hole conductors		Coord. Chem. Rev.	35	Yanagida, S	TRUE	FALSE	FALSE	FALSE
7531	10.1021/jo034330o	doi.org/10.1021/jo034330o	A new titanium tetrachloride mediated annulation of alpha-aryl-substituted carbonyl compounds with alkynes: A simple and highly efficient method for the regioselective synthesis of polysubstituted naphthalene derivatives		J. Org. Chem.	35	Kabalka, GW	FALSE	FALSE	FALSE	FALSE
7532	10.1021/ol034283m	doi.org/10.1021/ol034283m	Copper-catalyzed anti-stereocontrolled ring opening of oxabicyclic alkenes with Grignard reagents		Org. Lett.	35	Carretero, JC	FALSE	FALSE	FALSE	FALSE
7533	10.1002/1521-3773(20010401)40:7<1286::AID-ANIE1286>3.3.CO;2-9	doi.org/10.1002/1521-3773(20010401)40:7<1286::AID-ANIE1286>3.3.CO;2-9	Nickel-catalyzed highly regio- and stereoselective cyclization of oxanorbornenes with alkyl propiolates: A novel method for the synthesis of benzocoumarin derivatives		Angew. Chem.-Int. Edit.	35	Cheng, CH	FALSE	FALSE	FALSE	FALSE
7534	10.5059/yukigoseikyokaishi.57.845	doi.org/10.5059/yukigoseikyokaishi.57.845	Coupling reactions using boron ate complexes and application in organic synthesis		J. Synth. Org. Chem. Jpn.	35	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
7535	10.1021/jo990316t	doi.org/10.1021/jo990316t	4-trifloxy-9-SEM-beta-carboline: Preparation and synthetic utility		J. Org. Chem.	35	Busacca, CA	FALSE	FALSE	FALSE	FALSE
7536	10.1016/S0040-4020(98)01154-5	doi.org/10.1016/S0040-4020(98)01154-5	Enantioposition-selective arylation of biaryl ditriflates by palladium-catalyzed asymmetric Grignard cross-coupling		Tetrahedron	35	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7537	10.1021/ja970885n	doi.org/10.1021/ja970885n	Stereoselective heteroatom-assisted allylic alkylation of cyclic ethers with Grignard reagents. A convenient route to enantiomerically pure carbocycles		J. Am. Chem. Soc.	35		FALSE	FALSE	FALSE	FALSE
7538	10.1002/anie.199705181	doi.org/10.1002/anie.199705181	Asymmetric Heck reactions via neutral intermediates: Enhanced enantioselectivity with halide additives gives mechanistic insights		Angew. Chem.-Int. Edit. Engl.	35	Overman, LE	FALSE	FALSE	FALSE	FALSE
7539	10.1021/ic00130a006	doi.org/10.1021/ic00130a006	[Pt-2(dppf)(2)(mu-S)(2)] as a heterometallic ligand. Simple assembly of an electroactive interpolymetallic complex [Pt2Tl(dppf)(2)(mu(3)-S)(2)]X (X=NO3, PF6) (dppf=1,1'-bis(diphenylphosphino)ferrocene)		Inorg. Chem.	35	Zhou, MS	FALSE	FALSE	FALSE	FALSE
7540	10.1021/jo00042a046	doi.org/10.1021/jo00042a046	A DELTA-KETO ALDEHYDE SYNTHESIS - APPLICATION TO THE PREPARATION OF THE SEX-PHEROMONE OF THE DOUGLAS-FIR TUSSOCK MOTH		J. Org. Chem.	35	STOWELL, JC	FALSE	FALSE	FALSE	FALSE
7541	10.1021/jo00006a016	doi.org/10.1021/jo00006a016	BENZYNE GENERATION FROM ARYL TRIFLATES		J. Org. Chem.	35	WICKHAM, PP	FALSE	FALSE	FALSE	FALSE
7542	10.1021/jo00390a007	doi.org/10.1021/jo00390a007	PALLADIUM-CATALYZED DECARboxYLATION ALLYLATION OF ALLYLIC ESTERS OF ALPHA-SUBSTITUTED BETA-KETO CARboxYLIC, MALONIC, CYANOACETIC, AND NITROACETIC ACIDS		J. Org. Chem.	35	TSUJI, J	FALSE	FALSE	FALSE	FALSE
7543	10.1016/S0022-328X(00)82039-2	doi.org/10.1016/S0022-328X(00)82039-2	REACTIVITY OF ORGANOMAGNESIUM WITH ACETYLENIC-COMPOUNDS IN PRESENCE OF NICKEL-COMPLEX (PPH3)2NICL2		J. Organomet. Chem.	35	DUBOUDIN, JG	FALSE	FALSE	FALSE	FALSE
7544	10.3390/molecules26237148	doi.org/10.3390/molecules26237148	BN-Embedded Perylenes		Molecules	35	Fang, XD	FALSE	FALSE	FALSE	FALSE
7545	10.1021/acs.orglett.1c01871	doi.org/10.1021/acs.orglett.1c01871	Synthesis of 3,3-Dialkyl-Substituted Isoindolinones Enabled by Nickel-Catalyzed Reductive Dicarbofunctionalization of Enamides		Org. Lett.	35	Chen, YF	FALSE	FALSE	FALSE	FALSE
7546	10.1038/s41467-021-23971-7	doi.org/10.1038/s41467-021-23971-7	C(sp(3))-C(sp(3)) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine		Nat. Commun.	35	Li, CJ	FALSE	FALSE	FALSE	FALSE
7547	10.1021/acs.orglett.1c00162	doi.org/10.1021/acs.orglett.1c00162	Pyrenedione-Catalyzed alpha-Olefination of Nitriles under Visible-Light Photoredox Conditions		Org. Lett.	35	Adhikari, D	TRUE	FALSE	FALSE	FALSE
7548	10.1021/acs.orglett.7b01598	doi.org/10.1021/acs.orglett.7b01598	Electrochemical Nickel Catalysis for Sp(2)-Sp(3) Cross-Electrophile Coupling Reactions of Unactivated Alkyl Halides		Org. Lett.	35	Hansen, EC	FALSE	TRUE	FALSE	FALSE
7549	10.1002/ejoc.201700585	doi.org/10.1002/ejoc.201700585	Pd-Catalyzed Amination of Functionalized 6-Bromo-pyridinyl-1,2,4-triazine Complexant Scaffolds		Eur. J. Org. Chem.	35	Carrick, JD	FALSE	FALSE	FALSE	FALSE
7550	10.1016/j.ica.2016.10.001	doi.org/10.1016/j.ica.2016.10.001	Exploring the coordination chemistry of N-heterocyclic phosphenium/phosphido ligands using nickelocene as a synthon		Inorg. Chim. Acta	35	Thomas, CM	FALSE	FALSE	FALSE	FALSE
7551	10.6023/cjoc201610009	doi.org/10.6023/cjoc201610009	Nickel-Catalyzed Intramolecular Addition of Aryl Bromides to C=O Bonds		Chin. J. Org. Chem.	35	Jia, YX	FALSE	FALSE	FALSE	FALSE
7552	10.1021/acscatal.6b03434	doi.org/10.1021/acscatal.6b03434	Development of Versatile Sulfone Electrophiles for Suzuki-Miyaura Cross-Coupling Reactions		ACS Catal.	35	Nambo, M; Crudden, CM	FALSE	TRUE	FALSE	FALSE
7553	10.1007/s10847-016-0673-5	doi.org/10.1007/s10847-016-0673-5	Pillar[5]arene-based N-heterocyclic carbene ligand for Pd-catalysed Suzuki reaction		J. Incl. Phenom. Macrocycl. Chem.	35	Wang, JW	FALSE	FALSE	FALSE	FALSE
7554	10.1007/s00706-016-1878-4	doi.org/10.1007/s00706-016-1878-4	A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada-Corriu and Negishi cross-coupling reactions		Mon. Chem.	35	Kirchner, K	FALSE	FALSE	FALSE	FALSE
7555	10.1021/acs.organomet.6b00650	doi.org/10.1021/acs.organomet.6b00650	A Comparative Reactivity Survey of Some Prominent Bisphosphine Nickel(II) Precatalysts in C-N Cross-Coupling		Organometallics	35	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7556	10.1016/j.tetlet.2016.06.083	doi.org/10.1016/j.tetlet.2016.06.083	Synthesis of novel pillar[5]arene-based N-heterocyclic carbene ligands for Pd-catalysed Heck reactions		Tetrahedron Lett.	35	Wang, JW	FALSE	FALSE	FALSE	FALSE
7557	10.1021/jacs.6b04818	doi.org/10.1021/jacs.6b04818	Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling		J. Am. Chem. Soc.	35	MacMillan, DWC	FALSE	TRUE	FALSE	FALSE
7558	10.6023/cjoc201602007	doi.org/10.6023/cjoc201602007	Nickel-Catalyzed Addition and Coupling Reaction of Aryl Triflates to Aldehydes		Chin. J. Org. Chem.	35	Jia, YX	FALSE	FALSE	FALSE	FALSE
7559	10.1126/science.aaf6635	doi.org/10.1126/science.aaf6635	Native functionality in triple catalytic cross-coupling: sp(3) C-H bonds as latent nucleophiles		Science	35	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
7560	10.1016/j.jorganchem.2016.02.019	doi.org/10.1016/j.jorganchem.2016.02.019	A new N-heterocyclic carbene palladium complex immobilized on nano silica: An efficient and recyclable catalyst for Suzuki-Miyaura C-C coupling reaction		J. Organomet. Chem.	35	Moghadam, M; Mirkhani, V	FALSE	FALSE	FALSE	FALSE
7561	10.1002/chem.201600167	doi.org/10.1002/chem.201600167	Chemoselective Synthesis of Polysubstituted Pyridines from Heteroaryl Fluorosulfates		Chem.-Eur. J.	35	Zhang, EX	FALSE	FALSE	FALSE	FALSE
7562	10.1021/acs.joc.5b02770	doi.org/10.1021/acs.joc.5b02770	On-Water Synthesis of Biaryl Sulfonyl Fluorides		J. Org. Chem.	35	Arvidsson, PI	FALSE	FALSE	FALSE	FALSE
7563	10.1021/jasms.0c00384	doi.org/10.1021/jasms.0c00384	Monoacylation of Symmetrical Diamines in Charge Microdroplets	A direct introduction of vinyl ethers into C-H bond of heterocycles is reported. For this purpose, decarboxylative direct C-H cross-coupling of 1,3-diazoles with alpha-carboxyvinyl ethers as coupling partners was achieved under Pd(0)/Cu(I) cooperative catalysis to produce various alpha-heteroarylated vinylethers. This methodology was applied to the innovative production of heteroarylated enolizable ketones and naturally occurring bis-oxa(thia)zoles.	J. Am. Soc. Mass Spectrom.	34	Badu-Tawiah, AK	FALSE	FALSE	FALSE	FALSE
7564	10.1021/acs.orglett.1c00023	doi.org/10.1021/acs.orglett.1c00023	Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible-Light Irradiation of EDA Complexes	The reaction of C6F5H and H2C CHSiMe3 with catalytic [(i)Pr(2)Im]Ni(eta(2)-H2C CHSiMe3)(2) (1b) exclusively forms the C-H silylation product C6F5SiMe3 with ethylene as a byproduct ([(i)Pr(2)Im] = 1,3-di(isopropyl)imidazole-2-ylidene). Catalytic C-H bond silylation is facile with partially fluorinated aromatic substrates containing two ortho fluorine substituents adjacent to the C-H bond and 1,2,3,4-tetrafluorobenzene. Less fluorinated substrates react slower. Under the same reaction conditions, catalytic [IPr]Ni(eta(2)-H2C=CHSiMe3)(2) (1a) ([IPr] = 1,3-bis [2,6-diisopropylphenyl]-1,3-dihydro-2H-imidazol-2-ylidene) provided only the alkene hydroarylation product C6F5CH2CH2SiMe3. Mechanistic studies reveal that the C-H activation and beta-Si elimination steps are reversible under catalytic conditions with both catalysts la and 1b. With catalytic la, reversible ethylene loss after beta-Si elimination was also observed despite its inability to catalyze C-H silylation; the reductive elimination step to form the silylation product is much slower than reductive elimination to form the alkene hydroarylation product. Reversible ethylene loss was not observed with 1b, which suggests that the rate-limiting step in the reaction is neither C-H activation nor beta-Si elimination but either ethylene loss or reductive elimination of cis-disposed aryl and SiMe3 moieties.	Org. Lett.	34	Overman, LE	FALSE	FALSE	FALSE	FALSE
7565	10.1002/adsc.202001496	doi.org/10.1002/adsc.202001496	Zirconium Oxide-Catalyzed Direct Amidation of Unactivated Esters under Continuous-Flow Conditions	The efficient multi-step, large-scale synthesis, spectroscopic characterization and solid-state molecular structure of a new type of three-fold functionalized, sterically demanding triazine is reported. The aromatic heterocycle 6,6 ',6('')((1,3,5-triazine-2,4,6-triy1)tris(methylene))tris(2,4-di-tert-butylphenol) possesses three 2,4-di-tert-butylphenol synthons bound to the 1,3,5-triazine ring via synthetically challenging methylene linkages in the 2,4,6 positions. The key to success was found in the generation of a highly reactive imidate hydrochloride salt, namely ethyl 2-(3,5-di-tert-butyl-2-methoxyphenyl)acetimidate hydrochloride, that readily undergoes cyclotrimerization. The reported preparation opens new perspectives in the design and synthesis of novel triazine molecules bearing flexible and sterically demanding functionalized groups for various applications. (C) 2017 Elsevier Ltd. All rights reserved.	Adv. Synth. Catal.	34	Koumura, N; Sato, K; Kobayashi, S	FALSE	FALSE	FALSE	FALSE
7566	10.1002/ejoc.202001485	doi.org/10.1002/ejoc.202001485	Nickel- and Palladium-Catalyzed Cross-Coupling of Aryl Fluorosulfonates and Phosphites: Synthesis of Aryl Phosphonates	The synthesis and/or NMR/X-ray characterization of a new series of (L)AuCl complexes is reported, featuring BippyPhos, AdJohnPhos, silyl ether based ligands including OTips-DalPhos, and PAd-DalPhos. These complexes, along with previously reported analogues featuring cataCXium-A, tBuJohnPhos, and Mor-DalPhos, were screened as precatalysts using LiB(C6F5)425Et(2)O as an activator in the hydrohydrazination of terminal aryl alkynes with hydrazine hydrate under unprecedentedly mild conditions (25 degrees C, 1 mol % Au). The precatalyst (cataCXium-A)AuCl proved to be particularly effective in such transformations, demonstrating useful scope.	Eur. J. Org. Chem.	34	Ding, CR	FALSE	FALSE	FALSE	FALSE
7567	10.1039/d0dt01119c	doi.org/10.1039/d0dt01119c	Oxidative addition of activated aryl-carboxylates to Pd(0): divergent reactivity dependant on temperature and structure	Palladium-catalyzed cross-coupling reactions are indispensable tools in molecular syntheses with numerous applications in academia and for the practitioners in the chemical and pharmaceutical industries. Recent years have witnessed the increasing use of biomass-derived solvents as green reaction media in the palladium-, copper-and nickel-catalyzed cross-coupling technology, the key advances until January 2017 being summarized in this review. In addition, very recent first examples of transition metal-catalyzed C-H activations in biomass-originated solvents, such as gamma-valerolactone and 2-MeTHF, are discussed as well.	Dalton Trans.	34	Leitch, DC	FALSE	FALSE	FALSE	FALSE
7568	10.1039/d0qo01087a	doi.org/10.1039/d0qo01087a	Rh-Catalyzed diastereo- and linear-selective alpha-allylation of chiral cycloenamines	An Ir-catalyzed intermolecular asymmetric dearomatization reaction of beta-naphthols with allyl alcohols or allyl ethers was developed. When an iridium catalyst generated from [Ir(COD)Cl](2) (COD = cyclooctadiene) and a chiral P/olefin ligand is employed, highly functionalized beta-naphthalenone compounds bearing an all-carbon-substituted quaternary chiral center were obtained in up to 92% yield and 98% ee. The direct utilization of allyl alcohols as electrophiles represents an improvement from the viewpoint of atom economy. Allyl ethers were found to undergo asymmetric allylic substitution reaction under Ir catalysis for the first time. The diverse transformations of the dearomatized product to various motifs render this method attractive.	Org. Chem. Front.	34	Wang, XJ	FALSE	FALSE	FALSE	FALSE
7569	10.1021/acs.orglett.0c03146	doi.org/10.1021/acs.orglett.0c03146	Cu-Catalyzed Dehydrogenative Olefinsulfonation of Alkyl Arenes	The conversion of substituted 1,3-cyclohexane-diones to the alkyl ethers of resorcinol using a Pd/C ethylene system is reported. In these reactions, ethylene works as a hydrogen acceptor. The efficient synthesis of resveratrol was achieved using this protocol as a key step. In addition, the direct formation of substituted resorcinols was carried out by adding K2CO3 into the reaction media.	Org. Lett.	34	Leng, YT; Wu, JL	FALSE	FALSE	FALSE	FALSE
7570	10.2533/chimia.2020.866	doi.org/10.2533/chimia.2020.866	Lithium-mediated Ferration of Fluoroarenes	We report the direct allylation of benzyl alcohols, diarylmethanols and triarylmethanols mediated by XtalFluor-E using allyltrimethylsilane. The resulting allylated products are obtained in moderate to high yield. (C) 2016 Elsevier Ltd. All rights reserved.	Chimia	34	Hevia, E	FALSE	FALSE	FALSE	FALSE
7571	10.1021/acs.orglett.0c02566	doi.org/10.1021/acs.orglett.0c02566	Halide-Accelerated Acyl Fluoride Formation Using Sulfuryl Fluoride	Conventional organic synthesis has been mainly based upon the reactivities of pi-bonds and polar sigma-bonds. Carbon-carbon single bonds are nonpolar and generally far less reactive. Although they remain intact under most reaction conditions, it is possible to activate and cleave them if suitable organometallic compounds or metal catalysts are applied. Such C-C single bond cleavage reactions are attracting increasing attention in the context of synthetic chemistry because they provide a unique and more straightforward route from readily available substances to targets, while requiring significantly fewer steps. The present Perspective aims to exemplify the potential of metal-catalyzed C-C single bond cleavage for organic synthesis.	Org. Lett.	34	Hein, JE; Sammis, GM	FALSE	FALSE	FALSE	FALSE
7572	10.1016/j.tet.2020.131216	doi.org/10.1016/j.tet.2020.131216	A substituted tricyclohexylphosphane with conformational lock	A protocol for the Pd-catalyzed CS(sp(3))-H arylation of readily available 1-Boc-3-(picolinoylamino)piperidine with iodo(hetero)arenes is reported. The substrate can be obtained from a biorenewable feedstock, namely L-arginine. The use of the right N1 protective group is decisive to get arylation. The addition of a catalytic amount of 2,6-dimethylbenzoic acid and performing the reaction at high concentration are important to achieve a high conversion and yield. The procedure gives arylated 1-Boc-3-(picolinoylamino)piperidines in a regiospecific (C5) and stereo-specific (cis) manner. Orthogonal cleavage of the amide over the carbamate group allows one to further selectively derivatize the amino moieties of the piperidine scaffold.	Tetrahedron	34	Zhao, JH; Tang, WJ	FALSE	FALSE	FALSE	FALSE
7573	10.1016/j.polymertesting.2020.106354	doi.org/10.1016/j.polymertesting.2020.106354	Reaction mechanism of halogenated rubber crosslinking using a novel environmentally friendly curing system	The copper-mediated direct ortho CH bond arylation of benzamide derivatives with arylboronic acids was achieved by employing an 8-aminoquinoline moiety as the bidentate directing group. Various biaryls were synthesized in good yields with excellent regioselectivity. The reaction shows good functional group compatibility and proceeds in a highly selective manner at the ortho-position of the benzamides. Deuterium-labelling experiments indicated that the ortho CH bond cleavage of benzamide was involved in the rate-determining step of the arylation.	Polym. Test	34	Dziemidkiewicz, A	FALSE	FALSE	FALSE	FALSE
7574	10.1021/jacs.0c00359	doi.org/10.1021/jacs.0c00359	Evolution of a Strategy for the Enantioselective Synthesis of (-)-Cajanusine	In this frontier article we overview the emergence and scope of NHC-based CCC and CNC pincer systems, i.e. complexes containing mer-tridentate ligands bearing two NHC donor groups, comment on their effectiveness in applications, and highlight areas for future development and exploitation.	J. Am. Chem. Soc.	34	Brown, MK	FALSE	FALSE	FALSE	FALSE
7575	10.1021/acs.organomet.9b00561	doi.org/10.1021/acs.organomet.9b00561	Amidation of Aryl Chlorides Using a Microwave-Assisted, Copper-Catalyzed Concurrent Tandem Catalytic Methodology		Organometallics	34	Lin, S; MacArthur, AHR	FALSE	FALSE	FALSE	FALSE
7576	10.1021/acs.joc.9b01819	doi.org/10.1021/acs.joc.9b01819	Nickel-Catalyzed Double Dehydrogenative Coupling of Secondary Alcohols and beta-Amino Alcohols To Access Substituted Pyrroles		J. Org. Chem.	34	Banerjee, D	FALSE	FALSE	FALSE	FALSE
7577	10.1016/j.tet.2019.130561	doi.org/10.1016/j.tet.2019.130561	Synthetic access to 3,4-disubstituted pyroglutamates from tetramate derivatives from serine, allo-threonine and cysteine		Tetrahedron	34	Moloney, MG	FALSE	FALSE	FALSE	FALSE
7578	10.1039/c9qo00822e	doi.org/10.1039/c9qo00822e	TfOH-promoted transformation of TMS-ethers of diarylsubstituted CF3-allyl alcohols with arenes into CF3-indanes		Org. Chem. Front.	34	Vasilyev, AV	FALSE	FALSE	FALSE	FALSE
7579	10.1039/c9cc01977d	doi.org/10.1039/c9cc01977d	Computational mapping of redox-switchable metal complexes based on ferrocene derivatives		Chem. Commun.	34	Diaconescu, PL	FALSE	FALSE	FALSE	FALSE
7580	10.1021/acs.orglett.9b01576	doi.org/10.1021/acs.orglett.9b01576	Chemoselective Synthesis of 1,1-Disubstituted Vinyl Triflates from Terminal Alkynes Using TfOH in the Presence of TMSN3		Org. Lett.	34	Tummatorn, J	FALSE	FALSE	FALSE	FALSE
7581	10.3390/molecules24122296	doi.org/10.3390/molecules24122296	Cross-Coupling Reaction of Allylic Ethers with Aryl Grignard Reagents Catalyzed by a Nickel Pincer Complex		Molecules	34	Hashimoto, T; Yamaguchi, Y	FALSE	FALSE	FALSE	FALSE
7582	10.1021/acs.joc.8b02785	doi.org/10.1021/acs.joc.8b02785	Synthesis of N-Acyl Sulfamates from Fluorosulfates and Amides		J. Org. Chem.	34	De Borggraeve, WM	FALSE	FALSE	FALSE	FALSE
7583	10.1002/ejoc.201801494	doi.org/10.1002/ejoc.201801494	Nickel-Catalyzed Directed Hydroarylation of Alkynes with Boronic Acids		Eur. J. Org. Chem.	34	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
7584	10.1021/acs.orglett.8b03567	doi.org/10.1021/acs.orglett.8b03567	Stereoselective Preparation of alpha-C-Vinyl/Aryl Glycosides via Nickel-Catalyzed Reductive Coupling of Glycosyl Halides with Vinyl and Aryl Halides		Org. Lett.	34	Gong, HG	FALSE	FALSE	FALSE	FALSE
7585	10.1021/acs.joc.8b00631	doi.org/10.1021/acs.joc.8b00631	Cascading Auto-oxidative Biproline Guanylations Form Optically Active Dispacamide Dimers and Permit an Eight-Step Synthesis of (-)-Ageliferin		J. Org. Chem.	34	Harran, PG	FALSE	FALSE	FALSE	FALSE
7586	10.1039/c8ta00910d	doi.org/10.1039/c8ta00910d	Ultrafine nickel nanocatalyst-engineering of an organic layered double hydroxide towards a super-efficient fire-safe epoxy resin via interfacial catalysis		J. Mater. Chem. A	34	Wang, DY	FALSE	FALSE	FALSE	FALSE
7587	10.1016/j.catcom.2017.09.021	doi.org/10.1016/j.catcom.2017.09.021	Nickel embedded on triazole-modified magnetic nanoparticles: A novel and sustainable heterogeneous catalyst for Hiyama reaction in fluoride-free condition		Catal. Commun.	34	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
7588	10.1039/c8ra05311a	doi.org/10.1039/c8ra05311a	Copper-catalyzed C-S direct cross-coupling of thiols with 5-arylpenta-2,4-dienoic acid ethyl ester		RSC Adv.	34	Xu, RS	FALSE	FALSE	FALSE	FALSE
7589	10.1021/acs.orglett.7b02867	doi.org/10.1021/acs.orglett.7b02867	Asymmetric Synthesis of Functionalized trans-Cyclopropoxy Building Block for Grazoprevir		Org. Lett.	34	Xu, F; Zhong, YL	FALSE	FALSE	FALSE	FALSE
7590	10.1039/c7ob02012k	doi.org/10.1039/c7ob02012k	Copper-catalyzed oxidative cross-coupling of alpha-aminocarbonyl compounds with primary amines toward 2-oxo-acetamidines		Org. Biomol. Chem.	34	Xiang, JN	FALSE	FALSE	FALSE	FALSE
7591	10.1039/c6gc00932h	doi.org/10.1039/c6gc00932h	N-Butylpyrrolidinone as a dipolar aprotic solvent for organic synthesis		Green Chem.	34	Hunt, AJ	FALSE	FALSE	FALSE	FALSE
7592	10.1021/jacs.5b06466	doi.org/10.1021/jacs.5b06466	Nickel-Catalyzed Asymmetric Reductive Cross-Coupling between Heteroaryl Iodides and alpha-Chloronitriles		J. Am. Chem. Soc.	34	Reisman, SE	FALSE	FALSE	FALSE	FALSE
7593	10.1016/j.tet.2015.03.030	doi.org/10.1016/j.tet.2015.03.030	Scalable synthesis of dihydroxyterphenylphosphine ligands		Tetrahedron	34	Manabe, K	FALSE	FALSE	FALSE	FALSE
7594	10.1016/j.tetlet.2014.10.065	doi.org/10.1016/j.tetlet.2014.10.065	O-(Aminosulfonylation) of phenols and an example of slow hydrolytic release		Tetrahedron Lett.	34	Knapp, S	FALSE	FALSE	FALSE	FALSE
7595	10.1016/j.ica.2014.08.012	doi.org/10.1016/j.ica.2014.08.012	Ni(II) catalyzed bromination of aryl C-H bonds		Inorg. Chim. Acta	34	Das, S	FALSE	FALSE	FALSE	FALSE
7596	10.1021/ja500706v	doi.org/10.1021/ja500706v	Catalytic Enantioselective Cyclization/Cross-Coupling with Alkyl Electrophiles		J. Am. Chem. Soc.	34	Fu, GC	FALSE	TRUE	FALSE	FALSE
7597	10.1515/pac-2014-5031	doi.org/10.1515/pac-2014-5031	Activation of stable sigma-bonds for organic synthesis		Pure Appl. Chem.	34	Hiyama, T	FALSE	FALSE	FALSE	FALSE
7598	10.1021/jo4023974	doi.org/10.1021/jo4023974	Aminolysis of Aryl Ester Using Tertiary Amine as Amino Donor via C-O and C-N Bond Activations		J. Org. Chem.	34	Bao, YS	FALSE	FALSE	FALSE	FALSE
7599	10.1039/c3ob41989d	doi.org/10.1039/c3ob41989d	Nickel-catalyzed cross-coupling of aryltrimethylammonium triflates and amines		Org. Biomol. Chem.	34	Wang, ZX	FALSE	FALSE	FALSE	FALSE
7600	10.1021/ol402887z	doi.org/10.1021/ol402887z	Oxonium Ylide Rearrangement of Enzymatically Desymmetrized Glutarates		Org. Lett.	34	Deska, J	FALSE	FALSE	FALSE	FALSE
7601	10.1016/j.jbiotec.2013.06.015	doi.org/10.1016/j.jbiotec.2013.06.015	Concurrent obtaining of aromatic (R)-2-hydroxyacids and aromatic 2-ketoacids by asymmetric oxidation with a newly isolated Pseudomonas aeruginosa ZJB1125		J. Biotechnol.	34	Zheng, YG	FALSE	FALSE	FALSE	FALSE
7602	10.1002/ejoc.201300102	doi.org/10.1002/ejoc.201300102	Total Synthesis of Neo-Tanshinlactones through a Cascade Benzannulation-Lactonization as the Key Step		Eur. J. Org. Chem.	34	Mal, D	FALSE	FALSE	FALSE	FALSE
7603	10.1002/jhet.1710	doi.org/10.1002/jhet.1710	Rapid and Convenient Synthesis of N-Arylmorpholines under Microwave Irradiation		J. Heterocycl. Chem.	34	Li, HB	FALSE	FALSE	FALSE	FALSE
7604	10.3762/bjoc.9.81	doi.org/10.3762/bjoc.9.81	Intramolecular carbonickelation of alkenes		Beilstein J. Org. Chem.	34	Durandetti, M	FALSE	FALSE	FALSE	FALSE
7605	10.1039/c3cc45836a	doi.org/10.1039/c3cc45836a	The crucial role of a Ni(I) intermediate in Ni-catalyzed carboxylation of aryl chloride with CO2: a theoretical study		Chem. Commun.	34	Sakaki, S	FALSE	FALSE	FALSE	FALSE
7606	10.1039/c3dt51196k	doi.org/10.1039/c3dt51196k	A thiocyanato-bridged copper(I) cubane complex and its application in palladium-catalyzed Sonogashira coupling of aryl halides		Dalton Trans.	34	Trivedi, M	FALSE	FALSE	FALSE	FALSE
7607	10.2174/157017812803901854	doi.org/10.2174/157017812803901854	Hematoxylin as a General and Efficient Ligand for the Cu(I)-catalyzed S-arylation of Thiols with Aryl Halides in DMF-H2O		Lett. Org. Chem.	34	Wu, XM	FALSE	FALSE	FALSE	FALSE
7608	10.1016/j.tetlet.2012.08.015	doi.org/10.1016/j.tetlet.2012.08.015	Ni-catalyzed arylation of bromomagnesium diarylamides with aryl N,N-dimethylsulfamates		Tetrahedron Lett.	34	Yamakawa, T	FALSE	FALSE	FALSE	FALSE
7609	10.1021/ol300908g	doi.org/10.1021/ol300908g	K2CO3-Catalyzed Synthesis of Chromones and 4-Quinolones through the Cleavage of Aromatic C-O Bonds		Org. Lett.	34	Fu, H	FALSE	FALSE	FALSE	FALSE
7610	10.1055/s-0031-1289717	doi.org/10.1055/s-0031-1289717	Base-Mediated Tandem Reaction of alpha-Aryloxyacetophenones with Phosphonates: Selective Synthesis of Enol Phosphates		Synthesis	34	Xie, YX	FALSE	FALSE	FALSE	FALSE
7611	10.1021/ol203322v	doi.org/10.1021/ol203322v	Nickel(0)-Catalyzed Heck Cross-Coupling via Activation of Aryl C-OPiv Bonds		Org. Lett.	34	Watson, MP	FALSE	FALSE	FALSE	FALSE
7612	10.1590/S0100-40422012001100039	doi.org/10.1590/S0100-40422012001100039	OTTO R. GOTTLIEB AND ERNEST WENKERT's CONNECTIONS WITH BRAZIL		Quim. Nova	34	Pinto, AC	FALSE	FALSE	FALSE	FALSE
7613	10.1021/ol202068p	doi.org/10.1021/ol202068p	Oxazolidine Synthesis by Complementary Stereospecific and Stereoconvergent Methods		Org. Lett.	34	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
7614	10.1021/ol200059u	doi.org/10.1021/ol200059u	A Simple, Nontoxic Iron System for the Allylation of Zinc Enolates		Org. Lett.	34	Cook, SP	FALSE	FALSE	FALSE	FALSE
7615	10.1002/chem.201003731	doi.org/10.1002/chem.201003731	Cross-Coupling of Aryl/Alkenyl Ethers with Aryl Grignard Reagents through Nickel-Catalyzed C-O Activation		Chem.-Eur. J.	34	Wang, ZX	FALSE	FALSE	FALSE	FALSE
7616	10.1021/ol1029673	doi.org/10.1021/ol1029673	Reductive Alkylation of Indoles with Alkynes and Hydrosilanes under Indium Catalysis		Org. Lett.	34	Tsuchimoto, T	FALSE	FALSE	FALSE	FALSE
7617	10.1039/c0cc05805j	doi.org/10.1039/c0cc05805j	High efficiency of cavity-based triaryl-phosphines in nickel-catalysed Kumada-Tamao-Corriu cross-coupling		Chem. Commun.	34	Semeril, D	FALSE	FALSE	FALSE	FALSE
7618	10.3998/ark.5550190.0012.a10	doi.org/10.3998/ark.5550190.0012.a10	Smiles rearrangement for the synthesis of diarylamines		Arkivoc	34	Zuo, H	FALSE	FALSE	FALSE	FALSE
7619	10.1016/j.tetasy.2010.03.045	doi.org/10.1016/j.tetasy.2010.03.045	Palladium-catalyzed regio- and enantio-selective allylic substitution reaction of monosubstituted allyl substrates with benzyl alcohols		Tetrahedron-Asymmetry	34	Hou, XL	FALSE	FALSE	FALSE	FALSE
7620	10.1021/ja910808x	doi.org/10.1021/ja910808x	Neopentylglycolborylation of Aryl Mesylates and Tosylates Catalyzed by Ni-Based Mixed-Ligand Systems Activated with Zn		J. Am. Chem. Soc.	34	Percec, V	FALSE	FALSE	FALSE	FALSE
7621	10.1021/jo901504n	doi.org/10.1021/jo901504n	Isomerization of 7-Oxabenzonorbornadienes into Naphthols Catalyzed by [RuCl2(CO)(3)](2)		J. Org. Chem.	34	Tam, W	FALSE	FALSE	FALSE	FALSE
7622	10.1007/s11172-009-0150-z	doi.org/10.1007/s11172-009-0150-z	New heterocyclic ferrocenes with planar chirality		Russ. Chem. Bull.	34	Chupakhin, ON	FALSE	FALSE	FALSE	FALSE
7623	10.1021/jo802731j	doi.org/10.1021/jo802731j	Indium-Catalyzed C-S Cross-Coupling of Aryl Halides with Thiols		J. Org. Chem.	34	Rao, KR	FALSE	FALSE	FALSE	FALSE
7624	10.1039/b821520k	doi.org/10.1039/b821520k	Nanofiber formation via the self-assembly of a chiral regioregular poly(azomethine)		Chem. Commun.	34	Chujo, Y	FALSE	FALSE	FALSE	FALSE
7625	10.1021/ja805635c	doi.org/10.1021/ja805635c	Trans-Selective Asymmetric Aziridination of Diazoacetamides and N-Boc Imines Catalyzed by Axially Chiral Dicarboxylic Acid		J. Am. Chem. Soc.	34	Maruoka, K	FALSE	FALSE	FALSE	FALSE
7626	10.1002/ejoc.200600026	doi.org/10.1002/ejoc.200600026	CuI/DABCO-catalyzed cross-coupling reactions of aryl halides with arylboronic acids		Eur. J. Org. Chem.	34	Li, JH	FALSE	FALSE	FALSE	FALSE
7627	10.1002/anie.200504450	doi.org/10.1002/anie.200504450	Catalytic arylation reactions by C-H bond activation with aryl tosylates		Angew. Chem.-Int. Edit.	34	Ackermann, L	FALSE	FALSE	FALSE	FALSE
7628	10.1080/104265090969225	doi.org/10.1080/104265090969225	Synthesis and single crystal X-ray structures of N,N '-bis(diphenylphosphinothioyl)piperzine and bis(diphenylphosphinoselenoyl)piperzine		Phosphorus Sulfur Silicon Relat. Elem.	34	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
7629	10.1021/ja056327n	doi.org/10.1021/ja056327n	Nickel-catalyzed cross-coupling reaction of aryl fluorides and chlorides with Grignard reagents under nickel/magnesium bimetallic cooperation		J. Am. Chem. Soc.	34	Nakamura, E	FALSE	FALSE	FALSE	FALSE
7630	10.1021/jo0513764	doi.org/10.1021/jo0513764	Mild and room temperature C-C bond forming reactions of nucleoside C-6 arylsulfonates		J. Org. Chem.	34	Lakshman, MK	FALSE	FALSE	FALSE	FALSE
7631	10.1002/anie.200462280	doi.org/10.1002/anie.200462280	Easy access to aryl- and heteroaryl-annulated[a]carbazoles by the indium-catalyzed reaction of 2-arylindoles with propargyl ethers		Angew. Chem.-Int. Edit.	34	Tsuchimoto, T	FALSE	FALSE	FALSE	FALSE
7632	10.1002/ejoc.2004002636	doi.org/10.1002/ejoc.2004002636	Connective synthesis of spirovetivanes: Total synthesis of (+/-)-agarospirol, (+/-)-hinesol and (+/-)-alpha-vetispirene		Eur. J. Org. Chem.	34	Marko, IE	FALSE	FALSE	FALSE	FALSE
7633	10.1039/b314246a	doi.org/10.1039/b314246a	The Sonogashira coupling reaction catalyzed by ultrafine nickel(0) powder		Chem. Commun.	34	Wang, L	FALSE	FALSE	FALSE	FALSE
7634	10.1039/b408185d	doi.org/10.1039/b408185d	Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen		Green Chem.	34	Kaneda, K	FALSE	FALSE	FALSE	FALSE
7635	10.1002/anie.200351817	doi.org/10.1002/anie.200351817	Formal synthesis of Leucascandrolide A		Angew. Chem.-Int. Edit.	34	Williams, DR	FALSE	FALSE	FALSE	FALSE
7636	10.1016/S0040-4039(02)00863-8	doi.org/10.1016/S0040-4039(02)00863-8	Platinum-catalyzed cross-couplings of organoboronic acids with aryl iodides		Tetrahedron Lett.	34	Oh, CH	FALSE	FALSE	FALSE	FALSE
7637	10.1016/S0957-4166(01)00199-9	doi.org/10.1016/S0957-4166(01)00199-9	1,1 '-binaphthylazepine-based ligands for asymmetric catalysis. Part 1: Preparation and characterization of some new aminoalcohols and diamines		Tetrahedron-Asymmetry	34	Rosini, C	FALSE	FALSE	FALSE	FALSE
7638	10.1021/jo981745e	doi.org/10.1021/jo981745e	Stereoselective chelate-controlled addition of Grignard reagents to unsaturated medium-ring heterocycles		J. Org. Chem.	34	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
7639	10.1016/S0040-4039(98)01882-6	doi.org/10.1016/S0040-4039(98)01882-6	An optimized palladium catalyzed cross-coupling of nonracemic trifluoromethylsulfonyl and fluorosulfonyl enol ethers to arylboronic acids		Tetrahedron Lett.	34	Pridgen, LN	FALSE	FALSE	FALSE	FALSE
7640	10.1021/ja964391m	doi.org/10.1021/ja964391m	Nickel-catalyzed amination of aryl chlorides		J. Am. Chem. Soc.	34		FALSE	FALSE	FALSE	FALSE
7641	10.1080/00304949409458034	doi.org/10.1080/00304949409458034	AN ALTERNATIVE SYNTHESIS OF ARYL AND HETEROARYL BROMIDES FROM ACTIVATED ARYL HYDROXY COMPOUNDS		Org. Prep. Proced. Int.	34	KATRITZKY, AR	FALSE	FALSE	FALSE	FALSE
7642	10.1021/om00018a016	doi.org/10.1021/om00018a016	ENANTIOSELECTIVE NICKEL-CATALYZED GRIGNARD CROSS-COUPLING OF ALLYL ELECTROPHILES - THE INFLUENCE OF THE ALKYL GROUP OF THE GRIGNARD-REAGENT		Organometallics	34		FALSE	FALSE	FALSE	FALSE
7643	10.1021/om00056a007	doi.org/10.1021/om00056a007	ENANTIOSELECTIVE ALLYLATION OF GRIGNARD-REAGENTS WITH NICKEL DIPHOSPHINE CATALYSTS		Organometallics	34	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
7644	10.1016/0040-4039(90)80227-D	doi.org/10.1016/0040-4039(90)80227-D	PALLADIUM CATALYZED CROSS-COUPLING OF PHENOL TRIFLATES WITH ORGANOSTANNANES - A VERSATILE APPROACH FOR THE SYNTHESIS OF SUBSTITUTED RESORCINOL DIMETHYL ETHERS		Tetrahedron Lett.	34		FALSE	FALSE	FALSE	FALSE
7645	10.1021/ja00185a051	doi.org/10.1021/ja00185a051	NICKEL-CATALYZED CROSS-COUPLINGS OF ALKENYL AND ALPHA-METALATED ALKENYL SULFOXIMINES WITH ORGANOMETALLICS - STEREOSELECTIVE SYNTHESIS OF CARBACYCLINS		J. Am. Chem. Soc.	34		FALSE	FALSE	FALSE	FALSE
7646	10.1021/jacs.1c10042	doi.org/10.1021/jacs.1c10042	Three-Component Coupling of Acyl Fluorides, Silyl Enol Ethers, and Alkynes by P(III)/P(V) Catalysis		J. Am. Chem. Soc.	34	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7647	10.1016/j.jorganchem.2021.122073	doi.org/10.1016/j.jorganchem.2021.122073	Recyclable heterogeneous iron supported on imidazolium ionic liquid catalysed palladium and copper-free Heck reaction		J. Organomet. Chem.	34	Parasuraman, K	FALSE	FALSE	FALSE	FALSE
7648	10.1016/j.jorganchem.2021.122068	doi.org/10.1016/j.jorganchem.2021.122068	New Nickel-Based Catalytic System with Pincer Pyrrole-Functionalized N-Heterocyclic Carbene as Ligand for Suzuki-Miyaura Cross-Coupling Reactions		J. Organomet. Chem.	34	Lei, XY	FALSE	FALSE	FALSE	FALSE
7649	10.1002/ejoc.202100565	doi.org/10.1002/ejoc.202100565	A Highly Congested Dioxapyrenophane from an Attempted Synthesis of the Highly-Strained 1,1,6,6-Tetramethyl[6](2,11)teropyrenophane		Eur. J. Org. Chem.	34	Bodwell, GJ	FALSE	FALSE	FALSE	FALSE
7650	10.1016/j.tetlet.2021.153129	doi.org/10.1016/j.tetlet.2021.153129	Ni-catalyzed cross-electrophile coupling of alpha-hydroxy carbonyl compound-derived oxalates with vinyl triflates		Tetrahedron Lett.	34	Yao, K; Xue, WC	FALSE	FALSE	FALSE	FALSE
7651	10.1055/s-0040-1720474	doi.org/10.1055/s-0040-1720474	Copper-Catalyzed Alkynylation of Benzylic C-H Bonds with Alkynylboronic Esters		Synlett	34	Kramer, S	FALSE	FALSE	FALSE	FALSE
7652	10.1016/j.tet.2021.132034	doi.org/10.1016/j.tet.2021.132034	Regioselection in the synthesis of 4-benzyltetral-1-ones and the new 4-arylbenzosuber-1-ones		Tetrahedron	34	Thompson, PE	FALSE	FALSE	FALSE	FALSE
7653	10.1002/chem.201703239	doi.org/10.1002/chem.201703239	Catalytic Asymmetric Total Synthesis and Stereochemical Revision of Leucinostatin A: A Modulator of Tumor-Stroma Interaction		Chem.-Eur. J.	34	Watanabe, T; Shibasaki, M	FALSE	FALSE	FALSE	FALSE
7654	10.1038/NCHEM.2741	doi.org/10.1038/NCHEM.2741	Parameterization of phosphine ligands demonstrates enhancement of nickel catalysis via remote steric effects		Nat. Chem.	34	Doyle, AG	FALSE	FALSE	FALSE	FALSE
7655	10.1021/acscatal.7b00757	doi.org/10.1021/acscatal.7b00757	Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis		ACS Catal.	34	Toste, FD	FALSE	FALSE	FALSE	FALSE
7656	10.1039/c6dt04533b	doi.org/10.1039/c6dt04533b	Fundamental organometallic chemistry under bimetallic influence: driving beta-hydride elimination and diverting migratory insertion at Cu and Ni		Dalton Trans.	34	Mankad, NP	FALSE	FALSE	FALSE	FALSE
7657	10.1016/j.cclet.2016.09.006	doi.org/10.1016/j.cclet.2016.09.006	Efficient N-heterocyclic carbene nickel pincer complexes catalyzed cross coupling of benzylic ammonium salts with boronic acids		Chin. Chem. Lett.	34	Tu, T	FALSE	FALSE	FALSE	FALSE
7658	10.1021/jacs.6b12911	doi.org/10.1021/jacs.6b12911	Nucleophilic Deoxyfluorination of Phenols via Aryl Fluorosulfonate Intermediates		J. Am. Chem. Soc.	34	Sanford, MS	FALSE	FALSE	FALSE	FALSE
7659	10.1021/jacs.6b09533	doi.org/10.1021/jacs.6b09533	Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp(3)-sp(2) Cross-Coupling of Oxalates with Aryl Halides		J. Am. Chem. Soc.	34	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
7660	10.1021/acs.orglett.6b02094	doi.org/10.1021/acs.orglett.6b02094	Catalyst-Free and Regioconvergent Substitution Reactions of Bromothiophenes with a BH3-Substituted Phosphide Anion		Org. Lett.	34	Imamoto, T	FALSE	FALSE	FALSE	FALSE
7661	10.1039/d1cc00203a	doi.org/10.1039/d1cc00203a	On the mechanism of the formation of alkyl-Ni(i) catalysts	Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.	Chem. Commun.	33	Cardenas, DJ	FALSE	FALSE	FALSE	FALSE
7662	10.1021/acs.orglett.0c03836	doi.org/10.1021/acs.orglett.0c03836	Nickel-Catalyzed Amination of Aryl Chlorides with Amides	Palladium-catalyzed cross-coupling reaction of 4-trifloxy-quinolin-2(1H)-ones or 4-chlorocoumarins with polyfluoroarenes has been successfully developed. Under mild conditions, the reactions afforded 4-polyfluoroarylquinolin-2(1H)-ones and 4-polyfluoroarylcoumarins, which feature a wide range of bioactive compounds, with good yields.	Org. Lett.	33	Tu, B; Tu, T	FALSE	FALSE	FALSE	FALSE
7663	10.1134/S1023193521020075	doi.org/10.1134/S1023193521020075	Electrochemical Generation of Pyrazolyl-Pyridyl N-Heterocyclic Carbene Complexes of Nickel	A DCP promoted metal-free, regio and stereoselective S-methylation/phenylation of allyl halides using sulfoxides as sulfenylating agent is described. A variety of multifunctional allyl halides underwent S-methylation and S-phenylation by using dimethyl sulfoxide (DMSO) and diphenyl sulfoxide (DPSO) under the reaction conditions employed to provide the resulting thioethers in good to excellent yields. (C) 2017 Elsevier Ltd. All rights reserved.	Russ. J. Electrochem.	33	Gafurov, ZN	FALSE	TRUE	FALSE	FALSE
7664	10.1039/d0cc05271j	doi.org/10.1039/d0cc05271j	Cut and sew: benzofuran-ring-opening enabled cyclopentenone ring formation	This report describes a method for the deoxyfluorination of phenols with sulfuryl fluoride (SO2F2) and tetramethylammonium fluoride (NMe4F) via aryl fluorosulfonate (ArOFs) intermediates. We first demonstrate that the reaction of ArOFs with NMe4F proceeds under mild conditions (often at room temperature) to afford a broad range of electronically diverse and functional group-rich aryl fluoride products. This transformation was then translated to a one-pot conversion of phenols to aryl fluorides using the combination of SO2F2 and NMe4F. Ab initio calculations suggest that carbon fluorine bond formation proceeds via a concerted transition state rather than a discrete Meisenheimer intermediate.	Chem. Commun.	33	Zhao, JF	FALSE	FALSE	FALSE	FALSE
7665	10.1248/cpb.c20-00196	doi.org/10.1248/cpb.c20-00196	Development of Transition-Metal-Catalysed Cross-Coupling Reactions through Ammonium C-N Bond Cleavage	This review summarizes transformations using copper hydride (Cu-H), boryl copper (Cu-B) or silyl copper (Cu-Si) as active catalyst species. Semihydrogenation, hydroboration, and hydrocarboxylation have been developed using Cu-H as active catalyst species. Preferential reduction of sterically hindered ketones is accompanied by Cu-H species bearing a bowl-shaped phosphine as a crucial ligand. Employing Cu-B species, hydroboration of alkynes and allenes, synthesis of 2-boryl-1,3-butadiene, and borylative allyl-allyl coupling are established. Silacarboxylation of alkynes, regiodivergent silacarboxylation of allenes, and silylative allylation of ketones involve Cu-Si species. The key to these selective transformations is regioselective addition of Cu-H, Cu-B, or Cu-Si species to carbon-carbon multiple bonds of alkynes and allenes to afford the corresponding alkenylcopper or allylcopper intermediates.	Chem. Pharm. Bull.	33	Wang, C	FALSE	FALSE	FALSE	FALSE
7666	10.1039/d0cc02058c	doi.org/10.1039/d0cc02058c	Organocatalytic enantioselective allylic alkylation of alpha-aryl gamma-lactones: an approach to densely functionalized quaternary stereocentres	An enantioselective copper-catalyzed propargylic etherification of both aromatic and aliphatic propargylic esters with phenols has been developed, in which the employment of inorganic base additives, in particular cesium carbonate (Cs2CO3), was found to significantly promote not only the reactivity but also the enantioselectivity of the reaction. By using a structurally hindered chiral ketimine P,N,N-ligand, a wide range of optically active propargylic ethers were prepared in high yields and with excellent enantioselectivities (up to 98% ee).	Chem. Commun.	33	Riguet, E	FALSE	FALSE	FALSE	FALSE
7667	10.1021/acs.joc.0c00549	doi.org/10.1021/acs.joc.0c00549	Nickel-Catalyzed Cross-Electrophile Reductive Couplings of Neopentyl Bromides with Aryl Bromides	In this study, nickel-catalyzed coupling reactions between arylhalides and tert-alkyl Grignard reagents were developed. Our original bicyclic NHC ligands reduced the formation of isomerized products, and we found that NMP as a co-solvent suppressed the reduction process. Under the optimal conditions we developed, the catalyst loading was lowered to 0.5 mol %, and catalyst loading using ortho-substituted aryl bromides was also applicable at the level of 2.0 mol %. (C) 2016 Elsevier Ltd. All rights reserved.	J. Org. Chem.	33	Qu, B; Desrosiers, JN	FALSE	TRUE	FALSE	FALSE
7668	10.1007/s10562-019-02966-6	doi.org/10.1007/s10562-019-02966-6	Nickel-Catalyzed Esterification of Amides Under Mild Conditions	An interesting nanotube based nickel nanocatalyst was successfully prepared through click reaction of azide-functionalized nanotube with propargyl alcohol followed by immobilization of nickel nanoparticles. The as-prepared nanocatalysts behave as very efficient heterogeneous catalysts in the Suzuki-Miyaura cross coupling reaction in terms of activity and recyclability.	Catal. Lett.	33	Wang, JW	FALSE	FALSE	FALSE	FALSE
7669	10.1002/jhet.3918	doi.org/10.1002/jhet.3918	A catalytic synthesis of dihydrofuran-3(2H)-imine skeletons from isocyanides, terminal alkynes, and oxiranes	The first effective and simple method for the direct one-pot transformation of 2-, 3-, and 4-aminopyridines, 2,6-diaminopyridines, and 2-aminoquinoline into the corresponding pyridinyl and quinolinyl trifluoromethanesulfonates and tosylates in solvents was developed. The procedure involves diazotization of the heterocyclic amines with sodium nitrite in mixed hexane-DMSO or hexane-DMF solutions in the presence of trifluoromethanesulfonic acid or p-toluenesulfonic acid.	J. Heterocycl. Chem.	33	Samzadeh-Kermani, A	FALSE	FALSE	FALSE	FALSE
7670	10.1016/j.jorganchem.2019.120943	doi.org/10.1016/j.jorganchem.2019.120943	Concise access to aluminum containing [3.3](2,6)pyridinophane and molecular bowl using 2,6-diamidopyridine modules		J. Organomet. Chem.	33	Singh, S	FALSE	FALSE	FALSE	FALSE
7671	10.1021/acs.orglett.9b02923	doi.org/10.1021/acs.orglett.9b02923	Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Alkenylaluminum Reagents		Org. Lett.	33	Wu, XF	FALSE	FALSE	FALSE	FALSE
7672	10.1021/acscatal.9b02760	doi.org/10.1021/acscatal.9b02760	Well-Designed N-Heterocyclic Carbene Ligands for Palladium-Catalyzed Denitrative C-N Coupling of Nitroarenes with Amines		ACS Catal.	33	Chen, WZ	FALSE	FALSE	FALSE	FALSE
7673	10.1021/acs.orglett.9b01645	doi.org/10.1021/acs.orglett.9b01645	N-Heterocyclic Carbene Ligand-Controlled Regioselectivity for Nickel-Catalyzed Hydroarylation of Vinylarenes with Benzothiazoles		Org. Lett.	33	Sun, HM	FALSE	FALSE	FALSE	FALSE
7674	10.1002/anie.201900095	doi.org/10.1002/anie.201900095	PAd2-DalPhos Enables the Nickel-Catalyzed C-N Cross-Coupling of Primary Heteroarylamines and (Hetero)aryl Chlorides		Angew. Chem.-Int. Edit.	33	Stradiotto, M	FALSE	FALSE	FALSE	FALSE
7675	10.1038/s41586-018-0628-7	doi.org/10.1038/s41586-018-0628-7	Base-free nickel-catalysed decarbonylative Suzuki-Miyaura coupling of acid fluorides		Nature	33	Sanford, MS	FALSE	FALSE	FALSE	FALSE
7676	10.1039/c8gc00860d	doi.org/10.1039/c8gc00860d	Towards environmentally friendlier Suzuki-Miyaura reactions with precursors of Pd-NHC (NHC = N-heterocyclic carbene) complexes		Green Chem.	33	Nahra, F; Nolan, SP; Cazin, CSJ	FALSE	FALSE	FALSE	FALSE
7677	10.1021/jacs.8b06228	doi.org/10.1021/jacs.8b06228	Total Synthesis of Salimabromide: A Tetracyclic Polyketide from a Marine Myxobacterium		J. Am. Chem. Soc.	33	Magauer, T	FALSE	FALSE	FALSE	FALSE
7678	10.1021/acs.orglett.8b01520	doi.org/10.1021/acs.orglett.8b01520	Sulfonamide Synthesis via Calcium Triflimide Activation of Sulfonyl Fluorides		Org. Lett.	33	Ende, CWA	FALSE	FALSE	FALSE	FALSE
7679	10.1016/j.jorganchem.2018.04.022	doi.org/10.1016/j.jorganchem.2018.04.022	Highly effective and recoverable Pd(II) catalyst immobilized on thermally stable Schiff base polymer containing phenol group: Production, characterization and application in Suzuki coupling reactions		J. Organomet. Chem.	33	Baran, NY	FALSE	FALSE	FALSE	FALSE
7680	10.1016/j.tetlet.2018.04.076	doi.org/10.1016/j.tetlet.2018.04.076	Synthesis of substituted phenols via 1,1-dichloro-2-nitroethene promoted condensation of carbonyl compounds with DMF		Tetrahedron Lett.	33	Li, Z	FALSE	FALSE	FALSE	FALSE
7681	10.1055/s-0036-1589093	doi.org/10.1055/s-0036-1589093	Rhodium-Catalyzed Reductive Cleavage of Aryl Carbamates Using Isopropanol as a Reductant		Synlett	33	Chatani, N; Tobisu, M	FALSE	FALSE	FALSE	FALSE
7682	10.1002/asia.201701303	doi.org/10.1002/asia.201701303	Synthesis, Characterization and Catalytic Application of Pyridine-Bridged N-Heterocyclic Carbene-Ruthenium Complexes in the Hydrogenation of Carbonates		Chem.-Asian J.	33	Tu, T	FALSE	FALSE	FALSE	FALSE
7683	10.3762/bjoc.11.235	doi.org/10.3762/bjoc.11.235	Half-sandwich nickel(II) complexes bearing 1,3-di(cycloalkyl)imidazol-2-ylidene ligands		Beilstein J. Org. Chem.	33	Nelson, DJ	FALSE	FALSE	FALSE	FALSE
7684	10.1021/jacs.5b06735	doi.org/10.1021/jacs.5b06735	Synthesis of 2-Nickela(II)oxetanes from Nickel(0) and Epoxides: Structure, Reactivity, and a New Mechanism of Formation		J. Am. Chem. Soc.	33	Love, JA	FALSE	FALSE	FALSE	FALSE
7685	10.1002/anie.201505136	doi.org/10.1002/anie.201505136	Nanonickel-Catalyzed Suzuki-Miyaura Cross-Couplings in Water		Angew. Chem.-Int. Edit.	33	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
7686	10.1021/ol503518h	doi.org/10.1021/ol503518h	Applications of alpha-Phosphonovinyl Tosylates in the Synthesis of alpha-Arylethenylphosphonates via Suzuki-Miyaura Cross-Coupling Reactions		Org. Lett.	33	Fang, YW	FALSE	FALSE	FALSE	FALSE
7687	10.1039/c5ra01187f	doi.org/10.1039/c5ra01187f	Proline-functionalized chitosan-palladium(II) complex, a novel nanocatalyst for C-C bond formation in water		RSC Adv.	33	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
7688	10.1039/c5ob00515a	doi.org/10.1039/c5ob00515a	A transition-metal-free Heck-type reaction between alkenes and alkyl iodides enabled by light in water		Org. Biomol. Chem.	33	Li, CJ	FALSE	FALSE	FALSE	FALSE
7689	10.1016/j.tet.2014.10.061	doi.org/10.1016/j.tet.2014.10.061	A practical nickel-catalyzed reductive alkylation of amidophenyl bromides		Tetrahedron	33	Shen, YH	FALSE	FALSE	FALSE	FALSE
7690	10.1055/s-0034-1378581	doi.org/10.1055/s-0034-1378581	Type 2 Ring-Opening Reactions of Cyclopropanated 7-Oxabenzonorbornadienes under Acid Catalysis		Synlett	33	Tam, W	FALSE	FALSE	FALSE	FALSE
7691	10.1126/science.1253647	doi.org/10.1126/science.1253647	Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis		Science	33	Molander, GA	FALSE	FALSE	FALSE	FALSE
7692	10.1021/ol500902p	doi.org/10.1021/ol500902p	Kinetic Diastereomer Differentiation in Au(III)- and Bi(III)-Catalyzed Benzylic Arylation: Concise and Stereocontrolled Synthesis of 2-Amino-1,1-diarylalkanes		Org. Lett.	33	Hanessian, S	FALSE	FALSE	FALSE	FALSE
7693	10.1021/om5001869	doi.org/10.1021/om5001869	Direct Access to Fluorene by Successive C-O/C-H Bond Activations of 2-Phenylbenzyl Ester		Organometallics	33	Hirano, M	FALSE	FALSE	FALSE	FALSE
7694	10.1007/s11426-013-5024-4	doi.org/10.1007/s11426-013-5024-4	Pd-catalyzed cross-coupling of polyfluoroarenes with cyclic vinyl triflates		Sci. China-Chem.	33	Zhang, XG	FALSE	FALSE	FALSE	FALSE
7695	10.1039/c3ob41546e	doi.org/10.1039/c3ob41546e	Palladium-catalyzed reductive homocoupling of N '-tosyl arylhydrazines		Org. Biomol. Chem.	33	Lu, G	FALSE	FALSE	FALSE	FALSE
7696	10.1055/s-0033-1339643	doi.org/10.1055/s-0033-1339643	Asymmetric Aziridination of Chalcone Promoted by Binaphthalene-Based Chiral Amines		Synlett	33	Page, PCB	FALSE	FALSE	FALSE	FALSE
7697	10.3184/174751913X13726940260318	doi.org/10.3184/174751913X13726940260318	Suzuki cross-coupling of aryl halides with phenylboronic acid catalysed by an amidoxime fibres-nickel(0) complex		J. Chem. Res	33	Tao, TX	FALSE	FALSE	FALSE	FALSE
7698	10.1080/00304948.2013.786568	doi.org/10.1080/00304948.2013.786568	Facile Construction of Biaryls by Homocoupling of Aryl Halides		Org. Prep. Proced. Int.	33	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
7699	10.1016/j.molstruc.2012.12.014	doi.org/10.1016/j.molstruc.2012.12.014	Effect of molecular conformation on spectroscopic properties of symmetrical Schiff bases derived from 1,4-phenylenediamine		J. Mol. Struct.	33	Cao, CZ	FALSE	FALSE	FALSE	FALSE
7700	10.1021/ol303465c	doi.org/10.1021/ol303465c	Distinctive Meta-Directing Group Effect for Iridium-Catalyzed 1,1-Diarylalkene Enantioselective Hydrogenation		Org. Lett.	33	Sigman, MS	FALSE	FALSE	FALSE	FALSE
7701	10.1246/cl.2013.45	doi.org/10.1246/cl.2013.45	Polyarylene Synthesis by Cross-Coupling with HOMSi Reagents		Chem. Lett.	33	Hiyama, T	FALSE	FALSE	FALSE	FALSE
7702	10.1055/s-0032-1316825	doi.org/10.1055/s-0032-1316825	Efficient Multigram Syntheses of Air-Stable, Chiral Primary Phosphine Ligand Precursors via Palladium-Catalyzed Phosphonylation of Aryltriflates		Synthesis	33	Higham, LJ	FALSE	FALSE	FALSE	FALSE
7703	10.1055/s-0032-1317076	doi.org/10.1055/s-0032-1317076	Palladium-Catalyzed One-Pot Cross-Coupling of Phenols Using Nonafluorobutanesulfonyl Fluoride		Synlett	33	Akai, S	FALSE	FALSE	FALSE	FALSE
7704	10.1021/ol3013342	doi.org/10.1021/ol3013342	Nickel-Catalyzed Reductive Coupling of Aryl Halides with Secondary Alkyl Bromides and Allylic Acetate		Org. Lett.	33	Gong, HG	FALSE	FALSE	FALSE	FALSE
7705	10.1021/ol300471a	doi.org/10.1021/ol300471a	Highly Efficient Synthesis of N-Substituted Isoindolinones and Phthalazinones Using Pt Nanowires as Catalysts		Org. Lett.	33	Cao, XQ	FALSE	FALSE	FALSE	FALSE
7706	10.1039/c1ob06404e	doi.org/10.1039/c1ob06404e	Resorcin[4]arene-derived mono-, bis-and tetra-imidazolium salts as ligand precursors for Suzuki-Miyaura cross-coupling		Org. Biomol. Chem.	33	Semeril, D	FALSE	FALSE	FALSE	FALSE
7707	10.1039/c1gc16174a	doi.org/10.1039/c1gc16174a	O-Allylation of phenols with allylic acetates in aqueous media using a magnetically separable catalytic system		Green Chem.	33	Saha, A	FALSE	FALSE	FALSE	FALSE
7708	10.1021/ol2023278	doi.org/10.1021/ol2023278	Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via eta(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization		Org. Lett.	33	Bao, M	FALSE	FALSE	FALSE	FALSE
7709	10.1021/ja206050b	doi.org/10.1021/ja206050b	Enantioselective alpha-Arylation of Carbonyls via Cu(I)-Bisoxazoline Catalysis		J. Am. Chem. Soc.	33	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
7710	10.1246/cl.2011.913	doi.org/10.1246/cl.2011.913	An Improvement of Nickel Catalyst for Cross-coupling Reaction of Arylboronic Acids with Aryl Carbonates by Using a Ferrocenyl Bisphosphine Ligand		Chem. Lett.	33	Kuwano, R	FALSE	FALSE	FALSE	FALSE
7711	10.1134/S1560090411030031	doi.org/10.1134/S1560090411030031	N-Allyl-bis(diphenylphosphino)amide Nickel Dibromide as a Catalyst of the Polymerization of Methyl Methacrylate		Polym. Sci. Ser. B	33	Il'ichev, IS	FALSE	FALSE	FALSE	FALSE
7712	10.1021/ol200098d	doi.org/10.1021/ol200098d	Nickel-Catalyzed Negishi Cross-Coupling Reactions of Secondary Alkylzinc Halides and Aryl Iodides		Org. Lett.	33	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
7713	10.1002/anie.201007598	doi.org/10.1002/anie.201007598	A Nickel-Catalyzed Benzannulation Approach to Aromatic Boronic Esters		Angew. Chem.-Int. Edit.	33	Harrity, JPA	FALSE	FALSE	FALSE	FALSE
7714	10.1080/00397911.2010.488310	doi.org/10.1080/00397911.2010.488310	Zinc-Mediated Tandem-One-Pot Facile Synthesis of 1-(Arylsulfonyl) Aryl/Heteryl Methanes: A Case of C-S Bond Formation		Synth. Commun.	33	Dubey, PK	FALSE	FALSE	FALSE	FALSE
7715	10.1021/ja106943q	doi.org/10.1021/ja106943q	Ni-Catalyzed Reduction of Inert C-O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups		J. Am. Chem. Soc.	33	Martin, R	FALSE	FALSE	FALSE	FALSE
7716	10.1021/ja108074t	doi.org/10.1021/ja108074t	A Multiligand Based Pd Catalyst for C-N Cross-Coupling Reactions		J. Am. Chem. Soc.	33	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
7717	10.1021/ol100720x	doi.org/10.1021/ol100720x	Pd-Catalyzed Cross-Coupling Reactions of Amides and Aryl Mesylates		Org. Lett.	33	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
7718	10.1039/c0dt01083a	doi.org/10.1039/c0dt01083a	A robust hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex: Synthesis and its catalytic application towards Suzuki-Miyaura couplings in aqueous solvents		Dalton Trans.	33	Tu, T	FALSE	FALSE	FALSE	FALSE
7719	10.1021/ol901676f	doi.org/10.1021/ol901676f	Catalytic Asymmetric Alkylation of Substituted Isoflavanones		Org. Lett.	33	Scheidt, KA	FALSE	FALSE	FALSE	FALSE
7720	10.1021/jo900291f	doi.org/10.1021/jo900291f	Nucleophilic Addition onto Methyl-4H-1,4-oxazine-3-carboxylate Moiety: Short Access to 1,4-Diazine Privileged Substructures		J. Org. Chem.	33	Gillaizeau, I	FALSE	FALSE	FALSE	FALSE
7721	10.1021/ja8056503	doi.org/10.1021/ja8056503	Biaryl Construction via Ni-Catalyzed C-O Activation of Phenolic Carboxylates		J. Am. Chem. Soc.	33	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
7722	10.1002/anie.200703874	doi.org/10.1002/anie.200703874	Ligand-dependent mechanistic dichotomy in iron-catalyzed allylic substitutions: sigma-allyl versus pi-allyl mechanism		Angew. Chem.-Int. Edit.	33	Plietker, B	FALSE	FALSE	FALSE	FALSE
7723	10.1016/j.tetlet.2007.08.083	doi.org/10.1016/j.tetlet.2007.08.083	Palladium-catalyzed homocoupling of arenediazonium salts: an operationally simple synthesis of symmetrical biaryls		Tetrahedron Lett.	33	Hanna, JM	FALSE	FALSE	FALSE	FALSE
7724	10.1016/j.tetlet.2006.07.008	doi.org/10.1016/j.tetlet.2006.07.008	Efficient copper-catalyzed coupling of aryl iodides and thiobenzoic acid		Tetrahedron Lett.	33	Sawada, N	FALSE	FALSE	FALSE	FALSE
7725	10.1002/adsc.200606002	doi.org/10.1002/adsc.200606002	Synthesis of novel bisphosphine-containing polymers and their applications as bidentate ligands for nickel(0)-catalyzed cross-coupling reactions		Adv. Synth. Catal.	33	Hu, QS	FALSE	FALSE	FALSE	FALSE
7726	10.1021/jo052369i	doi.org/10.1021/jo052369i	Triphenylphosphine as a ligand for room-temperature Ni(O)-catalyzed cross-coupling reactions of aryl chlorides with arylboronic acids		J. Org. Chem.	33	Hu, QS	FALSE	FALSE	FALSE	FALSE
7727	10.1016/j.jorganchem.2004.10.037	doi.org/10.1016/j.jorganchem.2004.10.037	Transition metal catalyzed cross-coupling of aryl Grignard reagents with aryl fluorides via Pd- or Ni-activation of the C-F bond: an efficient synthesis of unsymmetrical biaryls - application of microwave technology in ligand and catalyst screening		J. Organomet. Chem.	33	Dankwardt, JW	FALSE	FALSE	FALSE	FALSE
7728	10.1002/anie.200462513	doi.org/10.1002/anie.200462513	Catalytic dehydrative allylation of alcohols		Angew. Chem.-Int. Edit.	33	Kitamura, M	FALSE	FALSE	FALSE	FALSE
7729	10.1002/adsc.200390036	doi.org/10.1002/adsc.200390036	Catalytic carbon-fluorine bond activation with monocoordinated nickel-carbene complexes: reduction of fluoroarenes		Adv. Synth. Catal.	33	Fort, Y	FALSE	FALSE	FALSE	FALSE
7730	10.1021/ja0286876	doi.org/10.1021/ja0286876	Unusual reactivity of molecular oxygen with pi-allylnickel(N-heterocyclic carbene) chloride complexes		J. Am. Chem. Soc.	33	Sigman, MS	FALSE	FALSE	FALSE	FALSE
7731	10.1039/b305043b	doi.org/10.1039/b305043b	Synthesis and deprotonation of 2-(pyridyl)phenols and 2-(pyridyl)anilines		Org. Biomol. Chem.	33	Mongin, F	FALSE	FALSE	FALSE	FALSE
7732	10.1021/jo010609y	doi.org/10.1021/jo010609y	Cross [2+2] cycloaddition of bicyclic alkenes with alkynes mediated by cobalt complexes: A facile synthesis of cyclobutene derivatives		J. Org. Chem.	33	Cheng, CH	FALSE	FALSE	FALSE	FALSE
7733	10.1021/jo010691x	doi.org/10.1021/jo010691x	Preparation of enantiomerically pure 2 '-substituted 2-diphenylphosphino-1,1 '-binaphthyls by reductive cleavage of the carbon-phosphorus bond in a borane complex of 2-diphenylphosphino-2 '-diphenylphosphinyl-1,1 '-binaphthyl		J. Org. Chem.	33	Hayashi, T	FALSE	FALSE	FALSE	FALSE
7734	10.1039/b107904b	doi.org/10.1039/b107904b	Kinetic resolution of secondary alcohols via chiral Pd(II)-complex-catalysed enantioselective benzoylation using CO and organobismuth(v) compound		Chem. Commun.	33	Uemura, S	FALSE	FALSE	FALSE	FALSE
7735	10.1016/S0277-5387(01)00934-2	doi.org/10.1016/S0277-5387(01)00934-2	Allyl-palladium compounds with fluorinated benzenethiolate ligands. X-ray crystal structure of [(eta(3)-C3H5)Pd(mu-SC6H4F-4)(2)Pd(eta(3)-C3H5)]		Polyhedron	33	Torrens, H	FALSE	FALSE	FALSE	FALSE
7736	10.1021/ja000134c	doi.org/10.1021/ja000134c	Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: A new enantioselective carbon-heteroatom bond forming process		J. Am. Chem. Soc.	33	Lautens, M	FALSE	FALSE	FALSE	FALSE
7737	10.1021/jo981130h	doi.org/10.1021/jo981130h	Reactivity of organocerium compounds with allyl alcohols		J. Org. Chem.	33	Dalpozzo, R	FALSE	FALSE	FALSE	FALSE
7738	10.1021/jo971771x	doi.org/10.1021/jo971771x	Synthesis of 2-substituted dihydropyran 3-O-carbamates via combined metalation-Suzuki-Miyaura cross-coupling reactions		J. Org. Chem.	33	Snieckus, V	FALSE	FALSE	FALSE	FALSE
7739	10.1016/0304-5102(93)85091-7	doi.org/10.1016/0304-5102(93)85091-7	STEREOCHEMISTRY IN CROSS-COUPLING REACTION OF CROTYL ALCOHOL DERIVATIVES AND ARYLMAGNESIUM BROMIDES ON TRANS-BIS-1S,2S-(DIPHENYLPHOSPHINO)CYCLOPENTANENICKEL AND TRANS-BIS-1R,2R-(DIPHENYLPHOSPHINO)CYCLOPENTANENICKEL DIBROMIDE			33	PAVLOV, VA	FALSE	FALSE	FALSE	FALSE
7740	10.1021/jo00304a032	doi.org/10.1021/jo00304a032	A TANDEM DENITRATION DEOXYGENATION OF ALPHA-NITRO KETONES VIA (PARA-TOLYLSULFONYL)HYDRAZONES WITH LITHIUM ALUMINUM-HYDRIDE - A PRACTICAL SYNTHESIS OF (Z)-9-TRICOSENE, THE SEX-PHEROMONE OF THE HOUSEFLY (MUSCA-DOMESTICA)		J. Org. Chem.	33	BALLINI, R	FALSE	FALSE	FALSE	FALSE
7741	10.1016/S0040-4039(00)97858-4	doi.org/10.1016/S0040-4039(00)97858-4	EVALUATION OF A CHIRAL ARYL AUXILIARY DESIGN FOR SULFUR - CONSTRUCTION OF AUXILIARY-MODIFIED REAGENTS AND STEREOSELECTION IN SULFOXIDE FORMATION		Tetrahedron Lett.	33	SWINDELL, CS	FALSE	FALSE	FALSE	FALSE
7742	10.1039/dt9890000161	doi.org/10.1039/dt9890000161	SYNTHESIS AND STEREOCHEMICAL STUDIES OF ETA-3-ALLYL PALLADIUM(II) COMPLEXES CONTAINING A CHIRAL CHELATING LIGAND		J. Chem. Soc.-Dalton Trans.	33		FALSE	FALSE	FALSE	FALSE
7743	10.1016/S0040-4020(01)86177-9	doi.org/10.1016/S0040-4020(01)86177-9	KINETIC RESOLUTION OF EPOXIDES BY CHIRAL ORGANO-ALUMINUM CATALYST SHORT SYNTHESIS OF (-)-C-16 JUVENILE-HORMONE		Tetrahedron	33		FALSE	FALSE	FALSE	FALSE
7744	10.1021/om00072a023	doi.org/10.1021/om00072a023	UNCATALYZED AND LOW-VALENT NICKEL-ASSISTED REACTIONS OF ALPHA,BETA-UNSATURATED ALDEHYDE DIMETHYL ACETALS WITH GRIGNARD-REAGENTS		Organometallics	33		FALSE	FALSE	FALSE	FALSE
7745	10.1039/d2cc00141a	doi.org/10.1039/d2cc00141a	Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes		Chem. Commun.	33	Casares, JA; Espinet, P	FALSE	FALSE	FALSE	FALSE
7746	10.1021/acs.orglett.1c03849	doi.org/10.1021/acs.orglett.1c03849	Synthesis of 2-Hydroxy-2 '-aroyl-1,1 '-biaryls via Oxidative Ring-Opening of 9H-Fluoren-9-ols		Org. Lett.	33	Gu, ZH	FALSE	FALSE	FALSE	FALSE
7747	10.3762/bjoc.17.167	doi.org/10.3762/bjoc.17.167	Direct C(sp(3))-H allylation of 2-alkylpyridines with Morita-Baylis-Hillman carbonates via a tandem nucleophilic substitution/aza-Cope rearrangement		Beilstein J. Org. Chem.	33	Zheng, LY; Xiang, JB	FALSE	FALSE	FALSE	FALSE
7748	10.1055/a-1608-5069	doi.org/10.1055/a-1608-5069	Transition-Metal-Catalyzed Hydroxylation Reaction of Aryl Halide for the Synthesis of Phenols		Synlett	33	Xue, D	FALSE	FALSE	FALSE	FALSE
7749	10.3390/catal11070858	doi.org/10.3390/catal11070858	Direct Cross-Coupling of Alcohols with O-Nucleophiles Mediated by N-Iodosuccinimide as a Precatalyst under Mild Reaction Conditions		Catalysts	33	Ajvazi, N	FALSE	FALSE	FALSE	FALSE
7750	10.1177/17475198211026479	doi.org/10.1177/17475198211026479	Organozinc-mediated direct cross-coupling under microwave irradiation		J. Chem. Res	33	Li, CJ	FALSE	FALSE	FALSE	FALSE
7751	10.1002/anie.202102233	doi.org/10.1002/anie.202102233	Enantio- and Regioconvergent Nickel-Catalyzed C(sp(3))-C(sp(3)) Cross-Coupling of Allylic Electrophiles Steered by a Silyl Group		Angew. Chem.-Int. Edit.	33	Oestreich, M	FALSE	TRUE	FALSE	FALSE
7752	10.1021/acs.orglett.1c01053	doi.org/10.1021/acs.orglett.1c01053	Nickel-Catalyzed Ring-Opening C-O Functionalization of peri-Xanthenoxanthenes for 8-Substituted Binaphthol Synthesis		Org. Lett.	33	Kamei, T	FALSE	FALSE	FALSE	FALSE
7753	10.1039/d1dt01206a	doi.org/10.1039/d1dt01206a	Unusual mechanism of paramagnetic nickel-catalysed alpha-alkylation of amides		Dalton Trans.	33	Zhao, CY	FALSE	FALSE	FALSE	FALSE
7754	10.1016/j.jorganchem.2017.02.004	doi.org/10.1016/j.jorganchem.2017.02.004	Direct use of CO2 for O-arylcarbamate synthesis via mild Cu(II)-catalyzed aerobic C-H functionalization in pincer-like macrocyclic systems		J. Organomet. Chem.	33	Company, A; Ribas, X	FALSE	FALSE	FALSE	FALSE
7755	10.1021/jacs.7b07983	doi.org/10.1021/jacs.7b07983	Cobalt-Catalyzed Carbonylative Cross-Coupling of Alkyl Tosylates and Dienes: Stereospecific Synthesis of Dienones at Low Pressure		J. Am. Chem. Soc.	33	Alexanian, EJ	FALSE	FALSE	FALSE	FALSE
7756	10.1021/acs.joc.6b03037	doi.org/10.1021/acs.joc.6b03037	Dehydrogenative Formation of Resorcinol Derivatives Using Pd/C-Ethylene Catalytic System		J. Org. Chem.	33	Hayashi, M	FALSE	FALSE	FALSE	FALSE
7757	10.1248/yakushi.15-00294	doi.org/10.1248/yakushi.15-00294	Reaction Development on pi- and sigma-Conjugated Bonds and Creation of Innovative Functions		Yakugaku Zasshi-J. Pharm. Soc. Jpn.	33	Takita, R	FALSE	FALSE	FALSE	FALSE
7758	10.1016/j.carres.2016.03.021	doi.org/10.1016/j.carres.2016.03.021	Improvement of the stereoselectivity of the glycosylation reaction with 2-azido-2-deoxy-1-thioglucoside donors		Carbohydr. Res.	33	Ventura, MR	FALSE	FALSE	FALSE	FALSE
7759	10.1021/acs.joc.5b02562	doi.org/10.1021/acs.joc.5b02562	Mild and Site-Selective Allylation of Enol Carbamates with Allylic Carbonates under Rhodium Catalysis		J. Org. Chem.	33	Kim, IS	FALSE	FALSE	FALSE	FALSE
7760	10.1016/j.catcom.2020.106175	doi.org/10.1016/j.catcom.2020.106175	CuO-catalyzed conversion of arylacetic acids into aromatic nitriles with K4Fe(CN)(6) as the nitrogen source	Two families of nickel complexes bearing chelating diphenylphosphine-functionalized NHC ligands [Ni-II(ArNHCPPh2)(allyl)]Cl 1a (Ar = Mes); 1b, (Ar = 2,6-iPr(2)-C6H3) and [Ni-0(ArNHCPPh2)(alkene)] 2a (Ar = 2,6-iPr(2)-C6H3, alkene = styrene); 2b (Ar = 2,6-iPr(2-) C6H3, alkene = diethyl fumarate) have been prepared and fully characterized. VT-NMR experiments in solution reveal that the allyl derivatives 1a-b are stereo-chemically nonrigid. The solid-state structure of the Ni-0 derivative 2b is also reported. These complexes display interesting catalytic properties in various cross-coupling reactions. The precatalyst [Ni-0(ArNHCPPh2)(styrene)] 2a was found to be the most active system. The bulkiness of the N-substituent on the imidazole ring and the low oxidation state of the metal center in 2a accounted for its enhanced catalytic performance. This system catalyzed effectively the coupling of (hetero)aryl chlorides with a range of nucleophiles including Grignard reagents, boronic acids, secondary amines and indoles.	Catal. Commun.	32	Tian, XZ; Ren, YL	FALSE	FALSE	FALSE	FALSE
7761	10.1021/acs.joc.0c02157	doi.org/10.1021/acs.joc.0c02157	Rh-Catalyzed Base-Free Decarbonylative Borylation of Twisted Amides	The direct addition of pyridine and diazine units to electron-poor alkenes has been achieved via a redox radical mechanism that is enabled by limiting the effective concentration of the hydrogen-atom source. The described method is tolerant of acidic functional groups and is generally applicable to the union of a wide range of Michael acceptors and 6-membered heterocyclic halides.	J. Org. Chem.	32	Liu, XJ	FALSE	FALSE	FALSE	FALSE
7762	10.1016/j.tetlet.2020.152123	doi.org/10.1016/j.tetlet.2020.152123	Proton-exchanged montmorillonite-mediated reactions of hetero-benzyl acetates: Application to the synthesis of Zafirlukast		Tetrahedron Lett.	32	Feng, LL; Li, F; Chen, DY	FALSE	FALSE	FALSE	FALSE
7763	10.1039/d0ob00406e	doi.org/10.1039/d0ob00406e	A one-pot protocol for the fluorosulfonation and Suzuki coupling of phenols and bromophenols, streamlined access to biaryls and terphenyls	Efficient asymmetric Suzuki-Miyaura coupling of ortho-bromo aryl triflates with various arylboronic acids were described, providing a series of chiral biaryl triflates in high yields and up to 91% ee under mild conditions. The aryl triflates could be easily transformed to various chiral biaryl products by further derivatization. A one-pot tandem asymmetric cross-coupling/cross-coupling sequence was also achieved by using a single palladium catalyst, demonstrating the versatility of this method for preparation of chiral biaryl products. (C) 2015 Elsevier Ltd. All rights reserved.	Org. Biomol. Chem.	32	Li, XM; Yuan, ZL	FALSE	FALSE	FALSE	FALSE
7764	10.1021/acs.jmedchem.9b01979	doi.org/10.1021/acs.jmedchem.9b01979	Discovery of Novel Allosteric Inhibitors of Deoxyhypusine Synthase	We report an efficient copper(I) iodide catalyzed cross-coupling of diarylzinc reagents with aryl iodides. The reaction proceeds under ligand-free conditions at low catalyst loading (5 mol%) and tolerates a variety of functional groups.	J. Med. Chem.	32	Tanaka, Y	FALSE	FALSE	FALSE	FALSE
7765	10.1055/s-0039-1690010	doi.org/10.1055/s-0039-1690010	Leaving Group Ability in Nucleophilic Aromatic Amination by Sodium Hydride-Lithium Iodide Composite		Synthesis	32	Chiba, S	FALSE	FALSE	FALSE	FALSE
7766	10.1002/chem.201904717	doi.org/10.1002/chem.201904717	A Hydroperoxide-Mediated Decarboxylation of alpha-Ketoacids Enables the Chemoselective Acylation of Amines		Chem.-Eur. J.	32	Takemoto, Y	FALSE	FALSE	FALSE	FALSE
7767	10.1016/j.tetlet.2019.150955	doi.org/10.1016/j.tetlet.2019.150955	In(OTf)(3) catalyzed reductive etherification of 2-aiyloxybenzaldehydes and 2-(arylthio)benzaldehydes		Tetrahedron Lett.	32	Basak, AK	FALSE	FALSE	FALSE	FALSE
7768	10.1002/ijch.201900071	doi.org/10.1002/ijch.201900071	Stereospecific Cross-Coupling Reactions Provide Conformationally-Biased Arylalkanes with Anti-Leukemia Activity		Isr. J. Chem.	32	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
7769	10.1021/acscatal.9b02316	doi.org/10.1021/acscatal.9b02316	Microballs Containing Ni(0)Pd(0) Nanoparticles for Highly Selective Miceliar Catalysis in Water		ACS Catal.	32	Handa, S	FALSE	FALSE	FALSE	FALSE
7770	10.1002/chir.23085	doi.org/10.1002/chir.23085	Enantioselective synthesis of (R)-Cinacalcet via cobalt-catalysed asymmetric Negishi cross-coupling		Chirality	32	Zhong, JC	FALSE	FALSE	FALSE	FALSE
7771	10.1039/c9cc02319d	doi.org/10.1039/c9cc02319d	Nickel-catalysed dehydrogenative coupling of aromatic diamines with alcohols: selective synthesis of substituted benzimidazoles and quinoxalines		Chem. Commun.	32	Banerjee, D	FALSE	FALSE	FALSE	FALSE
7772	10.1002/hlca.201800242	doi.org/10.1002/hlca.201800242	[2.2.2.2](2,7)-1-Bromonaphthalenophane from a Desymmetrized Building Block Bearing Electrophilic and Masked Nucleophilic Functionalities		Helv. Chim. Acta	32	Tobe, Y	FALSE	TRUE	FALSE	FALSE
7773	10.1021/jacs.8b12801	doi.org/10.1021/jacs.8b12801	Zn-Mediated Fragmentation of Tertiary Alkyl Oxalates Enabling Formation of Alkylated and Arylated Quaternary Carbon Centers		J. Am. Chem. Soc.	32	Gong, HG	FALSE	FALSE	FALSE	FALSE
7774	10.1002/jhet.3375	doi.org/10.1002/jhet.3375	A Facile Synthesis of Novel (Z)-ethyl-3-(5-substituted-1-alkyl/aryl-1H-indol-3-yl)-2-(1H-tetrazol-5-yl)acrylate		J. Heterocycl. Chem.	32	Bakkolla, MG	FALSE	FALSE	FALSE	FALSE
7775	10.1002/slct.201802120	doi.org/10.1002/slct.201802120	Palladium-Catalyzed Ligand-Free Suzuki-Miyaura Reaction of Aryl Fluorosulfates and Various Arylboron Compounds		ChemistrySelect	32	Li, XM; Yuan, ZL	FALSE	FALSE	FALSE	FALSE
7776	10.1039/c8qo00632f	doi.org/10.1039/c8qo00632f	Striving to exploit alkyl electrophiles: challenge and choice in transition metal-catalyzed cross-coupling reactions of sulfones		Org. Chem. Front.	32	Qiu, GYS	FALSE	FALSE	FALSE	FALSE
7777	10.1055/s-0037-1610024	doi.org/10.1055/s-0037-1610024	Selective Preparation of C-2v-Symmetric Hexaphenylbenzene Derivatives through Sequential Suzuki Coupling		Synlett	32	Kojima, T; Hiraoka, S	FALSE	FALSE	FALSE	FALSE
7778	10.1021/acs.joc.8b00882	doi.org/10.1021/acs.joc.8b00882	Synthesis of (+)-Vitepyrroloid A and (+)-Vitepyrroloid B by Late-Stage Ni-Catalyzed C(sp2)-C(sp3) Cross-Electrophile Coupling		J. Org. Chem.	32	Christmann, M	FALSE	TRUE	FALSE	FALSE
7779	10.1021/acs.orglett.8b01305	doi.org/10.1021/acs.orglett.8b01305	Manganese-Catalyzed Direct Conversion of Ester to Amide with Liberation of H-2		Org. Lett.	32	Balaraman, E	FALSE	FALSE	FALSE	FALSE
7780	10.1021/acs.orglett.8b00313	doi.org/10.1021/acs.orglett.8b00313	Nickel-Catalyzed System for the Cross-Coupling of Alkenyl Methyl Ethers with Grignard Reagents under Mild Conditions		Org. Lett.	32	Cossy, J	FALSE	FALSE	FALSE	FALSE
7781	10.1021/jacs.7b13601	doi.org/10.1021/jacs.7b13601	Multimetallic Ni- and Pd-Catalyzed Cross-Electrophile Coupling To Form Highly Substituted 1,3-Dienes		J. Am. Chem. Soc.	32	Weix, DJ	FALSE	TRUE	FALSE	FALSE
7782	10.1039/c7cc07332a	doi.org/10.1039/c7cc07332a	Radical halogenation-mediated latent-active glycosylations of allyl glycosides		Chem. Commun.	32	Jayaraman, N	FALSE	FALSE	FALSE	FALSE
7783	10.1021/acs.organomet.7b00726	doi.org/10.1021/acs.organomet.7b00726	Cobalt-Catalyzed Cross-Coupling Reactions of Arylboronic Esters and Aryl Halides		Organometallics	32	Duong, HA	FALSE	FALSE	FALSE	FALSE
7784	10.1039/c6ra02989b	doi.org/10.1039/c6ra02989b	Nickel(II)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for Heck and Henry reactions		RSC Adv.	32	Karabach, YY; Martins, LMDRS; Pombeiro, AJL	FALSE	FALSE	FALSE	FALSE
7785	10.1021/acs.orglett.5b01913	doi.org/10.1021/acs.orglett.5b01913	Beyond Directed ortho Metalation: Ruthenium-Catalyzed Amide-Directed C-Ar-OMe Activation/Cross-Coupling Reaction of Naphthamides with Aryl Boronates		Org. Lett.	32	Snieckus, V	FALSE	FALSE	FALSE	FALSE
7786	10.1021/acs.orglett.5b01283	doi.org/10.1021/acs.orglett.5b01283	Aminocarbonylation of Aryl Tosylates to Carboxamides		Org. Lett.	32	Chung, S	FALSE	FALSE	FALSE	FALSE
7787	10.1016/j.tetasy.2015.03.008	doi.org/10.1016/j.tetasy.2015.03.008	An oxazaborolidine-based catalytic method for the asymmetric synthesis of chiral allylic alcohols		Tetrahedron-Asymmetry	32	Yildiz, T	FALSE	FALSE	FALSE	FALSE
7788	10.6023/cjoc201408028	doi.org/10.6023/cjoc201408028	Synthesis of a Carbene Complex and Its Application in Suzuki Reaction		Chin. J. Org. Chem.	32	Tang, Y	FALSE	FALSE	FALSE	FALSE
7789	10.1039/c5cc02884a	doi.org/10.1039/c5cc02884a	Unexpected lateral-lithiation-induced alkylative ring opening of tetrahydrofurans in deep eutectic solvents: synthesis of functionalised primary alcohols		Chem. Commun.	32	Capriati, V	FALSE	FALSE	FALSE	FALSE
7790	10.1126/science.1259662	doi.org/10.1126/science.1259662	Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation		Science	32	Mulvey, RE	FALSE	FALSE	FALSE	FALSE
7791	10.1016/j.tetasy.2014.06.019	doi.org/10.1016/j.tetasy.2014.06.019	Asymmetric Henry reactions catalyzed by copper(II) complexes of chiral 1,2,4-triazine-oxazoline ligands: the impact of substitution in the oxazoline ring on ligand activity		Tetrahedron-Asymmetry	32	Wolinska, E	FALSE	FALSE	FALSE	FALSE
7792	10.1021/sc5002287	doi.org/10.1021/sc5002287	Cyclic Carbonates as Green Alternative Solvents for the Heck Reaction		ACS Sustain. Chem. Eng.	32	Hunt, AJ	FALSE	FALSE	FALSE	FALSE
7793	10.1021/jo402526z	doi.org/10.1021/jo402526z	Metal-Free Coupling of Saturated Heterocyclic Sulfonylhydrazones with Boronic Acids		J. Org. Chem.	32	Allwood, DM	FALSE	FALSE	FALSE	FALSE
7794	10.1039/c4cc04743e	doi.org/10.1039/c4cc04743e	Tunable reversible metallo-hydrogels: a new platform for visual discrimination of biothiols		Chem. Commun.	32	Tu, T	FALSE	FALSE	FALSE	FALSE
7795	10.1039/c4cc00959b	doi.org/10.1039/c4cc00959b	From acetone metalation to the catalytic alpha-arylation of acyclic ketones with NHC-nickel(II) complexes		Chem. Commun.	32	Chetcuti, MJ	FALSE	FALSE	FALSE	FALSE
7796	10.1039/c4cc05151c	doi.org/10.1039/c4cc05151c	Synthesis of 2-phenylnaphthalenes from styryl-2-methoxybenzenes		Chem. Commun.	32	Vishwakarma, RA	FALSE	FALSE	FALSE	FALSE
7797	10.1039/c4ob01979b	doi.org/10.1039/c4ob01979b	Palladium-catalyzed coupling of N-tosylhydrazones and beta-bromostyrene derivatives: new approach to 2H-chromenes		Org. Biomol. Chem.	32	Wang, JB	FALSE	FALSE	FALSE	FALSE
7798	10.1021/ol4029447	doi.org/10.1021/ol4029447	Two-Component, Three-Molecule Reactions between 2,3-Dihydroinden-1-ones and Aryl Chlorides Catalyzed by an N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex		Org. Lett.	32	Shao, LX	FALSE	FALSE	FALSE	FALSE
7799	10.1080/10426507.2012.704103	doi.org/10.1080/10426507.2012.704103	Synthesis and Characterization of Homoleptic and Heteroleptic Complexes Involving Dithiocarbamates, Triphenylphosphine, and Nickel(II)		Phosphorus Sulfur Silicon Relat. Elem.	32	Thirumaran, S	FALSE	FALSE	FALSE	FALSE
7800	10.1002/cmdc.201300114	doi.org/10.1002/cmdc.201300114	Synthesis and invitro Evaluation of West Nile Virus Protease Inhibitors Based on the 2-{6-[2-(5-Phenyl-4H-{1,2,4]triazol-3-ylsulfanyl)acetylamino]benzothiazol-2-ylsulfanyl}acetamide Scaffold		ChemMedChem	32	Samanta, S	FALSE	FALSE	FALSE	FALSE
7801	10.6023/cjoc201209008	doi.org/10.6023/cjoc201209008	Base-Free Cu(II)-Catalyzed Coupling Reaction of Arylboronic Acids and Thiols		Chin. J. Org. Chem.	32	Yang, MH	FALSE	FALSE	FALSE	FALSE
7802	10.1039/c2nj40709d	doi.org/10.1039/c2nj40709d	New anellated 4H-1,4,2-diazaphospholes		New J. Chem.	32	Karaghiosoff, K	FALSE	FALSE	FALSE	FALSE
7803	10.1039/c3ra43363c	doi.org/10.1039/c3ra43363c	Nickel catalyzed one pot synthesis of biaryls under air at room temperature		RSC Adv.	32	Bhat, BR	FALSE	FALSE	FALSE	FALSE
7804	10.1002/anie.201208843	doi.org/10.1002/anie.201208843	Nickel-Catalyzed Decarbonylative C-H Coupling Reactions: A Strategy for Preparing Bis(heteroaryl) Backbones		Angew. Chem.-Int. Edit.	32	Martin, R	FALSE	FALSE	FALSE	FALSE
7805	10.1039/c2cc38646a	doi.org/10.1039/c2cc38646a	[F-18]Fluorination of an arylboronic ester using [F-18]selectfluor bis(triflate): application to 6-[F-18]fluoro-L-DOPA		Chem. Commun.	32	Gouverneur, V	FALSE	FALSE	FALSE	FALSE
7806	10.1080/00397911.2011.604896	doi.org/10.1080/00397911.2011.604896	INDIUM-PROMOTED ALLYLATION OF ALKYNES WITH ALLYLIC ALCOHOLS: HIGHLY REGIOSELECTIVE SYNTHESIS OF HALOGEN-SUBSTITUTED 1,4-DIENES		Synth. Commun.	32	Ma, L	FALSE	FALSE	FALSE	FALSE
7807	10.1021/jo301393s	doi.org/10.1021/jo301393s	The Galactosamine Residue in Mycobacterial Arabinogalactan Is alpha-Linked		J. Org. Chem.	32	Lowary, TL	FALSE	FALSE	FALSE	FALSE
7808	10.1055/s-0031-1289747	doi.org/10.1055/s-0031-1289747	Synthesis of Aryl Triolborates via Nickel-Catalyzed Borylation of Aryl Halides with 5-(tert-Butyldimethylsiloxymethyl)-5-methyl-1,3,2-dioxaborinane		Synthesis	32	Murata, M	FALSE	FALSE	FALSE	FALSE
7809	10.1039/c2cc34454h	doi.org/10.1039/c2cc34454h	Hydrogenolysis-hydrogenation of aryl ethers: selectivity pattern		Chem. Commun.	32	Samant, BS	FALSE	FALSE	FALSE	FALSE
7810	10.1039/c2cc31718d	doi.org/10.1039/c2cc31718d	Ni-catalyzed construction of C-P bonds from electron-deficient phenols via the in situ aryl C-O activation by PyBroP		Chem. Commun.	32	Han, FS	FALSE	FALSE	FALSE	FALSE
7811	10.1021/ol201469r	doi.org/10.1021/ol201469r	Cross-Coupling of Mesylated Phenol Derivatives with Potassium Alkoxymethyltrifluoroborates		Org. Lett.	32	Molander, GA	FALSE	FALSE	FALSE	FALSE
7812	10.1016/j.tet.2011.03.066	doi.org/10.1016/j.tet.2011.03.066	Probing the electronic demands of transmetalation in the palladium-catalyzed cross-coupling of arylsilanolates		Tetrahedron	32	Denmark, SE	FALSE	FALSE	FALSE	FALSE
7813	10.1021/ja202769t	doi.org/10.1021/ja202769t	Nickel-Catalyzed Kumada Cross-Coupling Reactions of Tertiary Alkylmagnesium Halides and Aryl Bromides/Triflates		J. Am. Chem. Soc.	32	Biscoe, MR	FALSE	FALSE	FALSE	FALSE
7814	10.1039/c0ob01208d	doi.org/10.1039/c0ob01208d	Palladium-catalyzed tandem reaction to construct benzo[c]phenanthridine: application to the total synthesis of benzo[c]phenanthridine alkaloids		Org. Biomol. Chem.	32	Xu, XH	FALSE	FALSE	FALSE	FALSE
7815	10.1039/c0cc01950j	doi.org/10.1039/c0cc01950j	Desymmetrizations of meso-tert-norbornenols by rhodium(I)-catalyzed enantioselective retro-allylations		Chem. Commun.	32	Cramer, N	FALSE	FALSE	FALSE	FALSE
7816	10.1016/j.molcata.2009.02.003	doi.org/10.1016/j.molcata.2009.02.003	Mild liquid-phase Friedel-Crafts acylation of heteroaromatic compounds over zeolite Beta		J. Mol. Catal. A-Chem.	32	Brigas, AF	FALSE	FALSE	FALSE	FALSE
7817	10.1021/ma802215y	doi.org/10.1021/ma802215y	Synthetic Approaches to Regioregular Unsymmetrical Dialkoxy-Substituted Poly(1,4-phenylene ethynylene)s		Macromolecules	32	Collard, DM	FALSE	FALSE	FALSE	FALSE
7818	10.1039/b911286c	doi.org/10.1039/b911286c	Nickel-catalyzed cross-coupling of diarylamines with haloarenes		Org. Biomol. Chem.	32	Yang, LM	FALSE	FALSE	FALSE	FALSE
7819	10.1016/j.tetlet.2008.04.117	doi.org/10.1016/j.tetlet.2008.04.117	Benzylation of arenes through FeCl3-catalyzed Friedel-Crafts reaction via C-O activation of benzyl ether		Tetrahedron Lett.	32	Zhao, KQ	FALSE	FALSE	FALSE	FALSE
7820	10.1016/j.tetasy.2007.05.026	doi.org/10.1016/j.tetasy.2007.05.026	Asymmetric hydrogenation of aromatic ketones with new P-chirogenic monophosphine ligands		Tetrahedron-Asymmetry	32	Lemaire, M	FALSE	FALSE	FALSE	FALSE
7821	10.1002/pola.21974	doi.org/10.1002/pola.21974	Synthesis and morphological characterization of poly(epsilon-caprolactone) and poly(2-methyloxazoline) substituted phenyl rings and phenylene oligorners		J. Polym. Sci. Pol. Chem.	32	Demirel, AL	FALSE	FALSE	FALSE	FALSE
7822	10.1002/ejic.200601051	doi.org/10.1002/ejic.200601051	Low-valent nickel and palladium complexes with 1,1 '-bis(phosphanyl)ferrocenes: Syntheses and structures of acrylic acid and ethylene complexes		Eur. J. Inorg. Chem.	32	Walther, D	FALSE	FALSE	FALSE	FALSE
7823	10.1021/jo061502j	doi.org/10.1021/jo061502j	Design, synthesis, and properties of conformationally fixed semiquinone monoradical species		J. Org. Chem.	32	Sloop, JC	FALSE	FALSE	FALSE	FALSE
7824	10.1021/ja063934h	doi.org/10.1021/ja063934h	Palladium-catalyzed asymmetric silaboration of allenes		J. Am. Chem. Soc.	32	Suginome, M	FALSE	FALSE	FALSE	FALSE
7825	10.1246/bcsj.79.1248	doi.org/10.1246/bcsj.79.1248	Inclusion properties of 11b-substituted 2,3,5,6,11,11b-hexahydro-3-oxo-1H-indolizino[8,7-b]indole-5-carboxylic acid esters. New chiral host compounds derived from L-tryptophan		Bull. Chem. Soc. Jpn.	32	Irikawa, H	FALSE	FALSE	FALSE	FALSE
7826	10.1021/ja058621l	doi.org/10.1021/ja058621l	Ruthenium-catalyzed isomerization of oxa/azabicyclic alkenes: an expedient route for the synthesis of 1,2-naphthalene oxides and imines		J. Am. Chem. Soc.	32	Tam, W	FALSE	FALSE	FALSE	FALSE
7827	10.1002/anie.200503274	doi.org/10.1002/anie.200503274	A highly regioselective salt-free iron-catalyzed allylic alkylation		Angew. Chem.-Int. Edit.	32	Plietker, B	FALSE	FALSE	FALSE	FALSE
7828	10.1055/s-2005-869856	doi.org/10.1055/s-2005-869856	Microwave irradiation as a high-speed tool for activation of sluggish aryl chlorides in Grignard reactions		Synlett	32	Nilsson, P	FALSE	FALSE	FALSE	FALSE
7829	10.1016/j.poly.2004.12.009	doi.org/10.1016/j.poly.2004.12.009	A new diphosphinite derived from cyclohexane-1,4-diol: oxidation reactions, metal complexes, P-O bond cleavage and X-ray,crystal structures of Ph2P(E)O(C6H10)OP(E)Ph-2 (E = S, Se)		Polyhedron	32	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
7830	10.1021/ja038752r	doi.org/10.1021/ja038752r	Room-temperature Ni(0)-catalyzed cross-coupling reactions of aryl arenesulfonates with arylboronic acids		J. Am. Chem. Soc.	32	Hu, QS	FALSE	FALSE	FALSE	FALSE
7831	10.1002/jlcr.745	doi.org/10.1002/jlcr.745	Synthesis of no-carrier-added [C-11]methanesulfonyl chloride as a new labeling agent for PET radiopharmaceutical development		J. Label. Compd. Radiopharm.	32	McCarron, JA	FALSE	FALSE	FALSE	FALSE
7832	10.1039/b307705e	doi.org/10.1039/b307705e	Palladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate		Chem. Commun.	32	Tsukada, N	FALSE	FALSE	FALSE	FALSE
7833	10.1021/om020814j	doi.org/10.1021/om020814j	Synthesis of diruthenium complexes containing chiral thiolate-bridged ligands and their application to catalytic propargylic alkylation of propargylic alcohols with acetone		Organometallics	32	Uemura, S	FALSE	FALSE	FALSE	FALSE
7834	10.1016/S0040-4039(02)01894-4	doi.org/10.1016/S0040-4039(02)01894-4	Oxidative dimerization: Pd(II) catalysis in the presence of oxygen using aqueous media		Tetrahedron Lett.	32	Jung, KW	FALSE	FALSE	FALSE	FALSE
7835	10.5059/yukigoseikyokaishi.60.434	doi.org/10.5059/yukigoseikyokaishi.60.434	Combinatorial approaches towards organic synthetic catalysts		J. Synth. Org. Chem. Jpn.	32	Uozumi, Y	FALSE	FALSE	FALSE	FALSE
7836	10.1021/ja990432d	doi.org/10.1021/ja990432d	Nickel on charcoal (Ni/C): An expedient and inexpensive heterogeneous catalyst for cross-couplings between aryl chlorides and organometallics. I. Functionalized organozinc reagents		J. Am. Chem. Soc.	32	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
7837	10.1016/S1381-1169(97)00008-3	doi.org/10.1016/S1381-1169(97)00008-3	Asymmetric palladium(0)-catalyzed synthesis of allylic ethers		J. Mol. Catal. A-Chem.	32		FALSE	FALSE	FALSE	FALSE
7838	10.1016/S0040-4020(01)87192-1	doi.org/10.1016/S0040-4020(01)87192-1	CHEMISTRY OF 7-LABDEN-3-BETA,15-DIOL (I) - HOMOCHIRAL SYNTHESIS OF FREGENEDADIOL		Tetrahedron	32	URONES, JG	FALSE	FALSE	FALSE	FALSE
7839	10.1139/v83-436	doi.org/10.1139/v83-436	SYNTHESIS OF (+/-)-TRIXAGOL BY AN ELECTROPHILIC CYCLIZATION OF AN ALLYLSILANE		Can. J. Chem.-Rev. Can. Chim.	32		FALSE	FALSE	FALSE	FALSE
7840	10.1021/acs.orglett.1c04223	doi.org/10.1021/acs.orglett.1c04223	Stereoselective Access to Conjugated and Cross-Conjugated Dienoates by Rh- and Ru-Catalyzed Isomerizations of Vinylcyclopropanes		Org. Lett.	32	Mazet, C	FALSE	FALSE	FALSE	FALSE
7841	10.1007/s10562-021-03799-y	doi.org/10.1007/s10562-021-03799-y	Carbon-Carbon Bond Formation for the Synthesis of 5-Aryl-2-Substituted Furans Catalyzed by K-3[Fe(CN)(6)]		Catal. Lett.	32	Singh, PP	FALSE	FALSE	FALSE	FALSE
7842	10.1055/a-1650-8519	doi.org/10.1055/a-1650-8519	Electrochemical Synthesis of 2-Bromoethyl and 2-Iodoethyl Ketones from Cyclopropanols		Synlett	32	Hurski, AL	FALSE	TRUE	FALSE	FALSE
7843	10.1002/adsc.202100641	doi.org/10.1002/adsc.202100641	Nickel-Catalyzed Amination of Aryl Nitriles for Accessing Diarylamines through C-CN Bond Activation		Adv. Synth. Catal.	32	Jin, LQ; Hu, XQ	FALSE	FALSE	FALSE	FALSE
7844	10.1055/s-0040-1720446	doi.org/10.1055/s-0040-1720446	Role of Benzylic Deprotonation in Nickel-Catalyzed Benzylic Dehydrogenation		Synlett	32	Newhouse, TR	FALSE	FALSE	FALSE	FALSE
7845	10.1055/a-1477-7059	doi.org/10.1055/a-1477-7059	Iridium-Catalyzed Direct C-H Allylation of Ketimines		Synthesis	32	Nishimura, T	FALSE	FALSE	FALSE	FALSE
7846	10.1039/c7qo00097a	doi.org/10.1039/c7qo00097a	Pd-Catalyzed 1,2-diarylation of vinylarenes at ambient temperature		Org. Chem. Front.	32	Song, QL	FALSE	FALSE	FALSE	FALSE
7847	10.1016/j.jscs.2016.10.001	doi.org/10.1016/j.jscs.2016.10.001	Bromo-catalyzed photo esterification of benzylsilanes with alcohols under aerobic conditions		J. Saudi Chem. Soc.	32	Sun, J	FALSE	FALSE	FALSE	FALSE
7848	10.1055/s-0036-1588075	doi.org/10.1055/s-0036-1588075	A Modular Synthesis of 2-Alkyl- and 2-Arylchromans via a Three-Step Sequence		Synthesis	32	Orr, RK	FALSE	FALSE	FALSE	FALSE
7849	10.1016/j.jorganchem.2016.09.018	doi.org/10.1016/j.jorganchem.2016.09.018	Suzuki-Miyaura cross-coupling of phenylboronic acid with aryl halides catalyzed by palladium and nickel species supported on alumina-based oxides		J. Organomet. Chem.	32	Gniewek, A	FALSE	FALSE	FALSE	FALSE
7850	10.1016/j.tetlet.2016.05.072	doi.org/10.1016/j.tetlet.2016.05.072	Catalytic asymmetric synthesis of CPZEN-45		Tetrahedron Lett.	32	Watanabe, T; Shibasaki, M	FALSE	FALSE	FALSE	FALSE
7851	10.1016/j.tet.2016.02.005	doi.org/10.1016/j.tet.2016.02.005	PBr3-mediated unexpected reductive deoxygenation of alpha-aryl-pyridinemethanols: synthesis of arylmethylpyridines		Tetrahedron	32	Seto, S	FALSE	FALSE	FALSE	FALSE
7852	10.1039/c6cc05400e	doi.org/10.1039/c6cc05400e	Rhodium-catalyzed transformation of heteroaryl aryl ethers into heteroaryl fluorides		Chem. Commun.	32	Arisawa, M; Yamaguchi, M	FALSE	FALSE	FALSE	FALSE
7853	10.1021/acscatal.1c00185	doi.org/10.1021/acscatal.1c00185	C(sp(3))-H Selective Benzylic Borylation by In Situ Reduced Ultrasmall Ni Species on CeO2	A nickel-catalyzed cross-electrophile coupling of aryl triflates and nonaflates with alkyl iodides using manganese(0) as a reductant is described. The method is applicable to the reductive alkylation of various aryl sulfonates, including o-borylaryl triflate, which enabled efficient construction of diverse alkylated arenes under mild conditions.	ACS Catal.	31	Yamaguchi, K	FALSE	FALSE	FALSE	FALSE
7854	10.1002/slct.202003634	doi.org/10.1002/slct.202003634	Pd(II)-NNN Pincer Complexes for Catalyzing Transfer Hydrogenation of Ketones	This Feature Article presents and discusses the use of different methods to quantify and explore the steric impact of N-heterocyclic carbene (NHC) ligands. These include (a) the percent buried volume (% V-bur), which provides a convenient single number to measure steric impact and (b) steric maps, which provide a graphical representation of the steric profile of a ligand using colour-coded contour maps. A critical discussion of the scope and limitations of these tools is presented, along with some examples of their use in organometallic chemistry and catalysis. This Article should provide all users of NHCs, from organic, organometallic, and inorganic chemistry backgrounds, with an appreciation of how these tools can be used to quantify and compare their steric properties.	ChemistrySelect	31	Karvembu, R	FALSE	FALSE	FALSE	FALSE
7855	10.1039/d0sc04383d	doi.org/10.1039/d0sc04383d	Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocksviapalladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones	Reaction of a condensed flavonoid tannin, namely mimosa tannin extract with a hexamethylene diamine, has been investigated. For that purpose, catechin was also used as a flavonoid model compound and treated in similar conditions. Solid-state cross-polarisation/ magic-angle spinning (CP-MAS) carbon 13 nuclear magnetic resonance (C-13 NMR) and matrix assisted laser desorption ionisation time of flight (MALDI-ToF) mass spectroscopy studies revealed that polycondensation compounds leading to resins were obtained by the reaction of the amines with the phenolic hydroxy groups of the tannin. Simultaneously, a second reaction leading to the formation of ionic bonds between the two groups occurred. These new reactions have been shown to clearly lead to the reaction of several phenolic hydroxyl groups, and flavonoid unit oligomerisation, to form hardened resins.	Chem. Sci.	31	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
7856	10.1016/j.jcat.2020.06.034	doi.org/10.1016/j.jcat.2020.06.034	Palladium-catalyzed carbonylative transformation of phenols via in-situ triflyl exchangement	In its neutral state, bis(diisopropylphosphino)amine HL reacts in equimolar amounts with the nickel halides NiCl2.6H(2)O, NiBr2, and NiI2 in ethanol solutions to give the air- and moisture-stable P,P-chelated complexes (HL)NiX2 (X = CI, Br, I). Under similar conditions, complexes of the form [(HL)(2)Ni]X-2(X = BF4, NO3, ClO4) were prepared from 2:1 ligand-metal ratios of Ni(BF4)(2).6H(2)O, Ni(NO3)(2).6H(2)O, or Ni (ClO4)(2).6H(2)O. Deprotonation of the ligand with NaNH2 followed by reaction with NiI2 gives L2Ni when performed in Et2O, but leads to the co-crystal L2Ni.2[NCCHC(Me)NH2] when the solvent is acetonitrile. In addition to these Ni2+ compounds, the Ni complex (HL)(2)Ni can be prepared from a toluene solution of Ni(cod)(2). Each complex has been characterized by a combination of IR and multi-nuclear NMR spectroscopies, as well as single-crystal X-ray diffraction. Electrochemical studies of the complexes revealed irreversible decomposition of the (HL)NiX2 (X = Cl, Br, I) series, but electrocatalytic CO2 reduction by the [(HP2Ni]X-2 (X=NO3, ClO4) compounds. (C) 2016 Elsevier B.V. All rights reserved.	J. Catal.	31	Wu, XF	FALSE	FALSE	FALSE	FALSE
7857	10.1021/acsomega.0c00953	doi.org/10.1021/acsomega.0c00953	Electrochemical Synthesis of Sulfinate Esters: Nickel(II)-Catalyzed Oxidative Esterification of Thiols with Alcohols in an Undivided Cell	The synthesis and characterization of the new air-stable precatalyst (L1)Ni(o-tol)Cl (Cl; where L1 = JosiPhos CyPF-Cy) is reported, along with the results of a comparative reactivity survey involving Cl and analogous PAd-DalPhos- and DPPF-containing precatalysts (C2 and C3, respectively) in representative nickel-catalyzed C(sp(2))-N cross-coupling reactions. Precatalyst C1 was found to be competitive with, and in some cases complementary to, C2 in the monoarylation of ammonia and primary alkylamines with (hetero)aryl chlorides, including in otherwise challenging room temperature transformations. (Pseudo)halide comparison studies involving the cross-coupling of furfurylamine at room temperature revealed that in contrast to C2 precatalyst Cl performs less effectively with aryl bromides. Whereas C3 was found to be ineffective for such transformations, this DPPF-derived precatalyst proved superior to C1 and C2 in reactions involving the secondary dialkylamine test substrate morpholine.	ACS Omega	31	Kaboudin, B	FALSE	TRUE	FALSE	FALSE
7858	10.1007/s10562-019-03062-5	doi.org/10.1007/s10562-019-03062-5	C-N Cross-coupling Reactions of Amines with Aryl Halides Using Amide-Based Pincer Nickel(II) Catalyst	One-pot ketone synthesis has been developed with in situ activation of alkyl halides to alkylzinc halides in the presence of thioesters and Pd-catalyst. The new method provides us with a reliable option for a coupling at a late stage in a convergent synthesis of complex molecules, with use of a near 1:1 molar ratio of coupling partners. First, two facile, orthogonal methods have been developed for preparation of alkylzinc halides: (1) direct insertion of zinc dust to 1 degrees- and 2 degrees-alkyl halides in the presence of LiI in DMI and (2) early transition-metal assisted activation of alkyl halides via a single electron transfer (SET) process. CrCl2 has been found as an unprecedented, inevitable mediator for preparation of alkylzinc halides from alkyl halides, where CrCl2 likely functions to trap R, generated via a SET process, and transfer it to Zn(II) to form RZnX. In addition to a commonly used CoPc, a new radical initiator NbCpCl4 has been discovered through the study. Second, with use of the two orthogonal methods, three sets of coupling conditions have been developed to complete one-pot ketone synthesis, with Condition A (Pd(2)dba(3), PR3, Zn, LiI, TESCl, DMI), Condition B (A + CrCl2), and Condition C (B + NbCpCl4 or CoPc) being useful for simple linear and a substituted substrates; simple linear and beta-substituted substrates, and complex substrates; respectively. Condition C is applicable to the broadest range of substrates. Overall, one-pot ketone synthesis gives excellent yields, with good functional group tolerance. controlled formation of alkylzinc halides by a combination of CrCl2 and NbCpCl4 or CoPc is crucial for its application to complex substrates. Interestingly, one-pot ketone synthesis does not suffer from the chemical instability due to the inevitable radical pathway(s), for example a 1,5-H shift. Notably, even with the increase in molecular size, no significant decrease in coupling efficiency has been noticed. to illustrate the synthetic value at a late stage in a complex molecule synthesis, ketone 4sc, containing all the carbons of Eribulin, has been synthesized from 1s and 3c.	Catal. Lett.	31	Ghosh, A	FALSE	FALSE	FALSE	FALSE
7859	10.1007/s11814-020-0541-2	doi.org/10.1007/s11814-020-0541-2	Gas-phase dehydration of glycerol to acrolein over different metal phosphate catalysts	The first Ni-catalyzed Suzuki-Miyaura coupling of amides for the synthesis of widely occurring biaryl compounds through N-C amide bond activation is reported. The reaction tolerates a wide range of electron-withdrawing, electron-neutral, and electron-donating substituents on both coupling partners. The reaction constitutes the first example of the Ni-catalyzed generation of aryl electrophiles from bench-stable amides with potential applications for a broad range of organometallic reactions.	Korean J. Chem. Eng.	31	Ma, TL	FALSE	FALSE	FALSE	FALSE
7860	10.1021/acs.joc.0c00573	doi.org/10.1021/acs.joc.0c00573	Dehydroxylated C-3 Alkylation of Indole Accompanied by 1,2-Sulfur Migration	Highly monodisperse graphene oxide-supported Ru/Pd nanoparticles (RuPd@GO NPs) have been reproducibly and easily synthesized by microwave assisted method. RuPd@GO NPs was performed for dehalogenation of arylhalides in the presence of ammonia borane in a mild condition as novel, highly efficient and exceptional reusable heterogeneous catalyst. The novel materials were characterized by transmission electron microscopy (TEM), the high resolution electron micrograph (HRTEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results showed that the prepared catalysts are highly crystalline, monodisperse and colloidally stable. The current one-pot catalytic process was described as a new methodology for dehalogenation of arylhalides which can be assessed as a quite simple, eco-friendly and highly efficient as well as exceptional reusable. All products were provided with one of the highest yield and the shortest time in the presence of novel RuPd@GO NPs due to the the synergistic effect of Ru and Pd. Our synthesis process comes with a facile and eco-friendly option to RuPd@GO NPs, allowing further scrutiny of current catalysts for numerous other chemical reactions.	J. Org. Chem.	31	Lu, T; Feng, J	FALSE	FALSE	FALSE	FALSE
7861	10.1055/s-0039-1690718	doi.org/10.1055/s-0039-1690718	Nickel-Catalyzed Amination of alpha-Aryl Methyl Ethers	An efficient synthesis of 7-substituted pyrazolo[1,5-a] pyrimidines using a one-pot, two-step process via Pd-catalyzed direct CH-arylation followed by a saponification-decarboxylation reaction is reported. Compared to the classical method (Negishi coupling), this new procedure has the advantages of convenient manipulation, short reaction times, excellent yields and the use of commercially available and relatively non-toxic compounds.	Synlett	31	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
7862	10.6023/cjoc201901004	doi.org/10.6023/cjoc201901004	Asymmetric 1,3-Dipolar Cycloaddition Reaction of C,N-Diarylnitrone with N-alpha,beta-Unsaturated Acyl Compounds Catalyzed by Chiral Bisoxazoline Metal Complex		Chin. J. Org. Chem.	31	You, J; Yu, YC	FALSE	FALSE	FALSE	FALSE
7863	10.1007/s13738-019-01615-4	doi.org/10.1007/s13738-019-01615-4	An efficient transformation of methyl ethers and nitriles to amides catalyzed by Iron(III) perchlorate hydrate		J. Iran Chem. Soc.	31	Yin, GB	FALSE	FALSE	FALSE	FALSE
7864	10.1039/c9ob00628a	doi.org/10.1039/c9ob00628a	Deoxygenative cross-electrophile coupling of benzyl chloroformates with aryl iodides		Org. Biomol. Chem.	31	Gong, HG	FALSE	FALSE	FALSE	FALSE
7865	10.1021/acs.organomet.8b00307	doi.org/10.1021/acs.organomet.8b00307	Advances in Base-Metal Catalysis: Development of a Screening Platform for Nickel-Catalyzed Borylations of Aryl (Pseudo)halides with B-2(OH)(4)		Organometallics	31	Wisniewski, SR	FALSE	FALSE	FALSE	FALSE
7866	10.1038/s41586-018-0669-y	doi.org/10.1038/s41586-018-0669-y	Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins		Nature	31	Fu, GC	FALSE	FALSE	FALSE	FALSE
7867	10.1039/c8nj01518j	doi.org/10.1039/c8nj01518j	The first report on the transition metal-free homocoupling of aryl halides in the presence of L-cysteine		New J. Chem.	31	Ghorbani-Choghamarani, A	FALSE	FALSE	FALSE	FALSE
7868	10.1016/j.molstruc.2017.10.096	doi.org/10.1016/j.molstruc.2017.10.096	Copper-based 2D-coordination polymer as catalyst for allylation of aldehydes		J. Mol. Struct.	31	da Silva, FF	FALSE	FALSE	FALSE	FALSE
7869	10.1021/acs.orglett.8b00235	doi.org/10.1021/acs.orglett.8b00235	Nickel-Catalyzed Reductive Bis-Allylation of Alkynes		Org. Lett.	31	Komeyama, K	FALSE	FALSE	FALSE	FALSE
7870	10.1002/ejlt.201700133	doi.org/10.1002/ejlt.201700133	Efficient microwave-assisted synthesis of glycerol monodecanoate		Eur. J. Lipid Sci. Technol.	31	Plasseraud, L	FALSE	FALSE	FALSE	FALSE
7871	10.1039/c8ra01430b	doi.org/10.1039/c8ra01430b	Synthesis, characterization and evaluation of bulky bis(pyrazolyl)palladium complexes in Suzuki-Miyaura cross-coupling reactions		RSC Adv.	31	Darkwa, J; Makhubela, BCE	FALSE	FALSE	FALSE	FALSE
7872	10.6023/cjoc201705044	doi.org/10.6023/cjoc201705044	Copper Montmorillonite Modified by Biquaternary Ammonium Salts for Coupling of Aryl Halides with Aqueous Ammonia		Chin. J. Org. Chem.	31	Zhou, LM	FALSE	FALSE	FALSE	FALSE
7873	10.1039/c6ra06748d	doi.org/10.1039/c6ra06748d	Bioactivity-guided synthesis of tropine derivatives as new agonists for melatonin receptors		RSC Adv.	31	Chen, JJ	FALSE	FALSE	FALSE	FALSE
7874	10.1002/adsc.201500461	doi.org/10.1002/adsc.201500461	Nickel-Catalyzed Synthesis of Enamides and Enecarbamates via Isomerization of Allylamides and Allylcarbamates		Adv. Synth. Catal.	31	Manolikakes, G	FALSE	FALSE	FALSE	FALSE
7875	10.1021/acs.orglett.5b00766	doi.org/10.1021/acs.orglett.5b00766	A Modular, Air-Stable Nickel Precatalyst		Org. Lett.	31	Doyle, AG	FALSE	FALSE	FALSE	FALSE
7876	10.1039/c4ra16452k	doi.org/10.1039/c4ra16452k	Ni(II) source as a pre-catalyst for the cross-coupling of benzylic pivalates with arylboronic acids: facile access to tri- and diarylmethanes		RSC Adv.	31	Yang, LM	FALSE	FALSE	FALSE	FALSE
7877	10.1016/j.tetlet.2014.10.077	doi.org/10.1016/j.tetlet.2014.10.077	Step-economy etherification of acylated alcohols		Tetrahedron Lett.	31	Xu, HD	FALSE	FALSE	FALSE	FALSE
7878	10.1007/s11434-014-0239-0	doi.org/10.1007/s11434-014-0239-0	Progress of transition metal-catalyzed cross-coupling mediated by PyBroP		Chin. Sci. Bull.	31	Chen, GJ	FALSE	FALSE	FALSE	FALSE
7879	10.1080/07328303.2014.907908	doi.org/10.1080/07328303.2014.907908	Attempted Synthesis of the Imidazylate of an a- Hydroxylactone Results in Unexpected Chlorination: Synthesis and X- Ray Crystal Structure of 5-Chloro-5-deoxy1,2-O-isopropylidene- beta-Lidurono-6,3-lactone		J. Carbohydr. Chem.	31	Ferro, V	FALSE	FALSE	FALSE	FALSE
7880	10.1021/ol500587m	doi.org/10.1021/ol500587m	Cooperative Catalysis by Palladium-Nickel Binary Nanocluster for Suzuki-Miyaura Reaction of Ortho-Heterocycle-Tethered Sterically Hindered Aryl Bromides		Org. Lett.	31	Chakraborti, AK	FALSE	FALSE	FALSE	FALSE
7881	10.1016/j.bbrc.2014.02.067	doi.org/10.1016/j.bbrc.2014.02.067	New fluorescent probes for ligand-binding assays of odorant-binding proteins		Biochem. Biophys. Res. Commun.	31	Napolitano, E	FALSE	FALSE	FALSE	FALSE
7882	10.1021/ol4031364	doi.org/10.1021/ol4031364	Enantioselective, Nickel-Catalyzed Suzuki Cross-Coupling of Quinolinium Ions		Org. Lett.	31	Doyle, AG	FALSE	FALSE	FALSE	FALSE
7883	10.1039/c4cc00853g	doi.org/10.1039/c4cc00853g	Oxidative addition of ether O-methyl bonds at a Pt(0) centre		Chem. Commun.	31	Perutz, RN	FALSE	FALSE	FALSE	FALSE
7884	10.1016/j.saa.2013.03.082	doi.org/10.1016/j.saa.2013.03.082	Substituent effects on the UV spectra of extended benzylidene anilines p-X-PhCH=NPhCH=CHPh-p-Y		Spectroc. Acta Pt. A-Molec. Biomolec. Spectr.	31	Cao, CZ	FALSE	FALSE	FALSE	FALSE
7885	10.1016/j.jfluchem.2012.12.001	doi.org/10.1016/j.jfluchem.2012.12.001	Microwave-assisted amination from fluorobenzenes without catalyst and strong base		J. Fluor. Chem.	31	Zhou, WC	FALSE	FALSE	FALSE	FALSE
7886	10.1039/c3cy00303e	doi.org/10.1039/c3cy00303e	Bimetallic gold-palladium alloy nanoclusters: an effective catalyst for Ullmann coupling of chloropyridines under ambient conditions		Catal. Sci. Technol.	31	Dhital, RN	FALSE	FALSE	FALSE	FALSE
7887	10.1002/anie.201208571	doi.org/10.1002/anie.201208571	Synthetic Studies on Pseudo-Dimeric Lycopodium Alkaloids: Total Synthesis of Complanadine B		Angew. Chem.-Int. Edit.	31	Sarpong, R	FALSE	FALSE	FALSE	FALSE
7888	10.1016/j.tet.2012.07.084	doi.org/10.1016/j.tet.2012.07.084	Synthesis and properties of phenylogous amides		Tetrahedron	31	Yamasaki, R	FALSE	FALSE	FALSE	FALSE
7889	10.1039/c2cc33755j	doi.org/10.1039/c2cc33755j	Synthesis of unsymmetrical biaryl ethers through nickel-promoted coupling of polyfluoroarenes with arylboronic acids and oxygen		Chem. Commun.	31	Cao, S	FALSE	FALSE	FALSE	FALSE
7890	10.1021/ol202271k	doi.org/10.1021/ol202271k	N-Capping of Primary Amines with 2-Acyl-benzaldehydes To Give Isoindolinones		Org. Lett.	31	Schmalz, HG	FALSE	FALSE	FALSE	FALSE
7891	10.1007/s11243-011-9525-8	doi.org/10.1007/s11243-011-9525-8	Microwave-enhanced cyanation of aryl halides with a dimeric ortho-palladated complex catalyst		Transit. Met. Chem.	31	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
7892	10.1021/ol101592r	doi.org/10.1021/ol101592r	Nickel-Catalyzed C-O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates		Org. Lett.	31	Molander, GA	FALSE	FALSE	FALSE	FALSE
7893	10.1038/NCHEM.518	doi.org/10.1038/NCHEM.518	A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres		Nat. Chem.	31	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
7894	10.1021/ol901978e	doi.org/10.1021/ol901978e	Nickel-Catalyzed Cross-Coupling Reaction of Alkenyl Methyl Ethers with Aryl Boronic Esters		Org. Lett.	31	Tobisu, M	FALSE	FALSE	FALSE	FALSE
7895	10.1021/ja808935n	doi.org/10.1021/ja808935n	Facile Synthesis of Highly Stable Gold Nanoparticles and Their Unexpected Excellent Catalytic Activity for Suzuki-Miyaura Cross-Coupling Reaction in Water		J. Am. Chem. Soc.	31	Guo, R	FALSE	FALSE	FALSE	FALSE
7896	10.1080/00958970902939814	doi.org/10.1080/00958970902939814	X-ray structure of trans-chloro(1-naphthyl) bis(triphenylphosphine)nickel(II) and its application for catalytic dehalogenation of aryl chlorides		J. Coord. Chem.	31	Bao, M	FALSE	FALSE	FALSE	FALSE
7897	10.1002/aoc.1359	doi.org/10.1002/aoc.1359	Suzuki cross-coupling reaction of aryl and heterocyclic bromides and aromatic polybromides on a Pd(II)-hydrotalcite catalyst		Appl. Organomet. Chem.	31	Ruiz, JR	FALSE	FALSE	FALSE	FALSE
7898	10.1002/asia.200700391	doi.org/10.1002/asia.200700391	A heterogeneous-catalyst-based, microwave-assisted protocol for the synthesis of 2,2 '-bipyridines		Chem.-Asian J.	31	Vicic, DA	FALSE	FALSE	FALSE	FALSE
7899	10.1016/j.tet.2007.09.074	doi.org/10.1016/j.tet.2007.09.074	Iodocyclization/base-induced hydrodeiodination reaction of 5-substituted 4-alkenols. The influence of substituent on the stereoselective pathway		Tetrahedron	31	Paolucci, C	FALSE	FALSE	FALSE	FALSE
7900	10.1021/ol060666j	doi.org/10.1021/ol060666j	Asymmetric silaboration of terminal allenes bearing alpha-stereogenic centers: Stereoselection based on reagent control		Org. Lett.	31	Suginome, M	FALSE	FALSE	FALSE	FALSE
7901	10.1055/s-2006-939051	doi.org/10.1055/s-2006-939051	Grignard-triggered fragmentation of vinylogous acyl triflates: Synthesis of (Z)-6-heneicosen-11-one, the Douglas fir tussock moth sex pheromone		Synlett	31	Dudley, GB	FALSE	FALSE	FALSE	FALSE
7902	10.1016/j.tetlet.2005.08.136	doi.org/10.1016/j.tetlet.2005.08.136	Synthesis of aromatic phosphates via cycloaddition of phosphate dienes		Tetrahedron Lett.	31	Wiemer, DF	FALSE	FALSE	FALSE	FALSE
7903	10.1021/ol051871m	doi.org/10.1021/ol051871m	Synthesis of a diverse series of phosphacoumarins with biological activity		Org. Lett.	31	Li, XS	FALSE	FALSE	FALSE	FALSE
7904	10.1039/b416703a	doi.org/10.1039/b416703a	Luminescent silver metal chains with unusual mu(4)-bonded 2,2 '-bipyrazine		Dalton Trans.	31	Lu, KL	FALSE	FALSE	FALSE	FALSE
7905	10.1002/qsar.200420040	doi.org/10.1002/qsar.200420040	Rapid microwave-promoted cross-coupling reaction of aryl bromides with aryl boronic acids and sodium tetraphenylborate catalyzed by a reusable polymer-supported palladium complex		QSAR Comb. Sci.	31	Wang, JX	FALSE	FALSE	FALSE	FALSE
7906	10.1021/op0340457	doi.org/10.1021/op0340457	Cross-coupling methods for the large-scale preparation of an imidazole-thienopyridine: Synthesis of [2-(3-methyl-3H-imidazol-4-yl)thieno[3,2-b]pyridin-7-yl]-(2-methyl-1H-indol-5-yl)-amine		Org. Process Res. Dev.	31	Ragan, JA	FALSE	FALSE	FALSE	FALSE
7907	10.1055/s-2003-37120	doi.org/10.1055/s-2003-37120	Ruthenium-bisimine: A new catalytic precursor for regioselective allylic alkylation		Synlett	31	Renaud, JL	FALSE	FALSE	FALSE	FALSE
7908	10.1016/S0040-4039(02)01502-2	doi.org/10.1016/S0040-4039(02)01502-2	Palladium-catalyzed hydrodehalogenations by fluoride activated polymethylhydrosiloxane		Tetrahedron Lett.	31	Maleczka, RE	FALSE	FALSE	FALSE	FALSE
7909	10.1016/S0040-4039(01)01467-8	doi.org/10.1016/S0040-4039(01)01467-8	Regioselective rhodium-catalyzed allylic alkylation/ring-closing metathesis approach to carbocycles		Tetrahedron Lett.	31	Evans, PA	FALSE	FALSE	FALSE	FALSE
7910	10.1021/ja0108640	doi.org/10.1021/ja0108640	General strategies for the synthesis of the major classes of C-aryl glycosides		J. Am. Chem. Soc.	31	Martin, SF	FALSE	FALSE	FALSE	FALSE
7911	10.1016/S0040-4020(97)10208-3	doi.org/10.1016/S0040-4020(97)10208-3	Synthetic and kinetic aspects of nickel-catalysed amination of allylic alcohol derivatives		Tetrahedron	31	Mortreux, A	FALSE	FALSE	FALSE	FALSE
7912	10.1016/0040-4039(96)00786-1	doi.org/10.1016/0040-4039(96)00786-1	Optically active allylsilanes .20. Asymmetric hydrosilylation of cyclic 1,3-dienes catalyzed by an axially chiral monophosphine-palladium complex		Tetrahedron Lett.	31		FALSE	FALSE	FALSE	FALSE
7913	10.1016/0957-4166(95)00371-1	doi.org/10.1016/0957-4166(95)00371-1	Saponaceolides: Differential cytotoxicity and enantioselective synthesis of the right-hand lactone moiety		Tetrahedron-Asymmetry	31	Vidari, G	FALSE	FALSE	FALSE	FALSE
7914	10.1039/c39940001789	doi.org/10.1039/c39940001789	NICKEL-CATALYZED SUBSTITUTION-REACTIONS OF ALLYLIC CARBONATES WITH ARYL-BORATES AND ALKENYL-BORATES		J. Chem. Soc.-Chem. Commun.	31	KOBAYASHI, Y	FALSE	FALSE	FALSE	FALSE
7915	10.1021/ja00188a095	doi.org/10.1021/ja00188a095	A STEREOSELECTIVE SYNTHESIS OF FUNCTIONALIZED ALKENYLLITHIUMS AND ALKENYL CYANOCUPRATES BY THE CU(I)-CATALYZED COUPLING OF ORGANO-LITHIUM REAGENTS WITH ALPHA-LITHIATED CYCLIC ENOL ETHERS		J. Am. Chem. Soc.	31	KOCIENSKI, P	FALSE	FALSE	FALSE	FALSE
7916	10.1021/jo00226a030	doi.org/10.1021/jo00226a030	STUDIES IN SRNI SERIES .19. A GENERAL SRN1-BASED METHOD FOR TOTAL SYNTHESIS OF UNSYMMETRICALLY HYDROXYLATED 2,2'-BINAPHTHALENES		J. Org. Chem.	31	BEUGELMANS, R	FALSE	FALSE	FALSE	FALSE
7917	10.1246/cl.1982.223	doi.org/10.1246/cl.1982.223	CHEMISTRY OF ORGANO-SILICON COMPOUNDS .159. HIGHLY REGIOSELECTIVE SYNTHESIS OF (1-METHYL-2-PROPENYL)TRIMETHYLSILANE USING THE CROTYL GRIGNARD-REAGENT AND TRIMETHYLCHLOROSILANE		Chem. Lett.	31	HOSOMI, A	FALSE	FALSE	FALSE	FALSE
7918	10.1016/S0020-1693(00)86943-1	doi.org/10.1016/S0020-1693(00)86943-1	NICKEL(II), PALLADIUM(II) AND PLATINUM(II) DICHLORO COMPLEXES CONTAINING OPTICALLY-ACTIVE DIPHOSPHINES			31	MORANDINI, F	FALSE	FALSE	FALSE	FALSE
7919	10.1002/chem.202102031	doi.org/10.1002/chem.202102031	Electrocatalytic H-2 Generation from Water Relying on Cooperative Ligand Electron Transfer in (PNP)-P-3 Pincer-Supported Ni-II Complexes		Chem.-Eur. J.	31	Richeson, D	FALSE	TRUE	FALSE	FALSE
7920	10.1246/bcsj.20200364	doi.org/10.1246/bcsj.20200364	Conjugate Addition of Acetal-Derived Benzyl Radicals Generated from Low-Valent Titanium-Mediated C-O Bond Cleavage		Bull. Chem. Soc. Jpn.	31	Suga, T; Ukaji, Y	FALSE	FALSE	FALSE	FALSE
7921	10.1002/adsc.201600887	doi.org/10.1002/adsc.201600887	Expeditious Synthesis of Functionalized 1-Arylcyclooctadienes via Palladium-Catalyzed Lithium Cross-Coupling		Adv. Synth. Catal.	31	Brase, S	FALSE	FALSE	FALSE	FALSE
7922	10.3762/bjoc.12.209	doi.org/10.3762/bjoc.12.209	Palladium-catalyzed ring-opening reactions of cyclopropanated 7-oxabenzonorbornadiene with alcohols		Beilstein J. Org. Chem.	31	Tam, W	FALSE	FALSE	FALSE	FALSE
7923	10.1002/bkcs.10871	doi.org/10.1002/bkcs.10871	Synthesis of Oxazine-Embedded 1,1-Biaryl-2,2-diamine via [3,3]-Sigmatropic Rearrangement of Oxazine Diarylhydrazine		Bull. Korean Chem. Soc.	31	Cho, CG	FALSE	FALSE	FALSE	FALSE
7924	10.1039/c6ra14670h	doi.org/10.1039/c6ra14670h	Regioselective copper-diamine-catalyzed C-H arylation of 1,2,4-triazole ring with aryl bromides		RSC Adv.	31	Teo, YC	FALSE	FALSE	FALSE	FALSE
7925	10.1080/00958972.2021.1881066	doi.org/10.1080/00958972.2021.1881066	Iron-catalyzed N-alkylation of aromatic amines via borrowing hydrogen strategy	The Ni-catalyzed Suzuki-Miyaura coupling of N-tert-butoxycarbonyl (N-Boc)-protected amides provides a versatile strategy for the construction of C-C bonds. In this study, density functional theory (DFT) methods have been used to elucidate the mechanism of this reaction, with particular emphasis on the roles of N-Boc, K3PO4 and H2O. Our results corroborated those of previous reports, indicating that the overall catalytic cycle consists of three steps, including oxidative addition, transmetalation, and reductive elimination. Three of the possible transmetalation mechanisms were examined to interpret the effects of K3PO4 and H2O. According to the most feasible of these transmetalation mechanisms, K3PO4 (acting as a Lewis base) would initially interact with the Lewis acid PhBpin to give a K3PO4-PhBpin complex, which would readily undergo a hydrogen transfer step with H2O. The H transfer in the transmetalation step was determined to be the rate-determining step. Notably, the theoretical results showed good agreement with the experimental data.	J. Coord. Chem.	30	Liu, TT	FALSE	FALSE	FALSE	FALSE
7926	10.1055/a-1337-6459	doi.org/10.1055/a-1337-6459	Nickel-Catalyzed N-Arylation of Amides with (Hetero)aryl Electrophiles by Using a DBU/NaTFA Dual-Base System	A practical one-pot process for hydrodeoxygenation (HDO) of phenolic derivatives to their corresponding arenes was developed. This method provided a facile route to upgrading bio-oil. The substrate scope of this protocol was wide, complicated and multi-phenolic compounds were also smoothly hydrodeoxygenated to their corresponding arenes. (C) 2017 Elsevier Ltd. All rights reserved.	Synlett	30	Stradiotto, M	FALSE	TRUE	FALSE	FALSE
7927	10.1021/acs.organomet.0c00628	doi.org/10.1021/acs.organomet.0c00628	Insight into the Scope and Mechanism for Transmetalation of Hydrocarbyl Ligands on Complexes Relevant to C-H Activation	In this study, a MnI/AgI-based relay catalysis process is described for the one-pot synthesis of polycyclic products by a formal [3+2] and [4+2] cycloaddition reaction cascade. A manganese(I) complex catalyzed the first example of directed C-H allylation with allenes, setting the stage for an in situ Povarov cyclization catalyzed by silver(I). The reaction proceeds with high bond-forming efficiency (three C-C bonds), broad substrate scope, high regio- and stereoselectivity, and 100% atom economy.	Organometallics	30	Lewis, JC	FALSE	FALSE	FALSE	FALSE
7928	10.1039/d0sc04074f	doi.org/10.1039/d0sc04074f	What can reaction databases teach us about Buchwald-Hartwig cross-couplings?	Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition, allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.	Chem. Sci.	30	Fitzner, M	FALSE	FALSE	FALSE	FALSE
7929	10.1039/d0cy00748j	doi.org/10.1039/d0cy00748j	Nickel catalysed construction of benzazolesviahydrogen atom transfer reactions	A novel catalytic reaction of alcohol etherification in the system ROH - PtCl42- - PtCl62- was found. Methanol easily transforms into dimethyl ether in the presence of catalytic amounts of Pt-II chloro complexes at 70 degrees C. Under the same conditions reaction of ethanol affords diethyl ether (catalytic) and pi-ethylene Pt-II complex (stoichiometric). The reactions are accompanied by multiple HAD exchange, which is indicative of intermediacy of corresponding alkyl platinum derivatives. The plausible reaction mechanism involves oxidative addition of alcohol forming intermediate alkyl platinum(IV) derivative followed by decomposition of it via reductive elimination step under the action of alcohol giving the ether and regenerating catalyst. In the case of ethyl alcohol reaction, beta-hydrogen abstraction from the intermediate Pt-ethyl species yields pi-ethylene platinum(II) complex. Although it seems that the reaction does not involve the initial breaking of C-H bonds of an alcohol, this system can be regarded as a model for studying of some peculiarities of Shilov chemistry, in particular, of isotope scrambling mechanisms in Shilov alkane activation. In contrast to reactions of dimethyl and diethyl ethers formation, tert-butyl ethers formation in CD3OH/t-BuOH medium is catalyzed by Pt-IV chloro complexes also and is not accompanied by isotope scrambling. These observations argue against intermediacy of alkyl platinum.derivatives suggesting that acid-catalyzed mechanism operates in tert-butyl alcohol etherification. (C) 2016 Elsevier B.V. All rights reserved.	Catal. Sci. Technol.	30	Adhikari, D	FALSE	FALSE	FALSE	FALSE
7930	10.3987/COM-20-14253	doi.org/10.3987/COM-20-14253	SULFAMIC ACID-CATALYZED CONVERSION OF o-AMINOTHIOPHENOL AND AROMATIC ALDEHYDES TO 2-ARYLBENZOTHIAZOLES	Protecting-group-independent cross-coupling of alpha-alkoxyalkyl- and alpha-acyloxyalkyltrifluoroborates with aryl and heteroaryl bromides is achieved through application of photoreddx/nickel dual catalysis. Reactions occur under exceptionally mild conditions, with outstanding functional group compatibility and excellent observed tolerance of heteroarenes. This method offers expedient access to protected secondary benzylic alcohol motifs bearing benzyl, pivaloyl, and N,N-diisopropylcarbamoyl protecting groups.	Heterocycles	30	Yu, XF	FALSE	FALSE	FALSE	FALSE
7931	10.3762/bjoc.16.89	doi.org/10.3762/bjoc.16.89	Suzuki-Miyaura cross coupling is not an informative reaction to demonstrate the performance of new solvents	By the use of 1-chloro-1,2-benziodoxol-3-one, an age-old reagent, the practical and efficient chlorination method is achieved. This hypervalent iodine reagent is amenable not only to the chlorination of nitrogen-containing heterocycles but also to selected classes of arenes, BODIPY dyes, and pharmaceuticals. In addition, the advantages, such as easy preparation and recyclable, air- and moisture-stable, in combination with the success in a gram-scale experiment grant this reagent great potential for industrial application.	Beilstein J. Org. Chem.	30	Sherwood, J	FALSE	FALSE	FALSE	FALSE
7932	10.6023/A19050193	doi.org/10.6023/A19050193	Modular Synthesis of Functionalized 4-Quinolones via a Radical Cyclization Cascade Reaction		Acta Chim. Sin.	30	Xu, HC	FALSE	FALSE	FALSE	FALSE
7933	10.1038/s41467-019-09766-x	doi.org/10.1038/s41467-019-09766-x	Nickel-catalyzed Suzuki-Miyaura cross-couplings of aldehydes		Nat. Commun.	30	Rueping, M	FALSE	FALSE	FALSE	FALSE
7934	10.1016/j.poly.2018.10.028	doi.org/10.1016/j.poly.2018.10.028	Highly active homoleptic nickel(II) bis-N-heterocyclic carbene catalyst for Suzuki-Miyaura and Heck cross-coupling reactions		Polyhedron	30	Ganesan, P	FALSE	FALSE	FALSE	FALSE
7935	10.1002/anie.201810757	doi.org/10.1002/anie.201810757	Nickel-Catalyzed Mizoroki-Heck-Type Reactions of Unactivated Alkyl Bromides		Angew. Chem.-Int. Edit.	30	Alexanian, EJ	FALSE	FALSE	FALSE	FALSE
7936	10.1039/c8sc03430c	doi.org/10.1039/c8sc03430c	Reductive cleavage of C=C bonds as a new strategy for turn-on dual fluorescence in effective sensing of H2S		Chem. Sci.	30	Zhang, HJ; Zhang, XJ	FALSE	FALSE	FALSE	FALSE
7937	10.1055/S-0036-1591774	doi.org/10.1055/S-0036-1591774	Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers		Synlett	30	Nagano, T	FALSE	FALSE	FALSE	FALSE
7938	10.1002/anie.201800699	doi.org/10.1002/anie.201800699	Sulfonamidation of Aryl and Heteroaryl Halides through Photosensitized Nickel Catalysis		Angew. Chem.-Int. Edit.	30	MacMillan, DWC	TRUE	FALSE	FALSE	FALSE
7939	10.1021/acs.organomet.7b00848	doi.org/10.1021/acs.organomet.7b00848	Synthesis of NHC Pincer Hydrido Nickel Complexes and Their Catalytic Applications in Hydrodehalogenation		Organometallics	30	Sun, HJ	FALSE	FALSE	FALSE	FALSE
7940	10.1080/00304948.2018.1405334	doi.org/10.1080/00304948.2018.1405334	Simple and Efficient Large-scale Metal-free Synthesis of o-(5-Formyl-2-thienyl)benzonitrile and o-(5-Formyl-2-furyl)benzonitrile		Org. Prep. Proced. Int.	30	Lovric, M	FALSE	FALSE	FALSE	FALSE
7941	10.1002/anie.201710053	doi.org/10.1002/anie.201710053	Cobalt-Catalyzed Suzuki Biaryl Coupling of Aryl Halides		Angew. Chem.-Int. Edit.	30	Bedford, RB	FALSE	FALSE	FALSE	FALSE
7942	10.1021/acs.joc.7b02423	doi.org/10.1021/acs.joc.7b02423	TfOH-Catalyzed Reaction between 3-Diazoindolin-2-imines and Electron-Rich Arenes: Access to 3-Aryl-2-aminoindoles		J. Org. Chem.	30	Lu, P; Wang, YG	FALSE	TRUE	FALSE	FALSE
7943	10.1016/j.jfluchem.2017.07.017	doi.org/10.1016/j.jfluchem.2017.07.017	Fluorodecarboxylation: Synthesis of aryl trifluoromethyl ethers (ArOCF3) and thioethers (ArSCF3)		J. Fluor. Chem.	30	Prakash, GKS	FALSE	FALSE	FALSE	FALSE
7944	10.1039/c6cc00971a	doi.org/10.1039/c6cc00971a	Pd-II/CuBr2 catalysed keto alpha-C-sp3-H benzoxylation of N,N-dialkylamides directed by o-hydroxy groups		Chem. Commun.	30	Patel, BK	FALSE	FALSE	FALSE	FALSE
7945	10.1038/NCHEM.2388	doi.org/10.1038/NCHEM.2388	Nickel-catalysed Suzuki-Miyaura coupling of amides		Nat. Chem.	30	Garg, NK	FALSE	FALSE	FALSE	FALSE
7946	10.1039/c6dt00064a	doi.org/10.1039/c6dt00064a	Oxidatively-induced aromatic cyanation mediated by Ni(III)		Dalton Trans.	30	Mirica, LM	FALSE	FALSE	FALSE	FALSE
7947	10.1016/j.tetlet.2015.10.022	doi.org/10.1016/j.tetlet.2015.10.022	A direct facile and effective synthesis of various 1,1-heterodiaryl alkenes through Pd catalyzed cross coupling reaction using N-tosylhydrazones via C-OH bond activation		Tetrahedron Lett.	30	Chikhalia, KH	FALSE	FALSE	FALSE	FALSE
7948	10.1021/acs.oprd.5b00148	doi.org/10.1021/acs.oprd.5b00148	Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard Reagents		Org. Process Res. Dev.	30	Jarvo, ER	FALSE	FALSE	FALSE	FALSE
7949	10.1038/nature14615	doi.org/10.1038/nature14615	Conversion of amides to esters by the nickel-catalysed activation of amide C-N bonds		Nature	30	Houk, KN	FALSE	FALSE	FALSE	FALSE
7950	10.1016/j.tetlet.2015.03.039	doi.org/10.1016/j.tetlet.2015.03.039	Pd(II)-mediated cyclodehydrogenation of formyldiarylamines-total synthesis of natural carbazoles clauraila A, clausenal and 6-methoxymurrayanine		Tetrahedron Lett.	30	Emery, FD	FALSE	FALSE	FALSE	FALSE
7951	10.1016/j.cclet.2014.10.021	doi.org/10.1016/j.cclet.2014.10.021	Mechanistic study on the regioselectivity of Co-catalyzed hydroacylation of 1,3-dienes		Chin. Chem. Lett.	30	Yu, HZ	FALSE	FALSE	FALSE	FALSE
7952	10.1039/c5cc02552d	doi.org/10.1039/c5cc02552d	Stereoselective synthesis of glycosides using (salen)Co catalysts as promoters		Chem. Commun.	30	Galan, MC	FALSE	FALSE	FALSE	FALSE
7953	10.1080/00397911.2015.1100746	doi.org/10.1080/00397911.2015.1100746	Copper(II) Bromide-Catalyzed C-C/C-N Bond-Forming Reactions: Synthesis of Pyrrole-Incorporated Triarylmethanes		Synth. Commun.	30	Rao, HSP	FALSE	FALSE	FALSE	FALSE
7954	10.1016/j.catcom.2014.08.010	doi.org/10.1016/j.catcom.2014.08.010	Trans-chloro-(1-naphthyl)bis[tris-(4-methoxyphenyl) phosphane]-nickel(II) catalyzed Suzuki- Miyaura coupling of aryl chlorides with phenylboronic acid		Catal. Commun.	30	Li, RX	FALSE	FALSE	FALSE	FALSE
7955	10.1016/j.tet.2014.04.059	doi.org/10.1016/j.tet.2014.04.059	A nickel precatalyst for efficient cross-coupling reactions of aryl tosylates with arylboronic acids: vital role of dppf		Tetrahedron	30	Lei, XY	FALSE	FALSE	FALSE	FALSE
7956	10.1039/c4ra05999a	doi.org/10.1039/c4ra05999a	Copper nanoparticle-catalyzed borylation of alkyl bromides with an organodiboron compound		RSC Adv.	30	Chung, YK	FALSE	FALSE	FALSE	FALSE
7957	10.1021/ol402336u	doi.org/10.1021/ol402336u	Regio- and Enantiospecific Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent		Org. Lett.	30	Evans, PA	FALSE	FALSE	FALSE	FALSE
7958	10.1016/j.tca.2013.07.013	doi.org/10.1016/j.tca.2013.07.013	Some aspects of catalytic activity of pyrolyzed coals		Thermochim. Acta	30	Strojwas, A	FALSE	FALSE	FALSE	FALSE
7959	10.1080/00397911.2011.632830	doi.org/10.1080/00397911.2011.632830	Palladium-Catalyzed Synthesis of Symmetrical Biaryls Under Microwave Irradiation and Conventional Heating		Synth. Commun.	30	Hajipour, AR	FALSE	FALSE	FALSE	FALSE
7960	10.3184/174751913X13635315066265	doi.org/10.3184/174751913X13635315066265	Efficient Stille cross-coupling reaction catalysed by the Pd(OAc)(2)/orotic acid catalytic system		J. Chem. Res	30	Zhang, HP	FALSE	FALSE	FALSE	FALSE
7961	10.1021/ja311669p	doi.org/10.1021/ja311669p	Nickel-Catalyzed Carbon-Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations		J. Am. Chem. Soc.	30	Fu, GC	FALSE	FALSE	FALSE	FALSE
7962	10.6023/cjoc1202052	doi.org/10.6023/cjoc1202052	Nickel-Catalyzed Negishi Cross-Coupling Reactions of Secondary Alkylzinc Halides with 6-Chloropurines		Chin. J. Org. Chem.	30	Wang, DC	FALSE	FALSE	FALSE	FALSE
7963	10.1016/j.jphotochem.2012.02.008	doi.org/10.1016/j.jphotochem.2012.02.008	Conversion of aryl C-O to C-C bond through a UV light activation/TEMPO oxidation cascade reaction		J. Photochem. Photobiol. A-Chem.	30	Xia, WJ	FALSE	FALSE	FALSE	FALSE
7964	10.1016/j.poly.2011.01.007	doi.org/10.1016/j.poly.2011.01.007	Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes		Polyhedron	30	Xia, AB	FALSE	FALSE	FALSE	FALSE
7965	10.1080/17415993.2011.628991	doi.org/10.1080/17415993.2011.628991	Synthesis and spectral studies of Ni(II) heterocyclic dithiocarbamates with S2PN chromophore: X-ray crystal structures of bis(1,2,3,4-tetrahydroquinolinecarbodithioato-S,S ')nickel(II) and 1,2,3,4-tetrahydroquinolinecarbodithioato-S,S ')(thiocyanato-N)(triphenylphosphine)nickel(II)		J. Sulfur Chem.	30	Thirumaran, S	FALSE	FALSE	FALSE	FALSE
7966	10.1007/s10562-010-0385-1	doi.org/10.1007/s10562-010-0385-1	Highly Efficient Pd-Catalyzed Cyanation of Aryl Chlorides and Arenesulfonates with Potassium Ferrocyanide in Aqueous Media		Catal. Lett.	30	Huang, J	FALSE	FALSE	FALSE	FALSE
7967	10.1021/jo100352b	doi.org/10.1021/jo100352b	Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex		J. Org. Chem.	30	Sawamura, M	FALSE	FALSE	FALSE	FALSE
7968	10.1039/b919246h	doi.org/10.1039/b919246h	Nickel/magnesium-lanthanum mixed oxide catalyst in the Kumada-coupling		Org. Biomol. Chem.	30	Hell, Z	FALSE	FALSE	FALSE	FALSE
7969	10.1021/ja903880q	doi.org/10.1021/ja903880q	Palladium-Catalyzed Enantioselective alpha-Arylation and alpha-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand		J. Am. Chem. Soc.	30	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
7970	10.1021/ja900805y	doi.org/10.1021/ja900805y	Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides		J. Am. Chem. Soc.	30	Kurahashi, T	FALSE	FALSE	FALSE	FALSE
7971	10.1021/ja902829p	doi.org/10.1021/ja902829p	Cleavage of C-N Bonds in Aniline Derivatives on a Ruthenium Center and Its Relevance to Catalytic C-C Bond Formation		J. Am. Chem. Soc.	30	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
7972	10.1055/s-0028-1087673	doi.org/10.1055/s-0028-1087673	Catalytic Enantioselective alpha-Arylation of Carbonyl Compounds		Synlett	30	Burtoloso, ACB	FALSE	FALSE	FALSE	FALSE
7973	10.1016/j.molcata.2006.06.004	doi.org/10.1016/j.molcata.2006.06.004	Aryl Grignard cross-coupling of aryl chlorides catalysed by new, highly active phosphine/imidazolium nickel(II) complexes		J. Mol. Catal. A-Chem.	30	Labande, A	FALSE	FALSE	FALSE	FALSE
7974	10.1080/00397910600638937	doi.org/10.1080/00397910600638937	Simple synthesis of versatile coumarin scaffolds		Synth. Commun.	30	Lay, L	FALSE	FALSE	FALSE	FALSE
7975	10.1016/j.jorganchem.2004.11.023	doi.org/10.1016/j.jorganchem.2004.11.023	Highly enantioselective catalytic asymmetric ring opening reaction employing the Daniphos ligand		J. Organomet. Chem.	30	Salzer, A	FALSE	FALSE	FALSE	FALSE
7976	10.1021/ol0478133	doi.org/10.1021/ol0478133	Copper-catalyzed anti-stereocontrolled ring-opening of azabicyclic alkenes with grignard reagents		Org. Lett.	30	Arrayas, RG	FALSE	FALSE	FALSE	FALSE
7977	10.1021/ol047854z	doi.org/10.1021/ol047854z	Stereoselective enol tosylation: Preparation of trisubstituted alpha,beta-unsaturated esters		Org. Lett.	30	Baxter, JM	FALSE	FALSE	FALSE	FALSE
7978	10.1055/s-2004-832845	doi.org/10.1055/s-2004-832845	Palladium-catalyzed homocoupling of arylboronic acids and esters using fluoride in aqueous solvents		Synlett	30	Finn, MG	FALSE	FALSE	FALSE	FALSE
7979	10.1021/jo049394t	doi.org/10.1021/jo049394t	Direct preparation of allylic indium(III) reagents from allylic alcohols via a reductive transmetalation of pi-allylnickel(II) with indium(I) iodide		J. Org. Chem.	30	Araki, S	FALSE	FALSE	FALSE	FALSE
7980	10.1016/S0040-4039(03)00191-6	doi.org/10.1016/S0040-4039(03)00191-6	Facile and efficient total synthesis of (+/-)-cryptotanshinone and tanshinone IIA		Tetrahedron Lett.	30	Lu, W	FALSE	FALSE	FALSE	FALSE
7981	10.1351/pac200375010063	doi.org/10.1351/pac200375010063	Unified strategy for the synthesis of C-aryl glycosides		Pure Appl. Chem.	30	Martin, SF	FALSE	FALSE	FALSE	FALSE
7982	10.1021/ja027716+	doi.org/10.1021/ja027716+	Copper-catalyzed Suzuki cross-coupling using mixed nanocluster catalysts		J. Am. Chem. Soc.	30	Rothenberg, G	FALSE	FALSE	FALSE	FALSE
7983	10.1016/S0022-328X(00)00173-X	doi.org/10.1016/S0022-328X(00)00173-X	Kinetic resolution in Pd-catalyzed allylic substitution using the helical PHelix ligand		J. Organomet. Chem.	30	Reetz, MT	FALSE	FALSE	FALSE	FALSE
7984	10.1016/S1381-1169(98)00067-3	doi.org/10.1016/S1381-1169(98)00067-3	Nickel vs. palladium catalysts for coupling reactions of allyl alcohol with soft nucleophiles: activities and deactivation processes		J. Mol. Catal. A-Chem.	30	Mortreux, A	FALSE	FALSE	FALSE	FALSE
7985	10.1016/S0040-4020(98)00603-6	doi.org/10.1016/S0040-4020(98)00603-6	Highly enantioselective benzylic hydroxylation with concave type of (salen)manganese(III) complex		Tetrahedron	30	Katsuki, T	FALSE	FALSE	FALSE	FALSE
7986	10.1016/S0040-4039(96)02329-5	doi.org/10.1016/S0040-4039(96)02329-5	Asymmetric allylic alkylation catalyzed by palladium complexes with a new chiral bisphosphine ligand		Tetrahedron Lett.	30		FALSE	FALSE	FALSE	FALSE
7987	10.1016/0040-4039(96)01302-0	doi.org/10.1016/0040-4039(96)01302-0	Bis(aminophosphine)-nickel complexes as efficient catalysts for alkylation of allylic acetates with stabilized nucleophiles		Tetrahedron Lett.	30		FALSE	FALSE	FALSE	FALSE
7988	10.1039/c39940001923	doi.org/10.1039/c39940001923	TRANSITION-METAL-CATALYZED IPSO-REPLACEMENT REACTIONS OF HETEROAROMATIC PHENOLIC ETHERS BY ZINC AND TIN ORGANOMETALLIC COMPOUNDS		J. Chem. Soc.-Chem. Commun.	30		FALSE	FALSE	FALSE	FALSE
7989	10.1016/0022-328X(93)80158-8	doi.org/10.1016/0022-328X(93)80158-8	RUTHENIUM COMPLEX-CATALYZED ALLYLIC ALKYLATION OF CARBONUCLEOPHILES WITH ALLYLIC CARBONATES		J. Organomet. Chem.	30		FALSE	FALSE	FALSE	FALSE
7990	10.1016/S0040-4020(01)91955-6	doi.org/10.1016/S0040-4020(01)91955-6	SELECTIVE MONO-ARYLATION AND MONO-ALKYLATION OF BIS(ALKYLTHIO)BENZENES - THE IMPORTANCE OF STERIC EFFECTS IN THE NICKEL-CATALYZED CROSS-COUPLING OF ARYL ALKYL SULFIDES WITH GRIGNARD-REAGENTS		Tetrahedron	30	TIECCO, M	FALSE	FALSE	FALSE	FALSE
7991	10.1039/d1nj04008a	doi.org/10.1039/d1nj04008a	An evaluation of palladium-based catalysts for the base-free borylation of alkenyl carboxylates		New J. Chem.	30	Leitch, DC	FALSE	FALSE	FALSE	FALSE
7992	10.1002/hlca.202100110	doi.org/10.1002/hlca.202100110	Teflon Magnetic Stirring Capsules (TMSC) as a Practical and Reusable Delivery System for Sensitive Reagents and Catalysts		Helv. Chim. Acta	30	Mazet, C	FALSE	FALSE	FALSE	FALSE
7993	10.1016/j.tetlet.2021.153270	doi.org/10.1016/j.tetlet.2021.153270	Synthesis of indoles through acceptorless dehydrogenative coupling catalyzed by nickel on silica-alumina		Tetrahedron Lett.	30	Duguet, N; Metay, E	FALSE	FALSE	FALSE	FALSE
7994	10.1016/j.mencom.2021.03.043	doi.org/10.1016/j.mencom.2021.03.043	Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes		Mendeleev Commun.	30	Li, SB	FALSE	FALSE	FALSE	FALSE
7995	10.1021/acscatal.7b02025	doi.org/10.1021/acscatal.7b02025	Silyloxyarenes as Versatile Coupling Substrates Enabled by Nickel-Catalyzed C-O Bond Cleavage		ACS Catal.	30	Montgomery, J	FALSE	FALSE	FALSE	FALSE
7996	10.1021/acs.oprd.7b00185	doi.org/10.1021/acs.oprd.7b00185	Kumada-Corriu Heteroaryl Cross-Coupling for Synthesis of a Pharmaceutical Intermediate: Comparison of Batch Versus Continuous Reaction Modes		Org. Process Res. Dev.	30	Xin, LH	FALSE	FALSE	FALSE	FALSE
7997	10.1021/acs.orglett.7b01549	doi.org/10.1021/acs.orglett.7b01549	Nickel-Catalyzed Amination of Aryl 2-Pyridyl Ethers via Cleavage of the Carbon-Oxygen Bond		Org. Lett.	30	Wang, ZX	FALSE	FALSE	FALSE	FALSE
7998	10.1021/acs.joc.7b00419	doi.org/10.1021/acs.joc.7b00419	Stereospecific Hydrogenolysis of Lactones: Application to the Total Syntheses of (R)-ar-Himachalene and (R)-Curcumene		J. Org. Chem.	30	de Figueiredo, RM; Campagne, JM	FALSE	FALSE	FALSE	FALSE
7999	10.1007/s13738-017-1050-z	doi.org/10.1007/s13738-017-1050-z	Ullmann homocoupling of aryl iodides catalyzed by gold nanoparticles stabilized on magnetic mesoporous silica		J. Iran Chem. Soc.	30	Rostamizadeh, S	FALSE	FALSE	FALSE	FALSE
8000	10.1002/chem.201606046	doi.org/10.1002/chem.201606046	Enantioselective Synthesis of Oxetanes Bearing All-Carbon Quaternary Stereocenters via Iridium-Catalyzed C-C Bond-Forming Transfer Hydrogenation		Chem.-Eur. J.	30	Krische, MJ	FALSE	FALSE	FALSE	FALSE
8001	10.3987/COM-16-S(S)21	doi.org/10.3987/COM-16-S(S)21	PALLADIUM-CATALYZED CROSS-COUPLING OF ARYL CHLORIDES WITH ARYLSILATRANES		Heterocycles	30	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
8002	10.1016/j.molcata.2016.10.033	doi.org/10.1016/j.molcata.2016.10.033	Suzuki-Miyaura coupling reactions using novel metal oxide supported ionic palladium catalysts		J. Mol. Catal. A-Chem.	30	Gruber-Woelfler, H	FALSE	FALSE	FALSE	FALSE
8003	10.1016/j.tetlet.2016.11.044	doi.org/10.1016/j.tetlet.2016.11.044	A general Bronsted acid-catalyzed allylation of benzhydryl alcohols		Tetrahedron Lett.	30	Solshan, Y	FALSE	FALSE	FALSE	FALSE
8004	10.1021/acs.orglett.6b02977	doi.org/10.1021/acs.orglett.6b02977	Synthesis of Non-natural, Frame-Shifted Isoprenoid Diphosphate Analogues		Org. Lett.	30	Temple, KJ	FALSE	FALSE	FALSE	FALSE
8005	10.1002/mrc.4477	doi.org/10.1002/mrc.4477	H-1 and C-13 NMR spectral assignments of novel adamantyl and di-adamantyl derivatives of 1,2-dihydroxynaphthalenes, 1,8-dihydroxynaphthalenes, 2,3-dihydroxynaphthalenes, 2,6-dihydroxynaphthalenes and 2,7-dihydroxynaphthalenes		Magn. Reson. Chem.	30	Peterson, IV	FALSE	FALSE	FALSE	FALSE
8006	10.1021/acs.orglett.6b01758	doi.org/10.1021/acs.orglett.6b01758	Benchtop Delivery of Ni(cod)(2) using Paraffin Capsules		Org. Lett.	30	Garg, NK	FALSE	FALSE	FALSE	FALSE
8007	10.1126/science.aag0209	doi.org/10.1126/science.aag0209	Aryl amination using ligand-free Ni(II) salts and photoredox catalysis		Science	30	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
8008	10.1039/d0cc05895e	doi.org/10.1039/d0cc05895e	Boronic acid-mediated ring-opening and Ni-catalyzed arylation of 1-arylcyclopropyl tosylates	Efficient copper-catalyzed cross-coupling reactions of non-activated alkyl chlorides, including primary, secondary, and tertiary alkyl chlorides, with phenyl Grignard reagents were achieved. Preparation of phenylmagnesium bromide in 2-methyltetrahydrofuran is critical for the success of the reaction. This protocol expands the synthetic toolbox for the construction of C-C bonds of non-activated primary, secondary, and tertiary alkyl chlorides via copper-catalyzed cross-coupling. (C) 2016 Elsevier Ltd. All rights reserved.	Chem. Commun.	29	Rousseaux, SAL	FALSE	FALSE	FALSE	FALSE
8009	10.1038/s41929-020-0473-6	doi.org/10.1038/s41929-020-0473-6	Overcoming limitations in dual photoredox/nickel-catalysed C-N cross-couplings due to catalyst deactivation	Three neutral pyridine-based selone compounds, 2,6-bis(1-methylimidazole-2-selone)pyridine (Bmsp), 2,6-bis(1-ethylimidazole-2-selone)pyridine (Besp) and 2,6-bis(1-isopropylimidazole-2-selone)pyridine (Bpsp) have been synthesized and characterized. Reactions of HAuCl4 with pyridine-based selone ligands result in the formation of the complexes [Au(L)Cl-2](+)[AuCl2] (L = Bmsp (1); L = Besp (2) and L = Bpsp (3)), respectively. All compounds have been characterized by elemental analysis, NMR IR spectra and electrospray ionization mass spectroscopic (ESI-MS). The molecular structure of 2 has been determined by X-ray crystallography. Moreover, the gold complexes are efficiently catalyzed nitroarenes reduction to aromatic amines in the presence of sodium tetrahydroborate reducing agent in water. (C) 2016 Elsevier B.V. All rights reserved.	Nat. Catal.	29	Pieber, B	FALSE	FALSE	FALSE	FALSE
8010	10.1039/c9gc04306c	doi.org/10.1039/c9gc04306c	Simplifying levulinic acid conversion towards a sustainable biomass valorisation	We report the catalytic alkylation of amide derivatives, which relies on the use of nonprecious metal catalysis. Amide derivatives are treated with organozinc reagents, utilizing nickel catalysis, to yield ketone products. The methodology is performed at ambient temperature and is tolerant of variation in both coupling partners. A precursor to a nanomolar glucagon receptor modulator was synthesized using the methodology, underscoring the mild nature of this chemistry and its potential utility in pharmaceutical synthesis. These studies are expected to further promote the use of amides as synthetic building blocks.	Green Chem.	29	Giordano, C	FALSE	FALSE	FALSE	FALSE
8011	10.1016/j.tetlet.2019.151057	doi.org/10.1016/j.tetlet.2019.151057	Palladium-catalyzed mono-gamma-arylation of 7-methoxy-4-methylcoumarin		Tetrahedron Lett.	29	Malachowski, WP	FALSE	FALSE	FALSE	FALSE
8012	10.1016/j.tetlet.2019.150991	doi.org/10.1016/j.tetlet.2019.150991	Palladium-catalyzed carbonylative/decarboxylative cross-coupling of alpha-bromo-ketones with allylic alcohols to gamma,delta-unsaturated ketones		Tetrahedron Lett.	29	Wu, XF	FALSE	FALSE	FALSE	FALSE
8013	10.1002/ajoc.201900409	doi.org/10.1002/ajoc.201900409	Copper-Catalyzed Selective Cross-Couplings of Propargylic Ethers with Aryl Grignard Reagents		Asian J. Org. Chem.	29	Li, ZP	FALSE	FALSE	FALSE	FALSE
8014	10.3762/bjoc.15.48	doi.org/10.3762/bjoc.15.48	Dirhodium(II)-catalyzed [3+2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives		Beilstein J. Org. Chem.	29	Wang, YH	FALSE	FALSE	FALSE	FALSE
8015	10.1016/j.ica.2018.06.045	doi.org/10.1016/j.ica.2018.06.045	Structural analysis of (5-methyl-[1,3,5]-dithiazinan-2-yl)phosphines and their oxides. N-Borane adducts as conformational probes		Inorg. Chim. Acta	29	Flores-Parra, A	FALSE	FALSE	FALSE	FALSE
8016	10.1002/cctc.201800486	doi.org/10.1002/cctc.201800486	The Rhodium Catalysed Direct Conversion of Phenols to Primary Cyclohexylamines		ChemCatChem	29	De Vos, DE	FALSE	FALSE	FALSE	FALSE
8017	10.1039/c7ob02386c	doi.org/10.1039/c7ob02386c	Ligand-free, palladacycle-facilitated Suzuki coupling of hindered 2-arylbenzothiazole derivatives yields potent and selective COX-2 inhibitors		Org. Biomol. Chem.	29	Cushman, M	FALSE	FALSE	FALSE	FALSE
8018	10.1039/c7cc08670a	doi.org/10.1039/c7cc08670a	Practical synthesis of pharmaceutically relevant molecules enriched in sp(3) character		Chem. Commun.	29	Jamieson, C	FALSE	FALSE	FALSE	FALSE
8019	10.1021/acs.orglett.7b03059	doi.org/10.1021/acs.orglett.7b03059	Synthesis of N-Substituted Sulfamate Esters from Sulfamic Acid Salts by Activation with Triphenylphosphine Ditriflate		Org. Lett.	29	Roizen, JL	FALSE	FALSE	FALSE	FALSE
8020	10.1016/j.jorganchem.2017.07.006	doi.org/10.1016/j.jorganchem.2017.07.006	Copper catalysed alkylation of heteroaryl chloride via migratory insertion of carbenes		J. Organomet. Chem.	29	Chikhalia, KH	FALSE	FALSE	FALSE	FALSE
8021	10.1002/anie.201403894	doi.org/10.1002/anie.201403894	Direct Functionalization with Complete and Switchable Positional Control: Free Phenol as a Role Model		Angew. Chem.-Int. Edit.	29	Glorius, F	FALSE	FALSE	FALSE	FALSE
8022	10.1039/c4ob00744a	doi.org/10.1039/c4ob00744a	Design, synthesis, and fungicidal activity of novel carboxylic acid amides represented by N-benzhydryl valinamode carbamates		Org. Biomol. Chem.	29	Bian, Q	FALSE	FALSE	FALSE	FALSE
8023	10.1039/c4ob00813h	doi.org/10.1039/c4ob00813h	Copper-catalysed direct radical alkenylation of alkyl bromides		Org. Biomol. Chem.	29	Lei, AW	FALSE	FALSE	FALSE	FALSE
8024	10.5059/yukigoseikyokaishi.71.576	doi.org/10.5059/yukigoseikyokaishi.71.576	Nickel-Catalyzed Direct Coupling of Heteroarenes		J. Synth. Org. Chem. Jpn.	29	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
8025	10.1016/j.tetlet.2012.12.078	doi.org/10.1016/j.tetlet.2012.12.078	Tandem reaction between chalcone epoxides and 2-naphthyl ethers to construct complex naphtho[2,1-b]furans		Tetrahedron Lett.	29	Huo, CD	FALSE	FALSE	FALSE	FALSE
8026	10.1016/j.tetlet.2012.06.048	doi.org/10.1016/j.tetlet.2012.06.048	An unprecedented iron-catalyzed cross-coupling of primary and secondary alkyl Grignard reagents with non-activated aryl chlorides		Tetrahedron Lett.	29	Perry, MC	FALSE	FALSE	FALSE	FALSE
8027	10.1055/s-0031-1290885	doi.org/10.1055/s-0031-1290885	Efficient Pyrimidone-Promoted Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction		Synlett	29	Zhang, HP	FALSE	FALSE	FALSE	FALSE
8028	10.1021/ja300031w	doi.org/10.1021/ja300031w	Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group		J. Am. Chem. Soc.	29	Fu, GC	FALSE	TRUE	FALSE	FALSE
8029	10.1016/j.tetlet.2011.07.023	doi.org/10.1016/j.tetlet.2011.07.023	Synthesis of N-acyl-N,O-acetals from N-aryl amides and acetals in the presence of TMSOTf		Tetrahedron Lett.	29	Downey, CW	FALSE	FALSE	FALSE	FALSE
8030	10.1002/rcm.4847	doi.org/10.1002/rcm.4847	Fragmentation patterns of novel dithiocarbamate derivatives with pharmaceutical activity under electrospray ionization tandem mass spectrometry conditions		Rapid Commun. Mass Spectrom.	29	Sha, YW	FALSE	FALSE	FALSE	FALSE
8031	10.1039/c0cc03064c	doi.org/10.1039/c0cc03064c	Room-temperature nickel-catalysed cross-couplings of aryl chlorides with arylzincs		Chem. Commun.	29	Wang, ZX	FALSE	FALSE	FALSE	FALSE
8032	10.1039/c1cc12240a	doi.org/10.1039/c1cc12240a	A versatile palladium catalyst system for Suzuki-Miyaura coupling of alkenyl tosylates and mesylates		Chem. Commun.	29	Kwong, FY	FALSE	FALSE	FALSE	FALSE
8033	10.1016/j.bmcl.2010.07.130	doi.org/10.1016/j.bmcl.2010.07.130	Synthesis and biological evaluation of novel coumarin-based inhibitors of Cdc25 phosphatases		Bioorg. Med. Chem. Lett.	29	Kirsch, G	FALSE	FALSE	FALSE	FALSE
8034	10.1021/ja1035557	doi.org/10.1021/ja1035557	Decarboxylative Benzylations of Alkynes and Ketones		J. Am. Chem. Soc.	29	Tunge, JA	FALSE	FALSE	FALSE	FALSE
8035	10.1016/j.tetlet.2010.01.020	doi.org/10.1016/j.tetlet.2010.01.020	Selenium dioxide-mediated methoxyhydroxylation of cyclic arylolefin		Tetrahedron Lett.	29	Chang, MY	FALSE	FALSE	FALSE	FALSE
8036	10.1016/j.catcom.2009.09.024	doi.org/10.1016/j.catcom.2009.09.024	Nickel(0) powder catalysis in Suzuki-Miyaura cross-coupling reaction		Catal. Commun.	29	Cho, CS	FALSE	FALSE	FALSE	FALSE
8037	10.1021/ja809220j	doi.org/10.1021/ja809220j	Catalytic Homologation of Cycloalkanones with Substituted Diazomethanes. Mild and Efficient Single-Step Access to alpha-Tertiary and alpha-Quaternary Carbonyl Compounds		J. Am. Chem. Soc.	29	Kingsbury, JS	FALSE	FALSE	FALSE	FALSE
8038	10.1002/anie.200804888	doi.org/10.1002/anie.200804888	Catalytic Asymmetric Cross-Couplings of Racemic alpha-Bromoketones with Arylzinc Reagents		Angew. Chem.-Int. Edit.	29	Fu, GC	FALSE	FALSE	FALSE	FALSE
8039	10.1021/ja807188s	doi.org/10.1021/ja807188s	Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines		J. Am. Chem. Soc.	29	Xiao, JL	FALSE	FALSE	FALSE	FALSE
8040	10.1021/ol800837z	doi.org/10.1021/ol800837z	A mild, one-pot synthesis of 4-quinolones via sequential pd-catalyzed amidation and base-promoted cyclization		Org. Lett.	29	Huang, J	FALSE	FALSE	FALSE	FALSE
8041	10.1021/ol800832n	doi.org/10.1021/ol800832n	Sequential Ni-catalyzed borylation and cross-coupling of aryl halides via in situ prepared neopentylglycolborane		Org. Lett.	29	Percec, V	FALSE	FALSE	FALSE	FALSE
8042	10.1021/ol702499h	doi.org/10.1021/ol702499h	Direct aminoalkylation of arenes and hetarenes via Ni-Catalyzed Negishi cross-coupling reactions		Org. Lett.	29	Knochel, P	FALSE	FALSE	FALSE	FALSE
8043	10.1002/pola.21837	doi.org/10.1002/pola.21837	Multiblock copolymers of poly(2,5-benzophenone) and disulfonated poly(arylene ether sulfone) for proton-exchange membranes. I. Synthesis and characterization		J. Polym. Sci. Pol. Chem.	29	McGrath, JE	FALSE	FALSE	FALSE	FALSE
8044	10.1351/pac200678020377	doi.org/10.1351/pac200678020377	New technologies in catalysis using base metals		Pure Appl. Chem.	29	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
8045	10.1002/anie.200462672	doi.org/10.1002/anie.200462672	Gold catalysis: Proof of arene oxides as intermediates in the phenol synthesis		Angew. Chem.-Int. Edit.	29	Hashmi, ASK	FALSE	FALSE	FALSE	FALSE
8046	10.1246/cl.2004.1322	doi.org/10.1246/cl.2004.1322	A study on the electronic effect of reactions of pi-allylpalladiums using 2-arylsulfonyloxy-3-chloropropenes with ethyl malonate and their synthetic utilization		Chem. Lett.	29	Yoshimatsu, M	FALSE	FALSE	FALSE	FALSE
8047	10.1021/ja036947t	doi.org/10.1021/ja036947t	The first general palladium catalyst for the Suzuki-Miyaura and carbonyl enolate coupling of aryl arenesulfonates		J. Am. Chem. Soc.	29	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8048	10.1016/S0040-4039(02)02666-7	doi.org/10.1016/S0040-4039(02)02666-7	General entries to C-aryl glycosides. Formal synthesis of galtamycinone		Tetrahedron Lett.	29	Martin, SF	FALSE	FALSE	FALSE	FALSE
8049	10.1016/S0040-4039(02)02643-6	doi.org/10.1016/S0040-4039(02)02643-6	[2+2+2]-Co-cyclotrimerization 6-alkynylpurines with diynes: a method for preparation of 6-arylpurines		Tetrahedron Lett.	29	Kotora, M	FALSE	FALSE	FALSE	FALSE
8050	10.1007/BF03184324	doi.org/10.1007/BF03184324	Cross-coupling reaction of cy-clopropylboronic acids with aryl omega-halo-oxo-perfluoroalkyl-sulfonates		Chin. Sci. Bull.	29	Deng, MZ	FALSE	FALSE	FALSE	FALSE
8051	10.1016/S0022-328X(01)00764-1	doi.org/10.1016/S0022-328X(01)00764-1	Transition metal chemistry of phosphorus based ligands: synthesis and transition metal chemistry of N,N '-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)(3){Ph2PN(Me)CH2CH2(Me)NPPh2}]		J. Organomet. Chem.	29	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
8052	10.1016/S0022-328X(00)00164-9	doi.org/10.1016/S0022-328X(00)00164-9	Nickel-catalyzed allylation of lithium 1-alkynyl(trialkoxy)borates with 1,3-disubstituted allyl carbonates		J. Organomet. Chem.	29	Deng, MZ	FALSE	FALSE	FALSE	FALSE
8053	10.1039/a906589j	doi.org/10.1039/a906589j	A formal synthesis of (+)-pyripyropene A using a biomimetic epoxy-olefin cyclisation: effect of epoxy alcohol/ether on cyclisation efficiency		J. Chem. Soc.-Perkin Trans. 1	29	Aggarwal, VK	FALSE	FALSE	FALSE	FALSE
8054	10.1016/S0022-328X(98)00679-2	doi.org/10.1016/S0022-328X(98)00679-2	Stereochemistry in palladium- and nickel-catalyzed addition of phenylmagnesium bromide to unsaturated carbohydrates		J. Organomet. Chem.	29	Sinou, D	FALSE	FALSE	FALSE	FALSE
8055	10.1016/S0040-4039(98)00768-0	doi.org/10.1016/S0040-4039(98)00768-0	Diphenylphosphinooxazoline ligands with a chiral binaphthyl backbone for Pd-catalyzed allylic alkylation		Tetrahedron Lett.	29	Ikeda, I	FALSE	FALSE	FALSE	FALSE
8056	10.1080/00397919208021314	doi.org/10.1080/00397919208021314	A NEW EFFICIENT AND STEREOSELECTIVE SYNTHESIS OF 1,3E,5Z-UNDECATRIENE		Synth. Commun.	29	ALEXAKIS, A	FALSE	FALSE	FALSE	FALSE
8057	10.1016/S0040-4020(01)89243-7	doi.org/10.1016/S0040-4020(01)89243-7	A TOTAL SYNTHESIS OF (+/-)-ZOAPATANOL AND DEMETHYL-ORF13811		Tetrahedron	29	KOCIENSKI, PJ	FALSE	FALSE	FALSE	FALSE
8058	10.1021/ja00226a067	doi.org/10.1021/ja00226a067	AN UNUSUALLY LOWER BARRIER TO REDUCTIVE ELIMINATION OF AN 18-ELECTRON ETA-3-ALLYL(ORGANO)NICKEL(II) COMPLEX THAN THOSE OF A 16-ELECTRON ETA-3-ALLYL COUNTERPART AND A 16-ELECTRON ETA-1-ALLYL ISOMER		J. Am. Chem. Soc.	29	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
8059	10.1021/jo00205a042	doi.org/10.1021/jo00205a042	SYNTHESIS OF ACYCLIC, CIS OLEFINIC PHEROMONES BY WAY OF NICKEL-CATALYZED GRIGNARD REACTIONS		J. Org. Chem.	29	WENKERT, E	FALSE	FALSE	FALSE	FALSE
8060	10.1021/ja00488a030	doi.org/10.1021/ja00488a030	STEREOSELECTIVE CONVERSION OF KETO GROUPS INTO METHYL VINYL QUATERNARY CARBON CENTERS		J. Am. Chem. Soc.	29		FALSE	FALSE	FALSE	FALSE
8061	10.1021/acs.jpclett.1c04099	doi.org/10.1021/acs.jpclett.1c04099	Volcano Plots of Reaction Yields in Cross-Coupling Catalysis		J. Phys. Chem. Lett.	29	Zhang, RQ	FALSE	FALSE	FALSE	FALSE
8062	10.1055/a-1657-5543	doi.org/10.1055/a-1657-5543	Diastereoselective Pd-Catalyzed Decarboxylative Allylation To Construct Quaternary Stereocenters Using Sulfinimine as the -Directing Group		Synlett	29	Yang, G; Luo, YH	FALSE	FALSE	FALSE	FALSE
8063	10.1039/d1cc02696h	doi.org/10.1039/d1cc02696h	Visible light-induced one-pot synthesis of CF3/CF2-substituted cyclobutene derivatives		Chem. Commun.	29	Xu, DW; Guo, H	FALSE	FALSE	FALSE	FALSE
8064	10.1021/acs.orglett.1c01103	doi.org/10.1021/acs.orglett.1c01103	Rh-Catalyzed General Method for Directed C-H Functionalization via Decarbonylation of in-Situ-Generated Acid Fluorides from Carboxylic Acids		Org. Lett.	29	Ren, YX; Su, WP	FALSE	FALSE	FALSE	FALSE
8065	10.1021/acs.orglett.7b01510	doi.org/10.1021/acs.orglett.7b01510	Pd-Catalyzed Desulfonative Cross-Coupling of Benzylic Sulfone Derivatives with 1,3-Oxazoles		Org. Lett.	29	Nambo, M; Crudden, CM	FALSE	FALSE	FALSE	FALSE
8066	10.1021/acs.orglett.7b01128	doi.org/10.1021/acs.orglett.7b01128	Fe/Cu-Mediated One-Pot Ketone Synthesis		Org. Lett.	29	Kishi, Y	FALSE	FALSE	FALSE	FALSE
8067	10.1039/c7ob00175d	doi.org/10.1039/c7ob00175d	Palladium/zinc co-catalyzed asymmetric transfer hydrogenation of oxabenzonorbornadienes with alcohols as hydrogen sources		Org. Biomol. Chem.	29	Chen, JC; Fan, BM	FALSE	FALSE	FALSE	FALSE
8068	10.1002/chem.201601320	doi.org/10.1002/chem.201601320	Cross-Electrophile Coupling of Vinyl Halides with Alkyl Halides		Chem.-Eur. J.	29	Weix, DJ	FALSE	TRUE	FALSE	FALSE
8069	10.1007/s10593-016-1856-0	doi.org/10.1007/s10593-016-1856-0	General and efficient one-pot synthesis of N-substituted 7-bromo-2,3-dihydro-1H-pyrrolo[3,4-b]quinolin-1-ones		Chem. Heterocycl. Compds.	29	Li, Y	FALSE	FALSE	FALSE	FALSE
8070	10.1055/a-1337-5504	doi.org/10.1055/a-1337-5504	Nickel-Catalyzed C-F/N-H Annulation of 2-(2-Fluoroaryl) N-Heteroaromatic Compounds with Alkynes: Activation of C-F Bonds	The first nickel-catalyzed ortho-sulfonylation of C(sp(2))-H bonds with sodium sulfinates directed by (pyridin-2-yl) isopropylamine (PIP-amine) is described. This strategy exhibits a broad substrate scope and good functional group tolerance with high monosulfonylation selectivity. Besides arenes and heteroarenes, the reaction can also be extended to alkenes, providing diverse diaryl and alkyl aryl sulfones in high yields. Furthermore, a plausible Ni(I)/Ni(III) mechanism is outlined based on our experimental results and related precedents.	Synthesis	28	Chatani, N	FALSE	FALSE	FALSE	FALSE
8071	10.1016/j.inoche.2020.108143	doi.org/10.1016/j.inoche.2020.108143	Nanoporous palladium catalyzed one-pot synthesis N-alkyl amines by hydrogen transfer reaction under mild conditions	A metal free, regio and stereoselective syntheses of allylic thioethers using allyl iodides and aryl or alkyl disulfides as coupling partners is described. The densely functionalized allyl iodides having different stereochemistry (E & Z) reacted well with a variety of disulfides in a regio and stereoselective manner providing the resulting allyl aryl thioethers in 62-92% yields.	Inorg. Chem. Commun.	28	Li, ZW	FALSE	FALSE	FALSE	FALSE
8072	10.1002/ejoc.202000417	doi.org/10.1002/ejoc.202000417	Br vs. TsO Chemoselective Suzuki-Miyaura Cross-Coupling Reaction on Nicotinaldehyde Moiety for the Preparation of 2,3,5-Trisubstituted Pyridines	Professor Masakatsu Shibasaki's distinguished scientific accomplishments in the field of asymmetric catalysis are compiled here with particular emphasis on multimetallic cooperative catalysis. In 1992, he discovered revolutionary multimetallic chiral complexes composed of a rare earth metal, alkaline metals, and 1,1'-binaphthyl-2-binaphthols (BINOLs) that promoted a number of enantioselective reactions in a highly efficient and stereoselective manner. This finding resulted in chiral multimetallic catalysts that have significantly advanced the field of enantioselective catalysis.	Eur. J. Org. Chem.	28	Voisin-Chiret, AS	FALSE	FALSE	FALSE	FALSE
8073	10.1016/j.cclet.2019.04.013	doi.org/10.1016/j.cclet.2019.04.013	A ketone-functionalized aromatic saddle as a potential building block for negatively curved carbon nanobelts		Chin. Chem. Lett.	28	Miao, Q	FALSE	FALSE	FALSE	FALSE
8074	10.1021/jacs.9b02751	doi.org/10.1021/jacs.9b02751	Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines		J. Am. Chem. Soc.	28	Chatani, N; Tobisu, M	FALSE	FALSE	FALSE	FALSE
8075	10.1039/c9dt00668k	doi.org/10.1039/c9dt00668k	Simplified and versatile access to low valent Ni complexes by metal-free reduction of Ni-II precursors		Dalton Trans.	28	Breuil, PAR	FALSE	FALSE	FALSE	FALSE
8076	10.1080/00397911.2019.1566474	doi.org/10.1080/00397911.2019.1566474	Copper-catalyzed one-pot synthesis of alkynylphophonates		Synth. Commun.	28	Song, WZ; Zheng, YB	FALSE	FALSE	FALSE	FALSE
8077	10.1039/c8cc05458d	doi.org/10.1039/c8cc05458d	Stereoselective aldol reactions using pseudo C-2 symmetric 1-benzyl-4-(trifluoromethyl)-piperidine-2,6-dione		Chem. Commun.	28	Yamazaki, T	FALSE	FALSE	FALSE	FALSE
8078	10.1055/s-0036-1589164	doi.org/10.1055/s-0036-1589164	Diastereoselective Synthesis of Functionalized Indolines Using in situ Generated Allyl Boronic Species		Synlett	28	Pastre, JC	FALSE	FALSE	FALSE	FALSE
8079	10.1021/acs.orglett.7b03699	doi.org/10.1021/acs.orglett.7b03699	Vitamin B-12 Catalyzed Atom Transfer Radical Addition		Org. Lett.	28	Proinsias, KO; Gryko, D	FALSE	FALSE	FALSE	FALSE
8080	10.1246/cl.170897	doi.org/10.1246/cl.170897	Tishchenko Reaction Using Substoichiometric Amount of Metallic Zinc		Chem. Lett.	28	Akiyama, T	FALSE	FALSE	FALSE	FALSE
8081	10.1021/acs.oprd.7b00253	doi.org/10.1021/acs.oprd.7b00253	Development of a Kilogram-Scale Process for the Enantioselective Synthesis of 3-lsopropenyl-cyclohexan-1-one via Rh/DTBM-SEGPHOS-Catalyzed Asymmetric Hayashi Addition Enabled by 1,3-Diol Additives		Org. Process Res. Dev.	28	Simmons, EM; Mudryk, B	FALSE	FALSE	FALSE	FALSE
8082	10.1515/znb-2015-0053	doi.org/10.1515/znb-2015-0053	Novel conformationally constrained pyrazole derivatives as potential anti-cancer agents		Z.Naturforsch.(B)	28	Kasiotis, KM	FALSE	FALSE	FALSE	FALSE
8083	10.1080/00397911.2014.965330	doi.org/10.1080/00397911.2014.965330	STUDY ON THE REGIOSELECTIVITY OF RHODIUM-CATALYZED RING OPENING REACTIONS OF C-1-SUBSTITUTED 7-OXABENZONORBORNADIENES WITH BORONIC ACIDS		Synth. Commun.	28	Tam, W	FALSE	FALSE	FALSE	FALSE
8084	10.1021/jo502260x	doi.org/10.1021/jo502260x	Suzuki-Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates		J. Org. Chem.	28	Molander, GA	FALSE	FALSE	FALSE	FALSE
8085	10.5012/bkcs.2014.35.8.2304	doi.org/10.5012/bkcs.2014.35.8.2304	Synthesis and In vivo Evaluation of 5-Methoxy-2-(phenylethynyl)quinoline (MPEQ) and [C-11]MPEQ Targeting Metabotropic Glutamate Receptor 5 (mGluR5)		Bull. Korean Chem. Soc.	28	Lee, HY	FALSE	FALSE	FALSE	FALSE
8086	10.1039/c4cc04962d	doi.org/10.1039/c4cc04962d	The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2		Chem. Commun.	28	Sakaki, S	FALSE	FALSE	FALSE	FALSE
8087	10.1021/jo4011415	doi.org/10.1021/jo4011415	Development of Second Generation Gold-Supported Palladium Material with Low-Leaching and Recyclable Characteristics in Aromatic Amination		J. Org. Chem.	28	Arisawa, M	FALSE	FALSE	FALSE	FALSE
8088	10.1002/cjoc.201300340	doi.org/10.1002/cjoc.201300340	Cobalt-catalyzed Selective C - F Bond Activation and Alkylation of Polyfluoroaryl Imines		Chin. J. Chem.	28	Li, XY	FALSE	FALSE	FALSE	FALSE
8089	10.1039/c2cc35823a	doi.org/10.1039/c2cc35823a	Nickel-catalyzed alpha-glycosylation of C(1)-hydroxyl D-myo-inositol: a formal synthesis of mycothiol		Chem. Commun.	28	Nguyen, HM	FALSE	FALSE	FALSE	FALSE
8090	10.1246/cl.2012.1503	doi.org/10.1246/cl.2012.1503	Synthesis of Unsymmetrical Diarylethynes by Pd(0)/Cu(I)-cocatalyzed Sila-Sonogashira-Hagihara Coupling Reactions of Alkynylsilanes with Aryl Tosylates or Mesylates		Chem. Lett.	28	Nishihara, Y	FALSE	FALSE	FALSE	FALSE
8091	10.6023/cjoc201206020	doi.org/10.6023/cjoc201206020	Study on the Dehydrate Amination of Alcohols in Water Using Sulfonic Calix[6]resorcinarene		Chin. J. Org. Chem.	28	Yan, LQ	FALSE	FALSE	FALSE	FALSE
8092	10.1071/CH12044	doi.org/10.1071/CH12044	Synthesis, Solid-state Structures, Solution Behaviour and Catalysis Studies of Nickel Complexes of Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligands		Aust. J. Chem.	28	Brown, DH	FALSE	FALSE	FALSE	FALSE
8093	10.1126/science.1200437	doi.org/10.1126/science.1200437	Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers		Science	28	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
8094	10.1002/ejoc.201000251	doi.org/10.1002/ejoc.201000251	RETRACTED: Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates in Water (Retracted article. See May, pg. 5722, 2010)		Eur. J. Org. Chem.	28	Plenio, H	FALSE	FALSE	FALSE	FALSE
8095	10.1134/S1070427210050253	doi.org/10.1134/S1070427210050253	Polymerization of styrene and methyl methacrylate using a catalytic system based on 1,2-bis(diphenylphosphino)ethanenickel dibromide		Russ. J. Appl. Chem.	28	Valetova, NB	FALSE	FALSE	FALSE	FALSE
8096	10.1021/ja906477r	doi.org/10.1021/ja906477r	Suzuki-Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates		J. Am. Chem. Soc.	28	Garg, NK	FALSE	FALSE	FALSE	FALSE
8097	10.1002/anie.200900892	doi.org/10.1002/anie.200900892	Nickel-Catalyzed Formation of a Carbon-Nitrogen Bond at the beta Position of Saturated Ketones		Angew. Chem.-Int. Edit.	28	Ueno, S	FALSE	FALSE	FALSE	FALSE
8098	10.1021/jm701390c	doi.org/10.1021/jm701390c	Nitrite anion: The key intermediate in alkyl nitrates degradative mechanism		J. Med. Chem.	28	Grossi, L	FALSE	FALSE	FALSE	FALSE
8099	10.1021/ja0713431	doi.org/10.1021/ja0713431	Ruthenium-catalyzed carbon-carbon bond formation via the cleavage of an unreactive aryl carbon-nitrogen bond in aniline derivatives with organoboronates		J. Am. Chem. Soc.	28	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
8100	10.1016/j.tet.2007.03.061	doi.org/10.1016/j.tet.2007.03.061	A practical palladium catalyzed dehalogenation of aryl halides and alpha-haloketones		Tetrahedron	28	Zhang, H	FALSE	FALSE	FALSE	FALSE
8101	10.1016/j.tetlet.2006.08.085	doi.org/10.1016/j.tetlet.2006.08.085	Room temperature Ni-catalyzed reduction of aryl tosylates by borane hydrides		Tetrahedron Lett.	28	Kogan, V	FALSE	FALSE	FALSE	FALSE
8102	10.1021/op060083p	doi.org/10.1021/op060083p	Development of a scalable synthetic route towards a thrombin inhibitor, LB30057		Org. Process Res. Dev.	28	Shin, H	FALSE	FALSE	FALSE	FALSE
8103	10.1002/jccs.200500119	doi.org/10.1002/jccs.200500119	Microwave-assisted synthesis of difuran and furan-thiophene via Suzuki coupling		J. Chin. Chem. Soc.	28	Tsai, TYR	FALSE	FALSE	FALSE	FALSE
8104	10.1016/j.tetlet.2005.06.016	doi.org/10.1016/j.tetlet.2005.06.016	Convenient phosphorus tribromide induced syntheses of substituted 1-arylmethylnaphthalenes from 1-tetralone derivatives		Tetrahedron Lett.	28	Panda, G	FALSE	FALSE	FALSE	FALSE
8105	10.1016/j.tetlet.2005.03.203	doi.org/10.1016/j.tetlet.2005.03.203	Synthesis of 4-substituted tetrahydropyridines by cross-coupling of enol phosphates		Tetrahedron Lett.	28	Begtrup, M	FALSE	FALSE	FALSE	FALSE
8106	10.1021/ol050608i	doi.org/10.1021/ol050608i	Arylation of diarylamines catalyzed by Ni(II)-PPh3 system		Org. Lett.	28	Chen, C	FALSE	FALSE	FALSE	FALSE
8107	10.1002/adsc.200404150	doi.org/10.1002/adsc.200404150	Room temperature nickel (0)-catalyzed Suzuki-Miyaura cross-couplings of activated alkenyl tosylates: Efficient synthesis of 4-substituted coumarins and 4-substituted 2(5H)-furanones		Adv. Synth. Catal.	28	Tang, ZY	FALSE	FALSE	FALSE	FALSE
8108	10.1021/jo026421b	doi.org/10.1021/jo026421b	Cobalt-catalyzed direct electrochemical cross-coupling between aryl or heteroaryl halides and allylic acetates or carbonates		J. Org. Chem.	28	Gosmini, C	FALSE	FALSE	FALSE	FALSE
8109	10.1039/b305617a	doi.org/10.1039/b305617a	A novel and effective Ni complex catalyst system for the coupling reactions of carbon dioxide and epoxides		Chem. Commun.	28	Xia, CG	FALSE	FALSE	FALSE	FALSE
8110	10.1021/ol025563p	doi.org/10.1021/ol025563p	P-chirogenic binaphthyl-substituted monophosphines: Synthesis and use in enolate vinylation/arylation reactions		Org. Lett.	28	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8111	10.1021/ol017300l	doi.org/10.1021/ol017300l	Ni-catalyzed highly regio- and chemoselective cocycloaddition of nonconjugated diynes with 1,3-diynes: A novel method for polysubstituted arylalkynes		Org. Lett.	28	Cheng, CH	FALSE	FALSE	FALSE	FALSE
8112	10.1080/02678290110078793	doi.org/10.1080/02678290110078793	New liquid crystalline di- and tetra-acrylates for network formation		Liq. Cryst.	28	Giesa, R	FALSE	FALSE	FALSE	FALSE
8113	10.1016/S1387-1609(00)01138-5	doi.org/10.1016/S1387-1609(00)01138-5	Palladium-catalysed symmetrical and unsymmetrical coupling of aryl halides		Comptes Rendus Acad. Sci. Ser. II C	28	Lemaire, M	FALSE	FALSE	FALSE	FALSE
8114	10.1039/b001051k	doi.org/10.1039/b001051k	A practical approach to stereodefined cyclopropyl-substituted heteroarenes using a Suzuki-type reaction		New J. Chem.	28	Deng, MZ	FALSE	FALSE	FALSE	FALSE
8115	10.1021/ja0003831	doi.org/10.1021/ja0003831	Regioselective and enantiospecific rhodium-catalyzed intermolecular allylic etherification with ortho-substituted phenols		J. Am. Chem. Soc.	28	Evans, PA	FALSE	FALSE	FALSE	FALSE
8116	10.1021/ja994059l	doi.org/10.1021/ja994059l	A novel asymmetric cyclization of omega-formyl-1,3-dienes catalyzed by a zerovalent nickel complex in the presence of silanes		J. Am. Chem. Soc.	28	Mori, M	FALSE	FALSE	FALSE	FALSE
8117	10.1016/S0040-4020(99)00176-3	doi.org/10.1016/S0040-4020(99)00176-3	Synthetic studies towards ML-3000 - A concise synthesis of this non-steroidal anti-inflammatory drug		Tetrahedron	28	Cossy, J	FALSE	FALSE	FALSE	FALSE
8118	10.1002/(SICI)1521-3773(19990816)38:16<2395::AID-ANIE2395>3.3.CO;2-N	doi.org/10.1002/(SICI)1521-3773(19990816)38:16<2395::AID-ANIE2395>3.3.CO;2-N	Acylzirconocene chloride as an unmasked acyl anion: Enantioselective 1,2-addition to alpha,beta-unsaturated ketone derivatives		Angew. Chem.-Int. Edit.	28	Hanzawa, Y	FALSE	FALSE	FALSE	FALSE
8119	10.1021/ja973150r	doi.org/10.1021/ja973150r	Retention of regiochemistry of allylic esters in palladium-catalyzed allylic alkylation in the presence of a MOP ligand		J. Am. Chem. Soc.	28	Hayashi, T	FALSE	FALSE	FALSE	FALSE
8120	10.1021/jo961915s	doi.org/10.1021/jo961915s	Palladium-catalyzed amination of aryl triflates		J. Org. Chem.	28		FALSE	FALSE	FALSE	FALSE
8121	10.1016/0040-4039(96)01984-3	doi.org/10.1016/0040-4039(96)01984-3	Nickel-catalyzed coupling reaction of lithium organoborates and aryl mesylates possessing an electron withdrawing group		Tetrahedron Lett.	28	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
8122	10.1021/jo9516852	doi.org/10.1021/jo9516852	Nickel-mediated cyclobutabenzene syntheses. trans-7,8-dibromocyclobutabenzenes: Their one-pot preparation, X-ray structure, and Diels-Alder reactions		J. Org. Chem.	28	Stanger, A	FALSE	FALSE	FALSE	FALSE
8123	10.1021/jo00059a059	doi.org/10.1021/jo00059a059	SYNTHESIS OF OPTICALLY-ACTIVE 2-(DIARYLPHOSPHINO)-1,1'-BINAPHTHYLS, EFFICIENT CHIRAL MONODENTATE PHOSPHINE-LIGANDS		J. Org. Chem.	28	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
8124	10.1016/0304-5102(92)80265-I	doi.org/10.1016/0304-5102(92)80265-I	MECHANISTIC ASPECTS IN OXIDATIVE ADDITION AND REDUCTIVE ELIMINATION INVOLVING ALLYLIC COMPLEXES OF PALLADIUM AND PLATINUM - SPECIFIC ROLE OF THE OLEFIN LIGAND IN CATALYTIC ALLYLIC COUPLING			28	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
8125	10.1016/0304-5102(90)85256-H	doi.org/10.1016/0304-5102(90)85256-H	SYNTHESES OF NEW CHIRAL FERROCENYLAMINE SULFIDE AND SELENIDE COMPLEXES OF GROUP-X METALS AND THEIR APPLICATION TO ENANTIOSELECTIVE CROSS-COUPLING REACTIONS AND SELECTIVE HYDROGENATION			28		FALSE	FALSE	FALSE	FALSE
8126	10.1016/0022-328X(87)80312-1	doi.org/10.1016/0022-328X(87)80312-1	RUTHENIUM-CATALYZED ADDITION-REACTION OF ACETIC-ACID TO PROPARGYL ALCOHOL DERIVATIVES - REAGENTS FOR PALLADIUM-CATALYZED 2-ACETOXYALLYLATION OF CARBONUCLEOPHILES		J. Organomet. Chem.	28		FALSE	FALSE	FALSE	FALSE
8127	10.3987/R-1987-02-0355	doi.org/10.3987/R-1987-02-0355	PALLADIUM CATALYZED COUPLING OF 5-HYDROXYURACIL TRIFLUOROMETHANE-SULFONATES (TRIFLATES) WITH ALKENES AND ALKYNES		Heterocycles	28	HIROTA, K	FALSE	FALSE	FALSE	FALSE
8128	10.1021/jacs.1c11712	doi.org/10.1021/jacs.1c11712	Photochemical Organocatalytic Benzylation of Allylic C-H Bonds		J. Am. Chem. Soc.	28	Melchiorre, P	TRUE	FALSE	FALSE	FALSE
8129	10.1080/24701556.2021.2025075	doi.org/10.1080/24701556.2021.2025075	Use of biogenic NiONPs as nanocatalyst in Kumada-Corriu coupling reaction		Inorg. Nano-Met. Chem.	28	Kumar, D	FALSE	FALSE	FALSE	FALSE
8130	10.2174/1570178618666210125161436	doi.org/10.2174/1570178618666210125161436	Synthesis, Characterization, and Antimicrobial Evaluation of New Furan-2-Carboxamide Derivatives		Lett. Org. Chem.	28	Sweidan, K	FALSE	FALSE	FALSE	FALSE
8131	10.1021/acs.orglett.1c04029	doi.org/10.1021/acs.orglett.1c04029	Photocatalytic C-O Bond Cleavage of Alcohols Using Xanthate Salts		Org. Lett.	28	Nanjo, T; Takemoto, Y	TRUE	FALSE	FALSE	FALSE
8132	10.1016/j.tetlet.2021.153369	doi.org/10.1016/j.tetlet.2021.153369	Cu-catalyzed cross-coupling of benzylboronic esters and epoxides		Tetrahedron Lett.	28	Barker, TJ	FALSE	FALSE	FALSE	FALSE
8133	10.1002/anie.202107490	doi.org/10.1002/anie.202107490	Skeletal Editing-Nitrogen Deletion of Secondary Amines by Anomeric Amide Reagents		Angew. Chem.-Int. Edit.	28	Brase, S	FALSE	FALSE	FALSE	FALSE
8134	10.1021/acs.jchemed.6b00273	doi.org/10.1021/acs.jchemed.6b00273	Synthesis of Dichlorophosphinenickel(II) Compounds and Their Catalytic Activity in Suzuki Cross-Coupling Reactions: A Simple Air Free Experiment for Inorganic Chemistry Laboratory		J. Chem. Educ.	28	Thananatthanachon, T	FALSE	FALSE	FALSE	FALSE
8135	10.1038/NCHEM.2587	doi.org/10.1038/NCHEM.2587	New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries		Nat. Chem.	28	Hansen, EC	FALSE	FALSE	FALSE	FALSE
8136	10.1002/adsc.201600213	doi.org/10.1002/adsc.201600213	Cobalt-Catalyzed C-sp3-C-sp3 Homocoupling		Adv. Synth. Catal.	28	Gosmini, C	FALSE	FALSE	FALSE	FALSE
8137	10.1002/ps.4055	doi.org/10.1002/ps.4055	4-Phenylphenalenones as a template for new photodynamic compounds against Mycosphaerella fijiensis		Pest Manag. Sci.	28	Schneider, B	FALSE	FALSE	FALSE	FALSE
8138	10.1055/s-0035-1560392	doi.org/10.1055/s-0035-1560392	A Novel Convenient Synthesis of Pyridinyl and Quinolinyl Triflates and Tosylates via One-Pot Diazotization of Aminopyridines and Aminoquinolines in Solution		Synthesis	28	Krasnokutskaya, EA	FALSE	FALSE	FALSE	FALSE
8139	10.1002/ejoc.202000707	doi.org/10.1002/ejoc.202000707	Exploration of the Fluoride Reactivity of Aryltrifluoroborate on Selective Cleavage of Diphenylmethylsilyl Groups	Photoredox/nickel dual catalysis via single electron transmetalation allows coupling of C-sp(3)-C-sp(2) hybridized centers under mild conditions. A procedure for the coupling of electron deficient aryltriflates, -tosylates, and -mesylates with alkylbis-(catecholato)silicates is presented. This method represents the first example of the use of phenol derivatives as electrophilic coupling partners in photoredox/nickel dual catalysis.	Eur. J. Org. Chem.	27	Fujiki, K; Tanaka, K	FALSE	FALSE	TRUE	TRUE
8140	10.1039/d0cc02261f	doi.org/10.1039/d0cc02261f	Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols		Chem. Commun.	27	Banerjee, D	FALSE	FALSE	FALSE	FALSE
8141	10.1177/1747519820925376	doi.org/10.1177/1747519820925376	Light-emitting diode light-enabled denitrative etherification of 4-nitrobenzonitrile under catalyst-free conditions at room temperature	A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO, at atmospheric pressure is described. This protocol represents the first intermolecular cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.	J. Chem. Res	27	Ghaderi, A	FALSE	FALSE	FALSE	FALSE
8142	10.1016/j.tetlet.2019.151228	doi.org/10.1016/j.tetlet.2019.151228	Acid-catalyzed intramolecular ring-opening reactions of cyclopropanated oxabenzonorbornadienes with alcohol nucleophiles		Tetrahedron Lett.	27	Tam, W	FALSE	FALSE	FALSE	FALSE
8143	10.1021/acscatal.9b01785	doi.org/10.1021/acscatal.9b01785	Enantioselective Electroreductive Coupling of Alkenyl and Benzyl Halides via Nickel Catalysis		ACS Catal.	27	Reisman, SE	FALSE	TRUE	FALSE	FALSE
8144	10.1002/pola.29426	doi.org/10.1002/pola.29426	Toward one-pot olefin/thiophene block copolymers using an in situ ligand exchange		J. Polym. Sci. Pol. Chem.	27	McNeil, AJ	FALSE	FALSE	FALSE	FALSE
8145	10.1002/anie.201814208	doi.org/10.1002/anie.201814208	Enantioconvergent Cross-Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes		Angew. Chem.-Int. Edit.	27	Fu, GC	FALSE	TRUE	FALSE	FALSE
8146	10.1016/j.tet.2018.05.064	doi.org/10.1016/j.tet.2018.05.064	Structure-activity relationship study of leucinostatin A, a modulator of tumor-stroma interaction		Tetrahedron	27	Watanabe, T; Shibasaki, M	FALSE	FALSE	FALSE	FALSE
8147	10.1039/c6ra01918h	doi.org/10.1039/c6ra01918h	Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions		RSC Adv.	27	Bai, J	FALSE	FALSE	FALSE	FALSE
8148	10.1021/acs.joc.5b01253	doi.org/10.1021/acs.joc.5b01253	Suzuki-Miyaura Coupling Reactions of Conjunctive Reagents: 2-Borylated Allylic Sulfones		J. Org. Chem.	27	Harmata, M	FALSE	FALSE	FALSE	FALSE
8149	10.1021/acscatal.5b00498	doi.org/10.1021/acscatal.5b00498	Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling		ACS Catal.	27	Monfette, S	FALSE	FALSE	FALSE	FALSE
8150	10.6023/cjoc201411004	doi.org/10.6023/cjoc201411004	Design, Synthesis and Molecular Docking Study of 6,7-Dioxo-4-aryl-aminocoumarin		Chin. J. Org. Chem.	27	Wang, AL	FALSE	FALSE	FALSE	FALSE
8151	10.1016/j.jorganchem.2014.08.014	doi.org/10.1016/j.jorganchem.2014.08.014	Synthesis and structure of [Ru(PPh3)(2)(bipy)(MeCN)Cl][BPh4] and it's catalytic property towards regioselective and stereoselective allylation of phenols		J. Organomet. Chem.	27	Bhattacharjee, M	FALSE	FALSE	FALSE	FALSE
8152	10.1021/ol501495d	doi.org/10.1021/ol501495d	Reductive Cross-Coupling of 3-Bromo-2,1-borazaronaphthalenes with Alkyl Iodides		Org. Lett.	27	Molander, GA	FALSE	FALSE	FALSE	FALSE
8153	10.1002/anie.201308391	doi.org/10.1002/anie.201308391	Nickel-Catalyzed Mizoroki-Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products		Angew. Chem.-Int. Edit.	27	Jamison, TF	FALSE	TRUE	FALSE	FALSE
8154	10.1039/c4cc04939j	doi.org/10.1039/c4cc04939j	Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions		Chem. Commun.	27	Clarke, ML	FALSE	FALSE	FALSE	FALSE
8155	10.1016/j.tetlet.2013.05.102	doi.org/10.1016/j.tetlet.2013.05.102	Ultrasound induced, copper mediated homocoupling using polymer supported aryltrifluoroborates		Tetrahedron Lett.	27	Kabalka, GW	FALSE	FALSE	FALSE	FALSE
8156	10.1021/jo400692p	doi.org/10.1021/jo400692p	Synthesis of Thiophene-Based TAK-779 Analogues by C-H Arylation		J. Org. Chem.	27	Itami, K	FALSE	FALSE	FALSE	FALSE
8157	10.1016/j.tetlet.2012.05.081	doi.org/10.1016/j.tetlet.2012.05.081	CuI/N,N-dimethylglycine-catalyzed synthesis of N-aryloxazolidinones from aryl bromides		Tetrahedron Lett.	27	Zhang, YH	FALSE	FALSE	FALSE	FALSE
8158	10.1007/s11172-012-0162-y	doi.org/10.1007/s11172-012-0162-y	Polymeric 2,2'-biquinolyl-containing Ni-II complexes as catalysts for the Suzuki reaction		Russ. Chem. Bull.	27	Magdesieva, TV	FALSE	FALSE	FALSE	FALSE
8159	10.1055/s-0031-1290111	doi.org/10.1055/s-0031-1290111	Recent Developments in Asymmetric Coupling of Enolates		Synlett	27	Zhou, JR	FALSE	FALSE	FALSE	FALSE
8160	10.1039/c1ob05893b	doi.org/10.1039/c1ob05893b	Development of highly stereoselective GalN(3) donors and their application in the chemical synthesis of precursors of Tn antigen		Org. Biomol. Chem.	27	Li, ZT	FALSE	FALSE	FALSE	FALSE
8161	10.1248/cpb.58.1066	doi.org/10.1248/cpb.58.1066	Novel Tetrahydroisoquinoline Derivatives with Inhibitory Activities against Acyl-CoA: Cholesterol Acyltransferase and Lipid Peroxidation		Chem. Pharm. Bull.	27	Shirahase, H	FALSE	FALSE	FALSE	FALSE
8162	10.1021/ja102436z	doi.org/10.1021/ja102436z	Copper-Catalyzed Tandem [2,3]-Rearrangement and 6 pi-3-Azatriene Electrocyclization in (E)-O-Propargylic alpha,beta-Unsaturated Oximes		J. Am. Chem. Soc.	27	Nakamura, I	FALSE	TRUE	FALSE	FALSE
8163	10.1055/s-0029-1217964	doi.org/10.1055/s-0029-1217964	A One-Pot Preparation of Aryl- and Heteroarylcycloalkenes: Application to the Total Synthesis of (+/-)-Laurokamurene B		Synlett	27	Lecornue, F	FALSE	FALSE	FALSE	FALSE
8164	10.1021/ol9013359	doi.org/10.1021/ol9013359	General, Robust, and Stereocomplementary Preparation of alpha,beta-Disubstituted alpha,beta-Unsaturated Esters		Org. Lett.	27	Tanabe, Y	FALSE	FALSE	FALSE	FALSE
8165	10.1039/b718998b	doi.org/10.1039/b718998b	Methylation of arenes via Ni-catalyzed aryl C-O/F activation		Chem. Commun.	27	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
8166	10.1016/j.tetlet.2007.08.089	doi.org/10.1016/j.tetlet.2007.08.089	Ni-catalyzed cross-coupling reaction of aryl chlorides with arylboronic acids in IPA without using a reducing reagent		Tetrahedron Lett.	27	He, R	FALSE	FALSE	FALSE	FALSE
8167	10.1016/j.tetlet.2007.03.142	doi.org/10.1016/j.tetlet.2007.03.142	A general and efficient route to 3-amino-4-sulfanylcoumarins via substitution and palladium-catalyzed amination of 3-bromo-4-tosyloxycoumarins		Tetrahedron Lett.	27	Fan, RH	FALSE	FALSE	FALSE	FALSE
8168	10.1055/s-2007-973875	doi.org/10.1055/s-2007-973875	Synthesis of 3-sulfonyloxypyridines: Oxidative ring expansion of alpha-furylsulfonamides and N -> O sulfonyl transfer		Synlett	27	Nelson, A	FALSE	FALSE	FALSE	FALSE
8169	10.1166/jnn.2006.017	doi.org/10.1166/jnn.2006.017	Ormosil nanocomposite materials as modifiers for acrylic coating systems		J. Nanosci. Nanotechnol.	27	Hay, JN	FALSE	FALSE	FALSE	FALSE
8170	10.1246/cl.2006.118	doi.org/10.1246/cl.2006.118	General microwave-assisted protocols for the expedient synthesis of furo[3,2-c]chromen-4-ones		Chem. Lett.	27	Wu, J	FALSE	FALSE	FALSE	FALSE
8171	10.1021/jo051581j	doi.org/10.1021/jo051581j	Enantiomerically pure 2-bromo-2 '-diphenylphosphinyl-1,1 '-binaphthyl as a monophosphorus template for electrophilic functionalization in chiral MOP-type ligand synthesis		J. Org. Chem.	27	Hoshi, T	FALSE	FALSE	FALSE	FALSE
8172	10.1139/V05-085	doi.org/10.1139/V05-085	Rh(I)-catalyzed cleavage of unactivated C-O bonds - Carbonylative rearrangement reactions of allenyl ethers to 2-carboalkoxy-1,3-dienes		Can. J. Chem.	27	Wender, PA	FALSE	FALSE	FALSE	FALSE
8173	10.1021/jo0477897	doi.org/10.1021/jo0477897	Palladium-catalyzed coupling of pyrazole triflates with arylboronic acids		J. Org. Chem.	27	Dvorak, CA	FALSE	FALSE	FALSE	FALSE
8174	10.1016/j.tetlet.2004.02.094	doi.org/10.1016/j.tetlet.2004.02.094	Direct allylic substitution of allyl alcohols by carbon pronucleophiles in the presence of a palladium/carboxylic acid catalyst under neat conditions		Tetrahedron Lett.	27	Yamamoto, Y	FALSE	FALSE	FALSE	FALSE
8175	10.1021/jo0350561	doi.org/10.1021/jo0350561	Rapid, easy cyanation of aryl bromides and chlorides using nickel salts in conjunction with microwave promotion		J. Org. Chem.	27	Leadbeater, NE	FALSE	FALSE	FALSE	FALSE
8176	10.1021/ja035835z	doi.org/10.1021/ja035835z	Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature		J. Am. Chem. Soc.	27	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
8177	10.1016/S0040-4039(00)01886-4	doi.org/10.1016/S0040-4039(00)01886-4	Baylis-Hillman chemistry: a novel synthesis of functionalized 1,4-pentadienes		Tetrahedron Lett.	27	Basavaiah, D	FALSE	FALSE	FALSE	FALSE
8178	10.1021/ol9907872	doi.org/10.1021/ol9907872	New efficient nickel- and palladium-catalyzed cross-coupling reactions mediated by tetrabutylammonium iodide		Org. Lett.	27	Knochel, P	FALSE	FALSE	FALSE	FALSE
8179	10.1039/a905378f	doi.org/10.1039/a905378f	Lithium hydride mediated nickel(0) catalysed biaryl synthesis from aryl chlorides and bromides		J. Chem. Res	27	Fort, Y	FALSE	FALSE	FALSE	FALSE
8180	10.1039/a608612h	doi.org/10.1039/a608612h	Substrate directed diastereoselective hydroformylation of acyclic homomethallylic alcohols		Chem. Commun.	27	Breit, B	FALSE	FALSE	FALSE	FALSE
8181	10.1016/0957-4166(96)00391-6	doi.org/10.1016/0957-4166(96)00391-6	Enantioselective synthesis of gamma-cyclohomocitral, pallescensone, and ancistrodial		Tetrahedron: Asymmetry	27	Vidari, G	FALSE	FALSE	FALSE	FALSE
8182	10.1139/v93-234	doi.org/10.1139/v93-234	PALLADIUM(0)-CATALYZED CONVERSION OF VINYL TRIFLUOROMETHANESULFONATES INTO ALPHA,BETA-UNSATURATED NITRILES		Can. J. Chem.-Rev. Can. Chim.	27	PIERS, E	FALSE	FALSE	FALSE	FALSE
8183	10.1021/jo00041a004	doi.org/10.1021/jo00041a004	NI(0)-CATALYZED CROSS COUPLING OF ARYL O-CARBAMATES AND ARYL TRIFLATES WITH GRIGNARD-REAGENTS - DIRECTED ORTHOMETALLATION-ALIGNED SYNTHETIC METHODS FOR POLYSUBSTITUTED AROMATICS VIA A 1,2-DIPOLE EQUIVALENT		J. Org. Chem.	27	SENGUPTA, S	FALSE	FALSE	FALSE	FALSE
8184	10.1016/S0040-4039(00)94338-7	doi.org/10.1016/S0040-4039(00)94338-7	APPLICATION OF AMPP-PD CATALYSTS IN AN UNUSUAL ASYMMETRIC ALLYLIC COUPLING REACTION OF 1-TRIMETHYLSILYL VINYL MAGNESIUM BROMIDE		Tetrahedron Lett.	27		FALSE	FALSE	FALSE	FALSE
8185	10.1016/0304-5102(89)85054-0	doi.org/10.1016/0304-5102(89)85054-0	ENANTIOSELECTIVE CARBON-DIOXIDE EXTRUSION FROM ALLYL PHENYL CARBONATES BY NICKEL, PALLADIUM AND RHODIUM CATALYSTS			27	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
8186	10.1016/S0020-1693(00)88365-6	doi.org/10.1016/S0020-1693(00)88365-6	STEREOCHEMISTRY OF CHIRAL RUTHENIUM-CYCLOPENTADIENYL AND IRON-CYCLOPENTADIENYL ALKYLIDENECARBENE-DIPHOSPHINE COMPLEXES		Inorg. Chim. Acta	27	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
8187	10.1016/S0040-4039(00)94166-2	doi.org/10.1016/S0040-4039(00)94166-2	ORGANOCUPRATE-INDUCED SUBSTITUTION OF THE ENOL OXYGEN MOIETY IN 2,2-DIFLUORO ENOL PHOSPHATES WITH ALLYL HALIDES - A NOVEL ROUTE TO GEM-DIFLUOROOLEFINS FROM CHLORODIFLUOROMETHYL KETONES		Tetrahedron Lett.	27	ISHIHARA, T	FALSE	FALSE	FALSE	FALSE
8188	10.1039/dt9830002293	doi.org/10.1039/dt9830002293	DIASTEREOMERIC CHIRAL DIPHOSPHINE CHLORO(ETA-5-CYCLOPENTADIENYL)-RUTHENIUM(II) COMPLEXES AND THE CRYSTAL-STRUCTURE OF [(S)RUCL(ETA-5-C5H5)((R)PH2PCH(ME)CH2PPH2)]		J. Chem. Soc.-Dalton Trans.	27		FALSE	FALSE	FALSE	FALSE
8189	10.1021/acs.orglett.2c00355	doi.org/10.1021/acs.orglett.2c00355	Bioinspired Cobalt-Catalysis Enables Generation of Nucleophilic Radicals from Oxetanes		Org. Lett.	27	Chaladaj, W; Gryko, D	FALSE	FALSE	FALSE	FALSE
8190	10.1039/d1ra04478h	doi.org/10.1039/d1ra04478h	New biomaterials for Ni biosorption turned into catalysts for Suzuki-Miyaura cross coupling of aryl iodides in green conditions		RSC Adv.	27	Grison, C	FALSE	FALSE	FALSE	FALSE
8191	10.1039/d1sc00822f	doi.org/10.1039/d1sc00822f	Nickel-catalyzed asymmetric reductive cross-coupling of alpha-chloroesters with (hetero)aryl iodides		Chem. Sci.	27	Reisman, SE	FALSE	FALSE	FALSE	FALSE
8192	10.14102/j.cnki.0254-5861.2011-1301	doi.org/10.14102/j.cnki.0254-5861.2011-1301	A 3D Nickel(II) Complex Constructed by Bis(2-dimethylaminoethyl) Ether: Solvothermal Synthesis, Crystal Structure and Catalytic Properties		Chin. J. Struct. Chem.	27	Liu, C	FALSE	FALSE	FALSE	FALSE
8193	10.1021/acs.orglett.6b02556	doi.org/10.1021/acs.orglett.6b02556	Palladium-Catalyzed Decarbonylative Cross-Coupling of Azinecarboxylates with Arylboronic Acids		Org. Lett.	27	Yamaguchi, J	FALSE	FALSE	FALSE	FALSE
8194	10.1021/acs.joc.6b01034	doi.org/10.1021/acs.joc.6b01034	Chemoselective Radical Dehalogenation and C-C Bond Formation on Aryl Halide Substrates Using Organic Photoredox Catalysts		J. Org. Chem.	27	Hawker, CJ; de Alaniz, JR	TRUE	FALSE	FALSE	FALSE
8195	10.3390/catal10020229	doi.org/10.3390/catal10020229	Regeneration of Raney (R)-Nickel Catalyst for the Synthesis of High-Value Amino-Ester Renewable Monomers		Catalysts	26	Soutelo-Maria, A	FALSE	FALSE	FALSE	FALSE
8196	10.1080/00397911.2019.1695838	doi.org/10.1080/00397911.2019.1695838	Highly regioselective O-allylation of phenol derivatives using MMZ(Cu(I)Y) catalyst		Synth. Commun.	26	Kumarraja, M	FALSE	FALSE	FALSE	FALSE
8197	10.1021/acs.joc.9b00633	doi.org/10.1021/acs.joc.9b00633	Asymmetric Synthesis of Natural and Unnatural Dibenzylbutane Lignans from a Common Intermediate		J. Org. Chem.	26	Lindsley, CW	FALSE	FALSE	FALSE	FALSE
8198	10.1016/j.cclet.2018.12.027	doi.org/10.1016/j.cclet.2018.12.027	Ligand-free nickel-catalyzed Kumada couplings of aryl bromides with tert-butyl Grignard reagents		Chin. Chem. Lett.	26	Xu, B	FALSE	FALSE	FALSE	FALSE
8199	10.6023/cjoc201808014	doi.org/10.6023/cjoc201808014	Nickel-Catalyzed Difluoromethylation of (Hetero)aryl Bromides with BrCF2H		Chin. J. Org. Chem.	26	Zhang, XG	FALSE	FALSE	FALSE	FALSE
8200	10.1039/c8cy00613j	doi.org/10.1039/c8cy00613j	Versatile etherification of alcohols with allyl alcohol by a titanium oxide- supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide		Catal. Sci. Technol.	26	Kon, Y	FALSE	FALSE	FALSE	FALSE
8201	10.1021/acs.organomet.8b00567	doi.org/10.1021/acs.organomet.8b00567	Simple Nickel Salts for the Amination of (Hetero)aryl Bromides and Iodides with Lithium Bis(trimethylsilyl)amide		Organometallics	26	Fout, AR	FALSE	FALSE	FALSE	FALSE
8202	10.1021/jacs.8b03739	doi.org/10.1021/jacs.8b03739	Manganese-Mediated Reductive Transamidation of Tertiary Amides with Nitroarenes		J. Am. Chem. Soc.	26	Hu, XL	FALSE	FALSE	FALSE	FALSE
8203	10.1039/c7cc04397j	doi.org/10.1039/c7cc04397j	The acid promoted Petasis reaction of organotrifluoroborates with imines and enamines		Chem. Commun.	26	Carrera, DE	FALSE	FALSE	FALSE	FALSE
8204	10.1039/c6qo00178e	doi.org/10.1039/c6qo00178e	Pd(II)-catalyzed direct functionalization of C-H bonds of benzamides for synthesis of 1,1-difluoro-1-alkenes		Org. Chem. Front.	26	Liu, H	FALSE	FALSE	FALSE	FALSE
8205	10.1039/c5gc01869b	doi.org/10.1039/c5gc01869b	Electrochemical synthesis of organochalcogenides in aqueous medium		Green Chem.	26	Neto, PBR	FALSE	TRUE	FALSE	FALSE
8206	10.1016/j.tetlet.2015.05.117	doi.org/10.1016/j.tetlet.2015.05.117	Concise synthesis of the DEFG ring system in rubriflordilactone B		Tetrahedron Lett.	26	Peng, Y	FALSE	FALSE	FALSE	FALSE
8207	10.1016/j.tet.2015.01.008	doi.org/10.1016/j.tet.2015.01.008	Pd(0)-mediated [C-11]carbonylation of aryl and heteroaryl boronic acid pinacol esters with [C-11]carbon monoxide under ambient conditions and a facile process for the conversion of [carbonyl-C-11] esters to [carbonyl-C-11]amides		Tetrahedron	26	Ishii, H	FALSE	FALSE	FALSE	FALSE
8208	10.1002/aoc.3134	doi.org/10.1002/aoc.3134	Nickel( II) complex containing N-(4,5dihydrooxazol-2-yl) benzamide ligands: highly efficient catalyst for Heck coupling reactions		Appl. Organomet. Chem.	26	Wang, JK	FALSE	FALSE	FALSE	FALSE
8209	10.1007/s40242-014-3257-1	doi.org/10.1007/s40242-014-3257-1	Facile Synthesis of Enantiomerically Pure 1-(5-Bromo-2-chlorophenyl)-1-(4-ethoxyphenyl)ethane		Chem. Res. Chin. Univ.	26	Wang, JW	FALSE	FALSE	FALSE	FALSE
8210	10.1016/j.tetlet.2013.01.008	doi.org/10.1016/j.tetlet.2013.01.008	One-step method for the synthesis of aryl olefins from aryl aldehydes and aliphatic aldehydes		Tetrahedron Lett.	26	Borate, HB	FALSE	FALSE	FALSE	FALSE
8211	10.1039/c3cc46271d	doi.org/10.1039/c3cc46271d	A mechanistic investigation of hydrodehalogenation using ESI-MS		Chem. Commun.	26	McIndoe, JS	FALSE	FALSE	FALSE	FALSE
8212	10.1039/c3cc42746c	doi.org/10.1039/c3cc42746c	A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO4/SiO2		Chem. Commun.	26	Aoyama, T	FALSE	FALSE	FALSE	FALSE
8213	10.1016/j.comptc.2012.08.010	doi.org/10.1016/j.comptc.2012.08.010	Theoretical study on effects of substituent, ligand, and metal on Pd-catalyzed polymerization of norbornene		Comput. Theor. Chem.	26	Li, Z	FALSE	FALSE	FALSE	FALSE
8214	10.1021/om300323d	doi.org/10.1021/om300323d	Carbon-Oxygen Bond Activation in Esters by Platinum(0): Cleavage of the Less Reactive Bond		Organometallics	26	Jones, WD	FALSE	FALSE	FALSE	FALSE
8215	10.1007/s11172-012-0130-6	doi.org/10.1007/s11172-012-0130-6	N(2)-Monosubstituted bishydrazides of oxalic acid as new efficient components of the system for the copper-catalyzed C-N cross-coupling in water		Russ. Chem. Bull.	26	Boyarskiy, VP	FALSE	FALSE	FALSE	FALSE
8216	10.1021/ol203303b	doi.org/10.1021/ol203303b	Efficient Palladium-Catalyzed Cross-Coupling of Highly Acidic Substrates, Nitroacetates		Org. Lett.	26	Dreher, SD	FALSE	FALSE	FALSE	FALSE
8217	10.1021/ol201437g	doi.org/10.1021/ol201437g	Nickel-Catalyzed Amination of Aryl Phosphates through Cleaving Aryl C-O Bonds		Org. Lett.	26	Yang, LM	FALSE	FALSE	FALSE	FALSE
8218	10.1021/ol201069x	doi.org/10.1021/ol201069x	New Synthetic Methodology for the Construction of 7-Substituted Farnesyl Diphosphate Analogs		Org. Lett.	26	Gibbs, RA	FALSE	FALSE	FALSE	FALSE
8219	10.1021/ol1018739	doi.org/10.1021/ol1018739	Room Temperature Palladium-Catalyzed Cross Coupling of Aryltrimethylammonium Triflates with Aryl Grignard Reagents		Org. Lett.	26	Reeves, JT	FALSE	FALSE	FALSE	FALSE
8220	10.1002/anie.201003379	doi.org/10.1002/anie.201003379	BO Chemistry Comes Full Circle		Angew. Chem.-Int. Edit.	26	Westcott, SA	FALSE	FALSE	FALSE	FALSE
8221	10.1021/ol902155e	doi.org/10.1021/ol902155e	Neopentylglycolborylation of Aryl Chlorides Catalyzed by the Mixed Ligand System NiCl2(dppp)/dppf		Org. Lett.	26	Percec, V	FALSE	FALSE	FALSE	FALSE
8222	10.1021/om900558a	doi.org/10.1021/om900558a	Use of Aryliron Complexes [CpFe(CO)(2)Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones		Organometallics	26	Yorimitsu, H	FALSE	FALSE	FALSE	FALSE
8223	10.1055/s-2008-1067222	doi.org/10.1055/s-2008-1067222	Synthesis of 2-substituted cyclohexene derivatives through cross-coupling reactions via pi-allylmetal intermediate using N-heterocyclic carbenes (NHCs) as ligands		Synthesis	26	Sato, Y	FALSE	FALSE	FALSE	FALSE
8224	10.1139/V08-038	doi.org/10.1139/V08-038	Linear free-energy correlation analysis of the electronic effects of the substituents in the Sonogashira coupling reaction		Can. J. Chem.	26	Gottardo, C	FALSE	FALSE	FALSE	FALSE
8225	10.1021/ja710944j	doi.org/10.1021/ja710944j	Direct benzylic alkylation via Ni-catalyzed selective benzylic sp(3) C-O activation		J. Am. Chem. Soc.	26	Shi, ZJ	FALSE	FALSE	FALSE	FALSE
8226	10.1021/ja0703170	doi.org/10.1021/ja0703170	Palladium-catalyzed asymmetric silaborative C-C cleavage of meso-methylenecyclopropanes		J. Am. Chem. Soc.	26	Suginome, M	FALSE	FALSE	FALSE	FALSE
8227	10.1002/chem.200601737	doi.org/10.1002/chem.200601737	Simple and efficient recyclable catalytic system for performing copper-catalysed S-arylation reactions in the presence of water		Chem.-Eur. J.	26	SanMartin, R	FALSE	FALSE	FALSE	FALSE
8228	10.1080/00397910601039044	doi.org/10.1080/00397910601039044	Application of polymer-supported triphenylphosphine and microwave irradiation to the palladium-catalyzed cyanation of aryl triflates		Synth. Commun.	26	Srivastava, RR	FALSE	FALSE	FALSE	FALSE
8229	10.1039/b605732b	doi.org/10.1039/b605732b	Convenient synthesis of electron-donating substituted benzonitriles by photolysis of phenyl halides and esters		Chem. Commun.	26	Fagnoni, M	FALSE	FALSE	FALSE	FALSE
8230	10.1002/marc.200350009	doi.org/10.1002/marc.200350009	eta(3)-benzyl-nickel-diimine complex: Synthesis and catalytic properties in ethylene polymerization		Macromol. Rapid Commun.	26	Monteiro, AL	FALSE	FALSE	FALSE	FALSE
8231	10.1021/ja035216q	doi.org/10.1021/ja035216q	Regio- and enantiospecific rhodium-catalyzed arylation of unsymmetrical fluorinated acyclic allylic carbonates: inversion of absolute configuration		J. Am. Chem. Soc.	26	Evans, PA	FALSE	FALSE	FALSE	FALSE
8232	10.1007/s007060070008	doi.org/10.1007/s007060070008	Mechanism of the nickel-catalyzed electrosynthesis of ketones by heterocoupling of aryl and benzyl halides		Mon. Chem.	26	Amatore, C	FALSE	FALSE	FALSE	FALSE
8233	10.3987/COM-00-8920	doi.org/10.3987/COM-00-8920	Palladium-catalyzed asymmetric allylic alkylation using chiral P,N-ligands		Heterocycles	26	Mino, T	FALSE	FALSE	FALSE	FALSE
8234	10.1021/ja000693j	doi.org/10.1021/ja000693j	Zr-catalyzed olefin alkylations and allylic substitution reactions with electrophiles		J. Am. Chem. Soc.	26	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
8235	10.1016/S0040-4039(99)01178-8	doi.org/10.1016/S0040-4039(99)01178-8	Synthesis of aryl esters of protected amino acids from aryl sulfonates		Tetrahedron Lett.	26	Vilaivan, T	FALSE	FALSE	FALSE	FALSE
8236	10.1039/a900181f	doi.org/10.1039/a900181f	Homocoupling of substituted benzenes to symmetrical biaryls with mercury(II) in the presence of cerium(IV)		J. Chem. Res.-S	26	Iranpoor, N	FALSE	FALSE	FALSE	FALSE
8237	10.1016/S0022-328X(96)06752-6	doi.org/10.1016/S0022-328X(96)06752-6	The hydrostannation of a propargylglycine derivative		J. Organomet. Chem.	26	Crisp, GT	FALSE	FALSE	FALSE	FALSE
8238	10.1016/S0040-4039(97)00187-1	doi.org/10.1016/S0040-4039(97)00187-1	New multi-coupling benzylic zinc reagents for the preparation of flexible aromatic compounds		Tetrahedron Lett.	26		FALSE	FALSE	FALSE	FALSE
8239	10.1016/S0040-4039(00)88045-4	doi.org/10.1016/S0040-4039(00)88045-4	ERYTHROSELECTIVITY IN ADDITION OF GAMMA-SUBSTITUTED ALLYLSILANES TO ALDEHYDES IN THE PRESENCE OF TITANIUM CHLORIDE		Tetrahedron Lett.	26	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
8240	10.1016/S0022-328X(00)93274-1	doi.org/10.1016/S0022-328X(00)93274-1	REACTION OF ORGANOMAGNESIUM COMPOUNDS WITH ALLYLIC ALCOHOLS IN PRESENCE OF NICKEL-COMPLEXES .2. HYDROGENOLYSIS OF ALLYLIC ALCOHOLS		J. Organomet. Chem.	26		FALSE	FALSE	FALSE	FALSE
8241	10.1021/acs.orglett.1c04134	doi.org/10.1021/acs.orglett.1c04134	Guiding Target Synthesis with Statistical Modeling Tools: A Case Study in Organocatalysis		Org. Lett.	26	Reid, JP	FALSE	FALSE	FALSE	FALSE
8242	10.1021/acs.orglett.1c03844	doi.org/10.1021/acs.orglett.1c03844	Soft Enolization of 3-Substituted Cycloalkanones Exhibits Significantly Improved Regiocontrol vs Hard Enolization Conditions		Org. Lett.	26	Vanderwal, CD	FALSE	FALSE	FALSE	FALSE
8243	10.6023/cjoc202010027	doi.org/10.6023/cjoc202010027	Facile Preparation of Aryl C-Glycosides by Nickel-Catalyzed Reductive Coupling of Glycosyl Halides with Aryl Halides		Chin. J. Org. Chem.	26	Qun, Q	FALSE	FALSE	FALSE	FALSE
8244	10.6023/cjoc202007059	doi.org/10.6023/cjoc202007059	Design, Synthesis and Activity Evaluation of Novel Bromodomain-Containing Protein 4 (BRD4) Small Molecule Inhibitor Based on ABBV-075		Chin. J. Org. Chem.	26	Li, W; Sun, K; Liu, HM	FALSE	FALSE	FALSE	FALSE
8245	10.1016/j.tetlet.2017.04.070	doi.org/10.1016/j.tetlet.2017.04.070	A facile and mild Pd-catalyzed one-pot process for direct hydrodeoxygenation (HDO) phenols to arenes through a ArOSO2F intermediates transformation		Tetrahedron Lett.	26	Qin, HL	FALSE	FALSE	FALSE	FALSE
8246	10.1055/s-0036-1588132	doi.org/10.1055/s-0036-1588132	Nickel-Catalyzed Reductive Cross-Coupling of Vinyl Bromides with Unactivated Alkyl Halides		Synthesis	26	Gong, HG	FALSE	FALSE	FALSE	FALSE
8247	10.1016/j.jorganchem.2016.11.005	doi.org/10.1016/j.jorganchem.2016.11.005	Cobalt pincer complex catalyzed Suzuki-Miyaura cross coupling - A green approach		J. Organomet. Chem.	26	Bhat, BR	FALSE	FALSE	FALSE	FALSE
8248	10.1039/c6cc03956a	doi.org/10.1039/c6cc03956a	Development of a supramolecular ensemble of an AIEE active hexaphenylbenzene derivative and Ag@Cu2O core-shell NPs: an efficient photocatalytic system for C-H activation		Chem. Commun.	26	Bhalla, V	FALSE	FALSE	FALSE	FALSE
8249	10.1016/j.tet.2015.12.051	doi.org/10.1016/j.tet.2015.12.051	Efficient synthesis of chiral biaryls via asymmetric Suzuki-Miyaura cross-coupling of ortho-bromo aryl triflates		Tetrahedron	26	Tang, WJ	FALSE	FALSE	FALSE	FALSE
8250	10.1039/d0cc07169b	doi.org/10.1039/d0cc07169b	Nickel-catalysed chemoselective C-3 alkylation of indoles with alcohols through a borrowing hydrogen method	A highly efficient catalyst for the direct C-H arylation of simple arenes was developed on the basis of a palladium-diimine complex. The developed catalyst exhibited the highest turnover number reported to date for the direct arylation of benzene due to increased stability provided by the diimine ligand. The reaction was also performed using only 2-3 equiv of simple arenes. Mechanistic studies in combination with kinetic measurements, isotope effect experiments, synthesis of possible intermediates, and stoichiometric reactions suggested that this reaction follows a cooperative bimetallic mechanism.	Chem. Commun.	25	Adhikari, D	FALSE	FALSE	FALSE	FALSE
8251	10.1007/s40010-020-00722-9	doi.org/10.1007/s40010-020-00722-9	Efficient Synthesis of 1,1-Dimethoxymethane from Methanol and Paraformaldehyde Catalyzed by a Molecularly defined Ni(II)-Complex	Ruthenium thiolate complexes with one chiral monodentate phosphine ligand are applied to enantioselective hydrosilylation of enolizable 'mines and ketones. The structural features of the catalyst exclude the presence of more than one phosphine ligand at the ruthenium center in the enantioselectivity-determining step. The enantiomeric excesses obtained in these reduction reactions ate moderate (up to 66% ee), but the stereochemical outcome enables an experimental analysis of the reaction pathways operative in this catalysis. A two-step sequence consisting of successive N-Si/O Si dehydrogenative coupling and enamine/enol ether hydrogenation is, the prevailing mechanisin Of action. Both steps involve cooperative bond activation at the Ru-S bond of the coordinatively unsaturated ruthenium complex: Si-H bond activation in the dehydrogenative coupling and heterolytic H-H splitting in the hydrogenation. Previously documented side reactions such as deprotonation/protonation equilibria as well as competing direct C=N or C=O hydrogenation have been excluded.	Proc. Nat. Acad. Sci. India A	25	Balaraman, E	FALSE	FALSE	FALSE	FALSE
8252	10.1007/s11696-019-00841-7	doi.org/10.1007/s11696-019-00841-7	A new route for the synthesis of Palbociclib		Chem. Pap.	25	Chen, JQ	FALSE	FALSE	FALSE	FALSE
8253	10.1039/c9cc03591e	doi.org/10.1039/c9cc03591e	Nickel-catalysed direct alpha-olefination of alkyl substituted N-heteroarenes with alcohols		Chem. Commun.	25	Banerjee, D	FALSE	FALSE	FALSE	FALSE
8254	10.1055/s-0037-1611537	doi.org/10.1055/s-0037-1611537	Triphenylphosphine Oxide-Catalyzed Selective ,-Reduction of Conjugated Polyunsaturated Ketones		Synlett	25	Toy, PH	FALSE	FALSE	FALSE	FALSE
8255	10.1021/acs.orglett.9b01019	doi.org/10.1021/acs.orglett.9b01019	Ni-Catalyzed Cross-Electrophile Coupling for the Synthesis of Skipped Polyenes		Org. Lett.	25	Jamison, TF	FALSE	TRUE	FALSE	FALSE
8256	10.1002/slct.201702416	doi.org/10.1002/slct.201702416	Base-Promoted Heterogeneous Reusable Copper Fluorapatite (CuFAP) Catalyzed Facile Synthesis of 1,2-Diarylethanols via C(sp(3))-H Functionalization of Nitrotoluene		ChemistrySelect	25	Mulla, SAR	FALSE	FALSE	FALSE	FALSE
8257	10.3987/COM-15-13314	doi.org/10.3987/COM-15-13314	A GENERAL SYNTHESIS OF NOVEL QUINOLINE-BASED ISOINDOLIN-1-ONE DERIVATIVES		Heterocycles	25	Zhang, H	FALSE	FALSE	FALSE	FALSE
8258	10.1002/anie.201503204	doi.org/10.1002/anie.201503204	Nickel-Catalyzed CO/CH Cross-Coupling Reactions for CC Bond Formation		Angew. Chem.-Int. Edit.	25	Chen, TQ	FALSE	FALSE	FALSE	FALSE
8259	10.1002/anie.201503391	doi.org/10.1002/anie.201503391	Gadolinium-Catalyzed Regio- and Enantioselective Aminolysis of Aromatic trans-2,3-Epoxy Sulfonamides		Angew. Chem.-Int. Edit.	25	Yamamoto, H	FALSE	FALSE	FALSE	FALSE
8260	10.1155/2015/912104	doi.org/10.1155/2015/912104	Catalytic Hydrodechlorination of Trichlorobenzenes with Pd(Phen)Cl-2 as Catalyst Precursor		J. Nanomater.	25	Xu, H	FALSE	FALSE	FALSE	FALSE
8261	10.1139/cjc-2014-0217	doi.org/10.1139/cjc-2014-0217	Regioselective palladium-catalyzed ring-opening reactions of C-1-substituted oxabenzonorbornadienes		Can. J. Chem.	25	Tam, W	FALSE	FALSE	FALSE	FALSE
8262	10.1039/c3cc47633b	doi.org/10.1039/c3cc47633b	Organocatalytic photoreduction of Zn(II) to zinc metal		Chem. Commun.	25	Bernhard, S	FALSE	FALSE	FALSE	FALSE
8263	10.1039/c4ra04398g	doi.org/10.1039/c4ra04398g	Benzylic-type couplings provide an important asymmetric entry to functionalized, non-racemic helicenes		RSC Adv.	25	Gingras, M	FALSE	FALSE	FALSE	FALSE
8264	10.1021/ja408561b	doi.org/10.1021/ja408561b	Nickel/Bis(oxazoline)-Catalyzed Asymmetric Negishi Arylations of Racemic Secondary Benzylic Electrophiles to Generate Enantioenriched 1,1-Diarylalkanes		J. Am. Chem. Soc.	25	Fu, GC	FALSE	TRUE	FALSE	FALSE
8265	10.1021/ja2066829	doi.org/10.1021/ja2066829	An Enantioselective, Intermolecular alpha-Arylation of Ester Enolates To Form Tertiary Stereocenters		J. Am. Chem. Soc.	25	Zhou, JR	FALSE	FALSE	FALSE	FALSE
8266	10.1016/j.jorganchem.2010.10.037	doi.org/10.1016/j.jorganchem.2010.10.037	Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst		J. Organomet. Chem.	25	Komiya, S	FALSE	FALSE	FALSE	FALSE
8267	10.1021/ol1011949	doi.org/10.1021/ol1011949	Two-Component Approach Toward a Fully Substituted N-Fused Pyrrole Ring		Org. Lett.	25	Gevorgyan, V	FALSE	FALSE	FALSE	FALSE
8268	10.1021/jo1001615	doi.org/10.1021/jo1001615	Room Temperature Cross-Coupling of Highly Functionalized Organozinc Reagents with Thiomethylated N-Heterocycles by Nickel Catalysis		J. Org. Chem.	25	Knochel, P	FALSE	FALSE	FALSE	FALSE
8269	10.1002/anie.200905544	doi.org/10.1002/anie.200905544	DHTP Ligands for the Highly Ortho-Selective, Palladium-Catalyzed Cross-Coupling of Dihaloarenes with Grignard Reagents: A Conformational Approach for Catalyst Improvement		Angew. Chem.-Int. Edit.	25	Manabe, K	FALSE	FALSE	FALSE	FALSE
8270	10.1002/anie.201001028	doi.org/10.1002/anie.201001028	A Synthetic Double Punch: Suzuki-Miyaura Cross-Coupling Mates with C-H Functionalization		Angew. Chem.-Int. Edit.	25	Jacobi von Wangelin, A	FALSE	FALSE	FALSE	FALSE
8271	10.1007/s00706-009-0199-2	doi.org/10.1007/s00706-009-0199-2	Structural variations of nickel complexes in NiS4 and NiS2PN coordination environments: spectral and single-crystal X-ray structural studies on bis(4-methylpiperidinecarbodithioato-S,S ')nickel(II) and (4-methylpiperidinecarbodithioato-S,S ')(thiocyanato-N)(triphenylphosphine)nickel(II)		Mon. Chem.	25	Thirumaran, S	FALSE	FALSE	FALSE	FALSE
8272	10.1055/s-0029-1217067	doi.org/10.1055/s-0029-1217067	Enol Phosphinates and Phosphonates: Practical Electrophiles for Cross-Coupling Strategies		Synthesis	25	Steel, PG	FALSE	TRUE	FALSE	FALSE
8273	10.1080/00958970802483624	doi.org/10.1080/00958970802483624	Trans influences of Cl-, NCO- and NCS- donors on planar NiS2PN(CO), NiS2PN(CS), NiS2PCl and NiS2P2 chromophores: synthesis, NMR spectral and single crystal X-ray structural studies		J. Coord. Chem.	25	Ramalingam, K	FALSE	FALSE	FALSE	FALSE
8274	10.1039/b914982a	doi.org/10.1039/b914982a	Aminations of allylic phenyl ethers via micellar catalysis at room temperature in water		Chem. Commun.	25	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
8275	10.1021/ja805810p	doi.org/10.1021/ja805810p	Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature		J. Am. Chem. Soc.	25	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
8276	10.1021/ja805094j	doi.org/10.1021/ja805094j	Asymmetric intramolecular arylcyanation of unactivated Olefins via C-CN bond activation		J. Am. Chem. Soc.	25	Jacobsen, EN	FALSE	FALSE	FALSE	FALSE
8277	10.1002/adsc.200700002	doi.org/10.1002/adsc.200700002	Palladium-catalyzed cross-coupling reaction using arylgermanium sesquioxide		Adv. Synth. Catal.	25	Fugami, K	FALSE	FALSE	FALSE	FALSE
8278	10.1016/S0040-4039(03)01804-5	doi.org/10.1016/S0040-4039(03)01804-5	Efficient preparation of (Z)-alkenyl derivatives from (Z)-vinyl (N,N-diisopropyl)carbamate via Ni-catalysed coupling reactions		Tetrahedron Lett.	25	Betzer, JF	FALSE	FALSE	FALSE	FALSE
8279	10.1021/ol034948k	doi.org/10.1021/ol034948k	Simple and efficient protocol for the synthesis of functionalized styrenes from 1,2-dibromoethane and arylboronic acids		Org. Lett.	25	Monteiro, AL	FALSE	FALSE	FALSE	FALSE
8280	10.1016/S0040-4020(02)01351-0	doi.org/10.1016/S0040-4020(02)01351-0	Rapid analogue synthesis of C-5 substituted 1,2,3-triazolo[1,5-a]quinazolines		Tetrahedron	25	Jones, P	FALSE	FALSE	FALSE	FALSE
8281	10.1016/S0040-4020(02)00826-8	doi.org/10.1016/S0040-4020(02)00826-8	Practical enantioselective synthesis of a COX-2 specific inhibitor		Tetrahedron	25	Tan, L	FALSE	FALSE	FALSE	FALSE
8282	10.1021/ja9927220	doi.org/10.1021/ja9927220	Rhodium-catalyzed asymmetric arylation of imines with organostannanes. Asymmetric synthesis of diarylmethylamines		J. Am. Chem. Soc.	25	Hayashi, T	FALSE	FALSE	FALSE	FALSE
8283	10.1021/ja9929537	doi.org/10.1021/ja9929537	A ruthenium-catalyzed alkylative cycloetherification		J. Am. Chem. Soc.	25	Trost, BM	FALSE	FALSE	FALSE	FALSE
8284	10.1071/CH99073	doi.org/10.1071/CH99073	Reaction of bromonaphthofurans with bis(pinacolato)diboron		Aust. J. Chem.	25	Brimble, MA	FALSE	FALSE	FALSE	FALSE
8285	10.1016/S0040-4039(97)00178-0	doi.org/10.1016/S0040-4039(97)00178-0	Nickel-catalyzed asymmetric allylation of alkyl Grignard reagents. Effect of ligands, leaving groups and a kinetic resolution with a hard nucleophile		Tetrahedron Lett.	25		FALSE	FALSE	FALSE	FALSE
8286	10.1021/jo961615a	doi.org/10.1021/jo961615a	Nickel-catalyzed addition of grignard reagents to oxabicyclic compounds. Ring-opening reactions with previously unreactive substrates and nucleophiles		J. Org. Chem.	25	Lautens, M	FALSE	FALSE	FALSE	FALSE
8287	10.1016/0304-5102(90)85092-V	doi.org/10.1016/0304-5102(90)85092-V	RELATIONSHIP BETWEEN PRODUCT CONFIGURATION AND COMPLEX CONFORMATION IN ASYMMETRIC CATALYSIS ON METAL-COMPLEXES (CROSS-COUPLING AND HYDROSILYLATION REACTIONS)			25	PAVLOV, VA	FALSE	FALSE	FALSE	FALSE
8288	10.1039/c39900000399	doi.org/10.1039/c39900000399	NICKEL-CATALYZED ALKYLATIVE ALKENATION OF ORTHOTHIOESTERS WITH GRIGNARD-REAGENTS - A CONVENIENT PROCEDURE FOR INTRODUCING THE ISOPROPENYL GROUP - SYNTHESIS OF SUBSTITUTED 1,3-(BIS-TRIMETHYLSILYL)PROPENES		J. Chem. Soc.-Chem. Commun.	25		FALSE	FALSE	FALSE	FALSE
8289	10.1016/S0040-4039(01)81055-8	doi.org/10.1016/S0040-4039(01)81055-8	METAL-PROMOTED CYCLIZATION .16. HIGHLY STEREOSELECTIVE SYNTHESIS OF EXOCYCLIC ALKENES VIA CYCLIALKYLATION		Tetrahedron Lett.	25	NEGISHI, E	FALSE	FALSE	FALSE	FALSE
8290	10.1021/jo00220a042	doi.org/10.1021/jo00220a042	THE EFFECT OF ADDED SILVER-NITRATE ON THE PALLADIUM-CATALYZED ARYLATION OF ALLYLTRIMETHYLSILANES		J. Org. Chem.	25		FALSE	FALSE	FALSE	FALSE
8291	10.1021/ja00328a063	doi.org/10.1021/ja00328a063	PALLADIUM-CATALYZED COUPLING OF VINYL TRIFLATES WITH ORGANOSTANNANES - A SHORT SYNTHESIS OF PLERAPLYSILLIN-1		J. Am. Chem. Soc.	25		FALSE	FALSE	FALSE	FALSE
8292	10.1016/S0022-328X(00)91443-8	doi.org/10.1016/S0022-328X(00)91443-8	KHARASCH-TYPE HOMOCOUPLING REACTION CATALYZED BY IRON COMPLEXES		J. Organomet. Chem.	25	FELKIN, H	FALSE	FALSE	FALSE	FALSE
8293	10.1007/s11419-021-00597-4	doi.org/10.1007/s11419-021-00597-4	Identification and structural characterization of three psychoactive substances, phenylpiperazines (pBPP and 3,4-CFPP) and a cocaine analogue (troparil), in collected samples		Forensic Toxicol.	25	Poplawska, M; Bednarek, E	FALSE	FALSE	FALSE	FALSE
8294	10.1021/acs.orglett.1c02346	doi.org/10.1021/acs.orglett.1c02346	Cu-Catalyzed C-H Allylation of Benzimidazoles with Allenes		Org. Lett.	25	Breit, B	FALSE	FALSE	FALSE	FALSE
8295	10.1039/d0ra10868e	doi.org/10.1039/d0ra10868e	Fe-mediated synthesis of N-aryl amides from nitroarenes and acyl chlorides		RSC Adv.	25	Guo, L	FALSE	FALSE	FALSE	FALSE
8296	10.3390/catal11050645	doi.org/10.3390/catal11050645	Ni-Containing Catalysts		Catalysts	25	Da Costa, P	FALSE	FALSE	FALSE	FALSE
8297	10.1246/cl.160133	doi.org/10.1246/cl.160133	Palladium-catalyzed C-H Arylation of Pyridines with Aryl Triflates		Chem. Lett.	25	Itami, K	FALSE	FALSE	FALSE	FALSE
8298	10.1016/j.tetlet.2020.152629	doi.org/10.1016/j.tetlet.2020.152629	Recyclable CuFe2O4 for the synthesis of 2,3-disubstituted indoles	An operationally simple, efficient and straight forward approach was developed for the synthesis of new hybrid nitrogen heterocycles bearing dihydroquinazoline with quinoline, isoquinoline, quinoxaline and azole via iron-catalyzed dehydrative cross coupling reaction between heterocyclic aminol and 2-methyl azaarenes. Furthermore, this protocol applied to couple simple methyl ketones to achieve C4-alkylated-dihydroquinazolines with broad substrate scope. (C) 2017 Elsevier Ltd. All rights reserved.	Tetrahedron Lett.	24	Le, NTH; Nguyen, TT	FALSE	FALSE	FALSE	FALSE
8299	10.1016/j.catcom.2020.106085	doi.org/10.1016/j.catcom.2020.106085	Borrowing hydrogen activity of NH2-MIL-125 for N-alkylation of amines with alcohols under solvent and base free condition	A combination of nickel and photoredox catalysts promoted novel cross-coupling reactions of aryl halides with 4-alkyl-1,4-dihydropyridines. 4-Alkyl-1,4-dihydropyridines act as formal nucleophilic alkylation reagents through a photoredox-catalyzed carbon-carbon (C-C) bond-cleavage process. The present strategy provides an alternative to classical carbon-centered nucleophiles, such as organometallic reagents.	Catal. Commun.	24	Mishra, MK	FALSE	FALSE	FALSE	FALSE
8300	10.1016/j.tetlet.2019.151216	doi.org/10.1016/j.tetlet.2019.151216	Synthesis of homo-propargylic ethers: A domino ring opening/coupling reaction of oxiranes with terminal alkynes and aryl iodides		Tetrahedron Lett.	24	Manafi, M	FALSE	FALSE	FALSE	FALSE
8301	10.1246/cl.190405	doi.org/10.1246/cl.190405	Further Studies on Ni/Zr-mediated One-pot Ketone Synthesis: Use of a Mixture of Ni-I- and Ni-II-catalysts Greatly Improves the Molar Ratio of Coupling Partners		Chem. Lett.	24	Kishi, Y	FALSE	FALSE	FALSE	FALSE
8302	10.1002/chem.201902123	doi.org/10.1002/chem.201902123	Soluble and Planar 2,9-Diazaperopyrenes through Reductive Aromatization of Perylene Diimides: Tunable Emission and Aggregation Behaviors		Chem.-Eur. J.	24	Miyake, Y	FALSE	FALSE	FALSE	FALSE
8303	10.1021/acs.jced.8b00719	doi.org/10.1021/acs.jced.8b00719	Solubility Modeling and Solution Thermodynamics of 4-Amino-2,6-Dimethoxypyrimidine in Cosolvent Mixtures of Methanol, Ethanol, Isopropanol, and N,N-Dimethylformamide plus Water		J. Chem. Eng. Data	24	Xu, RJ	FALSE	FALSE	FALSE	FALSE
8304	10.1021/acs.orglett.8b00139	doi.org/10.1021/acs.orglett.8b00139	BABIPhos Family of Biaryl Dihydrobenzooxaphosphole Ligands for Asymmetric Hydrogenation		Org. Lett.	24	Li, GS; Zatolochnaya, OV	FALSE	FALSE	FALSE	FALSE
8305	10.1016/j.tetlet.2015.10.096	doi.org/10.1016/j.tetlet.2015.10.096	Facile approaches toward the synthesis of N-4-monosubstituted quinazolin-2,4-diamines		Tetrahedron Lett.	24	Rao, PPN	FALSE	FALSE	FALSE	FALSE
8306	10.1021/acs.oprd.5b00302	doi.org/10.1021/acs.oprd.5b00302	Spotlight on Non-Precious Metal Catalysis		Org. Process Res. Dev.	24	Dunetz, JR	FALSE	FALSE	FALSE	FALSE
8307	10.1126/science.1255525	doi.org/10.1126/science.1255525	Merging photoredox with nickel catalysis: Coupling of alpha-carboxyl sp(3)-carbons with aryl halides		Science	24	Doyle, AG	FALSE	FALSE	FALSE	FALSE
8308	10.1002/chem.201303638	doi.org/10.1002/chem.201303638	Simulating Microwave Chemistry in a Resistance-Heated Autoclave Made of Semiconducting Silicon Carbide Ceramic		Chem.-Eur. J.	24	Kappe, CO	FALSE	FALSE	FALSE	FALSE
8309	10.1016/j.tetlet.2013.08.049	doi.org/10.1016/j.tetlet.2013.08.049	Alder-ene reaction of aryne with olefins		Tetrahedron Lett.	24	Yin, J	FALSE	FALSE	FALSE	FALSE
8310	10.7503/cjcu20130279	doi.org/10.7503/cjcu20130279	Total Synthesis of Chelerythrine		Chem. J. Chin. Univ.-Chin.	24	Xie, LG	FALSE	FALSE	FALSE	FALSE
8311	10.1021/ja301612y	doi.org/10.1021/ja301612y	New Directing Groups for Metal-Catalyzed Asymmetric Carbon-Carbon Bond-Forming Processes: Stereoconvergent Alkyl-Alkyl Suzuki Cross-Couplings of Unactivated Electrophiles		J. Am. Chem. Soc.	24	Fu, GC	FALSE	TRUE	FALSE	FALSE
8312	10.1021/ol202058r	doi.org/10.1021/ol202058r	Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations		Org. Lett.	24	Yang, LM	FALSE	FALSE	FALSE	FALSE
8313	10.1039/c0cc05186a	doi.org/10.1039/c0cc05186a	Unexpected preparation of (Z)-chloromethyleneketals and their sulfur analogues by a novel three-component condensation		Chem. Commun.	24	Marko, IE	FALSE	FALSE	FALSE	FALSE
8314	10.1016/j.tetlet.2010.08.051	doi.org/10.1016/j.tetlet.2010.08.051	S(N)2-Selective allylic substitution of chiral gamma-aryl substituted allylic picolinates with alkynylcopper reagents		Tetrahedron Lett.	24	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
8315	10.1039/b917777a	doi.org/10.1039/b917777a	Direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes via Pd/Cu-catalyzed phosphonium coupling		Chem. Commun.	24	Kang, FA	FALSE	FALSE	FALSE	FALSE
8316	10.1055/s-0029-1218356	doi.org/10.1055/s-0029-1218356	Gold Catalysis in Glycosylation Reactions		Synlett	24	Kunz, H	FALSE	FALSE	FALSE	FALSE
8317	10.1021/ol900295u	doi.org/10.1021/ol900295u	Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides		Org. Lett.	24	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8318	10.1016/j.jorganchem.2008.10.052	doi.org/10.1016/j.jorganchem.2008.10.052	Palladium catalyzed-dehalogenation of aryl chlorides and bromides using phosphite ligands		J. Organomet. Chem.	24	Lee, S	FALSE	FALSE	FALSE	FALSE
8319	10.1002/anie.200900465	doi.org/10.1002/anie.200900465	Devising Boron Reagents for Orthogonal Functionalization through Suzuki-Miyaura Cross-Coupling		Angew. Chem.-Int. Edit.	24	Tobisu, M	FALSE	FALSE	FALSE	FALSE
8320	10.1021/ja8055358	doi.org/10.1021/ja8055358	A highly active catalyst for Pd-catalyzed amination reactions: Cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides		J. Am. Chem. Soc.	24	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8321	10.1016/j.tetlet.2008.07.060	doi.org/10.1016/j.tetlet.2008.07.060	Palladium-free Suzuki-Miyaura cross-coupling at elevated pressures		Tetrahedron Lett.	24	Young, DJ	FALSE	FALSE	FALSE	FALSE
8322	10.3184/030823408X338729	doi.org/10.3184/030823408X338729	Synthesis of tetrasubstituted olefins by stereoselective allylzincation-Negishi tandem reaction of acetylenic sulfones		J. Chem. Res	24	Cai, MZ	FALSE	FALSE	FALSE	FALSE
8323	10.1134/S0023158408040125	doi.org/10.1134/S0023158408040125	Polymerization of methyl methacrylate using the NiX2(PPh3)(2)/Zn catalytic system		Kinet. Catal.	24	Il'ichev, IS	FALSE	FALSE	FALSE	FALSE
8324	10.1002/adsc.200800082	doi.org/10.1002/adsc.200800082	Gallium trichloride-promoted ethynylation reaction of 1,4-dienes		Adv. Synth. Catal.	24	Yamaguchi, M	FALSE	FALSE	FALSE	FALSE
8325	10.1039/b803072c	doi.org/10.1039/b803072c	Nickel-catalyzed cross-coupling reactions of benzylic zinc reagents with aromatic bromides, chlorides and tosylates		Chem. Commun.	24	Knochel, P	FALSE	FALSE	FALSE	FALSE
8326	10.1016/j.catcom.2007.05.008	doi.org/10.1016/j.catcom.2007.05.008	Pd(OAc)(2)-catalyzed room temperature homocoupling reaction of arylboronic acids under air without ligand		Catal. Commun.	24	Mao, JC	FALSE	FALSE	FALSE	FALSE
8327	10.1134/S107042800705017X	doi.org/10.1134/S107042800705017X	Synthesis of 3-bromosubstituted 2-arylbornylenes by cross-coupling		Russ. J. Organ. Chem.	24	Ilaldinov, IZ	FALSE	FALSE	FALSE	FALSE
8328	10.1016/j.tet.2006.11.053	doi.org/10.1016/j.tet.2006.11.053	Regiospecific synthesis of 1,5-disubstituted-1H-pyrazoles containing differentiated 3,4-dicarboxylic acid esters via Suzuki coupling of the corresponding 5-trifluoromethane sulfonates		Tetrahedron	24	Dragovich, PS	FALSE	FALSE	FALSE	FALSE
8329	10.1016/j.tetlet.2006.10.154	doi.org/10.1016/j.tetlet.2006.10.154	Synthesis of substituted tetralones as intermediates of CNS agents via palladium-catalyzed cross-coupling reactions		Tetrahedron Lett.	24	Ravina, E	FALSE	FALSE	FALSE	FALSE
8330	10.1016/j.tetasy.2006.06.013	doi.org/10.1016/j.tetasy.2006.06.013	Synthesis of homologated binaphthyl N,P-ligands for Pd-catalyzed asymmetric allylic alkylation		Tetrahedron-Asymmetry	24	Ha, DC	FALSE	FALSE	FALSE	FALSE
8331	10.1021/ol0517271	doi.org/10.1021/ol0517271	Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids		Org. Lett.	24	McLaughlin, M	FALSE	FALSE	FALSE	FALSE
8332	10.1016/j.tetlet.2004.12.067	doi.org/10.1016/j.tetlet.2004.12.067	A thermally-cleavable linker for solid-phase synthesis		Tetrahedron Lett.	24	Finn, MG	FALSE	FALSE	FALSE	FALSE
8333	10.1002/adsc.200404192	doi.org/10.1002/adsc.200404192	Novel nickel-catalyzed coupling reaction of allyl ethers with chlorosilanes, alkyl tosylates, or alkyl halides promoted hy vinyl-Grignard reagent leading to allylsilanes or alkenes		Adv. Synth. Catal.	24	Terao, J	FALSE	FALSE	FALSE	FALSE
8334	10.1021/ol048490d	doi.org/10.1021/ol048490d	Azoles as Suzuki cross-coupling leaving groups: Syntheses of 6-arylpurine 2 '-deoxynucleosides and nucleosides from 6-(imidazol-1-yl)- and 6-(1,2,4-triazol-4-yl)purine derivatives		Org. Lett.	24	Liu, JQ	FALSE	FALSE	FALSE	FALSE
8335	10.1021/ol036131x	doi.org/10.1021/ol036131x	Palladium-catalyzed Suzuki-Miyaura cross-couplings of sulfonyl chlorides and boronic acids		Org. Lett.	24	Vogel, P	FALSE	FALSE	FALSE	FALSE
8336	10.1002/anie.200453765	doi.org/10.1002/anie.200453765	Nickel-catalyzed cross-coupling of aryl Grignard reagents with aromatic alkyl ethers: An efficient synthesis of unsymmetrical biaryls		Angew. Chem.-Int. Edit.	24	Dankwardt, JW	FALSE	FALSE	FALSE	FALSE
8337	10.1021/ja035983p	doi.org/10.1021/ja035983p	Regioselective and enantiospecific rhodium-catalyzed allylic alkylation reactions using copper(I) enolates: Synthesis of (-)-sugiresinol dimethyl ether		J. Am. Chem. Soc.	24	Evans, PA	FALSE	FALSE	FALSE	FALSE
8338	10.1002/1521-3749(200206)628:5<971::AID-ZAAC971>3.0.CO;2-G	doi.org/10.1002/1521-3749(200206)628:5<971::AID-ZAAC971>3.0.CO;2-G	Synthesis and characterization of intramolecularly stabilized chiral dimethylindium alkoxides and their use as cross coupling reagents		Z. Anorg. Allg. Chem.	24	Schumann, H	FALSE	FALSE	FALSE	FALSE
8339	10.1021/ja0157346	doi.org/10.1021/ja0157346	Regioselective catalytic allylic alkylation directed by removable 2-PyMe2Si group		J. Am. Chem. Soc.	24	Yoshida, J	FALSE	FALSE	FALSE	FALSE
8340	10.1016/S0040-4039(00)01690-7	doi.org/10.1016/S0040-4039(00)01690-7	Modular Mo-based catalysts for efficient asymmetric olefin metathesis. Catalytic enantioselective synthesis of cyclic ethers and acetals		Tetrahedron Lett.	24	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
8341	10.1016/S0040-4020(00)00815-2	doi.org/10.1016/S0040-4020(00)00815-2	The cross-coupling reaction of arylboronic acids with chloropyridines and electron-deficient chloroarenes catalyzed by a polymer-bound palladium complex		Tetrahedron	24	Miyaura, N	FALSE	FALSE	FALSE	FALSE
8342	10.1039/a903345i	doi.org/10.1039/a903345i	Palladium-catalyzed cyanation of aryl and heteroaryl iodides with copper(I) cyanide		J. Chem. Soc.-Perkin Trans. 1	24	Sakamoto, T	FALSE	FALSE	FALSE	FALSE
8343	10.1016/S0040-4039(99)00239-7	doi.org/10.1016/S0040-4039(99)00239-7	Cross-coupling of chloroarenes with boronic acids using a water-soluble nickel catalyst.		Tetrahedron Lett.	24	Genet, JP	FALSE	FALSE	FALSE	FALSE
8344	10.1016/S0040-4039(98)00996-4	doi.org/10.1016/S0040-4039(98)00996-4	Syntheses of [5]-helicene by McMurry or carbenoid couplings		Tetrahedron Lett.	24	Gingras, M	FALSE	FALSE	FALSE	FALSE
8345	10.1021/jo00109a045	doi.org/10.1021/jo00109a045	ARYL MESYLATES IN METAL-CATALYZED HOMOCOUPLING AND CROSS-COUPLING REACTIONS .3. A SIMPLE AND GENERAL-METHOD FOR THE SYNTHESIS OF 2,2'-DIAROYL-4,4'-DIHYDROXYBIPHENYLS		J. Org. Chem.	24	PERCEC, V	FALSE	FALSE	FALSE	FALSE
8346	10.1016/S0040-4039(00)73479-4	doi.org/10.1016/S0040-4039(00)73479-4	NICKEL AND PALLADIUM-CATALYZED COUPLING OF VINYL SELENIDES WITH TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE - A NEW SYNTHESIS OF ALLYL SILANES		Tetrahedron Lett.	24	HEVESI, L	FALSE	FALSE	FALSE	FALSE
8347	10.1021/ic00301a012	doi.org/10.1021/ic00301a012	UNANTICIPATED FORMATION OF DIBROMO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) BY SEQUENTIAL MICHAEL REVERSION AND MICHAEL ADDITION OF DIBROMOBIS(DIPHENYLVINYLPHOSPHINE)NICKEL(II)		Inorg. Chem.	24		FALSE	FALSE	FALSE	FALSE
8348	10.1016/S0040-4039(00)88199-X	doi.org/10.1016/S0040-4039(00)88199-X	ONE-STEP SYNTHESIS OF KETONES FROM CARboxYLIC-ACIDS AND GRIGNARD-REAGENTS IN THE PRESENCE OF A NICKEL(II)-PHOSPHINE CATALYST		Tetrahedron Lett.	24		FALSE	FALSE	FALSE	FALSE
8349	10.1016/j.jclepro.2017.02.121	doi.org/10.1016/j.jclepro.2017.02.121	Highly active bio-waste cellulose supported poly(amidoxime) palladium(II) complex for Heck reactions		J. Clean Prod.	24	Sarkar, SM	FALSE	FALSE	FALSE	FALSE
8350	10.1002/jhet.2394	doi.org/10.1002/jhet.2394	Synthesis of 2-Phenylquinoline and its Derivatives by Multicomponent Reaction of Aniline, Benzylamine, Alcohols, and CCl4 Catalyzed by FeCl3 center dot 6H(2)O		J. Heterocycl. Chem.	24	Khusnutdinov, R	FALSE	FALSE	FALSE	FALSE
8351	10.1007/s10870-020-00859-w	doi.org/10.1007/s10870-020-00859-w	Methods, Syntheses and Characterization of Diaryl, Aryl Benzyl, and Dibenzyl Sulfides	The first Rh(I)-catalyzed asymmetric approach for the intermolecular functionalization of C(sp(3))-H bonds is reported. For the first time, unsymmetrical N-heterocyclic carbenes (NHCs) were used for asymmetric catalysis that is capable of achieving not only high site-selectivity but also enantioselectivity. The Rh(I)/NHC* catalytic systems were ;applied to asymmetric direct C(sp(3))-H arylation, which provides a synthetic route toward enantioenriched triarylmethanes.	J. Chem. Crystallogr.	23	Zhang, QF	FALSE	FALSE	FALSE	FALSE
8352	10.1038/s41598-020-62695-4	doi.org/10.1038/s41598-020-62695-4	Handy and highly efficient oxidation of benzylic alcohols to the benzaldehyde derivatives using heterogeneous Pd/AlO(OH) nanoparticles in solvent-free conditions	A rapid and highly selective oxidative cross-coupling reaction between readily available and shelf-stable arylboronic acids and primary or secondary potassium alkyltrifluoroborates was devised and developed, which works under mild conditions using copper(II) acetate as the catalyst and silver oxide as the oxidant. Initial experimental results indicate that a single electron transmetalation process is involved. This approach effectively bypasses the problems associated with the traditional cross-coupling reactions of alkylboronates and thus provides a complementary method in building C(sp(2))-C(sp(3)) bonds.	Sci Rep	23	Goksu, H	FALSE	FALSE	FALSE	FALSE
8353	10.1016/j.saa.2019.117708	doi.org/10.1016/j.saa.2019.117708	Original synthesis and spectroscopic study of thiophene triazine derivatives with enhanced luminescence properties		Spectroc. Acta Pt. A-Molec. Biomolec. Spectr.	23	Robitzer, M	FALSE	FALSE	FALSE	FALSE
8354	10.1021/acs.orglett.9b03672	doi.org/10.1021/acs.orglett.9b03672	Diborylalkyllithium Salts Trigger Regioselective Ring Opening of Vinyl Aziridines		Org. Lett.	23	Gava, R; Fernandez, E	FALSE	FALSE	FALSE	FALSE
8355	10.3390/molecules24203678	doi.org/10.3390/molecules24203678	Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose		Molecules	23	Yuan, CL	FALSE	FALSE	FALSE	FALSE
8356	10.1039/c8ra07355d	doi.org/10.1039/c8ra07355d	An efficient and atom-economical route to N-aryl amino alcohols from primary amines		RSC Adv.	23	Li, D	FALSE	FALSE	FALSE	FALSE
8357	10.1007/s10593-018-2220-3	doi.org/10.1007/s10593-018-2220-3	Boron trifluoride-mediated synthesis of N-aryl-substituted pyrrolidines from tetrahydrofuran and amines		Chem. Heterocycl. Compds.	23	Wang, ZH	FALSE	FALSE	FALSE	FALSE
8358	10.1021/ol501600k	doi.org/10.1021/ol501600k	Pd(dba)(2) vs Pd-2(dba)(3): An in-Depth Comparison of Catalytic Reactivity and Mechanism via Mixed-Ligand Promoted C-N and C-S Coupling Reactions		Org. Lett.	23	Peng, L	FALSE	FALSE	FALSE	FALSE
8359	10.1002/jccs.201300134	doi.org/10.1002/jccs.201300134	Nickel Complexes Catalyzed Hydrodechlorination of Aryl Chlorides in Ionic Liquid		J. Chin. Chem. Soc.	23	Wang, YH	FALSE	FALSE	FALSE	FALSE
8360	10.1021/ol401021x	doi.org/10.1021/ol401021x	Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions between Sulfamates and Potassium Boc-Protected Aminomethyltrifluoroborates		Org. Lett.	23	Molander, GA	FALSE	FALSE	FALSE	FALSE
8361	10.3987/COM-12-S(N)94	doi.org/10.3987/COM-12-S(N)94	SYNTHESIS OF A NEW OSELTAMIVIR DERIVATIVE THROUGH LATE-STAGE CATALYTIC C-H FUNCTIONALIZATION		Heterocycles	23	Saito, K	FALSE	FALSE	FALSE	FALSE
8362	10.1021/jo301069c	doi.org/10.1021/jo301069c	Cross-Coupling Reactions		J. Org. Chem.	23		FALSE	FALSE	FALSE	FALSE
8363	10.1021/jo300437t	doi.org/10.1021/jo300437t	Ligand Effects on the Stereochemical Outcome of Suzuki-Miyaura Couplings		J. Org. Chem.	23	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
8364	10.1021/op3000064	doi.org/10.1021/op3000064	Initial Process Development and Scale-Up of the Synthesis of a Triple Reuptake Inhibitor ALB 109780		Org. Process Res. Dev.	23	Yang, Q	FALSE	FALSE	FALSE	FALSE
8365	10.3987/COM-11-S(P)20	doi.org/10.3987/COM-11-S(P)20	Ni- AND Cu-CATALYZED COUPLING REACTIONS UISING 2-(4,5-DIHYDRO-1H-IMIDAZO-2-YL)PHENOL AS A VERSATILE PHOSPHINE-FREE LIGAND		Heterocycles	23	Haneda, S	FALSE	FALSE	FALSE	FALSE
8366	10.1016/j.tetlet.2010.05.098	doi.org/10.1016/j.tetlet.2010.05.098	Manganese-catalyzed cross-coupling reactions of aliphatic amines with aryl halides		Tetrahedron Lett.	23	Teo, YC	FALSE	FALSE	FALSE	FALSE
8367	10.1016/j.tetlet.2009.04.012	doi.org/10.1016/j.tetlet.2009.04.012	TfOH-catalyzed allylation of alkynes with cyclic Baylis-Hillman alcohols		Tetrahedron Lett.	23	Liu, L	FALSE	FALSE	FALSE	FALSE
8368	10.1021/ja805165y	doi.org/10.1021/ja805165y	Nickel-catalyzed asymmetric cross-couplings of racemic propargylic halides with arylzinc reagents		J. Am. Chem. Soc.	23	Fu, GC	FALSE	FALSE	FALSE	FALSE
8369	10.1021/ol051896l	doi.org/10.1021/ol051896l	Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates		Org. Lett.	23	Wehn, PM	FALSE	FALSE	FALSE	FALSE
8370	10.1055/s-2005-871544	doi.org/10.1055/s-2005-871544	Palladium-catalyzed Suzuki-Miyaura reactions of potassium aryl- and heteroaryltrifluoroborates with aryl- and heteroaryl triflates		Synlett	23	Molander, GA	FALSE	FALSE	FALSE	FALSE
8371	10.1016/j.tetlet.2004.09.020	doi.org/10.1016/j.tetlet.2004.09.020	Synthesis of diarylmethane derivatives from Pd-catalyzed cross-coupling reactions of benzylic halides with arylboronic acids		Tetrahedron Lett.	23	Monteiro, AL	FALSE	FALSE	FALSE	FALSE
8372	10.1021/ol048517t	doi.org/10.1021/ol048517t	Facile synthesis of 2-substituted 1,2-dihydro-1-naphthols and 2-substituted 1-naphthols		Org. Lett.	23	Chen, CL	FALSE	FALSE	FALSE	FALSE
8373	10.1016/j.tetlet.2003.10.176	doi.org/10.1016/j.tetlet.2003.10.176	A novel methodology for the synthesis of 1-desoxy-Delta(8)-tetrahydrocannabinol (THC) analogues		Tetrahedron Lett.	23	Razdan, RK	FALSE	FALSE	FALSE	FALSE
8374	10.1016/S0040-4039(03)01789-1	doi.org/10.1016/S0040-4039(03)01789-1	Pd/C-catalyzed room-temperature hydrodehalogenation of aryl halides with hydrazine hydrochloride		Tetrahedron Lett.	23	Taillefer, M	FALSE	FALSE	FALSE	FALSE
8375	10.1021/ja0299708	doi.org/10.1021/ja0299708	Copper-catalyzed domino halide exchange-cyanation of aryl bromides		J. Am. Chem. Soc.	23	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8376	10.1071/CH03113	doi.org/10.1071/CH03113	Synthetic studies of the phosphatidylinositol 3-kinase inhibitor LY294002 and related analogues		Aust. J. Chem.	23	Thompson, P	FALSE	FALSE	FALSE	FALSE
8377	10.1016/S1387-7003(02)00558-0	doi.org/10.1016/S1387-7003(02)00558-0	Synthesis, spectroscopic study and X-ray crystal structure of unsymmetrical bis(phosphine)-platinum complex, [PtCl2{eta(2)-Ph2POCH2CH2N(CH3)PPh2]		Inorg. Chem. Commun.	23	Balakrishna, MS	FALSE	FALSE	FALSE	FALSE
8378	10.1021/jo010289i	doi.org/10.1021/jo010289i	Nickel-catalyzed coupling of aryl iodides with aromatic aldehydes: Chemoselective synthesis of ketones		J. Org. Chem.	23	Cheng, CH	FALSE	FALSE	FALSE	FALSE
8379	10.1021/ol0160607	doi.org/10.1021/ol0160607	Zr-catalyzed electrophilic carbomagnesation of aryl olefins. Mechanism-based control of Zr-Mg ligand exchange		Org. Lett.	23	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
8380	10.1016/S0040-4020(00)00814-0	doi.org/10.1016/S0040-4020(00)00814-0	Synthesis of biaryls via cross-coupling reaction of arylboronic acids with aryl chlorides catalyzed by NiCl2/triphenylphosphine complexes		Tetrahedron	23	Miyaura, N	FALSE	FALSE	FALSE	FALSE
8381	10.1021/jo961900u	doi.org/10.1021/jo961900u	Ni-catalyzed cross coupling of alkoxide-containing vinyl halides with grignard reagents. A ''one-pot'' synthesis of 2-[(trimethylsilyl)methyl]-2-propen-1-yl acetate		J. Org. Chem.	23	Organ, MG	FALSE	FALSE	FALSE	FALSE
8382	10.1016/0957-4166(95)00053-R	doi.org/10.1016/0957-4166(95)00053-R	NEW CHIRAL AMINOPHOSPHINES AND THEIR USE IN ASYMMETRIC CATALYSIS		Tetrahedron: Asymmetry	23	WIMMER, P	FALSE	FALSE	FALSE	FALSE
8383	10.1016/S0040-4039(00)92687-X	doi.org/10.1016/S0040-4039(00)92687-X	THE SYNTHESIS OF ALPHA-STANNYL-SILANES AND THEIR USE IN THE FORMATION OF ALKENES		Tetrahedron Lett.	23	BARRETT, AGM	FALSE	FALSE	FALSE	FALSE
8384	10.1246/bcsj.61.3368	doi.org/10.1246/bcsj.61.3368	SIMPLE SYNTHESIS OF (Z)-12-NONADECEN-9-ONE, (Z)-13-ICOSEN-10-ONE, THE SEX-PHEROMONE OF PEACH FRUIT MOTH, AND (Z)-5-UNDECEN-2-ONE, A BIOLOGICALLY-ACTIVE MOLECULE FROM THE PEDAL GLAND OF THE BONTEBOK		Bull. Chem. Soc. Jpn.	23	YAMASHITA, M	FALSE	FALSE	FALSE	FALSE
8385	10.1021/ja00278a057	doi.org/10.1021/ja00278a057	CATALYTIC EFFECT OF NICKEL(II) CHLORIDE AND PALLADIUM(II) ACETATE ON CHROMIUM(II)-MEDIATED COUPLING REACTION OF IODO OLEFINS WITH ALDEHYDES		J. Am. Chem. Soc.	23		FALSE	FALSE	FALSE	FALSE
8386	10.1016/S0040-4039(00)83974-X	doi.org/10.1016/S0040-4039(00)83974-X	MODIFICATION OF OPTICALLY-ACTIVE FERROCENYLPHOSPHINE LIGANDS FOR PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC ALKYLATION		Tetrahedron Lett.	23	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
8387	10.1016/S0040-4039(00)98166-8	doi.org/10.1016/S0040-4039(00)98166-8	ASYMMETRIC COUPLING OF ARYLMAGNESIUM BROMIDES WITH ALLYLIC ESTERS		Tetrahedron Lett.	23	HIYAMA, T	FALSE	FALSE	FALSE	FALSE
8388	10.1039/c39820000840	doi.org/10.1039/c39820000840	A GENERAL OLEFIN SYNTHESIS		J. Chem. Soc.-Chem. Commun.	23		FALSE	FALSE	FALSE	FALSE
8389	10.1002/chem.201702824	doi.org/10.1002/chem.201702824	Catalytic Functionalization of Styrenyl Epoxides via 2-Nickela(II)oxetanes		Chem.-Eur. J.	23	Love, JA	FALSE	FALSE	FALSE	FALSE
8390	10.1016/j.catcom.2016.07.019	doi.org/10.1016/j.catcom.2016.07.019	Cu-ZSM5 as reusable catalyst for the one-pot, odorless and ligand-free C-S bond formation		Catal. Commun.	23	Rostami, A	FALSE	FALSE	FALSE	FALSE
8391	10.1246/cl.160439	doi.org/10.1246/cl.160439	Silicon-based Cross-coupling of Aryl Tosylates by Cooperative Palladium/Copper Catalysis		Chem. Lett.	23	Nakao, Y	FALSE	FALSE	FALSE	FALSE
8392	10.1107/S2053229619012567	doi.org/10.1107/S2053229619012567	Unusual structure of a biphenyl fragment: the important role of weak interactions		Acta Crystallogr. Sect. C-Struct. Chem.	22	Vashchenko, A	FALSE	FALSE	FALSE	FALSE
8393	10.3762/bjoc.13.263	doi.org/10.3762/bjoc.13.263	Preparation and isolation of isobenzofuran		Beilstein J. Org. Chem.	22	Herges, R	FALSE	FALSE	FALSE	FALSE
8394	10.1002/anie.201706982	doi.org/10.1002/anie.201706982	Buchwald-Hartwig Amination of Nitroarenes		Angew. Chem.-Int. Edit.	22	Nakao, Y	FALSE	FALSE	FALSE	FALSE
8395	10.1055/s-0035-1560726	doi.org/10.1055/s-0035-1560726	One-Pot Synthesis of O-Aryl Carbamates		Synthesis	22	Adler, MJ	FALSE	FALSE	FALSE	FALSE
8396	10.3390/catal5010018	doi.org/10.3390/catal5010018	Palladium on Carbon-Catalyzed Suzuki-Miyaura Coupling Reaction Using an Efficient and Continuous Flow System		Catalysts	22	Monguchi, Y	FALSE	FALSE	FALSE	FALSE
8397	10.1107/S2053229615001680	doi.org/10.1107/S2053229615001680	Tris(tri-o-tolyl phosphite-kappa P)nickel: a coordinatively unsaturated nickel(0) complex		Acta Crystallogr. Sect. C-Struct. Chem.	22	Koutsantonis, GA	FALSE	FALSE	FALSE	FALSE
8398	10.3762/bjoc.10.109	doi.org/10.3762/bjoc.10.109	Palladium-catalysed cross-coupling reaction of ultra-stabilised 2-aryl-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole compounds with aryl bromides: A direct protocol for the preparation of unsymmetrical biaryls		Beilstein J. Org. Chem.	22	Robinson, RS	FALSE	FALSE	FALSE	FALSE
8399	10.1002/ejic.201301115	doi.org/10.1002/ejic.201301115	On the Mechanism of Reduction of Maleate Ions by Ni-I Complexes with Tetraazamacrocyclic Ligands in Aqueous Solutions		Eur. J. Inorg. Chem.	22	Meyerstein, D	FALSE	FALSE	FALSE	FALSE
8400	10.1055/s-0031-1291146	doi.org/10.1055/s-0031-1291146	Synthesis of 4-Quinolones through Nickel-Catalyzed Intramolecular Amination on the beta-Carbon of o-(N-Alkylamino)propiophenones		Synlett	22	Kuwano, R	FALSE	FALSE	FALSE	FALSE
8401	10.1021/ol301436v	doi.org/10.1021/ol301436v	Cross-Coupling Reactions		Org. Lett.	22		FALSE	FALSE	FALSE	FALSE
8402	10.1021/jo3003503	doi.org/10.1021/jo3003503	A Copper-Catalyzed Petasis Reaction for the Synthesis of Tertiary Amines and Amino Esters		J. Org. Chem.	22	Bergin, E	FALSE	FALSE	FALSE	FALSE
8403	10.1002/ejoc.201001428	doi.org/10.1002/ejoc.201001428	Palladium-Catalyzed alpha-Ketone Arylation under Mild Conditions		Eur. J. Org. Chem.	22	Shi, YH	FALSE	FALSE	FALSE	FALSE
8404	10.1246/cl.2010.1050	doi.org/10.1246/cl.2010.1050	Homogeneous Ruthenium Precatalyst for Suzuki-Miyaura Coupling Reaction		Chem. Lett.	22	Kawatsura, M	FALSE	FALSE	FALSE	FALSE
8405	10.2174/157017810790534002	doi.org/10.2174/157017810790534002	Homocoupling Reaction of Aryl Boronic Acids Catalyzed by Pd(OAc)(2)/K2CO3 in Water under Air Atmosphere		Lett. Org. Chem.	22	Wu, N	FALSE	FALSE	FALSE	FALSE
8406	10.1021/ja902046m	doi.org/10.1021/ja902046m	Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides		J. Am. Chem. Soc.	22	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8407	10.1021/ja802704j	doi.org/10.1021/ja802704j	Asymmetric imino aza-enamine reaction catalyzed by axially chiral dicarboxylic acid: Use of arylaldehyde N,N-dialkylhydrazones as acyl anion equivalent		J. Am. Chem. Soc.	22	Maruoka, K	FALSE	FALSE	FALSE	FALSE
8408	10.1021/jo7026189	doi.org/10.1021/jo7026189	An expedient synthesis of the fibril binding compound FSB via sequential pd-catalyzed coupling reactions		J. Org. Chem.	22	Skrydstrup, T	FALSE	FALSE	FALSE	FALSE
8409	10.1021/ja711449e	doi.org/10.1021/ja711449e	Palladium-catalyzed carbonylation of aryl tosylates and mesylates		J. Am. Chem. Soc.	22	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8410	10.1039/b812396a	doi.org/10.1039/b812396a	Polyfunctional benzylic zinc chlorides by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl2		Chem. Commun.	22	Knochel, P	FALSE	FALSE	FALSE	FALSE
8411	10.1007/s11172-007-0048-6	doi.org/10.1007/s11172-007-0048-6	Trisodium heptaphosphide in reactions with alkyl and aryl tosylates		Russ. Chem. Bull.	22	Milyukov, VA	FALSE	FALSE	FALSE	FALSE
8412	10.1246/cl.2004.1356	doi.org/10.1246/cl.2004.1356	Iron-catalyzed dechlorination of aryl chlorides		Chem. Lett.	22	Takahashi, T	FALSE	FALSE	FALSE	FALSE
8413	10.1081/SCC-120030306	doi.org/10.1081/SCC-120030306	Solvent-free synthesis of aryl tosylates under microwave activation		Synth. Commun.	22	Xia, CG	FALSE	FALSE	FALSE	FALSE
8414	10.1163/156855503768336289	doi.org/10.1163/156855503768336289	Novel boron reagents for designed organic syntheses. 1. Direct synthesis of aromatic esters in the presence of boric acid		Des. Monomers Polym.	22	Tanasa, F	FALSE	FALSE	FALSE	FALSE
8415	10.1021/ja005689m	doi.org/10.1021/ja005689m	Regioselective rhodium-catalyzed allylic linchpin cross-coupling reactions: Diastereospecific construction of anti-1,3-carbon stereogenic centers and C-2-symmetrical fragments		J. Am. Chem. Soc.	22	Evans, PA	FALSE	FALSE	FALSE	FALSE
8416	10.1016/S0040-4039(98)00142-7	doi.org/10.1016/S0040-4039(98)00142-7	Regioselective rhodium-catalyzed allylic alkylation with a modified Wilkinson's catalyst		Tetrahedron Lett.	22	Evans, PA	FALSE	FALSE	FALSE	FALSE
8417	10.1021/om970514f	doi.org/10.1021/om970514f	Reaction between ruthenium(0) complexes and dihalo compounds. A new method for the synthesis of ruthenium olefin metathesis catalysts		Organometallics	22		FALSE	FALSE	FALSE	FALSE
8418	10.1039/p19950002073	doi.org/10.1039/p19950002073	REGIOSELECTIVITY IN THE NICKEL-CATALYZED COUPLING OF CYCLIC CARBONATES OF BUT-3-ENE-1,2-DIOLS WITH ORGANOBORATES		J. Chem. Soc.-Perkin Trans. 1	22		FALSE	FALSE	FALSE	FALSE
8419	10.1080/10406639408015152	doi.org/10.1080/10406639408015152	ABBREVIATED SYNTHESIS OF BENZO[C]PHENANTHRENE, BENZ[A]ANTHRACENE AND THEIR RESPECTIVE 5-METHYL DERIVATIVES VIA COMBINED METALATION-PALLADIUM-CATALYZED CROSS-COUPLING STRATEGY		Polycycl. Aromat. Compd.	22		FALSE	FALSE	FALSE	FALSE
8420	10.1021/ja00163a060	doi.org/10.1021/ja00163a060	NOVEL DEPENDENCY OF STEREOCHEMISTRY UPON METAL, LIGAND, AND SOLVENT IN OXIDATIVE ADDITION OF ALLYLIC CHLORIDE TO PD(0) AND PT(0) COMPLEXES		J. Am. Chem. Soc.	22	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
8421	10.1021/ja00312a071	doi.org/10.1021/ja00312a071	SPECIFIC RATE ENHANCEMENT BY OLEFIN COORDINATION IN REDUCTIVE ELIMINATION OF ETA-3-ALLYLPALLADIUM COMPLEXES		J. Am. Chem. Soc.	22	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
8422	10.1021/jo00218a004	doi.org/10.1021/jo00218a004	L-CYSTEINE-DERIVED, L-METHIONINE-DERIVED, AND D-PENICILLAMINE-DERIVED LIGANDS FOR TRANSITION-METAL CATALYZED CARBON CARBON BOND-FORMING REACTIONS		J. Org. Chem.	22		FALSE	FALSE	FALSE	FALSE
8423	10.1021/bk-1982-0185.ch007	doi.org/10.1021/bk-1982-0185.ch007	HIGHLY SELECTIVE SYNTHESIS WITH NOVEL METALLIC REAGENTS			22	NOZAKI, H	FALSE	FALSE	FALSE	FALSE
8424	10.1016/0040-4039(80)80215-2	doi.org/10.1016/0040-4039(80)80215-2	NICKEL-CATALYZED CROSS-COUPLING OF SILYL ENOL ETHERS WITH GRIGNARD-REAGENTS - REGIO-CONTROLLED AND STEREOCONTROLLED SYNTHESIS OF OLEFINS		Tetrahedron Lett.	22		FALSE	FALSE	FALSE	FALSE
8425	10.1016/0040-4039(80)80120-1	doi.org/10.1016/0040-4039(80)80120-1	CARBON-CARBON BOND FORMATION BY CROSS-COUPLING OF ENOL PHOSPHATES WITH ORGANO-ALUMINUM COMPOUNDS CATALYZED BY PALLADIUM(0) COMPLEX		Tetrahedron Lett.	22		FALSE	FALSE	FALSE	FALSE
8426	10.1021/acs.orglett.1c00923	doi.org/10.1021/acs.orglett.1c00923	Symmetric 32 pi (1.0.1.0.1.0.1) Core-Modified Heptaphyrins from Asymmetric Building Block		Org. Lett.	22	Anand, VG	FALSE	FALSE	FALSE	FALSE
8427	10.1002/chem.201701362	doi.org/10.1002/chem.201701362	The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2)Pd(eta(2)-N2C(Ph)CO2Et)]		Chem.-Eur. J.	22	Fructos, MR; Belderrain, TR; Perez, PJ	FALSE	FALSE	FALSE	FALSE
8428	10.1166/nnl.2017.2265	doi.org/10.1166/nnl.2017.2265	Recyclable Ligand-Free Nickel Catalysts in Heterogeneous Heck Coupling Reaction		Nanosci. Nanotechnol. Lett.	22	Li, CL	FALSE	FALSE	FALSE	FALSE
8429	10.1016/j.tetlet.2016.11.076	doi.org/10.1016/j.tetlet.2016.11.076	Regioselective one-pot synthesis of 2,3-diaryl-2H-1-benzopyrans via Bronsted acid-catalyzed [4+2] cycloaddition of salicylaldehydes with diarylacetylenes		Tetrahedron Lett.	22	Honda, K	FALSE	FALSE	FALSE	FALSE
8430	10.1021/jacs.6b08486	doi.org/10.1021/jacs.6b08486	Catalytic Enantioselective Carbon-Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C-H Bonds		J. Am. Chem. Soc.	22	Fu, GC	FALSE	FALSE	FALSE	FALSE
8431	10.2533/chimia.2020.495	doi.org/10.2533/chimia.2020.495	Mechanistic Studies of the Oxidative Addition of Aryl Halides to Ni(0) Centers Bearing Phosphine Ligands	A Pd/(R)-H-8-BINAP-catalyzed asymmetric benzylic alkylation of active methylene compounds has been developed. The reaction proceeds without the use of an external base, and the starting racemic diarylmethyl carbonates are converted into the optically active coupling products which contain the benzylic chiral stereocenter by a dynamic kinetic asymmetric transformation (DYKAT). Additionally, with suitable carbonates bases, the same palladium catalysis allows the corresponding pivalates to be adopted in the same DYKAT process.	Chimia	21	Moret, ME	FALSE	FALSE	FALSE	FALSE
8432	10.1016/j.tetlet.2020.151729	doi.org/10.1016/j.tetlet.2020.151729	Nickel catalyzed deoxygenative cross-coupling of benzyl alcohols with aryl-bromides	A new transformation is presented that enables chemists to couple simple alkyl carboxylic acids with aryl zinc reagents under Ni-catalysis. The success of this reaction hinges on the unique use of redox-active esters that allow one to employ such derivatives as alkyl halides surrogates. The chemistry exhibits broad substrate scope and features a high degree of practicality. The simple procedure and extremely inexpensive nature of both the substrates and pre-catalyst (NiCl2 center dot 6H(2)O, ca. $9.5/mol) bode well for the immediate widespread adoption of this method.	Tetrahedron Lett.	21	Rahaim, R	FALSE	FALSE	FALSE	FALSE
8433	10.1039/c9sc04127c	doi.org/10.1039/c9sc04127c	Enantioselective construction of the tricyclic core of curcusones A-D via a cross-electrophile coupling approach		Chem. Sci.	21	Stoltz, BM	FALSE	FALSE	FALSE	FALSE
8434	10.1016/j.tet.2018.07.057	doi.org/10.1016/j.tet.2018.07.057	An extension of nickel-catalyzed reductive coupling between tertiary alkyl halides with allylic carbonates		Tetrahedron	21	Qian, Q; Yao, K; Gong, HG	FALSE	FALSE	FALSE	FALSE
8435	10.1021/acs.organomet.8b00351	doi.org/10.1021/acs.organomet.8b00351	Bench-Stable Nickel Precatalysts with Heck-type Activation		Organometallics	21	Jamison, TF	FALSE	FALSE	FALSE	FALSE
8436	10.1021/acs.joc.5b01681	doi.org/10.1021/acs.joc.5b01681	Friedel-Crafts Hydroxyalkylation of Indoles Mediated by Trimethylsilyi Trifluoromethanesulfonate		J. Org. Chem.	21	Downey, CW	FALSE	FALSE	FALSE	FALSE
8437	10.1515/hc-2015-0058	doi.org/10.1515/hc-2015-0058	Synthesis of new 4 '-(N-alkylpyrrol-2-yl)-2,2 ': 6 ',2 ''-terpyridines via N-alkylation of a pyrrole moiety		Heterocycl. Commun.	21	Husson, J	FALSE	FALSE	FALSE	FALSE
8438	10.1016/j.tetlet.2015.02.061	doi.org/10.1016/j.tetlet.2015.02.061	A nickel-catalyzed alpha,beta-coupling of saturated ketones		Tetrahedron Lett.	21	Helquist, P	FALSE	FALSE	FALSE	FALSE
8439	10.1016/j.polymer.2015.02.037	doi.org/10.1016/j.polymer.2015.02.037	C(sp(3))-C(sp(3)) coupling polymerization of alkyl dibromides for preparation of polymers with precisely located phenyl pendants		Polymer	21	Chen, YM	FALSE	FALSE	FALSE	FALSE
8440	10.1002/aoc.3144	doi.org/10.1002/aoc.3144	Copper activation of boronic acids: factors affecting reactivity		Appl. Organomet. Chem.	21	Bergin, E	FALSE	FALSE	FALSE	FALSE
8441	10.1021/jo301803h	doi.org/10.1021/jo301803h	Studies on Catalytic Enantioselective Total Synthesis of Caprazamycin B: Construction of the Western Zone		J. Org. Chem.	21	Watanabe, T	FALSE	FALSE	FALSE	FALSE
8442	10.1016/j.tetlet.2012.05.146	doi.org/10.1016/j.tetlet.2012.05.146	One-pot method for alpha-phenylation of ketones using isoxazolidine and triphenylaluminum		Tetrahedron Lett.	21	Miyata, O	FALSE	FALSE	FALSE	FALSE
8443	10.1002/cctc.201100087	doi.org/10.1002/cctc.201100087	Alkoxy-Arene Cleavage using Ni Catalysts		ChemCatChem	21	McGlacken, GP	FALSE	FALSE	FALSE	FALSE
8444	10.1016/j.tetlet.2011.03.151	doi.org/10.1016/j.tetlet.2011.03.151	A novel organozinc reagent 4-coumarinylzinc bromide; preparation and application in the synthesis of 4-substituted coumarin derivatives		Tetrahedron Lett.	21	Kim, SH	FALSE	FALSE	FALSE	FALSE
8445	10.1080/10426500903036022	doi.org/10.1080/10426500903036022	Synthesis of Unsymmetrical Ureas with Coumarin and Thiadiazole Ring Under Microwave Irradiation		Phosphorus Sulfur Silicon Relat. Elem.	21	Chai, LQ	FALSE	FALSE	FALSE	FALSE
8446	10.1021/ol801972f	doi.org/10.1021/ol801972f	Two-Step, One-Pot Ni-Catalyzed Neopentylglycolborylation and Complementary Pd/Ni-Catalyzed Cross-Coupling with Aryl Halides, Mesylates, and Tosylates		Org. Lett.	21	Percec, V	FALSE	FALSE	FALSE	FALSE
8447	10.1021/ja067612p	doi.org/10.1021/ja067612p	Direct observation of the oxidative addition of the aryl carbon-oxygen bond to a ruthenium complex and consideration of the relative reactivity between aryl carbon-oxygen and aryl carbon-hydrogen bonds		J. Am. Chem. Soc.	21	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
8448	10.1055/s-2006-942451	doi.org/10.1055/s-2006-942451	Nitro-group-directed selective deacylation and desulfonation		Synthesis	21	Li, CB	FALSE	FALSE	FALSE	FALSE
8449	10.1021/ol052640i	doi.org/10.1021/ol052640i	Highly regio- and stereoselective synthesis of tetrasubstituted olefins by the three-component tandem reaction of allylzinc bromide, acetylenic sulfone, and halohydrocarbon		Org. Lett.	21	Xie, MH	FALSE	FALSE	FALSE	FALSE
8450	10.1039/b409241d	doi.org/10.1039/b409241d	Synthesis and characterization of electron-rich nickel tris-carbene complexes		Chem. Commun.	21	Meyer, K	FALSE	FALSE	FALSE	FALSE
8451	10.1016/S1010-6030(03)00113-8	doi.org/10.1016/S1010-6030(03)00113-8	Facile synthesis and photo-Fries rearrangement of 2-benzoyl-4-benzoyloxyphenol leading to dibenzoyldihydroxybenzene derivatives		J. Photochem. Photobiol. A-Chem.	21	Park, KK	FALSE	FALSE	FALSE	FALSE
8452	10.1016/S0040-4039(99)00517-1	doi.org/10.1016/S0040-4039(99)00517-1	Nickel-catalyzed cross-couplings of cyclohexenyl phosphate and arylboronic acids		Tetrahedron Lett.	21	Yang, Z	FALSE	FALSE	FALSE	FALSE
8453	10.1021/ja970619+	doi.org/10.1021/ja970619+	Palladium-catalyzed functionalization of lactones via their cyclic ketene acetal phosphates. Efficient new synthetic technology for the construction of medium and large cyclic ethers		J. Am. Chem. Soc.	21	Nicolaou, KC	FALSE	FALSE	FALSE	FALSE
8454	10.1007/s002890050081	doi.org/10.1007/s002890050081	Synthesis of polyarylene homopolymers and copolymers via nickel(0)-catalyzed homocoupling of arylenebismesylates derived from bisphenols		Polym. Bull.	21	Percec, V	FALSE	FALSE	FALSE	FALSE
8455	10.1080/00397919308011138	doi.org/10.1080/00397919308011138	A SHORT, EFFICIENT SYNTHESIS OF 6-CYANO-1-TETRALONES		Synth. Commun.	21		FALSE	FALSE	FALSE	FALSE
8456	10.1016/0304-5102(90)85186-L	doi.org/10.1016/0304-5102(90)85186-L	SELECTIVITY CONTROL IN THE REARRANGEMENT OF 1,3-DIENE MONOEPOXIDES BY PALLADIUM(0) CATALYSTS			21	VISENTIN, G	FALSE	FALSE	FALSE	FALSE
8457	10.1080/00304949009356683	doi.org/10.1080/00304949009356683	A SIMPLE AND SHORT SYNTHESIS OF (Z)-13-EICOSEN-10-ONE, THE SEX-PHEROMONE OF THE PEACH FRUIT MOTH		Org. Prep. Proced. Int.	21	KANG, SK	FALSE	FALSE	FALSE	FALSE
8458	10.1016/0040-4039(90)80134-8	doi.org/10.1016/0040-4039(90)80134-8	SHORT, REGIOSELECTIVE AND STEREOSELECTIVE PREPARATION OF 1,5-DIENES AND 1,6-DIENES - SYNTHESES OF EUDIA-PAVONIA PHEROMONE AND GOSSYPLURE		Tetrahedron Lett.	21		FALSE	FALSE	FALSE	FALSE
8459	10.1016/S0040-4039(00)96684-X	doi.org/10.1016/S0040-4039(00)96684-X	TOTAL SYNTHESIS OF (+/-)-STERPURIC ACID		Tetrahedron Lett.	21	PAQUETTE, LA	FALSE	FALSE	FALSE	FALSE
8460	10.1021/ja00279a068	doi.org/10.1021/ja00279a068	REACTIONS OF ALKENYLCHROMIUM REAGENTS PREPARED FROM ALKENYL TRIFLUOROMETHANESULFONATES (TRIFLATES) WITH CHROMIUM(II) CHLORIDE UNDER NICKEL CATALYSIS		J. Am. Chem. Soc.	21	TAKAI, K	FALSE	FALSE	FALSE	FALSE
8461	10.1016/S0040-4039(00)98674-X	doi.org/10.1016/S0040-4039(00)98674-X	MACROCYCLES WITH SULFIDE AND AMINE BINDING-SITES AS CHIRAL LIGANDS FOR NICKEL CATALYZED CROSS COUPLING OF A GRIGNARD-REAGENT WITH VINYL BROMIDE		Tetrahedron Lett.	21		FALSE	FALSE	FALSE	FALSE
8462	10.1039/c39830000112	doi.org/10.1039/c39830000112	NICKEL CATALYZED ASYMMETRIC COUPLING REACTION BETWEEN ALLYL PHENYL ETHERS AND GRIGNARD-REAGENTS		J. Chem. Soc.-Chem. Commun.	21	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
8463	10.1039/c39820000647	doi.org/10.1039/c39820000647	A STEREOSPECIFIC ROUTE TO OLEFINS THROUGH SEQUENTIAL COUPLING REACTIONS OF GRIGNARD-REAGENTS WITH 1-BROMO-2-PHENYLTHIOETHENE IN THE PRESENCE OF NICKEL OR PALLADIUM CATALYSTS		J. Chem. Soc.-Chem. Commun.	21		FALSE	FALSE	FALSE	FALSE
8464	10.1002/asia.202101004	doi.org/10.1002/asia.202101004	Synthesis of Pentacyclic Framework of Herquline A		Chem.-Asian J.	21	Han, S	FALSE	FALSE	FALSE	FALSE
8465	10.1246/cl.210333	doi.org/10.1246/cl.210333	Photoinduced Carbamoylation of C(sp(3))-H Bonds with Isocyanates		Chem. Lett.	21	Ishida, N; Murakami, M	TRUE	FALSE	FALSE	FALSE
8466	10.1002/hlca.202100089	doi.org/10.1002/hlca.202100089	Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Involving C-O Bond Activation		Helv. Chim. Acta	21	Chatani, N	FALSE	FALSE	FALSE	FALSE
8467	10.1142/S1088424621500528	doi.org/10.1142/S1088424621500528	Acylation of electrophilic bicyclo[1.1.0]butanes via Co/Ni-catalyzed reductive cross-coupling		J. Porphyr. Phthalocyanines	21	Gryko, D	FALSE	FALSE	FALSE	FALSE
8468	10.1055/s-0036-1588793	doi.org/10.1055/s-0036-1588793	Synthesis of Allylbenzene Derivatives through sp(3) C-H Bond Functionalization of Toluene Derivatives		Synlett	21	Abbasi, A	FALSE	FALSE	FALSE	FALSE
8469	10.1080/10426507.2018.1543305	doi.org/10.1080/10426507.2018.1543305	Reactivity patterns of benzhydryl(mesityl)phosphane oxide - a potential intermediate in carbonyl-carbonyl coupling reactions?		Phosphorus Sulfur Silicon Relat. Elem.	20	Arkhypchuk, AI	FALSE	FALSE	FALSE	FALSE
8470	10.1039/c8cc03604g	doi.org/10.1039/c8cc03604g	alpha-Arylation of alkylamines with sulfonylarenes through a radical chain mechanism		Chem. Commun.	20	Shirakawa, E	FALSE	FALSE	FALSE	FALSE
8471	10.1016/j.matpr.2017.11.256	doi.org/10.1016/j.matpr.2017.11.256	Syntheses, Characterization and in vitro biological potent of 2-aminobenzothiazole moiety with Ce(III) metal complexes		Mater. Today-Proc.	20	Neelima	FALSE	FALSE	FALSE	FALSE
8472	10.1016/j.tetlet.2015.10.097	doi.org/10.1016/j.tetlet.2015.10.097	Stereoselective synthesis of two highly potent 5-oxo-ETE receptor antagonists		Tetrahedron Lett.	20	Rokach, J	FALSE	FALSE	FALSE	FALSE
8473	10.1016/j.inoche.2013.12.026	doi.org/10.1016/j.inoche.2013.12.026	C-O bond activation and subsequent decarbonylation of ester promoted by Fe(PMe3)(4)		Inorg. Chem. Commun.	20	Sun, HJ	FALSE	FALSE	FALSE	FALSE
8474	10.1016/j.ultsonch.2011.08.013	doi.org/10.1016/j.ultsonch.2011.08.013	Ultrasound-assisted synthesis of unsymmetrical biaryls by Stille cross-coupling reactions		Ultrason. Sonochem.	20	Domini, CE	FALSE	FALSE	FALSE	FALSE
8475	10.3987/COM-09-S(S)63	doi.org/10.3987/COM-09-S(S)63	PALLADIUM- OR NICKEL-CATALYZED COUPLING REACTION OF DIALKOXYBORANES WITH CHLOROARENES: ARYLATION OF 1,3,2-DIOXABOROLANES OR 1,3,2-DIOXABORINANES		Heterocycles	20	Murata, M	FALSE	FALSE	FALSE	FALSE
8476	10.1021/ol9015892	doi.org/10.1021/ol9015892	A Versatile Catalyst System for Suzuki-Miyaura Cross-Coupling Reactions of C(sp(2))-Tosylates and Mesylates		Org. Lett.	20	Buchwald, SL	FALSE	FALSE	FALSE	FALSE
8477	10.1016/j.tetlet.2008.10.138	doi.org/10.1016/j.tetlet.2008.10.138	Asymmetric total synthesis of MK8383: the iron-mediated coupling reaction is the only effective method for the construction of the (Z)-trisubstituted side-chain alkene		Tetrahedron Lett.	20	Nakada, M	FALSE	FALSE	FALSE	FALSE
8478	10.1021/ja067456m	doi.org/10.1021/ja067456m	Lewis base activation of Grignard reagents with N-heterocyclic carbenes. Cu-free catalytic enantioselective additions to gamma-chloro-alpha,beta-unsaturated esters		J. Am. Chem. Soc.	20	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
8479	10.1016/j.fluid.2005.09.019	doi.org/10.1016/j.fluid.2005.09.019	Impact of configuration and fluorination on the solubility of octyl ester benzoate dimers in CO2		Fluid Phase Equilib.	20	McHugh, MA	FALSE	FALSE	FALSE	FALSE
8480	10.1016/j.polymer.2004.06.021	doi.org/10.1016/j.polymer.2004.06.021	Synthesis and properties of new sulfonated poly(p-phenylene) derivatives for proton exchange membranes. I		Polymer	20	McGrath, JE	FALSE	FALSE	FALSE	FALSE
8481	10.1002/(SICI)1099-0518(199810)36:14<2611::AID-POLA21>3.0.CO;2-K	doi.org/10.1002/(SICI)1099-0518(199810)36:14<2611::AID-POLA21>3.0.CO;2-K	Alkyl-substituted poly(2,5-benzophenone)s synthesized via Ni(0)-catalyzed coupling of aromatic dichlorides and their miscible blends		J. Polym. Sci. Pol. Chem.	20	Sheares, VV	FALSE	FALSE	FALSE	FALSE
8482	10.1021/ja980499l	doi.org/10.1021/ja980499l	Ni-catalyzed asymmetric addition of Grignard reagents to unsaturated cyclic acetals. The influence of added phosphine on enantioselectivity		J. Am. Chem. Soc.	20	Hoveyda, AH	FALSE	FALSE	FALSE	FALSE
8483	10.1016/S0040-4020(97)10206-X	doi.org/10.1016/S0040-4020(97)10206-X	Nickel-catalyzed coupling reaction of sterically congested cis bromides and lithium alkenylborates		Tetrahedron	20	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
8484	10.1039/c39860000922	doi.org/10.1039/c39860000922	PALLADIUM-CATALYZED PREPARATION OF 1,2-DIENES BY SELECTIVE HYDROGENOLYSIS OF ALK-2-YNYL CARBONATES WITH AMMONIUM FORMATE		J. Chem. Soc.-Chem. Commun.	20	TSUJI, J	FALSE	FALSE	FALSE	FALSE
8485	10.1351/pac198658050767	doi.org/10.1351/pac198658050767	A GENERAL-METHOD FOR THE STEREOCONTROLLED SYNTHESIS OF POLYPROPIONATE-DERIVED SEQUENCES		Pure Appl. Chem.	20	STORK, G	FALSE	FALSE	FALSE	FALSE
8486	10.1021/ic00131a090	doi.org/10.1021/ic00131a090	ENANTIOSITE SELECTION IN THE DISPLACEMENT REACTION OF PPH3 BY CHIRAL DIPHOSPHINES IN (ETA-5-C5H5)RUCL(PPH3)2		Inorg. Chem.	20	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
8487	10.1016/S0040-4039(01)90390-9	doi.org/10.1016/S0040-4039(01)90390-9	PD(0) PROMOTED ALKYLATION OF ENOL PHOSPHATES WITH ORGANO-ALUMINUM COMPOUNDS AND ITS SYNTHETIC APPLICATIONS		Tetrahedron Lett.	20		FALSE	FALSE	FALSE	FALSE
8488	10.1021/acs.orglett.6b00911	doi.org/10.1021/acs.orglett.6b00911	Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis		Org. Lett.	20	Molander, GA	TRUE	TRUE	FALSE	FALSE
8489	10.1039/c8py01162a	doi.org/10.1039/c8py01162a	Exploration and development of gold- and silver-catalyzed cross dehydrogenative coupling toward donor-acceptor pi-conjugated polymer synthesis		Polym. Chem.	19	Luscombe, CK	FALSE	FALSE	FALSE	FALSE
8490	10.1016/j.tetlet.2018.11.038	doi.org/10.1016/j.tetlet.2018.11.038	Suzuki-Miyaura cross-coupling reaction of monohalopyridines and L-aspartic acid derivative		Tetrahedron Lett.	19	Usuki, T	FALSE	FALSE	FALSE	FALSE
8491	10.1021/acs.orglett.8b02222	doi.org/10.1021/acs.orglett.8b02222	Scalable Synthesis of (-)-Rasfonin Enabled by a Convergent Enantioselective alpha-Hydroxymethylation Strategy		Org. Lett.	19	Boeckman, RK	FALSE	FALSE	FALSE	FALSE
8492	10.3390/molecules190913603	doi.org/10.3390/molecules190913603	Synthesis and Reactivity of New Aminophenolate Complexes of Nickel		Molecules	19	Vicic, DA	FALSE	FALSE	FALSE	FALSE
8493	10.1021/ml500161v	doi.org/10.1021/ml500161v	Two Potent OXE-R Antagonists: Assignment of Stereochemistry		ACS Med. Chem. Lett.	19	Rokach, J	FALSE	FALSE	FALSE	FALSE
8494	10.1021/ol4010195	doi.org/10.1021/ol4010195	Thermally Controlled Decarboxylative [4+2] Cycloaddition between Alkoxyoxazoles and Acrylic Acid: Expedient Access to 3-Hydroxypyridines		Org. Lett.	19	Sabot, C	FALSE	FALSE	FALSE	FALSE
8495	10.1590/S0100-40422012000500034	doi.org/10.1590/S0100-40422012000500034	STRATEGIES FOR STUDYING FREE-ENERGY CORRELATIONS OF SUZUKI ARYL-ARYL COUPLING: ELUCIDATING CATALYTIC CYCLES BY WAY OF THE HAMMETT EQUATION		Quim. Nova	19	Rosa, GR	FALSE	FALSE	FALSE	FALSE
8496	10.1021/ic201184x	doi.org/10.1021/ic201184x	Redox Trends in Terpyridine Nickel Complexes		Inorg. Chem.	19	Budnikova, YH	FALSE	FALSE	FALSE	FALSE
8497	10.1002/anie.201002745	doi.org/10.1002/anie.201002745	Selective cine Substitution of 1-Arylethenyl Acetates with Arylboron Reagents and a Diene/Rhodium Catalyst		Angew. Chem.-Int. Edit.	19	Kuwano, R	FALSE	FALSE	FALSE	FALSE
8498	10.1246/cl.2009.710	doi.org/10.1246/cl.2009.710	Ni-0-catalyzed Direct Amination of Anisoles Involving the Cleavage of Carbon-Oxygen Bonds		Chem. Lett.	19	Tobisu, M	FALSE	FALSE	FALSE	FALSE
8499	10.1080/00397910802656026	doi.org/10.1080/00397910802656026	Novel and Efficient Route for the Synthesis of 4-Aryl-Substituted 2(5H)-Furanones		Synth. Commun.	19	Desai, J	FALSE	FALSE	FALSE	FALSE
8500	10.1021/ja806244b	doi.org/10.1021/ja806244b	Cross-Coupling Reactions of Aryl Pivalates with Boronic Acids		J. Am. Chem. Soc.	19	Garg, NK	FALSE	FALSE	FALSE	FALSE
8501	10.1021/ja804222c	doi.org/10.1021/ja804222c	Bidirectional transfer of phenyl and methyl groups between Pt-IV and boron in platinum dipyridylborato complexes		J. Am. Chem. Soc.	19	Vedernikov, AN	FALSE	FALSE	FALSE	FALSE
8502	10.1246/cl.2007.236	doi.org/10.1246/cl.2007.236	Pd-catalyzed coupling reaction of allyl and propargyl ethers with chlorosilanes		Chem. Lett.	19	Terao, J	FALSE	FALSE	FALSE	FALSE
8503	10.1021/ja056132f	doi.org/10.1021/ja056132f	Zirconium-mediated S(N)2 ' substitution of allylic ethers: Regio- and stereospecific formation of protected allylic amines		J. Am. Chem. Soc.	19	Bergman, RG	FALSE	FALSE	FALSE	FALSE
8504	10.1021/ja0393170	doi.org/10.1021/ja0393170	Ruthenium-catalyzed functionalization of aryl carbon-oxygen bonds in aromatic ethers with organoboron compounds		J. Am. Chem. Soc.	19	Kakiuchi, F	FALSE	FALSE	FALSE	FALSE
8505	10.1016/j.tetasy.2003.10.034	doi.org/10.1016/j.tetasy.2003.10.034	A concise synthesis of 2-diarylphosphino-2 '-methoxy-1,1 '-binaphthalenes (MOPs) by simple resolution		Tetrahedron-Asymmetry	19	Zhang, ZG	FALSE	FALSE	FALSE	FALSE
8506	10.1016/S0040-4039(01)02221-3	doi.org/10.1016/S0040-4039(01)02221-3	Facile synthesis of polymer-supported cyclopentadienes		Tetrahedron Lett.	19	Leadbeater, NE	FALSE	FALSE	FALSE	FALSE
8507	10.1039/b207344g	doi.org/10.1039/b207344g	1-Phosphino-2-sulfenylferrocenes: efficient ligands in enantioselective palladium-catalyzed allylic substitutions and ring opening of 7-oxabenzonorbornadienes		Chem. Commun.	19	Carretero, JC	FALSE	FALSE	FALSE	FALSE
8508	10.1246/cl.2000.1272	doi.org/10.1246/cl.2000.1272	Modification of chiral monodentate phosphine (MOP) ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes		Chem. Lett.	19	Hayashi, T	FALSE	FALSE	FALSE	FALSE
8509	10.1021/ol005729r	doi.org/10.1021/ol005729r	Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with phenols		Org. Lett.	19	Lautens, M	FALSE	FALSE	FALSE	FALSE
8510	10.1039/a906086c	doi.org/10.1039/a906086c	Ni(acac)(2)-catalyzed cross-coupling and carbonylative cross-coupling of organostannanes with hypervalent iodonium salts		J. Chem. Soc.-Perkin Trans. 1	19	Kang, SK	FALSE	FALSE	FALSE	FALSE
8511	10.1016/S0040-4039(99)00247-6	doi.org/10.1016/S0040-4039(99)00247-6	Directed ortho metalation cross coupling route to indolo-4,5-quinodimethanes. Synthesis of benz[e]indoles		Tetrahedron Lett.	19	Snieckus, V	FALSE	FALSE	FALSE	FALSE
8512	10.1016/S0040-4039(97)01655-9	doi.org/10.1016/S0040-4039(97)01655-9	Control of reactive site in palladium-catalyzed Grignard cross-coupling of arenes containing both bromide and triflate		Tetrahedron Lett.	19		FALSE	FALSE	FALSE	FALSE
8513	10.1080/00397919708006790	doi.org/10.1080/00397919708006790	Palladium- and copper-catalyzed homocoupling of organolead compounds: Synthesis of biaryls and diynes		Synth. Commun.	19	Kang, SK	FALSE	FALSE	FALSE	FALSE
8514	10.1039/c39950001863	doi.org/10.1039/c39950001863	NICKEL-CATALYZED SUBSTITUTION-REACTIONS OF ALLYLIC COMPOUNDS WITH SOFT NUCLEOPHILES - AN EFFICIENT ALTERNATIVE TO PALLADIUM CATALYSIS		J. Chem. Soc.-Chem. Commun.	19		FALSE	FALSE	FALSE	FALSE
8515	10.1039/p19920003431	doi.org/10.1039/p19920003431	A STEREOSELECTIVE SYNTHESIS OF TRISUBSTITUTED ALKENES .2. THE NICKEL-CATALYZED COUPLING OF GRIGNARD-REAGENTS WITH 6-ALKYL-3,4-DIHYDRO-2H-PYRANS AND ACYCLIC ENOL ETHERS		J. Chem. Soc.-Perkin Trans. 1	19		FALSE	FALSE	FALSE	FALSE
8516	10.1021/jm00103a003	doi.org/10.1021/jm00103a003	A NOVEL ORALLY ACTIVE INHIBITOR OF IL-1 GENERATION - SYNTHESIS AND STRUCTURE-ACTIVITY-RELATIONSHIPS OF 3-(4-HYDROXY-1-NAPHTHALENYL)-2-PROPENOIC ACID-DERIVATIVES		J. Med. Chem.	19	TANAKA, M	FALSE	FALSE	FALSE	FALSE
8517	10.1002/cber.19911241222	doi.org/10.1002/cber.19911241222	A VERSATILE SYNTHESIS OF 1,4-DIENES - USE OF VINYL ETHERS AS VINYL CATION EQUIVALENTS		Chem. Ber.-Recl.	19		FALSE	FALSE	FALSE	FALSE
8518	10.1016/S0040-4039(00)79422-6	doi.org/10.1016/S0040-4039(00)79422-6	CARBON-CARBON BOND FORMATION BY THE REACTION OF ORGANOLITHIUMS WITH ALPHA-LITHIATED CYCLIC ENOL ETHERS - STEREOSELECTIVE SYNTHESIS OF BETA-HYDROXY AND GAMMA-HYDROXY DISUBSTITUTED AND TRI-SUBSTITUTED ALKENES		Tetrahedron Lett.	19		FALSE	FALSE	FALSE	FALSE
8519	10.1039/p19890002513	doi.org/10.1039/p19890002513	PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF TRIALKYLALUMINUMS WITH ARYL TRIFLATES - FACILE CONVERSION OF A PHENOLIC HYDROXY GROUP INTO AN ALKYL GROUP		J. Chem. Soc.-Perkin Trans. 1	19	HIROTA, K	FALSE	FALSE	FALSE	FALSE
8520	10.1246/bcsj.62.2913	doi.org/10.1246/bcsj.62.2913	HEXACARBONYLMOLYBDENUM(O)-INDUCED DECHALCOGENIZATION OF ALLYLIC SULFIDES, SULFONES, AND SELENIDES - NUCLEOPHILIC-SUBSTITUTION AND REDUCTIVE DECHALCOGENIZATION		Bull. Chem. Soc. Jpn.	19	MASUYAMA, Y	FALSE	FALSE	FALSE	FALSE
8521	10.1016/0040-4039(88)85233-X	doi.org/10.1016/0040-4039(88)85233-X	A SYNTHESIS OF ZOAPATANOL		Tetrahedron Lett.	19	KOCIENSKI, P	FALSE	FALSE	FALSE	FALSE
8522	10.1021/jo00210a051	doi.org/10.1021/jo00210a051	THREOPHOS - A NEW CHIRAL AMINOPHOSPHINE PHOSPHINITE (AMPP) LIGAND HIGHLY EFFICIENT IN ASYMMETRIC HYDROVINYLATION OF CYCLOHEXA-1,3-DIENE CATALYZED BY NICKEL-COMPLEXES		J. Org. Chem.	19	BUONO, G	FALSE	FALSE	FALSE	FALSE
8523	10.1021/jo00207a044	doi.org/10.1021/jo00207a044	REPLACEMENT OF METHYLTHIO FUNCTIONS ON AROMATIC HETEROCYCLES BY HYDROGEN, ALKYL, AND ARYL GROUPS VIA NICKEL-INDUCED GRIGNARD REACTIONS		J. Org. Chem.	19	WENKERT, E	FALSE	FALSE	FALSE	FALSE
8524	10.1016/S0040-4039(00)99926-X	doi.org/10.1016/S0040-4039(00)99926-X	REACTIVITY OF ALPHA,BETA-UNSATURATED ACETALS AND KETALS TOWARD ORGANO-LITHIUM REAGENTS IN PENTANE		Tetrahedron Lett.	19	MIOSKOWSKI, C	FALSE	FALSE	FALSE	FALSE
8525	10.1016/S0040-4039(00)87370-0	doi.org/10.1016/S0040-4039(00)87370-0	MIXED COUPLING BETWEEN VINYLIC SULFONES AND GRIGNARD-REAGENTS IN THE PRESENCE OF SALTS OF TRANSITION-METALS - STEREOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS		Tetrahedron Lett.	19		FALSE	FALSE	FALSE	FALSE
8526	10.1021/acs.oprd.0c00435	doi.org/10.1021/acs.oprd.0c00435	Safe and Expeditious Preparation of Ni(cod)(2) for Same-Day High-Throughput Screening	An asymmetric Ni-catalyzed reductive cross-coupling of (hetero)aryl iodides and benzylic chlorides has been developed to prepare enantioenriched 1,1-diarylalkanes. As part of these studies, a new chiral BiOxazoline ligand, 4-heptyl-BiOx (L1), was developed in order to obtain products in synthetically useful yield and enantioselectivity. The reaction tolerates a variety of heterocyclic coupling partners, including pyridines, pyrimidines, indoles, and piperidines.	Org. Process Res. Dev.	18	Baker, RT	FALSE	FALSE	FALSE	FALSE
8527	10.1134/S1070363220040258	doi.org/10.1134/S1070363220040258	Nickel-Catalyzed Phosphorylation of Tosylates	Direct arylation of cyclopentanones has been a longstanding challenge because of competitive self-aldol condensation and multiple arylations. Reported herein is a direct mono-a-C-H arylation of cyclopentanones with aryl bromides which is enabled by palladium/amine cooperative catalysis. This method is scalable and chemoselective with broad functional-group tolerance. Application to controlled sequential arylation of cyclopentanones has been also demonstrated.	Russ. J. Gen. Chem.	18	Li, CJ	FALSE	FALSE	FALSE	FALSE
8528	10.1021/acs.orglett.9b04445	doi.org/10.1021/acs.orglett.9b04445	Mechanistic Insights into La-Catalyzed Amidation of Aldehyde with Amine		Org. Lett.	18	Luo, G; Luo, Y	FALSE	FALSE	FALSE	FALSE
8529	10.1021/acs.orglett.9b02678	doi.org/10.1021/acs.orglett.9b02678	Arene Cyanation via Cation-Radical Accelerated-Nucleophilic Aromatic Substitution		Org. Lett.	18	Nicewicz, DA	FALSE	FALSE	FALSE	FALSE
8530	10.1021/acs.orglett.8b00319	doi.org/10.1021/acs.orglett.8b00319	Transformation of Substituted Glycals to Chiral Fused Aromatic Cores via Annulative pi-Extension Reactions with Arynes		Org. Lett.	18	Mukherjee, D	FALSE	FALSE	FALSE	FALSE
8531	10.1016/j.tetlet.2015.05.006	doi.org/10.1016/j.tetlet.2015.05.006	Asymmetric synthesis of diarylmethane derivatives by dynamic kinetic resolution		Tetrahedron Lett.	18	Wilkinson, JA	FALSE	FALSE	FALSE	FALSE
8532	10.14233/ajchem.2013.15232	doi.org/10.14233/ajchem.2013.15232	Synthesis and Crystal Structure of O-Methyldithiophosphato Nickel Complex [Ni(S2P{O}OCH3)(dppe)]		Asian J. Chem.	18	Li, YL	FALSE	FALSE	FALSE	FALSE
8533	10.1021/op200238p	doi.org/10.1021/op200238p	Multkilogram Scale-Up of a Reductive Alkylation Route to a Novel PARP Inhibitor		Org. Process Res. Dev.	18	Gillmore, AT	FALSE	FALSE	FALSE	FALSE
8534	10.1016/j.tetlet.2012.05.054	doi.org/10.1016/j.tetlet.2012.05.054	Simultaneous dehalogenation and hydrogenation reduction of halogen-heteroaromatic aldehydes		Tetrahedron Lett.	18	Ren, JM	FALSE	FALSE	FALSE	FALSE
8535	10.1002/aoc.1822	doi.org/10.1002/aoc.1822	Functionalization of some benzylthioarylboronic acids by benzylic lithiation of their N-butyldiethanolamine esters or lithium (triisopropoxy)borates		Appl. Organomet. Chem.	18	Klis, T	FALSE	FALSE	FALSE	FALSE
8536	10.1016/j.jorganchem.2011.03.038	doi.org/10.1016/j.jorganchem.2011.03.038	Room-temperature nickel-catalyzed amination of heteroaryl/aryl chlorides with Ni(II)-(sigma-Aryl) complex as precatalyst		J. Organomet. Chem.	18	Yang, LM	FALSE	FALSE	FALSE	FALSE
8537	10.1016/j.tetlet.2010.10.163	doi.org/10.1016/j.tetlet.2010.10.163	A new one-pot solvent-free synthesis of pyridinyl tosylates via diazotization of aminopyridines		Tetrahedron Lett.	18	Filimonov, VD	FALSE	FALSE	FALSE	FALSE
8538	10.1021/ol101493m	doi.org/10.1021/ol101493m	Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex		Org. Lett.	18	Sawamura, M	FALSE	FALSE	FALSE	FALSE
8539	10.1007/s10562-010-0383-3	doi.org/10.1007/s10562-010-0383-3	Highly Efficient Rhodium-Catalyzed Asymmetric Ring-Opening Reactions of Oxabenzonorbornadiene with Amine Nucleophiles		Catal. Lett.	18	Yang, DQ	FALSE	FALSE	FALSE	FALSE
8540	10.1021/ja9026902	doi.org/10.1021/ja9026902	Enantioselective alpha-Arylation of Aldehydes via Organo-SOMO Catalysis. An Ortho-Selective Arylation Reaction Based on an Open-Shell Pathway		J. Am. Chem. Soc.	18	MacMillan, DWC	FALSE	FALSE	FALSE	FALSE
8541	10.1021/ol900834c	doi.org/10.1021/ol900834c	A Desymmetrization Approach toward Highly Oxygenated cis-Decalins		Org. Lett.	18	Gromov, A	FALSE	FALSE	FALSE	FALSE
8542	10.1016/j.tetlet.2008.09.173	doi.org/10.1016/j.tetlet.2008.09.173	DABCO-catalyzed formation of 4-methoxy-1,3-dioxolan-2-ones and their synthetic applications in the aromatic electrophilic substitution		Tetrahedron Lett.	18	Hon, YS	FALSE	FALSE	FALSE	FALSE
8543	10.3987/COM-08-S(F)69	doi.org/10.3987/COM-08-S(F)69	CONSTRUCTION OF CYCLOPENTYL CARBINOLS FROM omega-TOSYLOXY-1-ALKENYL BORONATE ESTERS AND GRIGNARD REAGENTS		Heterocycles	18	Kobayashi, Y	FALSE	FALSE	FALSE	FALSE
8544	10.1021/ol702714y	doi.org/10.1021/ol702714y	Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles		Org. Lett.	18	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
8545	10.1021/ja800103z	doi.org/10.1021/ja800103z	Nickel-catalyzed asymmetric Negishi cross-couplings of secondary allylic chlorides with alkylzincs		J. Am. Chem. Soc.	18	Fu, GC	FALSE	FALSE	FALSE	FALSE
8546	10.1039/b809577a	doi.org/10.1039/b809577a	Phosphinates as new electrophilic partners for cross-coupling reactions		Org. Biomol. Chem.	18	Steel, PG	FALSE	FALSE	FALSE	FALSE
8547	10.1246/cl.2007.928	doi.org/10.1246/cl.2007.928	New preparative method of aryl tosylates by using organobismuth reagents		Chem. Lett.	18	Mukaiyama, T	FALSE	FALSE	FALSE	FALSE
8548	10.1002/qua.21034	doi.org/10.1002/qua.21034	Protonation of phenylboronic acid: Comparison of G3B3 and G2MP2 methods		Int. J. Quantum Chem.	18	Drew, MGB	FALSE	FALSE	FALSE	FALSE
8549	10.1007/s11172-006-0556-9	doi.org/10.1007/s11172-006-0556-9	Novel initiating systems based on nickel phosphine complexes		Russ. Chem. Bull.	18	Grishin, DF	FALSE	FALSE	FALSE	FALSE
8550	10.1021/jo050671l	doi.org/10.1021/jo050671l	Sequential Pd(II)-Pd(0) catalysis for the rapid synthesis of coumarins		J. Org. Chem.	18	Tunge, JA	FALSE	FALSE	FALSE	FALSE
8551	10.1016/j.polymer.2004.06.009	doi.org/10.1016/j.polymer.2004.06.009	New multiblock copolymers of sulfonated poly(4 '-phenyl-2,5-benzophenone) and poly(arylene ether sulfone) for proton exchange membranes. II		Polymer	18	McGrath, JE	FALSE	FALSE	FALSE	FALSE
8552	10.1021/ma0355453	doi.org/10.1021/ma0355453	Advances in Ni(0)-catalyzed coupling for the synthesis of polythiophenes and polyphenylenes		Macromolecules	18	Sheares, VV	FALSE	FALSE	FALSE	FALSE
8553	10.1016/S0957-4166(00)00361-X	doi.org/10.1016/S0957-4166(00)00361-X	Enantioselective synthesis of 5-substituted pipecolic acids using an intramolecular allylsilane-iminium ion cyclization		Tetrahedron: Asymmetry	18	Gelas-Mialhe, Y	FALSE	FALSE	FALSE	FALSE
8554	10.1016/S0040-4020(99)01095-9	doi.org/10.1016/S0040-4020(99)01095-9	Reaction of gem-dibromocyclopropanes or iodobenzofuran with trialkylmanganate		Tetrahedron	18	Oshima, K	FALSE	FALSE	FALSE	FALSE
8555	10.1016/S0040-4020(98)00809-6	doi.org/10.1016/S0040-4020(98)00809-6	Synthesis of biaryls via nickel-catalyzed cross-coupling reaction of arylboronic acids and aryl mesylates		Tetrahedron	18	Miyaura, N	FALSE	FALSE	FALSE	FALSE
8556	10.1246/cl.1998.1053	doi.org/10.1246/cl.1998.1053	New protocol for the site-selective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions		Chem. Lett.	18	Murai, S	FALSE	FALSE	FALSE	FALSE
8557	10.1021/om960750a	doi.org/10.1021/om960750a	Chirality transfer via the palladium-catalyzed cross-coupling reaction of optically active 2-cyclohexenylsilane: Stereochemical and mechanistic aspects		Organometallics	18	Hiyama, T	FALSE	FALSE	FALSE	FALSE
8558	10.1039/c39950001533	doi.org/10.1039/c39950001533	PALLADIUM-CATALYZED ASYMMETRIC HYDROSILYLATION OF STYRENES WITH A NEW CHIRAL MONODENTATE PHOSPHINE LIGAND		J. Chem. Soc.-Chem. Commun.	18		FALSE	FALSE	FALSE	FALSE
8559	10.1135/cccc19911744	doi.org/10.1135/cccc19911744	SYNTHESES OF SOME CIS-MONO-OLEFINIC INSECT SEX-PHEROMONES		Collect. Czech. Chem. Commun.	18	SHARMA, ML	FALSE	FALSE	FALSE	FALSE
8560	10.1016/S0040-4039(00)94557-X	doi.org/10.1016/S0040-4039(00)94557-X	PREPARATION OF 1-NAPHTHOLS FROM ACETYLENES AND ORTHO-PHTHALALDEHYDE USING LOW-VALENT TANTALUM AND NIOBIUM		Tetrahedron Lett.	18		FALSE	FALSE	FALSE	FALSE
8561	10.1021/jo00382a002	doi.org/10.1021/jo00382a002	ON THE REGIOSELECTIVITY AND STEREOSELECTIVITY OF BU4N[FE(CO)3NO]-CATALYZED ALLYLIC ALKYLATION		J. Org. Chem.	18	XU, YY	FALSE	FALSE	FALSE	FALSE
8562	10.1002/aocs.12484	doi.org/10.1002/aocs.12484	A Facile and Efficient Method for the Synthesis of Labeled and Unlabeled Very Long Chain Polyunsaturated Fatty Acids		J. Am. Oil Chem. Soc.	18	Hamberg, M	FALSE	FALSE	FALSE	FALSE
8563	10.1039/d1qo00380a	doi.org/10.1039/d1qo00380a	Tunable C-H arylation and acylation of azoles with carboxylic acids by Pd/Cu cooperative catalysis		Org. Chem. Front.	18	Chen, TQ	FALSE	FALSE	FALSE	FALSE
8564	10.1002/cjoc.202000500	doi.org/10.1002/cjoc.202000500	Pd-Catalyzed Ortho-Directed C-H Glycosylation of Arenes Using N-linked Bidentate Auxiliaries	The cross-coupling reaction of unactivated alkyl fluorides with alkyl Grignard reagents by a CoCl2/LiI/1,3-pentadiene catalytic system is described. The present reaction smoothly cleaved C-F bonds under mild conditions and achieved alkyl-alkyl cross-coupling even when sterically hindered tertiary alkyl Grignard reagents were employed. Since alkyl fluorides are inert toward many reagents and catalytic intermediates, the use of the present reaction enables a new multistep synthetic route to construct carbon frameworks by combining conventional transformations.	Chin. J. Chem.	17	He, G; Chen, G	FALSE	FALSE	FALSE	FALSE
8565	10.1021/acs.joc.7b02612	doi.org/10.1021/acs.joc.7b02612	Ag-Catalyzed Tandem Three-Component Reaction toward the Synthesis of Multisubstituted Imidazoles		J. Org. Chem.	17	Cao, H	FALSE	FALSE	FALSE	FALSE
8566	10.1016/j.poly.2013.09.041	doi.org/10.1016/j.poly.2013.09.041	New synthesis and structural characterization of O-aryldithiophosphato and O-alkyldithiophosphato nickel complexes with diphosphine ligands		Polyhedron	17	Li, YL	FALSE	FALSE	FALSE	FALSE
8567	10.14233/ajchem.2014.15478	doi.org/10.14233/ajchem.2014.15478	Synthesis, Characterization and Crystal Structure of Nickel Complex (dppv)Ni(C7H4NS2)(2)		Asian J. Chem.	17	Li, YL	FALSE	FALSE	FALSE	FALSE
8568	10.1021/ja2082087	doi.org/10.1021/ja2082087	Nickel-Catalyzed Asymmetric alpha-Arylation and Heteroarylation of Ketones with Chloroarenes: Effect of Halide on Selectivity, Oxidation State, and Room-Temperature Reactions		J. Am. Chem. Soc.	17	Hartwig, JF	FALSE	FALSE	FALSE	FALSE
8569	10.1021/jo200941r	doi.org/10.1021/jo200941r	Catalytic Asymmetric Synthesis of a Tertiary Benzylic Carbon Center via Phenol-Directed Alkene Hydrogenation		J. Org. Chem.	17	Caille, S	FALSE	FALSE	FALSE	FALSE
8570	10.1002/adsc.201000267	doi.org/10.1002/adsc.201000267	Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water		Adv. Synth. Catal.	17	Fu, GC	FALSE	FALSE	FALSE	FALSE
8571	10.1016/j.tet.2010.01.097	doi.org/10.1016/j.tet.2010.01.097	Straightforward stereoselective synthesis of polyfunctionalized cyclohexenols using a multicomponent approach		Tetrahedron	17	Basso, A	FALSE	FALSE	FALSE	FALSE
8572	10.1007/s10600-006-0247-7	doi.org/10.1007/s10600-006-0247-7	Total synthesis of miltirone		Chem. Nat. Compd.	17	Huang, WG	FALSE	FALSE	FALSE	FALSE
8573	10.1021/ol062208g	doi.org/10.1021/ol062208g	An efficient catalyst for Pd-catalyzed carbonylation of aryl arenesulfonates		Org. Lett.	17	Cai, CX	FALSE	FALSE	FALSE	FALSE
8574	10.1246/cl.2006.562	doi.org/10.1246/cl.2006.562	Facile synthesis of 4-arylsulfanylcoumarin library through reaction of 4-tosyloxycoumarins with thiols on solid phase		Chem. Lett.	17	Wu, J	FALSE	FALSE	FALSE	FALSE
8575	10.1021/ol0340641	doi.org/10.1021/ol0340641	New chemical cross-coupling between aryl halides and allylic acetates using a cobalt catalyst		Org. Lett.	17	Gosmini, C	FALSE	FALSE	FALSE	FALSE
8576	10.1021/jo0158377	doi.org/10.1021/jo0158377	Bis-cyclopentadienyl nickel (nickelocene): A convenient starting material for reactions catalyzed by Ni(0) phosphine complexes		J. Org. Chem.	17	Leadbeater, NE	FALSE	FALSE	FALSE	FALSE
8577	10.1021/ma0011791	doi.org/10.1021/ma0011791	Novel poly(paraphenylene)s via nucleophilic aromatic substitution of poly(4 '-fluoro-2,5-diphenyl sulfone)		Macromolecules	17	Sheares, VV	FALSE	FALSE	FALSE	FALSE
8578	10.1021/jo0006268	doi.org/10.1021/jo0006268	Palladium-catalyzed reactions of N-allylbenzotriazoles with amines and sulfonamides: A facile route to functionalized allylamines and N-allylsulfonamides		J. Org. Chem.	17	Katritzky, AR	FALSE	FALSE	FALSE	FALSE
8579	10.1002/jhet.5570360408	doi.org/10.1002/jhet.5570360408	Investigation of the reaction of N-substituted indolylborates: Palladium catalyzed cross-coupling reactions and intramolecular alkyl migration reactions		J. Heterocycl. Chem.	17	Ishikura, M	FALSE	FALSE	FALSE	FALSE
8580	10.1016/S0040-4039(98)00513-9	doi.org/10.1016/S0040-4039(98)00513-9	Synthesis of 2-phenyl-2-cycloalkenones via palladium-catalyzed tandem epoxide isomerization-intramolecular aldol condensation		Tetrahedron Lett.	17	Kulawiec, RJ	FALSE	FALSE	FALSE	FALSE
8581	10.1039/a705078j	doi.org/10.1039/a705078j	Nickel-catalysed cross-coupling reactions of aryl halides with organostannanes		J. Chem. Soc.-Perkin Trans. 1	17	Shirakawa, E	FALSE	FALSE	FALSE	FALSE
8582	10.1039/a700045f	doi.org/10.1039/a700045f	Regio- and enantio-selective allylic alkylation catalysed by a chiral monophosphine-palladium complex		Chem. Commun.	17	Hayashi, T	FALSE	FALSE	FALSE	FALSE
8583	10.1021/ja00132a039	doi.org/10.1021/ja00132a039	DIRECTED REGIOSELECTIVE AND STEREOSELECTIVE NICKEL-CATALYZED ADDITION OF ALKYL GRIGNARD-REAGENTS TO ALLYLIC ETHERS		J. Am. Chem. Soc.	17		FALSE	FALSE	FALSE	FALSE
8584	10.1016/0022-328X(94)24751-4	doi.org/10.1016/0022-328X(94)24751-4	SYNTHESES OF CYCLOHEXENONE DERIVATIVES BY THE RUTHENIUM COMPLEX-CATALYZED REACTIONS OF ALLYLIC COMPOUNDS WITH BETA-KETO-ESTERS		J. Organomet. Chem.	17		FALSE	FALSE	FALSE	FALSE
8585	10.1016/0022-328X(94)88138-3	doi.org/10.1016/0022-328X(94)88138-3	C-O BOND-CLEAVAGE AND OXIDATIVE ADDITION OF ALLYL CARboxYLATE TO RUTHENIUM(0) COMPLEX - ISOLATION OF (PI-ALLYL)(TRIFLUOROACETATO)TRIS(TRIETHYLPHOSPHINE)RUTHENIUM(II)		J. Organomet. Chem.	17	KOMIYA, S	FALSE	FALSE	FALSE	FALSE
8586	10.1016/0040-4039(94)88017-4	doi.org/10.1016/0040-4039(94)88017-4	PREPARATION OF ALKYLZINC BROMIDES USING A NEW MN/CU CATALYZED BROMINE-ZINC EXCHANGE-REACTION		Tetrahedron Lett.	17		FALSE	FALSE	FALSE	FALSE
8587	10.3891/acta.chem.scand.47-0716	doi.org/10.3891/acta.chem.scand.47-0716	LEWIS-ACID INDUCED ALKOXYALKYLATION OF ALLYLSILANES WITH ACETALS (THE SAKURAI REACTION) - REGIOCHEMICAL AND STEREOCHEMICAL ASPECTS		Acta Chem. Scand.	17		FALSE	FALSE	FALSE	FALSE
8588	10.1021/jo00253a049	doi.org/10.1021/jo00253a049	STUDIES ON THE ENANTIOSELECTIVITY IN BU4N[FE(CO)3NO]-CATALYZED NUCLEOPHILIC-SUBSTITUTION OF OPTICALLY-ACTIVE ALLYLIC CARBONATES WITH MALONATE		J. Org. Chem.	17		FALSE	FALSE	FALSE	FALSE
8589	10.1016/0022-328X(85)80323-5	doi.org/10.1016/0022-328X(85)80323-5	PALLADIUM-CATALYZED ASYMMETRIC COUPLING REACTIONS BETWEEN ALLYLIC ACETATES AND ORGANOZINC REAGENTS - MECHANISTIC IMPLICATIONS		J. Organomet. Chem.	17	FIAUD, JC	FALSE	FALSE	FALSE	FALSE
8590	10.1021/jo00220a029	doi.org/10.1021/jo00220a029	REGIOCHEMISTRY AND STEREOCHEMISTRY OF NICKEL-PROMOTED, CARBON CARBON BOND-FORMING REACTIONS OF CYCLIC SULFUR-COMPOUNDS		J. Org. Chem.	17	TIECCO, M	FALSE	FALSE	FALSE	FALSE
8591	10.3390/polym9020037	doi.org/10.3390/polym9020037	Polycondensation Resins by Flavonoid Tannins Reaction with Amines		Polymers	17	Pizzi, A	FALSE	FALSE	FALSE	FALSE
8592	10.1107/S2053229619012038	doi.org/10.1107/S2053229619012038	Synthesis, characterization, and crystal structures of organonickel(II) complexes coordinated to novel 1-bromo-2,6-bis{[(lambda(5)-phosphanylidene)-imino]methyl}benzene NCN-pincer ligands		Acta Crystallogr. Sect. C-Struct. Chem.	16	Guillet, GL	FALSE	FALSE	FALSE	FALSE
8593	10.1007/s11227-019-02896-5	doi.org/10.1007/s11227-019-02896-5	Application of combined kernel function artificial intelligence algorithm in mobile communication network security authentication mechanism		J. Supercomput.	16	Wang, ZR	FALSE	FALSE	FALSE	FALSE
8594	10.1080/00397911.2019.1584318	doi.org/10.1080/00397911.2019.1584318	A highly efficient and recyclable NiCl2(dppp)/PEG-400 system for Suzuki-Miyaura reaction of aryl chlorides with arylboronic acids		Synth. Commun.	16	Cai, MZ	FALSE	FALSE	FALSE	FALSE
8595	10.6023/A14120828	doi.org/10.6023/A14120828	Base Effects in Metal-Catalyzed Organic Reactions		Acta Chim. Sin.	16	Qin, GP	FALSE	FALSE	FALSE	FALSE
8596	10.1016/j.tet.2014.03.061	doi.org/10.1016/j.tet.2014.03.061	Total synthesis of ent-(-)-azonazine using a biomimetic direct oxidative cyclization and structural reassignment of natural product		Tetrahedron	16	Yao, ZJ	FALSE	FALSE	FALSE	FALSE
8597	10.1007/s10593-012-1083-2	doi.org/10.1007/s10593-012-1083-2	Synthesis and properties of 4-(3-aminothieno-[2,3-b]pyridin-2-yl)coumarins		Chem. Heterocycl. Compds.	16	Frasinyuk, MS	FALSE	FALSE	FALSE	FALSE
8598	10.3184/174751912X13249848731931	doi.org/10.3184/174751912X13249848731931	Synthesis of asymmetric semicarbazides using a coumarin ring		J. Chem. Res	16	Chai, LQ	FALSE	FALSE	FALSE	FALSE
8599	10.4155/FMC.10.266	doi.org/10.4155/FMC.10.266	ESF-COST High-Level Research Conference Natural Products Chemistry, Biology and Medicine III		Future Med. Chem.	16	Catino, A	FALSE	FALSE	FALSE	FALSE
8600	10.3184/030823410X12887880118791	doi.org/10.3184/030823410X12887880118791	Synthesis and photophysical properties of novel biphenyl derivatives containing furan and thiophene groups		J. Chem. Res	16	Yu, MX	FALSE	FALSE	FALSE	FALSE
8601	10.1016/j.jorganchem.2009.06.024	doi.org/10.1016/j.jorganchem.2009.06.024	Asymmetric synthesis of 1,2-bis(diphenylphosphino)-1-phenylethane via a chiral palladium template promoted hydrophosphination reaction		J. Organomet. Chem.	16	Leung, PH	FALSE	FALSE	FALSE	FALSE
8602	10.1002/hc.10006	doi.org/10.1002/hc.10006	A study on the selective phosphorylation and phosphinylation of hydroxyphenols		Heteroatom Chem.	16	Keglevich, G	FALSE	FALSE	FALSE	FALSE
8603	10.1021/ol016526l	doi.org/10.1021/ol016526l	NiCl2(PCy3)(2): A simple and efficient catalyst precursor for the Suzuki cross-coupling of aryl tosylates and arylboronic acids		Org. Lett.	16	Monteiro, AL	FALSE	FALSE	FALSE	FALSE
8604	10.1016/S0040-4039(00)01276-4	doi.org/10.1016/S0040-4039(00)01276-4	The asymmetric addition of trimethylsilylcyanide to aldehydes catalysed by anionic chiral nucleophiles. Part 2		Tetrahedron Lett.	16	Kagan, HB	FALSE	FALSE	FALSE	FALSE
8605	10.1016/S0040-4039(00)00384-1	doi.org/10.1016/S0040-4039(00)00384-1	Palladium-catalyzed cyanation reactions of aryl chlorides		Tetrahedron Lett.	16	Jin, FQ	FALSE	FALSE	FALSE	FALSE
8606	10.1021/ja980030q	doi.org/10.1021/ja980030q	Conservation of absolute configuration in the acyclic rhodium-catalyzed allylic alkylation reaction: Evidence for an enyl (sigma+pi) organorhodium intermediate		J. Am. Chem. Soc.	16	Evans, PA	FALSE	FALSE	FALSE	FALSE
8607	10.1016/S0040-4039(98)00414-6	doi.org/10.1016/S0040-4039(98)00414-6	Palladium-catalyzed cyanation of hindered, electron-rich aryl triflates by zinc cyanide		Tetrahedron Lett.	16	Rice, KC	FALSE	FALSE	FALSE	FALSE
8608	10.1016/S0040-4039(96)02510-5	doi.org/10.1016/S0040-4039(96)02510-5	Further developments in metal-catalysed C-C bond cleavage in allylic dimethyl malonate derivatives		Tetrahedron Lett.	16		FALSE	FALSE	FALSE	FALSE
8609	10.1351/pac199466102155	doi.org/10.1351/pac199466102155	COMBINED DIRECTED ORTHO-METALATION CROSS-COUPLING STRATEGIES - DESIGN FOR NATURAL PRODUCT SYNTHESIS		Pure Appl. Chem.	16	SNIECKUS, V	FALSE	FALSE	FALSE	FALSE
8610	10.1016/S0040-4039(00)60454-9	doi.org/10.1016/S0040-4039(00)60454-9	SYNTHESIS OF OPTICALLY-ACTIVE SECONDARY ALLYLIC ALCOHOLS FROM ALLYLSILANES VIA SUCCESSIVE ASYMMETRIC DIHYDROXYLATION (AD) AND PETERSON OLEFINATION REACTIONS		Tetrahedron Lett.	16		FALSE	FALSE	FALSE	FALSE
8611	10.1016/0022-328X(89)87015-9	doi.org/10.1016/0022-328X(89)87015-9	COPPER(I) PROMOTED C-C BOND FORMING REACTIONS - DIRECT ACTIVATION OF ALLYL ALCOHOLS		J. Organomet. Chem.	16		FALSE	FALSE	FALSE	FALSE
8612	10.1016/0022-328X(89)85259-3	doi.org/10.1016/0022-328X(89)85259-3	EFFECTIVE ACTIVATION OF ALLYLIC ETHERS BY BORON-OXIDE IN PALLADIUM CATALYZED ALLYLIC ALKYLATION		J. Organomet. Chem.	16	LU, XY	FALSE	FALSE	FALSE	FALSE
8613	10.1016/S0040-4039(00)86059-1	doi.org/10.1016/S0040-4039(00)86059-1	A STEREOSELECTIVE SYNTHESIS OF THE C(8)-C(20) FRAGMENT OF PREMONENSIN-B		Tetrahedron Lett.	16	KOCIENSKI, P	FALSE	FALSE	FALSE	FALSE
8614	10.1246/bcsj.60.1525	doi.org/10.1246/bcsj.60.1525	HEXACARBONYLMOLYBDENUM(0)-CATALYZED REACTION OF ALLYLIC CARBONATES WITH ARYLSULFONYL-STABILIZED CARBANIONS		Bull. Chem. Soc. Jpn.	16	MASUYAMA, Y	FALSE	FALSE	FALSE	FALSE
8615	10.1246/nikkashi.1985.416	doi.org/10.1246/nikkashi.1985.416	THE COUPLING REACTION OF GRIGNARD-REAGENTS WITH UNSATURATED SULFIDES CATALYZED BY NICKEL-COMPLEXES		Nippon Kagaku Kaishi	16	SUGIMURA, H	FALSE	FALSE	FALSE	FALSE
8616	10.1016/j.jscs.2020.101178	doi.org/10.1016/j.jscs.2020.101178	C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines	N-Heterocyclic carbene (NHC) ligands are attracting worldwide interest because of their considerable scope and potential in coordination/organometallic chemistry, catalysis and materials science and this is reflected by the exponential growth in the number of relevant publications. The focus of this review is on the synthesis, structures and reactivity of 3d metals complexes with bis-NHC, tripodal NHC and tetrapodal NHC ligands. These metals are particularly relevant because of their generally lower cost and availability. The literature coverage includes the year 2015. This review is organized in six major sections, five of them are dedicated to each of the families of NHC ligands covered (chelating NHC, bridging NHC, chelating and bridging NHC, tripodal NHC and tetrapodal NHC ligands). Each section is in turn divided into subparts, one for each 3d metal. The seventh section is concerned with the catalytic applications, and we first examine C-H and C-C bond formation, the latter including polymerization, oligomerization and cross coupling reactions (Suzuki, Heck...). This is followed by C-N, C-O, C-B, C-Si, C-S and C-Br bond formation reactions. Reduction reactions and the conversion of sugars into 5-hydroxymethylfurfural are also discussed. After the Conclusion, a paragraph provides an update of the most recent articles that appeared in the literature after completion of the review. (C) 2017 Elsevier B.V. All rights reserved.	J. Saudi Chem. Soc.	15	Habib, A	FALSE	FALSE	FALSE	FALSE
8617	10.1007/s11172-014-0808-z	doi.org/10.1007/s11172-014-0808-z	Synthesis of substituted naphthalenes by GaCl3-mediated cross-dimerization-fragmentation of 2-arylcyclopropane-1,1-dicarboxylates		Russ. Chem. Bull.	15	Tomilov, YV	FALSE	FALSE	FALSE	FALSE
8618	10.1002/cctc.201100181	doi.org/10.1002/cctc.201100181	Catalytic Hydrogenolysis of C-O Bonds in Aryl Ethers		ChemCatChem	15	Tobisu, M	FALSE	FALSE	FALSE	FALSE
8619	10.3987/COM-09-11803	doi.org/10.3987/COM-09-11803	REGIOSELECTIVE NITROALKYLATION OF THE 1-METHYL-2-QUINOLONE FRAMEWORK		Heterocycles	15	Asahara, M	FALSE	FALSE	FALSE	FALSE
8620	10.1016/j.poly.2006.10.006	doi.org/10.1016/j.poly.2006.10.006	Synthesis, NMR spectral and single crystal X-ray structural studies on Ni(II) dithiocarbamates with NiS2PN, NiS2PC, NiS2P2 chromophores: Crystal structures of (4-methylpiperazinecarbodithioato)(thiocyanato-N) (triphenylphosphine)nickel(II) and bis(triphenylphosphine) (4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate		Polyhedron	15	Ramalingam, K	FALSE	FALSE	FALSE	FALSE
8621	10.1055/s-2005-864790	doi.org/10.1055/s-2005-864790	Nickel(0) catalysts in organic synthesis		Synlett	15	Zhang, Z	FALSE	FALSE	FALSE	FALSE
8622	10.1002/pola.10745	doi.org/10.1002/pola.10745	A series of new high-performance materials based on poly[4 '-fluorophenyl-bis(4-phenyl)phosphine oxide]		J. Polym. Sci. Pol. Chem.	15	Sheares, VV	FALSE	FALSE	FALSE	FALSE
8623	10.1016/S0040-4039(02)00716-5	doi.org/10.1016/S0040-4039(02)00716-5	Suzuki cross-coupling of aryl halides with aryl boronic acids catalyzed by phosphine-free NiCl2 center dot 6H(2)O		Tetrahedron Lett.	15	Monteiro, AL	FALSE	FALSE	FALSE	FALSE
8624	10.1081/SCC-100104004	doi.org/10.1081/SCC-100104004	A novel synthesis of beta-aryl-alpha,beta-unsaturated amides		Synth. Commun.	15	Wang, YG	FALSE	FALSE	FALSE	FALSE
8625	10.1016/S0040-4039(00)00934-5	doi.org/10.1016/S0040-4039(00)00934-5	Et3B-promoted, Pd(0)-catalyzed allylation of active methylene compounds with allylic alcohols		Tetrahedron Lett.	15	Tamaru, Y	FALSE	FALSE	FALSE	FALSE
8626	10.1016/S0040-4039(99)01975-9	doi.org/10.1016/S0040-4039(99)01975-9	The reactivity of furanoid and pyranoid glycals towards aromatic Grignard reagents and a nickel catalyst		Tetrahedron Lett.	15	Tingoli, M	FALSE	FALSE	FALSE	FALSE
8627	10.1021/ol991133w	doi.org/10.1021/ol991133w	New access to 2,3-disubstituted quinolines through cyclization of o-alkynylisocyanobenzenes		Org. Lett.	15	Ito, Y	FALSE	FALSE	FALSE	FALSE
8628	10.1016/S0040-4039(98)00196-8	doi.org/10.1016/S0040-4039(98)00196-8	Direct homocoupling of aryl halides catalyzed by palladium		Tetrahedron Lett.	15	Lemaire, M	FALSE	FALSE	FALSE	FALSE
8629	10.1007/BF00695820	doi.org/10.1007/BF00695820	NERYLTRIETHYLAMMONIUM AND GERANYLTRIETHYLAMMONIUM HALIDES IN THE ALLYLATION OF SODIUM DIETHYL MALONATE - THE EFFECT OF THE LEAVING GROUP OF THE ALLYLATING REAGENT ON THE SELECTIVITY OF THE REACTION		Russ. Chem. Bull.	15	PETRUSHKINA, EA	FALSE	FALSE	FALSE	FALSE
8630	10.1039/c39870000429	doi.org/10.1039/c39870000429	A SYNTHETIC APPROACH TO ZOAPATANOL AND RELATED BICYCLIC ANALOGS		J. Chem. Soc.-Chem. Commun.	15		FALSE	FALSE	FALSE	FALSE
8631	10.1016/S0040-4039(00)84086-1	doi.org/10.1016/S0040-4039(00)84086-1	PALLADIUM-CATALYZED CARBONYLATION OF PROPARGYLIC CARBONATES - PREPARATION OF 2,3- AND 2,4-DIENYL CARboxYLATES		Tetrahedron Lett.	15	TSUJI, J	FALSE	FALSE	FALSE	FALSE
8632	10.1021/ja00334a060	doi.org/10.1021/ja00334a060	ON THE REGIOCHEMISTRY OF METAL-CATALYZED ALLYLIC ALKYLATION - A MODEL		J. Am. Chem. Soc.	15	TROST, BM	FALSE	FALSE	FALSE	FALSE
8633	10.1246/cl.1982.1641	doi.org/10.1246/cl.1982.1641	A CONVENIENT METHOD FOR THE STEREOSPECIFIC SYNTHESIS OF (E)-3-ALKEN-1-OLS UTILIZING THE RING-OPENING REACTION OF 2,3-DIHYDROFURAN WITH ORGANOCUPRATES		Chem. Lett.	15	FUJISAWA, T	FALSE	FALSE	FALSE	FALSE
8634	10.1177/17475198211063806	doi.org/10.1177/17475198211063806	One-pot nickel-catalyzed cross-coupling of (Het)arylammonium salts prepared in situ and organozinc reagents		J. Chem. Res	15	Huang, YM	FALSE	FALSE	FALSE	FALSE
8635	10.1039/d1qo00100k	doi.org/10.1039/d1qo00100k	Nickel-catalyzed alkenylboration of alkenylarenes to access homoallylic boronic esters		Org. Chem. Front.	15	Zhang, C	FALSE	FALSE	FALSE	FALSE
8636	10.1016/j.tetlet.2016.02.069	doi.org/10.1016/j.tetlet.2016.02.069	3,4-Bis-phosphanyl-1H-pyrrole derivatives via direct electrophilic phosphanylation of 1-tert-butyl-1H-pyrrole		Tetrahedron Lett.	15	Smaliy, RV	FALSE	FALSE	FALSE	FALSE
8637	10.1134/S1070363219120405	doi.org/10.1134/S1070363219120405	LiCl-Accelerated Nickel Catalyzed Cross-Coupling of Aryl Tosylates with the Aryl Grignard Reagents		Russ. J. Gen. Chem.	14	He, XY; Li, Y	FALSE	FALSE	FALSE	FALSE
8638	10.3987/COM-07-S(U)24	doi.org/10.3987/COM-07-S(U)24	Efficient synthesis of 6-substituted purine derivatives using Pd-catalyzed cross-coupling reactions with 2 '-deoxyguanosine O-6-tosylate		Heterocycles	14	Nagatsugi, F	FALSE	FALSE	FALSE	FALSE
8639	10.1039/b600540c	doi.org/10.1039/b600540c	Facile synthesis of chromeno[4,3-b]quinolin-6-ones from unexpected reactions of aryl isocyanides with 4-chloro-2-oxo-2H-chromene-3-carbaldehyde		Org. Biomol. Chem.	14	Wu, J	FALSE	FALSE	FALSE	FALSE
8640	10.1039/b108808d	doi.org/10.1039/b108808d	Rhodium-catalysed addition of arylboronic acids to oxabenzonorbornadienes		Chem. Commun.	14	Murakami, M	FALSE	FALSE	FALSE	FALSE
8641	10.1002/pola.1331	doi.org/10.1002/pola.1331	Synthesis of poly (p-phenylene) macromonomers and multiblock copolymers		J. Polym. Sci. Pol. Chem.	14	Sheares, VV	FALSE	FALSE	FALSE	FALSE
8642	10.1016/S0040-4039(99)01255-1	doi.org/10.1016/S0040-4039(99)01255-1	Reductions of aryl perfluorosulfonates with dimethylamine center dot borane (Me2NH center dot BH3) catalyzed by Pd(0): an operationally simple, inexpensive, and general protocol		Tetrahedron Lett.	14	Lipshutz, BH	FALSE	FALSE	FALSE	FALSE
8643	10.1039/a802876a	doi.org/10.1039/a802876a	Rhodium complex-catalysed allylic alkylation of allylic acetates		New J. Chem.	14	Takeuchi, R	FALSE	FALSE	FALSE	FALSE
8644	10.1007/s002890050237	doi.org/10.1007/s002890050237	Synthesis and characterization of ABA-triblock copolymers with poly(ethylene glycol) segments and LC-segments		Polym. Bull.	14	Schulze, U	FALSE	FALSE	FALSE	FALSE
8645	10.1016/0032-3861(96)00195-4	doi.org/10.1016/0032-3861(96)00195-4	Synthesis of adamantyl and benzoxazole substituted poly(m-phenylene)s via the nickel catalysed coupling of aryl chlorides		Polymer	14	Mathias, LJ	FALSE	FALSE	FALSE	FALSE
8646	10.1016/0040-4039(96)00482-0	doi.org/10.1016/0040-4039(96)00482-0	A synthesis of biaryls via nickel(0)-catalyzed cross-coupling reaction of chloroarenes with phenylboronic acids		Tetrahedron Lett.	14		FALSE	FALSE	FALSE	FALSE
8647	10.1039/c39950000717	doi.org/10.1039/c39950000717	THE REACTION OF [NI(ACAC)(2)] WITH TRIETHOXYSILANE IN THE PRESENCE OF PPH(3) - A NEW METHOD FOR SYNTHESIS OF [NI(ACAC)ET(PPH(3))]		J. Chem. Soc.-Chem. Commun.	14	MARCINIEC, B	FALSE	FALSE	FALSE	FALSE
8648	10.1515/znb-1991-1018	doi.org/10.1515/znb-1991-1018	INTERMEDIATES IN THE PALLADIUM-CATALYZED REACTION OF 1,3-DIENES, .6. A SOLID-STATE NMR SPECTROSCOPIC INVESTIGATION OF BUTADIENE COMPLEXES OF NICKEL, PALLADIUM AND PLATINUM		Z.Naturforsch.(B)	14		FALSE	FALSE	FALSE	FALSE
8649	10.1016/S0040-4039(01)80770-X	doi.org/10.1016/S0040-4039(01)80770-X	ALLYL ETHYL CARBONATE PALLADIUM-(0), A NEW SYSTEM FOR THE ONE-STEP CONVERSION OF ALCOHOLS INTO ALLYL ETHERS UNDER NEUTRAL CONDITIONS		Tetrahedron Lett.	14		FALSE	FALSE	FALSE	FALSE
8650	10.1016/S0040-4039(00)85219-3	doi.org/10.1016/S0040-4039(00)85219-3	RUTHENIUM-CATALYZED SYNTHESIS OF 2-ACETOXYALLYL CARBONATES - A SYNTHON FOR PALLADIUM-CATALYZED 2-ACETOXYALLYLATION OF CARBONUCLEOPHILES		Tetrahedron Lett.	14		FALSE	FALSE	FALSE	FALSE
8651	10.1016/0022-328X(83)85087-6	doi.org/10.1016/0022-328X(83)85087-6	ALLYLIC ALKYLATIONS CATALYZED ON NICKEL		J. Organomet. Chem.	14	CUVIGNY, T	FALSE	FALSE	FALSE	FALSE
8652	10.1139/v82-098	doi.org/10.1139/v82-098	ELECTROPHILIC CYCLIZATION OF POLYENE ALLYLSILANES - SYNTHESIS OF ALBICANYL ACETATE		Can. J. Chem.-Rev. Can. Chim.	14		FALSE	FALSE	FALSE	FALSE
8653	10.1039/d1cc04915a	doi.org/10.1039/d1cc04915a	Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling		Chem. Commun.	14	Espinet, P	FALSE	FALSE	FALSE	FALSE
8654	10.1016/j.tetlet.2018.02.073	doi.org/10.1016/j.tetlet.2018.02.073	Synthesis of a biofuel target through conventional organic chemistry		Tetrahedron Lett.	13	Cosimbescu, L	FALSE	FALSE	FALSE	FALSE
8655	10.1107/S1600536811032326	doi.org/10.1107/S1600536811032326	trans-Chlorido(phenanthren-9-yl)bis-(triphenylphosphane)nickel(II)		Acta Crystallogr. Sect. E.-Crystallogr. Commun.	13	Lei, XY	FALSE	FALSE	FALSE	FALSE
8656	10.1002/nadc.201178359	doi.org/10.1002/nadc.201178359	The palladium of little brother: News from the Nickel-Catalysis.		Nachr. Chem.	13	Koester, DC	FALSE	FALSE	FALSE	FALSE
8657	10.1016/j.tetlet.2010.10.114	doi.org/10.1016/j.tetlet.2010.10.114	Chemoselective O-tert-butoxycarbonylation of phenols using 6,7-dimethoxyisoquinoline as a novel organocatalyst		Tetrahedron Lett.	13	Takahata, H	FALSE	FALSE	FALSE	FALSE
8658	10.1107/S1600536805005064	doi.org/10.1107/S1600536805005064	Bis[1,3-bis(diphenylphosphino)propane-kappa P-2,P ']-nickel(0)		Acta Crystallogr. Sect. E.-Struct Rep. Online	13	Davies, SC	FALSE	FALSE	FALSE	FALSE
8659	10.1016/j.tetlet.2004.05.074	doi.org/10.1016/j.tetlet.2004.05.074	A convenient synthetic approach to bis-functionalised quaterfluorenes		Tetrahedron Lett.	13	Suranna, GP	FALSE	FALSE	FALSE	FALSE
8660	10.1055/s-2003-37028	doi.org/10.1055/s-2003-37028	Inhibition of 5 alpha-reductase activity by diarylheptanoids from Alpinia officinarum		Planta Med.	13	Lee, SK	FALSE	FALSE	FALSE	FALSE
8661	10.1016/S0040-4039(99)00439-6	doi.org/10.1016/S0040-4039(99)00439-6	Cross coupling of vinyl triflates and alkyl Grignard reagents catalyzed by Nickel(0)-complexes		Tetrahedron Lett.	13	Busacca, CA	FALSE	FALSE	FALSE	FALSE
8662	10.1039/a801674g	doi.org/10.1039/a801674g	Novel concepts in directed biaryl synthesis - Part 69 - Palladium-mediated intramolecular acylation reaction in the attempted phosphinylation of a sterically hindered trifluoromethylsulfonyloxybiaryl carboxylic ester		Chem. Commun.	13	Bringmann, G	FALSE	FALSE	FALSE	FALSE
8663	10.1016/S0040-4039(97)10240-4	doi.org/10.1016/S0040-4039(97)10240-4	Ni(0) catalyzed reactions of aryl and vinyl halides with alkenes and alkynes		Tetrahedron Lett.	13	Iyer, S	FALSE	FALSE	FALSE	FALSE
8664	10.1016/S0040-4039(00)73192-3	doi.org/10.1016/S0040-4039(00)73192-3	STEREOSELECTIVE SYNTHESIS OF (PLUS-OR-MINUS)-CLAVUKERIN-A AND (PLUS-OR-MINUS)-ISOCLAVUKERIN-A BASED ON PALLADIUM-CATALYZED REDUCTIVE CLEAVAGE OF ALKENYLCYCLOPROPANES WITH FORMIC-ACID		Tetrahedron Lett.	13	SHIMIZU, I	FALSE	FALSE	FALSE	FALSE
8665	10.1016/0040-4039(93)85089-F	doi.org/10.1016/0040-4039(93)85089-F	2-(N,N-DIETHYLCARBAMOYLOXY)ALLYLSILANE - DUAL REACTIVITY WITH ALPHA,ALPHA'-ACETONE DIANION AND ALLENE 1,2-DIPOLE EQUIVALENCY		Tetrahedron Lett.	13		FALSE	FALSE	FALSE	FALSE
8666	10.1002/jhet.5570290509	doi.org/10.1002/jhet.5570290509	PALLADIUM-CATALYZED OR RUTHENIUM-CATALYZED SYNTHESIS OF 2-PHENYLINDOLES		J. Heterocycl. Chem.	13	IZUMI, T	FALSE	FALSE	FALSE	FALSE
8667	10.1016/0040-4039(91)80851-V	doi.org/10.1016/0040-4039(91)80851-V	NICKEL-CATALYZED CROSS-COUPLING OF UNACTIVATED NEOPENTYL IODIDES WITH GRIGNARD-REAGENTS		Tetrahedron Lett.	13		FALSE	FALSE	FALSE	FALSE
8668	10.1007/BF00959380	doi.org/10.1007/BF00959380	OMICRON-COMPLEXES OF TRANSITION-METALS IN ORGANIC-SYNTHESIS .1. CROSS-COUPLING OF ORGANOTITANIUM COMPOUNDS WITH ALLYL HALIDES IN THE PRESENCE OF PALLADIUM COMPLEXES			13	KASATKIN, AN	FALSE	FALSE	FALSE	FALSE
8669	10.1038/d41586-021-01205-6	doi.org/10.1038/d41586-021-01205-6	Unprecedented reactions for molecular editing		Nature	13	Avestro, AJ	FALSE	FALSE	FALSE	FALSE
8670	10.1002/ps.4517	doi.org/10.1002/ps.4517	Improved synthetic route to quinoxyfen photometabolite 2-chloro-10-fluorochromeno[2,3,4-de]quinoline		Pest Manag. Sci.	13	Johnson, PL	FALSE	FALSE	FALSE	FALSE
8671	10.1055/s-0036-1592031	doi.org/10.1055/s-0036-1592031	Cluster Preface: C-O And Related Bond Activation		Synlett	12	Tobisu, M; Chatani, N	FALSE	FALSE	FALSE	FALSE
8672	10.5059/yukigoseikyokaishi.73.649	doi.org/10.5059/yukigoseikyokaishi.73.649	Nickel-catalyzed Reductive Cross-Coupling Reaction		J. Synth. Org. Chem. Jpn.	12		FALSE	FALSE	FALSE	FALSE
8673	10.1016/j.tetlet.2013.01.040	doi.org/10.1016/j.tetlet.2013.01.040	Total synthesis of (+/-)-mimosifoliol by lateral lithiation		Tetrahedron Lett.	12	Wilkinson, JA	FALSE	FALSE	FALSE	FALSE
8674	10.1007/s11094-011-0605-z	doi.org/10.1007/s11094-011-0605-z	A NEW PREPARATIVE METHOD FOR THE SYNTHESIS OF 6-[3-(1-ADAMANTYL)-4-METHOXYPHENYL]-2-NAPHTHOIC ACID		Pharm. Chem. J.	12	Tribulovich, VG	FALSE	FALSE	FALSE	FALSE
8675	10.3724/SP.J.1088.2011.01018	doi.org/10.3724/SP.J.1088.2011.01018	Cross-Coupling Reaction of Benzylic Halides with Allyltributylstannane Catalyzed by Cu(OTf)(2)		Chin. J. Catal.	12	Yu, XQ	FALSE	FALSE	FALSE	FALSE
8676	10.1166/jnn.2010.2343	doi.org/10.1166/jnn.2010.2343	Catalytic Sol-Gel Co-Polycondensation of Para-Substituted Phenylsilanes and Bis(silyl)phenylene to Robust Organosilicas Using Colloidal Nickel Nanoparticles		J. Nanosci. Nanotechnol.	12	Woo, HG	FALSE	FALSE	FALSE	FALSE
8677	10.1055/s-2003-41008	doi.org/10.1055/s-2003-41008	Efficient synthesis of (+/-)-dihydrorhipocephalin, a bioactive terpenoid from Caribbean marine algae of the Genera Penicillus and Udotea		Synlett	12	Parrain, JL	FALSE	FALSE	FALSE	FALSE
8678	10.1039/a702954c	doi.org/10.1039/a702954c	Efficient coupling reactions of allylamines with soft nucleophiles using nickel-based catalysts		Chem. Commun.	12		FALSE	FALSE	FALSE	FALSE
8679	10.1007/s002890050132	doi.org/10.1007/s002890050132	Synthesis of side chain liquid crystalline poly(vinyl ether)s containing 2,2'-dimethyl-4-methoxy-4'-[undecanyloxy-4-benzoyl]ester biphenyl side group		Polym. Bull.	12	Lee, M	FALSE	FALSE	FALSE	FALSE
8680	10.1016/S0040-4039(96)02065-5	doi.org/10.1016/S0040-4039(96)02065-5	Biaryl formation using the Suzuki protocol: Considerations of base, halide, and protecting group.		Tetrahedron Lett.	12	Benbow, JW	FALSE	FALSE	FALSE	FALSE
8681	10.1021/jo00266a047	doi.org/10.1021/jo00266a047	A HIGHLY STEREOSELECTIVE AND ITERATIVE APPROACH TO ISOPRENOID CHAINS - SYNTHESIS OF HOMOGERANIOL, HOMOFARNESOL, AND HOMOGERANYLGERANIOL		J. Org. Chem.	12	KOCIENSKI, P	FALSE	FALSE	FALSE	FALSE
8682	10.1016/S0040-4039(00)80811-4	doi.org/10.1016/S0040-4039(00)80811-4	CATALYZED IPSO REPLACEMENT OF PHENOLIC ETHERS BY GRIGNARD-REAGENTS		Tetrahedron Lett.	12	JOHNSTONE, RAW	FALSE	FALSE	FALSE	FALSE
8683	10.1246/nikkashi.1987.1227	doi.org/10.1246/nikkashi.1987.1227	CHEMISTRY OF CYCLIC PHOSPHORUS-COMPOUNDS .2. SYNTHESIS OF DOUGLAS-FIR TUSSOCK MOTH SEX-PHEROMONE FROM CYCLIC PHOSPHONIUM SALT		Nippon Kagaku Kaishi	12	YAMAMOTO, I	FALSE	FALSE	FALSE	FALSE
8684	10.1016/S0040-4039(00)96043-X	doi.org/10.1016/S0040-4039(00)96043-X	FUNCTIONALIZED KETONES BY IRON MEDIATED REACTION OF GRIGNARD-REAGENTS WITH ACYL CHLORIDES		Tetrahedron Lett.	12		FALSE	FALSE	FALSE	FALSE
8685	10.1039/c39840000968	doi.org/10.1039/c39840000968	ACCELERATION OF THE REDUCTIVE ELIMINATION STEP IN PD-CATALYZED ALLYLIC ALKYLATION BY ALLYLIC SUBSTRATES		J. Chem. Soc.-Chem. Commun.	12	KUROSAWA, H	FALSE	FALSE	FALSE	FALSE
8686	10.1002/hlca.19800630427	doi.org/10.1002/hlca.19800630427	NICKEL-CATALYZED ASYMMETRIC ALKYLATION OF SOME CHIRAL AND ACHIRAL ALLYLIC ALCOHOLS		Helv. Chim. Acta	12	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
8687	10.1016/j.chempr.2020.05.022	doi.org/10.1016/j.chempr.2020.05.022	Precise and Accelerated Polymer Synthesis via Mixed-Ligand and Mixed-RAFT Agents	The activation and cleavage of benzyl fluorides by the electrophilic organofluorophosphonium catalyst, [(C6F5)(3)PF][B(C6F5)(4)], is reported and used for the preparation of 1,1-diarylalkanes (37 examples) and substituted aryl homoallylic alkenes (14 examples). This procedure involves mild conditions, avoids harmful waste, and is compatible with a range of substituted arenes and allylic silanes.	Chem	11	Percec, V	FALSE	FALSE	FALSE	FALSE
8688	10.2174/138527281909150507104019	doi.org/10.2174/138527281909150507104019	Untitled		Curr. Org. Chem.	11	Pineschi, M	FALSE	FALSE	FALSE	FALSE
8689	10.1016/S0040-4039(03)00075-3	doi.org/10.1016/S0040-4039(03)00075-3	Nickel catalyzed cross-coupling of modified alkyl and alkenyl Grignard reagents with aryl- and heteroaryl nitriles: activation of the C-CN bond		Tetrahedron Lett.	11	Dankwardt, JW	FALSE	FALSE	FALSE	FALSE
8690	10.1039/a804198i	doi.org/10.1039/a804198i	Synthesis of N-heterocycles via lactam-derived ketene aminal phosphates. Asymmetric synthesis of cyclic amino acids.		Chem. Commun.	11	Nicolaou, KC	FALSE	FALSE	FALSE	FALSE
8691	10.1080/00397919608004631	doi.org/10.1080/00397919608004631	Ruthenium-catalyzed allylic substitution of allylic cyclic carbonates		Synth. Commun.	11	Kang, SK	FALSE	FALSE	FALSE	FALSE
8692	10.1016/0040-4039(95)00082-N	doi.org/10.1016/0040-4039(95)00082-N	PALLADIUM-CATALYZED CROSS-COUPLING OF ALLYLIC CARBONATES WITH ALKENYLFLUOROSILANES IN THE ABSENCE OF FLUORIDE-ION		Tetrahedron Lett.	11		FALSE	FALSE	FALSE	FALSE
8693	10.1080/00397919508015448	doi.org/10.1080/00397919508015448	A CONVENIENT SYNTHESIS OF N-ARYLANTHRANILIC ACIDS USING ULTRASONICS IN THE ULLMANN-GOLDBERG CONDENSATION		Synth. Commun.	11		FALSE	FALSE	FALSE	FALSE
8694	10.1080/00397919508015850	doi.org/10.1080/00397919508015850	NI(II)-CATALYZED REGIOSTEREOSELECTIVE AND DIASTEREOSELECTIVE ALLYLATION OF GRIGNARDS REAGENTS TO CHIRAL ALLYLIC CYCLIC CARBONATES		Synth. Commun.	11	KANG, SK	FALSE	FALSE	FALSE	FALSE
8695	10.1135/cccc19911916	doi.org/10.1135/cccc19911916	STEREOSELECTIVE SYNTHESIS OF (Z)-7-OCTADECENYL ISOVALERATE, A SEX-PHEROMONE OF EUPROCTIS-SIMILIS-XANTHOCAMPA		Collect. Czech. Chem. Commun.	11	SHARMA, ML	FALSE	FALSE	FALSE	FALSE
8696	10.1039/c39880000975	doi.org/10.1039/c39880000975	NICKEL-INDUCED CONVERSION OF CARBON NITROGEN INTO CARBON CARBON BONDS - ONE-STEP TRANSFORMATIONS OF ARYL, QUATERNARY AMMONIUM-SALTS INTO ALKYLARENES AND BIARYLS		J. Chem. Soc.-Chem. Commun.	11	WENKERT, E	FALSE	FALSE	FALSE	FALSE
8697	10.1246/cl.1987.1373	doi.org/10.1246/cl.1987.1373	NEW BIS(BENZENE-1,2-DITHIOLATO)NI(II) COMPLEXES HAVING INTENSE NEAR-INFRARED ABSORPTIONS		Chem. Lett.	11		FALSE	FALSE	FALSE	FALSE
8698	10.1246/cl.1986.407	doi.org/10.1246/cl.1986.407	ULTRASOUNDS IN SYNTHETIC REACTIONS .4. ULLMANN-TYPE COUPLING REACTION OF ARYL TRIFLUOROMETHANESULFONATES CATALYZED BY INSITU-GENERATED LOW VALENT NICKEL-COMPLEXES		Chem. Lett.	11	YAMASHITA, J	FALSE	FALSE	FALSE	FALSE
8699	10.1016/S0040-4039(01)90263-1	doi.org/10.1016/S0040-4039(01)90263-1	STEREOCHEMICAL AND MECHANISTIC ASPECTS OF THE NICKEL-COMPLEX CATALYZED FORMATION OF OLEFINS FROM ALLYLIC ALCOHOLS AND GRIGNARD-REAGENTS		Tetrahedron Lett.	11	FELKIN, H	FALSE	FALSE	FALSE	FALSE
8700	10.1016/S0022-328X(00)84071-1	doi.org/10.1016/S0022-328X(00)84071-1	REDUCTION OF CARBON-DIOXIDE BY REDUCING METAL (ZINC, ALUMINUM)-TITANOCENE CHLORIDE SYSTEM - NEW METHOD FOR PREPARING CP2TI(CO)2 AND SYNTHESIS OF TITANIUM (III) CARBONATE COMPLEX		J. Organomet. Chem.	11	DEMERSEMAN, B	FALSE	FALSE	FALSE	FALSE
8701	10.1038/s41929-019-0407-3	doi.org/10.1038/s41929-019-0407-3	From glovebox to benchtop		Nat. Catal.	10	Garg, NK	FALSE	FALSE	FALSE	FALSE
8702	10.1126/science.aaw5825	doi.org/10.1126/science.aaw5825	When two metal atoms are better than one		Science	10	Weix, D	FALSE	FALSE	FALSE	FALSE
8703	10.1016/j.chempr.2018.05.012	doi.org/10.1016/j.chempr.2018.05.012	Ketone C-C Bond Activation Meets the Suzuki-Miyaura Cross-coupling		Chem	10	Larrosa, I	FALSE	FALSE	FALSE	FALSE
8704	10.1055/s-0033-1339297	doi.org/10.1055/s-0033-1339297	Gram-Scale Ketone Synthesis by Direct Reductive Coupling of Alkyl Iodides with Acid Chlorides		Synthesis	10	Qian, Q	FALSE	FALSE	FALSE	FALSE
8705	10.1021/ja8009428	doi.org/10.1021/ja8009428	Catalytic asymmetric Hiyama cross-couplings of racemic alpha-bromo esters		J. Am. Chem. Soc.	10	Fu, GC	FALSE	FALSE	FALSE	FALSE
8706	10.1166/jnn.2007.084	doi.org/10.1166/jnn.2007.084	Dry sol-gel polycondensation of hydrosilanes to organosilicas catalyzed by colloidal nickel nanoparticles		J. Nanosci. Nanotechnol.	10	Woo, HG	FALSE	FALSE	FALSE	FALSE
8707	10.1166/jnn.2006.017	doi.org/10.1166/jnn.2006.017	Dry sol-gel condensation of p-X-C6H4SiH3 (X = H, CH3, CH3O, F, Cl) to organosilica p-X-C6H4SiO3 using nickelocene		J. Nanosci. Nanotechnol.	10	Woo, HG	FALSE	FALSE	FALSE	FALSE
8708	10.1039/b209855e	doi.org/10.1039/b209855e	Chemoselective transfer hydrodechlorination of aryl chlorides catalyzed by Cp*Rh complexes		Chem. Commun.	10	Fujita, K	FALSE	FALSE	FALSE	FALSE
8709	10.1016/S0040-4039(97)00707-7	doi.org/10.1016/S0040-4039(97)00707-7	Suzuki-type coupling of chloroarenes with arylboronic acids catalysed by nickel complexes		Tetrahedron Lett.	10	Indolese, AF	FALSE	FALSE	FALSE	FALSE
8710	10.1246/cl.1997.617	doi.org/10.1246/cl.1997.617	Reduction of aryl mesylates catalyzed by nickel complexes		Chem. Lett.	10	Sasaki, K	FALSE	FALSE	FALSE	FALSE
8711	10.1016/0040-4039(96)00660-0	doi.org/10.1016/0040-4039(96)00660-0	Directed regioselective Ni-catalyzed alkylation and hydride addition of allylic ethers. A remarkable turnover in regioselectivity		Tetrahedron Lett.	10		FALSE	FALSE	FALSE	FALSE
8712	10.1016/0304-5102(93)85084-7	doi.org/10.1016/0304-5102(93)85084-7	NOVEL PHOSPHINE PALLADIUM COMPLEX-CATALYZED REGIOSELECTIVE ALLYLATION OF A GRIGNARD-REAGENT			10	TAKUMA, Y	FALSE	FALSE	FALSE	FALSE
8713	10.1016/S0040-4039(00)86058-X	doi.org/10.1016/S0040-4039(00)86058-X	A STEREOSELECTIVE SYNTHESIS OF TRI-SUBSTITUTED ALKENES - THE NICKEL-CATALYZED COUPLING OF GRIGNARD-REAGENTS WITH 6-ALKYL-3,4-DIHYDRO-2H-PYRANS		Tetrahedron Lett.	10	KOCIENSKI, P	FALSE	FALSE	FALSE	FALSE
8714	10.1246/cl.1987.2203	doi.org/10.1246/cl.1987.2203	CARBON-CARBON BOND FORMATION BY CROSS COUPLING OF ENOL PHOSPHATES OR ENOL TRIFLATES WITH ORGANOMANGANESE COMPOUNDS		Chem. Lett.	10		FALSE	FALSE	FALSE	FALSE
8715	10.1080/00397918608056418	doi.org/10.1080/00397918608056418	A SIMPLIFIED WITTIG SYNTHESIS USING A SOLID-LIQUID TRANSFER PROCESS .6. SYNTHESIS OF GAMMA-UNSATURATED ALCOHOLS FROM AROMATIC AND HETEROAROMATIC ALDEHYDES		Synth. Commun.	10		FALSE	FALSE	FALSE	FALSE
8716	10.1016/S0040-4039(00)84380-4	doi.org/10.1016/S0040-4039(00)84380-4	OXIDATION OF ALCOHOLS WITH ALLYL METHYL CARBONATE BY MEANS OF RUTHENIUM CATALYST		Tetrahedron Lett.	10		FALSE	FALSE	FALSE	FALSE
8717	10.1039/c39840000309	doi.org/10.1039/c39840000309	CHIRAL (MACROCYCLIC) SULFIDES AS LIGANDS FOR NICKEL CATALYZED CARBON CARBON BOND FORMATION		J. Chem. Soc.-Chem. Commun.	10		FALSE	FALSE	FALSE	FALSE
8718	10.1016/j.chempr.2021.09.006	doi.org/10.1016/j.chempr.2021.09.006	Accessing aliphatic alcohols for metallaphotoredox catalyzed C(sp(3))-arylation		Chem	10	Beil, SB	FALSE	FALSE	FALSE	FALSE
8719	10.6023/cjoc202100028	doi.org/10.6023/cjoc202100028	Nickel/N-Heterocyclic Carbene Catalysis Catalyzed Enantioselective Suzuki-Miyaura Coupling of Ketones		Chin. J. Org. Chem.	10	Yin, GY	FALSE	FALSE	FALSE	FALSE
8720	10.1038/nchem.2851	doi.org/10.1038/nchem.2851	ORGANOMETALLIC MECHANISMS Measuring up with the early metals		Nat. Chem.	10	Tonks, IA	FALSE	FALSE	FALSE	FALSE
8721	10.1002/anie.201609757	doi.org/10.1002/anie.201609757	Variable Time Normalization Analysis: General Graphical Elucidation of Reaction Orders from Concentration Profiles		Angew. Chem.-Int. Edit.	10	Bures, J	FALSE	FALSE	FALSE	FALSE
8722	10.1016/S0040-4039(02)01600-3	doi.org/10.1016/S0040-4039(02)01600-3	Palladium-catalyzed cross coupling of Grignard reagents with in situ-derived enol phosphates		Tetrahedron Lett.	9	Miller, JA	FALSE	FALSE	FALSE	FALSE
8723	10.1016/S0040-4039(00)77678-7	doi.org/10.1016/S0040-4039(00)77678-7	TOTAL SYNTHESIS OF MARINE DITERPENE FUSCOL		Tetrahedron Lett.	9		FALSE	FALSE	FALSE	FALSE
8724	10.1021/jo00259a029	doi.org/10.1021/jo00259a029	DETERMINATION OF THE ENANTIOMERIC PURITY OF CHIRAL ALLYL ALCOHOLS AND ALLYL ETHERS BY PT-195 NMR-SPECTROSCOPY		J. Org. Chem.	9	SALVADORI, P	FALSE	FALSE	FALSE	FALSE
8725	10.1016/0040-4039(88)85165-7	doi.org/10.1016/0040-4039(88)85165-7	HOMOALLYLIC ALCOHOLS FROM (Z)-1,4-DI(2-TETRAHYDROPYRANYLOXY)-BUT-2-ENE AND GRIGNARD-REAGENTS - A PROMISING 4-CARBON HOMOLOGATION		Tetrahedron Lett.	9	MENICAGLI, R	FALSE	FALSE	FALSE	FALSE
8726	10.1016/S0040-4039(00)86039-6	doi.org/10.1016/S0040-4039(00)86039-6	A MILD PROCEDURE FOR SYNTHESIS OF THE CYTOCHALASIN ISOINDOLONE - ALLYL SELENIDES FROM ALLYL SILANES AND PHSESE+(CH3)PHBF4-		Tetrahedron Lett.	9	VEDEJS, E	FALSE	FALSE	FALSE	FALSE
8727	10.1016/S0040-4039(01)80135-0	doi.org/10.1016/S0040-4039(01)80135-0	ACTIVATION OF C-H BONDS IN SATURATED-HYDROCARBONS - THE FORMATION OF BIS-(TRIPHENYLPHOSPHINE) (ETA-ALKADIENE)RHENIUM TRIHYDRIDES FROM N-ALKANES, AND THEIR SELECTIVE CONVERSION INTO THE CORRESPONDING 1-ALKENES		Tetrahedron Lett.	9	BAUDRY, D	FALSE	FALSE	FALSE	FALSE
8728	10.1021/ja00397a048	doi.org/10.1021/ja00397a048	STEREOCHEMICAL ASPECTS OF THE NICKEL-CATALYZED ALKYLATION OF ALLYLIC ALCOHOLS		J. Am. Chem. Soc.	9	CONSIGLIO, G	FALSE	FALSE	FALSE	FALSE
8729	10.1016/S0040-4039(01)82980-4	doi.org/10.1016/S0040-4039(01)82980-4	NICKEL-CATALYZED CROSS-COUPLING OF ARYL PHOSPHATES WITH GRIGNARD AND ORGANO-ALUMINUM REAGENTS - SYNTHESIS OF ALKYLBENZENES, ALKENYLBENZENES AND ARYLBENZENES FROM PHENOLS		Tetrahedron Lett.	9		FALSE	FALSE	FALSE	FALSE
8730	10.6023/cjoc202100076	doi.org/10.6023/cjoc202100076	Ni-Catalyzed Ligand-Controlled Regiodivergent Reductive Dicarbofunctionalization of Alkenes		Chin. J. Org. Chem.	9	Chu, LL	FALSE	FALSE	FALSE	FALSE
8731	10.6023/cjoc202000074	doi.org/10.6023/cjoc202000074	Synthesis of Trifluoromethylarenes via Nickel-Mediated C-O Bond Activation of Phenol Derivatives	A homocoupling method for organohalides and organosulfonates promoted by samarium metal and HMPA, and catalyzed by NiCl2 has been developed. Various organohalides (benzyl, aryl, heterocyclic, alkenyl and alkyl halides), -haloacetophenones, and phenyl organosulfonates were tolerated, and the reaction afforded coupling products with high efficiency. Excellent chemoselectivity was exhibited between halides and other groups, such as -COOH, -NO2, halogen, heterocyclic ring, ester, and ketone groups. The stereoselectivity suggested that the reaction mechanism might involve an organosamarium species.	Chin. J. Org. Chem.	8	Dai, HX	FALSE	FALSE	FALSE	FALSE
8732	10.6023/cjoc202000059	doi.org/10.6023/cjoc202000059	Light-Promoted Nickel Catalysis: Etherification of Aryl Electrophiles with Alcohols Catalyzed by Ni(II)/Aryl Complex	New dihalosalicylamides and trihalophenol derivatives have been synthesized from easily available O-(3,n-dihalophenyl) N,N-diethylcarbamates by using a directed ortho-metalation (DoM) strategy. The o-lithiation reactions with sBuLi take place regioselectively at the doubly activated C-2 position, which demonstrates the ability of O-carbamates as directed metalating groups. In addition, highly functionalized arylnitriles were accessed from organolithium intermediates by using a tandem transnitrilation/SNAr reaction sequence.	Chin. J. Org. Chem.	8	Xiao, WJ	FALSE	TRUE	FALSE	FALSE
8733	10.1051/e3sconf/20183804026	doi.org/10.1051/e3sconf/20183804026	Thermal distribution analysis of inner defects in TSV			8	Jiang, CK	FALSE	FALSE	FALSE	FALSE
8734	10.1039/b107736h	doi.org/10.1039/b107736h	Palladium-catalysed asymmetric arylation of tert-cyclobutanols via enantioselective C-C bond cleavage		Chem. Commun.	8	Uemura, S	FALSE	FALSE	FALSE	FALSE
8735	10.1246/cl.1991.2017	doi.org/10.1246/cl.1991.2017	NICKEL(0)-CATALYZED REDUCTION OF ARYL TRIFLATES WITH ZINC POWDER AND METHANOL		Chem. Lett.	8	SASAKI, K	FALSE	FALSE	FALSE	FALSE
8736	10.1246/cl.1990.2205	doi.org/10.1246/cl.1990.2205	NOVEL CONSTRUCTION OF 4H-2,3-DIHYDRO-1,3-BENZOTHIAZINE RING VIA NICKEL(0)-CATALYZED REACTION OF ORTHO-IODOBENZAMIDE OR ORTHO-IODOBENZONITRILE WITH THIOUREAS		Chem. Lett.	8	TAKAGI, K	FALSE	FALSE	FALSE	FALSE
8737	10.1080/00397918908052600	doi.org/10.1080/00397918908052600	THE USE OF ULTRASOUND IN THE SYNTHESIS OF N-ARYLANTHRANILIC ACIDS BY THE ULLMANN GOLDBERG REACTION		Synth. Commun.	8		FALSE	FALSE	FALSE	FALSE
8738	10.1246/cl.1984.1505	doi.org/10.1246/cl.1984.1505	PREPARATION OF 1-ALKENYL PHENYL SULFIDES BY THE NICKEL(II)-COMPLEXES CATALYZED COUPLING REACTION OF 3-METHOXY-1-PHENYLTHIO-1-PROPENE WITH GRIGNARD-REAGENTS		Chem. Lett.	8		FALSE	FALSE	FALSE	FALSE
8739	10.1021/ja00502a074	doi.org/10.1021/ja00502a074	NICKEL-INDUCED CONVERSION OF CARBON-OXYGEN INTO CARBON-CARBON BONDS - ONE-STEP TRANSFORMATIONS OF ENOL ETHERS INTO OLEFINS AND ARYL ETHERS INTO BIARYLS		J. Am. Chem. Soc.	8	WENKERT, E	FALSE	FALSE	FALSE	FALSE
8740	10.1055/s-0039-1691241	doi.org/10.1055/s-0039-1691241	Nickel-Catalyzed Mono-Selective alpha-Arylation of Acetone with Aryl Chlorides and Phenol Derivatives	Alcohols are promising sustainable starting materials because they can be obtained from abundant and indigestible biomass. The substitution of expensive noble metals in catalysis by earth abundant 3d metals, such as Mn, Fe, or Co, (nonprecious or base metals) is a related key concept with respect to sustainability. Here, we report on the first cobalt-catalyzed alkylation of secondary alcohols with primary alcohols. Easy-to-synthesize and easy-to-activate PN5P-pincer-ligand-stabilized Co complexes developed in our laboratory mediate the reaction most efficiently. The catalysis is applicable to a broad substrate scope and proceeds under relatively mild conditions. We have even demonstrated the coupling of a variety of purely aliphatic alcohols with a base or nonprecious metal catalyst. Mechanistic studies indicate that the reaction follows the borrowing hydrogen or hydrogen autotransfer concept.	Synthesis	7	Abou Derhamine, S	FALSE	FALSE	FALSE	FALSE
8741	10.1021/jo00206a036	doi.org/10.1021/jo00206a036	DIELS-ALDER REACTIONS OF CYCLOALKENONES .4. SHORT SYNTHESES OF SOME CADINENES		J. Org. Chem.	7	FRINGUELLI, F	FALSE	FALSE	FALSE	FALSE
8742	10.1039/c39830001215	doi.org/10.1039/c39830001215	THE ASYMMETRIC CYCLIZATION OF SUBSTITUTED PENT-4-ENALS BY A CHIRAL RHODIUM PHOSPHINE CATALYST		J. Chem. Soc.-Chem. Commun.	7	JAMES, BR	FALSE	FALSE	FALSE	FALSE
8743	10.1080/00397919508015477	doi.org/10.1080/00397919508015477	AN IMPROVED PROCEDURE FOR THE CYANATION OF ARYL TRIFLATES - A CONVENIENT SYNTHESIS OF 6-CYANO-1,2,3,4-TETRAHYDROISOQUINOLINE		Synth. Commun.	6	SELNICK, HG	FALSE	FALSE	FALSE	FALSE
8744	10.1039/c39810000681	doi.org/10.1039/c39810000681	ASYMMETRIC-SYNTHESIS IN THE NICKEL-COMPLEX-CATALYZED FORMATION OF OLEFINS FROM ALLYL ALCOHOLS AND GRIGNARD-REAGENTS		J. Chem. Soc.-Chem. Commun.	6	CHEREST, M	FALSE	FALSE	FALSE	FALSE
8745	10.1016/S0022-328X(00)93827-0	doi.org/10.1016/S0022-328X(00)93827-0	CROSS-COUPLING REACTION OF SECONDARY ALKYL GRIGNARD-REAGENTS WITH ALLYLIC ALCOHOLS CATALYZED BY DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)-FERROCENE]PALLADIUM(II)		J. Organomet. Chem.	6	HAYASHI, T	FALSE	FALSE	FALSE	FALSE
8746	10.1039/c39790000637	doi.org/10.1039/c39790000637	NICKEL-INDUCED CONVERSION OF CARBON-SULFUR INTO CARBON-CARBON BONDS - ONE-STEP TRANSFORMATIONS OF ENOL SULFIDES INTO OLEFINS AND BENZENETHIOL DERIVATIVES INTO ALKYLARENES AND BIARYLS		J. Chem. Soc.-Chem. Commun.	6	WENKERT, E	FALSE	FALSE	FALSE	FALSE
8747	10.1039/c39870000241	doi.org/10.1039/c39870000241	AN EFFICIENT AND STEREOSELECTIVE SYNTHESIS OF HOMOALLYLIC ALCOHOLS VIA NICKEL-CATALYZED COUPLING OF 5-ALKYL-2,3-DIHYDROFURANS WITH GRIGNARD-REAGENTS		J. Chem. Soc.-Chem. Commun.	5		FALSE	FALSE	FALSE	FALSE
8748	10.1016/S0040-4039(01)82007-4	doi.org/10.1016/S0040-4039(01)82007-4	SCOPE OF THE PALLADIUM-CATALYZED COUPLING REACTION OF ORGANOMETALLICS WITH ALLYLIC ELECTROPHILES - EFFECT OF THE LEAVING GROUP		Tetrahedron Lett.	5	NEGISHI, E	FALSE	FALSE	FALSE	FALSE
8749	10.1023/A:1022529227102	doi.org/10.1023/A:1022529227102	Mesogenic triad with a benzoyl group		Russ. J. Organ. Chem.	3	Bol'shakov, MN	FALSE	FALSE	FALSE	FALSE
8750	10.1021/jo00196a043	doi.org/10.1021/jo00196a043	TRIFLUOROACETIC ACID-CATALYZED ALLYLIC PHENYLATION OF ALPHA-METHYLALLYL ACETATE, ALPHA-METHYLALLYL TRIFLUOROACETATE, AND ALPHA-METHYLALLYL ALCOHOL WITH BENZENE		J. Org. Chem.	3	FUJIWARA, Y	FALSE	FALSE	FALSE	FALSE
8751	10.1007/BF00960306	doi.org/10.1007/BF00960306	CROSS-COUPLING REACTION OF PHENYLTRIETHOXYTITANIUM WITH ALLYL HALIDES CATALYZED BY PALLADIUM COMPLEXES			3	TOLSTIKOV, GA	FALSE	FALSE	FALSE	FALSE
8752	10.1039/c39840000617	doi.org/10.1039/c39840000617	A SYNTHESIS OF CONJUGATED DIENES FROM AROMATIC, 5-MEMBERED HETEROCYCLES		J. Chem. Soc.-Chem. Commun.	3	WENKERT, E	FALSE	FALSE	FALSE	FALSE
8753	10.1016/S0040-4039(00)94062-0	doi.org/10.1016/S0040-4039(00)94062-0	SYNTHESIS OF CONJUGATED DIENES BY NICKEL-CATALYZED REACTIONS OF 1,3-ALKADIEN-2-YL PHOSPHATES WITH GRIGNARD-REAGENTS		Tetrahedron Lett.	3	CLAESSON, A	FALSE	FALSE	FALSE	FALSE
8754	10.1039/c5sc90021b	doi.org/10.1039/c5sc90021b	Cobalt co-catalysis for cross-electrophile coupling: diarylmethanes from benzyl mesylates and aryl halides (vol 6, pg 1115, 2015)		Chem. Sci.	1	Weix, DJ	FALSE	FALSE	FALSE	FALSE
8755	10.1021/jo048572f	doi.org/10.1021/jo048572f	NiCl2(dppe)-catalyzed cross-coupling of aryl mesylates, arenesulfonates, and halides with arylboronic acids (vol 69, pg 3447, 2004)		J. Org. Chem.	1		FALSE	FALSE	FALSE	FALSE
8756	10.1039/c6sc90082h	doi.org/10.1039/c6sc90082h	Cobalt co-catalysis for cross-electrophile coupling: diarylmethanes from benzyl mesylates and aryl halides (vol 6, pg 1115, 2015)		Chem. Sci.	1	Weix, DJ	FALSE	FALSE	FALSE	FALSE
8757	10.1021/jacs.7b01463	doi.org/10.1021/jacs.7b01463	Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex		J. Am. Chem. Soc.	0		FALSE	FALSE	FALSE	FALSE